In Situ Generation of a Regio- and Diastereoselective Hydroaminoalkylation Catalyst Using Commercially Available Starting Materials.
Edwards, Peter M.; Schafer, Laurel L.; Organic letters 19 (2017) 5720–5723; doi:10.1021/acs.orglett.7b02149

data_1547726
_publ_section_title
;
 In Situ Generation of a Regio- and Diastereoselective
 Hydroaminoalkylation Catalyst Using Commercially Available Starting
 Materials.
;
_journal_issue                   21
_journal_name_full               'Organic letters'
_journal_page_first              5720
_journal_page_last               5723
_journal_paper_doi               10.1021/acs.orglett.7b02149
_journal_volume                  19
_journal_year                    2017
_chemical_formula_sum            'C18 H24 N O4'
_chemical_formula_weight         318.38
_chemical_name_systematic
;
 ?
;
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_space_group_name_Hall           '-P 1'
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_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.80
_cell_measurement_theta_min      2.19
_cell_volume                     929.0(3)
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
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_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.990
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_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         27.187
_diffrn_reflns_theta_min         2.127
_exptl_absorpt_coefficient_mu    0.080
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.138
_exptl_crystal_description       prism
_exptl_crystal_F_000             342
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_exptl_crystal_size_min          0.110
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     212
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0898P)^2^+2.1374P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_total             4055
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ol7b02149_si_001.cif
_cod_data_source_block           mo_ls686_0m_a
_cod_depositor_comments
'Adding full bibliography for 1547726--1547727.cif.'
_cod_database_code               1547726
_shelx_estimated_absorpt_t_min   0.984
_shelx_estimated_absorpt_t_max   0.991
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_shelx_hkl_checksum              14492