Synthesis, Structure, and Properties of a T-Shaped 14-Electron Stiboranyl-Gold Complex
Wade, Casey R.; Lin, Tzu-Pin; Nelson, Ryan C.; Mader, Elizabeth A.; Miller, Jeffrey T.; Gabbaï, François P; Journal of the American Chemical Society 133 (2011) 8948–8955; doi:10.1021/ja201092g

data_4106229
_publ_section_title
;
 Synthesis, Structure, and Properties of a T-Shaped 14-Electron
 Stiboranyl-Gold Complex
;
_journal_coden_ASTM              JACSAT
_journal_issue                   23
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              8948
_journal_page_last               8955
_journal_paper_doi               10.1021/ja201092g
_journal_volume                  133
_journal_year                    2011
_chemical_formula_moiety         'C32 H22 Au Sb'
_chemical_formula_sum            'C64 H44 Au2 Sb2'
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_symmetry_cell_setting           triclinic
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_cell_angle_beta                 82.757(3)
_cell_angle_gamma                69.417(3)
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_cell_length_a                   12.386(3)
_cell_length_b                   14.009(3)
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_cell_measurement_temperature    110(2)
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_cell_volume                     2321.8(9)
_computing_cell_refinement       'SAINT+ ver. (Bruker, 2001)'
_computing_data_collection       APEX2
_computing_data_reduction        'SAINT+ ver. (Bruker, 2001)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART APEX II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_limit_h_min       -14
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_diffrn_reflns_limit_l_min       -17
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_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.42
_exptl_absorpt_coefficient_mu    7.494
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.440095
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.075
_exptl_crystal_description       plate
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0540P)^2^+6.9500P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0936
_refine_ls_wR_factor_ref         0.1085
_reflns_number_gt                6665
_reflns_number_total             8148
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja201092g_si_002.cif
_cod_data_source_block           s
_cod_depositor_comments
;
 Updated bibliographic information.

 Antanas Vaitkus,
 2019-10-11
;
_cod_original_cell_volume        2321.9(10)
_cod_database_code               4106229