Miracle-dz/UniFAR-FTUs huggingface dataset:
Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 1. C1-C10

A compendium of phase change enthalpies published in 2010 is updated to include the period 1880–2015. Phase change enthalpies including fusion, vaporization, and sublimation enthalpies are included for organic, organometallic, and a few inorganic compounds. Part 1 of this compendium includes organic compounds from C1 to C10. Part 2 of this compendium, to be published separately, will include organic and organometallic compounds from C11 to C192. Sufficient data are presently available to permit thermodynamic cycles to be constructed as an independent means of evaluating the reliability of the data. Temperature adjustments of phase change enthalpies from the temperature of measurement to the standard reference temperature, T = 298.15 K, and a protocol for doing so are briefly discussed.
Defective graphitic carbon nitride synthesized by controllable co-polymerization with enhanced visible light photocatalytic hydrogen evolution

Defects have a vital effect on the band structures and properties of semiconductor photocatalysts. Herein, we developed a one-step strategy to introduce defects in the framework of g-C3N4 by controllable copolymerization of melamine with a series of partially reactive end capped monomers. The capping molecules have great impacts on the properties of modified g-C3N4. The obtained defective g-C3N4 exhibits an increased surface area, improved charge carrier separation efficiency, and a narrowed band gap with a negative shift of the conduction band. Particularly, defect-rich CN-DPT shows 10 times improvement of visible light activity for hydrogen production compared with pristine g-C3N4.
Website Quality Affects Online Impulse Buying Behavior (OIBB): Moderating Effects of Sales Promotion and Digital Wallet Use (A Study on Tokopedia E-Commerce)

This study aims to analyze the website quality effect on OIBB, along with the moderating effect of the sales promotions and digital wallet use on Tokopedia ecommerce. The population of this research is consumers who make purchases impulsively through the Tokopedia website within the last one month. The sample size was 150 residents living in Denpasar with a purposive sampling method and was distributed using a questionnaire, with criteria that had been adjusted through Google Form. Moderated regression analysis will be used as a data analysis technique. The results showed that website quality, sales promotion, and digital wallet use had an effect on OIBB simultaneously. Sales promotion does not have a significant effect on OIBB partially, meanwhile on other factors, there are positive and significant effects. Sales promotion and digital wallet use are also able to moderate and strengthen the relationship between website quality and OIBB.
Corporate Social Responsibility Of Shariah Compliant Consumer Product And Services Industry

This paper attempts to measure the financial performance of the Shariah-compliant companies, specifically on the consumer products and trading & services industry and to investigate the relationship between the Corporate Social Responsibility (CSR) practices and financial performance of the Shariah compliant consumer product and services industry. The idea of this comparative study is established from the prior literature pertaining to the embedded-typed and peripheral-typed CSR which attempt to reflect the nature of the business and CSR practices of the companies. Since this study is quantitative in nature, thus it employs analysis of secondary data through the Shariah-compliant company’s annual report. The findings of the study seem to suggest that the association between the tested variable(s) is relatively unable to be supported, as there is no significant relationship between the embedded CSR and peripheral CSR and the financial performance of the sample companies. Ways forward and limitation of the study are further deliberated.
Introduction of microscopic non-indigenous species through ballast water in Arzew Gulf (SW Mediterranean Sea): the case of the harmful raphidophyceae Fibrocapsa japonica S.Toriumi et H.Takano, 1973 (Chattonellaceae)

