LMucko/crystallography-open-database huggingface dataset:
Lead substitution in the 30K-superconductor Bi~2~Sr~4-y~Cu~2~CO~3~O~8-d~
Pelloquin, D; Caldes, M T; Michel, C; Maignan, A; Hervieu, M; Raveau, B; Physica C (Amsterdam) (152,1988-) 217 (1993) 27–33; doi:10.1016/0921-4534(93)90791-N

data_1001577
_publ_section_title
;
Lead substitution in the 30K-superconductor Bi~2~Sr~4-y~Cu~2~CO~3~O~8-d~
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              27
_journal_page_last               33
_journal_paper_doi               10.1016/0921-4534(93)90791-N
_journal_volume                  217
_journal_year                    1993
_chemical_formula_structural     '(Bi1.5 Pb0.5) Sr3.5 Cu2 O8 (C O3)'
_chemical_formula_sum            'C Bi1.5 Cu2 O11 Pb0.5 Sr3.5'
_chemical_name_systematic
;
Bismuth lead strontium copper oxide carbonate (1.5/0.5/3.5/2/8/1)
;
_space_group_IT_number           67
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      67
_symmetry_space_group_name_Hall  '-A 2b 2b'
_symmetry_space_group_name_H-M   'A b m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.468(5)
_cell_length_b                   5.427(5)
_cell_length_c                   39.530(4)
_cell_volume                     1173.0
_refine_ls_R_factor_all          0.09
_cod_depositor_comments
;
 Correcting the summary chemical formula by changing it from
 'Bi1.5 Cu2 O11 Pb0.5 Sr3.5' to 'C Bi1.5 Cu2 O11 Pb0.5 Sr3.5'.

 Antanas Vaitkus,
 2018-07-07
;
_cod_original_formula_sum        'Bi1.5 Cu2 O11 Pb.5 Sr3.5'
_cod_database_code               1001577
Synthesis of YBa~2~Cu~3~O~7-x~ by sol-gel route. Formation of YBaCuO oxycarbonate intermediate
Gotor, F J; Odier, P; Gervais, M; Choisnet, J; Monod, Ph; Physica C (Amsterdam) (152,1988-) 218 (1993) 429–436; doi:10.1016/0921-4534(93)90046-S

data_1001578
_publ_section_title
;
Synthesis of YBa~2~Cu~3~O~7-x~ by sol-gel route. Formation of YBaCuO
oxycarbonate intermediate
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              429
_journal_page_last               436
_journal_paper_doi               10.1016/0921-4534(93)90046-S
_journal_volume                  218
_journal_year                    1993
_chemical_formula_structural     'Y Ba2 Cu2.95 (C O3)0.35 O6.6'
_chemical_formula_sum            'C0.35 Ba2 Cu2.95 O7.65 Y'
_chemical_name_systematic
;
Yttrium barium copper carbonate oxide (1/2/2.95/0.35/6.6)
;
_space_group_IT_number           123
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      123
_symmetry_space_group_name_Hall  '-P 4 2'
_symmetry_space_group_name_H-M   'P 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   3.8706(4)
_cell_length_b                   3.8706(4)
_cell_length_c                   11.612(1)
_cell_volume                     174.0
_refine_ls_R_factor_all          0.055
_cod_depositor_comments
;
 Correcting the summary chemical formula by changing it from
 'Ba2 Cu2.95 O7.65 Y' to 'C0.35 Ba2 Cu2.95 O7.65 Y'.

