(Nitrato-κ^2^<i>O</i>,<i>O</i>')bis(tryptanthrin-κ<i>N</i>)silver(I)
Wu, Jie; Huang, Chao; Li, Guo-Qiang; Tian, Hai-Yan; Jiang, Ren-Wang; Acta Crystallographica Section E 68 (2012) m185–m186; doi:10.1107/S1600536812001821

data_2233614
_publ_section_title
;
 (Nitrato-\k^2^<i>O</i>,<i>O</i>')bis(tryptanthrin-\k<i>N</i>)silver(I)
;
_journal_coeditor_code           RN2096
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m185
_journal_page_last               m186
_journal_paper_doi               10.1107/S1600536812001821
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Ag (N O3) (C15 H8 N2 O2)2]'
_chemical_formula_moiety         'C30 H16 Ag N5 O7'
_chemical_formula_sum            'C30 H16 Ag N5 O7'
_chemical_formula_weight         666.35
_chemical_name_common
;
(Nitrato-\k^2^<i>O</i>,<i>O</i>')bis(tryptanthrin-\k<i>N</i>)silver(I)
;
_chemical_name_systematic
;
Bis(indolo[2,1-<i>b</i>]quinazoline-6,12-dione-\k<i>N</i>)(nitrato-
\k^2^<i>O</i>,<i>O</i>')silver(I)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                76.010(4)
_cell_angle_beta                 81.019(4)
_cell_angle_gamma                84.447(4)
_cell_formula_units_Z            2
_cell_length_a                   8.0598(19)
_cell_length_b                   10.873(3)
_cell_length_c                   14.541(3)
_cell_measurement_reflns_used    9843
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      80.90
_cell_measurement_theta_min      3.16
_cell_volume                     1219.0(5)
_computing_cell_refinement       'SMART and SAINT (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'XPREP  (Bruker, 1998)'
_computing_molecular_graphics    'XP in SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.960
_diffrn_measured_fraction_theta_max 0.960
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71074
_diffrn_reflns_av_R_equivalents  0.0339
_diffrn_reflns_av_sigmaI/netI    0.0665
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            9843
_diffrn_reflns_theta_full        27.08
_diffrn_reflns_theta_max         27.08
_diffrn_reflns_theta_min         1.46
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.893
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6256
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2004)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.815
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             668
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.22
_refine_diff_density_max         1.076
_refine_diff_density_min         -0.630
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     388
_refine_ls_number_reflns         5150
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0678
_refine_ls_R_factor_gt           0.0428
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0565P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0965
_refine_ls_wR_factor_ref         0.1083
_reflns_number_gt                3893
_reflns_number_total             5150
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            rn2096.cif
_cod_data_source_block           I
_cod_database_code               2233614
_cod_database_fobs_code          2233614