Crystal structures of six complexes of phosphane chalcogenides <i>R</i> <sup>1</sup> <i>R</i> <sup>2</sup> <i>R</i> <sup>3</sup>P<i>E</i> (<i>R</i> = <i>tert</i>-butyl or isopropyl, <i>E</i> = S or Se) with the metal halides <i>MX</i> <sub>2</sub> (<i>M</i> = Pd or Pt, <i>X</i> = Cl or Br), two halochalcogenyl-phospho-nium derivatives ( <sup><i>t</i></sup> Bu<sub>2</sub> <sup>i</sup>PrP<i>E</i>Br)<sub>2</sub>[Pd<sub>2</sub>Br<sub>6</sub>] and one hydrolysis product.
Upmann, Daniel; Jones, Peter G.; Acta crystallographica. Section E, Crystallographic communications 81 (2025) 183–194; doi:10.1107/S2056989025000805

data_2023376
_publ_section_title
;
 Crystal structures of six complexes of phosphane chalcogenides <i>R</i>
 <sup>1</sup> <i>R</i> <sup>2</sup> <i>R</i> <sup>3</sup>P<i>E</i>
 (<i>R</i> = <i>tert</i>-butyl or isopropyl, <i>E</i> = S or Se) with the
 metal halides <i>MX</i> <sub>2</sub> (<i>M</i> = Pd or Pt, <i>X</i> = Cl
 or Br), two halochalcogenyl-phospho-nium derivatives (
 <sup><i>t</i></sup> Bu<sub>2</sub>
 <sup>i</sup>PrP<i>E</i>Br)<sub>2</sub>[Pd<sub>2</sub>Br<sub>6</sub>] and
 one hydrolysis product.
;
_journal_coeditor_code           YZ2063
_journal_issue                   'Pt 3'
_journal_name_full
'Acta crystallographica. Section E, Crystallographic communications'
_journal_page_first              183
_journal_page_last               194
_journal_paper_doi               10.1107/S2056989025000805
_journal_volume                  81
_journal_year                    2025
_chemical_formula_iupac          '[Pd Cl2 (C11 H25 P1 S1)2]'
_chemical_formula_moiety         'C22 H50 Cl2 P2 Pt S2'
_chemical_formula_sum            'C22 H50 Cl2 P2 Pt S2'
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_chemical_name_systematic
;
Dichlorido(di-<i>tert</i>-butylisopropylphosphine
sulfide-\k<i>S</i>)palladium(II)
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
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_cell_length_b                   14.4191(3)
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_cell_measurement_temperature    100(2)
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_computing_cell_refinement
;
CrysAlisPro, Version 1.171.35.15 (Rigaku OD, 2012)
;
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;
CrysAlisPro, Version 1.171.35.15 (Rigaku OD, 2012)
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CrysAlisPro, Version 1.171.35.15 (Rigaku OD, 2012)
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Bruker XP, Version 5.1 (Bruker, 1998)
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publCIF (Westrip, 2010)
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;
<i>SHELXL2019/3</i> (Sheldrick, 2015)
;
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;
SHELXS-97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.950
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_diffrn_measurement_method       '\w scans'
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;
(CrysAlisPro; Rigaku OD, 2012)
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0154P)^2^+5.0893P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 2023372--2023380.cif.'
_cod_original_cell_volume        2911.53(12)
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