Purinyl <i>N</i>-directed aroylation of 6-arylpurine ribo- and 2'-deoxyribonucleosides, and mechanistic insights.
Lakshman, Mahesh K.; Malinchak, Casina T.; Shank, Nathaniel; Neary, Michelle C.; Stahl, Lothar; Organic & biomolecular chemistry 22 (2024) 6718–6726; doi:10.1039/d4ob00689e

data_7159977
_publ_section_title
;
 Purinyl <i>N</i>-directed aroylation of 6-arylpurine ribo- and
 2'-deoxyribonucleosides, and mechanistic insights.
;
_journal_issue                   33
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              6718
_journal_page_last               6726
_journal_paper_doi               10.1039/d4ob00689e
_journal_volume                  22
_journal_year                    2024
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_audit_update_record
;
2024-02-16 deposited with the CCDC.	2024-06-13 downloaded from the CCDC.
;
_cell_angle_alpha                91.2850(10)
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_computing_cell_refinement       'Bruker SMART'
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_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0661P)^2^+0.2896P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1197
_refine_ls_wR_factor_ref         0.1275
_reflns_number_gt                6077
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_cod_data_source_file            d4ob00689e2.cif
_cod_data_source_block           ml1_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 

 Adding full bibliography for 7159976--7159977.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C32.50 H23.50 N4 O'
_cod_database_code               7159977