Rosamine-Based Fluorescent Chemosensor for Selective Detection of Silver(I) in an Aqueous Solution
Shohei Iyoshi; Masayasu Taki; Yukio Yamamoto; Inorganic Chemistry 47 (2008) 3946–3948; doi:10.1021/ic800442y

data_4305127
_publ_section_title
;
Rosamine-Based Fluorescent Chemosensor for Selective Detection of Silver(I)
in an Aqueous Solution
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3946
_journal_page_last               3948
_journal_paper_doi               10.1021/ic800442y
_journal_volume                  47
_journal_year                    2008
_chemical_formula_moiety         'C15 H25 Ag N2 O4 S3 '
_chemical_formula_sum            'C15 H25 Ag N2 O4 S3'
_chemical_formula_weight         501.42
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.3451(18)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   9.3704(8)
_cell_length_b                   10.1330(9)
_cell_length_c                   20.4772(17)
_cell_measurement_reflns_used    9374
_cell_measurement_temperature    203.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     1944.3(3)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.029
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            18478
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    1.378
_exptl_absorpt_correction_T_max  0.759
_exptl_absorpt_correction_T_min  0.536
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
    Higashi, T. (1995). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.713
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1024.00
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         2.64
_refine_diff_density_min         -1.68
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     251
_refine_ls_number_reflns         15094
_refine_ls_R_factor_gt           0.0312
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0008Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0859
_reflns_number_gt                15042
_reflns_number_total             4427
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic800442y-file001.cif
_cod_data_source_block           '_AgS3O1'
_cod_original_formula_sum        'C15 H25 Ag N2 O4 S3 '
_cod_database_code               4305127