Diastereomeric separations and crystal structures of rhodium(iii) and iridium(iii) complexes containing adenosine and related nucleosidesElectronic supplementary information (ESI) available: 1H NMR and CD spectra. See http://www.rsc.org/suppdata/dt/b2/b209148h/
Yamanari, Kazuaki; Ito, Rie; Yamamoto, Shiori; Konno, Takumi; Fuyuhiro, Akira; Kobayashi, Mako; Arakawa, Ryuichi; Dalton Transactions  (2003) 380–; doi:10.1039/b209148h

data_7702871
_publ_section_title
;
 Diastereomeric separations and crystal structures of rhodium(iii) and
 iridium(iii) complexes containing adenosine and related
 nucleosidesElectronic supplementary information (ESI) available: 1H NMR
 and CD spectra. See http://www.rsc.org/suppdata/dt/b2/b209148h/
;
_journal_issue                   3
_journal_name_full               'Dalton Transactions'
_journal_page_first              380
_journal_paper_doi               10.1039/b209148h
_journal_year                    2003
_chemical_formula_moiety         'C44 H68 F6 N10 O19 S2 Rh2 '
_chemical_formula_sum            'C44 H68 F6 N10 O19 Rh2 S2'
_chemical_formula_weight         1425.00
_space_group_IT_number           4
_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      4
_symmetry_space_group_name_H-M   'P 1 21 1'
_audit_creation_date             'Tue Dec 26 12:49:12 2000'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90
_cell_angle_beta                 107.9928(5)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   12.1434(3)
_cell_length_b                   16.3817(4)
_cell_length_c                   15.6214(4)
_cell_measurement_reflns_used    60364
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.8
_cell_volume                     2955.58(13)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  SHELXL97
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 10.00
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.000
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            16294
_diffrn_reflns_theta_max         27.49
_exptl_absorpt_coefficient_mu    0.724
_exptl_absorpt_correction_T_max  0.749
_exptl_absorpt_correction_T_min  0.433
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.601
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.500
_exptl_crystal_size_min          0.400
_refine_diff_density_max         1.79
_refine_diff_density_min         -0.92
_refine_ls_abs_structure_Flack   0.03(3)
_refine_ls_extinction_coef       0.0000
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     747
_refine_ls_number_reflns         10728
_refine_ls_R_factor_gt           0.0483
_refine_ls_shift/su_max          -0.1290
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1378
_reflns_number_gt                10728
_reflns_number_total             12938
_reflns_threshold_expression     >2.0sigma(I)
_cod_data_source_file            b209148h.txt
_cod_data_source_block           '[Rh2(OH)2(Cp*)2(N-CH3-Hade'
_cod_original_cell_volume        2955.6(1)
_cod_original_formula_sum        'C44 H68 F6 N10 O19 S2 Rh2 '
_cod_database_code               7702871