LMucko/crystallography-open-database huggingface dataset:
Synthesis and Characterization of Metal Complexes Possessing the 5-(2-Pyridyl) Pyrazolate Ligands: The Observation of Remarkable Osmium-Induced Blue Phosphorescence in Solution at Room Temperature
Wu, Pei-Chi; Yu, Jen-Kan; Song, Yi-Hwa; Chi, Yun; Chou, Pi-Tai; Peng, Shie-Ming; Lee, Gene-Hsiang; Organometallics 22 (2003) 4938–4946; doi:10.1021/om034037e

data_4062380
_publ_section_title
;
 Synthesis and Characterization of Metal Complexes Possessing the
 5-(2-Pyridyl) Pyrazolate Ligands: The Observation of Remarkable
 Osmium-Induced Blue Phosphorescence in Solution at Room Temperature
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4938
_journal_page_last               4946
_journal_paper_doi               10.1021/om034037e
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C20 H10 F6 N6 O2 Ru'
_chemical_formula_weight         581.41
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   17.3441(2)
_cell_length_b                   13.4557(1)
_cell_length_c                   18.4594(2)
_cell_measurement_temperature    295(2)
_cell_volume                     4308.00(8)
_diffrn_ambient_temperature      295(2)
_exptl_crystal_density_diffrn    1.793
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062380
Synthesis and Characterization of Metal Complexes Possessing the 5-(2-Pyridyl) Pyrazolate Ligands: The Observation of Remarkable Osmium-Induced Blue Phosphorescence in Solution at Room Temperature
Wu, Pei-Chi; Yu, Jen-Kan; Song, Yi-Hwa; Chi, Yun; Chou, Pi-Tai; Peng, Shie-Ming; Lee, Gene-Hsiang; Organometallics 22 (2003) 4938–4946; doi:10.1021/om034037e

data_4062381
_publ_section_title
;
 Synthesis and Characterization of Metal Complexes Possessing the
 5-(2-Pyridyl) Pyrazolate Ligands: The Observation of Remarkable
 Osmium-Induced Blue Phosphorescence in Solution at Room Temperature
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4938
_journal_page_last               4946
_journal_paper_doi               10.1021/om034037e
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C20 H10 F6 N6 O2 Os'
_chemical_formula_weight         670.54
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 109.2293(12)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.2724(7)
_cell_length_b                   13.5524(7)
_cell_length_c                   12.9716(7)
_cell_measurement_temperature    295(2)
_cell_volume                     2203.1(2)
_diffrn_ambient_temperature      295(2)
_exptl_crystal_density_diffrn    2.022
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 2/c'
_cod_database_code               4062381
Reactions of Doubly Bridged Biscyclopentadienes with Molybdenum (Tungsten) Carbonyl
Wang, Baiquan; Zhu, Bolin; Xu, Shansheng; Zhou, Xiuzhong; Organometallics 22 (2003) 4842–4852; doi:10.1021/om034039z

data_4062382
_publ_section_title
;
 Reactions of Doubly Bridged Biscyclopentadienes with Molybdenum
 (Tungsten) Carbonyl
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4842
_journal_page_last               4852
_journal_paper_doi               10.1021/om034039z
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C21 H18 Mo2 N0 O6 Si'
_chemical_formula_weight         586.32
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 117.384(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   9.098(3)
_cell_length_b                   14.337(5)
_cell_length_c                   9.710(3)
_cell_measurement_temperature    293(2)
_cell_volume                     1124.5(6)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.732
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/m'
_cod_database_code               4062382
Reactions of Doubly Bridged Biscyclopentadienes with Molybdenum (Tungsten) Carbonyl
Wang, Baiquan; Zhu, Bolin; Xu, Shansheng; Zhou, Xiuzhong; Organometallics 22 (2003) 4842–4852; doi:10.1021/om034039z

