The heterometallic cadmium-silver complex cis-bis[dicyanidoargentato(I)-κN]bis(5,5'-dimethyl-2,2'-bipyridyl-κ(2)N,N')cadmium(II) monohydrate.
Piromchom, Jureepan; Wannarit, Nanthawat; Pakawatchai, Chaveng; Youngme, Sujittra; Acta crystallographica. Section C, Crystal structure communications 69 (2013) 1136–1139; doi:10.1107/S0108270113025201

data_2311611
_publ_section_title
;
 The heterometallic cadmium-silver complex
 cis-bis[dicyanidoargentato(I)-\kN]bis(5,5'-dimethyl-2,2'-bipyridyl-\k(2)N,N')cadmium(II)
 monohydrate.
;
_journal_coeditor_code           WQ3049
_journal_issue                   'Pt 10'
_journal_name_full
'Acta crystallographica. Section C, Crystal structure communications'
_journal_page_first              1136
_journal_page_last               1139
_journal_paper_doi               10.1107/S0108270113025201
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          '[Ag2 Cd (C N)4 (C12 H12 N2)2], H2 O'
_chemical_formula_moiety         'C28 H24 Ag2 Cd N8, H2 O'
_chemical_formula_sum            'C28 H26 Ag2 Cd N8 O'
_chemical_formula_weight         818.72
_chemical_name_common
'<i>cis</i>-Bis[dicyanidoargentato(I)-\k<i>N</i>]bis(5,5'-dimethyl-2,2'-bipyridyl-\k^2^<i>N</i>,<i>N</i>')cadmium(II) monohydrate'
_chemical_name_systematic
;
Di-\m-cyanido-1:3\k^2^<i>C</i>:<i>N</i>;2:3\k^2^<i>C</i>:<i>N</i>-\
dicyanido-1\k<i>C</i>,2\k<i>C</i>-bis(5,5'-dimethyl-2,2'-bipyridyl-\
3\k^2^<i>N</i>,<i>N</i>')cadmium(II)disilver(I) monohydrate
;
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                109.5250(10)
_cell_angle_beta                 100.5720(10)
_cell_angle_gamma                98.3240(10)
_cell_formula_units_Z            2
_cell_length_a                   9.6964(4)
_cell_length_b                   11.2487(5)
_cell_length_c                   15.7456(7)
_cell_measurement_reflns_used    9313
_cell_measurement_temperature    293
_cell_measurement_theta_max      28.23
_cell_measurement_theta_min      2.19
_cell_volume                     1551.30(12)
_computing_cell_refinement       'SMART (Bruker, 2000)'
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics
;
ORTEPIII for Windows (Farrugia, 2012) and Mercury (Macrae <i>et al.</i>,
2008)
;
_computing_publication_material
;
PLATON (Spek, 2009) and publCIF (Westrip, 2010)
;
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      293
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0172
_diffrn_reflns_av_sigmaI/netI    0.0210
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            21735
_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         1.95
_exptl_absorpt_coefficient_mu    1.963
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.799
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2000)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.753
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             800
_exptl_crystal_size_max          0.387
_exptl_crystal_size_mid          0.162
_exptl_crystal_size_min          0.092
_refine_diff_density_max         0.596
_refine_diff_density_min         -0.306
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     373
_refine_ls_number_reflns         7667
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0317
_refine_ls_R_factor_gt           0.0264
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0329P)^2^+0.3861P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0626
_refine_ls_wR_factor_ref         0.0652
_reflns_number_gt                6749
_reflns_number_total             7667
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            wq3049sup1.cif
_cod_data_source_block           I
_cod_database_code               2311611