Miracle-dz/UniFAR-FTUs huggingface dataset:
Preparation and Characterization of Bidimensional Zeolitic Structures Obtained from Synthetic Beidellite and Hydroxy-Aluminum Solutions

Beidellite was synthesized hydrothermally from a noncrystalline gel at 320°C and 130 bar pressure. The beidellitic character of the product was verified by infrared spectroscopy on the NH4+-exchanged form. Intercalation was achieved with hydroxy-aluminum solutions having different OH/Al molar ratios. The solutions were investigated by several methods, including 27Al nuclear magnetic resonance. Essentially, two Al species were detected: monomelic Al and a polymerized form containing Al in four-fold coordination. This latter species was found to be selectively fixed in the interlamellar region, which resulted in a stable spacing of 18 Å at 110°C and 16.2 Å at 700°C. The pillared beidellites had specific surface areas of > 300 m2/g, mainly due to micropores. Both Brönsted and Lewis acid sites were evidenced by infrared spectroscopy using pyridine as a probe molecule. RésuméUne beidellite obtenue par synthèse hydrothermale (320°C, 130 bar) à partir d’un gel précurseur et identifiée comme telle sur base des spectres infrarouges de la forme échangée à l’ammonium, a été pontée par des solutions hydroxy-aluminiques de rapports OH/Al différents. Les solutions de pontage ont été étudiées par différentes méthodes, dont la résonance magnétique nucléaire. Deux espèces d’aluminium, l’une monomérique, l’autre polymérique contenant de l’aluminium en coordination tétraédrique coexistent dans ces solutions. On a observé que l’espèce polymérique s’adsorbe préférentiellement dans l’espace interlamellaire, conférant à l’édifice un espacement de 18 Å à 120°C et de 16,2 Å après calcination à 700°C. La surface spécifique de ces beidellites pontées est de l’ordre de 300 m2/g. La spectrométrie infrarouge de la pyridine adsorbée décèle la présence des acidités Brönsted et Lewis.
Experimental study on tensile characteristics of plastic geogrid under low temperature

The data of plastic geogrid such as yield stress,elongation of yield,tensile force relating to different tensile stretches etc.,were obtained from the tensile test under low temperature.Through analyzing the test results,it is found that 1) The tensile characteristics of plastic geogrid enhance obviously under low temperature.2) Under low temperature,the larger the cross-sectional area of ribbing is,the wider the increasing extent of tensile force is;while more obvious the decreasing trend of the elongation of yield.Contrarily,with the decreasing of the cross-section area of ribbing,the effect of temperature reducing on tensile force and elongation of yield is weakened gradually.3) Compared with the unfrozen sample,the tensile characteristics change of the plastic geogrid suffered freeze-thaw cycling is not obvious.
Human Identification by Cross-Correlation and Pattern Matching of Personalized Heartbeat: Influence of ECG Leads and Reference Database Size

Human identification (ID) is a biometric task, comparing single input sample to many stored templates to identify an individual in a reference database. This paper aims to present the perspectives of personalized heartbeat pattern for reliable ECG-based identification. The investigations are using a database with 460 pairs of 12-lead resting electrocardiograms (ECG) with 10-s durations recorded at time-instants T1 and T2 > T1 + 1 year. Intra-subject long-term ECG stability and inter-subject variability of personalized PQRST (500 ms) and QRS (100 ms) patterns is quantified via cross-correlation, amplitude ratio and pattern matching between T1 and T2 using 7 features × 12-leads. Single and multi-lead ID models are trained on the first 230 ECG pairs. Their validation on 10, 20, . 230 reference subjects (RS) from the remaining 230 ECG pairs shows: (i) two best single-lead ID models using lead II for a small population RS = (10–140) with identification accuracy AccID = (89.4–67.2)% and aVF for a large population RS = (140–230) with AccID = (67.2–63.9)%; (ii) better performance of the 6-lead limb vs. the 6-lead chest ID model—(91.4–76.1)% vs. (90.9–70)% for RS = (10–230); (iii) best performance of the 12-lead ID model—(98.4–87.4)% for RS = (10–230). The tolerable reference database size, keeping AccID > 80%, is RS = 30 in the single-lead ID scenario (II); RS = 50 (6 chest leads); RS = 100 (6 limb leads), RS > 230—maximal population in this study (12-lead ECG).
Junctionless Versus Inversion-Mode Gate-All-Around Nanowire Transistors From a Low-Frequency Noise Perspective

