Copper Complexes of Nitrogen-Anchored Tripodal N-Heterocyclic Carbene Ligands
Xile Hu; Ingrid Castro-Rodriguez; Karsten Meyer; Journal of the American Chemical Society 125 (2003) 12237–12245; doi:10.1021/ja036880+

data_4114244
_publ_contact_author
;
        Karsten Meyer
        University of California, San Diego
        Department of Chemistry & Biochemistry
        9500 Gilman Dr. MC 0358
        La Jolla CA, 92093-0358
        United States of America
;
_publ_contact_author_email       kmeyer@ucsd.edu
_publ_contact_author_fax         '1 858 534 5383'
_publ_contact_author_phone       '1 858 822 4247'
_publ_section_title
;
 Copper Complexes of Nitrogen-Anchored Tripodal N-Heterocyclic Carbene
 Ligands
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              12237
_journal_page_last               12245
_journal_paper_doi               10.1021/ja036880+
_journal_volume                  125
_journal_year                    2003
_chemical_formula_sum            'C36 H39 Br Cu N7'
_chemical_formula_weight         713.19
_chemical_name_systematic
; 
 ? 
;
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_cell_length_c                   20.713(6)
_cell_measurement_temperature    100(2)
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_computing_cell_refinement       'Bruker SMART'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_av_sigmaI/netI    0.0757
_diffrn_reflns_limit_h_max       15
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_diffrn_reflns_theta_max         22.50
_diffrn_reflns_theta_min         1.13
_exptl_absorpt_coefficient_mu    1.867
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.404
_exptl_crystal_description       plates
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_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0441P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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