Hidden aryl-exchange processes in stable 16e Rh<sup>III</sup> [RhCp*Ar<sub>2</sub>] complexes, and their unexpected transmetalation mechanism.
Peñas-Defrutos, M N; Bartolomé, C; García-Melchor, M; Espinet, P.; Chemical communications (Cambridge, England) 54 (2018) 984–987; doi:10.1039/c7cc09352g

data_7121066
_publ_section_title
;
 Hidden aryl-exchange processes in stable 16e Rh<sup>III</sup>
 [RhCp*Ar<sub>2</sub>] complexes, and their unexpected transmetalation
 mechanism.
;
_journal_issue                   8
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              984
_journal_page_last               987
_journal_paper_doi               10.1039/c7cc09352g
_journal_volume                  54
_journal_year                    2018
_chemical_formula_moiety         'C22 H15 Cl4 F6 Rh'
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_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'
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Olex2 1.2-alpha
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2017-12-02 deposited with the CCDC.
2018-01-02 downloaded from the CCDC.
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_computing_cell_refinement
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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  1 omega  -15.00   65.00   1.0000    5.3350
omega____ theta____ kappa____ phi______ frames
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  2 omega   60.00   95.00   1.0000    5.3350
omega____ theta____ kappa____ phi______ frames
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  3 omega  -15.00   81.00   1.0000    5.3350
omega____ theta____ kappa____ phi______ frames
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omega____ theta____ kappa____ phi______ frames
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CrysAlisPro, Agilent Technologies,
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Numerical absorption correction based on gaussian integration over
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            black
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 Flack x determined using 1874 quotients [(I+)-(I-)]/[(I+)+(I-)]
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_refine_ls_abs_structure_Flack   -0.013(13)
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'w=1/[\s^2^(Fo^2^)+(0.0249P)^2^+0.6511P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7121066--7121070.cif.'
_cod_original_cell_volume        2360.15(12)
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_chemical_oxdiff_formula         'C22 H15 F6 Cl4 Rh'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.5 times of:
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2.a Idealised Me refined as rotating group:
 C39(H39A,H39B,H39C), C40(H40A,H40B,H40C), C36(H36A,H36B,H36C), C37(H37A,H37B,
 H37C), C38(H38A,H38B,H38C)
;
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