Galvanic replacement-induced introduction of a heteroligand into bimetallic and trimetallic nanoclusters.
Liao, Jian-Hong; Chiu, Tzu-Hao; Liang, Hao; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W.; Nanoscale 15 (2023) 6121–6125; doi:10.1039/d3nr00509g

data_1568558
_publ_section_title
;
 Galvanic replacement-induced introduction of a heteroligand into
 bimetallic and trimetallic nanoclusters.
;
_journal_issue                   13
_journal_name_full               Nanoscale
_journal_page_first              6121
_journal_page_last               6125
_journal_paper_doi               10.1039/d3nr00509g
_journal_volume                  15
_journal_year                    2023
_chemical_formula_sum            'C114 H158 Ag12 Au5 F12 O14 P13 S14'
_chemical_formula_weight         5111.12
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2023-01-23 deposited with the CCDC.	2023-03-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_length_c                   18.1905(18)
_cell_measurement_reflns_used    9906
_cell_measurement_temperature    100(2)
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_cell_volume                     15097(3)
_computing_cell_refinement       'Bruker SAINT'
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_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.1240
_diffrn_reflns_av_unetI/netI     0.1219
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       35
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_diffrn_reflns_limit_l_max       21
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_diffrn_reflns_point_group_measured_fraction_full 0.995
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_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         1.001
_exptl_absorpt_coefficient_mu    6.753
_exptl_absorpt_correction_T_max  0.7453
_exptl_absorpt_correction_T_min  0.5643
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.249
_exptl_crystal_description       plate
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.2054
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0798P)^2^+1285.1500P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2490
_refine_ls_wR_factor_ref         0.3172
_reflns_Friedel_coverage         0.000
_reflns_number_gt                13745
_reflns_number_total             26457
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3nr00509g2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 1568558--1568559.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1568558
_shelx_shelxl_version_number     2018/3
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_shelx_res_checksum              21807