Hydrocarbyl derivatives of dppm- or dppa-bridged alkoxysilyl heterobimetallic Fe‒Pd complexes and CO insertion reactions. Crystal structures of [(OC)3{(MeO)3Si}Fe(μ-dppm)Pd(8-mq)] (dppm = Ph2PCH2PPh2), [(OC)3Fe{μ-Si(OMe)2(OMe)}(μ-dppa)PdCl] and [(OC)3Fe{μ-Si(OMe)2(OMe)}(μ-dppa)PdPh] (dppa = Ph2PNHPPh2) †
Braunstein, Pierre; Durand, Jérôme; Kickelbick, Guido; Knorr, Michael; Morise, Xavier; Pugin, Raphael; Tiripicchio, Antonio; Ugozzoli, Franco; Journal of the Chemical Society, Dalton Transactions  (1999) 4175–; doi:10.1039/a907425b

data_7027800
_publ_section_title
;
 Hydrocarbyl derivatives of dppm- or dppa-bridged alkoxysilyl
 heterobimetallic Fe--Pd complexes and CO insertion reactions. Crystal
 structures of [(OC)3{(MeO)3Si}&#xE010;Fe(\m-dppm)P&#xE011;d(8-mq)]
 (dppm&#x2005;=&#x2005;Ph2PCH2PPh2),
 [(OC)3&#xE010;Fe{\m-Si(OMe)2(&#xE012;OMe)}(\m-dppa)P&#xE013;&#xE011;dCl]
 and
 [(OC)3&#xE010;Fe{\m-Si(OMe)2(&#xE012;OMe)}(\m-dppa)P&#xE013;&#xE011;dPh]
 (dppa&#x2005;=&#x2005;Ph2PNHPPh2)&#x200A;&#x2020;
;
_journal_issue                   23
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              4175
_journal_paper_doi               10.1039/a907425b
_journal_year                    1999
_chemical_compound_source        ?
_chemical_formula_sum            'C47 H53 Fe N O6 P2 Pd Si'
_chemical_formula_weight         980.22
_chemical_name_systematic        ?
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00(0)
_cell_angle_beta                 97.00(2)
_cell_angle_gamma                90.00(0)
_cell_formula_units_Z            4.00
_cell_length_a                   11.562(2)
_cell_length_b                   21.028(3)
_cell_length_c                   18.837(3)
_cell_measurement_radiation      Mokalpha
_cell_measurement_reflns_used    30
_cell_measurement_temperature    298
_cell_measurement_theta_max      19
_cell_measurement_theta_min      13
_cell_measurement_wavelength     0.71073
_cell_volume                     4545.6(13)
_diffrn_ambient_temperature      298
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           Mokapha
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            8470
_diffrn_reflns_reduction_process ?
_diffrn_reflns_theta_max         25
_diffrn_reflns_theta_min         3
_exptl_absorpt_coefficient_mu    0.8596
_exptl_crystal_density_diffrn    1.4323
_exptl_crystal_description       ?
_exptl_crystal_F_000             2024.0
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.1
_refine_ls_goodness_of_fit_all   0.899
_refine_ls_number_constraints    1
_refine_ls_number_parameters     535
_refine_ls_number_reflns         2910
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.055
_refine_ls_wR_factor_all         0.075
_cod_data_source_file            907425bsup1.cif
_cod_data_source_block           (I)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_cell_measurement_temperature' value '298K' was changed to '298' -
the value should be numeric and without a unit
designator.

'_diffrn_ambient_temperature' value '298K' was changed
to '298' - the value should be numeric and without a unit designator.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        4546.(1)
_cod_original_sg_symbol_H-M      ' P 21/N        '
_cod_original_formula_sum        'Pd1 Fe1 P2 Si1 O6 N1 C47 H53 '
_cod_database_code               7027800