The cation-dependent structural, magnetic and optical properties of a family of hypophosphite hybrid perovskites.
Mączka, Mirosław; Stefańska, Dagmara; Gągor, Anna; Pikul, Adam; Dalton transactions (Cambridge, England : 2003) 51 (2021) 352–360; doi:10.1039/d1dt03382d

data_7708953
_publ_section_title
;
 The cation-dependent structural, magnetic and optical properties of a
 family of hypophosphite hybrid perovskites.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              352
_journal_page_last               360
_journal_paper_doi               10.1039/d1dt03382d
_journal_volume                  51
_journal_year                    2021
_chemical_formula_sum            'C2 H14 Mn N O7 P3'
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;
2021-08-23 deposited with the CCDC.	2021-11-29 downloaded from the CCDC.
;
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_diffrn_source                   'fine-focus sealed X-ray tube'
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;
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    1.842
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_exptl_crystal_size_mid          0.14
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.046
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0310P)^2^+0.4398P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0648
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_reflns_number_gt                2303
_reflns_number_total             2774
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1dt03382d2.cif
_cod_data_source_block           EtAMn
_cod_depositor_comments
'Adding full bibliography for 7708953--7708954.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7708953
_shelx_shelxl_version_number     2018/3
_oxdiff_exptl_absorpt_empirical_full_min 0.954
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_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_shelx_res_checksum              19613
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