Ligand substituents modulate excited-state lifetime and energy-transfer reactivity in Cu(i) photosensitizers supported by salicylaldimine and isocyanide ligands.
Chakraborty, Soumi; Agyekum, Kianna; Kim, Dooyoung; Teets, Thomas S.; Chemical science 16 (2025) 22527–22535; doi:10.1039/d5sc07286g

data_1576082
_publ_section_title
;
 Ligand substituents modulate excited-state lifetime and energy-transfer
 reactivity in Cu(i) photosensitizers supported by salicylaldimine and
 isocyanide ligands.
;
_journal_issue                   47
_journal_name_full               'Chemical science'
_journal_page_first              22527
_journal_page_last               22535
_journal_paper_doi               10.1039/d5sc07286g
_journal_volume                  16
_journal_year                    2025
_chemical_formula_sum            'C24 H17 Cu F6 N2 O'
_chemical_formula_weight         526.93
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2025-05-23 deposited with the CCDC.	2025-10-17 downloaded from the CCDC.
;
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_cell_angle_gamma                73.694(6)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_av_R_equivalents  0.0331
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_exptl_absorpt_coefficient_mu    1.043
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0604P)^2^+1.2835P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1038
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5sc07286g9.cif
_cod_data_source_block           Cu2
_cod_depositor_comments
'Adding full bibliography for 1576081--1576086.cif.'
_cod_database_code               1576082
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