Assembly of strongly phosphorescent hetero-bimetallic and -trimetallic [2]catenane structures based on a coinage metal alkynyl system
Chang, Xiao-Yong; Xu, Guang-Tao; Cao, Bei; Wang, Juan-Yu; Huang, Jie-Sheng; Che, Chi-Ming; Chem. Sci.  (2017) –; doi:10.1039/C7SC03529B

data_1547531
_publ_section_title
;
 Assembly of strongly phosphorescent hetero-bimetallic and -trimetallic
 [2]catenane structures based on a coinage metal alkynyl system
;
_journal_name_full               'Chem. Sci.'
_journal_paper_doi               10.1039/C7SC03529B
_journal_year                    2017
_chemical_formula_moiety
'C256 H336 Ag8 Cu8, 5(C H2 Cl2), C0.44 H0.88 Cl0.98, C0.56 H1.12 Cl1.02'
_chemical_formula_sum            'C262 H348 Ag8 Cl12 Cu8'
_chemical_formula_weight         5294.06
_chemical_name_systematic        2
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2015-02-19
_audit_creation_method
;
Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
;
_audit_update_record
;
2016-08-18 deposited with the CCDC.
2017-09-18 downloaded from the CCDC.
;
_cell_angle_alpha                87.8191(17)
_cell_angle_beta                 73.8816(16)
_cell_angle_gamma                72.2845(16)
_cell_formula_units_Z            2
_cell_length_a                   20.1746(12)
_cell_length_b                   20.4429(12)
_cell_length_c                   34.225(2)
_cell_measurement_reflns_used    9583
_cell_measurement_temperature    100
_cell_measurement_theta_max      67.63
_cell_measurement_theta_min      2.70
_cell_volume                     12900.8(13)
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_diffrn_ambient_temperature      100.0
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0715
_diffrn_reflns_av_unetI/netI     0.0370
_diffrn_reflns_Laue_measured_fraction_full 0.974
_diffrn_reflns_Laue_measured_fraction_max 0.974
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       40
_diffrn_reflns_limit_l_min       -40
_diffrn_reflns_number            300578
_diffrn_reflns_point_group_measured_fraction_full 0.974
_diffrn_reflns_point_group_measured_fraction_max 0.974
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         67.692
_diffrn_reflns_theta_min         1.345
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.946
_exptl_absorpt_correction_T_max  0.7530
_exptl_absorpt_correction_T_min  0.3493
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2012/1 (Bruker,2012) was used for absorption correction. wR2(int) was 0.1537 before and 0.1099 after correction. The Ratio of minimum to maximum transmission is 0.4639. The \l/2 correction factor is 0.0015.'
