Enantioselective Synthesis of α-Silylamines by Meerwein-Ponndorf-Verley-Type Reduction of α-Silylimines by a Chiral Lithium Amide.
Kondo, Yasuhiro; Sasaki, Michiko; Kawahata, Masatoshi; Yamaguchi, Kentaro; Takeda, Kei; The Journal of organic chemistry 79 (2014) 3601–3609; doi:10.1021/jo500441a

data_4029294
_publ_section_title
;
 Enantioselective Synthesis of \a-Silylamines by
 Meerwein-Ponndorf-Verley-Type Reduction of \a-Silylimines by a Chiral
 Lithium Amide.
;
_journal_issue                   8
_journal_name_full               'The Journal of organic chemistry'
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_journal_paper_doi               10.1021/jo500441a
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;
 Flack x determined using 6010 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
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_refine_ls_structure_factor_coef Fsqd
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;
 w=1/[\s^2^(Fo^2^)+(0.0399P)^2^+7.1491P]
 where P=(Fo^2^+2Fc^2^)/3
;
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;Adding full bibliography for
 ./tmp-cod-update-bibliographies-12971/cifs/4029294.cif.
;
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