(C<sub>6</sub>H<sub>15</sub>N<sub>3</sub>)<sub>1.3</sub>(NH<sub>4</sub>)<sub>1.5</sub>H<sub>1.5</sub>In<sub>3</sub>SnS<sub>8</sub>: a layered metal sulfide based on supertetrahedral T2 clusters with photoelectric response and ion exchange properties.
Yang, Lu; Wen, Xin; Yang, Tian; Hu, Qian-Qian; Liu, Jia-Ting; Yin, Hai-Yan; Ablez, Abdusalam; Feng, Mei-Ling; Huang, Xiao-Ying; Dalton transactions (Cambridge, England : 2003) 53 (2024) 6063–6069; doi:10.1039/d4dt00262h

data_7715403
_publ_section_title
;
 (C<sub>6</sub>H<sub>15</sub>N<sub>3</sub>)<sub>1.3</sub>(NH<sub>4</sub>)<sub>1.5</sub>H<sub>1.5</sub>In<sub>3</sub>SnS<sub>8</sub>:
 a layered metal sulfide based on supertetrahedral T2 clusters with
 photoelectric response and ion exchange properties.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6063
_journal_page_last               6069
_journal_paper_doi               10.1039/d4dt00262h
_journal_volume                  53
_journal_year                    2024
_chemical_formula_sum            'C7.8 H27 In3 N5.4 S8 Sn'
_chemical_formula_weight         916.18
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2024-01-26 deposited with the CCDC.	2024-03-05 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 97.750(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.0236(3)
_cell_length_b                   11.0240(3)
_cell_length_c                   21.0862(6)
_cell_measurement_reflns_used    16207
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30.5560
_cell_measurement_theta_min      2.6110
_cell_volume                     2539.08(12)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'XtaLAB Synergy R, HyPix'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_unetI/netI     0.0227
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -5
_diffrn_reflns_number            2251
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.024
_diffrn_reflns_theta_max         25.024
_diffrn_reflns_theta_min         1.949
_exptl_absorpt_coefficient_mu    4.327
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.397
_exptl_crystal_description       plate
_exptl_crystal_F_000             1746
_refine_diff_density_max         0.975
_refine_diff_density_min         -1.505
_refine_diff_density_rms         0.150
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.182
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     57
_refine_ls_number_reflns         2251
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.182
_refine_ls_R_factor_all          0.0474
_refine_ls_R_factor_gt           0.0408
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0305P)^2^+49.4379P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1049
_refine_ls_wR_factor_ref         0.1089
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1820
_reflns_number_total             2251
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4dt00262h2.cif
_cod_data_source_block           x_tw_Sq
_cod_depositor_comments          'Adding full bibliography for 7715403.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C7.80 H27 In3 N5.40 S8 Sn'
_cod_database_code               7715403
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              20916
_shelx_fab_checksum              66664