Miracle-dz/UniFAR-FTUs huggingface dataset:
3-Hydroxy-3-[(2-methylpropanoyl)methyl]indolin-2-one

The title compound, C13H15NO3, was synthesized by the Aldol reaction of isatin and 3-methylbutan-2-one refluxing in methanol catalyzed by dimethylamine. The packing of the molecules in the crystal structure features intermolecular N—H⋯O and O—H⋯O hydrogen bonds.
(Z)-3-Benzyl-2-[(2-phenylcyclohex-2-enyl)imino]-1,3-thiazolidin-4-one

The title compound, C22H22N2OS, exists in a Z configuration with respect to the N=C bond. The cyclohexene ring adopts a distorted sofa conformation. The thiazolidine ring is essentially planar, with a maximum deviation of 0.030 (2) Å, and forms dihedral angles of 76.66 (6) and 74.55 (6)° with the terminal phenyl rings. The dihedral angle between the phenyl rings is 71.55 (7)°. In the crystal, a C—H⋯π interaction is observed.
Chlorido{4-ethyl-1-[1-(pyrazin-2-yl)ethylidene]thiosemicabazidato-κS}bis(triphenylphosphane-κP)silver(I)

The title compound, [Ag(C9H13N5S)Cl(C18H15P)2], crystallizes with four independent molecules in the asymmetric unit, in each of which the Ag atom is in a distorted tetrahedral coordination, defined by the chloride ligand, the S atom of the neutral ligand and two P atoms derived from the triphenyl phosphine ligands. The thiosemicarbazone acts as a monodentate ligand through its thione S atom. An intramolecular N—H⋯Cl hydrogen bond occurs in two of the independent molecules. In the crystal, the molecules are assembled through N—H⋯Cl hydrogen bonds, forming chains along [101].
{6-[(2-Anilinoethyl)iminomethyl]-2-ethoxyphenolato}(thiocyanato-κN)copper(II)

In the title complex, [Cu(C17H19N2O2)(NCS)], the CuII atom is chelated by the phenolate O atom, the imine N atom and the amine N atom of the N,N′,O-tridentate 2-ethoxy-6-[(2-anilinoethyl)iminomethyl]phenolate ligand, and by the N atom of a thiocyanate anion, forming a distorted CuON3 square-planar geometry. The dihedral angle between the aromatic rings of the ligand is 67.9 (4)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds occur, generating R 2 2(8) loops.
4,4′,4′′-Tris(2-pyridyl)-2,2′,2′′-[(2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene)tris(sulfanediyl)]tripyrimidine

The title compound, C39H33N9S3, features a mesitylene unit substituted with three thioether arms. The distances from the center of mesitylene unit to the N atoms of the three pyridine rings in the arms are 10.05 (1), 9.94 (3) and 8.79 (3) Å. The crystal structure shows weak intramolecular C—H⋯N hydrogen bonds.
Identifying Data Problems and Improving Data Quality in the Survey of Consumer Finances

Since the Survey of Consumer Finances (SCF) delves into every financial detail of a household’s finances, maximizing data quality is a constant challenge. Staff at NORC at the University of Chicago (NORC) and economists at the Board of Governors of the Federal Reserve (FRB) have collaborated in the design and implementation of a refined data quality process and review cycle. All interviewer commentary including call record entries, interviewer comments recorded during questionnaire administration and interviewer debriefing notes recorded post-interview are reviewed for potential quality issues related to respondent identification and questionnaire administration. Along with economists at the FRB, the NORC team evaluates the questionnaire data and identifies potential errors and anomalies that require follow-up. These evaluations are incorporated into a timely and systematic feedback loop delivered to interviewers. This feedback will trigger remedial actions designed to address quality deficiencies (e.g., broadcast memos regarding proper protocol, self-directed electronic training, and supervisor-led training) and provide an on-going assessment of interviewer performance. We will describe the processes used to identify data quality issues, our data quality improvement protocols, and data quality measures over time.
1-(4-Chloro-3-fluorophenyl)-2-[(3-phenylisoquinolin-1-yl)sulfanyl]ethanone

In the title compound, C23H15ClFNOS, the isoquinoline system and the 4-chloro-3-fluorophenyl ring are aligned at 80.4 (1)°. The dihedral angle between the isoquinoline system and the pendant (unsubstituted) phenyl ring is 19.91 (1)°.
2-[(1-Methyl-1H-pyrrol-2-yl)carbonylmethyl]isoindoline-1,3-dione

