A new spodium bond driven coordination polymer constructed from mercury(ii) azide and 1,2-bis(pyridin-2-ylmethylene)hydrazine
Mahmoudi, Ghodrat; Lawrence, Simon E.; Cisterna, Jonathan; Cárdenas, Alejandro; Brito, Iván; Frontera, Antonio; Safin, Damir A.; New Journal of Chemistry 44 (2020) 21100–21107; doi:10.1039/D0NJ04444J

data_7060126
_publ_section_title
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 A new spodium bond driven coordination polymer constructed from
 mercury(ii) azide and 1,2-bis(pyridin-2-ylmethylene)hydrazine
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_journal_issue                   48
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              21100
_journal_page_last               21107
_journal_paper_doi               10.1039/D0NJ04444J
_journal_volume                  44
_journal_year                    2020
_chemical_formula_moiety         'C12 H10 Hg2 N16'
_chemical_formula_sum            'C12 H10 Hg2 N16'
_chemical_formula_weight         779.54
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
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2020-11-09 deposited with the CCDC.	2020-11-18 downloaded from the CCDC.
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_diffrn_ambient_temperature      300(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_theta_min         2.989
_exptl_absorpt_coefficient_mu    15.308
_exptl_absorpt_correction_T_max  0.7453
_exptl_absorpt_correction_T_min  0.2465
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2008/1 (Bruker AXS)'
_exptl_crystal_colour            orange
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_exptl_crystal_description       needle
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         1871
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0723
_refine_ls_R_factor_gt           0.0596
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1074P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1556
_refine_ls_wR_factor_ref         0.1651
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1545
_reflns_number_total             1871
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0nj04444j1.cif
_cod_data_source_block           shelx
_cod_depositor_comments          'Adding full bibliography for 7060126.cif.'
_cod_original_cell_volume        502.08(19)
_cod_database_code               7060126
_publcif_datablock.id            {e2845047-39b7-49d2-85db-697ca874eb51}
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              92211
_publcif_funding_html
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