Miracle-dz/UniFAR-FTUs huggingface dataset:
Risk for Court Contact and Predictors of an Early Age for a First Court Contact Among a Sample of High Risk Youths: A Survival Analysis Approach

This study examined the rate of court contact and predictors of an early age for a first court contact for a sample of 203 youths who were seen at a children's mental health center, between the ages of 6 and 12 years, for conduct problem behaviours. Survival analyses revealed that the probabilities for a male and female to have court contact by age 18 were 65.9% and 32.9%, respectively. The clinician's rating of the child's likeability was a significant predictor of an early age for first court contact for males and a history of abuse was a significant predictor for females. The implications of these findings for early identification of high risk youth are discussed. (Abstract Adapted from Source: Canadian Journal of Criminology, 1998. Copyright © 1998 by the Canadian Criminal Justice Association; the University of Toronto Press) For more information on the Earlscourt Under 12 Outreach Project for Boys (ORP), see VioPro record number 4069. Ontario Canada Middle Childhood Late Childhood Child Male Child Female Child Offender Female Offender Male Offender Child Delinquency Child Behavior Child Problem Behavior Female Behavior Male Behavior Court Contact 09-00
Fungal Dilated Cardiomyopathy in a Patient with Acute Leukemia, How to Treat?: Case Report

Candida infection is an uncommon cause of myocarditis, endocarditis and dilated cardiomyopathy. It is well-known that the initiation time of antifungal treatment in these patients affects mortality rates. The optimal antifungal choice and duration of treatment for cardiac Candida infection is not yet well defined. In this report, a rare case of dilated cardiomyopathy and endocarditis due to Candida albicans in a 4-year-old child diagnosed with acute lymphoblastic leukemia is shared and its treatment is discussed. (J Pediatr Inf 2013; 7: 000-000)
Poly[hexaaquabis(μ3-terephthalato)(μ2-terephthalato)diytterbium(III)]

In the title two-dimensional coordination polymer, [Yb2(C8H4O4)3(H2O)6]n, the unique YbIII ion is eight-coordinated in a distorted dodecahedral coordination geometry by three water O atoms and five O atoms from carboxylate groups belonging to four different terephthalate ligands. One of the terephthalate ligands is located around an inversion center. The coordination polymers are parallel to (121) and are connected by O—H⋯O hydrogen bonds into a three-dimensional framework.
Quinazoline-2,4(1H,3H)-dione

In the title compound, C8H6N2O2, intermolecular N—H⋯O hydrogen bonds involving the amine and carbonyl groups create centrosymmetric dimers between adjacent nearly coplanar molecules. These dimers are further connected by weak N—H⋯O hydrogen bonds, forming a two-dimensional network. Molecules are packed in the crystal structure with adjacent benzene and pyrimidine rings approximately coplanar; the centroid–centroid separation is 3.863 Å and the dihedral angle between the mean planes is 0.64°, indicating the presence of weak intermolecular face-to-face π–π stacking interactions.
2,3-Dibromo-3-(5-nitro-2-furyl)-1-phenylpropan-1-one

In the title compound, C13H9Br2NO4, the phenyl and 2-nitrofuran rings are linked by a 2,3-dibromopropanal group, six atoms of which, including a furyl C atom, are disordered over two positions with a site-occupancy ratio of 0.733 (11):0.267 (11). The dihedral angle between the furan [maximum deviation = 0.028 (4) Å] and phenyl rings in the major component is 16.9 (3)°. In the minor component, the corresponding values are 0.87 (4) Å and 23.3 (5)°. In the crystal, intermolecular C—H⋯O hydrogen bonds link the molecules into two-dimensional arrays parallel to the ab plane.
(2E)-3-(4-Bromophenyl)-1-(2-methyl-4-phenyl-3-quinolyl)prop-2-en-1-one

