Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II [electronic resource] : State of the art and Perspectives /
GIAMBASTIANI, Giuliano.editor.
CAMPORA, Juan.editor.
Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II: State of the art and Perspectives provides a critical review of the state-of-the-art developments in industrially relevant processes connected to efficient and selective olefin upgrading. Specific attention is devoted to catalysts containing imine- and amine-based ligands. All the chapters in this book have been designed to provide a systematic account of the vast amount of information available for this type of catalyst as well as to highlight the factors that ultimately control the catalyst’s performance and productivity. A comprehensive panorama of catalyst precursors is presented, spanning from group 10 α-diimine complexes and iron and cobalt 2,6-bis(imino)pyridine derivatives, to vanadium, chromium, titanium, zirconium and lanthanide complexes supported by nitrogen-containing ligands. The authors of this collective work are currently involved in the development of imine-based catalysts for efficient and selective olefin upgrading and the majority of them have dedicated most of their scientific career to this important field. In writing this book, their major goal is to transfer as many ideas and experiences as possible to the global audience of scientists engaged in this area of research.
Description based upon print version of record.
Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II; Foreword; Preface; Contents; List of Contributors; 1 Phenoxy--Imine Group 4 Metal Complexes for Olefin (co)Polymerization Including Polar Monomer Copolymerization; Abstract; 1.1...Introduction; 1.2...Key Features of FI Catalysts; 1.2.1 General Synthetic Schemes of FI Complexes; 1.2.2 Structural Features; 1.2.3 Electronic Features; 1.2.4 Activation Methods and Active Species; 1.3...Homopolymerization by FI Catalysts; 1.3.1 Ethylene Polymerization and Oligomerization; 1.3.1.1 Exploration of High Activity
1.3.1.2 Control of Molecular Weight1.3.1.3 Monodisperse Polymers; 1.3.1.4 Selective Ethylene Trimerization; 1.3.1.5 Ultra-Fine Non-Coherent Polyethylene Particles; 1.3.1.6 End Functionalization of Polyethylenes; 1.3.2 Propylene Polymerization; 1.3.2.1 Syndiotactic Polypropylene; 1.3.2.2 Atactic and Isotactic Polypropylene; 1.3.3 Higher alpha -Olefins Polymerization; 1.3.4 Styrene Polymerization; 1.4...Copolymerization by FI Catalysts; 1.4.1 Ethylene/ alpha -Olefin Copolymers; 1.4.2 Ethylene/Cyclic Olefin Copolymers; 1.4.3 Ethylene/Polar Functional Monomer Copolymers; 1.4.4 Block Copolymers
1.5...Concluding RemarksReferences; 2 Development of Imine Derivative Ligands for the Exocyclic Activation of Late Transition Metal Polymerization Catalysts; Abstract; 2.1...Introduction; 2.2...Ligand Synthesis; 2.2.1 Grafting Functionality onto the Ligand Backbone; 2.2.2 FTIR Characterization of Imine Ligands; 2.2.3 NMR Characterization of Imine Ligands; 2.2.4 Imine Ligand Properties and Coordination Modes; 2.2.5 Synthesis and Characterization of Specific Imine Derivative Ligands; 2.2.5.1 alpha -Iminocarboxamide; 2.2.5.2 alpha -Imine- beta -ketone Ligand; 2.2.5.3 alpha -Keto- beta -diimine Ligand
2.3...Preparation of Nickel Polymerization Catalysts2.3.1 Commonly Used Nickel Precursors; 2.3.2 Metallation/Transmetallation of Ligands with Metal Precursors; 2.3.3 Synthesis of Nickel Complexes by Using Precursor P2, P3 and P9; 2.4...Activation of Compounds for Olefin Polymerization; 2.4.1 Activation with Soluble Lewis Acids; 2.4.2 Single Component Systems; 2.4.3 Polymerization Reactions; 2.4.3.1 Effect of Activator Choice on Polymerization Activity and Polymer Properties; 2.4.3.2 Effect of Ligand Structure on the Polymerization Activities/Properties
3.2.3.2 Oligomerization of Ethylene
Includes bibliographical references and index.
Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II: State of the art and Perspectives provides a critical review of the state-of-the-art developments in industrially relevant processes connected to efficient and selective olefin upgrading. Specific attention is devoted to catalysts containing imine- and amine-based ligands. All the chapters in this book have been designed to provide a systematic account of the vast amount of information available for this type of catalyst as well as to highlight the factors that ultimately control the catalyst’s performance and productivity. A comprehensive panorama of catalyst precursors is presented, spanning from group 10 α-diimine complexes and iron and cobalt 2,6-bis(imino)pyridine derivatives, to vanadium, chromium, titanium, zirconium and lanthanide complexes supported by nitrogen-containing ligands. The authors of this collective work are currently involved in the development of imine-based catalysts for efficient and selective olefin upgrading and the majority of them have dedicated most of their scientific career to this important field. In writing this book, their major goal is to transfer as many ideas and experiences as possible to the global audience of scientists engaged in this area of research.
Organic chemistry.
Polymers  .
Organic Chemistry.
Polymer Sciences.
Catalysis by metal complexes