Trisubstituted olefin synthesis via Ni-catalyzed hydroalkylation of internal alkynes with non-activated alkyl halides.
Lu, Xiao-Yu; Hong, Mei-Lan; Zhou, Hai-Pin; Wang, Yue; Wang, Jin-Yu; Ge, Xiu-Tao; Chemical communications (Cambridge, England) 54 (2018) 4417–4420; doi:10.1039/c8cc01577e

data_7121452
_publ_section_title
;
 Trisubstituted olefin synthesis via Ni-catalyzed hydroalkylation of
 internal alkynes with non-activated alkyl halides.
;
_journal_issue                   35
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              4417
_journal_page_last               4420
_journal_paper_doi               10.1039/c8cc01577e
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C21 H25 N O2 S'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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_audit_update_record
;
2017-09-26 deposited with the CCDC.
2018-03-27 downloaded from the CCDC.
;
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    1.247
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0818P)^2^+0.1458P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7121452.cif.'
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