Copper(i)-assisted red-shifted phosphorescence in Au(i)Cu(i) heteropolynuclear complexes.
Catalano, Vincent J.; López-de-Luzuriaga, José M; Monge, Miguel; Olmos, M. Elena; Pascual, David; Dalton transactions (Cambridge, England : 2003) 43 (2014) 16486–16497; doi:10.1039/c4dt02154a

data_7032665
_publ_section_title
;
 Copper(i)-assisted red-shifted phosphorescence in Au(i)Cu(i)
 heteropolynuclear complexes.
;
_journal_issue                   43
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              16486
_journal_page_last               16497
_journal_paper_doi               10.1039/c4dt02154a
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C23 H14 Au Cl2 F3 N P'
_chemical_formula_weight         660.19
_chemical_name_common            1
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_cell_length_b                   14.0807(4)
_cell_length_c                   14.7208(4)
_cell_measurement_reflns_used    8472
_cell_measurement_temperature    100(2)
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_cell_measurement_theta_min      2.31
_cell_volume                     2190.20(12)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0178P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                8142
_reflns_number_total             10052
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c4dt02154a2.cif
_cod_data_source_block           cat3
_cod_depositor_comments
;
Adding full bibliography for 7032665--7032668.cif.

2017-03-09
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C46 H28 Au2 Cl4 F6 N2 P2'
_cod_original_formula_weight         1320.38
_cod_original_formula_units_Z            2
_cod_original_cell_volume        2190.20(11)
_cod_database_code               7032665
_shelx_estimated_absorpt_t_min   0.197
_shelx_estimated_absorpt_t_max   0.293
_shelxl_version_number           2014-3
_shelx_res_checksum              74198