Pushing the limits of electron donation for <i>cis</i>-chelating ligands <i>via</i> an alliance of phosphonium ylide and anionic abnormal NHC.
El Kadiri, Mustapha; Cherradi, Abdelhaq; Filippov, Oleg A.; Duhayon, Carine; César, Vincent; Shubina, Elena S.; Lahcini, Mohammed; Valyaev, Dmitry A.; Canac, Yves; Chemical communications (Cambridge, England) 61 (2025) 2778–2781; doi:10.1039/d4cc06177b

data_7134129
_publ_section_title
;
 Pushing the limits of electron donation for <i>cis</i>-chelating ligands
 <i>via</i> an alliance of phosphonium ylide and anionic abnormal NHC.
;
_journal_issue                   13
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              2778
_journal_page_last               2781
_journal_paper_doi               10.1039/d4cc06177b
_journal_volume                  61
_journal_year                    2025
_chemical_formula_moiety         'C50 H45 Mn N2 O4 P Rh, C4 H8 O'
_chemical_formula_sum            'C54 H53 Mn N2 O5 P Rh'
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_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_audit_update_record
;
2024-12-17 deposited with the CCDC.	2025-01-07 downloaded from the CCDC.
;
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'XtaLAB Synergy, Dualflex,HyPix, (Rigaku, 2021)'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0485P)^2^+2.3253P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0843
_refine_ls_wR_factor_ref         0.0852
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_reflns_number_gt                9172
_reflns_number_total             9608
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4cc06177b2.cif
_cod_data_source_block           complex_5a
_cod_depositor_comments
'Adding full bibliography for 7134129--7134130.cif.'
_cod_original_cell_volume        2435.42(5)
_cod_database_code               7134129
_shelx_res_checksum              41902
_shelx_fab_checksum              82223