Silylamide Complexes of Chromium(II), Manganese(II), and Cobalt(II) Bearing the Ligands N(SiHMe2)2 and N(SiPhMe2)2.
König, Sonja N; Schädle, Christoph; Maichle-Mössmer, Cäcilia; Anwander, Reiner; Inorganic chemistry 53 (2014) 4585–4597; doi:10.1021/ic5002682

data_4338218
_publ_section_title
;
 Silylamide Complexes of Chromium(II), Manganese(II), and Cobalt(II)
 Bearing the Ligands N(SiHMe2)2 and N(SiPhMe2)2.
;
_journal_issue                   9
_journal_name_full               'Inorganic chemistry'
_journal_page_first              4585
_journal_page_last               4597
_journal_paper_doi               10.1021/ic5002682
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C30 H88 Co2 N6 Si8'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
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_diffrn_radiation_type           MoK\a
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_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.094
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0415P)^2^+1.0546P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic5002682_si_002.cif
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_cod_depositor_comments
'Adding full bibliography for 4338216--4338226.cif.'
_cod_original_cell_volume        2657.69(9)
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_cod_database_code               4338218