The transfer of non-indigenous species (NIS) into the marine environment is mainly carried out by maritime transport (biofouling or ballast water). Ports are therefore the gateway to NIS, which can alter local biodiversity. In this study, the port of Arzew and Bethioua (Algeria, south-western Mediterranean) were studied for the presence of NIS by taking the case of the harmful Raphidophyceae Fibrocapsa japonica. Seawater samples were collected following a comparative sampling strategy between Arzew Gulf (AG region: presence of two hydrocarbon transport ports) and Ain Temouchent (AT region: absence of transport port reference area). The Almeria-Oran front separates the two regions. The AT and AG regions generally have the same temperature, salinity and chlorophyll characteristics. The phtyhoplankton population showed a homogeneous quantitative distribution between the AT and AG regions. Diatoms and dinoflagellates have an equal density in both regions, nevertheless diatoms are more abundant in each region, (diatoms 6950 ind/l in AT 6380 ind/l in AG, dinoflagellates 1920 ind/l in AT and 1770 ind/l in AG). The specific assessment of the phytoplankton population revealed the presence of F. japonica at around 110 ind/l in the AG region in one station across the ports of Arzew and Bethioua and near the coast, and its absence in the reference area AT. Despite its presence in low density in a single station, this species remains harmful and presents a real danger if it is transported by the Algerian current along the coast to other places, in particular fisheries and aquaculture production areas. This study is part of a prevention process, is the first signaling of microscopic non-indigenous species on the Algerian coast, and contributes to establish a database for future assessments of microscopic NIS in Algerian ports.
Morphology regulation, structural, and photocatalytic properties of ZnO hierarchical microstructures synthesized by a simple hydrothermal method

Zinc Oxide (ZnO) hierarchical microstructures with diverse morphologies were prepared through a simple one‐step hydrothermal method with zinc chloride and sodium hydroxide as source materials, and citric acid as the modifying agent. The structure and morphology of the samples were studied through X‐ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, and Brunauer–Emmett–Teller specific surface area determination. The morphology of the samples was easily regulated by changing the concentration of citric acid. Branchy structures, porous flowers, porous microspheres, solid flowers, solid flower spheres, and solid spheres of ZnO were obtained. The porous structures obtained with 150–200 mmol · L−1 citric acid showed excellent photocatalytic activities for the degradation of methylene blue under UV irradiation. A possible regulation mechanism of citric acid in ZnO crystals was proposed based on the experimental results.
Impact of mobile advertising wearout on consumer irritation, perceived intrusiveness, engagement and loyalty: A partial least squares structural equation modelling analysis

Purpose: Mobile and smart devices provide a platform for firms/brands to communicate directly with past, present, or potential consumers (via online pop-ups, sponsored ads, ads on social media messengers, timelines, and walls, etc.). Intense competition among firms and brands resulted in repetitive exposures to Ads by consumers. Existing research on human–mobile interaction and end-user mobile management only highlights the positive fronts of repetitive exposures to mobile ads, ignoring the negative. The present study examines the effects of Mobile Ad Wearout on irritation, intrusiveness, engagement, and loyalty via social media outlets. Design/methodology/approach: Survey data were solicited from consumers in Jordan and partial least squares structural equation modeling (PLS-SEM) was applied on data ( n = 388). Findings: The PLS-SEM results show that Mobile Ad Wearout is a strong determinant for increased perceived consumer irritation and intrusiveness. Intrusiveness resulted in lower levels of consumer engagement and higher levels of consumer loyalty. Irritation resulted in lower levels of consumer engagement; no changes were observed in consumer loyalty Practical implications: The study shows managers how Mobile Ad Wearout causes irritation and intrusiveness, which in turn diminishes consumer engagement and loyalty. In essence, managers can gain insights on the positive and negative outcomes of Mobile Ad Wearout. Originality/value: This study expands the conceptualization of repetitive mobile Ads by showing the negative fronts of mobile Ads. Implications for theory and practice offered, limitations and future research directions are discussed.
SISTEM INFORMASI PENJUALAN SEPEDA BERBASIS WEB MENGGUNAKAN FRAMEWORK CODEIGNITER

