Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and germylene-decorated phosphanes and their reactions with Group 10 metal complexes.
Cabeza, Javier A.; García-Álvarez, Pablo; Laglera-Gándara, Carlos J; Pérez-Carreño, Enrique; Dalton transactions (Cambridge, England : 2003) 49 (2020) 8331–8339; doi:10.1039/d0dt01727b

data_7704537
_publ_section_title
;
 Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and
 germylene-decorated phosphanes and their reactions with Group 10 metal
 complexes.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8331
_journal_page_last               8339
_journal_paper_doi               10.1039/d0dt01727b
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C28 H46 Cl2 N3 P Pd Si, C4 H8 O'
_chemical_formula_sum            'C32 H54 Cl2 N3 O P Pd Si'
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_audit_update_record
;
2020-05-06 deposited with the CCDC.	2020-06-01 downloaded from the CCDC.
;
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'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
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'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
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'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
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'MERCURY (Cambridge Crystallographic Data Centre: Cambridge, UK, 2018)'
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_diffrn_ambient_temperature      150(2)
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;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0505P)^2^+9.1132P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7704536--7704539.cif.'
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_cod_database_code               7704537
_shelxl_version_number           2014-3
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