LMucko/crystallography-open-database huggingface dataset:
Model of a Solvent-Shared Ion Pair with N‒H⋯C Hydrogen Bonds between Amine and Carbanion-Crystal Structure of [Fluorenyllithium·2 Ethylenediamine]~∞~
Buchholz, Stefan; Harms, Klaus; Marsch, Michael; Massa, Werner; Boche, Gernot; Angewandte Chemie, International Edition in English 28 (1989) 72–73; doi:10.1002/anie.198900721

data_1100300
_publ_section_title
;
 Model of a Solvent-Shared Ion Pair with N--H&#x22EF;C Hydrogen Bonds
 between Amine and Carbanion-Crystal Structure of
 [Fluorenyllithium&#x00B7;2 Ethylenediamine]~\\infty ~
;
_journal_coden_ASTM              ACIEAY
_journal_issue                   1
_journal_name_full
;
 Angewandte Chemie, International Edition in English
;
_journal_page_first              72
_journal_page_last               73
_journal_paper_doi               10.1002/anie.198900721
_journal_volume                  28
_journal_year                    1989
_chemical_formula_sum            'C17 H25 Li N4'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 104.11(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.724(3)
_cell_length_b                   8.561(2)
_cell_length_c                   13.267(3)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C17 H25 Li1 N4'
_cod_database_code               1100300
Hydrogen Bonds between an NH~4~^⊕^ Ion and a Carbanion—Crystal Structure of Ammonium 1,2,4-Tricyanocyclopentadienide
Buchholz, Stefan; Harms, Klaus; Massa, Werner; Boche, Gernot; Angewandte Chemie, International Edition in English 28 (1989) 73–75; doi:10.1002/anie.198900731

data_1100301
_publ_section_title
;
 Hydrogen Bonds between an NH~4~^&#x2295;^ Ion and a Carbanion---Crystal
 Structure of Ammonium 1,2,4-Tricyanocyclopentadienide
;
_journal_coden_ASTM              ACIEAY
_journal_issue                   1
_journal_name_full
;
 Angewandte Chemie, International Edition in English
;
_journal_page_first              73
_journal_page_last               75
_journal_paper_doi               10.1002/anie.198900731
_journal_volume                  28
_journal_year                    1989
_chemical_formula_sum            'C8 H6 N4'
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      62
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.941(2)
_cell_length_b                   9.450(1)
_cell_length_c                   6.459(1)
_cod_database_code               1100301
Aminocarbene annulation by alkynes: a regio- and diastereo-selective route to indanone complexes
Dötz, Karl Heinz; Erben, Hans-Georg; Harms, Klaus; Journal of the Chemical Society, Chemical Communications  (1989) 692–693; doi:10.1039/c39890000692

data_1100302
_publ_section_title
;
 Aminocarbene annulation by alkynes: a regio- and diastereo-selective
 route to indanone complexes
;
_journal_coden_ASTM              JCCCAT
_journal_issue                   11
_journal_name_full
;
 Journal of the Chemical Society, Chemical Communications
;
_journal_page_first              692
_journal_page_last               693
_journal_paper_doi               10.1039/c39890000692
_journal_year                    1989
_chemical_formula_sum            'C19 H22 Cr O5'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 107.86(2)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   22.736(5)
_cell_length_b                   6.809(1)
_cell_length_c                   25.373(10)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C19 H22 Cr1 O5'
_cod_database_code               1100302
X-Ray Structure Analysis of α-Lithiophenylacetonitrile · Lithium Diisopropyl amide · 2 Tetramethylethylenediamine—a "Quasi-Dianion Complex"
Zarges, Wolfgang; Marsch, Michael; Harms, Klaus; Boche, Gernot; Angewandte Chemie, International Edition in English 28 (1989) 1392–1394; doi:10.1002/anie.198913921

