Synthesis and crystal structure of three silver(I) complexes with (S )-(+)-5-oxo-2-tetrahydrofurancarboxylic acid (S-Hothf ) and its isomeric forms (R-Hothf and R,S-Hothf ) showing wide spectra of effective antibacterial and antifungal activities. Chiral helical polymers in the solid state formed by self-assembly of the dimeric [Ag(othf )]2 cores
Nomiya, Kenji; Takahashi, Satoshi; Noguchi, Ryusuke; Journal of the Chemical Society, Dalton Transactions  (2000) 1343–; doi:10.1039/a910251p

data_7009315
_publ_section_title
;
 Synthesis and crystal structure of three silver(I) complexes with
 (S&#x200A;)-(+)-5-oxo-2-tetrahydrofurancarboxylic acid
 (S-Hothf&#x200A;) and its isomeric forms (R-Hothf and
 R,S-Hothf&#x200A;) showing wide spectra of effective antibacterial and
 antifungal activities. Chiral helical polymers in the solid state
 formed by self-assembly of the dimeric [Ag(othf&#x200A;)]2 cores
;
_journal_issue                   8
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1343
_journal_paper_doi               10.1039/a910251p
_journal_year                    2000
_chemical_formula_moiety         'C10 H10 Ag2 O8 '
_chemical_formula_sum            'C10 H10 Ag2 O8'
_chemical_formula_weight         473.92
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      4
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90
_cell_angle_beta                 109.37(1)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.560(2)
_cell_length_b                   5.417(2)
_cell_length_c                   12.858(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      12.3
_cell_measurement_theta_min      10.0
_cell_volume                     628.2(3)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    'DIRDIF92 (PATTY)'
_diffrn_ambient_temperature      296.2
_diffrn_measurement_device       'Rigaku AFC5S'
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      0.10882
_diffrn_orient_matrix_UB_12      0.02617
_diffrn_orient_matrix_UB_13      0.01676
_diffrn_orient_matrix_UB_21      0.01378
_diffrn_orient_matrix_UB_22      0.00835
_diffrn_orient_matrix_UB_23      0.08048
_diffrn_orient_matrix_UB_31      0.01623
_diffrn_orient_matrix_UB_32      -0.18257
_diffrn_orient_matrix_UB_33      0.00608
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.03461
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            1682
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         3.23
_diffrn_standards_decay_%        -0.71
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.144
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_correction_T_min  0.863
_exptl_absorpt_correction_type
;
\y scans (North,Phillips & Matthews, 1968)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.506
_exptl_crystal_density_meas      ?
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             456.00
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.71
_refine_diff_density_min         -0.56
_refine_ls_abs_structure_Flack   -0.0013
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.256
_refine_ls_goodness_of_fit_ref   1.260
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     180
_refine_ls_number_reflns         973
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0357
_refine_ls_R_factor_gt           0.0360
_refine_ls_shift/su_max          0.0000
_refine_ls_shift/su_mean         0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00000|Fo|^2^]'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0260
_refine_ls_wR_factor_ref         0.0260
_reflns_number_gt                973
_reflns_number_total             1592
_reflns_threshold_expression     I>2.00\s(I)
_cod_data_source_file            a910251p.txt
_cod_data_source_block           2
_cod_original_cell_volume        628.1(3)
_cod_original_sg_symbol_H-M      'P 21       '
_cod_original_formula_sum        'C10 H10 Ag2 O8 '
_cod_database_code               7009315