White luminescence achieved by a multiple thermochromic emission in a hybrid organic-inorganic compound based on 3-picolylamine and copper(i) iodide.
Farinella, F.; Maini, L.; Mazzeo, P. P.; Fattori, V.; Monti, F.; Braga, D.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 17939–17947; doi:10.1039/c6dt03049a

data_7040839
_publ_section_title
;
 White luminescence achieved by a multiple thermochromic emission in a
 hybrid organic-inorganic compound based on 3-picolylamine and copper(i)
 iodide.
;
_journal_issue                   44
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              17939
_journal_page_last               17947
_journal_paper_doi               10.1039/c6dt03049a
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C8 H11 N3 Cu I'
_chemical_formula_sum            'C8 H11 Cu I N3'
_chemical_formula_weight         339.64
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_update_record
;
2016-08-01 deposited with the CCDC.
2016-10-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90.4695(7)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.3471(10)
_cell_length_b                   14.4575(16)
_cell_length_c                   8.0186(9)
_cell_measurement_temperature    298
_cell_volume                     1083.6(2)
_diffrn_ambient_temperature      298
_diffrn_measurement_device_type  'Debye Scherrer'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.775311
_exptl_crystal_colour            white
_exptl_crystal_density_diffrn    2.082
_exptl_crystal_description       powder
_exptl_crystal_preparation       ', Luminescent'
_pd_char_colour                  white
_pd_meas_number_of_points        12779
_pd_proc_2theta_range_inc        0.0036
_pd_proc_2theta_range_max        50.0004
_pd_proc_2theta_range_min        3.9996
_pd_proc_ls_prof_R_factor        0.0365
_pd_proc_ls_prof_wR_expected     0.0041
_pd_proc_ls_prof_wR_factor       0.0475
_pd_spec_mounting                'glass capillary'
_pd_spec_mount_mode              transmission
_refine_ls_goodness_of_fit_all   11.61371
_refine_ls_number_parameters     73
_refine_ls_R_I_factor            0.0247
_refine_ls_shift/su_max          0.0185935273
_reflns_d_resolution_high        0.90912
_reflns_d_resolution_low         7.84926
_reflns_limit_h_max              10
_reflns_limit_h_min              0
_reflns_limit_k_max              15
_reflns_limit_k_min              -15
_reflns_limit_l_max              8
_reflns_limit_l_min              -8
_reflns_number_total             1508
_cod_data_source_file            c6dt03049a2.cif
_cod_data_source_block           YCN_Final_PM3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7040837--7040839.cif.
;
_cod_original_sg_symbol_H-M      P21/n
_cod_original_formula_sum        'C8 H11 N3 Cu I'
_cod_database_code               7040839