Regioselective B(3)-H bond activation based on an o-carboranyl dithiocarboxylate ligand and its derivatives.
Yuan, Run-Ze; Cui, Peng-Fei; Guo, Shu-Ting; Jin, Guo-Xin; Dalton transactions (Cambridge, England : 2003) 50 (2021) 1060–1068; doi:10.1039/d0dt03832f

data_7705936
_publ_section_title
;
 Regioselective B(3)-H bond activation based on an o-carboranyl
 dithiocarboxylate ligand and its derivatives.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1060
_journal_page_last               1068
_journal_paper_doi               10.1039/d0dt03832f
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C16 H37 B20 Rh S4'
_chemical_formula_weight         676.80
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2020-11-04 deposited with the CCDC.	2020-12-08 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_diffrn_reflns_limit_h_max       15
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_exptl_absorpt_correction_T_max  0.754
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_R_factor_all          0.0725
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0790P)^2^+33.1617P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1766
_refine_ls_wR_factor_ref         0.1770
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6595
_reflns_number_total             6717
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt03832f2.cif
_cod_data_source_block           cu_200808a_a
_cod_depositor_comments
'Adding full bibliography for 7705931--7705941.cif.'
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_cod_database_code               7705936
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.180
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_shelx_res_checksum              66012