LMucko/crystallography-open-database huggingface dataset:
Ga~9~(CMe~3~)~9~, an Important New Building Block in the Structural Chemistry of the Alkylelement(I) Compounds EnRn (E=B-In)
Uhl, Werner; Cuypers, Lars; Harms, Klaus; Kaim, Wolfgang; Wanner, Matthias; Winter, Rainer; Koch, Rainer; Saak, Wolfgang; Zeitschrift für Anorganische und Allgemeine Chemie 40 (2001) 566–568; doi:10.1002/1521-3773(20010202)40:3<566::aid-anie566>3.0.co;2-t

data_1100213
_publ_section_title
;
 Ga~9~(CMe~3~)~9~, an Important New Building Block in the Structural
 Chemistry of the Alkylelement(I) Compounds EnRn (E=B-In)
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              566
_journal_page_last               568
_journal_paper_doi
10.1002/1521-3773(20010202)40:3<566::aid-anie566>3.0.co;2-t
_journal_volume                  40
_journal_year                    2001
_chemical_formula_moiety         'C36 H81 Ga9,0.33(C7 H8)'
_chemical_formula_sum            'C38.31 H83.64 Ga9'
_chemical_name_systematic
;
nonakis(t-Butyl-gallium(i)) toluene solvate
;
_space_group_IT_number           58
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      58
_symmetry_space_group_name_Hall  '-P 2 2n'
_symmetry_space_group_name_H-M   'P n n m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            12
_cell_length_a                   19.0073(5)
_cell_length_b                   21.8155(4)
_cell_length_c                   37.5145(7)
_cell_volume                     15555.528
_diffrn_ambient_temperature      193
_exptl_crystal_colour            black-green
_exptl_crystal_density_diffrn    1.498
_refine_ls_R_factor_gt           4.54
_refine_ls_wR_factor_gt          4.54
_cod_database_code               1100213
The Stereoselective Synthesis of 2-Substituted 3-Azabicyclo[3.2.0]heptanes by Intramolecular [2+2]-Photocycloaddition Reactions
Bach, Thorsten; Krüger, Christa; Harms, Klaus; Synthesis 2000 (2000) 305–320; doi:10.1055/s-2000-6261

data_1100214
_publ_section_title
;
 The Stereoselective Synthesis of 2-Substituted 3-Azabicyclo[3.2.0]heptanes
 by Intramolecular [2+2]-Photocycloaddition Reactions
;
_journal_coden_ASTM              SYNTBF
_journal_issue                   2
_journal_name_full               Synthesis
_journal_page_first              305
_journal_page_last               320
_journal_paper_doi               10.1055/s-2000-6261
_journal_volume                  2000
_journal_year                    2000
_chemical_formula_moiety         'C14 H15 N1 O2'
_chemical_formula_sum            'C14 H15 N O2'
_chemical_melting_point          397.15
_chemical_name_systematic
;
(3RS,4SR,6SR,7SR)-1-Aza-9-oxa-4-phenyltricyclo(5.3.0.0^3,6^)decan-10-one
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                96.28(2)
_cell_angle_beta                 90.192(19)
_cell_angle_gamma                98.240(19)
_cell_formula_units_Z            4
_cell_length_a                   6.434(1)
_cell_length_b                   7.4927(13)
_cell_length_c                   24.108(4)
_cell_volume                     1143.085
_diffrn_ambient_temperature      193
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.332
_exptl_crystal_description       needle
_refine_ls_R_factor_gt           4.52
_refine_ls_wR_factor_gt          4.52
_cod_original_formula_sum        'C14 H15 N1 O2'
_cod_database_code               1100214
Crystal structure of bis[bis(diethylether)lithium (trimethylsilyl)methyl-cyanocuprate], [(C~4~H~10~O)~2~Li(C~3~H~9~)SiCH~2~CuCN]~2~
Bosold, F.; Marsch, M.; Harms, K.; Boche, G.; Zeitschrift für Kristallographie - New Crystal Structures 216 (2001) 143–144; doi:10.1524/ncrs.2001.216.14.143

