Rhodium(III)-catalyzed olefinic C-H alkynylation of acrylamides using tosyl-imide as directing group.
Feng, Chao; Feng, Daming; Luo, Yang; Loh, Teck-Peng; Organic letters 16 (2014) 5956–5959; doi:10.1021/ol502984g

data_1518262
_publ_section_title
;
 Rhodium(III)-catalyzed olefinic C-H alkynylation of acrylamides using
 tosyl-imide as directing group.
;
_journal_issue                   22
_journal_name_full               'Organic letters'
_journal_page_first              5956
_journal_page_last               5959
_journal_paper_doi               10.1021/ol502984g
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'C28 H37 N O4 S Si'
_chemical_formula_weight         511.73
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_diffrn_ambient_temperature      103.(2)
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_diffrn_radiation_monochromator  graphite
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_exptl_crystal_colour            colourless
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_refine_ls_number_reflns         7017
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_refine_ls_R_factor_all          0.1590
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1231P)^2^+6.8454P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 1518262.cif.'
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