Patent ID: 6677392
Filing Date: 2004-01-13
Classification: C07D,C07F,C08K

Abstract:
A compound of formula (I) or (II) whereinG1 and G6 are independently hydrogen or halogen; G2 and G7 are independently cyano, perfluoroalkyl of 1 to 12 carbon atoms, fluoro, chloro, â€”COâ€”G3, â€”COOG3, â€”CONHG3, â€”CON(G3)2, E3SO2â€”, E3SO2â€”, â€”PO(C6H5)2, NHâ€”T2â€”Si(OR2)n(R1)3-n or â€”COâ€”Xâ€”T1â€”Si(OR2)n(R1)3-n;or G7 is also hydrogen; or G2 may also be hydrogen when E1 is a group of formula (IV) or (V); T1 and T2 are independently alkylene of 1 to 18 carbon atoms or alkylene-phenylene-alkylene of 8 to 20 carbon atoms; R1 and R2 are independently alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 10 carbon atoms or phenylalkyl of 7 to 20 carbon atoms; n is 0, 1, 2 or 3; X is â€”Oâ€”, â€”NE4â€” or â€”NHâ€”; G3 is hydrogen, straight or branched chain alkyl of 1 to 24 carbon atoms, straight or branched chain alkenyl of 2 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 15 carbon atoms, phenyl, or said phenyl or said phenylalkyl substituted on the phenyl ring by 1 to 4 alkyl of 1 to 4 carbon atoms; E1 is hydrogen, straight or branched chain alkyl of 1 to 24 carbon atoms, straight or branched chain alkenyl of 2 to 24 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 15 carbon atoms, phenyl, or said phenyl or said phenylalkyl substituted on the phenyl ring by 1 to 4 alkyl of 1 to 4 carbon atoms or by one or more of the following groups â€”T1â€”Si(OR2)n(R1)3-n, â€”T1â€”Xâ€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n, â€”T1â€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n, â€”Xâ€”T1â€”Si(OR2)n(R1)3-n, or â€”Xâ€”T2â€”Xâ€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n; or E1 is alkyl of 1 to 24 carbon atoms substituted by one or two hydroxy groups; or E1 is a group of formula (IV) or (V) whereE27 and E28 are independently alkyl of 1 to 18 carbon atoms, or cycloalkyl of 5 to 12 carbon atoms; E22, E23, E24, E25 and E26 are independently hydrogen, halogen, straight or branched alkyl of 1 to 18 carbon atoms, alkenyl of 2 to 18 carbon atoms, said alkyl or said alkenyl substituted by one or more halogen, â€”OCOE11, â€”OE4, â€”NCO, â€”NHCOE11, or â€”NE7E8, or mixtures thereof, where E4 is straight or branched chain alkyl of 1 to 24 carbon atoms or straight or branched chain alkenyl of 2 to 18 carbon atoms; or said alkyl or said alkenyl interrupted by one or more â€”Oâ€”, â€”NHâ€” or â€”NE4â€” groups or mixtures thereof and which can be unsubstituted or substituted by one or more â€”OH, â€”OE4 or â€”NH2, or mixtures thereof; or E22, E23, E24, E25 and E26 are independently phenyl, â€”OH, â€”OCOE11, â€”OE29, â€”NCO, â€”NHCOE11 or â€”NE7E8, cyano, nitro, perfluoroalkyl of 1 to 12 carbon atoms, â€”COG3, â€”COOG3, â€”CON(G3)2, â€”CONHG3, E3Sâ€”, E3SOâ€”, E3SO2â€”, â€”P(O)(C6H5)2, â€”P(O)(C3)2, â€”SO2â€”X1â€”E29; X1 is â€”Oâ€”, â€”NHâ€” or â€”NE4â€”; E29 is straight or branched chain alkyl of 1 to 24 carbon atoms, straight or branched chain alkenyl of 2 to 18 carbon atoms, said alkyl or said alkenyl substituted by one or more â€”OH, â€”OCOE11, â€”OE4, â€”NCO, â€”NHCOE11, â€”NE7E8, phthalimido, or mixtures thereof, where E4 is straight or branched chain alkyl of 1 to 24 carbon atoms or alkenyl of 2 to 18 carbon atoms; or said alkyl or said alkenyl interrupted by one or more