Poly[[(μ~2~-4,4'-bipyridyl-κ^2^<i>N</i>:<i>N</i>')bis{μ~2~-<i>N</i>-[2-(2-hydroxybenzoyl)carbamothioyl]acetamidato-κ^4^<i>O</i>,<i>N</i>,<i>O</i>':<i>S</i>}bis(nitrato-κ^2^<i>O</i>,<i>O</i>')dicadmium] dimethylformamide tetrasolvate]
You, Ming-Hua; Li, Fo-Jun; Yang, Xiao-Ping; Lin, Xu-Xiang; Ye, Hua-Yan; Acta Crystallographica Section E 69 (2013) m647–m648; doi:10.1107/S1600536813030055

data_2238915
_publ_section_title
;
 Poly[[(\m~2~-4,4'-bipyridyl-\k^2^<i>N</i>:<i>N</i>')bis{\m~2~-<i>N</i>-[2-(2-hydroxybenzoyl)carbamothioyl]acetamidato-\k^4^<i>O</i>,<i>N</i>,<i>O</i>':<i>S</i>}bis(nitrato-\k^2^<i>O</i>,<i>O</i>')dicadmium]
 dimethylformamide tetrasolvate]
;
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m647
_journal_page_last               m648
_journal_paper_doi               10.1107/S1600536813030055
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac
'[Cd2 (C10 H10 N3 O3 S)2 (C10 H8 N2) (N O3)2], 4C3 H7 N O'
_chemical_formula_moiety         'C30 H28 Cd2 N10 O12 S2, 4(C3 H7 N O)'
_chemical_formula_sum            'C42 H56 Cd2 N14 O16 S2'
_chemical_formula_weight         1301.93
_chemical_name_systematic
'Poly[[(\m~2~-4,4'-bipyridyl-\k^2^<i>N</i>:<i>N</i>')bis{\m~2~-<i>N</i>-[2-(2-hydroxybenzoyl)carbamothioyl]acetamidato-\k^4^<i>O</i>,<i>N</i>,<i>O</i>':<i>S</i>}bis(nitrato-\k^2^<i>O</i>,<i>O</i>')dicadmium] dimethylformamide tetrasolvate]'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.55(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.831(3)
_cell_length_b                   15.280(3)
_cell_length_c                   14.363(3)
_cell_measurement_reflns_used    10007
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.5126
_cell_measurement_theta_min      3.0294
_cell_volume                     2842.3(12)
_computing_cell_refinement       'CrystalClear (Rigaku, 2007)'
_computing_data_collection       'CrystalClear (Rigaku, 2007)'
_computing_data_reduction        'CrystalClear (Rigaku, 2007)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku Saturn 724+ CCD'
_diffrn_measurement_method       '\w scans at fixed \c = 45\%'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0429
_diffrn_reflns_av_sigmaI/netI    0.0338
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            18197
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.03
_exptl_absorpt_coefficient_mu    0.896
_exptl_absorpt_correction_T_max  0.946
_exptl_absorpt_correction_T_min  0.813
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   '(CrystalClear; Rigaku, 2007)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.521
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1324
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.697
_refine_diff_density_min         -0.626
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.276
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     349
_refine_ls_number_reflns         4980
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.276
_refine_ls_R_factor_all          0.0637
_refine_ls_R_factor_gt           0.0599
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0474P)^2^+4.0842P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1388
_refine_ls_wR_factor_ref         0.1410
_reflns_number_gt                4753
_reflns_number_total             4980
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            rz5087.cif
_cod_data_source_block           I
_cod_original_cell_volume        2842.4(12)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2238915