A rare cationic building block that generates a new type of polyhedral network with "cross-linked" pto topology.
Lusi, Matteo; Fechine, Pierre B. A.; Chen, Kai-Jie; Perry, John J.; Zaworotko, Michael J.; Chemical communications (Cambridge, England) 52 (2016) 4160–4162; doi:10.1039/c5cc10203k

data_7118758
_publ_section_title
;
 A rare cationic building block that generates a new type of polyhedral
 network with &quot;cross-linked&quot; pto topology.
;
_journal_issue                   22
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              4160
_journal_page_last               4162
_journal_paper_doi               10.1039/c5cc10203k
_journal_volume                  52
_journal_year                    2016
_chemical_formula_sum            'C160 H112 Cu6 F18 Ge3 N32'
_chemical_formula_weight         3423.82
_chemical_name_systematic
;
 ?
;
_chemical_properties_physical    'Air-sensitive, Moisture-sensitive'
_space_group_crystal_system      cubic
_space_group_IT_number           200
_space_group_name_Hall           '-P 2 2 3'
_space_group_name_H-M_alt        'P m -3'
_symmetry_space_group_name_Hall  '-P 2 2 3'
_symmetry_space_group_name_H-M   'P m -3'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2015-12-10 deposited with the CCDC.
2016-02-16 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
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_diffrn_measurement_device_type  'Bruker D8 Quest'
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_exptl_absorpt_correction_T_max  0.75
_exptl_absorpt_correction_T_min  0.5531
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    0.596
_exptl_crystal_description       Needle
_exptl_crystal_F_000             1728
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.804
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_refine_ls_matrix_type           full
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.4423
_refine_ls_wR_factor_ref         0.4511
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1670
_reflns_number_total             1867
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5cc10203k2.cif
_cod_data_source_block           added_by_encifer
_cod_depositor_comments
'Adding full bibliography for 7118758--7118762.cif.'
_cod_original_cell_volume        9543.1(11)
_cod_database_code               7118758
_shelxl_version_number           2014-3
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