Unsupported monomeric stibine oxides (R<sub>3</sub>SbO) remain undiscovered.
Wenger, John S.; Johnstone, Timothy C.; Chemical communications (Cambridge, England) 57 (2021) 3484–3487; doi:10.1039/d1cc00619c

data_7128001
_publ_section_title
;
 Unsupported monomeric stibine oxides (R<sub>3</sub>SbO) remain
 undiscovered.
;
_journal_issue                   28
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3484
_journal_page_last               3487
_journal_paper_doi               10.1039/d1cc00619c
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C27 H34 O Sb, C6 H5 O3 S'
_chemical_formula_sum            'C33 H39 O4 S Sb'
_chemical_formula_weight         653.45
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-02-02 deposited with the CCDC.	2021-03-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_measurement_temperature    100(2)
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_cell_volume                     5966.81(8)
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_computing_data_collection       'CrysAlisPro 1.171.41.58a (Rigaku OD, 2020)'
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_diffrn_ambient_temperature      100(2)
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_diffrn_measurement_device_type  'PhotonJet (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
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'CrysAlisPro 1.171.41.58a (Rigaku Oxford Diffraction, 2020)'
_exptl_crystal_colour            colorless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0306P)^2^+2.0693P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                13467
_reflns_number_total             15556
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cc00619c2.cif
_cod_data_source_block           1
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'Adding full bibliography for 7128001--7128003.cif.'
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