Patent ID: 6613915
Filing Date: 2003-09-02
Classification: C07C,C07D,C07F,C08F

Abstract:
A compound of the formula: wherein:A is a &pgr;-allyl or &pgr;-benzyl group; L1 is a neutral monodentate ligand which may be displaced by an olefin, and L2 is a monoanionic monodentate ligand, or L1 and L2 taken together are a monoanionic bidentate ligand, provided that said monoanionic monodentate ligand or said monoanionic bidentate ligand may add to said olefin; Ar1, Ar2, Ar4, Ar5, Ar10, Ar11, Ar12 and Ar13 are each independently aryl or substituted aryl; R1 and R2 are each independently hydrogen, hydrocarbyl, substituted hydrocarbyl, or R1 and R2 taken together form a ring, and R3 is hydrogen, hydrocarbyl or substituted hydrocarbyl or R1, R2 and R3 taken together form a ring; R10 and R15 are each independently hydrogen, hydrocarbyl or substituted hydrocarbyl; R11, R12, R13, R14, R16, R17, R18, R19, R20, R21, R30, R31, R32, R33, R34, R35, R50, R51, R52, R53 and R54 are each independently hydrogen, hydrocarbyl, substituted hydrocarbyl, an inert functional group, and provided that any two of these groups vicinal to one another taken together may form a ring; K is N or CR27; R22 is hydrocarbyl, substituted hydrocarbyl, â€”SR117, â€”OR117, or â€”NR1182, R24 is hydrogen, a functional group, hydrocarbyl or substituted hydrocarbyl, and R27 is hydrocarbyl or substituted hydrocarbyl, and provided that R22 and R24 or R24 and R27 taken together may form a ring; R117 is hydrocarbyl or substituted hydrocarbyl; each R118 is independently hydrogen, hydrocarbyl or substituted hydrocarbyl; G and L are both N or G is CR57 and L is CR55; R55, R56 and R57 are each independently hydrogen, hydrocarbyl or substituted hydrocarbyl, or any two of R55, R56 and R57 taken together form a ring; R78 is hydrocarbyl or substituted hydrocarbyl; R79, R80, R81, R82, R83, R84, R85, R86, R87, R88 and R89 are each independently hydrogen, hydrocarbyl, substituted hydrocarbyl, or a functional group; R90, R91, R92 and R93 are each independently hydrocarbyl or substituted hydrocarbyl; R94 and R95 are each independently hydrocarbyl or substituted hydrocarbyl; R96, R97, R98, and R99 are each independently hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group; both of T are S (sulfur) or NH (amino); each E is N (nitrogen) or CR108 wherein R108 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group; R100, R101, R102, R103, R104, R105, R106, and R107 are each independently hydrogen, hydrocarbyl, substituted hydrocarbyl, or a functional group; R109, R110, R111, R112, R113, R114, R115 and R116 are each independently hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group; and R28 and R29 are each independently hydrogen, hydrocarbyl or substituted hydrocarbyl.