Highly effective synthesis of a cobalt(ii) metal-organic coordination polymer by using continuous flow chemistry.
Gong, Chunhua; Zhang, Junyong; Zeng, Xianghua; Xie, Jingli; Dalton transactions (Cambridge, England : 2003) 46 (2016) 25–28; doi:10.1039/c6dt04000d

data_1544686
_publ_section_title
;
 Highly effective synthesis of a cobalt(ii) metal-organic coordination
 polymer by using continuous flow chemistry.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              25
_journal_page_last               28
_journal_paper_doi               10.1039/c6dt04000d
_journal_volume                  46
_journal_year                    2016
_chemical_formula_sum            'C70 H53 Cl4 Co2 N5 O7'
_chemical_formula_weight         1335.83
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2016-08-23 deposited with the CCDC.
2016-11-28 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 109.938(6)
_cell_angle_gamma                90
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_cell_length_a                   15.7510(10)
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_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      54.5060
_cell_measurement_theta_min      3.7180
_cell_volume                     6374.0(6)
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0831
_diffrn_reflns_av_unetI/netI     0.1135
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.975
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       23
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_diffrn_reflns_number            26792
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.975
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         72.316
_diffrn_reflns_theta_min         2.984
_exptl_absorpt_coefficient_mu    6.092
_exptl_absorpt_correction_T_max  0.737
_exptl_absorpt_correction_T_min  0.505
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.392
_exptl_crystal_description       block
_exptl_crystal_F_000             2744
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.453
_refine_diff_density_min         -0.461
_refine_diff_density_rms         0.102
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     783
_refine_ls_number_reflns         12274
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.1809
_refine_ls_R_factor_gt           0.0976
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1640P)^2^+3.4997P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2661
_refine_ls_wR_factor_ref         0.3284
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5968
_reflns_number_total             12274
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt04000d2.cif
_cod_data_source_block           shelx
_cod_depositor_comments          'Adding full bibliography for 1544686.cif.'
_cod_database_code               1544686
_shelxl_version_number           2014-3
_shelx_res_checksum              13298