Half-sandwich ruthenium(ii) complexes with tethered arene-phosphinite ligands: synthesis, structure and application in catalytic cross dehydrogenative coupling reactions of silanes and alcohols.
González-Fernández, Rebeca; Crochet, Pascale; Cadierno, Victorio; Dalton transactions (Cambridge, England : 2003) 49 (2020) 210–222; doi:10.1039/c9dt04421c

data_7702935
_publ_section_title
;
 Half-sandwich ruthenium(ii) complexes with tethered arene-phosphinite
 ligands: synthesis, structure and application in catalytic cross
 dehydrogenative coupling reactions of silanes and alcohols.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              210
_journal_page_last               222
_journal_paper_doi               10.1039/c9dt04421c
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C15 H25 Ru1 Cl2 O1 P1'
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;
2019-10-10 deposited with the CCDC.	2019-12-02 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Xcalibur, Onyx, Nova'
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            brown
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_exptl_crystal_description       needle
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_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0324
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0570P)^2^+0.2256P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0892
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                2899
_reflns_number_total             3147
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt04421c2.cif
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'Adding full bibliography for 7702933--7702936.cif.'
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