Rh(III)-Catalyzed Diastereodivergent Spiroannulation of Cyclic Imines with Activated Alkenes.
Liu, Bingxian; Hu, Panjie; Zhang, Ying; Li, Yunyun; Bai, Dachang; Li, Xingwei; Organic letters 19 (2017) 5402–5405; doi:10.1021/acs.orglett.7b02678

data_1547397
_publ_section_title
;
 Rh(III)-Catalyzed Diastereodivergent Spiroannulation of Cyclic Imines
 with Activated Alkenes.
;
_journal_issue                   19
_journal_name_full               'Organic letters'
_journal_page_first              5402
_journal_page_last               5405
_journal_paper_doi               10.1021/acs.orglett.7b02678
_journal_volume                  19
_journal_year                    2017
_chemical_formula_moiety         'C22 H17 N O3 S'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43f (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0040P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             3078
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           436-4-1
_cod_depositor_comments
'Adding full bibliography for 1547395--1547397.cif.'
_cod_database_code               1547397
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