data_1100303
_publ_section_title
;
 X-Ray Structure Analysis of \a-Lithiophenylacetonitrile &#x00B7; Lithium
 Diisopropyl amide &#x00B7; 2 Tetramethylethylenediamine---a
 "Quasi-Dianion Complex"
;
_journal_coden_ASTM              ACIEAY
_journal_issue                   10
_journal_name_full
;
 Angewandte Chemie, International Edition in English
;
_journal_page_first              1392
_journal_page_last               1394
_journal_paper_doi               10.1002/anie.198913921
_journal_volume                  28
_journal_year                    1989
_chemical_formula_sum            'C26 H52 Li2 N6'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                77.24(2)
_cell_angle_beta                 73.47(1)
_cell_angle_gamma                87.16(2)
_cell_formula_units_Z            2
_cell_length_a                   9.968(2)
_cell_length_b                   11.966(3)
_cell_length_c                   14.171(2)
_cod_database_code               1100303
Activated Aminocarbene Complexes of the Fischer Type: Synthesis, Structure, and Annelation Reactions
Dötz, Karl Heinz; Grotjahn, Douglas; Harms, Klaus; Angewandte Chemie, International Edition in English 28 (1989) 1384–1386; doi:10.1002/anie.198913841

data_1100304
_publ_section_title
;
 Activated Aminocarbene Complexes of the Fischer Type: Synthesis, Structure,
 and Annelation Reactions
;
_journal_coden_ASTM              ACIEAY
_journal_issue                   10
_journal_name_full
;
 Angewandte Chemie, International Edition in English
;
_journal_page_first              1384
_journal_page_last               1386
_journal_paper_doi               10.1002/anie.198913841
_journal_volume                  28
_journal_year                    1989
_chemical_formula_sum            'C17 H17 Cr N O6'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 111.66(1)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   23.355(5)
_cell_length_b                   11.187
_cell_length_c                   15.629
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C17 H17 Cr1 N1 O6'
_cod_database_code               1100304
[{Li~2~(Me~3~SiCCN)}~12~(Et~2~O)~6~(C~6~H~14~)], Kristallstruktur mit dem Trimethylsilylacetonitril-Dianion
Zarges, Wolfgang; Marsch, Michael; Harms, Klaus; Boche, Gernot; Chemische Berichte 122 (1989) 1307–1311; doi:10.1002/cber.19891220714

data_1100305
_publ_section_title
;
 [{Li~2~(Me~3~SiCCN)}~12~(Et~2~O)~6~(C~6~H~14~)], Kristallstruktur mit dem
 Trimethylsilylacetonitril-Dianion
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   7
_journal_name_full               'Chemische Berichte'
_journal_page_first              1307
_journal_page_last               1311
_journal_paper_doi               10.1002/cber.19891220714
_journal_volume                  122
_journal_year                    1989
_chemical_formula_sum            'C90 H182 Li24 N12 O6 Si12'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                74.01(1)
_cell_angle_beta                 84.38(1)
_cell_angle_gamma                61.32(1)
_cell_formula_units_Z            1
_cell_length_a                   15.574(2)
_cell_length_b                   15.678(1)
_cell_length_c                   16.257(1)
_cod_database_code               1100305
Carbene complexes in intramolecular Diels-Alder reactions
Dötz, K. H.; Noack, R.; Harms, K.; Müller, G.; Tetrahedron 46 (1990) 1235–1252; doi:10.1016/s0040-4020(01)86689-8

data_1100306
_publ_section_title
;
 Carbene complexes in intramolecular Diels-Alder reactions
;
_journal_coden_ASTM              TETRAB
_journal_issue                   4
_journal_name_full               Tetrahedron
_journal_page_first              1235
_journal_page_last               1252
_journal_paper_doi               10.1016/s0040-4020(01)86689-8
_journal_volume                  46
_journal_year                    1990
_chemical_formula_sum            'C16 H13 N O6 W'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                82.96(3)
_cell_angle_beta                 83.11(2)
_cell_angle_gamma                85.04(2)
_cell_formula_units_Z            2
_cell_length_a                   6.110(2)
_cell_length_b                   9.353(3)
_cell_length_c                   14.739(4)
_cod_original_formula_sum        'C16 H13 N1 O6 W1'
_cod_database_code               1100306
Stereoselective synthesis of α,γ-diamino-β-hydroxy amino acid esters: A new class of amino acids
Reetz, M. T.; Wünsch, T.; Harms, K.; Tetrahedron: Asymmetry 1 (1990) 371–374; doi:10.1016/0957-4166(90)90036-a