Orbit Station merupakan salah satu perusahaan penjual sepeda yang berada di kota Bandar Lampung. Permasalahan yang dihadapi, selama ini sistem penjualan masih mengandalkan media interaksi dengan konsumen secara langsung dan konsumen yang akan membeli harus datang ke toko secara langsung. Kendala lain, pengelolaan data pemesanan konsumen yang tidak tersusun secara rapih, serta proses penjualan yang masih menyita banyak waktu dikarenakan pengelolaan data masih dilakukan secara manual di buku catatan, lalu akan direkap menggunakan aplikasi Ms.Excel. Sebagai solusi maka dibangunnya sistem informasi penjualan sepeda pada Orbit Station berbasis website.Tujuan dari penelitian yang dilakukan adalah untuk membangun sistem informasi penjualan sepeda untuk mempermudah proses penjualan produk pada Orbit Station. Dalam pengembangan sistem ini digunakan metode waterfall yang meliputi tahap komunikasi, perencanaan, pemodelan, pengkodean dan pengujian sistem. Pada Tahap perancangan ini pengembangan sistem menggunakan PHP dan MySQL dikarenakan PHP merupakan Script yang terintegrasi dengan HTML dan berada pada server (server side HTML embedded scripting ). PHP adalah script yang digunakan untuk membuat halaman website yang dinamis yang berarti halaman yang akan ditampilkan dibuat saat halaman itu diminta oleh client. Mekanisme ini menyebabkan informasi yang diterima client selalu yang terbaru/ uptodate. Dengan menggunakan program PHP, sebuah webesite akan lebih interaktif dan dinamis. PHP adalah bahasa server-side-scripting yang menyatu dengan HTML untuk membuat halaman web yang dinamis. Sedangkan MySQL adalah singkatan dari structur Query Language yang digunakan untuk mendefinisikan structur data, memodifikasi data pada basis data, menspesifikasi batasan keamanan (scurity), hingga pemeliharaan basis data. MySQL adalah RDBMS yang cepat dan mudah digunakan, serta sudah banyak digunakan untuk berbagai kebutuhan. Perancangan sistem pada penelitian ini menggunakan UML (Univiet Modeling language). UML merupakan bahasa visual untuk pemodelan dan komunikasi mengenai sebuah sistem dengan menggunakan diagram dan teks-teks pendukung.Hasil penelitian yang didapat sistem informasi penjualan yaitu untuk memudahkan kinerja petugas dalam meningkatkan penjualan produk sepeda kepada konsumen sekaligus mempermudah petugas dalam pengelolaan data produk dan mempermudah proses pencatatan barang secara terkomputerisasi. Pengujian kelayakan sistem informasi penjualan telah berhasil diuji menggunakan teknik kuesinoer dan dikonversi berdasarkan kriteria kelayakan sistem. Beberapa hasil uji kelayakan sistem terhadap fungsional admin diperoleh nilai 100% atau layak dan fungsional konsumen diperoleh nilai 100% atau layak.
Minimally-invasive donor hepatectomy at the dawn of a decade: can we pick up the pace?

Next year will mark two decades since the first minimally-invasive donor hepatectomy (MIDH) was performed in Paris to facilitate an adult-to-child live donor liver transplant (LDLT). Despite improvements and widespread proliferation of LDLT throughout the world, a concomitant broader application of the MIDH technique has not been wholly realized due to concerns over donor safety and the technical difficulties inherent to MIDH. On the contrary, during the same time period, minimallyinvasive liver surgery (MILS) rapidly evolved into a standard approach for many benign and malignant forms of liver disease. To support this growth, numerous novel technologies such as advanced laparoscopy and robotic surgical systems, three-dimensional (3D) flexible videoscopy, real-time near-infrared fluorescence cholangiography with indocyanine green (ICG), and a variety of thermal energy devices and endovascular staplers have evolved and matured in the setting of MILS. A handful of select, high-volume liver transplant centers have incorporated these MILS advancements into their established segmental liver surgery and LDLT programs in order to develop the requisite technical sophistication to execute MIDH in an impactful manner. Two techniques, pure laparoscopic donor hepatectomy (PLDH) and robotic donor hepatectomy (DH), have emerged as the dominant modalities in MIDH surgery with each having their proponents and detractors. A few centers in Asia, France, the United States, and Saudi Arabia have recently reported series of sufficient volume and nuance to be instructive for the field in general. The intent of this review is to describe the experience to date in MIDH with a particular focus on lessons learned at these pioneering institutions who navigated through the learning curves in these demanding technical endeavors. The tricks, observations, and recommendations gleaned from this article should serve as a vital resource for those motivated surgeons embarking upon the challenging but rewarding field of MIDH surgery.
Examining the Immunomodulatory Effects of the Novel Probiotic Bacillus subtilis de111

