Enantioselective Synthesis of α-Silylamines by Meerwein-Ponndorf-Verley-Type Reduction of α-Silylimines by a Chiral Lithium Amide.
Kondo, Yasuhiro; Sasaki, Michiko; Kawahata, Masatoshi; Yamaguchi, Kentaro; Takeda, Kei; The Journal of organic chemistry 79 (2014) 3601–3609; doi:10.1021/jo500441a

data_4029295
_publ_section_title
;
 Enantioselective Synthesis of \a-Silylamines by
 Meerwein-Ponndorf-Verley-Type Reduction of \a-Silylimines by a Chiral
 Lithium Amide.
;
_journal_issue                   8
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;
 Classical Flack method preferred over Parsons because s.u. lower.
;
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;
 w=1/[\s^2^(Fo^2^)+(0.0956P)^2^+0.1394P]
 where P=(Fo^2^+2Fc^2^)/3
;
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;Adding full bibliography for
 ./tmp-cod-update-bibliographies-12971/cifs/4029295.cif.
;
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