A series of rare-earth phosphine-oxygen complexes containing [PW12O40]3− with highly efficient photocatalytic degradation of MB
Li, Ying-Yu; Qiu, Qi-Ming; Fan, Si-Jie; Xu, Jian-Jie; Mou, Wen-Long; Hou, Chuan-Bing; Liu, Min; Yang, Yu-Ping; Dai, Li-Xiong; Han, Hong-Liang; Jin, Qiong-Hua; CrystEngComm 26 (2024) 5809–5819; doi:10.1039/D4CE00851K

data_7249347
_publ_section_title
;
 A series of rare-earth phosphine-oxygen complexes containing
 [PW12O40]3&#x2212; with highly efficient photocatalytic degradation of MB
;
_journal_issue                   40
_journal_name_full               CrystEngComm
_journal_page_first              5809
_journal_page_last               5819
_journal_paper_doi               10.1039/D4CE00851K
_journal_volume                  26
_journal_year                    2024
_chemical_formula_sum            'C42 H100 Dy O60 P7 W12'
_chemical_formula_weight         4150.70
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_space_group_name_Hall           '-P 1'
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_audit_update_record
;
2023-03-10 deposited with the CCDC.	2024-09-12 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2019/2 (Sheldrick, 2019)'
_diffrn_ambient_temperature      293(2)
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
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_exptl_crystal_size_max          0.180
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_platon_squeeze_details
;
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0853P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                5395
_reflns_number_total             18471
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4ce00851k21.cif
_cod_data_source_block           221123c
_cod_depositor_comments
'Adding full bibliography for 7249339--7249349.cif.'
_cod_original_cell_volume        5352.9(9)
_cod_database_code               7249347
_shelx_shelxl_version_number     2019/2
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