Patent ID: 8860076
Filing Date: 2014-10-14
Classification: C08G,C08L,H01L

Abstract:
1. An optical semiconductor sealing curable composition, wherein the optical semiconductor sealing curable composition contains: (A) 100 parts by mass of a linear polyfluoro compound represented by the following general formula (1), wherein X represents a group represented by any one of —CH 2 —, —CH 2 O—, —CH 2 OCH 2 —, and —Y—NR 1 —CO— (Y represents —CH 2 — or an o, m, or p-dimethylsilylphenylene group represented by the following structural formula (2), and R 1 represents a hydrogen atom or an unsubstituted or substituted monovalent hydrocarbon group), X′ represents a group represented by any one of —CH 2 —, —OCH 2 —, —CH 2 OCH 2 —, and —CO—NR 1 —Y′— (Y′ represents —CH 2 — or an o, m, or p-dimethylsilylphenylene group represented by the following structural formula (3), and R 1 represents the same group as above, and a represents independently 0 or 1, Rf 1 represents a divalent perfluoropolyether group represented by the following general formula (4) or (5), wherein each of p and q represents an integer of 1 to 150, and an average of sums of p and q is 2 to 300, further, r represents an integer of 0 to 6, and t represents 2 or 3, wherein u represents an integer of 1 to 300, s represents an integer of 1 to 80, and t represents the same as above; (B) cyclic organopolysiloxane which is represented by the following general formula (6) and has a hydrogen atom directly bonded to a silicon atom and a monovalent perfluoroalkyl group or a monovalent perfluorooxyalkyl group bonded to the silicon atom through a divalent hydrocarbon group which is allowed to contain an oxygen atom or a nitrogen atom per molecule, and whose amount allows the hydrogen atom directly bonded to the silicon atom to be 0.5 to 2.0 mole with respect to 1 mole of the alkenyl group in the component (A), wherein a represents an integer of 3 to 6, b represents an integer of 1 to 4, a+b represents an integer of 4 to 10, R 2 represents a substituted or unsubstituted monovalent hydrocarbon group, and A represents a monovalent perfluoroalkyl group or a monovalent perfluorooxyalkyl group bonded to a silicon atom through a divalent hydrocarbon group that is allowed to contain an oxygen atom or a nitrogen atom; (C) 0.1 to 500 ppm of a platinum group metal catalyst when converted into a platinum group metal atom; (D) 0.1 to 10.0 parts by mass of cyclic organopolysiloxane which is represented by the following general formula (7) and has a hydrogen atom directly bonded to a silicon atom, a monovalent perfluoroalkyl group or a monovalent perfluorooxyalkyl group bonded to a silicon atom through a divalent hydrocarbon group that is allowed to contain an oxygen atom or a nitrogen atom, and an epoxy group bonded to a silicon atom through a divalent hydrocarbon group that is allowed to contain an oxygen atom per molecule, wherein i represents an integer of 1 to 6, j represents an integer of 1 to 4, k represents an integer of 1 to 4, i+j+k represents an integer of 4 to 10, R 3 represents a substituted or unsubstituted monovalent hydrocarbon group, L represents a monovalent perfluoroalkyl group or a monovalent perfluorooxyalkyl group bonded to a silicon atom through a divalent hydrocarbon group that is allowed to contain an oxygen atom or a nitrogen atom, and M represents an epoxy group bonded to a silicon atom through a divalent hydrocarbon group that is allowed to contain an oxygen atom; and (E) 0.01 to 5.0 parts by mass of cyclic organopolysiloxane which is represented by the following general formula (8) and has a hydrogen atom directly bonded to a silicon atom, a monovalent perfluoroalkyl group or a monovalent perfluorooxyalkyl group bonded to a silicon atom through a divalent hydrocarbon group that is allowed to contain an oxygen atom or a nitrogen atom, and a cyclic carboxylic acid anhydride residue bonded to a silicon atom through a divalent hydrocarbon group per molecule, wherein x represents an integer of 1 to 6, y represents an integer of 1 to 4, z represents an integer of 1 to 4, x+y+z represents an integer of 4 to 10, R 4 represents a substituted or unsubstituted monovalent hydrocarbon group, Q represents a monovalent perfluoroalkyl group or a monovalent perfluorooxyalkyl group bonded to a silicon atom through a divalent hydrocarbon group that is allowed to contain an oxygen atom or a nitrogen atom, and T is a cyclic carboxylic acid anhydride residue bonded to a silicon atom through a divalent hydrocarbon group, wherein the monovalent perfluoroalkyl group or the monovalent perfluorooxyalkyl group included in each cyclic organopolysiloxane in the component (B), the component (D), and the component (E) is represented by the following general formula (9) or general formula (10), wherein f represents an integer of 1 to 10, wherein g represents an integer of 1 to 10, and wherein a transmittance for linear light having a wavelength of 450 nm in a cured material having a thickness of 2 mm after curing is not lower than 80%, and a refractive index of the cured material after curing at 25° C. and 589 nm (a D line of sodium) is 1.30 to 1.39.