Hydroalumination of Alkenes and Alkynes by Primary Aluminum Hydrides under Mild Conditions
Fettinger, James C.; Gray, Paul A.; Melton, Christopher E.; Power, Philip P.; Organometallics 33 (2014) 6232–; doi:10.1021/om500911f

data_4084517
_publ_section_title
;
 Hydroalumination of Alkenes and Alkynes by Primary Aluminum Hydrides
 under Mild Conditions
;
_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              6232
_journal_paper_doi               10.1021/om500911f
_journal_volume                  33
_journal_year                    2014
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_chemical_formula_moiety         'C58 H79 Al'
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;
 ?
;
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_cell_measurement_reflns_used    4165
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_cell_volume                     6083.0(11)
_computing_cell_refinement       'SAINT (8.27b) (Bruker, 2012)'
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;
;
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;
 Flack x determined using 6195 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   0.01(6)
_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0836P)^2^+1.1925P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1124
_refine_ls_wR_factor_ref         0.1138
_reflns_Friedel_coverage         0.955
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_reflns_number_gt                13045
_reflns_number_total             13592
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            om500911f_si_002.cif
_cod_data_source_block           cem031f_shelxl
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2827 2014-09-09 07:05:25Z andrius 

 Adding full bibliography for 4084515--4084521.cif.
;
_cod_original_cell_volume        6083.0(10)
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