Homogeneous Palladium Catalyst Suppressing Pd Black Formation in Air Oxidation of Alcohols
Tetsuo Iwasawa; Makoto Tokunaga; Yasushi Obora; Yasushi Tsuji; Journal of the American Chemical Society 126 (2004) 6554–6555; doi:10.1021/ja031936l

data_4112601
_publ_section_title
;
 Homogeneous Palladium Catalyst Suppressing Pd Black Formation in Air
 Oxidation of Alcohols
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              6554
_journal_page_last               6555
_journal_paper_doi               10.1021/ja031936l
_journal_volume                  126
_journal_year                    2004
_chemical_formula_moiety         'C92 H78 N4 O4 Pd '
_chemical_formula_sum            'C92 H78 N4 O4 Pd'
_chemical_formula_weight         1410.05
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_symmetry_cell_setting           monoclinic
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_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
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_cell_angle_beta                 98.94(4)
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_cell_length_c                   20.68(6)
_cell_measurement_reflns_used    117
_cell_measurement_temperature    113.0
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
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_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
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_computing_structure_refinement  CRYSTALS
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_diffrn_measurement_method       \w
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_exptl_absorpt_correction_T_min  0.741
_exptl_absorpt_correction_type   none
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_refine_ls_hydrogen_treatment    refall
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[0.0010Fo^2^ + 1.0000\s(Fo^2^)]'
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_cod_original_formula_sum        'C92 H78 N4 O4 Pd '
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