data_1100215
_publ_section_title
;
 Crystal structure of bis[bis(diethylether)lithium
 (trimethylsilyl)methyl-cyanocuprate],
 [(C~4~H~10~O)~2~Li(C~3~H~9~)SiCH~2~CuCN]~2~
;
_journal_coden_ASTM              ZKNSFT
_journal_issue                   1-4
_journal_name_full
;
 Zeitschrift f\"ur Kristallographie - New Crystal Structures
;
_journal_page_first              143
_journal_page_last               144
_journal_paper_doi               10.1524/ncrs.2001.216.14.143
_journal_volume                  216
_journal_year                    2001
_chemical_formula_moiety         'C26 H62 Cu2 Li2 N2 O4 Si2'
_chemical_formula_sum            'C26 H62 Cu2 Li2 N2 O4 Si2'
_chemical_name_systematic
;
bis((\m~3~-Cyano)-bis(diethylether)-(trimethylsilyl)methyl-copper(i)-lithium)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 106.091(9)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.0080(8)
_cell_length_b                   11.1636(6)
_cell_length_c                   18.0294(15)
_cell_volume                     1935.424
_diffrn_ambient_temperature      193
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.139
_exptl_crystal_description       Prism
_refine_ls_R_factor_gt           3.13
_refine_ls_wR_factor_gt          3.13
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1100215
Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~, [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~] und [Ni(PMePh~2~)~4~]
Krieger, Matthias; Gould, Robert O.; Harms, Klaus; Greiner, Andreas; Dehnicke, Kurt; Zeitschrift fuer Anorganische und Allgemeine Chemie 627 (2001) 747–754; doi:10.1002/1521-3749(200104)627:4<747::AID-ZAAC747>3.0.CO;2-H

data_1100216
_publ_section_title
;
 Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die
 Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~,
 [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~]
 und [Ni(PMePh~2~)~4~]
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   4
_journal_name_full
;
 Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_page_first              747
_journal_page_last               754
_journal_paper_doi
10.1002/1521-3749(200104)627:4<747::AID-ZAAC747>3.0.CO;2-H
_journal_volume                  627
_journal_year                    2001
_chemical_formula_moiety         'C16 H36 F12 N4 Ni4 O12 P4 S4'
_chemical_formula_sum            'C16 H36 F12 N4 Ni4 O12 P4 S4'
_chemical_name_systematic
;\
tetrakis(\m~3~-Trimethylphosphoraneiminato)-tris(trifluoromethanesulfonato-\
O,O')-(trifluoromethanesulfonato-O)-tetra-nickel(II)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 105.908(9)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.6666(15)
_cell_length_b                   14.7993(10)
_cell_length_c                   19.6063(18)
_cell_volume                     4371.722
_diffrn_ambient_temperature      193
_exptl_crystal_colour            black-violet
_exptl_crystal_density_diffrn    1.81
_exptl_crystal_preparation       dichloromethane/n-hexane
_refine_ls_R_factor_gt           4.43
_refine_ls_wR_factor_gt          4.43
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1100216
Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~, [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~] und [Ni(PMePh~2~)~4~]
Krieger, Matthias; Gould, Robert O.; Harms, Klaus; Greiner, Andreas; Dehnicke, Kurt; Zeitschrift fuer Anorganische und Allgemeine Chemie 627 (2001) 747–754; doi:10.1002/1521-3749(200104)627:4<747::AID-ZAAC747>3.0.CO;2-H

data_1100217
_publ_section_title
;
 Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die
 Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~,
 [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~]
 und [Ni(PMePh~2~)~4~]
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   4
_journal_name_full
;
 Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_page_first              747
_journal_page_last               754
_journal_paper_doi
10.1002/1521-3749(200104)627:4<747::AID-ZAAC747>3.0.CO;2-H
_journal_volume                  627
_journal_year                    2001
_chemical_formula_moiety         'C12 H38 Br2 N8 Ni1 P2'
_chemical_formula_sum            'C12 H38 Br2 N8 Ni P2'
_chemical_name_systematic
;
Dibromo-bis(tris(dimethylamino)phosphaneimine)-nickel(ii)
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 94.74(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   18.407(1)
_cell_length_b                   8.101(1)
_cell_length_c                   16.072(2)
_cell_volume                     2388.382
_diffrn_ambient_temperature      203
_exptl_crystal_colour            'deep blue'
_exptl_crystal_density_diffrn    1.599
_refine_ls_R_factor_gt           3.4
_refine_ls_wR_factor_gt          3.4
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C12 H38 Br2 N8 Ni1 P2'
_cod_database_code               1100217
Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~, [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~] und [Ni(PMePh~2~)~4~]
Krieger, Matthias; Gould, Robert O.; Harms, Klaus; Greiner, Andreas; Dehnicke, Kurt; Zeitschrift fuer Anorganische und Allgemeine Chemie 627 (2001) 747–754; doi:10.1002/1521-3749(200104)627:4<747::AID-ZAAC747>3.0.CO;2-H

