Stable homogeneous silver(I) catalysts for the highly efficient cycloaddition of azides onto terminal alkynes in water.
Kakavand, Meysam; Kozakiewicz-Piekarz, Anna; Neshat, Abdollah; Dalton transactions (Cambridge, England : 2003) 53 (2024) 18458–18461; doi:10.1039/d4dt02825b

data_7717478
_publ_section_title
;
 Stable homogeneous silver(I) catalysts for the highly efficient
 cycloaddition of azides onto terminal alkynes in water.
;
_journal_issue                   46
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18458
_journal_page_last               18461
_journal_paper_doi               10.1039/d4dt02825b
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         'C102 H84 Ag2 Fe3 P6, B2 F8'
_chemical_formula_sum            'C102 H84 Ag2 B2 F8 Fe3 P6'
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;
2024-09-05 deposited with the CCDC.	2024-11-06 downloaded from the CCDC.
;
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_diffrn_source                   'micro-focus sealed X-ray tube'
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;
CrysAlisPro 1.171.42.89a (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.476
_exptl_crystal_description       block
_exptl_crystal_F_000             1040
_exptl_crystal_size_max          0.054
_exptl_crystal_size_mid          0.037
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2019/2 (Sheldrick 2019)'
_refine_ls_goodness_of_fit_ref   1.041
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_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0556
_refine_ls_R_factor_gt           0.0502
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0741P)^2^+4.9397P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1324
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                8296
_reflns_number_total             9269
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7717477--7717478.cif.'
_cod_database_code               7717478
_shelx_shelxl_version_number     2019/3
_shelx_estimated_absorpt_t_min   0.656
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