Miracle-dz/UniFAR-FTUs huggingface dataset:
Synthesis, Coordination, and Catalytic Use of 1′-(Diphenylphosphino)ferrocene-1-sulfonate Anion

Sulfonation of (diphenylphosphinothioyl)ferrocene (1) with chlorosulfonic acid in acetic anhydride affords the crude sulfonic acid Ph2P(S)fcSO3H (2; fc = ferrocene-1,1′-diyl), which can be efficiently purified and isolated after conversion to Ph2P(S)fcSO3(HNEt3) (3). Methyl triflate/P(NMe2)3 can be used to convert compound 3 to the stable sulfonate salt Ph2PfcSO3(HNEt3) (4) and Ph2P(Me)fcSO3 (5) as a minor, zwitterionic byproduct. Alternatively, compound 4 can be prepared by lithiation of 1′-(diphenylphosphino)-1-bromoferrocene (6; Ph2PfcBr) and trapping of the lithiated intermediate with SO3·NMe3. Reactions of [(LNC)PdX]2 and [(LSC)PdX]2, where X = Cl, AcO, LNC = 2-[(dimethylamino-κN)methyl]phenyl-κC1, and LSC = 2-[(methylthio-κS)methyl]phenyl-κC1, with 4 uniformly produced the bis-chelate complexes [(LNC)Pd(Ph2PfcSO3-κ2O,P)] (7) and [(LSC)Pd(Ph2PfcSO3-κ2O,P)] (8), respectively. The reaction of [PdCl2(MeCN)2] with 4 afforded the bis(phosphine) complex trans-(Et3NH)2[PdCl2(Ph2PfcSO3-κP)2] (9). Complexes 7.
Electron collisions and internal excitation in stored molecular ion beams

In storage ring experiments the role, which the initial internal excitation of a molecular ion can play in electron collisions, and the effect of these collisions on the internal excitation are investigated. Dissociative recombination (DR) and inelastic and super-elastic collisions are studied in the system of He2+. The DR rate coefficient at low energies depends strongly on the initial vibrational excitation in this system. Therefore changes in the DR rate coefficient are a very sensitive probe for changes in the vibrational excitation in He2+, which is used to investigate the effects of collisions with electrons and residual gas species. The low-energy DR of HD+ is rich with resonances from the indirect DR process, when certain initial rotational levels in the molecular ion are coupled to levels in neutral Rydberg states lying below the ion state. Using new procedures for high-resolution electron-ion collision spectroscopy developed here, these resonances in the DR cross section can be measured with high energy sensitivity. This allows a detailed comparison with results of a MQDT calculation in an effort to assign some or all of the resonances to certain intermediate Rydberg levels.
Learning not to take the bait: a longitudinal examination of digital training methods and overlearning on phishing susceptibility

ABSTRACT As phishing becomes increasingly sophisticated and costly, interventions that improve and prolong resistance to attacks are needed. Previous research supported digital training as a method to reduce phishing susceptibility. However, the effects of training degrade with time. Therefore, we investigate overlearning as an approach that may increase skill retention through repetition and developing automaticity. We performed a longitudinal experiment crossing overlearning with anti-phishing digital training (rule-based, mindfulness, and control). Participants were tested using email identification tests (immediately following and 10 weeks after training) and mock phishing messages delivered to their inboxes (1 week and 8 weeks following training). Results showed that compared to rule-based training, mindfulness training resulted in significantly greater retention in terms of better email discrimination and less susceptibility to phishing attacks but similar levels of caution towards phishing after 2 months. Overlearning resulted in significantly less susceptibility to phishing attacks and more caution towards phishing compared to no overlearning but did not impact the digital training approaches. Even so, mindfulness was more beneficial compared to overlearning. Altogether, the results demonstrate the stability of the benefits of mindfulness training over time in terms of mitigating phishing susceptibility without influencing the chances of missing legitimate emails.
Outcome of the Traumatic Extradural Hematoma on the Basis of Size of Extradural Hematoma

