Different transmetallation behaviour of [M(P4HR4)] salts toward rhodium(i) and copper(i) (M = Na, K; R = Ph, Mes; Mes = 2,4,6-Me3C6H2)
Gómez-Ruiz, Santiago; Wolf, Robert; Hey-Hawkins, Evamarie; Dalton Transactions  (2008) 1982–1988; doi:10.1039/b718727k

data_7003687
_publ_section_title
;
 Different transmetallation behaviour of [M(P4HR4)] salts toward
 rhodium(i) and copper(i) (M = Na, K; R = Ph, Mes; Mes = 2,4,6-Me3C6H2)
;
_journal_issue                   15
_journal_name_full               'Dalton Transactions'
_journal_page_first              1982
_journal_page_last               1988
_journal_paper_doi               10.1039/b718727k
_journal_year                    2008
_chemical_formula_sum            'C44 H57 P4 Rh'
_chemical_formula_weight         812.69
_chemical_name_systematic
;
?
;
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_cell_angle_gamma                92.753(13)
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_cell_length_a                   8.2250(14)
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_cell_measurement_temperature    130(2)
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_computing_cell_refinement
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CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
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_computing_data_collection
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CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
;
_computing_data_reduction
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CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
;
_computing_molecular_graphics    'ORTEP3 for Windows (L. J. Farrugia, 1997)'
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_diffrn_ambient_temperature      130(2)
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'ccd xcalibur s'
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_diffrn_orient_matrix_UB_11      0.0381206203
_diffrn_orient_matrix_UB_12      0.0268802094
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_diffrn_orient_matrix_UB_21      -0.0522476259
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_diffrn_orient_matrix_UB_32      0.0308804222
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_diffrn_radiation_monochromator  graphite
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_exptl_absorpt_correction_type   multi-scan
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CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.333
_exptl_crystal_density_method    'not measured'
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_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0361P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0731
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_cod_data_source_file            b718727k.txt
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;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7003687