The first example of polymeric lanthanide <i>tetrakis</i>-trifluoroacetates in chemical solution deposition of up-converting NaGdF<sub>4</sub>:Yb,Er,Nd thin films.
Burlakova, Maria; Blinnikova, Daria; Volkonovskiy, Gleb; Chai, Haoyang; Grebenyuk, Dimitry; Tsymbarenko, Dmitry; Dalton transactions (Cambridge, England : 2003) 53 (2024) 18183–18192; doi:10.1039/d4dt01114g

data_7717227
_publ_section_title
;
 The first example of polymeric lanthanide
 <i>tetrakis</i>-trifluoroacetates in chemical solution deposition of
 up-converting NaGdF<sub>4</sub>:Yb,Er,Nd thin films.
;
_journal_issue                   45
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18183
_journal_page_last               18192
_journal_paper_doi               10.1039/d4dt01114g
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         'C12 H26 F6 N6 O4 Yb, C2 F3 O2'
_chemical_formula_sum            'C14 H26 F9 N6 O6 Yb'
_chemical_formula_weight         718.45
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2024-10-05 deposited with the CCDC.	2024-10-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90.018(2)
_cell_angle_gamma                90
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_cell_length_c                   8.5495(6)
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_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.57
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_cell_volume                     2318.4(3)
_computing_cell_refinement       'SAINT (Bruker, 2014)'
_computing_data_collection       'APEX4 (Bruker, 2014)'
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_computing_molecular_graphics    'SHELXTL-2013/1 (Sheldrick, 2013)'
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_computing_structure_solution    'SHELXTL-2013/1 (Sheldrick, 2013)'
_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 Quest with Photon III detector'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_point_group_measured_fraction_full 0.997
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_diffrn_source                   'Micro-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    4.150
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            colorless
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_exptl_crystal_size_min          0.059
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+35.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                4746
_reflns_number_total             5041
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4dt01114g2.cif
_cod_data_source_block           Ybtfa3deta2
_cod_depositor_comments
'Adding full bibliography for 7717225--7717231.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7717227
_shelx_shelxl_version_number     2018/3
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_shelx_res_checksum              14364
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