Miracle-dz/UniFAR-FTUs huggingface dataset:
Adult attachment, hostile conflict, and relationship adjustment among couples facing multiple sclerosis.

OBJECTIVE Couples facing multiple sclerosis (MS) report significantly elevated rates of relationship distress, yet the effects of attachment have never been examined in this population. We examined whether hostile conflict mediated the dyadic effects of attachment on relationship adjustment in couples facing MS and whether these associations were moderated by gender or role. We also explored whether dyadic adjustment mediated the relationship between attachment and hostile conflict. DESIGN The study was cross-sectional and included 103 couples in which one partner had been diagnosed with MS. METHODS Participants completed the Experiences in Close Relationships-Revised, Dyadic Adjustment Scale, and Aversive Interactions Scale, as well as demographic variables. We used the actor-partner interdependence model for data analysis. RESULTS There were significant actor and partner effects of greater anxious attachment and worse dyadic adjustment. Actor and partner effects of anxious attachment were significantly mediated by greater hostile conflict. Gender significantly moderated the effects between avoidant attachment and dyadic adjustment. The actor effect was significant for males and females; the partner effect was only significant for females. The actor effect for females but not males was significantly mediated by greater hostile conflict. Role was not a significant moderator. Exploratory analyses also showed that dyadic adjustment mediated the relationship between anxious and avoidant attachment and hostile conflict. CONCLUSIONS Findings highlight the important effects of attachment on relationship adjustment in MS couples. Both hostile conflict and dyadic adjustment appear to be mechanisms through which insecure attachment has a detrimental effect. Statement of contribution What is already known on this subject? Despite higher-than-normal rates of marital distress and separation/divorce, the effects of attachment on relationship adjustment among couples facing multiple sclerosis have never been examined. Prior studies within healthy populations have supported within-person and cross-dyadic associations between attachment and relationship adjustment; however, they have failed to use dyadic analyses. Hostile conflict has been associated with both insecure attachment and relationship adjustment and therefore may be an important mediator to help understand these relationships. What does this study add? Women were more negatively affected by their partner's avoidant attachment then men. Hostile conflict mediated the effects of anxious attachment on dyadic adjustment for individuals and across dyads. Hostile conflict accounted for the individual effect of avoidant attachment on dyadic adjustment for women.
Energy-Efficient D2D Overlaying Communications With Spectrum-Power Trading

In this paper, we investigate device-to-device (D2D) overlaying communications with spectrum-power trading, where D2D users (DUs) consume transmit power to relay cell-edge cellular users (CUs) for uplink transmission in exchange for bandwidth from CUs for D2D communications. The proposed spectrum-power trading aims at exploiting individual disparities from both the spectrum and the power perspectives. Recently, energy efficiency (EE) defined by the ratio of the date rate to the power consumption has become increasingly important for devices due to their limited capacity batteries. As such, our goal is to maximize the weighted sum EE (WSEE) of DUs via a joint D2D relay selection, bandwidth allocation, and power allocation while guaranteeing the quality of service of each CU. Specifically, we study WSEE maximization problems for two different cases, i.e., public-interest DUs and self-interest DUs, depending on whether the DUs are willing to share their obtained bandwidth with each other or not. For the case of public-interest DUs, we show that for a given D2D relay selection, the objective function of the WSEE maximization problem in a fractional form can be transformed into a subtractive form that is more tractable based on the fractional programming theory. To perform D2D relay selection, we first reveal a fundamental relationship between the WSEE and two other EE metrics, i.e., system-centric EE and fairness-centric EE, which, to the best of our knowledge, has never been found in the existing works. Based on this insight, the D2D relay selection problem can be cast as a minimum weighted bipartite matching problem. For the case of self-interest DUs, we show that the corresponding problem can also be solved with optimality by the algorithm proposed for the previous case. Simulation results demonstrate the effectiveness of the proposed algorithm.
Socio-Environmental Factors Associated with Self-Rated Oral Health in South Africa: A Multilevel Effects Model

Aim: This study examined the influence of the social context in which people live on self-ratings of their oral health. Method: This study involved a representative sample of 2,907 South African adults (≥16 years) who participated in the 2007 South African Social Attitude Survey (SASAS). We used the 2005 General Household Survey (n = 107,987 persons from 28,129 households) to obtain living environment characteristics of SASAS participants, including sources of water and energy, and household cell-phone ownership (a proxy measure for the social network available to them). Information obtained from SASAS included socio-demographic data, respondents’ level of trust in people, oral health behaviors and self-rated oral health. Results: Of the respondents, 76.3% self-rated their oral health as good. Social context influenced women’s self-rated oral health differently from that of men. Good self-rated oral health was significantly higher among non-smokers, employed respondents and women living in areas with higher household cell-phone ownership. Furthermore, trust and higher social position were associated with good self-rated oral health among men and women respectively. Overall, 55.1% and 18.3% of the variance in self-rated oral health were explained by factors operating at the individual and community levels respectively. Conclusion: The findings highlight the potential role of social capital in improving the population’s oral health.
Observations of Ice Crystal Habits with a Scanning Polarimetric W-Band Radar at Slant Linear Depolarization Ratio Mode

