Bis(1-{bis[2-(diphenylphosphinoyl)ethyl]phosphanyl}-2-(diphenylphosphanyl)ethane)dinitratoplatinum(II) methanol tetrasolvate
Rieckborn, Timo Paul; Karakoc, Emine; Prosenc, Marc Heinrich; Acta Crystallographica Section E 64 (2008) m898–m899; doi:10.1107/S160053680801533X

data_2218811
_publ_section_title
;Bis(1-{bis[2-(diphenylphosphinoyl)ethyl]phosphanyl}-2-(diphenylphosphanyl)ethane)dinitratoplatinum(II)
 methanol tetrasolvate
;
_journal_coeditor_code           SI2089
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m898
_journal_page_last               m899
_journal_paper_doi               10.1107/S160053680801533X
_journal_volume                  64
_journal_year                    2008
_chemical_formula_iupac          '[Pt (N O3)2 (C42 H42 O2 P4)2], 4C H4 O'
_chemical_formula_moiety         'C84 H84 O4 P8 Pt 2+, 2(N O3 -), 4(C H4 O)'
_chemical_formula_sum            'C88 H100 N2 O14 P8 Pt'
_chemical_formula_weight         1852.64
_chemical_name_systematic
;
Bis(1-{bis[2-(diphenylphosphinoyl)ethyl]phosphanyl}-2-
(diphenylphosphanyl)ethane)dinitratoplatinum(II) methanol
tetrasolvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                66.2000(10)
_cell_angle_beta                 77.4790(10)
_cell_angle_gamma                88.4770(10)
_cell_formula_units_Z            1
_cell_length_a                   9.9905(9)
_cell_length_b                   14.3346(13)
_cell_length_c                   16.9916(15)
_cell_measurement_reflns_used    5288
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      49.386
_cell_measurement_theta_min      4.932
_cell_volume                     2168.4(3)
_computing_cell_refinement       'SMART (Bruker, 2000)'
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker SMART APEX CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0520
_diffrn_reflns_av_sigmaI/netI    0.0922
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            25181
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         2.44
_exptl_absorpt_coefficient_mu    1.828
_exptl_absorpt_correction_T_max  0.9472
_exptl_absorpt_correction_T_min  0.4740
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1995)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.419
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             952
_exptl_crystal_size_max          0.48
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.307
_refine_diff_density_min         -1.370
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.907
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     512
_refine_ls_number_reflns         9347
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.907
_refine_ls_R_factor_all          0.0471
_refine_ls_R_factor_gt           0.0390
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0185P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0659
_refine_ls_wR_factor_ref         0.0680
_reflns_number_gt                8160
_reflns_number_total             9347
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            si2089.cif
_cod_data_source_block           I
_cod_database_code               2218811
_cod_database_fobs_code          2218811