Synthesis and characterisation of an N-heterocyclic carbene with spatially-defined steric impact.
Shaw, Paul; Kennedy, Alan R.; Nelson, David J.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 11772–11780; doi:10.1039/c6dt02100j

data_7039572
_publ_section_title
;
 Synthesis and characterisation of an N-heterocyclic carbene with
 spatially-defined steric impact.
;
_journal_issue                   29
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               11780
_journal_paper_doi               10.1039/c6dt02100j
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C45 H40 Ag Cl N2'
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;
2016-05-25 deposited with the CCDC.
2016-06-16 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Oxford Diffraction Gemini S'
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0770P)^2^+1.2511P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt02100j2.cif
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_cod_depositor_comments
'Adding full bibliography for 7039571--7039574.cif.'
_cod_database_code               7039572