Single crystal growth of the novel Mn2(OH)2SO3, Mn2F(OH)SO3, and Mn5(OH)4(H2O)2[SO3]2[SO4] compounds using a hydrothermal method.
Ben Yahia, Hamdi; Shikano, Masahiro; Kobayashi, Hironori; Dalton transactions (Cambridge, England : 2003) 42 (2013) 7158–7166; doi:10.1039/c3dt50415h

data_7022962
_publ_section_title
;
 Single crystal growth of the novel Mn2(OH)2SO3, Mn2F(OH)SO3, and
 Mn5(OH)4(H2O)2[SO3]2[SO4] compounds using a hydrothermal method.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7158
_journal_page_last               7166
_journal_paper_doi               10.1039/c3dt50415h
_journal_volume                  42
_journal_year                    2013
_chemical_formula_moiety         'H8 Mn5 O16 S3'
_chemical_formula_sum            'H8 Mn5 O16 S3'
_chemical_formula_weight         634.9
_chemical_name_systematic        ' ?'
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      11
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_cell_angle_alpha                90
_cell_angle_beta                 101.6005(13)
_cell_angle_gamma                90
_cell_formula_units_Z            2
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_cell_length_c                   10.9273(9)
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_cell_measurement_temperature    293
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_cell_volume                     695.21(10)
_diffrn_ambient_temperature      293
_diffrn_measured_fraction_theta_full 0.98
_diffrn_measured_fraction_theta_max 0.96
_diffrn_measurement_device       'four-cycle diffractometer'
_diffrn_measurement_device_type  'Smart Apex'
_diffrn_measurement_method       Multi-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_limit_h_max       9
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_diffrn_reflns_limit_k_min       -10
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_exptl_absorpt_correction_T_min  0.1805
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
'Jana2006  (Petricek, Dusek & Palatinus, 2000)'
_exptl_crystal_colour            pink
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_exptl_crystal_description       needle
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_exptl_crystal_size_max          0.8
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.085
_refine_diff_density_max         0.50
_refine_diff_density_min         -0.36
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_gt    1.14
_refine_ls_goodness_of_fit_ref   1.15
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_constraints    0
_refine_ls_number_parameters     138
_refine_ls_number_reflns         1559
_refine_ls_number_restraints     5
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_refine_ls_R_factor_gt           0.0347
_refine_ls_shift/su_max          0.0010
_refine_ls_shift/su_mean         0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     w=1/(\s^2^(I)+0.0009I^2^)
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_reflns_number_gt                1500
_reflns_number_total             1559
_reflns_threshold_expression     I>3\s(I)
_cod_data_source_file            c3dt50415h_3.cif
_cod_data_source_block           I
_cod_database_code               7022962