Mono- and polynuclear Ag(i) complexes of N-functionalized bis(diphenylphosphino)amine DPPA-type ligands: synthesis, solid-state structures and reactivity.
Ghisolfi, Alessio; Fliedel, Christophe; de Frémont, Pierre; Braunstein, Pierre; Dalton transactions (Cambridge, England : 2003) 46 (2017) 5571–5586; doi:10.1039/c6dt04755f

data_7042580
_publ_section_title
;
 Mono- and polynuclear Ag(i) complexes of N-functionalized
 bis(diphenylphosphino)amine DPPA-type ligands: synthesis, solid-state
 structures and reactivity.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5571
_journal_page_last               5586
_journal_paper_doi               10.1039/c6dt04755f
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C62 H54 Ag2 B F4 N2 O2 P4, B F4'
_chemical_formula_sum            'C62 H54 Ag2 B2 F8 N2 O2 P4'
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_space_group_name_Hall           '-P 2n 2ab'
_space_group_name_H-M_alt        'P b c n'
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      60
_symmetry_space_group_name_Hall  '-P 2n 2ab'
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;
2016-08-01 deposited with the CCDC.
2017-03-10 downloaded from the CCDC.
;
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'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
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_diffrn_measurement_device_type  KappaCCD
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_diffrn_radiation_wavelength     0.71073
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;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            Colorless
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_exptl_crystal_description       Prism
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_exptl_crystal_recrystallization_method 'Acetone - Diethyl ether'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1504P)^2^+88.1929P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7042575--7042581.cif.'
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