Pd(II)/β-ICD-Cocatalyzed Asymmetric Route to Oxindole Scaffold via Cascade Reaction of Diazoacetamides and MBH-Carbonates.
Yang, Yang; Ma, Chaoqun; Thumar, Nilesh J.; Hu, Wenhao; The Journal of organic chemistry 81 (2016) 8537–8543; doi:10.1021/acs.joc.6b01703

data_4037200
_publ_section_title
;
 Pd(II)/\b-ICD-Cocatalyzed Asymmetric Route to Oxindole Scaffold via
 Cascade Reaction of Diazoacetamides and MBH-Carbonates.
;
_journal_issue                   18
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              8537
_journal_page_last               8543
_journal_paper_doi               10.1021/acs.joc.6b01703
_journal_volume                  81
_journal_year                    2016
_chemical_absolute_configuration ad
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_cell_length_a                   8.7384(5)
_cell_length_b                   12.1279(7)
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_cell_measurement_temperature    173(2)
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_cell_volume                     2198.6(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
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_diffrn_measurement_device_type  'Bruker Smart Apex II CCD'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_limit_h_max       10
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_exptl_absorpt_correction_T_min  0.6593
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.379
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             944
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.08
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.008(10)
_refine_ls_extinction_method     none
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_refine_ls_number_reflns         3883
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0282P)^2^+0.3597P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                3218
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_reflns_threshold_expression     >2sigma(I)
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