The low-frequency noise behavior of junctionless (JL) gate-all-around (GAA) nanowire (NW) FETs has been investigated and compared with similar inversion-mode (IM) devices. It is shown that the predominant 1/f-like noise is governed by carrier number fluctuation (CNF) around threshold voltage operation, while for the p-channel transistors, a pronounced increase in the noise power spectral density is observed at higher gate voltage overdrives. This is due to the impact of the access region to the flicker noise. While the CNF noise is roughly one decade higher for the n-channel than for the p-channel transistors, the opposite holds for the access-related component for both IM and JL GAA NWFETs. It is, finally, observed that the CNF noise is on the average slightly lower in the JL devices compared with their IM counterparts; the origin of this trend will be discussed.
Microstrip Patch Antennas With Multiple Parasitic Patches and Shorting Vias for Bandwidth Enhancement

Two novel microstrip patch antennas with multiple parasitic patches and shorting vias have been presented for the bandwidth enhancement. Based on the conventional triangular patch antenna, two more resonances can be obtained with the introduction of multiple parasitic patches, and consequently, the antenna bandwidth can be broadened. Parametric analysis of the patches has been studied for the verification of bandwidth enhancement. An example of the proposed antenna with multiple parasitic patches is designed, fabricated, and tested. The measured bandwidth with $\vert S_{11}\vert < -10$ dB ranges from 5.46 to 6.27 GHz (13.8%), and good far-field radiation patterns can be obtained within the frequency band. In addition, two shorting vias are inserted into the above proposed antenna to decrease the input impedance, resulting in further bandwidth enhancement of the antenna. This antenna is fabricated and tested as well, which achieves a measured 10-dB impedance bandwidth of 17.4% from 5.5 to 6.55 GHz.
Fertility Preservation in Breast Cancer

Abstract As more young women survive breast cancer, fertility preservation (FP) is an important component of care. This review highlights the importance of early pretreatment referral, reviews the risks of infertility associated with breast cancer treatment, and defines existing and emerging techniques for FP. The techniques reviewed include ovarian suppression, embryo cryopreservation, oocyte cryopreservation, and ovarian tissue cryopreservation and transplantation. The barriers women face, such as not being appropriately referred and the costs of treatment, also are addressed. Multidisciplinary, patient-centered care is essential to discussing FP with patients with breast cancer and ensuring appropriate care that includes quality of life in survivorship.
D2: Decentralized Training over Decentralized Data

While training a machine learning model using multiple workers, each of which collects data from their own data sources, it would be most useful when the data collected from different workers can be {\em unique} and {\em different}. Ironically, recent analysis of decentralized parallel stochastic gradient descent (D-PSGD) relies on the assumption that the data hosted on different workers are {\em not too different}. In this paper, we ask the question: {\em Can we design a decentralized parallel stochastic gradient descent algorithm that is less sensitive to the data variance across workers? } In this paper, we present D$^2$, a novel decentralized parallel stochastic gradient descent algorithm designed for large data variance \xr{among workers} (imprecisely, "decentralized" data). The core of D$^2$ is a variance blackuction extension of the standard D-PSGD algorithm, which improves the convergence rate from $O\left({\sigma \over \sqrt{nT}} + {(n\zeta^2)^{\frac{1}{3}} \over T^{2/3}}\right)$ to $O\left({\sigma \over \sqrt{nT}}\right)$ where $\zeta^{2}$ denotes the variance among data on different workers. As a result, D$^2$ is robust to data variance among workers. We empirically evaluated D$^2$ on image classification tasks where each worker has access to only the data of a limited set of labels, and find that D$^2$ significantly outperforms D-PSGD.
Design of electric air-heated box for batteries in electric vehicles

