{Fe3Nb25} cluster based on an Fe-centred Keggin unit.
Liang, Zhijie; Wang, Ke; Zhang, Dongdi; Ma, Pengtao; Niu, Jingyang; Wang, Jingping; Dalton transactions (Cambridge, England : 2003) 46 (2017) 1368–1371; doi:10.1039/c6dt04223f

data_7041471
_publ_section_title
;
 {Fe3Nb25} cluster based on an Fe-centred Keggin unit.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1368
_journal_page_last               1371
_journal_paper_doi               10.1039/c6dt04223f
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C57 H39 N5 O9 Zn2,4(C3 H7 N O),2(C2 H3 N)'
_chemical_formula_sum            'C73 H73 N11 O13 Zn2'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_atom_sites_solution_hydrogens   geom
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;
2016-12-10 deposited with the CCDC.
2016-12-15 downloaded from the CCDC.
;
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_computing_structure_solution    'SHELXTL Ver.6.10,(Sheldrick, 2000)'
_diffrn_ambient_temperature      296(2)
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_exptl_crystal_colour            yellowish
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_refine_ls_restrained_S_all      1.365
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0833P)^2^+27.1464P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             11989
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt04223f2.cif
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_cod_depositor_comments
'Adding full bibliography for 7041469--7041645.cif.'
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