Reactions of the Eight-Coordinate Rhenium Complex ReH4(hq)(PPh3)2 (hq = 2-Hydroxyquinoline Monoanion) with Monodentate Tertiary Phosphines: Formation of Pentagonal Bipyramidal Dihydridorhenium(III) Complexes of the Type ReH2(hq)(PPh3)2(PR3)
Talia M. McKinney; Phillip E. Fanwick; Richard A. Walton; Inorganic Chemistry 38 (1999) 1548–1554; doi:10.1021/ic981155z

data_4321884
_publ_contact_author
;
     Richard A. Walton
     Department of Chemistry
     Purdue University
     1393 Brown Building
     W. Lafayette
     IN 47907
     USA
;
_publ_contact_author_email       walton@chem.purdue.edu
_publ_contact_author_fax         '(765) 494 0239'
_publ_contact_author_phone       '(765) 494 5464'
_publ_section_title
;
 Reactions of the Eight-Coordinate Rhenium Complex ReH4(hq)(PPh3)2 (hq =
 2-Hydroxyquinoline Monoanion) with Monodentate Tertiary Phosphines:
 Formation of Pentagonal Bipyramidal Dihydridorhenium(III) Complexes of
 the Type ReH2(hq)(PPh3)2(PR3)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1548
_journal_page_last               1554
_journal_paper_doi               10.1021/ic981155z
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C63 H53 N O P3 Re'
_chemical_formula_weight         1119.25
_chemical_name_systematic        ' ?'
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_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_type_scat_source
'International Tables for Crystallography (Vol C) '
_cell_angle_alpha                90.00
_cell_angle_beta                 101.837(6)
_cell_angle_gamma                90.00
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_cell_length_a                   17.9318(15)
_cell_length_b                   12.8195(11)
_cell_length_c                   22.2897(13)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296
_cell_measurement_theta_max      46
_cell_measurement_theta_min      40
_cell_volume                     5014.9(7)
_computing_cell_refinement       CAD4_(Enraf-Nonius,_1977)
_computing_data_collection       CAD4_(Enraf-Nonius,_1977)
_computing_data_reduction        PROCESS_MolEN_(Fair,_1990)
_computing_molecular_graphics
;
    ORTEP (Johnson, 1976)
    Xtal_GX (Hall, 1995)
    PLUTON (Spek, 1991)
;
_computing_publication_material  CIF_VAX_MolEN_(Fair,_1990)
_computing_structure_refinement  LSFM_MolEN_(Fair,_1990)
_computing_structure_solution    PATTY_(DIRDIF92,_Beurskins,_1992)
_diffrn_ambient_temperature      296
_diffrn_measurement_device_type  Enraf_Nonius_CAD4
_diffrn_measurement_method       \q/2\q
_diffrn_radiation_type           Cu-K\a
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_diffrn_reflns_limit_k_max       0
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_diffrn_reflns_limit_l_min       -25
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_diffrn_standards_decay_%        1.95
_diffrn_standards_interval_time  83
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.817
_exptl_absorpt_correction_T_max  0.5590
_exptl_absorpt_correction_T_min  0.3322
_exptl_absorpt_correction_type   refdelf_(Walker_&_Stuart,_1983)
_exptl_crystal_colour            orange
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_exptl_crystal_description       needle
_exptl_crystal_F_000             2264
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.15
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_refine_diff_density_min         -0.16
_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     '4Fo^2^/ (\s^2^(Fo^2^) + 0.0025 Fo^4^)'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.039
_reflns_number_gt                6202
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_reflns_threshold_expression     >3.0\s(I)
_cod_data_source_file            ic981155z_3.cif
_cod_data_source_block           Compound4
_cod_original_cell_volume        5014.9(13)
_cod_original_formula_sum        'C63 H53 N1 O1 P3 Re1'
_cod_database_code               4321884