Supramolecular architecture consisting of an enantiopure amine and an achiral carboxylic acid: application to the enantioseparation of racemic alcohols.
Kobayashi, Yuka; Kodama, Koichi; Saigo, Kazuhiko; Organic letters 6 (2004) 2941–2944; doi:10.1021/ol048948b

data_1507049
_publ_section_title
;
 Supramolecular architecture consisting of an enantiopure amine and an
 achiral carboxylic acid: application to the enantioseparation of racemic
 alcohols.
;
_journal_issue                   17
_journal_name_full               'Organic letters'
_journal_page_first              2941
_journal_page_last               2944
_journal_paper_doi               10.1021/ol048948b
_journal_volume                  6
_journal_year                    2004
_chemical_absolute_configuration rm
_chemical_formula_moiety         'C30 H33 N O4 '
_chemical_formula_sum            'C30 H33 N O4'
_chemical_formula_weight         471.59
_chemical_name_systematic
;
 (R)-1-(2'-Methylphenyl)ethanol (1S,2R)-2-amino-1,2-diphenylethanol benzoic acid
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      4
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90
_cell_angle_beta                 101.632(8)
_cell_angle_gamma                90
_cell_formula_units_Z            2
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_cell_length_c                   15.534(3)
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_cell_measurement_temperature    123.1
_cell_measurement_theta_max      13.7
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_cell_volume                     1307.0(4)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 1.00'
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_diffrn_measured_fraction_theta_max 0.9945
_diffrn_measurement_device_type  'Rigaku MERCURY'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[0.010Fo^2^ + 1.000\s^2^(Fo)]'
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_cod_original_formula_sum        'C30 H33 N O4 '
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