Palladium-catalyzed selective B(3)-H arylation of o-carboranes with arylboronic acids at room temperature.
Yang, Ziyi; Wu, Yuanbo; Fu, Yatong; Yang, Jianxin; Lu, Jian; Lu, Ju-You; Chemical communications (Cambridge, England) 57 (2021) 1655–1658; doi:10.1039/d0cc07591d

data_7127821
_publ_section_title
;
 Palladium-catalyzed selective B(3)-H arylation of o-carboranes with
 arylboronic acids at room temperature.
;
_journal_issue                   13
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              1655
_journal_page_last               1658
_journal_paper_doi               10.1039/d0cc07591d
_journal_volume                  57
_journal_year                    2021
_chemical_formula_sum            'C13 H19 B10 N'
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_audit_update_record
;
2020-09-11 deposited with the CCDC.	2021-01-11 downloaded from the CCDC.
;
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_diffrn_ambient_environment      N~2~
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_diffrn_measured_fraction_theta_full 0.999
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_diffrn_radiation_monochromator  graphite
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.29a (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
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_refine_ls_R_factor_all          0.0774
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0686P)^2^+1.2630P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1578
_refine_ls_wR_factor_ref         0.1673
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2989
_reflns_number_total             3782
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0cc07591d2.cif
_cod_data_source_block           3
_cod_depositor_comments
'Adding full bibliography for 7127821--7127822.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7127821
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              50495