Synthesis and crystal structure of three silver(I) complexes with (S )-(+)-5-oxo-2-tetrahydrofurancarboxylic acid (S-Hothf ) and its isomeric forms (R-Hothf and R,S-Hothf ) showing wide spectra of effective antibacterial and antifungal activities. Chiral helical polymers in the solid state formed by self-assembly of the dimeric [Ag(othf )]2 cores
Nomiya, Kenji; Takahashi, Satoshi; Noguchi, Ryusuke; Journal of the Chemical Society, Dalton Transactions  (2000) 1343–; doi:10.1039/a910251p

data_7009316
_publ_section_title
;
 Synthesis and crystal structure of three silver(I) complexes with
 (S&#x200A;)-(+)-5-oxo-2-tetrahydrofurancarboxylic acid
 (S-Hothf&#x200A;) and its isomeric forms (R-Hothf and
 R,S-Hothf&#x200A;) showing wide spectra of effective antibacterial and
 antifungal activities. Chiral helical polymers in the solid state
 formed by self-assembly of the dimeric [Ag(othf&#x200A;)]2 cores
;
_journal_issue                   8
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1343
_journal_paper_doi               10.1039/a910251p
_journal_year                    2000
_chemical_formula_moiety         'C10 H10 Ag2 O8 '
_chemical_formula_sum            'C10 H10 Ag2 O8'
_chemical_formula_weight         473.92
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 102.58(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   23.766(4)
_cell_length_b                   5.466(1)
_cell_length_c                   10.128(1)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.6
_cell_volume                     1284.1(3)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    'SIR97 (Altomare, et. al. 1997) '
_diffrn_ambient_temperature      296.2
_diffrn_measurement_device       'Rigaku AFC5S'
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      -0.00194
_diffrn_orient_matrix_UB_12      0.00175
_diffrn_orient_matrix_UB_13      0.09764
_diffrn_orient_matrix_UB_21      0.04081
_diffrn_orient_matrix_UB_22      -0.05832
_diffrn_orient_matrix_UB_23      0.02539
_diffrn_orient_matrix_UB_31      0.01376
_diffrn_orient_matrix_UB_32      0.17339
_diffrn_orient_matrix_UB_33      0.00754
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.01710
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            1666
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.98
_diffrn_standards_decay_%        -0.21
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.075
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_correction_T_min  0.833
_exptl_absorpt_correction_type
;
"\y scans (North,Phillips & Matthews, 1968)"
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.451
_exptl_crystal_density_meas      ?
_exptl_crystal_description       cubic
_exptl_crystal_F_000             912.00
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.83
_refine_diff_density_min         -1.18
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.439
_refine_ls_goodness_of_fit_ref   1.440
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     91
_refine_ls_number_reflns         1090
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0322
_refine_ls_R_factor_gt           0.0320
_refine_ls_shift/su_max          0.0200
_refine_ls_shift/su_mean         0.0032
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00090|Fo|^2^]'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0550
_refine_ls_wR_factor_ref         0.0550
_reflns_number_gt                1090
_reflns_number_total             1627
_reflns_threshold_expression     I>2.00\s(I)
_cod_data_source_file            a910251p.txt
_cod_data_source_block           3
_cod_original_cell_volume        1284.2(3)
_cod_original_sg_symbol_H-M      'C 2/c      '
_cod_original_formula_sum        'C10 H10 Ag2 O8 '
_cod_database_code               7009316