Synthesis, Unusual trigonal Prismatic Geometry, and Theoretical Study of the Homoleptic Tris-(2,2'-biphosphinine) Complexes of Chromium, Molybdenum, and Tungsten
Patrick Rosa; Louis Ricard; Pascal Le Floch; François Mathey; Gjergji Sini; Odile Eisenstein; Inorganic Chemistry 37 (1998) 3154–3158; doi:10.1021/ic980042c

data_4322864
_publ_contact_author
;
  Louis Ricard,
  Labo DCPH,
   Ecole Polytechnique
   91128 Route de Palaiseau
   France
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_publ_contact_author_email       louis.ricard@polytechnique.fr
_publ_contact_author_fax         01-69-33-39-90
_publ_contact_author_phone       01-69-33-45-72
_publ_section_title
;
 Synthesis, Unusual trigonal Prismatic Geometry, and Theoretical Study of
 the Homoleptic Tris-(2,2'-biphosphinine) Complexes of Chromium,
 Molybdenum, and Tungsten
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3154
_journal_page_last               3158
_journal_paper_doi               10.1021/ic980042c
_journal_volume                  37
_journal_year                    1998
_chemical_formula_moiety         'C46 H56 O P6 W'
_chemical_formula_sum            'C46 H56 O P6 W'
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_chemical_name_systematic        ' ?'
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_refine_ls_weighting_details     'w = 4Fo^2^/(\s^2^(Fo^2^) + 0.0064 Fo^4^)'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                4973
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_reflns_threshold_expression     >3.0\s(I)
_cod_data_source_file            ic980042c.cif
_cod_data_source_block           wbiphos
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value '4Fo^2^/(\s^2^(Fo^2^) + 0.0064
Fo^4^)' was changed to 'calc'. New tag '_refine_ls_weighting_details'
was created. The value of the new tag was set to 'w =
4Fo^2^/(\s^2^(Fo^2^) + 0.0064 Fo^4^)'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        4844(2)
_cod_database_code               4322864