Unusual rearrangement of an N-heterocyclic carbene via a ring-opening and ring-closing process.
Yang, Chu-Fan; Lu, Taotao; Chen, Xue-Tai; Xue, Zi-Ling; Chemical communications (Cambridge, England) 54 (2018) 7830–7833; doi:10.1039/c8cc03589j

data_7121860
_publ_section_title
;
 Unusual rearrangement of an N-heterocyclic carbene via a ring-opening and
 ring-closing process.
;
_journal_issue                   56
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              7830
_journal_page_last               7833
_journal_paper_doi               10.1039/c8cc03589j
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C32 H31 F12 N9 P2 Pd'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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_audit_update_record
;
2018-05-04 deposited with the CCDC.
2018-06-20 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_theta_max         25.020
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_exptl_absorpt_coefficient_mu    0.711
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0369P)^2^+10.8419P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8cc03589j2.cif
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_cod_depositor_comments
'Adding full bibliography for 7121857--7121860.cif.'
_cod_database_code               7121860
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