Influence of pH on CeIV-[AsIIIW9O33]9− association for the formation of hexanuclear cerium(iv) oxo-hydroxo-clusters stabilized by trivacant polyanions
Dufaye, Maxime; Duval, Sylvain; Stoclet, Gregory; Loiseau, Thierry; CrystEngComm 22 (2020) 371–380; doi:10.1039/C9CE01663E

data_7239597
_publ_section_title
;
 Influence of pH on CeIV-[AsIIIW9O33]9&#x2212; association for the
 formation of hexanuclear cerium(iv) oxo-hydroxo-clusters stabilized by
 trivacant polyanions
;
_journal_issue                   2
_journal_name_full               CrystEngComm
_journal_page_first              371
_journal_page_last               380
_journal_paper_doi               10.1039/C9CE01663E
_journal_volume                  22
_journal_year                    2020
_chemical_formula_moiety         'As6 Ce12 Na18 O288 W58, 53(O)'
_chemical_formula_sum            'As6 Ce12 Na18 O341 W58'
_chemical_formula_weight         18664.08
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
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2019-11-26 deposited with the CCDC.	2019-11-27 downloaded from the CCDC.
;
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_diffrn_measurement_device       'three-circle diffractometer'
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_diffrn_source                   'microfocus sealed X-ray tube'
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'SADABS-2014/5 (Bruker,2014/5) was used for absorption correction. wR2(int) was 0.1578 before and 0.0657 after correction. The Ratio of minimum to maximum transmission is 0.6435. The \l/2 correction factor is Not present.'
_exptl_crystal_colour            'clear yellow'
_exptl_crystal_colour_lustre     clear
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0543P)^2^+87.9608P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                21655
_reflns_number_total             36338
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
;Adding full bibliography for 7239596--7239599.cif.

 Adding full bibliography for 7239596--7239599.cif.
;
_cod_original_cell_volume        8970.0(12)
_cod_database_code               7239597
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_shelx_estimated_absorpt_t_max   0.425
_shelx_estimated_absorpt_t_min   0.258
_olex2_refinement_description
;
1. Others
 Fixed Sof: W30(0.7) O119(0.7) W29(0.3) O114(0.3) Na6(0.5) OW27(0.5) OW19(0.5)
 OW32(0.5) Na4(0.5) OW15(0.5) OW14(0.5)
;
_shelx_res_checksum              19157
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_olex2_submission_special_instructions 'No special instructions were received'