Synthesis and properties of heterobimetallic rhodium complexes featuring Li<sup>I</sup>, Cu<sup>I</sup> or Zn<sup>II</sup> as a Lewis acidic metalloligand.
Steinhoff, Patrick; Steinbock, Ralf; Friedrich, Anna; Schieweck, Benjamin G.; Cremer, Christopher; Truong, Khai-Nghi; Tauchert, Michael E.; Dalton transactions (Cambridge, England : 2003) 47 (2018) 10439–10442; doi:10.1039/c8dt01267a

data_7047026
_publ_section_title
;
 Synthesis and properties of heterobimetallic rhodium complexes featuring
 Li<sup>I</sup>, Cu<sup>I</sup> or Zn<sup>II</sup> as a Lewis acidic
 metalloligand.
;
_journal_issue                   31
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10439
_journal_page_last               10442
_journal_paper_doi               10.1039/c8dt01267a
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C43 H36 Cl Li N4 O P2 Rh, C F3 O3 S'
_chemical_formula_sum            'C44 H36 Cl F3 Li N4 O4 P2 Rh S'
_chemical_formula_weight         981.07
_chemical_name_common            RS-22-1
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2018-03-30 deposited with the CCDC.
2018-07-05 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 96.943(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.8284(13)
_cell_length_b                   11.3718(11)
_cell_length_c                   29.6426(19)
_cell_measurement_reflns_used    1653
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      19.46
_cell_measurement_theta_min      2.26
_cell_volume                     4292.6(7)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        'SAINT-PLUS (Bruker, 2009)'
_computing_molecular_graphics    'PLATON (Spek, 2009)'
_computing_publication_material  'SHELXL2017 (Sheldrick, 2017)'
_computing_structure_refinement  'SHELXL2017 (Sheldrick, 2017)'
_computing_structure_solution    'SHELXS2013 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       '/w scans'
_diffrn_radiation_monochromator  'multilayer optics'
_diffrn_radiation_source         microsource
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1094
_diffrn_reflns_av_unetI/netI     0.0993
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            38602
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.514
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_exptl_absorpt_coefficient_mu    0.644
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.5859
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.518
_exptl_crystal_description       block
_exptl_crystal_F_000             1992
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.27
_refine_diff_density_max         0.543
_refine_diff_density_min         -0.728
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     550
_refine_ls_number_reflns         8851
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0790
_refine_ls_R_factor_gt           0.0488
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0242P)^2^+0.6999P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1029
_refine_ls_wR_factor_ref         0.1141
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6305
_reflns_number_total             8851
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt01267a3.cif
_cod_data_source_block           1-Li
_cod_depositor_comments
'Adding full bibliography for 7047026--7047028.cif.'
_cod_database_code               7047026
_shelx_shelxl_version_number     2017/1
_shelx_estimated_absorpt_t_min   0.825
_shelx_estimated_absorpt_t_max   0.845
_shelx_res_checksum              18772