Preparation and Crystal Structure of (Sb4O5)(ReO4)2 with Cationic Antimony Oxide Layers
Hiroyuki Watanabe; Hideo Imoto; Inorganic Chemistry 36 (1997) 4610–4612; doi:10.1021/ic970395w

data_4323597
_publ_section_title
;
 Preparation and Crystal Structure of (Sb4O5)(ReO4)2 with Cationic
 Antimony Oxide Layers
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4610
_journal_page_last               4612
_journal_paper_doi               10.1021/ic970395w
_journal_volume                  36
_journal_year                    1997
_chemical_formula_sum            'O13 Re2 Sb4'
_chemical_formula_weight         1067.4
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_type_scat_source           'Int. Tables Vol IV Tables 2.2B'
_cell_angle_alpha                114.95(2)
_cell_angle_beta                 111.16(2)
_cell_angle_gamma                90.12(2)
_cell_formula_units_Z            2.0
_cell_length_a                   9.938(2)
_cell_length_b                   9.430(2)
_cell_length_c                   7.688(2)
_cell_measurement_reflns_used    20
_cell_measurement_temperature    295
_cell_measurement_theta_max      26.9
_cell_measurement_theta_min      24.8
_cell_volume                     599.0(3)
_computing_cell_refinement       software_provied_by_Rigaku
_computing_data_collection       software_provied_by_Rigaku
_computing_structure_refinement  'ANYBLK(Imoto, 1990)'
_diffrn_ambient_temperature      295
_diffrn_measurement_device       Rigaku_AFC6S
_diffrn_measurement_method       \q/\2q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           Mo_K\a
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.0227
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            3745
_diffrn_reflns_theta_max         30.0
_diffrn_reflns_theta_min         2.5
_diffrn_standards_decay_%        1.6
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    29.1
_exptl_absorpt_correction_T_max  0.991
_exptl_absorpt_correction_T_min  0.777
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   '\y-scan method (North & Phillops, 1968)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    5.92
_exptl_crystal_density_method    not_measured
_exptl_crystal_F_000             916
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         3.00
_refine_diff_density_min         -3.91
_refine_ls_extinction_coef       4.92(6)E-8
_refine_ls_extinction_method     Zachariasen
_refine_ls_goodness_of_fit_obs   2.09
_refine_ls_matrix_type           full
_refine_ls_number_parameters     173
_refine_ls_number_reflns         3011
_refine_ls_R_factor_all          0.0412
_refine_ls_R_factor_obs          0.0354
_refine_ls_shift/esd_max         0.0001
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0341
_refine_ls_wR_factor_obs         0.0340
_reflns_limit_h_max              13
_reflns_limit_h_min              -13
_reflns_limit_k_max              11
_reflns_limit_k_min              -13
_reflns_limit_l_max              10
_reflns_limit_l_min              0
_reflns_number_observed          3011
_reflns_number_total             3322
_reflns_observed_criterion       refl_observed_if_F_>_3.0_sigma(F)
_cod_data_source_file            ic970395w.cif
_cod_data_source_block           Re2Sb4O13
_cod_original_cell_volume        598.9(3)
_cod_original_formula_sum        'Re2 Sb4 O13'
_cod_database_code               4323597