Reactivity of boraguanidinato germylenes toward carbonyl compounds and isocyanides: C-O, C-F and C-N bond activation.
Böserle, Jiří; Jambor, Roman; RůŽička, Aleš; Erben, Milan; Dostál, Libor; Dalton transactions (Cambridge, England : 2003) 49 (2020) 4869–4877; doi:10.1039/c9dt04839a

data_7703711
_publ_section_title
;
 Reactivity of boraguanidinato germylenes toward carbonyl compounds and
 isocyanides: C-O, C-F and C-N bond activation.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4869
_journal_page_last               4877
_journal_paper_doi               10.1039/c9dt04839a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C52 H69 B2 F3 Ge2 N6 O, 0.5(C6 H6)'
_chemical_formula_sum            'C55 H72 B2 F3 Ge2 N6 O'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_audit_update_record
;
2019-12-10 deposited with the CCDC.	2020-03-06 downloaded from the CCDC.
;
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;
SADABS-2016/2 - Bruker AXS area detector
scaling and absorption correction
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt04839a2.cif
_cod_data_source_block           ld180521ge1
_cod_depositor_comments
'Adding full bibliography for 7703706--7703711.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7703711
_exptl_absorpt_special_details
;
The ratio of minimum to maximum
apparent transmission was 0.649
;
_shelxl_version_number           2013-4
_shelx_res_checksum              67260
_shelx_fab_checksum              67661