Ti(II) and Rh(I) Complexes as Reagents toward a Thapsigargin Core.
Sanogo, Youssouf; Othman, Raja Ben; Dhambri, Sabrina; Selkti, Mohamed; Jeuken, Alan; Prunet, Joëlle; Férézou, Jean-Pierre; Ardisson, Janick; Lannou, Marie-Isabelle; Sorin, Geoffroy; The Journal of organic chemistry 84 (2019) 5821–5830; doi:10.1021/acs.joc.8b03249

data_4034344
_publ_section_title
;
 Ti(II) and Rh(I) Complexes as Reagents toward a Thapsigargin Core.
;
_journal_issue                   9
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              5821
_journal_page_last               5830
_journal_paper_doi               10.1021/acs.joc.8b03249
_journal_volume                  84
_journal_year                    2019
_chemical_formula_moiety         'C15 H22 O5'
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_cell_angle_gamma                90
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_cell_length_c                   25.876(3)
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_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
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_diffrn_reflns_limit_k_min       -9
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_exptl_absorpt_coefficient_mu    0.753
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_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.224
_exptl_crystal_description       Prism
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_exptl_crystal_size_max          0.20
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_exptl_crystal_size_min          0.20
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0993P)^2^+3.4194P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1973
_refine_ls_wR_factor_ref         0.2378
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1558
_reflns_number_total             2577
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            jo8b03249_si_002.cif
_cod_data_source_block           9b
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        3064.5(3)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4034344
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_shelx_res_checksum              50552
_shelx_hkl_checksum              22964