Diethyl <i>cis</i>-4,8-dioxo-3,4,7,8-tetrahydro-1<i>H</i>,5<i>H</i>-2,6-dioxa-3a,4a,7a,8a-tetraazacyclopenta[<i>def</i>]fluorene-8b,8c-dicarboxylate
Neng-Fang She; Hai-Ling Xi; Acta Crystallographica Section E 63 (2007) o3495–o3495; doi:10.1107/S1600536807033739

data_2214722
_publ_section_title
;Diethyl
 <i>cis</i>-4,8-dioxo-3,4,7,8-tetrahydro-1<i>H</i>,5<i>H</i>-2,6-dioxa-3a,4a,7a,8a-tetraazacyclopenta[<i>def</i>]fluorene-8b,8c-dicarboxylate
;
_journal_coeditor_code           HK2272
_journal_issue                   8
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              o3495
_journal_page_last               o3495
_journal_paper_doi               10.1107/S1600536807033739
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          'C14 H18 N4 O8'
_chemical_formula_moiety         'C14 H18 N4 O8'
_chemical_formula_sum            'C14 H18 N4 O8'
_chemical_formula_weight         370.32
_chemical_name_systematic
;
Diethyl cis-4,8-dioxo-3,4,7,8-tetrahydro-1H,5H-2,6-dioxa-3a,4a,7a,8a-
tetraazacyclopenta[def]fluorene-8b,8c-dicarboxylate
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.429(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.3182(11)
_cell_length_b                   12.4523(17)
_cell_length_c                   9.0479(12)
_cell_measurement_reflns_used    1973
_cell_measurement_temperature    292(2)
_cell_measurement_theta_max      24.89
_cell_measurement_theta_min      2.42
_cell_volume                     872.4(2)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  'SHELXTL (Bruker, 2001)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      292(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker SMART 4 K CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0238
_diffrn_reflns_av_sigmaI/netI    0.0285
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_number            5178
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         2.42
_exptl_absorpt_coefficient_mu    0.117
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.410
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             388
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.152
_refine_diff_density_min         -0.182
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.106
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     242
_refine_ls_number_reflns         1983
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.106
_refine_ls_R_factor_all          0.0474
_refine_ls_R_factor_gt           0.0423
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0548P)^2^+0.0447P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1019
_refine_ls_wR_factor_ref         0.1050
_reflns_number_gt                1764
_reflns_number_total             1983
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hk2272.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               2214722
_cod_database_fobs_code          2214722