Synthesis and structural features of the first thallium(I) selenoether derivatives
Hill, Nicholas J.; Levason, William; Light, Mark E.; Reid, Gillian; Chemical Communications (Cambridge, United Kingdom)  (2003) 110–111; doi:10.1039/b209729j

data_7103631
_publ_section_title
;
 Synthesis and structural features of the first thallium(I) selenoether
 derivatives
;
_journal_coden_ASTM              CHCOFS
_journal_issue                   1
_journal_name_full
;
 Chemical Communications (Cambridge, United Kingdom)
;
_journal_page_first              110
_journal_page_last               111
_journal_paper_doi               10.1039/b209729j
_journal_year                    2003
_chemical_compound_source        MeCN
_chemical_formula_moiety         '[Tl{MeSe(CH2)2SeMe}]PF6'
_chemical_formula_sum            'C4 H10 F6 P Se2 Tl'
_chemical_formula_weight         565.38
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 92.311(2)
_cell_angle_gamma                90
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_cell_length_b                   9.0243(3)
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_cell_measurement_temperature    120.0(1)
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_cell_volume                     1179.06(5)
_computing_cell_refinement       'Nonius Kappa CCD Diffractometer Control'
_computing_data_collection       'Nonius Kappa CCD Diffractometer Control'
_computing_data_reduction
'teXsan for Windows version 1.06 (MSC, 1997-1999)'
_computing_publication_material
'teXsan for Windows version 1.06 (MSC, 1997-1999)'
_computing_structure_refinement
'teXsan for Windows version 1.06 (MSC, 1997-1999)'
_computing_structure_solution
;
DIRDIF92 PATTY (Beurskens, 1992)
;
_diffrn_ambient_temperature      120.0(1)
_diffrn_measurement_device       'Nonius Kappa CCD'
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_diffrn_radiation_detector       'mercury CCD'
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_diffrn_radiation_source         'X-ray tube'
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_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_reduction_process 'Lp corrections applied'
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_diffrn_standards_decay_%        0.00
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_refine_ls_abs_structure_Flack   -
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_refine_ls_extinction_method     none
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_refine_ls_goodness_of_fit_ref   1.650
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_refine_ls_R_factor_gt           0.0370
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_refine_ls_shift/su_mean         0.0002
_refine_ls_structure_factor_coef F
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_reflns_threshold_expression     I>2.00\s(I)
_cod_data_source_file            b209729j.txt
_cod_data_source_block           Template_texray.inf
_cod_original_sg_symbol_H-M      'P 21/n     '
_cod_original_formula_sum        'C4 H10 F6 P Se2 Tl '
_cod_database_code               7103631