New mononuclear Dy(III) complex based on a calix[4]arene ligand with two appended salicylideneamine groups decorated with azophenyl fragments: synthesis, crystalline assembly and slow magnetic relaxation behavior.
Strelnikova, Iuliia V.; Iova, Angelina A.; Ovsyannikov, Alexander S.; Islamov, Daut R.; Litvonov, Igor A.; Lazarenko, Vladimir A.; Kulikova, Elizaveta S.; Bogomyakov, Artem S.; Lin, Meijin; Kiiamov, Airat G.; Solovieva, Svetlana E.; Antipin, Igor S.; Dalton transactions (Cambridge, England : 2003) 54 (2025) 9584–9593; doi:10.1039/d5dt00936g

data_7718685
_publ_section_title
;
 New mononuclear Dy(III) complex based on a calix[4]arene ligand with two
 appended salicylideneamine groups decorated with azophenyl fragments:
 synthesis, crystalline assembly and slow magnetic relaxation behavior.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9584
_journal_page_last               9593
_journal_paper_doi               10.1039/d5dt00936g
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C74 H82 N6 O6'
_chemical_formula_sum            'C74 H82 N6 O6'
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_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2025-03-06 deposited with the CCDC.	2025-05-12 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      105(2)
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 QUEST'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_source                   'I\mS DIAMOND'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0681P)^2^+8.0098P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1918
_refine_ls_wR_factor_ref         0.2091
_reflns_Friedel_coverage         0.000
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_reflns_number_total             9325
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7718685--7718686.cif.'
_cod_original_cell_volume        3162.5(6)
_cod_database_code               7718685
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