The Salts of Copper Octafluoro- and Hexadecafluorophthalocyanines Containing [Cu(II)(F8Pc)(4-)](2-) Dianions and [CuF16Pc](-) Monoanions.
Konarev, Dmitri V.; Troyanov, Sergey I.; Kuzmin, Alexey V.; Nakano, Yoshiaki; Ishikawa, Manabu; Faraonov, Maxim A.; Khasanov, Salavat S.; Litvinov, Alexey L.; Otsuka, Akihiro; Yamochi, Hideki; Saito, Gunzi; Lyubovskaya, Rimma N.; Inorganic chemistry 56 (2017) 1804–1813; doi:10.1021/acs.inorgchem.6b01932

data_4345166
_publ_section_title
;
 The Salts of Copper Octafluoro- and Hexadecafluorophthalocyanines
 Containing [Cu(II)(F8Pc)(4-)](2-) Dianions and [CuF16Pc](-) Monoanions.
;
_journal_issue                   4
_journal_name_full               'Inorganic chemistry'
_journal_page_first              1804
_journal_page_last               1813
_journal_paper_doi               10.1021/acs.inorgchem.6b01932
_journal_volume                  56
_journal_year                    2017
_chemical_formula_moiety
'3(C32 N8 Cu F16), 3(C36 H30 N P2), 2(C7 H5 N)'
_chemical_formula_sum            'C218 H100 Cu3 F48 N29 P6'
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
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_diffrn_reflns_limit_k_min       -12
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_diffrn_reflns_theta_full        30.100
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_diffrn_reflns_theta_min         2.508
_diffrn_source                   'BL 14.1, PSF, BESSY, Berlin, Germany'
_exptl_absorpt_coefficient_mu    0.820
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.615
_exptl_crystal_description       needle
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0500P)^2^+11.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             21841
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ic6b01932_si_003.cif
_cod_data_source_block           ppncufpc
_cod_depositor_comments
'Adding full bibliography for 4345165--4345166.cif.'
_cod_database_code               4345166
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.964
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_shelx_res_checksum              89402
_shelx_hkl_checksum              33303