Synthesis of parent amido (NH2)-bridged dinuclear complexes of ruthenium and iridium by stepwise transfer hydrogenation of μ-azido complexes
Kimura, Takashi; Arita, Hiroko; Ishiwata, Koji; Kuwata, Shigeki; Ikariya, Takao; Dalton Transactions  (2009) 2912–2914; doi:10.1039/b902810m

data_7001016
_publ_section_title
;
 Synthesis of parent amido (NH2)-bridged dinuclear complexes of
 ruthenium and iridium by stepwise transfer hydrogenation of \m-azido
 complexes
;
_journal_issue                   16
_journal_name_full               'Dalton Transactions'
_journal_page_first              2912
_journal_page_last               2914
_journal_paper_doi               10.1039/b902810m
_journal_year                    2009
_chemical_formula_moiety         'C20 H31 Cl2 N Ru2 '
_chemical_formula_sum            'C20 H31 Cl2 N Ru2'
_chemical_formula_weight         558.52
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                70.900(14)
_cell_angle_beta                 84.302(17)
_cell_angle_gamma                70.759(16)
_cell_formula_units_Z            2
_cell_length_a                   9.245(4)
_cell_length_b                   10.429(4)
_cell_length_c                   12.464(6)
_cell_measurement_reflns_used    3858
_cell_measurement_temperature    193.1
_cell_measurement_theta_max      31.5
_cell_measurement_theta_min      3.2
_cell_volume                     1072.1(8)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.932
_diffrn_measured_fraction_theta_max 0.790
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.043
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            9582
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         31.40
_exptl_absorpt_coefficient_mu    1.662
_exptl_absorpt_correction_T_max  0.717
_exptl_absorpt_correction_T_min  0.564
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.730
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             560.00
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.08
_refine_diff_density_min         -0.97
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_hydrogen_treatment    mixed
_refine_ls_number_parameters     259
_refine_ls_number_reflns         4591
_refine_ls_R_factor_gt           0.0433
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0008Fo^2^ + 0.9000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1206
_reflns_number_gt                3306
_reflns_number_total             4592
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b902810m.txt
_cod_data_source_block           '__2a'
_cod_original_cell_volume        1072.0(8)
_cod_original_formula_sum        'C20 H31 Cl2 N Ru2 '
_cod_database_code               7001016