<i>catena</i>-Poly[[lead(II)-μ-(2-oxidobenzaldehyde isonicotinoylhydrazonato)] methanol monosolvate]
Shahverdizadeh, Gholam Hossein; Ng, Seik Weng; Tiekink, Edward R. T.; Mirtamizdoust, Babak; Acta Crystallographica Section E 67 (2011) m1583–; doi:10.1107/S1600536811043078

data_2232469
_publ_section_title
;
 <i>catena</i>-Poly[[lead(II)-\m-(2-oxidobenzaldehyde
 isonicotinoylhydrazonato)] methanol monosolvate]
;
_journal_coeditor_code           SU2329
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1583
_journal_paper_doi               10.1107/S1600536811043078
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Pb (C13 H9 N3 O2)], C H4 O'
_chemical_formula_moiety         'C13 H9 N3 O2 Pb, C H4 O'
_chemical_formula_sum            'C14 H13 N3 O3 Pb'
_chemical_formula_weight         478.46
_chemical_name_systematic
;
<i>catena</i>-Poly[[lead(II)-\m-(2-oxidobenzaldehyde
isonicotinoylhydrazonato)] methanol monosolvate]
;
_space_group_IT_number           148
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            18
_cell_length_a                   28.6702(5)
_cell_length_b                   28.6702(5)
_cell_length_c                   9.0146(2)
_cell_measurement_reflns_used    12065
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.2941
_cell_measurement_theta_min      2.3988
_cell_volume                     6417.1(2)
_computing_cell_refinement       'CrysAlis PRO (Agilent, 2010)'
_computing_data_collection       'CrysAlis PRO (Agilent, 2010)'
_computing_data_reduction        'CrysAlis PRO (Agilent, 2010)'
_computing_molecular_graphics
;
ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)
;
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.4041
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type
'Agilent SuperNova Dual diffractometer with an Atlas detector'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  Mirror
_diffrn_radiation_source         'SuperNova (Cu) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0264
_diffrn_reflns_av_sigmaI/netI    0.0169
_diffrn_reflns_limit_h_max       35
_diffrn_reflns_limit_h_min       -35
_diffrn_reflns_limit_k_max       35
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            17626
_diffrn_reflns_theta_full        26.50
_diffrn_reflns_theta_max         26.50
_diffrn_reflns_theta_min         2.40
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    11.844
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.34874
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrysAlis PRO; Agilent, 2010)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.229
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             4032
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.950
_refine_diff_density_min         -0.600
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.108
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     193
_refine_ls_number_reflns         2958
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.108
_refine_ls_R_factor_all          0.0161
_refine_ls_R_factor_gt           0.0146
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0114P)^2^+19.9099P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0318
_refine_ls_wR_factor_ref         0.0322
_reflns_number_gt                2816
_reflns_number_total             2958
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            su2329.cif
_cod_data_source_block           I
_cod_original_cell_volume        6417.1(3)
_cod_original_sg_symbol_H-M      'R -3'
_cod_database_code               2232469
_cod_database_fobs_code          2232469