Kinetic and mechanistic study on the reactions of [Pt(bpma)(H2O)]2+ and [Pd(bpma)(H2O)]2+ with some nucleophiles. Crystal structure of [Pd(bpma)(py)](ClO4)2.
Jaganyi, Deogaratius; Tiba, Felicia; Munro, Orde Q.; Petrović, Biljana; Bugarcić, Zivadin D; Dalton transactions (Cambridge, England : 2003)  (2006) 2943–2949; doi:10.1039/b602950g

data_7007294
_publ_section_title
;
 Kinetic and mechanistic study on the reactions of [Pt(bpma)(H2O)]2+
 and [Pd(bpma)(H2O)]2+ with some nucleophiles. Crystal structure of
 [Pd(bpma)(py)](ClO4)2.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2943
_journal_page_last               2949
_journal_paper_doi               10.1039/b602950g
_journal_year                    2006
_chemical_formula_moiety         'C17 H18 N4 Pd, 2(Cl O4)'
_chemical_formula_sum            'C17 H18 Cl2 N4 O8 Pd'
_chemical_formula_weight         583.65
_chemical_name_common            '[Pd(pap)py](ClO4)2'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                89.20(2)
_cell_angle_beta                 81.03(2)
_cell_angle_gamma                60.61(2)
_cell_formula_units_Z            2
_cell_length_a                   8.522(2)
_cell_length_b                   8.627(2)
_cell_length_c                   16.730(4)
_cell_measurement_reflns_used    2149
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      32
_cell_measurement_theta_min      4
_cell_volume                     1055.8(5)
_computing_cell_refinement       'CrysAlis RED 170'
_computing_data_collection       'CrysAlis CCD 170'
_computing_data_reduction        'CrysAlis RED 170'
_computing_molecular_graphics    'WinGX (Farrugia, 1999)'
_computing_publication_material  'ORTEP-3 (Farrugia, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.887
_diffrn_measurement_device_type  'Oxford Diffraction Xcalibur 2 CCD'
_diffrn_measurement_method       'omega-2theta scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0318
_diffrn_reflns_av_sigmaI/netI    0.0400
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            10217
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         31.61
_diffrn_reflns_theta_min         4.73
_exptl_absorpt_coefficient_mu    1.186
_exptl_absorpt_correction_T_max  0.659
_exptl_absorpt_correction_T_min  0.564
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.836
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'rectangular block'
_exptl_crystal_F_000             584
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.35
_refine_diff_density_max         1.112
_refine_diff_density_min         -1.141
_refine_diff_density_rms         0.116
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     330
_refine_ls_number_reflns         6296
_refine_ls_number_restraints     93
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.0701
_refine_ls_R_factor_gt           0.0541
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0723P)^2^+1.3562P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1365
_refine_ls_wR_factor_ref         0.1475
_reflns_number_gt                5089
_reflns_number_total             6296
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b602950g.txt
_cod_data_source_block           pd_pap
_cod_original_cell_volume        1055.7(5)
_cod_database_code               7007294