Palladium-catalyzed direct β-arylation of ketones with diaryliodonium salts: a stoichiometric heavy metal-free and user-friendly approach
Huang, Zhongxing; Sam, Quynh P.; Dong, Guangbin; Chem. Sci. 6 (2015) 5491–; doi:10.1039/C5SC01636C

data_1520715
_publ_section_title
;
 Palladium-catalyzed direct \b-arylation of ketones with diaryliodonium
 salts: a stoichiometric heavy metal-free and user-friendly approach
;
_journal_issue                   10
_journal_name_full               'Chem. Sci.'
_journal_page_first              5491
_journal_paper_doi               10.1039/C5SC01636C
_journal_volume                  6
_journal_year                    2015
_chemical_formula_moiety         C28H28N2O4S4
_chemical_formula_sum            'C28 H28 N2 O4 S4'
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_space_group_name_Hall           '-I 2ya'
_space_group_name_H-M_alt        'I 1 2/a 1'
_symmetry_space_group_name_Hall  '-I 2ya'
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_audit_update_record
;
2015-04-07 deposited with the CCDC.
2015-06-30 downloaded from the CCDC.
;
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0486P)^2^+0.4197P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1080
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                7408
_reflns_number_total             8824
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5sc01636c2.cif
_cod_data_source_block           shelx
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 1520713--1520715.cif.
;
_cod_database_code               1520715
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_shelx_res_checksum              56187