Bis[1,3-bis(diphenylphosphino)propane-κ^2^<i>P</i>:<i>P</i>']silver(I) bis(chlorodifluoroacetato-κ<i>O</i>)triphenylstannate(IV)
Teo, Yin Yin; Lo, Kong Mun; Ng, Seik Weng; Acta Crystallographica Section E 64 (2008) m703–; doi:10.1107/S1600536808010763

data_2218093
_publ_section_title
;
 Bis[1,3-bis(diphenylphosphino)propane-\k^2^<i>P</i>:<i>P</i>']silver(I)
 bis(chlorodifluoroacetato-\k<i>O</i>)triphenylstannate(IV)
;
_journal_coeditor_code           CV2399
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m703
_journal_paper_doi               10.1107/S1600536808010763
_journal_volume                  64
_journal_year                    2008
_chemical_formula_iupac
'[Ag (C27 H26 P2)2] [Sn (C6 H5)3 (C2 Cl F2 O2)]'
_chemical_formula_moiety         'C54 H52 Ag1 P4 +, C22 H15 Cl2 F4 O4 Sn -'
_chemical_formula_sum            'C76 H67 Ag Cl2 F4 O4 P4 Sn'
_chemical_formula_weight         1541.64
_chemical_name_systematic
;
Bis[1,3-bis(diphenylphosphino)propane-\k^2^<i>P</i>:<i>P</i>']silver(I)
bis(chlorodifluoroacetato-\kO)triphenylstannate(IV)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                91.5810(10)
_cell_angle_beta                 94.9310(10)
_cell_angle_gamma                104.5350(10)
_cell_formula_units_Z            2
_cell_length_a                   10.5554(2)
_cell_length_b                   17.6600(4)
_cell_length_c                   19.1383(4)
_cell_measurement_reflns_used    4777
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      24.
_cell_measurement_theta_min      2.2
_cell_volume                     3436.10(13)
_computing_cell_refinement       'SAINT (Bruker, 2007)'
_computing_data_collection       'APEX2 (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics    'X-SEED (Barbour, 2001)'
_computing_publication_material  'publCIF (Westrip, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.975
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type  'Bruker SMART APEX'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0648
_diffrn_reflns_av_sigmaI/netI    0.1025
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            35712
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.07
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.880
_exptl_absorpt_correction_T_max  0.9573
_exptl_absorpt_correction_T_min  0.8577
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.490
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1564
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.861
_refine_diff_density_min         -0.762
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     829
_refine_ls_number_reflns         15398
_refine_ls_number_restraints     48
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0764
_refine_ls_R_factor_gt           0.0489
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+1.3097P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0972
_refine_ls_wR_factor_ref         0.1123
_reflns_number_gt                10993
_reflns_number_total             15398
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            cv2399.cif
_cod_data_source_block           I
_cod_original_cell_volume        3436.10(10)
_cod_database_code               2218093
_cod_database_fobs_code          2218093