A cationic tetrahedral Zn(ii) cluster based on a new salicylamide imine multidentate ligand: synthesis, structure and fluorescence sensing study.
Meng, Huan-Huan; Wang, Cai-Yun; Xi, Wei; Song, Xue-Qin; Wang, Li; Dalton transactions (Cambridge, England : 2003) 48 (2019) 12326–12335; doi:10.1039/c9dt01376h

data_7700528
_publ_section_title
;
 A cationic tetrahedral Zn(ii) cluster based on a new salicylamide imine
 multidentate ligand: synthesis, structure and fluorescence sensing study.
;
_journal_issue                   32
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'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               12335
_journal_paper_doi               10.1039/c9dt01376h
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C228 H254 N28 O81 Zn16'
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_symmetry_space_group_name_Hall  '-P 2ac 2ab 3'
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2018-11-26 deposited with the CCDC.    2019-07-12 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.650
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0455P)^2^+6.4617P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0846
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                3062
_reflns_number_total             3636
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt01376h2.cif
_cod_data_source_block           songxq0916_sx
_cod_depositor_comments          'Adding full bibliography for 7700528.cif.'
_cod_original_cell_volume        11530.77(15)
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_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              46546