Multi-stimuli responsive behavior of two Zn(ii) complexes based on a Schiff base with high contrast
Xia, Zhong-Gang; Shi, Yong-Sheng; Xiao, Tong; Zheng, Xiang-Jun; CrystEngComm 26 (2024) 1015–1021; doi:10.1039/D3CE01214J

data_7248028
_publ_section_title
;
 Multi-stimuli responsive behavior of two Zn(ii) complexes based on a
 Schiff base with high contrast
;
_journal_issue                   7
_journal_name_full               CrystEngComm
_journal_page_first              1015
_journal_page_last               1021
_journal_paper_doi               10.1039/D3CE01214J
_journal_volume                  26
_journal_year                    2024
_chemical_formula_sum            'C25 H23 Br2 N3 O2 Zn'
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_space_group_name_Hall           '-P 1'
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_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2023-04-07 deposited with the CCDC.	2024-01-15 downloaded from the CCDC.
;
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_cell_formula_units_Z            2
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_cell_length_b                   11.9818(4)
_cell_length_c                   14.0657(4)
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.827
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.827
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_diffrn_reflns_limit_k_max       15
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_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -14
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_diffrn_reflns_theta_max         29.918
_diffrn_reflns_theta_min         3.383
_exptl_absorpt_coefficient_mu    4.312
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     300
_refine_ls_number_reflns         5835
_refine_ls_number_restraints     0
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0529P)^2^+0.1301P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3ce01214j2.cif
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_cod_depositor_comments
'Adding full bibliography for 7248027--7248028.cif.'
_cod_original_cell_volume        1219.17(7)
_cod_database_code               7248028
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.358
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_shelx_res_checksum              46280