Luminescent mononuclear mixed ligand complexes of copper(i) with 5-phenyl-2,2'-bipyridine and triphenylphosphine.
Safin, Damir A.; Mitoraj, Mariusz P.; Robeyns, Koen; Filinchuk, Yaroslav; Vande Velde, Christophe M. L.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 16824–16832; doi:10.1039/c5dt02755a

data_7036339
_publ_section_title
;
 Luminescent mononuclear mixed ligand complexes of copper(i) with
 5-phenyl-2,2'-bipyridine and triphenylphosphine.
;
_journal_issue                   38
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              16824
_journal_page_last               16832
_journal_paper_doi               10.1039/c5dt02755a
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C34 H27 Cu I N2 P'
_chemical_formula_sum            'C34 H27 Cu I N2 P'
_chemical_formula_weight         684.98
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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2015-07-01 deposited with the CCDC.
2015-09-01 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
(compiled Jan 14 2014,18:38:05)
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'MERCURY (Macrae et al., 2008), Platon (Spek, 2009)'

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_diffrn_radiation_source         'Rigaku UltraX 18 rotating anode'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0491
_diffrn_reflns_av_unetI/netI     0.0381
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
(compiled Jan 14 2014,18:38:05)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.576
_exptl_crystal_description       plate
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_refine_ls_number_reflns         5202
_refine_ls_number_restraints     0
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0404P)^2^+2.0348P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0785
_refine_ls_wR_factor_ref         0.0824
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4470
_reflns_number_total             5202
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt02755a2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7036338--7036340.cif.'
_cod_original_cell_volume        2886.76(16)
_cod_database_code               7036339
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              19023