Synthetic Study of Phainanoids. Highly Diastereoselective Construction of the 4,5-Spirocycle via Palladium-Catalyzed Intramolecular Alkenylation.
Xie, Jiaxin; Wang, Jianchun; Dong, Guangbin; Organic letters 19 (2017) 3017–3020; doi:10.1021/acs.orglett.7b01303

data_1546079
_publ_section_title
;
 Synthetic Study of Phainanoids. Highly Diastereoselective Construction of
 the 4,5-Spirocycle via Palladium-Catalyzed Intramolecular Alkenylation.
;
_journal_issue                   11
_journal_name_full               'Organic letters'
_journal_page_first              3017
_journal_page_last               3020
_journal_paper_doi               10.1021/acs.orglett.7b01303
_journal_volume                  19
_journal_year                    2017
_chemical_formula_moiety         'C25 H24 O2'
_chemical_formula_sum            'C25 H24 O2'
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_computing_structure_solution
;

SUPERFLIP.  Palatinus, L. and Chapuis, G. (2007).  J. Appl. Cryst. 40, 786-790.
 
;
_diffrn_ambient_temperature      100(2)
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_diffrn_source                   'sealed fine focus tube'
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_exptl_absorpt_process_details
;
Abscor. T. Higashi (2001). The Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            colorless
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_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0431P)^2^+0.3912P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments          'Adding full bibliography for 1546079.cif.'
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