Racemic cobalt phosphonates incorporating flexible bis(imidazole) co-ligands.
Feng, Jian-Shen; Cai, Zhong-Sheng; Ren, Min; Bao, Song-Song; Zheng, Li-Min; Dalton transactions (Cambridge, England : 2003) 44 (2015) 18122–18129; doi:10.1039/c5dt03046c

data_7036565
_publ_section_title
;
 Racemic cobalt phosphonates incorporating flexible bis(imidazole)
 co-ligands.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18122
_journal_page_last               18129
_journal_paper_doi               10.1039/c5dt03046c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C46 H46 Co3 N10 O10 P2, 4(H2 O)'
_chemical_formula_sum            'C46 H54 Co3 N10 O14 P2'
_chemical_formula_weight         1209.72
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2015-04-13 deposited with the CCDC.
2015-09-16 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX II'
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_diffrn_reflns_av_R_equivalents  0.0303
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_diffrn_reflns_laue_measured_fraction_full 0.996
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_diffrn_reflns_point_group_measured_fraction_full 0.996
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_exptl_absorpt_process_details   'SADABS(Bruker, 2000)'
_exptl_crystal_colour            'pruple red'
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_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1745P)^2^+29.2202P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt03046c2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7036565--7036568.cif.'
_cod_original_cell_volume        5362.7(11)
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_shelx_res_checksum              54713