Patent ID: 6174635
Filing Date: 2001-01-16
Classification: G03G

Abstract:
An electrophotographic recording material comprising an electrically conductive support and a photosensitive recording layer having charge generating capacity by photo-exposure and containing as photoconductive pigment a photoconductive crystalline substituted metal-free phthalocyanine compound and/or mixed crystal pigment of said substituted metal-free phthalocyanine compound with an unsubstituted metal-free phthalocyanine, characterized in that said substituted metal-free phthalocyanine compound is represented by following general formula (I): ##STR26##wherein:R represents cyano substituent in ortho-position on at least one of the 6-membered rings in the phthalocyanine structure in which each substituted 6-membered ring is only mono-substituted, the possible ortho-positions being marked by asterisk (*), andx is an integer 1, 2, 3 or 4,wherein the major part by weight of said substituted metal-free phthalocyanine compound and mixed crystals of said substituted metal-free phthalocyanine compound with unsubstituted metal-free phthalcyanine is (are) present in the X-morphological form and wherein said electrically conductive support has thereon a positively chargeable photoconductive recording layer which contains in an electrically insulating organic polymer binder at least one p-type pigment substance and at least one n-type photoconductive charge transport substance, wherein (i) at least one of the p-type pigment substances is a compound corresponding to said general formula (I) mainly in morphological X-type form or a mixed crystal pigment mainly with an X-morphology comprising a p-type compound corresponding to said general formula (I) in a molar ratio range from 0.14:1 to 3.3:1 with p-type unsubstituted metal-free phthalocyanine, (ii) said layer has a thickness in the range of 4 to 40 .mu.m and comprises 5 to 40% by weight of said p-type pigment substances and 0.0001 to 15% by weight of at least one of said n-type charge transport substance(s) that is (are) molecularly distributed in said electrically insulating organic polymeric binder material that has a volume resistivity of at least 10.sup.14 Ohm-m, and wherein (iii) said recording layer in electrostatically charged state requires for 10% and 90% discharge respectively exposures to conductivity increasing electromagnetic radiation that differ by a factor 4.5 or less.