<i>catena</i>-Poly[[tetrakis(μ-2,2-dimethylpropionato-<i>O</i>:<i>O</i>')dicopper(II)]-μ-dioxane-<i>O</i>:<i>O</i>'] and <i>catena</i>-poly[[tetrakis(μ-3,3-dimethylbutyrato-<i>O</i>:<i>O</i>')dicopper(II)]-μ-dioxane-<i>O</i>,<i>O</i>']
Kani, Yoshiyuki; Tsuchimoto, Masanobu; Ohba, Shigeru; Tokii, Tadashi; Acta Crystallographica Section C 56 (2000) e80–e81; doi:10.1107/S0108270100002304

data_2010751
_publ_section_title
;<i>catena</i>-Poly[[tetrakis(\m-2,2-dimethylpropionato-<i>O</i>:<i>O</i>')dicopper(II)]-\m-dioxane-<i>O</i>:<i>O</i>']
 and
 <i>catena</i>-poly[[tetrakis(\m-3,3-dimethylbutyrato-<i>O</i>:<i>O</i>')dicopper(II)]-\m-dioxane-<i>O</i>,<i>O</i>']
;
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              e80
_journal_page_last               e81
_journal_paper_doi               10.1107/S0108270100002304
_journal_volume                  56
_journal_year                    2000
_chemical_formula_iupac          '[Cu2 (C5 H9 O2)4 (C4 H8 O2)]'
_chemical_formula_moiety         'C24 H44 Cu2 O10'
_chemical_formula_sum            'C24 H44 Cu2 O10'
_chemical_formula_weight         619.70
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                112.280(10)
_cell_angle_beta                 110.19(2)
_cell_angle_gamma                83.720(10)
_cell_formula_units_Z            1
_cell_length_a                   9.633(2)
_cell_length_b                   10.6650(10)
_cell_length_c                   9.030(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    297
_cell_measurement_theta_max      15
_cell_measurement_theta_min      10
_cell_volume                     805.5(3)
_computing_cell_refinement       'MSC/AFC Diffractometer Control Software'
_computing_data_collection
;
MSC/AFC Diffractometer Control Software
(Molecular Structure Corporation, 1993)
;
_computing_data_reduction
'teXsan (Molecular Structure Corporation, 1999)'
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    'SIR92 (Altomare et al., 1994)'
_diffrn_ambient_temperature      297
_diffrn_measurement_device_type  'Rigaku AFC-7R'
_diffrn_measurement_method       \q-2\q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .091
_diffrn_reflns_av_sigmaI/netI    .072
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            4955
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         30
_diffrn_reflns_theta_min         2.5
_diffrn_standards_decay_%        3.9
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.364
_exptl_absorpt_correction_T_max  .886
_exptl_absorpt_correction_T_min  .829
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   '(Coppens et al., 1965)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.278
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             326
_exptl_crystal_size_max          .5
_exptl_crystal_size_mid          .1
_exptl_crystal_size_min          .1
_refine_diff_density_max         .58
_refine_diff_density_min         -.65
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.08
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     163
_refine_ls_number_reflns         2697
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           .051
_refine_ls_shift/su_max          .008
_refine_ls_shift/su_mean         .001
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00250|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         .070
_reflns_number_gt                2697
_reflns_number_total             4697
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            qa0224.cif
_cod_data_source_block           I
_cod_original_cell_volume        805.4(3)
_cod_database_code               2010751