Patent ID: 6533843
Filing Date: 2003-03-18
Classification: B01D,Y02C,Y02P

Abstract:
In a process for the production of ethylene oxide whereina) ethylene is reacted with molecular oxygen to form a reaction gas mixture Comprised of ethylene oxide, carbon dioxide and unreacted ethylene, b) the reaction gas mixture of step a) is scrubbed with water and a solution comprised of ethylene oxide absorbed in water is separated from a gas mixture comprised of carbon dioxide and unreacted ethylene, c) the gas mixture comprised of carbon dioxide and unreacted ethylene from step b) is scrubbed with potassium carbonate scrubbing solution and a potassium carbonate scrubbing solution enriched in bicarbonate and containing dissolved ethylene is recovered, the improvement which comprises 1) flashing the potassium carbonate scrubbing solution enriched in bicarbonate and containing dissolved ethylene, 2) separating flashed vapor containing the bulk of the dissolved ethylene from liquid containing the bicarbonate, 3) flashing the liquid from step 2 and separating vapor containing ethylene from liquid containing the bicarbonate, 4) and recovering liquid flash bottoms from step 3 containing an amount of dissolved ethylene low enough to meet environmental discharge requirements.