The asymmetric unit of the title compound, C15H12N2O3, contains two almost identical molecules forming an nearly C 2-symmetric dimeric pattern. The dihedral angles between the pyrrole ring and the phthalimide unit are 82.95 (8) and 86.57 (8)° for the two molecules. Within such a dimer, the phthalimide units of the two molecules form a dihedral angle of 1.5 (5)°.
5-(4-Ethoxybenzyl)-1H-tetrazole

In the title molecule, C10H12N4O, the tetrazole and benzene rings form a dihedral angle of 67.52 (2)°. In the crystal, intermolecular N—H⋯N hydrogen bonds link the molecules into chains along the a axis. The relatively short distance of 3.760 (3) Å between the centroids of the tetrazole rings suggests the existence of π–π interactions.
2,4-Bis(2-bromophenyl)-7-tert-pentyl-3-azabicyclo[3.3.1]nonan-9-one

The title compound, C25H29Br2NO, is a tert-pentyl analog of 2,4-bis(2-bromophenyl)-3-azabicyclo[3.3. 1]nonan-9-one [Parthiban et al. (2008 ▶). Acta Cryst. E64, o2385]. Similar to its analog, the title compound exists in a twin-chair conformation with an equatorial orientation of the 2-bromophenyl groups. The benzene rings are inclined to each other at a dihedral angle of 29.6 (3)°. The tert-pentyl group on the cyclohexanone ring also adopts an exocyclic equatorial disposition.
Diffusion Networks, Products of Experts, and Factor Analysis

Hinton (in press) recently proposed a learning algorithm called contrastive divergence learning for a class of probabilistic models called product of experts (PoE). Whereas in standard mixture models the “beliefs” of individual experts are averaged, in PoEs the “beliefs” are multiplied together and then renormalized. One advantage of this approach is that the combined beliefs can be much sharper than the individual beliefs of each expert. It has been shown that a restricted version of the Boltzmann machine, in which there are no lateral connections between hidden units or between observation units, is a PoE. In this paper we generalize these results to diffusion networks, a continuous-time, continuous-state version of the Boltzmann machine. We show that when the unit activation functions are linear, this PoE architecture is equivalent to a factor analyzer. This result suggests novel non-linear generalizations of factor analysis and independent component analysis that could be implemented using interactive neural circuitry.
2,5-Bis(4-fluorophenyl)-2-methylsulfanyl-1-benzofuran

The crystal studied of the title compound, C21H14F2OS, was an inversion twin with a 0.67 (8):0.33 (8) domain ratio. The 4-fluorophenyl ring in the 2-position makes a dihedral angle of 25.14 (6)° with the mean plane of the benzofuran fragment, and the dihedral angle between 4-fluorophenyl ring in the 5-position and the mean plane of the benzofuran fragment is 28.50 (7)°. In the crystal, molecules are linked through weak intermolecular C—H⋯F and C—H⋯π interactions.
5-(4-Bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridine

The title compound, C23H18BrN, was synthesized by the reaction of 4-bromobenzaldehyde, naphthalen-2-amine and cyclohexanone in tetrahydrofuran, catalyzed by iodine. The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results in a significant deviation from planarity for the pyridine ring. In the crystal, a weak C—H⋯π interaction occurs, leading to inversion dimers.
A eficácia das intervenções não-farmacológicas na diminuição da dor no pós-operatório

Nursing can be add to reducing the pain of the patient postoperative with the adoption of unconventional techniques, known as non-pharmacological. The question is: If the implementations of non-pharmacologic techniques are an effective strategy in reducing pain in patients (adult) postoperative? Using the PICO helped to describe all the components that are related to the problem identified and searching the best evidence. From the literature review was chosen the most scientific evidence for the research question [Level I, Grade A; (Crowe et al. 2008)] EBSCO‘s database which consists of a systematic review and meta-analysis. The conclusions of this review demonstrated that there isn´t strong evidence to justify in the context of nursing the effectiveness of the adoption of non-pharmacological techniques in reducing postoperative pain.
(Z)-N′-Hydroxy-4-(trifluoromethyl)benzimidamide