data_4062383
_publ_section_title
;
 Reactions of Doubly Bridged Biscyclopentadienes with Molybdenum
 (Tungsten) Carbonyl
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4842
_journal_page_last               4852
_journal_paper_doi               10.1021/om034039z
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C21 H18 O6 Si W2'
_chemical_formula_weight         762.14
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                101.693(7)
_cell_angle_beta                 93.921(7)
_cell_angle_gamma                92.578(8)
_cell_formula_units_Z            2
_cell_length_a                   9.540(4)
_cell_length_b                   10.366(5)
_cell_length_c                   11.167(5)
_cell_measurement_temperature    293(2)
_cell_volume                     1077.0(8)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    2.350
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062383
Three-Coordinate β-Diketiminato Nickel Nitrosyl Complexes from Nickel(I)-Lutidine and Nickel(II)-Alkyl Precursors
Puiu, Simona C.; Warren, Timothy H.; Organometallics 22 (2003) 3974–3976; doi:10.1021/om034041q

data_4062384
_publ_section_title
;
 Three-Coordinate \b-Diketiminato Nickel Nitrosyl Complexes from
 Nickel(I)-Lutidine and Nickel(II)-Alkyl Precursors
;
_journal_issue                   20
_journal_name_full               Organometallics
_journal_page_first              3974
_journal_page_last               3976
_journal_paper_doi               10.1021/om034041q
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C23 H29 N3 Ni O'
_chemical_formula_weight         422.20
_chemical_name_common            '[2,4,6-Me3NN]Ni(NO)'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 104.775(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   8.7841(10)
_cell_length_b                   32.094(4)
_cell_length_c                   16.5738(19)
_cell_measurement_temperature    173(2)
_cell_volume                     4518.0(9)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.241
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C23 H29 N3 Ni1 O1'
_cod_database_code               4062384
Three-Coordinate β-Diketiminato Nickel Nitrosyl Complexes from Nickel(I)-Lutidine and Nickel(II)-Alkyl Precursors
Puiu, Simona C.; Warren, Timothy H.; Organometallics 22 (2003) 3974–3976; doi:10.1021/om034041q

data_4062385
_publ_section_title
;
 Three-Coordinate \b-Diketiminato Nickel Nitrosyl Complexes from
 Nickel(I)-Lutidine and Nickel(II)-Alkyl Precursors
;
_journal_issue                   20
_journal_name_full               Organometallics
_journal_page_first              3974
_journal_page_last               3976
_journal_paper_doi               10.1021/om034041q
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C23 H30 N4 Ni O2'
_chemical_formula_weight         453.22
_chemical_name_common            '[Me2NN]Ni(h2-O2N2Et)'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 103.443(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.1946(6)
_cell_length_b                   28.514(2)
_cell_length_c                   11.0223(9)
_cell_measurement_temperature    173(2)
_cell_volume                     2199.2(3)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.369
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062385
Synthesis of Aryloxo Cyclopentadienyl Group 4 Metal-Containing Dendrimers
Arévalo, Silvia; de Jesús, Ernesto; de la Mata, F. Javier; Flores, Juan C.; Gómez, Rafael; Gómez-Sal, M. Pilar; Ortega, Paula; Vigo, Susana; Organometallics 22 (2003) 5109–5113; doi:10.1021/om034042i

data_4062386
_publ_section_title
;
 Synthesis of Aryloxo Cyclopentadienyl Group 4 Metal-Containing Dendrimers
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              5109
_journal_page_last               5113
_journal_paper_doi               10.1021/om034042i
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C21 H28 Cl2 O3 Ti'
_chemical_formula_weight         447.23
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 112.41(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   30.543(2)
_cell_length_b                   9.5370(10)
_cell_length_c                   16.588(2)
_cell_measurement_temperature    293(2)
_cell_volume                     4467.0(8)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.330
_cod_depositor_comments
;
 Copying the _atom_site_occupancy, _atom_site_symmetry_multiplicity,
 _atom_site_calc_flag, _atom_site_refinement_flags,
 _atom_site_disorder_assembly and _atom_site_disorder_group data item
 values for atom 'Ti1' from the original data file.

