Palladium-Assisted Regioselective Olefin Insertion into and -Hydrogen Elimination of Hydrogen-Molybdenum and -Tungsten Bonds. Synthesis and Reactions of Heterodinuclear Hydrido Complexes of Palladium and Platinum with Molybdenum and Tungsten
Ayako Kuramoto; Kouhei Nakanishi; Tatsuya Kawabata; Nobuyuki Komine; Masafumi Hirano; Sanshiro Komiya; Organometallics 25 (2006) 311–314; doi:10.1021/om0506872

data_4063311
_publ_section_title
;
 Palladium-Assisted Regioselective Olefin Insertion into and -Hydrogen
 Elimination of Hydrogen-Molybdenum and -Tungsten Bonds. Synthesis and
 Reactions of Heterodinuclear Hydrido Complexes of Palladium and
 Platinum with Molybdenum and Tungsten
;
_journal_issue                   2
_journal_name_full               Organometallics
_journal_page_first              311
_journal_page_last               314
_journal_paper_doi               10.1021/om0506872
_journal_volume                  25
_journal_year                    2006
_chemical_formula_sum            'C40 H36 Mo O3 P2 Pt'
_chemical_formula_weight         917.70
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 105.33(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.403(6)
_cell_length_b                   10.846(5)
_cell_length_c                   22.757(5)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    200.2
_cell_measurement_theta_max      14.9
_cell_measurement_theta_min      14.9
_cell_volume                     3666(2)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    'DIRDIF94 (PATTY)'
_diffrn_measured_fraction_theta_full 0.9945
_diffrn_measured_fraction_theta_max 0.9945
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.038
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            17421
_diffrn_reflns_theta_full        27.38
_diffrn_reflns_theta_max         27.38
_diffrn_standards_decay_%        7.12
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.261
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.819
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.662
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_refine_diff_density_max         5.58
_refine_diff_density_min         -2.65
_refine_ls_extinction_coef       0.020(2)
_refine_ls_extinction_method     'Zachariasen(1967) type 2 Gaussian isotropic'
_refine_ls_goodness_of_fit_ref   1.383
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     357
_refine_ls_number_reflns         4435
_refine_ls_R_factor_gt           0.0994
_refine_ls_shift/su_max          0.0017
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.01000|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1465
_reflns_number_gt                4435
_reflns_number_total             8277
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_original_formula_sum        'C40 H36 Mo O3 P2 Pt '
_cod_database_code               4063311