Excited-State Energy-Transfer Dynamics in Self-Assembled Triads Composed of Two Porphyrins and an Intervening Bis(dipyrrinato)metal Complex
Lianhe Yu; Kannan Muthukumaran; Igor V. Sazanovich; Christine Kirmaier; Eve Hindin; James R. Diers; Paul D. Boyle; David F. Bocian; Dewey Holten; Jonathan S. Lindsey; Inorganic Chemistry 42 (2003) 6629–6647; doi:10.1021/ic034559m

data_4312334
_publ_contact_author_address
;
Department of Chemistry
North Carolina State University
Raleigh, NC 27695-8204
;
_publ_contact_author_email       jlindsey@ncsu.edu
_publ_contact_author_fax         1(919)5155079
_publ_contact_author_name        'Jonathan S. Lindsey'
_publ_contact_author_phone       1(919)5156406
_publ_section_title
;
 Excited-State Energy-Transfer Dynamics in Self-Assembled Triads Composed
 of Two Porphyrins and an Intervening Bis(dipyrrinato)metal Complex
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6629
_journal_page_last               6647
_journal_paper_doi               10.1021/ic034559m
_journal_volume                  42
_journal_year                    2003
_chemical_compound_source        'laboratory synthesis'
_chemical_formula_moiety         'C31 H23 Cl3 N4 Zn '
_chemical_formula_sum            'C31 H23 Cl3 N4 Zn'
_chemical_formula_weight         623.28
_chemical_name_systematic
;
Bis(5-phenyldipyrrinato)zinc(II)
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.0
_cell_angle_beta                 111.866(16)
_cell_angle_gamma                90.0
_cell_formula_units_Z            8
_cell_length_a                   25.478(5)
_cell_length_b                   10.9632(10)
_cell_length_c                   22.143(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    148
_cell_measurement_theta_max      18.00
_cell_measurement_theta_min      15.00
_cell_volume                     5740.0(17)
_computing_cell_refinement       'Nonius CAD4 Argus'
_computing_data_collection       'Nonius CAD4 Argus'
_computing_data_reduction        'NRCVAX DATRD2'
_computing_molecular_graphics    NRCVAX
_computing_publication_material  'NRCVAX TABLES Jan 94 Version'
_computing_structure_refinement  'NRCVAX LSTSQ'
_computing_structure_solution    SIR92
_diffrn_ambient_temperature      148
_diffrn_measurement_device       'Nonius CAD-4    '
_diffrn_measurement_method       'Omega scan b/P/b        '
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'xray tube'
_diffrn_radiation_type           'Molybdenum K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .000
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            5016
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.20
_diffrn_standards_decay_%        1.9
_diffrn_standards_interval_time  80
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.16
_exptl_absorpt_correction_T_max  .9976
_exptl_absorpt_correction_T_min  .8427
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   'NRCVAX ABSORP'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.443
_exptl_crystal_description       plate
_exptl_crystal_F_000             2551.13
_exptl_crystal_size_max          .38
_exptl_crystal_size_mid          .18
_exptl_crystal_size_min          .12
_refine_diff_density_max         1.46
_refine_diff_density_min         -1.26
_refine_ls_extinction_coef       0.0
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   2.59
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     353
_refine_ls_number_reflns         3330
_refine_ls_R_factor_all          .116
_refine_ls_R_factor_gt           .064
_refine_ls_shift/su_max          .000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     '1/(\s^2^(F)+ .0003F^2^) '
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         .079
_refine_ls_wR_factor_ref         .077
_reflns_number_gt                3334
_reflns_number_total             5016
_reflns_threshold_expression     'Inet > 1.0\s(Inet)'
_cod_data_source_file            ic034559m.cif
_cod_data_source_block           Zn-2a
_cod_original_cell_volume        5740.0(16)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C31 H23 Cl3 N4 Zn '
_cod_database_code               4312334