Unusual C‒C Bond Cleavage in the Formation of Amine-Bis(phenoxy) Group 4 Benzyl Complexes: Mechanism of Formation and Application to Stereospecific Polymerization
Gowda, Ravikumar R.; Caporaso, Lucia; Cavallo, Luigi; Chen, Eugene Y.-X.; Organometallics 33 (2014) 4118–; doi:10.1021/om500661y

data_4084153
_publ_section_title
;
 Unusual C--C Bond Cleavage in the Formation of Amine-Bis(phenoxy) Group 4
 Benzyl Complexes: Mechanism of Formation and Application to
 Stereospecific Polymerization
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              4118
_journal_paper_doi               10.1021/om500661y
_journal_volume                  33
_journal_year                    2014
_chemical_formula_sum            'C59 H75 N O2 Zr'
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_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
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_exptl_crystal_density_meas      ?
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;
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0984P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4084153.cif.

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
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_cod_database_code               4084153