New palladium(II) β-ketoesterates for focused electron beam induced deposition: synthesis, structures, and characterization.
Butrymowicz-Kubiak, A; Muzioł, T M; Kaczmarek-Kędziera, A; Jureddy, C. S.; Maćkosz, K; Utke, I.; Szymańska, I B; Dalton transactions (Cambridge, England : 2003) 53 (2024) 13662–13677; doi:10.1039/d4dt01287a

data_7716792
_publ_section_title
;
 New palladium(II) &#x3b2;-ketoesterates for focused electron beam induced
 deposition: synthesis, structures, and characterization.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13662
_journal_page_last               13677
_journal_paper_doi               10.1039/d4dt01287a
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         '(Pd 2+), (C7 H11 O3 1-)2'
_chemical_formula_sum            'C14 H22 O6 Pd'
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_audit_update_record
;
2024-02-26 deposited with the CCDC.	2024-07-12 downloaded from the CCDC.
;
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.89a (Rigaku Oxford Diffraction, 2023)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
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_exptl_crystal_description       needle
_exptl_crystal_F_000             400
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_exptl_crystal_size_mid          0.040
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_refine_ls_R_factor_all          0.0384
_refine_ls_R_factor_gt           0.0346
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0641P)^2^+0.1273P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0948
_refine_ls_wR_factor_ref         0.0981
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1404
_reflns_number_total             1605
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4dt01287a3.cif
_cod_data_source_block           nab22-3Dshape
_cod_depositor_comments
'Adding full bibliography for 7716790--7716792.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7716792
_shelx_shelxl_version_number     2018/1
_shelx_estimated_absorpt_t_min   0.370
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_shelx_res_checksum              87162