Reductive Cleavage of CO2 by Metal-Ligand-Cooperation Mediated by an Iridium Pincer Complex.
Feller, Moran; Gellrich, Urs; Anaby, Aviel; Diskin-Posner, Yael; Milstein, David; Journal of the American Chemical Society 138 (2016) 6445–6454; doi:10.1021/jacs.6b00202

data_4130100
_publ_section_title
;
 Reductive Cleavage of CO2 by Metal-Ligand-Cooperation Mediated by an
 Iridium Pincer Complex.
;
_journal_issue                   20
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              6445
_journal_page_last               6454
_journal_paper_doi               10.1021/jacs.6b00202
_journal_volume                  138
_journal_year                    2016
_chemical_formula_moiety         'C25 H44 Ir N O4 P2, 3(C H2 Cl2)'
_chemical_formula_sum            'C28 H50 Cl6 Ir N O4 P2'
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'dtrek-CrysAlisPro-abstract goniometer imported rigaku-d*trek images'
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_exptl_absorpt_correction_T_max  1.00000
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0300P)^2^+2.5542P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_block           m1861
_cod_original_cell_volume        3722.49(17)
_cod_original_sg_symbol_H-M      'P 21/c'
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