Water-stable fluorinated metal‒organic frameworks (F-MOFs) with hydrophobic properties as efficient and highly active heterogeneous catalysts in aqueous solution
Joharian, Monika; Morsali, Ali; Azhdari Tehrani, Alireza; Carlucci, Lucia; Proserpio, Davide M.; Green Chemistry 20 (2018) 5336–; doi:10.1039/C8GC02367K

data_7231667
_publ_section_title
;
 Water-stable fluorinated metal--organic frameworks (F-MOFs) with
 hydrophobic properties as efficient and highly active heterogeneous
 catalysts in aqueous solution
;
_journal_issue                   23
_journal_name_full               'Green Chemistry'
_journal_page_first              5336
_journal_paper_doi               10.1039/C8GC02367K
_journal_volume                  20
_journal_year                    2018
_chemical_formula_sum            'C51 H37 F12 N5 O9 Zn2'
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_space_group_name_Hall           '-C 2yc'
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_symmetry_space_group_name_Hall  '-C 2yc'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2018-06-28 deposited with the CCDC.
2018-10-16 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_exptl_crystal_colour            'pale yellow'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0687P)^2^+7.9436P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1279
_refine_ls_wR_factor_ref         0.1470
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5089
_reflns_number_total             8088
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8gc02367k2.cif
_cod_data_source_block           TMU-47
_cod_depositor_comments          'Adding full bibliography for 7231667.cif.'
_cod_database_code               7231667
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