A porous metal-organic framework with -COOH groups for highly efficient pollutant removal
Qi Zhang; Jiancan Yu; Jianfeng Cai; Ruijing Song; Yuanjing Cui; Yu Yang; Banglin Chen; Guodong Qian; Chem.Commun. 50 (2014) 14455–; doi:10.1039/C4cc06648K

data_7115950
_publ_section_title
;
 A porous metal-organic framework with -COOH groups for highly efficient
 pollutant removal
;
_journal_name_full               Chem.Commun.
_journal_page_first              14455
_journal_paper_doi               10.1039/C4cc06648K
_journal_volume                  50
_journal_year                    2014
_chemical_formula_sum            'C24 H8 Cu2 O14'
_chemical_formula_weight         647.38
_chemical_name_systematic
;
 ?
;
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_space_group_name_Hall           '-R 3 2"'
_space_group_name_H-M_alt        'R -3 m :H'
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
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_cell_measurement_temperature    296(2)
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_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
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_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      296(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_theta_min         1.365
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    0.860
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    0.833
_exptl_crystal_description       block
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_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.26
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1288P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1768
_refine_ls_wR_factor_ref         0.1940
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1954
_reflns_number_total             2800
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c4cc06648k2.cif
_cod_data_source_block           ZJU-24
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_cod_database_code               7115950
_shelxl_version_number           2013-4
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