Synthesis and properties of Rh(I) and Ir(I) distibine complexes with organometallic co-ligands.
Brown, Michael D.; Levason, William; Reid, Gillian; Webster, Michael; Dalton transactions (Cambridge, England : 2003)  (2006) 4039–4046; doi:10.1039/b605198g

data_7007441
_publ_section_title
;
 Synthesis and properties of Rh(I) and Ir(I) distibine complexes with
 organometallic co-ligands.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4039
_journal_page_last               4046
_journal_paper_doi               10.1039/b605198g
_journal_year                    2006
_chemical_formula_moiety         'C42 H42 Cl4 Rh Sb4 1+, Cl 1-, C H Cl3'
_chemical_formula_structural
'((Rh Cl2) (C27 H26 Sb2) (C15 H16 Cl2 Sb2)) (Cl) (C H Cl3)'
_chemical_formula_sum            'C43 H43 Cl8 Rh Sb4'
_chemical_formula_weight         1433.28
_chemical_name_systematic
;
Dichloro(1,3-bis(diphenylstibino)propane)(1,3-bis(chlorophenylstibino)-
propane)rhodium(III) chloride chloroform solvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2006-02-16
_audit_creation_method           'SHELXL-97 + hand edit'
_cell_angle_alpha                90.00
_cell_angle_beta                 104.095(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   28.147(6)
_cell_length_b                   10.9609(16)
_cell_length_c                   15.724(3)
_cell_measurement_reflns_used    6754
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.91
_cell_volume                     4705.1(15)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.923
_diffrn_measured_fraction_theta_max 0.923
_diffrn_measurement_device_type  'area detector, Nonius Kappa ccd'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  '10cm confocal mirrors'
_diffrn_radiation_source         'Nonius rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0895
_diffrn_reflns_av_sigmaI/netI    0.1200
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            31249
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.91
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.096
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7141
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'G.M. Sheldrick, (2003). SADABS. Version 2.10. Bruker AXS Inc.'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.023
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2744
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.625
_refine_diff_density_min         -1.606
_refine_diff_density_rms         0.319
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.164
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     505
_refine_ls_number_reflns         9970
_refine_ls_number_restraints     8
_refine_ls_restrained_S_all      1.164
_refine_ls_R_factor_all          0.1508
_refine_ls_R_factor_gt           0.1057
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0000P)^2^+131.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1492
_refine_ls_wR_factor_ref         0.1730
_reflns_number_gt                6847
_reflns_number_total             9970
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            b605198g.txt
_cod_data_source_block           05mdb024
_cod_original_cell_volume        4705.2(15)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7007441