Rh(iii)-Catalyzed regio- and stereoselective bisindolylation of vinyl acetate: an efficient approach toward (E)-1,2-bis(2-indolyl)ethenes
Qin, Wen-Bing; Li, Wei-Wei; Zhu, Peng-Fei; Mo, Xiao-Gang; Zhang, Hui-Jun; Wen, Ting-Bin; Organic Chemistry Frontiers 5 (2018) 1096–; doi:10.1039/C7QO01041A

data_1553950
_publ_section_title
;
 Rh(iii)-Catalyzed regio- and stereoselective bisindolylation of vinyl
 acetate: an efficient approach toward (E)-1,2-bis(2-indolyl)ethenes
;
_journal_issue                   7
_journal_name_full               'Organic Chemistry Frontiers'
_journal_page_first              1096
_journal_paper_doi               10.1039/C7QO01041A
_journal_volume                  5
_journal_year                    2018
_chemical_formula_moiety         'C28 H20 N4'
_chemical_formula_sum            'C28 H20 N4'
_chemical_formula_weight         412.48
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
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Olex2 1.2
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2017-08-20 deposited with the CCDC.
2018-01-12 downloaded from the CCDC.
;
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
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(compiled Dec  3 2012,18:21:49)
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
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omega____ theta____ kappa____ phi______ frames
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  2 omega    9.00  103.00   1.0000    1.0000
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  3 omega   76.00  114.00   1.0000    1.0000
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  4 omega   35.00   84.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
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  5 omega -130.00 -105.00   1.0000    2.0000
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  6 omega  122.00  148.00   1.0000    2.0000
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  7 omega  125.00  158.00   1.0000    2.0000
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  8 omega   83.00  109.00   1.0000    2.0000
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  9 omega   19.00   46.00   1.0000    2.0000
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 10 omega   18.00   58.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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 11 omega   52.00   78.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       90.5000 -112.0000  120.0000 26

 12 omega   22.00   90.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       90.5000 -112.0000  150.0000 68

 13 omega   56.00  108.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       90.5000   25.0000  -60.0000 52

 14 omega  125.00  166.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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 15 omega   29.00   70.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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 16 omega   17.00   42.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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 17 omega   92.00  141.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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 18 omega   27.00   75.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       90.5000  -46.0000 -108.0000 48

 19 omega  124.00  152.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       90.5000   38.0000   90.0000 28

 20 omega -103.00   -9.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
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 21 omega -105.00    1.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
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 22 omega -103.00   -9.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -      -32.3584  -57.0000 -120.0000 94

 23 omega   35.00  112.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       32.3584  178.0000 -180.0000 77

 24 omega -147.00 -110.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      -75.0000  -77.0000   30.0000 37

 25 omega -147.00  -42.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      -75.0000  -76.0000  166.5838 105

 26 omega -147.00  -42.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      -75.0000  -77.0000   90.0000 105

 27 omega -147.00  -44.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -      -75.0000  -74.0000  -35.0000 103

 28 omega   17.00  132.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       90.5000  -92.0000 -120.0000 115

 29 omega   59.00  164.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       90.5000   38.0000  150.0000 105

 30 omega   17.00  132.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       90.5000  -92.0000   60.0000 115

 31 omega   59.00  163.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       90.5000   74.0000   35.0000 104

 32 omega   64.00  161.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       90.5000   64.0000 -150.0000 97
;
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
(compiled Dec  3 2012,18:21:49)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light yellow'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0430P)^2^+0.2220P] where P=(Fo^2^+2Fc^2^)/3'
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_olex2_refinement_description
;
;
_shelx_res_checksum              12954
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_shelx_shelxl_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'