Patent ID: 6521649
Filing Date: 2003-02-18
Classification: A01N,C07D

Abstract:
A method for controlling agricultural and horticultural diseases of plants which comprises applying a 1,2,3 thiadiazole derivative represented by the general formula (I), or a salt thereof at an active amount to control said plant diseases: wherein R1 is {circle around (1)} a hydrogen atom, {circle around (2)} a (C1-C12)alkyl group, {circle around (3)} a halo(C1-C12)alkyl group, {circle around (4)} a (C2-C12)-alkenyl group, {circle around (5)} a halo(C2-C12)alkenyl group, {circle around (6)} a (C2-C12)alkynyl group, a halo(C2-C12)alkynyl group, {circle around (8)} a (C3-C6)cycloalkyl group, {circle around (9)} an unsubstituted phenyl group, {circle around (10)} a substituted phenyl group having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups, {circle around (11)} a group represented by the formula: (wherein R3 and R4, which may be the same or different, are hydrogen atoms, (C1-C12)alkyl groups or halo(C1-C12)alkyl groups, m is zero or an integer of 1 to 6, and R5 is a hydrogen atom; a (C1-C12)alkyl group; a halo(C1-C12)alkyl group; a (C2-C12)alkenyl group; a (C2-C12)alkynyl group; an unsubstituted phenyl group; a substituted phenyl group having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups; an unsubstituted phenyl(C1-C6)alkyl group; or a substituted phenyl(C1-C6)alkyl group having on the ring one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups), {circle around (12)} a group represented by the formula: (wherein R3, R4 and m are as defined above, and R6 and R7, which may be the same or different, are hydrogen atoms; (C1-C12)alkyl groups; halo(C1-C12)alkyl groups; (C2-C12)alkenyl groups; (C2-C12)alkynyl groups; (C1-C12)alkoxy(C1-C6)alkyl groups; (C1-C12)alkylthio (C1-C6)alkyl groups; cyano(C1-C12)alkyl groups; unsubstituted phenyl groups; substituted phenyl groups having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups; unsubstituted phenyl(C1-C6)alkyl groups; or substituted phenyl(C1-C6)alkyl groups having on the ring one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups; R6 and R7 being able to be taken together to represent a (C4-C6)alkylene group which may contain an oxygen atom between adjacent carbon atoms of the carbon chain), {circle around (13)} a group represented by the formula: (wherein R3, R4, R6 and R7 are as defined above, and n is an integer of 1 to 6), or {circle around (14)} a group represented by the formula: {{wherein R3, R4 and n are as defined above, A is (wherein R9 is a hydrogen atom, a (C1-C12)alkyl group or a halo(C1-C12)alkyl group), {wherein R9 is as defined above, and R10 is a hydrogen atom, a (C1-C12)alkyl group or a halo(C1-C12)alkyl group, R9 and R10 being able to be taken together to represent a (C4-C6)alkylene group which may contain, between adjacent carbon atoms of the carbon chain, an oxygen atom, a sulfur atom orNâ€”R11 (wherein R11 is a hydrogen atom, a (C1-C12)alkyl group or a halo(C1-C12)alkyl group)}, orâ€ƒâ€”N(R10)(wherein R10 is as defined above), and R8 is a hydrogen atom; a (C1-C12)alkyl group; a halo(C1-C12)alkyl group; a (C2-C12)alkenyl group; a (C2-C12)alkynyl group; a (C1-C12)alkoxy(C1-C12)alkyl group; a (C1-C12)alkylthio-(C1-C12)alkyl group; a cyano(C1-C12)alkyl group; an unsubstituted phenyl group; a substituted phenyl group having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups; an unsubstituted phenyl(C1-C6)-alkyl group; a substituted phenyl(C1-C6)alkyl group having on the ring one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkyl-thio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups; an unsubstituted 5- or 6-membered heterocyclic ring having one or more heteroatoms which may be the same or different and are selected from the group consisting