Multifunctional ZnII‒LnIII (Ln = Tb, Dy) complexes based on the amine-phenol ligand with field-induced slow magnetic relaxation, luminescence, and proton conduction
Zhang, Xiao-Nuan; Hu, Jun-Jie; Zhang, Jia-Li; Liu, Sui-Jun; Liao, Jin-Sheng; Wen, He-Rui; New Journal of Chemistry 45 (2021) 3392–3399; doi:10.1039/D0NJ04926C

data_7060170
_publ_section_title
;
 Multifunctional ZnII--LnIII (Ln = Tb, Dy) complexes based on the
 amine-phenol ligand with field-induced slow magnetic relaxation,
 luminescence, and proton conduction
;
_journal_issue                   7
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              3392
_journal_page_last               3399
_journal_paper_doi               10.1039/D0NJ04926C
_journal_volume                  45
_journal_year                    2021
_chemical_formula_sum            'C88 H126 Cl6 Dy2 N8 O59 Zn4'
_chemical_formula_weight         3039.14
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2020-10-08 deposited with the CCDC.	2020-12-16 downloaded from the CCDC.
;
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_cell_angle_gamma                111.683(4)
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_cell_length_b                   14.342(3)
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_cell_measurement_theta_min      2.91
_cell_volume                     3044.4(12)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_structure_solution    'Bruker SHELXTL'
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_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0262
_diffrn_reflns_av_unetI/netI     0.0242
_diffrn_reflns_Laue_measured_fraction_full 0.996
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_diffrn_reflns_limit_h_max       15
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_diffrn_reflns_theta_min         2.905
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    2.216
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0595P)^2^+18.7350P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1236
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_reflns_number_gt                9323
_reflns_number_total             10707
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0nj04926c2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7060170--7060171.cif.'
_cod_original_cell_volume        3044.4(11)
_cod_database_code               7060170
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