Mechano-induced reversible colour and luminescence switching of a gold(i)-diphosphine complex.
Baranyai, Péter; Marsi, Gábor; Jobbágy, Csaba; Domján, Attila; Oláh, Laura; Deák, Andrea; Dalton transactions (Cambridge, England : 2003) 44 (2015) 13455–13459; doi:10.1039/c5dt01795e

data_7035575
_publ_section_title
;
 Mechano-induced reversible colour and luminescence switching of a
 gold(i)-diphosphine complex.
;
_journal_issue                   30
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13455
_journal_page_last               13459
_journal_paper_doi               10.1039/c5dt01795e
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C37 H27 Au N2 O P2 S'
_chemical_formula_sum            'C37 H27 Au N2 O P2 S'
_chemical_formula_weight         806.57
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-06-15 deposited with the CCDC.
2015-06-26 downloaded from the CCDC.
;
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_cell_angle_gamma                110.6760(10)
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_cell_length_c                   13.2977(5)
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_cell_measurement_theta_min      3.06
_cell_volume                     1530.04(13)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_molecular_graphics    'PLATON (Spek, 2014)'
_computing_publication_material  'WinGX (Farrugia, 2014), PLATON (Spek, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SIR92 (Altomare <i>et al.</i>, 1994)'
_diffrn_ambient_temperature      93(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'R Axis Rapid'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0596
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_diffrn_reflns_laue_measured_fraction_full 0.999
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrystalClear (Rigaku/MSC, 2005)'
_exptl_crystal_colour            colorless
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+14.2861P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0658
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                7252
_reflns_number_total             8213
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt01795e2.cif
_cod_data_source_block           Au_nixantphos_SCN
_cod_depositor_comments          'Adding full bibliography for 7035575.cif.'
_cod_original_cell_volume        1530.04(12)
_cod_database_code               7035575
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