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.363
_exptl_crystal_description       block
_exptl_crystal_F_000             5464
_exptl_crystal_preparation       'solvent evaporation, Luminescent'
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: dichloromethane'
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.1
_refine_diff_density_max         4.482
_refine_diff_density_min         -1.895
_refine_diff_density_rms         0.196
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     2892
_refine_ls_number_reflns         45465
_refine_ls_number_restraints     265
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0846
_refine_ls_R_factor_gt           0.0803
_refine_ls_shift/su_max          0.015
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1617P)^2^+68.3794P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2342
_refine_ls_wR_factor_ref         0.2400
_reflns_Friedel_coverage         0.000
_reflns_number_gt                41298
_reflns_number_total             45465
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7sc03529b2.cif
_cod_data_source_block           cxy176_0m-sr
_cod_original_cell_volume        12900.6(13)
_cod_database_code               1547531
_shelxl_version_number           2013-4
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 Cl1-C273 = Cl4-C274 = Cl3-C274 = Cl2-C273
 1.79 with sigma of 0.02
 C138-C137 = C140-C137 = C290-C287 = C137-C139 = C288-C287 = C287-C289
 1.54 with sigma of 0.02
 C303-C306 = C220-C217 = C303-C304 = C218-C217 = C303-C305 = C219-C217
 1.54 with sigma of 0.02
 C10A-C9A = C10-C9 = C11A-C9A = C11-C9 = C12A-C9A = C12-C9
 1.54 with sigma of 0.02
 C25-C27 = C26-C25 = C25-C28 = C28A-C25A = C26A-C25A = C27A-C25A
 1.54 with sigma of 0.02
 C291-C293 = C141-C143 = C141-C144 = C291-C294 = C141-C142 = C291-C292
 1.54 with sigma of 0.02
 C159-C157 = C297-C295 = C158-C157 = C160-C157 = C298-C295 = C296-C295
 1.53 with sigma of 0.02
 C170-C169 = C300-C299 = C301-C299 = C171-C169 = C302-C299 = C172-C169
 1.53 with sigma of 0.02
 C32-C29 = C32A-C29A = C31-C29 = C30A-C29A = C30-C29 = C31A-C29A
 1.54 with sigma of 0.02
 C43-C41 = C43A-C41A = C42A-C41A = C42-C41 = C41A-C44A = C41-C44
 1.54 with sigma of 0.02
 Cl13-C279
 1.79 with sigma of 0.02
 Cl14-C279 = Cl15-C280 = Cl16-C280
 1.79 with sigma of 0.02
 Cl1-Cl2 = Cl4-Cl3
 2.9 with sigma of 0.04
 C293-C292 = C143-C142
 2.53 with sigma of 0.04
 C292-C294 = C142-C144
 2.53 with sigma of 0.04
 C144-C143 = C294-C293
 2.53 with sigma of 0.04
 C172-C170 = C300-C302
 2.5 with sigma of 0.04
 C302-C301 = C172-C171
 2.5 with sigma of 0.04
