Patent ID: 6703182
Filing Date: 2004-03-09
Classification: B33Y,C07C,C09D,G03F,Y10S

Abstract:
Compounds of formulae I, II or III m is zero or 1; n is 1, 2 or 3; R1 is phenyl, which is unsubstituted or substituted by one or more of the radicals C1-C12alkyl, C1-C4haloalkyl, halogen, phenyl, OR6, NR7R8, SR9 and/or â€”S-phenyl, it being possible for the substituents OR6, SR9 and NR7R8 to form 5- or 6-membered rings, via the radicals R6, R7, R8 and/or R9, with further substituents on the phenyl ring or with one of the carbon atoms of the phenyl ring; or R1 is naphthyl, anthracyl or phenanthryl, wherein the radicals naphthyl, anthracyl and phenanthryl are unsubstituted or substituted by C1-C6alkyl, phenyl, OR6, NR7R8, SR9 and/or â€”S-phenyl, it being possible for the substituents OR6, SR9 and NR7R8 to form 5- or 6-membered rings, via the radicals R6, R7, R8 and/or R9 with further substituents on the naphthyl, anthracyl or phenanthryl ring or with one of the carbon atoms of the naphthyl, anthracyl or phenanthryl ring; or R1 is a heteroaryl radical which is unsubstituted or substituted by C1-C6alkyl, phenyl, OR6, NR7R8, SR9 and/or â€”S-phenyl, it being possible for the substituents OR6, SR9 and NR7R8 to form 5- or 6-membered rings, via the radicals R6, R7, R8 and/or R9 with further substituents on the heteroaryl ring or with one of the carbon atoms of the heteroaryl ring; or R1 is C2-C12alkenyl, C4-C8cycloalkenyl, or C6-C12bicycloalkenyl, with the proviso that the double bond (or the double bonds) of the radicals C2-C12alkenyl, C4-C8cycloalkenyl, or C6-C12bicycloalkenyl is (are) conjugated with the double bond substituted by R4 and R5; or, if m is zero, R1 additionally is benzoyl, 2-furoyl, 2-thio-phenecarbonyl, 2-pyridinecarbonyl or 2-pyrrolecarbonyl, wherein the radicals benzoyl, 2-furoyl, 2-thiophenecarbonyl, 2-pyridinecarbonyl or 2-pyrrolecarbonyl are unsubstituted or substituted by one or more of the radicals C1-C12alkyl, C1-C4haloalkyl, halogen, phenyl, OR6, NR7R8, SR9 and/or â€”S-phenyl, it being possible for the substituents OR6, SR9 and NR7R8 to form 5- or 6-membered rings, via the radicals R6, R7, R8 and/or R9, with further substituents on the benzoyl, 2-furoyl, 2-thiophenecarbonyl, 2-pyridinecarbonyl or 2-pyrrolecarbonyl ring or with one of the carbon atoms of the benzoyl, 2-furoyl, 2-thiophenecarbonyl, 2-pyridinecarbonyl or 2-pyrrolecarbonyl ring; or, if m is zero, n is 1 and simultaneously R5 is phenyl which is unsubstituted or substituted by one or more C1-C12alkyl, C1-C4haloalkyl, halogen, phenyl, OR6, NR7R8, SR9 and/or â€”S-phenyl, R1 additionally is hydrogen or halogen; Râ€²1 is vinylene, phenylene, naphthylene, â€ƒdiphenylene or oxydiphenylene, wherein the radicals phenylene, naphthylene, â€ƒdiphenylene and oxydiphenylene are unsubstituted or substituted by C1-C12alkyl; R2 is CN, C1-C4haloalkyl, C2-C6alkoxycarbonyl, phenoxycarbonyl, C1-C6alkyl-S(O)xâ€”, C6-C12aryl-S(O)xâ€”, which is unsubstituted or substituted by C1-C12alkyl, or R2 is C1-C6alkyl-SO2Oâ€”, C6-C10aryl-SO2Oâ€”, diphenyl-phosphinoyl or R2 is benzoyl which is unsubstituted or substituted by CN, NO2 or C1-C4haloalkyl; x is 1 or 2; R3 is