Electrochemical synthesis of sulfonamide derivatives based on the oxidation of 2,5-diethoxy-4-morpholinoaniline in the presence of arylsulfinic acids.
Beiginejad, Hadi; Nematollahi, Davood; The Journal of organic chemistry 79 (2014) 6326–6329; doi:10.1021/jo500812d

data_4029626
_publ_section_title
;
 Electrochemical synthesis of sulfonamide derivatives based on the
 oxidation of 2,5-diethoxy-4-morpholinoaniline in the presence of
 arylsulfinic acids.
;
_journal_issue                   13
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              6326
_journal_page_last               6329
_journal_paper_doi               10.1021/jo500812d
_journal_volume                  79
_journal_year                    2014
_chemical_formula_sum            'C28 H34 N2 O7 S2'
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_computing_data_collection       'X-Area 1.31 (Stoe & Cie GmbH, 2005)'
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
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_diffrn_ambient_temperature      298(2)
_diffrn_detector_area_resol_mean '0.15 mm'
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_diffrn_measurement_device_type  'STOE IPDS II'
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_diffrn_radiation_monochromator  graphite
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_exptl_absorpt_correction_type   numerical
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_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.318
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_exptl_crystal_description       Prism
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_refine_ls_R_factor_all          0.0912
_refine_ls_R_factor_gt           0.0851
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_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1918
_refine_ls_wR_factor_ref         0.1992
_reflns_number_gt                5312
_reflns_number_total             5646
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            jo500812d_si_002.cif
_cod_data_source_block           d:\determination\solution\743\kh743-abs
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4029626.cif.
;
_cod_original_cell_volume        1448.2(4)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4029626