Patent ID: 6133464
Filing Date: 2000-10-17
Classification: B01J,C07B,C07D,C07F

Abstract:
A compound of formula ##STR33## R.sub.1 is C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl or phenyl substituted by from 1 to 3 substituents selected from C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.4 alkoxy;R.sub.a is --P(R.sub.10 R.sub.11) or --SR.sub.12 ;R.sub.b is --P(R'.sub.10 R'.sub.11), --SR'.sub.12, --CH.dbd.NR.sub.12, --CH.sub.2 --NH--R.sub.12 or --CH.sub.2 --O--P(R.sub.10 R.sub.11);R.sub.10 and R.sub.11 are each independently of the other C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkyl substituted by C.sub.1 -C.sub.4 alkoxy, C.sub.5 -C.sub.12 cycloalkyl or by phenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl, C.sub.5 -C.sub.12 cycloalkyl substituted by C.sub.1 -C.sub.4 alkyl or by C.sub.1 -C.sub.4 alkoxy, or phenyl substituted by from one to three substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --SiR.sub.4 R.sub.5 R.sub.6, halogen, --SO.sub.3 M, --CO.sub.2 M, PO.sub.3 M, --NR.sub.7 R.sub.8, --{.sup.+ NR.sub.7 R.sub.8 R.sub.9 }X.sup.- and C.sub.1 -C.sub.5 fluoroalkyl; orR.sub.10 and R.sub.11 together are C.sub.4 -C.sub.8 alkylene, C.sub.4 -C.sub.8 alkylene substituted by C.sub.1 -C.sub.4 alkyl or by phenyl, or annelated C.sub.4 -C.sub.8 alkylene;R'.sub.10 and R'.sub.11 are each independently of the other as defined for R.sub.10 and R.sub.11, with the proviso that --P(R.sub.10 R.sub.11) is not identical to --P(R'.sub.10 R'.sub.11);R.sub.12 is H, C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkyl substituted by C.sub.1 -C.sub.4 alkoxy, C.sub.5 -C.sub.12 cycloalkyl or by phenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl, C.sub.5 -C.sub.12 cycloalkyl substituted by C.sub.1 -C.sub.4 alkyl or by C.sub.1 -C.sub.4 alkoxy, or phenyl substituted by from one to three substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --SiR.sub.4 R.sub.5 R.sub.6, halogen, --SO.sub.3 M, --CO.sub.2 M, --PO.sub.3 M, --NR.sub.7 R.sub.8, --{.sup.+ NR.sub.7 R.sub.8 R.sub.9 }X.sup.- and C.sub.1 -C.sub.5 fluoroalkyl;R'.sub.12 is as defined for R.sub.12, with the proviso that --SR.sub.12 is not identical to --SR'.sub.12 ;R.sub.4, R.sub.5 and R.sub.6 are each independently of the others C.sub.1 -C.sub.12 alkyl or phenyl;R.sub.7 and R.sub.8 are each independently of the other H, C.sub.1 -C.sub.12 alkyl or phenyl, or R.sub.7 and R.sub.8 are tetramethylene, pentamethylene or 3-oxa-1,5-pentylene,R.sub.9 is H or C.sub.1 -C.sub.4 alkyl;M is H or an alkali metal;X.sup.- is the anion of an acid;Y is --OR.sub.13, --SR.sub.14 or --NR.sub.15 R.sub.16 ;R.sub.13 is H, C.sub.1 -C.sub.18 alkyl, --C(O)--C.sub.1-8 alkyl, phenyl or phenyl substituted by from one to three substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --SiR.sub.4 R.sub.5 R.sub.6, halogen, --SO.sub.3 M, --CO.sub.2 M, --PO.sub.3 M, --NR.sub.7 R.sub.8, --{.sup.+ NR.sub.7 R.sub.8 R.sub.9 }X.sup.- and C.sub.1 -C.sub.5 fluoroalkyl;R.sub.14 is H, C.sub.1 -C.sub.18 alkyl, phenyl or phenyl substituted by from one to three substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 -alkoxy, --SiR.sub.4 R.sub.5 R.sub.6, halogen, --SO.sub.3 M, --CO.sub.2 M, --PO.sub.3 M, --NR.sub.7 R.sub.8, {.sup.+ NR.sub.7 R.sub.8 R.sub.9 }X.sup.- and C.sub.1 -C.sub.5 -fluoroalkyl; andR.sub.15 and R.sub.16 are each independently of the other C.sub.1 -C.sub.18 alkyl that may be substituted and/or interrupted by one or more hetero atoms, arylenes or carbocycles; or --NR.sub.15 R.sub.16 is a cyclic amine with the proviso that formula (I) does not embrace a compound in which R.sub.1 is --CH.sub.3 and Y is --N(CH.sub.3).sub.2, when R.sub.a is --P(C.sub.6 H.sub.5).sub.2 and R.sub.b is --P{C(CH.sub.3).sub.3 }.sub.2 or when R.sub.a is --P{C(CH.sub.3).sub.3 }.sub.2 and R.sub.b is --P(C.sub.6 H.sub.5).sub.2.