Migratory Transmetalation in Diphenoxo-Bridged CuIIMII Complexes of a Dinucleating Macrocycle with N(amine)2O2 and N(imine)2O2 Metal-Binding Sites
Masami Yonemura; Yukiko Matsumura; Hideki Furutachi; Masaaki Ohba; Hisashi Ōkawa; David E. Fenton; Inorganic Chemistry 36 (1997) 2711–2717; doi:10.1021/ic9614430

data_4323474
_publ_section_title
;
 Migratory Transmetalation in Diphenoxo-Bridged CuIIMII Complexes of a
 Dinucleating Macrocycle with N(amine)2O2 and N(imine)2O2 Metal-Binding
 Sites
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2711
_journal_page_last               2717
_journal_paper_doi               10.1021/ic9614430
_journal_volume                  36
_journal_year                    1997
_chemical_formula_sum            'C25 H29 Br2 Cl Cu N4 O8 Zn'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Wed Mar 12 21:12:20 1997'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                95.10(2)
_cell_angle_beta                 116.68(2)
_cell_angle_gamma                112.00(2)
_cell_formula_units_Z            2.00
_cell_length_a                   12.290(3)
_cell_length_b                   13.402(4)
_cell_length_c                   11.501(2)
_cell_measurement_reflns_used    23
_cell_measurement_temperature    20.0
_cell_measurement_theta_max      23.63
_cell_measurement_theta_min      20.15
_cell_volume                     1491.9(8)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_diffrn_ambient_temperature      20.0
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
_diffrn_orient_matrix_UB_11      -0.00142
_diffrn_orient_matrix_UB_12      0.07101
_diffrn_orient_matrix_UB_13      0.03241
_diffrn_orient_matrix_UB_21      0.08956
_diffrn_orient_matrix_UB_22      0.02426
_diffrn_orient_matrix_UB_23      0.08670
_diffrn_orient_matrix_UB_31      0.05067
_diffrn_orient_matrix_UB_32      0.03920
_diffrn_orient_matrix_UB_33      -0.04374
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  7.40
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_diffrn_standards_decay_%        -0.59
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu_cm 43.468
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.696
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.865
_exptl_crystal_description       prismatic
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_refine_ls_extinction_method     Zachariasen_type_2_Gaussian_isotropic
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_refine_ls_shift/esd_max         0.1090
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0340
_cod_data_source_file            ic9614430_2.cif
_cod_data_source_block           '[CuZn(L)(AcO)](ClO4)'
_cod_original_cell_volume        1491.8(9)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_database_code               4323474