Patent ID: 8716698
Filing Date: 2014-05-06
Classification: C07D,H01L

Abstract:
1. An organic electroluminescent device comprising at least an anode electrode, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer and a cathode electrode in this order, wherein the hole injection layer comprises an arylamine compound having four triphenylamine structures in the molecule, the hole transport layer comprises an arylamine compound having two triphenylamine structures in the molecule, wherein the electron transport layer comprises a substituted bipyridyl compound represented by the following general formula (1): wherein R 1 to R 7 may be the same or different, and each represents a hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, a trifluoromethyl group, a linear or branched alkyl group having from 1 to 6 carbon atoms, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group; n1 is an integer of from 2 to 4; A 1 represents a di- to tetra-valent substituted or unsubstituted aromatic hydrocarbon groups, a di- to tetra-valent substituted or unsubstituted aromatic heterocyclic groups, a di- to tetra-valent substituted or unsubstituted condensed polycyclic aromatic group or a trivalent group represented by the following general formula (2): wherein X, Y and Z each represents a carbon atom or a nitrogen atom, provided that when n1=2, two bipyridyl structures may directly bond to each other, and in that case, A 1 is absent, wherein the arylamine compound having four triphenylamine structures in the molecule and contained in the hole injection layer is an arylamine compound represented by the following general formula (3): wherein R 8 to R 19 may be the same or different, and each represents a fluorine atom, a chlorine atom, a cyano group, a trifluoromethyl group, a linear or branched alkyl group having from 1 to 6 carbon atoms, a linear or branched alkenyl group having from 1 to 6 carbon atoms, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group, provided that when a plurality of those substituents bond to the same benzene ring, those substituents may be combined to form a ring; r 8 to r 19 are 0 or an integer of from 1 to 4; and A 2 , A 3 and A 4 may be the same or different, and each represents a divalent group represented by the following structural formulae (B) to (F), or a single bond: wherein n2 is an integer of from 1 to 3; and wherein the arylamine compound having two triphenylamine structures in the molecule and contained in the hole transport layer is an arylamine compound represented by the following general formula (4): wherein R 20 to R 25 may be the same or different, and each represents a fluorine atom, a chlorine atom, a cyano group, a trifluoromethyl group, a linear or branched alkyl group having from 1 to 6 carbon atoms, a linear or branched alkenyl group having from 1 to 6 carbon atoms, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group, provided that when a plurality of those substituents are bonded to the same benzene ring, those substituents may be combined to form a ring; r 20 to r 25 are 0 or an integer of from 1 to 4; and A 5 represents a divalent group represented by the following structural formulae (B) to (F), or a single bond: wherein n2 is an integer of from 1 to 3;