A symmetry breaking phase transition-triggered high-temperature solid-state quadratic nonlinear optical switch coupled with a switchable dielectric constant in an organic-inorganic hybrid compound.
Mei, Guang-Quan; Zhang, Han-Yue; Liao, Wei-Qiang; Chemical communications (Cambridge, England) 52 (2016) 11135–11138; doi:10.1039/c6cc05512e

data_7124920
_publ_section_title
;
 A symmetry breaking phase transition-triggered high-temperature
 solid-state quadratic nonlinear optical switch coupled with a switchable
 dielectric constant in an organic-inorganic hybrid compound.
;
_journal_issue                   74
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              11135
_journal_page_last               11138
_journal_paper_doi               10.1039/c6cc05512e
_journal_volume                  52
_journal_year                    2016
_chemical_formula_moiety         'C5 H16 N2, Cl5 Sb'
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_audit_update_record
;
2016-06-15 deposited with the CCDC.
2016-08-16 downloaded from the CCDC.
;
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_refine_ls_abs_structure_details
;
 Flack x determined using 1063 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.009(16)
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0130P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_fraction_max     0.998
_reflns_number_gt                2966
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_cod_original_cell_volume        1428.8(17)
_cod_database_code               7124920
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