Synthesis, structure, and alkynylation reactivity of alkynyl-silicate, -germanate, and -stannate.
Iwabuchi, Shuta; Morofuji, Tatsuya; Kano, Naokazu; Dalton transactions (Cambridge, England : 2003) 53 (2024) 10829–10833; doi:10.1039/d4dt01688b

data_7716396
_publ_section_title
;
 Synthesis, structure, and alkynylation reactivity of alkynyl-silicate,
 -germanate, and -stannate.
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10829
_journal_page_last               10833
_journal_paper_doi               10.1039/d4dt01688b
_journal_volume                  53
_journal_year                    2024
_chemical_formula_sum            'C34 H33 F12 Ge N O2'
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;
2024-03-07 deposited with the CCDC.	2024-06-12 downloaded from the CCDC.
;
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.99a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0216P)^2^+2.5397P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0759
_refine_ls_wR_factor_ref         0.0819
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7591
_reflns_number_total             9898
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4dt01688b2.cif
_cod_data_source_block           20211004iwabuchi2_auto
_cod_depositor_comments
'Adding full bibliography for 7716394--7716396.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7716396
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