Patent ID: 6255369
Filing Date: 2001-07-03
Classification: C08G,C08L,C09J,Y10T

Abstract:
A water-resistant, viscosity stable, alkaline curing starch-based corrugating adhesive composition comprising:a) from about 10 to 40% by weight, based on the total weight of the adhesive, of starch;b) from about 0.3 to 5% by weight, based on the total weight of starch, of an alkali;c) from about 0.3 to 12% by weight , dry basis, based on the weight of starch, of a crosslinking additive prepared by reacting a ketone and formaldehyde in a molar ratio of 1 mole of ketone to about 1.5 to 6 moles of formaldehyde under aqueous alkaline conditions at about 20 to 80.degree. C. to obtain a water-soluble ketone-formaldehyde condensate containing about 1 to 4% by weight of unreacted formaldehyde and wherein from about 2 to 6.5 parts by weight of a water-soluble alkali metal or alkaline earth metal sulfite per part by weight of unreacted formaldehyde is added to the condensate to react with the unreacted formaldehyde present and allowing the reaction to proceed at about 20 to 45.degree. C. at a pH of about 5 to 9 until the unreacted formaldehyde is reduced to less than about 0.6% by weight, based on the weight of condensate; andd) form about 54 to 89% by weight of water, based on the total weight of the adhesive wherein the viscosity of the adhesive composition does not increase more than 32% over 24 hours.