Heterobimetallic μ-Oxido Complexes Containing Discrete V(V)-O-M(III) (M = Mn, Fe) Cores: Targeted Synthesis, Structural Characterization, and Redox Studies.
Bhattacharya, Kisholoy; Abtab, Sk Md Towsif; Majee, Mithun Chandra; Endo, Akira; Chaudhury, Muktimoy; Inorganic chemistry 53 (2014) 8287–8297; doi:10.1021/ic501563r

data_4340778
_publ_section_title
;
 Heterobimetallic \m-Oxido Complexes Containing Discrete V(V)-O-M(III) (M
 = Mn, Fe) Cores: Targeted Synthesis, Structural Characterization, and
 Redox Studies.
;
_journal_issue                   16
_journal_name_full               'Inorganic chemistry'
_journal_page_first              8287
_journal_page_last               8297
_journal_paper_doi               10.1021/ic501563r
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C58 H58 Fe2 N10 O14 S4 V2'
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_chemical_name_systematic
;
 ?
;
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_symmetry_space_group_name_Hall  '-P 1'
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_cell_measurement_temperature    150(2)
_cell_volume                     1546.0(2)
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.652
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_diffrn_radiation_type           MoK\a
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_exptl_absorpt_coefficient_mu    0.961
_exptl_crystal_colour            BROWN
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
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_refine_ls_number_reflns         3644
_refine_ls_number_restraints     72
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.1637P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                2261
_reflns_number_total             3644
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ic501563r_si_002.cif
_cod_data_source_block           6
_cod_depositor_comments
'Adding full bibliography for 4340774--4340778.cif.'
_cod_database_code               4340778
_shelx_estimated_absorpt_t_min   0.809
_shelx_estimated_absorpt_t_max   0.854
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