Three-component assembly of a metal‒inorganic 3D Co(ii) polymer containing bridging hydrazine
Sengupta, Oindrila; Mukherjee, Partha Sarathi; Dalton Transactions  (2009) 7599–7601; doi:10.1039/b907204g

data_7002297
_publ_section_title
;
 Three-component assembly of a metal--inorganic 3D Co(ii) polymer
 containing bridging hydrazine
;
_journal_issue                   37
_journal_name_full               'Dalton Transactions'
_journal_page_first              7599
_journal_page_last               7601
_journal_paper_doi               10.1039/b907204g
_journal_year                    2009
_chemical_formula_sum            'Co3 H8 N22'
_chemical_formula_weight         493.07
_space_group_IT_number           14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.4390(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   9.8472(8)
_cell_length_b                   7.1125(6)
_cell_length_c                   10.5241(8)
_cell_measurement_temperature    293(2)
_cell_volume                     729.11(10)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.964
_diffrn_measured_fraction_theta_max 0.964
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0194
_diffrn_reflns_av_sigmaI/netI    0.0190
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            6077
_diffrn_reflns_theta_full        28.34
_diffrn_reflns_theta_max         28.34
_diffrn_reflns_theta_min         2.65
_exptl_absorpt_coefficient_mu    3.420
_exptl_absorpt_correction_T_max  0.5337
_exptl_absorpt_correction_T_min  0.4075
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    2.246
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             486
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.21
_refine_diff_density_max         0.380
_refine_diff_density_min         -0.263
_refine_diff_density_rms         0.070
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.099
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     131
_refine_ls_number_reflns         1746
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.099
_refine_ls_R_factor_all          0.0215
_refine_ls_R_factor_gt           0.0195
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0275P)^2^+0.0393P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0470
_refine_ls_wR_factor_ref         0.0479
_reflns_number_gt                1639
_reflns_number_total             1746
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            b907204g.txt
_cod_data_source_block           Comp_1
_cod_original_formula_sum        'H8 Co3 N22'
_cod_database_code               7002297