Patent ID: 6225468
Filing Date: 2001-05-01
Classification: C07D

Abstract:
A process for preparing a composition comprising one or more triazine compounds of Formula A: ##STR28##wherein R.sub.1 is hydrogen, R.sub.2 is hydrogen, alkyl of 1 to 24 carbon atoms, alkenyl of 2 to 24 carbon atoms, acyl of 1 to 24 carbon atoms, aryl of 6 to 24 carbon atoms, cycloalkyl of 5 to 24 carbon atoms, cycloacyl of 5 to 24 carbon atoms, aralkyl of 7 to 24 carbon atoms, aracyl of 6 to 24 carbon atoms and, when Y is a direct bond, halogen, R.sub.3, R.sub.4 and R.sub.5 are the same or different and each is hydrogen, halogen, alkyl of 1 to 24 carbon atoms, alkenyl of 2 to 24 carbon atoms, acyl of 1 to 24 carbon atoms, aryl of 6 to 24 carbon atoms, cycloalkyl of 5 to 24 carbon atoms, cycloacyl of 5 to 24 carbon atoms, aralkyl of 7 to 24 carbon atoms, aracyl of 6 to 24 carbon atoms, OR, NRR', CONRR', OCOR, CN, SR, SO.sub.2 R, SO.sub.3 H, SO.sub.3 M, wherein M is an alkali metal, R and R' are the same or different and each is hydrogen, alkyl of 1 to 24 carbon atoms, alkenyl of 2 to 24 carbon atoms, acyl of 1 to 24 carbon atoms, aryl of 6 to 24 carbon atoms, cycloalkyl of 5 to 24 carbon atoms, cycloacyl of 5 to 24 carbon atoms, aralkyl of 7 to 24 carbon atoms, or aracyl of 6 to 24 carbon atoms, optionally with either of R.sub.3 and R.sub.4, or R.sub.4 and R.sub.5, taken together being a part of a saturated or unsaturated fused carbocyclic ring optionally containing O, N or S atoms in the ring, with the proviso that when R.sub.3, R.sub.4 or R.sub.5 is NRR', R and R' are not both hydrogen, and Y is a direct bond, O, NR"", or SR"", wherein R"" is hydrogen, alkyl of 1 to 24 carbon atoms, alkenyl of 2 to 24 carbon atoms, acyl of 1 to 24 carbon atoms, aryl of 6 to 24 carbon atoms, cycloalkyl of 5 to 24 carbon atoms, cycloacyl of 5 to 24 carbon atoms, aralkyl of 7 to 24 carbon atoms or aracyl of 6 to 24 carbon atoms; andAr.sub.1 and Ar.sub.2 are the same or different, and each independently is a radical of a compound of Formula B: ##STR29##wherein R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are the same or different and each is hydrogen, halogen, alkyl of 1 to 24 carbon atoms, aryl of 6 to 24 carbon atoms, alkenyl of 2 to 24 carbon atoms, acyl of 1 to 24 carbon atoms, aralkyl of 7 to 24 carbon atoms, aracyl of 6 to 24 carbon atoms, NRR', CONRR', CN, SR, SO.sub.2 R, SO.sub.3 H, SO.sub.3 M, wherein M is an alkali metal, R and R' are as defined above, and R'""is alkyl of 1 to 24 carbon atoms, aryl of 6 to 24 carbon atoms, alkenyl of 2 to 24 carbon atoms, acyl of 1 to 24 carbon atoms, cycloalkyl of 5 to 24 carbon atoms, cycloacyl of 5 to 24 carbon atoms, aralkyl of 7 to 24 carbon atoms, or aracyl of 6 to 24 carbon atoms, and optionally with either of R.sub.6 and R.sub.7 taken together, R.sub.7 and R.sub.8 taken together, R.sub.8 and R.sub.9 taken together, or R.sub.9 and R.sub.10 taken together being a part of a saturated or unsaturated fused carbocyclic ring optionally containing O, N or S atoms in the ring,which process comprises a single step of:simultaneously reacting in the presence of a catalyst, sufficient amounts of a compound of Formula C: ##STR30##wherein X is a halogen, a compound of Formula D: ##STR31##wherein Y, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are as described above, and a compound of Formula E: ##STR32##wherein R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.10 are as described above,at a suitable temperature and pressure, and for a time sufficient to produce a reaction mixture comprising the composition.