OpenLLM-France/wikimedia huggingface dataset:
# Methylthiomethyl ether

In organic chemistry a methylthiomethyl (MTM) ether is a protective group for hydroxyl groups. Hydroxyl groups are present in many chemical compounds and they must be protected during oxidation, acylation, halogenation, dehydration and other reactions to which they are susceptible.
Many kinds of protective groups for hydroxyl groups have been developed and used in organic chemistry, but the number of protective groups for tertiary hydroxyl groups, which are susceptible to acid-catalyzed dehydration, is still small because of their poor reactiveness. They can be easily protected with MTM ethers and recovered in good yield.
To introduce an MTM ether to a hydroxyl group, two methods are mainly used. One is a typical Williamson ether synthesis using an MTM halide as an MTM resource and sodium hydride (NaH) as a base. The other is a special method, in which dimethyl sulfoxide (DMSO) and acetic anhydride (Ac$_2$O) are used. In this case, the reaction proceeds with Pummerer rearrangement:
MTM ethers have another advantage. They are removed by neutral (but toxic) mercuric chloride, to which most other ethers are stable. As a result, the selective deprotection of polyfunctional molecules becomes possible using MTM ethers as the protective groups for their hydroxyl groups.

## Alcohol protection

Methylthiomethyl (MTM) group is used as a protecting group for alcohols in organic synthesis. This type of alcohol protecting group is robust under mild acidic reaction conditions.

### Most common protection methods

* Treatment of alcohol with sodium hydride and methylthiomethyl halide
* Dimethyl sulfoxide (DMSO) and acetic acid (AcOH) in acetic anhydride (Ac$_2$O) at ambient temperature

### Most common deprotection methods

* Mercury (II) chloride (HgCl$_2$); calcium carbonate (CaCO$_3$) is used as an acid scavenger for acid sensitive substrates
* Iodomethane (MeI) in presence of sodium bicarbonate (NaHCO$_3$) at elevated temperatures (this type of reaction is generally carried out in acetone/H$_2$O solution)
* Magnesium iodide (MgI$_2$) and acetic anhydride (Ac$_2$O) in ether at ambient temperature
# Koumala Airport

Koumala Airport (IATA: KOL) was a rural airstrip in the Bamingui-Bangoran prefecture of the Central African Republic.
Aerial photos show the remains of an airstrip overgrown with trees.
# Ross Dunning

Ross William Dunning AC FCILT FAIM FIEAust FIRSE (born 4 March 1942) served as the Commissioner for Railways in Queensland, President of the Australian Railways Association and as chairman and director for a number of public and listed companies including Chairman of Port of Brisbane Corporation, Chairman of Port of Townsville Limited, Chairman of the Central Queensland Ports Authority, Director General of Administrative Services for the Queensland Government from 1990 to 1994, Director of Brisbane Airport Corporation Pty Ltd. and many others.
In 2002 he was appointed a Companion of the Order of Australia (AC) "For service to the development of transport systems, particularly the development of modern and efficient rail services, to the export economy, to the construction industry, and to the community through support for cultural activities and charitable organisations."
# Huitzila

Huitzila may refer to the following places in Mexico:
* Huitzila, Hidalgo
* Huitzila, Zacatecas
# KABA

KABA may refer to:
* Kaba Group, locks and security company
* KABA (FM), a radio station (90.3 FM) licensed to serve Louise, Texas, United States
* KNIK-LD, a low-power television station (channel 6) licensed to serve Anchorage, Alaska, United States, which held the call sign KABA-LP from June to September 2009
* KVNT, a radio station (1020 AM) licensed to serve Eagle River, Alaska, which held the call sign KABA from March 2008 to June 2009
* KABA (Radio personality)
# Paik's Mysterious Kitchen

Paik's Mysterious Kitchen (Korean: 백종원의 미스터리 키친) is a South Korean show. It airs on SBS., following Baek Jong-won's Top 3 Chef King and Baek Jong-won's Food Truck after the Baek Jong-won's Alley Restaurant, the fourth part of the Baek Jong-won series. The programs were broadcast on May 18 and 25, 2019.

