LMucko/crystallography-open-database huggingface dataset:
Pd-Pt Heterobimetallic Complexes with Bridging Si-Ligands. Structure and Reaction with Isonitrile to Afford a Platinacyclopentane Containing Si, N, and C Atoms
Tetsuyuki Yamada; Makoto Tanabe; Kohtaro Osakada; Yong-Joo Kim; Organometallics  (2004) –; doi:10.1021/om049858d

data_4063057
_publ_section_title
;
Pd-Pt Heterobimetallic Complexes with Bridging Si-Ligands. Structure
and Reaction with Isonitrile to Afford
a Platinacyclopentane Containing Si, N, and C Atoms
;
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049858d
_journal_year                    2004
_chemical_formula_moiety         'C42 H65 P3 Pd Pt Si2 '
_chemical_formula_sum            'C42 H65 P3 Pd Pt Si2'
_chemical_formula_weight         1020.56
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                65.69(1)
_cell_angle_beta                 73.11(2)
_cell_angle_gamma                78.03(2)
_cell_formula_units_Z            4
_cell_length_a                   11.8945(5)
_cell_length_b                   20.3726(8)
_cell_length_c                   21.3757(7)
_cell_measurement_temperature    293.1
_cell_volume                     4494.1(3)
_exptl_crystal_density_diffrn    1.508
_cod_original_formula_sum        'C42 H65 P3 Pd Pt Si2 '
_cod_database_code               4063057
Pd-Pt Heterobimetallic Complexes with Bridging Si-Ligands. Structure and Reaction with Isonitrile to Afford a Platinacyclopentane Containing Si, N, and C Atoms
Tetsuyuki Yamada; Makoto Tanabe; Kohtaro Osakada; Yong-Joo Kim; Organometallics  (2004) –; doi:10.1021/om049858d

data_4063058
_publ_section_title
;
Pd-Pt Heterobimetallic Complexes with Bridging Si-Ligands. Structure
and Reaction with Isonitrile to Afford
a Platinacyclopentane Containing Si, N, and C Atoms
;
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049858d
_journal_year                    2004
_chemical_formula_moiety         'C80 H110 N4 P2 Pt2 Si4 '
_chemical_formula_sum            'C80 H110 N4 P2 Pt2 Si4'
_chemical_formula_weight         1692.25
_space_group_IT_number           1
_space_group_name_Hall           'P 1'
_space_group_name_H-M_alt        'P 1'
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      1
_symmetry_space_group_name_Hall  'P 1'
_symmetry_space_group_name_H-M   'P 1'
_cell_angle_alpha                73.20(2)
_cell_angle_beta                 81.52(2)
_cell_angle_gamma                58.98(1)
_cell_formula_units_Z            1
_cell_length_a                   11.787(3)
_cell_length_b                   12.124(3)
_cell_length_c                   17.936(6)
_cell_measurement_temperature    293.1
_cell_volume                     2102.8(10)
_exptl_crystal_density_diffrn    1.336
_cod_original_formula_sum        'C80 H110 N4 P2 Pt2 Si4 '
_cod_database_code               4063058
Pd-Pt Heterobimetallic Complexes with Bridging Si-Ligands. Structure and Reaction with Isonitrile to Afford a Platinacyclopentane Containing Si, N, and C Atoms
Tetsuyuki Yamada; Makoto Tanabe; Kohtaro Osakada; Yong-Joo Kim; Organometallics  (2004) –; doi:10.1021/om049858d

data_4063059
_publ_section_title
;
Pd-Pt Heterobimetallic Complexes with Bridging Si-Ligands. Structure
and Reaction with Isonitrile to Afford
a Platinacyclopentane Containing Si, N, and C Atoms
;
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049858d
_journal_year                    2004
_chemical_formula_moiety         'C46 H68 N2 P2 Pt2 Si2'
_chemical_formula_sum            'C46 H68 N2 P2 Pt2 Si2'
_chemical_formula_weight         1157.36
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 106.471(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   19.222(5)
_cell_length_b                   11.727(2)
_cell_length_c                   22.376(5)
_cell_measurement_temperature    293.1
_cell_volume                     4836.7(20)
_exptl_crystal_density_diffrn    1.589
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4063059
Walter Figueroa; Mauricio Fuentealba; Carolina Manzur; David Carrilllo; Andrés Vega; Jean-Yves Saillard; Jean-Rene Hamon; Organometallics  (2004) –; doi:10.1021/om0498605

data_4063060
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om0498605
_journal_year                    2004
_chemical_formula_sum            'C20.8 H22.6 Cl1.6 Fe N3'
_chemical_formula_weight         427.19
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 102.40(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.19(3)
_cell_length_b                   8.056(15)
_cell_length_c                   14.43(3)
_cell_measurement_temperature    293(2)
_cell_volume                     2065(7)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.374
_cod_depositor_comments
;
The following automatic conversions were performed:
'_geom_bond_publ_flag' value 'Y' changed to 'y' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (9 times).

