Evaluating the Elemental Composition, Transformation Behavior, Crystalline Structure, and Mechanical Properties of Three 0.016-Inch by 0.022-Inch Nickel-Titanium Archwires: An In Vitro Study

Background Nickel-titanium (NiTi) archwires are considered the most attractive wires during the first stage of orthodontic treatment because of their unique properties throughout several generations. This study aimed to evaluate three different NiTi wires in terms of their elemental composition, transformation behavior, crystalline structure, and mechanical properties. Materials and methods The study used three different groups of NiTi archwires with dimensions of 0.016 x 0.022-inch (American Orthodontics®, Sheboygan, WI, USA). The first group included six superelastic NiTi archwires (NT3-SE®), with normal force and a stable structure that was not affected by temperature changes. The second group included six heat-activated NiTi archwires activated at 25°C (Thermal Ti-D®), with moderate force and a sensitive structure to thermal changes, especially at room temperature. The third group included six heat-activated NiTi archwires activated at 35°C (Thermal Ti-Lite®), with light force and a sensitive structure to thermal changes, especially at body temperature. X-ray fluorescence (XRF) was performed to determine wire element composition, whereas differential scanning calorimetry (DSC) was performed to determine the austenite finish temperature (Af). The X-ray diffraction (XRD) analysis was used to identify the crystalline structure at room temperature, and a three-point bending test was carried out under constant temperature (37°C) with respect to the instructions of ISO15841/DIS to evaluate the mechanical properties of these wires. Results The XRF analysis revealed that the superelastic NiTi archwires (NT3-SE) were composed of NiTi and chrome, whereas the heat-activated wires (Thermal Ti-D and Thermal Ti-Lite) were composed of NiTi and copper. The DSC showed the Af was at +16.84°C for the superelastic type (NT3-SE), +23°C for the heat-activated at 25°C (Thermal Ti-D), and +33.99°C for the heat-activated at 35°C (Thermal Ti-Lite). The XRD analysis identified the crystalline structure at room temperature for the superelastic type (NT3-SE) as austenite, while for thermal types (Thermal Ti-D and Thermal Ti-Lite) were a compound structure of austenite and martensite phase. Finally, the bending test showed that the highest forces were delivered from the superelastic type (NT3-SE), followed by heat-activated at 25°C (Thermal Ti-D), while the lowest forces were delivered from heat-activated at 35°C (Thermal Ti-Lite). There was no significant difference between the superelastic type (NT3-SE) and thermally activated type at 25°C (Thermal Ti-D), while there was a significant difference between the two previous types and the thermally activated type at 35°C (Thermal Ti-Lite) for all studied unloading points. Conclusions The thermal types of archwires (Thermal Ti-D and Thermal Ti-Lite) had lower unloading values in comparison with the superelastic type (NT3-SE). The elemental composition was different between the superelastic wires and the thermal ones. The superelastic wires were also different from the other two types in terms of crystalline structure. The three types of archwires had an activation degree located in the range of oral cavity variations.