data_1100307
_publ_section_title
;
 Stereoselective synthesis of \a,\g-diamino-\b-hydroxy amino acid esters:
 A new class of amino acids
;
_journal_coden_ASTM              TASYE3
_journal_issue                   6
_journal_name_full               'Tetrahedron: Asymmetry'
_journal_page_first              371
_journal_page_last               374
_journal_paper_doi               10.1016/0957-4166(90)90036-a
_journal_volume                  1
_journal_year                    1990
_chemical_formula_sum            'C30 H38 N2 O5'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                97.07(1)
_cell_angle_beta                 108.05(1)
_cell_angle_gamma                107.29(1)
_cell_formula_units_Z            2
_cell_length_a                   9.617(1)
_cell_length_b                   11.345(1)
_cell_length_c                   15.090(2)
_cod_depositor_comments
;
 Restoring coordinates of atoms 'O5', 'C29', 'C30' and 'C31?' that were
 accidentally removed in a previous revision.

 Antanas Vaitkus,
 2017-09-09
;
_cod_database_code               1100307
Stereocontrolled Intramolecular Diels-Alder Reaction of Heterodienes; Studies on the Synthesis of Cannabinoids
Tietze, Lutz-F.; von Kiedrowski, Günter; Harms, Klaus; Clegg, William; Sheldrick, George; Angewandte Chemie, International Edition in English 19 (1980) 134–135; doi:10.1002/anie.198001341

data_1100308
_publ_section_title
;
 Stereocontrolled Intramolecular Diels-Alder Reaction of Heterodienes;
 Studies on the Synthesis of Cannabinoids
;
_journal_coden_ASTM              ACIEAY
_journal_issue                   2
_journal_name_full
;
 Angewandte Chemie, International Edition in English
;
_journal_page_first              134
_journal_page_last               135
_journal_paper_doi               10.1002/anie.198001341
_journal_volume                  19
_journal_year                    1980
_chemical_formula_sum            'C16 H24 O2'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_H-M   'P 21/n'
_cell_angle_alpha                90
_cell_angle_beta                 90.03(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.907(3)
_cell_length_b                   8.094(2)
_cell_length_c                   14.868(5)
_cod_database_code               1100308
[(1RS,2RS,3SR)-3-Hydroxy-2-methylcyclopentyl]trimethylammonium chloride
Harms, K.; Sheldrick, G. M.; Fischer, R.; Tietze, L. F.; Acta Crystallographica, Section B: Structural Crystallography and Crystal Chemistry 36 (1980) 3206–3208; doi:10.1107/S0567740880011338

data_1100309
_publ_section_title
;
 [(1RS,2RS,3SR)-3-Hydroxy-2-methylcyclopentyl]trimethylammonium chloride
;
_journal_coden_ASTM              ACBCAR
_journal_issue                   12
_journal_name_full
;
 Acta Crystallographica, Section B: Structural Crystallography
 and Crystal Chemistry
;
_journal_page_first              3206
_journal_page_last               3208
_journal_paper_doi               10.1107/S0567740880011338
_journal_volume                  36
_journal_year                    1980
_chemical_formula_sum            'C9 H20 Cl N O'
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.440(2)
_cell_length_b                   11.609(2)
_cell_length_c                   12.295(3)
_cod_original_formula_sum        'C9 H20 Cl1 N1 O1'
_cod_database_code               1100309
(2S,6aR,10aR)-6,6,9-Trimethyl-1-oxo-2-phenylseleno-1,2,3,4,6a,7,8,9,10,10a-decahydro-6H-dibenzo[b,d]pyran
Clegg, W.; Harms, K.; Sheldrick, G. M.; von Kiedrowski, G.; Tietze, L. F.; Acta Crystallographica, Section B: Structural Crystallography and Crystal Chemistry 36 (1980) 3159–3162; doi:10.1107/S0567740880011144

