In situ generation of Ph<sub>3</sub>PO in cyanido-bridged heterometallic {Fe<sup>III</sup>Ln<sup>III</sup>}<sub>2</sub> molecular squares (Ln = Eu, Sm).
Alexandru, Maria-Gabriela; Visinescu, Diana; Braun-Cula, Beatrice; Shova, Sergiu; Lloret, Francesc; Julve, Miguel; Dalton transactions (Cambridge, England : 2003) 48 (2019) 7532–7536; doi:10.1039/c9dt01445d

data_7049858
_publ_section_title
;
 In situ generation of Ph<sub>3</sub>PO in cyanido-bridged heterometallic
 {Fe<sup>III</sup>Ln<sup>III</sup>}<sub>2</sub> molecular squares (Ln =
 Eu, Sm).
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7532
_journal_page_last               7536
_journal_paper_doi               10.1039/c9dt01445d
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C76 H62 B2 Fe2 N28 O14 P2 Sm2, 2(C2 H3 N)'
_chemical_formula_sum            'C80 H68 B2 Fe2 N30 O14 P2 Sm2'
_chemical_formula_weight         2169.60
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_audit_creation_method           SHELXL-2013
_audit_update_record
;
2019-04-04 deposited with the CCDC.    2019-04-25 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick 2013)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 VENTURE'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0281
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_diffrn_reflns_Laue_measured_fraction_full 0.978
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0163P)^2^+4.6753P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                7639
_reflns_number_total             7801
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt01445d2.cif
_cod_data_source_block           FeSmP
_cod_depositor_comments
'Adding full bibliography for 7049857--7049858.cif.'
_cod_database_code               7049858
_shelx_estimated_absorpt_t_min   0.668
_shelx_estimated_absorpt_t_max   0.858
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