Coordination and supramolecular assembly of {Cd2Ge8V12O48} building block and cucurbit[6] to form rotaxane-shaped hybrids.
Wei, Mei-Jie; Zang, Hong-Ying; Zhou, En-Long; Shao, Kui-Zhan; Song, Bai-Qiao; Wang, Xin-Long; Su, Zhong-Min; Dalton transactions (Cambridge, England : 2003) 45 (2016) 4989–4992; doi:10.1039/c6dt00496b

data_7038582
_publ_section_title
;
 Coordination and supramolecular assembly of {Cd2Ge8V12O48} building block
 and cucurbit[6] to form rotaxane-shaped hybrids.
;
_journal_issue                   12
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4989
_journal_page_last               4992
_journal_paper_doi               10.1039/c6dt00496b
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C46 H98 Cd4 Ge8 N34 O67 V12'
_chemical_formula_weight         3841.18
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2016-01-27 deposited with the CCDC.
2016-02-25 downloaded from the CCDC.
;
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_cell_angle_gamma                90.000(5)
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_cell_length_c                   36.902(5)
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_cell_volume                     11306(5)
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_computing_structure_solution    'Bruker SHELXTL 2014/4'
_diffrn_ambient_temperature      298(2)
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_diffrn_measurement_device_type  'Bruker Smart Apex II CCD'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
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_diffrn_reflns_number            32176
_diffrn_reflns_point_group_measured_fraction_full 0.972
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_diffrn_source                   'fine-focus sealed tube'
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_exptl_absorpt_correction_T_min  0.378
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2014/4 Bruker AXS Madison WI USA'
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_refine_ls_R_factor_all          0.0991
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1136P)^2^+440.6374P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             9937
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7038581--7038582.cif.'
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_shelx_estimated_absorpt_t_max   0.483
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