of oxygen atom, sulfur atom and nitrogen atom; or a substituted 5- or 6-membered heterocyclic ring having one or more heteroatoms which may be the same or different and are selected from the group consisting of oxygen atom, sulfur atom and nitrogen atom, said substituted heterocyclic ring having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkyl-thio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups}}, and R2 is (i) a group represented by the formula:â€”Xâ€”R12 wherein X is an oxygen atom or a sulfur atom, and R12 is {circle around (1)} a hydrogen atom, {circle around (2)} a (C1-C12)alkyl group, {circle around (3)} a halo(C1-C12)alkyl group, {circle around (4)} a (C2-C20)alkenyl group, {circle around (5)} a halo(C2-C20)alkenyl group, {circle around (6)} a (C2-C12)alkynyl group, {circle around (7)} a halo(C2-C12)alkynyl group, {circle around (8)} a hydroxy(C1-C6)alkyl group, {circle around (9)} a (C1-C12)alkoxy(C1-C12)alkyl group, {circle around (10)} a (C1-C12)alkylthio(C1-C12)alkyl group, {circle around (11)} a (C3-C6)cycloalkyl group, {circle around (12)} a (C3-C6)cycloalkyl(C1-C12)alkyl group, {circle around (13)} an unsubstituted phenyl group, a substituted phenyl group having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkyl-thio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups, (C2-C6)alkynyl groups, and (C1-C6)alkoxy carbonyl(C1-C6)alkyloxy groups {circle around (15)} an unsubstituted phenyl(C1-C6)alkyl group, {circle around (16)} a substituted phenyl (C1-C6)alkyl group having on the ring one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups, {circle around (17)} a diphenyl(C1-C6)alkyl group, {circle around (18)} a phenoxy(C1-C6)alkyl group, {circle around (19)} a group represented by the formula:â€”Bâ€”N(R13)R14 {wherein B is a (C1-C6)alkylene group which may be substituted by a (C1-C6)alkyl group or a phenyl group, and R13 and R14, which may be the same or different, are hydrogen atoms; formyl groups; (C1-C12)alkyl groups; (C2-C12)alkenyl groups; (C2-C12)alkynyl groups;(C2-C12)-alkylcarbonyl groups; unsubstituted phenyl groups; substituted phenyl groups having one or more substituents which may be the same or different and are selected from the group consisting of hydrogen atom, halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl, groups; phenylcarbonyl groups; unsubstituted 1,2,3-thiadiazol-5-yl-carbonyl groups; or substituted 1,2,3-thiadiazol-5-yl-carbonyl groups having a halogen atom or a (C1-C6)alkyl group as the substituent; R13 and R14 being able to be taken together to represent a (C4-C5)alkylene group which may contain, between adjacent carbon atoms of the carbon chain, an oxygen atom, a sulfur atom orâ€ƒNâ€”R11 (wherein R11 is as defined above)), {circle around (20)} a group represented by the formula:â€”C(R15)&boxH;C(R16)â€”R17 (wherein R15 is a hydrogen atom or a (C1-C6)alkyl group, R16 is a hydrogen atom, a halogen atom or a (C1-C6)alkyl group, and R17 is a nitro group, a cyano group, a (C1-C6)alkylcarbonyl group, a (C1-C6)alkoxycarbonyl group, a phenylcarbonyl group, or a substituted aminocarbonyl group having one or more substituents which may be the same or different and are selected from the group consisting of hydrogen atom, (C1-C12)alkyl groups, unsubstituted phenyl group, and substituted phenyl groups having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, cyano group, nitro group, (C1-C6)alkyl groups and (C1-C6)alkoxy groups, R15 and R17 being able to be taken together to represent a (C3-C4)alkylene group which may be substituted by one or more (C1-C6)alkyl group and/or an oxo group), {circle around (21)} a group represented by the formula: (wherein two R18's which may be the same or different, are hydrogen atoms, (C1-C6)alkylcarbonyl groups, phenylcarbonyl