## Broadcast time

| Broadcast period | Airtime | Airtime | Type |
| May 18, 2019 - May 25, 2019 | Saturday | Saturday | Pilot |
| May 18, 2019 - May 25, 2019 | 1 | 18:40－17:30 | Pilot |
| May 18, 2019 - May 25, 2019 | 2 | 17:30－18:10 | Pilot |

## Format

Mysterious Kitchen is a new cooking show featuring elements of mystery. Each week, two mysterious chefs cook their own signature dish in four-walled kitchens. Baek Jong-won, the famous businessman and food expert, and Kim Hee-chul, a K-pop star/food enthusiast, guess who the chef is based on various clues: how to understand ingredients, what technique they use, how to handle the fire, etc. Then, five culinary experts taste the finished dishes and vote for the winner. The show will entertain you by showing the masterful culinary skills, providing a vicarious satisfaction on delicious food, and making you solve the mystery. Plus, you can get the recipe for the winning dish.

## Program list

| Episode | Broadcast date | Food Evaluation Group | Rating |
| Pilot | May 18, 2019 | Lee Yeon-bok, Lee Won-il, Fabrizio Ferrari, Yoo Min-ju, Park Sang Hyun | 3.8% |
| Pilot | May 25, 2019 | Lee Yeon-bok, Lee Won-il, Fabrizio Ferrari, Yoo Min-ju, Park Sang Hyun | 4.3% |
# Utami

Utami is both a given name and a surname. Notable people with the name include:
* Ayu Utami (born 1968), Indonesian writer
* Utami Hayashishita (林下 詩美, born 1998), Japanese professional wrestler
* Utami Kinard (born 1951), Indonesian badminton player
* Putu Dini Jasita Utami (born 1994), Indonesian beach volleyball player
* Trie Utami (born 1968), Indonesian singer
# Mauricius Ó Leaáin

Mauricius Ó Leaáin was Bishop of Kilmacduagh, Ireland, from 1254 to 1284. Ó Leaáin (O'Leane, Lane, Linnane) is associated with the Oranmore–Clarenbridge area of County Galway. He was the first of three men of the surname to become bishop of Kilmacduagh.
Ó Leaáin was elected before 15 May 1254 and received possession of the temporalities after that date. He died before 16 January 1284.
# Methylthioribulose 1-phosphate dehydratase

The enzyme methylthioribulose 1-phosphate dehydratase (EC .2.1.109) catalyzes the chemical reaction
    5-(methylsulfanyl)-D)ribulose 1-phosphate $\rightleftharpoons$ 5-(methylthio)-2,3-dioxopentyl phosphate + H$_2$
This enzyme belongs to the family of lyases, specifically the hydro-lyases, which cleave carbon-oxygen bonds. The systematic name of this enzyme class is 5-methyl-5-thio-D-ribulose-1-phosphate 4-hydro-lyase [5-(methylthio)-2,3-dioxopentyl-phosphate-forming]. Other names in common use include 1-PMT-ribulose dehydratase, and S-methyl-5-thio-D-ribulose-1-phosphate hydro-lyase. This enzyme participates in methionine metabolism.
# Koumala

Koumala is a town in the Bamingui-Bangoran Prefecture of the northern Central African Republic.

## Transport

The town is served by Koumala Airport.
# Poet Laureate of Hawaii

The Poet Laureate of Hawaii or Ka Haku-Mele O Hawaii is the poet laureate for the U.S. state of Hawaii. Prior to statehood Don Blanding, originally from Oklahoma, was unofficially referred to as the poet laureate of Hawaii. In 1951 Hawaii Territorial Senator Thelma Akana Harrison in concurrent resolution 28, declared Lloyd Stone, who was originally from California, poet laureate. When the modern program was established, Native Hawaiian Kealoha was appointed on May 3, 2012, and he is the first poet laureate for the state of Hawaii, serving through 2022. In January 2023, Brandy Nālani McDougall began her appointment as Poet Laureate of Hawaii, which she will serve through 2025.
* Poet Laureates of Hawaii
* Kealoha
* Brandy Nālani McDougall
# Sampleville, Ohio

Sampleville (also Kitsom Corners, Kitson Corner) is an unincorporated community in Preble County, Ohio, United States.
# KABAL

KABAL (or sometimes K.A.B.A.L. — Knights and Berserkers and Legerdemain) is a role-playing game published by Kabal Gaming Systems in 1982. Critics did not like the mathematical formulae needed to play the game.

