3,4-Lutidinium salts with the diiodidoaurate(I) anion: structure of [(3,4-lut)<sub>2</sub>H]<sup>+</sup>·[AuI<sub>2</sub>]<sup>-</sup> and of two polymorphs of [(3,4-lut)<sub>2</sub>H<sup>+</sup>]<sub>2</sub>·[AuI<sub>2</sub>]<sup>-</sup>·I<sup/>.
Döring, Cindy; Sui, Zhihong; Jones, Peter G.; Acta crystallographica. Section C, Structural chemistry 74 (2018) 289–294; doi:10.1107/S2053229618002218

data_2311984
_publ_section_title
;
 3,4-Lutidinium salts with the diiodidoaurate(I) anion: structure of
 [(3,4-lut)<sub>2</sub>H]<sup>+</sup>&#x00B7;[AuI<sub>2</sub>]<sup>-</sup>
 and of two polymorphs of
 [(3,4-lut)<sub>2</sub>H<sup>+</sup>]<sub>2</sub>&#x00B7;[AuI<sub>2</sub>]<sup>-</sup>&#x00B7;I<sup/>.
;
_journal_coeditor_code           KY3135
_journal_issue                   'Pt 3'
_journal_name_full
'Acta crystallographica. Section C, Structural chemistry'
_journal_page_first              289
_journal_page_last               294
_journal_paper_doi               10.1107/S2053229618002218
_journal_volume                  74
_journal_year                    2018
_chemical_formula_iupac          '(C14 H19 N2) [Au I2]'
_chemical_formula_moiety         'C14 H19 N2 +, Au I2 -'
_chemical_formula_sum            'C14 H19 Au I2 N2'
_chemical_formula_weight         666.08
_chemical_name_systematic
;
3,4-Dimethylpyridine--3,4-dimethylpyridinium diiodidoaurate(I)
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           13
_space_group_name_Hall           '-P 2yc'
_space_group_name_H-M_alt        'P 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2017/1
_cell_angle_alpha                90
_cell_angle_beta                 116.528(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.5270(5)
_cell_length_b                   7.468020(10)
_cell_length_c                   17.0254(5)
_cell_measurement_reflns_used    24363
_cell_measurement_temperature    105(2)
_cell_measurement_theta_max      30.7850
_cell_measurement_theta_min      2.6600
_cell_volume                     1766.35(10)
_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_molecular_graphics
;
XP (Siemens, 1994)
;
_computing_publication_material
;
SHELXL2017 (Sheldrick, 2015)
;
_computing_structure_refinement
;
SHELXL2017 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXL97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      105(2)
_diffrn_detector_area_resol_mean 16.1419
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.956
_diffrn_measurement_device_type  'Oxford Diffraction Xcalibur Eos'
_diffrn_measurement_method       \w-scan
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0484
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            90918
_diffrn_reflns_theta_full        30.000
_diffrn_reflns_theta_max         31.130
_diffrn_reflns_theta_min         2.408
_exptl_absorpt_coefficient_mu    11.815
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.55791
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Rigaku OD, 2015)
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.505
_exptl_crystal_description       block
_exptl_crystal_F_000             1208
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.071
_refine_diff_density_min         -1.178
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.098
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     182
_refine_ls_number_reflns         5434
_refine_ls_number_restraints     9
_refine_ls_restrained_S_all      1.097
_refine_ls_R_factor_all          0.0270
_refine_ls_R_factor_gt           0.0207
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0148P)^2^+1.8741P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0396
_refine_ls_wR_factor_ref         0.0411
_reflns_number_gt                4885
_reflns_number_total             5434
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ky3135sup1.cif
_cod_data_source_block           1
_cod_original_cell_volume        1766.34(10)
_cod_original_sg_symbol_H-M      'P 2/c'
_cod_database_code               2311984
_shelx_estimated_absorpt_t_min   0.385
_shelx_estimated_absorpt_t_max   0.492
_shelx_hkl_checksum              7887
_shelx_res_checksum              37171