Comparative study of the peroxidase-like activity of copper(ii) complexes with N<sub>4</sub> and N<sub>2</sub>O<sub>2</sub> coordination environments. Application to the oxidation of phenol at moderate temperature.
Ferreyra, Joaquín; Palopoli, Claudia; Pellegri, Nora; Terrestre, Gustavo; Signorella, Sandra R.; RSC advances 16 (2025) 220–230; doi:10.1039/d5ra08195e

data_7251721
_publ_section_title
;
 Comparative study of the peroxidase-like activity of copper(ii) complexes
 with N<sub>4</sub> and N<sub>2</sub>O<sub>2</sub> coordination
 environments. Application to the oxidation of phenol at moderate
 temperature.
;
_journal_issue                   1
_journal_name_full               'RSC advances'
_journal_page_first              220
_journal_page_last               230
_journal_paper_doi               10.1039/d5ra08195e
_journal_volume                  16
_journal_year                    2025
_chemical_formula_moiety         'C26 H19 Cu N5, 2(Cl O4)'
_chemical_formula_sum            'C26 H19 Cl2 Cu N5 O8'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
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_atom_sites_solution_primary     intrinsic-phasing
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_audit_update_record
;
2025-10-15 deposited with the CCDC.	2025-12-16 downloaded from the CCDC.
;
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_cell_measurement_theta_min      2.57
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_diffrn_measured_fraction_theta_max 0.995
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'Bruker D8 Quest ECO Photon II CPAD diffractometer'
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_diffrn_radiation_monochromator  'Triumph curved graphite crystal'
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_diffrn_reflns_point_group_measured_fraction_full 0.995
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_diffrn_source                   'sealed X-ray tube'
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_exptl_absorpt_process_details
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            blue
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_exptl_crystal_size_min          0.066
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0487P)^2^+4.9038P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0934
_refine_ls_wR_factor_ref         0.1002
_reflns_Friedel_coverage         0.000
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_reflns_number_total             2335
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           JF23Sep_A_0m_a
_cod_original_cell_volume        2566.65(15)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7251721
_shelx_shelxl_version_number     2019/1
_shelx_res_checksum              92242