Iron hexamesityl-5,15-diazaporphyrin: synthesis, structure and catalytic use for direct oxidation of sp<sup>3</sup> C-H bonds.
Nishimura, Tsubasa; Sakurai, Takahiro; Shinokubo, Hiroshi; Miyake, Yoshihiro; Dalton transactions (Cambridge, England : 2003) 50 (2021) 6343–6348; doi:10.1039/d1dt00893e

data_7707063
_publ_section_title
;
 Iron hexamesityl-5,15-diazaporphyrin: synthesis, structure and catalytic
 use for direct oxidation of sp<sup>3</sup> C-H bonds.
;
_journal_issue                   18
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6343
_journal_page_last               6348
_journal_paper_doi               10.1039/d1dt00893e
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C80 H89 Fe N6 O'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-03-18 deposited with the CCDC.	2021-04-05 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.975
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'dtrek-CrysAlisPro-abstract goniometer imported rigaku-d*trek images'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1291P)^2^+5.4650P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7707061--7707063.cif.'
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