With the booming development of the modern vehicle industry,the safety problems caused by heat generation of batteries become more severe,thus an effective cooling and heating device is necessary.Compared with most studies on thermal dissipation for batteries in high temperature,there are little studies on heating batteries in low temperature.According to thermal principles,a heat transfer model of hot wires was established.With this model,an electric air-heated box made of 11 electric heating wires in parallel was designed and produced.The Air with constant 20 ℃ was input into the box.Less than 8 minutes later,the output air temperature could be raised to 90 ℃. And then the high temperature air was used to heat the low temperature batteries.The box and the battery pack in series were put in the thermostat at-15 ℃. About 21 minutes later,the battery-surface temperature could be raised to 0 ℃. Therefore it is effective that the high temperature air heated by hot wires was used to heat the low temperature batteries.
Structural Control of Elastic Constants of Mullite in Comparison to Sillimanite

Nine elastic stiffness coefficients, cij, of a mullite single crystal (2Al2O3·SiO2) are measured using acoustic resonance spectroscopy. The obtained values are similar to those of the structurally related aluminosilicate phase sillimanite (Al2O3·SiO2). Characteristic elastic properties of the two minerals are interpreted with the help of their crystal structures and atomic force constants for sillimanite. The high longitudinal stiffness coefficients, c33, of mullite (∼352 GPa) and sillimanite (∼388 GPa) are caused by continuous “stiff” load-bearing tetrahedral chains parallel to c-axis, while the “soft” octahedral chains have minor direct influence. They stabilize the tetrahedal chains against tilting. The lower c33 value of mullite in comparison to the sillimanite value may be caused by a weakening of the load-bearing tetrahedral chains which are parallel to c-axis because of partial replacement of silicon by the weaker-bonded aluminum. The longitudinal stiffness coefficients perpendicular to c-axis are significantly lower, because of sequences of alternating “soft” octahedral and “stiff” tetrahedral units. Within the plane (001), the compliant octahedra exhibit stiffness-controlling influence with coefficients parallel to b-axis (c22∼ 233 GPa) being somewhat lower than parallel to a-axis (c11∼ 291 GPa). This is explained with the occurrence of compliant octahedral Al(1)–O(D) bonds, which are more effective parallel to b-axis rather than to a-axis. Because octahedra are unaffected by the aluminum to silicon substitution, c11 and c22 coefficients of mullite and sillimanite are very similar. Shear stiffness coefficients of mullite increase from c55 (∼77 GPa) to c66 (∼80 GPa) to c44 (∼110 GPa), indicating increasing resistance against shear deformation within the planes (010), (001), and (100). The lattice plane of the highest shear stiffness (100) is built up of an oxygen-oxygen network, diagonally braced along 〈011〉 (“Jagerzaun”). This network with short oxygen–oxygen distances can be sheared by compression and elongation along oxygen–oxygen interaction lines only which is rather unlikely. Because of the lack of such networks in the planes (010) and (001), bending and deformation of structural units become easier, and consequently c55 and c66 are
Do patients and health care providers have discordant preferences about which aspects of treatments matter most? Evidence from a systematic review of discrete choice experiments

Objectives To review studies eliciting patient and healthcare provider preferences for healthcare interventions using discrete choice experiments (DCEs) to (1) review the methodology to evaluate similarities, differences, rigour of designs and whether comparisons are made at the aggregate level or account for individual heterogeneity; and (2) quantify the extent to which they demonstrate concordance of patient and healthcare provider preferences. Methods A systematic review searching Medline, EMBASE, Econlit, PsycINFO and Web of Science for DCEs using patient and healthcare providers. Inclusion criteria: peer-reviewed; complete empiric text in English from 1995 to 31July 2015; discussing a healthcare-related topic; DCE methodology; comparing patients and healthcare providers. Design Systematic review. Results We identified 38 papers exploring 16 interventions in 26 diseases/indications. Methods to analyse results, determine concordance between patient and physician values, and explore heterogeneity varied considerably between studies. The majority of studies we reviewed found more evidence of mixed concordance and discordance (n=28) or discordance of patient and healthcare provider preferences (n=12) than of concordant preferences (n=4). A synthesis of concordance suggested that healthcare providers rank structure and outcome attributes more highly than patients, while patients rank process attributes more highly than healthcare providers. Conclusions Discordant patient and healthcare provider preferences for different attributes of healthcare interventions are common. Concordance varies according to whether attributes are processes, structures or outcomes, and therefore determining preference concordance should consider all aspects jointly and not a binary outcome. DCE studies provide excellent opportunities to assess value concordance between patients and providers, but assessment of concordance was limited by a lack of consistency in the approaches used and consideration of heterogeneity of preferences. Future DCEs assessing concordance should fully report the framing of the questions and investigate the heterogeneity of preferences within groups and how these compare.
Challenges in Modeling of Large Synchronous Machines

