From molecular germanates to microporous Ge@C via twin polymerization.
Kitschke, Philipp; Walter, Marc; Rüffer, Tobias; Lang, Heinrich; Kovalenko, Maksym V.; Mehring, Michael; Dalton transactions (Cambridge, England : 2003) 45 (2016) 5741–5751; doi:10.1039/c6dt00049e

data_7038574
_publ_section_title
;
 From molecular germanates to microporous Ge@C via twin polymerization.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5741
_journal_page_last               5751
_journal_paper_doi               10.1039/c6dt00049e
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety
'8(C24 H24 Ge O6), C2 H4 Cl4, 15(C H2 Cl2), 16(C2 H8 N)'
_chemical_formula_sum            'C241 H354 Cl34 Ge8 N16 O48'
_chemical_formula_weight         6029.40
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 ?
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2015-12-07 deposited with the CCDC.
2016-02-24 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
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_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.387
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_refine_ls_extinction_method     none
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_refine_ls_number_restraints     15
_refine_ls_restrained_S_all      1.037
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0606P)^2^+17.9385P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1280
_refine_ls_wR_factor_ref         0.1349
_reflns_Friedel_coverage         0.000
_reflns_number_gt                20742
_reflns_number_total             25388
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt00049e2.cif
_cod_data_source_block           shelx
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'Adding full bibliography for 7038574--7038576.cif.'
_cod_database_code               7038574
_shelxl_version_number           2013-4
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