Neighboring phenolic group-activated gem-difluoroallylboration of imines for the catalyst-free synthesis of gem-difluorohomoallylamines.
Yang, Xing; Zhang, Feng; Zhou, Yang; Huang, Yi-Yong; Organic & biomolecular chemistry 16 (2018) 3367–3371; doi:10.1039/c8ob00541a

data_7156231
_publ_section_title
;
 Neighboring phenolic group-activated gem-difluoroallylboration of imines
 for the catalyst-free synthesis of gem-difluorohomoallylamines.
;
_journal_issue                   18
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              3367
_journal_page_last               3371
_journal_paper_doi               10.1039/c8ob00541a
_journal_volume                  16
_journal_year                    2018
_chemical_formula_sum            'C24 H20 F2 N2 O4 S'
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-03-23 deposited with the CCDC.
2018-04-11 downloaded from the CCDC.
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0469P)^2^+0.2798P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7156231.cif.'
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