Synthesis and Solid-State Structures of Gold(I) Complexes of Diphosphines
Molitor, Sebastian; Mahler, Christoph; Gessner, Viktoria H.; New J. Chem. 40 (2016) 6467–6474; doi:10.1039/C6NJ00786D

data_7055569
_publ_section_title
;
 Synthesis and Solid-State Structures of Gold(I) Complexes of Diphosphines
;
_journal_issue                   7
_journal_name_full               'New J. Chem.'
_journal_page_first              6467
_journal_page_last               6474
_journal_paper_doi               10.1039/C6NJ00786D
_journal_volume                  40
_journal_year                    2016
_chemical_formula_sum            'C32 H40 Au2 Cl2 N4 P2'
_chemical_formula_weight         1007.45
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-03-10 deposited with the CCDC.
2016-05-16 downloaded from the CCDC.
;
_cell_angle_alpha                94.108(2)
_cell_angle_beta                 90.027(2)
_cell_angle_gamma                92.970(2)
_cell_formula_units_Z            4
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_cell_length_b                   15.3421(7)
_cell_length_c                   21.1914(10)
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_cell_measurement_theta_min      4.662
_cell_volume                     3723.3(3)
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_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-CCD'
_diffrn_measurement_method       omega-scans
_diffrn_radiation_type           MoK\a
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0121P)^2^+0.1000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             13083
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6nj00786d2.cif
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_shelx_shelxl_version_number     2014/7
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