Palladium nanoparticles immobilized on a nano-silica triazine dendritic polymer: a recyclable and sustainable nanoreactor for C–S cross-coupling
Landarani-Isfahani, Amir; Mohammadpoor-Baltork, Iraj; Mirkhani, Valiollah; Moghadam, Majid; Tangestaninejad, Shahram; Amiri Rudbari, Hadi; RSC Advances 10 (2020) 21198–21205; doi:10.1039/D0RA00719F

data_7240627
_publ_section_title
;
 Palladium nanoparticles immobilized on a nano-silica triazine dendritic
 polymer: a recyclable and sustainable nanoreactor for C--S cross-coupling
;
_journal_issue                   36
_journal_name_full               'RSC Advances'
_journal_page_first              21198
_journal_page_last               21205
_journal_paper_doi               10.1039/D0RA00719F
_journal_volume                  10
_journal_year                    2020
_chemical_formula_sum            'C19 H17 N S2'
_chemical_formula_weight         323.45
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2020-05-02 deposited with the CCDC.	2020-05-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 105.87(3)
_cell_angle_gamma                90
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_cell_length_b                   8.8654(18)
_cell_length_c                   15.322(3)
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_computing_data_collection       'X-AREA (Stoe & Cie, 2005)'
_computing_data_reduction        'X-AREA (Stoe & Cie, 2005)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_device_type  'Stoe IPDS-II'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.1340
_diffrn_reflns_av_unetI/netI     0.1364
_diffrn_reflns_Laue_measured_fraction_full 0.965
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_diffrn_reflns_theta_max         24.999
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_exptl_absorpt_coefficient_mu    0.313
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
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_exptl_crystal_description       irregular
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0147P)^2^+5.5482P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1411
_refine_ls_wR_factor_ref         0.1602
_reflns_Friedel_coverage         0.000
_reflns_number_gt                825
_reflns_number_total             1435
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0ra00719f2.cif
_cod_data_source_block           shelx
_cod_depositor_comments          'Adding full bibliography for 7240627.cif.'
_cod_original_cell_volume        1677.2(6)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7240627
_shelx_shelxl_version_number     2016/6
_shelx_res_checksum              86452