Bis[1,2-bis(diphenylphosphino)ethane-κ^2^<i>P</i>,<i>P</i>']silver(I) bis(chlorodifluoroacetato-κ<i>O</i>)(cyclohexyl)diphenylstannate(IV)
Teo, Yin Yin; Lo, Kong Mun; Ng, Seik Weng; Acta Crystallographica Section E 63 (2007) m1365–m1367; doi:10.1107/S1600536807016662

data_2213201
_publ_section_title
;
 Bis[1,2-bis(diphenylphosphino)ethane-\k^2^<i>P</i>,<i>P</i>']silver(I)
 bis(chlorodifluoroacetato-\k<i>O</i>)(cyclohexyl)diphenylstannate(IV)
;
_journal_coeditor_code           CI2314
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1365
_journal_page_last               m1367
_journal_paper_doi               10.1107/S1600536807016662
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac
'[Ag (C26 H24 P2)2] [Sn (C6 H5)2 (C6 H11) (C2 Cl F2 O2)2]'
_chemical_formula_moiety         'C52 H48 Ag1 P4 +, C22 H21 Cl2 F4 O4 Sn1 -'
_chemical_formula_sum            'C74 H69 Ag Cl2 F4 O4 P4 Sn'
_chemical_formula_weight         1519.63
_chemical_name_systematic
;
Bis[1,2-bis(diphenylphosphino)ethane-\k^2^P,P']silver(I)
bis(chlorodifluoroacetato-\kO)(cyclohexyl)diphenylstannate(IV)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                97.5820(10)
_cell_angle_beta                 94.6410(10)
_cell_angle_gamma                105.5500(10)
_cell_formula_units_Z            2
_cell_length_a                   11.7453(2)
_cell_length_b                   14.7704(2)
_cell_length_c                   21.1302(3)
_cell_measurement_reflns_used    6891
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      31.8
_cell_measurement_theta_min      2.4
_cell_volume                     3474.62(9)
_computing_cell_refinement       'SAINT (Bruker, 2004)'
_computing_data_collection       'APEX2 (Bruker, 2004)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'X-SEED (Barbour, 2001)'
_computing_publication_material  'publCIF (Westrip, 2007)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.99
_diffrn_measured_fraction_theta_max 0.99
_diffrn_measurement_device_type  'Bruker APEXII area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'medium-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.028
_diffrn_reflns_av_sigmaI/netI    0.028
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            54063
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         1.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.869
_exptl_absorpt_correction_T_max  0.874
_exptl_absorpt_correction_T_min  0.735
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.452
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1544
_exptl_crystal_size_max          0.49
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.16
_refine_diff_density_max         2.61
_refine_diff_density_min         -1.35
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.30
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1252
_refine_ls_number_reflns         15831
_refine_ls_number_restraints     1021
_refine_ls_restrained_S_all      1.35
_refine_ls_R_factor_all          0.066
_refine_ls_R_factor_gt           0.049
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0845P)^2^+3.9457P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.142
_refine_ls_wR_factor_ref         0.168
_reflns_number_gt                12918
_reflns_number_total             15831
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            ci2314.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2213201
_cod_database_fobs_code          2213201