Tuning of magnetic properties of the 2D CN-bridged Ni<sup>II</sup>-Nb<sup>IV</sup> framework by incorporation of guest cations of alkali and alkaline earth metals.
Heczko, Michał; Reczyński, Mateusz; Näther, Christian; Nowicka, Beata; Dalton transactions (Cambridge, England : 2003) 50 (2021) 7537–7544; doi:10.1039/d1dt00367d

data_7707124
_publ_section_title
;
 Tuning of magnetic properties of the 2D CN-bridged
 Ni<sup>II</sup>-Nb<sup>IV</sup> framework by incorporation of guest
 cations of alkali and alkaline earth metals.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7537
_journal_page_last               7544
_journal_paper_doi               10.1039/d1dt00367d
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C46 H120 Mg N28 Nb2 Ni3 O24'
_chemical_formula_weight         1835.95
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2021-03-26 deposited with the CCDC.	2021-04-15 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_computing_cell_refinement       'X-AREA (STOE, 2008)'
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_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device_type  'IPDS-2 from STOE'
_diffrn_measurement_method       'Omega scans'
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_exptl_absorpt_coefficient_mu    1.022
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
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_exptl_crystal_description       block
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0546P)^2^+0.6405P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0949
_refine_ls_wR_factor_ref         0.1018
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6029
_reflns_number_total             7927
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1dt00367d2.cif
_cod_data_source_block           3mg
_cod_depositor_comments
'Adding full bibliography for 7707121--7707126.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7707124
_shelx_shelxl_version_number     2016/6
_shelx_res_checksum              41844
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