Mixed nitrosyl/phosphinidene and nitrene/phosphinidene clusters of rutheniumElectronic supplementary information (ESI) available: experimental, preparation of compounds. See http://www.rsc.org/suppdata/cc/b1/b110927h
Scoles, Ludmila; Sterenberg, Brian T.; Udachin, Konstantin A.; Carty, Arthur J.; Chemical Communications  (2002) 320–; doi:10.1039/b110927h

data_7114103
_publ_section_title
;
 Mixed nitrosyl/phosphinidene and nitrene/phosphinidene clusters of
 rutheniumElectronic supplementary information (ESI) available:
 experimental, preparation of compounds. See
 http://www.rsc.org/suppdata/cc/b1/b110927h
;
_journal_issue                   4
_journal_name_full               'Chemical Communications'
_journal_page_first              320
_journal_paper_doi               10.1039/b110927h
_journal_year                    2002
_chemical_formula_sum            'C20 H17 Cl2 N2 O13 P Ru5'
_chemical_formula_weight         1100.58
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.7800(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.4582(7)
_cell_length_b                   12.9073(7)
_cell_length_c                   19.4653(10)
_cell_measurement_temperature    293(2)
_cell_volume                     3181.8(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0213
_diffrn_reflns_av_sigmaI/netI    0.0129
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            37058
_diffrn_reflns_theta_full        28.71
_diffrn_reflns_theta_max         28.71
_diffrn_reflns_theta_min         1.93
_exptl_absorpt_coefficient_mu    2.598
_exptl_crystal_density_diffrn    2.298
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2096
_refine_diff_density_max         0.595
_refine_diff_density_min         -0.874
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     402
_refine_ls_number_reflns         8224
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.091
_refine_ls_R_factor_all          0.0218
_refine_ls_R_factor_gt           0.0182
_refine_ls_shift/su_max          0.037
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0182P)^2^+2.4375P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0416
_refine_ls_wR_factor_ref         0.0432
_reflns_number_gt                7490
_reflns_number_total             8224
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b110927h.txt
_cod_data_source_block           ld40
_cod_database_code               7114103