<i>catena</i>-Poly[[(acetato-κ^2^<i>O</i>,<i>O</i>')[2-(4-oxo-1,4-dihydroquinolin-1-yl)acetato-κ<i>O</i>^1^]copper(II)]-μ-4,4'-bipyridine-κ^2^<i>N</i>:<i>N</i>']
Wang, Jun; Dai, Chuntao; Nie, Jianhua; Acta Crystallographica Section E 68 (2012) m1132–; doi:10.1107/S160053681203303X

data_2235734
_publ_section_title
;
 <i>catena</i>-Poly[[(acetato-\k^2^<i>O</i>,<i>O</i>')[2-(4-oxo-1,4-dihydroquinolin-1-yl)acetato-\k<i>O</i>^1^]copper(II)]-\m-4,4'-bipyridine-\k^2^<i>N</i>:<i>N</i>']
;
_journal_coeditor_code           BG2474
_journal_issue                   8
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1132
_journal_paper_doi               10.1107/S160053681203303X
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Cu (C11 H8 N O3) (C2 H3 O2) (C10 H8 N2)]'
_chemical_formula_moiety         'C23 H21 Cu  N3 O6'
_chemical_formula_sum            'C23 H21 Cu N3 O6'
_chemical_formula_weight         498.97
_chemical_name_systematic
;
<i>catena</i>-Poly[[(acetato-\k^2^<i>O</i>,<i>O'</i>')[2-(4-oxo-1,4-
dihydroquinolin-1-yl)acetato-\k<i>O</i>^1^]copper(II)]-\m-4,4'-bipyridine-
\k^2^<i>N</i>:<i>N</i>']
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                70.03(3)
_cell_angle_beta                 71.27(3)
_cell_angle_gamma                88.03(3)
_cell_formula_units_Z            2
_cell_length_a                   9.543(2)
_cell_length_b                   11.121(2)
_cell_length_c                   11.381(2)
_cell_measurement_reflns_used    3600
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      28.00
_cell_measurement_theta_min      1.26
_cell_volume                     1071.2(5)
_computing_cell_refinement       'SAINT (Bruker, 2004)'
_computing_data_collection       'APEX2 (Bruker, 2004)'
_computing_data_reduction        'SAINT (Bruker, 2004)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker APEXII area-detector'
_diffrn_measurement_method       '\f and \w scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0182
_diffrn_reflns_av_sigmaI/netI    0.0349
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            5588
_diffrn_reflns_theta_full        25.20
_diffrn_reflns_theta_max         25.20
_diffrn_reflns_theta_min         1.96
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.066
_exptl_absorpt_correction_T_max  0.7993
_exptl_absorpt_correction_T_min  0.7066
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.547
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             514
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.267
_refine_diff_density_min         -0.294
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     305
_refine_ls_number_reflns         3815
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0440
_refine_ls_R_factor_gt           0.0346
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0368P)^2^+0.6150P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0812
_refine_ls_wR_factor_ref         0.0867
_reflns_number_gt                3217
_reflns_number_total             3815
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            bg2474.cif
_cod_data_source_block           I
_cod_original_cell_volume        1071.3(5)
_cod_original_formula_sum        'C23 H21 Cu  N3 O6'
_cod_database_code               2235734
_cod_database_fobs_code          2235734