Coordination of a monomeric diphosphido platinum complex as a bridging ligand
Berenguer, Jesús R.; Chaouche, Naima; Forniés, Juan; Fortuño, Consuelo; Martín, Antonio; New Journal of Chemistry 30 (2006) 473–; doi:10.1039/b517726j

data_7051554
_publ_section_title
;
 Coordination of a monomeric diphosphido platinum complex as a bridging
 ligand
;
_journal_issue                   3
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              473
_journal_paper_doi               10.1039/b517726j
_journal_volume                  30
_journal_year                    2006
_chemical_formula_sum            'C72 H50 Ag2 F10 P4 Pt'
_chemical_formula_weight         1639.83
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.2240(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.68200(10)
_cell_length_b                   23.9780(3)
_cell_length_c                   21.7910(3)
_cell_measurement_reflns_used    118964
_cell_measurement_temperature    223(2)
_cell_volume                     6499.66(13)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Nonius BV, 1997-2000)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      223.0(10)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device       '95mm CCD camera on \k-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       CCD
_diffrn_orient_matrix_type       'by Nonius Collect from scalepack cell'
_diffrn_orient_matrix_UB_11      -0.0524863
_diffrn_orient_matrix_UB_12      -0.0215094
_diffrn_orient_matrix_UB_13      -0.0314015
_diffrn_orient_matrix_UB_21      -0.038574
_diffrn_orient_matrix_UB_22      0.0353777
_diffrn_orient_matrix_UB_23      -0.0146458
_diffrn_orient_matrix_UB_31      0.0471113
_diffrn_orient_matrix_UB_32      0.0050033
_diffrn_orient_matrix_UB_33      -0.0314377
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0727
_diffrn_reflns_av_unetI/netI     0.0608
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            72340
_diffrn_reflns_theta_full        27.88
_diffrn_reflns_theta_max         27.88
_diffrn_reflns_theta_min         2.98
_exptl_absorpt_coefficient_mu    2.913
_exptl_absorpt_correction_T_max  0.6691
_exptl_absorpt_correction_T_min  0.3887
_exptl_crystal_colour            pale-yellow
_exptl_crystal_density_diffrn    1.676
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3216
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.703
_refine_diff_density_min         -1.831
_refine_diff_density_rms         0.357
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     802
_refine_ls_number_reflns         11407
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0519
_refine_ls_R_factor_gt           0.0316
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0850P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0874
_refine_ls_wR_factor_ref         0.1236
_reflns_number_gt                11059
_reflns_number_total             15283
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b517726j.txt
_cod_data_source_block           2
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7051554