 Antanas Vaitkus,
 2018-07-07
;
_cod_database_code               1001578
A 70K superconductor. The oxycarbonate Tl~0.5~Pb~0.5~Sr~4~Cu~2~(CO~3~)O~7~
Huve, M; Michel, C; Maignan, A; Hervieu, M; Martin, C; Raveau, B; Physica C (Amsterdam) (152,1988-) 205 (1993) 219–224; doi:10.1016/0921-4534(93)90386-5

data_1001579
_publ_section_title
;
A 70K superconductor. The oxycarbonate
Tl~0.5~Pb~0.5~Sr~4~Cu~2~(CO~3~)O~7~
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              219
_journal_page_last               224
_journal_paper_doi               10.1016/0921-4534(93)90386-5
_journal_volume                  205
_journal_year                    1993
_chemical_formula_structural     '(Tl0.5 Pb0.5) Sr4 Cu2 (C O3) O7'
_chemical_formula_sum            'C Cu2 O10 Pb0.5 Sr4 Tl0.5'
_chemical_name_systematic
;
Thallium lead strontium copper carbonate oxide (0.5/0.5/4/2/1/7)
;
_space_group_IT_number           123
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      123
_symmetry_space_group_name_Hall  '-P 4 2'
_symmetry_space_group_name_H-M   'P 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   3.8244(1)
_cell_length_b                   3.8244(1)
_cell_length_c                   16.516(1)
_cell_volume                     241.6
_refine_ls_R_factor_all          0.066
_cod_depositor_comments
;
 Correcting the summary chemical formula by changing it from
 'Cu2 O10 Pb0.5 Sr4 Tl0.5' to 'C Cu2 O10 Pb0.5 Sr4 Tl0.5'.

 Antanas Vaitkus,
 2018-07-07
;
_cod_original_formula_sum        'Cu2 O10 Pb.5 Sr4 Tl.5'
_cod_database_code               1001579
Structure and properties of Tl~0.5~Pb~0.5~Sr~2~Gd~2-x~Ce~x~Cu~2~O~9-d~
Vijayaraghavan, R; Michel, C; Maignan, A; Hervieu, M; Martin, C; Raveau, B; Rao, C N R; Physica C (Amsterdam) (152,1988-) 206 (1993) 81–89; doi:10.1016/0921-4534(93)90704-T

data_1001580
_publ_section_title
;
Structure and properties of Tl~0.5~Pb~0.5~Sr~2~Gd~2-x~Ce~x~Cu~2~O~9-d~
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              81
_journal_page_last               89
_journal_paper_doi               10.1016/0921-4534(93)90704-T
_journal_volume                  206
_journal_year                    1993
_chemical_formula_structural     '(Tl0.5 Pb0.5) Sr2 Gd2 Cu2 O9'
_chemical_formula_sum            'Cu2 Gd2 O9 Pb0.5 Sr2 Tl0.5'
_chemical_name_systematic
;
Thallium lead strontium gadolinium copper oxide (0.5/0.5/2/2/2/9)
;
_space_group_IT_number           139
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      139
_symmetry_space_group_name_Hall  '-I 4 2'
_symmetry_space_group_name_H-M   'I 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   3.8385(1)
_cell_length_b                   3.8385(1)
_cell_length_c                   29.5815(11)
_cell_volume                     435.9
_refine_ls_R_factor_all          0.047
_cod_original_formula_sum        'Cu2 Gd2 O9 Pb.5 Sr2 Tl.5'
_cod_database_code               1001580
Structure and properties of Tl~0.5~Pb~0.5~Sr~2~Gd~2-x~Ce~x~Cu~2~O~9-d~
Vijayaraghavan, R; Michel, C; Maignan, A; Hervieu, M; Martin, C; Raveau, B; Rao, C N R; Physica C (Amsterdam) (152,1988-) 206 (1993) 81–89; doi:10.1016/0921-4534(93)90704-T

