n-Type Organic Field-Effect Transistors with High Electron Mobilities Based on Thiazole−Thiazolothiazole Conjugated Molecules
Mamada, Masashi; Nishida, Jun-ichi; Kumaki, Daisuke; Tokito, Shizuo; Yamashita, Yoshiro; Chemistry of Materials 19 (2007) 5404–; doi:10.1021/cm071505s

data_4001417
_publ_section_title
;
 n-Type Organic Field-Effect Transistors with High Electron Mobilities
 Based on Thiazole&#x2212;Thiazolothiazole Conjugated Molecules
;
_journal_issue                   22
_journal_name_full               'Chemistry of Materials'
_journal_page_first              5404
_journal_paper_doi               10.1021/cm071505s
_journal_volume                  19
_journal_year                    2007
_chemical_formula_sum            'C24 H10 F6 N4 S4'
_chemical_formula_weight         596.60
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                93.22(6)
_cell_angle_beta                 101.18(5)
_cell_angle_gamma                103.56(5)
_cell_formula_units_Z            3
_cell_length_a                   8.43(1)
_cell_length_b                   13.05(2)
_cell_length_c                   16.35(3)
_cell_measurement_reflns_used    13804
_cell_measurement_temperature    93.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     1706(5)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9715
_diffrn_measured_fraction_theta_max 0.9715
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.032
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            16351
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_exptl_absorpt_coefficient_mu    0.492
_exptl_absorpt_correction_T_max  0.995
_exptl_absorpt_correction_T_min  0.617
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.742
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_size_max          0.700
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.010
_refine_diff_density_max         0.63
_refine_diff_density_min         -0.55
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.989
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     514
_refine_ls_number_reflns         7136
_refine_ls_R_factor_gt           0.0422
_refine_ls_shift/su_max          0.0391
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.02000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0840
_reflns_number_gt                5212
_reflns_number_total             7563
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            cm071505s-file003.cif
_cod_data_source_block           2_
_cod_original_cell_volume        1705(15)
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C24 H10 F6 N4 S4 '
_cod_database_code               4001417