Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt(IV) hydrides
Poveda, Dionisio; Vivancos, Angela; Bautista, Delia; González-Herrero, Pablo; Chemical Science  (2020) –; doi:10.1039/D0SC04879H

data_1559346
_publ_section_title
;
 Visible light driven generation and alkyne insertion reactions of stable
 bis-cyclometalated Pt(IV) hydrides
;
_journal_name_full               'Chemical Science'
_journal_paper_doi               10.1039/D0SC04879H
_journal_year                    2020
_chemical_formula_sum            'C27 H27 Cl N2 O Pt'
_chemical_formula_weight         626.04
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2020-07-24 deposited with the CCDC.	2020-10-13 downloaded from the CCDC.
;
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_cell_measurement_reflns_used    9931
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_cell_volume                     2363.3(2)
_computing_cell_refinement       'SAINT V8.38A (Bruker AXS Inc.)'
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker D8 QUEST'
_diffrn_measurement_method       '\w-scans and phi scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_min         2.248
_diffrn_source                   'high brilliance microfocus sealed tube '
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_exptl_absorpt_correction_T_max  0.7461
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABAS-2016/2
_exptl_crystal_colour            colourless
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         7271
_refine_ls_number_restraints     0
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0123P)^2^+1.8551P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_original_sg_symbol_H-M      'P 21/c'
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_shelx_res_checksum              28623