Mixing and matching <i>N</i>,<i>N</i>- and <i>N</i>,<i>O</i>-chelates in anionic Mg(I) compounds: synthesis and reactivity with RNCNR and CO.
O'Reilly, Andrea; Haynes, Matthew D.; Turner, Zoë R; McMullin, Claire L.; Harder, Sjoerd; O'Hare, Dermot; Fulton, J. Robin; Coles, Martyn P.; Chemical communications (Cambridge, England) 60 (2024) 7204–7207; doi:10.1039/d4cc02594f

data_7133227
_publ_section_title
;
 Mixing and matching <i>N</i>,<i>N</i>- and <i>N</i>,<i>O</i>-chelates in
 anionic Mg(I) compounds: synthesis and reactivity with
 RN&#xe001;C&#xe001;NR and CO.
;
_journal_issue                   56
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              7204
_journal_page_last               7207
_journal_paper_doi               10.1039/d4cc02594f
_journal_volume                  60
_journal_year                    2024
_chemical_formula_moiety         'C42  H68  N2  O3  Mg1  Si2  K1'
_chemical_formula_sum            'C42 H68 K Mg N2 O3 Si2'
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;
2024-06-14 deposited with the CCDC.	2024-06-16 downloaded from the CCDC.
;
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'CrysAlisPro convention (1999,Acta A55,543-557)'
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
        CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
        Numerical absorption correction based on gaussian integration over
                        a multifaceted crystal model
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.13
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1668
_exptl_crystal_size_max          0.439
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_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0478
_refine_ls_R_factor_gt           0.0448
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0590P)^2^+3.1284P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 7133226--7133229.cif.'
_cod_original_cell_volume        4519.27(9)
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