 C300-C301 = C170-C171
 2.5 with sigma of 0.04
 C32A-C31A
 2.53 with sigma of 0.04
 C30A-C31A
 2.53 with sigma of 0.04
 Cl14-Cl13
 2.9 with sigma of 0.04
 Cl15-Cl16
 2.9 with sigma of 0.04
 C45-C39 \\sim C45A-C39
 with sigma of 0.02
 C45A-C48A \\sim C45-C46 \\sim C46A-C45A \\sim C45-C47 \\sim C45A-C47A
 with sigma of 0.02
3. Rigid bond restraints
 C137, C138, C139, C140
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
Cl3 \\sim Cl4 \\sim C274: within 2A with sigma of 0.01 and sigma for terminal
atoms of 0.02
C9 \\sim C10 \\sim C11 \\sim C12: within 1.7A with sigma of 0.01 and sigma for
terminal atoms of 0.02
C141 \\sim C142 \\sim C143 \\sim C144: within 1.7A with sigma of 0.01 and sigma
for terminal atoms of 0.02
C295 \\sim C296 \\sim C297 \\sim C298: within 1.7A with sigma of 0.01 and sigma
for terminal atoms of 0.02
C169 \\sim C170 \\sim C171 \\sim C172: within 1.7A with sigma of 0.01 and sigma
for terminal atoms of 0.02
C29 \\sim C30 \\sim C31 \\sim C32: within 1.7A with sigma of 0.01 and sigma for
terminal atoms of 0.02
C122 \\sim C123 \\sim C124: within 2.7A with sigma of 0.01 and sigma for
terminal atoms of 0.02
C137 \\sim C138 \\sim C139 \\sim C140: within 1.7A with sigma of 0.01 and sigma
for terminal atoms of 0.02
Uanis(C171) \\sim Ueq, Uanis(C169) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
Uanis(C254) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C15) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C42) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C254) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(Cl1) = Uanis(Cl4)
Uanis(Cl2) = Uanis(Cl3)
Uanis(C273) = Uanis(C274)
Uanis(C47) = Uanis(C47A)
Uanis(C45) = Uanis(C45A)
Uanis(C138) = Uanis(C288)
Uanis(C137) = Uanis(C287)
Uanis(C140) = Uanis(C290)
Uanis(C139) = Uanis(C289)
Uanis(C217) = Uanis(C303)
Uanis(C160) = Uanis(C298)
Uanis(C159) = Uanis(C297)
Uanis(C46A) = Uanis(C48)
Uanis(C46) = Uanis(C48A)
Uanis(C10) = Uanis(C10A)
Uanis(C11) = Uanis(C11A)
Uanis(C12) = Uanis(C12A)
Uanis(C9) = Uanis(C9A)
Uanis(C29) = Uanis(C29A)
Uanis(C25) = Uanis(C25A)
Uanis(C26) = Uanis(C26A)
Uanis(C27A) = Uanis(C27)
Uanis(C28A) = Uanis(C28)
Uanis(C141) = Uanis(C291)
Uanis(C292) = Uanis(C142)
Uanis(C293) = Uanis(C143)
Uanis(C144) = Uanis(C294)
Uanis(C158) = Uanis(C296)
Uanis(C157) = Uanis(C295)
Uanis(C302) = Uanis(C172)
Uanis(C170) = Uanis(C300)
Uanis(C301) = Uanis(C171)
Uanis(C169) = Uanis(C299)
Uanis(C31) = Uanis(C32A)
Uanis(C32) = Uanis(C30A)
Uanis(C30) = Uanis(C31A)
Uanis(C41) = Uanis(C41A)
Uanis(C43) = Uanis(C43A)
Uanis(C42) = Uanis(C42A)
Uanis(C23) = Uanis(C23A)
Uanis(C24) = Uanis(C24A)