Objective: This study aimed to determine the outcome of traumatic extradural hematoma and to compare the outcome of small and large size extradural hematoma. Materials & Methods: A descriptive case series was carried out in the Department of Neurosurgery, Hayatabad Medical Complex Peshawar for six months and included 188 patients. The detailed history and clinical examinations were noted through a pre-designed proforma. Patients were followed post-operatively till the time of discharge and for either favorable outcome or unfavorable outcome according to the GOS. Results: 73% of patients had extradural hematoma volume between 25 – 50 mL, while 27% patients had extradural hematoma >50 mL. 12% of patients had Glasgow Outcome Score (GOS) scores 1 – 3, while 88% of patients had GOS scores: 4 – 5. The mean GOS was 3. Patients with favorable outcomes were 88% while 12% had an unfavorable outcome. Conclusion: The size of the extradural hematoma has a strong correlation with outcome. The greater the size of the hematoma, the poorer the outcome.
Outpatient Shoulder Arthroplasty—A Systematic Review

Objective Recent reports have shown that outpatient shoulder arthroplasty (SA) may be a safe alternative to inpatient management in appropriately selected patients. The purpose was to review the literature reporting on outpatient SA. Methods A systematic review of publications on outpatient SA was performed. Included publications discussed patients who were discharged on the same calendar day or within 23 hours from surgery. Articles were categorized by discussions on complications, readmissions, and safety, patient selection, pain management strategies, cost effectiveness, and patient and surgeon satisfaction. Results Twenty-six articles were included. Patients undergoing outpatient SA were younger and with a lower BMI than those undergoing inpatient SA. Larger database studies reported more medical complications for patients undergoing inpatient compared to outpatient SA. Articles on pain management strategies discussed both single shot and continuous interscalene blocks with similar outcomes. Both patients and surgeons reported high levels of satisfaction following outpatient SA, and cost analysis studies demonstrated significant cost savings for outpatient SA. Conclusion In appropriately selected patients, outpatient SA can be a safe, cost-saving alternative to inpatient care and may lead to high satisfaction of both patients and physicians, though further studies are needed to clarify appropriate utilization of outpatient SA.
PLANT GROWTH-PROMOTING BACTERIA ASSOCIATED WITH NITROGEN FERTILIZATION IN Eucalyptus urophylla INCREASE GROWTH

The objective of this study was to evaluate plant growth-promoting bacteria in eucalyptus, associated with different levels of ammonium sulfate, to know the benefits to initial plant growth, determining which nitrogen level and bacterial isolate is the most effective. Five bacterial isolates and one control without inoculation were used, besides 4 levels of ammonium sulfate, 0, 20, 40 and 60 mg dm -3 N, in a factorial scheme and randomized block design, set in a 20-L pot, with Eucalyptus urophylla clone AEC144. Height, diameter, dry matter, leaf area, Spad index, Ntotal and photosynthesis were evaluated. The isolates UESBJMR32E and UESBJNR32E promote initial growth in eucalyptus plants associated with intermediate doses of ammonium sulfate.
Assessing Environmental Criteria to Support Forest Connectivity

Establishing forest connection in landscapes under urban sprawl is essential for maintaining the ecological processes and ensuring biodiversity conservation. However, the major challenge is incorporated the ecological network in the land-use/land-cover planning. This way, the main objective of the study was the evaluation of environmental criteria for prioritizing areas to obtain forest functional connectivity in a landscape subject to the urban sprawl. The second objective was to understand how the criteria are associated with the structural forest attributes represented by traditional landscape ecology metrics. The criteria were defined through the literature review, representing the landscape characteristics as the topographic, conflicts, and biotics. The metrics used to characterize the forest structure were perimeter, shape index, and distance to the nearest neighbor. They were generated to a selected group of forest remnants, which represent the landscape forest structure. Sampling the criteria and forest fragments maps (i.e., different maps representing the metrics-values) through the hexagon network, we assessed how the criteria are associated with the structural forest attributes. The statistical analysis used to evaluate these sampled values were The Moran Global (Moran I) and Moran Local (LISA). We obtained that the urban expansion process is diffuse, although it does not occur randomly in our landscape. The criteria slope, TWI, distance from drainage network, distance from highways, distance from the low-density urban area, and distance from forest patches have characteristics that support this process. Furthermore, our results indicated a spatial autocorrelation among metrics and after, among metrics and these criteria. Also, we obtained that the external influences on the fragments did not occur randomly and that the criteria act on the landscape. This way, through these criteria, we can identify regions where it is possible to have the persistence of forest fragments, even though in places under the impact of urban sprawl.
Petrological and Geochemical Studies on the Si-Undersaturated Rocks of the Mount Cameroon: Genesis of the Camptonite and Nephelinite at the Cameroon Hot Line

