Aluminum dihydride from E(IV) precursors (E = Si, Ge) and its bond-activation reactivities.
Kumar, Hemant; Kelley, Steven P.; Batra, Tanya; Nagendran, Selvarajan; Walensky, Justin R.; Dalton transactions (Cambridge, England : 2003)  (2026) –; doi:10.1039/d6dt00474a

data_7720842
_publ_section_title
;
 Aluminum dihydride from E(IV) precursors (E = Si, Ge) and its
 bond-activation reactivities.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6453
_journal_page_last               6461
_journal_paper_doi               10.1039/d6dt00474a
_journal_volume                  55
_journal_year                    2026
_chemical_formula_moiety         'C15 H24 Cl2 N2 Si'
_chemical_formula_sum            'C15 H24 Cl2 N2 Si'
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Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
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2026-02-19 deposited with the CCDC.	2026-04-02 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0175P)^2^+1.3140P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 7720842--7720848.cif.'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All C(H,H,H,H) groups
;
_shelx_res_checksum              65046
_olex2_submission_special_instructions 'No special instructions were received'