## Description

KABAL is a fantasy role-playing system. The game includes three booklets: a 24-page "Referee's Guide", a 34-page "Player's Guide", and a 36-page "KABAL Magic Spells". The rules, which are largely derivative of popular role-playing games of the time, cover character creation, skills, combat, magic, 70 spells, monsters, and treasure.
KABAL is notable for the mathematical formulae needed to play the game. For example, to determine a character's height and weight:
* Height (in meters): Roll 20 six-sided dice, then take the square root of the result and multiply it by 21.5.
* Weight (in kilograms):
** Take the character's height arrived at in Step 1, cube it and multiply the result by the character's Strength. Reserve this number.
** Roll 20 six-sided dice, square the result and divide it by the character's Endurance score, then raise it to the .75 power. Add that result to the reserved number from Step 2.1 to arrive at the character's weight.

## Publication history

KABAL was designed by Ernest T. Hams, with a cover by Darlene, and published by Kabal Gaming Systems in 1982 as a boxed set with three digest-sized books and 12 reference sheets.

## Reception

In Issue 5 of Fantasy Gamer, Scott Haring noted "the system suffers from terrible organization and offers next to nothing new." Haring also pointed out the complex mathematics needed for the game, pointing out, "Standard equipment with this game should not only include paper, dice, and pencils, but a good calculator as well." Despite this, Haring did find a few bright spots, such as the realistic times given for missile fire, commenting, "A beginning character needs five minutes to ready a windlass crossbow for shooting, and can shoot a bow just once every 12 seconds. Experience can cut that time down, but it strikes me as being realistic without being unduly complicated." Haring concluded, "as a stand-alone system, KABAL is complicated, fraught with problems and overly difficult to learn ... for now, I cannot recommend it."
In his 1990 book The Complete Guide to Role-Playing Games, game critic Rick Swan called KABAL "hopelessly derivative", and derided the "mountain of mathematics" needed to play the game. Swan concluded by giving the game a very poor rating of one 1 out of 4, asking "This is supposed to be fun?"
In his 1991 book Heroic Worlds, Lawrence Schick called the game a "Lame fantasy system requiring numerous and complex mathematical calculations."
# More of the Night

Professional ratings :
| Review scores ||
| Source | Rating |
| allmusic | |
| Select | |
More of the Night is the fifteenth studio album by American R&B/Soul group The Whispers. It was released on February 6, 1990 as the follow-up to their massively successful 1987 album, Just Gets Better with Time. While it did not sell quite as well as its predecessor, More of the Night did include several hits, including three R&B top 10 tunes: "My Heart Your Heart," "Innocent," and "Is it Good to You." The album went Gold.
Written by Gary Taylor, "My Heart Your Heart" was originally performed in 1988 by Taylor himself, with exactly the same musical backing and arrangement used here, and appeared as a bonus track on his Compassion album. Taylor actually produced the version by The Whispers, who turned it into a big hit.

## Track listing (compact disc)

* "More Of The Night" (Joel Davis) (6:02)
* "My Heart Your Heart" (Gary Taylor) (5:19)
* "Mind Blowing" (Robert Brookins, Gordon P. Jones, Dianne Quander) (4:55)
* "Don't Be Late For Love" (Ferguson, Lindsey, Jenkins) (5:12)
* "You Are the One" (Joel Davis) (5:26)
* "Is It Good To You" (Tsuyoshi "Taka" Takayanagi, Kevin Spencer) (6:16)
* "Innocent" (Brookins, Jones, King) (5:16)
* "Girl Don't Make Me Wait" (Zack Harmon, Christopher Troy) (4:26)
* "Misunderstanding" (Steve Russell, Rodney Benford) (5:48)
* "Forever Lover" (Greg Dalton) (4:49)
* "Babes" (Riddler, C. Romance) (4:14)
* "I Want 2B the 1 4U" (Skylark) (4:06)
* "Help Them See the Light" (Jerry McNeil) (5:24)
* "Innocent" (Heat of the Heat Edit) (Robert Brookins, Gordon P. Jones, Marva King) (4:37)

