Alkyne aza-Prins cyclization of N-(hexa-3,5-diynyl) tosylamides with aldehydes using triflic acid and binuclear aluminum complex
Kobayashi, Naoko; Kaneko, Kazuma; Amemiya, Sho; Noguchi, Keiichi; Yamanaka, Masahiro; Saito, Akio; Chemical Communications  (2019) –; doi:10.1039/C9CC03700D

data_7123747
_publ_section_title
;
 Alkyne aza-Prins cyclization of N-(hexa-3,5-diynyl) tosylamides with
 aldehydes using triflic acid and binuclear aluminum complex
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/C9CC03700D
_journal_year                    2019
_chemical_formula_moiety         'C25 H25 F3 N2 O7 S2'
_chemical_formula_sum            'C25 H25 F3 N2 O7 S2'
_chemical_formula_weight         586.59
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2019-05-11 deposited with the CCDC.    2019-07-01 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 92.7190(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.2055(3)
_cell_length_b                   8.4329(2)
_cell_length_c                   20.7092(4)
_cell_measurement_reflns_used    40045
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      68.26
_cell_measurement_theta_min      3.53
_cell_volume                     2652.48(10)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, 2004)'
_computing_data_reduction        'RAPID AUTO'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'Il Milione (Burla, et al., 2007)'
_diffrn_ambient_temperature      193(2)
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54187
_diffrn_reflns_av_R_equivalents  0.0272
_diffrn_reflns_av_unetI/netI     0.0132
_diffrn_reflns_Laue_measured_fraction_full 0.981
_diffrn_reflns_Laue_measured_fraction_max 0.979
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            46990
_diffrn_reflns_point_group_measured_fraction_full 0.981
_diffrn_reflns_point_group_measured_fraction_max 0.979
_diffrn_reflns_theta_full        67.687
_diffrn_reflns_theta_max         68.244
_diffrn_reflns_theta_min         4.275
_diffrn_source                   'rotating anode'
_exptl_absorpt_coefficient_mu    2.439
_exptl_absorpt_correction_T_max  0.885
_exptl_absorpt_correction_T_min  0.384
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'NUMABS (Rigaku, 1999)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.469
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1216
_exptl_crystal_size_max          0.600
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.050
_refine_diff_density_max         0.567
_refine_diff_density_min         -0.332
_refine_diff_density_rms         0.059
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     388
_refine_ls_number_reflns         4753
_refine_ls_number_restraints     76
_refine_ls_restrained_S_all      1.097
_refine_ls_R_factor_all          0.0497
_refine_ls_R_factor_gt           0.0465
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0776P)^2^+1.2786P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1279
_refine_ls_wR_factor_ref         0.1310
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4260
_reflns_number_total             4753
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9cc03700d2.cif
_cod_data_source_block           I
_cod_database_code               7123747
_shelx_estimated_absorpt_t_min   0.322
_shelx_estimated_absorpt_t_max   0.888
_shelxl_version_number           2014-3
_shelx_res_checksum              21682