In the title compound, C8H7F3N2O, the OH and NH2 substituents adopt a Z configuration with respect to the C=N bond. The hydroxyimidamide unit is almost planar (r.m.s. deviation = 0.007 Å) and subtends an angle of 26.25 (13)° with the benzene ring. The F atoms of the trifluoromethyl substituent are disordered over two sets of sites with an occupancy ratio of 0.783 (15):0.217 (15). In the crystal, O—H⋯N hydrogen bonds form centrosymmetric dimers. Additional N—H⋯O hydrogen bonds link the dimers into zigzag chains along the b axis. Weak intermolecular F⋯F contacts of 2.714 (5) Å are also observed.
Road User Detection and Analysis in Traffic Surveillance Videos

Road user data collection and behaviour analysis has been an active research topic in the last decade. Automated solutions can be achieved based on video analysis with computer vision techniques. In this thesis, we propose a method to estimate traffic objects’ locations with state-of-the-art vision features and learning models. Our focus is put on the applications of cyclist’s helmet recognition and 3D vehicle localization. With limited human labelling, we adopt a semi-supervised learning process: tri-training with views of shapes and motion flow for vehicle detection. Experiments are conducted in real-world traffic surveillance videos.
(2Z)-2-{[N-(2-Formylphenyl)-4-methylbenzenesulfonamido]methyl}-3-(4-methylphenyl)prop-2-enenitrile

In the title compound, C25H22N2O3S, the sulfonyl-bound benzene ring forms dihedral angles of 36.8 (2) and 81.4 (2)°, respectively, with the formylbenzene and methylbenzene rings. The molecular conformation is stabilized by an intramolecular C—H⋯O hydrogen bond, which generates an S(5) ring motif. The crystal packing is stabilized by C—H⋯O hydrogen bonds, which generate C(11) chains along the b axis. The crystal packing is further stabilized by π–π interactions [centroid–centroid distance = 3.927 (2) Å].
2-[(E)-({4-[(4,6-Dimethylpyrimidin-2-yl)sulfamoyl]phenyl}iminio)methyl]-6-hydroxyphenolate

The title compound, C19H18N4O4S, exists as a zwitterion in the solid state, with nominal proton transfer from a phenol group to the imine N atom. The 2,3-dihydroxybenzaldehyde fragment is oriented at a dihedral angle of 35.51 (11)° to the adajacent aniline group and makes a dihedral angle of 76.99 (6)° with the 4,6-dimethylpyrimidin-2-amine group. Intramolecular O—H⋯O and N—H⋯O hydrogen bonds close S(5) and S(6) rings, respectively; the same O atom accepts both bonds. In the crystal, polymeric chains along [001] are formed from molecules joined end-to-end by N—H⋯O and O—H⋯N hydrogen bonds; these feature R 2 3(6) loops. The polymeric chains are linked by C—H⋯O interactions and there are π–π interactions between the pyrimidine rings with a centroid–centroid distance of 3.446 (2) Å.
mmunology of bovine respiratory syncytial virus infection of cattle

Bovine respiratory syncytial virus (BRSV) is a respiratory pathogen of cattle that causes severe disease in calves alone and as one of several viruses and bacteria that cause bovine respiratory disease complex. Like human RSV this virus modulates the immune response to avoid stimulation of a vibrant CD8+ T cytotoxic cell response and instead promotes a Th2 response. The Th2 skew sometimes results in the production of IgE antibodies and depresses production of the Th1 cytokine interferon . Innate immune cells have a pivotal role in guiding the adaptive response to BRSV, with selective secretion of cytokines by pulmonary dendritic cells. Here we review some of the pertinent observations on immune responses to BRSV infection and vaccination and illustrate how experimental infection models have been used to elucidate the immunopathogenesis of BRSV infection. Recent experiments using intranasal vaccination and/or immune modulation with DNA based adjuvants show promise for effective vaccination by the stimulation of Th1 T cell responses. © 2012 Elsevier Ltd. All rights reserved.
2-[(Ferrocen-1-yl)(hydroxy)methyl]prop-2-enenitrile

In the title ferrocene derivative, [Fe(C5H5)(C9H8NO)], the dihedral angle between the enenitrile group and the substituted cyclopentadienyl ring is 71.2 (1)°. The cyclopentadienyl rings of the ferrocene moiety are arranged in an eclipsed conformation. The hydroxy group, and the corresponding methine H atom, are disordered over two sets of sites with site-occupancy factors of 0.744 (4) and 0.256 (4). An intramolecular C—H⋯O close contact is observed. In the crystal, O—H⋯N hydrogen bonds form a C(6) chain along [100].
Developing in OMG’s New Model-Driven Architecture

