Unsupported monomeric stibine oxides (R<sub>3</sub>SbO) remain undiscovered.
Wenger, John S.; Johnstone, Timothy C.; Chemical communications (Cambridge, England) 57 (2021) 3484–3487; doi:10.1039/d1cc00619c

data_7128003
_publ_section_title
;
 Unsupported monomeric stibine oxides (R<sub>3</sub>SbO) remain
 undiscovered.
;
_journal_issue                   28
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3484
_journal_page_last               3487
_journal_paper_doi               10.1039/d1cc00619c
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety
'C32 H12 B F24, C27 H34 O Sb, 0.5(C5 H12), 0.5(C5 H12)'
_chemical_formula_sum            'C64 H58 B F24 O Sb'
_chemical_formula_weight         1431.66
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-02-02 deposited with the CCDC.	2021-03-03 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      100(2)
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_diffrn_measurement_device_type  'PhotonJet (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_number            70027
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_diffrn_source                   'micro-focus sealed X-ray tube'
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'CrysAlisPro 1.171.41.58a (Rigaku Oxford Diffraction, 2020)'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0850P)^2^+3.6443P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7128001--7128003.cif.'
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