Patent ID: 6599860
Filing Date: 2003-07-29
Classification: A01N,C07D

Abstract:
A haloalkyl-substituted 3-(4,5-dihydroisoxazol-3-yl)benzoylcyclohexenone of the formula I in whichR1 is C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy or C1-C6-haloalkoxy; R2 is C1--C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, halogen, cyano or nitro; R3 is hydrogen, C1-C6-alkyl or halogen; R4 is C1-C4-haloalkyl; R5, R6, R7 independently of one another are hydrogen, C1-C4-alkyl or C1-C4-haloalkyl; R8 is hydroxyl, mercapto, halogen, OR15, SR15, SOR16 or SO2R16; R9, R13 independently of one another are hydrogen, C1-C4-alkyl, C1-C4-alkylthio or C1-C4-alkoxycarbonyl; R10, R12, R14 independently of one another are hydrogen or C1-C4-alkyl; R11 is hydrogen, hydroxyl, halogen, C1-C6-alkyl, C1-C6-haloalkyl, di(C1-C6-alkoxy)methyl, (C1-C6-alkoxy) (C1-C6-alkylthio)methyl, di(C1-C6-alkylthio)methyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkoxycarbonyl, C1-C6-haloalkoxycarbonyl, 1,3-dioxolan-2-yl, 1,3-dioxan-2-yl, 1,3-oxathiolan-2-yl, 1,3-oxathian-2-yl, 1,3-dithiolan-2-yl or 1,3-dithian-2-yl, where the six lastmentioned radicals may carry one, two or three substituents selected from C1-C4-alkyl; or R9 and R10 or R13 and R14 together are C1-C5-alkanediyl which may carry one, two or three substituents selected from the group consisting of halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4-alkoxycarbonyl; or R10 and R11 or R11 and R14 together are a chemical bond or C1-C5-alkanediyl which may carry one, two or three substituents selected from the group consisting of halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4-alkoxycarbonyl; or R10 and R14 together are C1-C4-alkanediyl which may carry one, two or three substituents selected from the group consisting of halogen, cyano, C1-C4-alkyl, C1-C4-alkoxycarbonyl; or R11 and R12 together are â€”Oâ€”(CH2)pâ€”Oâ€”, â€”Oâ€”(CH2)pâ€”Sâ€”, â€”Sâ€”(CH2)pâ€”Sâ€”, â€”Oâ€”(CH2)qâ€” or â€”Sâ€”(CH2)qâ€” which may carry one, two or three substituents selected from the group consisting of halogen, cyano, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4-alkoxycarbonyl; or R11 and R12 together are an oxygen atom; R15 is C1-C6-alkyl, C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkynyl, C3-C6-cycloalkyl, C1-C20-alkylcarbonyl, C2-C20-alkenylcarbonyl, C2-C6-alkynylcarbonyl, C1-C6-alkoxycarbonyl, C3-C6-alkenyloxycarbonyl, C3-C6-alkynyloxycarbonyl, C1-C6-alkylthiocarbonyl, C1-C6-alkylaminocarbonyl, C3-C6-alkenylaminocarbonyl, C3-C6-alkynylaminocarbonyl, N,N-di(C1-C6-alkyl)aminocarbonyl, N-(C3-C6-alkenyl)-N-(C1-C6-alkyl)aminocarbonyl, N-(C3-C6-alkynyl)-N-(C1-C6-alkyl)aminocarbonyl, N-(C1-C6-alkoxy)-N-(C1-C6-alkyl)aminocarbonyl, N,N-di(C1-C6-alkyl)aminothiocarbonyl, C1-C6-alkoxyimino-C1-C6-alkyl, where the alkyl, alkoxy and cycloalkyl radicals mentioned may be partially or fully halogenated and/or may carry one, two or three substituents selected from the group consisting of cyano, C1-C4-alkoxy, C1-C4-alkylthio, di(C1-C4-alkyl)amino, C1-C4-alkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-alkoxy-C1-C4-alkoxycarbonyl, C1-C4-alkylaminocarbonyl, N,N-di(C1-C4-alkyl)aminocarbonyl and C3-C6-cycloalkyl; is phenyl, phenyl-C1-C6-alkyl, phenylcarbonyl-C1-C6-alkyl, phenylcarbonyl, phenoxycarbonyl, phenoxythiocarbonyl, heterocyclyl, heterocyclyl-C1-C6-alkyl, heterocyclylcarbonyl-C1-C6-alkyl, heterocyclylcarbonyl, heterocyclyloxycarbonyl, heterocyclyloxythiocarbonyl, where the phenyl or heterocyclyl radical of the radicals mentioned may be partially or fully halogenated and/or may carry one, two or three substituents selected from the group consisting of nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy; R16 is C1-C6-alkyl, C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkynyl or C3-C6-cycloalkyl, where the alkyl and cycloalkyl radicals mentioned may be partially or fully halogenated and/or may carry one, two or three substituents selected from the group consisting of cyano, C1-C4-alkoxy, C1-C4-alkylthio, di(C1-C4-alkyl)amino, C1-C4-alkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-alkoxy-C1-C4-alkoxycarbonyl, C1-C4-alkylaminocarbonyl, N,N-di(C1-C4-alkyl)aminocarbonyl and C3-C6-cycloalkyl; is phenyl, phenyl-C1-C6-alkyl, phenylcarbonyl-C1-C6-alkyl, heterocyclyl, heterocyclyl-C1-C6-alkyl or heterocyclylcarbonyl-C1-C6-alkyl, where the phenyl or heterocyclyl radical of the radicals mentioned may be partially or fully halogenated and/or may carry one, two or three substituents selected from the group consisting of nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy; p is 2, 3 or 4; q is 1, 2, 3, 4 or 5; and its agriculturally useful salts.