Stereoselective Preparation, Structures, and Reactivities of Phosphine-Bridged Mixed-Metal Trinuclear and Pentanuclear Complexes with Tris[2-(diphenylphosphino)ethyl]phosphine
Aizawa, Sen-ichi; Saito, Kenji; Kawamoto, Tatsuya; Matsumoto, Emi; Inorganic Chemistry 45 (2006) 4859–4866; doi:10.1021/ic060277l

data_4332356
_publ_section_title
;
 Stereoselective Preparation, Structures, and Reactivities of
 Phosphine-Bridged Mixed-Metal Trinuclear and Pentanuclear Complexes with
 Tris[2-(diphenylphosphino)ethyl]phosphine
;
_journal_issue                   12
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4859
_journal_page_last               4866
_journal_paper_doi               10.1021/ic060277l
_journal_volume                  45
_journal_year                    2006
_chemical_formula_moiety         'C98 H94 B2 Cl10 F8 P8 Pd2 Pt S2 '
_chemical_formula_sum            'C98 H94 B2 Cl10 F8 P8 Pd2 Pt S2'
_chemical_formula_weight         2519.76
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                97.53(1)
_cell_angle_beta                 102.72(1)
_cell_angle_gamma                96.58(1)
_cell_formula_units_Z            2
_cell_length_a                   15.510(2)
_cell_length_b                   15.854(3)
_cell_length_c                   22.923(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.1
_cell_measurement_theta_max      12.2
_cell_measurement_theta_min      11.0
_cell_volume                     5390.6(15)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 3.5.1'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SHELXS86
_diffrn_measured_fraction_theta_full 0.8618
_diffrn_measured_fraction_theta_max 0.8618
_diffrn_measurement_device_type  'Rigaku AFC5R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.038
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            25558
_diffrn_reflns_theta_full        22.50
_diffrn_reflns_theta_max         22.50
_diffrn_standards_decay_%        -1.02
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.082
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            pale
_exptl_crystal_density_diffrn    1.552
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2512.00
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.16
_refine_diff_density_min         -1.27
_refine_ls_extinction_coef       12(5)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   1.806
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     1292
_refine_ls_number_reflns         7502
_refine_ls_R_factor_gt           0.0500
_refine_ls_shift/su_max          0.0020
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w = 1/\s^2^(Fo^2^)'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0860
_reflns_number_gt                7494
_reflns_number_total             12165
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic060277lsup1.cif
_cod_data_source_block           '_6(BF4)2'
_cod_original_cell_volume        5390(1)
_cod_original_sg_symbol_H-M      'P -1       '
_cod_original_formula_sum        'C98 H94 B2 Cl10 F8 P8 Pd2 Pt S2 '
_cod_database_code               4332356