A novel structural rearrangement reaction of dialkylated derivatives of [Pt(2)(μ-S)(2)(PPh(3))(4)] involving Pt-C bond formation.
Ujam, Oguejiofo T.; Devoy, Sarah M.; Henderson, William; Nicholson, Brian K.; Hor, T. S. Andy; Dalton transactions (Cambridge, England : 2003) 41 (2012) 12773–12780; doi:10.1039/c2dt31637d

data_7020469
_publ_section_title
;
 A novel structural rearrangement reaction of dialkylated derivatives of
 [Pt(2)(\m-S)(2)(PPh(3))(4)] involving Pt-C bond formation.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12773
_journal_page_last               12780
_journal_paper_doi               10.1039/c2dt31637d
_journal_volume                  41
_journal_year                    2012
_chemical_formula_moiety
'C75 H64 O P4 Pt2 S2, 2(C24 H20 B), 0.6C H2 Cl2'
_chemical_formula_sum            'C124 H104 B2 Cl2 O P4 Pt2 S2'
_chemical_formula_weight         2280.77
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                79.154(1)
_cell_angle_beta                 88.571(1)
_cell_angle_gamma                76.680(1)
_cell_formula_units_Z            2
_cell_length_a                   14.1462(3)
_cell_length_b                   14.8139(3)
_cell_length_c                   26.7666(4)
_cell_measurement_reflns_used    8192
_cell_measurement_temperature    90(2)
_cell_measurement_theta_max      25
_cell_measurement_theta_min      2
_cell_volume                     5359.82(18)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      90(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.2199
_diffrn_reflns_av_sigmaI/netI    0.3308
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            44917
_diffrn_reflns_theta_full        25.24
_diffrn_reflns_theta_max         25.24
_diffrn_reflns_theta_min         0.77
_exptl_absorpt_coefficient_mu    2.806
_exptl_absorpt_correction_T_max  0.64
_exptl_absorpt_correction_T_min  0.33
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.413
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2296
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         4.995
_refine_diff_density_min         -3.239
_refine_diff_density_rms         0.317
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.984
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     590
_refine_ls_number_reflns         18935
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.984
_refine_ls_R_factor_all          0.2402
_refine_ls_R_factor_gt           0.1169
_refine_ls_shift/su_max          0.016
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1364P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2697
_refine_ls_wR_factor_ref         0.3296
_reflns_number_gt                7977
_reflns_number_total             18935
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt31637d.txt
_cod_data_source_block           whco
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7020469