Effect of pyridyl substituents leading to the formation of green luminescent mercury(ii) coordination polymers, zinc(ii) dimers and a monomer
Singh, Vikram; Kumar, Vinod; Gupta, Ajit N.; Drew, Michael G. B.; Singh, Nanhai; New Journal of Chemistry 38 (2014) 3737–; doi:10.1039/C4NJ00435C

data_7054228
_publ_section_title
;
 Effect of pyridyl substituents leading to the formation of green
 luminescent mercury(ii) coordination polymers, zinc(ii) dimers and a
 monomer
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              3737
_journal_paper_doi               10.1039/C4NJ00435C
_journal_volume                  38
_journal_year                    2014
_chemical_formula_sum            'C28 H30 N4 S4 Zn'
_chemical_formula_weight         616.17
_chemical_name_systematic
;
 ?
;
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_cell_angle_beta                 81.671(17)
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_cell_formula_units_Z            2
_cell_length_a                   10.751(2)
_cell_length_b                   7.834(3)
_cell_length_c                   18.396(3)
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_cell_measurement_theta_max      27.50
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_computing_molecular_graphics    PLATON(Spek,2004)
_computing_publication_material  'SHELXL-97, PLATON'
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_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device       'Oxford Diffaction X-Calibur System'
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_diffrn_measurement_method       '321 frames, counting time 10 s.'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_limit_l_min       -21
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_diffrn_reflns_theta_max         25.00
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_exptl_crystal_colour            white
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
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_exptl_crystal_size_max          0.28
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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;
_refine_ls_weighting_details
  w=1/[\s^2^(Fo^2^)+(0.0998P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3
;
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_refine_ls_wR_factor_gt          0.2214
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_reflns_number_gt                2948
_reflns_number_total             4894
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_cod_depositor_comments
'Adding full bibliography for 7054219--7054228.cif.'
_cod_original_cell_volume        1410.6(6)
_cod_original_sg_symbol_H-M      P-1
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