Experimental and theoretical insights into Co-Ln magnetic exchange and the rare slow-magnetic relaxation behavior of [CoII2Pr]<sup>2+</sup> in a series of linear [CoII2Ln]<sup>2+</sup> complexes.
Ahmed, Naushad; Uddin Ansari, Kamal; Dalton transactions (Cambridge, England : 2003) 51 (2022) 4122–4134; doi:10.1039/d1dt03573h

data_7709411
_publ_section_title
;
 Experimental and theoretical insights into Co-Ln magnetic exchange and
 the rare slow-magnetic relaxation behavior of [CoII2Pr]<sup>2+</sup> in a
 series of linear [CoII2Ln]<sup>2+</sup> complexes.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4122
_journal_page_last               4134
_journal_paper_doi               10.1039/d1dt03573h
_journal_volume                  51
_journal_year                    2022
_chemical_formula_sum            'C60 H56 Co2 N7 O21 Pr'
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;
2021-09-24 deposited with the CCDC.	2022-02-02 downloaded from the CCDC.
;
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;
CrystalClear-SM Expert 2.1 b28 (Rigaku, 2013)
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CrystalClear-SM Expert 2.1 b28 (Rigaku, 2013)
;
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;
CrystalClear-SM Expert 2.1 b28 (Rigaku, 2013)
;
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
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;
Rigaku Saturn724+ (4x4 bin mode)
;
_diffrn_measurement_method       'profile data from \w-scans'
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_exptl_absorpt_correction_type   numerical
_exptl_crystal_colour            'orange Red'
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_refine_ls_R_factor_all          0.0653
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0304P)^2^+8.2359P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1142
_refine_ls_wR_factor_ref         0.1205
_reflns_Friedel_coverage         0.000
_reflns_number_gt                15342
_reflns_number_total             17178
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1dt03573h2.cif
_cod_data_source_block           Co2Pr_sq
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Numerical' was
changed to 'numerical' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7709409--7709411.cif.
;
_cod_original_cell_volume        3214.4(14)
_cod_database_code               7709411
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              61916
_shelx_fab_checksum              87732