Stereoselective synthesis of 6/7/6-fused heterocycles with multiple stereocenters <i>via</i> an internal redox reaction/inverse electron-demand hetero-Diels-Alder reaction sequence.
Sakai, Dan; Kojima, Tatsuhiro; Kawasaki-Takasuka, Tomoko; Mori, Keiji; Chemical communications (Cambridge, England) 60 (2024) 6797–6800; doi:10.1039/d4cc02351j

data_7133151
_publ_section_title
;
 Stereoselective synthesis of 6/7/6-fused heterocycles with multiple
 stereocenters <i>via</i> an internal redox reaction/inverse
 electron-demand hetero-Diels-Alder reaction sequence.
;
_journal_issue                   53
_journal_name_full               'Chemical communications (Cambridge, England)'
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_journal_paper_doi               10.1039/d4cc02351j
_journal_volume                  60
_journal_year                    2024
_chemical_formula_sum            'C29 H32 Cl2 N2 O4'
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;
2024-04-25 deposited with the CCDC.	2024-06-04 downloaded from the CCDC.
;
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;
CrysAlisPro 1.171.40.75a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0830P)^2^+0.5854P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7133150--7133151.cif.'
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_shelx_estimated_absorpt_t_min   0.971
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_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_shelx_res_checksum              13315
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