## Track listing (cassette)

Side One: Dancin
* "Innocent" (Brookins, Jones, King) (5:16)
* "Girl Don't Make Me Wait" (Zack Harmon, Christopher Troy) (4:26)
* "Misunderstanding" (Steve Russell, Rodney Benford) (5:48)
* "Forever Lover" (Greg Dalton) (4:49)
* "Babes" (Riddler, C. Romance) (4:14)
* "I Want 2B the 1 4U" (Skylark) (4:06)
* "Innocent" (Heat of the Heat Edit) (Robert Brookins, Gordon P. Jones, Marva King) (4:37)
Side Two: Romancin
* "More Of The Night" (Joel Davis) (6:02)
* "My Heart Your Heart" (Gary Taylor) (5:19)
* "Mind Blowing" (Robert Brookins, Gordon P. Jones, Dianne Quander) (4:55)
* "Don't Be Late For Love" (Ferguson, Lindsey, Jenkins) (5:12)
* "You Are the One" (Joel Davis) (5:26)
* "Is It Good To You" (Tsuyoshi "Taka" Takayanagi, Kevin Spencer) (6:16)
* "Help Them See the Light" (Jerry McNeil) (5:24)

## Track listing (vinyl)

* The vinyl version of More of the Night had a radically different track listing with songs in a different order and five songs that only appeared on the cassette and compact disc formats.
* "Innocent" (Brookins, Jones, King) (5:16)
* "Girl Don't Make Me Wait" (Zack Harmon, Christopher Troy) (4:26)
* "Misunderstanding" (Steve Russell, Rodney Benford) (5:48)
* "Forever Lover" (Greg Dalton) (4:49)
* "Babes" (Riddler, C. Romance) (4:14)
* "More of the Night" (Joel Davis) (6:02)
* "My Heart Your Heart" (Gary Taylor) (5:19)
* "Mind Blowing" (Robert Brookins, Jones, Dianne Quander) (4:55)
* "Is It Good To You" (Tsuyoshi "Taka" Takayanagi, Kevin Spencer) (6:16)
# Kaldhol

Kaldhol is a Norwegian surname. Notable people with the surname include:
* Marit Kaldhol (born 1955), Norwegian poet and children's writer
* Ottar Kaldhol (born 1946), Norwegian politician
# Shanhaiguan railway station

Shanhaiguan railway station (simplified Chinese: 山海关站; traditional Chinese: 山海關站; pinyin: Shānhǎiguān zhàn) is a station located in Shanhaiguan District, Qinhuangdao, Hebei, China. It is the end of the Beijing–Shanhaiguan railway and the start of the Shenyang–Shanhaiguan railway.
| Preceding station | China Railway | China Railway | China Railway | Following station |
| Qinhuangdaotowards Beijing | | Beijing–Harbin railway | | Suizhong Northtowards Harbin |
| Qinhuangdaotowards Beijing | | Beijing–Shanhaiguan railway | | Terminus |
| Qianweitowards Shenyang | | Shenyang–Shanhaiguan railway | | Terminus |
| Preceding station | China Railway High-speed | China Railway High-speed | China Railway High-speed | Following station |
| QinhuangdaoTerminus | | Qinhuangdao–Shenyang high-speed railwayPart of the Beijing–Harbin Railway | | Suizhong Northtowards Shenyang |
# Mau Narok

