An Organometalllic NiIV Complex That Participates in Competing Transmetalation and C(sp2)‒O Bond-Forming Reductive Elimination Reactions
Meucci, Elizabeth A.; Camasso, Nicole M.; Sanford, Melanie S.; Organometallics 36 (2017) 247–; doi:10.1021/acs.organomet.6b00810

data_4086845
_publ_section_title
;
 An Organometalllic NiIV Complex That Participates in Competing
 Transmetalation and C(sp2)--O Bond-Forming Reductive Elimination
 Reactions
;
_journal_issue                   2
_journal_name_full               Organometallics
_journal_page_first              247
_journal_paper_doi               10.1021/acs.organomet.6b00810
_journal_volume                  36
_journal_year                    2017
_chemical_formula_moiety         'C23 H18 B F3 N6 Ni O2'
_chemical_formula_sum            'C23 H18 B F3 N6 Ni O2'
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_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
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'CrystalClear-SM Expert 2.0 r16 (Rigaku, 2014)'
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_diffrn_measurement_device_type  'Rigaku Saturn 944+ CCD'
_diffrn_measurement_method       '\w scans'
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; 
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015) 
Empirical absorption correction using spherical harmonics, 
 implemented in SCALE3 ABSPACK scaling algorithm. 
;
_exptl_crystal_colour            yellow
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'w=1/[\s^2^(Fo^2^)+(0.1672P)^2^+9.6531P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_total             4297
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 4086845.cif.'
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