Dibismuthanes in catalysis: from synthesis and characterization to redox behavior towards oxidative cleavage of 1,2-diols.
Magre, Marc; Kuziola, Jennifer; Nöthling, Nils; Cornella, Josep; Organic & biomolecular chemistry 19 (2021) 4922–4929; doi:10.1039/d1ob00367d

data_7158063
_publ_section_title
;
 Dibismuthanes in catalysis: from synthesis and characterization to redox
 behavior towards oxidative cleavage of 1,2-diols.
;
_journal_issue                   22
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              4922
_journal_page_last               4929
_journal_paper_doi               10.1039/d1ob00367d
_journal_volume                  19
_journal_year                    2021
_chemical_formula_moiety         'C38 H30 Bi2 Cl4 O, C6 H6'
_chemical_formula_sum            'C44 H36 Bi2 Cl4 O'
_chemical_formula_weight         1140.49
_chemical_name_systematic
;
4,6-bis(dichlorodiphenyl-\l^5^-bismuthanyl)-10,11-dihydrodibenzo[b,f]oxepine
;
_chemical_properties_physical    none
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Olex2 1.3
(compiled 2020.07.31 svn.rc2a77460 for OlexSys, GUI svn.r6145)
;
_audit_update_record
;
2021-02-19 deposited with the CCDC.	2021-04-26 downloaded from the CCDC.
;
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'Re-crystallisation from solvent:  benzene, pentane'
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'w=1/[\s^2^(Fo^2^)+(0.0102P)^2^+2.5079P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7158061--7158068.cif.'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C8(H8A,H8B)
2.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C10(H10), C11(H11), C12(H12), C16(H16), C17(H17),
 C18(H18), C19(H19), C20(H20), C22(H22), C23(H23), C24(H24), C25(H25), C26(H26),
  C28(H28), C29(H29), C30(H30), C31(H31), C32(H32), C34(H34), C35(H35),
 C36(H36), C37(H37), C38(H38), C51(H51), C52(H52), C53(H53), C61(H61), C62(H62),
  C63(H63)
;
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_olex2_submission_special_instructions 'No special instructions were received'
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