Novel dinuclear gold(i) complexes containing bis(diphenylphosphano)alkanes and (biphenyl-2-yl)(di-tert-butyl)phosphane: synthesis, structural characterization and anticancer activity
Sulaiman, Adam A. A.; Ahmad, Saeed; Mujahid Hashimi, Saeed; Alqosaibi, Amany I.; Peedikakkal, Abdul Malik Puthan; Alhoshani, Ali; Alsaleh, Nasser B.; Isab, Anvarhusein A.; New Journal of Chemistry 46 (2022) 16821–16831; doi:10.1039/D2NJ01680J

data_7061681
_publ_section_title
;
 Novel dinuclear gold(i) complexes containing
 bis(diphenylphosphano)alkanes and
 (biphenyl-2-yl)(di-tert-butyl)phosphane: synthesis, structural
 characterization and anticancer activity
;
_journal_issue                   35
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              16821
_journal_page_last               16831
_journal_paper_doi               10.1039/D2NJ01680J
_journal_volume                  46
_journal_year                    2022
_chemical_formula_sum            'C66 H78 Au2 F12 P6'
_chemical_formula_weight         1679.03
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2022-03-28 deposited with the CCDC.	2022-08-01 downloaded from the CCDC.
;
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_cell_angle_gamma                75.288(2)
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_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      51.113
_cell_measurement_theta_min      4.352
_cell_volume                     1748.68(14)
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker AXS D8 Quest diffractometer'
_diffrn_measurement_method       'Omega and Phi scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0432
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       14
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_diffrn_reflns_limit_k_max       17
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_diffrn_reflns_limit_l_min       -18
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_diffrn_reflns_point_group_measured_fraction_max 0.997
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_diffrn_reflns_theta_min         2.061
_diffrn_source                   'Microfocus Sealed tube'
_exptl_absorpt_coefficient_mu    4.397
_exptl_crystal_colour            Colorless
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_exptl_crystal_description       Block
_exptl_crystal_F_000             830
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.35
_refine_diff_density_max         1.681
_refine_diff_density_min         -1.254
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_refine_ls_extinction_coef       0.0000(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2016/6 (Sheldrick 2016)'
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     395
_refine_ls_number_reflns         8718
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.105
_refine_ls_R_factor_all          0.0596
_refine_ls_R_factor_gt           0.0396
_refine_ls_shift/su_max          8.641
_refine_ls_shift/su_mean         0.022
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0615P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0973
_refine_ls_wR_factor_ref         0.1045
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6790
_reflns_number_total             8718
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d2nj01680j2.cif
_cod_data_source_block           AMAD172_0m
_cod_depositor_comments
'Adding full bibliography for 7061681--7061683.cif.'
_cod_database_code               7061681
_shelx_shelxl_version_number     2016/6
_shelx_res_checksum              85789