Insertion of Isonitriles into the M-C Bonds of Group 4 Dialkyl Complexes.
Chen, Jiawei; Yassin, Nadine; Gunasekara, Thilina; Norton, Jack R.; Rauch, Michael; Journal of the American Chemical Society 140 (2018) 8980–8989; doi:10.1021/jacs.8b05377

data_4132647
_publ_section_title
;
 Insertion of Isonitriles into the M-C Bonds of Group 4 Dialkyl Complexes.
;
_journal_issue                   28
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              8980
_journal_page_last               8989
_journal_paper_doi               10.1021/jacs.8b05377
_journal_volume                  140
_journal_year                    2018
_chemical_formula_sum            'C21 H37 Hf N Si'
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_atom_sites_solution_hydrogens   geom
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_cell_length_c                   29.381(4)
_cell_measurement_reflns_used    9061
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_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_Laue_measured_fraction_full 0.999
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_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
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_refine_ls_number_reflns         13315
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_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0078P)^2^+13.1138P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             13315
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_original_cell_volume        4342.8(9)
_cod_original_sg_symbol_H-M      'P 21/c'
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