Reactivity of the carbodiphosphorane, (Ph<sub>3</sub>P)<sub>2</sub>C, towards main group metal alkyl compounds: coordination and cyclometalation.
Quinlivan, Patrick J.; Shlian, Daniel G.; Amemiya, Erika; Parkin, Gerard; Dalton transactions (Cambridge, England : 2003) 48 (2019) 9139–9151; doi:10.1039/c9dt00678h

data_7700121
_publ_section_title
;
 Reactivity of the carbodiphosphorane, (Ph<sub>3</sub>P)<sub>2</sub>C,
 towards main group metal alkyl compounds: coordination and
 cyclometalation.
;
_journal_issue                   25
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9139
_journal_page_last               9151
_journal_paper_doi               10.1039/c9dt00678h
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C55 H59 N P2 Si2 Zn'
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_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2019-02-13 deposited with the CCDC.    2019-04-29 downloaded from the CCDC.
;
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'w=1/[\s^2^(Fo^2^)+(0.0430P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7700119--7700124.cif.'
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