C1-C18alkylsulfonyl, phenyl-C1-C3alkylsulfonyl, camphorylsulfonyl, C1-C10haloalkylsulfonyl, phenylsulfonyl, naphthylsulfonyl, anthracylsulfonyl or phenanthrylsulfonyl, wherein the groups phenyl, naphthyl, anthracyl and phenanthryl of the radicals phenyl-C1-C3alkylsulfonyl, phenylsulfonyl, naphthylsulfonyl, anthracylsulfonyl and phenanthrylsulfonyl are unsubstituted or substituted by one or more halogen, C1-C4haloalkyl, CN, NO2, C1-C16alkyl, phenyl, C1-C4alkylthio, OR6, COOR9, C1-C4alkyl-OCOâ€”, R9OSO2â€” and/or â€”NR7R8; or R3 is C2-C6haloalkanoyl, halobenzoyl, triphenylsilyl, or a group â€ƒor Y1, Y2 and Y3 are independently of each other O or S; Râ€²3 is C2-C12alkylenedisulfonyl, phenylenedisulfonyl, naphthylenedisulfonyl, â€ƒdiphenylenedisulfonyl, or oxydiphenylenedisulfonyl, wherein the groups phenylene, naphthylene, â€ƒdiphenylene and oxydiphenylene of the radicals phenylenedisulfonyl, naphthylenedisulfonyl, â€ƒdiphenylenedisulfonyl, or oxydiphenylenedisulfonyl are unsubstituted or substituted by C1-C12alkyl; R4 and R5 are independently of each other hydrogen, halogen, C1-C8alkyl, C1-C6alkoxy, C1-C4haloalkyl, CN, NO2, C2-C6alkanoyl, benzoyl, phenyl, â€”S-phenyl, OR6, SR9, NR7R8, C2-C6alkoxycarbonyl or phenoxycarbonyl, or R4 and R5 together are a direct bond; R6 is hydrogen, phenyl, C1-C12alkyl which is unsubstituted or substituted by phenyl, OH, C1-C12alkoxy, C1-C12alkylsulfonyl, phenylsulfonyl, (4-methylphenyl)sulfonyl and/or by C2-C6alkanoyl, or R6 is C2-C12alkyl which is interrupted by one or more â€”Oâ€” or â€”Sâ€”, wherein the interrupted C2-C12alkyl is unsubtstituted or substituted by phenyl, OH, C1-C12alkoxy, C1-C12alkylsulfonyl, phenylsulfonyl, (4-methylphenyl)sulfonyl and/or by C2-C6alkanoyl; R7 and R8 are independently of each other hydrogen or C1-C12alkyl which is unsubstituted or substituted by OH, C1-C4alkoxy, C1-C12alkylsulfonyl, phenylsulfonyl, (4-methyl-phenyl)sulfonyl and/or C1-C6alkanoyl; or R7 and R8 are C2-C12alkyl which is interrupted by one or more â€”Oâ€”, wherein the â€”O-interrupted C2-C12alkyl is unsubtstituted or substituted by OH, C1-C4alkoxy, C1-C12alkylsulfonyl, phenylsulfonyl, (4-methylphenyl)sulfonyl and/or C1-C6alkanoyl; or R7 and R8 are phenyl, C2-C6alkanoyl, benzoyl, C1-C6alkylsulfonyl, phenylsulfonyl, (4-methylphenyl)sulfonyl, naphthylsulfonyl, anthracylsulfonyl or phenanthrylsulfonyl; or R7 and R8, together with the nitrogen atom to which they are bonded, form a 5-, 6- or 7-membered ring which may be interrupted by â€”Oâ€” or by â€”NR6â€”; R9 is C1-C12 alkyl which is unsubstituted or substituted by OH and/or C1-C4alkoxy, or R9 is C2-C12alkyl which is interrupted by one or more â€”Oâ€” or â€”Sâ€” and which interrupted C2-C12alkyl is unsubstituted or substituted by OH and/or C1-C4alkoxy; R10, R11 and R12 independently of one another are C1-C6alkyl which is unsubstituted or substituted by halogen; or R10, R11 and R12 are phenyl which is unsubstituted or substituted by C1-C4alkyl or halogen; or R11 and R12 together are 1,2-phenylene or C2-C6alkylene which is unsubstituted or substituted by C1-C4alkyl or halogen; with the proviso that if m and n both are 1, R4 and R5 both are hydrogen and R1 is phenyl, R3 is not p-tolylsulfonyl.