AbstractScanning polarimetric W-band radar data were evaluated for the purpose of identifying predominant ice hydrometeor habits. Radar and accompanying cloud microphysical measurements were conducted during the Storm Peak Laboratory Cloud Property Validation Experiment held in Steamboat Springs, Colorado, during the winter season of 2010/11. The observed ice hydrometeor habits ranged from pristine and rimed dendrites/stellars to aggregates, irregulars, graupel, columns, plates, and particle mixtures. The slant 45° linear depolarization ratio (SLDR) trends as a function of the radar elevation angle are indicative of the predominant hydrometeor habit/shape. For planar particles, SLDR values increase from values close to the radar polarization cross coupling of about −21.8 dB at zenith viewing to maximum values at slant viewing. These maximum values depend on predominant aspect ratio and bulk density of hydrometeors and also show some sensitivity to particle characteristic size. The highest observed SLDRs w.
Metal complexes of curcumin for cellular imaging, targeting, and photoinduced anticancer activity.

Curcumin is a polyphenolic species. As an active ingredient of turmeric, it is well-known for its traditional medicinal properties. The therapeutic values include antioxidant, anti-inflammatory, antiseptic, and anticancer activity with the last being primarily due to inhibition of the transcription factor NF-κB besides affecting several biological pathways to arrest tumor growth and its progression. Curcumin with all these positive qualities has only remained a potential candidate for cancer treatment over the years without seeing any proper usage because of its hydrolytic instability involving the diketo moiety in a cellular medium and its poor bioavailability. The situation has changed considerably in recent years with the observation that curcumin in monoanionic form could be stabilized on binding to a metal ion. The reports from our group and other groups have shown that curcumin in the metal-bound form retains its therapeutic potential. This has opened up new avenues to develop curcumin-based metal complexes as anticancer agents. Zinc(II) complexes of curcumin are shown to be stable in a cellular medium. They display moderate cytotoxicity against prostate cancer and neuroblastoma cell lines. A similar stabilization and cytotoxic effect is reported for (arene)ruthenium(II) complexes of curcumin against a variety of cell lines. The half-sandwich 1,3,5-triaza-7-phosphatricyclo-[3.3. 1.1]decane (RAPTA)-type ruthenium(II) complexes of curcumin are shown to be promising cytotoxic agents with low micromolar concentrations for a series of cancer cell lines. In a different approach, cobalt(III) complexes of curcumin are used for its cellular delivery in hypoxic tumor cells using intracellular agents that reduce the metal and release curcumin as a cytotoxin. Utilizing the photophysical and photochemical properties of the curcumin dye, we have designed and synthesized photoactive curcumin metal complexes that are used for cellular imaging by fluorescence microscopy and damaging the cancer cells on photoactivation in visible light while being minimally toxic in darkness. In this Account, we have made an attempt to review the current status of the chemistry of metal curcumin complexes and present results from our recent studies on curcumin complexes showing remarkable in vitro photocytotoxicity. The undesirable dark toxicity of the complexes can be reduced with suitable choice of the metal and the ancillary ligands in a ternary structure. The complexes can be directed to specific subcellular organelles. Selectivity by targeting cancer cells over normal cells can be achieved with suitable ligand design. We expect that this methodology is likely to provide an impetus toward developing curcumin-based photochemotherapeutics for anticancer treatment and cure.
Mineral content of the maternal diet influences ectopic mineralization in offspring of Abcc6−/− mice

Ectopic mineralization disorders inflicting the connective tissues display a spectrum of severity, some developing in utero and being diagnosed by prenatal ultrasound. This study was designed to test the hypothesis that the mineral content of maternal diet can influence the mineralization in the offspring. Pregnant Abcc6−/− mice, on 2 different strain backgrounds, were maintained either on normal rodent diet or on “acceleration diet,” rich in phosphate and low in magnesium, which has been previously shown to enhance the mineralization processes. The offspring were examined for mineralization by histopathology of various tissues and quantitated by chemical assay of calcium. The ectopic mineralization in the dermal sheath of vibrissae, a progressive biomarker of the overall mineralization, was readily detectable at the age of 4 weeks in the pups whose mothers were on the acceleration diet, while no evidence of mineralization was noted in those on normal diet. The mineralization of the vibrissae progressively increased when examined at 12 weeks of age. There was a significant reduction in urinary calcium and significant increase in urinary phosphorus concentrations both at 4 and 12 weeks of age in mice on the acceleration diet as compared to those on control diet. The results demonstrate that the mineral content of the maternal diet can influence ectopic mineralization in the offspring of mice genetically predisposed to ectopic mineralization (Abcc6−/−). These observations have implications for dietary management of pregnancies in which the fetus is diagnosed by prenatal ultrasound to have an ectopic mineralization disorder.
The effects of tribological factors and load sequence on surface pitting and cracks in bearing steel

