Supramolecular hydrogen-bonded networks formed from copper(II) carboxylate dimers.
Abrahams, Brendan F.; Commons, Christopher J.; Hudson, Timothy A.; Sanchez-Arlt, Robin; Acta crystallographica. Section C, Structural chemistry 80 (2024) –; doi:10.1107/S2053229624004534

data_2312515
_publ_section_title
;
 Supramolecular hydrogen-bonded networks formed from copper(II)
 carboxylate dimers.
;
_journal_coeditor_code           JX3083
_journal_issue                   6
_journal_name_full
'Acta crystallographica. Section C, Structural chemistry'
_journal_paper_doi               10.1107/S2053229624004534
_journal_volume                  80
_journal_year                    2024
_chemical_formula_iupac
'(C14 H19 N2)2 [Cu2 (C7 H5 O3)2 (C7 H4 O3)2 (H2 O1)2], 3(C4 H8 O2), H2 O1'
_chemical_formula_moiety
'2(C14 H19 N2 +), C28 H22 Cu2 O14 2-, 3(C4 H8 O2), H2 O1'
_chemical_formula_sum            'C68 H84 Cu2 N4 O21'
_chemical_formula_weight         1420.47
_chemical_name_systematic
;
Bis[8-(dimethylamino)-<i>N</i>,<i>N</i>-dimethylnaphthalen-1-aminium]
bis(\m-4-hydroxybenzoato)bis(\m-4-oxidobenzoato)bis[aquacopper(II)]
dioxane trisolvate monohydrate
;
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
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;
CrysAlis PRO (Rigaku OD, 2021)
;
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CrysAlis PRO (Rigaku OD, 2021)
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CrysAlis PRO (Rigaku OD, 2021)
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OLEX2 (Dolomanov <i>et al.</i>, 2009)
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OLEX2 (Dolomanov <i>et al.</i>, 2009)
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SHELXL2018 (Sheldrick, 2015<i>b</i>)
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SHELXT2018 (Sheldrick, 2015<i>a</i>)
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_diffrn_ambient_temperature      100.01(10)
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_diffrn_measurement_device       'four-circle diffractometer'
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'Rigaku XtaLAB Synergy Dualflex diffractometer with a HyPix detector'
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;
(CrysAlis PRO; Rigaku OD, 2021)
;
_exptl_crystal_colour            'dark green'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1040P)^2^+1.3001P] where P=(Fo^2^+2Fc^2^)/3'
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