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C20.80 H22.60 Cl1.60 Fe N3'
_cod_database_code               4063060
; Organometallics  (2004) –; doi:10.1021/om049861x

data_4063061
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049861x
_journal_year                    2004
_chemical_formula_sum            'C10 H29 Al Cl N Si2'
_chemical_formula_weight         281.95
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 93.782(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.852(2)
_cell_length_b                   13.087(3)
_cell_length_c                   14.642(4)
_cell_measurement_temperature    150(2)
_cell_volume                     1692.6(7)
_diffrn_ambient_temperature      150(2)
_exptl_crystal_density_diffrn    1.106
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4063061
; Organometallics  (2004) –; doi:10.1021/om049861x

data_4063062
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049861x
_journal_year                    2004
_chemical_formula_sum            'C5 H14 Al Cl2 N'
_chemical_formula_weight         186.05
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   6.2541(5)
_cell_length_b                   10.3327(6)
_cell_length_c                   15.1307(9)
_cell_measurement_temperature    150(2)
_cell_volume                     977.77(11)
_diffrn_ambient_temperature      150(2)
_exptl_crystal_density_diffrn    1.264
_cod_database_code               4063062
; Organometallics  (2004) –; doi:10.1021/om049863h

data_4063063
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049863h
_journal_year                    2004
_chemical_formula_sum            'C71 H131 N3 O15 Si6 Zn8'
_chemical_formula_weight         1958.29
_space_group_IT_number           1
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  'P 1'
_symmetry_space_group_name_H-M   'P 1'
_cell_angle_alpha                68.66(3)
_cell_angle_beta                 69.74(3)
_cell_angle_gamma                79.88(3)
_cell_formula_units_Z            1
_cell_length_a                   12.893(3)
_cell_length_b                   13.297(3)
_cell_length_c                   15.071(3)
_cell_measurement_temperature    133(2)
_cell_volume                     2254.4(8)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.442
_cod_database_code               4063063
; Organometallics  (2004) –; doi:10.1021/om049863h

data_4063064
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049863h
_journal_year                    2004
_chemical_formula_sum            'C96 H166 N4 O17 Si8 Zn7'
_chemical_formula_weight         2330.64
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                96.43(3)
_cell_angle_beta                 100.64(3)
_cell_angle_gamma                114.54(3)
_cell_formula_units_Z            2
_cell_length_a                   14.512(3)
_cell_length_b                   15.663(3)
_cell_length_c                   28.867(6)
_cell_measurement_temperature    133(2)
_cell_volume                     5734(2)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.350
_cod_database_code               4063064
; Organometallics  (2004) –; doi:10.1021/om049863h

data_4063065
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049863h
_journal_year                    2004
_chemical_formula_sum            'C102 H172 O17 Si8 Zn8'
_chemical_formula_weight         2418.08
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                82.35(3)
_cell_angle_beta                 89.79(3)
_cell_angle_gamma                66.49(3)
_cell_formula_units_Z            2
_cell_length_a                   14.436(3)
_cell_length_b                   16.042(3)
_cell_length_c                   27.288(6)
_cell_measurement_temperature    133(2)
_cell_volume                     5735(2)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.400
_cod_database_code               4063065
; Organometallics  (2004) –; doi:10.1021/om049866u

data_4063066
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049866u
_journal_year                    2004
_chemical_formula_sum            'C39 H0 N9 Y'
_chemical_formula_weight         683.39
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                105.460(5)
_cell_angle_beta                 92.172(5)
_cell_angle_gamma                119.811(4)
_cell_formula_units_Z            2
_cell_length_a                   13.302(5)
_cell_length_b                   13.375(5)
_cell_length_c                   17.960(6)
_cell_measurement_temperature    293(2)
_cell_volume                     2616.1(16)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    0.868
_cod_database_code               4063066
; Organometallics  (2004) –; doi:10.1021/om049866u

data_4063067
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049866u
_journal_year                    2004
_chemical_formula_sum            'C23 H38 N3 Y'
_chemical_formula_weight         445.47
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 108.416(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.803(4)
_cell_length_b                   30.028(12)
_cell_length_c                   9.573(4)
_cell_measurement_temperature    293(2)
_cell_volume                     2401.0(16)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.232
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4063067
; Organometallics  (2004) –; doi:10.1021/om049866u

