Regulating iminophosphorane PN bond reactivity through geometric constraints with cage-shaped triarylphosphines.
Hu, Lei; Chakraborty, Sayandip; Tumanov, Nikolay; Wouters, Johan; Robiette, Raphaël; Berionni, Guillaume; Chemical communications (Cambridge, England) 60 (2024) 7073–7076; doi:10.1039/d4cc01868k

data_7133215
_publ_section_title
;
 Regulating iminophosphorane P&#xe001;N bond reactivity through geometric
 constraints with cage-shaped triarylphosphines.
;
_journal_issue                   55
_journal_name_full               'Chemical communications (Cambridge, England)'
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_journal_page_last               7076
_journal_paper_doi               10.1039/d4cc01868k
_journal_volume                  60
_journal_year                    2024
_chemical_formula_moiety         'C25 H18 N P'
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_chemical_name_common            N-phenyl-5\l^5^-9-phosphatriptycene-imine
_chemical_name_systematic        N-phenyl-5\l^5^-9-phosphatriptycene-imine
_space_group_crystal_system      orthorhombic
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;
2024-04-10 deposited with the CCDC.	2024-04-28 downloaded from the CCDC.
;
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;
Krause, L., Herbst-Irmer, R., Sheldrick, G. M., Stalke, D. (2015).
"Comparison of silver and molybdenum microfocus X-ray sources for
single-crystal structure determination"
J. Appl. Cryst. 48, 3-10.
doi:10.1107/S1600576714022985
;
_exptl_crystal_colour            colourless
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;
 Refined as an inversion twin.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0362P)^2^+1.2368P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7133202--7133219.cif.'
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