Directly linked dehydropurpurin‒porphyrin dyads from Ag(i)-promoted oxidation of meso-phenylethynyl substituted zinc(ii) porphyrins
Nakano, Aiko; Aratani, Naoki; Furuta, Hiroyuki; Osuka, Atsuhiro; Chemical Communications  (2001) 1920–; doi:10.1039/b106050n

data_7115019
_publ_section_title
;
 Directly linked dehydropurpurin--porphyrin dyads from Ag(i)-promoted
 oxidation of meso-phenylethynyl substituted zinc(ii) porphyrins
;
_journal_issue                   19
_journal_name_full               'Chemical Communications'
_journal_page_first              1920
_journal_paper_doi               10.1039/b106050n
_journal_year                    2001
_chemical_formula_sum            'C91 H62 Cu2 N8'
_chemical_formula_weight         1394.64
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_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
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_audit_creation_date             2000-11-18
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?
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_cell_angle_alpha                99.737(2)
_cell_angle_beta                 106.210(3)
_cell_angle_gamma                83.472(5)
_cell_formula_units_Z            2
_cell_length_a                   13.204(1)
_cell_length_b                   24.665(1)
_cell_length_c                   11.0879(9)
_cell_measurement_reflns_used    15197
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      1.9
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_computing_cell_refinement       'MSC/AFC Diffractometer Control'
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'teXsan for Windows version 1.06 (MSC, 1997-1999)'
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'teXsan for Windows version 1.06 (MSC, 1997-1999)'
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'teXsan for Windows version 1.06 (MSC, 1997-1999)'
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SIR92 (Altomare, et. al. 1994)
;
_diffrn_ambient_temperature      296.2
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_diffrn_orient_matrix_UB_33      0.08967
_diffrn_radiation_detector       'Imaging Plate'
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_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_limit_h_max       17
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_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -31
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_diffrn_reflns_reduction_process 'Lp corrections applied'
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_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 0
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_refine_ls_structure_factor_coef F
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_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            b106050n.txt
_cod_data_source_block           '_Cu-dimer'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        3409.1(5)
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C91 H62 Cu2 N8 '
_cod_database_code               7115019