Embedding 1D or 2D cobalt-carboxylate substrates in 3D coordination polymers exhibiting slow magnetic relaxation behaviors: crystal structures, high-field EPR, and magnetic studies.
Mao, Nannan; Zhang, Biquan; Yu, Fan; Chen, Xi; Zhuang, Gui-Lin; Wang, Zhenxing; Ouyang, Zhongwen; Zhang, Tianle; Li, Bao; Dalton transactions (Cambridge, England : 2003) 46 (2017) 4786–4795; doi:10.1039/c7dt00168a

data_7042466
_publ_section_title
;
 Embedding 1D or 2D cobalt-carboxylate substrates in 3D coordination
 polymers exhibiting slow magnetic relaxation behaviors: crystal
 structures, high-field EPR, and magnetic studies.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4786
_journal_page_last               4795
_journal_paper_doi               10.1039/c7dt00168a
_journal_volume                  46
_journal_year                    2017
_chemical_formula_sum            'C26 H26 Co3 N4 O20'
_chemical_formula_weight         891.20
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-10-10 deposited with the CCDC.
2017-03-13 downloaded from the CCDC.
;
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_cell_volume                     3319(5)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
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_diffrn_measurement_device_type  BRUKER
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0760
_diffrn_reflns_Laue_measured_fraction_full 0.943
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_exptl_absorpt_coefficient_mu    1.622
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_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             2096
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_exptl_crystal_size_min          0.1
_refine_diff_density_max         1.120
_refine_diff_density_min         -1.787
_refine_diff_density_rms         0.185
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     243
_refine_ls_number_reflns         3105
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.1315
_refine_ls_R_factor_gt           0.1006
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1227P)^2^+87.1946P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             3105
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7042465--7042466.cif.'
_cod_database_code               7042466
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              76335