Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex
Kazuya Arashiba; Shogo Kuriyama; Kazunari Nakajima; Yoshiaki Nishibayashi; Chem.Commun. 49 (2013) 11215–; doi:10.1039/c3cc46946h

data_7110053
_publ_section_title
;
 Preparation and reactivity of a dinitrogen-bridged
 dimolybdenum-tetrachloride complex
;
_journal_name_full               Chem.Commun.
_journal_page_first              11215
_journal_paper_doi               10.1039/c3cc46946h
_journal_volume                  49
_journal_year                    2013
_chemical_formula_moiety         'C52 H100 Cl4 Mo2 N4 P4 '
_chemical_formula_sum            'C52 H100 Cl4 Mo2 N4 P4'
_chemical_formula_weight         1238.98
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                88.584(4)
_cell_angle_beta                 86.511(3)
_cell_angle_gamma                87.074(3)
_cell_formula_units_Z            2
_cell_length_a                   12.3345(16)
_cell_length_b                   12.7158(16)
_cell_length_c                   20.165(2)
_cell_measurement_reflns_used    11347
_cell_measurement_temperature    173.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     3152.0(6)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR97
_diffrn_ambient_temperature      173.1
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.049
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            30283
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.703
_exptl_absorpt_correction_T_max  0.869
_exptl_absorpt_correction_T_min  0.743
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
    Higashi, T. (1995). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.305
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1304.00
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.15
_refine_diff_density_min         -0.90
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     665
_refine_ls_number_reflns         14181
_refine_ls_R_factor_gt           0.0478
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w = 1/[1.7000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1210
_reflns_number_gt                10208
_reflns_number_total             14181
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            c3cc46946h.txt
_cod_data_source_block           '_20091009'
_cod_original_cell_volume        3151.9(7)
_cod_original_formula_sum        'C52 H100 Cl4 Mo2 N4 P4 '
_cod_database_code               7110053