Heterocyclic substituted methanides as promising alternatives to the ubiquitous nacnac ligand.
Dauer, David-R; Stalke, Dietmar; Dalton transactions (Cambridge, England : 2003) 43 (2014) 14432–14439; doi:10.1039/c4dt01008f

data_7031034
_publ_section_title
;
 Heterocyclic substituted methanides as promising alternatives to the
 ubiquitous nacnac ligand.
;
_journal_issue                   38
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14432
_journal_page_last               14439
_journal_paper_doi               10.1039/c4dt01008f
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C15.67 H12.67 Al0.83 Cl0.83 N1.67 O1.67'
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_chemical_name_systematic
;
 ?
;
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_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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_refine_ls_R_factor_all          0.0464
_refine_ls_R_factor_gt           0.0414
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0262P)^2^+10.6027P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           ddauer_5
_cod_depositor_comments
'Adding full bibliography for 7031030--7031038.cif.'
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_shelx_estimated_absorpt_t_max   0.976
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