Iron achieves noble metal reactivity and selectivity: highly reactive and enantioselective iron complexes as catalysts in the hydrosilylation of ketones.
Bleith, Tim; Wadepohl, Hubert; Gade, Lutz H.; Journal of the American Chemical Society 137 (2015) 2456–2459; doi:10.1021/ja512986m

data_4123437
_publ_section_title
;
 Iron achieves noble metal reactivity and selectivity: highly reactive and
 enantioselective iron complexes as catalysts in the hydrosilylation of
 ketones.
;
_journal_issue                   7
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              2456
_journal_page_last               2459
_journal_paper_doi               10.1021/ja512986m
_journal_volume                  137
_journal_year                    2015
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C41 H36 Fe N4 O3, C5 H5 N'
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_symmetry_cell_setting           monoclinic
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 22 omega  -49.00  112.00   0.5000   15.0000
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 31 omega   -5.00  107.00   0.5000   15.0000
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 32 omega  -44.00   68.00   0.5000   15.0000
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 33 omega  -49.00  112.00   0.5000   15.0000
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 34 omega   -7.00   24.00   0.5000   15.0000
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 35 omega  -49.00  112.00   0.5000   15.0000
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1. Fixed Uiso
 At 1.2 times of:
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 At 1.5 times of:
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 C12(H12), C22(H22), C29(H29)
2.b Secondary CH2 refined with riding coordinates:
 C11(H11A,H11B), C21(H21A,H21B)
2.c Aromatic/amide H refined with riding coordinates:
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 C30(H30A,H30B,H30C)
;
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