Patent ID: 6398987
Filing Date: 2002-06-04
Classification: C07C,C07D,C09K,G02B

Abstract:
A compound having the following formula (I): in which:X is a linear or branched perfluoroalkyl comprising 1 to 6 carbon atoms; R1 and R2, which are identical or different, independently represent: hydrogen, a linear or branched alkyl group comprising 1 to 12 carbon atoms, a cycloalkyl group comprising 3 to 12 carbon atoms, an aryl group comprising in its basic structure 6 to 24 carbon atoms or a heteroaryl group comprising in its basic structure 4 to 24 carbon atoms and at least one heteroatom selected from sulfur, oxygen and nitrogen, said aryl or heteroaryl group's basic structure being optionally substituted with at least one substituent selected from the group consisting of: a halogen, a hydroxy group, a linear or branched alkyl group comprising 1 to 12 carbon atoms, a linear or branched alkoxy group comprising 1 to 12 carbon atoms, a haloalkyl or haloalkoxy group corresponding respectively to the (C1-C12) alkyl or alkoxy groups above which are substituted with at least one halogen atom, a phenoxy or naphthoxy group optionally substituted with at least one linear or branched alkyl or alkoxy group comprising 1 to 12 carbon atoms, a linear or branched alkenyl group comprising 2 to 12 carbon atoms, an â€”NH2 group, an â€”NHR group, R representing a linear or branched alkyl group comprising 1 to 6 carbon atoms, or a phenyl group optionally substituted with at least one linear or branched alkyl group comprising 1 to 6 carbon atoms, a group wherein Râ€² and Râ€³, which are identical or different, independently represent a linear or branched alkyl group comprising 1 to 6 carbon atoms or a phenyl group optionally substituted with at least one linear or branched alkyl group comprising 1 to 6 carbon atoms or wherein Râ€² and Râ€³ represent together with the nitrogen atom to which they are bound a 5- to 7-membered ring which optionally comprises at least one other heteroatom selected from oxygen, sulfur, and nitrogen, said nitrogen being optionally substituted with an Râ€²â€³ group, which is a linear or branched alkyl group comprising 1 to 6 carbon atoms, and a methacryloyl group or an acryloyl group, or an aralkyl or heteroaralkyl group, the alkyl part of which is linear or branched and comprises 1 to 4 carbon atoms and the aryl part or heteroaryl part of which has the same definition as that given above for the aryl and or heteroaryl group; â€ƒor â€ƒsaid two substituents R1 and R2 together form an adamantyl, norbornyl, fluorenylidene, di(C1-C6)alkylanthracenylidene, or spiro(C5-C6)cycloalkylanthracenylidene group, said group being optionally substituted with at least one substituent selected from the group consisting of: a halogen, a hydroxy group, a linear or branched alkyl group comprising 1 to 12 carbon atoms, a linear or branched alkoxy group comprising 1 to 12 carbon atoms, a haloalkyl or haloalkoxy group corresponding to the (C1-C12) alkyl or alkoxy groups above, respectively, which are substituted with at least one halogen atom, a linear or branched alkenyl group comprising 2 to 12 carbon atoms, an â€”NH2 group, an â€”NHR group, wherein R represents a linear or branched alkyl group comprising 1 to 6 carbon atoms, a group, wherein Râ€² and Râ€³, which are identical or different, represent, independently, a linear or branched alkyl group comprising 1 to 6 carbon atoms or Râ€² and Râ€³, together with the nitrogen atom to which they are bound, represent a 5- to 7-membered ring which optionally comprises at least one other heteroatom selected from oxygen, sulphur, and nitrogen, said nitrogen being optionally substituted with an Râ€²â€³ group, which is a linear or branched alkyl group comprising 1 to 6 carbon atoms, and a methacryloyl group or an acryloyl group; R3, which are identical or different, represent, independently: a halogen, a hydroxy, a linear or branched alkyl group comprising 1 to 12 carbon atoms, a cycloalkyl group comprising 3 to 12 carbon atoms, a linear or branched alkoxy group comprising 1 to 12 carbon atoms, a haloalkyl, halocycloalkyl, or haloalkoxy group corresponding respectively to the alkyl, cycloalkyl, and alkoxy groups above, which are substituted with at least one halogen atom, an aryl or heteroaryl group having the same definition as that given above for R1, R2, an aralkyl or heteroaralkyl group, the alkyl part of which is linear or branched and comprises 1 to 4 carbon atoms and the aryl and heteroaryl part of which has the same definitions as those given above for R1, R2, a phenoxy or naphthoxy group optionally substituted with at least one linear or branched alkyl or alkoxy group comprising 1 to 12 carbon atoms, an amine or amide group: â€”NH2, â€”NHR, â€”CONH2, â€”CONHR, â€ƒwherein R represents a linear or branched alkyl group comprising 1 to 6 carbon atoms and wherein Râ€² and Râ€³, which are identical or different, represent, independently, a linear or branched alkyl group comprising 1 to 6 carbon atoms or Râ€² and Râ€³, together with the nitrogen atom to which they are bound, represent a 5- to 7-membered ring which optionally comprises at least one other heteroatom selected from oxygen, sulphur, and nitrogen, said nitrogen being optionally substituted with an Râ€²â€³ group, which is a linear or branched alkyl group comprising 1 to 6 carbon atoms, an â€”OCOR6 or â€”COOR6 group, R6 representing a linear or branched alkyl group comprising 1 to 6 carbon atoms, a cycloalkyl group comprising 3 to 6 carbon atoms, or a phenyl group, optionally substituted with at least one substituent selected from the group consisting of: a halogen, a hydroxy group, a linear or branched alkyl group comprising 1 to 12 carbon atoms, a linear or branched alkoxy group comprising 1 to 12 carbon atoms, a haloalkyl or haloalkoxy group corresponding to the (C1-C12) alkyl or alkoxy groups above, respectively, which are substituted with at least one halogen atom, a linear or branched alkenyl group comprising 2 to 12 carbon atoms, an â€”NH2 group, an â€”NHR group, wherein R represents a linear or branched alkyl group comprising 1 to 6 carbon atoms, a group, wherein Râ€² and Râ€³, which are identical or different, represent, independently, a linear or branched alkyl group comprising 1 to 6 carbon atoms or Râ€² and Râ€³, together with the nitrogen atom to which they are bound, represent a 5- to 7-membered ring which optionally comprises at least one other heteroatom selected from oxygen, sulphur, and nitrogen, said nitrogen being optionally substituted with an Râ€²â€³ group, which is a linear or branched alkyl group comprising 1 to 6 carbon atoms, and a methacryloyl group or an acryloyl group; â€ƒor â€ƒat least two of the adjacent R3 groups together form an aromatic or non-aromatic cyclic group having one or two annelated rings, optionally comprising at least one heteroatom selected from the group consisting of oxygen, sulfur, and nitrogen, this or these annelated rings being independently 5- to 7-membered aromatic or non-aromatic rings and being optionally substituted with at least one substituent selected from those having the definition given above for the aryl or heteroaryl groups representing R1 or R2; m is an integer of 0 to 4; and R4 represents a hydrogen, a hydroxy, a linear or branched alkyl comprising 1 to 12 carbon atoms, a linear or branched alkoxy comprising 1 to 12 carbon atoms, an aryl or heteroaryl as defined above for R1 or R2, or an ester of formula OCOR6, where R6 is as defined above.