Living Polymerization of Bulky Aryl Isocyanide with Arylrhodium Complexes
Onitsuka, Kiyotaka; Yamamoto, Mari; Mori, Tomoko; Takei, Fumie; Takahashi, Shigetoshi; Organometallics 25 (2006) 1270–1278; doi:10.1021/om0509692

data_4074878
_publ_section_title
;
 Living Polymerization of Bulky Aryl Isocyanide with Arylrhodium Complexes
;
_journal_coden_ASTM              ORGND7
_journal_issue                   5
_journal_name_full               Organometallics
_journal_page_first              1270
_journal_page_last               1278
_journal_paper_doi               10.1021/om0509692
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C36 H32 P Rh '
_chemical_formula_sum            'C36 H32 P Rh'
_chemical_formula_weight         598.53
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 105.5(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.42(2)
_cell_length_b                   14.78(3)
_cell_length_c                   17.18(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    198.2
_cell_measurement_theta_max      18.3
_cell_measurement_theta_min      12.8
_cell_volume                     2794(9)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    'DIRDIF94 (PATTY)'
_diffrn_measured_fraction_theta_max 0.9987
_diffrn_measurement_device_type  'Rigaku AFC5R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.050
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            6760
_diffrn_reflns_theta_max         27.5
_diffrn_standards_decay_%        0.08
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.690
_exptl_absorpt_correction_T_max  0.980
_exptl_absorpt_correction_T_min  0.879
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.422
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.88
_refine_diff_density_min         -0.93
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.140
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     343
_refine_ls_number_reflns         3621
_refine_ls_R_factor_gt           0.0517
_refine_ls_shift/su_max          0.0120
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00212|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0760
_reflns_number_gt                3621
_reflns_number_total             6446
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            om0509692si20051111_060040.cif
_cod_data_source_block           Rh(2-Me-1-naphthyl)(nbd)(PPh3)
_cod_original_cell_volume        2795(7)
_cod_original_formula_sum        'C36 H32 P Rh '
_cod_database_code               4074878