Di-μ-chlorobis[hydrogen bis(diphenylphosphinito)(1–)-<i>P</i>,<i>P</i>']dipalladium, [Pd~2~Cl~2~{(C~6~H~5~)~2~PO^{···^}H^{···^}OP(C~6~H~5~)~2~}~2~]
Ghaffar, T.; Kieszkiewicz, A.; Nyburg, S.C.; Parkins, A.W.; Acta Crystallographica Section C 50 (1994) 697–700; doi:10.1107/S010827019301162X

data_2009720
_publ_section_title
;Di-\m-chlorobis[hydrogen
 bis(diphenylphosphinito)(1--)-<i>P</i>,<i>P</i>']dipalladium,
 [Pd~2~Cl~2~{(C~6~H~5~)~2~PO^{&#x00B7;&#x00B7;&#x00B7;^}H^{&#x00B7;&#x00B7;&#x00B7;^}OP(C~6~H~5~)~2~}~2~]
;
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              697
_journal_page_last               700
_journal_paper_doi               10.1107/S010827019301162X
_journal_volume                  50
_journal_year                    1994
_chemical_formula_sum            'C48 H42 Cl2 O4 P4 Pd2'
_chemical_formula_weight         1090.45
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_type_scat_source
'NRCVAX (Gabe, Le Page, Charland, Lee & White, 1989)'
_cell_angle_alpha                100.79(8)
_cell_angle_beta                 100.88(8)
_cell_angle_gamma                116.60(8)
_cell_formula_units_Z            2
_cell_length_a                   11.920(12)
_cell_length_b                   13.299(13)
_cell_length_c                   17.407(13)
_cell_measurement_reflns_used    16
_cell_measurement_temperature    298
_cell_measurement_theta_max      25
_cell_measurement_theta_min      22.5
_cell_volume                     2304(5)
_diffrn_measurement_device       Picker
_diffrn_measurement_method       \q/2\q
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            6033
_diffrn_reflns_theta_max         22.5
_diffrn_standards_decay_%        0.50
_diffrn_standards_interval_count 100
_diffrn_standards_number         1
_exptl_absorpt_coefficient_mu    1.06
_exptl_absorpt_correction_T_max  0.891
_exptl_absorpt_correction_T_min  0.703
_exptl_absorpt_correction_type   integration
_exptl_crystal_colour            'Pale yellow'
_exptl_crystal_density_diffrn    1.572
_exptl_crystal_description       Needles
_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.13
_refine_diff_density_min         -0.77
_refine_ls_goodness_of_fit_obs   2.23
_refine_ls_hydrogen_treatment    'H atom parameters refined for H1 and H2'
_refine_ls_number_parameters     117
_refine_ls_number_reflns         4849
_refine_ls_R_factor_obs          0.047
_refine_ls_shift/esd_max         0.14
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     w=1/\s^2^(F~o~)
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_obs         0.048
_reflns_number_observed          4849
_reflns_number_total             6033
_reflns_observed_criterion       I>2.5\s(I)
_cod_data_source_file            mu1069.cif
_cod_data_source_block           mu1069_structure_1_of_1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'w=1/\s^2^(F~o~)' was changed to
'calc'. New tag '_refine_ls_weighting_details' was created. The value
of the new tag was set to 'w=1/\s^2^(F~o~)'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2304(3)
_cod_database_code               2009720