Miracle-dz/UniFAR-FTUs huggingface dataset:
The effects of aqueous chemical environments on crack propagation in quartz

The chemical role of water and other aqueous environments in crack propagation was examined in a series of crack propagation tests in natural and synthetic quartz. The potential roles of surface free energy reduction and zeta potential (surface electrostatic potential) in chemical weakening were specifically examined by running the crack propagation tests in the presence-of six surface active aqueous environments which varied sub-stantially in these parameters with respect to quartz. Calorimetric and electrophoresis tests were also undertaken in order to determine the degree of reduction of the surface energy of quartz produced by each chemical environment and the zeta potential between each environment and quartz. It was found that there was a moderate correlation between reduction of the crack propagation stress of quartz and the degree by which the surface energy was reduced in the presence of a particular environment. No such correlation was found with respect to zeta potential. It was also observed that some of the chemical environments appeared to produce highly branched cracks in quartz. This branching effect is probably related to the velocity of crack propagation.
Aspects of landscape evolution in the Lapstone Monocline area, New South Wales

The concept that the Lapstone Monocline and associated faults are old structures which have dominated landform development in the lower Blue Mountains of New South Wales by exhumation of structural ridges of resistant Hawkesbury Sandstone is examined. It is suggested that the Lapstone Monocline is of pre‐Jurassic age and that landforms developed initially on a land surface of more uniform lithology, some features of which are now incised into the topographically higher levels of the Hawkesbury Sandstone. The Rickabys Creek Gravel, the age of which is critical in determining the timing of events and the testing of this theory, has defied all attempts to obtain internal evidence of age.
Daily snow cover estimation from Advanced Very High Resolution Radiometer Polar Pathfinder data over Northern Hemisphere land surfaces during 1982-2004

[1] The Global Climate Observing System has identified the need for systematic global daily snow cover data sets over land. Current in situ snow cover data sets have limited spatial coverage while satellite-based snow cover records have either limited historical extent or limited temporal and spatial resolution because of cloud cover or specific sensor availability. NOAA Advanced Very High Resolution Radiometer (AVHRR) data offers nearly complete daily global coverage of the Northern Hemisphere, extending back to the early 1980s with successors slated to continue into the next decade. In this paper, we apply a new algorithm, Snowcover, to estimate daily snow cover, including periods of cloudy conditions, from AVHRR Polar Pathfinder (APP) data over Northern Hemisphere land surfaces. This new snow cover product is compared to snow cover estimates derived from long-term in situ snow depth measurements over Canada and the northern Eurasia. The APP snow cover maps showed an 80% agreement rate or better at 95% of the in situ sites. This performance was comparable to the agreement of MODIS 0.05 degree snow cover products over the same sites; although the MODIS product was only retrieved ∼20% of the time corresponding to clear sky conditions in contrast to over 95% of the time with the APP snow product. The almost continuously temporal and spatial coverage for the past 23 years from 1982 to 2004 over Northern Hemisphere makes the new daily snow cover product especially suitable for analysis of large-scale patterns of spring snowmelt in association with variability of circumpolar climate and ecological parameters.
Inversion around the Bass Basin, SE Australia

Abstract Regional seismic reflection and fission track thermochronological studies of the Bass Basin area illustrate two types of inversion, both confined to the Bass failed rift. The first type involved 1–2 km of uplift, denudation and cooling of basement over more than 200 km along both margins of a failed rift, with lesser erosion within the rift basin. This occurred during renewed extension that bypassed the Bass Basin area leaving it as a failed rift. The uplift resulted from breaking of the lithosphere and may have been due, in part, to rebound following several kilometres of rapid sediment loading in the preceding 20 Ma. The second type comprised repeated structural inversion involving 1–3 km of uplift by compressional reactivation of extensional faults and along new reverse faults. These inversions occurred along the zone of maximum extension in a failed Mesozoic rift, such that Tasmania acted as a buttress to compression. The rifting and structural inversions are interpreted to have been controlled by a long-lived zone of weakness, perhaps overlying a Palaeozoic greenstone belt, with the maximum principal stress being roughly perpendicular to faults within the zone during inversion. Significantly, Miocene-Pliocene inversion resulted from the Australian craton being placed into compression following arc collision 3500 km to the north, emphasizing the importance of long distance transmission of compressional stresses through the lithosphere.
Maturity and Impedance Analysis of Organic-Rich Shales

