New Heterometallic Coordination Polymers Self-Assembled from Copper(II) Nitrate and (Diamine)PtII(pyridinecarboxylates)2
Rita Song; Kwan Mook Kim; Youn Soo Sohn; Inorganic Chemistry 42 (2003) 821–826; doi:10.1021/ic0204777

data_4313016
_publ_section_title
;
 New Heterometallic Coordination Polymers Self-Assembled from Copper(II)
 Nitrate and (Diamine)PtII(pyridinecarboxylates)2
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              821
_journal_page_last               826
_journal_paper_doi               10.1021/ic0204777
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C21 H39 Cu2.5 N10 O26 Pt1.5'
_chemical_formula_weight         1299.11
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.80(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   24.042(8)
_cell_length_b                   12.490(4)
_cell_length_c                   31.150(7)
_cell_measurement_temperature    293(2)
_cell_volume                     8906(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.620
_diffrn_measured_fraction_theta_max 0.620
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0274
_diffrn_reflns_av_sigmaI/netI    0.0528
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            3949
_diffrn_reflns_theta_full        23.01
_diffrn_reflns_theta_max         23.01
_diffrn_reflns_theta_min         1.37
_exptl_absorpt_coefficient_mu    5.969
_exptl_crystal_density_diffrn    1.938
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             5060
_refine_diff_density_max         1.535
_refine_diff_density_min         -0.686
_refine_diff_density_rms         0.176
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.125
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     588
_refine_ls_number_reflns         3851
_refine_ls_number_restraints     24
_refine_ls_restrained_S_all      1.125
_refine_ls_R_factor_all          0.0566
_refine_ls_R_factor_gt           0.0532
_refine_ls_shift/su_max          0.599
_refine_ls_shift/su_mean         0.025
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1409
_refine_ls_wR_factor_ref         0.1437
_reflns_number_gt                3677
_reflns_number_total             3851
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0204777_3.cif
_cod_data_source_block           cu
_cod_original_cell_volume        8907(5)
_cod_original_formula_sum        'C21 H39 Cu2.50 N10 O26 Pt1.50'
_cod_database_code               4313016