Patent ID: 6165229
Filing Date: 2000-12-26
Classification: A61K,A61Q

Abstract:
A process for the oxidation dyeing of keratin fibers comprising(a) applying to the keratin fibers an effective amount for dyeing of at least one dyeing composition;(b) developing color at acidic, neutral, or alkaline pH in presence of an oxidizing agent which is added to said at least one dyeing composition at the same time said at least one dyeing composition is applied, or which is present in an oxidizing composition that is applied:(i) separately from said at least on dyeing composition at the same time that said at least one dyeing composition is applied to the fibers, or(ii) sequentially with said at least one dyeing composition,wherein said at least one dyeing composition comprises, in a medium which is suitable for dyeing, at least one oxidation base and at least one coupler chosen from imidazoloazole compounds of formula (I) and acid addition salts thereof; ##STR11## in which: R.sub.1 is chosen from a hydrogen atom; a halogen atom; a linear or branched C.sub.1 -C.sub.5 alkyl radical, unsubstituted or substituted with one or two halogen, hydroxyl, alkoxy, aryloxy, amino, alkylamino, acyl or acylamino radicals; a C.sub.1 -C.sub.4 alkoxy radical; a C.sub.1 -C.sub.4 alkylthio radical; an arylthio radical; a benzylthio radical, an acyl radical; an acylamino radical; an acyloxy radical; a carbamoyl radical; a phenyl radical, unsubstituted or substituted with one or two halogen, nitro, sulphonyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 trifluoroalkyl, amino or alkylamino groups; an alkoxycarbonyl radical; an aryloxycarbonyl radical; a cyano radical; a nitro radical; a dialkylphosphinyl radical; an arylsulphinyl radical; an alkylsulphinyl radical; a sulphamoyl radical; a carboxyl group; a sulpho group; an aryloxy radical; a C.sub.1 -C.sub.4 alkylamino radical; a ureido radical; a sulphamoylamino radical; a sulphonamido radical; an alkoxycarbonylamino radical; an aryloxycarbonylamino radical; a heteroarylthio radical; and a phosphonyl group;R.sub.2 is chosen from a hydrogen atom; a halogen atom; an acetylamido group; an alkoxy radical; an aryloxy radical; an acyloxy radical; an arylthio radical; an alkylthio radical; a heteroarylthio radical; a heteroaryloxy radical; a thiocyano radical; an N,N-diethylthiocarbonylthio radical; a dodecyloxythiocarbonylthio radical; a benzenesulphonamido radical; an N-ethyltoluenesulphonamido radical; a pentafluorobutanamido radical; a 2,3,4,5,6-pentafluorobenzamido radical; a p-cyanophenylureido radical; an N,N-diethylsulphamoylamino radical; a pyrazolyl radical; an imidazolyl radical; a triazolyl radical; a tetrazolyl radical; a benzimidazolyl radical; a 1-benzyl-5-ethoxy-3-hydantoinyl radical; a 1-benzyl-3-hydantoinyl radical; 5,5-dimethyl-2,4-dioxo-3-oxazolidinyl; a 2-oxy-1,2-dihydro-1-pyridyl radical; an alkylamido; an arylamino; and a radical NR.sup.III R.sup.IV wherein R.sup.III and R.sup.IV are independently chosen from a C.sub.1 -C.sub.4 alkyl, a hydroxyalkyl, a carboxyl, and an alkyoxycarbonxylic radical;Z.sub.a and Z.sub.b independently are chosen from a nitrogen atom and a carbon atom bearing a radical R.sub.3, R.sub.4 and R.sub.5, with the proviso that at least one of Z.sub.a and Z.sub.b is a carbon atom;R.sub.3 and R.sub.4 independently are chosen from a hydrogen atom; a halogen atom; a linear or branched C.sub.1 -C.sub.5 alkyl radical, unsubstituted or substituted with one or two halogen, hydroxyl, alkoxy, aryloxy, amino, alkylamino, acyl or acylamino radicals; an arylthio radical; an acyl radical; an acyloxy radical; a carbamoyl radical; a phenyl radical, unsubstituted or substituted with one or two halogen, nitro, sulphonyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 trifluoroalkyl, amino or alkylamino groups; an alkoxycarbonyl radical; an aryloxycarbonyl radical; a cyano radical; a nitro radical; a dialkylphosphono radical; a diarylphosphono radical; a dialkylphosphinyl radical; a diarylsulphonyl radical; an alkylsulphinyl radical; an arylsulphinyl radical; an arylsulphonyl radical; an alkylsulphonyl radical; a sulphonyloxy radical; an acylthio radical; a sulphamoyl radical; a thiocyanate radical; a thiocarbonyl radical; a haloalkylamino radical; and a heterocycle; or R.sub.3 and R.sub.4 can together form a substituted or unsubstituted aromatic ring;R.sub.5 is chosen from a hydrogen atom; a linear or branched C.sub.1 -C.sub.20 alkyl radical, unsubstituted or substituted with one or two radicals R; an aryl radical, unsubstituted or substituted with one or two radicals R; and a 5- or 6-membered heterocycle having at least one nitrogen, oxygen or sulphur atom, unsubstituted or substituted with one or two radicals R;wherein R is chosen from halogen, nitro, cyano, hydroxyl, alkoxy, aryloxy, amino, alkylamino, acylamino, carbamoyl, sulphonamido, sulphamoyl, imido, alkylthio, arylthio, aryl, alkoxycarbonyl, and acyl groups; andwherein when R.sub.5 is an alkyl radical, aryl radical or 5- or 6-membered heterocycle, R.sub.5 is linked to the carbon atom of the ring via an oxygen, nitrogen or sulphur atom so that R.sub.5 becomes XR.sub.5, wherein X is O, NH, or S; andR.sub.5 can also be chosen from a halogen atom; an acyl radical; a sulphonyl radical; a sulphinyl radical; a phosphonyl radical, a carbamoyl radical; a sulphamoyl radical; a cyano radical; a siloxy radical, an amino radical; an acylamino radical; an acyloxy radical; a carbamoyloxy radical; a sulphonamide radical; an imide radical; a ureido radical; a sulphamoylamino radical; an alkoxycarbonylamino radical; an aryloxycarbonylamino radical; an alkoxycarbonyl radical; an aryloxycarbonyl radical; and a carboxyl radical.