Organic-rich shales (ORSs) need to be studied in detail to understand the provenance and the generation of hydrocarbons from source rocks. In recent years, ORSs have gained importance as hydrocarbon resources as well. Successful exploration and production programs for ORSs need reliable identification of their kerogen content as well as maturity through indirect seismic methods. However, the properties of kerogen are poorly understood, so predictions about maturity and rock-kerogen systems remain a challenge. Assessment of maturity from indirect measurements can be greatly enhanced by establishing and exploiting correlations between physical properties, microstructure, and kerogen content. We show correlations between the impedance microstructure of ORSs and their maturity and elastic properties. We have used scanning acoustic microscopy to analyze and map the impedance microstructure in ORSs. We quantified textural properties in the images and related these textural properties to maturity and to impedance from acoustic-wave propagation measured at centimeter scales. This combined study of acoustic properties and microstructures of ORSs gives important insight into changes resulting from kerogen maturation. We introduce a modified porosity term and find that (1) there is a significant correlation between velocity and modified porosity of all ORSs; (2) imaging and quantifying microscale impedance texture and contrast in the images allow us to correlate them with ultrasonic measurements on a centimeter scale; and (3) textural heterogeneity, elastic impedance, velocity, and density increase with increasing shale maturity. We also discuss possible methods to predict maturity from impedance on the basis of understanding the changes resulting from maturity in well-log response, core measurements, and microstructure of ORSs. Our work has important bearing on developing successful production and stimulation methodologies.
Ground‐based investigation of soil moisture variability within remote sensing footprints During the Southern Great Plains 1997 (SGP97) Hydrology Experiment

Surface soil moisture content is highly variable in both space and time. While remote sensing provides an effective methodology for mapping surface moisture content over large areas, it averages within‐pixel variability thereby masking the underlying heterogeneity observed at the land surface. This variability must be better understood in order to rigorously evaluate sensor performance and to enhance the utility of the larger‐scale remotely sensed averages by quantifying the underlying variability that remote sensing cannot record explicitly. In support of the Southern Great Plains 1997 (SGP97) Hydrology Experiment (a surface soil moisture mapping mission conducted between June 18 and July 17, 1997, in central Oklahoma) an investigation was conducted to characterize soil moisture variability within remote sensing footprints (approximately 0.64 km2) with more certainty than would be afforded with conventional gravimetric moisture content sampling. Nearly every day during the experiment period, portable impedance probes were used to intensively monitor volumetric moisture content in the 0‐ to 6‐cm surface soil layer at six footprint‐sized fields scattered over the SGP97 study area. A minimum of 49 daily moisture content measurements were made on most fields. Higher‐resolution grid and transect data were also collected periodically. In total, more than 11,000 impedance probe measurements of volumetric moisture content were made at the six sites by over 35 SGP97 participants. The wide spatial distribution of the sites, combined with the intensive, near‐daily monitoring, provided a unique opportunity (relative to previous smaller‐scale and shorter‐duration soil moisture studies) to characterize variations in surface moisture content over a range of wetness conditions. In this paper the range and temporal dynamics of the variability in moisture content within each of the six fields are described, as are general relationships between the variability and footprint‐mean moisture content. Results indicate that distinct differences in mean moisture content between the six sites are consistent with variations in soil type, vegetation cover, and rainfall gradients. Within fields the standard deviation, coefficient of variation, skewness, and kurtosis increased with decreasing moisture content; the distribution of surface moisture content evolved from negatively skewed/nonnormal under very wet conditions, to normal in the midrange of mean moisture content, to positively skewed/nonnormal under dry conditions; and agricultural practices of row tilling and terracing were shown to exert a major control on observed moisture content variations. Results presented here can be utilized to better evaluate sensor performance, to extrapolate estimates of subgrid‐scale variations in moisture content across the entire SGP97 region, and in the parameterization of soil moisture dynamics in hydrological and land surface models.
Winter fluxes of CO2 and CH4 from subalpine soils in Rocky Mountain National Park, Colorado

