Preparation and reactivity of half-sandwich organic azide complexes of osmium.
Albertin, Gabriele; Antoniutti, Stefano; Castro, Jesús; Ganz, Verena; Sibilla, Francesca; Dalton transactions (Cambridge, England : 2003) 47 (2018) 11658–11668; doi:10.1039/c8dt02230e

data_7047246
_publ_section_title
;
 Preparation and reactivity of half-sandwich organic azide complexes of
 osmium.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11658
_journal_page_last               11668
_journal_paper_doi               10.1039/c8dt02230e
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety
'C52 H58 N2 O6 Os2 P4, 2(C24 H20 B), 2(C H2 Cl2)'
_chemical_formula_sum            'C102 H102 B2 Cl4 N2 O6 Os2 P4'
_chemical_formula_weight         2119.55
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-05-30 deposited with the CCDC.
2018-08-03 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 Venture Photon 100 CMOS'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  'Incoatec HeliosTM multilayer optics'
_diffrn_radiation_source         'Incoatec high brillance I\muS microsource'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_min         2.222
_exptl_absorpt_coefficient_mu    3.062
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6693
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS-2016/2 (Bruker AXS Inc.)'
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         11224
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_refine_ls_restrained_S_all      1.094
_refine_ls_R_factor_all          0.0364
_refine_ls_R_factor_gt           0.0326
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0387P)^2^+10.7990P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0849
_refine_ls_wR_factor_ref         0.0867
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10461
_reflns_number_total             11224
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt02230e2.cif
_cod_data_source_block           vv69_a
_cod_depositor_comments          'Adding full bibliography for 7047246.cif.'
_cod_original_cell_volume        2254.3(6)
_cod_database_code               7047246
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.781
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_shelx_res_checksum              65073