Thioether-NHC bidentate manganese complexes as efficient phosphine-free catalysts for hydrogenation at room temperature.
Hruzd, Mariia; Kleynemeyer, Sabrina L.; Michon, Christophe; Bastin, Stéphanie; Pollet, Eric; Ritleng, Vincent; Sortais, Jean-Baptiste; Chemical communications (Cambridge, England) 61 (2025) 2969–2972; doi:10.1039/d4cc06627h

data_7134178
_publ_section_title
;
 Thioether-NHC bidentate manganese complexes as efficient phosphine-free
 catalysts for hydrogenation at room temperature.
;
_journal_issue                   14
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              2969
_journal_page_last               2972
_journal_paper_doi               10.1039/d4cc06627h
_journal_volume                  61
_journal_year                    2025
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C23 H22 Br Mn N2 O3 S'
_chemical_formula_sum            'C23 H22 Br Mn N2 O3 S'
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;
2024-12-02 deposited with the CCDC.	2025-01-14 downloaded from the CCDC.
;
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;
 Flack x determined using 1897 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.027(5)
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_refine_ls_shift/su_mean         0.000
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'w=1/[\s^2^(Fo^2^)+(0.0295P)^2^+0.7612P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7134175--7134178.cif.'
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