Machine simulation models allow the use of embedded numerical computation techniques. The finite element model accuracy is usually gauged by comparing its performance with experimental measurements. In this paper, a large hydrogenerator is modeled and the sensitivity of various model parameters is investigated by comparing the simulated results with experimental measurements. Four hydrogenerator units with the same design drawings are considered in the analysis. The effect of the model parameters was studied by considering the response of the open-circuit voltage in comparison with the measured open-circuit voltage, of the different units. Parameters considered included the effective model depth for a two-dimensional simulation, effective air gap, and effective material permeability of the B–H curve. A 20% variation in operational air gap between two machines of the same design resulted in over 18% difference in open-circuit voltage, particularly beyond the knee point. Reduction in permeability of the soft magnetic materials resulted in agreement between the simulation and measured results at saturation. Consequently, for large machines, the B–H curves from the Epstein measurements are insufficient and should be adjusted accordingly.
Early Postoperative Complications after Oncoplastic Reduction

Background Breast-conserving surgery with adjuvant radiation therapy (BCT) has been established as safe oncologically. Oncoplastic breast surgery uses both oncologic and plastic surgery techniques for breast conservation to improve cosmetic outcomes. We evaluated the risk factors associated with complications after oncoplastic breast reduction. Methods A single-institution, institutional review board–approved, retrospective review of electronic medical records of female patients with breast cancer who underwent oncoplastic breast reduction from 2008 to 2014. A review of electronic medical records collected relevant medical history, clinical and pathological information, and data on postoperative complications within 6 months stratified into major or minor complications. Categorical variables analyzed with the &khgr;2 exact method; continuous variables were analyzed with the Wilcoxon rank sum test exact method. Results We identified 59 patients; 4 required re-excision for positive margins, and 1 moved on to completion mastectomy. The overall complication rate was 33.9% (n = 20): 12 major (20.3%) and 8 minor (13.6%). Of the continuous variables (age, body mass index, and tissue removed), increased age was associated with minor complications (P = 0.02). Among the categorical variables (stratified body mass index, prior breast surgery, hypertension, diabetes mellitus, hyperlipidemia, vascular disease, pulmonary disease, and stratified weight of tissue removed), none were associated with overall or major complications. Pulmonary disease was associated with minor complications (P = 0.03). Bilateral versus unilateral oncoplastic breast reduction showed no statistically significant increase in complications. Conclusions The overall complication rate after oncoplastic breast reduction was markedly higher than that in nationally published data for breast-conserving surgery. The complication rate resembled more closely the complication rate after bilateral mastectomy with immediate reconstruction. No risk factors were associated with major or overall complications. Age and pulmonary disease were associated with minor complications. Patients should be selected and counseled appropriately when considering oncoplastic breast reduction.
Phytoplankton-Specific Response to Enrichment of Phosphorus-Rich Surface Waters with Ammonium, Nitrate, and Urea

