Copper(ii) triflate catalyzed three-component reaction for the synthesis of 2,3-diarylquinoline derivatives using aryl amines, aryl aldehydes and styrene oxides.
Ali, Saghir; Khan, Abu T.; Organic & biomolecular chemistry 19 (2021) 3255–3262; doi:10.1039/d1ob00125f

data_7157982
_publ_section_title
;
 Copper(ii) triflate catalyzed three-component reaction for the synthesis
 of 2,3-diarylquinoline derivatives using aryl amines, aryl aldehydes and
 styrene oxides.
;
_journal_issue                   14
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              3255
_journal_page_last               3262
_journal_paper_doi               10.1039/d1ob00125f
_journal_volume                  19
_journal_year                    2021
_chemical_formula_sum            'C22 H16 F N O'
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_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2020-10-27 deposited with the CCDC.	2021-03-19 downloaded from the CCDC.
;
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_cell_measurement_theta_min      2.71
_cell_volume                     1682.63(12)
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_exptl_absorpt_coefficient_mu    0.087
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.8558P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                2817
_reflns_number_total             4268
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1ob00125f2.cif
_cod_data_source_block           SA-4FBZ_0ma_a
_cod_depositor_comments
;
          Adding full bibliography for 7157982.cif.

2025-03-31
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C88 H64 F4 N4 O4'
_cod_original_formula_weight         1317.43
_cod_original_formula_units_Z            1
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7157982
_shelx_shelxl_version_number     2016/6
_shelx_res_checksum              32281