Alkyl and Hydrido Complexes of Platinum(IV) Supported by the Bis(8-quinolyl)methylsilyl Ligand
Sangtrirutnugul, Preeyanuch; Tilley, T. Don; Organometallics 27 (2008) 2223–; doi:10.1021/om701162h

data_4070971
_publ_section_title
;
 Alkyl and Hydrido Complexes of Platinum(IV) Supported by the
 Bis(8-quinolyl)methylsilyl Ligand
;
_journal_issue                   10
_journal_name_full               Organometallics
_journal_page_first              2223
_journal_paper_doi               10.1021/om701162h
_journal_volume                  27
_journal_year                    2008
_chemical_formula_moiety         'C22 H21 F3 N2 O3 Pt S Si '
_chemical_formula_sum            'C22 H21 F3 N2 O3 Pt S Si'
_chemical_formula_weight         673.65
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             'Wed Mar 28 19:07:24 2007'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90
_cell_angle_beta                 113.369(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.4120(7)
_cell_length_b                   13.1627(7)
_cell_length_c                   14.2154(8)
_cell_measurement_reflns_used    4792
_cell_measurement_temperature    140.2
_cell_measurement_theta_max      25.6
_cell_measurement_theta_min      1.8
_cell_volume                     2303.7(2)
_computing_cell_refinement       'Bruker-AXS SAINT v6.40'
_computing_data_collection       'Bruker-AXS SMART v5.054'
_computing_data_reduction        'Bruker-AXS SAINT v6.40'
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    SIR97
_diffrn_measured_fraction_theta_full 0.8936
_diffrn_measured_fraction_theta_max 0.8936
_diffrn_measurement_device_type  'Bruker SMART 1000'
_diffrn_measurement_method       \w-scans
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.067
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            10352
_diffrn_reflns_theta_full        25.60
_diffrn_reflns_theta_max         25.60
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.261
_exptl_absorpt_correction_T_max  0.630
_exptl_absorpt_correction_T_min  0.380
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.942
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1304.00
_exptl_crystal_size_max          0.260
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.81
_refine_diff_density_min         -1.46
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.232
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     298
_refine_ls_number_reflns         2787
_refine_ls_R_factor_all          0.0270
_refine_ls_R_factor_gt           0.0270
_refine_ls_shift/su_max          0.0008
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00022|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0298
_refine_ls_wR_factor_ref         0.0298
_reflns_number_gt                2787
_reflns_number_total             4067
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            om701162h-file001.cif
_cod_data_source_block           Nuch15
_cod_original_sg_symbol_Hall     '-P 2yn     '
_cod_original_sg_symbol_H-M      'P 21/n     '
_cod_original_formula_sum        'C22 H21 F3 N2 O3 Pt S Si '
_cod_database_code               4070971