Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates.
Plajer, Alex J.; Kopf, Sara; Colebatch, Annie L.; Bond, Andrew D.; Wright, Dominic S.; García-Rodríguez, Raúl; Dalton transactions (Cambridge, England : 2003) 48 (2019) 5692–5697; doi:10.1039/c9dt00869a

data_7049506
_publ_section_title
;
 Deprotonation, insertion and isomerisation in the post-functionalisation
 of tris-pyridyl aluminates.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5692
_journal_page_last               5697
_journal_paper_doi               10.1039/c9dt00869a
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C54 H58 Li2 N6 O2 Al2, 2.7(C7 H8)'
_chemical_formula_sum            'C72.93 H79.63 Al2 Li2 N6 O2'
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_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_audit_update_record
;
2019-02-15 deposited with the CCDC.    2019-03-26 downloaded from the CCDC.
;
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_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      66.82
_cell_measurement_theta_min      3.02
_cell_volume                     1711.41(11)
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_computing_data_collection       'APEX3 (Bruker, 2016)'
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_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
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_diffrn_measurement_device_type  'Bruker D8-QUEST PHOTON-100'
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_diffrn_radiation_type           CuK\a
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_diffrn_source                   'Incoatec I\mS Cu microsource'
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_exptl_crystal_colour            colourless
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_exptl_crystal_description       lath
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1648P)^2^+4.7209P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                4995
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt00869a2.cif
_cod_data_source_block           DW_B2_0295
_cod_depositor_comments
'Adding full bibliography for 7049506--7049509.cif.'
_cod_database_code               7049506
_cambridge_user_name             'Alex Plajer'
_cambridge_user_crsid            ajp233
_cambridge_supervisor_name       'Dominic Wright'
_cambridge_supervisor_crsid      dsw1000
_cambridge_crystallographer_name 'Andrew Bond'
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