Patent ID: 6379860
Filing Date: 2002-04-30
Classification: G03F,Y10S

Abstract:
A positive photosensitive composition comprising(a) a compound which generates an acid upon irradiation with actinic rays or a radiation and (b) a resin having groups which decompose by the action of an acid to enhance solubility in an alkaline developing solution, said resin being obtained by reacting an alkali-soluble resin having phenolic hydroxyl groups with at least one compound represented by the following general formula (I) under acid conditions in at least one organic solvent selected from the group consisting of ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monopropyl ether acetate, ethylene glycol monobutyl ether acetate, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol dipropyl ether, diethylene glycol dibutyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, propylene glycol dimethyl ether, propylene glycol diethyl ether, propylene glycol dipropyl ether, propylene glycol dibutyl ether, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monobutyl ether acetate, propylene glycol methyl ether propionate, propylene glycol ethyl ether propionate, propylene glycol propyl ether propionate, propylene glycol butyl ether propionate, methyl lactate, ethyl lactate, n-propyl lactate, isopropyl lactate, n-butyl lactate, isobutyl lactate, methyl formate, ethyl formate, n-propyl formate, isopropyl formate, n-butyl fornate, isobutyl formate, n-amyl formate, isoamyl formate, methyl acetate, ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, n-amyl acetate, isoamyl acetate, methyl propionate, ethyl propionate, n-propyl propionate, isopropyl propionate, n-butyl propionate, isobutyl propionate, n-amyl propionate, isoamyl propionate, methyl butyrate, ethyl butyrate, n-propyl butyrate, isopropyl butyrate, n-butyl butyrate, isobutyl butyrate, n-amyl butyrate, isoamyl butyrate, ethyl hydroxyacetate, ethyl 2-hydroxy-2-methylpropionate, methyl 2-hydroxy-3-methylbutyrate, ethyl methoxyacetate, ethyl ethoxyacetate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, 3-methoxybutyl acetate, 3-methyl-3-methoxybutyl acetate, 3-methyl-3-methoxybutyl butyrate, methyl acetoacetate, ethyl acetoacetate, methyl pyruvate, ethyl pyruvate, toluene, xylene, methyl ethyl ketone, methyl propyl ketone, methyl butyl ketone, 2-heptanone, 3-heptanone, 4-heptanone, and cyclohexanone: wherein R11 to R13 may be the same or different, and each represents a hydrogen atom, an alkyl group, an allyl group, an aralkyl group, or a cycloalkyl group; and R14 represents an alkyl group, an allyl group, an aralkyl group, or a cycloalkyl group; provided that either R11 and R13 or R11 and R12 may be bonded to each other to form either a five- to ten-membered carbon atom ring or a hetero ring containing at least one selected from the group consisting of â€”Oâ€”, â€”Sâ€”, â€”SO2â€”, and â€”N(R15)â€”, wherein R15 represents an alkyl group, an allyl group, or an aralkyl group, and that R12 and R14 may be bonded to each other to form a five- to eight-membered ring containing the oxygen atom and carbon atoms, wherein the resin (b) is a resin synthesized by dissolving an alkali-soluble resin having phenolic hydroxyl groups in the organic solvent, subjecting the resultant solution to vacuum distillation, then adding at least one compound represented by general formula (I) to react the same with the alkali-soluble resin, neutralizing the resultant reaction mixture with a base, subsequently washing and extracting the organic layer with water, and then conducting vacuum distillation.