Selective B-B bond activation in an unsymmetrical diborane(4) by [(Me3P)4Rh-X] (X = Me, OtBu): a switch of mechanism?
Borner, C.; Brandhorst, K.; Kleeberg, C.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 8600–8604; doi:10.1039/c5dt00618j

data_7034814
_publ_section_title
;
 Selective B-B bond activation in an unsymmetrical diborane(4) by
 [(Me3P)4Rh-X] (X = Me, OtBu): a switch of mechanism?
;
_journal_issue                   18
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8600
_journal_page_last               8604
_journal_paper_doi               10.1039/c5dt00618j
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C18 H48 B O2 P4 Rh'
_chemical_formula_sum            'C18 H48 B O2 P4 Rh'
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_chemical_name_systematic
;
 ?
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2014-12-04 deposited with the CCDC.
2015-03-31 downloaded from the CCDC.
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 CrysAlisPro, Agilent Technologies,
 Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
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 CrysAlisPro, Agilent Technologies,
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 CrysAlisPro, Agilent Technologies,
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 Diamond 3.2i, K. Brandenburg, Crystal Impact GbR, Bonn, Germany.
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 WinGX v2013.2 (L. J. Farrugia, J. Appl. Cryst. 2012, 45, 849-854.)
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 SHELXL-2013 (G. M. Sheldrick, Acta Cryst. (2008). A64, 122-122)'
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 SIR-92 (A. Altomare, G. Cascarano, C. Giacovazzo and A. Guagliardi,
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 CrysAlisPro, Agilent Technologies,
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 Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            'clear colourless'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0557P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_refine_ls_wR_factor_gt          0.0878
_refine_ls_wR_factor_ref         0.0911
_reflns_number_gt                21727
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7034812--7034816.cif.'
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