Patent ID: 6228885
Filing Date: 2001-05-08
Classification: A01N,C07B,C07C

Abstract:
A fungicidal composition, comprising:(a) A compound, which is (N-phenylacetyl-N-2,6-xylyl)methyl alaninate, having the formula (I): ##STR27##wherein more than 50% of said compound having the formula (I) consists of the levorotatory enantiomer; and(b) one or more fungicided compounds selected from the group consisting of(1) Cymoxanil, which is 1-(2-cyano-2-methoxyiminoacetyl)-3-ethyl-urea;(2) Fosetyl, having the formula: ##STR28##(3) Metalaxyl, which is methyl-N-(2-methoxyacetyl)-N-2,6-xylyl-DL-alaninate;(4) Oxadixyl, which is 2-methoxy-N-(2-oxo-1,3-oxazolidin-3-yl)-acet-2'-6'-xylidine;(5) Ofurace, which is DL-3-[N-chloroacetyl-N-(2,6-dimethylphenyl)-amino]-.gamma.-butyrolactone;(6) Fluazinam, which is 3-chloro-N-[3-chloro-2,6-dinitro-4-(trifluoromethyl)-phenyl]-5-trifluorome thyl-2-2-pyridinamine;(7) (E)-2-[2-([6-(2-cyanophenoxy)-pyrimidin-4-yloxy]-phenyl-3-methyl methoxyacrylate;(8) (E)-methoxyimino-.alpha.-o-tolyloxy)-o-tolyl]-methyl acetate;(9) N-methyl-(E)-methoxyimino-[2-(2,5-dimethyl-phenoxymethyl)-phenyl]acetamide ;(10) N-methyl-(E)-methoxyimino[2-phenoxyphenyl]acetamide;(11) O-(1-methylethyl)-N-[2-methyl-1-[[1-(4-chloro-phenyl)ethyl]-amino]-carbony l]-propyl]-carbamate;(12) O-(1-methylethyl)-N-[2-methyl-1-[[[1-(4-methyl-phenyl)ethyl]-amino]-carbon yl]-propyl]-carbamate;(13) O-(1-methylethyl)-N-[2-methyl-1-[[[1-(4-ethyl-phenyl)-ethyl]-amino]-carbon yl]-propyl]-carbamate;(14) O-(1-methylethyl)-N-[2-methyl-1-[[[1-(4-methoxyphenyl)-ethyl]-amino]-carbo nyl]-propyl]-carbamate;(15) O-(phenyl)-N-[2-methyl-1-[[[1-(4-methoxyphenyl)-ethyl]-amino]-carbonyl]-pr opyl]-carbamate;(16) dithiocarbamates having the formula: ##STR29##wherein M represents manganese or zinc;(17) Thiram, which is bis-(dimethyl-t-biocarbamoyl)-disulfide;(18) Propineb, having the formula: ##STR30##(19) Anilazine, which is N-(4,6-dichloro-1,3,5-triazin-2-yl)-aniline;(20) Dichlofluanid, having the formula: ##STR31##(21) Tolylfluanid, having the formula: ##STR32##(22) Captan, having the formula: ##STR33##(23) Folpet, having the formula: ##STR34##(24) Chlorothalonil, which is 1,3-dicyano-2,4,5,6-tetrachlorobenzene;(25) Dimethomorph, having the formula: ##STR35##(26) Flumetover, which is N,N-diethyl-amide of 4-trifluoromethyl-6-(3,4-dimethoxyphenyl)-benzoic acid;(27) Dithianon, which is 5,10-dihydro-5,10-dioxonaphthol-[2,3-b]-1,4-diethin-2,3-dicarbonitrile;(28) Tetraconazole, which is 1-(1H-1,2,4-triazol-1-yl)-2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroeth oxy)-propane;(29) Propiconazole, which is 1-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dixolan-2-yl-methyl]-1H-1,2,4-triaz ole;(30) Triadimefon, which is 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-butanone;(31) Triadimenol, which is 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol;(32) Bitertanol, which is 1-(diphenyl-4-yloxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-butan-2-ol;(33) Etridiazole, which is ethyl 3-trichloromethyl-1,2,4-thiadiazolyl ether;(34) Pencycuron, which is 1-(4-chlorobenzyl)-1-cyclopentyl-3-phenylurea;(35) Hymexanol, which is 5-methyl-soxazol-3-ol;(36) Protiocarb, which is S-ethyl-(3-dimethylaminopropyl)-thiocarbamate;(37) Propamocarb, which is propyl 3-(dimethylamino)-propylcarbamate;(38) salts of copper (I) or copper (II);(39) Andoprim; which is 2-p-methoxy-aniline-4,6-dimethyl-pyrimidine;(40) Famoxadone