Patent ID: 6600074
Filing Date: 2003-07-29
Classification: C07C,C07D

Abstract:
An aniline compound represented by the formula (I) wherein R1 denotes a hydrogen atom, R2 denotes a hydrogen atom, (C1-12)alkyl group, (C3-8)cycloalkyl group, hydroxy (C1-12) alkyl group, hydroxycarbonyl (C1-12) alkyl group, (C1-6)alkoxycarbonyl (C1-6)alkyl group, â€”COR8 (wherein R8 is a hydrogen atom, (C1-12)alkyl group, halo(C1-12)alkyl group, (C3-8)cycloalkyl group, phenyl group or phenyl group substituted with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, hydroxyl group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6) alkoxy group, halo(C1-6)alkoxy group, carboxyl group and (C1-6) alkoxycarbonyl group) or COOR9 (wherein R9 is a (C1-6)alkyl group, halo(C1-6) alkyl group, phenyl group, phenyl group substituted with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, hydroxyl group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6) alkoxy group, halo (CC1-6) alkoxy group, carboxyl group and (C1-6) alkoxycarbonyl group, benzyl group or benzyl group substituted on the ring with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, hydroxyl group, halogen atom, (C1-6) alkyl group, halo(C1-6)alkyl group, (C1-6)alkoxy group, halo (C1-6)alkoxy group, carboxyl group and (C1-6)alkoxy-carbonyl group); R3, R4, R5, R6 and R7 are the same or different and each denote a hydrogen atom, halogen atom, hydroxyl group, nitro group, (C1-12)alkyl group, halo(C1-12)alkyl group, (C1-12)alkoxy group, halo(C1-12)alkoxy group, (C1-12)alkylthio group, halo(C1-12)alkylthio group, (C1-6)alkylthio (C1-6)alkyl group, hydroxy(C1-6) alkyl group, amino (C1-6) alkyl group, amino(C1-6)alkyl group substituted with one or two (C1-6)alkyl groups which are the same or different, phenyl group, phenyl group substituted with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, halogen atom, (C1-6)alkyl group, halo (C1-6)alkyl group, (C1-6)alkoxy group and halo (C1-6)alkoxy group, phenoxy group, phenoxy group substituted with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6)alkoxy group, and halo (C1-6) alkoxy group, benzyl group, benzyl group substituted on the ring with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6)alkoxy group and halo(C1-6)alkoxy group, â€”N(R10)R11(wherein R10 and R11 are the same or different and are each a hydrogen atom, (C1-12)alkyl group, (C3-8)cycloalkyl group, phenyl group, phenyl group substituted with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, hydroxyl group, halogen atom, (C1-6)alkyl group, halo (C1-6)alkyl group, (C1-6)alkoxy group, halo(C1-6)alkoxy group, carboxyl group and (C1-6)alkoxycarbonyl group, benzyl group, benzyl group substituted on the ring with 1-5 groups, which are the same or different, selected from the group consisting of cyano group, nitro group, hydroxyl group, halogen atom, (C1-6)alkyl group, halo(C1-6)alkyl group, (C1-6) alkoxy group, halo (C1-6) alkoxy group, carboxyl group and (C1-6)alkoxycarbonyl group, â€”COR8, wherein R8 has the same meaning as defined above, or â€”COOR9, wherein R9 has the same meaning as defined above, further R10 and R11 conjointly form a (C3-6)alkylene group), or (C2-27)perfluoroalkyl group; and further, R1 or R2 and R3 or R7 conjointly form a (C2-4)alkylene group, and R3, R4, R5, R6 and R7 form, with their two adjacent substituents joined together, a (C3-5)alkylene group or (C1-12)alkylenedioxy group, and at least one of the R3, R4, R5, R6 and R7 must denote, a secondary (C3-27)perfluoroalkyl group; provided that (1) when R1 and R2 are each a hydrogen atom, R3 is a methyl group and R4, R6 and R7 are simultaneously each a hydrogen atom, then R5 must not be a nonafluoro-sec-butyl group, (2) when R1, R2, R4, R6 and R7 are simultaneously each a hydrogen atom and R3 is a chlorine atom, then R5 must not be a nonafluoro-n-butyl group, (3) when R1 and R2 are each a hydrogen atom and any four of the R3, R4, R5, R6 and R7 simultaneously each a hydrogen atom, then the remaining one of the R3, R4, R5, R6 and R7 must not be a heptafluoroisopropyl group, (4) when R1, R2, R4 and R7 are simultaneously each a hydrogen atom, R6 is an amino group and one of the R3 is a hydrogen atom, then R5 must not be a heptafluoroisopropyl group.