Oxidative cyclization of thiosemicarbazide: a chemodosimetric approach for the highly selective fluorescence detection of cerium(iv)
Shaikh, Ahad; Mukherjee, Pallabi; Ta, Sabyasachi; Bhattacharyya, Arunasis; Ghosh, Abhijit; Das, Debasis; New Journal of Chemistry 44 (2020) 9452–9455; doi:10.1039/D0NJ01100B

data_7059591
_publ_section_title
;
 Oxidative cyclization of thiosemicarbazide: a chemodosimetric approach
 for the highly selective fluorescence detection of cerium(iv)
;
_journal_issue                   22
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              9452
_journal_page_last               9455
_journal_paper_doi               10.1039/D0NJ01100B
_journal_volume                  44
_journal_year                    2020
_chemical_formula_sum            'C22 H17 N3 S'
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_space_group_name_Hall           'P 2c -2n'
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_audit_update_record
;
2020-04-26 deposited with the CCDC.	2020-04-30 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.992
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_refine_ls_abs_structure_details
;
 Flack x determined using 1530 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.07(8)
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0167P)^2^+0.8608P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                4026
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_cod_data_source_file            d0nj01100b2.cif
_cod_data_source_block           HYANTPIT_2_5_a
_cod_depositor_comments
;Adding full bibliography for 7059591--7059592.cif.

 Adding full bibliography for 7059591--7059592.cif.
;
_cod_original_cell_volume        3584.8(9)
_cod_database_code               7059591
_shelxl_version_number           2014/6
_shelx_res_checksum              14386