Crystal structure of a one-dimensional helical-type silver(I) coordination polymer: <i>catena</i>-poly[[silver(I)-μ-<i>N</i>-(pyridin-4-ylmethyl)pyridine-3-amine-κ^2^<i>N</i>:<i>N</i>'] nitrate dimethyl sulfoxide disolvate]
Moon, Bokhee; Jeon, Youngeun; Moon, Suk-Hee; Park, Ki-Min; Acta Crystallographica Section E 70 (2014) 507–509; doi:10.1107/S1600536814024817

data_2240199
_publ_section_title
;
 Crystal structure of a one-dimensional helical-type silver(I)
 coordination polymer:
 <i>catena</i>-poly[[silver(I)-\m-<i>N</i>-(pyridin-4-ylmethyl)pyridine-3-amine-\k^2^<i>N</i>:<i>N</i>']
 nitrate dimethyl sulfoxide disolvate]
;
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              507
_journal_page_last               509
_journal_paper_doi               10.1107/S1600536814024817
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac          '[Ag (C11 H11 N3)] N O3, 2C2 H6 O S'
_chemical_formula_moiety         'C11 H11 Ag N3, N O3, 2(C2 H6 O S)'
_chemical_formula_sum            'C15 H23 Ag N4 O5 S2'
_chemical_formula_weight         511.36
_chemical_name_systematic
'<i>catena</i>-Poly[[silver(I)-\m-<i>N</i>-(pyridin-4-ylmethyl)pyridine-3-amine-\k^2^<i>N</i>:<i>N</i>'] nitrate dimethyl sulfoxide disolvate]'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXTL
_cell_angle_alpha                90.00
_cell_angle_beta                 91.9500(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.7046(6)
_cell_length_b                   16.7871(8)
_cell_length_c                   10.4922(5)
_cell_measurement_reflns_used    7555
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      2.29
_cell_volume                     2060.38(17)
_computing_cell_refinement
;
<i>SAINT-Plus</i> (Bruker, 2000)
;
_computing_data_collection
;
<i>SMART</i> (Bruker, 2000)
;
_computing_data_reduction
;
<i>SAINT-Plus</i> (Bruker, 2000)
;
_computing_molecular_graphics
;
<i>DIAMOND</i> (Brandenburg, 2005)
;
_computing_publication_material
;
<i>SHELXTL</i> (Sheldrick, 2008)
;
_computing_structure_refinement
;
<i>SHELXL97</i> (Sheldrick, 2008)
;
_computing_structure_solution
;
<i>SHELXS97</i> (Sheldrick, 2008)
;
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0627
_diffrn_reflns_av_sigmaI/netI    0.0461
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            11476
_diffrn_reflns_theta_full        25.99
_diffrn_reflns_theta_max         25.99
_diffrn_reflns_theta_min         1.74
_exptl_absorpt_coefficient_mu    1.214
_exptl_absorpt_correction_T_max  0.8680
_exptl_absorpt_correction_T_min  0.7047
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(<i>SADABS</i>; Bruker, 2000)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.649
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1040
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.576
_refine_diff_density_min         -0.628
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.079
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     255
_refine_ls_number_reflns         4039
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.079
_refine_ls_R_factor_all          0.0352
_refine_ls_R_factor_gt           0.0276
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0348P)^2^+1.0473P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0708
_refine_ls_wR_factor_ref         0.0776
_reflns_number_gt                3485
_reflns_number_total             4039
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hg5419sup1.cf
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2240199
_cod_database_fobs_code          2240199