Formation of U(VI) peroxide nanoclusters from cascade reactions with a persulfate radical initiator.
Samarasiri, Vidumini S.; Rajapaksha, Harindu; McGee, Sarah; Mason, Sara E.; Forbes, Tori Z.; Dalton transactions (Cambridge, England : 2003) 54 (2025) 13129–13142; doi:10.1039/d5dt00785b

data_1575257
_publ_section_title
;
 Formation of U(VI) peroxide nanoclusters from cascade reactions with a
 persulfate radical initiator.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13129
_journal_page_last               13142
_journal_paper_doi               10.1039/d5dt00785b
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'Na24 O180 U24'
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;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_audit_update_record
;
2025-03-24 deposited with the CCDC.	2025-07-28 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_diffrn_measurement_device_type  'Bruker Photon-III CCD'
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_diffrn_radiation_type           MoK\a
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_exptl_absorpt_coefficient_mu    22.655
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0372P)^2^+167.1439P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5dt00785b2.cif
_cod_data_source_block           1
_cod_depositor_comments          'Adding full bibliography for 1575257.cif.'
_cod_original_cell_volume        8614.7(6)
_cod_database_code               1575257
_shelx_shelxl_version_number     2019/1
_olex2_refinement_description
;
1. Others
 Fixed Sof: Na5A(0.125) Na5B(0.125) O20A(0.5) O20B(0.25) O21(0.5) O22(0.5)
 O23(0.5) O24A(0.25) O24B(0.25) O25(0.25) O26(0.5) O27(0.5) O28(0.5) O30(0.5)
 O31(0.25)
;
_shelx_res_checksum              7775
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_olex2_submission_special_instructions 'No special instructions were received'