 Antanas Vaitkus,
 2017-02-15

 Changing the _atom_site_occupancy data item value from '?' to '1'
 for all fully occupied atoms.

 Antanas Vaitkus,
 2017-02-14
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4062386
Synthesis and Preparation of Alkaline-Earth-Metal Triphenylmethanides M(CPh~3~)~2~(18-crown-6)(HMPA)~2~ and the Ether Scission Products [M(C~12~H~23~O~6~)(N(SiMe~3~)~2~)]~2~ (M = Sr, Ba)
Alexander, Jacob S.; Ruhlandt-Senge, Karin; Hope, Håkon; Organometallics 22 (2003) 4933–4937; doi:10.1021/om034043a

data_4062387
_publ_section_title
;
 Synthesis and Preparation of Alkaline-Earth-Metal Triphenylmethanides
 M(CPh~3~)~2~(18-crown-6)(HMPA)~2~ and the Ether Scission Products
 [M(C~12~H~23~O~6~)(N(SiMe~3~)~2~)]~2~ (M = Sr, Ba)
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4933
_journal_page_last               4937
_journal_paper_doi               10.1021/om034043a
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C18 H41 N O6 Si2 Sr'
_chemical_formula_weight         511.32
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                84.404(2)
_cell_angle_beta                 70.367(2)
_cell_angle_gamma                86.082(2)
_cell_formula_units_Z            2
_cell_length_a                   10.0717(13)
_cell_length_b                   11.1738(14)
_cell_length_c                   12.2770(16)
_cell_measurement_temperature    93(2)
_cell_volume                     1294.2(3)
_diffrn_ambient_temperature      93(2)
_exptl_crystal_density_diffrn    1.312
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062387
Synthesis and Preparation of Alkaline-Earth-Metal Triphenylmethanides M(CPh~3~)~2~(18-crown-6)(HMPA)~2~ and the Ether Scission Products [M(C~12~H~23~O~6~)(N(SiMe~3~)~2~)]~2~ (M = Sr, Ba)
Alexander, Jacob S.; Ruhlandt-Senge, Karin; Hope, Håkon; Organometallics 22 (2003) 4933–4937; doi:10.1021/om034043a

data_4062388
_publ_section_title
;
 Synthesis and Preparation of Alkaline-Earth-Metal Triphenylmethanides
 M(CPh~3~)~2~(18-crown-6)(HMPA)~2~ and the Ether Scission Products
 [M(C~12~H~23~O~6~)(N(SiMe~3~)~2~)]~2~ (M = Sr, Ba)
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4933
_journal_page_last               4937
_journal_paper_doi               10.1021/om034043a
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C70 H106 N6 O10 P2 Sr'
_chemical_formula_weight         1341.17
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 100.439(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.9225(10)
_cell_length_b                   21.0331(17)
_cell_length_c                   13.2066(10)
_cell_measurement_temperature    98(2)
_cell_volume                     3530.1(5)
_diffrn_ambient_temperature      98(2)
_exptl_crystal_density_diffrn    1.262
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062388
Synthesis, Stereochemistry, and Reactivity of Group 4 Metal Complexes That Contain a Chiral Tetradentate Diamine-Diamide Ligand
Carpentier, Jean-François; Martin, Alfredo; Swenson, Dale C.; Jordan, Richard F.; Organometallics 22 (2003) 4999–5010; doi:10.1021/om0340443

