<i>catena</i>-Poly[[[μ-1,3-bis(diphenylphosphanyl)propane-κ^2^<i>P</i>:<i>P</i>'][<i>O</i>-ethyl (4-methoxyphenyl)phosphonodithioato-κ^2^<i>S</i>,<i>S</i>']silver(I)] chloroform monosolvate]
Sun, Di; Huang, Rong-Bin; Acta Crystallographica Section C 67 (2011) m315–m317; doi:10.1107/S010827011103438X

data_2018225
_publ_section_title
;
 <i>catena</i>-Poly[[[\m-1,3-bis(diphenylphosphanyl)propane-\k^2^<i>P</i>:<i>P</i>'][<i>O</i>-ethyl
 (4-methoxyphenyl)phosphonodithioato-\k^2^<i>S</i>,<i>S</i>']silver(I)]
 chloroform monosolvate]
;
_journal_coeditor_code           SF3156
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m315
_journal_page_last               m317
_journal_paper_doi               10.1107/S010827011103438X
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac
'[Ag (C27 H26 P2) (C9 H12 O2 P S2)] , C H Cl3'
_chemical_formula_moiety         'C36 H38 Ag O2 P3 S2, C H Cl3'
_chemical_formula_sum            'C37 H39 Ag Cl3 O2 P3 S2'
_chemical_formula_weight         886.93
_chemical_name_systematic
;
<i>catena</i>-Poly[[[\m-1,3-bis(diphenylphosphanyl)propane-
\k^2^<i>P</i>:<i>P</i>'][<i>O</i>-ethyl (4-methoxyphenyl)phosphonodithioato-
\k^2^<i>S</i>,<i>S</i>']silver(I)] chloroform monosolvate]
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.95(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   7.1493(14)
_cell_length_b                   16.137(3)
_cell_length_c                   17.010(3)
_cell_measurement_reflns_used    28055
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      55.03
_cell_measurement_theta_min      6.07
_cell_volume                     1959.8(6)
_computing_cell_refinement       'CrysAlis RED (Oxford Diffraction, 2008)'
_computing_data_collection       'CrysAlis CCD (Oxford Diffraction, 2008)'
_computing_data_reduction        'CrysAlis RED (Oxford Diffraction, 2008)'
_computing_molecular_graphics
'DIAMOND (Brandenburg, 2008) and SHELXTL (Sheldrick, 2008)'
_computing_publication_material
;
SHELXL97 (Sheldrick, 2008) and publCIF (Westrip, 2010)
;
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 16.1903
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Oxford Gemini S Ultra'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0530
_diffrn_reflns_av_sigmaI/netI    0.0508
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            26211
_diffrn_reflns_theta_full        25.99
_diffrn_reflns_theta_max         25.99
_diffrn_reflns_theta_min         3.04
_exptl_absorpt_coefficient_mu    0.980
_exptl_absorpt_correction_T_max  0.9257
_exptl_absorpt_correction_T_min  0.9084
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrysAlis RED; Oxford Diffraction, 2008)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.503
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             904
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.640
_refine_diff_density_min         -0.779
_refine_ls_abs_structure_details 'Flack (1983), with how many Friedel pairs?'
_refine_ls_abs_structure_Flack   -0.01(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         7381
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.006
_refine_ls_R_factor_all          0.0420
_refine_ls_R_factor_gt           0.0380
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0103P)^2^+2.4402P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0718
_refine_ls_wR_factor_ref         0.0740
_reflns_number_gt                6876
_reflns_number_total             7381
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            sf3156.cif
_cod_data_source_block           I
_cod_original_cell_volume        1959.8(7)
_cod_original_sg_symbol_H-M      P21
_cod_database_code               2018225
_cod_database_fobs_code          2018225