Correction to Synthesis and Reactivity of Ruthenium Complexes Bearing Arsenic-Containing Arsenic-Nitrogen-Arsenic-Type Pincer Ligand
Tanabe, Yoshiaki; Kuriyama, Shogo; Arashiba, Kazuya; Nakajima, Kazunari; Nishibayashi, Yoshiaki; Organometallics 33 (2014) 7333–; doi:10.1021/om5011676

data_4084908
_publ_section_title
;
 Correction to Synthesis and Reactivity of Ruthenium Complexes Bearing
 Arsenic-Containing Arsenic-Nitrogen-Arsenic-Type Pincer Ligand
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              7333
_journal_paper_doi               10.1021/om5011676
_journal_volume                  33
_journal_year                    2014
_chemical_formula_moiety         'C60 H102 As4 Cl4 N4 Ru2'
_chemical_formula_sum            'C60 H102 As4 Cl4 N4 Ru2'
_chemical_formula_weight         1523.13
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.0000
_cell_angle_beta                 97.6953(7)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   12.6675(3)
_cell_length_b                   21.9658(4)
_cell_length_c                   24.5172(5)
_cell_measurement_reflns_used    38224
_cell_measurement_temperature    198
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.10
_cell_volume                     6760.5(2)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, 2010)'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics    'CrystalStructure 4.0'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_structure_refinement  'CRYSTALS (Carruthers, et al., 1999)'
_computing_structure_solution    SIR97
_diffrn_ambient_temperature      198
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0312
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            62342
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.48
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.586
_exptl_absorpt_correction_T_max  0.856
_exptl_absorpt_correction_T_min  0.727
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'NUMABS (Rigaku, 1999)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.496
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3112.00
_exptl_crystal_size_max          0.230
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.060
_refine_diff_density_max         1.870
_refine_diff_density_min         -1.060
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     641
_refine_ls_number_reflns         15403
_refine_ls_R_factor_gt           0.0478
_refine_ls_shift/su_max          0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w = 1/[15.6500\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0969
_reflns_number_gt                13303
_reflns_number_total             15403
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om5011676_si_001.cif
_cod_data_source_block           '[RuCl2(tBuPNP)]2(mu-N2).2C7H8'
_cod_depositor_comments
'Adding full bibliography for 4084908--4084909.cif.'
_cod_original_cell_volume        6760.5(3)
_cod_database_code               4084908