Ethylene Polymerization and Copolymerization with Polar Monomers by Cationic Phosphine Phosphonic Amide Palladium Complexes
Sui, Xuelin; Dai, Shengyu; Chen, Changle; ACS Catalysis 5 (2015) 5932–; doi:10.1021/acscatal.5b01490

data_4513679
_publ_section_title
;
 Ethylene Polymerization and Copolymerization with Polar Monomers by
 Cationic Phosphine Phosphonic Amide Palladium Complexes
;
_journal_issue                   10
_journal_name_full               'ACS Catalysis'
_journal_page_first              5932
_journal_paper_doi               10.1021/acscatal.5b01490
_journal_volume                  5
_journal_year                    2015
_chemical_formula_sum            'C32 H38 Cl3 N P2 Pd S'
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_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      orthorhombic
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_symmetry_space_group_name_Hall  '-P 2ac 2ab'
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_diffrn_reflns_theta_max         29.267
_diffrn_reflns_theta_min         3.379
_exptl_absorpt_coefficient_mu    0.952
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.80375
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    1.441
_exptl_crystal_description       block
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_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.320
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_refine_ls_extinction_method     none
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_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0847
_refine_ls_R_factor_gt           0.0505
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0973P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1446
_refine_ls_wR_factor_ref         0.1760
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5679
_reflns_number_total             8146
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            cs5b01490_si_003.cif
_cod_data_source_block           shelxl
_cod_database_code               4513679
_shelx_estimated_absorpt_t_min   0.691
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_shelxl_version_number           2013-4
_shelx_res_checksum              70956
_shelx_hkl_checksum              47165