Nickel(II) hydride and fluoride pincer complexes and their reactivity with Lewis acids BX3·L (X = H, L = thf; X = F, L = Et2O).
Rossin, Andrea; Peruzzini, Maurizio; Zanobini, Fabrizio; Dalton transactions (Cambridge, England : 2003) 40 (2011) 4447–4452; doi:10.1039/c0dt01836h

data_7015691
_publ_section_title
;
 Nickel(II) hydride and fluoride pincer complexes and their reactivity
 with Lewis acids BX3&#x00B7;L (X = H, L = thf; X = F, L = Et2O).
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4447
_journal_page_last               4452
_journal_paper_doi               10.1039/c0dt01836h
_journal_volume                  40
_journal_year                    2011
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C24 H45 B1 F4 Ni1 O1 P2'
_chemical_formula_sum            'C24 H45 B F4 Ni O P2'
_chemical_formula_weight         557.06
_chemical_name_systematic
;
?
;
_space_group_IT_number           61
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_symmetry_space_group_name_Hall  '-P 2ac 2ab'
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_atom_sites_solution_hydrogens   geom
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_computing_cell_refinement
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
(compiled May 6 2009,17:20:42)
;
_computing_data_collection
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
(compiled May 6 2009,17:20:42)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
(compiled May 6 2009,17:20:42)
;
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
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_diffrn_detector_area_resol_mean 16.4547
_diffrn_measured_fraction_theta_full 0.958
_diffrn_measured_fraction_theta_max 0.741
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_measurement_method       '\w scans'
_diffrn_orient_matrix_UB_11      -0.0009695637
_diffrn_orient_matrix_UB_12      0.0399121133
_diffrn_orient_matrix_UB_13      0.0078456036
_diffrn_orient_matrix_UB_21      -0.0059171994
_diffrn_orient_matrix_UB_22      0.0093163081
_diffrn_orient_matrix_UB_23      -0.0326362582
_diffrn_orient_matrix_UB_31      -0.0443800515
_diffrn_orient_matrix_UB_32      -0.002084203
_diffrn_orient_matrix_UB_33      0.0041840803
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
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_exptl_absorpt_coefficient_mu    0.829
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.89239
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
(compiled May 6 2009,17:20:42)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'golden yellow'
_exptl_crystal_density_diffrn    1.291
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2368
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.261
_refine_diff_density_min         -0.222
_refine_diff_density_rms         0.049
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.755
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     304
_refine_ls_number_reflns         2958
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.755
_refine_ls_R_factor_all          0.0806
_refine_ls_R_factor_gt           0.0326
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0141P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0465
_refine_ls_wR_factor_ref         0.0525
_reflns_number_gt                1691
_reflns_number_total             2958
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt01836h.txt
_cod_data_source_block           PCPNiaq
_cod_original_cell_volume        5734(3)
_cod_database_code               7015691