LMucko/crystallography-open-database huggingface dataset:
Synthesis of Nitrogen Heterocycles by Diastereoselective Intramolecular Aminocarbene Annelation
Dötz, Karl Heinz; Schäfer, Thomas; Harms, Klaus; Angewandte Chemie, International Edition in English 29 (1990) 176–177; doi:10.1002/anie.199001761

data_1100317
_publ_section_title
;
 Synthesis of Nitrogen Heterocycles by Diastereoselective Intramolecular
 Aminocarbene Annelation
;
_journal_coden_ASTM              ACIEAY
_journal_issue                   2
_journal_name_full
;
 Angewandte Chemie, International Edition in English
;
_journal_page_first              176
_journal_page_last               177
_journal_paper_doi               10.1002/anie.199001761
_journal_volume                  29
_journal_year                    1990
_chemical_formula_sum            'C16 H15 Cr N O4'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 95.38(1)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   8.854(2)
_cell_length_b                   13.399(1)
_cell_length_c                   25.919(6)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C16 H15 Cr1 N1 O4'
_cod_database_code               1100317
X-Ray Structure Investigation of 2,2-Diphenyl-1-(phenylsulfonyl)cyclopropyllithium-Dimethoxyethane (2/3): A Sulfonyl "Carbanion" Having an α-C Atom with a Tetrahedral Configuration
Hollstein, Werner; Harms, Klaus; Marsch, Michael; Boche, Gernot; Angewandte Chemie, International Edition in English 27 (1988) 846–847; doi:10.1002/anie.198808461

data_1100318
_publ_section_title
;
 X-Ray Structure Investigation of
 2,2-Diphenyl-1-(phenylsulfonyl)cyclopropyllithium-Dimethoxyethane (2/3):
 A Sulfonyl "Carbanion" Having an \a-C Atom with a Tetrahedral Configuration
;
_journal_coden_ASTM              ACIEAY
_journal_issue                   6
_journal_name_full
;
 Angewandte Chemie, International Edition in English
;
_journal_page_first              846
_journal_page_last               847
_journal_paper_doi               10.1002/anie.198808461
_journal_volume                  27
_journal_year                    1988
_chemical_formula_sum            'C54 H64 Li2 O10 S2'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                86.94(2)
_cell_angle_beta                 88.69(2)
_cell_angle_gamma                85.89(2)
_cell_formula_units_Z            1
_cell_length_a                   10.147(3)
_cell_length_b                   10.693(2)
_cell_length_c                   11.919(3)
_cod_database_code               1100318
An X-ray structural analysis of a chiral α-alkoxy-ketone/SnCl~4~ chelate
Reetz, M. T.; Harms, K.; Reif, W.; Tetrahedron Letters 29 (1988) 5881–5884; doi:10.1016/s0040-4039(00)82215-7

data_1100319
_publ_section_title
;
 An X-ray structural analysis of a chiral \a-alkoxy-ketone/SnCl~4~ chelate
;
_journal_coden_ASTM              TELEAY
_journal_issue                   46
_journal_name_full               'Tetrahedron Letters'
_journal_page_first              5881
_journal_page_last               5884
_journal_paper_doi               10.1016/s0040-4039(00)82215-7
_journal_volume                  29
_journal_year                    1988
_chemical_formula_sum            'C12 H16 Cl4 O2 Sn'
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.695(4)
_cell_length_b                   12.819(3)
_cell_length_c                   13.696(6)
_cod_original_formula_sum        'C12 H16 Cl4 O2 Sn1'
_cod_database_code               1100319
An X-ray structural analysis of a chiral α-alkoxy-ketone/SnCl~4~ chelate
Reetz, M. T.; Harms, K.; Reif, W.; Tetrahedron Letters 29 (1988) 5881–5884; doi:10.1016/s0040-4039(00)82215-7

