Patent ID: 6511940
Filing Date: 2003-01-28
Classification: A01N

Abstract:
A herbicidal composition which comprises a mixture ofA. a herbicidally active amount of one or more herbicides of the formula (I) â€ƒin which V is a radical selection from the group consisting of (V1), or (V3), â€ƒwhere the symbols and indices have the following meanings: R is hydrogen, (C1-C4)alkoxycarbonyl, (C1-C4)haloalkoxycarbonyl, COOH, cyano; R1 is hydrogen or an optionally substituted (C1-C7)alkyl, (C2-C7)alkenyl, (C2-C7)alkynyl, (C3-C7)cycloalkyl, (C3-C7)cycloalkenyl, (C1-C7)alkyl-(C3-C7)cycloalkyl, (C3-C7)halocycloalkyl, or (C1-C7)alkylthiocycloalkyl radical; R5 is an optionally substituted (C1-C12)alkyl, (C1-C12)alkoxy, (C1-C12)alkoxy-(C1-C12)alkyl, (C1-C12)dialkoxy-(C1-C12)alkyl, (C1-C12)alkylthio radical, halogen or substituted or unsubstituted aryl, or heterocycle; R6 is hydroxyl, an optionally substituted (C1-C4)alkoxy, (C1-C4)alkylcarbonyloxy, (C1-C4)alkylsulfonyloxy, (C1-C4)alkylthio, (C1-C4)alkylsulfinyl, or (C1-C4)alkylsulfonyl radical or formyloxy m is an integer from 0 to 6; and Z is a radical selection from the group consisting of (Z1), or (Z2), â€ƒwhere the symbols and indices have the following meanings: R9 is nitro, amino, cyano, halogen or an optionally substituted (C1-C8)alkyl, (C2-C8)alkenyl, (C2-C8)alkynyl, (C1-C8)alkoxycarbonyl, (C1-C8)alkylsulfonyl, (C1-C8)alkylsulfinyl, (C1-C8)alkylthio, aryl, arylsulfonyl, arysulfinyl, arylthio, aryloxy, (C1-C8)alkoxy, (C1-C8)alkoxy-(C1-C8)alkoxy, (C1-C8)alkylcarbonyl, (C1-C8)alkylaminosulfonyl, (C1-C8)dialkylaminosulfonyl, (C1-C8)alkylcarbamoyl, (C1-C8)diakylcarbamoyl, (C1-C8)alkoxy-(C1-C8)alkyl, (C1-C8)alkylamino, or (C1-C8)dialkylamino radical; R10 is optionally substituted heteroaryl, or optionally substituted heteroaryl(C1-C4)alkyl, wherein the heteroaryl group is oxazole or isoxazole; R11 is identical or different hydrogen, (C1-C4)alkyl, halogen; R12 is identical or different (C1-C4)alkyl, (C2-C4)alkenyl, (C2-C4)alkynyl, halogen, (C1-C4)haloalkyl, (C2-C4)haloalkenyl, (C2-C4)haloakynyl, (C1-C4)haloalkoxy, (C1-C4)haloalkylthio, (C1-C4)alkoxycarbonyl, (C1-C4)alkylsulfonyl, (C1-C4)haloalkylsulfonyl, (C1-C4)alkylsulfinyl, (C1-C4)haloalkylsulfinyl, (C1-C4)alkylthio, (C1-C4)alkoxy, (C1-C4)alkylcarbonyl, (C1-C4)alkylaminosulfonyl, (C1-C4)diakylaminosulfonyl, (C1-C4)alkylcarbamoyl, (C1-C4)diakylcarbamoyl, (C1-C4)alkoxyalkyl, phenoxy, nitro, cyano, aryl, di-(C1-C4)alkylphosphono(C1-C4)alkyl; q is 0, 1, 2, 3, or 4; r is 0, 1, 2, or 3; t is 1 or 2; X1 is O, CR14R15, CHOH, C&boxH;O, C&boxH;NO(C1-C4)alkyl; X2 is SO2; R14, R15 is identical or different hydrogen, (C1-C4)alkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C1-C4)alkylthio, (C1-C4)haloalkylthio or R14 and R15 together form one of the groups â€”Oâ€”(CH2)2â€”Oâ€”, â€”Oâ€”(CH2)3â€”Oâ€”, Sâ€”(CH2)2â€”Sâ€”, â€”Sâ€”(CH2)3â€”Sâ€”, â€”(CH2)4â€”, â€”(CH2)5â€”; and B. an antidote-effective amount of one or more safeners selected from the groups consisting of a), c), and d); a) compounds of the formulae (II) or (III) â€ƒwhere the symbols and indices have the following