Modular synthesis of heptaarylindole.
Suzuki, Shin; Asako, Takashi; Itami, Kenichiro; Yamaguchi, Junichiro; Organic & biomolecular chemistry 16 (2018) 3771–3776; doi:10.1039/c8ob00993g

data_7156239
_publ_section_title
;
 Modular synthesis of heptaarylindole.
;
_journal_issue                   20
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              3771
_journal_page_last               3776
_journal_paper_doi               10.1039/c8ob00993g
_journal_volume                  16
_journal_year                    2018
_chemical_formula_sum            'C99 H100 N2 O3'
_chemical_formula_weight         1365.80
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   mixed
_audit_block_doi                 10.5517/ccdc.csd.cc1zj9rk
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_audit_update_record
;
2018-03-27 deposited with the CCDC.
2018-05-03 downloaded from the CCDC.
;
_cell_angle_alpha                106.445(4)
_cell_angle_beta                 110.829(6)
_cell_angle_gamma                95.262(6)
_cell_formula_units_Z            2
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_cell_length_c                   18.304(7)
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_cell_measurement_temperature    123(2)
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_cell_volume                     3891(2)
_computing_cell_refinement
;
Rigaku CrystalClear-SM Expert 2.1 b29
;
_computing_data_collection
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Rigaku CrystalClear-SM Expert 2.1 b29
;
_computing_data_reduction
;
Rigaku CrystalClear-SM Expert 2.1 b29
;
_computing_molecular_graphics    'Yadokari-XG 2009 (Wakita Nemoto et al., 2009)'
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_diffrn_ambient_temperature      123(2)
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_diffrn_measured_fraction_theta_full 0.993
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_diffrn_measurement_device_type
;
Rigaku CrystalClear-SM Expert 2.1 b29
;
_diffrn_measurement_method       'profile data from \w-scans'
_diffrn_radiation_monochromator  Confocal
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_diffrn_reflns_av_R_equivalents  0.1612
_diffrn_reflns_av_unetI/netI     0.1873
_diffrn_reflns_Laue_measured_fraction_full 0.993
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_diffrn_reflns_limit_h_max       15
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_diffrn_source                   'Rotating Anode'
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_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.731
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '\'Jacobson, R. (1998) Private communication\''
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.166
_exptl_crystal_description       Block
_exptl_crystal_F_000             1464
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_refine_diff_density_max         0.744
_refine_diff_density_min         -0.323
_refine_diff_density_rms         0.057
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    mixed
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_refine_ls_number_restraints     37
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_refine_ls_R_factor_gt           0.0936
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1157P)^2^+1.2475P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2036
_refine_ls_wR_factor_ref         0.2860
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5423
_reflns_number_total             13591
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8ob00993g2.cif
_cod_data_source_block           1766
_cod_depositor_comments
'Adding full bibliography for 7156239--7156243.cif.'
_cod_database_code               7156239
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.995
_shelx_estimated_absorpt_t_max   0.999
_shelx_res_checksum              33242