A one-pot diastereoselective self assembly of C-stereogenic copper(i) diphosphine clusters.
Yang, Xiang-Yuan; Li, Yongxin; Pullarkat, Sumod A.; Inorganic chemistry 53 (2014) 10232–10239; doi:10.1021/ic501233w

data_4341117
_publ_section_title
;
 A one-pot diastereoselective self assembly of C-stereogenic copper(i)
 diphosphine clusters.
;
_journal_issue                   19
_journal_name_full               'Inorganic chemistry'
_journal_page_first              10232
_journal_page_last               10239
_journal_paper_doi               10.1021/ic501233w
_journal_volume                  53
_journal_year                    2014
_chemical_absolute_configuration ad
_chemical_formula_sum            'C144.62 H115.25 Cl7.25 Cu6 F6 O6 P6'
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;
Flack x determined using 9608 quotients [(I+)-(I-)]/[(I+)+(I-)]
(Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   0.050(5)
_refine_ls_extinction_method     none
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_refine_ls_number_reflns         38828
_refine_ls_number_restraints     14440
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1437P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 4341116--4341121.cif.'
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