Patent ID: 6262074
Filing Date: 2001-07-17
Classification: A01N,C07D

Abstract:
Hetaroyl derivatives of the formula ##STR373##where:R.sup.1 and R.sup.2 are each hydrogen, nitro, halogen, cyano, thiocyanato, hydroxyl, mercapto, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -haloalkoxy, C.sub.2 -C.sub.6 -alkenyloxy, C.sub.2 -C.sub.6 -alkynyloxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.6 -haloalkylthio, C.sub.2 -C.sub.6 -alkenylthio, C.sub.2 -C.sub.6 -alkynylthio, C.sub.1 -C.sub.6 -alkylsulfinyl, C.sub.1 -C.sub.6 -haloalkylsulfinyl, C.sub.2 -C.sub.6 -alkenylsulfinyl, C.sub.2 -C.sub.6 -alkynylsulfinyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.6 -haloalkylsulfonyl, C.sub.2 -C.sub.6 -alkenylsulfonyl, C.sub.2 -C.sub.6 -alkynylsulfonyl, C.sub.1 -C.sub.6 -alkoxysulfonyl, C.sub.1 -C.sub.6 -haloalkoxysulfonyl, C.sub.2 -C.sub.6 -alkenyloxysulfonyl, C.sub.2 -C.sub.6 -alkynyloxysulfonyl, phenyl, phenyloxy, phenylthio, phenylsulfinyl or phenylsulfonyl, where the last five substituents may be partially or fully halogenated and may carry one to three of the following groups:nitro, cyano, hydroxyl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy;Z is a building block from the group consisting of Z.sup.1 to Z.sup.12 ##STR374##whereR.sup.3, R.sup.5, R.sup.7 and R.sup.9 are each nitro, cyano, hydroxyl, mercapto, C.sub.2 -C.sub.4 -alkenyl, C.sub.2 -C.sub.4 -alkynyl, C.sub.2 -C.sub.4 -alkenyloxy, C.sub.2 -C.sub.4 -alkynyloxy, C.sub.2 -C.sub.4 -alkenylthio, C.sub.2 -C.sub.4 -alkynylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -haloalkylsulfinyl, C.sub.2 -C.sub.4 -alkenylsulfinyl, C.sub.2 -C.sub.4 -alkynylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 -haloalkylsulfonyl, C.sub.2 -C.sub.4 -alkenylsulfonyl, C.sub.2 -C.sub.4 -alkynylsulfonyl, C.sub.1 -C.sub.4 -alkoxysulfonyl, C.sub.1 -C.sub.4 -haloalkoxysulfonyl, C.sub.2 -C.sub.4 -alkenyloxysulfonyl, C.sub.2 -C.sub.4 -alkynyloxysulfonyl, --NR.sup.12 R.sup.13, --CO.sub.2 R.sup.12, --CONR.sup.12 R.sup.13, phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl, where the last five substituents may be partially or fully halogenated and may carry one to three of the following groups: nitro, cyano, hydroxyl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy; or one of the radicals mentioned under R.sup.4 ;R.sup.4, R.sup.6, R.sup.8 and R.sup.10 are each hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio or C.sub.1 -C.sub.4 -haloalkylthio;ora --CR.sup.3 R.sup.4 --, --CR.sup.5 R.sup.6 --, --CR.sup.7 R.sup.8 -- or --CR.sup.9 R.sup.10 -- unit may be replaced by C.dbd.O or C.dbd.NR.sup.13 ;R.sup.11 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkylcarbonyl, C.sub.1 -C.sub.6 -haloalkylcarbonyl, 13 CO.sub.2 R.sup.12, --CONR.sup.12 R.sup.13 or SO.sub.2 R.sup.12 ;R.sup.12 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl, where the last radical may be partially or fully halogenated and may carry one to three of the following radicals:nitro, cyano, hydroxyl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy;R.sup.13 is C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -haloalkoxy, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyloxy or one of the radicals mentioned under R.sup.12 ;Q is a hydroxypyrazole, linked through position 4, of the formula II ##STR375##whereR.sup.14 is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl or phenyl, where the last radical may be partially or fully halogenated and may carry one to three of the following radicals:nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy;R.sup.15 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkylcarbonyl, C.sub.1 -C.sub.6 -haloalkylcarbonyl, C.sub.1 -C.sub.6 -alkoxycarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.6 -haloalkylsulfonyl, phenyl-C.sub.1 -C.sub.4 -alkyl, phenylcarbonyl-C.sub.1 -C.sub.4 -alkyl, phenylcarbonyl, phenoxycarbonyl or phenylsulfonyl, where the last five substituents may be partially or fully halogenated and may carry one to three of the following radicals:nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy;R.sup.16 is hydrogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -haloalkyl;and their agriculturally useful salts.