Patent ID: 6391206
Filing Date: 2002-05-21
Classification: C23C

Abstract:
A method for recovery of aqueous wash in a phosphate chemical conversion of a shaped metal product involving carrying out chemical conversion and subsequent cleaning with water,wherein said cleaning with water is performed in one or more stages, said method comprising the steps of: withdrawing aqueous wash from a first cleaning stage and adjusting the pH of the wash with at least one acid selected from group consisting of phosphoric acid, nitric acid, hydrofluoric acid, hydrosilicofluoric acid and fluoroboric acid, treating said pH-adjusted aqueous wash with a first reverse osmosis membrane to separate it into a first filtrate and a first concentrate, and neutralizing said first filtrate with an alkali and treating the alkali-neutralized filtrate with a second reverse osmosis membrane to separate it into a second filtrate and a second concentrate, said first concentrate being recycled for said phosphate chemical conversion, said second filtrate being recycled as aqueous wash for cleaning, and said second concentrate being discarded from the system.