or DPX-HE874, which is 5-methyl-5-(4-phenoxyphenyl)-3-(phenylamino)-oxazolidin-2,4-dione;(41) 4-methyl-4-phenyl-1-(phenylamino)-2-methylthio-imidazolidin-5-one;(42) pyrimidinic compounds;(43) compounds having the following formula: ##STR36##wherein:R.sub.1 and R.sub.2, which are the same or different, each represents hydrogen; or C.sub.1 -C.sub.3 alkyl; or R.sub.1 and R.sub.2 together with the hydantoinic ring to which they are attached, represent a C.sub.3 -C.sub.7 saturated spiro ring;R.sub.3 and R.sub.4, which are different from each other, each represents C.sub.1 -C.sub.3 alkyl; phenyl group, said phenyl group optionally substituted with halogen, nitro, C.sub.1 -C.sub.3 alkoxyl, or C.sub.1 -C.sub.3 haloalkyl; or 3-iodo-propinyl;(44) compounds having the following formula: ##STR37##whereinR.sub.1 and R.sub.3, which are the same or different, each represents halogen; or C.sub.1 -C.sub.4 alkyl;R.sub.2 represents alky; alkenyl; C.sub.2 -C.sub.6 alkinyl; a C.sub.1 -C.sub.4 alkoxyl; cyano;R.sub.4 and R.sub.5, which are the same or different; each represents halogen; or C.sub.1 -C.sub.4 alkyl;with he proviso that at least one between R.sub.4 and R.sub.5, is alkyl;X represents halogen, thiocyano, or isothiocyano;(45) oligopeptidic compounds having the formula:K--[A].sub.z --[B].sub.w --Lwhereinz and w, which are the same or different, are 1 or 2;A represents an aminoacidic portion having the formula: ##STR38##wherein:R.sub.a represents linear or branched C.sub.3 -C.sub.4 alkyl; or C.sub.3 -C.sub.4 cycloalkyl;R' represents hydrogen; C.sub.1 -C.sub.3 alkyl; or, together with R.sub.a forms a linear or branched C.sub.3 -C.sub.5 alkylene chain;B represents an aminoacid portion having the formula: ##STR39##whereinR.sub.b represents phenyl or an aromatic heterocyclic group, said phenyl and heterocyclic groups, also being optionally substituted;m and n, which are the same or different, are 0 or 1;R"" represents hydrogen; or C.sub.1 -C.sub.3 alkyl;L represents a group having the formula: ##STR40##wherein:E represents a linear or branched C.sub.1 -C.sub.8 alkylene chain; a linear or branched C.sub.2 -C.sub.8.omega.-oxoalkyl chain; or a direct bond;R.sup.1 represents hydrogen; cycloalkyl; phenyl or an aromatic heterocyclic group; said phenyl and heterocyclic groups also being optionally substituted;R.sup.2 represents hydrogen; linear or branched C.sub.2 -C.sub.6 carboxyalkyl; linear or branched or cyclic C.sub.2 -C.sub.6 carbamoyl; or cyano;X represents --O--; --N(R.sup.3)--; or --N(R.sup.4)--O--; wherein:R.sup.3 represents hydrogen; C.sub.1 -C.sub.3 alkyl or alkoxyl; or, together with R.sub.1, represents a direct bond or a linear or branched C.sub.2 -C.sub.4 alkylene chain;R.sup.4 represents hydrogen; C.sub.1 -C.sub.3 alkyl; or, together with R.sub.1, represents a direct bond;K represents hydrogen; linear or branched C.sub.1 -C.sub.4 alkyl; or a protective group having the formula: ##STR41##wherein:Y represents oxygen; or a direct bond;M represents a linear, branched or cyclic C.sub.1 -C.sub.8 alkylene chain; or a direct bond;R.sup.5 represents hydrogen; phenyl group which is optionally substituted; linear, branched or cyclic C.sub.2 -C.sub.6 carbamoyl; linear, branched or cyclic C.sub.1 -C.sub.6 carboalkoxyl; or cyano;R.sup.6 represents hydrogen; C.sub.1 -C.sub.3 alkoxyl; acetate; or an acetamidic group;(46) methylbenzothiadiazole-7-thiocarboxylate.