Interactions between well-isolated Dy<sup>3+</sup> ions considerably contribute to the demagnetization of a mononuclear acetylacetonate-pyrazinate complex.
Gavrikov, Andrey V.; Ilyukhin, Andrey B.; Buzoverov, Mikhail E.; Babeshkin, Konstantin A.; Timokhina, Elena N.; Breslavskaya, Natalia N.; Vasilyev, Pavel N.; Efimov, Nikolay N.; Dalton transactions (Cambridge, England : 2003) 54 (2025) 9615–9630; doi:10.1039/d5dt00749f

data_7718677
_publ_section_title
;
 Interactions between well-isolated Dy<sup>3+</sup> ions considerably
 contribute to the demagnetization of a mononuclear
 acetylacetonate-pyrazinate complex.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9615
_journal_page_last               9630
_journal_paper_doi               10.1039/d5dt00749f
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C27 H25 Ho N4 O6'
_chemical_formula_sum            'C27 H25 Ho N4 O6'
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;
2024-06-25 deposited with the CCDC.	2025-05-09 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_limit_h_min       -19
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            yellow
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_refine_ls_shift/su_max          0.002
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0300P)^2^+1.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0
_reflns_number_gt                7346
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           2
_cod_depositor_comments
'Adding full bibliography for 7718676--7718680.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7718677
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