Patent ID: 8338640
Filing Date: 2012-12-25
Classification: C07C

Abstract:
1. A process for heterogeneously catalyzed partial direct oxidation of propane and/or isobutane to at least one of the target products acrylic acid, methacrylic acid, by feeding a starting reaction gas mixture comprising propane and/or isobutane, molecular oxygen and at least one inert diluent gas and having a inlet pressure P 1 to a reaction stage which, apart from an inlet for the starting reaction gas mixture, optionally further inlets for auxiliary gases, and an outlet for the product gas mixture, is sealed on the gas side, in the reaction stage directly oxidizing the propane and/or isobutane present in the starting reaction gas mixture partially to at least one target product by passing the starting reaction gas mixture at elevated temperature over a solid state catalyst, and conducting the reaction gas mixture as a product gas mixture comprising at least one target product and having the outlet pressure P 2 out of the reaction stage and, with this pressure P 2 , into a workup stage which, apart from an inlet for the product gas mixture, optionally further inlets for auxiliary gases, and an outlet for the residual product gas mixture, is sealed on the gas side, in the workup stage basically separating target product present in the product gas mixture of the reaction stage from said product gas mixture into a liquid phase and conducting the remaining residual product gas mixture which comprises not only propane and/or isobutane and also in some cases propene and/or isobutene and has the outlet pressure P 3 , where P 3 <P 1 , out of the workup stage and recycling propane and/or isobutane present in the residual product gas mixture into the reaction stage, which comprises selecting P 1 in such a way that P 3 ≧1.5 bar and dividing the residual product gas mixture into two portions of the same composition and discharging one portion as output and recycling the other portion as cycle gas and feeding it back to the reaction stage, compressed to the inlet pressure P 1 , as a constituent of the starting reaction gas mixture.