Reactions of Ru(CCPh)(PPh3)2Cp* with tetracyanoethene: cycloaddition, formation of unusual η2-CNR complexes and oligomerisation via bridging cyanocarbon ligands
Bruce, Michael I.; Skelton, Brian W.; White, Allan H.; Zaitseva, Natasha N.; Journal of the Chemical Society, Dalton Transactions  (2001) 3627–; doi:10.1039/b105131h

data_7010904
_publ_section_title
;
 Reactions of Ru(C&#xE002;CPh)(PPh3)2Cp* with tetracyanoethene:
 cycloaddition, formation of unusual \h2-CNR complexes and
 oligomerisation via bridging cyanocarbon ligands
;
_journal_issue                   24
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              3627
_journal_paper_doi               10.1039/b105131h
_journal_year                    2001
_chemical_formula_sum            'C43 H39 N4 O P Ru'
_chemical_formula_weight         759.86
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_cell_measurement_temperature    153
_cell_measurement_theta_max      26.4
_cell_measurement_theta_min      2.4
_cell_volume                     1814.7(3)
_computing_cell_refinement       'Siemens SAINT (Siemens, 1995)'
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_diffrn_measurement_device_type
;
Bruker SMART CCD diffractometer
;
_diffrn_measurement_method       '\w scans'
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_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_av_sigmaI/netI    .053
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_diffrn_reflns_theta_min         1.33
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    .516
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS; Sheldrick, 1996
;
_exptl_crystal_colour            dark
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_exptl_crystal_description       prism
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_exptl_crystal_size_max          .22
_exptl_crystal_size_mid          .19
_exptl_crystal_size_min          .1
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_refine_ls_structure_factor_coef F
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_refine_ls_wR_factor_ref         .037
_reflns_d_resolution_high        .726
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_reflns_Friedel_coverage         0
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_reflns_threshold_expression     'F    > 4.00 sig(F   )'
_cod_data_source_file            b105131h.txt
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_cod_original_sg_symbol_H-M      P_-1
_cod_original_formula_sum        'C43 H39 N4 O1 P1 Ru1'
_cod_database_code               7010904