How to not build a cage: endohedral functionalization of polyoxometalate-based metal-organic polyhedra.
Guo, Ji; Chang, Qing; Liu, Zhiwei; Wang, Yangming; Liu, Chuanhong; Wang, Mou; Huang, Danmeng; Chen, Guanying; Zhao, Hongmei; Wang, Wei; Fang, Xikui; Chemical science 12 (2021) 7361–7368; doi:10.1039/d1sc01243f

data_1561475
_publ_section_title
;
 How to not build a cage: endohedral functionalization of
 polyoxometalate-based metal-organic polyhedra.
;
_journal_issue                   21
_journal_name_full               'Chemical science'
_journal_page_first              7361
_journal_page_last               7368
_journal_paper_doi               10.1039/d1sc01243f
_journal_volume                  12
_journal_year                    2021
_chemical_formula_sum            'C309 H610 Cl N23 O245 P8 V56'
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_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-01-07 deposited with the CCDC.	2021-04-03 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_cell_length_c                   29.242(5)
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_cell_measurement_theta_min      2.23
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_computing_cell_refinement       'Bruker APEX3'
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_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.989
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_diffrn_measurement_device_type  'Bruker PHOTON II detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.989
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_diffrn_reflns_point_group_measured_fraction_full 0.989
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_exptl_crystal_colour            green
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1450P)^2^+720.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             20281
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1sc01243f3.cif
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_cod_depositor_comments
'Adding full bibliography for 1561473--1561476.cif.'
_cod_original_cell_volume        27292(9)
_cod_original_sg_symbol_H-M      'C 2/m'
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