Patent ID: 7504446
Filing Date: 2009-03-17
Classification: C09D

Abstract:
1. An ink composition comprising (a) an aqueous liquid vehicle, and (b) a colorant which comprises an anhydride-based copolymer having at least one chromogen covalently bonded thereto and at least one ester, amide, imide, or thioester group covalently bonded thereto, said colorant being soluble or dispersible in the aqueous liquid vehicle, wherein the ink has a viscosity at about 25° C. of no more than about 10 centipoise, wherein the anhydride-based copolymer has covalently bonded thereto a chromogen generated from one or more of (a) chromogenic compounds of the formula wherein R is an alkyl group, an aryl group, an arylalkyl group, or an alklaryl group, and wherein R can be joined to the phenyl moiety to form a ring, each R′, independently of the others, is a halogen atom, an alkyl group, an alkoxy group, a nitrile group, a nitro group, an amide group, or a sulfonamide group, z is an integer of 0, 1, 2, 3, or 4, n is an integer representing the number of carbon atoms in each repeat alkylene oxide unit, x is an integer representing the number of repeat alkylene oxide units, and A and B each, independently of the other, are hydrogen atoms, halogen atoms, tertiary amino groups, imine groups, ammonium groups, cyano groups, pyridine groups, pyridinium groups, ether groups, ester groups, amide groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium groups, phosphate groups, nitrile groups, mercapto groups, nitro groups, sulfone groups, acyl groups, azo groups, cyanato groups, alkyl groups, alkoxy groups, aryl groups, aryloxy groups, arylalkyl groups, arylalkyloxy groups, alkylaryl groups, or alkylaryloxy groups, wherein said colorant has no more than one —OH, —SH, or primary or secondary amino group per molecule; (b) chromogenic compounds of the formula wherein R, R 1 , R 2 , R 3 , and R 4 each, independently of the others, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and wherein R, R 1 , R 2 , R 3 , and R 4 each can be joined to a phenyl moiety to form a ring, each R′ a , R b , and R′ c , independently of the others, is a halogen atom, an alkyl group, an alkoxy group, a nitrile group, a nitro group, an amide group, or a sulfonamide group, z 1 , z 2 , and z 3 each, independently of the others, is an integer of 0, 1, 2, 3, or 4, n is an integer representing the number of carbon atoms in each repeat alkylene oxide unit, x is an integer representing the number of repeat alkylene oxide units, D is an anion, and g is the charge on the anion, wherein said colorant has no more than one —OH, —SH, or primary or secondary amino group per molecule; (c) chromogenic compounds of the formula wherein R is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and wherein R can be joined to the phenyl moiety to form a ring, R′ is an aromatic- or heteroaromatic-containing group, each R a , independently of the others, is a halogen atom, an alkyl group, an alkoxy group, a nitrile group, a nitro group, an amide group, or a sulfonamide group, w is an integer of 0, 1, 2, 3, or 4, n is an integer representing the number of carbon atoms in each repeat alkylene oxide unit, and x is an integer representing the number of repeat alkylene oxide units, wherein said colorant has no more than one —OH, —SH, or primary or secondary amino group per molecule; (d) Disperse Red 13, Disperse Blue 34, Disperse Red 156, Disperse Red 90, Disperse Blue 85, Disperse Blue 8, Disperse Red 91, Disperse Red 55, Disperse Red 1, Disperse Blue 3, Basic Blue 41, Disperse Red 8, Disperse Red 98, Disperse Red 109, or Disperse Red 97; or (e) mixtures thereof.