Patent ID: 8183420
Filing Date: 2012-05-22
Classification: C07C

Abstract:
1. An alkylaromatic hydrocarbon mixture comprising a plurality of alkylaromatic hydrocarbons wherein each alkylaromatic hydrocarbon having an aromatic moiety and an alkyl side chain obtained from an oligomerization product mixture, each of said alkylaromatic hydrocarbons having: (a) at least 12 carbon atoms in said alkyl side chain, (b) an average of from 0.8 to 1.3 methyl and ethyl branches bonded to said alkyl side chain and no branches bonded to said alkyl side chain other than methyl and ethyl branches, (c) an average of less than 0.1 quaternary carbon atoms in said alkyl side chain and (d) at least 95% of said aromatic moiety being located at the 2- or 3-position in said alkyl side chain, wherein said alkylaromatic hydrocarbon mixture produced by the process comprising the steps of: (1) oligomerizing an olefin selected from propylene, n-butene and mixtures thereof over an oligomerization catalyst having a surface deactivating agent, to form said oligomerization product mixture comprising at least 95% by weight of mono-olefin oligomers having the empirical formula:  wherein n is greater than or equal to 10, and said mono-olefins oligomers having at least 12 carbon atoms have an average of from 0.8 to 1.3 methyl and ethyl branches bonded to said alkyl side chain and no branches bonded to said alkyl side chain other than methyl and ethyl branches; (2) contacting said oligomerization product mixture and an aromatic compound under alkylation conditions with an aromatic alkylation catalyst to form said alkylaromatic hydrocarbon mixture, said aromatic alkylation catalyst comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstroms, wherein said oligomerization product mixture is not subject to any pretreatment other than to remove said surface deactivating agent prior to said contacting step, and wherein said oligomerization catalyst having the X-ray diffraction lines of Table 1: