Easily reduced bis-pincer (NS<sub>2</sub>)<sub>2</sub>molybdenum(iv) to (NHS<sub>2</sub>)<sub>2</sub>Mo(ii) by alcohols vs. redox-inert (NS<sub>2</sub>)(NHS<sub>2</sub>)iron(iii) complexes.
Robles-Marín, Elvis; Mondragón, Alexander; Martínez-Alanis, Paulina R; Aullón, Gabriel; Flores-Alamo, Marcos; Castillo, Ivan; Dalton transactions (Cambridge, England : 2003) 47 (2018) 10932–10940; doi:10.1039/c8dt01562g

data_7046792
_publ_section_title
;
 Easily reduced bis-pincer (NS<sub>2</sub>)<sub>2</sub>molybdenum(iv) to
 (NHS<sub>2</sub>)<sub>2</sub>Mo(ii) by alcohols vs. redox-inert
 (NS<sub>2</sub>)(NHS<sub>2</sub>)iron(iii) complexes.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10932
_journal_page_last               10940
_journal_paper_doi               10.1039/c8dt01562g
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C72 H58 F24 Mo N2 S4'
_chemical_formula_sum            'C72 H58 F24 Mo N2 S4'
_chemical_formula_weight         1631.38
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4.3
_audit_creation_date             2017-05-11T18:37:08-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2017-06-02 deposited with the CCDC.
2018-06-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 97.138(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.7875(5)
_cell_length_b                   13.7818(7)
_cell_length_c                   23.5674(10)
_cell_measurement_reflns_used    5180
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      29.4455
_cell_measurement_theta_min      3.3767
_cell_volume                     3476.6(3)
_computing_cell_refinement
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
;
_computing_data_collection
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics
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          'Ortep-3 for Windows (Farrugia, 1997)'
      L. J. Farrugia, J. Appl. Crystallogr., 1997, 30, 565.
;
_computing_publication_material
;    
        'WinGX publication routines (Farrugia, 1999)'                 
    L. J. Farrugia, J. Appl. Crystallogr., 1999, 32, 837-838.
;
_computing_structure_refinement
;
      'SHELXL-2014 (Sheldrick, 2015)'
      Sheldrick, G. M. (2015). Acta Cryst. C71, 3--8.
;
_computing_structure_solution
;
      'SHELXT (Sheldrick, 2015)'
      Sheldrick, G. M. (2015). Acta Cryst. A71, 3--8.
;
_diffrn_ambient_temperature      130(2)
_diffrn_detector_area_resol_mean 10.4685
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini'
_diffrn_measurement_method       '\w scans'
_diffrn_orient_matrix_UB_11      -0.0658329
_diffrn_orient_matrix_UB_12      0.0043927
_diffrn_orient_matrix_UB_13      -0.0023243
_diffrn_orient_matrix_UB_21      -0.0055806
_diffrn_orient_matrix_UB_22      -0.0513422
_diffrn_orient_matrix_UB_23      0.0006751
_diffrn_orient_matrix_UB_31      0.0032922
_diffrn_orient_matrix_UB_32      0.001494
_diffrn_orient_matrix_UB_33      0.0302364
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0565
_diffrn_reflns_av_unetI/netI     0.0949
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            20443
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.348
_diffrn_reflns_theta_min         3.377
_exptl_absorpt_coefficient_mu    0.418
_exptl_absorpt_correction_T_max  0.951
_exptl_absorpt_correction_T_min  0.88
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
Analytical numeric absorption correction using a multifaceted crystal
                        model based on expressions derived by R.C. Clark & J.S.
        (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.558
_exptl_crystal_description       plate
_exptl_crystal_F_000             1652
_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.12
_refine_diff_density_max         3.283
_refine_diff_density_min         -1.063
_refine_diff_density_rms         0.154
_refine_ls_extinction_coef       0.0073(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2016/6 (Sheldrick 2016)'
_refine_ls_goodness_of_fit_ref   1.05
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     441
_refine_ls_number_reflns         6340
_refine_ls_number_restraints     7
_refine_ls_restrained_S_all      1.05
_refine_ls_R_factor_all          0.1019
_refine_ls_R_factor_gt           0.0792
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1303P)^2^+16.0985P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2153
_refine_ls_wR_factor_ref         0.2395
_reflns_Friedel_coverage         0
_reflns_number_gt                4858
_reflns_number_total             6340
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt01562g2.cif
_cod_data_source_block           pinzamo
_cod_depositor_comments
'Adding full bibliography for 7046791--7046793.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7046792
_shelx_estimated_absorpt_t_min   0.803
_shelx_estimated_absorpt_t_max   0.952