Mn(III)-Mediated Reactions of Cyclopropanols with Vinyl Azides: Synthesis of Pyridine and 2-Azabicyclo[3.3.1]non-2-en-1-ol Derivatives
Yi-Feng Wang; Shunsuke Chiba; Journal of the American Chemical Society 131 (2009) 12570–12572; doi:10.1021/ja905110c

data_4104993
_publ_contact_author
;
Dr Shunsuke Chiba
Division of Chemistry and Biological Chemistry
School of Physical and Mathematical Sciences
Nanyang Technological University
21 Nanyang Link
Singapore 637371
Singapore
;
_publ_contact_author_email       shunsuke@ntu.edu.sg
_publ_contact_author_fax         '+65 6791 1961'
_publ_contact_author_phone       '+65 6513 8013'
_publ_section_title
;
 Mn(III)-Mediated Reactions of Cyclopropanols with Vinyl Azides: Synthesis
 of Pyridine and 2-Azabicyclo[3.3.1]non-2-en-1-ol Derivatives
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              12570
_journal_page_last               12572
_journal_paper_doi               10.1021/ja905110c
_journal_volume                  131
_journal_year                    2009
_chemical_absolute_configuration unk
_chemical_formula_moiety         'C14 H17 N O'
_chemical_formula_sum            'C14 H17 N O'
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_audit_creation_date             2008-12-16
_audit_creation_method           'by CrystalStructure 3.8.2'
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_cell_angle_beta                 70.861(6)
_cell_angle_gamma                77.939(8)
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_cell_length_b                   9.10940(10)
_cell_length_c                   10.52430(10)
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_cell_measurement_temperature    80.1
_cell_measurement_theta_max      66.1
_cell_measurement_theta_min      2.2
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_diffrn_reflns_theta_full        33.16
_diffrn_reflns_theta_max         33.16
_diffrn_source                   'rotating anode'
_diffrn_source_type              'Rigaku MM-007HF'
_exptl_absorpt_coefficient_mu    0.078
_exptl_absorpt_correction_T_max  0.984
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
    Higashi, T. (1995). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            yellow
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'Larson (1970) Crystallographic Computing eq. 22'
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_cod_data_source_block           '__Chiba-6aa'
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