Mau Narok is a small town in Kenya's Nakuru County.
Mau Narok is one of the sub county in Njoro constituency located on South East of Njoro town. It is known for agriculture where locals grow cabbages, potatoes and tomatoes. It is neighbouring Mau Forest hence the place is very cold during winters. People who live there are Maasai, Kikuyu and Kalenjins.
The Mau Narok - Kisiriri road passes through the town, reducing distance from Nakuru to Narok by 80 km.
# Mesbah Kamal

Mesbah Kamal is a Bangladeshi academic. He is the vice chancellor of Royal University of Dhaka (RUD). He was the vice chancellor of the Bangladesh University (BU). And he was also vice chancellor of Primeasia University. He is a professor in the department of history at Dhaka University.
Kamal is the chairman of the Research and Development Collective and the general secretary of the Bangladesh Adivasi Odhikar Andolon. He is the Chief Advisor of Bangladesh Dalit Forum.

## Early life

Kamal was born 21 July 1958 in Chapai Nawabganj District, East Bengali, Pakistan. He father was Manzoor Ahmed.
Kamal completed his bachelor's and master's in history at the University of Dhaka in 1980 and 1981 respectively. He finished his PhD from the University of Dhaka in 2015 and his thesis was on Manabendra Narayan Larma and the Chittagong Hill Tracts conflict.

## Career

Kamal joined the University of Rajshahi in 1983 and the University of Dhaka as a lecturer in 1984. He joined BBC Bengali Service in 1987.
Kamal has been critical of the politics of Bangladesh Nationalist Party and Khaleda Zia describing it as destructive nationalism. He claimed the Bangladesh Nationalist Party lost the general election in 2018 stance for Pakistan and against the Bangladesh Liberation War.
Kamal was appointed vice chancellor of Primeasia University on 21 May 2021.
Kamal was appointed vice chancellor of Royal University of Dhaka on 22 July 2022.
Lawyer Gazi M H Tamim filed a genocide complaint against Kamal, former prime minister Sheikh Hasina, 29 journalists, and 22 others including Muhammad Zafar Iqbal.
# Huia (plant)

Huia is a genus of extinct vascular plants of the Early Devonian (Pragian or Siegenian, around 410 million years ago). The genus was first described in 1985 based on fossil specimens from the Posongchong Formation, Wenshan district, Yunnan, China.

## Description

The sporophyte of H. recurvata consisted of leafless stems (axes), branching both dichotomously and pseudomonopodially (i.e. with unequal divisions creating a 'main stem'). The sporangia (spore-forming organs) were born in terminal spikes on fertile stems, with the sporangia spirally arranged on stalks which curved downwards. The central strand of vascular tissue contained G-type tracheids. It was initially provisionally assigned to the "rhyniophytes". However, this group is defined as having terminal sporangia, whereas those of Huia are lateral, suggesting affinity with the zosterophylls. The Huia plant may show traits of being similar to Lycophytina but has ovate reflexed sporangia which are long stalked and dehisce longitudinally while being vascular, making it more like a vascular plant (tracheophyte).
A second species, H. gracilis, was described from the Xujiachong Formation (Pragian–early Emsian), Qujing district, Yunnan, China. It differs from H. recurvata in its more slender morphology and its lack of pseudomonopodial branching. The adaxial sporangia, which were oval or elongated oval in shape, split (dehisced) along their length at right angles to the stem. It is suggested that Huia may have originated from early Cooksonia-like plants. Others suggest that its position is uncertain.

## Phylogeny

A cladogram published in 2004 by Crane et al. places Huia in a paraphyletic stem group of broadly defined "zosterophylls", basal to the lycopsids (living and extinct clubmosses and relatives).
By contrast, Hao and Xue in 2013 listed the genus as a rhyniophyte, thus placing it outside the zosterophylls and even lycophytes.
# Pleurothallis lamellaris

Pleurothallis lamellaris is a species of orchid found from central Colombia to Bolivia.
# Humbird, Wisconsin

Humbird is an unincorporated census-designated place in the Town of Mentor in Clark County, Wisconsin, United States. It is located on U.S. Route 12 north-northwest of Merrillan. As of the 2010 census, its population was 266. Humbird has a post office with ZIP code 54746.

