New Antimony-Based Organic-Inorganic Hybrid Material as Electron Extraction Layer for Efficient and Stable Polymer Solar Cells.
Fredj, Donia; Alkarsifi, Riva; Pourcin, Florent; Liu, Xianjie; Boudjada, Nassira Chniba; Pierron, Pascal; Nourdine, Ali; Boujelbene, Mohamed; Fahlman, Mats; Videlot-Ackermann, Christine; Flandin, Lionel; Ben Dkhil, Sadok; Margeat, Olivier; Ackermann, Jörg; ACS applied materials & interfaces 11 (2019) 44820–44828; doi:10.1021/acsami.9b12409

data_4516229
_publ_section_title
;
 New Antimony-Based Organic-Inorganic Hybrid Material as Electron
 Extraction Layer for Efficient and Stable Polymer Solar Cells.
;
_journal_issue                   47
_journal_name_full               'ACS applied materials &amp; interfaces'
_journal_page_first              44820
_journal_page_last               44828
_journal_paper_doi               10.1021/acsami.9b12409
_journal_volume                  11
_journal_year                    2019
_chemical_formula_sum            'C10 H16 Cl5 N6 Sb'
_chemical_formula_weight         519.29
_space_group_crystal_system      monoclinic
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_atom_sites_solution_hydrogens   geom
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_cell_angle_beta                 97.43(5)
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_cell_formula_units_Z            4
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_cell_length_b                   20.33(5)
_cell_length_c                   10.32(5)
_cell_measurement_reflns_used    942
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.540
_cell_measurement_theta_min      3.349
_cell_volume                     1895(15)
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 25.242
_diffrn_measured_fraction_theta_max 0.885
_diffrn_measurement_device_type  KCCD
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0330
_diffrn_reflns_Laue_measured_fraction_full 0.947
_diffrn_reflns_Laue_measured_fraction_max 0.885
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_diffrn_reflns_point_group_measured_fraction_full 0.947
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_diffrn_reflns_theta_max         27.550
_diffrn_reflns_theta_min         3.349
_exptl_absorpt_coefficient_mu    2.164
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_density_diffrn    1.820
_exptl_crystal_description       Block
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_refine_diff_density_min         -0.887
_refine_diff_density_rms         0.235
_refine_ls_extinction_method     none
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_refine_ls_number_parameters     199
_refine_ls_number_reflns         3869
_refine_ls_number_restraints     0
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0823P)^2^+27.6403P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1232
_refine_ls_wR_factor_ref         0.1381
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3281
_reflns_number_total             3869
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            am9b12409_si_002.cif
_cod_data_source_block           shelx
_cod_depositor_comments          'Adding full bibliography for 4516229.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4516229
_shelx_estimated_absorpt_t_min   0.948
_shelx_estimated_absorpt_t_max   0.951
_shelxl_version_number           2013-4
_shelx_res_checksum              78373
_shelx_hkl_checksum              69995