Perylene-Tetrapalladium Sandwich Complexes
Tetsuro Murahashi; Tomohito Uemura; Hideo Kurosawa; Journal of the American Chemical Society 125 (2003) 8436–8437; doi:10.1021/ja0358246

data_4113911
_publ_section_title
;
 Perylene-Tetrapalladium Sandwich Complexes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              8436
_journal_page_last               8437
_journal_paper_doi               10.1021/ja0358246
_journal_volume                  125
_journal_year                    2003
_chemical_formula_sum            'C238 H126 B4 Cl4 F96 N4 Pd8'
_chemical_formula_weight         5901.74
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
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_cell_angle_beta                 113.958(1)
_cell_angle_gamma                113.9237(8)
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_cell_measurement_temperature    223.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.2
_cell_volume                     5497.91(12)
_computing_cell_refinement       PROCESS-AUTO
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_computing_publication_material  'teXsan Ver. 1.11'
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_diffrn_detector_area_resol_mean 10.00
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_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.032
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
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_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.827
_exptl_absorpt_correction_T_max  0.906
_exptl_absorpt_correction_T_min  0.777
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            red
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_exptl_crystal_description       prism
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_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.120
_refine_diff_density_max         1.03
_refine_diff_density_min         -0.83
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_hydrogen_treatment    noref
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_refine_ls_R_factor_gt           0.0447
_refine_ls_shift/su_max          2.1703
_refine_ls_structure_factor_coef F
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_reflns_threshold_expression     F^2^>3.0\s(F^2^)
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_cod_data_source_block           uemura
_cod_original_cell_volume        5497.9(1)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C238 H126 B4 Cl4 F96 N4 Pd8 '
_cod_database_code               4113911