Reversible Heterolysis of H2 Mediated by an M-S(Thiolate) Bond (M = Ir, Rh): A Mechanistic Implication for [NiFe] Hydrogenase
Yasuhiro Ohki; Mayumi Sakamoto; Kazuyuki Tatsumi; Journal of the American Chemical Society 130 (2008) 11610–11611; doi:10.1021/ja804848w

data_4108287
_publ_section_title
;
 Reversible Heterolysis of H2 Mediated by an M-S(Thiolate) Bond (M = Ir,
 Rh): A Mechanistic Implication for [NiFe] Hydrogenase
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11610
_journal_page_last               11611
_journal_paper_doi               10.1021/ja804848w
_journal_volume                  130
_journal_year                    2008
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_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_cell_angle_gamma                90.0000
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_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
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_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
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'w = 1/[0.0007Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
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