Brønsted acid-catalysed conjugate addition of photochemically generated α-amino radicals to alkenylpyridines.
Hepburn, Hamish B.; Melchiorre, Paolo; Chemical communications (Cambridge, England) 52 (2016) 3520–3523; doi:10.1039/c5cc10401g

data_7118676
_publ_section_title
;
 Br\/onsted acid-catalysed conjugate addition of photochemically generated
 \a-amino radicals to alkenylpyridines.
;
_journal_issue                   17
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              3520
_journal_page_last               3523
_journal_paper_doi               10.1039/c5cc10401g
_journal_volume                  52
_journal_year                    2016
_chemical_formula_sum            'C24 H26 N2'
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_audit_update_record
;
2016-01-27 deposited with the CCDC.
2016-01-29 downloaded from the CCDC.
;
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;
 Fullsphere data collection, phi and omega scans
;
_diffrn_measurement_specimen_support 'magnetic support with MicroMount'
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; 
 SADABS Version 2008/1 Bruker-Nonius
 Blessing, Acta Cryst. (1995) A51 33-38
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0485P)^2^+1.9831P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             4645
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5cc10401g2.cif
_cod_data_source_block           mo_HBH296_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7118676.cif.
;
_cod_original_sg_symbol_H-M      Pbcn
_cod_database_code               7118676
_shelx_estimated_absorpt_t_min   0.986
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