Noble Metals in Polyoxometalate Chemistry: Palladium-Containing Derivatives of the Monolacunary Keggin and Wells-Dawson Tungstophosphates
Natalya V. Izarova; Abhishek Banerjee; Ulrich Kortz; Inorganic Chemistry 50 (2011) 10379–10386; doi:10.1021/ic201451x

data_4326552
_publ_contact_author_address
;Jacobs University
School of Engineering and Science
P.O. Box 750 561
28725 Bremen
Germany
;
_publ_contact_author_email       u.kortz@jacobs-university.de
_publ_contact_author_fax         '+49-421-200 3229'
_publ_contact_author_name        'Ulrich Kortz'
_publ_contact_author_phone       '+49-421-200 3235'
_publ_section_title
;
 Noble Metals in Polyoxometalate Chemistry: Palladium-Containing
 Derivatives of the Monolacunary Keggin and Wells-Dawson Tungstophosphates
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              10379
_journal_page_last               10386
_journal_paper_doi               10.1021/ic201451x
_journal_volume                  50
_journal_year                    2011
_chemical_formula_sum            'H41 K10 O157 P4 Pd2 W34'
_chemical_formula_weight         9531.91
_chemical_name_systematic
; 
 ? 
;
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_cell_angle_gamma                92.883(6)
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_cell_length_b                   21.595(2)
_cell_length_c                   26.390(3)
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_cell_measurement_theta_max      22.26
_cell_measurement_theta_min      3.09
_cell_volume                     7780.9(14)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       24
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_diffrn_reflns_limit_l_min       -29
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_diffrn_reflns_theta_full        23.41
_diffrn_reflns_theta_max         23.41
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_exptl_absorpt_correction_T_max  0.2667
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
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_exptl_crystal_density_diffrn    4.068
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_refine_diff_density_rms         0.725
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_refine_ls_number_reflns         22567
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1380P)^2^+1180.5690P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.2870
_reflns_number_gt                14569
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic201451x_si_002_4.cif
_cod_data_source_block           K-3
_cod_original_cell_volume        7781.2(14)
_cod_database_code               4326552