This paper presents an investigation of the influence of various tribological parameters on surface initiated damage through Rolling Sliding Tests (RSTs) using bearing steel specimens. The RSTs were conducted on a benchtop twin-disc machine, consisting of a tribometer and a rolling contact fatigue testing system. The parameters investigated were contact pressure, slipping ratio, rotational speed, lubricant viscosity and load sequence, with each of them varying between two values. The first step was an investigation of the Coefficient of Traction (COT) under different testing conditions, followed by a set of RSTs to investigate surface damage initiation. It was found that the COT increased significantly under certain conditions of opposite rotational direction. The RST results showed that cracks and spalls on the surface were severer when higher slip ratio, higher contact pressure and higher rotational speed were applied first than that when lower levels of these parameters were applied first.
FAULT DETECTION IN COAL MILLS USED IN POWER PLANTS

Abstract In order to achieve high performance and efficiency of coal-fired power plants, it is highly important to control the coal flow into the furnace in the power plant. This means suppression of disturbances and force the coal mill to deliver the required coal flow, as well as monitor the coal mill in order to detect faults in the coal mill when they emerge. This paper deals with the second objective. Based on a simple dynamic model of the energy balance a residual is formed for the coal mill. An optimal unknown input observer is designed to estimate this residual. The estimated residual is following tested on measured data of a fault in a coal mill, it can hereby be concluded that this residual is very useful for detecting faults in the coal mill.
POSTNATAL GROWTH RATE, BUT NOT MILD PRETERM BIRTH, INFLUENCES AIRWAY STRUCTURE IN ADULT SHEEP CHALLENGED WITH HOUSE DUST MITE

The authors recently showed that preterm birth per se, in the absence of assisted ventilation or elevated inhaled oxygen levels, alters the structure of the airway walls in young lambs. The initial aim of the present study was to determine whether these changes persist into adulthood. Preterm (P; n = 7) lambs were delivered 14 days before term and compared with control lambs (C; n = 8) born at term (∼ 147 days). After weaning, the sheep were kept as a flock with daily exposure to pasture until ∼ 1.2 years old. All sheep were sensitized to house dust mite extract and then given aerosol challenges with house dust mite 10 to 12 weeks before autopsy. At autopsy, the right lung was fixed in neutral-buffered formalin at an inflation pressure of 20 cm H2O. The architecture of the walls of airway generations 4, 6, and 8 and the bronchioles was assessed by computer-aided image analysis of histological sections of airway walls cut in cross-section. Morphometric analysis showed that preterm birth per se had no significant effect on airway wall structure. Within both groups (preterm and term), we identified animals that grew at different growth rates after birth; a second aim, therefore, was to determine the influence of postnatal growth rates on airway structure at maturity. The 15 sheep were divided into 2 groups based on nonoverlapping growth rates between birth and 200 days of age: slower growing sheep (SG; n = 7) gained 102 ± 5 g/day and faster growing sheep (FG; n = 8) gained 197 ± 14 g/day (P <.01). In SG sheep, the pulmonary airways had thinner walls and less smooth muscle in relation to basement membrane perimeter. The airway epithelium was also thinner in the SG sheep. In the bronchiolar epithelium, there were fewer goblet cells and Clara cells in SG compared to FG sheep. We conclude that the early effects of preterm birth on the airway epithelium do not persist to maturity. However, slow growth after birth results in altered airway development, with effects persisting to maturity.
Chemotaxonomic Analysis of the Aroma Compounds in Essential Oils of Two Different Ocimum basilicum L. Varieties from Iran

Hydrodistilled essential oils of 21 accessions of Ocimum basilicum L. belonging to two different varieties (var. purpurascens and var. dianatnejadii) from Iran were characterized by GC‐FID and GC/MS analyses. The oil yield was found to be between 0.6 and 1.1% (v/w). In total, 49 compounds, accounting for 96.6–99.7% of the oil compositions, were identified. Aromatic compounds, represented mainly by methyl chavicol (33.6–49.1%), and oxygenated monoterpenes, represented by linalool (14.4–39.3%), were the main components in all essential oils. Monoterpene hydrocarbons were present in the essential oils of all accessions of the purpurascens variety, whereas they were completely absent in those of the dianatnejadii variety, indicating that monoterpene hydrocarbons might be considered as marker constituents of the purpurascens variety. The chemotaxonomic value of the essential‐oil compositions was discussed according to the results of the cluster analysis (CA). The CA showed a clear separation of the O. basilicum var. purpurascens accessions and the O. basilicum var. dianatnejadii accessions, although the data showed no major chemotype variation between the studied varieties. Indeed, the CA revealed only one principal chemotype (methyl chavicol/linalool) for both varieties. In conclusion, GC/MS analyses in combination with CA showed to be a flexible and reliable method for the characterization of the chemical profiles of different varieties of Ocimum basilicum L.
Variability of Solar Radiation and CDOM in Surface Coastal Waters of the Northwestern Mediterranean Sea

