(<i>S</i>)-(–)-2,2'-Bis(2-methylallyloxy)-1,1'-binaphthyl
Ricken, Stefan; Angelovski, Goran; Schürmann, Markus; Preut, Hans; Eilbracht, Peter; Acta Crystallographica Section E 63 (2007) o551–o552; doi:10.1107/S1600536806055498

data_2212337
_publ_section_title
;
 (<i>S</i>)-(--)-2,2'-Bis(2-methylallyloxy)-1,1'-binaphthyl
;
_journal_coeditor_code           RZ2101
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              o551
_journal_page_last               o552
_journal_paper_doi               10.1107/S1600536806055498
_journal_volume                  63
_journal_year                    2007
_chemical_formula_moiety         'C28 H26 O2'
_chemical_formula_sum            'C28 H26 O2'
_chemical_formula_weight         394.49
_chemical_name_systematic
;
(S)-(-)-2,2'-Bis(2-methylallyloxy)-1,1'-binaphthyl
;
_space_group_IT_number           80
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  'I 4bw'
_symmetry_space_group_name_H-M   'I 41'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.5777(8)
_cell_length_b                   11.5777(8)
_cell_length_c                   16.2234(8)
_cell_measurement_reflns_used    14054
_cell_measurement_temperature    291.0(10)
_cell_measurement_theta_max      27.45
_cell_measurement_theta_min      3.52
_cell_volume                     2174.6(2)
_computing_cell_refinement
;
DENZO and SCALEPACK (Otwinowski & Minor, 1997)
;
_computing_data_collection       'COLLECT (Nonius, 1998)'
_computing_data_reduction
;
DENZO and SCALEPACK
;
_computing_molecular_graphics    'SHELXTL-Plus (Sheldrick, 1991)'
_computing_publication_material
;
SHELXL97, PARST95 (Nardelli, 1995) and PLATON (Spek, 2003)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      291.0(10)
_diffrn_detector_area_resol_mean '19 vertical, 18 horizontal'
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method
;
415 frames via \w-rotation (\D\w=1%) and two times 25 s per frame
(four sets at different \k-angles)
;
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.027
_diffrn_reflns_av_sigmaI/netI    0.0583
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            14054
_diffrn_reflns_theta_full        27.45
_diffrn_reflns_theta_max         27.45
_diffrn_reflns_theta_min         3.52
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.074
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.205
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             840
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.101
_refine_diff_density_min         -0.081
_refine_ls_extinction_coef       0.0185(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL97
_refine_ls_goodness_of_fit_ref   0.876
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     138
_refine_ls_number_reflns         1271
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.875
_refine_ls_R_factor_all          0.0677
_refine_ls_R_factor_gt           0.0273
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0252P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0536
_refine_ls_wR_factor_ref         0.0571
_reflns_number_gt                707
_reflns_number_total             1271
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            rz2101.cif
_cod_data_source_block           I
_cod_database_code               2212337
_cod_database_fobs_code          2212337