Selective Reduction of CO2 to CH4 by Tandem Hydrosilylation with Mixed Al/B Catalysts.
Chen, Jiawei; Falivene, Laura; Caporaso, Lucia; Cavallo, Luigi; Chen, Eugene Y.-X.; Journal of the American Chemical Society 138 (2016) 5321–5333; doi:10.1021/jacs.6b01497

data_4130250
_publ_section_title
;
 Selective Reduction of CO2 to CH4 by Tandem Hydrosilylation with Mixed
 Al/B Catalysts.
;
_journal_issue                   16
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5321
_journal_page_last               5333
_journal_paper_doi               10.1021/jacs.6b01497
_journal_volume                  138
_journal_year                    2016
_chemical_formula_moiety         'C25 H16 Al F15 O2 Si'
_chemical_formula_sum            'C25 H16 Al F15 O2 Si'
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_cell_length_b                   14.910(6)
_cell_length_c                   15.662(6)
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_cell_measurement_temperature    120(2)
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_diffrn_ambient_temperature      120(2)
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_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'Bruker SMART CCD Apex-II area-detector'
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_diffrn_reflns_av_R_equivalents  0.0424
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_exptl_absorpt_coefficient_mu    0.243
_exptl_absorpt_correction_type   none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0170P)^2^+2.4817P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_original_cell_volume        2759(2)
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_shelx_hkl_checksum              37249