Patent ID: 6166218
Filing Date: 2000-12-26
Classification: B41M,C07D,C07F,C08K,C09D,Y10S

Abstract:
A compound of formula I, III or IV ##STR13## wherein G.sub.1 is hydrogen or chloro,G.sub.2 is cyano, perfluoroalkyl of 1 to 12 carbon atoms or fluoro,G.sub.6 is perfluoroalkyl of 1 to 12 carbon atoms,G.sub.7 is hydrogen or perfluoroalkyl of 1 to 12 carbon atoms,E.sub.1 is hydrogen, straight or branched chain alkyl of 1 to 24 carbon atoms, straight or branched chain alkenyl of 2 to 24 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 15 carbon atoms, phenyl, or said phenyl or said phenylalkyl substituted on the phenyl ring by 1 to 4 alkyl of 1 to 4 carbon atoms; or E.sub.1 is alkyl of 1 to 24 carbon atoms substituted by one or two hydroxy groups,E.sub.2 and E.sub.2 ' are independently straight or branched alkyl chain of 1 to 24 carbon atoms, straight or branched chain alkenyl of 2 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 15 carbon atoms, phenyl, or said phenyl or said phenylalkyl substituted on the phenyl ring by one to three alkyl of 1 to 4 carbon atoms; or E.sub.2 and E.sub.2 ' are independently said alkyl of 1 to 24 carbon atoms or said alkenyl of 2 to 18 carbon atoms substituted by one or more --OH, --OCOE.sub.11, --OE.sub.4, --NCO, --NH.sub.2, --NHCOE.sub.11, --NHE.sub.4 or --N(E.sub.4).sub.2, or mixtures thereof, where E.sub.4 is straight or branched chain alkyl of 1 to 24 carbon atoms; or said alkyl or said alkenyl interrupted by one or more --O--, --NH-- or --NE.sub.4 -- groups or mixtures thereof and which can be unsubstituted or substituted by one or more --OH, --OE.sub.4 or --NH.sub.2 groups or mixtures thereof;n is 1 or 2,when n is 1, E.sub.5 is OE.sub.6 or NE.sub.7 E.sub.8, orE.sub.5 is --PO(OE.sub.12).sub.2, --OSi(E.sub.11).sub.3 or --OCO--E.sub.11, or straight or branched chain C.sub.1 -C.sub.24 alkyl which is interrupted by --O--, --S-- or --NE.sub.11 and which can be unsubstituted or substituted by --OH or --OCO--E.sub.11, C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by --OH, straight chain or branched C.sub.2 -C.sub.18 alkenyl which is unsubstituted or substituted by --OH, C.sub.7 -C.sub.15 aralkyl, --CH.sub.2 --CHOH--E.sub.13 or glycidyl,E.sub.6 is hydrogen, straight or branched chain C.sub.1 -C.sub.24 alkyl which is unsubstituted or substituted by one or more OH, OE.sub.4 or NH.sub.2 groups, or --OE.sub.6 is --(OCH.sub.2 CH.sub.2).sub.w OH or --(OCH.sub.2 CH.sub.2).sub.w OE.sub.21 where w is 1 to 12 and E.sub.21 is alkyl of 1 to 12 carbon atoms,E.sub.7 and E.sub.8 are independently hydrogen, alkyl of 1 to 18 carbon atoms, straight or branched chain C.sub.3 -C.sub.18 alkyl which is interrupted by --O--, --S-- or --NE.sub.11 --, C.sub.5 -C.sub.12 cycloaLkyl, C.sub.6 -C.sub.14 aryl or C.sub.1 -C.sub.3 hydroxylalkyl, or E.sub.7 and E.sub.8 together with the N atom are a pyrrolidine, piperidine, piperazine or morpholine ring,E.sub.5 is --X--(Z).sub.p --Y--E.sub.15whereinX is --O-- or --N(E.sub.16)--,Y is --O-- or --N(E.sub.17)--,Z is C.sub.2 -C.sub.12 -alkylene, C.sub.4 -C.sub.12 -alkylene interrupted by one to three nitrogen atoms, oxygen atoms or a mixture thereof, or is C.sub.3 -C.sub.12 -alkylene, butenylene, butynylene, cyclohexylene or phenylene, each substituted by a hydroxyl group,m is zero, 1 or 2,p is 1, or p is also zero when X and Y are --N(E.sub.16)-- and --N(E.sub.17)--, respectively,E.sub.15 is a group --CO--C(E.sub.18).dbd.C(H)E.sub.19 or, when Y is --N(E.sub.17)--, forms together with E.sub.17 a group --CO--CH.dbd.CH--CO--, wherein E.sub.18 is hydrogen or methyl, and E.sub.19 is hydrogen, methyl or --CO--X--E.sub.20, wherein E.sub.20 is hydrogen, C.sub.1 -C.sub.12 -alkyl or a group of the formula ##STR14## wherein the symbols E.sub.1, G.sub.2, X, Z, m and p have the meanings defined above, and E.sub.16 and E.sub.17 independently of one another are hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkyl interrupted by 1 to 3 oxygen atoms, or is cyclohexyl or C.sub.7 -C.sub.15 aralkyl, and E.sub.16 together with E.sub.17 in the case where Z is ethylene, also forms ethylene,when n is 2, E.sub.5 is one of divalent radicals --O--E.sub.9 --O-- or --N(E.sub.11)--E.sub.10 --N(E.sub.11)--,E.sub.9 is C.sub.2 -C.sub.8 alkylene, C.sub.4 -C.sub.8 alkenylene, C.sub.4 alkynylene, cyclohexylene, straight or branched chain C.sub.4 -C.sub.10 alkylene which is interrupted by --O-- or by --CH.sub.2 --CHOH--CH.sub.2 --O--E.sub.14 --O--CH.sub.2 --CHOH--CH.sub.2 --,E.sub.10 being straight or branched chain C.sub.2 -C.sub.12 alkylene which may be interrupted by --O--, cyclohexylene, or ##STR15## or E.sub.10 and E.sub.11 with the two nitrogen atoms form a piperazine ring,E.sub.14 is straight or branched chain C.sub.2 -C.sub.8 alkylene, straight or branched chain C.sub.4 -C.sub.10 alkylene which is interrupted by --O--, cycloalkylene, arylene or ##STR16## where E.sub.7 and E.sub.8 are independently hydrogen, alkyl of 1 to 18 carbon atoms or E.sub.7 and E.sub.8 together are alkylene of 4 to 6 carbon atoms, 3-oxapentamethylene, 3-iminopentamethylene or 3-methyliminopentamethylene,E.sub.11 is hydrogen, straight or branched chain C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl, straight or branched chain C.sub.2 -C.sub.18 alkenyl, C.sub.6 -C.sub.14 aryl or C.sub.7 -C.sub.15 aralkyl,E.sub.12 is straight or branched chain C.sub.1 -C.sub.18 alkyl, straight or branched chain C.sub.3 -C.sub.18 alkenyl, C.sub.5 -C.sub.10 cycloalkyl, C.sub.6 -C.sub.16 aryl or C.sub.7 -C.sub.15 aralkyl,E.sub.13 is H, straight chain or branched C.sub.1 -C.sub.18 alkyl which is substituted by --PO(OE.sub.12).sub.2, phenyl which is unsubstituted or substituted by OH, C.sub.7 -C.sub.15 aralkyl or --CH.sub.2 OE.sub.12,L is alkylene of 1 to 12 carbon atoms, alkylidene of 2 to 12 carbon atoms, benzylidene, p-xylylene, .alpha.,.alpha.,.alpha.',.alpha.'-tetramethyl-m-xylylene or cycloalkylidene, andwith the proviso that when G.sub.2 is CF.sub.3 and E.sub.1 is hydrogen, E.sub.2 is not methyl.