Stitching ynones with indolin-2-thiones: an eco-friendly reaction cascade towards functionalized thiopyrano[2,3-<i>b</i>]indoles and their inceptive optoelectronic profiling.
Balasubramani, Alagesan; Shivachalappa Salgar, Rupali; Lingamallu, Giribabu; Pabbaraja, Srihari; Mehta, Goverdhan; Organic & biomolecular chemistry 23 (2025) 9100–9104; doi:10.1039/d5ob01279a

data_7160737
_publ_section_title
;
 Stitching ynones with indolin-2-thiones: an eco-friendly reaction cascade
 towards functionalized thiopyrano[2,3-<i>b</i>]indoles and their
 inceptive optoelectronic profiling.
;
_journal_issue                   40
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              9100
_journal_page_last               9104
_journal_paper_doi               10.1039/d5ob01279a
_journal_volume                  23
_journal_year                    2025
_chemical_formula_moiety         'C23 H13 Br F N S'
_chemical_formula_sum            'C23 H13 Br F N S'
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_audit_update_record
;
2025-08-25 deposited with the CCDC.	2025-09-22 downloaded from the CCDC.
;
_cell_angle_alpha                115.183(8)
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_diffrn_measurement_device_type  'Bruker SMART CCD 6000'
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_diffrn_reflns_av_unetI/netI     0.0429
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_diffrn_reflns_limit_l_min       -13
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_diffrn_reflns_point_group_measured_fraction_full 0.984
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_exptl_absorpt_process_details
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            'metallic brownish brown'
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_exptl_crystal_description       'metallic brownish brown'
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1521P)^2^+0.3925P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.2199
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_reflns_number_gt                2406
_reflns_number_total             3182
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7160736--7160737.cif.'
_cod_original_cell_volume        920.4(9)
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_shelx_res_checksum              365