Stabilization of a bismuth-bismuth double bond by anionic N-heterocyclic carbenes.
Ho, Luong Phong; Tamm, Matthias; Dalton transactions (Cambridge, England : 2003) 50 (2021) 1202–1205; doi:10.1039/d1dt00140j

data_7706446
_publ_section_title
;
 Stabilization of a bismuth-bismuth double bond by anionic N-heterocyclic
 carbenes.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               1205
_journal_paper_doi               10.1039/d1dt00140j
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C45 H35 B Bi Cl2 F15 N2,3(C6 H6)'
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;
2020-12-14 deposited with the CCDC.	2021-01-18 downloaded from the CCDC.
;
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'SHELXS-2014/5 (G. M. Sheldrick, Acta Cryst., 2015, A71, 3-8)'
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;
CrysAlisPro 1.171.40.59a (Rigaku Oxford Diffraction, 2019)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_exptl_crystal_size_mid          0.185
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0237P)^2^+36.6437P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7706446--7706447.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
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