Mixed N-Heterocyclic Carbene‒Bis(oxazolinyl)borato Rhodium and Iridium Complexes in Photochemical and Thermal Oxidative Addition Reactions
Xu, Songchen; Manna, Kuntal; Ellern, Arkady; Sadow, Aaron D.; Organometallics 33 (2014) 6840–; doi:10.1021/om500891h

data_4084799
_publ_section_title
;
 Mixed N-Heterocyclic Carbene--Bis(oxazolinyl)borato Rhodium and Iridium
 Complexes in Photochemical and Thermal Oxidative Addition Reactions
;
_journal_issue                   23
_journal_name_full               Organometallics
_journal_page_first              6840
_journal_paper_doi               10.1021/om500891h
_journal_volume                  33
_journal_year                    2014
_chemical_formula_sum            'C29 H34 B N4 O3 Rh'
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_chemical_name_systematic
; 
 ? 
;
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_diffrn_ambient_temperature      173(2)
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_diffrn_measured_fraction_theta_max 0.993
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_exptl_absorpt_process_details   ' BRUKER TWINABS'
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_refine_ls_R_factor_all          0.0362
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0669P)^2^+0.4874P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           12ImMesRhHCO_twin5
_cod_depositor_comments
'Adding full bibliography for 4084789--4084803.cif.'
_cod_database_code               4084799
_shelx_estimated_absorpt_t_min   0.854
_shelx_estimated_absorpt_t_max   0.926
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