Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative
Cabeza, Javier A.; Fernández-Colinas, José M.; García-Álvarez, Pablo; Polo, Diego; RSC Advances 4 (2014) 31503–; doi:10.1039/C4RA05972G

data_7217195
_publ_section_title
;
 Steric effects in the reactions of amidinate germylenes with ruthenium
 carbonyl: isolation of a coordinatively unsaturated diruthenium(0)
 derivative
;
_journal_issue                   59
_journal_name_full               'RSC Advances'
_journal_page_first              31503
_journal_paper_doi               10.1039/C4RA05972G
_journal_volume                  4
_journal_year                    2014
_chemical_formula_moiety         'C25 H37 Ge N3 O6 Ru2 Si2'
_chemical_formula_sum            'C25 H37 Ge N3 O6 Ru2 Si2'
_chemical_formula_weight         806.49
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;
 ?
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_space_group_IT_number           2
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_computing_cell_refinement
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
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_computing_data_collection
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_molecular_graphics    'MERCUY CSD 3.1 (Build RC5)'
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_computing_structure_solution    'SIR-97 (Giacovazzo, 1999)'
_diffrn_ambient_temperature      153(4)
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_diffrn_measurement_device_type  'Xcalibur, Onyx, Nova'
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_diffrn_reflns_number            30345
_diffrn_reflns_theta_full        68.00
_diffrn_reflns_theta_max         68.00
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_exptl_absorpt_coefficient_mu    9.157
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.577
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       fragment
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_refine_ls_number_reflns         12298
_refine_ls_number_restraints     0
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0336P)^2^+1.3332P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0585
_refine_ls_wR_factor_ref         0.0597
_reflns_number_gt                11667
_reflns_number_total             12298
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4ra05972g2.cif
_cod_data_source_block           xn13_007_dp508
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'TRICLINIC' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        3396.02(13)
_cod_database_code               7217195