[μ-<i>N</i>,<i>N</i>'-Bis(2-aminoethyl)ethane-1,2-diamine-κ^4^<i>N</i>^1^,<i>N</i>^1'^:<i>N</i>^2^,<i>N</i>^2'^]bis{[<i>N</i>,<i>N</i>'-bis(2-aminoethyl)ethane-1,2-diamine-κ^4^<i>N</i>,<i>N</i>',<i>N</i>'',<i>N</i>''']cadmium} tetrakis(perchlorate)
Goudarziafshar, Hamid; Abbasityula, Yunes; Eigner, Václav; Dušek, Michal; Acta Crystallographica Section E 68 (2012) m1153–m1154; doi:10.1107/S1600536812033880

data_2236591
_publ_section_title
;
 [\m-<i>N</i>,<i>N</i>'-Bis(2-aminoethyl)ethane-1,2-diamine-\k^4^<i>N</i>^1^,<i>N</i>^1'^:<i>N</i>^2^,<i>N</i>^2'^]bis{[<i>N</i>,<i>N</i>'-bis(2-aminoethyl)ethane-1,2-diamine-\k^4^<i>N</i>,<i>N</i>',<i>N</i>'',<i>N</i>''']cadmium}
 tetrakis(perchlorate)
;
_journal_coeditor_code           RU2040
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1153
_journal_page_last               m1154
_journal_paper_doi               10.1107/S1600536812033880
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Cd2 (C6 H18 N4)3] (Cl O4)4'
_chemical_formula_moiety         'C18 H54 Cd2 N12 4+, 4(Cl O4 -)'
_chemical_formula_sum            'C18 H54 Cd2 Cl4 N12 O16'
_chemical_formula_weight         1061.3
_chemical_name_systematic
;
[\m-<i>N</i>,<i>N</i>'-Bis(2-aminoethyl)ethane-1,2-diamine-
\k^4^<i>N</i>^1^,<i>N</i>^1'^:<i>N</i>^2^,<i>N</i>^2'^]bis{[<i>N</i>,<i>N</i>'-
bis(2-aminoethyl)ethane-1,2-diamine-
\k^4^<i>N</i>,<i>N</i>',<i>N</i>'',<i>N</i>''']cadmium} tetrakis(perchlorate)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 95.4420(17)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   8.8056(2)
_cell_length_b                   15.0259(3)
_cell_length_c                   14.7516(3)
_cell_measurement_reflns_used    17686
_cell_measurement_temperature    120.00(14)
_cell_measurement_theta_max      29.34
_cell_measurement_theta_min      2.92
_cell_volume                     1943.02(7)
_computing_cell_refinement
;
CrysAlis PRO (Agilent, 2012)
;
_computing_data_collection
;
CrysAlis PRO (Agilent, 2012)
;
_computing_data_reduction
;
CrysAlis PRO (Agilent, 2012)
;
_computing_molecular_graphics
'ORTEP-3 for Windows (Farrugia, 1997) and Mercury (Macrae <i>et al.</i>, 2008)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'JANA2006 (Petricek <i>et al.</i>, 2006)'
_computing_structure_solution    'SUPERFLIP (Palatinus & Chapuis, 2007)'
_diffrn_ambient_temperature      120
_diffrn_detector_area_resol_mean 10.3784
_diffrn_measured_fraction_theta_full 0.98
_diffrn_measured_fraction_theta_max 0.92
_diffrn_measurement_device       'four-cycle diffractometer'
_diffrn_measurement_device_type  'Agilent Xcalibur Atlas Gemini ultra'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.0215
_diffrn_reflns_av_sigmaI/netI    0.0128
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            31295
_diffrn_reflns_theta_full        28.24
_diffrn_reflns_theta_max         29.41
_diffrn_reflns_theta_min         2.92
_exptl_absorpt_coefficient_mu    1.448
_exptl_absorpt_correction_T_max  0.738
_exptl_absorpt_correction_T_min  0.509
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
(CrysAlis PRO; Agilent, 2012)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.8135
_exptl_crystal_description       prism
_exptl_crystal_F_000             1076
_exptl_crystal_size_max          0.701
_exptl_crystal_size_mid          0.51
_exptl_crystal_size_min          0.328
_refine_diff_density_max         1.13
_refine_diff_density_min         -0.92
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   2.02
_refine_ls_hydrogen_treatment    mixed
_refine_ls_number_constraints    82
_refine_ls_number_parameters     269
_refine_ls_number_reflns         4952
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0350
_refine_ls_R_factor_gt           0.0301
_refine_ls_shift/su_max          0.0452
_refine_ls_shift/su_mean         0.0022
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     w=1/(\s^2^(I)+0.0016I^2^)
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_gt          0.1027
_refine_ls_wR_factor_ref         0.1057
_reflns_number_gt                4373
_reflns_number_total             4952
_reflns_threshold_expression     I>3\s(I)
_cod_data_source_file            ru2040.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2236591
_cod_database_fobs_code          2236591