Alkali-metal organomagnesiate complexes as catalysts for highly chemoselective crossed-Tishchenko reactions.
Guo, Zhiqiang; Pang, Tengfei; Wang, Yakong; Zhang, Yongbin; Wei, Xuehong; Dalton transactions (Cambridge, England : 2003) 49 (2020) 6418–6424; doi:10.1039/d0dt01114b

data_7704182
_publ_section_title
;
 Alkali-metal organomagnesiate complexes as catalysts for highly
 chemoselective crossed-Tishchenko reactions.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6418
_journal_page_last               6424
_journal_paper_doi               10.1039/d0dt01114b
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C38 H77 Mg2 N8 Na2'
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-04-21 deposited with the CCDC.	2020-04-23 downloaded from the CCDC.
;
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_cell_measurement_temperature    150(2)
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_cell_volume                     4648.1(3)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      150(2)
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_max         25.049
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_exptl_absorpt_coefficient_mu    0.104
_exptl_crystal_colour            colorless
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_exptl_crystal_description       block
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         8183
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_refine_ls_R_factor_all          0.0940
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0987P)^2^+5.3677P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.2121
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6002
_reflns_number_total             8183
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt01114b2.cif
_cod_data_source_block           161101a
_cod_depositor_comments
'Adding full bibliography for 7704180--7704184.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7704182
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.970
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_shelx_res_checksum              17482