Trinuclear scandium methylidyne complexes stabilized by pentamethylcyclopentadienyl ligands.
Deng, Peng; Shi, Xianghui; Gong, Xun; Cheng, Jianhua; Chemical communications (Cambridge, England) 57 (2021) 6436–6439; doi:10.1039/d1cc01645h

data_7128441
_publ_section_title
;
 Trinuclear scandium methylidyne complexes stabilized by
 pentamethylcyclopentadienyl ligands.
;
_journal_issue                   52
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              6436
_journal_page_last               6439
_journal_paper_doi               10.1039/d1cc01645h
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C24 H42 Sc2'
_chemical_formula_sum            'C24 H42 Sc2'
_chemical_formula_weight         420.49
_chemical_name_common            '[(Cp*)ScMe2]2'
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2020-09-28 deposited with the CCDC.	2021-05-31 downloaded from the CCDC.
;
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_computing_data_collection       'Bruker D8 Venture diffractometer'
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_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
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_diffrn_reflns_point_group_measured_fraction_full 0.993
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'Sheldrick, G. M. SADABS, Version 2.10; Bruker AXS, Inc.: Madison, WI 2003.'
_exptl_crystal_colour            Colorless
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'Re-crystallisation from solvent: benzene'
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'w=1/[\s^2^(Fo^2^)+(0.0773P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1451
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                2262
_reflns_number_total             4305
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           CE0610
_cod_depositor_comments
'Adding full bibliography for 7128441--7128448.cif.'
_cod_original_cell_volume        2458.8(13)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7128441
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_shelx_res_checksum              62773