Imino-stabilised phosphinidene (or azaphosphole?) and some of its derivatives.
Nguyen, Minh Tho; Gabidullin, Bulat; Nikonov, Georgii I.; Dalton transactions (Cambridge, England : 2003) 47 (2018) 17011–17019; doi:10.1039/c8dt03465f

data_7048036
_publ_section_title
;
 Imino-stabilised phosphinidene (or azaphosphole?) and some of its
 derivatives.
;
_journal_issue                   47
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              17011
_journal_page_last               17019
_journal_paper_doi               10.1039/c8dt03465f
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C32 H41 N2 P'
_chemical_formula_weight         484.64
_chemical_properties_physical    Air-sensitive
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_space_group_name_Hall           'C -2yc'
_space_group_name_H-M_alt        'C 1 c 1'
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2018-11-08 deposited with the CCDC.
2018-11-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_computing_cell_refinement       'APEX II (Bruker, 2009)'
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_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_description       plate
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.27(19)
_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0850P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                3587
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_cod_depositor_comments
'Adding full bibliography for 7048036--7048038.cif.'
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