Regioselective C8-metalation of N-phosphine tethered adenine derivatives via C8-H activation.
Brackemeyer, D.; Schulte To Brinke, C.; Roelfes, F.; Hahn, F. E.; Dalton transactions (Cambridge, England : 2003) 46 (2017) 4510–4513; doi:10.1039/c7dt00682a

data_7042338
_publ_section_title
;
 Regioselective C8-metalation of N-phosphine tethered adenine derivatives
 via C8-H activation.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4510
_journal_page_last               4513
_journal_paper_doi               10.1039/c7dt00682a
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C29 H33 Cl2 Ir N5 P, C H2 Cl2'
_chemical_formula_sum            'C30 H35 Cl4 Ir N5 P'
_chemical_formula_weight         830.60
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2017-03-04 deposited with the CCDC.
2017-03-07 downloaded from the CCDC.
;
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; 
 Multi-scan correction included in APEX2 package (Bruker AXS, 2012)
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0149P)^2^+10.3040P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             8725
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7042336--7042339.cif.'
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