Reactions of potassium bis(phosphinimino)methanide with group 11 compounds.
Panda, Tarun K.; Roesky, Peter W.; Larsen, Patrick; Zhang, Shuang; Wickleder, Claudia; Inorganic chemistry 45 (2006) 7503–7508; doi:10.1021/ic060932p

data_4350459
_publ_contact_author
;
      Prof. Dr. Peter Roesky
      Freie Universit\"at Berlin
      Fabeckstr. 34-36
      14195 Berlin
      Bundesrepublik Deutschland
;
_publ_section_title
;
 Reactions of potassium bis(phosphinimino)methanide with group 11
 compounds.
;
_journal_issue                   18
_journal_name_full               'Inorganic chemistry'
_journal_page_first              7503
_journal_page_last               7508
_journal_paper_doi               10.1021/ic060932p
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C67 H68 Au2 N2 P4 Si2'
_chemical_formula_weight         1475.23
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.587(3)
_cell_angle_beta                 91.235(3)
_cell_angle_gamma                115.643(3)
_cell_formula_units_Z            2
_cell_length_a                   12.6423(5)
_cell_length_b                   14.1578(5)
_cell_length_c                   19.4929(7)
_cell_measurement_temperature    293(2)
_cell_volume                     3134.6(2)
_computing_molecular_graphics    'Diamond 2.1e'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_measurement_method       'image plate (34 cm diameter)'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0577
_diffrn_reflns_av_sigmaI/netI    0.0343
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            62112
_diffrn_reflns_theta_full        29.28
_diffrn_reflns_theta_max         29.28
_diffrn_reflns_theta_min         3.29
_exptl_absorpt_coefficient_mu    4.853
_exptl_absorpt_correction_T_max  0.2058
_exptl_absorpt_correction_T_min  0.1166
_exptl_absorpt_correction_type   integration
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.562
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1460
_exptl_crystal_size_max          0.800
_exptl_crystal_size_mid          0.517
_exptl_crystal_size_min          0.350
_refine_diff_density_max         2.200
_refine_diff_density_min         -1.462
_refine_diff_density_rms         0.101
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.131
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     698
_refine_ls_number_reflns         16801
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.131
_refine_ls_R_factor_all          0.0328
_refine_ls_R_factor_gt           0.0294
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0245P)^2^+4.5427P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0694
_refine_ls_wR_factor_ref         0.0707
_reflns_number_gt                15616
_reflns_number_total             16801
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic060932psi20060529_045239.cif
_cod_data_source_block           2
_cod_original_cell_volume        3134.58(19)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4350459