Simple routes to bulky silyl-substituted acetylide ligands and examples of V(III), Fe(II), and Mn(II) complexes.
Yee, Gereon M.; Kowolik, Kristin; Manabe, Shuhei; Fettinger, James C.; Berben, Louise A.; Chemical communications (Cambridge, England) 47 (2011) 11680–11682; doi:10.1039/c1cc14758g

data_7112699
_publ_section_title
;
 Simple routes to bulky silyl-substituted acetylide ligands and examples
 of V(III), Fe(II), and Mn(II) complexes.
;
_journal_issue                   42
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              11680
_journal_page_last               11682
_journal_paper_doi               10.1039/c1cc14758g
_journal_volume                  47
_journal_year                    2011
_chemical_formula_moiety         'C56 H84 Si8 V, C16 H32 Li O4'
_chemical_formula_sum            'C72 H116 Li O4 Si8 V'
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;
?
;
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0643P)^2^+1.2522P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Tetragonal' changed to 'tetragonal'
according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        8328.30(13)
_cod_database_code               7112699