Synthesis of chiral organotin hydrides containing menthyl and oxazoline substituents†
Dakternieks, Dainis; Dunn, Kerri; Schiesser, Carl H.; Tiekink, Edward R. T.; Journal of the Chemical Society, Dalton Transactions  (2000) 3693–; doi:10.1039/b004259p

data_7009898
_publ_section_title
;
 Synthesis of chiral organotin hydrides containing menthyl and
 oxazoline substituents&#x2020;
;
_journal_issue                   20
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              3693
_journal_paper_doi               10.1039/b004259p
_journal_year                    2000
_chemical_formula_moiety         'C28 H38 Cl N O Sn '
_chemical_formula_sum            'C28 H38 Cl N O Sn'
_chemical_formula_weight         558.76
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      4
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90
_cell_angle_beta                 112.36(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   8.052(2)
_cell_length_b                   17.781(6)
_cell_length_c                   10.304(3)
_cell_measurement_reflns_used    3
_cell_measurement_temperature    173
_cell_measurement_theta_max      25.0
_cell_measurement_theta_min      24.5
_cell_volume                     1364.3(7)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan for Windows (MSC, 1997)'
_computing_publication_material  'teXsan for Windows (MSC, 1997)'
_computing_structure_refinement  'teXsan for Windows (MSC, 1997)'
_computing_structure_solution
;
'DIRDIF92 PATTY (Beurskens, 1992)
;
_diffrn_ambient_temperature      173
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      0.06472
_diffrn_orient_matrix_UB_12      -0.04215
_diffrn_orient_matrix_UB_13      -0.02480
_diffrn_orient_matrix_UB_21      -0.10980
_diffrn_orient_matrix_UB_22      -0.03210
_diffrn_orient_matrix_UB_23      -0.02538
_diffrn_orient_matrix_UB_31      -0.04232
_diffrn_orient_matrix_UB_32      0.01887
_diffrn_orient_matrix_UB_33      -0.09875
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.040
_diffrn_reflns_av_sigmaI/netI    0.066
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            3463
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         3.13
_diffrn_standards_decay_%        -0.05
_diffrn_standards_interval_count 400
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.053
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.360
_exptl_crystal_density_meas      ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             576
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.71
_refine_diff_density_min         -1.31
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   2.160
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     288
_refine_ls_number_reflns         2310
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           0.0350
_refine_ls_shift/su_max          0.0000
_refine_ls_shift/su_mean         0.0001
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00001|Fo|^2^]'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0430
_reflns_number_gt                2310
_reflns_number_total             3245
_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            b004259p.txt
_cod_data_source_block           '_MenPhLSnCl'
_cod_original_sg_symbol_H-M      'P 21       '
_cod_original_formula_sum        'C28 H38 Cl N O Sn '
_cod_database_code               7009898