Interaction of dicoordinate phosphorus with boranes: chemistry of 3a,6a-diaza-1,4-diphosphapentalene as masked phosphinidene.
Panova, Yulia; Khristolyubova, Alexandra; Zolotareva, Natalia; Sushev, Vyacheslav; Galperin, Vadim; Rumyantcev, Roman; Fukin, Georgy; Kornev, Alexander; Dalton transactions (Cambridge, England : 2003) 50 (2021) 5890–5898; doi:10.1039/d1dt00747e

data_7707078
_publ_section_title
;
 Interaction of dicoordinate phosphorus with boranes: chemistry of
 3a,6a-diaza-1,4-diphosphapentalene as masked phosphinidene.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5890
_journal_page_last               5898
_journal_paper_doi               10.1039/d1dt00747e
_journal_volume                  50
_journal_year                    2021
_chemical_absolute_configuration unk
_chemical_formula_moiety         'C24 H26 B2 Cl4 N2 P2'
_chemical_formula_sum            'C24 H26 B2 Cl4 N2 P2'
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_space_group_IT_number           33
_space_group_name_Hall           'P 2c -2n'
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;
2020-06-29 deposited with the CCDC.	2021-04-08 downloaded from the CCDC.
;
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_diffrn_source                   'microfocus tube'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
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_exptl_crystal_description       stick
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;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.5(2)
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_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0636
_refine_ls_R_factor_gt           0.0588
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0130P)^2^+13.2500P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1304
_refine_ls_wR_factor_ref         0.1326
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_reflns_Friedel_fraction_max     0.998
_reflns_number_gt                6038
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1dt00747e2.cif
_cod_data_source_block           pnnpbphcl2
_cod_depositor_comments
'Adding full bibliography for 7707078--7707081.cif.'
_cod_database_code               7707078
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_shelx_res_checksum              14290
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