μ-η1:η1-Peroxo-Bridged Dinuclear Peroxotungstate Catalytically Active for Epoxidation of Olefins
Keigo Kamata; Shinjiro Kuzuya; Kazuhiro Uehara; Syuhei Yamaguchi; Noritaka Mizuno; Inorganic Chemistry 46 (2007) 3768–3774; doi:10.1021/ic0701211

data_4308136
_publ_contact_author_address
;
Department of Applied Chemistry, School of Engineering,
The University of Tokyo, 
7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
;
_publ_contact_author_email       tmizuno@mail.ecc.u-tokyo.ac.jp
_publ_contact_author_fax         +81-3-5841-7220
_publ_contact_author_name        'Noritaka Mizuno'
_publ_contact_author_phone       +81-3-5841-7272
_publ_section_title
;
\m-\h1:\h1-Peroxo-Bridged Dinuclear Peroxotungstate Catalytically Active
for Epoxidation of Olefins
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3768
_journal_page_last               3774
_journal_paper_doi               10.1021/ic0701211
_journal_volume                  46
_journal_year                    2007
_chemical_formula_moiety         'C48 N3 O18 W3'
_chemical_formula_sum            'C48 N3 O18 W3'
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_symmetry_space_group_name_Hall  '-C 2yc'
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_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 121.6560(10)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   34.5727(3)
_cell_length_b                   14.2882(2)
_cell_length_c                   30.4695(4)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      0
_cell_measurement_theta_min      0
_cell_volume                     12811.9(3)
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
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_exptl_crystal_colour            white
_exptl_crystal_density_diffrn    1.512
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
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_exptl_crystal_size_max          0
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_refine_diff_density_max         4.667
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.1181P)^2^+58.7105P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_file            ic0701211si20070123_105041.cif
_cod_data_source_block           shelxl
_cod_database_code               4308136