Stable Fe(ii)-based coordination polymers: synthesis, structural diversity and catalytic applications in homo-coupling reactions.
Wu, Qiong; Han, Yanbing; Shao, Zhichao; Li, Junxia; Hou, Hongwei; Dalton transactions (Cambridge, England : 2003) 47 (2018) 8063–8069; doi:10.1039/c8dt01839a

data_7046579
_publ_section_title
;
 Stable Fe(ii)-based coordination polymers: synthesis, structural
 diversity and catalytic applications in homo-coupling reactions.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8063
_journal_page_last               8069
_journal_paper_doi               10.1039/c8dt01839a
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C78 H84 Fe3 N42 S6'
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
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;
2018-05-03 deposited with the CCDC.
2018-05-22 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_radiation_type           CuK\a
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_exptl_absorpt_coefficient_mu    5.643
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_exptl_crystal_description       prism
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.956
_refine_ls_R_factor_all          0.0688
_refine_ls_R_factor_gt           0.0587
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1214P)^2^+14.1759P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                7834
_reflns_number_total             9332
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt01839a2.cif
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'Adding full bibliography for 7046579--7046581.cif.'
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