Alkali metal complex-mediated ring-opening polymerization of rac-LA, ε-caprolactone, and δ-valerolactone
Harinath, Adimulam; Bhattacharjee, Jayeeta; Sarkar, Alok; Panda, Tarun K.; New Journal of Chemistry 43 (2019) 8882–; doi:10.1039/C9NJ01130G

data_7058378
_publ_section_title
;
 Alkali metal complex-mediated ring-opening polymerization of rac-LA,
 \e-caprolactone, and \d-valerolactone
;
_journal_issue                   23
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              8882
_journal_paper_doi               10.1039/C9NJ01130G
_journal_volume                  43
_journal_year                    2019
_chemical_formula_moiety         'C18 H15 N2 O2 P Se'
_chemical_formula_sum            'C18 H15 N2 O2 P Se'
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_space_group_name_Hall           '-C 2yc'
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_symmetry_space_group_name_Hall  '-C 2yc'
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;
2019-04-07 deposited with the CCDC.    2019-05-07 downloaded from the CCDC.
;
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'CrysAlisPro, Agilent Technologies,Version 1.171.35.19 (release 27-10-2011CrysAlis171 .NET)(compiled Oct 27'
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'CrysAlisPro, Agilent Technologies,Version 1.171.35.19 (release 27-10-2011CrysAlis171 .NET)(compiled Oct 27'
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'CrysAlisPro, Agilent Technologies,Version 1.171.35.19 (release 27-10-2011CrysAlis171 .NET)(compiled Oct 27'
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0509P)^2^+2.0904P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0985
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                2754
_reflns_number_total             3298
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           2-H
_cod_depositor_comments
'Adding full bibliography for 7058378--7058379.cif.'
_cod_original_cell_volume        3488.7(7)
_cod_database_code               7058378
_shelx_shelxl_version_number     2016/6
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