Manganese-Catalyzed Environmentally Benign Dehydrogenative Coupling of Alcohols and Amines to Form Aldimines and H2: A Catalytic and Mechanistic Study.
Mukherjee, Arup; Nerush, Alexander; Leitus, Gregory; Shimon, Linda J. W.; Ben David, Yehoshoa; Espinosa Jalapa, Noel Angel; Milstein, David; Journal of the American Chemical Society 138 (2016) 4298–4301; doi:10.1021/jacs.5b13519

data_4130067
_publ_section_title
;
 Manganese-Catalyzed Environmentally Benign Dehydrogenative Coupling of
 Alcohols and Amines to Form Aldimines and H2: A Catalytic and Mechanistic
 Study.
;
_journal_issue                   13
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              4298
_journal_page_last               4301
_journal_paper_doi               10.1021/jacs.5b13519
_journal_volume                  138
_journal_year                    2016
_chemical_formula_moiety         'C32 H50 Mn N O3 P2'
_chemical_formula_sum            'C32 H50 Mn N O3 P2'
_chemical_formula_weight         613.61
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
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_cell_measurement_temperature    100(2)
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXT-2014/7 (Sheldrick, 2014)'
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_diffrn_reflns_Laue_measured_fraction_full 0.997
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_exptl_absorpt_process_details   'Bruker Apex2'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0310P)^2^+4.7448P] where P=(Fo^2^+2Fc^2^)/3'
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_shelx_estimated_absorpt_t_min   0.908
_shelx_estimated_absorpt_t_max   0.973
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'77840 ---------------------------------------------------------------------------------------------------- 4:'