In search for tuneable intramolecular intermetallic interactions in polynuclear lanthanide complexes
Dalla Favera, Natalia; Guénée, Laure; Bernardinelli, Gérald; Piguet, Claude; Dalton Transactions  (2009) 7625–7638; doi:10.1039/b905131g

data_7002290
_publ_section_title
;
 In search for tuneable intramolecular intermetallic interactions in
 polynuclear lanthanide complexes
;
_journal_issue                   37
_journal_name_full               'Dalton Transactions'
_journal_page_first              7625
_journal_page_last               7638
_journal_paper_doi               10.1039/b905131g
_journal_year                    2009
_chemical_formula_moiety         'C21 H25 Eu N8 O10, 2(C2 H3 N)'
_chemical_formula_sum            'C25 H31 Eu N10 O10'
_chemical_formula_weight         783.6
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
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_audit_creation_date             2008-01-21
_audit_creation_method           from_xtal_archive_file_using_CIFIO
_audit_update_record             2008-04-15
_cell_angle_alpha                94.322(8)
_cell_angle_beta                 93.184(9)
_cell_angle_gamma                105.660(8)
_cell_formula_units_Z            2
_cell_length_a                   9.7831(7)
_cell_length_b                   9.9818(7)
_cell_length_c                   16.8841(12)
_cell_measurement_reflns_used    7998
_cell_measurement_temperature    150
_cell_measurement_theta_max      26.5
_cell_measurement_theta_min      4.1
_cell_volume                     1578.1(2)
_computing_cell_refinement       'CELL (Stoe & Cie, 1999)'
_computing_data_collection       'EXPOSE (Stoe & Cie, 1999)'
_computing_data_reduction        'XRED (Stoe & Cie, 1999)'
_computing_molecular_graphics    xtal_gx3
_computing_publication_material  xtal_CIFIO
_computing_structure_refinement  xtal_CRYLSQ
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 6
_diffrn_measured_fraction_theta_full 1.0
_diffrn_measured_fraction_theta_max 1.0
_diffrn_measurement_device_type  'Stoe Ipds'
_diffrn_measurement_method       \f
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .022
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            20807
_diffrn_reflns_theta_full        26.5
_diffrn_reflns_theta_max         26.5
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    2.06
_exptl_absorpt_correction_T_max  .8314
_exptl_absorpt_correction_T_min  .6241
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'XRED; Stoe & Cie, 1999'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.649
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             788
_exptl_crystal_size_max          .368
_exptl_crystal_size_mid          .175
_exptl_crystal_size_min          .095
_refine_diff_density_max         1.081
_refine_diff_density_min         -.633
_refine_ls_abs_structure_details none
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.36(1)
_refine_ls_hydrogen_treatment    noref
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_refine_ls_R_factor_gt           .022
_refine_ls_shift/su_max          .002
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     \w=1/[\s^2^(Fo)+0.0001(Fo^2^)]
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         .024
_reflns_number_gt                5416
_reflns_number_total             6349
_reflns_threshold_expression     'refl observed if Fo > 3.99 \s(Fo)'
_cod_data_source_file            b905131g.txt
_cod_data_source_block           3
_cod_database_code               7002290