A Dinuclear Palladium Compound, [Pd~2~(PPh~3~)~2~(SC~2~H~4~S)~2~]
Cao, R.; Hong, M.; Jiang, F.; Liu, H.; Acta Crystallographica Section C 51 (1995) 1280–1282; doi:10.1107/S0108270194015076

data_2003618
_publ_section_title
;
 A Dinuclear Palladium Compound, [Pd~2~(PPh~3~)~2~(SC~2~H~4~S)~2~]
;
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1280
_journal_page_last               1282
_journal_paper_doi               10.1107/S0108270194015076
_journal_volume                  51
_journal_year                    1995
_chemical_formula_moiety         'C40 H38 P2 Pd2 S4'
_chemical_formula_sum            'C40 H38 P2 Pd2 S4'
_chemical_formula_weight         921.75
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_type_scat_source           IntTabIV
_cell_angle_alpha                102.96(4)
_cell_angle_beta                 97.46(3)
_cell_angle_gamma                81.64(3)
_cell_formula_units_Z            2
_cell_length_a                   10.879(5)
_cell_length_b                   17.591(7)
_cell_length_c                   10.649(5)
_cell_measurement_reflns_used    20
_cell_measurement_temperature    296
_cell_measurement_theta_max      12
_cell_measurement_theta_min      9
_cell_volume                     1954.9(15)
_diffrn_measurement_device       'MSC/Rigaku AFC5R'
_diffrn_measurement_method       \w/2\q
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.023
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            7280
_diffrn_reflns_theta_max         25
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 250
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.2213
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.823
_exptl_absorpt_correction_type
;
empirical, \y scans before and DIFABS (Walker & Stuart, 1983) during
refinement
;
_exptl_crystal_colour            violet
_exptl_crystal_density_diffrn    1.566
_exptl_crystal_description       rectangular
_exptl_crystal_size_max          0.65
_exptl_crystal_size_mid          0.55
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.78
_refine_diff_density_min         -0.53
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_obs   3.327
_refine_ls_hydrogen_treatment    'H atoms not located'
_refine_ls_number_parameters     433
_refine_ls_number_reflns         5949
_refine_ls_R_factor_obs          0.041
_refine_ls_shift/esd_max         0.08
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme
'Unit weights: I>3\s(I) w = 1, I<=3\s(I) w = 0'
_refine_ls_wR_factor_obs         0.047
_reflns_number_observed          5949
_reflns_number_total             7156
_reflns_observed_criterion       I>3\s(I)
_cod_data_source_file            ab1192.cif
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_cod_original_cell_volume        1955(2)
_cod_database_code               2003618