Reactions of α,β-Unsaturated Thioesters with Platinum(0): Implication of a Dual Mechanism Leading to the Formation of Acyl Platinum†
Minami, Yasunori; Kato, Tomohiro; Kuniyasu, Hitoshi; Terao, Jun; Kambe, Nobuaki; Organometallics 25 (2006) 2949–; doi:10.1021/om050834w

data_4074725
_publ_section_title
;
 Reactions of \a,\b-Unsaturated Thioesters with Platinum(0):&#x00A0;
 Implication of a Dual Mechanism Leading to the Formation of Acyl
 Platinum&#x2020;
;
_journal_issue                   12
_journal_name_full               Organometallics
_journal_page_first              2949
_journal_paper_doi               10.1021/om050834w
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C68 H58 O2 P2 Pt2 S2 '
_chemical_formula_sum            'C68 H58 O2 P2 Pt2 S2'
_chemical_formula_weight         1423.45
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                101.256(3)
_cell_angle_beta                 92.958(4)
_cell_angle_gamma                103.578(6)
_cell_formula_units_Z            1
_cell_length_a                   10.950(1)
_cell_length_b                   11.2767(8)
_cell_length_c                   12.122(1)
_cell_measurement_reflns_used    8451
_cell_measurement_temperature    223.2
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      2.3
_cell_volume                     1419.5(2)
_computing_cell_refinement       PROCESS-AUTO
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_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
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_computing_structure_solution    SAPI91
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9862
_diffrn_measured_fraction_theta_max 0.9862
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.038
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            13296
_diffrn_reflns_theta_full        27.41
_diffrn_reflns_theta_max         27.41
_exptl_absorpt_coefficient_mu    5.078
_exptl_absorpt_correction_T_max  0.602
_exptl_absorpt_correction_T_min  0.318
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.665
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       chip
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.41
_refine_diff_density_min         -2.41
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.758
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     343
_refine_ls_number_reflns         5554
_refine_ls_R_factor_gt           0.0395
_refine_ls_shift/su_max          0.0039
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1056
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_reflns_threshold_expression     F^2^>3.0\s(F^2^)
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_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C68 H58 O2 P2 Pt2 S2 '
_cod_database_code               4074725