New fluorescent compounds based on zinc thiocyanate: influence of structure on spectral properties.
Swiatkowski, Marcin; Kruszynski, Rafal; Acta crystallographica. Section C, Structural chemistry 73 (2017) 1144–1150; doi:10.1107/S2053229617016564

data_2311972
_publ_section_title
;
 New fluorescent compounds based on zinc thiocyanate: influence of
 structure on spectral properties.
;
_journal_coeditor_code           KU3206
_journal_issue                   'Pt 12'
_journal_name_full
'Acta crystallographica. Section C, Structural chemistry'
_journal_page_first              1144
_journal_page_last               1150
_journal_paper_doi               10.1107/S2053229617016564
_journal_volume                  73
_journal_year                    2017
_chemical_formula_iupac          '[Zn (C H4 N2 O)4 (H2 O)2] [Zn (N C S)4]'
_chemical_formula_moiety         'C4 H20 N8 O6 Zn 2+, C4 N4 S4 Zn 2-'
_chemical_formula_sum            'C8 H20 N12 O6 S4 Zn2'
_chemical_formula_weight         639.34
_chemical_name_systematic
;Diaquatetrakis(urea-\k<i>O</i>)zinc(II)
tetrakis(isothiocyanato-\k<i>N</i>)zinc(II)
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
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_cell_measurement_theta_min      4.1550
_cell_volume                     2373.27(16)
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;
CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
;
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;
CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
;
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CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
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XP in SHELXTL (Sheldrick, 2008) and ORTEP-3 for Windows (Farrugia,
2012)
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SHELXL2014 (Sheldrick, 2015b) and PLATON (Spek, 2009)
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SHELXL2014 (Sheldrick, 2015b)
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SHELXT (Sheldrick, 2015a)
;
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_diffrn_reflns_limit_k_min       -5
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_diffrn_reflns_limit_l_min       -30
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;
(CrysAlis PRO; Rigaku Oxford Diffraction, 2015)
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0251P)^2^+1.7969P] where P=(Fo^2^+2Fc^2^)/3'
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