data_1001581
_publ_section_title
;
Structure and properties of Tl~0.5~Pb~0.5~Sr~2~Gd~2-x~Ce~x~Cu~2~O~9-d~
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              81
_journal_page_last               89
_journal_paper_doi               10.1016/0921-4534(93)90704-T
_journal_volume                  206
_journal_year                    1993
_chemical_formula_structural     '(Tl0.5 Pb0.5) Sr2 (Gd1.6 Ce0.4) Cu2 O9'
_chemical_formula_sum            'Ce0.4 Cu2 Gd1.6 O9 Pb0.5 Sr2 Tl0.5'
_chemical_name_systematic
;
Thallium lead strontium gadolinium cerium copper oxide
(0.5/0.5/2/1.6/0.4/2/9)
;
_space_group_IT_number           139
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      139
_symmetry_space_group_name_Hall  '-I 4 2'
_symmetry_space_group_name_H-M   'I 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   3.8429(1)
_cell_length_b                   3.8429(1)
_cell_length_c                   29.5096(10)
_cell_volume                     435.8
_refine_ls_R_factor_all          0.058
_cod_original_formula_sum        'Ce.4 Cu2 Gd1.6 O9 Pb.5 Sr2 Tl.5'
_cod_database_code               1001581
Ordered substitution of "CO~3~" groups for CuO~4~ square groups in the "123" structure. The oxycarbonate Y~4~Sr~8~Cu~11~CO~3~O~25~, n=4 member of the series Y~n~Sr~2n~Cu~3n-1~CO~3~O~7n-3~
Domenges, B; Hervieu, M; Raveau, B; Physica C (Amsterdam) (152,1988-) 207 (1993) 65–78; doi:10.1016/0921-4534(93)90424-O

data_1001582
_publ_section_title
;
Ordered substitution of "CO~3~" groups for CuO~4~ square groups in the
"123" structure. The oxycarbonate Y~4~Sr~8~Cu~11~CO~3~O~25~, n=4 member
of the series Y~n~Sr~2n~Cu~3n-1~CO~3~O~7n-3~
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              65
_journal_page_last               78
_journal_paper_doi               10.1016/0921-4534(93)90424-O
_journal_volume                  207
_journal_year                    1993
_chemical_formula_structural     'Y4 Sr8 Cu11 (C O3) O25'
_chemical_formula_sum            'C Cu11 O28 Sr8 Y4'
_chemical_name_systematic
;
Yttrium strontium copper carbonate oxide (4/8/11/1/25)
;
_space_group_IT_number           35
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      35
_symmetry_space_group_name_Hall  'B -2 -2'
_symmetry_space_group_name_H-M   'B m 2 m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.311
_cell_length_b                   3.851
_cell_length_c                   22.371
_cell_volume                     1319.1
_cod_depositor_comments
;
 Correcting the summary chemical formula by changing it from 'Cu11 O28 Sr8 Y4'
 to 'C Cu11 O28 Sr8 Y4'.

 Antanas Vaitkus,
 2018-07-07
;
_cod_database_code               1001582
The bismuth oxycarbonate Bi~2~Sr~4~Cu~2~CO~3~O~8~. A new superconductor with a T~c~ of 30K
Pelloquin, D; Caldes, M; Maignan, A; Michel, C; Hervieu, M; Raveau, B; Physica C (Amsterdam) (152,1988-) 208 (1993) 121–129; doi:10.1016/0921-4534(93)90678-J

data_1001583
_publ_section_title
;
The bismuth oxycarbonate Bi~2~Sr~4~Cu~2~CO~3~O~8~. A new superconductor
with a T~c~ of 30K
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              121
_journal_page_last               129
_journal_paper_doi               10.1016/0921-4534(93)90678-J
_journal_volume                  208
_journal_year                    1993
_chemical_formula_structural     'Bi2 Sr4 Cu2 (C O3) O8'
_chemical_formula_sum            'C Bi2 Cu2 O11 Sr4'
_chemical_name_systematic
;
Dibismuth tetrastrontium dicopper carbonate oxide
;
_space_group_IT_number           67
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      67
_symmetry_space_group_name_Hall  '-A 2b 2b'
_symmetry_space_group_name_H-M   'A b m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.466(2)
_cell_length_b                   5.460(2)
_cell_length_c                   39.500(9)
_cell_volume                     1178.9
_refine_ls_R_factor_all          0.13
_cod_depositor_comments
;
 Correcting the summary chemical formula by changing it from 'Bi2 Cu2 O11 Sr4'
 to 'C Bi2 Cu2 O11 Sr4'.

