Redox-induced reversible metal assembly through translocation and reversible ligand coupling in tetranuclear metal sandwich frameworks.
Murahashi, Tetsuro; Shirato, Katsunori; Fukushima, Azusa; Takase, Kohei; Suenobu, Tomoyoshi; Fukuzumi, Shunichi; Ogoshi, Sensuke; Kurosawa, Hideo; Nature chemistry 4 (2012) 52–58; doi:10.1038/nchem.1202

data_1508168
_publ_section_title
;
 Redox-induced reversible metal assembly through translocation and
 reversible ligand coupling in tetranuclear metal sandwich frameworks.
;
_journal_issue                   1
_journal_name_full               'Nature chemistry'
_journal_page_first              52
_journal_page_last               58
_journal_paper_doi               10.1038/nchem.1202
_journal_volume                  4
_journal_year                    2012
_chemical_formula_moiety         'C63 H61 B4 F16 N3 O6 Pd4'
_chemical_formula_sum            'C63 H61 B4 F16 N3 O6 Pd4'
_chemical_formula_weight         1729.01
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.0000
_cell_angle_beta                 104.0230(11)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   26.6501(11)
_cell_length_b                   11.2467(4)
_cell_length_c                   21.7172(8)
_cell_measurement_reflns_used    46567
_cell_measurement_temperature    123
_cell_measurement_theta_max      27.47
_cell_measurement_theta_min      3.06
_cell_volume                     6315.2(4)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_data_reduction        'RAPID AUTO'
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_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
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_computing_structure_solution    'DIRDIF99-PATTY (Gould, et al., 1999)'
_diffrn_ambient_temperature      123
_diffrn_detector_area_resol_mean 10.000
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0358
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -34
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_exptl_crystal_density_method    'not measured'
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details
;
    Chebychev polynomial with 3 parameters (Carruthers & Watkin, 1979)
    2.9905    0.5425    2.1793
;
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