Poly[[μ~2~-1,2-bis(diphenylphosphanyl)-1,2-diethylhydrazine]-μ~4~-nitrato-μ~2~-nitrato-silver(I)]
Kriel, Frederik H.; Fernandes, Manuel A.; Coates, Judy; Acta Crystallographica Section E 66 (2010) m710–; doi:10.1107/S1600536810019094

data_2226112
_publ_section_title
;
 Poly[[\m~2~-1,2-bis(diphenylphosphanyl)-1,2-diethylhydrazine]-\m~4~-nitrato-\m~2~-nitrato-silver(I)]
;
_journal_coeditor_code           FK2018
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m710
_journal_paper_doi               10.1107/S1600536810019094
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Ag2 (N O3)2 (C28 H30 N2 P2)]'
_chemical_formula_moiety         'C28 H30 Ag2 N4 O6 P2'
_chemical_formula_sum            'C28 H30 Ag2 N4 O6 P2'
_chemical_formula_weight         796.24
_chemical_name_systematic
Poly[[\m-1,2-bis(diphenylphosphanyl)-1,2-diethylhydrazine]-\m~4~-nitrato-\m~2~-disilver(I)]
_space_group_IT_number           33
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2c -2n'
_symmetry_space_group_name_H-M   'P n a 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.3320(10)
_cell_length_b                   20.6486(13)
_cell_length_c                   9.0164(5)
_cell_measurement_reflns_used    3919
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      26.52
_cell_measurement_theta_min      2.33
_cell_volume                     3040.6(3)
_computing_cell_refinement       'SAINT-Plus (Bruker, 1999)'
_computing_data_collection       'SMART-NT (Bruker, 1998)'
_computing_data_reduction        'SAINT-Plus (Bruker, 1999)'
_computing_molecular_graphics
;
ORTEP-3 (Farrugia, 1997) and Mercury (Macrae <i>et al.</i>,
2008)
;
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0508
_diffrn_reflns_av_sigmaI/netI    0.0872
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            13103
_diffrn_reflns_theta_full        30.48
_diffrn_reflns_theta_max         30.48
_diffrn_reflns_theta_min         1.59
_exptl_absorpt_coefficient_mu    1.441
_exptl_absorpt_correction_T_max  0.9069
_exptl_absorpt_correction_T_min  0.7877
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details   '(SADABS; Bruker, 1999)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.739
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1592
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_refine_diff_density_max         0.583
_refine_diff_density_min         -0.734
_refine_ls_abs_structure_details 'Flack (1983), 3898 Friedel pairs'
_refine_ls_abs_structure_Flack   0.53(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     380
_refine_ls_number_reflns         8801
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.0818
_refine_ls_R_factor_gt           0.0464
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0891P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1116
_refine_ls_wR_factor_ref         0.1607
_reflns_number_gt                6217
_reflns_number_total             8801
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            fk2018.cif
_cod_data_source_block           I
_cod_database_code               2226112
_cod_database_fobs_code          2226112