10-Hydroxybenzo[<i>h</i>]quinolinium tetrachlorido(2-methylquinolin-8-olato-κ^2^<i>N</i>,<i>O</i>)stannate(IV) methanol disolvate
Najafi, Ezzatollah; Vafaee, Marzieh; Amini, Mostafa M.; Ng, Seik Weng; Acta Crystallographica Section E 67 (2011) m1223–; doi:10.1107/S1600536811031461

data_2231738
_publ_section_title
;
 10-Hydroxybenzo[<i>h</i>]quinolinium
 tetrachlorido(2-methylquinolin-8-olato-\k^2^<i>N</i>,<i>O</i>)stannate(IV)
 methanol disolvate
;
_journal_coeditor_code           XU5283
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1223
_journal_paper_doi               10.1107/S1600536811031461
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac
'(C13 H10 N O) [Sn Cl4 (C10 H8 N O)], 2C H4 O'
_chemical_formula_moiety
'C13 H10 N O +, C10 H8 Cl4 N O Sn -, 2(C H4 O)'
_chemical_formula_sum            'C25 H26 Cl4 N2 O4 Sn'
_chemical_formula_weight         678.97
_chemical_name_systematic
;
10-Hydroxybenzo[<i>h</i>]quinolinium
tetrachlorido(2-methylquinolin-8-olato-\k^2^<i>N</i>,<i>O</i>)stannate(IV)
methanol disolvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.105(3)
_cell_angle_beta                 95.653(3)
_cell_angle_gamma                97.509(3)
_cell_formula_units_Z            2
_cell_length_a                   7.5645(2)
_cell_length_b                   10.1112(3)
_cell_length_c                   17.7837(5)
_cell_measurement_reflns_used    6565
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.27
_cell_measurement_theta_min      2.33
_cell_volume                     1325.56(7)
_computing_cell_refinement       'CrysAlis PRO (Agilent, 2010)'
_computing_data_collection       'CrysAlis PRO (Agilent, 2010)'
_computing_data_reduction        'CrysAlis PRO (Agilent, 2010)'
_computing_molecular_graphics    'X-SEED (Barbour, 2001)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.4041
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_device_type
'Agilent SuperNova Dual diffractometer with an Atlas detector'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  Mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0555
_diffrn_reflns_av_sigmaI/netI    0.0611
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            10548
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         2.52
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.402
_exptl_absorpt_correction_T_max  0.8725
_exptl_absorpt_correction_T_min  0.6784
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrysAlis PRO; Agilent, 2010)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.701
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             680
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.234
_refine_diff_density_min         -1.138
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.108
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     340
_refine_ls_number_reflns         5871
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.108
_refine_ls_R_factor_all          0.0510
_refine_ls_R_factor_gt           0.0409
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0329P)^2^+1.5116P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0900
_refine_ls_wR_factor_ref         0.0947
_reflns_number_gt                5239
_reflns_number_total             5871
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            xu5283.cif
_cod_data_source_block           I
_cod_original_cell_volume        1325.56(6)
_cod_database_code               2231738
_cod_database_fobs_code          2231738