[μ-1,6-Bis(diphenylarsanyl)hexane]bis[chloridogold(I)]
bin Shawkataly, Omar; Tariq, Abu; Khan, Imthyaz Ahmad; Yeap, Chin Sing; Fun, Hoong-Kun; Acta Crystallographica Section E 67 (2011) m427–m428; doi:10.1107/S1600536811008646

data_2229716
_publ_section_title
;
 [\m-1,6-Bis(diphenylarsanyl)hexane]bis[chloridogold(I)]
;
_journal_coeditor_code           IS2685
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m427
_journal_page_last               m428
_journal_paper_doi               10.1107/S1600536811008646
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Au2 Cl2 (C30 H32 As2)]'
_chemical_formula_moiety         'C30 H32 As2 Au2 Cl2'
_chemical_formula_sum            'C30 H32 As2 Au2 Cl2'
_chemical_formula_weight         1007.23
_chemical_name_systematic
;
[\m-1,6-Bis(diphenylarsanyl)hexane]bis[chloridogold(I)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                69.7230(10)
_cell_angle_beta                 83.9590(10)
_cell_angle_gamma                79.8140(10)
_cell_formula_units_Z            2
_cell_length_a                   9.4881(3)
_cell_length_b                   11.0350(4)
_cell_length_c                   15.5254(5)
_cell_measurement_reflns_used    9948
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      35.07
_cell_measurement_theta_min      3.23
_cell_volume                     1499.06(9)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'APEX2 (Bruker, 2009)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material
;
SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009)
;
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      100
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type
;
Bruker SMART APEXII CCD area-detector
;
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0274
_diffrn_reflns_av_sigmaI/netI    0.0291
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            23816
_diffrn_reflns_theta_full        28.50
_diffrn_reflns_theta_max         28.50
_diffrn_reflns_theta_min         2.54
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    12.162
_exptl_absorpt_correction_T_max  0.4074
_exptl_absorpt_correction_T_min  0.0936
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(<i>SADABS</i>; Bruker, 2009)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.231
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             940
_exptl_crystal_size_max          0.368
_exptl_crystal_size_mid          0.215
_exptl_crystal_size_min          0.093
_refine_diff_density_max         2.518
_refine_diff_density_min         -2.997
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.091
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     371
_refine_ls_number_reflns         7451
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.091
_refine_ls_R_factor_all          0.0343
_refine_ls_R_factor_gt           0.0314
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0596P)^2^+0.9210P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0856
_refine_ls_wR_factor_ref         0.0880
_reflns_number_gt                6817
_reflns_number_total             7451
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            is2685.cif
_cod_data_source_block           I
_cod_database_code               2229716
_cod_database_fobs_code          2229716