Patent ID: 8563096
Filing Date: 2013-10-22
Classification: C23C

Abstract:
1. A method for using a vertical film formation apparatus for forming a silicon nitride film, the film formation apparatus comprising a vertical process container configured to hold a vacuum state therein, the process container including an inner surface made of quartz, from which Na can be released as a contaminant, a holder configured to hold a plurality of target objects at intervals in a vertical direction inside a process container, a heater disposed around the process container to heat the target objects, a first process gas supply system configured to supply a Si source gas containing Si and Cl into the process container, the first process gas supply system including a first nozzle extending vertically with a plurality of gas spouting holes formed thereon to spout the Si source gas in horizontal directions, a second process gas supply system configured to supply a ammonia gas into the process container, the second process gas supply system including a second nozzle extending vertically with a plurality of gas spouting holes formed thereon to spout the ammonia gas in horizontal directions, a plasma generation system attached to the process container and configured to turn into plasma the ammonia gas spouted from the second nozzle, and an exhaust system configured to exhaust gas from inside the process container, the method comprising: performing a coating process inside the process container without product target objects present therein to cover the inner surface of the process container with a coating film, then, performing a film formation process inside the process container accommodating the holder with the product target objects placed thereon to form the silicon nitride film on the product target objects, the coating process and the film formation process respectively forming the coating film and the silicon nitride film to have a predetermined thickness by repeating a cycle a plurality of times to laminate thin films respectively formed by the plurality of times, the cycle comprising: a first supply step of supplying the Si source gas into the process container by spouting the Si source gas from the first nozzle without supplying the ammonia gas into the process container, thereby forming an adsorbed layer derived from the Si source gas; then a first purge step of exhausting gas from inside the process container without supplying either of the Si source gas or the ammonia gas into the process container; then an second supply step of supplying the ammonia gas into the process container by spouting the ammonia gas from the second nozzle without supplying the Si source gas into the process container, thereby nitriding the adsorbed layer; and then a second purge step of exhausting gas from inside the process container without supplying either of the Si source gas and the ammonia gas into the process container, wherein the coating process forms the coating film in a thermal atomic layer deposition (ALD) manner by setting the process container at a coating temperature during the cycle, and supplying the Si source gas and the ammonia gas into the process container without turning either of the Si source gas and the ammonia gas into plasma, wherein the film formation process forms the silicon nitride film in a plasma ALD manner by setting the process container at a film formation temperature lower than the coating temperature during the cycle, in which the first supply step is a step of supplying the Si source gas into the process container without turning the Si source gas into plasma, and the second supply step is a step of supplying the ammonia gas into the process container while turning the ammonia gas into plasma by the plasma generating system, and wherein the coating process uses conditions to control concentration of chlorine in the coating film, the chlorine being derived from the Si source gas and serving to trap the Na, such that the conditions include time periods of the first and second purge steps of the coating process set to be respectively shorter than time periods of the first and second purge steps of the film formation process.