The first acetimino complexes of Rh(III). 4-imino-2-methylpentan-2-amino-Rh(III) complexes through metal-assisted intramolecular aldol-type condensation of two acetimino ligands.
Vicente, José; Chicote, María-Teresa; Guerrero, Rita; Vicente-Hernández, Inmaculada; Alvarez-Falcón, Miguel M; Inorganic chemistry 45 (2006) 181–188; doi:10.1021/ic051521w

data_4340293
_publ_section_title
;
 The first acetimino complexes of Rh(III).
 4-imino-2-methylpentan-2-amino-Rh(III) complexes through metal-assisted
 intramolecular aldol-type condensation of two acetimino ligands.
;
_journal_issue                   1
_journal_name_full               'Inorganic chemistry'
_journal_page_first              181
_journal_page_last               188
_journal_paper_doi               10.1021/ic051521w
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C16 H29 Cl2 N2 Rh'
_chemical_formula_weight         423.22
_chemical_name_systematic
;

 ?

;
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_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.644(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
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_cell_length_b                   12.0370(4)
_cell_length_c                   22.7027(8)
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_cell_measurement_temperature    133(2)
_cell_measurement_theta_max      30.49
_cell_measurement_theta_min      2.27
_cell_volume                     3686.1(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Siemens XP'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      133(2)
_diffrn_detector_area_resol_mean 8.192
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       '\w- & \f-scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0458
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_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            43299
_diffrn_reflns_theta_full        30.00
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_exptl_absorpt_correction_T_max  0.8883
_exptl_absorpt_correction_T_min  0.7774
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.525
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rhomb
_exptl_crystal_F_000             1744
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.11
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_refine_diff_density_min         -0.366
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         5620
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_refine_ls_R_factor_all          0.0397
_refine_ls_R_factor_gt           0.0262
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0272P)^2^+4.2156P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0607
_reflns_number_gt                4569
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_reflns_threshold_expression     >2sigma(I)
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_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4340293