The Platinum Center is a Stronger Nucleophile than the Free Nitrogen Donors in a Dimethylplatinum Complex with a Dipyridylpyridazine Ligand
McCready, Matthew S.; Puddephatt, Richard J.; Organometallics 34 (2015) 2261–; doi:10.1021/om501023r

data_4084598
_publ_section_title
;
 The Platinum Center is a Stronger Nucleophile than the Free Nitrogen
 Donors in a Dimethylplatinum Complex with a Dipyridylpyridazine Ligand
;
_journal_issue                   11
_journal_name_full               Organometallics
_journal_page_first              2261
_journal_paper_doi               10.1021/om501023r
_journal_volume                  34
_journal_year                    2015
_chemical_formula_moiety         'C22 H26 Br2 Hg N4 Pt, 2(C H Cl3)'
_chemical_formula_sum            'C24 H28 Br2 Cl6 Hg N4 Pt'
_chemical_formula_weight         1140.70
_chemical_name_systematic
; 
 ? 
;
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_cell_angle_beta                 78.27(3)
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_cell_measurement_theta_min      2.10
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_computing_cell_refinement       'DENZO-SMN (Otwinowski & Minor, 1997)'
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_computing_molecular_graphics    'SHELXTL/PC (Sheldrick, 2001)'
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_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Nonius Kappa-CCD'
_diffrn_measurement_method       '\f scans, and \w scans with \k offsets'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_full        27.63
_diffrn_reflns_theta_max         27.63
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_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.332
_exptl_crystal_density_method    'not measured'
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0867
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0750P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1342
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om501023r_si_002.cif
_cod_data_source_block           3b
_cod_depositor_comments
'Adding full bibliography for 4084597--4084602.cif.'
_cod_original_cell_volume        1624.8(6)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4084598