Uanis(C21) = Uanis(C21A)
Uanis(C22) = Uanis(C22A)
Uanis(C19) = Uanis(C19A)
Uanis(C20) = Uanis(C20A)
Uanis(C44) = Uanis(C44A)
Uanis(C131) = Uanis(C281)
Uanis(C136) = Uanis(C286)
Uanis(C135) = Uanis(C285)
Uanis(C134) = Uanis(C284)
Uanis(C133) = Uanis(C283)
Uanis(C132) = Uanis(C282)
Uanis(C280) = Uanis(C279)
Uanis(Cl14) = Uanis(Cl16)
Uanis(Cl13) = Uanis(Cl15)
5. Others
 Sof(C19A)=Sof(C24A)=Sof(H24D)=Sof(C23A)=Sof(C22A)=Sof(H22M)=Sof(C21A)=
 Sof(C20A)=Sof(H20S)=Sof(C25A)=Sof(C26A)=Sof(H26D)=Sof(H26E)=Sof(H26F)=
 Sof(C27A)=Sof(H27D)=Sof(H27E)=Sof(H27F)=Sof(C28A)=Sof(H28J)=Sof(H28K)=
 Sof(H28L)=Sof(C29A)=Sof(C30A)=Sof(H30V)=Sof(H30W)=Sof(H30X)=Sof(C31A)=
 Sof(H31D)=Sof(H31E)=Sof(H31F)=Sof(C32A)=Sof(H32D)=Sof(H32E)=Sof(H32F)=1-FVAR(1)
 Sof(C19)=Sof(C24)=Sof(H24)=Sof(C23)=Sof(C22)=Sof(H22)=Sof(C21)=Sof(C20)=
 Sof(H20)=Sof(C25)=Sof(C26)=Sof(H26A)=Sof(H26B)=Sof(H26C)=Sof(C27)=Sof(H27A)=
 Sof(H27B)=Sof(H27C)=Sof(C28)=Sof(H28A)=Sof(H28B)=Sof(H28C)=Sof(C29)=Sof(C30)=
 Sof(H30A)=Sof(H30B)=Sof(H30C)=Sof(C31)=Sof(H31A)=Sof(H31B)=Sof(H31C)=Sof(C32)=
 Sof(H32A)=Sof(H32B)=Sof(H32C)=FVAR(1)
 Sof(C45A)=Sof(C46A)=Sof(H46D)=Sof(H46E)=Sof(H46F)=Sof(C47A)=Sof(H47D)=
 Sof(H47E)=Sof(H47F)=Sof(C48A)=Sof(H48D)=Sof(H48E)=Sof(H48F)=1-FVAR(2)
 Sof(C45)=Sof(C46)=Sof(H46A)=Sof(H46B)=Sof(H46C)=Sof(C47)=Sof(H47A)=Sof(H47B)=
 Sof(H47C)=Sof(C48)=Sof(H48A)=Sof(H48B)=Sof(H48C)=FVAR(2)
 Sof(C303)=Sof(C304)=Sof(H30M)=Sof(H30N)=Sof(H30O)=Sof(C305)=Sof(H30P)=
 Sof(H30Q)=Sof(H30R)=Sof(C306)=Sof(H30S)=Sof(H30T)=Sof(H30U)=1-FVAR(3)
 Sof(C217)=Sof(C218)=Sof(H21A)=Sof(H21B)=Sof(H21C)=Sof(C219)=Sof(H21D)=
 Sof(H21E)=Sof(H21F)=Sof(C220)=Sof(H22A)=Sof(H22B)=Sof(H22C)=FVAR(3)
 Sof(C282)=Sof(H282)=Sof(C281)=Sof(C286)=Sof(H286)=Sof(C285)=Sof(C284)=
 Sof(H284)=Sof(C283)=Sof(C287)=Sof(C288)=Sof(H28D)=Sof(H28E)=Sof(H28F)=
 Sof(C289)=Sof(H28G)=Sof(H28H)=Sof(H28I)=Sof(C290)=Sof(H29A)=Sof(H29B)=
 Sof(H29C)=1-FVAR(4)
 Sof(C131)=Sof(C136)=Sof(H136)=Sof(C135)=Sof(C134)=Sof(H134)=Sof(C133)=
 Sof(C132)=Sof(H132)=Sof(C137)=Sof(C138)=Sof(H13A)=Sof(H13B)=Sof(H13C)=
 Sof(C139)=Sof(H13D)=Sof(H13E)=Sof(H13F)=Sof(C140)=Sof(H14D)=Sof(H14E)=
 Sof(H14F)=FVAR(4)
 Sof(Cl3)=Sof(Cl4)=1-FVAR(5)
 Sof(Cl1)=Sof(Cl2)=FVAR(5)
 Sof(C295)=Sof(C296)=Sof(H29M)=Sof(H29N)=Sof(H29O)=Sof(C297)=Sof(H29P)=
 Sof(H29Q)=Sof(H29R)=Sof(C298)=Sof(H29S)=Sof(H29T)=Sof(H29U)=1-FVAR(6)
 Sof(C157)=Sof(C158)=Sof(H15M)=Sof(H15N)=Sof(H15O)=Sof(C159)=Sof(H15P)=
 Sof(H15Q)=Sof(H15R)=Sof(C160)=Sof(H16D)=Sof(H16E)=Sof(H16F)=FVAR(6)
 Sof(C9A)=Sof(C10A)=Sof(H10M)=Sof(H10N)=Sof(H10O)=Sof(C11A)=Sof(H11M)=
 Sof(H11N)=Sof(H11O)=Sof(C12A)=Sof(H12V)=Sof(H12W)=Sof(H12X)=1-FVAR(7)
