A three-component reaction of phosphorus ylides with isocyanates: facile synthesis of 2-amino-3-carboxylate-4-quinolones.
Babu, Kaki Raveendra; Han, Wendan; Chen, Jian-Bo; Li, Yang; Tang, Yuhai; Zhang, Wenquan; Xu, Wenbo; Xu, Silong; Chemical communications (Cambridge, England) 56 (2020) 5909–5912; doi:10.1039/d0cc01401j

data_7126393
_publ_section_title
;
 A three-component reaction of phosphorus ylides with isocyanates: facile
 synthesis of 2-amino-3-carboxylate-4-quinolones.
;
_journal_issue                   44
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              5909
_journal_page_last               5912
_journal_paper_doi               10.1039/d0cc01401j
_journal_volume                  56
_journal_year                    2020
_chemical_formula_moiety         'C63 H60 N2 O8 P2'
_chemical_formula_sum            'C63 H60 N2 O8 P2'
_chemical_formula_weight         1035.07
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2019-11-07 deposited with the CCDC.	2020-04-17 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_cell_length_b                   9.680(7)
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      296(2)
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_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0478
_diffrn_reflns_Laue_measured_fraction_full 1.000
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_refine_ls_R_factor_all          0.1032
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1258P)^2^+4.6773P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0cc01401j2.cif
_cod_data_source_block           mo_KRB05_20190301_0m
_cod_depositor_comments
'Adding full bibliography for 7126391--7126394.cif.'
_cod_original_cell_volume        5430(7)
_cod_original_sg_symbol_H-M      'C 2/c'
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_shelx_res_checksum              85190