Patent ID: 6066638
Filing Date: 2000-05-23
Classification: C07D

Abstract:
A compound selected from Formula I, N-oxides and agriculturally suitable salts thereof, ##STR150## wherein W is O, S(O), or NR.sup.5 ;n is 0, 1 or 2;Q is O or S;G is a fused thiophene or furan ring;R.sup.1 is C.sub.1 -C.sub.10 alkyl; C.sub.3 -C.sub.6 cycloalkyl; C.sub.3 -C.sub.10 alkenyl; C.sub.3 -C.sub.10 alkynyl; C.sub.1 -C.sub.10 haloalkyl; C.sub.3 -C.sub.10 haloalkenyl; C.sub.3 -C.sub.10 haloalkynyl; C.sub.2 -C.sub.10 alkoxyalkyl; C.sub.2 -C.sub.10 alkylthioalkyl; C.sub.2 -C.sub.10 alkylsulfonylalkyl; C.sub.4 -C.sub.10 cycloalkylalkyl; C.sub.4 -C.sub.10 alkenyloxyalkyl; C.sub.4 -C.sub.10 alkynyloxyalkyl; C.sub.4 -C.sub.10 alkenylthioalkyl; C.sub.4 -C.sub.10 alkynylthioalkyl; C.sub.2 -C.sub.10 haloalkoxyalkyl; C.sub.4 -C.sub.10 alkoxyalkenyl; C.sub.4 -C.sub.10 alkylthioalkenyl; C.sub.4 -C.sub.10 trialkylsilylalkyl; C.sub.1 -C.sub.10 alkoxy; NR.sup.6 R.sup.7 ; R.sup.11 ; phenyl, pyridinyl, furanyl, thienyl, naphthalenyl, benzofuiranyl, benzo[b]thiophenyl or quinolinyl each optionally substituted with R.sup.8, R.sup.9 and R.sup.10 ; or C.sub.1 -C.sub.10 alkyl substituted with NR.sup.6 R.sup.7, nitro, cyano, CO.sub.2 R.sup.6 or phenyl optionally substituted with R.sup.8, R.sup.9 and R.sup.10 ;R.sup.2 is C.sub.1 -C.sub.10 alkyl; C.sub.3 -C.sub.7 cycloalkyl; C.sub.3 -C.sub.10 alkenyl; C.sub.3 -C.sub.10 alkynyl; C.sub.1 -C.sub.10 haloalkyl; C.sub.3 -C.sub.10 haloalkenyl; C.sub.3 -C.sub.10 haloalkynyl; C.sub.2 -C.sub.10 alkoxyalkyl; C.sub.2 -C.sub.10 alkylthioalkyl; C.sub.2 -C.sub.10 alkylsulfonylalkyl; C.sub.4 -C.sub.10 cycloalkylalkyl; C.sub.4 -C.sub.10 alkenyloxyalkyl; C.sub.4 -C.sub.10 alkynyloxyalkyl; C.sub.4 -C.sub.10 alkenylthioalkyl; C.sub.4 -C.sub.10 alkynylthioalkyl; C.sub.2 -C.sub.10 haloalkoxyalkyl; C.sub.4 -C.sub.10 alkoxyalkenyl; C.sub.4 -C.sub.10 alkylthioalkenyl; C.sub.4 -C.sub.10 trialkylsilylalkyl; R.sup.11 ; phenyl optionally substituted with R.sup.8, R.sup.9 and R.sup.10 ; or C.sub.1 -C.sub.10 alkyl substituted with NR.sup.6 R.sup.7, cyano, nitro, CO.sub.2 R.sup.6, or phenyl optionally substituted with R.sup.8, R.sup.9 and R.sup.10 ; orwhen W is NR.sup.5, then R.sup.2 can additionally be selected from --OR.sup.7 ; --N.dbd.CR.sup.6 R.sup.6 ; --NR.sup.6 R.sup.7 ; and pyridinyl, furanyl, thienyl and naphthalenyl each optionally substituted with R.sup.8, R.sup.9 and R.sup.10 ; orwhen W is O, then R.sup.2 can additionally be selected from --N.dbd.CR.sup.6 R.sup.6 and --NR.sup.6 R.sup.7 ;R.sup.3 is hydrogen; halogen; C.sub.1 -C.sub.8 alkyl; C.sub.3 -C.sub.8 cycloalkyl; C.sub.2 -C.sub.8 alkenyl; C.sub.2 -C.sub.8 alkynyl; C.sub.1 -C.sub.8 haloalkyl; C.sub.3 -C.sub.8 haloalkenyl; C.sub.3 -C.sub.8 haloalkynyl; C.sub.1 -C.sub.8 alkoxy; C.sub.1 -C.sub.8 haloalkoxy; C.sub.3 -C.sub.8 