Two polymorph modifications of tris(hexafluoroacetylacetonato)iron(III) revealed: is that common for other trivalent metals?
Chang, Joyce; Defeo, Julianna N.; Wei, Zheng; Dikarev, Evgeny V.; Acta crystallographica. Section C, Structural chemistry 80 (2024) –; doi:10.1107/S2053229624007575

data_2312582
_publ_section_title
;
 Two polymorph modifications of tris(hexafluoroacetylacetonato)iron(III)
 revealed: is that common for other trivalent metals?
;
_journal_coeditor_code           VX3007
_journal_issue                   9
_journal_name_full
'Acta crystallographica. Section C, Structural chemistry'
_journal_paper_doi               10.1107/S2053229624007575
_journal_volume                  80
_journal_year                    2024
_chemical_formula_iupac          '[Fe (C5 H1 F6 O2)3]'
_chemical_formula_moiety         'C15 H3 F18 Fe O6'
_chemical_formula_sum            'C15 H3 F18 Fe O6'
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_chemical_name_common
;
Tris(hexafluoroacetylacetonato)iron(III)
;
_chemical_name_systematic
;
Tris(1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olato)iron(III)
;
_space_group_crystal_system      trigonal
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Olex2 1.5-ac6-020
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SAINT (Bruker, 2018)
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APEX3 (Bruker, 2018)
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SAINT (Bruker, 2018)
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OLEX2 (Dolomanov <i>et al.</i>,  2009)
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OLEX2 (Dolomanov <i>et al.</i>,  2009)
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SHELXL2019 (Sheldrick, 2015b)
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SHELXT2018 (Sheldrick, 2015a)
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(SADABS; Bruker, 2018)
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SHELXL2019 (Sheldrick, 2015b)
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'w=1/[\s^2^(Fo^2^)+(0.0325P)^2^+0.8379P] where P=(Fo^2^+2Fc^2^)/3'
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