Iodine monobromide catalysed regioselective synthesis of 3-arylquinolines from α-aminoacetophenones and trans-β-nitrostyrenes.
Gattu, Radhakrishna; Mondal, Santa; Ali, Saghir; Khan, Abu T.; Organic & biomolecular chemistry 17 (2019) 347–353; doi:10.1039/c8ob02333f

data_7156599
_publ_section_title
;
 Iodine monobromide catalysed regioselective synthesis of 3-arylquinolines
 from \a-aminoacetophenones and trans-\b-nitrostyrenes.
;
_journal_issue                   2
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              347
_journal_page_last               353
_journal_paper_doi               10.1039/c8ob02333f
_journal_volume                  17
_journal_year                    2019
_chemical_formula_sum            'C16 H12 Br N'
_chemical_formula_weight         298.18
_chemical_name_systematic        3-arylquinoline
_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           '-P 2n 2ab'
_space_group_name_H-M_alt        'P b c n'
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
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;
2018-04-05 deposited with the CCDC.
2018-12-04 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'CCD area detector'
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_diffrn_reflns_theta_max         25.050
_diffrn_reflns_theta_min         2.940
_exptl_absorpt_coefficient_mu    3.157
_exptl_crystal_colour            brown
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_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: acetonitrile'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0100P)^2^+0.0900P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                911
_reflns_number_total             2283
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8ob02333f2.cif
_cod_data_source_block           exp_4183
_cod_depositor_comments          'Adding full bibliography for 7156599.cif.'
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_cod_database_code               7156599
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