Catalytic Silylation of Dinitrogen by a Family of Triiron Complexes.
Ferreira, Ricardo B.; Cook, Brian J.; Knight, Brian J.; Catalano, Vincent J.; García-Serres, Ricardo; Murray, Leslie J.; ACS catalysis 8 (2018) 7208–7212; doi:10.1021/acscatal.8b02021

data_4515558
_publ_section_title
;
 Catalytic Silylation of Dinitrogen by a Family of Triiron Complexes.
;
_journal_issue                   8
_journal_name_full               'ACS catalysis'
_journal_page_first              7208
_journal_page_last               7212
_journal_paper_doi               10.1021/acscatal.8b02021
_journal_volume                  8
_journal_year                    2018
_chemical_formula_sum            'C57 H75 Cl3 Fe3 N6'
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   geom
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_cell_length_c                   16.6470(6)
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_cell_measurement_temperature    100(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
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_refine_ls_R_factor_all          0.1038
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0480P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_shelx_res_checksum              71247
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