A pentacoordinated norbornenyl-acyl-rhodium(iii) complex as a likely intermediate in the catalytic hydroacylation of norbornadiene.
Almenara, N.; Ibarlucea, L.; Mendicute-Fierro, C; Seco, J. M.; Rodríguez-Diéguez, A; Garralda, M. A.; Huertos, M. A.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 18502–18509; doi:10.1039/c6dt03778j

data_7040961
_publ_section_title
;
 A pentacoordinated norbornenyl-acyl-rhodium(iii) complex as a likely
 intermediate in the catalytic hydroacylation of norbornadiene.
;
_journal_issue                   46
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18502
_journal_page_last               18509
_journal_paper_doi               10.1039/c6dt03778j
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C37 H31 Cl5 F3 N O P Rh'
_chemical_formula_weight         873.76
_chemical_name_systematic
;
 ?
;
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_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2016-09-21 deposited with the CCDC.
2016-10-18 downloaded from the CCDC.
;
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;
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0496P)^2^+0.3047P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7040960--7040962.cif.'
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