Cobalt–NHC promoted selective functionalization of alkynes via auxiliary-ligand modulation
Sahoo, Sangita; Pandey, Vipin K.; Barik, Jogendrananda; Rit, Arnab; Catalysis Science & Technology 15 (2025) 734–740; doi:10.1039/D4CY01375A

data_1573436
_publ_section_title
;
 Cobalt--NHC promoted selective functionalization of alkynes via
 auxiliary-ligand modulation
;
_journal_issue                   3
_journal_name_full               'Catalysis Science &amp; Technology'
_journal_page_first              734
_journal_page_last               740
_journal_paper_doi               10.1039/D4CY01375A
_journal_volume                  15
_journal_year                    2025
_chemical_formula_sum            'C20 H27 Br Co N3 O5'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2024-05-22 deposited with the CCDC.	2024-12-10 downloaded from the CCDC.
;
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'ORTEP3 (Farrugia, 1997) and Mercury (Bruno et al., 2002)'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0934P)^2^+1.6499P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1491
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           co
_cod_depositor_comments          'Adding full bibliography for 1573436.cif.'
_cod_original_cell_volume        2295.1(7)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1573436
_shelx_shelxl_version_number     2019/3
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_shelx_res_checksum              40825
_shelx_hkl_checksum              71624