Copper-Catalyzed Tandem [2,3]-Rearrangement and 6π-3-Azatriene Electrocyclization in (E)-O-Propargylic α,β-Unsaturated Oximes
Itaru Nakamura; Dong Zhang; Masahiro Terada; Journal of the American Chemical Society 133 (2011) 6862–6862; doi:10.1021/ja201076c

data_4106078
_publ_contact_author_email       itaru-n@m.tohoku.ac.jp
_publ_contact_author_fax         +81-22-795-6754
_publ_contact_author_name        'Itaru Nakamura'
_publ_contact_author_phone       +81-22-795-6602
_publ_section_title
;
 Copper-Catalyzed Tandem [2,3]-Rearrangement and 6\p-3-Azatriene
 Electrocyclization in (E)-O-Propargylic \a,\b-Unsaturated Oximes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              6862
_journal_page_last               6862
_journal_paper_doi               10.1021/ja201076c
_journal_volume                  133
_journal_year                    2011
_chemical_formula_moiety         'C24 H19 N O'
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_cell_length_b                   14.492(4)
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_cell_measurement_theta_min      3.22
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_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2006)'
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_diffrn_ambient_temperature      173
_diffrn_detector_area_resol_mean 7.314
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
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_exptl_absorpt_coefficient_mu    0.074
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_exptl_absorpt_correction_type   numerical
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_refine_ls_structure_factor_coef Fsqd
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'w = 1/[\s^2^(Fo^2^)+(0.0242P)^2^+2.8831P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_file            ja201076c_si_001.cif
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