Preparation of carbon-based AuAg alloy nanoparticles by using the heterometallic [Au<sub>4</sub>Ag<sub>4</sub>] cluster for efficient oxidative coupling of anilines.
Gao, Bin-Bin; Zhang, Min; Chen, Xu-Ran; Zhu, Da-Liang; Yu, Hong; Zhang, Wen-Hua; Lang, Jian-Ping; Dalton transactions (Cambridge, England : 2003) 47 (2018) 5780–5788; doi:10.1039/c8dt00695d

data_7045897
_publ_section_title
;
 Preparation of carbon-based AuAg alloy nanoparticles by using the
 heterometallic [Au<sub>4</sub>Ag<sub>4</sub>] cluster for efficient
 oxidative coupling of anilines.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5780
_journal_page_last               5788
_journal_paper_doi               10.1039/c8dt00695d
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety
'C112 H117 Ag4 Au4 N12 P4 S4, 8(F6 P), 7(C2 H3 N)'
_chemical_formula_sum            'C126 H138 Ag4 Au4 F48 N19 P12 S4'
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_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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;
2018-03-19 deposited with the CCDC.
2018-03-21 downloaded from the CCDC.
;
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
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_computing_data_reduction
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics    'SHELXL-2013 (Sheldrick, 2013)'
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_diffrn_radiation_type           MoK\a
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.826
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_exptl_crystal_size_min          0.200
_refine_diff_density_max         5.923
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_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.057
_refine_ls_hydrogen_treatment    constr
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_refine_ls_number_restraints     41
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.1407
_refine_ls_R_factor_gt           0.0987
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1654P)^2^+18.6694P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2427
_refine_ls_wR_factor_ref         0.2886
_reflns_Friedel_coverage         0.000
_reflns_number_gt                19097
_reflns_number_total             29113
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt00695d2.cif
_cod_data_source_block           AU_CCDC1
_cod_depositor_comments
'Adding full bibliography for 7045896--7045897.cif.'
_cod_database_code               7045897
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.224
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_shelx_res_checksum              3437
_shelx_fab_checksum              31978