Hosting of [Cs(crown ether)<sub>2</sub>]<sup>+</sup> type host-guest complexes by a nano-sized molecular cuboid.
Ray, Manaswini; Krishnaswamy, Shobhana; Chand, Dillip Kumar; Chemical science 16 (2025) 17127–17138; doi:10.1039/d5sc03202d

data_1575539
_publ_section_title
;
 Hosting of [Cs(crown ether)<sub>2</sub>]<sup>+</sup> type host-guest
 complexes by a nano-sized molecular cuboid.
;
_journal_issue                   37
_journal_name_full               'Chemical science'
_journal_page_first              17127
_journal_page_last               17138
_journal_paper_doi               10.1039/d5sc03202d
_journal_volume                  16
_journal_year                    2025
_chemical_formula_sum            'C224 H280 Cs0.48 N43 O49 Pd8'
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_audit_creation_method           SHELXL-2019/3
_audit_update_record
;
2025-02-12 deposited with the CCDC.	2025-08-22 downloaded from the CCDC.
;
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_diffrn_source                   'fine focus sealed tube'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS-2016/2 - Bruker AXS area detector 
 scaling and absorption correction 
;
_exptl_crystal_colour            colorless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1600P)^2^+73.5142P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2729
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_reflns_number_gt                18414
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5sc03202d2.cif
_cod_data_source_block           shelx_CCDC3
_cod_depositor_comments
'Adding full bibliography for 1575536--1575539.cif.'
_cod_original_cell_volume        8410.8(13)
_cod_database_code               1575539
_shelx_shelxl_version_number     2019/3
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_shelx_res_checksum              50591
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