<i>catena</i>-Poly[[(triphenylphosphane-κ<i>P</i>)silver(I)]-μ-4,4'-bipyridine-κ^2^<i>N</i>:<i>N</i>'-[(triphenylphosphane-κ<i>P</i>)silver(I)]-di-μ-chlorido]
Song, Xiao-Ming; Hu, Feng; Shi, Hua-Tian; Chen, Qun; Zhang, Qian-Feng; Acta Crystallographica Section E 69 (2013) m342–; doi:10.1107/S160053681301413X

data_2238095
_publ_section_title
;
 <i>catena</i>-Poly[[(triphenylphosphane-\k<i>P</i>)silver(I)]-\m-4,4'-bipyridine-\k^2^<i>N</i>:<i>N</i>'-[(triphenylphosphane-\k<i>P</i>)silver(I)]-di-\m-chlorido]
;
_journal_coeditor_code           XU5704
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m342
_journal_paper_doi               10.1107/S160053681301413X
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          '[Ag2 Cl2 (C10 H8 N2) (C18 H15 P)2]'
_chemical_formula_moiety         'C46 H38 Ag2 Cl2 N2 P2'
_chemical_formula_sum            'C46 H38 Ag2 Cl2 N2 P2'
_chemical_formula_weight         967.36
_chemical_name_systematic
<i>catena</i>-Poly[[(triphenylphosphane-\k<i>P</i>)silver(I)]-\m-4,4'-bipyridine-\k^2^<i>N</i>:<i>N</i>'-[(triphenylphosphane-\k<i>P</i>)silver(I)]-di-\m-chlorido]
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                70.753(3)
_cell_angle_beta                 79.332(4)
_cell_angle_gamma                75.190(3)
_cell_formula_units_Z            2
_cell_length_a                   9.1042(16)
_cell_length_b                   13.887(2)
_cell_length_c                   17.826(3)
_cell_measurement_reflns_used    4454
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.92
_cell_measurement_theta_min      2.33
_cell_volume                     2044.5(6)
_computing_cell_refinement       'SAINT (Bruker, 2007)'
_computing_data_collection       'APEX2 (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.969
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'Bruker SMART APEXII CCD area-detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0180
_diffrn_reflns_av_sigmaI/netI    0.0409
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            14039
_diffrn_reflns_theta_full        29.15
_diffrn_reflns_theta_max         29.15
_diffrn_reflns_theta_min         1.59
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.202
_exptl_absorpt_correction_T_max  0.8498
_exptl_absorpt_correction_T_min  0.7695
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2001)'
_exptl_crystal_colour            'light yellow'
_exptl_crystal_density_diffrn    1.571
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             972
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.14
_refine_diff_density_max         0.586
_refine_diff_density_min         -0.443
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.012
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     487
_refine_ls_number_reflns         9594
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.012
_refine_ls_R_factor_all          0.0685
_refine_ls_R_factor_gt           0.0388
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0251P)^2^+1.3705P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0806
_refine_ls_wR_factor_ref         0.0923
_reflns_number_gt                6338
_reflns_number_total             9594
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            xu5704.cif
_cod_data_source_block           I
_cod_database_code               2238095
_cod_database_fobs_code          2238095