Synthesis of Heteroleptic Bis(diimine)carbonylchlororuthenium(II) Complexes from Photodecarbonylated Precursors
Christopher M. Kepert; Glen B. Deacon; Norma Sahely; Leone Spiccia; Gary D. Fallon; Brian W. Skelton; Allan H. White; Inorganic Chemistry 43 (2004) 2818–2827; doi:10.1021/ic0351895

data_4310909
_publ_contact_author_address
;
   Department of Chemistry
   University of Western Australia
   Crawley  
   Western Australia 6009
   Australia
;
_publ_contact_author_email       bws@crystal.uwa.edu.au
_publ_contact_author_fax         (+61)_08_9380_1118
_publ_contact_author_name        'Skelton, B. W.'
_publ_contact_author_phone       (+61)_08-9380_3481
_publ_section_title
;
 Synthesis of Heteroleptic Bis(diimine)carbonylchlororuthenium(II)
 Complexes from Photodecarbonylated Precursors
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2818
_journal_page_last               2827
_journal_paper_doi               10.1021/ic0351895
_journal_volume                  43
_journal_year                    2004
_chemical_formula_sum            'C27 H24 Cl2 N4 O5 Ru'
_chemical_formula_weight         656.49
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_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
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_cell_angle_beta                 81.69(4)
_cell_angle_gamma                81.05(5)
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_cell_length_b                   11.172(6)
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_cell_measurement_theta_max      18.6
_cell_measurement_theta_min      16.3
_cell_volume                     1335.1(13)
_computing_cell_refinement       'Enraf Nonius software'
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_computing_molecular_graphics    xtal
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;
 CAD4  diffractometer
;
_diffrn_measurement_method       '2\q-\w scans'
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_diffrn_reflns_limit_k_min       -13
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_diffrn_standards_decay_%        0
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_exptl_absorpt_process_details
;
 XTAl absorb               
;
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_exptl_crystal_description       plate
_exptl_crystal_F_000             664
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_refine_diff_density_min         -1.235
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         .079
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_reflns_limit_h_min              0
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_reflns_limit_k_min              -12
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_reflns_limit_l_min              -9
_reflns_number_gt                3472
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_reflns_threshold_expression     'I    > 3.00 sig(I   )'
_cod_data_source_file            ic0351895si20040210_044127_5.cif
_cod_data_source_block           ck455
_cod_original_sg_symbol_Hall     -p_1
_cod_original_formula_sum        'C27 H24 Cl2 N4 O5 Ru1'
_cod_database_code               4310909