Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex
Gründemann, Stephan; Kovacevic, Anes; Albrecht, Martin; Faller Robert, Jack W.; Crabtree, H.; Chemical Communications  (2001) 2274–; doi:10.1039/b107881j

data_7114879
_publ_section_title
;
 Abnormal binding in a carbene complex formed from an imidazolium salt and
 a metal hydride complex
;
_journal_issue                   21
_journal_name_full               'Chemical Communications'
_journal_page_first              2274
_journal_paper_doi               10.1039/b107881j
_journal_year                    2001
_chemical_formula_moiety         'C48 H47 Ir N3 P2, B F4 '
_chemical_formula_sum            'C48 H47 B F4 Ir N3 P2'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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?
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_cell_angle_alpha                90
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_cell_length_c                   22.0865(6)
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_cell_measurement_temperature    183.2
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SIR92 (Altomare, et. al. 1994)
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_diffrn_ambient_temperature      183.2
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_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            b107881j.txt
_cod_data_source_block           '_2134[IrP2Py-imidazole-iPr'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'multiscan' changed to
'multi-scan' according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        4313.6(2)
_cod_original_sg_symbol_H-M      'P 21/c     '
_cod_original_formula_sum        'C48 H47 B F4 Ir N3 P2 '
_cod_database_code               7114879