An efficient method for the preparation of styrene derivatives via Rh(III)-catalyzed direct C-H vinylation.
Otley, Kate D.; Ellman, Jonathan A.; Organic letters 17 (2015) 1332–1335; doi:10.1021/acs.orglett.5b00340

data_1554837
_publ_contact_author
;
 Jonathan A. Ellman         
 The Department of Chemistry 
 Yale University 
 P. O. Box 208107 
 New Haven 
 Connecticut 06520 USA.
;
_publ_section_title
;
 An efficient method for the preparation of styrene derivatives via
 Rh(III)-catalyzed direct C-H vinylation.
;
_journal_issue                   5
_journal_name_full               'Organic letters'
_journal_page_first              1332
_journal_page_last               1335
_journal_paper_doi               10.1021/acs.orglett.5b00340
_journal_volume                  17
_journal_year                    2015
_chemical_formula_moiety         'C24 B F20, C25 H29 N O2 Rh'
_chemical_formula_sum            'C49 H29 B F20 N O2 Rh'
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_cell_measurement_theta_max      27.5
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'CrystalClear-SM Expert 2.0 r15 (Rigaku, 2011)'
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'CrystalClear-SM Expert 2.0 r15 (Rigaku, 2011)'
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'CrystalClear-SM Expert 2.0 r15 (Rigaku, 2011)'
_computing_molecular_graphics
;
Dolomanov, O.V.; Bourhis, L.J.; Gildea, R.J.; Howard, J.A.K.; Puschmann, H., 
OLEX2: A complete structure solution, refinement and analysis program
(2009). J. Appl. Cryst., 42, 339-341.
;
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID imaging plate'
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_exptl_crystal_colour            Orange
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_exptl_crystal_density_method    'not measured'
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         10332
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0279P)^2^+6.2038P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0742
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_reflns_number_gt                8759
_reflns_number_total             10332
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           spider-14125
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1554837
_shelx_estimated_absorpt_t_min   0.928
_shelx_estimated_absorpt_t_max   0.980
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_shelx_res_checksum              96878
_shelx_hkl_checksum              74631