Syntheses and luminescence studies of mixed-metal gold(i)‒copper(i) and ‒silver(i) alkynyl complexes. The “turning-on” of emission upon d10 metal ion encapsulation
Wing-Wah Yam, Vivian; Cheung, Kai-Leung; Chung-Chin Cheng, Eddie; Zhu, Nianyong; Cheung, Kung-Kai; Dalton Transactions  (2003) 1830–; doi:10.1039/b211909a

data_7012545
_publ_section_title
;
 Syntheses and luminescence studies of mixed-metal gold(i)--copper(i)
 and --silver(i) alkynyl complexes. The &#x201C;turning-on&#x201D; of
 emission upon d10 metal ion encapsulation
;
_journal_issue                   9
_journal_name_full               'Dalton Transactions'
_journal_page_first              1830
_journal_paper_doi               10.1039/b211909a
_journal_year                    2003
_chemical_formula_moiety         'C44 H38 Au2 Fe P2 '
_chemical_formula_sum            'C44 H38 Au2 Fe P2'
_chemical_formula_weight         1078.51
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_date             'Tue Jan 19 10:32:35 1999'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 104.14(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.464(2)
_cell_length_b                   9.378(2)
_cell_length_c                   19.868(3)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    301.2
_cell_measurement_theta_max      0.0
_cell_measurement_theta_min      0.0
_cell_volume                     1890.6(6)
_computing_cell_refinement       'MAR Data Collection Software & DENZO'
_computing_data_collection       'MAR Data Collection Software & DENZO'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    SIR92
_diffrn_ambient_temperature      301.2
_diffrn_measurement_device       'MAR IPDS'
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_diffrn_orient_matrix_UB_11      0.00000
_diffrn_orient_matrix_UB_12      0.00000
_diffrn_orient_matrix_UB_13      0.00000
_diffrn_orient_matrix_UB_21      0.00000
_diffrn_orient_matrix_UB_22      0.00000
_diffrn_orient_matrix_UB_23      0.00000
_diffrn_orient_matrix_UB_31      0.00000
_diffrn_orient_matrix_UB_32      0.00000
_diffrn_orient_matrix_UB_33      0.00000
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            3483
_diffrn_reflns_theta_max         25.43
_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    8.261
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.894
_exptl_crystal_density_meas      0.000
_exptl_crystal_description       plate
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_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
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_refine_ls_number_restraints     0
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_refine_ls_shift/esd_max         0.0240
_refine_ls_shift/esd_mean        0.01
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0746
_reflns_number_observed          2782
_reflns_number_total             3483
_reflns_observed_criterion       3.00
_cod_data_source_file            b211909a.txt
_cod_data_source_block           ip588_Yam_Cheung_KL's_DAn38_08_11_98
_cod_depositor_comments
;
The following automatic conversions were performed:

'_atom_site_thermal_displace_type' tag value 'Uij' was replaced with
'Uani' value 44 times.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/c     '
_cod_original_formula_sum        'C44 H38 Au2 Fe P2 '
_cod_database_code               7012545