Self-assembly of a cobalt(II)-based metal‒organic framework as an effective water-splitting heterogeneous catalyst for light-driven hydrogen production
Dou, Yong; Yang, Lu; Qin, Lan; Dong, Yunhui; Zhou, Zhen; Zhang, Daopeng; Wang, Suna; Acta Crystallographica Section C 76 (2020) –; doi:10.1107/S2053229620007044

data_2022131
_publ_section_title
;
 Self-assembly of a cobalt(II)-based metal--organic framework as an
 effective water-splitting heterogeneous catalyst for light-driven
 hydrogen production
;
_journal_coeditor_code           YP3203
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229620007044
_journal_volume                  76
_journal_year                    2020
_chemical_formula_iupac          '[Co (C30 H16 O8) (C10 H8 N2)]'
_chemical_formula_moiety         'C40 H24 Co2 N2 O8'
_chemical_formula_sum            'C40 H24 Co2 N2 O8'
_chemical_formula_weight         778.48
_chemical_name_systematic
Poly[(\m-4,4'-bipyridyl)[\m~8~-4,4',4'',4'''-(ethene-1,1,2,2-tetrayl)tetrabenzoato]cobalt(II)]
_space_group_crystal_system      orthorhombic
_space_group_IT_number           51
_space_group_name_Hall           '-P 2a 2a'
_space_group_name_H-M_alt        'P m m a'
_atom_sites_solution_hydrogens   geom
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;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
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_computing_cell_refinement
;
SAINT (Bruker, 2008)
;
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;
SMART (Bruker, 2008)
;
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SAINT (Bruker, 2008)
;
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OLEX2 (Dolomanov <i>et al.</i>,  2009)
;
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OLEX2 (Dolomanov <i>et al.</i>,  2009)
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SHELXL2018 (Sheldrick, 2015b) and
OLEX2 (Dolomanov <i>et al.</i>,  2009)
;
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;
SHELXT (Sheldrick, 2015a)
;
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_diffrn_reflns_theta_min         1.574
_diffrn_standards_number         0
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_exptl_absorpt_process_details
;
(SADABS; Bruker, 2008)
;
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_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0828
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1050P)^2^+1.8388P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1774
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_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_fab_checksum              21679
_cod_database_fobs_code 2022131