Two pH-directed coordination polymers of cadmium isomers based on a semi-rigid polycarboxylic acid: crystal structure and fluorescence sensing of tetracyclines
Li, Shaodong; Li, Mengzhao; Li, Jia; Zhang, Yang; Su, Feng; Ma, Longlong; Wang, Guangyan; Li, Xinlei; Wang, Zhijun; CrystEngComm 27 (2025) 2354–2365; doi:10.1039/D5CE00103J

data_7250060
_publ_section_title
;
 Two pH-directed coordination polymers of cadmium isomers based on a
 semi-rigid polycarboxylic acid: crystal structure and fluorescence
 sensing of tetracyclines
;
_journal_issue                   15
_journal_name_full               CrystEngComm
_journal_page_first              2354
_journal_page_last               2365
_journal_paper_doi               10.1039/D5CE00103J
_journal_volume                  27
_journal_year                    2025
_chemical_formula_moiety         'C36 H24 Cd2 N4 O10'
_chemical_formula_sum            'C36 H24 Cd2 N4 O10'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2025-01-24 deposited with the CCDC.	2025-03-03 downloaded from the CCDC.
;
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_computing_cell_refinement       'Bruker SAINT'
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0656
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_exptl_absorpt_coefficient_mu    1.362
_exptl_absorpt_correction_type   none
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_exptl_crystal_description       block
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0800P)^2^+1.0924P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1318
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4367
_reflns_number_total             5814
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7250060--7250061.cif.'
_cod_database_code               7250060
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              5014