Patent ID: 6455472
Filing Date: 2002-09-24
Classification: C07C,C07D,E04B

Abstract:
A compound of the formula (I) whereinAr represents Ar1, wherein Ar1 is selected from the group consisting of i) phenyl being substituted with from one to five substituents, ii) naphthyl being substituted with from one to five substituents, and iii) mono- or bicyclic hetaryl having five to ten ring atoms and being substituted with from zero to five substituents, with said substituents being selected from the group consisting of halogen, C1-C8-alkyl, C2-C8-alkenyl, C2-C8-alkinyl, C1-C8-alkoxy, C2-C8-alkenyloxy, C3-C8-alkinyloxy, C1-C8-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-halogenoalkyl, C1-C6-halogeno-alkoxy, C2-C8-halogeno-alkenyloxy, C1-C2-alkylidenediyl-dioxy, C1-C2-halogeno-alkylidenediyl-dioxy, halogeno-C1-C4-alkylthio, halogeno-C1-C4-alkylsulfinyl, halogeno-C1-C4-alkylsulfonyl, hydroxyl, mercapto, nitro, cyano, amino, a) â€”Lâ€”COâ€”R7, or Ar represents Ar2, where Ar2 represents Ar1 which is additionally substituted by phenyl, naphthyl, five- or six-membered hetaryl, phenyl-C1-C4-alkyl, phenoxy, phenyl-S(O)gâ€”, five- or six-membered hetaryloxy or hetaryl-S(O)g, where these substituents for their part are in each case unsubstituted or mono- to tetrasubstituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy, nitro or cyano, and K represents oxygen or sulphur, L represents oxygen or sulphur, X represents CN, Y represents halogen, C1-C6-alkyl, C1-C4-halogenoalkyl, C1-C6-alkoxy, or represents phenyl, phenyl-C1-C4-alkyl, five- or six-membered hetaryl or five- or six-membered hetaryl-C1-C4-alkyl, each of which is unsubstituted or mono- to tetrasubstituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy, cyano or nitro, or represents the groups two adjacent Yn represent a 5- to 8-membered, saturated or unsaturated cycle which may be interrupted by 1 to 3 heteroatoms from the group consisting of N, O, S and which may be unsubstituted or mono- to tri-substituted by halogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy, cyano or nitro, and Z represents hydrogen, or represents in each case unsubstituted or fluorine- and/or chlorine-substituted C1-C8-alkyl, cyano-C1-C6-alkyl, C3-C8-alkenyl, C3-C8-alkinyl, C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C2-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-halo-genoalkoxy-C1-C4-alkyl, or represents phenoxy-C1-C4-alkyl, phenyl-C1-C4-alkyloxy-C1-C4-alkyl, phenylthio-C1-C4-alkyl, phenyl-C1-C4-alkylthio-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, five- or six-membered hetaryl, five- or six-membered hetaryl-C1-C4-alkyl, each of which is unsubstituted or mono- to tetrasubstituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogeno-alkoxy, nitro or cyano, or represents the groups â€ƒor cyano, g represents 0 to 2, I represents 0 to 2, R1 represents hydrogen (but not for the radicals â€”CO2R1 and â€”SO2R1), or represents in each case fluorine- and/or chlorine-substituted C1-C10-alkyl, C2-C10-alkenyl, C3-C6-alkinyl, or represents in each case unsubstituted or fluorine-, chlorine-, C1-C4-alkyl-, C1-C4-alkoxy-substituted C3-C8-cycloalkyl or C5-C8-cycloalkenyl wherein optionally one methylene group may be interrupted by oxygen or sulphur, or represents phenyl, pyridyl, thienyl, pyrimidyl, thiazolyl, phenyl-C1-C4-alkyl, pyridyl-C1-C2-alkyl, thiazolyl-C1-C2-alkyl, each of which is unsubstituted or mono- to tetrasubstituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy, cyano or nitro, R2 represents hydrogen, or represents in each case unsubstituted or fluorine- and/or chlorine-substituted C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkinyl, C1-C6-alkoxy, C3-C6-alkenyloxy or represents phenyl, phenyl-C1-C4-alkyl or phenyl-C1-C4-alkoxy, each of which is unsubstituted or mono- to tetrasubstituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy, cyano or nitro, or R1, R2 together with the nitrogen atom to which they are attached represent an unsubstituted or C1-C4-alkyl-substituted five- to eight-membered cycle wherein optionally one methylene group may be replaced by oxygen or sulphur, R3 represents hydrogen, or unsubstituted or halogen-substituted C1-C6-alkyl or represents phenyl or phenyl-C1-C2-alkyl each of which is unsubstituted or mono- to tetrasubstituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy, cyano or nitro, R4 represents hydrogen or C1-C6-alkyl, R5, R6 independently of one another each represent hydrogen or unsubstituted or fluorine- and/or chlorine-substituted C1-C4-alkyl, R7 represents in each case unsubstituted or fluorine- and/or chlorine-substituted C1-C10-alkyl, C2-C10-alkenyl, C3-C10-alkinyl, C1-C10-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, in each case unsubstituted or fluorine- and/or chlorine-, C1-C4-alkyl-, C1-C4-alkoxy-substituted C3-C8-cycloalkyl or C3-C8-cycloalkyloxy wherein optionally one methylene group may be replaced by oxygen or sulphur, or represents phenyl, phenoxy, benzyloxy, five- or six-membered hetaryl or phenyl-C1-C4-alkyl, each of which is unsubstituted or mono- to tetrasubstituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogeno-alkyl, C1-C4-halogenoalkoxy, cyano or nitro, or, in the case of the radicals a) and c) mentioned under Ar, also represents a group â€ƒfor the radical g), also represents hydroxyl, R8 represents hydrogen or C1-C4-alkyl, R9 represents hydrogen, or represents unsubstituted or fluorine- and/or chlorine-substituted C1-C10-alkyl, C3-C8-alkenyl, C3-C8-alkinyl, C1-C10-alkoxy, C3-C8-alkenyloxy, unsubstituted or fluorine-, chlorine-, C1-C4-alkyl- or C1-C4-alkoxy-substituted C3-C8-cycloalkyl wherein optionally one methylene group may be replaced by oxygen or sulphur, or represents phenyl, phenyl-C1-C4-alkyl or phenyl-C1-C2-alkoxy, each of which is unsubstituted or mono- to tetrasubstituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, C1-C4-halogenoalkyl, C1-C4-halogenoalkoxy, cyano or nitro, R10 represents hydrogen, C1-C6-alkyl or C3-C6-alkenyl, or R9, R10 together with the nitrogen atom to which they are attached represent an unsubstituted or C1-C4-alkyl-substituted five- to eight-membered cycle wherein optionally one methylene group may be replaced by oxygen or sulphur, and m represents 1 to 3, and n depending on m, represents 0 to 3, except for compounds of the following formula