Patent ID: 6331507
Filing Date: 2001-12-18
Classification: A01N,C07D,C07F

Abstract:
A substituted aromatic thiocarboxamide of the formula (I) ##STR197##whereinR.sup.1 represents hydrogen, fluorine, chlorine or bromine,R.sup.2 represents the following group--A.sup.1 --A.sup.2 --A.sup.3in whichA.sup.1 represents a single bond, or represents oxygen, sulphur, --SO--, --SO.sub.2 --, --CO-- or the group --N(A.sup.4)--, in which A.sup.4 represents hydrogen, hydroxyl, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.4 -alkenyl, C.sub.3 -C.sub.4 -alkinyl, C.sub.1 -C.sub.4 -alkoxy, phenyl, C.sub.1 -C.sub.4 -alkylsulphonyl or phenylsulphonyl,A.sup.1 additionally represents in each case optionally fluorine- or chlorine-substituted C.sub.1 -C.sub.6 -alkanediyl, C.sub.2 -C.sub.6 -alkenediyl, C.sub.2 -C.sub.6 -alkinediyl, C.sub.3 -C.sub.6 -cycloalkanediyl, C.sub.3 -C.sub.6 -cycloalkenediyl or phenylene,A.sup.2 represents a single bond, or represents oxygen, sulphur, --SO--, --SO.sub.2 --, --CO-- or the group --N(A.sup.4)--, in which A.sup.4 represents hydrogen, hydroxyl, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.4 -alkenyl, C.sub.3 -C.sub.4 -alkinyl, C.sub.1 -C.sub.4 -alkoxy, phenyl, C.sub.1 -C.sub.4 -alkylsulphonyl or phenylsulphonyl,A.sup.2 additionally represents in each case optionally fluorine- or chlorine-substituted C.sub.1 -C.sub.6 -alkanediyl, C.sub.2 -C.sub.6 -alkenediyl, C.sub.2 -C.sub.6 -alkinediyl, C.sub.3 -C.sub.6 -cycloalkanediyl, C.sub.3 -C.sub.6 -cycloalkenediyl or phenylene,A.sup.3 represents hydrogen, hydroxyl, amino, cyano, isocyano, thiocyanato, nitro, carboxyl, carbamoyl, thiocarbamoyl, sulpho, chlorosulphonyl, halogen, or represents in each case optionally halogen- or C.sub.1 -C.sub.4 -alkoxy-substituted alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylamino, dialkylamino, alkoxycarbonyl or dialkoxy(thio)phosphoryl having in each case 1 to 6 carbon atoms in the alkyl groups, or represents in each case optionally halogen-substituted alkenyl, alkenyloxy, alkenylamino, alkylideneamino, alkenyloxycarbonyl, alkinyl, alkinyloxy, alkinylamino or alkinyloxycarbonyl having in each case 2 to 6 carbon atoms in the alkenyl, alkylidene or alkinyl groups, or represents in each case optionally halogen-, cyano-, carboxyl-, C.sub.1 -C.sub.4 -alkyl- and/or C.sub.1 -C.sub.4 -alkoxy-carbonyl-substituted cycloalkyl, cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylideneamino, cycloalkyloxycarbonyl or cycloalkylalkoxycarbonyl having in each case 3 to 6 carbon atoms in the cycloalkyl groups and optionally 1 to 4 carbon atoms in the alkyl groups, or represents in each case optionally nitro-, cyano-, carboxyl-, halogen-, C.sub.1 -C.sub.4 -alkyl-, C.sub.1 -C.sub.4 -halogenoalkyl-, C.sub.1 -C.sub.4 -alkyloxy-, C.sub.1 -C.sub.4 halogenoalkyloxy- and/or C.sub.1 -C.sub.4 -alkoxy-carbonyl-substituted phenyl, phenyloxy, phenyl-C.sub.1 -C.sub.4 -alkyl, phenyl-C.sub.1 -C.sub.4 -alkoxy, phenyloxycarbonyl or phenyl-C.sub.1 -C.sub.4 -alkoxycarbonyl, (in each case optionally totally or partially hydrogenated) pyrrolyl, pyrazolyl, imidazolyl, triazolyl, furyl, thienyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridinyl, pyrimidinyl, triazinyl, pyrazolyl-C.sub.1 -C.sub.4 -alkyl, furyl-C.sub.1 -C.sub.4 -alkyl, thienyl-C.sub.1 -C.sub.4 -alkyl, oxazolyl-C.sub.1 -C.sub.4 -alkyl, isoxazole-C.sub.1 -C.sub.4 -alkyl, thiazole-C.sub.1 -C.sub.4 -alkyl, pyridinyl-C.sub.1 -C.sub.4 -alkyl, pyrimidinyl-C.sub.1 -C.sub.4 -alkyl, pyrazolylmethoxy or furylmethoxy, or represents perhydropyranylmethoxy or pyridylmethoxy,R.sup.3 represents hydrogen, fluorine, chlorine or bromine or together with R.sup.2 represents an alkanediyl or alkenediyl group having in each case up to 4 carbon atoms which optionally contains at the beginning (or end) or within the hydrocarbon chain an oxygen atom, a sulphur atom, an SO.sub.2 group, an NH group, an N--C.sub.1 -C.sub.4 -alkyl group, a carbonyl group and/or a thiocarbonyl group, andZ represents Z.sup.3 : ##STR198##or Z.sup.15 : ##STR199##whereinQ.sup.1 represents a group from the series --CO--, --CS--, --CH.sub.2 --, --CH(OH)--, --CHCl--, --CHBr--, --C(.dbd.CH.sub.2)--, --C(.dbd.CHF)--, --C(.dbd.CF.sub.2)--, --C(.dbd.CHCl)--, --C(.dbd.CHBr)--, --C(.dbd.CHOCHF.sub.2)--, --C (.dbd.CHOCF.sub.3)--, --C(.dbd.CHOCH.sub.2 CF.sub.3)--,R.sup.6 represents hydrogen, amino, nitro, cyano, carboxyl, carbamoyl, fluorine, chlorine, bromine, methyl, ethyl, n- or i-propyl, cyclopropyl, difluoromethyl, trifluoromethyl, chlorodifluoromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy, trifluoromethoxy, chlorodifluoro-methoxy, methylthio, ethylthio, n- or i-propylthio, difluoromethylthio, trifluoromethylthio, chlorodifluoromethylthio, methylamino, ethylamino, n- or i-propylamino, dimethylamino, diethylamino, methoxycarbonyl or ethoxycarbonyl, andR.sup.7 represents hydrogen, hydroxyl, amino, cyano, methyl, ethyl, n- or i-propyl, difluoromethyl, methoxy, ethoxy, n- or i-propoxy.