An orbitally adapted push-pull template for N<sub>2</sub> activation and reduction to diazene-diide.
Specklin, David; Boegli, Marie-Christine; Coffinet, Anaïs; Escomel, Léon; Vendier, Laure; Grellier, Mary; Simonneau, Antoine; Chemical science 14 (2023) 14262–14270; doi:10.1039/d3sc04390h

data_1570357
_publ_section_title
;
 An orbitally adapted push-pull template for N<sub>2</sub> activation and
 reduction to diazene-diide.
;
_journal_issue                   48
_journal_name_full               'Chemical science'
_journal_page_first              14262
_journal_page_last               14270
_journal_paper_doi               10.1039/d3sc04390h
_journal_volume                  14
_journal_year                    2023
_chemical_formula_moiety         'C50 H50 B2 F24 N2 P4 W'
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_audit_update_record
;
2023-07-31 deposited with the CCDC.	2023-11-21 downloaded from the CCDC.
;
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_exptl_absorpt_process_details
;
        [c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            yellow
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_exptl_crystal_description       plate
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0239P)^2^+6.7315P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0525
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                10270
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3sc04390h2.cif
_cod_data_source_block           DSN210521
_cod_depositor_comments
'Adding full bibliography for 1570353--1570357.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1570357
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