SF5-Enolates in Ti(IV)-Mediated Aldol Reactions.
Ponomarenko, Maksym V.; Grabowsky, Simon; Pal, Rumpa; Röschenthaler, Gerd-Volker; Fokin, Andrey A.; The Journal of organic chemistry 81 (2016) 6783–6791; doi:10.1021/acs.joc.6b00946

data_4032035
_publ_contact_author
;
Dr. Simon Grabowsky
Emmy Noether Research Group Leader
Universit&#x00E4;t Bremen
Fachbereich 2 - Biologie/Chemie
Leobener Str. NW2
28359 Bremen
Germany
E-Mail: simon.grabowsky@uni-bremen.de

;
_publ_section_title
;
 SF5-Enolates in Ti(IV)-Mediated Aldol Reactions.
;
_journal_issue                   15
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              6783
_journal_page_last               6791
_journal_paper_doi               10.1021/acs.joc.6b00946
_journal_volume                  81
_journal_year                    2016
_chemical_compound_source        'see text'
_chemical_formula_moiety         'C10 H10 F5 N O5 S'
_chemical_formula_sum            'C10 H10 F5 N O5 S'
_chemical_formula_weight         351.25
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_cell_volume                     1294.9(4)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_exptl_crystal_colour            colorless
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_exptl_crystal_description       block
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_refine_ls_number_reflns         3944
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_refine_ls_R_factor_all          0.0416
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0551P)^2^+0.6190P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 4032034--4032036.cif.'
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_cod_database_code               4032035