Trinuclear Mn<sup>2+</sup>/Zn<sup>2+</sup> based microporous coordination polymers as efficient catalysts for ipso-hydroxylation of boronic acids.
Bora, Sanchay J.; Paul, Rima; Dutta, Anurag; Goswami, Shyam; Guha, Ankur K.; Thakur, Ashim J.; Dalton transactions (Cambridge, England : 2003) 49 (2020) 5454–5462; doi:10.1039/d0dt00794c

data_7703980
_publ_section_title
;
 Trinuclear Mn<sup>2+</sup>/Zn<sup>2+</sup> based microporous coordination
 polymers as efficient catalysts for ipso-hydroxylation of boronic acids.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5454
_journal_page_last               5462
_journal_paper_doi               10.1039/d0dt00794c
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C58 H46 N4 O14 Zn3'
_chemical_formula_weight         1219.10
_space_group_crystal_system      orthorhombic
_space_group_IT_number           60
_space_group_name_Hall           '-P 2n 2ab'
_space_group_name_H-M_alt        'P b c n'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-03-01 deposited with the CCDC.	2020-04-06 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
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_cell_length_c                   18.1249(7)
_cell_measurement_reflns_used    9564
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      293(2)
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_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0478
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_exptl_absorpt_coefficient_mu    1.141
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6504
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_exptl_crystal_colour            colourless
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_refine_ls_restrained_S_all      1.107
_refine_ls_R_factor_all          0.0836
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_refine_ls_shift/su_max          0.038
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0976P)^2^+6.0910P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1708
_refine_ls_wR_factor_ref         0.1843
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6713
_reflns_number_total             9564
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt00794c2.cif
_cod_data_source_block           ZnCP_sqd
_cod_depositor_comments
'Adding full bibliography for 7703979--7703980.cif.'
_cod_database_code               7703980
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