Preparation, Characterization, and Electroluminescence Characteristics of α-Diimine-type Platinum(II) Complexes with Perfluorinated Phenyl Groups as Ligands
Jun-ichi Nishida; Akihiro Maruyama; Takeshi Iwata; Yoshiro Yamashita; Chemistry Letters 34 (2005) 592–; doi:10.1246/cl.2005.592

data_8000043
_publ_section_title
;
 Preparation, Characterization, and Electroluminescence Characteristics
 of \a-Diimine-type Platinum(II) Complexes with Perfluorinated Phenyl
 Groups as Ligands
;
_journal_issue                   4
_journal_name_full               'Chemistry Letters'
_journal_page_first              592
_journal_paper_doi               10.1246/cl.2005.592
_journal_volume                  34
_journal_year                    2005
_chemical_formula_moiety         'C40 H20 F14 N2 Pt '
_chemical_formula_sum            'C40 H20 F14 N2 Pt'
_chemical_formula_weight         989.68
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 114.34(4)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   30.10(1)
_cell_length_b                   15.249(6)
_cell_length_c                   16.600(7)
_cell_measurement_reflns_used    31952
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     6941(5)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9942
_diffrn_measured_fraction_theta_max 0.9942
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.038
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            32039
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_exptl_absorpt_coefficient_mu    4.137
_exptl_absorpt_correction_T_max  0.437
_exptl_absorpt_correction_T_min  0.096
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.894
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_size_max          0.600
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.81
_refine_diff_density_min         -0.73
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.948
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     514
_refine_ls_number_reflns         7908
_refine_ls_R_factor_gt           0.0303
_refine_ls_shift/su_max          0.0194
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0769
_reflns_number_gt                6041
_reflns_number_total             7908
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_original_formula_sum        'C40 H20 F14 N2 Pt '
_cod_database_code               8000043