Two d10 luminescent metal‒organic frameworks as dual functional luminescent sensors for (Fe3+,Cu2+) and 2,4,6-trinitrophenol (TNP) with high selectivity and sensitivity
Zhou, Xiaojing; Guo, Xiaolei; Liu, Lili; Zhai, Haidong; Meng, Qingguo; Shi, Zhan; Tai, Xishi; RSC Advances 10 (2020) 4817–4824; doi:10.1039/C9RA07709J

data_7239845
_publ_section_title
;
 Two d10 luminescent metal--organic frameworks as dual functional
 luminescent sensors for (Fe3+,Cu2+) and 2,4,6-trinitrophenol (TNP) with
 high selectivity and sensitivity
;
_journal_issue                   8
_journal_name_full               'RSC Advances'
_journal_page_first              4817
_journal_page_last               4824
_journal_paper_doi               10.1039/C9RA07709J
_journal_volume                  10
_journal_year                    2020
_chemical_formula_sum            'C68 H54 N8 O14 Zn3'
_chemical_formula_weight         1403.30
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_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2018-08-29 deposited with the CCDC.	2020-01-16 downloaded from the CCDC.
;
_cell_angle_alpha                102.708(2)
_cell_angle_beta                 91.104(3)
_cell_angle_gamma                116.101(2)
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_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.841
_cell_measurement_theta_min      2.374
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku Saturn724 CCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.077
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             720
_exptl_crystal_size_max          0.31
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_platon_squeeze_details
;
;
_refine_diff_density_max         0.399
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0568P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1141
_refine_ls_wR_factor_ref         0.1247
_reflns_number_gt                5188
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c9ra07709j2.cif
_cod_data_source_block           111
_cod_depositor_comments
'Adding full bibliography for 7239844--7239845.cif.'
_cod_original_cell_volume        2164.58(19)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7239845