Poly[bis(μ~3~-benzyloxyiminoacetato)nitratotrisilver(I)]
Hongming Zhang; Sudershan R. Gondi; David Y. Son; Acta Crystallographica Section E 62 (2006) m1613–m1615; doi:10.1107/S160053680602246X

data_2209379
_publ_section_title
;
 Poly[bis(\m~3~-benzyloxyiminoacetato)nitratotrisilver(I)]
;
_journal_coeditor_code           AT2042
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1613
_journal_page_last               m1615
_journal_paper_doi               10.1107/S160053680602246X
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          '[Ag3 (C9 H8 N O3)2 (N O3)]'
_chemical_formula_moiety         'C18 H16 Ag3 N3 O9'
_chemical_formula_sum            'C18 H16 Ag3 N3 O9'
_chemical_formula_weight         741.95
_chemical_name_systematic
;
Poly[bis(\m~3~-benzyloxyiminoacetato)nitratotrisilver(I)]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.047(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.996(2)
_cell_length_b                   7.0691(7)
_cell_length_c                   12.2522(12)
_cell_measurement_reflns_used    5190
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.57
_cell_measurement_theta_min      2.58
_cell_volume                     2052.5(3)
_computing_cell_refinement       'SAINT (Bruker, 1997)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL (Bruker, 1997)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 83.33
_diffrn_measured_fraction_theta_full 0.967
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_device_type  'Bruker APEX'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.034
_diffrn_reflns_av_sigmaI/netI    0.033
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            17961
_diffrn_reflns_theta_full        28.36
_diffrn_reflns_theta_max         28.36
_diffrn_reflns_theta_min         1.72
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.894
_exptl_absorpt_correction_T_max  0.903
_exptl_absorpt_correction_T_min  0.463
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 1997)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.401
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'thin plate'
_exptl_crystal_F_000             1432
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.04
_refine_diff_density_max         2.577
_refine_diff_density_min         -1.781
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     298
_refine_ls_number_reflns         4958
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.076
_refine_ls_R_factor_gt           0.062
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0947P)^2^+8.7822P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.163
_refine_ls_wR_factor_ref         0.172
_reflns_number_gt                3988
_reflns_number_total             4958
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            at2042.cif
_cod_data_source_block           I
_cod_original_cell_volume        2052.5(4)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2209379
_cod_database_fobs_code          2209379