Blue luminescent zinc(II) complexes with polypyridylamine ligands: crystal structures and luminescence properties
Ho, Kin-Ying; Yu, Wing-Yiu; Cheung, Kung-Kai; Che, Chi-Ming; Journal of the Chemical Society, Dalton Transactions  (1999) 1581–; doi:10.1039/a900504h

data_7027268
_publ_contact_author
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    ENTER NAME
 ENTER ADDRESS
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_publ_section_title
;
 Blue luminescent zinc(II) complexes with polypyridylamine ligands:
 crystal structures and luminescence properties
;
_journal_issue                   10
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1581
_journal_paper_doi               10.1039/a900504h
_journal_year                    1999
_chemical_formula_sum            'C22 H18 F6 N6 O6 S2 Zn'
_chemical_formula_weight         705.91
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_creation_date             'Fri Jan 15 10:29:26 1999'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 103.05(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   16.393(3)
_cell_length_b                   8.897(2)
_cell_length_c                   19.610(3)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    301.2
_cell_measurement_theta_max      0.0
_cell_measurement_theta_min      0.0
_cell_volume                     2786.2(9)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    SIR92
_diffrn_ambient_temperature      301.2
_diffrn_measurement_device       'MAR IPDS'
_diffrn_measurement_method       'omega scans with profile analysis'
_diffrn_orient_matrix_UB_11      0.00000
_diffrn_orient_matrix_UB_12      0.00000
_diffrn_orient_matrix_UB_13      0.00000
_diffrn_orient_matrix_UB_21      0.00000
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_diffrn_orient_matrix_UB_31      0.00000
_diffrn_orient_matrix_UB_32      0.00000
_diffrn_orient_matrix_UB_33      0.00000
_diffrn_radiation_detector       IPDS
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.00
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       0
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_diffrn_reflns_limit_l_max       20
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_diffrn_standards_decay_%        0.00
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_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.121
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourlessprism
_exptl_crystal_density_diffrn    1.683
_exptl_crystal_density_meas      0.000
_exptl_crystal_description       prism
_exptl_crystal_F_000             1424.00
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_refine_ls_weighting_scheme      sigma
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_reflns_number_observed          2097
_reflns_number_total             2573
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_cod_data_source_file            900504hsup1.cif
_cod_data_source_block           (Cpd_2)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C22 H18 F6 N6 O6 S2 Zn '
_cod_database_code               7027268