Regio- and Stereoselective Insertion Reactions of Thiiranes into Pt-Mn (or Re) Bond in Organoplatinum-Manganese or -Rhenium Heterodinuclear Complexes as Intermediates toward Desulfurization Reaction
Sanshiro Komiya; Shin-ya Muroi; Masaki Furuya; Masafumi Hirano; Journal of the American Chemical Society 122 (2000) 170–171; doi:10.1021/ja993185m

data_4115871
_publ_contact_author_address
;
Department of Applied Chemistry
Tokyo University of Agriculture and Technology
2-24-16 Nakacho, Koganei, Tokyo 184-8588, Japan
;
_publ_contact_author_email       ' komiya@cc.tuat.ac.jp '
_publ_contact_author_fax         ' +81-42-387-7500 '
_publ_contact_author_name        ' Sanshiro Komiya'
_publ_contact_author_phone       ' +81-42-388-7043 '
_publ_section_title
;
 Regio- and Stereoselective Insertion Reactions of Thiiranes into Pt-Mn
 (or Re) Bond in Organoplatinum-Manganese or -Rhenium Heterodinuclear
 Complexes as Intermediates toward Desulfurization Reaction
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              170
_journal_page_last               171
_journal_paper_doi               10.1021/ja993185m
_journal_volume                  122
_journal_year                    2000
_chemical_formula_moiety         'C36 H35  Mn O5 P2 Pt S '
_chemical_formula_sum            'C36 H35 Mn O5 P2 Pt S'
_chemical_formula_weight         891.71
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                97.82(4)
_cell_angle_beta                 104.17(4)
_cell_angle_gamma                75.00(3)
_cell_formula_units_Z            2
_cell_length_a                   13.755(7)
_cell_length_b                   13.790(6)
_cell_length_c                   11.260(6)
_cell_measurement_reflns_used    22
_cell_measurement_temperature    113.2
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.9
_cell_volume                     1994.2(18)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    'DIRDIF92 (PATTY)'
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.036
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            9622
_diffrn_standards_decay_%        2.95
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.982
_exptl_absorpt_correction_T_max  0.992
_exptl_absorpt_correction_T_min  0.788
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.612
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.800
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_refine_diff_density_max         1.50
_refine_diff_density_min         -1.80
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   2.918
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     431
_refine_ls_number_reflns         6037
_refine_ls_R_factor_gt           0.0610
_refine_ls_shift/su_max          0.4750
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      unit
_refine_ls_wR_factor_ref         0.0804
_reflns_number_gt                6037
_reflns_number_total             0
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ja993185m_1.cif
_cod_data_source_block           trans-10
_cod_original_cell_volume        1994(1)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C36 H35  Mn O5 P2 Pt S '
_cod_database_code               4115871