The conformation about the ethene bond [1.316 (3) Å] in the title compound, C25H18BrNO, is E. The quinoline ring forms dihedral angles of 67.21 (10) and 71.68 (10)° with the benzene and bromo-substituted benzene rings, respectively. Highlighting the non-planar arrangement of aromatic rings, the dihedral angle formed between the benzene rings is 58.57 (12)°.
Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II)

The title compound, [Cd(NO3)2(C11H13N3)2], was synthesized by hydrothermal reaction of Cd(NO3)2 and S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole. The Cd atom lies on an inversion centre. The distorted octahedral Cd environment contains two planar trans-related N,N-chelating S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in one plane and two monodentate nitrate ligands. N—H⋯O hydrogen bonds involving a nitrate O atom build up an infinite chain parallel to the a axis.
Poly[(μ4-3-carboxypyrazine-2-carboxylato)(μ4-nitrato)dilithium]

In the title compound, [Li2(C6H3N2O4)2(NO3)]n, the two symmetry-independent LiI ions are each in a trigonal–bipyramidal coordination and are bridged by N,O-bonding ligands, forming molecular ribbons propagating in [010]. Each LiI ion is also coordinated by two O atoms from nitrate ions, connecting the ribbons into a three-dimensional network. Very strong intramolecular O—H⋯O hydrogen bonds occur between the carboxyl and the carboxylate group.
inter-glow

Inter-glow is a system that facilitates close interaction and communication among users in real space by using multiplexed visible-light communication technology. By shining light on an object containing an embedded photo sensor, users can get information about the object. In addition, several users can communicate with each other intimately by shining light on the object at the same time. We built a prototype to demonstrate the technology. In our prototype, when users point their lamps at the table in a miniature living room, the system can recognize which lamps are illuminating the table. According to the combination of illuminating lamps, the system produces the family conversations.
4,6-Dihydroxy-4,6-dimethyl-1,3-diazinane-2-thione

In the title compound, C6H12N2O2S, the heterocyclic ring has a sofa conformation. The molecular conformation is stabilized by an intramolecular O—H⋯O hydrogen-bond interaction with graph-set motif S(6). In the crystal, molecules are linked by O—H⋯S, N—H⋯S and N—H⋯O hydrogen-bond interactions, forming an extended two-dimensional framework parallel to the ac plane.
3-(4-Fluorobenzylidene)-1,5-dioxaspiro[5.5]undecane-2,4-dione

In the title molecule, C16H15FO4, the fused 1,3-dioxane and cyclohexane rings exhibit a bath and a chair conformation, respectively. In the crystal, weak intermolecular C—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers.
(E)-3-(4-Chlorophenyl)-1-(2,3,4-trichlorophenyl)prop-2-en-1-one

In the title chalcone derivative, C15H8Cl4O, the C=C double bond exists in an E configuration and the dihedral angle between the two benzene rings is 48.13 (11)°. In the crystal, molecules are arranged into columns and stacked down the a axis featuring possible weak aromatic π–π stacking interactions [centroid–centroid separation = 3.888 (2) Å].
3-(1-Adamantyl)-6-methyl-3-(3-methylbenzyl)isochroman-1-one

In the title compound, C(28)H(32)O(2), the oxanone ring adopts distorted half-boat conformation with the following Cremer and Pople puckering parameters: Q = 0.619 (2) Å, θ = 0.75 (19) and ϕ = 172 (13)°. The dihedral angle betwen two benzene rings is 21.32 (7)°. The adamantane unit consists of three fused cyclo-hexane rings in classical chair conformations, with absolute values of C-C-C-C torsion angles in the range 57.5 (2)-60.9 (2)°. Weak inter-actions of the type C-H⋯O link mol-ecules of each enanti-omer into chains parallel to the b axis and lying about inversion centers. The crystal packing is also stabilized by inter-molecular π-π stacking inter-actions [centroid-centroid distance of 3.8566 (11) Å].
21-Hydroxypregna-1,4-diene-3,20-dione

