Patent ID: 6696110
Filing Date: 2004-02-24
Classification: C07D,C09K

Abstract:
A compound of Formula 1: whereinRJ is CnH2n+1CH&boxH;CHCmH2mZ1 n is 1-5; m is 0-5; q is 0, 1 or 2; A1, A2 are independently chosen from 2,5-disubstituted furan, 2,5-disubstituted thiophene, 2,5-disubstituted oxazole, 2,5-disubstituted thiazole, 2,5-disubstituted 1,3,4-oxadiazole, 2,5-disubstituted 1,3,4-thiadiazole, 1,4-disubstituted benzene, 2,5-disubstituted pyrimidine, 2,5-disubstituted pyridine, 2,6-disubstituted naphthalene; laterally substituted 1,4-disubstituted benzene, laterally substituted 2,5-disubstituted pyrimidine, laterally substituted 2,5-disubstituted pyridine, laterally substituted 2,6-disubstituted naphthalene wherein the lateral substituents are independently selected from F, Cl, Br or CN and present in any of the available substitution positions; A3 is 2,5-disubstituted furan, 2,5-disubstituted thiophene, 2,5-disubstituted oxazole, 2,5-disubstituted thiazole, 2,5-disubstituted 1,3,4-oxadiazole, 2,5-disubstituted 1,3,4-thiadiazole, 1,4-disubstituted benzene, 2,5-disubstituted pyrimidine, 2,5-disubstituted pyridine, 2,6-disubstituted naphthalene; laterally substituted 1,4-disubstituted benzene, laterally substituted 2,5-disubstituted pyrirnidine, laterally substituted 2,5-disubstituted pyridine laterally substituted 2,6-disubstituted naphthalene wherein the lateral substituents are independently selected from F, Cl, Br or CN and is present in any of the available substitution positions; 1,4-disubstituted bicyclo(2.2.2)octane, trans-1,4-disubstituted cyclohexane, trans-2,5-disubstituted dioxane, or 1,4-disubstituted piperidine; Z1 is O, COO or OOC; Z2 and Z3 are independently selected from a direct bond, COO, OOC, C2H4, CH2O, OCH2, C4H8, C3H6O, (E)-CH&boxH;CHC2H4, (Z)-CH2CH&boxH;CHCH2, (E)-CH&boxH;CHCH2O or â€”C&boxH;Câ€”; R is alkyl, alkoxy, alkenyl, alkenyloxy, alkanoyloxy, alkenoyloxy or OCPF2p+1, and R contains 1 to 20 carbon atoms and is branched or a straight chain; and p is 1-20; provided that:when Z1 is O and m is 1, 3 or 5 the carbon-carbon double bond configuration in RJ is E, and when Z1 is O and m is 2 or 4 the carbon-carbon double bond configuration in RJ is Z, and when Z1 is COO or OOC and m is 0, 2 or 4 the carbon-carbon double bond configuration in RJ is E, and when Z1 is COO or OOC and m is 1, 3 or 5 the carbon-carbon double bond configuration in RJ is Z; wherein at least one of A1 A2 or A3 comprises one of the 5-membered heterocyclic rings listed above.