Gold-catalyzed highly regio- and enantioselective vinylcarbene insertion into O-H bonds of 2-pyridones.
Huang, Daorui; Xu, Guangyang; Peng, Shiyong; Sun, Jiangtao; Chemical communications (Cambridge, England) 53 (2017) 3197–3200; doi:10.1039/c6cc10246h

data_7119703
_publ_section_title
;
 Gold-catalyzed highly regio- and enantioselective vinylcarbene insertion
 into O-H bonds of 2-pyridones.
;
_journal_issue                   22
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              3197
_journal_page_last               3200
_journal_paper_doi               10.1039/c6cc10246h
_journal_volume                  53
_journal_year                    2017
_chemical_absolute_configuration unk
_chemical_formula_sum            'C19 H21 N O3'
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_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'
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_audit_update_record
;
2016-01-06 deposited with the CCDC.
2017-02-21 downloaded from the CCDC.
;
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; 
 Refined as an inversion twin. 
;
_refine_ls_abs_structure_Flack   -2.1(18)
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'w=1/[\s^2^(Fo^2^)+(0.0647P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7119703--7119704.cif.'
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