1,3-Iodo-amination of 2-methyl indoles via C<sub>sp<sup>2</sup></sub>-C<sub>sp<sup>3</sup></sub> dual functionalization with iodine reagent.
Moriyama, Katsuhiko; Hamada, Tsukasa; Ishida, Kazuma; Togo, Hideo; Chemical communications (Cambridge, England) 54 (2018) 4258–4261; doi:10.1039/c8cc00352a

data_7121264
_publ_section_title
;
 1,3-Iodo-amination of 2-methyl indoles via
 C<sub>sp<sup>2</sup></sub>-C<sub>sp<sup>3</sup></sub> dual
 functionalization with iodine reagent.
;
_journal_issue                   34
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              4258
_journal_page_last               4261
_journal_paper_doi               10.1039/c8cc00352a
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C30 H35 N5 O8 S'
_chemical_formula_weight         625.69
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_update_record
;
2017-12-07 deposited with the CCDC.
2018-02-09 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_computing_molecular_graphics    'XSHEL (Bruker AXS,2002)'
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_diffrn_ambient_temperature      173
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_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker APEXII CCD area detector'
_diffrn_measurement_method       'Phi and Omega scans'
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_diffrn_reflns_limit_l_min       -23
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0683P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1090
_refine_ls_wR_factor_ref         0.1286
_reflns_number_gt                4581
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7121262--7121264.cif.'
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