 Antanas Vaitkus,
 2018-07-07
;
_cod_database_code               1001583
A 55K superconducting copper oxycarbonate: Tl~1- x~Bi~x~Sr~4~Cu~2~CO~3~O~7~
Maignan, A; Huve, M; Michel, C; Hervieu, M; Martin, C; Raveau, B; Physica C (Amsterdam) (152,1988-) 208 (1993) 149–154; doi:10.1016/0921-4534(93)90682-G

data_1001584
_publ_section_title
;
A 55K superconducting copper oxycarbonate: Tl~1-
x~Bi~x~Sr~4~Cu~2~CO~3~O~7~
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              149
_journal_page_last               154
_journal_paper_doi               10.1016/0921-4534(93)90682-G
_journal_volume                  208
_journal_year                    1993
_chemical_formula_structural     '(Tl0.5 Bi0.5) Sr4 Cu2 (C O3) O7'
_chemical_formula_sum            'C Bi0.5 Cu2 O10 Sr4 Tl0.5'
_chemical_name_systematic
;
Thallium bismuth strontium copper carbonate oxide (0.5/0.5/4/2/1/7)
;
_space_group_IT_number           123
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      123
_symmetry_space_group_name_Hall  '-P 4 2'
_symmetry_space_group_name_H-M   'P 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   3.8309(2)
_cell_length_b                   3.8309(2)
_cell_length_c                   16.518(1)
_cell_volume                     242.4
_refine_ls_R_factor_all          0.085
_cod_depositor_comments
;
 Correcting the summary chemical formula by changing it from
 'Bi0.5 Cu2 O10 Sr4 Tl0.5' to 'C Bi0.5 Cu2 O10 Sr4 Tl0.5'.

 Antanas Vaitkus,
 2018-07-07
;
_cod_original_formula_sum        'Bi.5 Cu2 O10 Sr4 Tl.5'
_cod_database_code               1001584
A 2212 bismuth cuprate with a non-modulated structure Bi~2- x~La~x~Ba~2.5~La~0.5~Cu~2~O~8.25~
Hervieu, M; Pham, A Q; Michel, C; Raveau, B; Physica C (Amsterdam) (152,1988-) 209 (1993) 449–455; doi:10.1016/0921-4534(93)90559-9

data_1001585
_publ_section_title
;
A 2212 bismuth cuprate with a non-modulated structure Bi~2-
x~La~x~Ba~2.5~La~0.5~Cu~2~O~8.25~
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              449
_journal_page_last               455
_journal_paper_doi               10.1016/0921-4534(93)90559-9
_journal_volume                  209
_journal_year                    1993
_chemical_formula_structural     '(Bi1.59 La0.41) Ba2 (Ba0.5 La0.5) Cu2 O8.25'
_chemical_formula_sum            'Ba2.5 Bi1.59 Cu2 La0.91 O8.25'
_chemical_name_systematic
;
Bismuth barium lanthanum copper oxide (1.6/2.5/0.9/2/8.3)
;
_space_group_IT_number           139
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      139
_symmetry_space_group_name_Hall  '-I 4 2'
_symmetry_space_group_name_H-M   'I 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   3.938(1)
_cell_length_b                   3.938(1)
_cell_length_c                   31.213(5)
_cell_volume                     484.0
_refine_ls_R_factor_all          0.095
_cod_original_formula_sum        'Ba2.5 Bi1.59 Cu2 La.91 O8.25'
_cod_database_code               1001585
Influence of thermal treatment on Y~1-x~Ca~x~Ba~2~Cu~3-x~Co~x~O~7~. A neutron diffraction study
Suard, E; Caignaert, V; Maignan, A; Bouree, F; Raveau, B; Physica C (Amsterdam) (152,1988-) 210 (1993) 164–172; doi:10.1016/0921-4534(93)90021-H

