N-(Methyl)phthalimide para functionalized Ni(ii)–POCOP pincer complexes. Synthesis, characterization and biological activity
Amaya-Flórez, Andrés; Serrano-García, Juan S.; Ruiz-Galindo, Jordi; Arenaza-Corona, Antonino; Hernández-Ortega, Simón; Orjuela, Adrián L.; Alí-Torres, Jorge; Flores-Alamo, Marcos; Reyes-Márquez, Viviana; Morales-Morales, David; New Journal of Chemistry 49 (2025) 5173–5186; doi:10.1039/D4NJ05183A

data_7063662
_publ_section_title
;
 N-(Methyl)phthalimide para functionalized Ni(ii)--POCOP pincer complexes.
 Synthesis, characterization and biological activity
;
_journal_issue                   13
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              5173
_journal_page_last               5186
_journal_paper_doi               10.1039/D4NJ05183A
_journal_volume                  49
_journal_year                    2025
_chemical_formula_sum            'C27 H36 Cl N Ni O5 P2'
_chemical_formula_weight         610.67
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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_symmetry_space_group_name_Hall  '-P 1'
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2025-01-28 deposited with the CCDC.	2025-02-13 downloaded from the CCDC.
;
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        CrysAlisPro, Agilent Technologies,
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        CrysAlisPro, Agilent Technologies,
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        CrysAlisPro, Agilent Technologies,
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          'Ortep-3 for Windows (Farrugia, 1997)'
      L. J. Farrugia, J. Appl. Crystallogr., 1997, 30, 565.
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        L. J. Farrugia, WinGX and ORTEP for Windows: an update, 
	J. Appl. Cryst. 45 (2012)  849-854.   
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      'SHELXS-2018 (Sheldrick, 2015)'
      Sheldrick, G. M. (2015). Acta Cryst. C71, 3--8.
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      'SHELXS-2018 (Sheldrick, 2015)'
      Sheldrick, G. M. (2015). Acta Cryst. A71, 3--8.
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
Analytical numeric absorption correction using a multifaceted crystal
                        model based on expressions derived by R.C. Clark & J.S.
        (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.42
_exptl_crystal_description       prism
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_exptl_crystal_size_min          0.29
_refine_diff_density_max         0.324
_refine_diff_density_min         -0.446
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         6923
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.083
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_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0337P)^2^+0.6174P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4nj05183a2.cif
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_cod_depositor_comments
'Adding full bibliography for 7063661--7063663.cif.'
_cod_database_code               7063662
_shelx_estimated_absorpt_t_min   0.631
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