N,N-Dialkylbenzimidazol-2-ylidene platinum complexes - effects of alkyl residues and ancillary cis-ligands on anticancer activity.
Rehm, Tobias; Rothemund, Matthias; Bär, Alexander; Dietel, Thomas; Kempe, Rhett; Kostrhunova, Hana; Brabec, Viktor; Kasparkova, Jana; Schobert, Rainer; Dalton transactions (Cambridge, England : 2003) 47 (2018) 17367–17381; doi:10.1039/c8dt03360a

data_7048151
_publ_section_title
;
 N,N-Dialkylbenzimidazol-2-ylidene platinum complexes - effects of alkyl
 residues and ancillary cis-ligands on anticancer activity.
;
_journal_issue                   48
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              17367
_journal_page_last               17381
_journal_paper_doi               10.1039/c8dt03360a
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C45 H40 Cl1 N2 P2 Pt, Cl'
_chemical_formula_sum            'C45 H40 Cl2 N2 P2 Pt'
_chemical_formula_weight         936.72
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2018-07-23 deposited with the CCDC.
2018-11-13 downloaded from the CCDC.
;
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_cell_angle_gamma                90.000(5)
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_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SROE XRED-32'
_exptl_crystal_colour            colourless
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_exptl_crystal_description       platte
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         8450
_refine_ls_number_restraints     27
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_refine_ls_R_factor_all          0.1157
_refine_ls_R_factor_gt           0.0718
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1181P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1722
_refine_ls_wR_factor_ref         0.1903
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5359
_reflns_number_total             8450
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt03360a2.cif
_cod_data_source_block           shelx_CCDC2
_cod_depositor_comments
'Adding full bibliography for 7048149--7048151.cif.'
_cod_database_code               7048151
_shelx_shelxl_version_number     2016/6
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