data_1100218
_publ_section_title
;
 Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die
 Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~,
 [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~]
 und [Ni(PMePh~2~)~4~]
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   4
_journal_name_full
;
 Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_page_first              747
_journal_page_last               754
_journal_paper_doi
10.1002/1521-3749(200104)627:4<747::AID-ZAAC747>3.0.CO;2-H
_journal_volume                  627
_journal_year                    2001
_chemical_formula_moiety         'C52 H52 Ni1 P4'
_chemical_formula_sum            'C52 H52 Ni P4'
_chemical_name_systematic
;
tetrakis(Diphenyl(methyl)phosphine)-nickel(0)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                81.547(13)
_cell_angle_beta                 79.148(16)
_cell_angle_gamma                84.912(18)
_cell_formula_units_Z            2
_cell_length_a                   10.531(2)
_cell_length_b                   13.150(3)
_cell_length_c                   16.745(3)
_cell_volume                     2248.236
_diffrn_ambient_temperature      223
_exptl_crystal_colour            'pale red'
_exptl_crystal_density_diffrn    1.27
_refine_ls_R_factor_gt           4.97
_refine_ls_wR_factor_gt          4.97
_cod_original_formula_sum        'C52 H52 Ni1 P4'
_cod_database_code               1100218
Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~, [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~] und [Ni(PMePh~2~)~4~]
Krieger, Matthias; Gould, Robert O.; Harms, Klaus; Greiner, Andreas; Dehnicke, Kurt; Zeitschrift fuer Anorganische und Allgemeine Chemie 627 (2001) 747–754; doi:10.1002/1521-3749(200104)627:4<747::AID-ZAAC747>3.0.CO;2-H

data_1100219
_publ_section_title
;
 Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die
 Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~,
 [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~]
 und [Ni(PMePh~2~)~4~]
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   4
_journal_name_full
;
 Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_page_first              747
_journal_page_last               754
_journal_paper_doi
10.1002/1521-3749(200104)627:4<747::AID-ZAAC747>3.0.CO;2-H
_journal_volume                  627
_journal_year                    2001
_chemical_formula_moiety
;
C18 H54 Br5 N12 Ni4 P3,0.75(C1 H2 Cl2)
;
_chemical_formula_sum            'C18.75 H55.5 Br5 Cl1.5 N12 Ni4 P3'
_chemical_name_systematic
;\
(\m~3~-Bromo)-tris(\m~3~-tris(dimethylamino)phosphoraneiminato)-tetrabromo-\
tetra-nickel(ii) dichloromethane solvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 92.34(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.260(3)
_cell_length_b                   16.140(3)
_cell_length_c                   24.060(5)
_cell_volume                     4756.936
_diffrn_ambient_temperature      ?
_exptl_crystal_colour            needle.
_exptl_crystal_density_diffrn    1.717
_exptl_crystal_description       green
_refine_ls_R_factor_gt           7.03
_refine_ls_wR_factor_gt          7.03
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1100219
Intramolecular Iron(II)-catalyzed Nitrogen Transfer Reactions of Unsaturated Alkoxycarbonyl Azides: A Facile and Stereoselective Route to 4,5-Disubstituted Oxazolidinones
Bach, Thorsten; Schlummer, Björn; Harms, Klaus; Chemistry - A European Journal 7 (2001) 2581–2594; doi:10.1002/1521-3765(20010618)7:12<2581::aid-chem25810>3.0.co;2-o

