Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene.
Ledet, Anthony D.; Hudnall, Todd W.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 9820–9826; doi:10.1039/c6dt00300a

data_7038214
_publ_section_title
;
 Reduction of a diamidocarbene-supported borenium cation: isolation of a
 neutral boryl-substituted radical and a carbene-stabilized aminoborylene.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9820
_journal_page_last               9826
_journal_paper_doi               10.1039/c6dt00300a
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         {(C24H28N2O2)-B-Cl-N(C3H7)2-SO3CF3-CH2Cl2
_chemical_formula_sum            'C32 H44 B Cl3 F3 N3 O5 S'
_chemical_formula_weight         756.92
_chemical_name_common            DAC-BCl-N(iPr)2-OTf
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_audit_update_record
;
2016-01-20 deposited with the CCDC.
2016-02-01 downloaded from the CCDC.
;
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_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
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_diffrn_measurement_device_type  'CCD area detector'
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_diffrn_radiation_type           MoK\a
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0541P)^2^+3.3632P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             6614
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt00300a2.cif
_cod_data_source_block           3OTf
_cod_depositor_comments
'Adding full bibliography for 7038214--7038215.cif.'
_cod_database_code               7038214
_shelx_shelxl_version_number     2014/7
_exptl_absorpt_special_details   none
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