Scandium bis(trimethylsilyl)methyl complexes revisited: extending the <sup>45</sup>Sc NMR chemical shift range and a new structural motif of Li[CH(SiMe<sub>3</sub>)<sub>2</sub>].
Mortis, Alexandros; Barisic, Damir; Eichele, Klaus; Maichle-Mössmer, Cäcilia; Anwander, Reiner; Dalton transactions (Cambridge, England : 2003) 49 (2020) 7829–7841; doi:10.1039/d0dt01247e

data_7704428
_publ_section_title
;
 Scandium bis(trimethylsilyl)methyl complexes revisited: extending the
 <sup>45</sup>Sc NMR chemical shift range and a new structural motif of
 Li[CH(SiMe<sub>3</sub>)<sub>2</sub>].
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_paper_doi               10.1039/d0dt01247e
_journal_volume                  49
_journal_year                    2020
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;
2020-03-16 deposited with the CCDC.	2020-05-18 downloaded from the CCDC.
;
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'XT, VERSION 2014/5,SHELXS-13 (Sheldrick 2008)'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0423P)^2^+0.4492P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             4483
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           5_mo_db196c_0m_a
_cod_depositor_comments
'Adding full bibliography for 7704428--7704433.cif.'
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_cod_database_code               7704428
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_shelx_res_checksum              88068