Platinum(IV) Analogues of AMD473 (cis-[PtCl2(NH3)(2-picoline)]): Preparative, Structural, and Electrochemical Studies
Battle, Andrew R.; Choi, Robin; Hibbs, David E.; Hambley, Trevor W.; Inorganic Chemistry 45 (2006) 6317–6322; doi:10.1021/ic060273g

data_4332354
_publ_section_title
;
 Platinum(IV) Analogues of AMD473 (cis-[PtCl2(NH3)(2-picoline)]):&#x00A0;
 Preparative, Structural, and Electrochemical Studies
;
_journal_issue                   16
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6317
_journal_page_last               6322
_journal_paper_doi               10.1021/ic060273g
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C6 H14 Cl2 N2 O3 Pt'
_chemical_formula_weight         428.18
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2006-01-31T15:20:54-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 97.00(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_b                   9.7710(16)
_cell_length_c                   12.207(3)
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_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      2.09
_cell_volume                     1160.8(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.943
_diffrn_measured_fraction_theta_max 0.943
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0
_diffrn_reflns_av_unetI/netI     0.0284
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
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_diffrn_reflns_limit_k_min       0
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_diffrn_reflns_theta_full        28.27
_diffrn_reflns_theta_max         28.27
_diffrn_reflns_theta_min         2.09
_exptl_absorpt_coefficient_mu    12.532
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.45
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             800
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.125
_exptl_crystal_size_min          0.08
_refine_diff_density_max         2.223
_refine_diff_density_min         -2.669
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.03
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0394P)^2^+3.2670P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0749
_refine_ls_wR_factor_ref         0.0764
_reflns_number_gt                2585
_reflns_number_total             2712
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic060273gsup3.cif
_cod_data_source_block           s92amd1
_cod_original_cell_volume        1160.9(4)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4332354