Synthesis, Characterization, Biocide and Toxicological Activities of Di-n-butyl- and Diphenyl-tinIV-Salicyliden-β-Amino Alcohol Derivatives
Luis S. Zamudio-Rivera; Rocio George-Tellez; Gerson López-Mendoza; Adela Morales-Pacheco; Eugenio Flores; Herbert Höpfl; Victor Barba; Francisco J. Fernández; Nathalie Cabirol; Hiram I. Beltrán; Inorganic Chemistry 44 (2005) 5370–5378; doi:10.1021/ic048628o

data_4309248
_publ_contact_author_address
;
Programa de Ingenier\'ia Molecular, Instituto Mexicano del Petr\'oleo,
Eje Central L\'azaro C\'ardenas 152, Col. San Bartolo Atepehuacan,
C. P. 07730, M\'exico, D. F.
;
_publ_contact_author_fax         (52)55-91756239
_publ_contact_author_name        'Hiram Isaac Beltr\'an Conde'
_publ_contact_author_phone       (52)55-91757399
_publ_section_title
;
Synthesis, Characterization, Biocide and Toxicological Activities of
Di-n-butyl- and Diphenyl-tinIV-Salicyliden-\b-Amino Alcohol Derivatives
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5370
_journal_page_last               5378
_journal_paper_doi               10.1021/ic048628o
_journal_volume                  44
_journal_year                    2005
_chemical_formula_sum            'C18 H29 N O2 Sn'
_chemical_formula_weight         410.11
_chemical_name_systematic
;
 4b
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.2
_audit_creation_date             2004-06-24T12:18:03-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 99.699(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.1690(12)
_cell_length_b                   17.9743(17)
_cell_length_c                   8.7980(9)
_cell_measurement_temperature    293(2)
_cell_volume                     1896.9(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1
_diffrn_measured_fraction_theta_max 1
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0279
_diffrn_reflns_av_unetI/netI     0.0194
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            18142
_diffrn_reflns_theta_full        25
_diffrn_reflns_theta_max         25
_diffrn_reflns_theta_min         1.7
_exptl_absorpt_coefficient_mu    1.354
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    1.436
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             840
_refine_diff_density_max         0.346
_refine_diff_density_min         -0.25
_refine_diff_density_rms         0.053
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.06
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     279
_refine_ls_number_reflns         3343
_refine_ls_number_restraints     38
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0266
_refine_ls_R_factor_gt           0.0239
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0327P)^2^+0.5893P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0599
_refine_ls_wR_factor_ref         0.0614
_reflns_number_gt                3066
_reflns_number_total             3343
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic048628osi20041001_112216.cif
_cod_data_source_block           zarzwox
_cod_database_code               4309248