Mechanistic insights into hydroacylation with non-chelating aldehydes
Murphy, Stephen K.; Bruch, Achim; Dong, Vy M.; Chemical Science 6 (2015) 174–180; doi:10.1039/c4sc02026j

data_1518355
_publ_section_title
;
 Mechanistic insights into hydroacylation with non-chelating aldehydes
;
_journal_coden_ASTM              CSHCCN
_journal_issue                   1
_journal_name_full               'Chemical Science'
_journal_page_first              174
_journal_page_last               180
_journal_paper_doi               10.1039/c4sc02026j
_journal_volume                  6
_journal_year                    2015
_chemical_absolute_configuration unk
_chemical_formula_sum            'C32 H44 K N2 O13 Rh'
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; 
 Refined as an inversion twin. 
;
_refine_ls_abs_structure_Flack   0.51(3)
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'w=1/[\s^2^(Fo^2^)+(0.0365P)^2^+4.1212P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
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The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not_measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 1518355.cif.
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_cod_database_code               1518355
_shelx_estimated_absorpt_t_min   0.824
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