Patent ID: 6143696
Filing Date: 2000-11-07
Classification: A01N,C07D

Abstract:
4-(3-Alkenylbenzoyl)pyrazoles of the formula I ##STR702## where: R.sup.1 and R.sup.2 are each hydrogen, nitro, halogen, cyano, thiocyanato, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkoxy-C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, --OR.sup.6, --OCOR.sup.7, --OSO.sub.2 R.sup.7, --SH, --S(O).sub.n R.sup.8, --SO.sub.2 OR.sup.6, --SO.sub.2 NR.sup.6 R.sup.9, --NR.sup.9 SO.sub.2 R.sup.7 or --NR.sup.9 COR.sup.7 ;R.sup.3 is hydrogen, halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl;R.sup.4 and R.sup.5 are each hydrogen, nitro, halogen, cyano, thiocyanato, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.4 -C.sub.6 -cycloalkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.6 -haloalkoxy, --COR.sup.10, --CO.sub.2 R.sup.11, --COSR.sup.10, --CONR.sup.10 R.sup.11, --C(R.sup.12).dbd.NR.sup.13, --PO(OR.sup.10)(OR.sup.11), C.sub.1 -C.sub.4 -alkyl which carries a radical from the following group: hydroxyl, --COR.sup.10, --CO.sub.2 R.sup.10, --COSR.sup.10, --CONR.sup.10 R.sup.11 or --C(R.sup.12).dbd.NR.sup.13 ; heterocyclyl, heterocyclyl-C.sub.1 -C.sub.4 -alkyl (where the heterocyclyl radical of the two last-mentioned radicals is three- to seven-membered, saturated or partially unsaturated, mono- or polycyclic and contains one to three heteroatoms selected from the group consisting of oxygen, nitrogen and sulfur), phenyl, phenyl-C.sub.1 -C.sub.4 -alkyl, hetaryl or hetaryl-C.sub.1 -C.sub.4 -alkyl (where the hetaryl radical of the two last-mentioned radicals is aromatic, mono- or polycyclic and may, in addition to carbon ring members, additionally contain one to 4 nitrogen atoms or one to three nitrogen atoms and one oxygen or one sulfur atom or one oxygen or one sulfur atom), it being possible for the last six radicals to be substituted;orR.sup.4 and R.sup.5 together form a C.sub.2 -C.sub.6 -alkanediyl chain which may be mono- to tetrasubstituted by C.sub.1 -C.sub.4 -alkyl and/or interrupted by oxygen or sulfur or by nitrogen with or without substitution by C.sub.1 -C.sub.4 -alkyl;n is 0, 1 or 2;R.sup.6 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkoxy-C.sub.2 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl;R.sup.7 is C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -haloalkyl;R.sup.8 is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkoxy-C.sub.2 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl;R.sup.9 is hydrogen or C.sub.1 -C.sub.6 -alkyl;R.sup.10 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, phenyl or benzyl, it being possible for the last two radicals to be partially or fully halogenated and/or to carry one to three radicals from the following group:nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylcarbonyl or C.sub.1 -C.sub.4 -alkoxycarbonyl;R.sup.11 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl;orR.sup.10 and R.sup.11 together form a C.sub.2 -C.sub.6 -alkanediyl chain which may be mono- to tetrasubstituted by C.sub.1 -C.sub.4 -alkyl and/or interrupted by oxygen or sulfur or by nitrogen with or without substitution by C.sub.1 -C.sub.4 -alkyl;R.sup.12 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -alkoxycarbonyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, phenyl or benzyl, it being possible for the last two radicals to be partially or fully halogenated and/or to carry one to three radicals of the following group:nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylcarbonyl or C.sub.1 -C.sub.4 -alkoxycarbonyl;R.sup.13 is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -haloalkoxy, C.sub.3 -C.sub.6 -cycloalkoxy, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyloxy, phenyl, benzyl or phenyl-C.sub.1 -C.sub.4 -alkoxy, it being possible for the last three radicals to be partially or fully halogenated and/or to carry one to three radicals from the following group:nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylcarbonyl or C.sub.1 -C.sub.4 -alkoxycarbonyl;Q is a pyrazole of the formula II ##STR703## which is linked in position 4 and where R.sup.14 is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, phenyl or phenyl which is partially or fully halogenated and/or carries one to three of the following radicals:nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy;R.sup.15 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkylcarbonyl, C.sub.1 -C.sub.6 -haloalkylcarbonyl, C.sub.1 -C.sub.6 -alkoxycarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.6 -haloalkylsulfonyl, phenyl-C.sub.1 -C.sub.4 -alkyl, phenylcarbonyl, phenylcarbonylmethyl, phenoxycarbonyl or phenylsulfonyl, the last five substituents being unsubstituted or the phenyl ring in question being partially or fully halogenated and/or carrying one to three of the following radicals:nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy;R.sup.16 is hydrogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -haloalkyl;and agriculturally useful salts thereof.