data_1100220
_publ_section_title
;
 Intramolecular Iron(II)-catalyzed Nitrogen Transfer Reactions of
 Unsaturated Alkoxycarbonyl Azides: A Facile and Stereoselective
 Route to 4,5-Disubstituted Oxazolidinones
;
_journal_coden_ASTM              CEUJED
_journal_issue                   12
_journal_name_full               'Chemistry - A European Journal'
_journal_page_first              2581
_journal_page_last               2594
_journal_paper_doi
10.1002/1521-3765(20010618)7:12<2581::aid-chem25810>3.0.co;2-o
_journal_volume                  7
_journal_year                    2001
_chemical_formula_moiety         'C11 H12 Cl1 N1 O2'
_chemical_formula_sum            'C11 H12 Cl N O2'
_chemical_melting_point          386.15
_chemical_name_systematic
;
(4RS,5SR,1'RS)-4-(1-Chloro-1-phenylmethyl)-5-methyl-1,3-oxazolidin-2-one
;
_space_group_IT_number           45
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      45
_symmetry_space_group_name_Hall  'I 2 -2c'
_symmetry_space_group_name_H-M   'I b a 2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   11.0478(12)
_cell_length_b                   28.024(3)
_cell_length_c                   7.2693(7)
_cell_volume                     2250.601
_diffrn_ambient_temperature      193
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.332
_exptl_crystal_description       needle
_refine_ls_R_factor_gt           3.22
_refine_ls_wR_factor_gt          3.22
_cod_original_formula_sum        'C11 H12 Cl1 N1 O2'
_cod_database_code               1100220
Intramolecular Iron(II)-catalyzed Nitrogen Transfer Reactions of Unsaturated Alkoxycarbonyl Azides: A Facile and Stereoselective Route to 4,5-Disubstituted Oxazolidinones
Bach, Thorsten; Schlummer, Björn; Harms, Klaus; Chemistry - A European Journal 7 (2001) 2581–2594; doi:10.1002/1521-3765(20010618)7:12<2581::aid-chem25810>3.0.co;2-o

data_1100221
_publ_section_title
;
 Intramolecular Iron(II)-catalyzed Nitrogen Transfer Reactions of
 Unsaturated Alkoxycarbonyl Azides: A Facile and Stereoselective
 Route to 4,5-Disubstituted Oxazolidinones
;
_journal_coden_ASTM              CEUJED
_journal_issue                   12
_journal_name_full               'Chemistry - A European Journal'
_journal_page_first              2581
_journal_page_last               2594
_journal_paper_doi
10.1002/1521-3765(20010618)7:12<2581::aid-chem25810>3.0.co;2-o
_journal_volume                  7
_journal_year                    2001
_chemical_formula_moiety         'C7 H10 Cl1 N1 O2'
_chemical_formula_sum            'C7 H10 Cl N O2'
_chemical_melting_point          393.15
_chemical_name_systematic
;
(1RS,2SR,6RS)-9-Aza-2-chloro-7-oxabicyclo(4.3.0)nonan-8-one
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.864(17)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.3339(8)
_cell_length_b                   12.4601(17)
_cell_length_c                   11.8203(17)
_cell_volume                     783.802
_diffrn_ambient_temperature      193
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.488
_exptl_crystal_description       'thin plate'
_refine_ls_R_factor_gt           3.45
_refine_ls_wR_factor_gt          3.45
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C7 H10 Cl1 N1 O2'
_cod_database_code               1100221
Intramolecular Iron(II)-catalyzed Nitrogen Transfer Reactions of Unsaturated Alkoxycarbonyl Azides: A Facile and Stereoselective Route to 4,5-Disubstituted Oxazolidinones
Bach, Thorsten; Schlummer, Björn; Harms, Klaus; Chemistry - A European Journal 7 (2001) 2581–2594; doi:10.1002/1521-3765(20010618)7:12<2581::aid-chem25810>3.0.co;2-o

