Dendrimer N-heterocyclic carbene complexes with rhodium(I) at the core.
Fujihara, Tetsuaki; Obora, Yasushi; Tokunaga, Makoto; Sato, Hiromichi; Tsuji, Yasushi; Chemical communications (Cambridge, England)  (2005) 4526–4528; doi:10.1039/b506927k

data_7113351
_publ_section_title
;
 Dendrimer N-heterocyclic carbene complexes with rhodium(I) at the core.
;
_journal_issue                   36
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              4526
_journal_page_last               4528
_journal_paper_doi               10.1039/b506927k
_journal_year                    2005
_chemical_formula_moiety         'C54 H54 Cl3 N2 O4 Rh '
_chemical_formula_sum            'C54 H54 Cl3 N2 O4 Rh'
_chemical_formula_weight         1004.30
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                98.94(2)
_cell_angle_beta                 101.480(10)
_cell_angle_gamma                91.966(11)
_cell_formula_units_Z            2
_cell_length_a                   10.936(8)
_cell_length_b                   12.458(9)
_cell_length_c                   17.56(1)
_cell_measurement_reflns_used    8102
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     2311(3)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.6.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 14.63
_diffrn_measured_fraction_theta_full 0.9242
_diffrn_measured_fraction_theta_max 0.9242
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.038
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            17258
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.592
_exptl_absorpt_correction_T_max  0.971
_exptl_absorpt_correction_T_min  0.654
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            pale-Yellow
_exptl_crystal_density_diffrn    1.443
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1040.00
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         3.54
_refine_diff_density_min         -3.19
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     629
_refine_ls_number_reflns         12898
_refine_ls_R_factor_gt           0.0620
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0010Fo^2^ + 3.0000\s(Fo^2^) + 0.5000]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1590
_reflns_number_gt                12898
_reflns_number_total             16694
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b506927k.txt
_cod_data_source_block           2b
_cod_original_cell_volume        2310.8(30)
_cod_original_formula_sum        'C54 H54 Cl3 N2 O4 Rh '
_cod_database_code               7113351