The surprising lability of bis(2,2':6',2''-terpyridine)chromium(iii) complexes.
Constable, Edwin C; Housecroft, Catherine E; Neuburger, Markus; Schönle, Jonas; Zampese, Jennifer A; Dalton transactions (Cambridge, England : 2003) 43 (2014) 7227–7235; doi:10.1039/c4dt00200h

data_7029773
_publ_section_title
;
 The surprising lability of bis(2,2':6',2''-terpyridine)chromium(iii)
 complexes.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7227
_journal_page_last               7235
_journal_paper_doi               10.1039/c4dt00200h
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         '2(C30 H22 Cr N6), 6(F6 P), 5(C2 H3 N)'
_chemical_formula_sum            'C70 H59 Cr2 F36 N17 P6'
_chemical_formula_weight         2112.16
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
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_cell_angle_gamma                90
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_cell_measurement_theta_min      2.74
_cell_volume                     33927(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -23
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_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.984
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_refine_ls_R_factor_gt           0.0782
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; 
 w=1/[\s^2^(Fo^2^)+(0.0864P)^2^+119.5995P] 
 where P=(Fo^2^+2Fc^2^)/3 
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1973
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_cod_depositor_comments
;Adding full bibliography for
 ./tmp-cod-update-bibliographies-12899/cifs/7029773.cif.
;
_cod_database_code               7029773
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