Patent ID: 6096477
Filing Date: 2000-08-01
Classification: C08G,G03F

Abstract:
A method for producing a positive photoresist composition having superior lithographic performance comprising:a) condensing formaldehyde with one or more phenolic compounds, in the presence of an acid catalyst and a reaction solvent, the reaction solvent being a photoresist solvent;b) adding water to the reaction mixture and thereby forming two solution layers, a top layer comprising a solution of unreacted phenolic compounds, and novolak oligomers and monomer in water, and a bottom layer comprising a solution of the remaining reaction mixture in reaction solvent, and removing the top layer;c) adding a water soluble organic polar solvent and water to the remaining bottom solution layer, in the ratio of water soluble organic polar solvent:water ratio of 5:95 to 95:5, and thereby again forming two solution layers, a bottom layer comprising a solution of the novolak resin condensation product in reaction solvent and a top layer comprising a solution of low molecular weight novolak, novolak oligomers and novolak monomers in a solvent comprising water/water soluble organic polar solvent/ reaction solvent, and removing the top layer;d) repeating steps b) and c) 2 to 10 times for the bottom layer remaining after step c);e) diluting the remaining novolak resin solution with a solvent comprising the reaction solvent, and removing any remaining water and water soluble organic polar solvent, thereby producing a film forming, fractionated novolak resin; andf) providing an admixture of: 1) a photosensitive component in an amount sufficient to photosensitive a photoresist composition: 2) the film forming novolak resin from stop e); and 3) a suitable photoresist solvent which comprises the same solvent as the reaction solvent, and thereby forming a photoresist composition.