data_1100222
_publ_section_title
;
 Intramolecular Iron(II)-catalyzed Nitrogen Transfer Reactions of
 Unsaturated Alkoxycarbonyl Azides: A Facile and Stereoselective
 Route to 4,5-Disubstituted Oxazolidinones
;
_journal_coden_ASTM              CEUJED
_journal_issue                   12
_journal_name_full               'Chemistry - A European Journal'
_journal_page_first              2581
_journal_page_last               2594
_journal_paper_doi
10.1002/1521-3765(20010618)7:12<2581::aid-chem25810>3.0.co;2-o
_journal_volume                  7
_journal_year                    2001
_chemical_formula_moiety         'C9 H12 Cl1 N1 O2'
_chemical_formula_sum            'C9 H12 Cl N O2'
_chemical_melting_point          371.15
_chemical_name_systematic
;
(1RS,2RS,8SR)-2-Chloro-9-oxa-11-azabicyclo(6.3.0)undec-5-en-10-one
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 95.692(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.9246(5)
_cell_length_b                   6.8908(3)
_cell_length_c                   14.1918(10)
_cell_volume                     965.770
_diffrn_ambient_temperature      213
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.387
_exptl_crystal_description       plate
_refine_ls_R_factor_gt           5.99
_refine_ls_wR_factor_gt          5.99
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C9 H12 Cl1 N1 O2'
_cod_database_code               1100222
Intramolecular Iron(II)-catalyzed Nitrogen Transfer Reactions of Unsaturated Alkoxycarbonyl Azides: A Facile and Stereoselective Route to 4,5-Disubstituted Oxazolidinones
Bach, Thorsten; Schlummer, Björn; Harms, Klaus; Chemistry - A European Journal 7 (2001) 2581–2594; doi:10.1002/1521-3765(20010618)7:12<2581::aid-chem25810>3.0.co;2-o

data_1100223
_publ_section_title
;
 Intramolecular Iron(II)-catalyzed Nitrogen Transfer Reactions of
 Unsaturated Alkoxycarbonyl Azides: A Facile and Stereoselective
 Route to 4,5-Disubstituted Oxazolidinones
;
_journal_coden_ASTM              CEUJED
_journal_issue                   12
_journal_name_full               'Chemistry - A European Journal'
_journal_page_first              2581
_journal_page_last               2594
_journal_paper_doi
10.1002/1521-3765(20010618)7:12<2581::aid-chem25810>3.0.co;2-o
_journal_volume                  7
_journal_year                    2001
_chemical_formula_moiety         'C9 H12 Cl1 N1 O2'
_chemical_formula_sum            'C9 H12 Cl N O2'
_chemical_melting_point          381.15
_chemical_name_systematic
;
(1RS,2RS,3RS)-2-Chloro-9-oxa-11-azabicyclo(6.3.0)undec-5-en-10-one
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 113.363(7)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.9678(13)
_cell_length_b                   6.2949(3)
_cell_length_c                   13.7472(16)
_cell_volume                     950.748
_diffrn_ambient_temperature      213
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.409
_exptl_crystal_description       flat
_refine_ls_R_factor_gt           6.17
_refine_ls_wR_factor_gt          6.17
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C9 H12 Cl1 N1 O2'
_cod_database_code               1100223
Intramolecular Iron(II)-catalyzed Nitrogen Transfer Reactions of Unsaturated Alkoxycarbonyl Azides: A Facile and Stereoselective Route to 4,5-Disubstituted Oxazolidinones
Bach, Thorsten; Schlummer, Björn; Harms, Klaus; Chemistry - A European Journal 7 (2001) 2581–2594; doi:10.1002/1521-3765(20010618)7:12<2581::aid-chem25810>3.0.co;2-o

data_1100224
_publ_section_title
;
 Intramolecular Iron(II)-catalyzed Nitrogen Transfer Reactions of
 Unsaturated Alkoxycarbonyl Azides: A Facile and Stereoselective
 Route to 4,5-Disubstituted Oxazolidinones
;
_journal_coden_ASTM              CEUJED
_journal_issue                   12
_journal_name_full               'Chemistry - A European Journal'
_journal_page_first              2581
_journal_page_last               2594
_journal_paper_doi
10.1002/1521-3765(20010618)7:12<2581::aid-chem25810>3.0.co;2-o
_journal_volume                  7
_journal_year                    2001
_chemical_formula_moiety         'C11 H19 N1 O3'
_chemical_formula_sum            'C11 H19 N O3'
_chemical_name_systematic
;
4-(4-n-Butyltetrahydro-3-furyl)-1,3-oxazolidin-2-one
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                96.654(10)
_cell_angle_beta                 95.454(10)
_cell_angle_gamma                109.173(10)
_cell_formula_units_Z            2
_cell_length_a                   5.6138(10)
_cell_length_b                   7.0575(10)
_cell_length_c                   15.9015(10)
_cell_volume                     585.075
_diffrn_ambient_temperature      213
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.211
_exptl_crystal_description       prism
_refine_ls_R_factor_gt           6.88
_refine_ls_wR_factor_gt          6.88
_cod_original_formula_sum        'C11 H19 N1 O3'
_cod_database_code               1100224