Syntheses and Physical Properties of Quasi-One-Dimensional Halogen-Bridged CuII-PtIV Mixed-Metal Complexes [Cu(chxn)2][PtX2(chxn)2]X4
Takuya Kawashima; Kenzi Takai; Hidemitsu Aso; Toshio Manabe; Kouichi Takizawa; Chihiro Kachi-Terajima; Tomohiko Ishii; Hitoshi Miyasaka; Hiroyuki Matsuzaka; Masahiro Yamashita; Hiroshi Okamoto; Hiroshi Kitagawa; Motoo Shiro; Koshiro Toriumi; Inorganic Chemistry 40 (2001) 6651–6655; doi:10.1021/ic010341t

data_4320687
_publ_section_title
;
 Syntheses and Physical Properties of Quasi-One-Dimensional
 Halogen-Bridged CuII-PtIV Mixed-Metal Complexes
 [Cu(chxn)2][PtX2(chxn)2]X4
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6651
_journal_page_last               6655
_journal_paper_doi               10.1021/ic010341t
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C12 H28 Br3 Cu0.5 N4 Pt0.5'
_chemical_formula_weight         597.41
_space_group_IT_number           23
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      23
_symmetry_space_group_name_Hall  'I 2 2'
_symmetry_space_group_name_H-M   'I 2 2 2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   6.978(4)
_cell_length_b                   23.700(8)
_cell_length_c                   5.344(5)
_cell_measurement_temperature    123.2
_cell_volume                     883.8(10)
_computing_cell_refinement       'PROCESS (Rigaku, 1996)'
_computing_data_collection       'PROCESS (Rigaku, 1996)'
_computing_data_reduction        'teXsan (MSC & Rigaku, 1999)'
_computing_molecular_graphics    'ORTEP (Johnson, 1976)'
_computing_publication_material  'teXsan (MSC & Rigaku, 1999)'
_computing_structure_refinement  'teXsan (MSC & Rigaku, 1999)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9484
_diffrn_measured_fraction_theta_max 0.9484
_diffrn_measurement_device_type  'Rigaku RAXIS-IV Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.032
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -6
_diffrn_reflns_number            610
_diffrn_reflns_theta_full        27.53
_diffrn_reflns_theta_max         27.53
_exptl_absorpt_coefficient_mu    11.370
_exptl_absorpt_correction_T_max  0.403
_exptl_absorpt_correction_T_min  0.115
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Higashi, 1995)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.245
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.080
_refine_diff_density_max         1.59
_refine_diff_density_min         -2.02
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     50
_refine_ls_number_reflns         587
_refine_ls_R_factor_gt           0.0370
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.03700(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0980
_reflns_number_gt                571
_reflns_number_total             589
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic010341t_1.cif
_cod_data_source_block           XR0061raxlt_Nagoya_Univ._(
_cod_original_cell_volume        883.8(8)
_cod_original_sg_symbol_H-M      'I 2 2 2 '
_cod_original_formula_sum        'C12 H28 Br3 Cu0.50 N4 Pt0.50 '
_cod_database_code               4320687