Platinum(ii) diimine complexes of acetylides containing 7-azaindolyl and 2,2?-dipyridylamino functional groupsElectronic supplementary information (ESI) available: emission spectra of 1?4 in the solid state at 298 and 77 K; structures and packing diagrams of 1 and 4. See http://www.rsc.org/suppdata/dt/b3/b305408j/
Kang, Youngjin; Lee, Junghyun; Song, Datong; Wang, Suning; Dalton Transactions  (2003) 3493–; doi:10.1039/b305408j

data_7013191
_publ_section_title
;
 Platinum(ii) diimine complexes of acetylides containing 7-azaindolyl
 and 2,2?-dipyridylamino functional groupsElectronic supplementary
 information (ESI) available: emission spectra of 1?4 in the solid
 state at 298 and 77 K; structures and packing diagrams of 1 and 4. See
 http://www.rsc.org/suppdata/dt/b3/b305408j/
;
_journal_issue                   18
_journal_name_full               'Dalton Transactions'
_journal_page_first              3493
_journal_paper_doi               10.1039/b305408j
_journal_year                    2003
_chemical_formula_sum            'C52 H41 Cl2 N8 Pt'
_chemical_formula_weight         1043.93
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                70.846(4)
_cell_angle_beta                 81.790(5)
_cell_angle_gamma                72.416(6)
_cell_formula_units_Z            2
_cell_length_a                   10.154(3)
_cell_length_b                   13.057(3)
_cell_length_c                   19.080(5)
_cell_measurement_temperature    293(2)
_cell_volume                     2275.3(10)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.841
_diffrn_measured_fraction_theta_max 0.841
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0549
_diffrn_reflns_av_sigmaI/netI    0.2606
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            13823
_diffrn_reflns_theta_full        28.26
_diffrn_reflns_theta_max         28.26
_diffrn_reflns_theta_min         2.85
_exptl_absorpt_coefficient_mu    3.247
_exptl_absorpt_correction_T_max  0.81
_exptl_absorpt_correction_T_min  1.00
_exptl_absorpt_correction_type   empirical
_exptl_crystal_density_diffrn    1.524
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1042
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.758
_refine_diff_density_min         -1.344
_refine_diff_density_rms         0.143
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.850
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     553
_refine_ls_number_reflns         9491
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.850
_refine_ls_R_factor_all          0.1722
_refine_ls_R_factor_gt           0.0589
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0464P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1171
_refine_ls_wR_factor_ref         0.1437
_reflns_number_gt                3924
_reflns_number_total             9491
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b305408j.txt
_cod_data_source_block           compound_4
_cod_original_cell_volume        2275.4(10)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7013191