Syntheses, Characterization, and Structures of Tri- and Tetraruthenium Clusters Containing Sulfido, Phenylimido, and (Phenylimino)thio Ligands
Wen-Yann Yeh; Stern; Duward F. Shriver; Inorganic Chemistry 35 (1996) 7857–7862; doi:10.1021/ic960697i

data_4324004
_publ_contact_author
;
D.F. Shriver
Department of Chemistry
Northwestern University
Evanston, IL 60208-3113, USA
;
_publ_contact_author_email       ' Shriver@chem.nwu.edu '
_publ_contact_author_fax         ' 847-491-7713 '
_publ_contact_author_phone       ' 847-491-5655'
_publ_section_title
;
 Syntheses, Characterization, and Structures of Tri- and Tetraruthenium
 Clusters Containing Sulfido, Phenylimido, and (Phenylimino)thio Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7857
_journal_page_last               7862
_journal_paper_doi               10.1021/ic960697i
_journal_volume                  35
_journal_year                    1996
_chemical_formula_moiety         'C17 H5 N O11 S2 Ru4 '
_chemical_formula_sum            'C17 H5 N O11 Ru4 S2'
_chemical_formula_weight         867.63
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             'Tue Apr  1 11:05:50 1997'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 103.06(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.986(7)
_cell_length_b                   13.968(3)
_cell_length_c                   19.232(9)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    153.2
_cell_measurement_theta_max      24.2
_cell_measurement_theta_min      19.4
_cell_volume                     2351(2)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
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_diffrn_ambient_temperature      153.2
_diffrn_measurement_device       CAD4
_diffrn_measurement_method       'omega/theta scans'
_diffrn_orient_matrix_UB_11      -0.04860
_diffrn_orient_matrix_UB_12      0.03838
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_diffrn_reflns_limit_l_min       -21
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_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 90
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_exptl_absorpt_correction_type   analytical
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_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0254
_refine_ls_shift/esd_max         0.0260
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
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_reflns_number_observed          2929
_reflns_number_total             3919
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_cod_data_source_file            ic960697i_2.cif
_cod_data_source_block           compound3
_cod_original_cell_volume        2351(1)
_cod_original_sg_symbol_H-M      'P 21/n '
_cod_original_formula_sum        'C17 H5 N O11 S2 Ru4 '
_cod_database_code               4324004