meanings: nâ€² is a natural number from 1 to 5, T is a (C1 or C2)-alkanediyl chain which is unsubstituted or substituted by one or two (C1-C4)alkyl radicals or by [(C1-C3)-alkoxy]carbonyl, W is a radical selected from the group consisting of (W1) and (W4) â€ƒwhere mâ€² is 0 or 1; R26 is hydrogen, (C1-C8)alkyl, (C1-C8)haloalkyl, (C1-C4)alkoxy(C1-C4)alkyl, (C1-C6)hydroxyalkyl, (C3-C12)cycloalkyl or try(C1-C4)alkylsilyl; R27 and R29 are identical or different and are hydrogen, (C1-C8) alkyl, (C1-C8) haloalkyl, cycloalkyl cycloalkyl (C3-C12)cycloalkyl or substituted or unsubstituted phenyl R17 and R19 are halogen; R18 and R20 are identical or different OR24 or SR24 R24 is hydrogen or an unsubstituted or substituted aliphatic hydrocarbon radical; c) N-acylsulfonamides of the formula (V) and their salts, â€ƒwhere R30 is hydrogen, a hydrocarbon radical, a hydrocarbonoxy radical, a hydrocarbonthio radical or a heterocyclyl radical, each of the last-mentioned 4 radicals being unsubstituted or substituted by one or more identical or different radicals selected from the group consisting of halogen, cyano, nitro, amino, hydroxyl, carboxyl, formyl, carboxamide, sulfonamide and radicals of the formula â€”Zaâ€”Ra, R31 is hydrogen or (C1-C4)alkyl or R30 and R31 together with the group of the formula â€”COâ€”Nâ€” are the radical of a 3- to 8-membered saturated or unsaturated ring; and R32 in the event that n=1, or the R32 independently of one another, in the event that n is greater than 1, is in each case halogen, cyano, nitro, amino, hydroxyl, carboxyl, formyl, CONH2, SO2NH2 or a radical of the formula â€”Zbâ€”Rb, R33 is hydrogen or (C1-C4)alkyl; R34 in the event that m=1, or the R34 independently of one another, in the event that m is greater than 1, is in each case halogen, cyano, nitro, amino, hydroxyl, carboxyl, CHO, CONH2, SO2NH2 or a radical of the formula â€”Zcâ€”Rc, Ra is a hydrocarbon radical or a heterocyclyl radical, each of the two last-mentioned radicals are unsubstituted or substituted by one or more identical or different radicals selected from the group consisting of halogen, cyano, nitro, amino, hydroxyl, mono- and di-[(C1-C4)alkyl]amino, or is an alkyl radical in which more than one nonadjacent CH2 groups are each replaced by an oxygen atom, Rb, Rc independently one another are a hydrocarbon radical or a heterocyclyl radical, each of the two last-mentioned radicals being unsubstituted or substituted by one or more identical or different radicals selected from the group consisting of halogen, cyano, nitro, amino, hydroxyl, phosphoryl, halo(C1-C4)alkoxy, mono- and di[(C1-C4)alkyl]amino, or are an alkyl radical in which more than one nonadjacent CH2 groups are each replaced by an oxygen atom, Za is a divalent group of the formula â€”Oâ€”, â€”Sâ€”, â€”COâ€”, â€”CSâ€”, â€”COâ€”Oâ€”, â€”COâ€”Sâ€”, â€”Oâ€”COâ€”, â€”Sâ€”COâ€”, â€”SOâ€”, â€”SO2â€”, â€”NR*â€”, â€”COâ€”NR*â€”, â€”NR*â€”COâ€”, â€”SO2â€”NR*â€” or â€”NR*â€”SO2â€”, the bond shown on the right of the divalent group in question being the bond to the radical Ra and the R* in the last-mentioned 5 radicals