A RhII-AuII Bimetallic Core with a Direct Metal-Metal Bond
Arthur J. Esswein; Jillian L. Dempsey; Daniel G. Nocera; Inorganic Chemistry 46 (2007) 2362–2364; doi:10.1021/ic062203f

data_4307705
_publ_section_title
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A RhII-AuII Bimetallic Core with a Direct Metal-Metal Bond
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_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2362
_journal_page_last               2364
_journal_paper_doi               10.1021/ic062203f
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C23 H31 Au Cl4 F24 N3 O8 P4 Rh'
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; 
 ? 
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_computing_cell_refinement       'Bruker SMART'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
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_diffrn_reflns_limit_k_min       -30
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_diffrn_reflns_theta_min         1.55
_exptl_absorpt_coefficient_mu    3.840
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_exptl_absorpt_correction_T_min  0.5139
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_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.048
_exptl_crystal_density_meas      ?
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0725P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_file            ic062203fsi20061119_025119_3.cif
_cod_data_source_block           c06040_p21n
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Empirical' changed to
'empirical' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
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_cod_original_cell_volume        4862.4(9)
_cod_database_code               4307705