A dynamic tetranuclear gold(i)-cyclophane - gold(i)-centred chirality and fluxionality arising from an intramolecular shift of Au-S bonds.
Ang, Pau Lin; Nguyen, Van Ha; Yip, John H. K.; Dalton transactions (Cambridge, England : 2003) 50 (2021) 11422–11428; doi:10.1039/d1dt01984h

data_7707949
_publ_section_title
;
 A dynamic tetranuclear gold(i)-cyclophane - gold(i)-centred chirality and
 fluxionality arising from an intramolecular shift of Au-S bonds.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11422
_journal_page_last               11428
_journal_paper_doi               10.1039/d1dt01984h
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C96 H84 Au4 O2 P4 S4'
_chemical_formula_weight         2309.61
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_audit_update_record
;
2021-06-15 deposited with the CCDC.	2021-07-16 downloaded from the CCDC.
;
_cell_angle_alpha                109.2250(16)
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_diffrn_source                   'Microfocus Sealed Tube'
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_exptl_crystal_colour            Red
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_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'Not Measured'
_exptl_crystal_description       Thin_Plate
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0281P)^2^+3.3396P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0582
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_reflns_Friedel_coverage         0.000
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_reflns_number_total             10343
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_exptl_crystal_density_meas' value 'Not Measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7707949.cif.
;
_cod_database_code               7707949
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_shelx_estimated_absorpt_t_min   0.325
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