Synthesis, Characterization, and Biomimetic Chemistry of cis-Oxosulfidomolybdenum(VI) Complexes Stabilized by an Intramolecular Mo(O)S...S Interaction
Les J. Laughlin; Aston A. Eagle; Graham N. George; Edward R. T. Tiekink; Charles G. Young; Inorganic Chemistry 46 (2007) 939–948; doi:10.1021/ic061213d

data_4306923
_publ_section_title
;
Synthesis, Characterization, and Biomimetic Chemistry
of cis-Oxosulfidomolybdenum(VI) Complexes Stabilized by an Intramolecular
Mo(O)S...S Interaction
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              939
_journal_page_last               948
_journal_paper_doi               10.1021/ic061213d
_journal_volume                  46
_journal_year                    2007
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_chemical_formula_sum            'C21 H36 B Mo N6 O P S3'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_audit_creation_date             'Mon Mar  9 17:10:48 1998'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 90.09(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.601(1)
_cell_length_b                   10.899(1)
_cell_length_c                   20.595(3)
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_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
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_diffrn_measurement_device       CAD4
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_diffrn_orient_matrix_UB_11      0.00000
_diffrn_orient_matrix_UB_12      0.00000
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_diffrn_reflns_theta_min         3.0
_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 1
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.767
_exptl_absorpt_correction_type   analytical
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.462
_exptl_crystal_description       plate
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_exptl_crystal_size_max          0.240
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_refine_ls_R_factor_obs          0.0410
_refine_ls_shift/esd_max         0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0410
_reflns_number_observed          2390
_reflns_number_total             0
_reflns_observed_criterion       2.50
_cod_data_source_file            ic061213dsi20060702_100334.cif
_cod_data_source_block           Tp*MoOS(S2PPri2)
_cod_original_cell_volume        2828.5(4)
_cod_original_sg_symbol_H-M      'P 21/n '
_cod_original_formula_sum        'C21 H36 B Mo N6 O P S3 '
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