Phosphonium-stibonium and bis-stibonium cations as pnictogen-bonding catalysts for the transfer hydrogenation of quinolines.
Yang, Mengxi; Hirai, Masato; Gabbaï, François P; Dalton transactions (Cambridge, England : 2003) 48 (2019) 6685–6689; doi:10.1039/c9dt01357a

data_7049769
_publ_section_title
;
 Phosphonium-stibonium and bis-stibonium cations as pnictogen-bonding
 catalysts for the transfer hydrogenation of quinolines.
;
_journal_issue                   20
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6685
_journal_page_last               6689
_journal_paper_doi               10.1039/c9dt01357a
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C36 H29 P Sb, B F4'
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_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
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Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
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2019-03-12 deposited with the CCDC.    2019-04-17 downloaded from the CCDC.
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'SADABS-2014/5 (Bruker,2014/5) was used for absorption correction. wR2(int) was 0.0973 before and 0.0753 after correction. The Ratio of minimum to maximum transmission is 0.7760. The \l/2 correction factor is 0.00150.'
_exptl_crystal_colour            colourless
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0488P)^2^+1.4156P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 7049767--7049769.cif.'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C6(H6), C5(H5), C4(H4), C3(H3), C32(H32), C33(H33), C34(H34), C35(H35),
 C36(H36), C26(H26), C27(H27), C28(H28), C29(H29), C30(H30), C12(H12), C11(H11),
  C10(H10), C9(H9), C8(H8), C14(H14), C15(H15), C16(H16), C17(H17), C18(H18),
 C24(H24), C23(H23), C22(H22), C21(H21), C20(H20)
;
_shelx_res_checksum              8900
_olex2_submission_special_instructions 'No special instructions were received'