data_1001586
_publ_section_title
;
Influence of thermal treatment on Y~1-x~Ca~x~Ba~2~Cu~3-x~Co~x~O~7~. A
neutron diffraction study
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              164
_journal_page_last               172
_journal_paper_doi               10.1016/0921-4534(93)90021-H
_journal_volume                  210
_journal_year                    1993
_chemical_formula_structural
;
(Y0.86 Ca0.14) Ba2 Cu2 (Cu0.88 Co0.12) O6.96
;
_chemical_formula_sum            'Ba2 Ca0.14 Co0.12 Cu2.88 O6.96 Y0.86'
_chemical_name_systematic
;
Yttrium calcium barium copper cobalt oxide (0.9/0.1/2/2.9/0.1/6.96)
;
_space_group_IT_number           123
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      123
_symmetry_space_group_name_Hall  '-P 4 2'
_symmetry_space_group_name_H-M   'P 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   3.8618(1)
_cell_length_b                   3.8618(1)
_cell_length_c                   11.6910(3)
_cell_volume                     174.4
_refine_ls_R_factor_all          0.021
_cod_original_formula_sum        'Ba2 Ca.14 Co.12 Cu2.88 O6.96 Y.86'
_cod_database_code               1001586
Influence of thermal treatment on Y~1-x~Ca~x~Ba~2~Cu~3-x~Co~x~O~7~. A neutron diffraction study
Suard, E; Caignaert, V; Maignan, A; Bouree, F; Raveau, B; Physica C (Amsterdam) (152,1988-) 210 (1993) 164–172; doi:10.1016/0921-4534(93)90021-H

data_1001587
_publ_section_title
;
Influence of thermal treatment on Y~1-x~Ca~x~Ba~2~Cu~3-x~Co~x~O~7~. A
neutron diffraction study
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              164
_journal_page_last               172
_journal_paper_doi               10.1016/0921-4534(93)90021-H
_journal_volume                  210
_journal_year                    1993
_chemical_formula_structural     '(Y0.82 Ca0.18) Ba2 Cu2 (Cu0.76 Co0.24) O7'
_chemical_formula_sum            'Ba2 Ca0.18 Co0.24 Cu2.76 O7 Y0.82'
_chemical_name_systematic
;
Yttrium calcium barium copper cobalt oxide (0.8/0.2/2/2.8/0.2/7)
;
_space_group_IT_number           123
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      123
_symmetry_space_group_name_Hall  '-P 4 2'
_symmetry_space_group_name_H-M   'P 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   3.8649(1)
_cell_length_b                   3.8649(1)
_cell_length_c                   11.7053(3)
_cell_volume                     174.8
_refine_ls_R_factor_all          0.028
_cod_original_formula_sum        'Ba2 Ca.18 Co.24 Cu2.76 O7 Y.82'
_cod_database_code               1001587
Influence of thermal treatment on Y~1-x~Ca~x~Ba~2~Cu~3-x~Co~x~O~7~. A neutron diffraction study
Suard, E; Caignaert, V; Maignan, A; Bouree, F; Raveau, B; Physica C (Amsterdam) (152,1988-) 210 (1993) 164–172; doi:10.1016/0921-4534(93)90021-H

