Cobalt-catalyzed conformationally restricted alkylarylation enables divergent access to Csp<sup>3</sup>-rich N-heterocycles.
Chen, Kaixin; Lin, Jie; Jing, Jing; Wang, Junda; Hu, Jiayu; Yi, Hong; Lei, Aiwen; Li, Jie; Chemical science 15 (2024) 16250–16258; doi:10.1039/d4sc04056b

data_1572485
_publ_section_title
;
 Cobalt-catalyzed conformationally restricted alkylarylation enables
 divergent access to Csp<sup>3</sup>-rich N-heterocycles.
;
_journal_issue                   39
_journal_name_full               'Chemical science'
_journal_page_first              16250
_journal_page_last               16258
_journal_paper_doi               10.1039/d4sc04056b
_journal_volume                  15
_journal_year                    2024
_chemical_formula_sum            'C26 H20 Cl F2 N O S'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2024-02-02 deposited with the CCDC.	2024-09-03 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
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_diffrn_measured_fraction_theta_max 0.994
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_diffrn_reflns_point_group_measured_fraction_max 0.994
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_diffrn_reflns_theta_max         53.996
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_refine_ls_matrix_type           full
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1254P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           b230317c1_0m
_cod_depositor_comments
'Adding full bibliography for 1572482--1572485.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1572485
_shelx_estimated_absorpt_t_min   0.771
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_shelx_res_checksum              26059
_shelx_hkl_checksum              32422