Patent ID: 6767974
Filing Date: 2004-07-27
Classification: C08F

Abstract:
A process comprising:heating to a first polymerization temperature a first mixture comprising a first free radical polymerizable monomer, a first free radical initiator, and a first stable free radical compound to polymerize only a portion of the first monomer, resulting in a prepolymer composition; shearing a second mixture including the prepolymer composition, a continuous phase liquid, and a stabilizing compound to create a miniemulsion; and heating to a second polymerization temperature the miniemulsion to form polymeric particles, wherein there is added to the second mixture, the miniemulsion, or both the second mixture and the miniemulsion at any time prior to the formation of the polymeric particles a second free radical initiator, a second free radical polymerizable monomer, and an optional second stable free radical compound, wherein at least one of the second initiator and the second monomer includes a functional group, wherein the polymeric particles each includes a compound with the functional group covalently bound and with the functional group disposed on the particle surface.