groups, unsubstituted 1,2,3-thiadiazol-5-yl-carbonyl groups, or substituted 1,2,3-thiadiazol-5yl-carbonyl groups having a halogen atom or a (C1-C6)alkyl group as the substituent, and l is zero or an integer of 1 to 12), {circle around (22)} a 5- or 6-membered heterocyclic alkyl group having one or more heteroatoms which may be the same or different and are selected from the group consisting of oxygen atom, sulfur atom and nitrogen atom, {circle around (23)} tri(C1-C6)alkylsilyl(C1-C6)alkyl groups, or {circle around (24)} 1,2,3-thiadiazol-5-yl-carbonyloxy-(C1-C12)alkyl groups having on the ring a halogen atom or (C1-C6)alkyl group as the substituent {circle around (25)} (C1-C6)alkylcarbonyl(C1-C6)alkyol groups or {circle around (26)} (C1-C6)alkoxy-carbonyl(C1-C6)alkyl groups}}, (ii) a group represented by the formula:â€”Oâ€”N&boxH;C(R19)R20 {{wherein R19 and R20, which may be the same or different, are {circle around (1)} hydrogen atoms, {circle around (2)} halogen atoms, {circle around (3)} nitro groups, {circle around (4)} cyano groups, {circle around (5)} (C1-C12)alkyl groups, {circle around (6)} halo(C1-C12)alkyl groups, {circle around (7)} (C3-C6)cycloalkyl groups, {circle around (8)} (C2-C12)alkenyl groups, {circle around (9)} (C2-C12)alkynyl groups, {circle around (10)} (C1-C12)alkoxy(C1-C12)alkyl groups, {circle around (11)} (C1-C12)alkoxycarbonyl groups, {circle around (12)} unsubstituted phenyl groups, {circle around (13)} substituted phenyl groups having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio, groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups, {circle around (14)} unsubstituted 5- or 6-membered heterocyclic rings having one or more heteroatoms which may be the same or different and are selected from the group consisting of oxygen atom, sulfur atom and nitrogen atom, {circle around (15)} substituted 5- or 6-membered heterocyclic rings having one or more heteroatoms which may be the same or different and are selected from the group consisting of oxygen atom, sulfur atom and nitrogen atom, said substituted heterocyclic ring having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups, {circle around (16)} groups represented by the formula;â€”SR5 (wherein R5 is as defined above), or {circle around (17)} groups represented by the formula:â€”N(R6)R7 (wherein R6 and R7 are as defined above), R19 and R20 being able to be taken together to represent {circle around (18)} a (C3-C6)cycloalkane ring or a 5- or 6-membered heterocyclic ring containing, between adjacent carbon atoms of the carbon chain, one or more hetero atoms which may be the same or different and are selected from the group consisting of oxygen atom, sulfur atom and nitrogen atom}}, (iii) a group represented by the formula:â€”N(R21)R22 {{wherein R21 and R22, which may be the same or different, are, {circle around (2)} (C1-C12)alkyl groups, {circle around (3)} unsubstituted halo(C1-C12)alkyl groups, {circle around (4)} substituted halo(C1-C12)alkyl groups having a hydroxyl group or a (C1-C6)alkoxy group as the substituent, {circle around (5)} (C2-C12)alkenyl groups, {circle around (6)} (C2-C12)alkynyl groups, {circle around (7)} (C1-C12)alkoxy(C1-C6)alkyl groups, {circle around (8)} (C1-C12)alkylthio-(C1-C6)alkyl groups, {circle around (9)} cyano(C1-C12)alkyl groups, {circle around (10)} substituted cyano(C1-C6)alkyl groups having on the alkyl chain a substituent selected from the group consisting of (C1-C6)alkoxy groups, (C2-C6)alkenyloxy groups, (C2-C6)alkynyloxy groups, (C1-C6)alkylthio groups, (C1-C6)alkoxycarbonyl(C1-C6)alkoxy groups, (C1-C6)alkoxycarbonyl(C1-C6)alkylthio groups, phenoxy group, phenylthio group and pyrazol-1-yl group, {circle around (11)} unsubstituted carbamoyl(C1-C6)alkyl groups, {circle around (12)} substituted