Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes.
Geeson, Michael B.; Transue, Wesley J.; Cummins, Christopher C.; Journal of the American Chemical Society 141 (2019) 13336–13340; doi:10.1021/jacs.9b07069

data_4128904
_publ_section_title
;
 Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic
 Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes.
;
_journal_issue                   34
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13336
_journal_page_last               13340
_journal_paper_doi               10.1021/jacs.9b07069
_journal_volume                  141
_journal_year                    2019
_chemical_formula_sum            'C19 H22 B F4 Fe O2 P'
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_exptl_crystal_description       plate
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0502P)^2^+1.8461P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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