An Unusual Ligand Coordination Gives Rise to a New Family of Rhodium Metalloinsertors with Improved Selectivity and Potency.
Komor, Alexis C.; Barton, Jacqueline K.; Journal of the American Chemical Society 136 (2014) 14160–; doi:10.1021/ja5072064

data_4122925
_publ_section_title
;
 An Unusual Ligand Coordination Gives Rise to a New Family of Rhodium
 Metalloinsertors with Improved Selectivity and Potency.
;
_journal_issue                   40
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              14160
_journal_paper_doi               10.1021/ja5072064
_journal_volume                  136
_journal_year                    2014
_chemical_formula_sum            'C45 H48 Cl2 N5 O3 Rh'
_chemical_formula_weight         880.69
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
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_cell_length_b                   15.4046(19)
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_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.59
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_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.907
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_exptl_crystal_colour            red
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_exptl_crystal_description       Block
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         11087
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0277P)^2^+2.2653P] where P=(Fo^2^+2Fc^2^)/3'
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_shelx_estimated_absorpt_t_min   0.759
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