Patent ID: 6417386
Filing Date: 2002-07-09
Classification: A01N,C07C,C07D

Abstract:
A compound of the formula in whichA1 and A2 are phenyl; A1 is substituted with a substituent (R3a)n1 A2 with a substituent (R3b)n2; R1 is â€”CN; R2 is â€”OH, C1-C6alkyl, C1-C6alkoxy, C3-C6cycloalkyl, C3-C6alkenyl, C3-C6alkynyl, haloâ€”C1-C6alkyl, haloâ€”C3-C6alkenyl, haloâ€”C3-C6alkynyl, benzyl or benzoyl, in which the benzyl or benzoyl radical is unsubstituted or mono- to trisubstituted in the aromatic ring by substituents which are independent of one another and selected from the group consisting of halogen, â€”CN, NO2, C1-C6alkyl, C1-C6alkoxy, haloâ€”C1-C6alkyl and haloâ€”C1-C6alkoxy; C1-C6alkoxyâ€”C1-C6alkyl, cyanoâ€”C1-C6alkyl, â€”C(=X)â€”R7, â€”OC(=O)â€”R7, â€”C(=O)â€”C(=O)â€”R7, â€”S(=O)pN(R6)2 (in which the two R6 are independent of one another); cyano, â€”C1-C6alkylâ€”N(R10)â€”C(=O)â€”R8, â€”C1-C6alkylâ€”Sâ€”C(=S)â€”R8, â€”C2-C6alkylâ€”S(=O)pâ€”R9, â€”S(=O)pâ€”R9, or â€”CH2â€”N(R10)â€”SO2â€”R9; R3a is halogen, C1-C6alkyl, C2-C4alkenyl, C2-C4alkynyl, haloâ€”C1-C6alkyl, haloâ€”C2-C4alkenyl, haloâ€”C2-C4alkynyl, C1-C6alkoxy, haloâ€”C1-C6alkoxy, C2-C6alkenyloxy, C2-C6alkynyloxy, haloâ€”C2-C6alkenyloxy, haloâ€”C2-C6alkynyloxy, â€”OH, â€”SF5, â€”CHO, â€”C(=O)â€”C1-C6alkyl, â€”C(=O)â€”haloâ€”C1-C6alkyl, â€”C(=O)â€”OC1-C6alkyl, â€”C(=O)â€”Oâ€”haloâ€”C1-C6alkyl, â€”Oâ€”C(=O)N(R6)2 (in which the two R6 are independent of one another), â€”CN, â€”NO2, â€”S(=O)2N(R6)2 (in which the two R6 are independent of one another), â€”S(=O)pâ€”C1-C6alkyl, â€”S(=O)pâ€”haloâ€”C1-C6alkyl, â€”Oâ€”S(=O)p=C1-C6alkyl, â€”Oâ€”S(=O)pâ€”haloâ€”C1-C6alkyl, phenyl, benzyl, phenoxy or benzyloxy, each of the phenyl, benzyl, phenoxy or benzyloxy radicals being unsubstituted or mono- to penta- substituted in the aromatic ring by substituents which are independent of one another and selected from the group consisting of halogen, cyano, NO2, C1-C6alkyl, haloâ€”C1-C6alkyl, C1-C6alkoxy and haloâ€”C1-C6alkoxy; R3b is cyano or NO2; n1 is 2,3 or 4; n2 is 1 or 2; X is O or S; p is 0, 1 or 2; R5 radicals independently of one another are H or C1-C8alkyl; R6 radicals independently of one another are H, C1-C8alkyl, C3-C6cycloalkyl, phenyl or benzyl, the phenyl or benzyl group in the aromatic ring being unsubstituted or mono- to trisubstituted by substituents which are independent of one another and selected from the group consisting of halogen, â€”CN, NO2, C1-C6alkyl, C1-C4alkoxy, haloâ€”C1-C6alkyl and haloâ€”C1-C6alkoxy; or two alkyl radicals R6 together with the nitrogen atom to which they are bonded form a five- to seven-membered ring in which a CH2 group may be replaced by a hetero atom selected from the group consisting of O and S, or by NH, and where the five- to seven-membered ring is unsubstituted or mono- or disubstituted by C1-C4alkyl; R7 is H, C1-C8 alkyl, C2-C8alkenyl, haloâ€”C1-C8alkyl, haloâ€”C2-C8alkenyl, C1-C8alkoxy, haloâ€”C1-C8alkoxy, C3-C6cycloalkyl, phenyl, benzyl, phenoxy, benzyloxy or â€”N(R6)2(in which the two R6 are independent of one another); R8 is C1-C8alkyl, C1-C8alkoxy, haloâ€”C1-C8alkyl, haloâ€”C1-C8alkoxy, C1-C8alkylthio, phenyl, benzyl or â€”N(R6)2 (in which the two R6 are independent of one another); R9 is C1-C6alkyl, haloâ€”C1-C4alkyl or aryl which is unsubstituted or mono- to trisubstituted by substituents which are independent of one another and selected from the group consisting of C1-C6alkyl, C2-C4alkenyl, C2-C4alkynyl, C1-C4alkoxy, halogen, cyano, haloâ€”C1-C4alkyl, haloâ€”C2-C4alkenyl, haloâ€”C2-C4alkynyl, haloâ€”C1-C4alkoxy and nitro; and R10 is H, C1-C6alkyl, C3-C6cycloalkyl, phenyl or benzyl, the phenyl and benzyl radicals being unsubstituted or mono- to trisubstituted in the aromatic ring by substituents which are independent of one another and selected from the group consisting of C1-C4alkyl, C1-C4alkoxy, halogen, cyano, haloâ€”C1-C4alkyl, haloâ€”C1-C4alkoxy and nitro; or, where appropriate, E/Z isomer, E/Z isomer mixtures and/or tautomers thereof, in each case in free form or in agrochemically utilizable salt form; with the proviso, that R3a is not 2-nitro.