## History

Humbird was founded by Jacob Humbird, who was born at Ligonier, Pennsylvania on July 31, 1811. The second of five children of Solomon and Susan Humbert, Jacob was married to Eleanor McKee in 1835. They had four sons and four daughters. Jacob and his brother pursued careers in railroad building. He built Dom Pedro Secundo Railroad in Brazil from Rio de Janeiro to the interior of the country. In 1867 Humbird and D. A. Baldwin built the main line of the West Wisconsin Railroad from Elroy to Hudson. The tracks were laid to Humbird in late 1869. The depot opened for business on January 1, 1870.

## Geography

Humbird contains a pond, a bluff, farm land, recreational land, and several ATV trails. The pond is 13 acres (0.053 km$^2$) in area and 6 feet (1.8 m) at its deepest point. Although named Emerson Lake, it is commonly called Humbird Pond.

## Education

School District of Alma Center-Humbird-Merrillan operates public schools.
# Society of General Physiologists

The Society of General Physiologists (SGP) is a scientific organization whose purpose is to promote and disseminate knowledge in the field of general physiology, and otherwise to advance understanding and interest in the subject of general physiology. The Society’s main office is located at the Marine Biological Laboratory in Woods Hole, MA, where the society was founded in 1946. Past Presidents of the Society include Richard W. Aldrich, Richard W. Tsien, Clay Armstrong, and Andrew Szent-Gyorgi. The society's archives is held at the National Library of Medicine in Bethesda, Maryland.

## Membership

The Society's international membership is made up of nearly 600 career physiologists who work in academia, government, and industry. Membership in the Society is open to any individual actively interested in the field of general physiology and who has made significant contributions to knowledge in that field. The Society has become known for promoting research in many subfields of cellular and molecular physiology, but especially in the fields of membrane transport and ion channels, cell membrane structure, regulation, and dynamics, and cellular contractility and molecular motors.

## Activities

The major activity of the Society is its annual symposium, which is held at the Marine Biological Laboratory in Woods Hole, MA. Society of General Physiologists symposia cover the forefront of physiological research and are small enough to maximize discussion and interaction among both young and established investigators. Abstracts of the annual meeting are published in The Journal of General Physiology.
The 2015 symposium (September 16–20) topic is "Macromolecular Local Signaling Complexes." Detailed information regarding the scientific agenda and registration is provided at the symposium website:
https://web.archive.org/web/20150801070408/http://www.sgpweb.org/symposium2015.html
Recent past symposium topics include:
2014 Sensory Transduction
2013 The Enigmatic Chloride Ion: Transport, Regulation, and Roles in Physiology
2012 Integrative Membrane Physiology in the Post-Genome Era
2011 Mitochondrial Physiology and Medicine
2010 New Optical Methods in Cell Physiology
2009 Muscle in Health and Disease
2008 Calcium Signaling and Disease
2007 Membrane Biophysics of Fusion, Fission, and Rafts in Health and Disease
2006 Chemotaxis, Invasion, and Phagocytosis: From Bacteria to Humans
2005 Na,K-ATPase & Related Cation Pumps: Structures, Mechanisms, & Diseases
The Society also sponsors several award programs including the SGP Traveling Scholars Award Program to promote education and research in cell and molecular physiology.
# Moritz Georg Moshack

Moritz Georg Moshack (1730 – before 1772) was a builder of Danish clavichords. Three of his instruments are known to exist: a fret-free clavichord dating to 1768 at the Norsk Folkemuseum, Oslo, Norway; a single manual harpsichord dating to 1770 at the Falsters Minder Museum, Nykøbing, Falster, Denmark; and the fret-free Clavichord dating to 1770 at the Danish Music Museum in Copenhagen, Denmark.

## Biography

Moshack became licensed in 1761. In the same year, he received a royal monopoly to build and repair clavichords, harpsichords, and organs. Between 1759 and 1772, Moshack worked in Copenhagen, building organs and other instruments. Clavichords were purchased by the Royal Danish Theatre, and other instruments by Johan Foltmar at Trinitatis Church. Moshack also worked as a tuner.