Donor-Promoted 1,2-Hydrogen Migration from Silicon to a Saturated Ruthenium Center and Access to Silaoxiranyl and Silaiminyl Complexes.
Liu, Hsueh-Ju; Landis, Clark; Raynaud, Christophe; Eisenstein, Odile; Tilley, T. Don; Journal of the American Chemical Society 137 (2015) 9186–9194; doi:10.1021/jacs.5b05571

data_4123946
_publ_section_title
;
 Donor-Promoted 1,2-Hydrogen Migration from Silicon to a Saturated
 Ruthenium Center and Access to Silaoxiranyl and Silaiminyl Complexes.
;
_journal_issue                   28
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              9186
_journal_page_last               9194
_journal_paper_doi               10.1021/jacs.5b05571
_journal_volume                  137
_journal_year                    2015
_chemical_formula_moiety         'C57 H70 N2 O1 Ru1 Si1'
_chemical_formula_sum            'C57 H70 N2 O Ru Si'
_chemical_formula_weight         928.31
_chemical_name_common            hj4008
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_space_group_name_Hall           '-P 2yn'
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_cell_measurement_temperature    100(2)
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.139
_refine_ls_R_factor_all          0.0904
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0058P)^2^+24.5907P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja5b05571_si_001.cif
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_cod_depositor_comments
'Adding full bibliography for 4123944--4123947.cif.'
_cod_original_formula_sum        'C57 H70 N2 O1 Ru1 Si1'
_cod_database_code               4123946
_shelx_shelxl_version_number     2014/7
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