Enhanced lasing properties of dissymmetric Eu(III) complex with bidentate phosphine ligands.
Nakamura, Kazuki; Hasegawa, Yasuchika; Kawai, Hideki; Yasuda, Naoki; Kanehisa, Nobuko; Kai, Yasushi; Nagamura, Toshihiko; Yanagida, Shozo; Wada, Yuji; The journal of physical chemistry. A 111 (2007) 3029–3037; doi:10.1021/jp067672h

data_1505060
_publ_section_title
;
 Enhanced lasing properties of dissymmetric Eu(III) complex with bidentate
 phosphine ligands.
;
_journal_issue                   16
_journal_name_full               'The journal of physical chemistry. A'
_journal_page_first              3029
_journal_page_last               3037
_journal_paper_doi               10.1021/jp067672h
_journal_volume                  111
_journal_year                    2007
_chemical_formula_moiety         'C51 H31 F18 Eu O8 P2 '
_chemical_formula_sum            'C51 H31 Eu F18 O8 P2'
_chemical_formula_weight         1327.68
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 110.9240(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.3063(2)
_cell_length_b                   31.7409(6)
_cell_length_c                   13.5077(2)
_cell_measurement_reflns_used    42268
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.6
_cell_volume                     5328.81(15)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    'DIRDIF94 (PATTY)'
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9986
_diffrn_measured_fraction_theta_max 0.9986
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.070
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       41
_diffrn_reflns_limit_k_min       -41
_diffrn_reflns_limit_l_max       17
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_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_exptl_absorpt_coefficient_mu    1.349
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_exptl_absorpt_correction_T_min  0.727
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.655
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_size_max          0.200
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_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.47
_refine_diff_density_min         -1.03
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_refine_ls_shift/su_max          0.0191
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     F^2^>2.0\s(F^2^)
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_cod_data_source_block           Eu(hfa)3(BIPHEPO)
_cod_original_cell_volume        5328.8(2)
_cod_original_formula_sum        'C51 H31 F18 Eu O8 P2 '
_cod_database_code               1505060