Stereochemical Course of Deprotonation-Acylation of N-Boc- and N-Carbamoyl-2-cyano-6-methylpiperidines.
Kotomori, Yuri; Sasaki, Michiko; Kawahata, Masatoshi; Yamaguchi, Kentaro; Takeda, Kei; The Journal of organic chemistry 80 (2015) 11013–11020; doi:10.1021/acs.joc.5b02178

data_4036479
_publ_section_title
;
 Stereochemical Course of Deprotonation-Acylation of N-Boc- and
 N-Carbamoyl-2-cyano-6-methylpiperidines.
;
_journal_issue                   21
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              11013
_journal_page_last               11020
_journal_paper_doi               10.1021/acs.joc.5b02178
_journal_volume                  80
_journal_year                    2015
_chemical_formula_sum            'C17 H21 N3 O2'
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_space_group_name_H-M_alt        'P 1 21/n 1'
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_cell_length_c                   15.9110(17)
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_cell_measurement_temperature    100
_cell_measurement_theta_max      26.32
_cell_measurement_theta_min      2.21
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_diffrn_measured_fraction_theta_max 0.930
_diffrn_measurement_device_type  'Bruker APEX II CCD area detector'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_av_R_equivalents  0.0172
_diffrn_reflns_av_unetI/netI     0.0127
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_diffrn_reflns_theta_min         2.205
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_exptl_absorpt_coefficient_mu    0.083
_exptl_absorpt_correction_type   none
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0379P)^2^+0.5185P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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