Reversible σ-Bond Formation in Bowl-Shaped π-Radical Cations: The Effects of Curved and Planar Structures.
Yokoi, Hiroki; Hiroto, Satoru; Shinokubo, Hiroshi; Journal of the American Chemical Society 140 (2018) 4649–4655; doi:10.1021/jacs.8b00798

data_4132041
_publ_section_title
;
 Reversible \s-Bond Formation in Bowl-Shaped \p-Radical Cations: The
 Effects of Curved and Planar Structures.
;
_journal_issue                   13
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              4649
_journal_page_last               4655
_journal_paper_doi               10.1021/jacs.8b00798
_journal_volume                  140
_journal_year                    2018
_chemical_formula_sum            'C199.77 H195.32 N4'
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_diffrn_measured_fraction_theta_max 0.986
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_diffrn_measurement_method       \w
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_exptl_crystal_colour            yellow
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'w=1/[\s^2^(Fo^2^)+(0.0913P)^2^+5.9745P] where P=(Fo^2^+2Fc^2^)/3'
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