Interplay of anthracene luminescence and dysprosium magnetism by steric control of photodimerization.
Huang, Xin-Da; Jia, Jia-Ge; Kurmoo, Mohamedally; Bao, Song-Song; Zheng, Li-Min; Dalton transactions (Cambridge, England : 2003) 48 (2019) 13769–13779; doi:10.1039/c9dt02854d

data_7700861
_publ_section_title
;
 Interplay of anthracene luminescence and dysprosium magnetism by steric
 control of photodimerization.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13769
_journal_page_last               13779
_journal_paper_doi               10.1039/c9dt02854d
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C30 H47 Dy N3 O18 P3'
_chemical_formula_sum            'C30 H47 Dy N3 O18 P3'
_chemical_formula_weight         993.11
_chemical_name_systematic        3
_chemical_properties_physical    Photo-sensitive
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2019-07-05 deposited with the CCDC.    2019-08-16 downloaded from the CCDC.
;
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_cell_measurement_temperature    193(2)
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_cell_volume                     2117.9(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
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_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_diffrn_ambient_temperature      193(2)
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_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker APEX duo'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0257
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_diffrn_reflns_Laue_measured_fraction_full 0.983
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_diffrn_reflns_limit_l_max       23
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_diffrn_reflns_point_group_measured_fraction_full 0.983
_diffrn_reflns_point_group_measured_fraction_max 0.980
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_exptl_absorpt_coefficient_mu    1.950
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_exptl_absorpt_correction_T_min  0.408
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2014/5'
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_exptl_crystal_description       block
_exptl_crystal_F_000             1006
_exptl_crystal_preparation       'Magnetic properties,Luminescent'
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: Tetrahydrofuran'
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_refine_ls_extinction_method     none
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_refine_ls_restrained_S_all      1.133
_refine_ls_R_factor_all          0.0327
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_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0369P)^2^+0.8248P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0706
_refine_ls_wR_factor_ref         0.0729
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8675
_reflns_number_total             9519
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt02854d2.cif
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_cod_depositor_comments
'Adding full bibliography for 7700858--7700861.cif.'
_cod_database_code               7700861
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_shelx_estimated_absorpt_t_min   0.442
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_shelx_res_checksum              55099