Noncovalent Trapping and Stabilization of Dinuclear Ruthenium Complexes within a Coordination Cage
Shinnosuke Horiuchi; Takashi Murase; Makoto Fujita; Journal of the American Chemical Society 133 (2011) 12445–12447; doi:10.1021/ja205450a

data_4106583
_publ_contact_author             'Makoto Fujita'
_publ_contact_author_email       mfujita@appchem.t.u-tokyo.ac.jp
_publ_section_title
;
 Noncovalent Trapping and Stabilization of Dinuclear Ruthenium Complexes
 within a Coordination Cage
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              12445
_journal_page_last               12447
_journal_paper_doi               10.1021/ja205450a
_journal_volume                  133
_journal_year                    2011
_chemical_formula_sum            'C260 H316 N78.89 O120.31 Pd12 Ru4'
_chemical_formula_weight         8152.34
_chemical_name_systematic
; 
 ? 
;
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_cell_formula_units_Z            2
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_cell_measurement_temperature    90(2)
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_cell_measurement_theta_min      3.761
_cell_volume                     22839(13)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX-II'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker XP'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      90(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  'focusing mirror'
_diffrn_radiation_source         'fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_limit_k_min       -37
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_diffrn_reflns_theta_max         28.69
_diffrn_reflns_theta_min         3.70
_diffrn_standards_decay_%        none
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_exptl_absorpt_correction_T_max  0.9614
_exptl_absorpt_correction_T_min  0.8574
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_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            purple
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_exptl_crystal_description       Needle
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_exptl_crystal_size_min          0.06
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.2206
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     >2sigma(I)
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