Bulky magnesium(ii) and sodium(i) bisphenoxide catalysts for chemoselective transesterification of methyl (meth)acrylates.
Zhao, Xue; Ratanasak, Manussada; Kon, Kazumasa; Hasegawa, Jun-Ya; Ishihara, Kazuaki; Chemical science 14 (2023) 566–572; doi:10.1039/d2sc05413b

data_1568080
_publ_section_title
;
 Bulky magnesium(ii) and sodium(i) bisphenoxide catalysts for
 chemoselective transesterification of methyl (meth)acrylates.
;
_journal_issue                   3
_journal_name_full               'Chemical science'
_journal_page_first              566
_journal_page_last               572
_journal_paper_doi               10.1039/d2sc05413b
_journal_volume                  14
_journal_year                    2023
_chemical_formula_moiety         'C70 H108 Mg2 O6'
_chemical_formula_sum            'C70 H108 Mg2 O6'
_chemical_formula_weight         1094.18
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_audit_update_record
;
2022-02-17 deposited with the CCDC.	2022-11-28 downloaded from the CCDC.
;
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;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
;
_computing_data_collection
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
;
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CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
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_diffrn_source                   'micro-focus sealed X-ray tube'
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;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.107
_exptl_crystal_description       Block
_exptl_crystal_F_000             1200
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0757P)^2^+2.8566P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                6084
_reflns_number_total             8210
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d2sc05413b2.cif
_cod_data_source_block           Mg
_cod_depositor_comments
'Adding full bibliography for 1568080--1568081.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1568080
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.977
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_shelx_res_checksum              91021
_shelx_hkl_checksum              75888