Unexpected Reactivity and Coordination in Gallium(III) and Indium(III) Chloride Complexes With Geometrically Constrained Thio- and Selenoether Ligands
Kathryn George; Marek Jura; William Levason; Mark E. Light; Luke P. Ollivere; Gillian Reid; Inorganic Chemistry 51 (2012) 2231–2240; doi:10.1021/ic202670v

data_4328463
_publ_contact_author_address
;   School of Chemistry
    University of Southampton
    Southampton SO17 1BJ, UK
;
_publ_contact_author_email       gr@soton.ac.uk
_publ_contact_author_fax         '023 8059 3781'
_publ_contact_author_name        'Professor Gillian Reid'
_publ_contact_author_phone       '023 8059 3609'
_publ_section_title
;
 Unexpected Reactivity and Coordination in Gallium(III) and Indium(III)
 Chloride Complexes With Geometrically Constrained Thio- and Selenoether
 Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2231
_journal_page_last               2240
_journal_paper_doi               10.1021/ic202670v
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C10 H14 Cl2 S2 2+, 2(Cl4 Ga 1-)'
_chemical_formula_sum            'C10 H14 Cl10 Ga2 S2'
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_chemical_name_systematic
; 
1,2-phenylenebis[(chloromethyl)(methyl)sulfonium] bis(tetrachlorogallate(III)) 
;
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_audit_author_name               'Webster, M.'
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_diffrn_ambient_temperature      120(2)
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_diffrn_measured_fraction_theta_max 0.995
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'Bruker-Nonius 95mm CCD camera on \k-goniostat'
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'G.M. Sheldrick, (2007). SADABS. Version 2007/2. Bruker AXS Inc.'
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_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0989
_refine_ls_R_factor_gt           0.0734
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0885P)^2^+23.5717P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            ic202670v_si_001_7.cif
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_cod_original_cell_volume        2367.9(6)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4328463