data_1100310
_publ_section_title
;
 (2S,6aR,10aR)-6,6,9-Trimethyl-1-oxo-2-phenylseleno-1,2,3,4,6a,7,8,9,10,10a-decahydro-6H-dibenzo[b,d]pyran
;
_journal_coden_ASTM              ACBCAR
_journal_issue                   12
_journal_name_full
;
 Acta Crystallographica, Section B: Structural Crystallography
 and Crystal Chemistry
;
_journal_page_first              3159
_journal_page_last               3162
_journal_paper_doi               10.1107/S0567740880011144
_journal_volume                  36
_journal_year                    1980
_chemical_formula_sum            'C22 H28 O2 Se'
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90
_cell_angle_beta                 114.62(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.298(3)
_cell_length_b                   9.915(2)
_cell_length_c                   10.835(2)
_cod_original_sg_symbol_H-M      'P 21'
_cod_original_formula_sum        'C22 H28 O2 Se1'
_cod_database_code               1100310
Structure of a Chiral Lithium Azaenolate: Monomeric, Intramolecular Chelated Lithio-2-acetylnaphthalene-SAMP-hydrazone
Enders, Dieter; Bachstädter, Gerhard; Kremer, Kenneth A. M.; Marsch, Michael; Harms, Klaus; Boche, Gernot; Angewandte Chemie, International Edition in English 27 (1988) 1522–1524; doi:10.1002/anie.198815221

data_1100311
_publ_section_title
;
 Structure of a Chiral Lithium Azaenolate: Monomeric, Intramolecular
 Chelated Lithio-2-acetylnaphthalene-SAMP-hydrazone
;
_journal_coden_ASTM              ACIEAY
_journal_issue                   11
_journal_name_full
;
 Angewandte Chemie, International Edition in English
;
_journal_page_first              1522
_journal_page_last               1524
_journal_paper_doi               10.1002/anie.198815221
_journal_volume                  27
_journal_year                    1988
_chemical_formula_sum            'C26 H37 Li N2 O3'
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90
_cell_angle_beta                 101.01
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   7.894(1)
_cell_length_b                   16.227(2)
_cell_length_c                   9.707(2)
_cod_original_sg_symbol_H-M      'P 21'
_cod_original_formula_sum        'C26 H37 Li1 N2 O3'
_cod_database_code               1100311
Chirale Homoenolat-Äquivalente, IV. Kristallstruktur einer chiralen 1-Aminoallyllithium-Verbindung: dimeres, intramolekular chelatisiertes (3S)-3-Lithio-1-[(S)-2-(methoxymethyl)pyrrolidino]-1,3-diphenylpropen
Ahlbrecht, Hubertus; Boche, Gernot; Harms, Klaus; Marsch, Michael; Sommer, Horst; Chemische Berichte 123 (1990) 1853–1858; doi:10.1002/cber.19901230917

data_1100312
_publ_section_title
;
 Chirale Homoenolat-\"Aquivalente, IV. Kristallstruktur einer chiralen
 1-Aminoallyllithium-Verbindung: dimeres, intramolekular chelatisiertes
 (3S)-3-Lithio-1-[(S)-2-(methoxymethyl)pyrrolidino]-1,3-diphenylpropen
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   9
_journal_name_full               'Chemische Berichte'
_journal_page_first              1853
_journal_page_last               1858
_journal_paper_doi               10.1002/cber.19901230917
_journal_volume                  123
_journal_year                    1990
_chemical_formula_sum            'C56 H64 Li2 N2 O2'
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.141(2)
_cell_length_b                   15.338(2)
_cell_length_c                   20.827(2)
_cod_database_code               1100312
Asymmetric Induction in the Wittig-Still Rearrangement of Ethers Containing an Allylic Stereocenter – Diastereocontrol by Allylic Nitrogen
Priepke, Henning; Brückner, Reinhard; Harms, Klaus; Chemische Berichte 123 (1990) 555–563; doi:10.1002/cber.19901230323

