A cationic [Ag<sub>12</sub>S<sub>12</sub>] cluster-based 2D coordination polymer and its dye composite with enhanced photocurrent and dielectric responses.
Zhang, Min; Tan, Yu-Ling; Chen, Xu-Ran; Yu, Hong; Zhang, Wen-Hua; Lang, Jian-Ping; Dalton transactions (Cambridge, England : 2003) 48 (2019) 8546–8550; doi:10.1039/c9dt01566c

data_7700012
_publ_section_title
;
 A cationic [Ag<sub>12</sub>S<sub>12</sub>] cluster-based 2D coordination
 polymer and its dye composite with enhanced photocurrent and dielectric
 responses.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8546
_journal_page_last               8550
_journal_paper_doi               10.1039/c9dt01566c
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety
'C80 H101 Ag6 N11 S6, 6(F6 P), 3(C3 H7 N O), C2 H3 N [+ solvent]'
_chemical_formula_sum            'C91 H125 Ag6 F36 N15 O3 P6 S6'
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_space_group_name_Hall           '-P 1'
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;
2019-04-11 deposited with the CCDC.    2019-05-16 downloaded from the CCDC.
;
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_computing_data_reduction        'Bruker D8 Quest'
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_computing_publication_material  'publCIF (Westrip, 2010)'
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_computing_structure_solution    'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      223(2)
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_diffrn_measurement_device_type  'Bruker D8 Quest'
_diffrn_measurement_method       'phi and omega scans'
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_diffrn_reflns_limit_l_max       26
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_diffrn_reflns_point_group_measured_fraction_full 0.988
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_diffrn_reflns_theta_max         28.282
_diffrn_reflns_theta_min         2.166
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
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_exptl_absorpt_correction_T_max  0.745
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_exptl_absorpt_process_details
;
 Sheldrick, G.M. SADABS (Program for Scaling and Correction of Area Detector
 Data), version 2008/1; University of G\"ottingen: G\"ottingen, Germany, 2008.
;
_exptl_crystal_colour            yellow
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_refine_diff_density_rms         0.155
_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0911
_refine_ls_R_factor_gt           0.0723
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0353P)^2^+64.2587P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1591
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_reflns_number_gt                24603
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           AG12
_cod_depositor_comments          'Adding full bibliography for 7700012.cif.'
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_publcif_datablock.id            {b6903ea9-5a5e-4e2a-8470-8d789bc62c9d}
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_shelxl_version_number           2013-2
_shelx_res_checksum              17533
_shelx_fab_checksum              63589