A novel one-dimensional metal‒organic framework with a μ-cyanido-argentate group: <i>catena</i>-poly[[(5,5'-dimethyl-2,2'-bipyridyl-κ^2^<i>N</i>,<i>N</i>')silver(I)]-μ-cyanido-κ^2^<i>N</i>:<i>C</i>]
Piromchom, Jureepan; Othong, Jintana; Boonmak, Jaursup; Mutikainen, Ilpo; Youngme, Sujittra; Acta Crystallographica Section C 71 (2015) 1–0; doi:10.1107/S2053229615020288

data_2020291
_publ_section_title
;
 A novel one-dimensional metal--organic framework with a
 \m-cyanido-argentate group:
 <i>catena</i>-poly[[(5,5'-dimethyl-2,2'-bipyridyl-\k^2^<i>N</i>,<i>N</i>')silver(I)]-\m-cyanido-\k^2^<i>N</i>:<i>C</i>]
;
_journal_coeditor_code           FM3029
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1
_journal_page_last               0
_journal_paper_doi               10.1107/S2053229615020288
_journal_volume                  71
_journal_year                    2015
_chemical_formula_iupac          '[Ag (C N) (C12 H12 N2)]'
_chemical_formula_moiety         'C13 H12 Ag N3'
_chemical_formula_sum            'C13 H12 Ag N3'
_chemical_formula_weight         318.13
_chemical_name_systematic
<i>catena</i>-Poly[[(5,5'-dimethyl-2,2'-bipyridyl-\k^2^<i>N</i>,<i>N</i>')silver(I)]-\m-cyanido-\k^2^<i>N</i>:<i>C</i>]
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 112.832(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.464(2)
_cell_length_b                   8.6630(10)
_cell_length_c                   9.912(2)
_cell_measurement_reflns_used    8541
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.277
_cell_measurement_theta_min      2.752
_cell_volume                     1223.8(3)
_computing_cell_refinement
;
SAINT (Bruker, 2003)
;
_computing_data_collection
;
SMART (Bruker, 2000)
;
_computing_data_reduction
;
SAINT (Bruker, 2003)
;
_computing_molecular_graphics
;
SHELXTL (Sheldrick, 2008)
;
_computing_publication_material
;
SHELXTL (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0166
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            8245
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.277
_diffrn_reflns_theta_min         2.752
_exptl_absorpt_coefficient_mu    1.626
_exptl_absorpt_correction_T_max  0.865
_exptl_absorpt_correction_T_min  0.748
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Sheldrick, 2000)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.727
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             632
_exptl_crystal_size_max          0.253
_exptl_crystal_size_mid          0.154
_exptl_crystal_size_min          0.089
_refine_diff_density_max         0.891
_refine_diff_density_min         -0.702
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.139
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     82
_refine_ls_number_reflns         1525
_refine_ls_number_restraints     7
_refine_ls_restrained_S_all      1.136
_refine_ls_R_factor_all          0.0318
_refine_ls_R_factor_gt           0.0285
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0262P)^2^+2.5229P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0688
_refine_ls_wR_factor_ref         0.0708
_reflns_number_gt                1395
_reflns_number_total             1525
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            fm3029sup1.cif
_cod_data_source_block           I
_cod_database_code               2020291
_shelx_estimated_absorpt_t_min   0.684
_shelx_estimated_absorpt_t_max   0.869
_shelx_hkl_checksum              14795
_shelx_res_checksum              89387
_cod_database_fobs_code 2020291