 Sof(C9)=Sof(C10)=Sof(H10A)=Sof(H10B)=Sof(H10C)=Sof(C11)=Sof(H11A)=Sof(H11B)=
 Sof(H11C)=Sof(C12)=Sof(H12A)=Sof(H12B)=Sof(H12C)=FVAR(7)
 Sof(C291)=Sof(C292)=Sof(H29D)=Sof(H29E)=Sof(H29F)=Sof(C293)=Sof(H29G)=
 Sof(H29H)=Sof(H29I)=Sof(C294)=Sof(H29J)=Sof(H29K)=Sof(H29L)=1-FVAR(8)
 Sof(C141)=Sof(C142)=Sof(H14G)=Sof(H14H)=Sof(H14I)=Sof(C143)=Sof(H14J)=
 Sof(H14K)=Sof(H14L)=Sof(C144)=Sof(H14M)=Sof(H14N)=Sof(H14O)=FVAR(8)
 Sof(C274)=Sof(H27O)=Sof(H27P)=1-FVAR(9)
 Sof(C273)=Sof(H27Q)=Sof(H27R)=FVAR(9)
 Sof(Cl13)=Sof(Cl14)=Sof(C279)=Sof(H27S)=Sof(H27T)=1-FVAR(10)
 Sof(Cl15)=Sof(Cl16)=Sof(C280)=Sof(H28M)=Sof(H28N)=FVAR(10)
 Sof(C299)=Sof(C300)=Sof(H30D)=Sof(H30E)=Sof(H30F)=Sof(C301)=Sof(H30G)=
 Sof(H30H)=Sof(H30I)=Sof(C302)=Sof(H30J)=Sof(H30K)=Sof(H30L)=1-FVAR(11)
 Sof(C169)=Sof(C170)=Sof(H17A)=Sof(H17B)=Sof(H17C)=Sof(C171)=Sof(H17D)=
 Sof(H17E)=Sof(H17F)=Sof(C172)=Sof(H17G)=Sof(H17H)=Sof(H17I)=FVAR(11)
 Fixed Sof: C41(0.75) C42(0.75) H42A(0.75) H42B(0.75) H42C(0.75) C43(0.75)
 H43A(0.75) H43B(0.75) H43C(0.75) C44(0.75) H44A(0.75) H44B(0.75) H44C(0.75)
 C41A(0.25) C42A(0.25) H42D(0.25) H42E(0.25) H42F(0.25) C43A(0.25) H43D(0.25)
 H43E(0.25) H43F(0.25) C44A(0.25) H44D(0.25) H44E(0.25) H44F(0.25)
6.a Secondary CH2 refined with riding coordinates:
 C277(H27G,H27H), C278(H27I,H27J), C276(H27K,H27L), C275(H27M,H27N), C274(H27O,
 H27P), C273(H27Q,H27R), C279(H27S,H27T), C280(H28M,H28N)
6.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C6(H6), C8(H8), C24(H24), C22(H22), C20(H20), C36(H36), C38(H38),
 C40(H40), C52(H52), C54(H54), C56(H56), C68(H68), C70(H70), C72(H72), C84(H84),
  C86(H86), C88(H88), C100(H100), C102(H102), C104(H104), C116(H116),
 C118(H118), C120(H120), C136(H136), C134(H134), C132(H132), C148(H148),
 C150(H150), C152(H152), C164(H164), C166(H166), C168(H168), C180(H180),
 C182(H182), C184(H184), C196(H196), C198(H198), C200(H200), C212(H212),
 C214(H214), C216(H216), C228(H228), C230(H230), C232(H232), C244(H244),
 C246(H246), C248(H248), C282(H282), C286(H286), C284(H284), C24A(H24D),
 C22A(H22M), C20A(H20S)
6.c Fitted hexagon refined as free rotating group:
 C19(C24,C23,C22,C21,C20), C131(C136,C135,C134,C133,C132), C282(C281,C286,C285,
 C284,C283), C19A(C24A,C23A,C22A,C21A,C20A)
6.d Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), C12(H12A,H12B,H12C), C14(H14A,H14B,
 H14C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C), C26(H26A,H26B,H26C), C27(H27A,
 H27B,H27C), C28(H28A,H28B,H28C), C30(H30A,H30B,H30C), C31(H31A,H31B,H31C),
 C32(H32A,H32B,H32C), C42(H42A,H42B,H42C), C43(H43A,H43B,H43C), C44(H44A,H44B,
