Two Quasi-Stable Lead(II) Hydrides at Ambient Temperature
Queen, Joshua Douglas; Fettinger, James C.; Power, Philip P.; Chemical Communications  (2019) –; doi:10.1039/C9CC05106F

data_7123943
_publ_section_title
;
 Two Quasi-Stable Lead(II) Hydrides at Ambient Temperature
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/C9CC05106F
_journal_year                    2019
_chemical_formula_moiety         'C27 H41 Ga N2'
_chemical_formula_sum            'C27 H41 Ga N2'
_chemical_formula_weight         463.34
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
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_audit_block_doi                 10.5517/cczqq1f
_audit_creation_method           SHELXL-97
_audit_update_record
;
2012-12-13 deposited with the CCDC.    2019-08-02 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 92.91(3)
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_cell_measurement_temperature    173(2)
_cell_volume                     2683.5(10)
_computing_cell_refinement       X-AREA
_computing_data_collection       X-AREA
_computing_data_reduction        X-AREA
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'STOE IPDS II'
_diffrn_measurement_method       omega-scans
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_limit_k_min       -16
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_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         4.71
_exptl_absorpt_coefficient_mu    1.040
_exptl_absorpt_correction_T_max  0.7706
_exptl_absorpt_correction_T_min  0.6390
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   mulabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.147
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             992
_exptl_crystal_size_max          0.50
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0280P)^2^+1.7819P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0828
_refine_ls_wR_factor_ref         0.0862
_reflns_number_gt                5290
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c9cc05106f2.cif
_cod_data_source_block           Compound3a
_cod_original_cell_volume        2683.5(9)
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               7123943