Synthesis and Reactivity of Bis(alkoxyalkylidene)platinum(II) Complexes§
Werner, Michael; Lis, Tadeusz; Bruhn, Clemens; Lindner, Ronald; Steinborn, Dirk; Organometallics 25 (2006) 5946–; doi:10.1021/om060725x

data_4074517
_publ_section_title
;
 Synthesis and Reactivity of Bis(alkoxyalkylidene)platinum(II)
 Complexes&#x00A7;
;
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              5946
_journal_paper_doi               10.1021/om060725x
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C8 H16 Cl2 O2 Pt'
_chemical_formula_sum            'C8 H16 Cl2 O2 Pt'
_chemical_formula_weight         410.20
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.64(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.810(4)
_cell_length_b                   7.3312(15)
_cell_length_c                   10.694(3)
_cell_measurement_reflns_used    8000
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      24.99
_cell_measurement_theta_min      2.61
_cell_volume                     1225.4(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      223(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0648
_diffrn_reflns_av_sigmaI/netI    0.0435
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            3737
_diffrn_reflns_theta_full        24.99
_diffrn_reflns_theta_max         24.99
_diffrn_reflns_theta_min         2.61
_exptl_absorpt_coefficient_mu    11.857
_exptl_absorpt_correction_T_max  0.3922
_exptl_absorpt_correction_T_min  0.1345
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   'X-red (Stoe, 2004)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.223
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             768
_exptl_crystal_size_max          0.395
_exptl_crystal_size_mid          0.107
_exptl_crystal_size_min          0.096
_refine_diff_density_max         1.615
_refine_diff_density_min         -2.401
_refine_diff_density_rms         0.238
_refine_ls_extinction_coef       0.00271(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.354
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     58
_refine_ls_number_reflns         1075
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.354
_refine_ls_R_factor_all          0.0306
_refine_ls_R_factor_gt           0.0287
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0288P)^2^+19.3921P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0889
_refine_ls_wR_factor_ref         0.0937
_reflns_number_gt                1037
_reflns_number_total             1075
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om060725xrom20060724_024953.cif
_cod_data_source_block           ipds2349
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4074517