Bis[μ-<i>N</i>-(pyridin-2-ylmethyl)pyridin-2-amine-κ^2^<i>N</i>:<i>N</i>']disilver(I) bis(trifluoromethanesulfonate)
Moon, Suk-Hee; Kim, Tae Ho; Park, Ki-Min; Acta Crystallographica Section E 67 (2011) m1769–m1770; doi:10.1107/S1600536811047908

data_2232991
_publ_section_title
;
 Bis[\m-<i>N</i>-(pyridin-2-ylmethyl)pyridin-2-amine-\k^2^<i>N</i>:<i>N</i>']disilver(I)
 bis(trifluoromethanesulfonate)
;
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1769
_journal_page_last               m1770
_journal_paper_doi               10.1107/S1600536811047908
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Ag2 (C11 H11 N3)2] (C F3 O3 S)2'
_chemical_formula_moiety         'C22 H22 Ag2 N6, 2(C F3 O3 S)'
_chemical_formula_sum            'C24 H22 Ag2 F6 N6 O6 S2'
_chemical_formula_weight         884.34
_chemical_name_systematic
;
Bis[\m-<i>N</i>-(pyridin-2-ylmethyl)pyridin-2-amine-
\k^2^<i>N</i>:<i>N</i>']disilver(I) bis(trifluoromethanesulfonate)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                108.4890(10)
_cell_angle_beta                 92.8260(10)
_cell_angle_gamma                116.6060(10)
_cell_formula_units_Z            1
_cell_length_a                   8.4105(5)
_cell_length_b                   9.3500(6)
_cell_length_c                   11.1693(7)
_cell_measurement_reflns_used    3938
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.26
_cell_measurement_theta_min      2.74
_cell_volume                     725.58(8)
_computing_cell_refinement       'SAINT (Bruker, 2006)'
_computing_data_collection       'APEX2 (Bruker, 2006)'
_computing_data_reduction        'SAINT (Bruker, 2006)'
_computing_molecular_graphics
'SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg, 1998)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0120
_diffrn_reflns_av_sigmaI/netI    0.0202
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            4132
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.97
_exptl_absorpt_coefficient_mu    1.584
_exptl_absorpt_correction_T_max  0.6928
_exptl_absorpt_correction_T_min  0.6070
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.024
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             436
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.523
_refine_diff_density_min         -0.580
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     208
_refine_ls_number_reflns         2791
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.072
_refine_ls_R_factor_all          0.0232
_refine_ls_R_factor_gt           0.0220
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0304P)^2^+0.5885P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0577
_refine_ls_wR_factor_ref         0.0584
_reflns_number_gt                2665
_reflns_number_total             2791
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            wm2556.cif
_cod_data_source_block           I
_cod_database_code               2232991
_cod_database_fobs_code          2232991