Aurophilicity-Coordination Interplay in the Design of Cyano-Bridged Nickel(II)-Gold(I) Bimetallic Assemblies: Structural and Computational Studies of the Gold(I)-Gold(I) Interactions
Enrique Colacio; Francesc Lloret; Raikko Kivekäs; José Suárez-Varela; Markku R. Sundberg; Rolf Uggla; Inorganic Chemistry 42 (2003) 560–565; doi:10.1021/ic025949w

data_4312972
_publ_contact_author
;
     Prof. Enrique Colacio
     Departamento de Qu\'imica Inorg\'anica
     Facultad de Ciencias
     Universidad de Granada
     E-18071 Granada
     Spain
;
_publ_contact_author_email       ecolacio@ugr.es
_publ_contact_author_fax         '+34 958 248526'
_publ_contact_author_phone       '+34 958 243236'
_publ_section_title
;
 Aurophilicity-Coordination Interplay in the Design of Cyano-Bridged
 Nickel(II)-Gold(I) Bimetallic Assemblies: Structural and Computational
 Studies of the Gold(I)-Gold(I) Interactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              560
_journal_page_last               565
_journal_paper_doi               10.1021/ic025949w
_journal_volume                  42
_journal_year                    2003
_chemical_formula_moiety         'C6 H16 Au1 N6 Ni1, C2 N2 Au1'
_chemical_formula_sum            'C8 H16 Au2 N8 Ni'
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_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
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_atom_sites_solution_hydrogens   geom
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_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 119.21(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
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_cell_length_b                   13.075(3)
_cell_length_c                   6.524(2)
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;
MSC/AFC Diffractometer Control Software (Molecular Structure Corporation, 
1993a)
;
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MSC/AFC Diffractometer Control Software (Molecular Structure Corporation, 
1993a)
;
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;
Texsan Process (Molecular Structure Corporation, 1993b)
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_refine_ls_R_factor_all          0.0683
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_refine_ls_structure_factor_coef Fsqd
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;
w=1/[\s^2^(Fo^2^)+(0.0839P)^2^+1.9071P] where P=(Fo^2^+2Fc^2^)/3 
;
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_cod_data_source_file            ic025949w_s1_2.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_geom_angle_publ_flag' value 'Y' changed to 'y' according to the
built-in table from CIF Core dictionary named 'cif_core.dic' version
2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        764.3(3)
_cod_database_code               4312972