Nickel promoted functionalization of CO2 to anhydrides and ketoacids.
Greenburg, Zoe R.; Jin, Dong; G Williard, Paul; Bernskoetter, Wesley H.; Dalton transactions (Cambridge, England : 2003) 43 (2014) 15990–15996; doi:10.1039/c4dt01221f

data_7032622
_publ_section_title
;
 Nickel promoted functionalization of CO2 to anhydrides and ketoacids.
;
_journal_issue                   42
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15990
_journal_page_last               15996
_journal_paper_doi               10.1039/c4dt01221f
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C22 H36 N Ni P'
_chemical_formula_weight         404.20
_chemical_name_systematic        PNNiCOD
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                77.602(2)
_cell_angle_beta                 87.452(2)
_cell_angle_gamma                72.077(2)
_cell_formula_units_Z            2
_cell_length_a                   7.6680(4)
_cell_length_b                   9.5525(6)
_cell_length_c                   15.1227(9)
_cell_measurement_temperature    198(2)
_cell_volume                     1029.10(10)
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      198(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0221
_diffrn_reflns_av_unetI/netI     0.0142
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            28348
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.369
_diffrn_reflns_theta_min         2.413
_exptl_absorpt_coefficient_mu    1.025
_exptl_absorpt_correction_T_max  0.746
_exptl_absorpt_correction_T_min  0.698
_exptl_absorpt_correction_type   empirical
_exptl_crystal_density_diffrn    1.304
_exptl_crystal_F_000             436
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.460
_refine_diff_density_min         -0.431
_refine_diff_density_rms         0.053
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     232
_refine_ls_number_reflns         4205
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0278
_refine_ls_R_factor_gt           0.0253
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0369P)^2^+0.5094P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0666
_refine_ls_wR_factor_ref         0.0681
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3933
_reflns_number_total             4205
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c4dt01221f2.cif
_cod_data_source_block           wb18apr13_0m
_cod_depositor_comments
'Adding full bibliography for 7032621--7032623.cif.'
_cod_database_code               7032622
_shelx_estimated_absorpt_t_min   0.784
_shelx_estimated_absorpt_t_max   0.821
_shelxl_version_number           2013-2
_shelx_res_checksum              69334