Probiotics make up a large and growing segment of the commercial market of dietary supplements and are touted as offering a variety of human health benefits. Some of the purported positive impacts of probiotics include, but are not limited to, stabilization of the gut microbiota, prevention of gastrointestinal disorders and modulation of the host immune system. Current research suggests that the immunomodulatory effects of probiotics are strain specific and vary in mode of action. Here, we examined the immunomodulatory properties of Bacillus subtilis strain DE111 in a healthy human population. In a randomized, double blind, placebo-controlled four-week intervention, we examined peripheral blood mononuclear cells (PBMCs) at basal levels pre- and post-treatment as well as in response to stimulation with bacterial lipopolysaccharide (LPS). We observed an anti-inflammatory effect of B. subtilis, manifested as a decrease in immune cell populations within the basal state along with an increase in anti-inflammatory immune cells in response to LPS stimulation. Overall gastrointestinal health, microbiota, and circulating and fecal markers of inflammation and gut barrier function were largely unaffected by DE111 treatment. These data suggest that the novel probiotic B. subtilis DE111 may have clinical applications in modulating immune homeostasis via anti-inflammatory mechanisms.
Surface Properties of Al–Fe–Si Liquid Alloy Using Thermodynamic Database

Temperature-dependent interaction parameters for excess free energies of mixing of sub-binary systems of Al-Fe-Si ternary liquid alloys were optimised using the experiment data in the frame of Redlich-Kister (R-K) polynomials. These optimised parameters were then used to compute the partial excess free energy of sub-binary and ternary liquid alloys. The surface tension and surface concentration of sub-binary and the ternary liquid alloys were computed using Butler equation. The temperature dependent coefficients of R-K polynomials for excess surface tensions of the sub-binary systems were optimised which were then used to estimate the surface tension of ternary alloy using Chou, Kohler and Toop modelling equations at temperatures 1773, 1873, 1973 and 2073 K. The surface tension of the ternary alloy obtained using aforementioned models were found to be in good agreement from Fe and Al corners but some deviations were observed from Si corner.
Building Standardized and Secure Mobile Health Services Based on Social Media

Mobile devices and social media have been used to create empowering healthcare services. However, privacy and security concerns remain. Furthermore, the integration of interoperability biomedical standards is a strategic feature. Thus, the objective of this paper is to build enhanced healthcare services by merging all these components. Methodologically, the current mobile health telemonitoring architectures and their limitations are described, leading to the identification of new potentialities for a novel architecture. As a result, a standardized, secure/private, social-media-based mobile health architecture has been proposed and discussed. Additionally, a technical proof-of-concept (two Android applications) has been developed by selecting a social media (Twitter), a security envelope (open Pretty Good Privacy (openPGP)), a standard (Health Level 7 (HL7)) and an information-embedding algorithm (modifying the transparency channel, with two versions). The tests performed included a small-scale and a boundary scenario. For the former, two sizes of images were tested; for the latter, the two versions of the embedding algorithm were tested. The results show that the system is fast enough (less than 1 s) for most mHealth telemonitoring services. The architecture provides users with friendly (images shared via social media), straightforward (fast and inexpensive), secure/private and interoperable mHealth services.
Patterns of Interrelationships between Inflation, R&D, Innovation, and Economic Growth: Evidence from Central and Eastern European Countries

