Metal-ligand cooperativity enables zero-valent metal transfer.
Riu, Martin-Louis Y; Shan, Jing-Ran; Houk, K. N.; Nava, Matthew; Chemical science 16 (2025) 3888–3894; doi:10.1039/d4sc07938h

data_1573749
_publ_section_title
;
 Metal-ligand cooperativity enables zero-valent metal transfer.
;
_journal_issue                   9
_journal_name_full               'Chemical science'
_journal_page_first              3888
_journal_page_last               3894
_journal_paper_doi               10.1039/d4sc07938h
_journal_volume                  16
_journal_year                    2025
_chemical_formula_sum            'C31 H62 Al N3 O4'
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2024-04-10 deposited with the CCDC.	2025-01-16 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0604P)^2^+2.2891P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1465
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_reflns_number_gt                6677
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4sc07938h2.cif
_cod_data_source_block           nava2307
_cod_depositor_comments
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The following automatic conversions were performed:

data item '_exptl_crystal_density_meas' value 'not measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 

 Adding full bibliography for 1573748--1573752.cif.
;
_cod_database_code               1573749
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_shelx_estimated_absorpt_t_min   0.737
_shelx_estimated_absorpt_t_max   0.835
_shelx_res_checksum              83741