An efficient class of bis-NHC salts: applications in Pd-catalyzed reactions under mild reaction conditions
Chiu, Chien-Cheng; Chiu, Hui-Tzu; Lee, Dong-Sheng; Lu, Ta-Jung; RSC Advances 8 (2018) 26407–; doi:10.1039/C8RA04094J

data_7231230
_publ_section_title
;
 An efficient class of bis-NHC salts: applications in Pd-catalyzed
 reactions under mild reaction conditions
;
_journal_issue                   46
_journal_name_full               'RSC Advances'
_journal_page_first              26407
_journal_paper_doi               10.1039/C8RA04094J
_journal_volume                  8
_journal_year                    2018
_chemical_formula_moiety         'C66 H64 Ag2 N8 O4, 2(F6 P)'
_chemical_formula_sum            'C66 H64 Ag2 F12 N8 O4 P2'
_chemical_formula_weight         1538.93
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_audit_block_doi                 10.5517/ccdc.csd.cc1nl4x9
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-05-11 deposited with the CCDC.
2018-06-26 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 95.567(3)
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_cell_formula_units_Z            4
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_cell_measurement_temperature    150(2)
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_computing_cell_refinement
; 
CrysAlis RED, Oxford Diffraction Ltd., 
Version 1.171.32.29 (release 10-06-2008 CrysAlis171 .NET) 
(compiled Jun 10 2008,16:49:55) 
;
_computing_data_collection
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CrysAlis CCD, Oxford Diffraction Ltd., 
Version 1.171.32.29 (release 10-06-2008 CrysAlis171 .NET) 
(compiled Jun 10 2008,16:49:55) 
;
_computing_data_reduction
; 
CrysAlis RED, Oxford Diffraction Ltd., 
Version 1.171.32.29 (release 10-06-2008 CrysAlis171 .NET) 
(compiled Jun 10 2008,16:49:55) 
;
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.861
_diffrn_measurement_device_type  'CCD detector'
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_diffrn_reflns_limit_k_min       -20
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_reflns_theta_full        25.242
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_density_diffrn    1.403
_exptl_crystal_description       parallelepiped
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0834P)^2^+27.7882P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1780
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_reflns_number_gt                11775
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_reflns_threshold_expression     'I > 2\s(I)'
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