Preparation, Characterization, and Electroluminescence Characteristics of α-Diimine-type Platinum(II) Complexes with Perfluorinated Phenyl Groups as Ligands
Jun-ichi Nishida; Akihiro Maruyama; Takeshi Iwata; Yoshiro Yamashita; Chemistry Letters 34 (2005) 592–; doi:10.1246/cl.2005.592

data_8000041
_publ_section_title
;
 Preparation, Characterization, and Electroluminescence Characteristics
 of \a-Diimine-type Platinum(II) Complexes with Perfluorinated Phenyl
 Groups as Ligands
;
_journal_issue                   4
_journal_name_full               'Chemistry Letters'
_journal_page_first              592
_journal_paper_doi               10.1246/cl.2005.592
_journal_volume                  34
_journal_year                    2005
_chemical_formula_sum            'C39 H17 Cl3 F14 N2 Pt'
_chemical_formula_weight         1081.00
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                106.23(3)
_cell_angle_beta                 107.87(3)
_cell_angle_gamma                91.41(3)
_cell_formula_units_Z            2
_cell_length_a                   11.237(4)
_cell_length_b                   11.509(5)
_cell_length_c                   16.302(5)
_cell_measurement_reflns_used    19540
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      27.8
_cell_measurement_theta_min      3.5
_cell_volume                     1912(1)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    'DIRDIF94 (PATTY)'
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9814
_diffrn_measured_fraction_theta_max 0.9814
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.042
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            17411
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_exptl_absorpt_coefficient_mu    3.965
_exptl_absorpt_correction_T_max  0.042
_exptl_absorpt_correction_T_min  0.026
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.877
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_size_max          0.800
_exptl_crystal_size_mid          0.800
_exptl_crystal_size_min          0.800
_refine_diff_density_max         0.63
_refine_diff_density_min         -3.06
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.272
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     532
_refine_ls_number_reflns         8441
_refine_ls_R_factor_gt           0.0538
_refine_ls_shift/su_max          0.0437
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.10000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1585
_reflns_number_gt                7688
_reflns_number_total             8605
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C39 H17 Cl3 F14 N2 Pt '
_cod_database_code               8000041