Copper-Catalyzed Radical C-C Bond Cleavage and [4+1] Annulation Cascade of Cycloketone Oxime Esters with Enaminothiones.
He, Yuan; Lou, Jiang; Wu, Kaikai; Wang, Hongmei; Yu, Zhengkun; The Journal of organic chemistry 84 (2019) 2178–2190; doi:10.1021/acs.joc.8b03175

data_4033787
_publ_section_title
;
 Copper-Catalyzed Radical C-C Bond Cleavage and [4+1] Annulation Cascade
 of Cycloketone Oxime Esters with Enaminothiones.
;
_journal_issue                   4
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              2178
_journal_page_last               2190
_journal_paper_doi               10.1021/acs.joc.8b03175
_journal_volume                  84
_journal_year                    2019
_chemical_formula_sum            'C20 H18 N2 S'
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_diffrn_measured_fraction_theta_max 0.998
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_diffrn_measurement_method       'CrysAlisPro 1.171.39.38a (Rigaku OD, 2017)'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0497P)^2^+0.1716P] where P=(Fo^2^+2Fc^2^)/3'
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