Oligomerization of phosphaalkynes mediated by bulky N-heterocyclic carbenes: avenues to novel phosphorus frameworks.
Liu, Liu Leo; Zhou, Jiliang; Kim, Youngsuk; Cao, Levy L.; Stephan, Douglas W.; Dalton transactions (Cambridge, England : 2003) 48 (2019) 14242–14245; doi:10.1039/c9dt03185e

data_7700871
_publ_section_title
;
 Oligomerization of phosphaalkynes mediated by bulky N-heterocyclic
 carbenes: avenues to novel phosphorus frameworks.
;
_journal_issue                   38
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14242
_journal_page_last               14245
_journal_paper_doi               10.1039/c9dt03185e
_journal_volume                  48
_journal_year                    2019
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_audit_update_record
;
2019-05-30 deposited with the CCDC.    2019-08-21 downloaded from the CCDC.
;
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_exptl_absorpt_process_details
;
multi-scan from symmetry-related measurements
Sortav (Blessing 1995)
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0697P)^2^+2.4144P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1253
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_reflns_number_gt                9092
_reflns_number_total             12770
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt03185e2.cif
_cod_data_source_block           3
_cod_depositor_comments
'Adding full bibliography for 7700871--7700873.cif.'
_cod_original_formula_sum        'C38 H49 Cl1.50 N2 P1.50'
_cod_database_code               7700871
_shelx_shelxl_version_number     2014/7
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