Direct Observation of Oxidative Cyclization of η2-Alkene and η2-Aldehyde on Ni(0) Center. Significant Acceleration by Addition of Me3SiOTf
Sensuke Ogoshi; Masa-aki Oka; Hideo Kurosawa; Journal of the American Chemical Society 126 (2004) 11802–11803; doi:10.1021/ja0460716

data_4112960
_publ_section_title
;
 Direct Observation of Oxidative Cyclization of \h2-Alkene and
 \h2-Aldehyde on Ni(0) Center. Significant Acceleration by Addition of
 Me3SiOTf
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11802
_journal_page_last               11803
_journal_paper_doi               10.1021/ja0460716
_journal_volume                  126
_journal_year                    2004
_chemical_formula_moiety         'C68 H98 O2 Ni2 P2 '
_chemical_formula_sum            'C68 H98 Ni2 O2 P2'
_chemical_formula_weight         1126.87
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_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                98.863(2)
_cell_angle_beta                 95.684(3)
_cell_angle_gamma                95.960(4)
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_cell_length_b                   11.348(1)
_cell_length_c                   12.122(1)
_cell_measurement_reflns_used    8886
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_cell_volume                     1511.9(2)
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_computing_publication_material  'CrystalStructure 3.6.0'
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_diffrn_measured_fraction_theta_max 0.9701
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
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_diffrn_radiation_wavelength     0.7107
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_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            10284
_diffrn_reflns_theta_full        27.43
_diffrn_reflns_theta_max         27.43
_exptl_absorpt_coefficient_mu    0.719
_exptl_absorpt_correction_T_max  0.866
_exptl_absorpt_correction_T_min  0.592
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
    Higashi, T. (1995). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            unknown
_exptl_crystal_density_diffrn    1.238
_exptl_crystal_description       block
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_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         3.14
_refine_diff_density_min         -3.66
_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.0140
_refine_ls_structure_factor_coef Fsqd
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_reflns_threshold_expression     F^2^>2.0\s(F^2^)
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_cod_data_source_block           '_oka'
_cod_original_formula_sum        'C68 H98 O2 Ni2 P2 '
_cod_database_code               4112960