Patent ID: 6399768
Filing Date: 2002-06-04
Classification: C07F,C09B,Y10S,Y10T

Abstract:
A metallocenyl-phthalocyanine of formula I whereinM1 is a divalent metal, an oxometal group, halogenometal group or hydroxymetal group, or two hydrogen atoms, X is halogen Y1 is â€”OR1, â€”OOCâ€”R2, â€”NHR1, â€”N(R1)R2, Y2 is â€”SR1, R3 is wherein R4 and R5 may be each independently of the other hydrogen or C1-C4alkyl, n may be a number from 1 to 4, R6 and R7 are each independently of the other hydrogen, halogen, C1-C4alkyl, C1-C4alkoxy, amino-C1-C4alkyl diphenylphosphine or diphenylphosphine radical-substituted methylene, ethylene, propylene or butylene, R8 may be â€”C(&boxH;O)â€”Oâ€”R9 or â€”Oâ€”C(&boxH;O)â€”R9â€”, wherein R9 may be a single bond, C1-C4alkylene or C2-C4alkenyl and M2 is a divalent transition metal, and wherein R12 is hydrogen or methyl, R13 is a single bond, â€”CH2â€”, â€”CH2CH2â€”, â€”CH&boxH;CHâ€”, â€”CH2â€”C(&boxH;O)â€” or â€”CH2CH2â€”C(&boxH;O)â€”, x may be a rational number from 0 to 8, y1 and Y2 may be each independently of the other a rational number from 0 to 6, z may be a number from 1 to 4, wherein (x+y1+y2+z)is&lE;16, and wherein R1 and R2 may be each independently of the other C1-C20alkyl which is unsubstituted or substituted by halogen, hydroxy, C1-C20alkoxy, C1-C20alkylamino or C2-C20dialkylamino and which may be interrupted by â€”Oâ€”, â€”Sâ€”, â€”NHâ€” or â€”NR10â€”, wherein R10 may be C1-C6alkyl, C5-C20cycloalkyl, C2-C20alkenyl, C1-C12cycloalkenyl, C2-C20alkynyl, C6-C18aryl or C7-C18aralkyl.