Two coordination polymers constructed from a multidentate carboxylic acid ligand with a tertiary amine serve as acid-base catalysts for the synthesis of chloropropene carbonate from CO2 under atmospheric pressure.
Chen, Chao; Zhang, Jun; Li, Guanghua; Shen, Pan; Jin, Haichao; Zhang, Ning; Dalton transactions (Cambridge, England : 2003) 43 (2014) 13965–13971; doi:10.1039/c4dt00908h

data_7031779
_publ_section_title
;
 Two coordination polymers constructed from a multidentate carboxylic acid
 ligand with a tertiary amine serve as acid-base catalysts for the
 synthesis of chloropropene carbonate from CO2 under atmospheric pressure.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13965
_journal_page_last               13971
_journal_paper_doi               10.1039/c4dt00908h
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C15 H17 N1 Ni O9, C3 H7 N1 O1'
_chemical_formula_sum            'C18 H24 N2 Ni O10'
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_chemical_name_systematic
; 
 ? 
;
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_symmetry_space_group_name_Hall  '-C 2c 2'
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_cell_measurement_temperature    296(2)
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_cell_volume                     2050.28(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
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_computing_molecular_graphics    SHELXP-97
_computing_publication_material  SHELXP-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.998
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_diffrn_radiation_monochromator  graphite
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_exptl_absorpt_coefficient_mu    1.006
_exptl_absorpt_correction_T_max  0.9018
_exptl_absorpt_correction_T_min  0.7857
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.578
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
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_refine_diff_density_max         0.723
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1042P)^2^+2.4986P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1200
_refine_ls_wR_factor_ref         0.1422
_reflns_number_gt                1172
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt00908h2.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

'_symmetry_cell_setting' value
'Orthorhombic' changed to 'orthorhombic' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 7031778--7031779.cif.

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      Cmcm
_cod_database_code               7031779