The doubly-bonded ditungsten anion [W2Cp2(μ-PPh2)(NO)2](-): an entry to the chemistry of unsaturated nitrosyl complexes.
Alvarez, M. Angeles; García, M Esther; García-Vivó, Daniel; Ruiz, Miguel A.; Toyos, Adrián; Dalton transactions (Cambridge, England : 2003) 45 (2016) 13300–13303; doi:10.1039/c6dt02319c

data_7040103
_publ_section_title
;
 The doubly-bonded ditungsten anion [W2Cp2(\m-PPh2)(NO)2](-): an entry to
 the chemistry of unsaturated nitrosyl complexes.
;
_journal_issue                   34
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13300
_journal_page_last               13303
_journal_paper_doi               10.1039/c6dt02319c
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C43 H41 Au N2 O2 P2 W2, C H2 Cl2'
_chemical_formula_sum            'C44 H43 Au Cl2 N2 O2 P2 W2'
_chemical_formula_weight         1329.30
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
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_audit_update_record
;
2016-04-27 deposited with the CCDC.
2016-07-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_diffrn_measurement_device_type  'BRUKER APPEX-II CCD'
_diffrn_measurement_method       'omega/phi scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_l_min       -41
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.939
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
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_refine_diff_density_max         3.662
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_refine_ls_R_factor_gt           0.0565
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0478P)^2^+282.0319P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.119
_refine_ls_wR_factor_ref         0.1355
_reflns_number_gt                6277
_reflns_number_total             9294
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt02319c2.cif
_cod_data_source_block           compound6
_cod_depositor_comments
;
The following automatic conversions were performed:
'_diffrn_radiation_monochromador' tag replaced with
'_diffrn_radiation_monochromator' tag as specified in the replacement
file
'/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/lists/replacement-tags.lst'.

Automatic conversion script
Id: cif_correct_tags 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7040102--7040103.cif.
;
_cod_original_cell_volume        9108.9(11)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7040103