Isolable cyclic (alkyl)(amino)carbene-phosphonyl radical adducts.
Livshits-Kritsman, Yulia; Tumanskii, Boris; Ménard, Gabriel; Dobrovetsky, Roman; Chemical communications (Cambridge, England) 56 (2020) 1341–1344; doi:10.1039/c9cc09244g

data_7125675
_publ_section_title
;
 Isolable cyclic (alkyl)(amino)carbene-phosphonyl radical adducts.
;
_journal_issue                   9
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              1341
_journal_page_last               1344
_journal_paper_doi               10.1039/c9cc09244g
_journal_volume                  56
_journal_year                    2020
_chemical_formula_moiety         'C26 H45 N O3 P'
_chemical_formula_sum            'C26 H45 N O3 P'
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_space_group_name_Hall           '-P 1'
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_audit_update_record
;
2019-11-21 deposited with the CCDC.	2019-12-20 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      110(2)
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_diffrn_measurement_device_type  'ApexDuo, Bruker-AXS'
_diffrn_measurement_method       '0.5 deg. \f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_max         28.462
_diffrn_reflns_theta_min         1.322
_diffrn_source                   'ImuS micro-focus'
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_exptl_absorpt_correction_T_max  0.984
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_exptl_crystal_colour            yellow
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_exptl_crystal_description       prism
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         6695
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0468
_refine_ls_R_factor_gt           0.0385
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0459P)^2^+0.4033P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0952
_refine_ls_wR_factor_ref         0.1008
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5674
_reflns_number_total             6695
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9cc09244g2.cif
_cod_data_source_block           rom93
_cod_depositor_comments
'Adding full bibliography for 7125674--7125677.cif.'
_cod_database_code               7125675
_shelx_shelxl_version_number     2018/1
_shelx_estimated_absorpt_t_min   0.958
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_shelx_res_checksum              87063