1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group
Holger Braunschweig; Rian D. Dewhurst; Krzysztof Radacki; Benedikt Wennemann; Qing Ye; Chem.Commun. 51 (2015) 15465–; doi:10.1039/C5cc06425B

data_7117926
_publ_section_title
;
 1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl)
 complexes of iron: switching between borylenes and silylenes just by
 changing the alkyl group
;
_journal_name_full               Chem.Commun.
_journal_page_first              15465
_journal_paper_doi               10.1039/C5cc06425B
_journal_volume                  51
_journal_year                    2015
_chemical_formula_moiety         'C19 H31 B Cl Fe O3 P Si'
_chemical_formula_sum            'C19 H31 B Cl Fe O3 P Si'
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_secondary   other
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_audit_update_record
;
2015-04-27 deposited with the CCDC.
2015-09-01 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0316P)^2^+1.2242P] where P=(Fo^2^+2Fc^2^)/3'
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