Hydroxycarbonylation of alkenes with formic acid using a rhodium iodide complex and alkyl ammonium iodide.
Okada, Masaki; Takeuchi, Katsuhiko; Matsumoto, Kazuhiro; Oku, Tomoharu; Choi, Jun-Chul; Organic & biomolecular chemistry 19 (2021) 8727–8734; doi:10.1039/d1ob01060c

data_7158197
_publ_section_title
;
 Hydroxycarbonylation of alkenes with formic acid using a rhodium iodide
 complex and alkyl ammonium iodide.
;
_journal_issue                   40
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              8727
_journal_page_last               8734
_journal_paper_doi               10.1039/d1ob01060c
_journal_volume                  19
_journal_year                    2021
_chemical_formula_moiety         'C37 H31 I2 O P2 Rh, C H2 Cl2'
_chemical_formula_sum            'C38 H33 Cl2 I2 O P2 Rh'
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;
2021-02-22 deposited with the CCDC.	2021-07-27 downloaded from the CCDC.
;
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;
CrysAlisPro 1.171.40.84a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Orange
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+9.2676P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0678
_refine_ls_wR_factor_ref         0.0680
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7158197.cif.'
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