Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex.
Nicolay, Amélie; Ziegler, Micah S.; Small, David W.; Grünbauer, Rebecca; Scheer, Manfred; Tilley, T. Don; Chemical science 11 (2020) 1607–1616; doi:10.1039/c9sc05835d

data_1556677
_publ_section_title
;
 Isomerism and dynamic behavior of bridging phosphaalkynes bound to a
 dicopper complex.
;
_journal_issue                   6
_journal_name_full               'Chemical science'
_journal_page_first              1607
_journal_page_last               1616
_journal_paper_doi               10.1039/c9sc05835d
_journal_volume                  11
_journal_year                    2020
_chemical_formula_sum            'C45 H35 Cu2 F14 N8 O8 P S4'
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_chemical_name_common            '[(DPFN)Cu2PCAd](NTf2)2'
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_space_group_name_Hall           '-P 2yn'
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;
2019-11-17 deposited with the CCDC.	2019-12-16 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker D8 with PHOTON 100 detector'
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;
Advanced Light Source, station 12.2.1
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1114P)^2^+25.4197P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2019
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_reflns_number_gt                9919
_reflns_number_total             11763
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9sc05835d3.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

data name '__publ_section_acknowledgements' was replaced with
'_publ_section_acknowledgements'.

Automatic conversion script
Id: cif_correct_tags 7550 2019-12-06 10:49:48Z antanas 

 Adding full bibliography for 1556673--1556677.cif.

 Adding full bibliography for 1556673--1556677.cif.
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1556677
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.900
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_shelx_res_checksum              43689
_shelx_fab_checksum              64477