Photochemical Reaction of Diruthenium Tetrahydride-Bridged Complexes with Carbon Dioxide: Insertion of CO2into a Ru‒H Bond versus C═O Double-Bond Cleavage
Shimogawa, Ryuichi; Takao, Toshiro; Konishi, Gen-ichi; Suzuki, Hiroharu; Organometallics 33 (2014) 5066–; doi:10.1021/om500615u

data_4084327
_publ_section_title
;
 Photochemical Reaction of Diruthenium Tetrahydride-Bridged Complexes with
 Carbon Dioxide: Insertion of CO2into a Ru--H Bond versus C&#x2550;O
 Double-Bond Cleavage
;
_journal_issue                   19
_journal_name_full               Organometallics
_journal_page_first              5066
_journal_paper_doi               10.1021/om500615u
_journal_volume                  33
_journal_year                    2014
_chemical_formula_sum            'C21 H34 O2 Ru2'
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; 
 ? 
;
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_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0591P)^2^+3.5257P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Empirical'
changed to 'empirical' according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4084327--4084328.cif.

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        2082.1(3)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4084327