3D to 2D reorganization of silver-thiol nanostructures, triggered by solvent vapor annealing.
Dell'Elce, Simone; Liscio, Fabiola; Kovtun, Alessandro; Allegri, Stefano; Roscioni, Otello M.; Albonetti, Cristiano; De Luca, Giovanna; Amenitsch, Heinz W.; Demitri, Nicola; Giorgini, Loris; Morandi, Vittorio; Stellacci, Francesco; Liscio, Andrea; Palermo, Vincenzo; Nanoscale 10 (2018) 23018–23026; doi:10.1039/c8nr07109h

data_1550316
_publ_section_title
;
 3D to 2D reorganization of silver-thiol nanostructures, triggered by
 solvent vapor annealing.
;
_journal_issue                   48
_journal_name_full               Nanoscale
_journal_page_first              23018
_journal_page_last               23026
_journal_paper_doi               10.1039/c8nr07109h
_journal_volume                  10
_journal_year                    2018
_chemical_formula_moiety         'Ag44, 30 (C6 H4 F S), 4 (C24 H20 P)'
_chemical_formula_sum            'C276 H200 Ag44 F30 P4 S30'
_chemical_formula_weight         9918.31
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
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_atom_sites_solution_primary     direct
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_audit_update_record
;
2018-03-15 deposited with the CCDC.
2018-10-10 downloaded from the CCDC.
;
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_computing_molecular_graphics    'Ortep3 for Windows - Coot'
_computing_publication_material  'enCIFer - publCIF'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
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_diffrn_measured_fraction_theta_full 0.942
_diffrn_measured_fraction_theta_max 0.942
_diffrn_measurement_device_type
;
'Huber 4-circles Kappa Goniometer, Pilatus 2M detector'
;
_diffrn_measurement_method       'Rotating crystal'
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_diffrn_reflns_limit_h_min       -23
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_diffrn_reflns_point_group_measured_fraction_full 0.942
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_diffrn_source                   'Elettra Synchrotron - XRD1 BL'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.30a (Agilent, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Black
_exptl_crystal_density_diffrn    2.281
_exptl_crystal_description       'Thick prisms'
_exptl_crystal_F_000             4734
_exptl_crystal_size_max          0.100
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_refine_ls_R_factor_all          0.0880
_refine_ls_R_factor_gt           0.0585
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0559P)^2^+0.0543P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                15408
_reflns_number_total             22412
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           AgNPRT
_cod_depositor_comments
'Adding full bibliography for 1550315--1550316.cif.'
_cod_original_cell_volume        7219.0(3)
_cod_database_code               1550316
_shelx_shelxl_version_number     2017/1
_shelx_estimated_absorpt_t_min   0.744
_shelx_estimated_absorpt_t_max   0.912
_shelx_res_checksum              63648
_shelx_hkl_checksum              11996