Reactions of Anilines and Benzamides with a Fourteen-Electron Iridium(I) Bis(Phosphinite) Complex: N-H Oxidative Addition versus Lewis Base Coordination.
Sykes, Alison Cartwright; White, Peter; Brookhart, Maurice; Organometallics 25 (2006) 1664–1675; doi:10.1021/om051070n

data_4074974
_publ_section_title
;
 Reactions of Anilines and Benzamides with a Fourteen-Electron Iridium(I)
 Bis(Phosphinite) Complex: N-H Oxidative Addition versus Lewis Base
 Coordination.
;
_journal_issue                   7
_journal_name_full               Organometallics
_journal_page_first              1664
_journal_page_last               1675
_journal_paper_doi               10.1021/om051070n
_journal_volume                  25
_journal_year                    2006
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_chemical_name_systematic        ?
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_cell_length_c                   15.0255(15)
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_cell_measurement_temperature    173
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_cell_volume                     3145.6(6)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT/NRCVAX DATRD2'
_computing_molecular_graphics    NRCVAX
_computing_publication_material  'NRCVAX TABLES Jan 94 Version'
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_computing_structure_solution    'NRCVAX SOLVER'
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_diffrn_measurement_device       'Bruker SMART 1K'
_diffrn_measurement_method       'Omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'xray tube'
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_diffrn_reflns_limit_k_min       0
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_exptl_crystal_colour            yellow
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_exptl_crystal_description       block
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_refine_ls_structure_factor_coef F
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_cod_data_source_file            om051070nsi20051215_121938.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        3145.6(5)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C29 H41 F5 Ir N O3 P2 '
_cod_database_code               4074974