Employment of 2,6-Diacetylpyridine Dioxime as a New Route to High Nuclearity Metal Clusters: Mn6 and Mn8 Complexes
Theocharis C. Stamatatos; Brian S. Luisi; Brian Moulton; George Christou; Inorganic Chemistry 47 (2008) 1134–1144; doi:10.1021/ic7020269

data_4304525
_publ_section_title
;
Employment of 2,6-Diacetylpyridine Dioxime as a New Route to High
Nuclearity Metal Clusters: Mn6 and Mn8 Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1134
_journal_page_last               1144
_journal_paper_doi               10.1021/ic7020269
_journal_volume                  47
_journal_year                    2008
_chemical_formula_sum            'C119 H120 Ca2 Mn12 N44 O65'
_chemical_formula_weight         3946.03
_chemical_name_systematic
; 
 ? 
;
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_computing_molecular_graphics    'BRUKER SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
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_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
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_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_limit_h_max       29
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_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    .
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_exptl_crystal_size_min          0.05
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1046P)^2^+17.1115P] where P=(Fo^2^+2Fc^2^)/3'
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