Bis(μ-nitrato-κ^2^<i>O</i>:<i>O</i>)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-<i>closo</i>-dodecaborane-κ^2^<i>P</i>,<i>P</i>']silver(I)} dichloromethane disolvate
Yang, Liguo; Acta Crystallographica Section E 70 (2014) m141–; doi:10.1107/S1600536814006084

data_2239221
_publ_section_title
;
 Bis(\m-nitrato-\k^2^<i>O</i>:<i>O</i>)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-<i>closo</i>-dodecaborane-\k^2^<i>P</i>,<i>P</i>']silver(I)}
 dichloromethane disolvate
;
_journal_coeditor_code           RZ5111
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m141
_journal_paper_doi               10.1107/S1600536814006084
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac          '[Ag2 (N O3)2 (C14 H38 B10 P2)2], 2C H2 Cl2'
_chemical_formula_moiety         'C28 H76 Ag2 B20 N2 O6 P4, 2(C H2 Cl2)'
_chemical_formula_sum            'C30 H80 Ag2 B20 Cl4 N2 O6 P4'
_chemical_formula_weight         1262.58
_chemical_name_systematic
;Bis(\m-nitrato-\k^2^<i>O</i>:<i>O</i>)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-<i>closo</i>-dodecaborane-\k^2^<i>P</i>,<i>P</i>']silver(I)}
dichloromethane disolvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.734(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.9256(15)
_cell_length_b                   10.3003(10)
_cell_length_c                   21.8075(19)
_cell_measurement_reflns_used    5416
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.3915
_cell_measurement_theta_min      2.5035
_cell_volume                     2979.4(5)
_computing_cell_refinement       'SAINT (Siemens, 1996)'
_computing_data_collection       'SMART (Siemens, 1996)'
_computing_data_reduction        'SAINT (Siemens, 1996)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART1000 CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0270
_diffrn_reflns_av_sigmaI/netI    0.0322
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            14624
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.55
_exptl_absorpt_coefficient_mu    0.982
_exptl_absorpt_correction_T_max  0.7505
_exptl_absorpt_correction_T_min  0.6774
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.407
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1288
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.36
_exptl_crystal_size_min          0.31
_refine_diff_density_max         0.370
_refine_diff_density_min         -0.408
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     315
_refine_ls_number_reflns         5264
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0571
_refine_ls_R_factor_gt           0.0341
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0346P)^2^+2.5405P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0754
_refine_ls_wR_factor_ref         0.0911
_reflns_number_gt                3849
_reflns_number_total             5264
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            rz5111sup1.cf
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2239221
_cod_database_fobs_code          2239221