The title compound, C21H28O3, is a fungal transformed metabolite of decoxycorticosterone acetate, consisting of four fused rings A, B, C and D. Ring A is nearly planar, with a maximum deviation of 0.010 (3) Å from the least-squares plane, while the trans-fused rings B and C adopt chair conformations. The five-membered ring D is in an envelope conformation. The orientation of the side chain is stabilized by an intramolecular O—H⋯O hydrogen bond. In the crystal, adjecent molecules are linked by C—H⋯O hydrogen bonds into extended zigzag chains along the a axis.
(E)-5-(2-Nitroprop-1-enyl)-2,3-dihydro-1-benzofuran

The asymmetric unit of the title compound, C11H11NO3, contains two crystallographically independent molecules. The aromatic rings are oriented at a dihedral angle of 56.17 (5)°. The furan rings adopt envelope conformations. Intramolecular C—H⋯N interactions results in the formation of two six-membered rings with twisted conformations. In the crystal structure, three weak C—H⋯π interactions are found.
Open-EASE

Making future autonomous robots capable of accomplishing human-scale manipulation tasks requires us to equip them with knowledge and reasoning mechanisms. We propose Open-EASE, a remote knowledge representation and processing service that aims at facilitating these capabilities. Open-EASE gives its users unprecedented access to the knowledge of leading-edge autonomous robotic agents. It also provides the representational infrastructure to make inhomogeneous experience data from robots and human manipulation episodes semantically accessible, and is complemented by a suite of software tools that enable researchers and robots to interpret, analyze, visualize, and learn from the experience data. Using Open-EASE users can retrieve the memorized experiences of manipulation episodes and ask queries regarding to what the robot saw, reasoned, and did as well as how the robot did it, why, and what effects it caused.
2-[({2-[(2-Hydroxy-5-methoxybenzylidene)amino]ethyl}imino)methyl]-4-methoxyphenol

The asymmetric unit of the title compound, C18H20N2O4, contains one-half molecule with an inversion center located at the centroid of the molecule. In the crystal, molecules are linked by C—H⋯π interactions, forming layers parallel to (101). An intramolecular O—H⋯N hydrogen bond also occurs.
7-Chloro-4-(piperazin-1-yl)quinoline

There are two molecules in the asymmetric unit (Z′ = 2) of the title compound, C13H14ClN3, Each molecule is linked by N—H⋯N hydrogen bonds to another of the same type in a chain in [110]. The crystal studied was a non-merohedral twin with components 0.622 (2) and 0.378 (2).
THYROID HORMONE RELATED METABOLIC CHANGES IN NORMAL PREGNANCY

Article History: Received 6, November, 2014 Received in revised form 17, November, 2014 Accepted 8, December, 2014 Published online 28, December, 2014 Objective: Pregnancy is a physiological state accompanied by a high-energy demand and an increased oxygen requirement which leads to altered metabolic and hormonal status of the body. The present study was conducted to find out thyroid hormone status in various trimesters of normal pregnancy and its relation (if any exists) to various metabolic changes during pregnancy such as in lipedimic and glycemic index and oxidative stress levels. Design and Methods: Study designed with 40 healthy non pregnant females (group 1) who served as control and 60 normal pregnant females divided as group 2 (1 trimester), group 3 (2 trimester), group 4 (3 trimester). Thyroid function tests carried out by measuring total (T3, T4) and TSH levels investigated their association with changes in Lipedimic status (Total cholesterol, Triglycerides, High density lipoprotein, Low density lipoprotein, Very low density lipoprotein), Glycemic status (fasting serum glucose, insulin, c-peptide, HOMA-IR) and oxidative stress level (Superoxide dismutase, Malondialdehyde) in all groups. Results: Thyroid hormones (T3,T4) and TSH increased (at p<0.05) in pregnant females in all three trimesters as compared to non-pregnant females . Total cholesterol, triglyceride levels (at p<0.001) and levels of insulin and Insulin resistance ( at p<0.05) increased significantly during pregnancy especially in 2 and 3 trimesters when compared with non pregnant females. Oxidative stress level also increased during pregnancy in terms of significant increased levels of MDA (at p<0.05) from 2.50±0.73nmol/ml in non pregnant females to 2.65±0.57nmol/ml in 1 trimester, 3.67±0.73nmol/ml (at p<0.05) in 2 trimester, 5.35±0.57nmol/ml (at p<0.05) in 3 trimester respectively. Insulin was found to be directly related to thyroid hormone increase. Conclusions: Thyroid hormone changes during pregnancy is associated with alterations in Lipedimic and glycemic status along with increase in oxidative stress.
Early identification and brief intervention for risky drinkers in Finnish occupational health services