data_1100320
_publ_section_title
;
 An X-ray structural analysis of a chiral \a-alkoxy-ketone/SnCl~4~ chelate
;
_journal_coden_ASTM              TELEAY
_journal_issue                   46
_journal_name_full               'Tetrahedron Letters'
_journal_page_first              5881
_journal_page_last               5884
_journal_paper_doi               10.1016/s0040-4039(00)82215-7
_journal_volume                  29
_journal_year                    1988
_chemical_formula_sum            'C9 H10 Cl4 O2 Sn'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 99.43(3)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   14.876(2)
_cell_length_b                   13.720(5)
_cell_length_c                   14.101(6)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C9 H10 Cl4 O2 Sn1'
_cod_database_code               1100320
FunktionalisierteÜbergangsmetallalkyle: Synthese und Kristallstruktur von Ph~3~PAuCHPhSO~2~-t-Bu
Kneuper, Heinz-Josef; Harms, Klaus; Boche, Gernot; Journal of Organometallic Chemistry 364 (1989) 275–279; doi:10.1016/0022-328x(89)85350-1

data_1100321
_publ_section_title
;
 Funktionalisierte\"Ubergangsmetallalkyle: Synthese und Kristallstruktur
 von Ph~3~PAuCHPhSO~2~-t-Bu
;
_journal_coden_ASTM              JORCAI
_journal_issue                   1-2
_journal_name_full               'Journal of Organometallic Chemistry'
_journal_page_first              275
_journal_page_last               279
_journal_paper_doi               10.1016/0022-328x(89)85350-1
_journal_volume                  364
_journal_year                    1989
_chemical_formula_sum            'C29 H29 Au O2 P S'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 107.21(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.750(4)
_cell_length_b                   14.001(5)
_cell_length_c                   16.751(7)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C29 H29 Au1 O2 P1 S1'
_cod_database_code               1100321
Synthesis of 1,3-oxaphospholes via chromium mediated cyclization of carbenes, carbon monoxide, and phospha-alkynes
Dötz, Karl Heinz; Tiriliomis, Athanassios; Harms, Klaus; Journal of the Chemical Society, Chemical Communications  (1989) 788–790; doi:10.1039/c39890000788

data_1100322
_publ_section_title
;
 Synthesis of 1,3-oxaphospholes via chromium mediated cyclization
 of carbenes, carbon monoxide, and phospha-alkynes
;
_journal_coden_ASTM              JCCCAT
_journal_issue                   12
_journal_name_full
;
 Journal of the Chemical Society, Chemical Communications
;
_journal_page_first              788
_journal_page_last               790
_journal_paper_doi               10.1039/c39890000788
_journal_year                    1989
_chemical_formula_sum            'C19 H21 Cr O6 P'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 101.84(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.462(5)
_cell_length_b                   6.780(1)
_cell_length_c                   19.762(5)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C19 H21 Cr1 O6 P1'
_cod_database_code               1100322
Funktionalisierte Übergangsmetallalkyle, II. Synthese, Kristallstruktur und Reaktivität von (η~5~-C~5~H~5~)W(CO)~3~‒CH~2~‒S(O)‒C~6~H~5~, einem α-metallierten Sulfoxid
Kneuper, Heinz-Josef; Zimmermann, Christoph; Harms, Klaus; Boche, Gernot; Chemische Berichte 122 (1989) 1043–1047; doi:10.1002/cber.19891220605

data_1100323
_publ_section_title
;
 Funktionalisierte \"Ubergangsmetallalkyle, II. Synthese, Kristallstruktur
 und Reaktivit\"at von (\h~5~-C~5~H~5~)W(CO)~3~--CH~2~--S(O)--C~6~H~5~,
 einem \a-metallierten Sulfoxid
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   6
_journal_name_full               'Chemische Berichte'
_journal_page_first              1043
_journal_page_last               1047
_journal_paper_doi               10.1002/cber.19891220605
_journal_volume                  122
_journal_year                    1989
_chemical_formula_sum            'C15 H12 O4 S W'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 106.72
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.093(5)
_cell_length_b                   11.836(5)
_cell_length_c                   13.157(5)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C15 H12 O4 S1 W1'
_cod_database_code               1100323
Structure of dicyano-15-norcobyrinic acid heptamethyl ester
Battersby, A. R.; Grgurina, I.; Raithby, P. R.; Egert, E.; Harms, K.; Sheldrick, G. M.; Acta Crystallographica, Section C: Crystal Structure Communications 45 (1989) 1589–1593; doi:10.1107/S0108270189002969

