Patent ID: 6642383
Filing Date: 2003-11-04
Classification: C07D,C08G,C08K,G03C

Abstract:
A compound of formula (I) whereinp is zero or 1; q and r, independently of each other, are an integer from 1 to 6; and s is a number ranging from 1 to 8; X is â€”Oâ€” or, when p is 1, X is also a group Rw, Rx, Ry and Rz are, independently of each other, C1-C18alkyl, C5-C12cycloalkyl or C1-C5hydroxyalkyl; R1 is hydrogen; C1-C18alkyl; oxyl; OH; CH2CN; C1-C18alkoxy; C5-C12cycloalkoxy; C3-C8alkenyl; C3C8alkynyl; C7-C12phenylalkyl; C7-C15phenylalkyl, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; C7-C15phenylalkoxy; C7-C15phenylalkoxy, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; or R1 is C1-C8alkanoyl; C3-C5alkenoyl; C1-C18alkanoyloxy; glycidyl; or a group â€”CH2CH(OH)â€”G, in which G is hydrogen, methyl or phenyl; R2 and R6, independently of each other, are hydrogen, C1-C8alkyl, C5-C12cycloalkyl or C1-C4hydroxyalkyl; R3, R4, R5, R7, R8, R9, independently of each other, are hydrogen, C1-C8alkyl or C5-C12cycloalkyl; when s is 1, W is C1-C18alkyl; C2-C18alkyl which is substituted by NH2, NHR10, N(R10)2, nitro, hydroxy and/or ORâ€²13; or W is C5-C12cycloalkyl; C5-C12cycloalkyl which is substituted by OH, C1-C4alkyl or C1-C4alkoxy; C3-C6alkenyl; C3-C12epoxyalkyl; C7-C15phenylalkyl which is unsubstituted or substituted on the phenyl ring by a radical selected from C1-C4alkyl and C1-C4alkoxy; or W is one of the groups of the formulae (IIa)-(IIe) or, when R1 is a group â€”CH2CH(OH)â€”G, W may also be hydrogen;R10 is hydrogen, C1-C8alkyl, C5-C12cycloalkyl, C7-C15phenylalkyl which is unsubstituted or substituted on the phenyl ring by a radical selected from C1-C4alkyl and C1-C4alkoxy; R11 is hydrogen; C1-C17alkyl; C1-C12alkyl substituted by a radical selected from the group consisting of OH, C1-C12alkoxy, benzophenonyl and benzophenonyloxy, wherein one or both phenyl rings of the benzophenone moiety are unsubstituted or substituted by a radical selected from OH, halogen, C1-C4alkyl and C1-C18alkoxy; or R11 is C5-C12cycloalkyl which is unsubstituted or substituted by C1-C4alkyl; C2-C17alkenyl; phenyl; phenyl substituted by NH2, NHR10, N(R10)2, or C1-C4alkyl or C1-C4alkoxy; C7-C15phenylalkyl; C8-C15phenylalkenyl; or C7-C15phenylalkyl which is substituted on the phenyl ring by C1-C4alkyl and/or C1-C4alkoxy; R12 is a direct bond or C1-C12alkylene; phenylene; cyclohexylene; R13 is C1-C18alkyl; C2-C18alkyl which is substituted by a radical selected from NH2, NHR10, N(R10)2, nitro, hydroxy, OR13; C3-C18alkenyl; C5-C12cycloalkyl; C5-C12cycloalkyl which is substituted by C1-C4alkyl or interrupted by â€”Oâ€” or both substituted by C1-C4alkyl and interrupted by â€”Oâ€”; and when W is a group (IId) or W is a group (IIb) while R12 is not a direct bond, R13 can be also hydrogen, or one equivalent of a cation of main groups I or II of the periodic system; Râ€²13 is C1-C18alkyl; C2-C18alkyl which is substituted by a radical selected from NH2, NHR10, N(R10)2, nitro, hydroxy, OR13; C3-C18alkenyl; C5-C12cycloalkyl; C5-C12cycloalkyl which is substituted