<i>catena</i>-Poly[[bis(μ~2~-4-methylbenzoato-κ^2^<i>O</i>:<i>O</i>')disilver(I)(<i>Ag{—</i>Ag})]-μ~2~-di-2-pyridylamine-κ^2^<i>N</i>^2^:<i>N</i>^2'^] and <i>catena</i>-poly[[(di-2-pyridylamine-κ<i>N</i>^2^)(μ~2~-4-nitrobenzoato-κ^2^<i>O</i>:<i>O</i>')disilver(I)(<i>Ag{—</i>Ag})]-μ~3~-4-nitrobenzoato-κ^3^<i>O</i>:<i>O</i>':<i>O</i>']
Odoko, Mamiko; Ise, Tomoyasu; Okabe, Nobuo; Acta Crystallographica Section C 63 (2007) m22–m26; doi:10.1107/S010827010605102X

data_2015755
_publ_section_title
;<i>catena</i>-Poly[[bis(\m~2~-4-methylbenzoato-\k^2^<i>O</i>:<i>O</i>')disilver(I)(<i>Ag{---</i>Ag})]-\m~2~-di-2-pyridylamine-\k^2^<i>N</i>^2^:<i>N</i>^2'^]
 and
 <i>catena</i>-poly[[(di-2-pyridylamine-\k<i>N</i>^2^)(\m~2~-4-nitrobenzoato-\k^2^<i>O</i>:<i>O</i>')disilver(I)(<i>Ag{---</i>Ag})]-\m~3~-4-nitrobenzoato-\k^3^<i>O</i>:<i>O</i>':<i>O</i>']
;
_journal_coeditor_code           RB3021
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m22
_journal_page_last               m26
_journal_paper_doi               10.1107/S010827010605102X
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ag2 (C7 H4 N O4)2 (C10 H9 N3)]'
_chemical_formula_moiety         'C24 H17 Ag2 N5 O8'
_chemical_formula_sum            'C24 H17 Ag2 N5 O8'
_chemical_formula_weight         719.17
_chemical_name_systematic
;
catena-poly[[(di-2-pyridylamine-\kN^2^)(\m~2~-4-nitrobenzoato-
\k^2^O:O')disilver(I)(Ag---Ag)]-\m~3~-4-nitrobenzoato-\k^3^O:O':O']
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                82.66(5)
_cell_angle_beta                 84.84(4)
_cell_angle_gamma                72.01(4)
_cell_formula_units_Z            2
_cell_length_a                   7.259(8)
_cell_length_b                   11.070(10)
_cell_length_c                   15.38(2)
_cell_measurement_reflns_used    9330
_cell_measurement_temperature    296.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     1164(2)
_computing_cell_refinement       RAPID-AUTO
_computing_data_collection       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_reduction
;
CrystalStructure (Rigaku/MSC, 2005) and CRYSTALS (Betteridge <i>et
al.</i>,  2003)
;
_computing_molecular_graphics
'ORTEP-3 (Farrugia, 1997) and PLATON (Spek, 2003)'
_computing_publication_material  CrystalStructure
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare <i>et al.</i>,  1999)'
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9877
_diffrn_measured_fraction_theta_max 0.9877
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.024
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            11341
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.746
_exptl_absorpt_correction_T_max  0.957
_exptl_absorpt_correction_T_min  0.582
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.051
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             708.00
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.063
_refine_diff_density_min         -0.792
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     351
_refine_ls_number_reflns         5281
_refine_ls_R_factor_gt           0.0327
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0469P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0882
_reflns_number_gt                4093
_reflns_number_total             5281
_reflns_threshold_expression     F^2^>2\s(F^2^)
_cod_data_source_file            rb3021.cif
_cod_data_source_block           II
_cod_database_code               2015755