Crystal Growth, Structural, Electrical, and Magnetic Properties of Mixed-Valent Compounds YbOs2Al10 and LuOs2Al10.
Zhang, Xu; Yi, Wei; Feng, Kai; Wu, Desheng; Yang, Yifeng; Zheng, Ping; Yao, Jiyong; Matsushita, Yoshitaka; Sato, Akira; Jiang, Hongwei; Wang, Hai; Shi, Youguo; Yamaura, Kazunari; Wang, Nanlin; Inorganic chemistry 53 (2014) 4387–4393; doi:10.1021/ic403168v

data_4338171
_publ_section_title
;
 Crystal Growth, Structural, Electrical, and Magnetic Properties of
 Mixed-Valent Compounds YbOs2Al10 and LuOs2Al10.
;
_journal_issue                   9
_journal_name_full               'Inorganic chemistry'
_journal_page_first              4387
_journal_page_last               4393
_journal_paper_doi               10.1021/ic403168v
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'Al10 Lu Os2'
_chemical_formula_weight         825.17
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           63
_space_group_name_Hall           '-C 2c 2'
_space_group_name_H-M_alt        'C m c m'
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.0947(4)
_cell_length_b                   10.1608(5)
_cell_length_c                   9.1007(4)
_cell_measurement_reflns_used    6236
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      40.423
_cell_measurement_theta_min      3.006
_cell_volume                     840.99(7)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.964
_diffrn_measurement_device_type  'Bruker APEX CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0565
_diffrn_reflns_av_unetI/netI     0.0353
_diffrn_reflns_Laue_measured_fraction_full 0.979
_diffrn_reflns_Laue_measured_fraction_max 0.964
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            9404
_diffrn_reflns_point_group_measured_fraction_full 0.979
_diffrn_reflns_point_group_measured_fraction_max 0.964
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         40.637
_diffrn_reflns_theta_min         3.749
_exptl_absorpt_coefficient_mu    42.754
_exptl_absorpt_correction_T_max  0.0550
_exptl_absorpt_correction_T_min  0.0076
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2001)'
_exptl_crystal_colour            'Metallic gray'
_exptl_crystal_density_diffrn    6.517
_exptl_crystal_description       Plate
_exptl_crystal_F_000             1412
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.050
_refine_diff_density_max         9.291
_refine_diff_density_min         -5.784
_refine_diff_density_rms         0.800
_refine_ls_extinction_coef       0.0083(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     41
_refine_ls_number_reflns         1433
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.090
_refine_ls_R_factor_all          0.0363
_refine_ls_R_factor_gt           0.0357
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0635P)^2^+1.3076P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0904
_refine_ls_wR_factor_ref         0.0909
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1393
_reflns_number_total             1433
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ic403168v_si_003.cif
_cod_data_source_block           shelx
_cod_depositor_comments
'Adding full bibliography for 4338170--4338171.cif.'
_cod_database_code               4338171
_shelx_hkl_checksum              34052