The Cameroon hot line is dominated by magmatic rocks. The variations of magma and chemistry are generally due to the difference of physical conditions and chemistry in the magma source region during the ascent of magma. The Mt Etinde and the Mt Cameroon, both edifices belong to the Cameroon Hot line, have a particularity some rare rocks such as camptonite and nephelinite. The relationship between the silica undersaturated rocks in the both edifices is characterized by the lateral variation appear through the petrography of the different rocks. The concerned geochemical data allow to compare the Mount Etinde nephelinite and Mount Cameroon camptonite where the differentiation process reflects geochemical affinities from a basaltic magma source on the Cameroon hot line. The compatible elements between the Mount Etinde nephelinite and the Mount Cameroon camptonite and basalt correlate with the difference in modal compositions of mineral phases. The lateral variation of major and trace element contents in the Mount Cameroon camptonite and Mount Etinde nephelinite seem to be related to the difference in the fractional crystallization processes of mineral phases, the difference in the partial melting processes and the metasomatism source rich in volatile. The silica-undersaturated character of the camptonite and nephelinite could be attributed to assimilation of carbonate rocks within depth-level magma chambers. Trace element AFC modelling revealed that the parental magmas of both edifice volcanic rocks were mostly affected by fractional crystallisation coupled with metasomatism process in Ca rich source.
CARBON EMISSIONS DISCLOSURE AND FIRM VALUE: DOES ENVIRONMENTAL PERFORMANCE MODERATE THIS RELATIONSHIP?

The objectives of this research is to examine the role of environmental performance in the relation between carbon emissions disclosure and firm value. A measurement tool using content analysis method to measure carbon emissions disclosure that adopts a checklist from the Carbon Disclosure Project (CDP). Firm value is proxies with Tobin's Q, while environmental performance is assessed based on the results of the environmental management performance appraisal program (PROPER). Sample of this study using 34 companies that listed on the Indonesian Sharia Stock Index (ISSI) from 2014 to 2019. Moderated regression analysis (MRA) is used to test the hypothesis. The results indicate the carbon emissions disclosure has a positive and significant effect on firm value. This research also found that there is an evidence that environmental performance can strengthen the relation of carbon emissions disclosure to firm value, due to the company's efforts by participating in the PROPER program is a form of corporate responsibility in an effort to reduce the impact of environmental damage arising from the company's operational activities which have been responded positively by investors.
Fear of a School-to-Deportation Pipeline: How Teachers, Administrators, and Immigrant Students Respond to the Threat of Standardized Tests and Deportation

Existing studies evaluate zero tolerance policies and the school-to-prison pipeline. Additional research identifies the role of criminal justice systems in deporting immigrants. Our work bridges these two literatures by discussing how immigrant students navigate the criminal justice system within schools. Using interviews with immigrant students, teachers, and administrators, we address the question: How is the school-to-deportation pipeline maneuvered by stakeholders? Our study identifies how school authority figures react to and even use the fear of the pipeline to (1) either protect students from becoming criminalized or (2) exclude students from standardized exam participation so as to maintain funding sources.
A Dual Frequency Blade Antenna Enabling UAV-Based Operations in ADS-B and 5G Environments

Driven by the recent enhancements provided by Automatic Dependent Surveillance-Broadcast (ADS-B) and the latest developments in 5th Generation (5G) networks supported by Unmanned Air Vehicles (UAVs), this paper describes the design of an “all-in-one” SMA coaxial fed compact blade antenna with dual frequency characteristics for broadband applications on board of UAVs. A single antenna element is designed using CST Microwave Studio software which shows a dual frequency broadband characteristic, when compared to traditional blade antennas, covering the 1.030 - 1.090 GHz and the 3.4 - 3.8 GHz ranges thanks to an oblique side and a ‘C’ shaped cavity within the radiation element. The designed antenna is simulated on an ideal ground plane first and then extended to a bent ground plane. The results are compared and discussed in terms of return loss, bandwidth, gain and radiation pattern. These results show a lightweight antenna with a low profile and a simple structure that can find numerous applications in various airborne wideband communication systems, suiting future UAV-based networks for 5G and beyond while being perfectly compliant with the ongoing ADS-B based Detect-And-Avoid (DAA) technologies for integration of UAVs in Unmanned Aerial Traffic Management (UTM).
A role for prefoldin in H2A.Z deposition in Arabidopsis