â€”Oâ€”, â€”NHâ€” or â€”NE4â€” groups or mixtures thereof and which can be unsubstituted or substituted by one or more â€”OH, â€”OE4 or â€”NH2, or mixtures thereof; or E29 is phenyl or phenylalkyl of 7 to 15 carbon atoms, or said phenyl or said phenylalkyl substituted by one to three alkyl groups of 1 to 4 carbon atoms;E2 and E9 are independently hydrogen, straight or branched alkyl chain of 1 to 24 carbon atoms, straight or branched chain alkenyl of 2 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 15 carbon atoms, phenyl, or said phenyl or said phenylalkyl substituted on the phenyl ring by one to three alkyl of 1 to 4 carbon atoms or by one or more of the following groups â€”T1â€”Si(OR2)n(R1)3-n, â€”T1â€”Xâ€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n, â€”T1â€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n, â€”Xâ€”T1â€”Si(OR2)n(R1)3-n, or â€”Xâ€”T1â€”Xâ€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n; or E2 and E9 are independently said alkyl of 1 to 24 carbon atoms or said alkenyl of 2 to 18 carbon atoms substituted by one or more â€”OH, â€”OCOE11, â€”OE4, â€”NCO, â€”NH2, â€”NHCOE11, â€”NHE4 or â€”N(E4)2, or mixtures thereof, where E4 is straight or branched chain alkyl of 1 to 24 carbon atoms; or said alkyl or said alkenyl interrupted by one or more â€”Oâ€”, â€”NHâ€” or â€”NE4â€” groups or mixtures thereof and which can be unsubstituted or substituted by one or more â€”OH, â€”OE4 or â€”NH2 groups or mixtures thereof; or E1, E2 and E9 are also independently â€”T1â€”Si(OR2)n(R1)3-n, â€”T1â€”Xâ€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n or â€”T1â€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n; E11 is hydrogen, straight or branched chain alkyl of 1 to 18 carbon atoms, straight or branched chain alkenyl of 2 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 14 carbon atoms or phenylalkyl of 7 to 15 carbon atoms; L is alkylene of 1 to 12 carbon atoms, alkylidene of 2 to 12 carbon atoms, benzylidene, p-xylylene, cycloalkylidene of 5 to 12 carbon atoms or &agr;,&agr;,&agr;â€²,&agr;â€²-tetramethyl-m-xylylene; E3 is alkyl of 1 to 20 carbon atoms, said alkyl substituted by alkoxycarbonyl of 2 to 9 carbon atoms, hydroxyalkyl of 2 to 20 carbon atoms, alkenyl of 3 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon atoms or said aryl substituted by one or two alkyl of 1 to 4 carbon atoms or 1,1,2,2-tetrahydroperfluoroalkyl where the perfluoroalkyl moiety is of 6 to 16 carbon atoms, E5 and E8 are independently the same as E2; or E5 and E8 are independently hydrogen, â€”Xâ€”E1, â€”Xâ€”COâ€”E2, â€”Xâ€”COâ€”X1, â€”Xâ€”T1â€”Si(OR2)n(R1)3-n, or â€”Xâ€”T1â€”Xâ€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n; X1 is â€”NHâ€”E4 or â€”Xâ€”E2; with the proviso that at least one of G2, E1, E2 and E5 contains a group â€”T1â€”Si(OR2)n(R1)3-n, â€”T1â€”Xâ€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n or â€”T1â€”COâ€”Xâ€”T2â€”Si(OR2)n(R1)3-n; where T1 and T2 are independently alkylene of 1 to 18 carbon atoms or alkylene-phenylene-alkylene of 8 to 20 carbon atoms, and R1 and R2 are independently alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 10 carbon atoms or phenylalkyl of 7 to 20 carbon atoms, and n is 0, 1, 2 or 3 and with the proviso that when G1 is hydrogen and G2 is chloro, fluoro or â€”COOG3, E1 is a group of formula (IV) or (V).