Control of the spin state by charge and ligand substitution: two-step spin crossover behaviour in a novel neutral iron(ii) complex.
Seredyuk, Maksym; Znovjyak, Kateryna O.; Kusz, Joachim; Nowak, Maria; Muñoz, M Carmen; Real, Jose Antonio; Dalton transactions (Cambridge, England : 2003) 43 (2014) 16387–16394; doi:10.1039/c4dt01885k

data_7032077
_publ_section_title
;
 Control of the spin state by charge and ligand substitution: two-step
 spin crossover behaviour in a novel neutral iron(ii) complex.
;
_journal_issue                   43
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              16387
_journal_page_last               16394
_journal_paper_doi               10.1039/c4dt01885k
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety
;
C40 H26 Fe N8, 2(C H Cl3)
;
_chemical_formula_sum            'C42 H28 Cl6 Fe N8'
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 
;
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 
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Mercury (Macrae et al., 2006), Diamond (Brandenburg, 2007)
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SuperNova diffractometer (Agilent Technologies) with Atlas detector
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            black
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_exptl_crystal_description       polyhedron
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'calc w=1/[\s^2^(Fo^2^)+(0.0530P)^2^+6.0731P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                6131
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'Adding full bibliography for 7032074--7032079.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
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