Copper-Catalyzed Electrochemical Selective B-H Oxygenation of <i>o</i>-Carboranes at Room Temperature.
Au, Yik Ki; Lyu, Hairong; Quan, Yangjian; Xie, Zuowei; Journal of the American Chemical Society  (2020) –; doi:10.1021/jacs.0c02490

data_4134628
_publ_section_title
;
 Copper-Catalyzed Electrochemical Selective B-H Oxygenation of
 <i>o</i>-Carboranes at Room Temperature.
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_paper_doi               10.1021/jacs.0c02490
_journal_year                    2020
_chemical_formula_sum            'C12 H24 B10 O'
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_space_group_crystal_system      monoclinic
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_audit_creation_method           SHELXL-2018/3
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_cell_angle_gamma                90
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_cell_length_c                   19.748(3)
_cell_measurement_reflns_used    719
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      15
_cell_measurement_theta_min      15
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_computing_cell_refinement       'BRUKER D8VENTURE DIFFRACTOMETER'
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_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'BRUKER D8VENTURE DIFFRACTOMETER'
_diffrn_measurement_method       'PHI & OMEGA SCAN'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0157
_diffrn_reflns_Laue_measured_fraction_full 0.998
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0907P)^2^+1.0694P] where P=(Fo^2^+2Fc^2^)/3'
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_shelx_res_checksum              13571
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