Cooperation between Cis and Trans Influences in cis-PtII(PPh3)2 Complexes: Structural, Spectroscopic, and Computational Studies
Luca Rigamonti; Alessandra Forni; Mario Manassero; Carlo Manassero; Alessandro Pasini; Inorganic Chemistry 49 (2010) 123–135; doi:10.1021/ic901510m

data_4314412
_publ_section_title
;
 Cooperation between Cis and Trans Influences in cis-PtII(PPh3)2
 Complexes: Structural, Spectroscopic, and Computational Studies
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              123
_journal_page_last               135
_journal_paper_doi               10.1021/ic901510m
_journal_volume                  49
_journal_year                    2010
_chemical_formula_sum            'C37 H32 Cl2 N2 O6 P2 Pt'
_chemical_formula_weight         928.62
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_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
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_audit_creation_method           'from The Personal SDP version 2.1.1'
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_cell_angle_gamma                90
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_cell_length_b                   20.0334(11)
_cell_length_c                   15.4580(9)
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_computing_structure_refinement
' Full-matrix least-squares  (The Personal SDP, 1991)'
_computing_structure_solution
' SHELXS-86  (Sheldrick, 1986) as implemented in The Personal SDP'
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_diffrn_measurement_device       'SMART (Bruker)'
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_diffrn_radiation_detector       'SMART CCD area detector'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_reduction_process SAINT
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_exptl_absorpt_correction_T_min  0.822
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   '  SADABS'
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_exptl_crystal_description       prism
_exptl_crystal_F_000             1832
_exptl_crystal_size_max          0.320
_exptl_crystal_size_mid          0.340
_exptl_crystal_size_min          0.370
_refine_diff_density_max         1.183
_refine_diff_density_min         -.958
_refine_ls_goodness_of_fit_all   1.039
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_refine_ls_structure_factor_coef Fsqd
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_cod_data_source_file            ic901510m_si_009.cif
_cod_data_source_block           compound_5.CH2Cl2
_cod_database_code               4314412
_diffrn_reflns_number_total      104889
_diffrn_reflns_number_independent 9948
_r_int                           0.0296
_total_number_of_frames          3300
_time_per_frame_seconds          20
_frame_width_degrees             0.50
_detector_sample_distance_cm     6.00
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_reflections_with_i>2\s(i))      7911
_refine_diff_density_esd         0.199