Cyano-bridged gadolinium(III)-tungstate(V) bimetallic assembly with a one-dimensional chain structure.
Ikeda, Satoru; Hozumi, Toshiya; Hashimoto, Kazuhito; Ohkoshi, Shin-Ichi; Dalton transactions (Cambridge, England : 2003)  (2005) 2120–2123; doi:10.1039/b503426d

data_7008487
_publ_section_title
;
 Cyano-bridged gadolinium(III)-tungstate(V) bimetallic assembly with a
 one-dimensional chain structure.
;
_journal_issue                   12
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2120
_journal_page_last               2123
_journal_paper_doi               10.1039/b503426d
_journal_year                    2005
_chemical_formula_moiety         'C26 H42 Gd N14 O6 W '
_chemical_formula_sum            'C26 H42 Gd N14 O6 W'
_chemical_formula_weight         987.81
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 91.09(8)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   16.40(2)
_cell_length_b                   11.08(1)
_cell_length_c                   21.18(2)
_cell_measurement_reflns_used    30362
_cell_measurement_temperature    250.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     3848(7)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 3.5.1'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SHELXS97
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9961
_diffrn_measured_fraction_theta_max 0.9961
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.049
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            73294
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    4.760
_exptl_absorpt_correction_T_max  0.788
_exptl_absorpt_correction_T_min  0.356
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Higashi, T. (1995). Program for Absorption Correction.
Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.706
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1928.00
_exptl_crystal_size_max          0.70
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.86
_refine_diff_density_min         -1.18
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.990
_refine_ls_number_parameters     439
_refine_ls_number_reflns         4859
_refine_ls_R_factor_gt           0.0350
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[0.0017Fo^2^ + 1.0000\s(Fo^2^)]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0560
_reflns_number_gt                4859
_reflns_number_total             9265
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b503426d.txt
_cod_data_source_block           '_Gd(DMF)6[W(CN)8]_250K'
_cod_original_cell_volume        3846(6)
_cod_original_formula_sum        'C26 H42 Gd N14 O6 W '
_cod_database_code               7008487