Hydrogen bonding boosted the persistent room temperature phosphorescence of pure organic compounds for multiple applications
Zhang, Tingting; Gao, Heqi; Lv, Anqi; Wang, Ziyi; Gong, Yongyang; Ding, Dan; Ma, Huili; Zhang, Yongming; Yuan, Wang Zhang; Journal of Materials Chemistry C 7 (2019) 9095–; doi:10.1039/C9TC02879J

data_7237911
_publ_section_title
;
 Hydrogen bonding boosted the persistent room temperature phosphorescence
 of pure organic compounds for multiple applications
;
_journal_issue                   29
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              9095
_journal_paper_doi               10.1039/C9TC02879J
_journal_volume                  7
_journal_year                    2019
_chemical_formula_moiety         'C19 H13 N O2 [+ solvent]'
_chemical_formula_sum            'C19 H13 N O2'
_chemical_formula_weight         287.30
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-05-13 deposited with the CCDC.	2019-07-02 downloaded from the CCDC.
;
_cell_angle_alpha                88.065(17)
_cell_angle_beta                 75.24(2)
_cell_angle_gamma                68.408(16)
_cell_formula_units_Z            8
_cell_length_a                   11.660(2)
_cell_length_b                   15.654(4)
_cell_length_c                   18.325(4)
_cell_measurement_reflns_used    9080
_cell_measurement_temperature    299(2)
_cell_measurement_theta_max      68.19
_cell_measurement_theta_min      3.04
_cell_volume                     3000.7(12)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      299(2)
_diffrn_measured_fraction_theta_full 0.970
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0596
_diffrn_reflns_av_unetI/netI     0.0468
_diffrn_reflns_Laue_measured_fraction_full 0.970
_diffrn_reflns_Laue_measured_fraction_max 0.970
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            40507
_diffrn_reflns_point_group_measured_fraction_full 0.970
_diffrn_reflns_point_group_measured_fraction_max 0.970
_diffrn_reflns_theta_full        63.881
_diffrn_reflns_theta_max         63.881
_diffrn_reflns_theta_min         2.499
_exptl_absorpt_coefficient_mu    0.666
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.272
_exptl_crystal_description       block
_exptl_crystal_F_000             1200
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.180
_exptl_transmission_factor_max   0.7531
_exptl_transmission_factor_min   0.5397
_refine_diff_density_max         0.184
_refine_diff_density_min         -0.213
_refine_diff_density_rms         0.036
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.092
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     795
_refine_ls_number_reflns         9636
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.092
_refine_ls_R_factor_all          0.0798
_refine_ls_R_factor_gt           0.0608
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0469P)^2^+1.5253P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1359
_refine_ls_wR_factor_ref         0.1473
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7531
_reflns_number_total             9636
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9tc02879j3.cif
_cod_data_source_block           b
_cod_database_code               7237911
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.867
_shelx_estimated_absorpt_t_max   0.890
_shelx_res_checksum              35100
_shelx_fab_checksum              49260