Photoluminescent Dinuclear Lanthanide Complexes with Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand
Masayuki Watanabe; Takuya Nankawa; Teppei Yamada; Takaumi Kimura; Kosuke Namiki; Masaki Murata; Hiroshi Nishihara; Shoichi Tachimori; Inorganic Chemistry 42 (2003) 6977–6979; doi:10.1021/ic034816n

data_4312440
_publ_contact_author_address
;
    2-4, Shirakata Shirane, Tokai, Naka-gun, 
    Ibaraki, 319-1195, Department of 
    Materials Science
    Japan Atomic Energy Research Institute. 
;
_publ_contact_author_email       mw@popsvr.tokai.jaeri.go.jp
_publ_contact_author_fax         +81-29-282-5788
_publ_contact_author_name        'Masayuki Watanabe'
_publ_contact_author_phone       +81-29-282-6723
_publ_section_title
;
 Photoluminescent Dinuclear Lanthanide Complexes with
 Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6977
_journal_page_last               6979
_journal_paper_doi               10.1021/ic034816n
_journal_volume                  42
_journal_year                    2003
_chemical_formula_moiety         'C40 H34 F12 N8 O16 S4 Tb2 '
_chemical_formula_sum            'C40 H34 F12 N8 O16 S4 Tb2'
_chemical_formula_weight         1556.82
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                65.41(2)
_cell_angle_beta                 63.28(3)
_cell_angle_gamma                72.29(3)
_cell_formula_units_Z            1
_cell_length_a                   10.891(3)
_cell_length_b                   11.400(3)
_cell_length_c                   13.089(3)
_cell_measurement_reflns_used    6827
_cell_measurement_temperature    293.1
_cell_measurement_theta_max      30.0
_cell_measurement_theta_min      3.1
_cell_volume                     1306.1(7)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 3.10'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 14.62
_diffrn_measured_fraction_theta_full 0.9440
_diffrn_measured_fraction_theta_max 0.9440
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.031
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            14890
_diffrn_reflns_theta_full        30.02
_diffrn_reflns_theta_max         30.02
_exptl_absorpt_coefficient_mu    2.963
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.979
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1520.00
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.03
_refine_diff_density_min         -0.90
_refine_ls_extinction_coef       59.5(72)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   1.351
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     439
_refine_ls_number_reflns         7202
_refine_ls_R_factor_gt           0.0280
_refine_ls_shift/su_max          0.0030
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/\s^2^(Fo)'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0350
_reflns_number_gt                6692
_reflns_number_total             7202
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic034816nsi20030713_110704_2.cif
_cod_data_source_block           '__Tb7_35'
_cod_original_cell_volume        1306.1(6)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C40 H34 F12 N8 O16 S4 Tb2 '
_cod_database_code               4312440