Photo-release of acetonitrile in ruthenium(II) complexes with various substituted terpyridine ligands.
Mudrak, Vladyslav; Lacroix, Pascal G.; Labra-Vázquez, Pablo; Tassé, Marine; Mallet-Ladeira, Sonia; Malfant, Isabelle; Dalton transactions (Cambridge, England : 2003) 54 (2025) 9021–9031; doi:10.1039/d5dt00734h

data_7718626
_publ_section_title
;
 Photo-release of acetonitrile in ruthenium(II) complexes with various
 substituted terpyridine ligands.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9021
_journal_page_last               9031
_journal_paper_doi               10.1039/d5dt00734h
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C32 H34 N5 O2 Ru, F6 P, C3 H7 N O'
_chemical_formula_sum            'C35 H41 F6 N6 O3 P Ru'
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_audit_update_record
;
2025-03-24 deposited with the CCDC.	2025-05-02 downloaded from the CCDC.
;
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_diffrn_source                   'micro-focus sealed X-ray tube'
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;
CrysAlisPro 1.171.41.120a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
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_exptl_crystal_description       plate
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0667P)^2^+2.3775P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1072
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_reflns_number_gt                6997
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           VM-PLV-29
_cod_depositor_comments
'Adding full bibliography for 7718624--7718627.cif.'
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_shelx_shelxl_version_number     2018/3
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