alkenyloxy; C.sub.3 -C.sub.8 alkynyloxy; C.sub.1 -C.sub.8 alkylthio; C.sub.1 -C.sub.8 alkylsulfonyl; C.sub.2 -C.sub.8 alkoxyalkyl; C.sub.3 -C.sub.8 trialkylsilyl; nitro; NR.sup.6 R.sup.7 ; C.sub.5 -C.sub.8 trialkylsilylalkynyl; or phenyl optionally substituted with at least one R.sup.13 ;R.sup.4 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 haloalkoxy;R.sup.5 is hydrogen, C.sub.1 -C.sub.4 alkyl or --C(.dbd.O)R.sup.12 ;each R.sup.6 is independently hydrogen; C.sub.1 -C.sub.4 alkyl; or phenyl optionally substituted with at least one R.sup.13 ;each R.sup.7 is independently hydrogen; C.sub.1 -C.sub.8 alkyl; or phenyl optionally substituted with at least one R.sup.13 ; oreach pair of R.sup.6 and R.sup.7, when attached to the same nitrogen atom, can independently be taken together as --CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 --, --CH.sub.2 (CH.sub.2).sub.3 CH.sub.2 --, --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --, --CH.sub.2 CH(Me)CH.sub.2 CH(Me)CH.sub.2 -- or --CH.sub.2 CH(Me)OCH(Me)CH.sub.2 --;each R.sup.8 is independently C.sub.1 -C.sub.6 alkyl; C.sub.1 -C.sub.6 alkoxy; C.sub.1 -C.sub.6 haloalkyl; halogen; C.sub.2 -C.sub.8 alkynyl; C.sub.1 -C.sub.6 alkylthio; phenyl or phenoxy each optionally substituted with at least one R.sup.13 ; cyano; nitro; C.sub.1 -C.sub.6 haloalkoxy; C.sub.1 -C.sub.6 haloalkylthio; C.sub.2 -C.sub.6 alkenyl; C.sub.2 -C.sub.6 haloalkenyl; acetyl; CO.sub.2 Me; or N(C.sub.1 -C.sub.2 alkyl).sub.2 ;each R.sup.9 is independently methyl, ethyl, methoxy, methylthio, halogen, CO.sub.2 (C.sub.1 -C.sub.3 alkyl), C(O)NR.sup.6 R.sup.7 or trifluoromethyl;each R.sup.10 is independently halogen;each R.sup.11 is independently C.sub.1 -C.sub.10 alkyl substituted with an 8-, 9- or 10-membered fused carbobicyclic or fused heterobicyclic ring; or R.sup.11 is C.sub.1 -C.sub.10 alkyl substituted with a 3-, 4-, 5- or 6-membered heteromonocyclic ring; wherein said heterobicyclic or heteromonocyclic rings contain 1 to 4 heteroatoms independently selected from the group nitrogen, oxygen and sulfur, provided that each heterobicyclic or heteromonocyclic ring contains no more than 4 nitrogens, no more than 2 oxygens and no more than 2 sulfurs, wherein said heterobicyclic or heteromonocyclic ring is bonded to the alkyl group through a carbon atom of the ring, and wherein said carbobicyclic, heterobicyclic or heteromonocyclic ring is optionally substituted with R.sup.8, R.sup.9 and R.sup.10 ;R.sup.12 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or NR.sup.6 R.sup.7 ; andeach R.sup.13 is independently halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, nitro or cyano;provided that when G is a fused thiophene ring, then R.sup.3 is other than hydrogen, C.sub.1 -C.sub.8 alkyl, nitro or phenyl optionally substituted with at least one R.sup.13.