Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction.
Cinderella, Andrew P.; Vulovic, Bojan; Watson, Donald A.; Journal of the American Chemical Society  (2017) –; doi:10.1021/jacs.7b04364

data_4126091
_publ_section_title
;
 Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc
 Halides: A Silyl-Negishi Reaction.
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_paper_doi               10.1021/jacs.7b04364
_journal_year                    2017
_chemical_formula_sum            'C84 H126 I2 P2 Pd'
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_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_diffrn_ambient_temperature      200(2)
_diffrn_detector_area_resol_mean 8.33
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker AXS APEX diffractometer'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_Laue_measured_fraction_full 0.998
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_refine_ls_extinction_method     none
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_refine_ls_restrained_S_all      1.052
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0311P)^2^+3.5887P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_estimated_absorpt_t_max   0.696
_shelx_res_checksum              38511
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