Ion/Molecule Attachment Reactions: Mass Spectrometry [electronic resource] /
Fujii, Toshihiro.editor.
This book explores the mechanism of the alkali-metal ion/molecule association reaction, surveys the instrumental basis to study its kinetic, and describes the instrumentation to the measurement of alkali-metal ion affinities. The applications of the ion complexation mechanism in the condensed phase in reaction to direct analysis MS are also covered. Other topics include mechanism and reaction rates, experimental and theoretical ion affinities, applications of ion attachment reactions (IAR) to mass spectrometry such as alkali ion CIMS, and IAR-based direct analysis mass spectrometry. This book is ideal for graduate students and researchers in the fields of spectroscopy, mass spectrometry, and analytical  chemistry. This book also: ·         Covers the latest research on IAR-based direct analysis mass spectrometry, mechanism and reaction rates, and experimental and theoretical ion affinities ·         Broadens readers’ understanding of instrumentation drift tubes, SIFT, flowing afterglow, FTICR, and ion traps ·         Reviews exhaustively alkali metal ion affinities and ion attachment MS and cationization mass spectrometry of ESI, FAB, FD, LD, MALDI, and SIMS.
Description based upon print version of record.
Preface; Acknowledgments; Contents; List of Authors; Abbreviations; Lists of Synonym ; Chapter-1; Introduction; 1.1 Ion-Molecule Association Reactions; 1.2 Origin; 1.2.1 Flowing Afterglow; 1.2.2 Drift-Tube; 1.2.3 High-Pressure Mass Spectrometry; 1.2.4 Present; 1.3 Importance and Interest; 1.4 Ion Thermochemistry; 1.4.1 Importance; 1.4.2 Thermodynamics; 1.4.3 Bond Dissociation Energy (Metal Ion Affinity); 1.5 Cationization Mass Spectrometry Application to Analytical Mass Spectrometry; 1.5.1 Alkali Metal Ion in the Gas Phase; 1.5.2 Transition to the Gaseous to the Condensed Phase
1.6 Review, Tutorial, and Web Articles1.6.1 Reviews and Web Sites; 1.6.2 Tutorial Articles; References; Chapter-2; Fundamentals of Ion Chemistry; 2.1 Termolecular Association Reactions; 2.1.1 Association Reaction Mechanism; 2.1.2 Termolecular Reaction Kinetics; 2.1.3 Kinetic Data Base; 2.2 Dissociation Reaction; 2.2.1 Unimolecular Dissociation; 2.2.2 Collisional Dissociation; 2.2.3 Time-Resolved Photoactivated Dissociation, IRMPD, and BIRD; 2.2.4 Electron-Capture Dissociation and Electron-Transfer Dissociation; 2.2.5 ISD and PSD in MALDI; 2.3 Ion-molecule Association in the Condensed Phase
2.3.1 Cationization in Desorption Ionization2.3.2 Cationization Mechanism in MALDI; 2.3.3 Cationization Mechanism in ESI; References; Chapter-3; A Theoretical Approach to Ion-Molecule Complexation; 3.1 Basic Ion-Molecule Interactions; 3.2 Ion-Molecule Association/Dissociation Dynamics; 3.2.1 Transition State Theory (TST) and Variational TST; 3.2.2 Rice-Ramsperger-Kassel-Marcus Theory (RRKMT) and Quasi-equilibrium Theory (QET); 3.2.3 Phase Space Theory (PST); 3.2.4 Quasi-classical Trajectory Theory (QCT); 3.3 Overview of Computational Chemistry; 3.4 Computational Methodologies
3.4.1 Structure, Bonding Energies, Rate Constants, and Trajectories3.4.2 Nature of Bonding; 3.5 Ion-Molecule Complexes; 3.5.1 Interactions with Organic Molecules; 3.5.2 Interactions with Biomolecules; 3.5.3 Interactions with Materials; References; Chapter 4 ; Experimental Methods and Instrumentation ; 4.1  Introduction ; 4.2  Production of Gas-phase Alkali Metal ions ; 4.2.1  Thermoionic Emission ; 4.2.2  Laser Ionization ; 4.2.3  Desorption Ionization: Doping with Alkali Metal Salts ; 4.2.4  Solvent Additives in Electrospray Ionization ; 4.3  Tandem Mass Spectrometry ; 4.3.1  Introduction
4.3.2  Ion Dissociation Techniques 4.3.3  General Aspects of MS-MS Instrumentation ; 4.3.4  MS-MS in Sector Instruments ; 4.3.5  MS-MS in Tandem Quadrupole Instruments ; 4.3.6  MS-MS in Q-TOF Instruments ; 4.3.7  MS-MS in Q-LIT instruments ; 4.3.8  Reactive Gases in Collision Cells ; 4.4  Ion-Trapping Devices: Quadrupole Ion Traps and FT-ICR ; 4.4.1  Introduction ; 4.4.2  Ion Trap Mass Analysis ; 4.4.3  MSn in Ion Trap Instruments ; 4.4.4  Applications of Ion Trap MSn ; 4.4.5  Hybrid Systems Involving Ion Traps ; 4.4.6  Mass Analysis in Fourier Transform Ion Cyclotron Resonance Instruments
4.4.7  MS-MS in FT-ICR-MS
Includes bibliographical references at the end of each chapters and index.
This book explores the mechanism of the alkali-metal ion/molecule association reaction, surveys the instrumental basis to study its kinetic, and describes the instrumentation to the measurement of alkali-metal ion affinities. The applications of the ion complexation mechanism in the condensed phase in reaction to direct analysis MS are also covered. Other topics include mechanism and reaction rates, experimental and theoretical ion affinities, applications of ion attachment reactions (IAR) to mass spectrometry such as alkali ion CIMS, and IAR-based direct analysis mass spectrometry. This book is ideal for graduate students and researchers in the fields of spectroscopy, mass spectrometry, and analytical  chemistry. This book also: ·         Covers the latest research on IAR-based direct analysis mass spectrometry, mechanism and reaction rates, and experimental and theoretical ion affinities ·         Broadens readers’ understanding of instrumentation drift tubes, SIFT, flowing afterglow, FTICR, and ion traps ·         Reviews exhaustively alkali metal ion affinities and ion attachment MS and cationization mass spectrometry of ESI, FAB, FD, LD, MALDI, and SIMS.
Molecular biology.
Mass spectrometry.
Spectroscopy.
Molecular Medicine.
Mass Spectrometry.
Spectroscopy/Spectrometry.