Lead and tin β-diketiminato amido/anilido complexes: competitive nucleophilic reactivity at the β-diketiminato γ-carbon.
Harris, Lisa A.-M.; Tam, Eric C. Y.; Coles, Martyn P.; Fulton, J. Robin; Dalton transactions (Cambridge, England : 2003) 43 (2014) 13803–13814; doi:10.1039/c4dt01714e

data_7032365
_publ_section_title
;
 Lead and tin \b-diketiminato amido/anilido complexes: competitive
 nucleophilic reactivity at the \b-diketiminato \g-carbon.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13803
_journal_page_last               13814
_journal_paper_doi               10.1039/c4dt01714e
_journal_volume                  43
_journal_year                    2014
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C38 H53 N3 Pb1'
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_chemical_name_systematic
;
 ?
;
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_cell_angle_gamma                90
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_cell_length_b                   9.337(1)
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_cell_measurement_temperature    173(2)
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_cell_measurement_wavelength     0.71073
_cell_volume                     7214.8(13)
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'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
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_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
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_diffrn_ambient_temperature      173(2)
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_diffrn_orient_matrix_type       X=UH
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_diffrn_orient_matrix_UB_12      0
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_diffrn_orient_matrix_UB_22      0.01
_diffrn_orient_matrix_UB_23      0
_diffrn_orient_matrix_UB_31      0
_diffrn_orient_matrix_UB_32      0
_diffrn_orient_matrix_UB_33      0.01
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        [c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.398
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             3072
_exptl_crystal_size_max          0.15
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_refine_diff_density_max         0.715
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_refine_diff_density_rms         0.141
_refine_ls_extinction_method     none
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_refine_ls_number_reflns         15257
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_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0842
_refine_ls_R_factor_gt           0.047
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0203P)^2^+16.3893P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0763
_refine_ls_wR_factor_ref         0.0865
_reflns_number_gt                10974
_reflns_number_total             15257
_reflns_threshold_expression     >2sigma(I)
_cod_duplicate_entry             7031970
_cod_data_source_file            c4dt01714e2.cif
_cod_data_source_block           (4)-aug111
_cod_original_cell_volume        7214.8(12)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7032365