Multifaceted approach for the fabrication of metallomicelles and metallic nanoparticles using solvophobic bisdodecylaminepalladium (II) chloride as precursor.
Chaudhary, Ganga Ram; Singh, Prabjot; Kaur, Gurpreet; Mehta, S. K.; Kumar, Sandeep; Dilbaghi, Neeraj; Inorganic chemistry 54 (2015) 9002–9012; doi:10.1021/acs.inorgchem.5b01171

data_4346280
_publ_section_title
;
 Multifaceted approach for the fabrication of metallomicelles and metallic
 nanoparticles using solvophobic bisdodecylaminepalladium (II) chloride as
 precursor.
;
_journal_issue                   18
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9002
_journal_page_last               9012
_journal_paper_doi               10.1021/acs.inorgchem.5b01171
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'C24 H54 Cl2 N2 Pd'
_chemical_formula_sum            'C24 H54 Cl2 N2 Pd'
_chemical_formula_weight         547.99
_chemical_name_common            Pdamine
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90
_cell_angle_beta                 92.428(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   5.8218(4)
_cell_length_b                   7.0123(5)
_cell_length_c                   34.528(2)
_cell_measurement_reflns_used    1467
_cell_measurement_temperature    296.(2)
_cell_measurement_theta_max      26.8388
_cell_measurement_theta_min      1.2145
_cell_volume                     1408.31(16)
_computing_cell_refinement       'APEX2 v2010.11-3 (Bruker AXS)'
_computing_data_collection       'APEX 2 (Bruker)'
_computing_data_reduction        'SAINT V7.68A (Bruker AXS, 2009)'
_computing_molecular_graphics    'SHELXTL (Bruker AXS)'
_computing_publication_material  'SHELXTL (Bruker AXS)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296.(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker Kappa APEX II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0357
_diffrn_reflns_av_sigmaI/netI    0.0343
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -3
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_limit_l_min       -40
_diffrn_reflns_number            8991
_diffrn_reflns_theta_full        25.10
_diffrn_reflns_theta_max         25.10
_diffrn_reflns_theta_min         1.18
_diffrn_source                   'fine focus'
_diffrn_source_type              'sealed tube'
_exptl_absorpt_coefficient_mu    0.861
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.6524
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.292
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'rod shaped'
_exptl_crystal_F_000             584
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.300
_refine_diff_density_max         0.316
_refine_diff_density_min         -0.451
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.991
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     134
_refine_ls_number_reflns         2495
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.991
_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0264
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0677P)^2^+0.3593P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0835
_refine_ls_wR_factor_ref         0.1038
_reflns_number_gt                2024
_reflns_number_total             2495
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic5b01171_si_002.cif
_cod_data_source_block           I
_cod_original_cell_volume        1408.31(17)
_cod_database_code               4346280