data_4063068
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049866u
_journal_year                    2004
_chemical_formula_sum            'C21 H34 N3 Yb'
_chemical_formula_weight         501.55
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   11.068(7)
_cell_length_b                   15.049(9)
_cell_length_c                   26.599(16)
_cell_measurement_temperature    298(2)
_cell_volume                     4430(5)
_diffrn_ambient_temperature      298(2)
_exptl_crystal_density_diffrn    1.504
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4063068
; Organometallics  (2004) –; doi:10.1021/om049866u

data_4063069
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049866u
_journal_year                    2004
_chemical_formula_sum            'C21 H34 Er N3'
_chemical_formula_weight         495.77
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   11.058(5)
_cell_length_b                   15.086(7)
_cell_length_c                   26.498(12)
_cell_measurement_temperature    293(2)
_cell_volume                     4420(3)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.490
_cod_database_code               4063069
; Organometallics  (2004) –; doi:10.1021/om049866u

data_4063070
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049866u
_journal_year                    2004
_chemical_formula_sum            'C21 H34 Dy N3'
_chemical_formula_weight         491.01
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   11.145(4)
_cell_length_b                   15.116(6)
_cell_length_c                   26.522(10)
_cell_measurement_temperature    293(2)
_cell_volume                     4468(3)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.460
_cod_database_code               4063070
; Organometallics  (2004) –; doi:10.1021/om049866u

data_4063071
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049866u
_journal_year                    2004
_chemical_formula_sum            'C23 H30 N3 Yb'
_chemical_formula_weight         521.54
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 98.600(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   9.0720(14)
_cell_length_b                   8.4415(13)
_cell_length_c                   14.682(2)
_cell_measurement_temperature    298(2)
_cell_volume                     1111.8(3)
_diffrn_ambient_temperature      298(2)
_exptl_crystal_density_diffrn    1.558
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               4063071
Regio- and stereoselective hydride addition at η-vinyliminium ligands in cationic diiron complexes.
Albano, V. G.; Busetto, L.; Marchetti, F.; Monari, M.; Zacchini, S.; Zanotti, V.; Organometallics 23 (2004) 3348–3354; doi:10.1021/om049868e

data_4063072
_publ_section_title
;
Regio- and stereoselective hydride addition at \h-vinyliminium ligands in 
cationic diiron complexes.
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3348
_journal_page_last               3354
_journal_paper_doi               10.1021/om049868e
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C24 H25 Fe2 N O2'
_chemical_formula_weight         471.15
_space_group_IT_number           2
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                83.718(3)
_cell_angle_beta                 78.364(3)
_cell_angle_gamma                79.393(3)
_cell_formula_units_Z            2
_cell_length_a                   8.1439(8)
_cell_length_b                   10.3485(10)
_cell_length_c                   12.8178(12)
_cell_measurement_temperature    293(2)
_cell_volume                     1037.03(17)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.509
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4063072
Regio- and stereoselective hydride addition at η-vinyliminium ligands in cationic diiron complexes.
Albano, V. G.; Busetto, L.; Marchetti, F.; Monari, M.; Zacchini, S.; Zanotti, V.; Organometallics 23 (2004) 3348–3354; doi:10.1021/om049868e

data_4063073
_publ_section_title
;
Regio- and stereoselective hydride addition at \h-vinyliminium ligands in 
cationic diiron complexes.
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3348
_journal_page_last               3354
_journal_paper_doi               10.1021/om049868e
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C26 H27 Fe2 N O4'
_chemical_formula_weight         529.19
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 94.6270(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.6352(3)
_cell_length_b                   13.2769(3)
_cell_length_c                   16.3383(4)
_cell_measurement_temperature    293(2)
_cell_volume                     2299.49(10)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.529
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4063073
H2-Pd(II) and Pt(II) Complexes of a lambda4-Phosphinine anion: Syntheses, X-Ray Crystal Structures and DFT Calculations.
A. Moores; N. Mezailles; L. Ricard; Y. Jean; P. Le Floch; Organometallics  (2004) –; doi:10.1021/om049871y

data_4063074
_publ_section_title
;
H2-Pd(II) and Pt(II) Complexes of a lambda4-Phosphinine anion:
Syntheses, X-Ray Crystal Structures and DFT Calculations.
;
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om049871y
_journal_year                    2004
_chemical_formula_sum            'C42 H47 Cl P2 Pd Si2'
_chemical_formula_weight         811.77
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 106.4700(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.7040(10)
_cell_length_b                   18.8580(10)
_cell_length_c                   17.2190(10)
_cell_measurement_temperature    150.0(10)
_cell_volume                     3955.9(4)
_diffrn_ambient_temperature      150.0(10)
_exptl_crystal_density_diffrn    1.363
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4063074