The facile realization of RGB luminescence based on one yellow emissive four-coordinate organoboron material
Lu Wang; Kai Wang; Houyu Zhang; Chuanjun Jiao; Bo Zou; Kaiqi Ye; Hongyu Zhang; Yue Wang; Chem.Commun. 51 (2015) 7701–; doi:10.1039/C5cc01113B

data_7117041
_publ_section_title
;
 The facile realization of RGB luminescence based on one yellow emissive
 four-coordinate organoboron material
;
_journal_name_full               Chem.Commun.
_journal_page_first              7701
_journal_paper_doi               10.1039/C5cc01113B
_journal_volume                  51
_journal_year                    2015
_chemical_formula_sum            'C29 H16 B F10 N O2'
_chemical_formula_weight         611.24
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-12-03 deposited with the CCDC.
2015-03-30 downloaded from the CCDC.
;
_cell_angle_alpha                111.3160(10)
_cell_angle_beta                 103.8310(10)
_cell_angle_gamma                100.2430(10)
_cell_formula_units_Z            2
_cell_length_a                   11.0372(7)
_cell_length_b                   11.6357(7)
_cell_length_c                   11.8660(7)
_cell_measurement_reflns_used    7933
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.1475
_cell_measurement_theta_min      2.271
_cell_volume                     1318.13(14)
_computing_cell_refinement       'SHELXS-97 (Sheldrick, 1990)'
_computing_data_collection       'SHELXS-97 (Sheldrick, 1990)'
_computing_data_reduction        'SHELXS-97 (Sheldrick, 1990)'
_computing_molecular_graphics    'SHELXL-97 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0209
_diffrn_reflns_av_sigmaI/netI    0.0354
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            7932
_diffrn_reflns_theta_full        25.44
_diffrn_reflns_theta_max         25.44
_diffrn_reflns_theta_min         1.95
_exptl_absorpt_coefficient_mu    0.144
_exptl_absorpt_correction_T_max  0.9829
_exptl_absorpt_correction_T_min  0.9486
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.540
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             616
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.525
_refine_diff_density_min         -0.459
_refine_diff_density_rms         0.049
_refine_ls_extinction_coef       0.024(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     367
_refine_ls_number_reflns         4837
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.063
_refine_ls_R_factor_all          0.0778
_refine_ls_R_factor_gt           0.0578
_refine_ls_shift/su_max          0.018
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0671P)^2^+0.9582P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1484
_refine_ls_wR_factor_ref         0.1645
_reflns_number_gt                3548
_reflns_number_total             4837
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5cc01113b2.cif
_cod_data_source_block           1OC
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7117041