A simple one-pot route to stable formamidinatoiodidolanthanoid(III) complexes from lanthanoid metals.
Guo, Zhifang; Blair, Victoria L.; Deacon, Glen B.; Junk, Peter C.; Chemical communications (Cambridge, England) 57 (2021) 11513–11516; doi:10.1039/d1cc04080d

data_7129071
_publ_section_title
;
 A simple one-pot route to stable formamidinatoiodidolanthanoid(III)
 complexes from lanthanoid metals.
;
_journal_issue                   87
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              11513
_journal_page_last               11516
_journal_paper_doi               10.1039/d1cc04080d
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C25 H31 F4 I2 N2 Nd O3'
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Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
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_audit_update_record
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2021-10-04 deposited with the CCDC.	2021-10-08 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0068P)^2^+2.7416P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7129070--7129084.cif.'
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_olex2_refinement_description
;
1.a Secondary CH2 refined with riding coordinates:
 C23(H23A,H23B), C24(H24A,H24B), C25(H25A,H25B), C18(H18A,H18B), C21(H21A,
 H21B), C17(H17A,H17B), C22(H22A,H22B), C19(H19A,H19B), C15(H15A,H15B),
 C14(H14A,H14B), C16(H16A,H16B), C20(H20A,H20B)
1.b Aromatic/amide H refined with riding coordinates:
 C7(H7), C11(H11), C2(H2), C3(H3), C10(H10), C4(H4), C12(H12)
;
_shelx_res_checksum              35114
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_olex2_submission_special_instructions 'No special instructions were received'