Ligand assisted carbon dioxide activation and hydrogenation using molybdenum and tungsten amides.
Chakraborty, Subrata; Blacque, Olivier; Berke, Heinz; Dalton transactions (Cambridge, England : 2003) 44 (2015) 6560–6570; doi:10.1039/c5dt00278h

data_7034243
_publ_section_title
;
 Ligand assisted carbon dioxide activation and hydrogenation using
 molybdenum and tungsten amides.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6560
_journal_page_last               6570
_journal_paper_doi               10.1039/c5dt00278h
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         '8(C18 H38 N2 O4 P2 W), C4 H8 O'
_chemical_formula_sum            'C148 H312 N16 O33 P16 W8'
_chemical_formula_weight         4810.46
_chemical_name_systematic
'(2-[bis(1-methylethyl)phosphanyl-\k<i>P</i>]-<i>N</i>-{2-[bis(1-methylethyl)phosphanyl-\k<i>P</i>]ethyl}ethanamine-\k<i>N</i>)(carbonyl)(formato-\k<i>O</i>)(nitrosyl)tungsten tetrahydrofuran solvate (8/1)'
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;
2013-09-11 deposited with the CCDC.
2015-03-02 downloaded from the CCDC.
;
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_cell_angle_beta                 90.00
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_cell_measurement_temperature    183(2)
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_computing_cell_refinement
;
CrysAlisPro, version 1.171.35.11 (Agilent, 2011)
;
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CrysAlisPro, version 1.171.35.11 (Agilent, 2011)
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CrysAlisPro, version 1.171.35.11 (Agilent, 2011)
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DIAMOND (Brandenburg, 2006).
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<i>WinGX</i> (Farrugia, 1999), <i>PLATON for Windows</i> (Spek, 2003) and
<i>publCIF</i> (Westrip, 2010)
;
_computing_structure_refinement  ' SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    ' SHELXS97 (Sheldrick, 2008) '
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;
CrysAlisPro, Version 1.171.35.11 (Agilent Technologies, 2011)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid (1995).
;
_exptl_crystal_colour            orange
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_exptl_crystal_description       plate
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                5971
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_cod_data_source_file            c5dt00278h2.cif
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_cod_depositor_comments
'Adding full bibliography for 7034242--7034245.cif.'
_cod_original_cell_volume        19644.6(8)
_cod_original_sg_symbol_H-M      'I 41/a'
_cod_database_code               7034243