Dicopper(II) Complexes of H-BPMP-Type Ligands: pH-Induced Changes of Redox, Spectroscopic (19F NMR Studies of Fluorinated Complexes), Structural Properties, and Catecholase Activities
C. Belle; C. Beguin; I. Gautier-Luneau; S. Hamman; C. Philouze; J. L. Pierre; F. Thomas; S. Torelli; E. Saint-Aman; M. Bonin; Inorganic Chemistry 41 (2002) 479–491; doi:10.1021/ic010534g

data_4317479
_publ_contact_author_address
;
Laboratoire de Chimie Biomim\'etique 
(LEDSS, UMR CNRS 5616)
Universit\'e J. Fourier, BP 53, 38041 Grenoble Cedex 9 - France
;
_publ_contact_author_email       ' Catherine.Belle@ujf-grenoble.fr '
_publ_contact_author_name        ' Catherine BELLE '
_publ_section_title
;
 Dicopper(II) Complexes of H-BPMP-Type Ligands: pH-Induced Changes of
 Redox, Spectroscopic (19F NMR Studies of Fluorinated Complexes),
 Structural Properties, and Catecholase Activities
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              479
_journal_page_last               491
_journal_paper_doi               10.1021/ic010534g
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C16.5 H21 Cl1.5 Cu F1.5 N3 O9.5'
_chemical_formula_weight         558.58
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_symmetry_space_group_name_Hall  '-P 2n 2ab'
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_cell_angle_gamma                90
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_cell_length_c                   16.822(4)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    293
_cell_measurement_theta_max      0.0
_cell_measurement_theta_min      0.0
_cell_volume                     4490(2)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
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_refine_ls_shift/su_max          0.1030
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00040|Fo|^2^]'
_refine_ls_weighting_scheme      sigma
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_reflns_threshold_expression     I>2.00\s(I)
_cod_data_source_file            ic010534g_3.cif
_cod_data_source_block           '[Cu2(LCF3)(H2O)2]3+'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'P b c n '
_cod_original_formula_sum        'C16.50 H21 Cl1.50 Cu F1.50 N3 O9.50 '
_cod_database_code               4317479