Ketones and Aldehydes as O-Nucleophiles in Iridium-Catalyzed Intramolecular Asymmetric Allylic Substitution Reaction.
Wang, Ye; Zhang, Wen-Yun; You, Shu-Li; Journal of the American Chemical Society 141 (2019) 2228–2232; doi:10.1021/jacs.8b13182

data_4128160
_publ_section_title
;
 Ketones and Aldehydes as O-Nucleophiles in Iridium-Catalyzed
 Intramolecular Asymmetric Allylic Substitution Reaction.
;
_journal_issue                   6
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              2228
_journal_page_last               2232
_journal_paper_doi               10.1021/jacs.8b13182
_journal_volume                  141
_journal_year                    2019
_chemical_formula_sum            'C21 H24 N2 O6 S'
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0472P)^2^+0.1915P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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