Sterically-directed disassembly of diruthenium(II,III) tetraacetate using substituted and unsubstituted 2,2'-bipyridines and 1,10-phenanthrolines
Luc J. Boudreau; Terri L. Clarke; Adrian H. Murray; Katherine N. Robertson; T. Stanley Cameron; Manuel A.S. Aquino; Inorganica Chimica Acta 393 (2012) 152–158; doi:

data_1512712
_publ_section_title
;
 Sterically-directed disassembly of diruthenium(II,III) tetraacetate using
 substituted and unsubstituted 2,2'-bipyridines and 1,10-phenanthrolines
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              152
_journal_page_last               158
_journal_volume                  393
_journal_year                    2012
_chemical_formula_moiety         'C31 H32 Cl2 F6 N4 O2 P Ru '
_chemical_formula_sum            'C31 H32 Cl2 F6 N4 O2 P Ru'
_chemical_formula_weight         809.56
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 111.634(11)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   18.122(2)
_cell_length_b                   14.985(2)
_cell_length_c                   12.984(2)
_cell_measurement_reflns_used    24
_cell_measurement_temperature    153.1
_cell_measurement_theta_max      40.0
_cell_measurement_theta_min      39.8
_cell_volume                     3277.5(8)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR2004
_diffrn_ambient_temperature      153.1
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Rigaku AFC5R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.071
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            2764
_diffrn_reflns_theta_full        63.80
_diffrn_reflns_theta_max         63.80
_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 0
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    6.469
_exptl_absorpt_correction_T_max  0.943
_exptl_absorpt_correction_T_min  0.645
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.641
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1636.00
_exptl_crystal_size_max          0.51
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.23
_refine_diff_density_max         1.14
_refine_diff_density_min         -1.17
_refine_ls_extinction_coef       10(4)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     221
_refine_ls_number_reflns         2388
_refine_ls_R_factor_gt           0.0655
_refine_ls_shift/su_max          0.0046
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details
;
    Chebychev polynomial with 3 parameters (Carruthers & Watkin, 1979)
    7.9083    1.7338    6.3758
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0768
_reflns_number_gt                2388
_reflns_number_total             2643
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ICA-2013-394-152-158-2.cif
_cod_data_source_block           Complex-6
_cod_original_cell_volume        3277.3(8)
_cod_original_formula_sum        'C31 H32 Cl2 F6 N4 O2 P Ru '
_cod_database_code               1512712