The smaller, the better? How the aggregate size affects the reactivity of (trimethylsilyl)methyllithium.
Knauer, Lena; Wattenberg, Jonathan; Kroesen, Ulrike; Strohmann, Carsten; Dalton transactions (Cambridge, England : 2003) 48 (2019) 11285–11291; doi:10.1039/c9dt02182e

data_7700251
_publ_section_title
;
 The smaller, the better? How the aggregate size affects the reactivity of
 (trimethylsilyl)methyllithium.
;
_journal_issue                   30
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11285
_journal_page_last               11291
_journal_paper_doi               10.1039/c9dt02182e
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C22 H48 Li2 N2 Si2'
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Air-sensitive,Moisture-sensitive,Oxygen-sensitive
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_space_group_name_Hall           '-C 2yc'
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_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
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Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
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2019-04-09 deposited with the CCDC.    2019-06-12 downloaded from the CCDC.
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_diffrn_source                   'microfocus sealed X-ray tube'
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'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1337 before and 0.0800 after correction. The Ratio of minimum to maximum transmission is 0.8345. The \l/2 correction factor is Not present.'
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'Re-crystallisation from solvent: n-pentane'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0765P)^2^+0.8451P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7700249--7700251.cif.'
_cod_original_cell_volume        2667.6(6)
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_olex2_refinement_description
;
;
_olex2_submission_special_instructions 'No special instructions were received'