On the reactivity of complexes [Ni(NHC)<sub>2</sub>] with CS<sub>2</sub>.
Luff, Martin Simon; Corsei, Celine Sophie; Radius, Udo; Dalton transactions (Cambridge, England : 2003) 54 (2025) 3750–3758; doi:10.1039/d4dt03497j

data_7717873
_publ_section_title
;
 On the reactivity of complexes [Ni(NHC)<sub>2</sub>] with CS<sub>2</sub>.
;
_journal_issue                   9
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3750
_journal_page_last               3758
_journal_paper_doi               10.1039/d4dt03497j
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C19 H32 N4 Ni S2'
_chemical_formula_sum            'C19 H32 N4 Ni S2'
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;
2024-12-19 deposited with the CCDC.	2025-01-22 downloaded from the CCDC.
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;
CrysAlisPro 1.171.41.92a (Rigaku Oxford Diffraction, 2020)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
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;
 Flack x determined using 1890 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.000(12)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0431P)^2^+1.8091P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7717872--7717875.cif.'
_cod_database_code               7717873
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.439
_shelx_estimated_absorpt_t_max   0.680
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