Bis[μ-(<i>E</i>)-<i>N</i>-(pyridin-3-ylmethylidene)hydroxyamine]-κ^2^<i>N</i>^1^:<i>N</i>^3^;κ^2^<i>N</i>^3^:<i>N</i>^1^-bis{[(<i>E</i>)-<i>N</i>-(pyridin-3-ylmethylidene-κ<i>N</i>)hydroxyamine]silver(I)} dinitrate
Gao, Shan; Ng, Seik Weng; Acta Crystallographica Section E 68 (2012) m1547–; doi:10.1107/S1600536812045898

data_2237077
_publ_section_title
;
 Bis[\m-(<i>E</i>)-<i>N</i>-(pyridin-3-ylmethylidene)hydroxyamine]-\k^2^<i>N</i>^1^:<i>N</i>^3^;\k^2^<i>N</i>^3^:<i>N</i>^1^-bis{[(<i>E</i>)-<i>N</i>-(pyridin-3-ylmethylidene-\k<i>N</i>)hydroxyamine]silver(I)}
 dinitrate
;
_journal_coeditor_code           XU5646
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1547
_journal_paper_doi               10.1107/S1600536812045898
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Ag2 (C6 H6 N2 O)4] (N O3)2'
_chemical_formula_moiety         'C24 H24 Ag2 N8 O4 2+, 2(N O3 -)'
_chemical_formula_sum            'C24 H24 Ag2 N10 O10'
_chemical_formula_weight         828.27
_chemical_name_systematic
;
Bis[\m-(<i>E</i>)-<i>N</i>-(pyridin-3-ylmethylidene)hydroxyamine]-
\k^2^<i>N</i>^1^:<i>N</i>^3^;\k^2^<i>N</i>^3^:<i>N</i>^1^-bis{[(<i>E</i>)-
<i>N</i>-(pyridin-3-ylmethylidene-\k<i>N</i>)hydroxyamine]silver(I)}
dinitrate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.934(4)
_cell_angle_beta                 95.008(4)
_cell_angle_gamma                111.360(3)
_cell_formula_units_Z            1
_cell_length_a                   7.2913(10)
_cell_length_b                   8.3395(10)
_cell_length_c                   13.1415(17)
_cell_measurement_reflns_used    6130
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.44
_cell_measurement_theta_min      3.02
_cell_volume                     738.38(17)
_computing_cell_refinement       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_collection       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC, 2002)'
_computing_molecular_graphics    'X-SEED (Barbour, 2001)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID IP'
_diffrn_measurement_method       '\w scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0350
_diffrn_reflns_av_sigmaI/netI    0.0427
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            7293
_diffrn_reflns_theta_full        27.44
_diffrn_reflns_theta_max         27.44
_diffrn_reflns_theta_min         3.02
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.399
_exptl_absorpt_correction_T_max  0.7969
_exptl_absorpt_correction_T_min  0.7300
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.863
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             412
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.17
_refine_diff_density_max         1.714
_refine_diff_density_min         -0.336
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.112
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     210
_refine_ls_number_reflns         3341
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.112
_refine_ls_R_factor_all          0.0460
_refine_ls_R_factor_gt           0.0396
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0560P)^2^+0.3361P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0946
_refine_ls_wR_factor_ref         0.1072
_reflns_number_gt                2896
_reflns_number_total             3341
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            xu5646.cif
_cod_data_source_block           I
_cod_original_cell_volume        738.38(16)
_cod_database_code               2237077
_cod_database_fobs_code          2237077