Chiral induction upon coordination to form an enantiomeric bis-chelate ruthenium(II)‒tris(3-methyl-2-pyridylmethyl)amine complex
Kojima, Takahiko; Matsuda, Yoshihisa; Journal of the Chemical Society, Dalton Transactions  (2001) 958–; doi:10.1039/b100095k

data_7010545
_publ_section_title
;
 Chiral induction upon coordination to form an enantiomeric bis-chelate
 ruthenium(II)--tris(3-methyl-2-pyridylmethyl)amine complex
;
_journal_issue                   7
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              958
_journal_paper_doi               10.1039/b100095k
_journal_year                    2001
_chemical_formula_moiety         'C88 H112 F24 N16 O4 P4 Ru2 '
_chemical_formula_sum            'C88 H112 F24 N16 O4 P4 Ru2'
_chemical_formula_weight         2239.95
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 91.8028(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   19.9883(4)
_cell_length_b                   19.4365(5)
_cell_length_c                   24.5289(6)
_cell_measurement_reflns_used    86743
_cell_measurement_temperature    93.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.7
_cell_volume                     9524.8(4)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  SHELXL97
_computing_structure_solution    SIR92
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.000
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            72948
_diffrn_reflns_theta_max         27.49
_exptl_absorpt_coefficient_mu    0.491
_exptl_absorpt_correction_T_max  0.952
_exptl_absorpt_correction_T_min  0.620
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.562
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.17
_refine_diff_density_min         -1.21
_refine_ls_extinction_coef       0.0000
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.934
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     1270
_refine_ls_number_reflns         11997
_refine_ls_R_factor_gt           0.0546
_refine_ls_shift/su_max          -4.6030
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.0813P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1586
_reflns_number_gt                11997
_reflns_number_total             21711
_reflns_threshold_expression     >2.0sigma(I)
_cod_data_source_file            b100095k.txt
_cod_data_source_block           kojima6
_cod_original_formula_sum        'C88 H112 F24 N16 O4 P4 Ru2 '
_cod_database_code               7010545