Two Stereoisomers of an S-Bridged RhIII2PtII2 Tetranuclear Complex [{Pt(NH3)2}2{Rh(aet)3}2]4+ That Lead to a Discrete and a 1D RhIII2PtII2AgI Structures by Reacting with AgI (aet = 2-Aminoethanethiolate)
Yu Chikamoto; Tatsuya Kawamoto; Asako Igashira-Kamiyama; Takumi Konno; Inorganic Chemistry 44 (2005) 1601–1610; doi:10.1021/ic048680k

data_4308736
_publ_contact_author
;
     Takumi Konno
  Department of Chemistry, Graduate School of Science, Osaka University, 
Toyonaka, Osaka, 560-0043, Japan
;
_publ_contact_author_email       ' konno@ch.wani.osaka-u.ac.jp '
_publ_contact_author_fax         ' +81-6-6850-5765 '
_publ_contact_author_phone       ' +81-6-6850-5765 '
_publ_section_title
;
Two Stereoisomers of an S-Bridged RhIII2PtII2 Tetranuclear Complex
[{Pt(NH3)2}2{Rh(aet)3}2]4+ That Lead to a Discrete and a 1D
RhIII2PtII2AgI Structures by Reacting with AgI (aet = 2-Aminoethanethiolate)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1601
_journal_page_last               1610
_journal_paper_doi               10.1021/ic048680k
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C12 H48 Cl4 O16 Pt2 Rh2 N10 S6'
_chemical_formula_sum            'C12 H48 Cl4 N10 O16 Pt2 Rh2 S6'
_chemical_formula_weight         1518.80
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_type_scat_source           'International Tables (1974)'
_cell_angle_alpha                103.89(3)
_cell_angle_beta                 93.10(3)
_cell_angle_gamma                98.12(1)
_cell_formula_units_Z            2
_cell_length_a                   14.423(3)
_cell_length_b                   18.010(3)
_cell_length_c                   8.903(6)
_cell_measurement_reflns_used    22
_cell_measurement_temperature    298
_cell_measurement_theta_max      17.5
_cell_measurement_theta_min      15.8
_cell_volume                     2213.2(16)
_computing_cell_refinement       'MXC(MAC Science)'
_computing_data_collection       'MXC(MAC Science)'
_computing_data_reduction        Crystan
_computing_molecular_graphics    Crystan
_computing_publication_material  Crystan
_computing_structure_refinement  Crystan
_computing_structure_solution    Crystan
_diffrn_measurement_device       'Mac Science MXC3'
_diffrn_measurement_method       theta/2theta
_diffrn_orient_matrix_type       standard
_diffrn_orient_matrix_UB_11      0.04264
_diffrn_orient_matrix_UB_12      -0.03790
_diffrn_orient_matrix_UB_13      -0.04082
_diffrn_orient_matrix_UB_21      0.05171
_diffrn_orient_matrix_UB_22      0.04382
_diffrn_orient_matrix_UB_23      0.00334
_diffrn_orient_matrix_UB_31      0.02130
_diffrn_orient_matrix_UB_32      -0.00006
_diffrn_orient_matrix_UB_33      0.10873
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.033
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            8984
_diffrn_reflns_theta_max         26.43
_diffrn_standards_decay_%        33.887
_diffrn_standards_interval_count 100
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    7.671
_exptl_absorpt_correction_T_max  0.994
_exptl_absorpt_correction_T_min  0.568
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    2.279
_exptl_crystal_description       Needle
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         4.00
_refine_diff_density_min         -3.22
_refine_ls_extinction_method     None
_refine_ls_goodness_of_fit_obs   4.561
_refine_ls_hydrogen_treatment    refU
_refine_ls_number_parameters     313
_refine_ls_number_reflns         6147
_refine_ls_R_factor_obs          0.073
_refine_ls_shift/esd_max         1.3284
_refine_ls_shift/esd_mean        0.0159
_refine_ls_structure_factor_coef F^2
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_obs         0.089
_reflns_number_observed          6147
_reflns_number_total             7364
_reflns_observed_criterion       refl_observed_if_I_>_2.00_sigma(I)
_cod_data_source_file            ic048680ksi20041205_091750_2.cif
_cod_data_source_block           '[1b](ClO4)4*2H2O'
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_atom_site_thermal_displace_type' tag value 'Uij' was replaced with
'Uani' value 32 times.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        2213(2)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C12 H48 Cl4 O16 Pt2 Rh2 N10 S6'
_cod_database_code               4308736