Fluxes of CO2 and CH4 through a seasonal snowpack were measured in and adjacent to a subalpine wetland in Rocky Mountain National Park, Colorado. Gas diffusion through the snow was controlled by gas production or consumption in the soil and by physical snowpack properties. The snowpack insulated soils from cold midwinter air temperatures allowing microbial activity to continue through the winter. All soil types studied were net sources of CO2 to the atmosphere through the winter, whereas saturated soils in the wetland center were net emitters of CH4 and soils adjacent to the wetland were net CH4 consumers. Most sites showed similar temporal patterns in winter gas fluxes; the lowest fluxes occurred in early winter, and maximum fluxes occurred at the onset of snowmelt. Temporal changes in fluxes probably were related to changes in soil‐moisture conditions and hydrology because soil temperatures were relatively constant under the snowpack. Average winter CO2 fluxes were 42.3, 31.2, and 14.6 mmol m−2 d−1 over dry, moist, and saturated soils, respectively, which accounted for 8 to 23% of the gross annual CO2 emissions from these soils. Average winter CH4 fluxes were −0.016, 0.274, and 2.87 mmol m−2 d−1 over dry, moist, and saturated soils, respectively. Microbial activity under snow cover accounted for 12% of the annual CH4 consumption in dry soils and 58 and 12% of the annual CH4 emitted from moist and saturated soils, respectively. The observed ranges in CO2 and CH4 flux through snow indicated that winter fluxes are an important part of the annual carbon budget in seasonally snow‐covered terrains.
Reference spectra to classify Amazon water types

Reference spectra extracted from spectral libraries can distinguish different water types in images when associated with limnological information. In this study, we compiled available databases into a single spectral library, using field water reflectance spectra and limnological data collected by different researchers and campaigns in the Amazonian region. By using an iterative clustering procedure based on the combination of reflectance and optically active components (OACs), reference spectra representative of the major Amazonian water types were defined from this library. Differences between the resultant limnological classes were also evaluated by paired t-tests at significance level 0.05. Finally, reference spectra were tested for Spectral Angle Mapper (SAM) classification of waters in Hyperion/Earth Observing-One (EO-1) and Medium Resolution Imaging Spectrometer (MERIS)/Environment Satellite (Envisat) images acquired simultaneously as the field campaigns. Results showed highly variable concentrations of OACs due to the complexity of the Amazonian aquatic environments. Ten classes were defined to represent this complexity, broadly grouped into four limnological characteristics: clear waters with low concentrations of OACs (class 1); black waters rich in dissolved organic carbon (DOC) (class 2); waters with large concentrations of inorganic suspended solids (ISSs) (classes 3–7); and waters dominated by chlorophyll-a (chl-a) (classes 8–10). Using the ten reference spectra, SAM classification of the field water curves produced an overall accuracy of 86% with the highest values observed for classes 3, 4, 6 and 7 and the lowest accuracy for classes 1 and 2. The results of paired t-tests confirmed the class differences based on the concentrations of OACs. SAM classification of the Hyperion and MERIS images using ground truth information resulted in overall classification accuracies of 48% and 67%, respectively, with the highest errors associated with specific portions of the scenes that were not adequately represented in the spectral library.
Water stress effects on combining ability and gene action of yield and genetic properties of drought tolerance indices in maize.

