Patent ID: 6451736
Filing Date: 2002-09-17
Classification: A01N,C07D,C07F

Abstract:
Substituted aromatic thixocarboxamides of the formula (I) in whichR1 represents hydrogen, fluorine, chlorine or bromine, R2 represents the group â€”A1â€”A2â€”A3 â€ƒin which A1 represents a single bond, or represents oxygen, sulphur, â€”SOâ€”, â€”SO2â€”, â€”COâ€” or the group â€”Nâ€”A4â€”, in which A4 represents hydrogen, hydroxyl, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkinyl, C1-C4-alkoxy, phenyl, C1-C4-alkylsulphonyl or phenylsulphonyl, A1 further represents in each case optionally fluorine- or chlorine-substituted C1-C6-alkanediyl, C2-C6-alkenediyl, C3-C6-cycloalkanediyl, C3-C6-cycloalkendiyl or phenylene, A2 represents a single bond, or represents oxygen, sulphur, â€”SOâ€”, â€”SO2â€”, â€”COâ€” or the group â€”Nâ€”A4â€”, in which A4 represents hydrogen, hydroxyl, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkinyl, C1-C4-alkoxy, phenyl, C1-C4-alkylsulphonyl or phenylsulphonyl, A2 further represents in each case optionally fluorine- or chlorine-substituted C1-C6-alkanediyl, C2-C6-alkenediyl, C3-C6-cycloalkanediyl, C3-C6-cycloalkendiyl or phenylene, A3 represents hydrogen, hydroxyl, amino, cyano, isocyano, thiocyano, nitro, carboxyl, carbamoyl, thiocarbamoyl, sulpho, chlorosulphonyl, halogen, or represents in each case optionally halogen- or C1-C4-alkoxy-substituted alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylamino, dialkylalmino, alkoxycarbonyl or dialkoxy(thio)phosphoryl having in each case 1 to 6 carbon atomes in the alkyl groups, or represents in each case optionally halogen-substituted alkenyl, alkenyloxy, alkenylamino, alkylideneamino, alkenyloxycarbonyl, alkinyl, alkinyloxy, alkinylamino or alkinyloxycarbonyl having in each case 2 to 6 carbon atoms in the alkenyl, alkylidene or alkinyl groups, or represents in each case optionally halogen-, cyano-, carboxyl-, C1-C4-alkyl- and/or C1-C4-alkoxycarbonyl-substituted cycloalkyl, cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylideneamino, cycloalkyloxycarbonyl or cycloalkylalkoxycarbonyl having in each case 3 to 6 carbon atoms in the cycloalkyl groups and optionally 1 to 4 carbon atoms in the alkyl groups, or represents in each case optionally nitro-, cyano-, carboxyl-, halogen-, C1-C4-alkyl, C1-C4-halogenoalkyl-, C1-C4-alkoxy, C1-C4-halogenoalkyloxy- and/or C1-C4-alkoxy-carbonyl-substituted phenyl, phenyloxy, phenyl-C1-C4-alkoxy-carbonyl-substituted phenyl, phenyloxy, phenyl-C1-C4-alkyl, phenyl-C1-C4-alkoxy, phenyloxycarbonyl or phenyl-C1-C4-alkoxycarbonyl, R3 represents hydrogen, fluorine, chlorine or bromine or together with R2 represents an alkanediyl or alkenediyl group having in each case up to 4 carbon atoms, and Z is selected from the group consisting of â€ƒwhere in each case Q1 is selected from the group consisting of â€”COâ€”, â€”CSâ€”, â€”CH2â€”, â€”CH(OH)â€”, â€”CHClâ€”, â€”CHBrâ€”, â€”C(&boxH;CH2)â€”, â€”C(&boxH;CHF)â€”, â€”C(&boxH;CF2)â€”, â€”C(&boxH;CHCl), â€”C(&boxH;CHBr)â€”, â€”C(&boxH;CHOCHF2)â€”, R6 represents hydrogen, amino, nitro, cyano, carboxyl, carbamoyl, fluorine, chlorine, bromine, methyl, ethyl, n- or i-isopropyl, cyclopropyl, difluoromethyl, trifluormethyl, chlorodifluoromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy, trifluormethoxy, chlorodifluoromethoxy, methylthio, ethylthio, n- or i-propylthio, difluoromethylthio, trifluormethylthio, chlorodifluoromethylthio, methylamino, ethylamino, n- or i-propylamino, dimethylamino, diethylamino, methoxycarbonyl or ethoxycarbonyl, and R7 represents hydrogen, hydroxyl, amino, cyano, methyl, ethyl, n- or i-propyl, difluoromethyl, methoxy, ethoxy, n- or i-propoxy, or where two adjacent groups R6 and R6 or R6 and R7 together represent in each case optionally fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl substituted alkanediyl or alkenediyl having in each case up to 4 carbon atoms.