Silver Coordination Chemistry of a New Versatile "Janus"-type N2,O2-Bichelating Donor, Formation of an Unprecedented Supramolecular Network of Binuclear Silver Building Blocks Containing a Five-Coordinate β-Diketonate, and Isolation of Unexpected Silver-Tin-Silver Heterotrimetallic Complexes from Silver Metathesis Reactions
Augusto Cingolani; E. Effendy; Fabio Marchetti; Claudio Pettinari; Riccardo Pettinari; Brian W. Skelton; Allan H. White; Inorganic Chemistry 43 (2004) 4387–4399; doi:10.1021/ic0497376

data_4311257
_publ_contact_author_address
;
   Department of Chemistry
   University of Western Australia
   35 Stirling Highway
   Crawley
   Western Australia 6009
   Australia
;
_publ_contact_author_email       bws@crystal.uwa.edu.au
_publ_contact_author_fax         (+61)_08_9380_1118
_publ_contact_author_name        'Skelton, B. W.'
_publ_contact_author_phone       (+61)_08-9380_3481
_publ_section_title
;
 Silver Coordination Chemistry of a New Versatile "Janus"-type
 N2,O2-Bichelating Donor, Formation of an Unprecedented Supramolecular
 Network of Binuclear Silver Building Blocks Containing a Five-Coordinate
 \b-Diketonate, and Isolation of Unexpected Silver-Tin-Silver
 Heterotrimetallic Complexes from Silver Metathesis Reactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4387
_journal_page_last               4399
_journal_paper_doi               10.1021/ic0497376
_journal_volume                  43
_journal_year                    2004
_chemical_formula_moiety         'C76 H69 Ag2 Cl5 P4 Sn1'
_chemical_formula_sum            'C76 H69 Ag2 Cl5 P4 Sn'
_chemical_formula_weight         1618.01
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             03-12-04
_audit_creation_method           Xtal3.6
_cell_angle_alpha                67.144(2)
_cell_angle_beta                 81.879(2)
_cell_angle_gamma                74.320(2)
_cell_formula_units_Z            1
_cell_length_a                   10.2625(8)
_cell_length_b                   12.9580(10)
_cell_length_c                   14.4820(10)
_cell_measurement_reflns_used    6591
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      37.35
_cell_measurement_theta_min      2.37
_cell_volume                     1707.2(2)
_computing_cell_refinement       'Siemens SAINT (Siemens, 1995)'
_computing_data_collection       'Siemens SMART (Siemens, 1995)'
_computing_data_reduction        'Siemens SAINT'
_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  'xtal CRYLSQ'
_computing_structure_solution    xtal
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1.0
_diffrn_measured_fraction_theta_max .97
_diffrn_measurement_device_type
;
Bruker SMART CCD diffractometer
;
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_detector       'CCD area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .024
_diffrn_reflns_av_sigmaI/netI    .071
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            33994
_diffrn_reflns_theta_full        37.0
_diffrn_reflns_theta_max         37.55
_diffrn_reflns_theta_min         1.53
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.264
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  .83
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS; Sheldrick, 1996
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.574
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rhomb
_exptl_crystal_F_000             814
_exptl_crystal_size_max          .39
_exptl_crystal_size_mid          .28
_exptl_crystal_size_min          .17
_refine_diff_density_max         1.87
_refine_diff_density_min         -.884
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.014
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           atomblock
_refine_ls_number_constraints    0
_refine_ls_number_parameters     530
_refine_ls_number_reflns         13099
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .057
_refine_ls_R_factor_gt           .037
_refine_ls_shift/su_max          .014
_refine_ls_shift/su_mean         .001
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         .051
_refine_ls_wR_factor_ref         .047
_reflns_d_resolution_high        .583
_reflns_d_resolution_low         13.298
_reflns_Friedel_coverage         0
_reflns_limit_h_max              17
_reflns_limit_h_min              0
_reflns_limit_k_max              22
_reflns_limit_k_min              -21
_reflns_limit_l_max              24
_reflns_limit_l_min              -24
_reflns_number_gt                13099
_reflns_number_total             17429
_reflns_threshold_expression     'F    > 4.00 sig(F   )'
_cod_data_source_file            ic0497376si20040415_034835.cif
_cod_data_source_block           agqpsn
_cod_original_sg_symbol_Hall     -p_1
_cod_original_formula_sum        'C76 H69 Ag2 Cl5 P4 Sn1'
_cod_database_code               4311257