Oxidative stretching of metal-metal bonds to their limits.
Brogden, David W.; Turov, Yevgeniya; Nippe, Michael; Li Manni, Giovanni; Hillard, Elizabeth A.; Clérac, Rodolphe; Gagliardi, Laura; Berry, John F.; Inorganic chemistry 53 (2014) 4777–4790; doi:10.1021/ic5007204

data_4338167
_publ_section_title
;
 Oxidative stretching of metal-metal bonds to their limits.
;
_journal_issue                   9
_journal_name_full               'Inorganic chemistry'
_journal_page_first              4777
_journal_page_last               4790
_journal_paper_doi               10.1021/ic5007204
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety
;
C40 H32 N12 W2 O, B C24 H20, O3 S C F3, C4 H10 O, C2 H3 N
;
_chemical_formula_sum            'C71 H65 B F3 N13 O5 S W2'
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_symmetry_space_group_name_Hall  '-P 1'
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_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
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_diffrn_radiation_monochromator  'mirror optics'
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_diffrn_reflns_theta_max         26.37
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_diffrn_source                   'microfocus sealed X-ray tube'
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_exptl_crystal_colour            'dark yellow'
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_refine_ls_number_reflns         13355
_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0515
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0708P)^2^+20.5869P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2sigma(I)
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_cod_depositor_comments
'Adding full bibliography for 4338161--4338168.cif.'
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4338167