Patent ID: 6057380
Filing Date: 2000-05-02
Classification: B33Y,G03F

Abstract:
A composition consisting essentially of(A) as latent base catalyst, at least one compound of formula I, II or III ##STR18## Ar.sub.1 is an aromatic radical of formula IV, V, VI or VII ##STR19## X is a divalent radical of formula ##STR20## --N(R.sub.11)-- or --N(R.sub.11)--R.sub.12 --N(R.sub.11)--; Y is C.sub.1 -C.sub.6 alkylene, cyclohexylene or a direct bond;U is --O--, --S-- or --N(R.sub.17)--;V has one of the meanings of U or is --CO--, --CH.sub.2 --, --CH.sub.2 CH.sub.2 --, C.sub.2 -C.sub.6 alkylidene or a direct bond;W is unbranched or branched C.sub.1 -C.sub.7 alkylene or C.sub.2 -C.sub.6 alkylidene;R.sub.1 and R.sub.2 are each independently of one another(a) C.sub.1 -C.sub.12 alkyl, which is unsubstituted or substituted by OH, C.sub.1 -C.sub.4 alkoxy, SH, CN, --COO(C.sub.1 -C.sub.8 alkyl), (C.sub.1 -C.sub.4 alkyl)--COO--, phenoxy, halogen or phenyl, or are cyclopentyl or cyclohexyl(b) a radical of formula ##STR21## in which p is zero or 1, or (c) a radical of formula ##STR22## in which q is 0, 1, 2 or 3, or (d) a radical of formula ##STR23## (e) phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.12 alkyl or C.sub.1 -C.sub.12 alkoxy,(f) R.sub.1 and R.sub.2 together are unbranched or branched C.sub.2 -C.sub.9 alkylene or C.sub.3 -C.sub.9 oxaalkylene, or form a radical of formula ##STR24## Ar.sub.2 is phenyl, naphthyl, thienyl or furyl radical, each of which is unsubstituted or substituted by halogen, OH, C.sub.1 -C.sub.12 alkyl, or is substituted by C.sub.1 -C.sub.4 alkyl, which is substituted by OH, halogen, C.sub.1 -C.sub.12 alkoxy, --COO(C.sub.1 -C.sub.18 alkyl), --CO(OCH.sub.2 CH.sub.2).sub.n OCH.sub.3 or --OCO(C.sub.1 -C.sub.4 alkyl), or the radicals phenyl, naphthyl, thienyl or furyl are substituted by C.sub.1 -C.sub.12 alkoxy or by C.sub.1 -C.sub.4 alkoxy, which is substituted by --COO(C.sub.1 -C.sub.18 alkyl) or --CO(OCH.sub.2 CH.sub.2).sub.n OCH.sub.3, or the radicals phenyl, naphthyl, thienyl, furyl or pyridyl are substituted by --(OCH.sub.2 CH.sub.2).sub.n OH, --(OCH.sub.2 CH.sub.2).sub.n OCH.sub.3, C.sub.1 -C.sub.8 alkylthio, phenoxy, --COO(C.sub.1 -C.sub.18 alkyl), --CO(OCH.sub.2 CH.sub.2).sub.n OCH.sub.3, phenyl or benzoyl;n is 1-20;m is 1 or 2;R.sub.3 is C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.4 alkyl which is substituted by --OH, --C.sub.1 -C.sub.4 alkoxy, --CN or --COO(C.sub.1 -C.sub.4 alkyl), or R.sub.3 is C.sub.3 -C.sub.5 alkenyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-(C.sub.1 -C.sub.3 alkyl);R.sub.4 is C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.4 alkyl which is substituted by --OH, --C.sub.1 -C.sub.4 alkoxy, --CN or --COO(C.sub.1 -C.sub.4 alkyl), or R.sub.4 is C.sub.3 --C.sub.5 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.3 alkyl or phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.4 alkoxy or --COO(C.sub.1 -C.sub.4 alkyl), or R.sub.4, together with R.sub.2, is C.sub.1 -C.sub.7 alkylene, phenyl-C.sub.1 -C.sub.4 alkylene, o-xylylene, 2-butenylene or C.sub.2 -C.sub.3 oxaalkylene, or R.sub.3 and R.sub.4 together are C.sub.4 -C.sub.7 alkylene which can be interrupted by --O--, --S-- or --CO--, or R.sub.3 and R.sub.4 together are C.sub.3 -C.sub.7 alkylene which can be substituted by OH, C.sub.1 -C.sub.4 alkoxy or --COO(C.sub.1 -C.sub.4)alkyl);R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are