Stereoselective Preparation, Structures, and Reactivities of Phosphine-Bridged Mixed-Metal Trinuclear and Pentanuclear Complexes with Tris[2-(diphenylphosphino)ethyl]phosphine
Aizawa, Sen-ichi; Saito, Kenji; Kawamoto, Tatsuya; Matsumoto, Emi; Inorganic Chemistry 45 (2006) 4859–4866; doi:10.1021/ic060277l

data_4332357
_publ_section_title
;
 Stereoselective Preparation, Structures, and Reactivities of
 Phosphine-Bridged Mixed-Metal Trinuclear and Pentanuclear Complexes with
 Tris[2-(diphenylphosphino)ethyl]phosphine
;
_journal_issue                   12
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4859
_journal_page_last               4866
_journal_paper_doi               10.1021/ic060277l
_journal_volume                  45
_journal_year                    2006
_chemical_formula_moiety         'C85 H87 B2 Cl7 F8 O P8 Pd2 Pt '
_chemical_formula_sum            'C85 H87 B2 Cl7 F8 O P8 Pd2 Pt'
_chemical_formula_weight         2202.08
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   28.276(4)
_cell_length_b                   23.610(4)
_cell_length_c                   13.933(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.1
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.8
_cell_volume                     9302(3)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 3.5.1'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SHELXS97
_diffrn_measured_fraction_theta_full 0.9959
_diffrn_measured_fraction_theta_max 0.9959
_diffrn_measurement_device_type  'Rigaku AFC5R'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            23234
_diffrn_reflns_theta_full        27.53
_diffrn_reflns_theta_max         27.53
_diffrn_standards_decay_%        -17.23
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.275
_exptl_absorpt_correction_T_max  0.711
_exptl_absorpt_correction_T_min  0.492
_exptl_absorpt_correction_type   psi-scans
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.572
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             4384.00
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.50
_exptl_crystal_size_min          0.15
_refine_diff_density_max         3.37
_refine_diff_density_min         -2.63
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   2.953
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     529
_refine_ls_number_reflns         4824
_refine_ls_R_factor_gt           0.0750
_refine_ls_shift/su_max          0.9970
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w = 1/\s^2^(Fo^2^)'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.1170
_reflns_number_gt                4817
_reflns_number_total             10684
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic060277lsup1.cif
_cod_data_source_block           '_7a(BF4)2'
_cod_original_cell_volume        9301(2)
_cod_original_sg_symbol_Hall     'P 21/B 21/C 21/A '
_cod_original_sg_symbol_H-M      'P 21/b 21/c 21/a'
_cod_original_formula_sum        'C85 H87 B2 Cl7 F8 O P8 Pd2 Pt '
_cod_database_code               4332357