Phosphorus–nitrogen compounds: part 68. Synthesis, characterization, stereogenism, photophysical and bioactivity studies of novel unsymmetrical dispiro(N/N)cyclotriphosphazenes with carbazolyl and 4-chlorobenzyl pendant arms
Cemaloğlu, Reşit; Asmafiliz, Nuran; Kılıç, Zeynel; Çoşut, Bünyemin; Sabah, Büşra Nur; Açık, Leyla; Çerçi, Nebahat Aytuna; Hökelek, Tuncer; New Journal of Chemistry 47 (2023) 1900–1915; doi:10.1039/D2NJ05010B

data_7062160
_publ_section_title
;
 Phosphorus--nitrogen compounds: part 68. Synthesis, characterization,
 stereogenism, photophysical and bioactivity studies of novel
 unsymmetrical dispiro(N/N)cyclotriphosphazenes with carbazolyl and
 4-chlorobenzyl pendant arms
;
_journal_issue                   4
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              1900
_journal_page_last               1915
_journal_paper_doi               10.1039/D2NJ05010B
_journal_volume                  47
_journal_year                    2023
_chemical_formula_moiety         'C29 H36 Cl3 N8 P3'
_chemical_formula_sum            'C29 H36 Cl3 N8 P3'
_chemical_formula_weight         695.92
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2022-09-28 deposited with the CCDC.	2022-12-12 downloaded from the CCDC.
;
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_cell_volume                     6360.7(3)
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'WinGX publication routines (Farrugia, 2012) and PLATON (Spek, 2009)'
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_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
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'Bruker APEX II QUAZAR three-circle diffractometer'
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_refine_ls_restrained_S_all      1.070
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0417P)^2^+5.0857P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             7292
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7062159--7062160.cif.'
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