Patent ID: 6828029
Filing Date: 2004-12-07
Classification: C07F,C08G,C08L

Abstract:
A zwitterion containing adduct having the formula (I) whereinZ is a zwitterionic group with a general formula (IV) in which the moieties A2 and A3, which are the same or different, are â€”Oâ€”, â€”Sâ€”, â€”NHâ€” or a valence bond W+ is a group of formula â€”W1â€”N+R143, â€”W1â€”P+R153, â€”W1â€”S+R152 or â€”W1â€”Het+in which: W1 is alkanediyl of 1 or more carbon atoms optionally containing one or more ethylenically unsaturated double or triple bonds, disubstituted-aryl (arylene), alkylene arylene, arylene alkylene, or alkylene aryl alkylene, cycloalkanediyl, alkylene cycloalkyl, cycloalkyl alkylene or alkylene cycloalkyl alkylene, which group W1 optionally contains one or more fluorine substituents and/or one or more functional groups; and either the groups R14 are the same or different and each is hydrogen or alkyl of 1 to 4 carbon atoms, or two of the groups R14 together with the hetero atom to which they are attached form an aliphatic heterocyclic ring containing from 5 to 7 atoms, or the three groups R14 together with the hetero atom to which they are attached form a fused ring structure containing from 5 to 7 atoms in each ring, and optionally one or more of the groups R14 is substituted by a hydrophilic functional group, and the groups R15 are the same or different and each is R14 or a group OR14, where R14 is as defined above; or Het is an aromatic nitrogen-, phosphorus- or sulphur-containing ring; X is an electron withdrawing group selected from the group consisting of carbonyl and sulphone groups, sulphonium and phosphonium salts; R is selected from the group consisting of linear and branched alkanediyl, alkenediyl, alkynediyl, cycloalkanediyl, cycloalkenediyl, cycloalkynediyl, arylene, alkarylene, aralkylene, alkoxyarylene, alkoxyalkyl, oligo(alkoxy)alkyl, mono- and di-alkylaminoalkyl N-arylaminoalkyl, N-aryl-N-alkylaminoalkyl; R1 and R2 are independently selected from hydrogen and C1-C12 alkyl groups; A is O or NR6, where R6 is selected from the group consisting of hydrogen and C1-6 alkyl; R3 is selected from the group consisting hydrogen, linear and branched alkyl, alkenyl, and alkynyl groups, alkoxycarbonyl, alkylaminocarbonyl, cycloalkyl, cycloalkenyl, cycloalkynyl, haloaryl, haloalkyl, aryl, alkaryl, aralkyl, alkoxyaryl, alkoxyalkyl, oligoalkoxyalkyl, aminoalkyl, mono- and di-alkylaminoalkyl, arylaminoalkyl, N-aryl-N-alkylaminoalkyl and -aminoaryl, acyloxy, acyloxyalkyl, acylaminoalkyl, N-diacyl-iminoalkyl groups, mono- and di-alkylaminocarbonyl, organosilyl, arylamino carbonyl, aryl(alkyl)amino carbonyl, and organosiloxyl groups and any of the above groups substituted with a reactive group, a group NHCOOR5 in which R5 is selected from the group consisting hydrogen, linear and branched alkyl, alkenyl, and alkynyl groups, cycloalkyl, cycloalkenyl, cyctoalkynyl, haloaryl, haloalkyl, aryl, alkaryl, aralkyl, alkoxyaryl, alkoxyalkyl, oligoalkoxyalkyl, aminoalkyl, mono- and di-alkylaminoalkyl, arylaminoalkyl, N-aryl-N-alkylaminoalkyl and aminoaryl, acyloxyalkyl, acylaminoalkyl, N-diacyl-iminoalkyl groups, hydroxyalkyl, hydroxyalkenyl, hydroxyalkynyl, hydroxyaryl, hydroxyalkoxyalkyl and hydroxy(oligoalkoxy)alkyl; a group â€”NHCONR7R8 in which R7 and R8 are selected from the group consisting hydrogen, linear and branched alkyl, alkenyl, and alkynyl groups, cycloalkyl, cycioalkenyl, cycloalkynyl, haloaryl, haloalkyl, aryl, alkaryl, aralkyl, alkoxyaryl, alkoxyalkyl, oligoalkoxyalkyl, aminoalkyl, mono- and dialkylaminoalkyl, arylaminoalkyl, N-aryl-N-alkylaminoalkyl and aminoaryl, acyloxyalkyl, acylaminoalkyl, N-diacyl-iminoalkyl groups, hydroxyalkyl, hydroxyalkenyl, hydroxyalkynyl, hydroxyaryl, hydroxyalkoxyalkyl and hydroxy(oligoalkoxy)alkyl; or a polymeric moiety; and R4 is selected from the group consisting hydrogen, linear and branched alkyl, alkenyl, and alkynyl groups, alkoxycarbonyl, alkylaminocarbonyl, cycloalkyl, cycloalkenyl, cycloalkynyl, haloaryl, haloalkyl, aryl, alkaryl, aralkyl, alkoxyaryl, alkoxyalkyl, oligoalkoxyalkyl, aminoalkyl, mono- and di-alkylaminoalkyl, arylaminoalkyl, N-aryl-N-alkylaminoalkyl and -aminoaryl, acyloxy, acyloxyalkyl, acylaminoalkyl, N-diacyl-iminoalkyl groups, mono- and di-alkylaminocarbonyl, organosilyl, arylamino carbonyl, aryl(alkyl)amino carbonyl, and organosiloxyl groups and any of the above groups substituted with a group II in which the groups R, R1, R2, R4, Z and A are the same as in (I); a group III in which A1 is O or NR13 where R13 is hydrogen or C1-6 alkyl; X1 is an electron withdrawing group selected from carbonyl, sulphonyl, sulphonium and phosphonium groups; R12 is H or C1-6 alkyl; R10 and R11 are independently selected from H and C1-4 alkyl; and R9 is optionally substituted alkyl or aryl; a reactive group; or a polymeric moiety.