DMF as a Source of Oxygen and Aminomethine: Stereoselective 1,2-Insertion of Rhodium(II) Azavinyl Carbenes into the C═O Bond of Formamides for the Synthesis of cis-Diamino Enones.
Jung, Da Jung; Jeon, Hyun Ji; Kim, Ju Hyun; Kim, Youngmee; Lee, Sang-Gi; Organic letters 16 (2014) 2208–2211; doi:10.1021/ol500723s

data_1514265
_publ_section_title
;
 DMF as a Source of Oxygen and Aminomethine: Stereoselective 1,2-Insertion
 of Rhodium(II) Azavinyl Carbenes into the C&#x2550;O Bond of Formamides
 for the Synthesis of cis-Diamino Enones.
;
_journal_issue                   8
_journal_name_full               'Organic letters'
_journal_page_first              2208
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_journal_paper_doi               10.1021/ol500723s
_journal_volume                  16
_journal_year                    2014
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0581P)^2^+0.2511P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for
 ./tmp-cod-update-bibliographies-8800/cifs/1514265.cif.
;
_cod_original_cell_volume        1823.6(6)
_cod_original_sg_symbol_H-M      P2(1)/n
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