Reactivity of p-Toluenesulfonylmethyl Isocyanide: Iron-Involved C-H Tosylmethylation of Imidazopyridines in Nontoxic Media.
Lu, Shuai; Zhu, Xinju; Li, Ke; Guo, Yu-Jing; Wang, Meng-Dan; Zhao, Xue-Mei; Hao, Xin-Qi; Song, Mao-Ping; The Journal of organic chemistry 81 (2016) 8370–8377; doi:10.1021/acs.joc.6b01552

data_4037114
_publ_section_title
;
 Reactivity of p-Toluenesulfonylmethyl Isocyanide: Iron-Involved C-H
 Tosylmethylation of Imidazopyridines in Nontoxic Media.
;
_journal_issue                   18
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              8370
_journal_page_last               8377
_journal_paper_doi               10.1021/acs.joc.6b01552
_journal_volume                  81
_journal_year                    2016
_chemical_formula_sum            'C22 H20 Cl2 N2 O2 S'
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_cell_length_b                   12.521(3)
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_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      25.67
_cell_measurement_theta_min      2.22
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      294(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_h_max       16
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_diffrn_reflns_theta_min         2.217
_exptl_absorpt_coefficient_mu    0.414
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_exptl_crystal_description       block
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_refine_diff_density_rms         0.099
_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_total             5036
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            jo6b01552_si_002.cif
_cod_data_source_block           a-auto
_cod_original_cell_volume        2183.3(11)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4037114
_shelx_shelxl_version_number     2014/7
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