Hydrazinium(1+) Hexafluorogallate(III) and Hydrazinium(2+) Aquapentafluorogallate(III)
Meden, A.; Siftar, J.; Golic, L.; Acta Crystallographica Section C 52 (1996) 493–496; doi:10.1107/S0108270195011310

data_2004627
_publ_section_title
;
 Hydrazinium(1+) Hexafluorogallate(III) and Hydrazinium(2+)
 Aquapentafluorogallate(III)
;
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              493
_journal_page_last               496
_journal_paper_doi               10.1107/S0108270195011310
_journal_volume                  52
_journal_year                    1996
_chemical_formula_moiety         '(N2 H5 1+)3 (Ga F6 3-)'
_chemical_formula_structural     '(N2 H5) (Ga F6)'
_chemical_formula_sum            'F6 Ga H15 N6'
_chemical_formula_weight         282.87
_chemical_name_systematic
;
hydrazinium hexafluorogallate
;
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_audit_creation_method           from_xtal_archive_file_using_CIFIO
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.125(2)
_cell_length_b                   9.241(2)
_cell_length_c                   10.532(2)
_cell_measurement_reflns_used    75
_cell_measurement_temperature    293
_cell_measurement_theta_max      17.939
_cell_measurement_theta_min      9.987
_cell_volume                     888.1(3)
_computing_cell_refinement       'Xray PARAM, local program'
_computing_data_collection       'CAD-4 Software (Enraf-Nonius, 1989)'
_computing_data_reduction
'DIFDAT SORTRF ADDREF Xtal3.2 (Hall, Flack & Stewart, 1992)'
_computing_molecular_graphics    'ORTEP (Johnson, 1965)'
_computing_publication_material  'BONDLA CIFIO Xtal3.2'
_computing_structure_refinement  'CRYLSQ Xtal3.2'
_computing_structure_solution    Xtal3.2
_diffrn_ambient_temperature      293
_diffrn_measurement_device       'Enraf-Nonius CAD-4'
_diffrn_measurement_method       \w/2\q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         xray_tube
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  .029
_diffrn_reflns_av_sigmaI/netI    .023
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            10393
_diffrn_reflns_theta_max         29.94
_diffrn_reflns_theta_min         2.93
_diffrn_standards_decay_%        -1.14
_diffrn_standards_interval_time  333
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.16
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.116
_exptl_crystal_description       prism
_exptl_crystal_F_000             568
_exptl_crystal_size_max          0.53
_exptl_crystal_size_mid          0.46
_exptl_crystal_size_min          0.34
_refine_diff_density_max         .644
_refine_diff_density_min         -1.138
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.036
_refine_ls_goodness_of_fit_obs   1.024
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     178
_refine_ls_number_reflns         1469
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .035
_refine_ls_R_factor_obs          .033
_refine_ls_shift/esd_max         2.21
_refine_ls_shift/esd_mean        .163
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      'Regina weighting scheme'
_refine_ls_wR_factor_all         .019
_refine_ls_wR_factor_obs         .019
_reflns_number_observed          1429
_reflns_number_total             1497
_reflns_observed_criterion       refl_observed_if_Inet_>_2_sigma(Inet)
_cod_data_source_file            ka1142.cif
_cod_data_source_block           I
_cod_original_formula_sum        'H15 F6 Ga N6'
_cod_database_code               2004627