Dichlorido[6,8,22,24,34,36-hexamethyl-33,35-diaza-3,11,19,27-tetraazoniapentacyclo[27.3.1.1^5,9^.1^13,17^.1^21,25^]hexatriaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodecaene-κ^6^<i>N</i>^3^,<i>N</i>^11^,<i>N</i>^19^,<i>N</i>^27^,<i>N</i>^33^,<i>N</i>^35^]dipalladium(II) bis(perchlorate) <i>N</i>,<i>N</i>-dimethylformamide disolvate methanol disolvate
Oda, Kohei; Funahashi, Yasuhiro; Masuda, Hideki; Acta Crystallographica Section E 69 (2013) m520–m521; doi:10.1107/S1600536813022666

data_2238510
_publ_section_title
;
 Dichlorido[6,8,22,24,34,36-hexamethyl-33,35-diaza-3,11,19,27-tetraazoniapentacyclo[27.3.1.1^5,9^.1^13,17^.1^21,25^]hexatriaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodecaene-\k^6^<i>N</i>^3^,<i>N</i>^11^,<i>N</i>^19^,<i>N</i>^27^,<i>N</i>^33^,<i>N</i>^35^]dipalladium(II)
 bis(perchlorate) <i>N</i>,<i>N</i>-dimethylformamide disolvate methanol
 disolvate
;
_journal_coeditor_code           IS5294
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m520
_journal_page_last               m521
_journal_paper_doi               10.1107/S1600536813022666
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac
'[Pd2 (C36 H42 N6) Cl2] (Cl O4)2 , 2C3 H7 N O , 2C H4 O'
_chemical_formula_moiety
'C36 H46 Cl2 N6 Pd2, 2(Cl O4), 2(C3 H7 N O), 2(C H4 O)'
_chemical_formula_sum            'C44 H68 Cl4 N8 O12 Pd2'
_chemical_formula_weight         1255.68
_chemical_name_systematic
;Dichlorido[6,8,22,24,34,36-hexamethyl-33,35-diaza-3,11,19,27-tetraazoniapentacyclo[27.3.1.1^5,9^.1^13,17^.1^21,25^]hexatriaconta-1(33),5,7,9(34),13,15,17(35),21,23,25(36),29,31-dodecaene-\k^6^<i>N</i>^3^,<i>N</i>^11^,<i>N</i>^19^,<i>N</i>^27^,<i>N</i>^33^,<i>N</i>^35^]dipalladium(II) bis(perchlorate) <i>N</i>,<i>N</i>-dimethylformamide
disolvate methanol disolvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.0000
_cell_angle_beta                 104.201(2)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            2
_cell_length_a                   10.917(2)
_cell_length_b                   19.083(4)
_cell_length_c                   12.705(3)
_cell_measurement_reflns_used    6824
_cell_measurement_temperature    173
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.02
_cell_volume                     2565.9(9)
_computing_cell_refinement       'CrystalClear (Rigaku, 2001)'
_computing_data_collection       'CrystalClear (Rigaku, 2001)'
_computing_data_reduction        'CrystalClear (Rigaku, 2001)'
_computing_molecular_graphics    'CrystalStructure (Rigaku, 2001)'
_computing_publication_material  'CrystalStructure (Rigaku, 2001)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Altomare <i>et al.</i>, 1993)'
_diffrn_ambient_temperature      173
_diffrn_detector_area_resol_mean 7.314
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku Mercury70'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0285
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            19797
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.977
_exptl_absorpt_correction_T_max  0.823
_exptl_absorpt_correction_T_min  0.751
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   '(NUMABS; Rigaku, 1999)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.625
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1288.00
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.800
_refine_diff_density_min         -0.810
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.080
_refine_ls_hydrogen_treatment    mixed
_refine_ls_number_parameters     324
_refine_ls_number_reflns         5826
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           0.0375
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0439P)^2^+3.4810P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0965
_reflns_number_gt                4980
_reflns_number_total             5826
_reflns_threshold_expression     F^2^>2\s(F^2^)
_cod_data_source_file            is5294.cif
_cod_data_source_block           I
_cod_original_cell_volume        2566.0(8)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2238510
_cod_database_fobs_code          2238510