Triphos derivatives and diphosphines as ligands in the ruthenium-catalysed alcohol amination with NH3.
Nakagawa, N.; Derrah, E. J.; Schelwies, M.; Rominger, F.; Trapp, O.; Schaub, T.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 6856–6865; doi:10.1039/c5dt04870b

data_7038370
_publ_section_title
;
 Triphos derivatives and diphosphines as ligands in the
 ruthenium-catalysed alcohol amination with NH3.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6856
_journal_page_last               6865
_journal_paper_doi               10.1039/c5dt04870b
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C43 H52 B3 P3'
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_chemical_name_common            '2-PG in manuscript'
_chemical_name_systematic
; 
 ? 
;
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_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2015-12-04 deposited with the CCDC.
2016-02-08 downloaded from the CCDC.
;
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_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            12558
_diffrn_reflns_point_group_measured_fraction_full 0.561
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_exptl_absorpt_process_details
;
Sheldrick, G. M. (2008). <i>SADABS</i>. University of G\"ottingen, Germany.
;
_exptl_crystal_colour            colourless
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0814P)^2^+0.9134P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7038370--7038373.cif.'
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