data_1100324
_publ_section_title
;
 Structure of dicyano-15-norcobyrinic acid heptamethyl ester
;
_journal_coden_ASTM              ACSCEE
_journal_issue                   10
_journal_name_full
;
 Acta Crystallographica, Section C: Crystal Structure Communications
;
_journal_page_first              1589
_journal_page_last               1593
_journal_paper_doi               10.1107/S0108270189002969
_journal_volume                  45
_journal_year                    1989
_chemical_formula_sum            'C53 H71 Co N6 O14'
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.595(2)
_cell_length_b                   18.672(4)
_cell_length_c                   19.023(5)
_cod_original_formula_sum        'C53 H71 Co1 N6 O14'
_cod_database_code               1100324
Reaktionen von komplexliganden XXXVIII. Bisacylierung von aminocarben-komplexen zu 2-azaallenyl-komplexen
Dötz, Karl Heinz; Grotjahn, Douglas; Harms, Klaus; Journal of Organometallic Chemistry 375 (1989) C47–C50; doi:10.1016/0022-328x(89)85122-8

data_1100325
_publ_section_title
;
 Reaktionen von komplexliganden XXXVIII. Bisacylierung von
 aminocarben-komplexen zu 2-azaallenyl-komplexen
;
_journal_coden_ASTM              JORCAI
_journal_issue                   2
_journal_name_full               'Journal of Organometallic Chemistry'
_journal_page_first              C47
_journal_page_last               C50
_journal_paper_doi               10.1016/0022-328x(89)85122-8
_journal_volume                  375
_journal_year                    1989
_chemical_formula_sum            'C23 H25 Cr N O7'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.63(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.093(2)
_cell_length_b                   11.474(1)
_cell_length_c                   19.574
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C23 H25 Cr1 N1 O7'
_cod_database_code               1100325
η^1^-C~6~H~5~CH~2~Li·THF·TMEDA, Kristallstruktur eines Benzyllithium·THF·TMEDA-Komplexes mit einem pyramidalen Benzyl-C-Atom
Zarges, Wolfgang; Marsch, Michael; Harms, Klaus; Boche, Gernot; Chemische Berichte 122 (1989) 2303–2309; doi:10.1002/cber.19891221217

data_1100326
_publ_section_title
;
 \h^1^-C~6~H~5~CH~2~Li&#x00B7;THF&#x00B7;TMEDA, Kristallstruktur eines
 Benzyllithium&#x00B7;THF&#x00B7;TMEDA-Komplexes mit einem pyramidalen
 Benzyl-C-Atom
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   12
_journal_name_full               'Chemische Berichte'
_journal_page_first              2303
_journal_page_last               2309
_journal_paper_doi               10.1002/cber.19891221217
_journal_volume                  122
_journal_year                    1989
_chemical_formula_sum            'C17 H31 Li N2 O'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 103.30(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.682(2)
_cell_length_b                   15.387(1)
_cell_length_c                   13.934(3)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C17 H31 Li1 N2 O1'
_cod_database_code               1100326
Tetrahydrofuran-podands, stereoselective synthesis of trans-2,5-oligo-tetrahydrofurans
Koert, Ulrich; Stein, Matthias; Harms, Klaus; Tetrahedron Letters 34 (1993) 2299–2302; doi:10.1016/s0040-4039(00)77598-8

