GeII-H/SiIV-H dehydrocoupling and cycloaddition chemistry of a Ni0 bis(hydridogermylene) complex
Hadlington, Terrance John; Schubert, Emeric; Chemical Communications  (2026) –; doi:10.1039/D6CC00444J

data_7135746
_publ_section_title
;
 Ge<sup>II</sup>-H/Si<sup>IV</sup>-H dehydrocoupling and cycloaddition
 chemistry of a Ni<sup>0</sup> bis(hydridogermylene) complex.
;
_journal_issue                   36
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              9272
_journal_page_last               9276
_journal_paper_doi               10.1039/d6cc00444j
_journal_volume                  62
_journal_year                    2026
_chemical_formula_moiety         'C62 H88 Ge2 N2 Ni P2 Si2'
_chemical_formula_sum            'C62 H88 Ge2 N2 Ni P2 Si2'
_chemical_formula_weight         1183.35
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2025-05-21 deposited with the CCDC.	2026-04-17 downloaded from the CCDC.
;
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_diffrn_reflns_point_group_measured_fraction_full 0.994
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_diffrn_reflns_theta_max         26.000
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_diffrn_source                   'Genix 3D HF Mo'
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_exptl_absorpt_process_details   'STOE X-AREA 1.76'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0458P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0862
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d6cc00444j2.cif
_cod_data_source_block           4
_cod_depositor_comments
'Adding full bibliography for 7135746--7135748.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7135746
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              28904
_shelx_hkl_checksum              10815