Reactions of a persistent phosphinyl radical/diphosphine with heteroallenes.
Giffin, Nick A.; Hendsbee, Arthur D.; Masuda, Jason D.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 12636–12638; doi:10.1039/c6dt02790c

data_7040032
_publ_section_title
;
 Reactions of a persistent phosphinyl radical/diphosphine with
 heteroallenes.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12636
_journal_page_last               12638
_journal_paper_doi               10.1039/c6dt02790c
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C53 H76 N4 P2 S2'
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_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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_audit_update_record
;
2016-07-14 deposited with the CCDC.
2016-07-15 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Siemens/Bruker APEXII'
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_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       19
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_exptl_absorpt_process_details   '(sadabs, Bruker, 2008)'
_exptl_crystal_colour            colorless
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_exptl_crystal_description       plate
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0387P)^2^+1.5378P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                4642
_reflns_number_total             9113
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt02790c2.cif
_cod_data_source_block           NG111_0m
_cod_depositor_comments
'Adding full bibliography for 7040032--7040034.cif.'
_cod_database_code               7040032
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_shelx_estimated_absorpt_t_min   0.975
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