 H44C), C46(H46A,H46B,H46C), C47(H47A,H47B,H47C), C48(H48A,H48B,H48C), C58(H58A,
 H58B,H58C), C59(H59A,H59B,H59C), C60(H60A,H60B,H60C), C62(H62A,H62B,H62C),
 C63(H63A,H63B,H63C), C64(H64A,H64B,H64C), C74(H74A,H74B,H74C), C75(H75A,H75B,
 H75C), C76(H76A,H76B,H76C), C78(H78A,H78B,H78C), C79(H79A,H79B,H79C), C80(H80A,
 H80B,H80C), C90(H90A,H90B,H90C), C91(H91A,H91B,H91C), C92(H92A,H92B,H92C),
 C94(H94A,H94B,H94C), C95(H95A,H95B,H95C), C96(H96A,H96B,H96C), C106(H10D,H10E,
 H10F), C107(H10G,H10H,H10I), C108(H10J,H10K,H10L), C110(H11D,H11E,H11F),
 C111(H11G,H11H,H11I), C112(H11J,H11K,H11L), C122(H12D,H12E,H12F), C123(H12G,
 H12H,H12I), C124(H12J,H12K,H12L), C126(H12M,H12N,H12O), C127(H12P,H12Q,H12R),
 C128(H12S,H12T,H12U), C138(H13A,H13B,H13C), C139(H13D,H13E,H13F), C140(H14D,
 H14E,H14F), C142(H14G,H14H,H14I), C143(H14J,H14K,H14L), C144(H14M,H14N,H14O),
 C154(H15D,H15E,H15F), C155(H15G,H15H,H15I), C156(H15J,H15K,H15L), C158(H15M,
 H15N,H15O), C159(H15P,H15Q,H15R), C160(H16D,H16E,H16F), C170(H17A,H17B,H17C),
 C171(H17D,H17E,H17F), C172(H17G,H17H,H17I), C174(H17J,H17K,H17L), C175(H17M,
 H17N,H17O), C176(H17P,H17Q,H17R), C186(H18A,H18B,H18C), C187(H18D,H18E,H18F),
 C188(H18G,H18H,H18I), C190(H19A,H19B,H19C), C191(H19D,H19E,H19F), C192(H19G,
 H19H,H19I), C202(H20A,H20B,H20C), C203(H20D,H20E,H20F), C204(H20G,H20H,H20I),
 C206(H20J,H20K,H20L), C207(H20M,H20N,H20O), C208(H20P,H20Q,H20R), C218(H21A,
 H21B,H21C), C219(H21D,H21E,H21F), C220(H22A,H22B,H22C), C222(H22D,H22E,H22F),
 C223(H22G,H22H,H22I), C224(H22J,H22K,H22L), C234(H23A,H23B,H23C), C235(H23D,
 H23E,H23F), C236(H23G,H23H,H23I), C238(H23J,H23K,H23L), C239(H23M,H23N,H23O),
 C240(H24A,H24B,H24C), C250(H25A,H25B,H25C), C251(H25D,H25E,H25F), C252(H25G,
 H25H,H25I), C254(H25J,H25K,H25L), C255(H25M,H25N,H25O), C256(H25P,H25Q,H25R),
 C288(H28D,H28E,H28F), C289(H28G,H28H,H28I), C290(H29A,H29B,H29C), C292(H29D,
 H29E,H29F), C293(H29G,H29H,H29I), C294(H29J,H29K,H29L), C296(H29M,H29N,H29O),
 C297(H29P,H29Q,H29R), C298(H29S,H29T,H29U), C300(H30D,H30E,H30F), C301(H30G,
 H30H,H30I), C302(H30J,H30K,H30L), C304(H30M,H30N,H30O), C305(H30P,H30Q,H30R),
 C306(H30S,H30T,H30U), C10A(H10M,H10N,H10O), C11A(H11M,H11N,H11O), C12A(H12V,
 H12W,H12X), C26A(H26D,H26E,H26F), C27A(H27D,H27E,H27F), C28A(H28J,H28K,H28L),
 C30A(H30V,H30W,H30X), C31A(H31D,H31E,H31F), C32A(H32D,H32E,H32F), C42A(H42D,
 H42E,H42F), C43A(H43D,H43E,H43F), C44A(H44D,H44E,H44F), C46A(H46D,H46E,H46F),
 C47A(H47D,H47E,H47F), C48A(H48D,H48E,H48F)
;
_olex2_exptl_crystal_mounting_method 'Nylon loop'
_olex2_submission_special_instructions 'No special instructions were received'