Patent ID: 7741242
Filing Date: 2010-06-22
Classification: B01J,C07B,C07C,C07D,C07F

Abstract:
1. A catalyst composition comprising a crosslinked organic polymer compound and Pd(0) having no ligand, wherein said Pd(0) is physically carried on said crosslinked organic polymer compound, prepared by homogenizing a straight chain organic polymer compound having a crosslinkable functional group, and a palladium catalyst in a solvent dissolving said straight chain organic polymer compound; then depositing the composition formed; and subjecting a crosslinkable functional group in said deposited composition to a crosslinking reaction, and wherein said straight chain organic polymer compound is obtained by polymerizing 1) a monomer having a crosslinkable functional group and a polymerizable double bond represented by: (1) a glycidyl compound having an epoxy group as a crosslinkable functional group, selected from the group consisting of a glycidyl ether and a glycidyl ester represented by the following general formulas [1] and [2], respectively, wherein R wherein R 7 and R 8 each independently represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R 9 represents a direct-linkage, an alkylene group having 1 to 6 carbon atoms, an arylene group having 6 to 9 carbon atoms, an arylalkylene group having 7 to 12 carbon atoms or an arylenealkylene group having 7 to 15 carbon atoms, wherein the aromatic ring in the arylene or arylenealkylene group may have an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms and/or a halogen atom, as a substituent; (2) a monomer having a carboxyl group as a crosslinkable functional group, represented by the following general formula [4]: wherein R (3) a monomer having a hydroxyl group as a crosslinkable functional group, represented by the following general formula [5]: wherein R 2) a monomer having a polymerizable double bond is represented by the general formula [6]: wherein R 16 and R 17 each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R 19 represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 6 carbon atoms; R 18 represents a carboxyl group, a hydroxyl group, an acyloxy group having 2 to 6 carbon atoms, an arylacyloxy group having 7 to 15 carbon atoms, an alkoxycarbonyl group having 2 to 6 carbon atoms, an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 10 carbon atoms and an aralkyl group having 7 to 12 carbon atoms; an aromatic ring in the above arylacyloxy group, aryl group and aralkyl group, may have further an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms or a halogen atom, as a substituent, and wherein all of monomers having a crosslinkable functional group and a polymerizable double bond represented by the general formulas [1], [2], [4] and [5], and of monomers having a polymerizable double bond represented by the general formula [6], have an aromatic ring.