Supramolecular activation of a molecular photocatalyst.
Pfeffer, Michael G.; Pehlken, Christian; Staehle, Robert; Sorsche, Dieter; Streb, Carsten; Rau, Sven; Dalton transactions (Cambridge, England : 2003) 43 (2014) 13307–13315; doi:10.1039/c4dt00761a

data_7032299
_publ_section_title
;
 Supramolecular activation of a molecular photocatalyst.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13307
_journal_page_last               13315
_journal_paper_doi               10.1039/c4dt00761a
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety
'2 (C60 H60 Cl2 N10 Pd Ru), Mo8 O26, 18 (C3 H7 N O), 2 (H2 O)'
_chemical_formula_sum            'C168 H232 Cl4 Mo8 N38 O44 Pd2 Ru2'
_chemical_formula_weight         4812.16
_space_group_IT_number           2
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_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
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        CrysAlisPro, Agilent Technologies,
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
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_diffrn_radiation_monochromator  mirror
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        CrysAlisPro, Agilent Technologies,
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        Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            orange
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_refine_ls_number_restraints     20
_refine_ls_restrained_S_all      0.962
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_refine_ls_R_factor_gt           0.0447
_refine_ls_shift/su_max          0.018
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0698P)^2^]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1212
_refine_ls_wR_factor_ref         0.1266
_reflns_number_gt                13923
_reflns_number_total             22937
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_file            c4dt00761a2.cif
_cod_data_source_block           shelx_x
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