Gold(III) Adducts with Chiral Pyridinyl-Oxazolines. Synthesis, Reactivity of the Coordinated Ligands, and Structural Characterizations
Cinellu, Maria A.; Maiore, Laura; Minghetti, Giovanni; Cocco, Fabio; Stoccoro, Sergio; Zucca, Antonio; Manassero, Mario; Manassero, Carlo; Organometallics 28 (2009) 7015–; doi:10.1021/om900841b

data_4070474
_publ_section_title
;
 Gold(III) Adducts with Chiral Pyridinyl-Oxazolines. Synthesis, Reactivity
 of the Coordinated Ligands, and Structural Characterizations
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              7015
_journal_paper_doi               10.1021/om900841b
_journal_volume                  28
_journal_year                    2009
_chemical_formula_sum            'C11 H14 Au Cl N2 O2'
_chemical_formula_weight         438.67
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_audit_creation_date             09-06-01
_audit_creation_method           'from The Personal SDP version 2.1.1'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   4.5955(5)
_cell_length_b                   12.0430(10)
_cell_length_c                   22.3850(20)
_cell_measurement_reflns_used    5226
_cell_measurement_temperature    150
_cell_measurement_theta_max      28
_cell_measurement_theta_min      3
_cell_volume                     1238.9(2)
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_computing_data_collection       'APEX II (Bruker)'
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_computing_structure_refinement
' Full-matrix least-squares  (The Personal SDP, 1991)'
_computing_structure_solution
' SHELXS-86  (Sheldrick, 1986) as implemented in The Personal SDP'
_diffrn_ambient_temperature      150
_diffrn_measurement_device       'APEX II (Bruker)'
_diffrn_measurement_method       omega
_diffrn_radiation_detector       'APEX II CCD area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           Mo-K\a
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_diffrn_reflns_limit_h_max       6
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_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_reduction_process SAINT
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_diffrn_reflns_theta_min         3.00
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_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   '  SADABS'
_exptl_crystal_colour            yellow
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_exptl_crystal_description       needle
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_exptl_crystal_size_mid          0.030
_exptl_crystal_size_min          0.020
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_refine_diff_density_min         -3.080
_refine_ls_goodness_of_fit_all   0.960
_refine_ls_goodness_of_fit_obs   0.960
_refine_ls_hydrogen_treatment    noref
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_refine_ls_structure_factor_coef Fsqd
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_diffrn_reflns_number_total      14569
_diffrn_reflns_number_independent 3194
_r_int                           0.0909
_total_number_of_frames          2460
_time_per_frame_seconds          30
_frame_width_degrees             0.30
_detector_sample_distance_cm     6.00
_conventional_r1_(i>2\s(i))      0.054
_reflections_with_(i>2\s(i)      2465
_refine_diff_density_esd         1.750