Synthetic investigations of low-coordinate (N-phosphino-amidinate) nickel chemistry: agostic alkyl complexes and benzene insertion into Ni-H.
Macaulay, Casper M.; Samolia, Madhu; Ferguson, Michael J.; Sydora, Orson L.; Ess, Daniel H.; Stradiotto, Mark; Turculet, Laura; Dalton transactions (Cambridge, England : 2003) 49 (2020) 4811–4816; doi:10.1039/d0dt00527d

data_7703812
_publ_section_title
;
 Synthetic investigations of low-coordinate (N-phosphino-amidinate) nickel
 chemistry: agostic alkyl complexes and benzene insertion into Ni-H.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4811
_journal_page_last               4816
_journal_paper_doi               10.1039/d0dt00527d
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C32 H51 N2 Ni P'
_chemical_formula_sum            'C32 H51 N2 Ni P'
_chemical_formula_weight         553.42
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2019-08-30 deposited with the CCDC.	2020-03-19 downloaded from the CCDC.
;
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_computing_cell_refinement       'Bruker SAINT'
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_computing_publication_material  'Bruker SHELXTL'
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_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_point_group_measured_fraction_full 0.982
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_exptl_absorpt_process_details
; 
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D., 
 J. Appl. Cryst. 48 (2015) 3-10 
;
_exptl_crystal_colour            orange
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0253P)^2^+0.9953P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7703811--7703812.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
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