An isolable stannaimine and its cycloaddition/metathesis reactions with carbon dioxide.
Evans, Matthew J.; Parr, Joseph M.; Nguyen, Dat T.; Jones, Cameron; Chemical communications (Cambridge, England) 60 (2024) 10350–10353; doi:10.1039/d4cc04006f

data_7133605
_publ_section_title
;
 An isolable stannaimine and its cycloaddition/metathesis reactions with
 carbon dioxide.
;
_journal_issue                   75
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              10350
_journal_page_last               10353
_journal_paper_doi               10.1039/d4cc04006f
_journal_volume                  60
_journal_year                    2024
_chemical_formula_sum            'C62 H100 N4 O2 S2 Si4 Sn2'
_chemical_formula_weight         1347.31
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2024-08-06 deposited with the CCDC.	2024-08-26 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_computing_cell_refinement       'XDS (Kabsch, 2010)'
_computing_data_collection       'AS QEGUI'
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_exptl_absorpt_coefficient_mu    0.964
_exptl_absorpt_correction_T_max  'Value not reported by XDS'
_exptl_absorpt_correction_T_min  'Value not reported by XDS'
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'XDS (Kabsch, 2010)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.397
_exptl_crystal_description       plate
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_exptl_crystal_size_mid          0.080
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_exptl_transmission_factor_max   'Value not reported by XDS'
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_refine_diff_density_max         0.980
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0296
_refine_ls_R_factor_gt           0.0278
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0461P)^2^+1.6640P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0771
_refine_ls_wR_factor_ref         0.0787
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6116
_reflns_number_total             6512
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4cc04006f2.cif
_cod_data_source_block           cj1692
_cod_depositor_comments
'Adding full bibliography for 7133593--7133605.cif.'
_cod_original_cell_volume        3203.7(12)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7133605
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.910
_shelx_estimated_absorpt_t_max   0.962
_shelx_res_checksum              65606
_shelx_hkl_checksum              82882