A new Schiff base–copper(II) complex: [<i>N</i>-(2-hydroxyethyl)-<i>N</i>'-(2-oxidobenzylidene)ethylenediamine-1κ^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>'][μ-<i>N</i>-(2-oxidobenzylidene)-<i>N</i>'-(2-oxidoethyl)ethylenediamine-1κ<i>O</i>:2κ^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>']dicopper(II) perchlorate methanol solvate
Guang-Jun Xu; Li Feng; Shi-Ping Yan; Dai-Zheng Liao; Zong-Hui Jiang; Peng Cheng; Acta Crystallographica Section E 61 (2005) m2390–m2392; doi:10.1107/S1600536805033593

data_2207180
_publ_section_title
;A new Schiff base--copper(II) complex:
 [<i>N</i>-(2-hydroxyethyl)-<i>N</i>'-(2-oxidobenzylidene)ethylenediamine-1\k^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>'][\m-<i>N</i>-(2-oxidobenzylidene)-<i>N</i>'-(2-oxidoethyl)ethylenediamine-1\k<i>O</i>:2\k^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>']dicopper(II)
 perchlorate methanol solvate
;
_journal_coeditor_code           CI6661
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2390
_journal_page_last               m2392
_journal_paper_doi               10.1107/S1600536805033593
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac
'[Cu2 (C11 H14 N2 O2) (C11 H15 N2 O2)] Cl O4, C H4 O'
_chemical_formula_moiety         'C22 H29 Cu2 N4 O4 +, Cl O4 -, C H3 OH'
_chemical_formula_sum            'C23 H33 Cl Cu2 N4 O9'
_chemical_formula_weight         672.06
_chemical_name_systematic
;
[N-(2-hydroxyethyl)-N'-(2-oxidobenzylidene)ethylenediamine-
1\k^4^O,N,N',O'][\m-N-(2-oxidobenzylidene)-N'-(2-oxidoethyl)ethylenediamine-
1\kO:2\k^4^O,N,N',O']dicopper(II) perchlorate methanol solvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 100.590(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.479(3)
_cell_length_b                   15.731(4)
_cell_length_c                   14.274(4)
_cell_measurement_reflns_used    1002
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      25.82
_cell_measurement_theta_min      3.07
_cell_volume                     2754.4(12)
_computing_cell_refinement       'SAINT (Bruker, 1997)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL (Bruker, 1997)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0360
_diffrn_reflns_av_sigmaI/netI    0.0458
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            15671
_diffrn_reflns_theta_full        26.40
_diffrn_reflns_theta_max         26.40
_diffrn_reflns_theta_min         1.66
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.698
_exptl_absorpt_correction_T_max  0.762
_exptl_absorpt_correction_T_min  0.568
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.621
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1384
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.792
_refine_diff_density_min         -0.432
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.101
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     410
_refine_ls_number_reflns         5622
_refine_ls_number_restraints     48
_refine_ls_restrained_S_all      1.157
_refine_ls_R_factor_all          0.0792
_refine_ls_R_factor_gt           0.0455
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0651P)^2^+0.0776P] where P = (Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1061
_refine_ls_wR_factor_ref         0.1255
_reflns_number_gt                3994
_reflns_number_total             5622
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            ci6661.cif
_cod_data_source_block           I
_cod_original_cell_volume        2754.5(13)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2207180