Objectives Hazardous drinking is a problem in many occupational settings. Finland has been active in implementing early identification and brief intervention with respect to risky drinking habits. To obtain information on these activities in Finnish occupational health services, a questionnaire survey was carried out as part of a national survey of occupational health services in 1997 and 2000. Methods In 1998 and 2001, a questionnaire was sent to all Finnish occupational health centers in operation in 1997 and 2000, respectively. Information was obtained on 770 centers in 1998 (83.1%) and 672 centers in 2001 (77.6%). Every center filled out one questionnaire. The outcome variable was activity involving early identification and brief intervention for risky drinking in 1997 and in 2000, respectively. Statistical differences were tested with the chi-square test. Results Early identification and brief intervention for risky drinking increased the most in eastern Finland from 1997 to 2000 (from 30% to 55%). Large centers increased their early identification and brief intervention (from 48% to 69%) more than the small ones (from 20% to 30%) did. Conclusions There was a clear increase in early identification and brief intervention for risky drinking over a period of 3 years, but the number of clients receiving such a service from occupational health units is still low.
9-(4-Hydroxy-3-methoxyphenyl)-3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8,9,10-decahydroacridine-1,8-dione

In the title molecule, C24H29NO4, the central ring of the acridinedione system adopts a flat boat conformation and the four essentially planar atoms of this ring [maximum deviation = 0.001 (2) Å] form a dihedral angle of 85.99 (12)° with the benzene ring. The two outer rings of the acridinedione system adopt sofa conformations. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link the molecules, forming a two-dimensional network parallel to (100).
3-Methyl-5-(3-phenoxyphenyl)cyclohex-2-enone

In the title molecule, C19H18O2, the cyclohexene ring adopts an envelope conformation, with all substituents equatorial. The dihedral angle between the benzene and phenyl rings is 83.75 (16)°. No classical hydrogen bonds are found in the crystal structure.
4-(2-Chlorophenylamino)-pent-3-en-2-one

In the title compound, C11H12ClNO, intramolecular N—H⋯O hydrogen bonding is present. The dihedral angle between the benzene ring and the pentenone unit is 46.52 (5)°. In the crystal, C—H⋯O interactions between hydrogen atoms of the aryl moiety and two separate oxygen atoms occur, leading to a three-dimensional network.
2-[3-(4-Chlorophenyl)-5-(4-fluorophenyl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thiazole

In the title compound, C24H17ClFN3S, the pyrazole ring is almost planar (r.m.s. deviation = 0.030 Å). With the exception of the methine-bound benzene ring, which forms a dihedral angle of 85.77 (13)° with the pyrazole ring, the remaining non-C atoms lie in an approximate plane (r.m.s. deviation = 0.084 Å) so that overall the molecule has a T-shape. In the crystal, centrosymmetrically related molecules are connected via π–π interactions between pyrazole rings [centroid–centroid distance = 3.5370 (15) Å] and these stack along the a axis with no specific interactions between them.
Factors associated with outcomes in ruptured aneurysmal patients: Clinical Study of 80 Patients