Esta Tesis doctoral ha sido posible gracias al contrato de formacion de personal investigador ofrecido por la Universidad Politecnica de Valencia y a la financiacion de Pedro J. Mari & Asociados. El proyecto al que pertenece este trabajo ha sido financiado por la Agencia Espanola de Investigacion BIO2013-43184-P y BIO2016-79133-P
Hubungan Aktivitas Fisik dengan Kebugaran dan Tingkat Stres pada Karyawan Back Office Rumah Sakit Omni Alam Sutera dimasa Pandemi Covid-19

Tujuan: Untuk mengetahui hubungan aktivitas fisik dengan kebugaran dan tingkat stres pada karyawan back office RS. Omni Alam Sutera di masa pandemi covid-19. Metode: Penelitian bersifat deskriptif kuantitatif dengan pendekatan jenis cross sectional study. Total sampel adalah 40 orang karyawan (perempuan n=35 dan laki-laki n=15) dengan usia antara 23-54 tahun. Alat ukur yang digunakan adalah IPAQ untuk mengukur aktivitas fisik, Cooper tes lari 12 menit untuk mengukur kebugaran dan PSS untuk mengukur tingkat stres. Hasil: Uji hipotesis dengan chi square pada α=0,05 menunjukkan pada uji hipotesis I didapatkan nilai p=0,024 dengan OR(95%CI)=10,00(0,99-100,82) yang berarti ada hubungan antara aktivitas fisik dengan kebugaran, karyawan yang mempunyai aktivitas ringan memiliki resiko kebugaran yang kurang sebesar 10 kali dibanding dengan dengan aktivitas sedang dan berat. Uji hipotesis II didapatkan nilai p=0,015 dengan OR(95%CI)=0,18(0,04-0,75) yang berarti ada hubungan antara aktivitas fisik dengan tingkat stres, karyawan yang mempunyai aktivitas ringan memiliki resiko stres sedang sebesar 0,18 kali dibanding dengan aktivitas sedang dan berat. Uji hipotesis III didapatkan nilai p=0,015 dengan OR(95%CI)=0,08 (0,009-0,87) yang berarti ada hubungan antara kebugaran dengan tingkat stres, karyawan yang mempunyai kebugaran kurang memiliki resiko stres sedang sebesar 0,08 kali dibanding dengan kebugaran baik. Kesimpulan: Ada hubungan yang signifikan antara aktivitas fisik dengan kebugaran dan tingkat stres pada karyawan back office RS. Omni Alam Sutera di masa pandemi covid-19.Kata Kunci: Aktivitas fisik, kebugaran, tingkat stres, karyawan back office, pandemi.
New Approximations to Bond Prices in the Cox–Ingersoll–Ross Convergence Model with Dynamic Correlation

We study a particular case of a convergence model of interest rates. The bond prices are given as solutions of a parabolic partial differential equation and we consider different possibilities of approximating them, using approximate analytical solutions. We consider an approximation already suggested in the literature and compare it with a newly suggested one for which we derive the order of accuracy. Since the two formulae use different approaches and the resulting leading terms of the error depend on different parameter sets of the model, we propose their combination, which has a higher order of accuracy. Finally, we propose one more approach, which leads to higher accuracy of the resulting approximation formula.
Evaluation of biocontrol agents for management of wilt disease of tomato incited by Fusarium oxysporum f. sp. lycopersici

Abstract Fusarium wilt of tomato (Solanum lycopersicum L) incited by Fusarium oxysporum f.sp. lycopersici causes heavy yield loss due to the lack of a long term management options for this pathogen. The study was undertaken to assess the efficacy of biocontrol agents Trichoderma harzianum, T. viride and Aspergillus niger against wilt fungus. All biocontrol agents produced significant inhibitory effect on pathogen development. T. viride caused maximum reduction (83.56%) in growth and fresh (332.49 mg) and dry weight (52.19 mg) of the pathogen. In pot trial seed treatment with T. viride caused minimum disease severity (1.2) and maximum significant increase in plant fresh (60.23 g) and dry weight (23.82 g), plant length (63.91 cm) and yield/plant (258.05 g). T. harzianum seed treatment showed highest increase in chlorophyll (3.04 mg/g fresh weight) and lycopene content (75.43 mg/kg fresh weight) whereas T. viride seed treatment showed maximum total phenols (93.58 μg catechol/g fresh weight).
How to advance theory through literature reviews in logistics and supply chain management

