Strongly luminescent 5d/4f heterometal-organic macrocycles with open metal sites: post-assembly modification and sensing.
Zhu, Qiang-Yu; Zhou, Li-Peng; Sun, Qing-Fu; Dalton transactions (Cambridge, England : 2003) 48 (2019) 4479–4483; doi:10.1039/c9dt00710e

data_7049236
_publ_section_title
;
 Strongly luminescent 5d/4f heterometal-organic macrocycles with open
 metal sites: post-assembly modification and sensing.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4479
_journal_page_last               4483
_journal_paper_doi               10.1039/c9dt00710e
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C114 H142 Eu2 F18 N18 O30 Pt2 S6'
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2019-01-23 deposited with the CCDC.    2019-03-04 downloaded from the CCDC.
;
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_cell_volume                     4047.9(5)
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_diffrn_ambient_temperature      100(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_max         25.196
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_exptl_absorpt_coefficient_mu    2.649
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.425
_exptl_crystal_description       block
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0610
_refine_ls_R_factor_gt           0.0398
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0416P)^2^+14.2505P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0939
_refine_ls_wR_factor_ref         0.1046
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_reflns_number_gt                11254
_reflns_number_total             14503
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7049235--7049237.cif.'
_cod_database_code               7049236
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