data_1100327
_publ_section_title
;
 Tetrahydrofuran-podands, stereoselective synthesis of
 trans-2,5-oligo-tetrahydrofurans
;
_journal_coden_ASTM              TELEAY
_journal_issue                   14
_journal_name_full               'Tetrahedron Letters'
_journal_page_first              2299
_journal_page_last               2302
_journal_paper_doi               10.1016/s0040-4039(00)77598-8
_journal_volume                  34
_journal_year                    1993
_chemical_formula_sum            'C25 H30 O4 Si'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                109.38(1)
_cell_angle_beta                 104.620(1)
_cell_angle_gamma                96.65(1)
_cell_formula_units_Z            2
_cell_length_a                   8.109(1)
_cell_length_b                   11.7878(1)
_cell_length_c                   13.696(1)
_cod_original_formula_sum        'C25 H30 O4 Si1'
_cod_database_code               1100327
[α-(Dimethylamino)benzyllithium‒Diethyl Ether]~2~, (S)-α-(Methylpivaloylamino)benzyllithium ‒ (‒)-Sparteine, and [3-Iodo-2-lithio-1-methylindole ‒ 2 Tetrahydrofuran]~2~: Crystal Structure Investigations of α-Lithiated Amines
Boche, Gernot; Marsch, Michael; Harbach, Jürgen; Harms, Klaus; Ledig, Burkhard; Schubert, Frank; Lohrenz, John C. W.; Ahlbrecht, Hubertus; Chemische Berichte 126 (1993) 1887–1894; doi:10.1002/cber.19931260820

data_1100328
_publ_section_title
;
 [\a-(Dimethylamino)benzyllithium--Diethyl Ether]~2~,
 (S)-\a-(Methylpivaloylamino)benzyllithium -- (--)-Sparteine, and
 [3-Iodo-2-lithio-1-methylindole -- 2 Tetrahydrofuran]~2~:
 Crystal Structure Investigations of \a-Lithiated Amines
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   8
_journal_name_full               'Chemische Berichte'
_journal_page_first              1887
_journal_page_last               1894
_journal_paper_doi               10.1002/cber.19931260820
_journal_volume                  126
_journal_year                    1993
_chemical_formula_sum            'C26 H44 Li2 N2 O2'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 106.47(1)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.320(1)
_cell_length_b                   12.832(1)
_cell_length_c                   11.842(1)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1100328
[α-(Dimethylamino)benzyllithium–Diethyl Ether]~2~, (S)-α-(Methylpivaloylamino)benzyllithium – (–)-Sparteine, and [3-Iodo-2-lithio-1-methylindole – 2 Tetrahydrofuran]~2~: Crystal Structure Investigations of α-Lithiated Amines
Boche, Gernot; Marsch, Michael; Harbach, Jürgen; Harms, Klaus; Ledig, Burkhard; Schubert, Frank; Lohrenz, John C. W.; Ahlbrecht, Hubertus; Chemische Berichte 126 (1993) 1887–1894; doi:10.1002/cber.19931260820

data_1100329
_publ_section_title
;
 [\a-(Dimethylamino)benzyllithium--Diethyl Ether]~2~,
 (S)-\a-(Methylpivaloylamino)benzyllithium -- (--)-Sparteine, and
 [3-Iodo-2-lithio-1-methylindole -- 2 Tetrahydrofuran]~2~:
 Crystal Structure Investigations of \a-Lithiated Amines
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   8
_journal_name_full               'Chemische Berichte'
_journal_page_first              1887
_journal_page_last               1894
_journal_paper_doi               10.1002/cber.19931260820
_journal_volume                  126
_journal_year                    1993
_chemical_formula_sum            'C28 H44 Li N3 O'
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.466(3)
_cell_length_b                   12.907(3)
_cell_length_c                   21.268(3)
_cod_original_formula_sum        'C28 H44 Li1 N3 O1'
_cod_database_code               1100329
[α-(Dimethylamino)benzyllithium‒Diethyl Ether]~2~, (S)-α-(Methylpivaloylamino)benzyllithium ‒ (‒)-Sparteine, and [3-Iodo-2-lithio-1-methylindole ‒ 2 Tetrahydrofuran]~2~: Crystal Structure Investigations of α-Lithiated Amines
Boche, Gernot; Marsch, Michael; Harbach, Jürgen; Harms, Klaus; Ledig, Burkhard; Schubert, Frank; Lohrenz, John C. W.; Ahlbrecht, Hubertus; Chemische Berichte 126 (1993) 1887–1894; doi:10.1002/cber.19931260820

