Structural, Photophysical, and Mesomorphic Properties of Luminescent Platinum(II)-Salen Schiff Base Complexes
Yuriko Abe; Yuko Takagi; Miyuki Nakamura; Tomoaki Tanase; Miho Yokokawa; Hidetomo Mukai; Kazuchika Ohta; Inorganica Chimica Acta 392 (2012) 254–260; doi:10.1016/j.ica.2012.02.041

data_1512608
_publ_section_title
;
 Structural, Photophysical, and Mesomorphic Properties of Luminescent
 Platinum(II)-Salen Schiff Base Complexes
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              254
_journal_page_last               260
_journal_paper_doi               10.1016/j.ica.2012.02.041
_journal_volume                  392
_journal_year                    2012
_chemical_formula_moiety         'C24 H30 N2 O4 Pt'
_chemical_formula_sum            'C24 H30 N2 O4 Pt'
_chemical_formula_weight         605.60
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 94.771(4)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   12.107(5)
_cell_length_b                   7.056(3)
_cell_length_c                   26.797(12)
_cell_measurement_reflns_used    4804
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.3
_cell_volume                     2281.3(17)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.063
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            19220
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    6.159
_exptl_absorpt_correction_T_max  0.397
_exptl_absorpt_correction_T_min  0.191
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.763
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1192.00
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.35
_refine_diff_density_min         -1.06
_refine_ls_extinction_coef       0.0024(11)
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.110
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     309
_refine_ls_number_reflns         5074
_refine_ls_R_factor_gt           0.0731
_refine_ls_shift/su_max          0.0020
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.1225P)^2^+7.2422P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2286
_reflns_number_gt                3470
_reflns_number_total             5074
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ICA-2012-392-254-260.cif
_cod_data_source_block           General
_cod_original_cell_volume        2281.1(17)
_cod_database_code               1512608