Distinctly different reactivity of bis(silylenyl)-<i>versus</i> phosphanyl-silylenyl-substituted <i>o</i>-dicarborane towards O<sub>2</sub>, N<sub>2</sub>O and CO<sub>2</sub>.
Xiong, Yun; Yao, Shenglai; Ruzicka, Ales; Driess, Matthias; Chemical communications (Cambridge, England) 57 (2021) 5965–5968; doi:10.1039/d1cc01939b

data_7128322
_publ_section_title
;
 Distinctly different reactivity of bis(silylenyl)-<i>versus</i>
 phosphanyl-silylenyl-substituted <i>o</i>-dicarborane towards
 O<sub>2</sub>, N<sub>2</sub>O and CO<sub>2</sub>.
;
_journal_issue                   48
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'Chemical communications (Cambridge, England)'
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_journal_paper_doi               10.1039/d1cc01939b
_journal_volume                  57
_journal_year                    2021
_chemical_formula_sum            'C29 H60 B10 N4 O2.5 P Si'
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_audit_update_record
;
2021-04-06 deposited with the CCDC.	2021-05-13 downloaded from the CCDC.
;
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_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
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_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device       'four-circle diffractometer'
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'SuperNova, Single source at offset/far, Atlas'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
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_diffrn_reflns_limit_h_min       -31
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_exptl_absorpt_correction_T_max  1.00000
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.145
_exptl_crystal_description       prism
_exptl_crystal_F_000             2888
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_refine_ls_restrained_S_all      1.027
_refine_ls_R_factor_all          0.1325
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0587P)^2^+1.1114P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1418
_refine_ls_wR_factor_ref         0.1823
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_reflns_number_gt                7877
_reflns_number_total             14060
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cc01939b2.cif
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:

data name '__audit_creation_method' was replaced with
'_audit_creation_method'.

Automatic conversion script
Id: cif_correct_tags 7550 2019-12-06 10:49:48Z antanas 

 Adding full bibliography for 7128322--7128326.cif.
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C29 H60 B10 N4 O2.50 P Si'
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_shelx_res_checksum              28380
_shelx_hkl_checksum              99663