Regioselective B(3)-H bond activation based on an o-carboranyl dithiocarboxylate ligand and its derivatives.
Yuan, Run-Ze; Cui, Peng-Fei; Guo, Shu-Ting; Jin, Guo-Xin; Dalton transactions (Cambridge, England : 2003) 50 (2021) 1060–1068; doi:10.1039/d0dt03832f

data_7705932
_publ_section_title
;
 Regioselective B(3)-H bond activation based on an o-carboranyl
 dithiocarboxylate ligand and its derivatives.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1060
_journal_page_last               1068
_journal_paper_doi               10.1039/d0dt03832f
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C16 H37 B20 Ir S4'
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_audit_update_record
;
2020-11-04 deposited with the CCDC.	2020-12-08 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_limit_h_max       14
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_refine_ls_R_factor_all          0.0352
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0207P)^2^+9.7714P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0643
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_reflns_number_gt                5529
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt03832f2.cif
_cod_data_source_block           ga_200723d_a
_cod_depositor_comments
'Adding full bibliography for 7705931--7705941.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
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_shelx_shelxl_version_number     2016/6
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_shelx_res_checksum              1401