Reversible C-C bond activation enables stereocontrol in rh-catalyzed carbonylative cycloadditions of aminocyclopropanes.
Shaw, Megan H.; McCreanor, Niall G.; Whittingham, William G.; Bower, John F.; Journal of the American Chemical Society 137 (2015) 463–468; doi:10.1021/ja511335v

data_4123203
_publ_section_title
;
 Reversible C-C bond activation enables stereocontrol in rh-catalyzed
 carbonylative cycloadditions of aminocyclopropanes.
;
_journal_issue                   1
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              463
_journal_page_last               468
_journal_paper_doi               10.1021/ja511335v
_journal_volume                  137
_journal_year                    2015
_chemical_formula_moiety         'C8 H11.56 Cl0.89 N0.89 O3.56 Rh0.89'
_chemical_formula_sum            'C8 H11.56 Cl0.89 N0.89 O3.56 Rh0.89'
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_computing_data_collection       'USER DEFINED DATA COLLECTION'
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CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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;
 Method= Modified Sheldrick 
 w=1/[\s^2^(F^2^) + ( 0.04P)^2^ + 1.59P] 
 ,where P=(max(Fo^2^,0) + 2Fc^2^)/3 
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_refine_ls_weighting_scheme      calc
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_cod_data_source_file            ja511335v_si_007.cif
_cod_data_source_block           1
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The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 

 Adding full bibliography for 4123199--4123207.cif.
;
_cod_original_sg_symbol_H-M      'C 1 2/c 1 '
_cod_database_code               4123203