Strongest Ferromagnetic Coupling in Designed Gadolinium(III)-Nitroxide Coordination Compounds.
Kanetomo, Takuya; Yoshitake, Toru; Ishida, Takayuki; Inorganic chemistry 55 (2016) 8140–8146; doi:10.1021/acs.inorgchem.6b01072

data_4348197
_publ_section_title
;
 Strongest Ferromagnetic Coupling in Designed Gadolinium(III)-Nitroxide
 Coordination Compounds.
;
_journal_issue                   16
_journal_name_full               'Inorganic chemistry'
_journal_page_first              8140
_journal_page_last               8146
_journal_paper_doi               10.1021/acs.inorgchem.6b01072
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         '(C29 H27 F18 Gd N O8), 0.25(C7 H16)'
_chemical_formula_sum            'C30.75 H31 F18 Gd N O8'
_chemical_formula_weight         1041.81
_chemical_melting_point          343
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                68.282(13)
_cell_angle_beta                 78.289(14)
_cell_angle_gamma                76.722(16)
_cell_formula_units_Z            4
_cell_length_a                   10.530(4)
_cell_length_b                   17.475(7)
_cell_length_c                   23.745(7)
_cell_measurement_reflns_used    29036
_cell_measurement_temperature    100
_cell_measurement_theta_max      27.55
_cell_measurement_theta_min      3.06
_cell_volume                     3917(2)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
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_computing_molecular_graphics    'CrystalStructure 4.0'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_structure_refinement  'CRYSTALS (Carruthers, et al., 1999)'
_computing_structure_solution    'Superflip (Palatinus, et al., 2007)'
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean 29.412
_diffrn_measured_fraction_theta_full 0.962
_diffrn_measured_fraction_theta_max 0.962
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       \w
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_diffrn_reflns_theta_max         26.00
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_exptl_absorpt_correction_T_max  0.693
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.766
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
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'Larson (1970) Crystallographic Computing eq. 22'
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[0.0001Fo^2^ + 2.1000\s(Fo^2^)]'
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