Supply of anthropogenic nitrogen (N) to the biosphere has tripled since 1960; however, little is known of how in situ response to N fertilisation differs among phytoplankton, whether species response varies with the chemical form of N, or how interpretation of N effects is influenced by the method of analysis (microscopy, pigment biomarkers). To address these issues, we conducted two 21-day in situ mesocosm (3140 L) experiments to quantify the species- and genus-specific responses of phytoplankton to fertilisation of P-rich lake waters with ammonium (NH4 +), nitrate (NO3 −), and urea ([NH2]2CO). Phytoplankton abundance was estimated using both microscopic enumeration of cell densities and high performance liquid chromatographic (HPLC) analysis of algal pigments. We found that total algal biomass increased 200% and 350% following fertilisation with NO3 − and chemically-reduced N (NH4 +, urea), respectively, although 144 individual taxa exhibited distinctive responses to N, including compound-specific stimulation (Planktothrix agardhii and NH4 +), increased biomass with chemically-reduced N alone (Scenedesmus spp., Coelastrum astroideum) and no response (Aphanizomenon flos-aquae, Ceratium hirundinella). Principle components analyses (PCA) captured 53.2–69.9% of variation in experimental assemblages irrespective of the degree of taxonomic resolution of analysis. PCA of species-level data revealed that congeneric taxa exhibited common responses to fertilisation regimes (e.g., Microcystis aeruginosa, M. flos-aquae, M. botrys), whereas genera within the same division had widely divergent responses to added N (e.g., Anabaena, Planktothrix, Microcystis). Least-squares regression analysis demonstrated that changes in phytoplankton biomass determined by microscopy were correlated significantly (p<0.005) with variations in HPLC-derived concentrations of biomarker pigments (r 2 = 0.13–0.64) from all major algal groups, although HPLC tended to underestimate the relative abundance of cyanobacteria. Together, these findings show that while fertilisation of P-rich lakes with N can increase algal biomass, there is substantial variation in responses of genera and divisions to specific chemical forms of added N.
Phenotypic and Genotypic Analysis of Antimicrobial Resistance among Listeria monocytogenes Isolated from Australian Food Production Chains

The current global crisis of antimicrobial resistance (AMR) among important human bacterial pathogens has been amplified by an increased resistance prevalence. In recent years, a number of studies have reported higher resistance levels among Listeria monocytogenes isolates, which may have implications for treatment of listeriosis infection where resistance to key treatment antimicrobials is noted. This study examined the genotypic and phenotypic AMR patterns of 100 L. monocytogenes isolates originating from food production supplies in Australia and examined this in the context of global population trends. Low levels of resistance were noted to ciprofloxacin (2%) and erythromycin (1%); however, no resistance was observed to penicillin G or tetracycline. Resistance to ciprofloxacin was associated with a mutation in the fepR gene in one isolate; however, no genetic basis for resistance in the other isolate was identified. Resistance to erythromycin was correlated with the presence of the ermB resistance gene. Both resistant isolates belonged to clonal complex 1 (CC1), and analysis of these in the context of global CC1 isolates suggested that they were more similar to isolates from India rather than the other CC1 isolates included in this study. This study provides baseline AMR data for L. monocytogenes isolated in Australia, identifies key genetic markers underlying this resistance, and highlights the need for global molecular surveillance of resistance patterns to maintain control over the potential dissemination of AMR isolates.
Evaluation and determination of selenium deficiency in the food chain of sheep and cow reared in the endemic mountain regions of Middle Rhodope

РЕЗЮМЕ SUMMARY Cеленовият дефицит в почвите и в перманентния тревостой беше установен, както и нерегламентираното снабдяване на преживните животни със селен, поради сезонната динамика през периода на пашата, както и ниските нива на биоакумулиране на този съществен неорганичен компонент в храните за животни. Настоящото проучване за концентрациите на селена по цялата хранителната верига се разглеждат в детайли и се отчитат данните от почвата към хранителните продукти. Изследването е фокусирано върху недостатъчното предлагане на селен и последствията от него върху Se-съдържание в сурово мляко и бяло саламурено сирене от овче и краве мляко, разпространено в ендемичните райони. Ниските концентрации на Selenium deficiency of soils and natural pasture vegetation, as well as an irregular supply of trace-levels of selenium to ruminants due to the seasonal dynamics during the pasture period, a low bio-accumulation rates of selenium in feedstuffs have been established.