Hydride-Bridged Pt2M2Pt2Hexanuclear Metal Strings (M = Pt, Pd) Derived from Reductive Coupling of Pt2M Building Blocks Supported by Triphosphine Ligands
Goto, Eri; Begum, Rowshan Ara; Hosokawa, Aya; Yamamoto, Chie; Kure, Bunsho; Nakajima, Takayuki; Tanase, Tomoaki; Organometallics 31 (2012) 8482–; doi:10.1021/om300680p

data_4079329
_publ_section_title
;
 Hydride-Bridged Pt2M2Pt2Hexanuclear Metal Strings (M = Pt, Pd) Derived
 from Reductive Coupling of Pt2M Building Blocks Supported by Triphosphine
 Ligands
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              8482
_journal_paper_doi               10.1021/om300680p
_journal_volume                  31
_journal_year                    2012
_chemical_formula_moiety         'C153.50 H152 Cl7 F18 N2 O P15 Pd2 Pt4 '
_chemical_formula_sum            'C153.5 H152 Cl7 F18 N2 O P15 Pd2 Pt4'
_chemical_formula_weight         4088.81
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                91.459(3)
_cell_angle_beta                 89.822(2)
_cell_angle_gamma                94.575(3)
_cell_formula_units_Z            2
_cell_length_a                   20.405(4)
_cell_length_b                   21.847(4)
_cell_length_c                   18.268(3)
_cell_measurement_reflns_used    13473
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      3.0
_cell_volume                     8115(3)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_molecular_graphics    'Mercury 2.4'
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SHELXS97
_diffrn_ambient_temperature      153(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.055
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            75992
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.45
_exptl_absorpt_coefficient_mu    3.971
_exptl_absorpt_correction_T_max  0.452
_exptl_absorpt_correction_T_min  0.350
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            darkgreen
_exptl_crystal_density_diffrn    1.673
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             4010.00
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         2.01
_refine_diff_density_min         -1.73
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_number_parameters     1838
_refine_ls_number_reflns         35985
_refine_ls_R_factor_gt           0.0629
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0989P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1930
_reflns_number_gt                24391
_reflns_number_total             35985
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om300680p_si_002.cif
_cod_data_source_block           '_complex3a'
_cod_original_cell_volume        8115(2)
_cod_original_formula_sum        'C153.50 H152 Cl7 F18 N2 O P15 Pd2 Pt4 '
_cod_database_code               4079329