Fluorinated antimony(v) derivatives: strong Lewis acidic properties and application to the complexation of formaldehyde in aqueous solutions
Tofan, Daniel; Gabbaï, François P.; Chem. Sci. 7 (2016) 6768–; doi:10.1039/C6SC02558G

data_1543647
_publ_section_title
;
 Fluorinated antimony(v) derivatives: strong Lewis acidic properties and
 application to the complexation of formaldehyde in aqueous solutions
;
_journal_issue                   11
_journal_name_full               'Chem. Sci.'
_journal_page_first              6768
_journal_paper_doi               10.1039/C6SC02558G
_journal_volume                  7
_journal_year                    2016
_chemical_formula_sum            'C74.5 H53 Cl13 O4 P2 Sb2'
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_chemical_name_systematic
; 
 ? 
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_audit_update_record
;
2016-06-03 deposited with the CCDC.
2016-07-11 downloaded from the CCDC.
;
_cell_angle_alpha                105.844(3)
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
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_diffrn_reflns_theta_max         28.28
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_exptl_absorpt_correction_T_min  0.8594
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_exptl_crystal_colour            yellow
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_exptl_crystal_density_method    'not measured'
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0522P)^2^+2.9152P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0975
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_reflns_number_gt                13100
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6sc02558g2.cif
_cod_data_source_block           p-1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 1543644--1543652.cif.
;
_cod_original_cell_volume        3668.4(10)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1543647