Variable Coordination Modes of NO2- in a Series of Ag(I) Complexes Containing Triorganophosphines, -arsines, and -stibines. Syntheses, Spectroscopic Characterization (IR, 1H and 31P NMR, Electrospray Ionization Mass), and Structures of [AgNO2(R3E)x] Adducts (E = P, As, Sb, x = 1-3)
Augusto Cingolani; Effendy; Maura Pellei; Claudio Pettinari; Carlo Santini; Brian W. Skelton; Allan H. White; Inorganic Chemistry 41 (2002) 6633–6645; doi:10.1021/ic020375g

data_4318995
_publ_contact_author_address
;
  Department of Chemistry
  University of Western Australia
  35 Stirling Highway
  Crawley
  Western Australia 6009
  Australia
;
_publ_contact_author_email       bws@crystal.uwa.edu.au
_publ_contact_author_fax         (+61)_08_9380_1118
_publ_contact_author_name        'Skelton, B. W.'
_publ_contact_author_phone       (+61)_08-9380_3481
_publ_section_title
;
 Variable Coordination Modes of NO2- in a Series of Ag(I) Complexes
 Containing Triorganophosphines, -arsines, and -stibines. Syntheses,
 Spectroscopic Characterization (IR, 1H and 31P NMR, Electrospray
 Ionization Mass), and Structures of [AgNO2(R3E)x] Adducts (E = P, As, Sb,
 x = 1-3)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6633
_journal_page_last               6645
_journal_paper_doi               10.1021/ic020375g
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C21 H21 Ag N O2 P'
_chemical_formula_weight         458.25
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_cell_angle_alpha                90.00000
_cell_angle_beta                 90.00000
_cell_angle_gamma                90.00000
_cell_formula_units_Z            8
_cell_length_a                   13.467(6)
_cell_length_b                   14.127(7)
_cell_length_c                   20.298(5)
_cell_measurement_reflns_used    8
_cell_measurement_temperature    293
_cell_measurement_theta_max      18.6
_cell_measurement_theta_min      18.6
_cell_volume                     3862(3)
_computing_cell_refinement       'Enraf Nonius software'
_computing_data_collection       'Enraf Nonius software'
_computing_data_reduction        xtal
_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  xtal
_computing_structure_solution    xtal
_diffrn_ambient_temperature      293
_diffrn_measurement_device_type
;
CAD4  diffractometer
;
_diffrn_measurement_method       '2\q-\w scans'
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .018
_diffrn_reflns_av_sigmaI/netI    .027
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_diffrn_reflns_limit_h_min       0
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_diffrn_reflns_limit_k_min       -19
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_diffrn_reflns_limit_l_min       0
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_diffrn_reflns_reduction_process perpendicular_monochr-Lp
_diffrn_reflns_theta_max         29.97
_diffrn_reflns_theta_min         2.01
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  60
_diffrn_standards_number         8
_exptl_absorpt_coefficient_mu    1.141
_exptl_absorpt_correction_T_max  .72
_exptl_absorpt_correction_T_min  .60
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
XTAL absorb
;
_exptl_crystal_colour            colourless
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_exptl_crystal_size_mid          .58
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_refine_diff_density_max         .482
_refine_diff_density_min         -.606
_refine_ls_goodness_of_fit_all   .053
_refine_ls_goodness_of_fit_ref   1.118
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
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_refine_ls_number_reflns         3556
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           .036
_refine_ls_shift/su_max          .069
_refine_ls_shift/su_mean         .003
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         .069
_refine_ls_wR_factor_ref         .044
_reflns_d_resolution_high        .711
_reflns_d_resolution_low         10.128
_reflns_limit_h_max              18
_reflns_limit_h_min              0
_reflns_limit_k_max              19
_reflns_limit_k_min              0
_reflns_limit_l_max              28
_reflns_limit_l_min              0
_reflns_number_gt                3556
_reflns_number_observed          3556
_reflns_number_total             5628
_reflns_threshold_expression     'I    > 2.00 sig(I   )'
_cod_data_source_file            ic020375g_03.cif
_cod_data_source_block           cp15
_cod_original_sg_symbol_Hall     -p_2n_2ab
_cod_original_formula_sum        'C21 H21 Ag1 N1 O2 P1'
_cod_database_code               4318995