Janus-Type Bis(maloNHC) and Its Zwitterionic Gold and Silver Metal Complexes
Carter, Ashley; Mason, Alexander; Baker, Michael A.; Bettler, Donald G.; Changas, Angelo; McMillen, Colin D.; Tapu, Daniela; Organometallics 36 (2017) 1867–; doi:10.1021/acs.organomet.7b00206

data_4087256
_publ_section_title
;
 Janus-Type Bis(maloNHC) and Its Zwitterionic Gold and Silver Metal
 Complexes
;
_journal_issue                   9
_journal_name_full               Organometallics
_journal_page_first              1867
_journal_paper_doi               10.1021/acs.organomet.7b00206
_journal_volume                  36
_journal_year                    2017
_chemical_formula_sum            'C117 H118 Au2 N4 O4 P2'
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
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_cell_angle_gamma                90
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_cell_volume                     10456.5(7)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker D8 Venture Photon 100'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_min         2.035
_diffrn_source                   'Incoatec I\mS'
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_exptl_absorpt_correction_T_max  1.0000
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker'
_exptl_crystal_colour            yellow
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_refine_ls_R_factor_all          0.0541
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0608P)^2^+104.7210P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             11407
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            om7b00206_si_002.cif
_cod_data_source_block           8
_cod_depositor_comments
'Adding full bibliography for 4087254--4087257.cif.'
_cod_database_code               4087256
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              82305
_shelx_hkl_checksum              57263