Geminal arsa(III)amide and trisubstituted antimony and bismuth amides from the sterically hindered, N-functionalised amido ligand [{2-(6-Me)C5H3N}NSiMe3]−
Raston, Colin L.; Skelton, Brian W.; Tolhurst, Vicki-Anne; White, Allan H.; Journal of the Chemical Society, Dalton Transactions  (2000) 1279–; doi:10.1039/a909338i

data_7009215
_publ_section_title
;
 Geminal arsa(III)amide and trisubstituted antimony and bismuth amides
 from the sterically hindered, N-functionalised amido ligand
 [{2-(6-Me)C5H3N}NSiMe3]&#x2212;
;
_journal_issue                   8
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1279
_journal_paper_doi               10.1039/a909338i
_journal_year                    2000
_chemical_formula_sum            'C27 H45 N6 Sb Si3'
_chemical_formula_weight         659.72
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_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
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_audit_creation_date             97-01-24
_audit_creation_method           from_xtal_archive_file_using_CIFIO
_cell_angle_alpha                116.13(9)
_cell_angle_beta                 94.04(5)
_cell_angle_gamma                104.01(7)
_cell_formula_units_Z            2
_cell_length_a                   14.865(6)
_cell_length_b                   11.682(17)
_cell_length_c                   11.296(10)
_cell_measurement_reflns_used    8
_cell_measurement_temperature    293
_cell_measurement_theta_max      23.1
_cell_measurement_theta_min      18.6
_cell_volume                     1673(3)
_computing_cell_refinement       'Enraf Nonius software'
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_refine_ls_extinction_expression Eq22_p292_"Cryst._Comp."_Munksgaard_1970
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_refine_ls_R_factor_gt           .025
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_refine_ls_shift/su_mean         .007
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
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_refine_ls_wR_factor_ref         .032
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