Reversible metathesis of ammonia in an acyclic germylene–Ni0 complex
Keil, Philip M.; Szilvási, Tibor; Hadlington, Terrance J.; Chemical Science 12 (2021) 5582–5590; doi:10.1039/D1SC00450F

data_1560847
_publ_section_title
;
 Reversible metathesis of ammonia in an acyclic germylene--Ni0 complex
;
_journal_issue                   15
_journal_name_full               'Chemical Science'
_journal_page_first              5582
_journal_page_last               5590
_journal_paper_doi               10.1039/D1SC00450F
_journal_volume                  12
_journal_year                    2021
_chemical_formula_moiety         'C48 H63 K N2 O2 P Si'
_chemical_formula_sum            'C48 H63 K N2 O2 P Si'
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-01-19 deposited with the CCDC.	2021-03-05 downloaded from the CCDC.
;
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_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_point_group_measured_fraction_full 0.997
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_diffrn_source                   'Genix 3D HF Mo'
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_refine_ls_R_factor_all          0.0886
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1145P)^2^+1.4189P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1sc00450f2.cif
_cod_data_source_block           compound_PhPhDippNK
_cod_depositor_comments
'Adding full bibliography for 1560843--1560857.cif.'
_cod_database_code               1560847
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              15342
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