Bis-tetradentate complexes of Cd(ii) and Hg(ii) with N8 coordination: structural and NMR comparisons.
Bowers, Edith V.; Murphy, Geoffrey S.; Till, Stephanie N.; VandenBussche, Christopher J.; Yaroschak, Melissa M.; Pike, Robert D.; Butcher, Raymond J.; Bebout, Deborah C.; Dalton transactions (Cambridge, England : 2003) 43 (2014) 16475–16485; doi:10.1039/c4dt02435d

data_7032570
_publ_section_title
;
 Bis-tetradentate complexes of Cd(ii) and Hg(ii) with N8 coordination:
 structural and NMR comparisons.
;
_journal_issue                   43
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              16475
_journal_page_last               16485
_journal_paper_doi               10.1039/c4dt02435d
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C34 H38 Hg N10, 2(Cl O4), C7 H8'
_chemical_formula_sum            'C41 H46 Cl2 Hg N10 O8'
_chemical_formula_weight         1078.37
_chemical_name_systematic
'bis(((1-Methylimidazol-2-yl)methyl)bis((2-pyridyl)methyl)amine-N,N',N'',N''')-mercury(ii) diperchlorate'
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
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;
Psi-scans: North, A. C. T., Phillips, D. C. and Mathews, F. S. (1968) 
Acta. Cryst. A24, 351-359
;
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'Re-crystallisation from solvent: acetonitrile/toluene'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0483P)^2^]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 7032566--7032570.cif.'
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