[(<i>E</i>)-Oxido(pyridin-2-ylmethylidene)amine-κ^2^<i>N</i>,<i>N</i>'][(<i>E</i>)-<i>N</i>-(pyridin-2-ylmethylidene)hydroxylamine-κ^2^<i>N</i>,<i>N</i>']silver(I) perchlorate‒bis[(<i>E</i>)-<i>N</i>-(pyridin-2-ylmethylidene)hydroxylamine-κ^2^<i>N</i>,<i>N</i>']silver(I) (1/1)
Xu, Jing; Gao, Shan; Ng, Seik Weng; Tiekink, Edward R. T.; Acta Crystallographica Section E 68 (2012) m639–m640; doi:10.1107/S160053681201625X

data_2234643
_publ_section_title
;
 [(<i>E</i>)-Oxido(pyridin-2-ylmethylidene)amine-\k^2^<i>N</i>,<i>N</i>'][(<i>E</i>)-<i>N</i>-(pyridin-2-ylmethylidene)hydroxylamine-\k^2^<i>N</i>,<i>N</i>']silver(I)
 perchlorate--bis[(<i>E</i>)-<i>N</i>-(pyridin-2-ylmethylidene)hydroxylamine-\k^2^<i>N</i>,<i>N</i>']silver(I)
 (1/1)
;
_journal_coeditor_code           HB6736
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m639
_journal_page_last               m640
_journal_paper_doi               10.1107/S160053681201625X
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac
'[Ag (C6 H5 N2 O) (C6 H6 N2 O)] Cl O4, [Ag (C6 H6 N2 O)2]'
_chemical_formula_moiety         'C12 H11 Ag N4 O2, C12 H12 Ag N4 O2, Cl O4 '
_chemical_formula_sum            'C24 H23 Ag2 Cl N8 O8'
_chemical_formula_weight         802.69
_chemical_name_systematic
;
[(<i>E</i>)-Oxido(pyridin-2-ylmethylidene)amine-
\k^2^<i>N</i>,<i>N</i>'][(<i>E</i>)-<i>N</i>-(pyridin-2-
ylmethylidene)hydroxylamine-\k^2^<i>N</i>,<i>N</i>']silver(I) perchlorate--
bis[(<i>E</i>)-<i>N</i>-(pyridin-2-ylmethylidene)hydroxylamine-
\k^2^<i>N</i>,<i>N</i>']silver(I) (1/1)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.226(6)
_cell_angle_beta                 92.753(6)
_cell_angle_gamma                114.409(6)
_cell_formula_units_Z            2
_cell_length_a                   7.3925(18)
_cell_length_b                   8.3419(19)
_cell_length_c                   25.626(6)
_cell_measurement_reflns_used    7282
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.41
_cell_measurement_theta_min      3.03
_cell_volume                     1436.9(6)
_computing_cell_refinement       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_collection       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC and Rigaku, 2002)'
_computing_molecular_graphics
;
X-SEED (Barbour, 2001) and DIAMOND (Brandenburg, 2006)
;
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID IP'
_diffrn_measurement_method       '\w scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0460
_diffrn_reflns_av_sigmaI/netI    0.0599
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            11387
_diffrn_reflns_theta_full        24.99
_diffrn_reflns_theta_max         24.99
_diffrn_reflns_theta_min         3.03
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.518
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.3564
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.855
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             796
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.13
_refine_diff_density_max         1.185
_refine_diff_density_min         -0.576
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     430
_refine_ls_number_reflns         5042
_refine_ls_number_restraints     64
_refine_ls_restrained_S_all      1.092
_refine_ls_R_factor_all          0.0767
_refine_ls_R_factor_gt           0.0589
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0985P)^2^+1.2590P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1571
_refine_ls_wR_factor_ref         0.1869
_reflns_number_gt                3660
_reflns_number_total             5042
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb6736.cif
_cod_data_source_block           I
_cod_database_code               2234643
_cod_database_fobs_code          2234643