Two novel trimethylsulfonium salts with polymeric {[SbCl~4~]^{-^}}~<i>n~</i> or {[CdCl~3~]^{-^}}~<i>n~</i> anions
Liu, Ming-Liang; Kong, Li-Hui; Acta Crystallographica Section C 70 (2014) 169–172; doi:10.1107/S2053229613034207

data_2019398
_publ_section_title
;
 Two novel trimethylsulfonium salts with polymeric
 {[SbCl~4~]^{-^}}~<i>n~</i> or {[CdCl~3~]^{-^}}~<i>n~</i> anions
;
_journal_coeditor_code           KU3119
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              169
_journal_page_last               172
_journal_paper_doi               10.1107/S2053229613034207
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac          '(C3 H9 S) [Sb Cl4]'
_chemical_formula_moiety         'C3 H9 S +, Cl4 Sb -'
_chemical_formula_sum            'C3 H9 Cl4 S Sb'
_chemical_formula_weight         340.71
_chemical_name_systematic
;
Poly[trimethylsulfonium [[dichloridoantimony(III)]-di-\m-chlorido]]
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.58(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   13.182(3)
_cell_length_b                   13.214(3)
_cell_length_c                   12.374(3)
_cell_measurement_reflns_used    2461
_cell_measurement_temperature    293(2)
_cell_volume                     2154.6(9)
_computing_cell_refinement       'CrystalClear (Rigaku, 2005)'
_computing_data_collection       'CrystalClear (Rigaku, 2005)'
_computing_data_reduction        'CrystalClear (Rigaku, 2005)'
_computing_molecular_graphics
;
PLATON (Spek, 2009) and DIAMOND (Brandenburg & Putz, 2005)
;
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku Mercury2'
_diffrn_measurement_method       'CCD profile fitting'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0310
_diffrn_reflns_av_sigmaI/netI    0.0208
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            10903
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         3.08
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 180
_diffrn_standards_interval_time  9
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.677
_exptl_absorpt_correction_T_max  0.355
_exptl_absorpt_correction_T_min  0.275
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrystalClear; Rigaku, 2005)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.101
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1296
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.28
_refine_diff_density_max         0.487
_refine_diff_density_min         -0.386
_refine_ls_extinction_coef       0.00423(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL97 (Sheldrick, 2008)'
_refine_ls_goodness_of_fit_ref   1.217
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     89
_refine_ls_number_reflns         2461
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.217
_refine_ls_R_factor_all          0.0225
_refine_ls_R_factor_gt           0.0204
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0117P)^2^+2.4036P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0443
_refine_ls_wR_factor_ref         0.0448
_reflns_number_gt                2335
_reflns_number_total             2461
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            ku3119sup1.cif
_cod_data_source_block           Sb
_cod_original_cell_volume        2154.7(7)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2019398