A series of Rb<sub>4</sub>Ln<sub>2</sub>(P<sub>2</sub>S<sub>6</sub>)(PS<sub>4</sub>)<sub>2</sub> (Ln = La, Ce, Pr, Nd, Sm, Gd) rare earth thiophosphates with two distinct thiophosphate units [P<sup>V</sup>S<sub>4</sub>]<sup>3-</sup> and [P<sup>IV</sup><sub>2</sub>S<sub>6</sub>]<sup>4</sup>.
Kutahyali Aslani, Ceren; Breton, Logan S.; Klepov, Vladislav V.; Zur Loye, Hans-Conrad; Dalton transactions (Cambridge, England : 2003) 50 (2021) 1683–1689; doi:10.1039/d0dt03718d

data_7706354
_publ_section_title
;
 A series of
 Rb<sub>4</sub>Ln<sub>2</sub>(P<sub>2</sub>S<sub>6</sub>)(PS<sub>4</sub>)<sub>2</sub>
 (Ln = La, Ce, Pr, Nd, Sm, Gd) rare earth thiophosphates with two distinct
 thiophosphate units [P<sup>V</sup>S<sub>4</sub>]<sup>3-</sup> and
 [P<sup>IV</sup><sub>2</sub>S<sub>6</sub>]<sup>4</sup>.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1683
_journal_page_last               1689
_journal_paper_doi               10.1039/d0dt03718d
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'Nd2 P4 Rb4 S14'
_chemical_formula_weight         1203.08
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_audit_creation_method           SHELXL-2018/1
_audit_update_record
;
2020-10-26 deposited with the CCDC.	2021-01-05 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 122.0390(7)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   22.9712(5)
_cell_length_b                   6.82480(10)
_cell_length_c                   18.8874(4)
_cell_measurement_reflns_used    9772
_cell_measurement_temperature    300(2)
_cell_measurement_theta_max      36.30
_cell_measurement_theta_min      3.20
_cell_volume                     2510.04(9)
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_diffrn_ambient_temperature      300(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0298
_diffrn_reflns_av_unetI/netI     0.0142
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            48114
_diffrn_reflns_point_group_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.499
_diffrn_reflns_theta_min         3.163
_exptl_absorpt_coefficient_mu    13.209
_exptl_absorpt_correction_T_max  0.3874
_exptl_absorpt_correction_T_min  0.2686
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 Reference: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10.
;
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    3.184
_exptl_crystal_description       block
_exptl_crystal_F_000             2208
_exptl_crystal_size_max          0.110
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.040
_refine_diff_density_max         2.816
_refine_diff_density_min         -1.408
_refine_diff_density_rms         0.129
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     109
_refine_ls_number_reflns         2859
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0214
_refine_ls_R_factor_gt           0.0211
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0263P)^2^+20.2729P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0555
_refine_ls_wR_factor_ref         0.0558
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2812
_reflns_number_total             2859
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt03718d2.cif
_cod_data_source_block           Nd
_cod_depositor_comments
'Adding full bibliography for 7706350--7706355.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7706354
_shelx_shelxl_version_number     2018/1
_shelx_estimated_absorpt_t_min   0.324
_shelx_estimated_absorpt_t_max   0.620
_shelx_res_checksum              56793