Patent ID: 9079931
Filing Date: 2015-07-14
Classification: B01J,C07F,C09B

Abstract:
1. A ruthenium complex represented by the following Formula (2) wherein Ru represents a ruthenium atom; X represents an anionic group; R a , R b , and R c each independently represent a hydrogen atom, an optionally substituted C 1 -C 20 alkyl group, an optionally substituted C 2 -C 20 alkenyl group, an optionally substituted C 3 -C 8 cycloalkyl group, an optionally substituted C 7 -C 20 aralkyl group, an optionally substituted aryl group or an optionally substituted heterocyclic group, and R b and R c may form an alkylene group or an alkylenedioxy group; R d , R e , R f and R g each independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, a halogenated alkyl group having 1 to 5 carbon atoms, a halogen atom, an optionally substituted aryl group, an optionally substituted C 3 -C 8 cycloalkyl group, a tri-substituted silyl group or an alkoxy group having 1 to 20 carbon atoms; R N1 , R N2 , R N3 and R N4 each independently represent a hydrogen atom, or an optionally substituted C 1 -C 20 alkyl group, and at least one of R N1 , R N2 , R N3 and R N4 represents a hydrogen atom, and R N1 and R a may form an alkylene group; and represents a diphosphine represented by the following Formula (4) wherein R 1 , R 2 , R 3 and R 4 each independently represent an optionally substituted aryl group, an optionally substituted cycloalkyl group or an optionally substituted alkyl group, and R 1 and R 2 and/or R 3 and R 4 may form a ring; and Q represents an optionally substituted divalent arylene group, biphenyldiyl group, binaphthalenediyl group, bipyridinediyl group, paracyclophanediyl group or ferrocenediyl group.