Impact of Mn3+ upon Structure and Magnetism of the Perovskite Derivative Pb2-xBaxFeMnO5 (x~ 0.7)
N. Barrier; O. I. Lebedev; Md. Motin Seikh; F. Porcher; B. Raveau; Inorganic Chemistry 52 (2013) 6073–6082; doi:10.1021/ic400426m

data_4334920
_publ_contact_author_address
; 
Laboratoire CRISMAT 
UMR6508 
6 Boulevard du Mar\'echal Juin 
14050 CAEN cedex 4 FRANCE
;
_publ_contact_author_email       nicolas.barrier@ensicaen.fr
_publ_contact_author_fax
;
+33 2 31 95 16 00
;
_publ_contact_author_name
;
Nicolas Barrier
;
_publ_contact_author_phone
;
+33 2 31 45 26 31
;
_publ_section_title
;
 Impact of Mn3+ upon Structure and Magnetism of the Perovskite Derivative
 Pb2-xBaxFeMnO5 (x~ 0.7)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6073
_journal_page_last               6082
_journal_paper_doi               10.1021/ic400426m
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'Ba0.738 Fe1.026 Mn0.974 O5 Pb1.262'
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_chemical_name_systematic        ' ?'
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_cell_length_c                   21.4036(17)
_cell_measurement_temperature    293
_cell_volume                     482.36(6)
_diffrn_ambient_temperature      293
_diffrn_detector_type            PSD
_diffrn_measurement_device_type  '3T2 diffractometer'
_diffrn_radiation_probe          neutron
_diffrn_radiation_type           neutron
_diffrn_radiation_wavelength     1.22515
_diffrn_source                   'neutron LLB'
_diffrn_source_type              neutron
_exptl_absorpt_coefficient_mu    0.009
_exptl_crystal_density_diffrn    7.6212
_exptl_crystal_F_000             943
_pd_char_colour                  black
_pd_meas_2theta_range_inc        0.05
_pd_meas_2theta_range_max        121.030
_pd_meas_2theta_range_min        4.580
_pd_meas_number_of_points        2330
_pd_meas_scan_method             cont
_pd_proc_2theta_range_inc        0.05
_pd_proc_2theta_range_max        121.03
_pd_proc_2theta_range_min        4.58
_pd_proc_ls_background_function  '12 Legendre polynoms'
_pd_proc_ls_pref_orient_corr     none
_pd_proc_ls_profile_function     Pseudo-Voigt
_pd_proc_ls_prof_R_factor        0.0238
_pd_proc_ls_prof_wR_expected     0.0155
_pd_proc_ls_prof_wR_factor       0.0301
_pd_spec_mount_mode              transmission
_refine_diff_density_max         0.54
_refine_diff_density_min         -0.53
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_refine_ls_number_constraints    9
_refine_ls_number_parameters     47
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_refine_ls_R_factor_all          0.0226
_refine_ls_R_factor_gt           0.0224
_refine_ls_shift/su_max          0.0054
_refine_ls_shift/su_mean         0.0012
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0288
_refine_ls_wR_factor_gt          0.0288
_cod_data_source_file            ic400426m_si_001.cif
_cod_data_source_block           I
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