Formation, Characterization, and Reactivity of Bis(μ-oxo)dinickel(III) Complexes Supported by A Series of Bis[2-(2-pyridyl)ethyl]amine Ligands
Shinobu Itoh; Hideki Bandoh; Motonobu Nakagawa; Shigenori Nagatomo; Teizo Kitagawa; Kenneth D. Karlin; Shunichi Fukuzumi; Journal of the American Chemical Society 123 (2001) 11168–11178; doi:10.1021/ja0104094

data_4115773
_publ_section_title
;
 Formation, Characterization, and Reactivity of Bis(\m-oxo)dinickel(III)
 Complexes Supported by A Series of Bis[2-(2-pyridyl)ethyl]amine Ligands
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11168
_journal_page_last               11178
_journal_paper_doi               10.1021/ja0104094
_journal_volume                  123
_journal_year                    2001
_chemical_formula_sum            'C38 H55 Cl2 N7 Ni2 O11'
_chemical_formula_weight         974.20
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
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_cell_angle_beta                 90
_cell_angle_gamma                90
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_cell_length_b                   33.1982(5)
_cell_length_c                   11.0644(1)
_cell_measurement_reflns_used    55896
_cell_measurement_temperature    295.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.7
_cell_volume                     4448.88(11)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
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_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
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_diffrn_measurement_method       \w
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_diffrn_reflns_theta_max         27.49
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_exptl_crystal_colour            green
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_exptl_crystal_description       needle
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00250|Fo|^2^]'
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_cod_data_source_block           nakagawa825
_cod_original_cell_volume        4448.88(9)
_cod_original_sg_symbol_H-M      'P 21 21 21 '
_cod_original_formula_sum        'C38 H55 Cl2 N7 O11 Ni2 '
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