Endoplasmic reticulum targeted chemotherapeutics: the remarkable photo-cytotoxicity of an oxovanadium(IV) vitamin-B6 complex in visible light
Samya Banerjee; Akanksha Dixit; Radhika N. Shridharan; Anjali A. Karande; Akhil R. Chakravarty; Chem.Commun. 50 (2014) 5590–; doi:10.1039/C4CC02093F

data_7113327
_publ_section_title
;
 Endoplasmic reticulum targeted chemotherapeutics: the remarkable
 photo-cytotoxicity of an oxovanadium(IV) vitamin-B6 complex in visible
 light
;
_journal_name_full               Chem.Commun.
_journal_page_first              5590
_journal_paper_doi               10.1039/C4CC02093F
_journal_volume                  50
_journal_year                    2014
_chemical_formula_moiety         'C26 H27 Cl N4 O9 V'
_chemical_formula_sum            'C26 H27 Cl N4 O9 V'
_chemical_formula_weight         625.91
_chemical_name_systematic
;
 ?
;
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_cell_angle_beta                 77.535(5)
_cell_angle_gamma                84.902(6)
_cell_formula_units_Z            2
_cell_length_a                   9.4205(5)
_cell_length_b                   11.9369(11)
_cell_length_c                   13.5029(11)
_cell_measurement_temperature    293(2)
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_computing_cell_refinement       'Bruker Smart'
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_computing_data_reduction        'Bruker Saint'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 0.3
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker Smart CCD Area Detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_k_min       -15
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_diffrn_reflns_limit_l_min       -17
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_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         2.49
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_exptl_absorpt_correction_T_min  0.7471
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_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Brown
_exptl_crystal_density_diffrn    1.504
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Hexagonal
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         6319
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_refine_ls_R_factor_all          0.0862
_refine_ls_R_factor_gt           0.0578
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0503P)^2^+0.8166P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1246
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_cod_data_source_file            c4cc02093f2.cif
_cod_data_source_block           ARC_CCOM_sb
_cod_original_cell_volume        1381.80(19)
_cod_database_code               7113327