Half sandwich ruthenium(ii) hydrides: hydrogenation of terminal, internal, cyclic and functionalized olefins.
Bagh, Bidraha; Stephan, Douglas W.; Dalton transactions (Cambridge, England : 2003) 43 (2014) 15638–15645; doi:10.1039/c4dt02407a

data_7032279
_publ_section_title
;
 Half sandwich ruthenium(ii) hydrides: hydrogenation of terminal,
 internal, cyclic and functionalized olefins.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15638
_journal_page_last               15645
_journal_paper_doi               10.1039/c4dt02407a
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C54 H56 Cl2 F6 N6 Ru2, 2(C F3 O3 S)'
_chemical_formula_sum            'C56 H56 Cl2 F12 N6 O6 Ru2 S2'
_chemical_formula_weight         1474.22
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_diffrn_measurement_device_type  'Bruker Kappa APEX-DUO CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           CuK\a
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_diffrn_source                   'Bruker ImuS with multi-layer optics'
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.029
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0427P)^2^+1.6885P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_total             4855
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7032279--7032280.cif.'
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