Patent ID: 9068102
Filing Date: 2015-06-30
Classification: B32B,C08L,C09D,Y10T

Abstract:
1. A laminated article comprising a substrate (III), a primer layer (II) provided on the substrate (III) and a top coat layer (I) provided directly on the primer layer (II), in which the top coat layer (I) is formed with a cured article of a top coat composition comprising (A) a curable fluorine-containing resin, (B) a curing agent and (C) a coupling agent comprising a functional group-containing silane coupling agent and/or an aluminum chelating agent, and the primer layer (II) is formed with a primer composition comprising (D) a polydiorganosiloxane, (E) a polyorganosiloxane resin and (F) a coupling agent comprising a functional group-containing silane coupling agent and/or an aluminum chelating agent, wherein (B) the curing agent is at least one curing agent selected from the group consisting of an isocyanate curing agent and an amino curing agent, the isocyanate curing agent being at least one selected from the group consisting of 2,4-tolylene diisocyanate, diphenylmethane-4,4′-diisocyanate, xylylene diisocyanate, isophorone diisocyanate, lysine methyl ester diisocyanate, methylcyclohexyl diisocyanate, trimethylhexamethylene diisocyanate, hexamethylene diisocyanate, n-pentane-1,4-diisocyanate, trimers thereof, adducts and biurets thereof, polymers thereof having at least two isocyanate groups, and blocked isocyanates; the amino curing agent being at least one selected from the group consisting of a melamine resin, urea resin, guanamine resin, amine adduct, and polyamide; wherein (D) the polydiorganosiloxane comprises repeating siloxane units of the formula R wherein (E) the polyorganosiloxane resin comprises siloxane units of the formula R wherein a molar ratio of the R wherein the substrate (III) is a silicone rubber substrate.