data_1100330
_publ_section_title
;
 [\a-(Dimethylamino)benzyllithium--Diethyl Ether]~2~,
 (S)-\a-(Methylpivaloylamino)benzyllithium -- (--)-Sparteine, and
 [3-Iodo-2-lithio-1-methylindole -- 2 Tetrahydrofuran]~2~:
 Crystal Structure Investigations of \a-Lithiated Amines
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   8
_journal_name_full               'Chemische Berichte'
_journal_page_first              1887
_journal_page_last               1894
_journal_paper_doi               10.1002/cber.19931260820
_journal_volume                  126
_journal_year                    1993
_chemical_formula_sum            'C34 H46 I2 Li2 N2 O4'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                81.44(6)
_cell_angle_beta                 76.61(6)
_cell_angle_gamma                69.23(5)
_cell_formula_units_Z            2
_cell_length_a                   9.478(8)
_cell_length_b                   10.091(6)
_cell_length_c                   20.268(16)
_cod_database_code               1100330
Reactions of complex ligands. 45. (Acylamino)carbene complexes: synthesis, structure, and reactivity
Grotjahn, D. B.; Kroll, F. E. K.; Schaefer, T.; Harms, K.; Doetz, K. H.; Organometallics 11 (1992) 298–310; doi:10.1021/om00037a052

data_1100331
_publ_section_title
;
 Reactions of complex ligands. 45. (Acylamino)carbene complexes:
 synthesis, structure, and reactivity
;
_journal_coden_ASTM              ORGND7
_journal_issue                   1
_journal_name_full               Organometallics
_journal_page_first              298
_journal_page_last               310
_journal_paper_doi               10.1021/om00037a052
_journal_volume                  11
_journal_year                    1992
_chemical_formula_sum            'C17 H17 Cr N O6'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 111.66(1)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   23.355(5)
_cell_length_b                   11.187
_cell_length_c                   15.629
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C17 H17 Cr1 N1 O6'
_cod_database_code               1100331
Röntgenstrukturuntersuchung von α-(Trimethylsilyl)benzyllithium·Tetramethylendiamin [C~6~H~5~CH(SiMe~3~)Li·TMEDA] und α-(Phenylthio)-benzyllithium·3 Tetrahydrofuran [C~6~H~5~CH(SPh)Li·(THF)~3~] – zwei zentral-chirale Benzyllithium-Verbindungen
Zarges, Wolfgang; Marsch, Michael; Harms, Klaus; Frenking, Gernot; Boche, Gernot; Koch, Wolfram; Chemische Berichte 124 (1991) 543–549; doi:10.1002/cber.19911240321

data_1100332
_publ_section_title
;
 R\"ontgenstrukturuntersuchung von
 \a-(Trimethylsilyl)benzyllithium&#x00B7;Tetramethylendiamin
 [C~6~H~5~CH(SiMe~3~)Li&#x00B7;TMEDA] und
 \a-(Phenylthio)-benzyllithium&#x00B7;3 Tetrahydrofuran
 [C~6~H~5~CH(SPh)Li&#x00B7;(THF)~3~] -- zwei zentral-chirale
 Benzyllithium-Verbindungen
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   3
_journal_name_full               'Chemische Berichte'
_journal_page_first              543
_journal_page_last               549
_journal_paper_doi               10.1002/cber.19911240321
_journal_volume                  124
_journal_year                    1991
_chemical_formula_sum            'C16 H31 Li N2 Si'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 102.54(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.955(2)
_cell_length_b                   9.721(2)
_cell_length_c                   15.582(1)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C16 H31 Li1 N2 Si1'
_cod_database_code               1100332