Patent ID: 6214066
Filing Date: 2001-04-10
Classification: C01B,Y02P

Abstract:
A method for producing synthesis gas containing hydrogen and carbon monoxide which comprises:(a) providing a reaction zone having an oxidant side and a reactant side which are separated by a solid mixed conducting membrane;(b) heating an oxygen-containing oxidant gas feed to yield a heated oxidant gas feed and introducing the heated oxidant gas feed into the oxidant side of the reaction zone at an oxidant gas feed temperature and an oxidant gas feed pressure;(c) heating a methane-containing reactant gas to yield a heated reactant gas feed and introducing the heated reactant gas feed into the reactant side of the reaction zone at a reactant gas feed temperature and a reactant gas feed pressure;(d) permeating oxygen from the oxidant side of the reaction zone through the mixed conducting membrane to the reactant side of the reaction zone and reacting the oxygen with the heated reactant gas feed to form at least hydrogen and carbon monoxide;(e) withdrawing a synthesis gas product comprising at least hydrogen and carbon monoxide from the reactant side of the reaction zone at a product gas outlet temperature; and(f) maintaining the product gas outlet temperature above the reactant gas feed temperature;wherein the total pressure at any point in the reactant side of the reaction zone is greater than the total pressure at any point in the oxidant side of the reaction zone.