(Fluoren-9-ylidene)methanedithiolato Complexes of Platinum: Synthesis, Reactivity, and Luminescence1
José Vicente; Pablo González-Herrero; María Pérez-Cadenas; Peter G. Jones; Delia Bautista; Inorganic Chemistry 44 (2005) 7200–7213; doi:10.1021/ic050748o

data_4309664
_publ_section_title
;
(Fluoren-9-ylidene)methanedithiolato Complexes of Platinum: Synthesis,
Reactivity, and Luminescence1
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7200
_journal_page_last               7213
_journal_paper_doi               10.1021/ic050748o
_journal_volume                  44
_journal_year                    2005
_chemical_formula_sum            'C136 H136 Cl4 P2 Pt2 S8'
_chemical_formula_weight         2620.85
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                99.389(4)
_cell_angle_beta                 94.922(4)
_cell_angle_gamma                108.726(3)
_cell_formula_units_Z            2
_cell_length_a                   18.489(3)
_cell_length_b                   18.634(3)
_cell_length_c                   19.573(3)
_cell_measurement_temperature    133(2)
_cell_volume                     6231.6(17)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      133(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.989
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0941
_diffrn_reflns_av_sigmaI/netI    0.1143
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            102779
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         1.07
_exptl_absorpt_coefficient_mu    2.537
_exptl_absorpt_correction_T_max  0.8836
_exptl_absorpt_correction_T_min  0.6309
_exptl_crystal_density_diffrn    1.397
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2668
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.05
_refine_diff_density_max         9.749
_refine_diff_density_min         -7.841
_refine_diff_density_rms         0.368
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   2.196
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     667
_refine_ls_number_reflns         30572
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      2.196
_refine_ls_R_factor_all          0.1695
_refine_ls_R_factor_gt           0.1299
_refine_ls_shift/su_max          7.702
_refine_ls_shift/su_mean         0.169
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3624
_refine_ls_wR_factor_ref         0.3706
_reflns_number_gt                21307
_reflns_number_total             30572
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic050748osi20050706_032202_3.cif
_cod_data_source_block           ouik
_cod_original_cell_volume        6231.5(18)
_cod_database_code               4309664