Copper(ii) tetrafluoroborate complexes with the N(3),N(4)-bridging coordination of 1-(tert-butyl)-1H-tetrazole: synthesis, crystal structure and magnetic properties.
Degtyarik, Mikhail M.; Lyakhov, Alexander S.; Ivashkevich, Ludmila S.; Matulis, Vitaly E.; Matulis, Vadim E.; Gruschinski, Sina; Voitekhovich, Sergei V.; Kersting, Berthold; Ivashkevich, Oleg A.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 18518–18526; doi:10.1039/c5dt02871j

data_7036636
_publ_section_title
;
 Copper(ii) tetrafluoroborate complexes with the N(3),N(4)-bridging
 coordination of 1-(tert-butyl)-1H-tetrazole: synthesis, crystal structure
 and magnetic properties.
;
_journal_issue                   42
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18518
_journal_page_last               18526
_journal_paper_doi               10.1039/c5dt02871j
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C30 H72 Cu3 N24 O6, 6(B F4)'
_chemical_formula_sum            'C30 H72 B6 Cu3 F24 N24 O6'
_chemical_formula_weight         1576.59
_space_group_crystal_system      trigonal
_space_group_IT_number           148
_space_group_name_Hall           '-R 3'
_space_group_name_H-M_alt        'R -3 :H'
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_audit_update_record
;
2015-09-01 deposited with the CCDC.
2015-09-23 downloaded from the CCDC.
;
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_cell_measurement_temperature    100(2)
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_computing_cell_refinement       'SAINT (Bruker, 2010)'
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;
SHELXL-2014/7 (Sheldrick, 2014),
PLATON (Spek, 2009)
;
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_Laue_measured_fraction_max 0.984
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_diffrn_reflns_limit_l_min       -31
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0537P)^2^+11.2143P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                2825
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt02871j2.cif
_cod_data_source_block           00
_cod_depositor_comments
'Adding full bibliography for 7036634--7036636.cif.'
_cod_original_cell_volume        4887.11(9)
_cod_database_code               7036636
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              76988