carbamoyl(C1-C6)alkyl groups having on the alkyl chain a substituent selected from the group consisting of (C1-C6)alkoxy groups, (C2-C6)alkenyloxy groups, (C2-C6)alkynyloxy groups, (C1-C6)alkylthio groups, (C1-C6)alkoxycarbonyl(C1-C6)alkoxy groups, (C1-C6)alkoxycarbonyl(C1-C6)alkylthio groups, phenoxy group, phenylthio group and pyrazol-1-yl group, {circle around (13)} hydroxy (C1-C6)alkyl groups, di(C1-C6)alkoxy(C1-C6)alkyl groups in which the (C1-C6)alkoxy groups may be the same or different, {circle around (15)} unsubstituted (C1-C6)alkoxycarbonyl(C1-C6)alkyl groups, {circle around (16)} substituted (C1-C6)alkoxy-carbonyl(C1-C6)alkyl groups having on the alkyl chain a substituent selected from the group consisting of (C1-C6)alkyl groups, (C1-C6)alkoxy groups, (C2-C6)alkenyloxy groups, (C2-C6)alkynyloxy groups, (C1-C6)alkylthio groups, (C1-C6)alkoxycarbonyl(C1-C6)alkoxy groups, (C1-C6)alkoxycarbonyl(C1-C6)alkylthio groups, phenyl group, phenyl(C1-C6)alkyl group, phenoxy group, phenylthio group and pyrazol-1-yl group, unsubstituted phenyl groups, {circle around (7)} substituted phenyl groups having one or more substituents which may be the same or different and are selected from the group consisting of 2) nitro group, 3) cyano group, 5) halo(C1-C6)alkyl groups, 6) (C1-C6)alkoxy groups, 7) halo(C1-C6)alkoxy groups, 8) (C1-C6)alkylthio groups, 9) halo(C1-C6)alkylthio groups, 10) (C2-C6)alkenyl groups, 11) (C2-C6)alkynyl groups, 12) (C1-C6)alkylcarbonyl groups, 13) carboxyl group, 14) (C1-C12)alkoxycarbonyl groups, 15) methylenedioxy group, 16) phenyl group, 17) groups represented by the formula: (wherein R23 and R24, which may be the same or different, are hydrogen atoms; (C1-C12)alkyl groups; halo(C1-C12)alkyl groups; (C2-C12)alkenyl groups; (C2-C12)alkynyl groups; unsubstituted phenyl groups; substituted phenyl groups having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, cyano group, nitro group, (C1-C6)alkyl groups and (C1-C6)alkoxy groups; or 5- or 6-membered heterocyclic rings containing, between adjacent carbon atoms of the carbon chain, one or more hetero atoms which may be the same or different and are selected from the group consisting of oxygen atom, sulfur atom and nitrogen atom), 18) groups represented by the formula:â€”SO2â€”R25 (wherein R25 is a hydrogen atom, hydroxyl group, a (C1-C12)alkyl group, a halo(C1-C6)alkyl group, an unsubstituted phenyl group, a substituted phenyl group having as the substituent(s) one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, (C1-C6)alkyl groups and (C1-C6)alkoxy groups, unsubstituted 1,2,3 thiadiazol-5-yl group, or substituted 1,2,3-thiadiazol-5-yl groups having halogen atom, (C1-C6)alkyl group or (C1-C6)alkoxy group as the substituent), 19) groups represented by the formula: (wherein R25 is as defined above), 20) groups represented by the formula: (wherein R26 is a (C1-C6)alkyl group, a phenyl group or a phenyl(C1-C6)alkyl group), 21) groups represented by the formula:â€”NHâ€”SO2â€”R25 (wherein R25 is as defined above), 22) groups represented by the formula: (wherein R25 is as defined above), and 23) groups represented by the formula: (wherein R26 is as defined above), 24) amino group, 25) (C1-C6)alkylureid groups, and 26) hydroxy group, {circle around (20)} substituted phenyl(C1-C6)-alkyl groups having on the ring one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups, {circle around (20)}-1 phenylaminocarbonyl(C1-C6)alkyl groups and {circle around (20)}-2 substituted phenylaminocarbonyl(C1-C6)alkyl groups having on the ring one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, (C1-C6)alkyl groups and (C1-C6)alkoxy groups, {circle around (21)} naphthyl groups, {circle around (22)} groups represented by the formula:â€”(CH2)pNHR18 (wherein R18 is