Unusual magnetic and transport properties of heavily disordered Mn-Zn-M (M = Ga and Sn) alloys with a β-Mn-type chiral structure.
Pan, Rahul; Saraswati, Anyesh; Mondal, Amit; Biswal, Pujalin; Samal, Debakanta; Kumar, Nitesh; Jana, Partha Pratim; Dalton transactions (Cambridge, England : 2003) 54 (2025) 14469–14479; doi:10.1039/d5dt01357g

data_7719444
_publ_section_title
;
 Unusual magnetic and transport properties of heavily disordered Mn-Zn-M
 (M = Ga and Sn) alloys with a &#x3b2;-Mn-type chiral structure.
;
_journal_issue                   38
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14469
_journal_page_last               14479
_journal_paper_doi               10.1039/d5dt01357g
_journal_volume                  54
_journal_year                    2025
_chemical_formula_sum            'Mn0.917 Zn0.083'
_chemical_formula_weight         55.8
_space_group_IT_number           213
_space_group_name_Hall           'P 4bd 2ab 3'
_space_group_name_H-M_alt        'P 41 3 2'
_symmetry_cell_setting           cubic
_symmetry_Int_Tables_number      213
_symmetry_space_group_name_Hall  'P 4bd 2ab 3'
_symmetry_space_group_name_H-M   'P 41 3 2'
_audit_update_record
;
2025-08-16 deposited with the CCDC.	2025-08-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            20
_cell_length_a                   6.3928(4)
_cell_length_b                   6.3928(4)
_cell_length_c                   6.3928(4)
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_cell_measurement_temperature    293
_cell_measurement_theta_max      35.10
_cell_measurement_theta_min      3.19
_cell_volume                     261.26(3)
_diffrn_ambient_temperature      293
_diffrn_measured_fraction_theta_full 0.99
_diffrn_measured_fraction_theta_max 0.99
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Bruker Photon II'
_diffrn_measurement_method       'Bruker Photon II'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.053
_diffrn_reflns_av_unetI/netI     0.0203
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            3788
_diffrn_reflns_theta_full        35.1
_diffrn_reflns_theta_max         35.1
_diffrn_reflns_theta_min         4.51
_exptl_absorpt_coefficient_mu    24.923
_exptl_absorpt_correction_T_max  0.7469
_exptl_absorpt_correction_T_min  0.3258
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Silver
_exptl_crystal_density_diffrn    7.0938
_exptl_crystal_description       Rectangle
_exptl_crystal_F_000             508
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.48
_refine_diff_density_min         -0.52
_refine_ls_abs_structure_details '  50 of Friedel pairs used in the refinement'
_refine_ls_abs_structure_Flack   0.0(3)
_refine_ls_extinction_coef       810(80)
_refine_ls_extinction_method
'B-C type 1 Gaussian isotropic (Becker & Coppens, 1974)'
_refine_ls_goodness_of_fit_gt    1.43
_refine_ls_goodness_of_fit_ref   1.43
_refine_ls_number_constraints    5
_refine_ls_number_parameters     11
_refine_ls_number_reflns         197
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0180
_refine_ls_R_factor_gt           0.0164
_refine_ls_shift/su_max          0.0191
_refine_ls_shift/su_mean         0.0050
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     w=1/(\s^2^(I)+0.0004I^2^)
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_gt          0.0436
_refine_ls_wR_factor_ref         0.0441
_reflns_number_gt                191
_reflns_number_total             197
_reflns_threshold_expression     I>3\s(I)
_cod_data_source_file            d5dt01357g2.cif
_cod_data_source_block           I_CCDC1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_diffrn_radiation_probe' value 'X-ray' was changed to
'x-ray' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 

 Adding full bibliography for 7719443--7719449.cif.
;
_cod_original_sg_symbol_Hall     'P 4bd;2ab;3'
_cod_database_code               7719444