Copper(i), silver(i) and gold(i) complexes of N-heterocyclic carbene-phosphinidene.
Adiraju, Venkata A. K.; Yousufuddin, Muhammed; Rasika Dias, H. V.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 4449–4454; doi:10.1039/c4dt03285c

data_7033140
_publ_section_title
;
 Copper(i), silver(i) and gold(i) complexes of N-heterocyclic
 carbene-phosphinidene.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4449
_journal_page_last               4454
_journal_paper_doi               10.1039/c4dt03285c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C108 H116 Ag8 Cl8 N8 P4, 2(C H2 Cl2)'
_chemical_formula_sum            'C110 H120 Ag8 Cl12 N8 P4'
_chemical_formula_weight         2966.37
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_cell_angle_alpha                90
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_cell_measurement_temperature    100(2)
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_computing_cell_refinement       'Bruker SAINT'
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker D8 Quest'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0413
_diffrn_reflns_av_unetI/netI     0.0308
_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_limit_h_min       -24
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_exptl_absorpt_process_details   SADABS
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_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0564
_refine_ls_R_factor_gt           0.0392
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1212
_refine_ls_wR_factor_ref         0.1380
_reflns_Friedel_coverage         0.000
_reflns_number_gt                13105
_reflns_number_total             16516
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c4dt03285c1.cif
_cod_data_source_block           rad163_0m_a
_cod_depositor_comments
'Adding full bibliography for 7033139--7033142.cif.'
_cod_database_code               7033140
_shelx_estimated_absorpt_t_min   0.618
_shelx_estimated_absorpt_t_max   0.832
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