Four μ4-oxo-bridged copper(ii) complexes: magnetic properties and catalytic applications in liquid phase partial oxidation reactions
Roy, Partha; Nandi, Mahasweta; Manassero, Mario; Riccó, Mauro; Mazzani, Marcello; Bhaumik, Asim; Banerjee, Pradyot; Dalton Transactions  (2009) 9543–9554; doi:10.1039/b913556a

data_7002670
_publ_section_title
;
 Four \m4-oxo-bridged copper(ii) complexes: magnetic properties and
 catalytic applications in liquid phase partial oxidation reactions
;
_journal_issue                   43
_journal_name_full               'Dalton Transactions'
_journal_page_first              9543
_journal_page_last               9554
_journal_paper_doi               10.1039/b913556a
_journal_year                    2009
_chemical_formula_sum            'C58 H50 Cu4 F12 N4 O11'
_chemical_formula_weight         1461.21
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_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
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_audit_creation_date             07-11-13
_audit_creation_method           'from The Personal SDP version 2.1.1'
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_cell_angle_beta                 96.640(1)
_cell_angle_gamma                95.800(1)
_cell_formula_units_Z            2
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_cell_length_c                   17.0077(10)
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_computing_data_reduction        'SAINT (Bruker)'
_computing_structure_refinement
' Full-matrix least-squares (The Personal SDP, 1991)'
_computing_structure_solution
' SHELXS-86 (Sheldrick, 1986) as implemented in The Personal SDP'
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_diffrn_radiation_detector       'SMART CCD area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           Mo-K\a
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_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_reduction_process SAINT
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_diffrn_reflns_theta_min         3.00
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_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   ' SADABS'
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_exptl_crystal_description       prism
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_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.150
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_refine_diff_density_min         -1.036
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_refine_ls_structure_factor_coef Fsqd
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_r_int                           0.0314
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_time_per_frame_seconds          25
_frame_width_degrees             0.30
_detector_sample_distance_cm     6.00
_conventional_r1_(i>2\s(i))      0.048
_reflections_with_i>2\s(i)       7998
_refine_diff_density_esd         0.271