Photocatalyzed Dowd-Beckwith radical-polar crossover reaction for the synthesis of medium-sized carbocyclic compounds.
Singha, Tushar; Kadam, Ganesh Arjun; Hari, Durga Prasad; Chemical science 14 (2023) 6930–6935; doi:10.1039/d3sc01908j

data_1569214
_publ_section_title
;
 Photocatalyzed Dowd-Beckwith radical-polar crossover reaction for the
 synthesis of medium-sized carbocyclic compounds.
;
_journal_issue                   25
_journal_name_full               'Chemical science'
_journal_page_first              6930
_journal_page_last               6935
_journal_paper_doi               10.1039/d3sc01908j
_journal_volume                  14
_journal_year                    2023
_chemical_formula_moiety         'C22 H26 O4'
_chemical_formula_sum            'C22 H26 O4'
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_chemical_name_common            Cycloheptanone
_chemical_name_systematic
3-phenyl-3-(2,4,6-trimethoxyphenyl)cycloheptan-1-one
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
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_audit_update_record
;
2023-05-18 deposited with the CCDC.	2023-05-25 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker D8 Quest'
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_exptl_crystal_description       block
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0435P)^2^+4.9479P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 1569214--1569215.cif.'
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