Gold(i)-catalysed cascade reactions in the synthesis of 2,3-fused indole derivatives.
Gimeno, Ana; Rodríguez-Gimeno, Alejandra; Cuenca, Ana B.; Ramírez de Arellano, Carmen; Medio-Simón, Mercedes; Asensio, Gregorio; Chemical communications (Cambridge, England) 51 (2015) 12384–12387; doi:10.1039/c5cc04606h

data_7117570
_publ_section_title
;
 Gold(i)-catalysed cascade reactions in the synthesis of 2,3-fused indole
 derivatives.
;
_journal_issue                   62
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              12384
_journal_page_last               12387
_journal_paper_doi               10.1039/c5cc04606h
_journal_volume                  51
_journal_year                    2015
_chemical_formula_sum            'C73.5 H95 Au2 Cl3 F6 N5 O4 Sb'
_chemical_formula_weight         1848.57
_chemical_properties_physical
'Air-sensitive, Moisture-sensitive, Oxygen-sensitive'
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-04-23 deposited with the CCDC.
2015-07-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90.406(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_c                   21.9456(4)
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_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      29.2830
_cell_measurement_theta_min      3.4730
_cell_volume                     7842.6(3)
_computing_cell_refinement       'CrysAlisPro-2014, Agilent Technologies'
_computing_data_collection       'CrysAlisPro-2014, Agilent Technologies'
_computing_data_reduction        'CrysAlisPro-2014, Agilent Technologies'
_computing_molecular_graphics    'CrystalMaker-2014, CrystalMaker Software'
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_diffrn_ambient_temperature      120(2)
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_diffrn_measured_fraction_theta_full 0.879
_diffrn_measured_fraction_theta_max 0.739
_diffrn_measurement_device_type  'SuperNova, Agilent Technologies'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0986
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_diffrn_reflns_Laue_measured_fraction_full 0.879
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_diffrn_reflns_limit_h_max       25
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_diffrn_reflns_limit_k_max       29
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_diffrn_source                   'Single source at offset, Sapphire3'
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_exptl_crystal_description       tablet
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_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: dichloromethane/pentane'
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_exptl_crystal_size_mid          0.100
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0538P)^2^+34.8759P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1486
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_reflns_number_gt                14029
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           agindol1
_cod_original_formula_sum        'C73.50 H95 Au2 Cl3 F6 N5 O4 Sb'
_cod_database_code               7117570
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_shelx_estimated_absorpt_t_min   0.484
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_shelx_res_checksum              4936