Patent ID: 6037502
Filing Date: 2000-03-14
Classification: C07C

Abstract:
An etherification process that resists deactivation, by nitriles, of its acidic-ion-exchange-resin catalyst, said process comprising:(a) contacting a First Isoolefin Stream, which comprises isoolefins, nitriles, and nonreactive compounds, with a First Water Stream, which comprises water, in a first contacting zone under conditions that produce a Second Isoolefin Stream and a Second Water Stream from said First Isoolefin Stream and said First Water Stream, where said Second Ether Stream comprises said isoolefins and said nonreactive compounds, and where said Second Water Stream comprises said water and said nitriles, and where said Second Isoolefin Stream is lean in said nitriles when compared with said First Isoolefin Stream, and where said Second Water Stream is rich in said nitriles when compared with said First Water Stream;(b) contacting said Second Isoolefin Stream with a First Alcohol Stream, which comprises alcohols, in an Isoolefin.backslash.Alcohol contacting zone where said Second Isoolefin Stream can come into contact with said First Alcohol Stream, to form a First Isoolefin.backslash.Alcohol Stream that comprises said isoolefins, said nonreactive compounds, and said alcohols;(c) contacting said First Isoolefin.backslash.Alcohol Stream with an acidic-ion-exchange-resin catalyst, in a second contacting zone under conditions that produce a First Ether Stream from said First Isoolefin.backslash.Alcohol Stream, where said First Ether Stream comprises unreacted isoolefins, unreacted alcohols, said nonreactive compounds, and ethers;(d) separating said First Ether Stream in a first separating zone under conditions that produce a Second Isoolefin.backslash.Alcohol Stream and a Second Ether Stream from said First Ether Stream, where said Second Isoolefin.backslash.Alcohol Stream comprises said unreacted isoolefins, said unreacted alcohols, and said nonreactive compounds, and said Second Ether Stream comprises said ethers, and where said Second Isoolefin.backslash.Alcohol Stream is lean in said ethers and said Second Isoolefin Stream is rich in said ethers;(e) contacting said Second Isoolefin.backslash.Alcohol Stream with said Second Water Stream in a third contacting zone under conditions that produce a First Alcohol.backslash.Water Stream and a Third Isoolefin Stream from said Second Isoolefin.backslash.Alcohol Stream and said Second Water Stream, where said Third Isoolefin Stream comprises said unreacted isoolefins and said nonreactive compounds, and where said First Alcohol.backslash.Water Stream comprises said unreacted alcohols, said water, and said nitriles;(f) separating said First Alcohol.backslash.Water Stream in a second separating zone under conditions that produce said First Water Stream and a First Nitrile Stream from said First Alcohol.backslash.Water Stream, where said First Nitrile Stream comprises said unreacted alcohols and said nitriles, and said First Water Stream comprises water, and where said First Nitrile Stream is rich in said nitriles and said First Water Stream is lean in said nitriles;(g) contacting said First Nitrile Stream with an Hydrogen Stream, which comprises hydrogen, in a Nitrile.backslash.Hydrogen contacting zone where said First Nitrile Stream can come into contact with said Hydrogen Stream, to form a Second Nitrile Stream, which comprises said unreacted alcohols, said nitriles, and said hydrogen;(h) contacting said Second Nitrile Stream with an Hydrogenation Catalyst System in a fourth contacting zone under conditions that produce a First Converted-Nitrile Stream from said Second Nitrile Stream, where said First Converted-Nitrile Stream comprises said unreacted alcohols and said converted nitriles.