<i>catena</i>-Poly[[bis(μ~2~-4-aminobenzenesulfonato-κ^2^<i>O</i>:<i>O</i>)disilver]-bis(μ~2~-4,4'-bipyridine-κ^2^<i>N</i>:<i>N</i>')]
Ou, Guang-Chuan; Zhang, Min; Yuan, Xian-You; Dai, Yong-Qiang; Acta Crystallographica Section E 64 (2008) m1587–; doi:10.1107/S160053680803804X

data_2220309
_publ_section_title
<i>catena</i>-Poly[[bis(\m~2~-4-aminobenzenesulfonato-\k^2^<i>O</i>:<i>O</i>)disilver]-bis(\m~2~-4,4'-bipyridine-\k^2^<i>N</i>:<i>N</i>')]
_journal_coeditor_code           PV2110
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1587
_journal_paper_doi               10.1107/S160053680803804X
_journal_volume                  64
_journal_year                    2008
_chemical_formula_iupac          '[Ag2 (C6 H6 N O3 S)2 (C10 H8 N2 )2]'
_chemical_formula_moiety         'C32 H28 Ag2 N6 O6 S2'
_chemical_formula_sum            'C32 H28 Ag2 N6 O6 S2'
_chemical_formula_weight         872.46
_chemical_name_systematic
;
catena-Poly[[bis(\m~2~-4-aminobenzenesulfonato-\k^2^O:O)disilver]-
bis(\m~2~-4,4'-bipyridine-\k^2^N:N')]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.004(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   9.2105(19)
_cell_length_b                   15.774(3)
_cell_length_c                   11.433(2)
_cell_measurement_reflns_used    2489
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      26.98
_cell_measurement_theta_min      2.49
_cell_volume                     1579.7(5)
_computing_cell_refinement       'SMART (Bruker, 1997)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        'SAINT (Bruker, 2003)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2005)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0234
_diffrn_reflns_av_sigmaI/netI    0.0320
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            7741
_diffrn_reflns_theta_full        27.01
_diffrn_reflns_theta_max         27.01
_diffrn_reflns_theta_min         2.27
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.428
_exptl_absorpt_correction_T_max  0.8473
_exptl_absorpt_correction_T_min  0.5853
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            light-yellow
_exptl_crystal_density_diffrn    1.834
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             872
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.791
_refine_diff_density_min         -0.691
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.114
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     217
_refine_ls_number_reflns         3375
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.114
_refine_ls_R_factor_all          0.0422
_refine_ls_R_factor_gt           0.0319
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0458P)^2^+0.7557P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0822
_refine_ls_wR_factor_ref         0.0875
_reflns_number_gt                2774
_reflns_number_total             3375
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            pv2110.cif
_cod_data_source_block           I
_cod_original_cell_volume        1579.8(6)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2220309
_cod_database_fobs_code          2220309