Coordination polymers built up from an s-tetrazine derived ligand and rare-earth ions: from a sequential dimensional expansion to organic-inorganic energy transfer.
Rouschmeyer, Paul; Guillou, Nathalie; Serre, Christian; Clavier, Gilles; Allain, Clémence; Devic, Thomas; Dalton transactions (Cambridge, England : 2003) 47 (2018) 10715–10720; doi:10.1039/c8dt01268g

data_7046797
_publ_section_title
;
 Coordination polymers built up from an s-tetrazine derived ligand and
 rare-earth ions: from a sequential dimensional expansion to
 organic-inorganic energy transfer.
;
_journal_issue                   31
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10715
_journal_page_last               10720
_journal_paper_doi               10.1039/c8dt01268g
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         C15H20N8O11Tb
_chemical_formula_sum            'C15 H20 N8 O11 Tb'
_chemical_formula_weight         647.31
_chemical_name_common            Tb(Tz(OCH2CO2)2)1.5(DMF)2
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2018-05-31 deposited with the CCDC.
2018-06-06 downloaded from the CCDC.
;
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_cell_measurement_temperature    293(2)
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_cell_volume                     1280.0(7)
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_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.956
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_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1327
_diffrn_reflns_av_unetI/netI     0.3080
_diffrn_reflns_Laue_measured_fraction_full 0.956
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_diffrn_reflns_point_group_measured_fraction_full 0.956
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_exptl_absorpt_process_details   'SADABS 2014/5'
_exptl_crystal_colour            red
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_exptl_crystal_description       needle
_exptl_crystal_F_000             638
_exptl_crystal_preparation       Luminescent
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0384P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1053
_refine_ls_wR_factor_ref         0.1403
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2103
_reflns_number_total             4966
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt01268g2.cif
_cod_data_source_block           MIL-166(Tb)
_cod_depositor_comments
'Adding full bibliography for 7046794--7046797.cif.'
_cod_database_code               7046797
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.602
_shelx_estimated_absorpt_t_max   0.849
_shelx_res_checksum              76189
_shelx_fab_checksum              80186