In this paper, we’re going to describe the application development process supported by OMG’s Model Driven Architecture (MDA) – the model that you build, the artifacts that you produce, how information flows from one set of artifacts to the next, and how the MDA process ultimately yields an application running on virtually any target middleware platform. OMG has introduced the MDA in several papers, all accessible via a single click from our main MDA web page www.omg. org/mda. We’re not going to review the MDA or do any other introductory stage-setting here. If you need an introduction, check these references on the web.
Di-n-butylbis(N-n-butyl-N-ethyldithiocarbamato-κS)tin(IV)

The Sn atom in the title compound, [Sn(C4H9)2(C7H14NS2)2], exists in a tetrahedral C2S2Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bond S atoms [Sn—S = 2.521 (2) and Sn⋯S = 2.933 (2) Å]. The Sn atom lies on a special position of mm2 site symmetry and the tin-bound n-butyl chain is disordered about a mirror plane. The ethyl and n-butyl groups of the dithiocarbamate unit are disordered about another mirror plane.
1,10-Bis(4-nitrophenoxy)decane

The title compound, C22H28N2O6, crystallizes with four half-molecules in the asymmetric unit: each molecule is located about a crystallographic inversion centre. The central methylene groups of two molecules are disordered over two sets of equally occupied sites. The crystal packing is characterized by sheets of molecules parallel to (14).
3-({4-[(2-Methylbenzylidene)amino]-5-sulfanylidene-1H-1,2,4-triazol-3-yl}methyl)-1,3-benzoxazol-2(3H)-one

In the title compound, C18H15N5O2S, a weak intramolecular C—H⋯S hydrogen bond results in a small dihedral angle of 3.71 (9)° between the methylphenyl and triazole rings, which, in turn, form dihedral angles of 80.09 (8) and 77.32 (8)°, respectively, with the benzoxazolone mean plane. In the crystal, N—H⋯O hydrogen bonds link molecules into chains along [001], and weak C—H⋯N hydrogen bonds and π–π interactions between the five- and six-membered rings [centroid–centroid distances = 3.5074 (11) and 3.616 (1) Å] consolidate the crystal packing.
Bis(5-amino-2-chlorobenzoato-κO)triphenylantimony(V)

In the title compound, [Sb(C6H5)3(C7H5ClNO2)2], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxylate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intramolecular C—H⋯O interactions occur. The molecules are connected by intermolecular N—H⋯O, N—H⋯N and C—H⋯O hydrogen-bonding interactions and C—H⋯π stacking interactions, forming a three-dimensional supramolecular framework
Phenyl(3-methyl-1-phenylsulfonyl-1H-indol-2-yl)methanone

In the title compound, C22H17NO3S, the N atom of the indole ring system deviates by 0.031 (3) Å from a least-squares plane fitted through all nine non-H ring atoms. The geometry around the S atom can be described as distorted tetrahedral. As a result of the electron-withdrawing character of the phenylsulfonyl groups, the N—Csp 2 bond lengths are longer than the typical mean value for N atoms with a planar configuration.
(E)-5-[(3-Ethoxy-2-hydroxybenzylidene)amino]-1,3,4-thiadiazole-2(3H)-thione

In the title compound, C11H11N3O2S2, the dihedral angle between the benzene ring and the five-membered ring is 6.85 (9)°. An intramolecular O—H⋯N hydrogen bond makes an S(6) ring motif. In the crystal, molecules are linked through bifurcated N—H⋯(O,O) hydrogen bonds with R 1 2(5) ring motifs, forming chains along the b axis. A short C⋯S contact [3.3189 (19) Å], which is shorter than the sum of the van der Waals radii of these atoms (3.50 Å), occurs in the structure. The crystal structure is further stabilized by C—H⋯N hydrogen bonding and π–π interactions [centroid–centroid distance = 3.7649 (12) Å].
4-Ethoxy-N-(4-ethoxyphenyl)-N-(4-nitrophenyl)aniline

In the title molecule, C22H22N2O4, the ethoxyphenyl rings are oriented at dihedral angles of 69.31 (13) and 75.90 (13)° to the nitrophenyl ring and are twisted to each other, making a dihedral angle of 78.55 (13)°. In the crystal, weak C—H⋯O hydrogen bonds and C—H⋯π interaction link the molecules into a three-dimensional supramolecular architecture.
Doctor of Nursing Practice portfolio of Myra Ladd Thompson

