π-Nucleophile Traps for Metallonitrene/Alkyne Cascade Reactions: A Versatile Process for the Synthesis of α-Aminocyclopropanes and β-Aminostyrenes
Aaron R. Thornton; Véronique I. Martin; Simon B. Blakey; Journal of the American Chemical Society 131 (2009) 2434–2435; doi:10.1021/ja809078d

data_4103955
_publ_section_title
;
 \p-Nucleophile Traps for Metallonitrene/Alkyne Cascade Reactions: A
 Versatile Process for the Synthesis of \a-Aminocyclopropanes and
 \b-Aminostyrenes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              2434
_journal_page_last               2435
_journal_paper_doi               10.1021/ja809078d
_journal_volume                  131
_journal_year                    2009
_chemical_formula_moiety         'C15 H19 N O3 S'
_chemical_formula_sum            'C15 H19 N O3 S'
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_cell_angle_beta                 106.307(3)
_cell_angle_gamma                90.00
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_cell_length_b                   25.3593(12)
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_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      65.41
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_computing_cell_refinement       'Bruker SAINT'
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_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_theta_min         3.49
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_exptl_absorpt_correction_T_min  0.5147
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.360
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
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_exptl_crystal_size_max          0.37
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         2412
_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0400
_refine_ls_R_factor_gt           0.0345
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0850P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_database_code               4103955