Renewable Formate from C-H Bond Formation with CO2: Using Iron Carbonyl Clusters as Electrocatalysts.
Loewen, Natalia D.; Neelakantan, Taruna V.; Berben, Louise A.; Accounts of chemical research 50 (2017) 2362–2370; doi:10.1021/acs.accounts.7b00302

data_1547518
_publ_section_title
;
 Renewable Formate from C-H Bond Formation with CO2: Using Iron Carbonyl
 Clusters as Electrocatalysts.
;
_journal_issue                   9
_journal_name_full               'Accounts of chemical research'
_journal_page_first              2362
_journal_page_last               2370
_journal_paper_doi               10.1021/acs.accounts.7b00302
_journal_volume                  50
_journal_year                    2017
_chemical_formula_moiety         'C31 H15 Fe5 N O13 P, Na 2(C6 H14 O3)'
_chemical_formula_sum            'C43 H43 Fe5 N Na O19 P'
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_space_group_name_Hall           '-P 2ybc'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+28.8088P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_file            ar7b00302_si_002.cif
_cod_data_source_block           NL43FMI
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Numerical' changed to
'numerical' according to
/home/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 
;
_cod_original_cell_volume        5062.2(14)
_cod_database_code               1547518
_shelx_shelxl_version_number     2016/6
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_shelx_res_checksum              25084
_shelx_hkl_checksum              65691