<i>catena</i>-Poly[[silver(I)-μ-<i>N</i>-(pyridin-3-ylmethyl)pyridine-2-amine-κ^2^<i>N</i>:<i>N</i>'] trifluoromethanesulfonate]
Moon, Suk-Hee; Park, Ki-Min; Acta Crystallographica Section E 69 (2013) m414–m415; doi:10.1107/S1600536813016309

data_2238252
_publ_section_title
;
 <i>catena</i>-Poly[[silver(I)-\m-<i>N</i>-(pyridin-3-ylmethyl)pyridine-2-amine-\k^2^<i>N</i>:<i>N</i>']
 trifluoromethanesulfonate]
;
_journal_coeditor_code           SJ5332
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m414
_journal_page_last               m415
_journal_paper_doi               10.1107/S1600536813016309
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          '[Ag (C11 H11 N3)] (C F3 O3 S)'
_chemical_formula_moiety         'C11 H11 Ag N3 +, C F3 O3 S -'
_chemical_formula_sum            'C12 H11 Ag F3 N3 O3 S'
_chemical_formula_weight         442.17
_chemical_name_systematic
'<i>catena</i>-Poly[[silver(I)-\m-<i>N</i>-(pyridin-3-ylmethyl)pyridine-2-amine-\k^2^<i>N</i>:<i>N</i>'] trifluoromethanesulfonate]'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXTL
_cell_angle_alpha                90.00
_cell_angle_beta                 102.9940(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   14.0965(10)
_cell_length_b                   10.4007(7)
_cell_length_c                   20.6593(15)
_cell_measurement_reflns_used    5912
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.13
_cell_measurement_theta_min      2.22
_cell_volume                     2951.4(4)
_computing_cell_refinement       '<i>SAINT-Plus</i> (Bruker, 2000)'
_computing_data_collection       '<i>SMART</i> (Bruker, 2000)'
_computing_data_reduction        '<i>SAINT-Plus</i> (Bruker, 2000)'
_computing_molecular_graphics    '<i>DIAMOND</i> (Brandenburg, 2005)'
_computing_publication_material  '<i>SHELXTL</i> (Sheldrick, 2008)'
_computing_structure_refinement  '<i>SHELXL97</i> (Sheldrick, 2008)'
_computing_structure_solution    '<i>SHELXS97</i> (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0467
_diffrn_reflns_av_sigmaI/netI    0.0602
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            16169
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.48
_exptl_absorpt_coefficient_mu    1.558
_exptl_absorpt_correction_T_max  0.6967
_exptl_absorpt_correction_T_min  0.6522
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.990
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1744
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.25
_refine_diff_density_max         2.701
_refine_diff_density_min         -1.891
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     415
_refine_ls_number_reflns         5797
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.090
_refine_ls_R_factor_all          0.1111
_refine_ls_R_factor_gt           0.0881
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1255P)^2^+38.0270P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2239
_refine_ls_wR_factor_ref         0.2380
_reflns_number_gt                4479
_reflns_number_total             5797
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            sj5332.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2238252
_cod_database_fobs_code          2238252