[Bis(diphenylphosphino)amine-κ^2^<i>P</i>,<i>P</i>'][1,3-bis(diphenylphosphino)propane-κ^2^<i>P</i>,<i>P</i>']platinum(II) dichloride dichloromethane solvate
İri̇şli̇, Sevi̇l; Şen, Ayten; Acta Crystallographica Section E 61 (2005) m2097–m2099; doi:10.1107/S1600536805029880

data_2207045
_publ_section_title
;[Bis(diphenylphosphino)amine-\k^2^<i>P</i>,<i>P</i>'][1,3-bis(diphenylphosphino)propane-\k^2^<i>P</i>,<i>P</i>']platinum(II)
 dichloride dichloromethane solvate
;
_journal_coeditor_code           OM6258
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2097
_journal_page_last               m2099
_journal_paper_doi               10.1107/S1600536805029880
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac
'[Pt (C24 H21 N P2) (C27 H26 P2)] Cl2, C H2 Cl2'
_chemical_formula_moiety         'C51 H47 N P4 Pt 2+, 2Cl-, C H2 Cl2'
_chemical_formula_sum            'C52 H49 Cl4 N P4 Pt'
_chemical_formula_weight         1148.69
_chemical_melting_point          533
_chemical_name_systematic
;
1,3-(bis(diphenylphosphino)propane bis(diphenylphosphino)amine
platinum(II) chloride
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.049(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.2069(11)
_cell_length_b                   22.302(2)
_cell_length_c                   17.8300(16)
_cell_measurement_reflns_used    3963
_cell_measurement_temperature    297(2)
_cell_measurement_theta_max      19.73
_cell_measurement_theta_min      2.20
_cell_volume                     4853.2(8)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2001)'
_diffrn_ambient_temperature      297(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0743
_diffrn_reflns_av_sigmaI/netI    0.0717
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            38986
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         1.46
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.280
_exptl_absorpt_correction_T_max  0.7793
_exptl_absorpt_correction_T_min  0.6219
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker 2001)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.572
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2296
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.327
_refine_diff_density_min         -1.764
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.136
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     563
_refine_ls_number_reflns         9916
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.136
_refine_ls_R_factor_all          0.0702
_refine_ls_R_factor_gt           0.0554
_refine_ls_shift/su_max          0.015
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0273P)^2^+2.9082P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0965
_refine_ls_wR_factor_ref         0.1015
_reflns_number_gt                8258
_reflns_number_total             9916
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            om6258.cif
_cod_data_source_block           I
_cod_original_cell_volume        4853.3(8)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2207045
_cod_database_fobs_code          2207045