Retention of Configuration on the Oxidative Addition of P-H Bond to Platinum (0) Complexes: The First Straightforward Synthesis of Enantiomerically Pure P-Chiral Alkenylphosphinates via Palladium-Catalyzed Stereospecific Hydrophosphinylation of Alkynes
Li-Biao Han; Chang-Qiu Zhao; Shun-ya Onozawa; Midori Goto; Masato Tanaka; Journal of the American Chemical Society 124 (2002) 3842–3843; doi:10.1021/ja025816+

data_4114739
_publ_contact_author_address
;
     1-1-1
 Higashi
 central 5
 National  Institute
 of Advanced Industrial Science
 and Technology
;
_publ_contact_author_email       ' libiao-han@aist.go.jp '
_publ_contact_author_fax         ' 81-298-61-4511 '
_publ_contact_author_name        'Li-Biao Han'
_publ_contact_author_phone       ' 81-298-61-4855 '
_publ_section_title
;
 Retention of Configuration on the Oxidative Addition of P-H Bond to
 Platinum (0) Complexes: The First Straightforward Synthesis of
 Enantiomerically Pure P-Chiral Alkenylphosphinates via
 Palladium-Catalyzed Stereospecific Hydrophosphinylation of Alkynes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3842
_journal_page_last               3843
_journal_paper_doi               10.1021/ja025816+
_journal_volume                  124
_journal_year                    2002
_chemical_formula_moiety         'C42 H73 O2 P3 Pt '
_chemical_formula_sum            'C42 H73 O2 P3 Pt'
_chemical_formula_weight         898.05
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   17.455(6)
_cell_length_b                   21.777(4)
_cell_length_c                   11.484(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    203.2
_cell_measurement_theta_max      14.9
_cell_measurement_theta_min      14.6
_cell_volume                     4365(2)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 1.8034
_diffrn_measured_fraction_theta_max 1.8034
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.048
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            11078
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_standards_decay_%        8.02
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.343
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.927
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.366
_exptl_crystal_description       needle
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.050
_refine_diff_density_max         0.35
_refine_diff_density_min         -0.18
_refine_ls_abs_structure_details Flack
_refine_ls_abs_structure_Flack   0.000(8)
_refine_ls_extinction_coef       0.0046(3)
_refine_ls_extinction_method     'Zachariasen(1967) type 2 gaussian isotropic'
_refine_ls_goodness_of_fit_ref   1.266
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     435
_refine_ls_number_reflns         9964
_refine_ls_R_factor_gt           0.0486
_refine_ls_shift/su_max          0.0083
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1258
_reflns_number_gt                7841
_reflns_number_total             9964
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ja0258162B_s2_2.cif
_cod_data_source_block           Complex_3b
_cod_original_cell_volume        4365(1)
_cod_original_sg_symbol_H-M      'P 21 21 21 '
_cod_original_formula_sum        'C42 H73 O2 P3 Pt '
_cod_database_code               4114739