An iron(iii)-catalyzed dehydrogenative cross-coupling reaction of indoles with benzylamines to prepare 3-aminoindole derivatives
Chen, Wei-Li; Li, Kun; Liao, Wei-Cong; Liang, Wang-Fu; Qiu, Pei-Wen; Liang, Cui; Su, Gui-Fa; Mo, Dong-Liang; Green Chemistry 23 (2021) 9610–9616; doi:10.1039/D1GC02849A

data_7243785
_publ_section_title
;
 An iron(iii)-catalyzed dehydrogenative cross-coupling reaction of indoles
 with benzylamines to prepare 3-aminoindole derivatives
;
_journal_issue                   23
_journal_name_full               'Green Chemistry'
_journal_page_first              9610
_journal_page_last               9616
_journal_paper_doi               10.1039/D1GC02849A
_journal_volume                  23
_journal_year                    2021
_chemical_formula_moiety         'C20 H14 N2'
_chemical_formula_sum            'C20 H14 N2'
_chemical_formula_weight         282.33
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
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Olex2 1.2
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_audit_update_record
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2021-08-08 deposited with the CCDC.	2021-10-20 downloaded from the CCDC.
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_computing_cell_refinement
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
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  1 omega  -78.00   99.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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  2 omega  -99.00  -34.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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omega____ theta____ kappa____ phi______ frames
    -      -11.9283  -99.0000  150.0000 25
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_diffrn_measurement_device       'four-circle diffractometer'
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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'w=1/[\s^2^(Fo^2^)+(0.0476P)^2^+0.3851P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7243784--7243785.cif.'
_cod_database_code               7243785
_shelx_shelxl_version_number     2014/7
_reflns_odcompleteness_completeness 99.46
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C20(H20), C10(H10), C4(H4), C18(H18), C2(H2), C3(H3), C5(H5), C11(H11),
 C19(H19), C16(H16), C14(H14), C17(H17), C12(H12), C13(H13)
;
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