Terpyridine Molybdenum Dinitrogen Chemistry: Synthesis of Dinitrogen Complexes That Vary by Five Oxidation States.
Bezdek, Máté J; Guo, Sheng; Chirik, Paul J.; Inorganic chemistry 55 (2016) 3117–3127; doi:10.1021/acs.inorgchem.6b00053

data_4347353
_publ_section_title
;
 Terpyridine Molybdenum Dinitrogen Chemistry: Synthesis of Dinitrogen
 Complexes That Vary by Five Oxidation States.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3117
_journal_page_last               3127
_journal_paper_doi               10.1021/acs.inorgchem.6b00053
_journal_volume                  55
_journal_year                    2016
_chemical_formula_sum            'C164 H111 B2 F49 Mo2 N8 P4'
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_cell_length_c                   34.3598(9)
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_cell_measurement_theta_min      3.57
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_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
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_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_Laue_measured_fraction_max 0.978
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_diffrn_reflns_limit_l_min       -40
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_diffrn_reflns_theta_min         2.599
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_exptl_absorpt_correction_T_max  0.7528
_exptl_absorpt_correction_T_min  0.6234
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'TWINABS BRUKER AXS'
_exptl_crystal_colour            red
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_exptl_crystal_description       Rectangular
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_refine_ls_R_factor_all          0.0377
_refine_ls_R_factor_gt           0.0330
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0447P)^2^+6.3022P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0879
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_reflns_threshold_expression     'I > 2\s(I)'
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_shelxl_version_number           2014-3
_shelx_res_checksum              46040
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