Heterobimetallic aluminate derivatives with bulky phenoxide ligands: a catalyst for selective vinyl polymerization.
Palenzuela, Miguel; Muñoz, Mª Teresa; Vega, Juan F.; Gutiérrez-Rodríguez, Ángel; Cuenca, Tomás; Mosquera, Marta E. G.; Dalton transactions (Cambridge, England : 2003) 48 (2019) 6435–6444; doi:10.1039/c9dt00761j

data_7049638
_publ_section_title
;
 Heterobimetallic aluminate derivatives with bulky phenoxide ligands: a
 catalyst for selective vinyl polymerization.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6435
_journal_page_last               6444
_journal_paper_doi               10.1039/c9dt00761j
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C78  H84  Al2  Li2  O2.2C7 H8'
_chemical_formula_sum            'C92 H100 Al2 Li2 O2'
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_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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;
2019-03-24 deposited with the CCDC.    2019-04-09 downloaded from the CCDC.
;
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'Dirax/lsq (Duisenberg & Schreurs, 1989-2000)'
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;
 R.H. Blessing, Acta Cryst. (1995), A51, 33-38
;
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_platon_squeeze_details
;                           
Two molecules of toluene crystallized with every molecule of this 
 compound but presented severe disorder and it was not possible to get a 
 chemical sensible model for them, so Squeeze procedure was used to remove 
 their contribution to the structure factors.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1161P)^2^+5.8792P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2540
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_reflns_number_gt                5688
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_cod_depositor_comments
'Adding full bibliography for 7049638--7049641.cif.'
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_cod_database_code               7049638
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