Abstract Background: Due to insufficient data in the literature, the optimal timing for surgical intervention for ruptured intracranial aneurysms is still controversial. Some practitioners advocate early surgery, but others not. It is important to identify other factors that can be used to predict poor prognosis in ruptured intracranial aneurysm patients. Objective: To determine the influence of timing of clipping surgery, and other factors on the outcomes of ruptured intracranial aneurysms in Hunt & Hess I~III grade patients. Method: We have performed a retrospective study involving 80 patients who were surgically treated for ruptured intracranial aneurysm between 2007 and 2012. The patient population consisted of 50(62.5%) females and 30(37.5%) males, with an age range of 12 to 75 years old, mean age 52.33 ± 10.63 years. We measured association between the Glasgow Outcome Scores and Sex, timing of clipping surgery, aneurysm location and pre-operative patient's neurological condition using famous Hunt and Hess grade system. Results: We did not find any correlation between the outcomes of ruptured intracranial aneurysm patients and timing (early, intermediate, late stage) of clipping, sex, aneurysm location. Whereas there is a significant correlation between patients outcomes and pre-operative patient neurological condition (Hunt & Hess grade). Conclusion: Timing of Surgery (early, intermediate, late) does not affect outcomes in low Hunt and Hess grade patients I~III. Whereas neurological condition (Hunt & Hess) has strong impact on postoperative outcomes. Others factors like sex, Age, Aneurysm location have no effect on outcomes in ruptured intracranial aneurysms.
Poly[[μ2-1,2-bis(diphenylphosphanyl)-1,2-diethylhydrazine]-μ4-nitrato-μ2-nitrato-silver(I)]

The title compound, [Ag2(NO3)2(C28H30N2P2)]n, crystallizes in polymeric α-helices. Three O atoms from three different nitrate ions in equatorial positions and two Ag atoms at axial positions set up a trigonal bipyramid. These units are linked by the phosphine ligands into endless helical chains that run along the c axis. The crystal used for the data collection was a racemic twin.
{4-[(Diphenylphosphino)methylamino]pyridinium-κP}bis(nitrato-κO)silver(I)

In the title mononuclear complex, [Ag(C18H18N2P)(NO3)2], the metal centre is coordinated in a slightly distorted trigonal–planar geometry by the P atom of the phosphine ligand and the O atoms of the two monodentate nitrate anions. In the crystal structure, complex molecules are connected by intermolecular N—H⋯O hydrogen bonds, forming chains running parallel to the b axis.
(Z)-N-{(E)-10-[(2,6-Diisopropylphenyl)imino]-9,10-dihydrophenanthren-9-ylidene}-2,6-dimethylaniline

The title compound, C34H34N2, adopts a Z,E configuration with respect to the N=C—C=N backbone, with an N—C—C—N torsion angle of 41.1 (4)° The dihedral angle between the benzene rings in the 9,10-dihydrophenanthrene moiety is 18.0 (1)°.
6′-Amino-3′-methyl-2-oxo-1′-phenyl-1′,3a′,4′,7a′-tetrahydrospiro[1H-indole-3(2H),4′-pyrano[2,3-d]pyrazole]-5′-carbonitrile

In the crystal structure of the title compound, C21H15N5O2, the planar indolone unit and the pyran ring are almost perpendicular to each other [dihedral angle = 89.41 (2)°], and the pyrazole and phenyl rings are oriented at an angle of 25.74 (1)°. The molecular packing is stabilized by inter- and intramolecular C—H⋯O, N—H⋯O and C—H⋯π hydrogen bonds.
Di-μ-chlorido-bis({9-[(2,6-diisopropylphenyl)iminomethyl]anthracen-1-yl}palladium(II))

The centrosymmetric title compound, [Pd2Cl2(C27H26N)2], was obtained by a C—H bond-activation reaction of a Schiff base ligand with Li2PdCl4 in methanol, and was crystallized from dichloromethane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement.
4,6-Bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]pyrimidine

The complete mol-ecule of the the title compound, C(14)H(10)F(6)N(6), is generated by crystallographic twofold symmetry, with two C atoms lying on the roatation axis. The dihedral angle between the central and peripheral rings is 25.97 (8)°.
2,5-Bis(5-methylpyrazin-2-yl)-1,3,4-oxadiazole