This study was carried out, in order to investigate the genetic structure of the 36 maize hybrids established from eighteen female lines and two male testers according to linextester method under non water stress and water stress conditions. So, 36 generated hybrids were planted in two experiments with normal irrigation and water stress at grain filling stage in Iran in 2008, using a RBCD design with three replications. The results showed that the effect of gene action could be both non additive and additive in the expression of grain yield under both conditions. However, GCA/SCA variance ratio revealed that non additive genetic variance was more important for grain yield than additive variance. Grain yield recorded high genetic variance value under non water stress condition compared to those under water stress condition. Also, narrow and broad sense heritability estimates in non water stress condition were higher than water stress condition. The lines L8, L11 and L17 in non stress condition and the lines L15, L16 and L17 in stress condition showed better general combining abilities for grain yield. The crosses such as L1xT1, L4xT1 and L8xT1 in non stress condition and L9xT2 in stress condition showed better specific combining abilities for grain yield. For choosing high efficient drought tolerance indices (SSI, TOL, MP and STI), broad sense heritability, narrow sense heritability and correlation of these indices were estimated. The results showed that STI was a successful index to select high yield and tolerant genotypes in comparison to SSI and TOL indices. Based on yield in both conditions and STI, the crosses L1xT1, L4xT1, L8xT1 and L17xT1 had the best tolerance to water stress at grain filling stage
A Modeling Study of the Interannual Variability in the Wintertime North Atlantic Ocean

Abstract A new model for the upper North Atlantic Ocean is presented and used to hindcast the SST from 1950 to 1988. The model consists of a matrix of one-dimensional (independent) columns in which a variable-depth, bulk mixed layer overlies a diffusive convective thermocline. The climatological annual cycle of heat flux convergence by the oceanic circulation is implicitly included in the formulation of the forcing. The 39-yr control integration of the model includes as surface forcing the shortwave and net longwave radiation from a control integration of the community climate model. Sensible and latent heat fluxes are determined from instantaneous values of surface temperature, humidity, and wind speed from the atmospheric model, and the SST simulated by the ocean model using the bulk formulae. The hindcast is performed by repeating the control integration, adding the observed, monthly mean surface anomalies in surface temperature, humidity, and wind speed for the period 1950–88. Thus, the simulated SST .
On the Relationship between Subordinates’ Compliance to Power Sources and Organisational Attitudes

Social power involves the potential to influence others and is important in explaining organisational outcomes. Based on the assumptions posited in Raven’s (1992, 1993) power interaction model, we examined a set of potential antecedents and correlates of power sources. Participating in the study were 232 nurses and 32 supervisors from two municipal hospitals. Nurses and supervisors were asked to complete a battery of questionnaires including demographic items, the Interpersonal Power Inventory, job satisfaction, and organisational commitment. Convergent and discriminate validity of the power inventory yielded satisfactory results. Principal component analyses of the power inventory revealed a two-factor solution (harsh/soft sources) which was then used for comparison with predictors and outcome data. Among the major findings were the fact that compliance to power sources appears to be contingent on objective and subjective indices of professional distance between supervisors and subordinates, supervisor seniority in the department, and the type of promotion (from without or within department). Job satisfaction was found to be positively related to compliance with soft sources and negatively with harsh sources whereas commitment was positively associated with both.
Field Behavior of a Geogrid Reinforced Soil Retaining Wall with a Wrap-Around Facing

The earth pressure and deformation characteristics of a geogrid reinforced soil retaining wall were monitored during and for a period of 1.5 years after construction. Both vertical and lateral soil stresses were recorded with vibrating-wire earth pressure cells, and the reinforcement deformations were measured using flexible displacement sensors. The maximum vertical foundation pressure along the wall’s reinforcements occurred at the center of the reinforcement, gradually decreasing towards the front and back ends. The measured lateral earth pressure within the reinforced soil wall is non-linear along the wall height, and the value is less than the theoretical active lateral earth pressure. The distribution of tensile strain along the reinforcements within the lower portion of the wall has two peak values. The potential failure surface of the wall closely follows the theoretical Coulomb failure surface of an unreinforced backfill.
THE SHADOW-ZONE OF LARGE ITALIAN EARTHQUAKES. EARLY JOURNALISTIC SOURCES AND THEIR PERCEPTION OF 17TH-18TH CENTURIES SEISMICITY

