Patent ID: 6331506
Filing Date: 2001-12-18
Classification: A01N,C07D

Abstract:
A compound of the formula (I) or a salt thereof ##STR43##in whichR.sup.1 is H or a hydrocarbon radical which is unsubstituted or substituted, or a heterocyclyl radical which is unsubstituted or substituted, where each of the last two-mentioned radicals including substituents has 1 to 20 carbon atoms,R.sup.2 and R.sup.3 for the definition of R.sup.2 and R.sup.3 one of the following combinations a, b, or c applies:a) R.sup.2 is CN, NO.sub.2 or acyl andR.sup.3 is CN, NO.sub.2, acyl, CF.sub.3, a substituted or unsubstituted monocyclic, bicyclic or polycyclic aryl radical having from 6 to 20 carbon atoms including substituents, or a substituted or unsubstituted heterocycle,b) CR.sup.2 R.sup.3 together form a ring having 3 to 8 ring atoms which is carbocyclic or heterocyclic and has one heteroatom selected from the group consisting of O, N, S, SO, or SO.sub.2 or is a heterocycle selected from the group consisting of piperidyl, piperazinyl, dioxolanyl, morpholinyl; or from the following heterocyclic rings: ##STR44##whereinsaid rings have at least one carbon atom substituted by an oxo group in a position adjacent to the carbon atom in 1-position of the CR.sup.2 R.sup.3 and is optionally further substituted by one or more radicals selected from the group consisting of (C.sub.1 -C.sub.4)alkyl, (C.sub.1 -C.sub.4)haloalkyl, halogen, and oxo;c) R.sup.2 is NO.sub.2 or [(C.sub.1 -C.sub.4)alkyl]carbonyl andR.sup.3 is H or (C.sub.1 -C.sub.4)alkyl,R.sup.4 is H or an aliphatic hydrocarbon radical having 1 to 6 carbon atoms in the hydrocarbon moiety where the last-mentioned radical is unsubstituted or substituted by one or more radicals are selected from the group consisting of halogen, (C.sub.1 -C.sub.4)alkoxy, (C.sub.1 -C.sub.4)alkylthio, (C.sub.1 -C.sub.4)alkylsulfonyl, [(C.sub.1 -C.sub.4)alkyl]carbonyl, [(C.sub.1 -C.sub.4)alkoxy]carbonyl, CN, substituted or unsubstituted phenyl, unsubstituted or substituted (C.sub.3 -C.sub.6)cycloalkyl, (C.sub.3 -C.sub.6)alkenyl or (C.sub.3 -C.sub.6)alkynyl or an acyl radical,R.sup.5 is H, halogen, NO.sub.2, CN, (C.sub.1 -C.sub.4)alkyl, (C.sub.1 -C.sub.4)alkoxy, [(C.sub.1 -C.sub.4)alkyl]carbonyl or [(C.sub.1 -C.sub.4)alkoxy]carbonyl, where each of the four last-mentioned radicals is unsubstituted or substituted in the alkyl moiety by one or more halogen atoms,R.sup.6 is H or (C.sub.1 -C.sub.4)alkyl,W is an oxygen or sulfur atom,X, Y independently of one another are H, halogen, (C.sub.1 -C.sub.4)alkyl, (C.sub.1 -C.sub.4)alkoxy, (C.sub.1 -C.sub.4)alkylthio, where each of the 3 last-mentioned radicals is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C.sub.1 -C.sub.4)alkoxy and (C.sub.1 -C.sub.4)alkylthio, or is mono- or di[(C.sub.1 -C.sub.4)alkyl]amino, (C.sub.3 -C.sub.6)cycloalkyl, (C.sub.2 -C.sub.5)alkenyl, (C.sub.3 -C.sub.5)alkynyl, (C.sub.3 -C.sub.5)alkenyloxy or (C.sub.2 -C.sub.5)alkynyloxy andZ is CH,and whereinsaid substituents for the hydrocarbon or aryl radicals, unless otherwise defined, are halogen, alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy, haloalkoxy, alkylthio, hydroxyl, amino, nitro, carboxyl, cyano, azido, alkoxycarbonyl, alkylcarbonyl, formyl, carbamoyl, mono- and dialkylamninocarbonyl, acylamino, mono- and dialkylamino, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloakylsulfonyl, haloalkyl, haloalkenyl, haloalkynyl, alkenyloxy, alkynyloxy, phenoxy, optionally substituted aryl, and optionally substituted heterocycle,heterocycle, unless otherwise defined, is a saturated or unsaturated ring having from 3 to 7 ring atoms having one ring atom selected from the groups consisting of N, O, S, SO, and SO.sub.2 or is a heteroaromatic radical having 5 or 6 ring atoms having one ring atom selected from the group consisting of N, O or S; or is a heterocycle selected from the group consisting of pyrimidinyl, pyradazinyl, pyrazinyl, thiazole, oxazole, pyrazolyl, imidazole, piperidyl, piperazinyl, dioxolanyl and morpholinyl; andthe substituents for the heterocyclic groups are the same as identified above for the hydrocarbon and the aryl radicals or oxo; andacyl is a formyl or is a radical of an organic acid having 1 to 20 carbon atoms, said radical being optionally substituted by the hydrocarbyl or aryl substituents, identified above, and is selected from the group consisting of carboxylic acid, thiocarboxylic acid, N-substituted iminocarboxylic acid, carbonic monoesters, N-substituted carbamic acid, sulfonic acid, sulfinic acid, phosphonic acid, and phosphinic acid.