Patent ID: 9024093
Filing Date: 2015-05-05
Classification: C07B,C07C,C07D,C07J,C07K

Abstract:
1. A method of fluorinating an organic compound, the method comprising providing an organic compound selected from the group consisting of aryl and heteroaryl tin species; vinyl, aryl, and heteroaryl boron species; and vinyl, aryl, and heteroaryl silicon species; a silver salt; and an organic, electrophilic fluorinating agent selected from the group consisting of N-fluoropyridinium triflate, N-fluoro-2,4,6-trimethylpyridinium triflate, N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate, N-fluoro-2,6-dichloropyridinium tetrafluoroborate, N-fluoro-2,6-dichloropyridinium triflate, N-fluoropylidinium pyridine heptafluorodiborate, N-fluoropyridinium tetrafluoroborate, N-fluoropyridinium triflate, an N-fluoroarylsulfonimide, N-chloromethyl-N′-fluorotriethylenediammonium bis(tetrafluoroborate), and N-chloromethyl-N′-fluorotriethylenediammonium bis(hexafluorophosphate), under conditions sufficient to fluorinate the organic compound, thereby providing a fluorinated organic compound.