Gold(i)-doped films: new routes for efficient room temperature phosphorescent materials.
de Aquino, Araceli; Caparrós, Francisco J; Truong, Khai-Nghi; Rissanen, Kari; Ferrer, Montserrat; Jung, Yongsik; Choi, Hyeonho; Lima, João Carlos; Rodríguez, Laura; Dalton transactions (Cambridge, England : 2003) 50 (2021) 3806–3815; doi:10.1039/d1dt00087j

data_7706678
_publ_section_title
;
 Gold(i)-doped films: new routes for efficient room temperature
 phosphorescent materials.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3806
_journal_page_last               3815
_journal_paper_doi               10.1039/d1dt00087j
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C78 H60 Au4 P4'
_chemical_formula_sum            'C78 H60 Au4 P4'
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_space_group_name_Hall           '-P 2yn'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2021-01-08 deposited with the CCDC.	2021-02-24 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      28.700
_cell_measurement_theta_min      0.407
_cell_volume                     3550.69(18)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Bruker AXS BV, 1997-2004)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'PLATON (Spek, 2009)'
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_computing_structure_solution    'SHELXS2013 (Sheldrick, 2015)'
_diffrn_ambient_temperature      120(2)
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_diffrn_measurement_device       '95mm CCD camera on \k-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  'horizonally mounted graphite crystal'
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_diffrn_reflns_theta_max         25.249
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_exptl_absorpt_coefficient_mu    8.369
_exptl_absorpt_correction_T_max  0.7458
_exptl_absorpt_correction_T_min  0.5175
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.786
_exptl_crystal_description       block
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_exptl_crystal_size_min          0.19
_refine_diff_density_max         1.592
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
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_refine_ls_number_reflns         6436
_refine_ls_number_restraints     118
_refine_ls_restrained_S_all      1.008
_refine_ls_R_factor_all          0.1064
_refine_ls_R_factor_gt           0.0627
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0452P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1233
_refine_ls_wR_factor_ref         0.1367
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4087
_reflns_number_total             6436
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1dt00087j2.cif
_cod_data_source_block           2b
_cod_depositor_comments
'Adding full bibliography for 7706677--7706679.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7706678
_shelx_shelxl_version_number     2017/1
_shelx_estimated_absorpt_t_min   0.260
_shelx_estimated_absorpt_t_max   0.299
_shelx_res_checksum              292
_shelx_fab_checksum              33552