as defined above, and p is an integer of 1 to 12), or {circle around (23)} 5- or 6-membered heterocyclic rings having one or more hetero atoms which may be the same or different and are selected from the group consisting of oxygen atom, sulfur atom and nitrogen atom, R21 and R22 being able to be taken together to represent {circle around (24)} a (C4-C6)alkylene group which may contain an oxygen atom between adjacent carbon atoms of the carbon chain, or {circle around (25)} a diaminomethylene group}}, (iv) a group represented by the formula:â€”N(R6)NHR27 {{wherein R6 is as defined above, and R27 is {circle around (1)} a hydrogen atom, {circle around (2)} a (C1-C12)alkyl group, {circle around (3)} a halo(C1-C12)alkyl group, {circle around (4)} a (C2-C12)alkenyl group, {circle around (5)} a (C2-C12)alkynyl group, {circle around (6)} a (C1-C12)alkoxy(C1-C6)alkyl group, {circle around (7)} a (C1-C12)alkylthio(C1-C6)alkyl group, {circle around (8)} a cyano(C1-C12)alkyl group, {circle around (9)} an unsubstituted phenyl group, {circle around (10)} a substituted phenyl group having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups, {circle around (11)} an unsubstituted phenyl(C1-C6)alkyl group, {circle around (12)} a substituted phenyl(C1-C6)alkyl group having on the ring one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C1-C6)alkylthio groups, halo(C1-C6)alkylthio groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups, {circle around (13)} a group represented by the formula: (wherein R6 is as defined above), {circle around (14)} a group represented by the formula: (wherein R6 is as defined above), {circle around (15)} a group represented by the formula: (wherein R6 and R7 are as defined above), or {circle around (16)} a group represented by the formula:â€”SO2â€”R6 (wherein R6 is as defined above)}}, (v) a group represented by the formula:â€”NHN(R6)R27 {{wherein R6 and R27 are as defined above, R6 and R27 being able to be taken together to represent&boxH;C(R28)R29 (wherein R28 and R29, which may be the same or different, are hydrogen atoms; (C1-C6)alkyl groups; halo(C1-C6)alkyl groups; (C3-C6)cycloalkyl groups; unsubstituted phenyl groups; substituted phenyl groups having one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, (C1-C6)alkyl groups and (C1-C6)alkoxy groups; or 5- or 6-membered heterocyclic rings containing, between adjacent carbon atoms of the carbon chain, one or more hetero atoms which may be the same or different and are selected from the group consisting of oxygen atom, sulfur atom and nitrogen atom; R28 and R29 being able to be taken together to represent a (C3-C6)cycloalkane ring or a 5- or 6-membered heterocyclic ring containing one or more sulfur atoms between adjacent carbon atoms of the carbon chain), or R6 and R27 being able to be taken together with the nitrogen atom to which they are bonded, to represent a 5- or 6-membered heterocyclic ring which may contain, between adjacent carbon atoms of the carbon chain, one or more hetero atoms which may be the same or different and are selected from the group consisting of oxygen atom, sulfur atom and nitrogen atom}}, or (vi) a group represented by the formula:â€”N(R6)â€”OR30 (wherein R6 is as defined above, and R30 is a hydrogen atom, a (C1-C12)alkyl group, a halo(C1-C12)alkyl group, a (C3-C6)cycloalkyl group, a (C2-C12)alkenyl group, a (C2-C12)alkynyl group, an unsubstituted phenyl(C1-C6)-alkyl group, or a substituted phenyl(C1-C6)alkyl group having on the ring one or more substituents which may be the same or different and are selected from the group consisting of halogen atoms, nitro group, cyano group, (C1-C6)alkyl groups, halo(C1-C6)alkyl groups, (C1-C6)alkoxy groups, halo(C1-C6)alkoxy groups, (C2-C6)alkenyl groups and (C2-C6)alkynyl groups).