Mono- and Dinuclear Germapalladacycles Obtained via the Ge−Ge Bond Forming Reactions Promoted by Palladium Complexes
Tanabe, Makoto; Ishikawa, Naoko; Hanzawa, Masaya; Osakada, Kohtaro; Organometallics 27 (2008) 5152–; doi:10.1021/om8004349

data_4071864
_publ_section_title
;
 Mono- and Dinuclear Germapalladacycles Obtained via the Ge&#x2212;Ge Bond
 Forming Reactions Promoted by Palladium Complexes
;
_journal_issue                   19
_journal_name_full               Organometallics
_journal_page_first              5152
_journal_paper_doi               10.1021/om8004349
_journal_volume                  27
_journal_year                    2008
_chemical_formula_moiety         'C48 H62 Ge3 P4 Pd2 '
_chemical_formula_sum            'C48 H62 Ge3 P4 Pd2'
_chemical_formula_weight         1193.48
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 93.8134(16)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   16.2875(18)
_cell_length_b                   16.1779(18)
_cell_length_c                   18.868(2)
_cell_measurement_reflns_used    15337
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     4960.7(9)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SHELXS97
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.970
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.037
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            35463
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    2.668
_exptl_absorpt_correction_T_max  0.000
_exptl_absorpt_correction_T_min  0.000
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.598
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2392.00
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.07
_refine_diff_density_min         -0.74
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     576
_refine_ls_number_reflns         8732
_refine_ls_R_factor_gt           0.0287
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w = 1/[0.6000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0559
_reflns_number_gt                8685
_reflns_number_total             11042
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om8004349_si_001.cif
_cod_data_source_block           '__complex3'
_cod_original_cell_volume        4960.6(9)
_cod_original_formula_sum        'C48 H62 Ge3 P4 Pd2 '
_cod_database_code               4071864