A study of di(amino)stibines with terminal Sb(iii) hydrogen-ligands by X-ray- and neutron-diffraction.
Schwamm, Ryan J.; Edwards, Alison J.; Fitchett, Christopher M.; Coles, Martyn P.; Dalton transactions (Cambridge, England : 2003) 48 (2019) 2953–2958; doi:10.1039/c8dt05113e

data_7048828
_publ_section_title
;
 A study of di(amino)stibines with terminal Sb(iii) hydrogen-ligands by
 X-ray- and neutron-diffraction.
;
_journal_issue                   9
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2953
_journal_page_last               2958
_journal_paper_doi               10.1039/c8dt05113e
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C28 H46 Cl N2 O Sb Si2'
_chemical_formula_sum            'C28 H46 Cl N2 O Sb Si2'
_chemical_formula_weight         640.06
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_space_group_name_Hall           '-P 1'
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Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
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2019-01-30 deposited with the CCDC.
2019-01-31 downloaded from the CCDC.
;
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
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omega____ theta____ kappa____ phi______ frames
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  2 omega   10.00  100.00   1.0000   30.0000
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  3 omega  -48.00   48.00   1.0000   30.0000
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  6 omega   88.00  113.00   1.0000   30.0000
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  7 omega  -18.00   10.00   1.0000   30.0000
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  8 omega   34.00   65.00   1.0000   30.0000
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  9 omega   88.00  113.00   1.0000   30.0000
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 10 omega  -85.00  -59.00   1.0000   30.0000
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 11 omega -115.00  -84.00   1.0000   30.0000
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 12 omega -111.00  -64.00   1.0000   30.0000
omega____ theta____ kappa____ phi______ frames
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 13 omega  -19.00    9.00   1.0000   30.0000
omega____ theta____ kappa____ phi______ frames
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 14 omega  -39.00   33.00   1.0000   30.0000
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 15 omega    9.00  100.00   1.0000   30.0000
omega____ theta____ kappa____ phi______ frames
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_diffrn_radiation_monochromator  mirror
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_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            colourless
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'w=1/[\s^2^(Fo^2^)+(0.0226P)^2^+2.4751P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7048824--7048828.cif.'
_cod_original_cell_volume        4685.17(10)
_cod_database_code               7048828
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         C28H46N2O1CL1SI2SB1
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;
1. Fixed Uiso
 At 1.2 times of:
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 At 1.5 times of:
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2.a Ternary CH refined with riding coordinates:
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2.b Aromatic/amide H refined with riding coordinates:
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2.c Idealised Me refined as rotating group:
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 H53B,H53C), C55(H55A,H55B,H55C), C56(H56A,H56B,H56C)
;
_shelx_res_checksum              87330
_olex2_submission_special_instructions 'No special instructions were received'