Successive Formation of Hydrido(germyl)platinum, Germaplatinacycle, and Germylene-Bridged Dinuclear Platinum Complexes from the Reaction of a Zerovalent Platinum Complex with α,ω-Dihydrodigermanes
Usui, Yoko; Hosotani, Sayaka; Ogawa, Aki; Nanjo, Masato; Mochida, Kunio; Organometallics 24 (2005) 4337–; doi:10.1021/om0503287

data_4083942
_publ_section_title
;
 Successive Formation of Hydrido(germyl)platinum, Germaplatinacycle, and
 Germylene-Bridged Dinuclear Platinum Complexes from the Reaction of a
 Zerovalent Platinum Complex with \a,\w-Dihydrodigermanes
;
_journal_issue                   18
_journal_name_full               Organometallics
_journal_page_first              4337
_journal_paper_doi               10.1021/om0503287
_journal_volume                  24
_journal_year                    2005
_chemical_formula_moiety         'C60 H50 Ge2 P2 Pt2 '
_chemical_formula_sum            'C60 H50 Ge2 P2 Pt2'
_chemical_formula_weight         1368.36
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                80.341(9)
_cell_angle_beta                 80.978(11)
_cell_angle_gamma                73.924(10)
_cell_formula_units_Z            2
_cell_length_a                   9.4802(13)
_cell_length_b                   11.8928(17)
_cell_length_c                   23.244(4)
_cell_measurement_reflns_used    9824
_cell_measurement_temperature    150.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     2465.6(7)
_computing_cell_refinement       Unknown
_computing_data_collection       Unknown
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.952
_diffrn_measurement_device_type  'MacScience DIP2030 imaging plate'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.102
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            24646
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    6.945
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.843
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1320.00
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.98
_refine_diff_density_min         -3.66
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.943
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     645
_refine_ls_number_reflns         8956
_refine_ls_R_factor_gt           0.0736
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0010Fo^2^ + 2.0000\s(Fo^2^) + 0.5000]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1864
_reflns_number_gt                6881
_reflns_number_total             10772
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om0503287si20050713_102736.cif
_cod_data_source_block           '__[Pt(GePh2)(PPh3)]2'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        2465.6(6)
_cod_original_formula_sum        'C60 H50 Ge2 P2 Pt2 '
_cod_database_code               4083942