Observation of the single-ion magnet behavior of d8ions on two-coordinate Co(i)‒NHC complexes
Meng, Yin-Shan; Mo, Zhenbo; Wang, Bing-Wu; Zhang, Yi-Quan; Deng, Liang; Gao, Song; Chem. Sci. 6 (2015) 7156–; doi:10.1039/C5SC02611C

data_1530692
_publ_section_title
;
 Observation of the single-ion magnet behavior of d8ions on two-coordinate
 Co(i)--NHC complexes
;
_journal_issue                   12
_journal_name_full               'Chem. Sci.'
_journal_page_first              7156
_journal_paper_doi               10.1039/C5SC02611C
_journal_volume                  6
_journal_year                    2015
_chemical_formula_sum            'C66 H72 B Co N4'
_chemical_formula_weight         991.01
_chemical_name_systematic        '[Co(sMes)2][BPh4]'
_chemical_properties_physical
'Air-sensitive, Moisture-sensitive, Hygroscopic, Oxygen-sensitive'
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
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_audit_update_record
;
2015-04-07 deposited with the CCDC.
2015-09-10 downloaded from the CCDC.
;
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'Re-crystallisation from solvent: THF/toluene'
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'w=1/[\s^2^(Fo^2^)+(0.0916P)^2^+0.8800P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 1530691--1530693.cif.'
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