Emissive Terbium Probe for Multiphoton in Vitro Cell Imaging
Ga-Lai Law; Ka-Leung Wong; Cornelia Wing-Yin Man; Wing-Tak Wong; Sai-Wah Tsao; Michael Hon-Wah Lam; Paul Kwan-Sing Lam; Journal of the American Chemical Society 130 (2008) 3714–3715; doi:10.1021/ja710418d

data_4107589
_publ_contact_author_address
;
Department of Chemistry
The University of Hong Kong
Pokfulam Road, Pokfulam,
Hong Kong SAR,
P. R. CHINA
;
_publ_contact_author_email       wtwong@hkucc.hku.hk
_publ_contact_author_fax         '(852) 2547 2933'
_publ_contact_author_name        'Prof. Wing-Tak Wong'
_publ_contact_author_phone       '(852) 2859 2157'
_publ_section_title
;
 Emissive Terbium Probe for Multiphoton in Vitro Cell Imaging
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3714
_journal_page_last               3715
_journal_paper_doi               10.1021/ja710418d
_journal_volume                  130
_journal_year                    2008
_chemical_formula_moiety         'C30 H36 N7 O15 Tb '
_chemical_formula_sum            'C30 H36 N7 O15 Tb'
_chemical_formula_weight         893.58
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             2006-07-27
_audit_creation_method           'by CrystalStructure 3.6.0'
_cell_angle_alpha                90
_cell_angle_beta                 90.277(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.426(2)
_cell_length_b                   19.555(2)
_cell_length_c                   13.641(2)
_cell_measurement_reflns_used    22435
_cell_measurement_temperature    301(1)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.0
_cell_volume                     3581.3(8)
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction
'SAINT & CrystalStructure (Rigaku/MSC and Rigaku Corporation, 2003)'
_computing_molecular_graphics    'ORTEP-II (Johnson, 1976)'
_computing_publication_material  'CrystalStructure 3.6.0'
_computing_structure_refinement  'CRYSTALS (Watkin et al., 1996)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_measured_fraction_theta_full 0.9805
_diffrn_measured_fraction_theta_max 0.9805
_diffrn_measurement_device_type  'Bruker SMART 1K CCD Detector'
_diffrn_measurement_method       '\w & \f scans'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.030
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            22435
_diffrn_reflns_theta_full        27.52
_diffrn_reflns_theta_max         27.52
_exptl_absorpt_coefficient_mu    2.050
_exptl_absorpt_correction_T_max  0.940
_exptl_absorpt_correction_T_min  0.744
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1997)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.657
_exptl_crystal_description       plate
_exptl_crystal_F_000             1800.00
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.00
_refine_diff_density_min         -0.38
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     514
_refine_ls_number_reflns         5839
_refine_ls_R_factor_gt           0.0320
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[0.0002Fo^2^ + \s(Fo^2^) + 0.0005]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0330
_reflns_number_gt                5813
_reflns_number_total             8091
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ja710418d-file003.cif
_cod_data_source_block           wt1276w
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C30 H36 N7 O15 Tb '
_cod_database_code               4107589