Phenyl palladium(II) iodide complexes isolated after Sonogashira coupling of iodobenzenes with terminal alkynes
Bosch, Eric; Acta Crystallographica Section E Crystallographic Communications 81 (2025) –; doi:10.1107/S2056989025004025

data_2023500
_publ_section_title
;
 Phenyl palladium(II) iodide complexes isolated after Sonogashira coupling
 of iodobenzenes with terminal alkynes
;
_journal_coeditor_code           JY2058
_journal_issue                   6
_journal_name_full
'Acta Crystallographica Section E Crystallographic Communications'
_journal_paper_doi               10.1107/S2056989025004025
_journal_volume                  81
_journal_year                    2025
_chemical_formula_iupac          '[Pd (C8 H3 F6) I (C18 H15 P)2]'
_chemical_formula_moiety         'C44 H33 F6 I P2 Pd'
_chemical_formula_sum            'C44 H33 F6 I P2 Pd'
_chemical_formula_weight         971.010
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_primary     iterative
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;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
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_computing_molecular_graphics
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X-SEED 4 (Barbour, 2020)
;
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Olex2 1.5 (Dolomanov <i>et al.</i>,  2009)
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olex2.refine 1.5 (Bourhis <i>et al.</i>,  2015)
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olex2.solve 1.5 (Bourhis <i>et al.</i>,  2015)
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_diffrn_measurement_method       '\f and \w scans'
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;
(SADABS; Krause <i>et al.</i>,  2015)
;
_exptl_crystal_colour            'clear red'
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'w=1/[\s^2^(Fo^2^)+(0.0307P)^2^+8.0780P] where P=(Fo^2^+2Fc^2^)/3'
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