Spontaneous Resolution Induced by Self-Organization of Chiral Self-Complementary Cobalt(III) Complexes with Achiral Tripod-Type Ligands Containing Three Imidazole Groups
Ikuko Katsuki; Yuri Motoda; Yukinari Sunatsuki; Naohide Matsumoto; Toshio Nakashima; Masaaki Kojima; Journal of the American Chemical Society 124 (2002) 629–640; doi:10.1021/ja0123960

data_4114580
_publ_contact_author_address
;
Department of Chemistry, Faculty of Science, Kumamoto University, 
Kurokami 2-39-1, Kumamoto 860-8555, Japan
;
_publ_contact_author_email       ' naohide@aster.sci.kumamoto-u.ac.jp'
_publ_contact_author_fax         ' +81-96-342-3390'
_publ_contact_author_name        'Naohide Matsumoto'
_publ_contact_author_phone       ' +81-96-342-3390'
_publ_section_title
;
 Spontaneous Resolution Induced by Self-Organization of Chiral
 Self-Complementary Cobalt(III) Complexes with Achiral Tripod-Type Ligands
 Containing Three Imidazole Groups
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              629
_journal_page_last               640
_journal_paper_doi               10.1021/ja0123960
_journal_volume                  124
_journal_year                    2002
_chemical_formula_sum            'C18 H26 Cl3 Co N10 O13'
_chemical_formula_weight         755.75
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
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_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_cell_angle_alpha                90
_cell_angle_beta                 104.98(1)
_cell_angle_gamma                90
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_cell_length_c                   12.704(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293.2
_cell_measurement_theta_max      19.9
_cell_measurement_theta_min      18.3
_cell_volume                     5945.3(14)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
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_computing_publication_material  'teXsan for Windows (MSC, 1997)'
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_refine_diff_density_max         0.61
_refine_diff_density_min         -0.36
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.592
_refine_ls_goodness_of_fit_ref   1.590
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     810
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_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0402
_refine_ls_R_factor_gt           0.0400
_refine_ls_shift/su_max          16.1100
_refine_ls_shift/su_mean         0.9053
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00022|Fo|^2^]'
_refine_ls_weighting_scheme      sigma
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_reflns_threshold_expression     I>2.00\s(I)
_cod_data_source_file            ja0123960_2.cif
_cod_data_source_block           '_coh3hclo4________________'
_cod_original_cell_volume        5946(1)
_cod_original_sg_symbol_H-M      'C c '
_cod_original_formula_sum        'C18 H26 Cl3 Co N10 O13 '
_cod_database_code               4114580