each independently of one another hydrogen, halogen, C.sub.1 -C.sub.12 alkyl, cyclopentyl, cyclohexyl, phenyl, benzyl, benzoyl or a group --OR.sub.17, --SR.sub.18, --SOR.sub.18, --SO.sub.2 R.sub.18, --N(R.sub.20)(R.sub.19), --NH--SO.sub.2 R.sub.21 or ##STR25## Z is --O--, --S--, --N(R.sub.11)--, --N(R.sub.11)--R.sub.12 --N(R.sub.11)-- or ##STR26## R.sub.10 is hydrogen, C.sub.1 -C.sub.12 alkyl, halogen or C.sub.2 -C.sub.8 alkanoyl;R.sub.11 is C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.5 alkenyl, phenyl-C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.4 hydroxyalkyl or phenyl;R.sub.12 is unbranched or branched C.sub.2 -C.sub.16 alkylene, which can be interrupted by one or more --O-- or --S--;R.sub.13 is hydrogen, C.sub.1 -C.sub.8 alkyl or phenyl;R.sub.14, R.sub.15 and R.sub.16 are each independently of one another hydrogen or C.sub.1 -C.sub.4 alkyl, or C.sub.14 and R.sub.15 together are C.sub.3 -C.sub.7 alkylene;R.sub.17 is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.5 alkyl which is substituted by --SH, --CN, --OH, C.sub.1 -C.sub.4 alkoxy, C.sub.3 -C.sub.6 alkenoxy, --OCH.sub.2 CH.sub.2 CN, --OCH.sub.2 CH.sub.2 COO(C.sub.1 -C.sub.4 alkyl), --COOH or --O--CO--C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by SH, or R.sub.17 is --COO(C.sub.1 -C.sub.4 alkyl), or R.sub.17 is C.sub.1 -C.sub.6 alkyl which is interrupted by one or more --O--, or R.sub.17 is --(CH.sub.2 CH.sub.2 O).sub.n H, C.sub.2 -C.sub.8 alkanoyl, C.sub.3 -C.sub.12 alkenyl, cyclohexyl, hydroxycyclohexyl, phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.12 alkyl or C.sub.1 -C.sub.4 alkoxy, or R.sub.17 is phenyl-C.sub.1 -C.sub.3 alkyl or --Si(C.sub.1 -C.sub.8 alkyl).sub.r (phenyl).sub.3-r ;r is 1, 2 or 3;R.sub.18 is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.12 alkenyl, cyclohexyl, C.sub.2 -C.sub.12 alkyl which is substituted by --SH, --OH, --CN, --COOH, --COO(C.sub.1 -C.sub.4 alkyl), C.sub.1 -C.sub.4 alkoxy, --OCH.sub.2 CH.sub.2 CN or --O--CO--C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by SH or R.sub.18 is --OCH.sub.2 CH.sub.2 COO(C.sub.1 -C.sub.4 alkyl), or R.sub.18 is C.sub.1 -C.sub.12 alkyl which is interrupted by --S-- or --O--, or R.sub.18 is phenyl which is unsubstituted or substituted by halogen, SH, C.sub.1 -C.sub.12 alkyl or C.sub.1 -C.sub.4 alkoxy, or R.sub.18 is phenyl-C.sub.1 -C.sub.3 alkyl;R.sub.19 and R.sub.20 are each independently of the other, C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.4 hydroxyalkyl, C.sub.2 -C.sub.10 alkoxyalkyl, C.sub.3 -C.sub.5 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.3 alkyl, phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.12 alkyl or C.sub.1 -C.sub.4 alkoxy, or R.sub.19 and R.sub.20 are C.sub.2 -C.sub.3 alkanoyl or benzoyl, or R.sub.19 and R.sub.20 together are C.sub.2 -C.sub.8 alkylene which can be interrupted by --O-- or --S--, or R.sub.19 and R.sub.20 together are C.sub.2 -C.sub.8 alkylene which can be substituted by hydroxyl, C.sub.1 -C.sub.4 alkoxy or --COO(C.sub.1 -C.sub.4 alkyl); and or --COO(C.sub.1 -C.sub.4 alkyl); andR.sub.21 is C.sub.1 -C.sub.18 alkyl, phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.12 alkyl or C.sub.1 -C.sub.8 alkoxy, or R.sub.21 is naphthyl;(B) a mixture of at least one epoxide compound and at least one compound which is capable of reacting with epoxides in the presence of a base; and(C) optionally, a sensitizer.