A covalent deprotection strategy for assembling supramolecular coordination polymers from metal-organic cages.
Schneider, Matthew L.; Linder-Patton, Oliver M; Bloch, Witold M.; Chemical communications (Cambridge, England) 56 (2020) 12969–12972; doi:10.1039/d0cc05349j

data_7127747
_publ_section_title
;
 A covalent deprotection strategy for assembling supramolecular
 coordination polymers from metal-organic cages.
;
_journal_issue                   85
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              12969
_journal_page_last               12972
_journal_paper_doi               10.1039/d0cc05349j
_journal_volume                  56
_journal_year                    2020
_chemical_formula_sum            'C120 H100 Cu4 N8 O28'
_chemical_formula_weight         2356.23
_chemical_name_systematic        CBoc
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-06-30 deposited with the CCDC.	2020-09-29 downloaded from the CCDC.
;
_cell_angle_alpha                72.20(3)
_cell_angle_beta                 86.15(3)
_cell_angle_gamma                65.93(3)
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_cell_length_c                   23.421(5)
_cell_measurement_reflns_used    36618
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      22.25
_cell_measurement_theta_min      0.68
_cell_volume                     7610(4)
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_computing_data_collection       'BluIce (McPhillips, 2002)'
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_computing_molecular_graphics    'shelXle (Huebschle, 2014)'
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_computing_structure_solution    'SHELXT-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.921
_diffrn_measured_fraction_theta_max 0.921
_diffrn_measurement_device_type  'ADSC Quantum 210r'
_diffrn_measurement_method       'Phi Scan'
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_exptl_crystal_colour            green
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_exptl_crystal_recrystallization_method 'slow-vapour diffusion'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0942P)^2^+9.3601P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_block           Boc_Cu4L4
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