<i>catena</i>-Poly[[[diaqua(nitrato-κ^2^<i>O</i>,<i>O</i>')(2,2':6',2''-terpyridine-κ^3^<i>N</i>,<i>N</i>',<i>N</i>'')neodymium(III)]-μ-cyanido-κ^2^<i>N</i>:<i>C</i>-[dicyanidoplatinum(II)]-μ-cyanido-κ^2^<i>C</i>:<i>N</i>] acetonitrile solvate 2,2':6',2''-terpyridine hemisolvate]
Maynard, Branson A.; Smith, Philip A.; Sykora, Richard E.; Acta Crystallographica Section E 65 (2009) m1132–m1133; doi:10.1107/S160053680903325X

data_2223159
_publ_section_title
;<i>catena</i>-Poly[[[diaqua(nitrato-\k^2^<i>O</i>,<i>O</i>')(2,2':6',2''-terpyridine-\k^3^<i>N</i>,<i>N</i>',<i>N</i>'')neodymium(III)]-\m-cyanido-\k^2^<i>N</i>:<i>C</i>-[dicyanidoplatinum(II)]-\m-cyanido-\k^2^<i>C</i>:<i>N</i>]
 acetonitrile solvate 2,2':6',2''-terpyridine hemisolvate]
;
_journal_coeditor_code           NC2153
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1132
_journal_page_last               m1133
_journal_paper_doi               10.1107/S160053680903325X
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac
'[Nd Pt (C N)4 (N O3) (C15 H11 N3) (H2 O)2], C2 H3 N, 0.5C15 H11 N3'
_chemical_formula_moiety
'C19 H15 N8 Nd O5 Pt, C2 H3 N, 0.5(C15 H11 N3'
_chemical_formula_sum            'C28.5 H23.5 N10.5 Nd O5 Pt'
_chemical_formula_weight         932.4
_chemical_name_systematic
;
<i>catena</i>-Poly[[[diaqua(nitrato-\k^2^<i>O</i>,<i>O</i>')(2,2':6',2''-
terpyridine-\k^3^<i>N</i>,<i>N</i>',<i>N</i>'')neodymium(III)]-\m-cyanido-
\k^2^<i>N</i>:<i>C</i>-[dicyanidoplatinum(II)]-\m-cyanido-
\k^2^<i>C</i>:<i>N</i>] acetonitrile solvate 2,2':6',2''-terpyridine
hemisolvate]
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.931(16)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   33.231(6)
_cell_length_b                   14.3642(17)
_cell_length_c                   13.823(3)
_cell_measurement_pressure       101.3
_cell_measurement_reflns_used    25
_cell_measurement_temperature    290(2)
_cell_measurement_theta_max      15.41
_cell_measurement_theta_min      8.52
_cell_volume                     6241(2)
_computing_cell_refinement
;
<i>CAD-4-PC Software</i> (Enraf--Nonius, 1993)
;
_computing_data_collection
;
<i>CAD-4-PC Software</i> (Enraf--Nonius, 1993)
;
_computing_data_reduction        '<i>XCAD4</i> (Harms & Wocadlo, 1996)'
_computing_molecular_graphics    '<i>SHELXTL</i> (Sheldrick, 2008)'
_computing_publication_material  '<i>publCIF</i> (Westrip, 2009)'
_computing_structure_refinement  '<i>SHELXL97</i> (Sheldrick, 2008)'
_computing_structure_solution    '<i>SHELXS97</i> (Sheldrick, 2008)'
_diffrn_ambient_temperature      290(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Enraf--Nonius CAD-4'
_diffrn_measurement_method       \q/2\q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0310
_diffrn_reflns_av_sigmaI/netI    0.0795
_diffrn_reflns_limit_h_max       40
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            5824
_diffrn_reflns_theta_full        25.37
_diffrn_reflns_theta_max         25.37
_diffrn_reflns_theta_min         2.05
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  120
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    6.179
_exptl_absorpt_correction_T_max  0.6316
_exptl_absorpt_correction_T_min  0.3084
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details   '(SADABS; Bruker, 1998)'
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.985
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             3568
_exptl_crystal_size_max          0.452
_exptl_crystal_size_mid          0.168
_exptl_crystal_size_min          0.076
_refine_diff_density_max         0.855
_refine_diff_density_min         -0.844
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.996
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    44
_refine_ls_number_parameters     420
_refine_ls_number_reflns         5722
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.996
_refine_ls_R_factor_all          0.0759
_refine_ls_R_factor_gt           0.0355
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0283P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0769
_refine_ls_wR_factor_ref         0.0868
_reflns_number_gt                4089
_reflns_number_total             5722
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            nc2153.cif
_cod_data_source_block           I
_cod_original_cell_volume        6241.5(19)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C28.5 H23.5 N10.5 Nd1 O5 Pt1'
_cod_database_code               2223159
_cod_database_fobs_code          2223159