Patent ID: 8828527
Filing Date: 2014-09-09
Classification: C23C,Y10T

Abstract:
1. A surface-coated cutting tool comprising: a tool substrate made of tungsten carbide-based cemented carbide or titanium carbonitride-based cermet; and a hard coating layer, which is formed by vapor-depositing in order, a lower layer (a), an intermediate layer (b), and an upper layer (c) on the surface of the tool substrate, wherein the lower layer (a) is a Ti compound layer composed of one or more of a titanium carbide layer, a titanium nitride layer, a titanium carbonitride layer, a titanium carboxide layer, and a titanium oxycarbonitride layer, all of which are formed by chemical vapor deposition, and having a total mean layer thickness of 3 to 20 μm, wherein the intermediate layer (b) is an aluminum oxide layer having a mean layer thickness of 1 to 5 μm and having an α-type crystal structure in a chemically vapor-deposited state, wherein the upper layer (c) is an aluminum oxide layer having a mean layer thickness of 2 to 15 μm and an α-type crystal structure in a chemically vapor-deposited state, the aluminum oxide layer containing one or more kinds of elements selected from a group consisting of Ti, Y, Zr, Cr, and B, wherein, the intermediate layer (b) has properties indicated by a tilt-angle frequency distribution graph in which the highest peak exists in a tilt angle division ranging 0 to 10° and the total sum of frequencies existing in the range of 0 to 10° occupies a ratio of 45% or more of the total frequencies in the tilt-angle frequency distribution graph, the tilt-angle frequency distribution graph being obtained by utilizing a field-emission-type scanning electron microscope, irradiating electron beams to individual crystal grains with a hexagonal crystal lattice existing in a measurement range of a polished surface of the tool substrate, measuring a tilt angle formed by the normal line to the polished surface and the normal line to (0001) plane as a crystal plane of the crystal grains, sectioning the measured tilt angles belonging to a range of 0 to 45° every pitch of 0.25°, and collecting the frequencies existing in each section, wherein, the upper layer (c) is an aluminum oxide layer having a texture made of crystal grains with a flat-plate polygonal shape within a plane perpendicular to a layer thickness direction and have an elongated shape in the layer thickness direction within a plane parallel to the layer thickness direction and containing one or more kinds of elements selected from a group consisting of Ti, Y, Zr, Cr, and B, the texture being observed by a field-emission scanning electron microscope, wherein, the upper layer (c) has properties indicated by a tilt-angle frequency distribution graph in which the highest peak exists in a tilt angle division ranging 0 to 10° and the sum of frequencies existing in the range of 0 to 10° occupies a ratio of 60% or more of the total frequencies in the tilt-angle frequency distribution graph, the tilt-angle frequency distribution graph being obtained by utilizing a field-emission-type scanning electron microscope, irradiating electron beams to individual crystal grains with a hexagonal crystal lattice existing in a measurement range of a polished surface of the tool substrate, measuring a tilt angle formed by the normal line to the polished surface and the normal line to (0001) plane as a crystal plane of the crystal grains, sectioning the measured tilt angles belonging to a range of 0 to 45° every pitch of 0.25°, and collecting the frequencies existing in each section, and wherein when electron beams are radiated to the individual crystal grains existing within a measurable range of a polished surface of the tool substrate by utilizing a field-emission-type scanning electron microscope and an electron backscatter diffraction imaging device to measure angles formed by normal lines of crystal lattice faces with hexagonal crystal lattices and the normal line to the polished surface, a crystallographic orientation relationship between the adjacent crystal lattices is calculated from the measurement result, and a distribution of lattice points (constituent atom sharing lattice points) in each constituent atom of a crystal lattice interface shares one constituent atom between the crystal lattices is calculated, and when a constituent atom sharing lattice point type in which N lattice points not sharing the constituent atom exist between the constituent atom sharing lattice points (where N is an even number of 2 or more in view of a crystal structure of corundum type hexagonal close packed crystal but does not include even numbers of 4, 8, 14, 24, and 26 when the upper limit of N is set to 28 in view of distribution frequency) is expressed as ΣN+1, the insides of the above mentioned crystal grains, which constitutes the upper layer (c) and occupies 60% or more as an area ratio in the crystal grains of the upper layer, are divided by at least one crystal lattice interface with the constituent atom sharing lattice point type expressed by Σ3, and the upper layer (c) contains one or more kinds of elements selected from a group consisting of Ti, Y, Zr, Cr, and B.