Patent ID: 6717013
Filing Date: 2004-04-06
Classification: C07C,C07D

Abstract:
An aniline compound represented by the formula (I) wherein R1 denotes a hydrogen atom, R2 denotes a hydrogen atom, (C1-12)alkyl group, (C3-8)cycloalkyl group, hydroxy (C1-12)alkyl group, hydroxycarbonyl (C1-12) alkyl group, (C1-6)alkoxycarbonyl (C1-6)alkyl group, â€”COR8 (wherein R8 is a hydrogen atom, (C1-12)alkyl group, halo(C1-12)alkyl group, (C3-8)cycloalkyl group, phenyl group or phenyl group substituted with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, hydroxyl group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6)alkoxy group, halo(C1-6)alkoxy group, carboxyl group and (C1-6) alkoxycarbonyl group) or COOR9 (wherein R9 is a (C1-6)alkyl group, halo(C1-6)alkyl group, phenyl group, phenyl group substituted with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, hydroxyl group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6) alkoxy group, halo (C1-6) alkoxy group, carboxyl group and (C1-6)alkoxycarbonyl group, benzyl group or benzyl group substituted on the ring with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, hydroxyl group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6)alkoxy group, halo (C1-6)alkoxy group, carboxyl group and (C1-6)alkoxy-carbonyl group);R3, R4, R6 and R7 are the same or different and each denote a hydrogen atom, halogen atom, hydroxyl group, (C1-12)alkyl group, halo(C1-12)alkyl group, halo(C1-12)alkoxy group, (C1-12)alkylthio group, halo(C1-12)alkylthio group, (C1-6)alkylthio (C1-6)alkyl group, hydroxy(C1-6) alkyl group, amino (C1-6) alkyl group, amino(C1-6)alkyl group substituted with one or two (C1-6)alkyl groups which are the same or different, phenyl group, phenyl group substituted with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, halogen atom, (C1-6)alkyl group, halo (C1-6)alkyl group, (C1-6)alkoxy group and halo (C1-6)alkoxy group, phenoxy group, phenoxy group substituted with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6)alkoxy group, and halo (C1-6)alkoxy group, benzyl group, benzyl group substituted on the ring with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6)alkoxy group and halo(C1-6)alkoxy group, â€”N(R10 )R11 (wherein R10 andR11 are the same or different and are each a hydrogen atom, (C1-12)alkyl group, (C1-6)cycloalkyl group, phenyl group, phenyl group substituted with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, hydroxyl group, halogen atom, (C1-6)alkyl group, halo (C1-6)alkyl group, (C1-6)alkoxy group, halo(C1-6)alkoxy group, carboxyl group and (C1-6)alkoxycarbonyl group, benzyl group, benzyl group substituted on the ring with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, hydroxyl group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6) alkoxy group, halo (C1-6) alkoxy group, carboxyl group and (C1-4)alkoxycarbonyl group, â€”COR8, wherein R8 as the same meaning as defined above, or â€”COOR9, wherein R9 as the same meaning as defined above, further R10 and R11 conjointly form a (C3-6)alkylene group), or (C2-27)perfluoroalkyl group; and further, R1 or R2 and R3 or R7 conjointly form a (C2-4)alkylene group, and R3, R4, R5, R6 and R7 form, with their two adjacent substituents joined together, a (C3-5)alkylene group or (C1-2)alkylenedioxy group, and R5 denotes, a straight-chained (C2-27)perfluoroalkyl group; provided that (1) when R1, R2, R4 and R7 are each a hydrogen atom, R3 is a fluorine atom and R6 is a hydrogen atom, fluorine atom or chlorine atom, or when R1, R2, R4 and R7 are each a hydrogen atom, R7 is a fluorine atom and R4 is a hydrogen atom, fluorine atom or chlorine atom, then R5 not be a pentafluoroethyl group or heptafluoro-n-propyl group, (2) when R1 andR2 are each a hydrogen atom, R3 is a methyl group and R4, R6 and R7 are simultaneously each a hydrogen atom, or when R1 and R2 are each a hydrogen atom, R7 is a methyl group and R3, R4 and R6 are simultaneously each a hydrogen atom, then R5 must not be a pentafluoroethyl group, heptafluoropropyl group or nonafluoro-n-butyl group, (3) when R1, R2, R4, R6 and R7 are simultaneously each a hydrogen atom and R3 is a chlorine atom or when R1, R2, R3, R4 and R6 are simultaneously each a hydrogen atom and R7 is chlorine atom, then R5 must not be a pentafluoroethyl group, heptafluoropropyl group or nonafluoro-n-butyl group, (4) when R1, R2, R4, R6 and R7 are simultaneously each a hydrogen atom and R3 is an ethyl group, n-butyl group, trifluoromethyl group or pentafluoroethyl group, or when R1, R2, R3, R4 and R6 are simultaneously each a hydrogen atom and R7 is an ethyl group, n-butyl group, trifluoromethyl group or pentafluoroethyl group, then R5 must not be a pentafluoroethyl group, (5) when R1, R2, R3, R4, R6 and R7 are simultaneously each a hydrogen atom, then R5 must not be a perfluoro-n-(C2-8)alkyl group, and (6) when R1 is an acetyl group and R2, R3, R4, R6 and R7 are each a hydrogen atom, then R5 must not be a pentafluoroethyl groups.