data_1001588
_publ_section_title
;
Influence of thermal treatment on Y~1-x~Ca~x~Ba~2~Cu~3-x~Co~x~O~7~. A
neutron diffraction study
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              164
_journal_page_last               172
_journal_paper_doi               10.1016/0921-4534(93)90021-H
_journal_volume                  210
_journal_year                    1993
_chemical_formula_structural     '(Y0.73 Ca0.27) Ba2 Cu2 (Cu0.7 Co0.3) O7'
_chemical_formula_sum            'Ba2 Ca0.27 Co0.3 Cu2.7 O7 Y0.73'
_chemical_name_systematic
;
Yttrium calcium barium copper cobalt oxide (0.7/0.3/2/2.7/0.3/7)
;
_space_group_IT_number           123
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      123
_symmetry_space_group_name_Hall  '-P 4 2'
_symmetry_space_group_name_H-M   'P 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   3.8646(1)
_cell_length_b                   3.8646(1)
_cell_length_c                   11.7257(3)
_cell_volume                     175.1
_refine_ls_R_factor_all          0.025
_cod_original_formula_sum        'Ba2 Ca.27 Co.3 Cu2.7 O7 Y.73'
_cod_database_code               1001588
Influence of thermal treatment on Y~1-x~Ca~x~Ba~2~Cu~3-x~Co~x~O~7~. A neutron diffraction study
Suard, E; Caignaert, V; Maignan, A; Bouree, F; Raveau, B; Physica C (Amsterdam) (152,1988-) 210 (1993) 164–172; doi:10.1016/0921-4534(93)90021-H

data_1001589
_publ_section_title
;
Influence of thermal treatment on Y~1-x~Ca~x~Ba~2~Cu~3-x~Co~x~O~7~. A
neutron diffraction study
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              164
_journal_page_last               172
_journal_paper_doi               10.1016/0921-4534(93)90021-H
_journal_volume                  210
_journal_year                    1993
_chemical_formula_structural
;
(Y0.85 Ca0.15) Ba2 Cu2 (Cu0.64 Co0.36) O7.05
;
_chemical_formula_sum            'Ba2 Ca0.15 Co0.36 Cu2.64 O7.05 Y0.85'
_chemical_name_systematic
;
Yttrium calcium barium copper cobalt oxide (0.9/0.1/2/2.6/0.4/7.1)
;
_space_group_IT_number           123
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      123
_symmetry_space_group_name_Hall  '-P 4 2'
_symmetry_space_group_name_H-M   'P 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   3.8690(1)
_cell_length_b                   3.8690(1)
_cell_length_c                   11.6982(4)
_cell_volume                     175.1
_refine_ls_R_factor_all          0.034
_cod_original_formula_sum        'Ba2 Ca.15 Co.36 Cu2.64 O7.05 Y.85'
_cod_database_code               1001589
Influence of thermal treatment on Y~1-x~Ca~x~Ba~2~Cu~3-x~Co~x~O~7~. A neutron diffraction study
Suard, E; Caignaert, V; Maignan, A; Bouree, F; Raveau, B; Physica C (Amsterdam) (152,1988-) 210 (1993) 164–172; doi:10.1016/0921-4534(93)90021-H

data_1001590
_publ_section_title
;
Influence of thermal treatment on Y~1-x~Ca~x~Ba~2~Cu~3-x~Co~x~O~7~. A
neutron diffraction study
;
_journal_coden_ASTM              PHYCE6
_journal_name_full               'Physica C (Amsterdam) (152,1988-)'
_journal_page_first              164
_journal_page_last               172
_journal_paper_doi               10.1016/0921-4534(93)90021-H
_journal_volume                  210
_journal_year                    1993
_chemical_formula_structural
;
(Y0.85 Ca0.15) Ba2 (Cu1.99 Co0.01) (Cu0.89 Co0.11) O7.01
;
_chemical_formula_sum            'Ba2 Ca0.15 Co0.12 Cu2.88 O7.01 Y0.85'
_chemical_name_systematic
;
Yttrium calcium barium copper cobalt oxide (0.9/0.1/2/2.9/0.1/7.01)
;
_space_group_IT_number           47
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      47
_symmetry_space_group_name_Hall  '-P 2 2'
_symmetry_space_group_name_H-M   'P m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   3.8424(2)
_cell_length_b                   3.8810(2)
_cell_length_c                   11.6821(5)
_cell_volume                     174.2
_refine_ls_R_factor_all          0.03
_cod_original_formula_sum        'Ba2 Ca.15 Co.12 Cu2.88 O7.01 Y.85'
_cod_database_code               1001590