Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents with Heteroaryl Halides.
Yang, Yang; Niedermann, Katrin; Han, Chong; Buchwald, Stephen L.; Organic letters 16 (2014) 4638–; doi:10.1021/ol502230p

data_1517434
_publ_section_title
;
 Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary
 Alkylzinc Reagents with Heteroaryl Halides.
;
_journal_issue                   17
_journal_name_full               'Organic letters'
_journal_page_first              4638
_journal_paper_doi               10.1021/ol502230p
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'C35 H45 Br N3 P Pd'
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; 
 ? 
;
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_diffrn_measurement_device_type  'Bruker Smart APEX2 CCD'
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_exptl_crystal_colour            yellow
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0492P)^2^+2.9108P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                7428
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_cod_data_source_file            ol502230p_si_001.cif
_cod_data_source_block           x12158
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 1517434.cif.
;
_cod_original_cell_volume        1609.5(4)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1517434