independently of one another being in each case H, (C1-C4)alkyl or halo(C1-C4)alkyl, Zb, Zc independently of one another are a direct bond or a divalent group of the formula â€”Oâ€”, â€”Sâ€”, â€”COâ€”, â€”CSâ€”, â€”COâ€”Oâ€”, â€”COâ€”Sâ€”, â€”Oâ€”COâ€”, â€”Sâ€”COâ€”, â€”SOâ€”, â€”SO2â€”, â€”NR*â€”, â€”SO2â€”NR*â€”, â€”NR*â€”SO2â€”, â€”COâ€”NR*â€”or â€”NR*â€”COâ€”, the bond shown on the right of the divalent group in question being the bond to the radical Rb or Rc, respectively, and the R* in the last-mentioned 5 radicals independently of one another being in each case H, (C1-C4)alkyl or halo(C1-C4)alkyl, n is an integer from 0 to 4, and m is an integer from 0 to 5; or d) Acylsulfamoylbenzamides of the formula (VI), if appropriate in salt form, â€ƒwhere X3 is CH or N; R35 is hydrogen, heterocyclyl or a hydrocarbon radical, the two last-mentioned radicals are optionally substituted by one or more, identical or different radicals selected from the group consisting of halogen, cyano, nitro, amino, hydroxyl, carboxyl, CHO, CONH2, SO2NH2 and Zaâ€”Ra; R36 is hydrogen, hydroxyl, (C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C1-C6)alkoxy, (C2-C6)alkenyloxy, the five last-mentioned radicals are optionally substituted by one or more identical or different radicals selected from the group consisting of halogen, hydroxyl, (C1-C4)alkyl, (C1-C4)alkoxy and (C1-C4)alkylthio, or R35 and R36 together with the nitrogen atom to which they are attached are a 3- to 8-membered saturated or unsaturated ring; R37 is halogen, cyano, nitro, amino, hydroxyl, carboxyl, CHO, CONH2, SO2NH2 or Zbâ€”Rb; R38 is hydrogen, (C1-C4)alkyl, (C2-C4)alkenyl or (C2-C4)alkynyl; R39 is halogen, cyano, nitro, amino, hydroxyl, carboxyl, phosphoryl, CHO, CONH2, SO2NH2 or Zcâ€”Rc; Ra is a (C2-C20)alkyl radical whose carbon chain is interrupted once or more by oxygen atoms, or is heterocyclyl or a hydrocarbon radical, the two last-mentioned radicals are optionally substituted by one or more, identical or different radicals selected from the group consisting of halogen, cyano, nitro, amino, hydroxyl, mono- and di[(C1-C4)alkyl]amino; Rb, Rcidentical or different are a (C2-C20)alkyl radical whose carbon chain is interrupted once or more by oxygen atoms, or are heterocyclyl or a hydrocarbon radical the two last-mentioned radicals are optionally substituted by one or more identical or different radicals selected from the group consisting of halogen, cyano, nitro, amino, hydroxyl, phosphoryl, (C1-C4)haloalkoxy, mono- and di[(C1-C6)alkyl]amino; Za is a divalent unit selected from the group consisting of O, S, CO, CS, C(O)O, C(O)S, SO, SO2, NRd, C(O)NRd and SO2NRd; Zb, Zc independently of one another are a direct bond or a divalent unit selected from the group consisting of O, S, CO, CS, C(O)O, C(O)S, SO, SO2, NRd, SO2NRd and C(O)NRd; Rd is hydrogen, (C1-C4)alkyl or (C1-C4)haloalkyl; n is an integer from 0 to 4; and m in the event that X is CH, is an integer from 0 to 5 and, in the event that X is N, is an integer from 0 to 4; inclusive of the stereoisomers and of the salts conventionally used in agriculture.