Patent ID: 6071830
Filing Date: 2000-06-06
Classification: H01L

Abstract:
A method of forming an insulating film on wafer substrates comprising the steps of:(a) providing a wafer having a surface with a silicon oxide film formed by plasma CVD disposed on said surface;(b) hydroxylating the silicon oxide film by subjecting the silicon oxide film to a plasma processing using a plasma comprising N.sub.2 O or a mixture of Ar and H.sub.2 or to provide a hydroxylated silicon oxide film;(c) reacting the hydroxylated silicon oxide film with a silane coupling agent to provide a silanized silicon oxide film, the silane coupling agent having the formulaSi(OH)w(X)x(OR)yR'z (1)where w, x, y and z each are an integer satisfying 0.ltoreq.w.ltoreq.3, 0.ltoreq.x.ltoreq.3.0.ltoreq.y.ltoreq.3.1.ltoreq.z.ltoreq.3, w+x+y>1 and w+x+y+z=4.X is halogen, OR is an alkoxyl group, and R' is selected from a group consisting of an alkyl group, a halogenated alkyl group, an alkene group, an aminoalkyl group and their derivatives or an arbitrary combination of the same when z.gtoreq.2 and wherein at least one R' expressed in formula (1) contains a fluorine atom and the organic insulating film material is composed of a compound containing a fluorine atom;(d) coating an organic insulating film forming solution on the silanized silicon oxide film; and(e) heating the film forming solution to remove solvent and provide a firmly adherent organic insulating film on the silanized silicon oxide film.