N-Bromosuccinimide-Induced Aminocyclization-Aziridine Ring-Expansion Cascade: An Asymmetric and Highly Stereoselective Approach toward the Synthesis of Azepane.
Zhou, Jing; Yeung, Ying-Yeung; Organic letters 16 (2014) 2134–2137; doi:10.1021/ol5005609

data_1514209
_publ_section_title
;
 N-Bromosuccinimide-Induced Aminocyclization-Aziridine Ring-Expansion
 Cascade: An Asymmetric and Highly Stereoselective Approach toward the
 Synthesis of Azepane.
;
_journal_issue                   8
_journal_name_full               'Organic letters'
_journal_page_first              2134
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_journal_paper_doi               10.1021/ol5005609
_journal_volume                  16
_journal_year                    2014
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 ? 
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 Flack x determined using 2086 quotients [(I+)-(I-)]/[(I+)+(I-)] 
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;
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'w=1/[\s^2^(Fo^2^)+(0.0366P)^2^+4.6305P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                5388
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
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Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for
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The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'Not Measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        3008.7(6)
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