Fabrication of Schottky barrier diodes utilizing carboxylate bridged trinuclear mixed valence cobalt(iii/ii/iii) complexes of tetradentate N2O2 donor reduced Schiff base ligands
Bhunia, Sudip; Das, Pubali; Banerjee, Snehasis; Gomila, Rosa M.; Drew, Michael G. B.; Frontera, Antonio; Ray, Partha Pratim; Chattopadhyay, Shouvik; New Journal of Chemistry 47 (2023) 14202–14216; doi:10.1039/D3NJ01829F

data_7062589
_publ_section_title
;
 Fabrication of Schottky barrier diodes utilizing carboxylate bridged
 trinuclear mixed valence cobalt(iii/ii/iii) complexes of tetradentate
 N2O2 donor reduced Schiff base ligands
;
_journal_issue                   30
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              14202
_journal_page_last               14216
_journal_paper_doi               10.1039/D3NJ01829F
_journal_volume                  47
_journal_year                    2023
_chemical_formula_sum            'C58.04 H69.59 Cl1.59 Co3 N4 O16.78 S1.59'
_chemical_formula_weight         1375.85
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2023-06-15 deposited with the CCDC.	2023-06-20 downloaded from the CCDC.
;
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_cell_measurement_theta_min      1.985
_cell_volume                     1602.3(5)
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'Ortep-3 for Windows (Farrugia, 1999) and CAMERON (Watkin et al., 1993)'
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_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      273(2)
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_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker D8 QUEST area detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_l_min       -17
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0773P)^2^+3.1452P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1527
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7062588--7062590.cif.'
_cod_database_code               7062589
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