Syntheses, structure solutions, and catalytic performance of two novel layered silicates.
Liang, Jie; Su, Jie; Chen, Yanping; Li, Zhaofei; Li, Kuo; Zhang, Hao; Zou, Xiaodong; Liao, Fuhui; Wang, Yingxia; Lin, Jianhua; Dalton transactions (Cambridge, England : 2003) 44 (2015) 15567–15575; doi:10.1039/c5dt00487j

data_7035771
_publ_section_title
;
 Syntheses, structure solutions, and catalytic performance of two novel
 layered silicates.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15567
_journal_page_last               15575
_journal_paper_doi               10.1039/c5dt00487j
_journal_volume                  44
_journal_year                    2015
_chemical_formula_analytical     (Si10O19)(OH)3(C6H17N)2(H2O)
_chemical_formula_moiety         (Si10O19)(OH)3(C6H17)2(H2O)
_chemical_formula_sum            'C12 N2 O22 Si10'
_chemical_formula_weight         805.04
_chemical_melting_point          800
_chemical_name_common            'a layered silicate'
_chemical_name_systematic        PKU-13a
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_update_record
;
2014-07-17 deposited with the CCDC.
2015-07-13 downloaded from the CCDC.
;
_cell_angle_alpha                112.006(6)
_cell_angle_beta                 72.250(7)
_cell_angle_gamma                88.529(6)
_cell_formula_units_Z            1
_cell_length_a                   12.6249(15)
_cell_length_b                   7.3962(4)
_cell_length_c                   9.2524(6)
_cell_measurement_temperature    293
_cell_volume                     753.24(12)
_computing_structure_refinement  'Topas Academic V4.1'
_diffrn_ambient_temperature      293
_diffrn_radiation_monochromator  'Ge 1 1 1'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Cu K\a1'
_diffrn_radiation_wavelength     1.540596
_exptl_crystal_colour            white
_exptl_crystal_density_diffrn    1.775
_exptl_crystal_description       plate
_pd_char_colour                  white
_pd_char_particle_morphology     plate
_pd_meas_2theta_range_inc        0.02
_pd_meas_2theta_range_max        100.000
_pd_meas_2theta_range_min        5.000
_pd_meas_number_of_points        4750
_pd_proc_ls_background_function  'Chebychev polynomial'
_pd_proc_ls_pref_orient_corr     ' ?'
_pd_proc_ls_profile_function     'PearsonVII Peak Type'
_pd_proc_ls_prof_R_factor        0.0555
_pd_proc_ls_prof_wR_expected     0.0339
_pd_proc_ls_prof_wR_factor       0.0714
_pd_spec_mounting                ' ?'
_pd_spec_mount_mode              transmission
_pd_spec_shape                   flat_sheet
_refine_ls_goodness_of_fit_all   2.18
_refine_ls_number_parameters     108
_refine_ls_R_I_factor            0.0325
_cod_data_source_file            c5dt00487j2.cif
_cod_data_source_block           PKU-13a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_diffrn_radiation_probe' value 'X-ray' changed to 'x-ray' according
to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 7035770--7035771.cif.
;
_cod_database_code               7035771