In the title molecule, C12H10N6O, the dihedral angle between the two pyrazine rings [planar to within 0.009 (3) and 0.018 (3) Å] is 5.62 (15)°. They deviate from the central oxadiazole ring [planar to within 0.005 (3) Å] by 1.52 (16) and 5.55 (17)°, respectively. In the crystal, C—H⋯N interactions involving the pyrazine rings connect molecules to form zigzag supramolecular chains propagating in [010].
Poly[bis(μ7-3-sulfonato-l-alaninato)sodiumzinc]

The hydrothermal reaction of Zn(CH3COO)2, NaOH and l-cysteic acid produced the title compound, [Na2Zn(C3H5NO5S)2]n. The ZnII cation is situated on an inversion centre and is in a distorted octahedral environment, being chelated by two deprotoned l-cysteic acid ligands through two amino N atoms and two carboxylic O atoms, with the two axial positions occupied by two carboxylic O atoms from two other l-cysteic acid ligands. Each l-cysteic acid ligand bridges five NaI ions via its sulfonate group and two ZnII ions via its carboxyl group, forming a three-dimensional framework. Weak N—H⋯O hydrogen bonding is observed in the crystal structure.
Triphenylbis[4-(trifluoromethyl)benzoato-κO]antimony(V)

The title complex, [Sb(C6H5)3(C8H4F3O2)2], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The environment of the Sb atom approximates a trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 4-(trifluoromethyl)benzoate ligands. In this ligand, the CF3 group is disordered by rotation about the C—C bond and the F atoms are distributed over two sets of sites with occupancies of 0.62 (3) and 0.38 (3). In the crystal, molecules are assembled in a three-dimensional framework through weak C—H⋯O hydrogen bonds.
Reciprocity between partial immunization and malnutrition significantly impairs health of preschool children

A six month community-based cross-sectional study of sixty (60) randomly selected rural preschool children was done in rural part of Midnapore District and associated Jungle-Mahal area West Bengal. Evaluation of immunization status and nutritional assessment by standard questioner method and Kuppuswami’s socioeconomic status scale. Anthropometric measurement was done to evaluate thinness stunting and wasting. Statistic was done with Version 10.0 SPSS. The partial immunization (PI) rates are higher in girl than boys (55.17% vs. 45.16%) and body mass index is better in fully-immunized children of either sex (girls 14.04 vs. 13.18 and boys 14.54 vs. 13.31 p<0.05). The grade II/ III thinness stunting wasting and underweight are common in PI group but mild thinness as observed in fully immunized group indicates other factorial influences also. Partial immunization and malnourishment exhibits significant adverse and synergistic effects on children’s health.
Chlorido[3,3′-dibutyl-5,5′-(pyridine-2,6-diyl)dipyrazol-1-ido]gold(III)

The Au atom in the C2-symmetric pincer-type title complex, [AuCl(C19H23N5)], is in the +3 oxidation state. The ligand is composed of one pyridine unit and two n-butyl-substituted pyrazoles (pyrz). Both pyrazoles are deprotonated, thus forming a neutral compound. To the best of our knowledge, this is the first AuIII–bispyrazolate complex. According to the special geometry in the N,N′,N′′-tridentate ligand, containing two five-membered heterocycles, the complex deviates from an ideal square-planar coordination geometry; the Npyrz—Au—Npyrz angle is 160.8 (3)°, indicating a distortion of nearly 20°.
1-(1H-Imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol

In the title molecule, C23H14N4O, the dihedral angle between the pyridine rings of the phenanthroline unit is 4.43 (8)° and the dihedral angle formed by the nine essentially planar [maximum deviation 0.0389 (16)Å] non-H atoms of the benzimidazole unit and the naphthalene ring system is 74.22 (5)°. In the crystal, molecules are linked by intermolecular N—H⋯N and O—H⋯N hydrogen bonds, forming a three-dimensional network.