Rh-Catalyzed Decarbonylative Coupling with Alkynes via C-C Activation of Isatins.
Zeng, Rong; Dong, Guangbin; Journal of the American Chemical Society 137 (2015) 1408–1411; doi:10.1021/ja512306a

data_4123255
_publ_section_title
;
 Rh-Catalyzed Decarbonylative Coupling with Alkynes via C-C Activation of
 Isatins.
;
_journal_issue                   4
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              1408
_journal_page_last               1411
_journal_paper_doi               10.1021/ja512306a
_journal_volume                  137
_journal_year                    2015
_chemical_formula_sum            'C21 H19 Cl3 N3 O2 Rh'
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_chemical_name_systematic
;
 ?
;
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_cell_measurement_temperature    100(2)
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_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
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_diffrn_measured_fraction_theta_full 0.999
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_diffrn_reflns_theta_max         27.482
_diffrn_reflns_theta_min         2.064
_exptl_absorpt_coefficient_mu    1.197
_exptl_crystal_colour            colorless
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_refine_ls_restrained_S_all      1.023
_refine_ls_R_factor_all          0.0353
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0351P)^2^+0.1252P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             4891
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 4123252--4123255.cif.'
_cod_database_code               4123255
_shelx_estimated_absorpt_t_min   0.880
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