data_4062389
_publ_section_title
;
 Synthesis, Stereochemistry, and Reactivity of Group 4 Metal Complexes
 That Contain a Chiral Tetradentate Diamine-Diamide Ligand
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4999
_journal_page_last               5010
_journal_paper_doi               10.1021/om0340443
_journal_volume                  22
_journal_year                    2003
_chemical_formula_moiety         'C14 H28 Cl2 N4 Zr'
_chemical_formula_sum            'C14 H28 Cl2 N4 Zr'
_chemical_formula_weight         414.52
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.739(4)
_cell_length_b                   15.984(6)
_cell_length_c                   8.960(3)
_cell_measurement_temperature    213(2)
_cell_volume                     1824(1)
_diffrn_ambient_temperature      213(2)
_exptl_crystal_density_diffrn    1.509
_refine_ls_R_factor_obs          0.0483
_refine_ls_wR_factor_obs         0.0834
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062389
Synthesis, Stereochemistry, and Reactivity of Group 4 Metal Complexes That Contain a Chiral Tetradentate Diamine-Diamide Ligand
Carpentier, Jean-François; Martin, Alfredo; Swenson, Dale C.; Jordan, Richard F.; Organometallics 22 (2003) 4999–5010; doi:10.1021/om0340443

data_4062390
_publ_section_title
;
 Synthesis, Stereochemistry, and Reactivity of Group 4 Metal Complexes
 That Contain a Chiral Tetradentate Diamine-Diamide Ligand
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4999
_journal_page_last               5010
_journal_paper_doi               10.1021/om0340443
_journal_volume                  22
_journal_year                    2003
_chemical_formula_moiety         'C28 H42 N4 Ti'
_chemical_formula_sum            'C28 H42 N4 Ti'
_chemical_formula_weight         482.56
_space_group_IT_number           169
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  'P 61'
_symmetry_space_group_name_H-M   'P 61'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   8.436(2)
_cell_length_b                   8.436(2)
_cell_length_c                   65.573(15)
_cell_measurement_temperature    213(2)
_cell_volume                     4041(2)
_diffrn_ambient_temperature      213(2)
_exptl_crystal_density_diffrn    1.190
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062390
Reactions of Iminophosphorano(8-quinolyl)methane with AlMe~3~: Unexpected Formation of Aluminum Iminophosphorano(2-methyl-8-quinolyl)methandiide Complex
Wang, Zhong-Xia; Li, Ye-Xin; Organometallics 22 (2003) 4900–4904; doi:10.1021/om034045v

data_4062391
_publ_section_title
;
 Reactions of Iminophosphorano(8-quinolyl)methane with AlMe~3~: Unexpected
 Formation of Aluminum Iminophosphorano(2-methyl-8-quinolyl)methandiide
 Complex
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4900
_journal_page_last               4904
_journal_paper_doi               10.1021/om034045v
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C31 H39 Al2 N2 P'
_chemical_formula_weight         524.57
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                89.232(5)
_cell_angle_beta                 88.610(6)
_cell_angle_gamma                88.114(6)
_cell_formula_units_Z            2
_cell_length_a                   10.029(3)
_cell_length_b                   12.015(3)
_cell_length_c                   12.520(4)
_cell_measurement_temperature    293(2)
_cell_volume                     1507.3(8)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.156
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062391
Reactions of Iminophosphorano(8-quinolyl)methane with AlMe~3~: Unexpected Formation of Aluminum Iminophosphorano(2-methyl-8-quinolyl)methandiide Complex
Wang, Zhong-Xia; Li, Ye-Xin; Organometallics 22 (2003) 4900–4904; doi:10.1021/om034045v

data_4062392
_publ_section_title
;
 Reactions of Iminophosphorano(8-quinolyl)methane with AlMe~3~: Unexpected
 Formation of Aluminum Iminophosphorano(2-methyl-8-quinolyl)methandiide
 Complex
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4900
_journal_page_last               4904
_journal_paper_doi               10.1021/om034045v
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C29 H36 Al N2 P'
_chemical_formula_weight         470.55
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                88.417(5)
_cell_angle_beta                 65.396(5)
_cell_angle_gamma                63.159(5)
_cell_formula_units_Z            2
_cell_length_a                   10.912(3)
_cell_length_b                   11.610(4)
_cell_length_c                   13.007(4)
_cell_measurement_temperature    293(2)
_cell_volume                     1310.4(7)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.193
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062392