Metallophilic interactions: observations of the shortest metallophilicinteractions between closed shell (d<sup>10</sup>d<sup>10</sup>, d<sup>10</sup>d<sup>8</sup>, d<sup>8</sup>d<sup>8</sup>) metal ions [MM' M = Hg(ii) and Pd(ii) and M' = Cu(i), Ag(i), Au(i), and Pd(ii)].
Raju, Saravanan; Singh, Harkesh B.; Butcher, Ray J.; Dalton transactions (Cambridge, England : 2003) 49 (2020) 9099–9117; doi:10.1039/d0dt01008a

data_7704630
_publ_section_title
;
 Metallophilic interactions: observations of the shortest
 metallophilicinteractions between closed shell
 (d<sup>10</sup>d<sup>10</sup>, d<sup>10</sup>d<sup>8</sup>,
 d<sup>8</sup>d<sup>8</sup>) metal ions [MM' M = Hg(ii) and Pd(ii) and M'
 = Cu(i), Ag(i), Au(i), and Pd(ii)].
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               9117
_journal_paper_doi               10.1039/d0dt01008a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety
;
C20 H12 Au F6 Hg N2 O6 S2, 3(C18 H12 Au Hg N2), 2(C F3 O3 S)
;
_chemical_formula_sum            'C76 H48 Au4 F12 Hg4 N8 O12 S4'
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_audit_update_record
;
2019-02-21 deposited with the CCDC.	2020-06-03 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      100(2)
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;
3(C18 H12 Au Hg N2), C2 Au F6 Hg O6 S2, 2(C9 H6 N), 2(C F3 O3 S)
;
_exptl_crystal_colour            'clear intense colourless'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7704622--7704632.cif.'
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