<i>catena</i>-Poly[silver(I)-bis[μ-4-methyl-1<i>H</i>-1,2,4-triazole-3(4<i>H</i>)-thione-κ^2^<i>S</i>:<i>S</i>]-silver(I)-di-μ-thiocyanato-κ^2^<i>S</i>:<i>N</i>;κ^2^<i>N</i>:<i>S</i>]
Kodcharat, Kultida; Pakawatchai, Chaveng; Saithong, Saowanit; Acta Crystallographica Section E 69 (2013) m265–m266; doi:10.1107/S160053681300946X

data_2237858
_publ_section_title
;
 <i>catena</i>-Poly[silver(I)-bis[\m-4-methyl-1<i>H</i>-1,2,4-triazole-3(4<i>H</i>)-thione-\k^2^<i>S</i>:<i>S</i>]-silver(I)-di-\m-thiocyanato-\k^2^<i>S</i>:<i>N</i>;\k^2^<i>N</i>:<i>S</i>]
;
_journal_coeditor_code           HB7066
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m265
_journal_page_last               m266
_journal_paper_doi               10.1107/S160053681300946X
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          '[Ag2 (N C S)2 (C3 H5 N3 S)2]'
_chemical_formula_moiety         'C8 H10 Ag2 N8 S4'
_chemical_formula_sum            'C8 H10 Ag2 N8 S4'
_chemical_formula_weight         562.22
_chemical_name_systematic
<i>catena</i>-Poly[silver(I)-bis[\m-4-methyl-1<i>H</i>-1,2,4-triazole-3(4<i>H</i>)-thione-\k^2^<i>S</i>:<i>S</i>]-silver(I)-di-\m-thiocyanato-\k^2^<i>S</i>:<i>N</i>;\k^2^<i>N</i>:<i>S</i>]
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                79.985(2)
_cell_angle_beta                 84.329(2)
_cell_angle_gamma                64.5080(10)
_cell_formula_units_Z            1
_cell_length_a                   7.4842(6)
_cell_length_b                   7.5420(6)
_cell_length_c                   8.4262(7)
_cell_measurement_reflns_used    3160
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.12
_cell_measurement_theta_min      2.46
_cell_volume                     422.62(6)
_computing_cell_refinement       'SAINT (Bruker, 2003)'
_computing_data_collection       'SMART (Bruker, 2003)'
_computing_data_reduction        'SAINT (Bruker, 2003)'
_computing_molecular_graphics    'Mercury (Macrae <i>et al.</i>, 2008)'
_computing_publication_material
'SHELXTL (Sheldrick, 2008), PLATON (Spek, 2009) and publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX CCD'
_diffrn_measurement_method       'Frames, each covering 0.3 \% in \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0263
_diffrn_reflns_av_sigmaI/netI    0.0228
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            5887
_diffrn_reflns_theta_full        28.30
_diffrn_reflns_theta_max         28.30
_diffrn_reflns_theta_min         2.46
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.816
_exptl_absorpt_correction_T_max  0.879
_exptl_absorpt_correction_T_min  0.682
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2003)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.209
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             272
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.785
_refine_diff_density_min         -0.626
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     104
_refine_ls_number_reflns         2083
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0322
_refine_ls_R_factor_gt           0.0290
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0262P)^2^+0.3652P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0680
_refine_ls_wR_factor_ref         0.0695
_reflns_number_gt                1904
_reflns_number_total             2083
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb7066.cif
_cod_data_source_block           I
_cod_database_code               2237858
_cod_database_fobs_code          2237858