Patent ID: 8748669
Filing Date: 2014-06-10
Classification: B01J,C07C,C07F

Abstract:
1. A process for producing aldehydes or ketones by aerobic oxidation of alcohol comprising a step of oxidizing alcohol to aldehyde or ketone at room temperature, under neutral conditions, and in an organic solvent for about 1 to 24 hours using oxygen or air as oxidant, and ferric nitrate, 2,2,6,6-tetramethylpiperidinyloxy and one or more inorganic chloride as catalysts, wherein a molar ratio of said alcohol to said 2,2,6,6-tetramethylpiperidinyloxy, to said ferric nitrate, and to said one or more inorganic chloride is 100:1˜10:1˜10:1˜10, wherein said one or more inorganic chloride is selected from the group consisting of sodium chloride, potassium chloride, lithium chloride, rubidium chloride and cesium chloride.