Palladium-Assisted Regioselective Olefin Insertion into and -Hydrogen Elimination of Hydrogen-Molybdenum and -Tungsten Bonds. Synthesis and Reactions of Heterodinuclear Hydrido Complexes of Palladium and Platinum with Molybdenum and Tungsten
Ayako Kuramoto; Kouhei Nakanishi; Tatsuya Kawabata; Nobuyuki Komine; Masafumi Hirano; Sanshiro Komiya; Organometallics 25 (2006) 311–314; doi:10.1021/om0506872

data_4063312
_publ_section_title
;
 Palladium-Assisted Regioselective Olefin Insertion into and -Hydrogen
 Elimination of Hydrogen-Molybdenum and -Tungsten Bonds. Synthesis and
 Reactions of Heterodinuclear Hydrido Complexes of Palladium and
 Platinum with Molybdenum and Tungsten
;
_journal_issue                   2
_journal_name_full               Organometallics
_journal_page_first              311
_journal_page_last               314
_journal_paper_doi               10.1021/om0506872
_journal_volume                  25
_journal_year                    2006
_chemical_formula_sum            'C36 H34 Mo O3 P2 Pt'
_chemical_formula_weight         867.64
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 99.16(4)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   14.755(9)
_cell_length_b                   26.58(1)
_cell_length_c                   20.482(7)
_cell_measurement_reflns_used    11
_cell_measurement_temperature    240.2
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.9
_cell_volume                     7930(6)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 0.9891
_diffrn_measured_fraction_theta_max 0.9891
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.062
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            19160
_diffrn_reflns_theta_full        27.51
_diffrn_reflns_theta_max         27.51
_diffrn_standards_decay_%        34.72
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.935
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_correction_T_min  0.652
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.453
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_refine_diff_density_max         2.14
_refine_diff_density_min         -1.43
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.159
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     660
_refine_ls_number_reflns         5647
_refine_ls_R_factor_gt           0.0725
_refine_ls_shift/su_max          0.0021
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00766|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1150
_reflns_number_gt                5647
_reflns_number_total             18056
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_original_formula_sum        'C36 H34 Mo O3 P2 Pt '
_cod_database_code               4063312