Reactivity of N,C,N-Chelated Antimony(III) and Bismuth(III) Chlorides with Lithium Reagents: Addition vs Substitution
Vránová, Iva; Jambor, Roman; Růžička, Aleš; Jirásko, Robert; Dostál, Libor; Organometallics 34 (2015) 534–; doi:10.1021/om5011879

data_4085274
_publ_section_title
;
 Reactivity of N,C,N-Chelated Antimony(III) and Bismuth(III) Chlorides
 with Lithium Reagents: Addition vs Substitution
;
_journal_issue                   2
_journal_name_full               Organometallics
_journal_page_first              534
_journal_paper_doi               10.1021/om5011879
_journal_volume                  34
_journal_year                    2015
_chemical_formula_moiety         'C17 H24 Bi Cl5 N2, 0.5(C H Cl3)'
_chemical_formula_sum            'C17.5 H24.5 Bi Cl6.5 N2'
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_chemical_name_systematic
;
 ?
;
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_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_cell_measurement_temperature    150(1)
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_computing_cell_refinement       'COLLECT and DENZO'
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'COLLECT (Hooft, 1998) and DENZO (Otwinowski & Minor, 1997)'
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_diffrn_measurement_device_type  'Bruker Nonius KappaCCD area detector'
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_diffrn_reflns_limit_l_min       -25
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_diffrn_reflns_theta_min         3.294
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;
Gaussian integration (Coppens, 1970)
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0422P)^2^+9.4502P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0944
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 4085272--4085278.cif.'
_cod_original_cell_volume        2463.4(3)
_cod_original_formula_sum        'C17.50 H24.50 Bi Cl6.50 N2'
_cod_database_code               4085274