Synthesis of two new polyoxometalate-based organic complexes from 2D to 3D structures for improving supercapacitor performance.
Sun, Zhe; Yu, Xiaojing; Zhen, Qingfang; Yu, Tingting; Wang, Xinming; Yang, Guixin; Song, Yongbin; Pang, Haijun; Dalton transactions (Cambridge, England : 2003) 54 (2025) 6093–6102; doi:10.1039/d5dt00284b

data_7718281
_publ_section_title
;
 Synthesis of two new polyoxometalate-based organic complexes from 2D to
 3D structures for improving supercapacitor performance.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6093
_journal_page_last               6102
_journal_paper_doi               10.1039/d5dt00284b
_journal_volume                  54
_journal_year                    2025
_chemical_formula_sum            'C40 H36 Ag4 Mo12 N20 O40 P'
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_audit_update_record
;
2024-12-23 deposited with the CCDC.	2025-03-10 downloaded from the CCDC.
;
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_cell_volume                     3598.4(5)
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      273(2)
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_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_number_reflns         8467
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.213
_refine_ls_R_factor_all          0.0916
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_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0536P)^2^+8.9634P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1283
_refine_ls_wR_factor_ref         0.1406
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5664
_reflns_number_total             8482
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5dt00284b2.cif
_cod_data_source_block           Y7
_cod_depositor_comments
'Adding full bibliography for 7718281--7718282.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7718281
_shelxl_version_number           2014-3
_shelx_res_checksum              71482
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