β-Diketiminate Germylene-Supported Pentafluorophenylcopper(I) and -silver(I) Complexes [LGe(Me)(CuC6F5)n]2 (n = 1, 2), LGe[C(SiMe3)N2]AgC6F5, and {LGe[C(SiMe3)N2](AgC6F5)2}2 (L = HC[C(Me)N-2,6-iPr2C6H3]2): Synthesis and Structural Characterization
Na Zhao; Jinyuan Zhang; Ying Yang; Hongping Zhu; Yan Li; Gang Fu; Inorganic Chemistry 51 (2012) 8710–8718; doi:10.1021/ic300216m

data_4329995
_publ_section_title
;
 \b-Diketiminate Germylene-Supported Pentafluorophenylcopper(I) and
 -silver(I) Complexes [LGe(Me)(CuC6F5)n]2 (n = 1, 2),
 LGe[C(SiMe3)N2]AgC6F5, and {LGe[C(SiMe3)N2](AgC6F5)2}2 (L =
 HC[C(Me)N-2,6-iPr2C6H3]2): Synthesis and Structural Characterization
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8710
_journal_page_last               8718
_journal_paper_doi               10.1021/ic300216m
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C86 H104 Cu2 F10 Ge2 N4'
_chemical_formula_weight         1655.99
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.657(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.0177(8)
_cell_length_b                   16.8869(7)
_cell_length_c                   22.5197(9)
_cell_measurement_reflns_used    12577
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      30.0153
_cell_measurement_theta_min      2.7093
_cell_volume                     7984.2(6)
_computing_cell_refinement       CrysAlisPro
_computing_data_collection       CrysAlisPro
_computing_data_reduction        CrysAlisPro
_computing_molecular_graphics    Bluck
_computing_publication_material  Bluck
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 16.1903
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini ultra'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) x-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0432
_diffrn_reflns_av_sigmaI/netI    0.0508
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            31718
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.71
_exptl_absorpt_coefficient_mu    1.341
_exptl_absorpt_correction_T_max  0.6297
_exptl_absorpt_correction_T_min  0.5899
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   empirical
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.378
_exptl_crystal_description       block
_exptl_crystal_F_000             3440
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.38
_refine_diff_density_max         1.108
_refine_diff_density_min         -0.921
_refine_diff_density_rms         0.096
_refine_ls_goodness_of_fit_ref   1.118
_refine_ls_hydrogen_treatment    'refined in a riding mode to the carrier atom'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     452
_refine_ls_number_reflns         7817
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.118
_refine_ls_R_factor_all          0.0743
_refine_ls_R_factor_gt           0.0584
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0587P)^2^+50.8312P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1490
_refine_ls_wR_factor_ref         0.1531
_reflns_number_gt                6098
_reflns_number_total             7817
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic300216m_si_002_1.cif
_cod_data_source_block           compound_1
_cod_database_code               4329995