American children are growing up in an obeseogenic environment and will die sooner as a result. The malnutrition and chronic health problems found in overweight children create a public health concern that may be the most significant public health threat we face today in America. The United States is spending nearly $150 billion annually on obesity-related health conditions for adults and children. This places an enormous burden on our fragile health care system and the country‟s economic infrastructure as a whole. Reversing the trend of obesity and its associated health consequences is essential to reducing health care costs for future generations. The Child Nutrition Act (H.R. 1324) is currently under review and needs revision to mandate healthy food options. This paper proposes a policy option that would require that all federally funded school food programs offer a daily vegetarian main course food option. Children have a right to good health and they rely on us to amend legislative policies to improve their health and their future.
Comparison of Slide Surfaces for the Fabrication of Pain-Related Message Molecule Antibody Microarray

Current therapeutic principles are step-by-step trials with multiple drugs for pathological pain. Such treatment plans often make physicians or patients uncertain and discouraged. The real problem is focused on the limited view of pain network, It was impossible for past researchers to observe so multiplexed proteins changes within different pain syndromes. Conventional methods for protein expression focus only on one or a few targets. However, the investigation of new therapeutic targets to pain needs a better realization of the global regulation network. Fortunately, with advancement of new technologies, it is possible to able to examine hundreds and thousands of protein simultaneously right now. Such large-scale studies have the promise to assemble individual pieces together to gain insights into the overall picture of proteome-wide modifications on pain mechanisms. Antibody microarrays are an emerging technology that promises to be a powerful tool. It has significant applications in basic and clinical researches. particularly because of the rapidity of the experiments. Such analysis is possible, if many experiments with highly parallel with quantitative information can be performed. Especially for clinical researches, the results from antibody microarray could be correlated with clinical information to assess the clinical value of multiple proteins or sets of proteins. The microarray format facilitates not only the rapid evaluation of many proteins individually but also the evaluation of coordinate patterns of expression. Therefore, we tested four commercial antibody microarray surfaces printing on substance P (SP), brain-derived neurotrophic factor (BDNF), nerve growth factor (NGF), tumor necrosis factor-alpha (TNF-α). To improve the performance, protein G coating method was introduced into slide surface. The results showed the best performance can be achieved in aldehyde-derivatized slide by protein G coating method.
5-(2,6-Difluorophenyl)-1,3,4-thiadiazol-2-amine

The title compound, C8H5F2N3S, was synthesized by the reaction of 2,6-difluorobenzoic acid and thiosemicarbazide. The dihedral angle between the thiadiazole and phenyl ring is 35.19 (14)°. In the crystal structure, intermolecular N—H⋯N hydrogen bonds form chains along the b and c axes.
1-(2-Bromobenzyl)-3-isopropylbenzimidazolin-2-one

In the structure of the title compound, C17H17BrN2O, the central phenyl and imidazol-2-one rings are coplanar (dihedral angle between planes of 0.73 (11)°). The angles subtended by the substituents on the N atoms of the imidazol-2-one ring range from 109.71 (14)° to 128.53 (15) due to steric hindrance of these substituents with the phenyl H atoms. The carbonyl O and Br both make two weak C—H⋯O and C—H⋯Br interactions with two adjacent molecules, thus forming an three-dimensional array.
Tetraimidazolebis(trichloroacetato)copper(II)

The title compound, [Cu(C2Cl3O2)2(C3H4N2)4], was prepared by the reaction of imidazole and trichloroacetatocopper(II). The CuII atom adopts a distorted octahedral coordination geometry, binding the N atoms of four imidazole ligands and the carboxylate O atoms of two trichloroacetate anions. The molecular structure and packing are stabilized by N—H⋯O hydrogen-bonding interactions. Close intermolecular Cl⋯Cl contacts [3.498 (3) Å] are also found in the structure.
2-(4-Methylphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline

In the title compound, C20H14N4, all the non-H atoms are roughly coplanar with an r.m.s. deviation of 0.0776 Å. In the crystal, molecules are linked by N—H⋯N hydrogen bonds, forming chains along the (). The chains are connected by intermolecular C—H⋯N hydrogen bonds and π–π stacking interactions between inversion-related phenanthroline, imidazole and phenyl rings with centroid–centroid distances in the range 3.777 (1)–3.905 (1) Å.