Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate
Yoichi Arimoto; Shin-ichi Ohkoshi; Zhuang Jin Zhong; Hidetake Seino; Yasushi Mizobe; Kazuhito Hashimoto; Journal of the American Chemical Society 125 (2003) 9240–9241; doi:10.1021/ja030130i

data_4114001
_publ_section_title
;
 Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              9240
_journal_page_last               9241
_journal_paper_doi               10.1021/ja030130i
_journal_volume                  125
_journal_year                    2003
_chemical_formula_moiety         'C20 H10 Co Cs N12 O W '
_chemical_formula_sum            'C20 H10 Co Cs N12 O W'
_chemical_formula_weight         810.07
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                116.30(1)
_cell_angle_beta                 90.02(1)
_cell_angle_gamma                96.97(1)
_cell_formula_units_Z            2
_cell_length_a                   7.2979(7)
_cell_length_b                   13.937(3)
_cell_length_c                   14.381(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    298.1
_cell_measurement_theta_max      15.9
_cell_measurement_theta_min      12.5
_cell_volume                     1299.2(4)
_computing_cell_refinement       WinAFC
_computing_data_collection       WinAFC
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 2.00'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_measured_fraction_theta_full 0.9993
_diffrn_measured_fraction_theta_max 0.9993
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.021
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            6442
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_standards_decay_%        -3.20
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    6.486
_exptl_absorpt_correction_T_max  0.937
_exptl_absorpt_correction_T_min  0.286
_exptl_absorpt_correction_type
;
\y scans (North,Phillips & Matthews, 1968)
;
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.071
_exptl_crystal_description       plate
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.01
_refine_diff_density_max         2.73
_refine_diff_density_min         -1.49
_refine_ls_extinction_coef       71.3(5)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     361
_refine_ls_number_reflns         5070
_refine_ls_R_factor_gt           0.0330
_refine_ls_shift/su_max          0.0120
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.001Fo^2^ + 1.000\s^2^(Fo)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0880
_reflns_number_gt                5070
_reflns_number_total             5973
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ja030130i.cif
_cod_data_source_block           '_Cs[{Co(3-CNpy)2}{W(CN)8}]H2O'
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C20 H10 Co Cs N12 O W '
_cod_database_code               4114001