In Vitro and in Vivo Fluorescent Imaging of a Monofunctional Chelated Platinum Complex Excitable Using Visible Light
Shengde Wu; Chengcheng Zhu; Changli Zhang; Zhen Yu; Weijiang He; Yafeng He; Yizhi Li; Jing Wang; Zijian Guo; Inorganic Chemistry 50 (2011) 11847–11849; doi:10.1021/ic201506y

data_4326995
_publ_section_title
;
 In Vitro and in Vivo Fluorescent Imaging of a Monofunctional Chelated
 Platinum Complex Excitable Using Visible Light
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              11847
_journal_page_last               11849
_journal_paper_doi               10.1021/ic201506y
_journal_volume                  50
_journal_year                    2011
_chemical_formula_moiety
'C20 H19 Cl N7 O3 Pt, 0.5(H1.20 O0.60),  0.7(H2 O), Cl'
_chemical_formula_sum            'C20 H21 Cl2 N7 O4 Pt'
_chemical_formula_weight         689.43
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.496(3)
_cell_angle_beta                 91.829(4)
_cell_angle_gamma                106.319(3)
_cell_formula_units_Z            2
_cell_length_a                   8.111(3)
_cell_length_b                   10.413(4)
_cell_length_c                   16.871(3)
_cell_measurement_reflns_used    3668
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      26.84
_cell_measurement_theta_min      2.39
_cell_volume                     1366.6(8)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_diffrn_ambient_temperature      291(2)
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_device_type  'Bruker Smart Apex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0418
_diffrn_reflns_av_sigmaI/netI    0.0519
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            7203
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.04
_exptl_absorpt_coefficient_mu    5.366
_exptl_absorpt_correction_T_max  0.34
_exptl_absorpt_correction_T_min  0.25
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.675
_exptl_crystal_description       block
_exptl_crystal_F_000             668
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.374
_refine_diff_density_min         -1.349
_refine_diff_density_rms         0.192
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.087
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     322
_refine_ls_number_reflns         5172
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.087
_refine_ls_R_factor_all          0.0628
_refine_ls_R_factor_gt           0.0466
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.09P)^2^+1.99P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1256
_refine_ls_wR_factor_ref         0.1355
_reflns_number_gt                4264
_reflns_number_total             5172
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic201506y_si_002.cif
_cod_data_source_block           290929a_0m
_cod_original_sg_symbol_H-M      'P -1 '
_cod_database_code               4326995