Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp<sup>2</sup>)-H Oxidative Addition Results in <i>ortho</i>-to-Fluorine Selectivity.
Pabst, Tyler P.; Obligacion, Jennifer V.; Rochette, Étienne; Pappas, Iraklis; Chirik, Paul J.; Journal of the American Chemical Society 141 (2019) 15378–15389; doi:10.1021/jacs.9b07984

data_4128971
_publ_section_title
;
 Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control
 of C(sp<sup>2</sup>)-H Oxidative Addition Results in
 <i>ortho</i>-to-Fluorine Selectivity.
;
_journal_issue                   38
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              15378
_journal_page_last               15389
_journal_paper_doi               10.1021/jacs.9b07984
_journal_volume                  141
_journal_year                    2019
_chemical_formula_sum            'C27 H40 Co F4 N P2'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1089P)^2^+38.7684P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_original_sg_symbol_H-M      'P 21/n'
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_shelx_estimated_absorpt_t_max   0.427
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_shelx_res_checksum              22999
_shelx_hkl_checksum              6720
_shelx_fab_checksum              42850