From their earliest beginnings in the 16th century, journalists never failed to find earth-quakes interesting. As a result, early journalistic sources offer a huge hoard of original earthquake data, mostly untapped to this day for seismological purposes [Camassi and Castelli, 2003]. In the aftermath of large earthquakes, the journalists of the 17th and 18th centuries tended to react in two ways. Either their interest for seismic news would increase, leading them to hunt for more news of the same kind, or it would focus exclusively on the “big one” to the detriment of lesser contemporary earthquakes. In the first case, it was possible that more earthquakes than usual would be given coverage; but in the second case more earthquakes than usual were likely to be overlooked and shadowed by the larger event. Through a comprehensive cross-check of Italian early journalistic sources, this paper attempts to highlight the “shadow-zones” of some major 17th–18th centuries Italian earthquakes.
Postseismic displacement of the 1999 Athens earthquake retrieved by the Differential Interferometry by Synthetic Aperture Radar time series

[1] In September 1999, a moderate (Mw = 5.9) earthquake struck the Attica plain, causing unexpected and extensive damage to Athens and its population. In this work, we exploit the potential of multitemporal Differential Interferometry by Synthetic Aperture Radar (DInSAR) analysis, using about a hundred European Remote Sensing (ERS) 1/2 images to calculate the displacement time series from 1992 to 2002. This analysis allows us to clearly separate a strictly coseismic signal from a postseismic gradual subsidence, reaching a maximum value of about 3 cm in the following 2.5 years. We model this signal in terms of afterslip on the seismogenic fault. The afterslip distribution, retrieved by linear inversion, reflects the coseismic slip distribution and occurs mainly downdip of the area that ruptured during the main shock. The analysis of the static stress transfer suggests that the afterslip was triggered by the main shock, then it propagated aseismically through the fault plane. A partial overlap between the coseismic and aseismic slip area at the hypocentral region indicates that the 1999 rupture surface was not ‘‘healed’’ at least until the date of the last postseismic image (April 2002). The results obtained with a time series approach for this moderate magnitude earthquake suggest that multitemporal DInSAR analysis should become an important methodology for the study of large earthquake ruptures.
Exhumation of the Pyrenean orogen: implications for sediment discharge

Apatite fission track analyses of 21 samples from the central and eastern Pyrenees are modelled to generate time–temperature plots for the post 110±10 °C cooling history over the 40–10 Ma time interval. Modelled thermal histories have been converted into exhumation plots through the application of the present‐day geothermal gradient in the Pyrenees. The documented geology of the Pyrenees allows us to assume no significant extensional unroofing and subvertical exhumation trajectories, thus enabling exhumation to be translated into erosional denudation. Maps of denudation have been constructed for six, 5‐Myr time intervals. Denudation varied with a 20–50‐km length scale, and does not appear to have been related to the major structural zones of the mountain belt. Spatially averaged denudation rates for the six time intervals ranged from 34 to 61 mm kyr−1 assuming the present‐day geothermal gradient. Maximum rates of 240 mm kyr−1 occurred in the interval 35–30 Ma, in the region of the Querigut‐Millas massif.
(E)-N′-(5-Bromo-2-hydroxybenzylidene)-2-(4-isobutylphenyl)propanohydrazide

The title compound, C20H23BrN2O2, containing an ibuprofen core, crystallizes with three independent molecules of similar conformation in the asymmetric unit. In these three molecules, the two benzene rings make dihedral angles of 82.7 (2), 71.2 (2) and 78.0 (3)° with respect to each other. The atoms of the isobutyl groups in two of the molecules are disordered over two positions, with site-occupancy ratios of 0.516 (8):0.484 (8) and 0.580 (8):0.420 (8). In the crystal, molecules are linked by N—H⋯O, C—H⋯O and O—H⋯N hydrogen bonds. Furthermore, C—H⋯π interactions are also observed.