All inorganic coordination polymers have been made possible with the m-carboranylphosphinate ligand.
Oleshkevich, Elena; Romero, Isabel; Teixidor, Francesc; Viñas, Clara; Dalton transactions (Cambridge, England : 2003) 47 (2018) 14785–14798; doi:10.1039/c8dt03264e

data_7047590
_publ_section_title
;
 All inorganic coordination polymers have been made possible with the
 m-carboranylphosphinate ligand.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14785
_journal_page_last               14798
_journal_paper_doi               10.1039/c8dt03264e
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         '2(C2 H12 B10 O2 P), Co O6'
_chemical_formula_sum            'C4 H24 B20 Co O10 P2'
_chemical_formula_weight         569.30
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-09-13 deposited with the CCDC.
2018-09-18 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_volume                     1416.7(5)
_computing_cell_refinement       'XDS (Kabsch, 1993)'
_computing_data_collection       'M2DM bruker'
_computing_data_reduction        'XDS (Kabsch, 1993)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    SHELXTL
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_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.873
_diffrn_measurement_device_type  'PILATUS DECTRIS 6M'
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_diffrn_radiation_type           'synchrotron radiation'
_diffrn_radiation_wavelength     0.799890
_diffrn_reflns_av_R_equivalents  0.1602
_diffrn_reflns_av_unetI/netI     0.0782
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.873
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_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.873
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_diffrn_reflns_theta_max         29.725
_diffrn_reflns_theta_min         1.195
_diffrn_source                   synchrotron
_exptl_absorpt_coefficient_mu    1.036
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.335
_exptl_crystal_description       plates
_exptl_crystal_F_000             570
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_refine_ls_R_factor_all          0.0898
_refine_ls_R_factor_gt           0.0868
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1486P)^2^+4.9980P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2434
_refine_ls_wR_factor_ref         0.2473
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1723
_reflns_number_total             1887
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt03264e2.cif
_cod_data_source_block           oe361-co_2
_cod_depositor_comments
'Adding full bibliography for 7047589--7047590.cif.'
_cod_database_code               7047590
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              53275