The primary objective of the article is to examine the nexus between inflation, R&D, patents, and economic growth within a group of Central and Eastern European countries (CEECs). The examination is conducted in two parts. First, the impact of total R&D expenditures on economic growth is observed, as well as the influence of growth on private and public R&D investments. Second, the conversion from private and public R&D investment to innovation, measured by the number of patents, is observed. Throughout the analysis, economic growth and inflation are representative of macroeconomic stability. The outcomes of the panel auto-regressive distributed lag estimation indicate that total R&D expenditures are essential and positively significant for economic growth in the observed countries. The results also show that output growth has a remarkably positive impact on generating private R&D expenditures. Such an influence is also found, but at a weaker level, in the case of public R&D expenditures. In this part of the analysis, inflation has demonstrated a harmful influence on R&D expenditures. The results of the second part indicate that public and private R&D expenditures, at a significant level, generate innovation activities, while the impact of inflation has proven to be unimportant.
‘It’s just a case of chipping away': A postfeminist analysis of female coaches’ gendered experiences in grassroots sport

ABSTRACT A plethora of work has identified forms and sources of gender inequality in sport coaching. Quantitative studies with psychological framings dominate the literature. However, a smaller and more recent body of qualitative work has identified structural gender hierarchies as the root of inequalities, specifically the prevalence of hegemonic masculinity. Fewer studies have contextualised understandings of women’s experiences of this, particularly at grassroots levels and there is little acknowledgement of a notable shift in the visibility of women’s power and presence in society including sport. Thus, in this study [Gill, R. (2007). Gender and the media. Polity Press] postfeminist sensibility was used to examine seven female coaches’ experiences of various grassroots sports settings, specifically what might be novel in women’s contemporary coaching experiences, but also to acknowledge any persistent structural inequalities. Findings suggest that while female coaches are continually facing challenges borne out of dominant forms of masculinity which remain deeply rooted in sport cultures, they are actively contesting and navigating these by drawing upon performed masculinities. Consequently, new femininities have emerged, but these are fragile, often misinterpreted and can lead to women struggling to progress their coaching careers. Future work in this field should look to develop the use of postfeminist lenses in similar ways, to further identify new(er) femininities which have the potential to grow and develop women’s representation in coaching.
Reply on RC2

This manuscript presents a comparison of predictions from the CMAQ model driven by meteorological fields derived from the FV3-GFSv16 (or GFS) and WRF models for periods coinciding the 2019 FIREX-AQ field campaign. The GFS-CMAQ system comprising of CMAQv5.3. 1 and the FV3-GFSv16 now constitute the operational National Air Quality Forecast Capability. Consequently, a study assessing the performance of the system relative to both predictions from another modeling system (in this case the widely used WRF-CMAQ configuration) as well as multi-species measurements from a field campaign would be of interest for establishing the efficacy of the recently updated NAQFC system. While the manuscript presents a significant amount of work in terms of simulations with the two modeling systems and comparisons with airborne measurements taken during the FIREX-AQ campaign, and for most part shows similar performance for the GFS-CMAQ and WRF-CMAQ models, the execution of the analysis in the current form in my assessment did not present in a compelling manner either the impacts of the different meteorological drivers on the predicted air quality or the ability of the NAQFC improvements in capturing the effects of fire emissions on air quality. Some of this perhaps results from the study design trying to cover too much ground. For instance, uncertainties in estimating fire emissions (magnitude, composition, placement (vertically and burn area)) confound isolating meteorological differences from those resulting from emission uncertainties. Comparisons with high time (and space) resolution measurements are confounded by limitation in model grid to reasonably isolate meteorological difference impacts. Similarly, use of data assimilation (strong nudging) also likely reduces the differences between the GFS and WRF fields making it difficult to identify impacts associated with either physics (PBL, cloud representation), or computational differences (interpolation vs. native grid). Perhaps a clearer articulation of the study objectives and closer linkage of the analysis with the objectives would help improve the overall usefulness of the manuscript. Also, many of the inferences conveyed by the analysis could benefit from additional substantiation. The following suggestions are offered that may help address these shortcomings: