Dual ligand-based fluorescence and phosphorescence emission at room temperature from platinum thioxanthonyl complexes.
Geist, Fabian; Jackel, Andrej; Winter, Rainer F.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 3974–3987; doi:10.1039/c4dt02410a

data_7032880
_publ_section_title
;
 Dual ligand-based fluorescence and phosphorescence emission at room
 temperature from platinum thioxanthonyl complexes.
;
_journal_issue                   9
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3974
_journal_page_last               3987
_journal_paper_doi               10.1039/c4dt02410a
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C26 H37 N O P2 Pt S'
_chemical_formula_sum            'C26 H37 N O P2 Pt S'
_chemical_formula_weight         668.66
_chemical_name_systematic
; 
 ? 
;
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_symmetry_space_group_name_Hall  '-P 1'
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_cell_measurement_theta_min      1.62
_cell_volume                     1320.66(16)
_computing_cell_refinement       'STOE X-AREA'
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_computing_molecular_graphics    'ORTEP (Johnson, 1965)'
_computing_publication_material  'PLATON (Spek, 2003)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'STOE IPDS 2T'
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_diffrn_radiation_monochromator  graphite
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_exptl_crystal_density_method    'not measured'
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_exptl_crystal_preparation       Luminescent
_exptl_crystal_size_max          0.300
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_refine_ls_number_reflns         5594
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.099
_refine_ls_R_factor_all          0.0432
_refine_ls_R_factor_gt           0.0351
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0431P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt02410a2.cif
_cod_data_source_block           fgbw09
_cod_depositor_comments
'Adding full bibliography for 7032879--7032880.cif.'
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7032880