Annulative π-extension of BODIPYs made easy via gold(i)-catalyzed cycloisomerization
Labella, Jorge; Durán-Sampedro, Gonzalo; Martínez-Díaz, M. Victoria; Torres, Tomás; Chemical Science 11 (2020) 10778–10785; doi:10.1039/D0SC01054E

data_1558305
_publ_section_title
;
 Annulative \p-extension of BODIPYs made easy via gold(i)-catalyzed
 cycloisomerization
;
_journal_issue                   39
_journal_name_full               'Chemical Science'
_journal_page_first              10778
_journal_page_last               10785
_journal_paper_doi               10.1039/D0SC01054E
_journal_volume                  11
_journal_year                    2020
_chemical_formula_sum            'C34 H25 B F2 N2'
_chemical_formula_weight         510.37
_chemical_name_common            JL376-21_250K
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_update_record
;
2020-02-20 deposited with the CCDC.	2020-06-09 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 108.632(2)
_cell_angle_gamma                90
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_cell_length_b                   32.6033(10)
_cell_length_c                   7.6374(3)
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_cell_measurement_theta_min      3.0797
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      250.(2)
_diffrn_detector_area_resol_mean 8.3333
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_diffrn_measured_fraction_theta_max 0.999
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_diffrn_radiation_type           'Mo K\a'
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_exptl_crystal_colour            'clear intense purple'
_exptl_crystal_density_diffrn    1.238
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       ribbon
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0859P)^2^+0.2109P] where P=(Fo^2^+2Fc^2^)/3'
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_refine_ls_wR_factor_ref         0.1607
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0sc01054e2.cif
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'Adding full bibliography for 1558304--1558314.cif.'
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