by C1-C4alkyl or interrupted by â€”Oâ€” or both substituted by C1-C4alkyl and interrupted by â€”Oâ€”; R14 is C1-C18alkyl; C2-C18alkyl which is substituted by a radical selected from NH2, NHR10, N(R10)2, hydroxy, OR13; C5-C12cycloalkyl which is unsubstituted or substituted by C1-C4alkyl or interrupted by â€”Oâ€” or both substituted by C1-C4alkyl and interrupted by â€”Oâ€”; or R14 is C7-C15phenylalkyl which is unsubstituted or substituted on the phenyl ring by a radical selected from C1-C4alkyl and C1-C4alkoxy; R15 is a direct bond; C1-C20alkylene; C2-C10alkenylene; C2-C8alkenylene substituted by a radical selected from C6-C12aryl or C6-C12aryl which is substituted by C1-C8alkyl, C1-C8alkoxy, di(C1-C4-alkyl)amino, nitro, thienyl, phenoxyphenyl, phenylthiophenyl, benzo[b]thiophen-2-yl, benzofuran-2-yl, 9H-fluorenyl, biphenylyl, 10H-phenothiazinyl; or R15 is C2-C4oxaalkylene; C5-C7cycloalkylene; C5-C7cycloalkenylene or phenylene; when s is 2 W is C2-C12alkylene; C4-C12alkylene substituted by OH or interrupted by a divalent spacer selected from oxygen, sulfur and â€”NR10â€”, or both substituted by OH and interrupted by a divalent spacer selected from oxygen, sulfur and â€”NR10â€”; or W is C4-C12alkenylene; C6-C12alkenylene substituted by OH or interrupted by O or both substituted by OH and interrupted by O; C5-C7cycloalkylene; C5-C7cycloalkylene-di(C1-C4alkylene); C1-C4alkylene-di(C5-C7cyclo-alkylene); phenylene di(C1-C4alkylene); or one of the groups of the formulae (IIIa)-(IIIe) R18 is a direct bond; C1-C12alkylene; C2-C12alkylene interrupted by a divalent spacer selected from oxygen, sulfur, â€”NR10â€”; C5-C7cycloalkylene; C5-C7cycloalkenylene; phenylene; C2-C8alkenylene; C2-C8alkenylene substituted by C4-C12aryl or C4-Cl2aryl which is substituted by C1-C8alkyl, C1-C8alkoxy, di(C1-C4-alkyl)amino, nitro; or C2C8alkenylene substituted by thienyl, phenoxyphenyl, phenylthiophenyl, benzo[b]thiophen-2-yl, benzofuran-2-yl, 9H-fluorenyl, biphenylyl, 10H-phenothiazinyl, thiofuranyl; R19 is C2-C12alkylene; C4-C12alkylene interrupted by oxygen; C5-C7cycloalkylene; C5-C7cycloalkylene di(C1-C4alkylene); or C1-C4alkylidene di(C5-C7cycloalkylene); R20 is C2-C12alkylene; C5-C7cycloalkylene; phenylene; t is zero or an integer from 1 to 7; v and z, independently of each other, are an integer from 1 to 4; when s is 3 W is aliphatic C4-C18triacyl; cycloaliphatic C6-C18triacyl or aromatic C9-C18triacyl; or a group of the formula (IVa) where R22, R23, R24, independently of each other, are C1-C7alkylene; when s is 4 W is aliphatic C5-C18tetraacyl; cycloaliphatic C8-C18tetraacyl or aromatic C10-C18tetraacyl when s is 5, W is aliphatic C7-C18pentaacyl; cycloaliphatic C10-C18pentaacyl or aromatic C11-C18pentaacyl; when s is 6, W is aliphatic C8-C18hexaacyl; cycloaliphatic or aromatic C12-C18hexaacyl when s is 7, W is aliphatic, cycloaliphatic or aromatic C12-C18heptaacyl; when s is 8, W is aliphatic, cycloaliphatic or aromatic C12-C18octaacyl with the proviso that when s is 1 and p is zero, that W is not C2-C18 alkyl which is substituted by hydroxy.