Unexpected CC Bond Formation via Doubly Dehydrogenative Coupling of Two Saturated sp3 C-H Bonds Activated with a Polymolybdate
Qiang Li; Yongge Wei; Jian Hao; Yulin Zhu; Longsheng Wang; Journal of the American Chemical Society 129 (2007) 5810–5811; doi:10.1021/ja070600z

data_4109383
_publ_contact_author_address
;
Department of Chemistry
Tsinghua University
Beijing 100084
P. R. China
;
_publ_contact_author_email       ygwei@pku.edu.cn
_publ_contact_author_name        'Dr Yongge Wei'
_publ_section_title
;
 Unexpected CC Bond Formation via Doubly Dehydrogenative Coupling of Two
 Saturated sp3 C-H Bonds Activated with a Polymolybdate
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5810
_journal_page_last               5811
_journal_paper_doi               10.1021/ja070600z
_journal_volume                  129
_journal_year                    2007
_chemical_formula_sum            'C35 H77 Mo6 N3 O18'
_chemical_formula_weight         1403.64
_chemical_name_systematic
; 
 ? 
;
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_computing_cell_refinement       'Rigaku RAPID AUTO Ver2.30'
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_computing_molecular_graphics    'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
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_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
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_diffrn_radiation_source         'fine-focus sealed tube'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0430P)^2^+1.2568P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_file            ja070600zsi20070131_093528.cif
_cod_data_source_block           Mo12-Pr-Compound-1
_cod_original_cell_volume        2565.8(9)
_cod_database_code               4109383