Modulating the magnetization dynamics in Ln-Cu-Rad hetero-tri-spin complexes through <i>cis</i>/<i>trans</i> coordination of nitronyl nitroxide radicals around the metal center.
Lu, Jiao; Jing, Pei; Jin, Chaoyi; Xie, Junfang; Li, Licun; Dalton transactions (Cambridge, England : 2003) 50 (2021) 3280–3288; doi:10.1039/d1dt00090j

data_7706573
_publ_section_title
;
 Modulating the magnetization dynamics in Ln-Cu-Rad hetero-tri-spin
 complexes through <i>cis</i>/<i>trans</i> coordination of nitronyl
 nitroxide radicals around the metal center.
;
_journal_issue                   9
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3280
_journal_page_last               3288
_journal_paper_doi               10.1039/d1dt00090j
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C69 H45 Cu2 Dy F42 N8 O18'
_chemical_formula_sum            'C69 H45 Cu2 Dy F42 N8 O18'
_chemical_formula_weight         2361.71
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
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Olex2 1.2
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2021-01-05 deposited with the CCDC.	2021-02-03 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker P4'
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'w=1/[\s^2^(Fo^2^)+(0.1526P)^2^+40.0000P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7706571--7706575.cif.
;
_cod_database_code               7706573
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(F28) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(F25) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(F33) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(F31) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(F32) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(F1) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(F7) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
3.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C20(H20), C28(H28), C6(H6), C5(H5), C8(H8), C36(H36), C22(H22),
 C23(H23), C9(H9), C25(H25), C11(H11), C46(H46), C61(H61), C10(H10), C66(H66),
 C41(H41), C27(H27), C56(H56), C51(H51), C26(H26)
3.b Idealised Me refined as rotating group:
 C15(H15A,H15B,H15C), C34(H34A,H34B,H34C), C32(H32A,H32B,H32C), C33(H33A,H33B,
 H33C), C31(H31A,H31B,H31C), C17(H17A,H17B,H17C), C14(H14A,H14B,H14C), C16(H16A,
 H16B,H16C)
;
_shelx_res_checksum              59646
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_olex2_submission_special_instructions 'No special instructions were received'