Synthesis, Structure, and Reactivity of Ruthenium and Osmium Nitrido Complexes with 1,2-Benzenedithiolate Ligands: N- versus S-Alkylation
Dieter Sellmann; Michael W. Wemple; Wolfgang Donaubauer; Frank W. Heinemann; Inorganic Chemistry 36 (1997) 1397–1402; doi:10.1021/ic961240b

data_4323364
_publ_contact_author
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        Dr. F. W. Heinemann                                                     
        Institut f\"ur Anorganische Chemie II                                   
        Universit\"at Erlangen-N\"urnberg                                       
        Egerlandstr. 1                                                          
        D-91058 Erlangen                                                        
        Bundesrepublik Deutschland                                              
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_publ_contact_author_email       HEINEMAN@ANORGANIK.CHEMIE.UNI-ERLANGEN.DE
_publ_contact_author_fax         '049 9131 85-7367'
_publ_contact_author_phone       '049 9131 85-7383'
_publ_section_title
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 Synthesis, Structure, and Reactivity of Ruthenium and Osmium Nitrido
 Complexes with 1,2-Benzenedithiolate Ligands: N- versus S-Alkylation
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_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1397
_journal_page_last               1402
_journal_paper_doi               10.1021/ic961240b
_journal_volume                  36
_journal_year                    1997
_chemical_formula_sum            'C31 H23 N Os S4'
_chemical_formula_weight         727.94
_chemical_name_systematic
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 ? 
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'XDISK (Siemens Analytical X-Ray Instr., 1989)'
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'XP 5.03 (Siemens Analytical X-Ray Instr., 1994)'
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_diffrn_ambient_temperature      200(2)
_diffrn_measurement_device       'Siemens P4'
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_refine_ls_shift/esd_mean        0.007
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0671P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0897
_refine_ls_wR_factor_obs         0.0892
_reflns_number_observed          3020
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_cod_data_source_file            ic961240b_1.cif
_cod_data_source_block           mw56
_cod_depositor_comments
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The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0671P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0671P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        1351.9(13)
_cod_database_code               4323364