pH-Dependent Monomer \λeftarrow→Oligomer Interconversion of Copper(II) Complexes with N-(2-R-imidazol-4-ylmethylidene)-2-aminoethylpyridine (R = Methyl, Phenyl)
Naohide Matsumoto; Yuri Motoda; Toshihiro Matsuo; Toshio Nakashima; Nazzareno Re; Francoise Dahan; Jean-Pierre Tuchagues; Inorganic Chemistry 38 (1999) 1165–1173; doi:10.1021/ic981158b

data_4321840
_publ_contact_author             'Naohide Matsumoto'
_publ_contact_author_email       'naohide@aster.sci.kumamoto-u.ac.jp '
_publ_contact_author_fax         ' +81-96-342-3390 '
_publ_contact_author_phone       '+81-96-342-3390 '
_publ_section_title
;
 pH-Dependent Monomer \\leftarrow\\rightarrow Oligomer Interconversion of
 Copper(II) Complexes with
 N-(2-R-imidazol-4-ylmethylidene)-2-aminoethylpyridine (R = Methyl,
 Phenyl)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1165
_journal_page_last               1173
_journal_paper_doi               10.1021/ic981158b
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C12 H16 Cl2 Cu N4 O'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             'Thu Aug 7 13:34:40 1997'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 110.10(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4.00
_cell_length_a                   13.773(2)
_cell_length_b                   8.245(2)
_cell_length_c                   13.861(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    20.0
_cell_measurement_theta_max      29.99
_cell_measurement_theta_min      29.54
_cell_volume                     1478.2(5)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_diffrn_ambient_temperature      20.0
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  1.31
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
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_diffrn_reflns_theta_max         24.9903
_diffrn_standards_decay_%        1.81
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu_cm 18.336
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_correction_T_min  0.593
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            light
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_exptl_crystal_description       prismatic
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_exptl_crystal_size_min          0.200
_refine_diff_density_max         -0.39050
_refine_diff_density_min         0.35130
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_refine_ls_extinction_method     Zachariasen_type_2_Gaussian_isotropic
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_cod_data_source_file            ic981158b_1.cif
_cod_data_source_block           Cu(mertpy)Cl2
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_cod_database_code               4321840