Linear-chain bis(μ-<i>O,O</i>'-dimethyl dithiophosphato)lead(II)
Tetsuzo Ito; Yoshinori Maeda; Acta Crystallographica Section E 60 (2004) m1349–m1350; doi:10.1107/S1600536804020914

data_2204117
_publ_section_title
;
 Linear-chain bis(\m-<i>O,O</i>'-dimethyl dithiophosphato)lead(II)
;
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1349
_journal_page_last               m1350
_journal_paper_doi               10.1107/S1600536804020914
_journal_volume                  60
_journal_year                    2004
_chemical_formula_iupac          '[Pb (C2 H6 O2 P1 S2)2]'
_chemical_formula_moiety         'C4 H12 O4 P2 Pb S4'
_chemical_formula_sum            'C4 H12 O4 P2 Pb S4'
_chemical_formula_weight         521.56
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
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_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_b                   9.218(2)
_cell_length_c                   9.2160(10)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296
_cell_measurement_theta_max      16.5
_cell_measurement_theta_min      15.9
_cell_volume                     1506.9(4)
_computing_cell_refinement       'MSC/AFC Diffractometer Control Software'
_computing_data_collection
;
MSC/AFC Diffractometer Control Software
(Molecular Structure Corporation, 1988)
;
_computing_data_reduction
;
CrystalStructure (Rigaku/MSC, 2002)
;
_computing_molecular_graphics    'ORTEPIII (Burnett & Johnson, 1996)'
_computing_publication_material  CrystalStructure
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_computing_structure_solution    'SIR92 (Altomare et al., 1994)'
_diffrn_measured_fraction_theta_full 0.9970
_diffrn_measured_fraction_theta_max 0.9970
_diffrn_measurement_device_type  'Rigaku AFC-5S'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_av_R_equivalents  0.007
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_diffrn_reflns_limit_h_min       0
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_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_standards_decay_%        0.16
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    11.972
_exptl_absorpt_correction_T_max  0.238
_exptl_absorpt_correction_T_min  0.146
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North et al., 1968)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.299
_exptl_crystal_density_meas      2.292
_exptl_crystal_density_method    'flotation in zinc iodide (aq)'
_exptl_crystal_description       prism
_exptl_crystal_F_000             976.00
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.12
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/\s^2^(F~o~)'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0280
_reflns_number_gt                1005
_reflns_number_total             1727
_reflns_threshold_expression     I>3\s(I)
_cod_data_source_file            ac6113.cif
_cod_data_source_block           I
_cod_database_code               2204117
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