PurposeThe discipline's most common uses for literature reviews—identifying gaps, developing research agendas, and categorizing the literature—too often fail to challenge, change or advance theoretical perspectives. The authors offer guidance to theorization through literature reviews. The key to theory advancement is consistency between the state of theory and the chosen review type.Design/methodology/approachA conceptual approach is taken. The authors identify shortcomings in literature reviews of logistics and supply chain management (L&SCM) research and develop a framework to aid theorization from literature.FindingsLiterature review types are categorized as inductive theory building, contextualized explanations, theory testing and interpretive sensemaking. The authors argue that the effectiveness of a review type depends on the prior state of theory, which ranges from nascent, to intermediate, to mature. The authors propose the interpretive sensemaking review as a novel review type rooted in the interpretive paradigm.Practical implicationsThis study should be of immediate interest and value to logistics and supply chain management scholars—as well as scholars in other fields—because it offers a pathway to theory development through literature reviews. Appropriate applications of the proposed review types will result in more comprehensive theories.Originality/valueThis article lays down arguments for the need to change the way L&SCM scholars use literature reviews. It extends earlier work from the authors (Durach et al., 2017; A New Paradigm for Systematic Literature Reviews in Supply Chain Management, Journal of Supply Chain Management) by outlining four review types, and offering further insights to theorization, as is typically the goal in the synthesis step of literature reviews.
Dark Triad, Risk Taking and Counterproductive Work Behavior in Different Organizational Contexts

The purpose of this study is to analyze the relationship between Dark Triad of Personality, risk-taking and counterproductive work behaviort. The study involved 200 people aged between 18 and 51 years, M = 27.69, SD = 9.83, of which 35 are males (17.5%) and 165 are females (82.5%). The instruments used were The Dirty Dozen: A Concise Measure of the Dark Triad (Jonason & Webster, 2010), Counterproductive Work Behavior Checklist - CWBC (Spector, Bauer & Fox, 2010) and RISK-TAKING [JPI: Risk Taking [Rkt] (Goldberg et. al, 2006). The results showed that people who work in non-profit organizations (volunteers), those who have a low seniority in work or who hold a leadership position tend to take more risks than others. Low seniority at work also correlates with counterproductive behaviors. In contrast, no significant difference was observed as far as the other two demographic characteristics are concerned. Moreover, the results show that Machiavellianism is responsible for 16% of the variation of counterproductive work behavior, and risk-taking mediates this relatonship. Narcissism and psychopathy are responsible for 10% and 13% respectively of the variation of this behavior, the mediation percentage of risk taking being 19.2% concerning the first one and 22.4% concerning psychopathy. Given these results, the study can be useful in the organizational field, providing employers with more data that they can take into account when recruiting staff. It can also be helpful when it comes to better employee management, as well as a deeper understanding behind counterproductive behaviors, thus leading more easily to diminishing them.
The Commissioning and Validation of EclipseTM Treatment Planning System on a Varian VitalBeamTM Medical Linear Accelerator for Photon and Electron Beams

Purpose: Commissioning of a linear accelerator is a process of acquiring a set of data used for patient treatment. This article presents the beam data measurement results from the commissioning of a VitalBeamTM linac. Materials and Methods: Dosimetric properties for 6,10, and 15 MV photon beams and 6, 9, 12, and 16 MeV electron beams have been performed. Parameters, including Percentage Depth Dose (PDD), depth dose profile, symmetry, flatness, quality index, output factors, and the vital data for Treatment Planning System (TPS) commissioning were measured. The imported data were checked by CIRS phantom accordingly to IAEA TRS-430, TECDOC. Eight different positions of CIRS phantom CT were planned and treated. Finally, the calculated dose at a determined position was compared with measuring data to TPS validation. Results: After comparing 84 points in a different plan, the 83 points were in agreement with the criteria, and just for one point in 15 MV failed. Conclusion: Commissioning of dose and field flatness and symmetry are in tolerance intervals given by Varian. This proves that the studied lines meet the specification and can be used in clinical practice with all available electron and photon energies.