Atmospheric and in‐water solar radiation, including UVR‐B, UVR‐A and PAR, as well as chromophoric dissolved organic matter absorption [aCDOM(λ)] in surface waters were monthly measured from November 2007 to December 2008 at a coastal station in the Northwestern Mediterranean Sea (Bay of Marseilles, France). Our results showed that the UVR‐B/UVR–A ratio followed the same trend in the atmosphere and at 2 m depth in the water (P < 0.0001) with an increase (eight‐fold higher) during summer. The low diffuse attenuation coefficients for downward irradiance [Kd(λ)] of UVR‐B, UVR‐A and PAR indicated that the waters were highly transparent throughout the year. The relationships between aCDOM(λ) and Kd(λ) in this oligotrophic system suggested that CDOM contributed to UVR attenuation in the UVA domain, but also played a significant role in PAR attenuation. Mean UV doses received in the mixed layer depth were higher by a factor 1.4–33 relative to doses received at fixed depths (5 and 10 m) in summer (stratified period), while the inverse pattern was found in winter (mixing period). This shows the importance of taking into account the vertical mixing in the evaluation of UVR effects on marine organisms.
Reporting of Drug Expenditures in the MCBS

Comparing data from both the 1999 MCBS and drug utilization data supplied by the survey respondents' pharmacies, the author details the methods used to determine the level of misreporting of drug expenditures in the MCBS. Findings suggest that prescription drug expenditures are underreported by 17 percent and the number of prescriptions used is underreported by 17.7 percent. The data also identify demographic factors that predict a beneficiary's likelihood to either overreport or underreport his or her medications, as well as the extent to which beneficiaries misreport their drug use and spending.
Effect of Ionic Correlations on the Surface Forces in Thin Liquid Films: Influence of Multivalent Coions and Extended Theory

Experimental data for the disjoining pressure of foam films stabilized by anionic surfactant in the presence of 1:1, 1:2, 1:3, and 2:2 electrolytes: NaCl, Na2SO4, Na3Citrate, and MgSO4 are reported. The disjoining pressure predicted by the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory coincides with the experimental data in the case of a 1:1 electrolyte, but it is considerably greater than the measured pressure in all other cases. The theory is extended to account for the effects of ionic correlations and finite ionic radii. Original analytical expressions are derived for the local activity coefficient, electrostatic disjoining pressure, and asymptotic screening parameter. With the same parameter of counterion binding as for a 1:1 electrolyte, the curves predicted by the extended theory are in perfect agreement with the experimental data for 1:2 and 1:3 electrolytes. In comparison with the DLVO theory, the effect of ionic correlations leads to more effective screening of electrostatic interactions, and lower electric potential and counterion concentrations in the film’s midplane, resulting in lower disjoining pressure, as experimentally observed. The developed theory is applicable to both multivalent coions and multivalent counterions. Its application could remove some discrepancies between theory and experiment observed in studies with liquid films from electrolyte solutions.
Sensory Attributes of Composite Breads from Shelf Storable Orange-Fleshed Sweetpotato Puree

Abstract Technological advances in baking have enabled the use of bread as a food vehicle for various nutrients through use of composite flours. Orange-fleshed sweetpotato (OFSP) puree subjected to cold chain storage has been used to enrich bread with beta-carotene. However, this has proven expensive and inconsistent in supply of puree. This study sought to develop shelf-storable OFSP puree bread with similar sensory qualities to fresh OFSP puree bread. Bread in which two treatments of shelf-storable OFSP puree (treatments 1 and 2 with 0.5% potassium sorbate+0.5% sodium benzoate+1% citric acid and 0.2% potassium sorbate+0.2% sodium benzoate+1%citric acid respectively) were incorporated at 30% and 40% and were subjected to descriptive sensory analysis with white and fresh puree breads as controls. The results indicate that both the 40% and 30% wheat substitution with either treatment 1 or 2 OFSP puree bread are acceptable to the consumers, p<0.05. The saltiness, smoothness and crumb color scores for shelfstorable OFSP puree bread were similar to those of fresh puree bread but were significantly (p<0.05) higher than that of white bread. Shelf-storable OFSP puree bread had similar sensory profile to fresh OFSP puree bread thus can be exploited as an alternative to fresh puree bread.