data_1100313
_publ_section_title
;
 Asymmetric Induction in the Wittig-Still Rearrangement of Ethers
 Containing an Allylic Stereocenter -- Diastereocontrol by Allylic
 Nitrogen
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   3
_journal_name_full               'Chemische Berichte'
_journal_page_first              555
_journal_page_last               563
_journal_paper_doi               10.1002/cber.19901230323
_journal_volume                  123
_journal_year                    1990
_chemical_formula_sum            'C26 H29 N O'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                94.741(1)
_cell_angle_beta                 97.68(1)
_cell_angle_gamma                102.49(1)
_cell_formula_units_Z            2
_cell_length_a                   9.425(2)
_cell_length_b                   9.490(2)
_cell_length_c                   12.386(1)
_cod_original_formula_sum        'C26 H29 N1 O1'
_cod_database_code               1100313
Asymmetric Induction in the Wittig-Still Rearrangement of Ethers Containing an Allylic Stereocenter – Diastereocontrol by Allylic Nitrogen
Priepke, Henning; Brückner, Reinhard; Harms, Klaus; Chemische Berichte 123 (1990) 555–563; doi:10.1002/cber.19901230323

data_1100314
_publ_section_title
;
 Asymmetric Induction in the Wittig-Still Rearrangement of Ethers
 Containing an Allylic Stereocenter -- Diastereocontrol by Allylic
 Nitrogen
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   3
_journal_name_full               'Chemische Berichte'
_journal_page_first              555
_journal_page_last               563
_journal_paper_doi               10.1002/cber.19901230323
_journal_volume                  123
_journal_year                    1990
_chemical_formula_sum            'C20 H28 N2 O4'
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.939(2)
_cell_length_b                   8.520(2)
_cell_length_c                   23.674(1)
_cod_database_code               1100314
[nBuLi · LiOtBu]~4~, Solid-State Structure of an n-Butyllithium‒Lithiumtert-Butoxide Complex
Marsch, Michael; Harms, Klaus; Lochmann, Lubomir; Boche, Gernot; Angewandte Chemie, International Edition in English 29 (1990) 308–309; doi:10.1002/anie.199003081

data_1100315
_publ_section_title
;
 [nBuLi &#x00B7; LiOtBu]~4~, Solid-State Structure of
 an n-Butyllithium--Lithiumtert-Butoxide Complex
;
_journal_coden_ASTM              ACIEAY
_journal_issue                   3
_journal_name_full
;
 Angewandte Chemie, International Edition in English
;
_journal_page_first              308
_journal_page_last               309
_journal_paper_doi               10.1002/anie.199003081
_journal_volume                  29
_journal_year                    1990
_chemical_formula_sum            'C32 H72 Li8 O4'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 101.83(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.024(6)
_cell_length_b                   23.659(9)
_cell_length_c                   16.377(18)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1100315
Asymmetric Induction in the [2,3] Witting Rearrangement by Chiral Substituents in the Allyl Moiety: 1,3-Asymmetric Induction
Scheuplein, Stefan W.; Kusche, Andreas; Brückner, Reinhard; Harms, Klaus; Chemische Berichte 123 (1990) 917–925; doi:10.1002/cber.19901230443

data_1100316
_publ_section_title
;
 Asymmetric Induction in the [2,3] Witting Rearrangement by Chiral
 Substituents in the Allyl Moiety: 1,3-Asymmetric Induction
;
_journal_coden_ASTM              CHBEAM
_journal_issue                   4
_journal_name_full               'Chemische Berichte'
_journal_page_first              917
_journal_page_last               925
_journal_paper_doi               10.1002/cber.19901230443
_journal_volume                  123
_journal_year                    1990
_chemical_formula_sum            'C15 H26 O3 Si'
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90
_cell_angle_beta                 109.220(6)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   7.963(1)
_cell_length_b                   10.014(1)
_cell_length_c                   12.011(2)
_cod_original_sg_symbol_H-M      'P 21'
_cod_original_formula_sum        'C15 H26 O3 Si1'
_cod_database_code               1100316