Synthesis and Reactivity of a Ruthenium(III) Bis(anilide) Dimer by Oxidative Addition of an N,N‘-Disubstituted Hydrazine
Hoover, Jessica M.; DiPasquale, Antonio; Mayer, James M.; Michael, Forrest E.; Organometallics 26 (2007) 3297–; doi:10.1021/om0700462

data_4073065
_publ_section_title
;
 Synthesis and Reactivity of a Ruthenium(III) Bis(anilide) Dimer by
 Oxidative Addition of an N,N&#x2018;-Disubstituted Hydrazine
;
_journal_issue                   14
_journal_name_full               Organometallics
_journal_page_first              3297
_journal_paper_doi               10.1021/om0700462
_journal_volume                  26
_journal_year                    2007
_chemical_formula_moiety         'C32 H42 Cl2 N2 Ru2'
_chemical_formula_sum            'C32 H42 Cl2 N2 Ru2'
_chemical_formula_weight         727.72
_chemical_name_common            JMHI061
_chemical_name_systematic
;
 JMHI061
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                63.061(5)
_cell_angle_beta                 82.784(5)
_cell_angle_gamma                68.665(5)
_cell_formula_units_Z            1
_cell_length_a                   9.361(5)
_cell_length_b                   9.382(5)
_cell_length_c                   10.278(5)
_cell_measurement_reflns_used    852
_cell_measurement_temperature    130(2)
_cell_volume                     748.7(7)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       KappaCCD
_computing_data_reduction        'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'maXus, Zortep'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SIR-2004
_diffrn_ambient_temperature      130(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.948
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0778
_diffrn_reflns_av_sigmaI/netI    0.1207
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            5747
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         28.32
_diffrn_reflns_theta_min         3.15
_exptl_absorpt_coefficient_mu    1.211
_exptl_absorpt_correction_T_max  0.9200
_exptl_absorpt_correction_T_min  0.7598
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   HKL-2000
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.614
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             370
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.292
_refine_diff_density_min         -1.150
_refine_diff_density_rms         0.161
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     180
_refine_ls_number_reflns         3554
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0840
_refine_ls_R_factor_gt           0.0537
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0462P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1086
_refine_ls_wR_factor_ref         0.1186
_reflns_number_gt                2557
_reflns_number_total             3554
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om0700462-file003.cif
_cod_data_source_block           import
_cod_database_code               4073065