The Karavansalija Mineralized Center at the Rogozna Mountains in SW Serbia: Magma Evolution and Time Relationship of Intrusive Events and Skarn Au ± Cu–Pb–Zn Mineralization

The Karavansalija Mineralized Center (KMC) with its Au–Cu skarn mineralization associated with the Rogozna Mountains magmatic suite in southwestern Serbia belongs to the Oligocene Serbo-Macedonian magmatic and metallogenic belt (SMM-MB). Samples from intrusive and volcanic rocks at the KMC show typical arc signatures of subduction-derived magmas through enrichment in large-ion lithophile elements (LILE) and depletion of high–field strength elements (HFSE). The magmas developed a high-K (calc-alkaline) fractionation trend and evolved toward shoshonitic compositions. Whole-rock trace element data suggest plagioclase-absent, high-pressure amphibole ± garnet fractionation that generates adakite-like hydrous magmas during evolution in lower crustal magma chambers. Zircon LA–ICP–MS and high-precision CA–ID–TIMS dating together with zircon trace elements and Hf isotope measurements were carried out in order to couple the geochronologic and geochemical evolution of the KMC. The results suggest that magmatism starts around 29.34 Ma with granitic to rhyodacitic subvolcanic intrusions followed by a more evolved magmatic intrusion that was emplaced into Cretaceous limestone, generating a widespread skarn alteration at ca. 28.96 Ma. After a period of quiescence of about 1.2 My, either another magma body evolved or the same upper crustal magma chamber was recharged and also likely partly reactivated older plutonic rocks as indicated by xenocrysts. The REE ratios shift from apatite, titanite ± amphibole-dominated fractionation of the older magmatic event to crystallization of allanite, efficiently depleting the LREE and Th/U in the younger upper crustal magma. After a lamproite-like melt was injected, the increased heat and fluid pressure led to the expulsion of a quartz-monzonite porphyritic stock at ca. 27.72 Ma, strongly interacting with the skarns and established a fertile hydrothermal system. Soon after a non-mineralized second pulse of some porphyry dykes cut the previous phenocryst-rich “crowded” porphyries and skarns at ca. 27.60 Ma, thus bracketing the maximum timespan of ore mineralization to about 112 ± 45 Ka. Increased contribution of a lamproite-like melt is inferred from the presence of phlogopite micro-phenocrysts, phlogopitization of biotite, and diopside clusters in the latest porphyry dykes. There is a trend of increased crustal assimilation from the oldest volcanic phase to the emplacement of the youngest porphyry dykes recorded by ɛ-Hf of the zircons. Oligocene occurrences of significant base metal mineralization within Serbia, northern Macedonia, and Greece, e.g., Crnac, Rudnik, Veliki Majdan, Stratoniu, or the Cu–Au porphyry at Buchim (northern Macedonia), are all associated with trachy-andesitic (quartz latitic) porphyry dykes, which originated through post-collisional tectonic settings or upper plate extension involving reworking of crustal arc-derived rocks and partial melting of the mantle wedge. This study demonstrates that on the basis of field relationships and the application of high-precision CA-ID-TIMS zircon age data, pulses of porphyry dykes of a 10ka age range can be distinguished, and the timing of mineralization can be parenthized.