Base-catalyzed thio-lactamization of 2-(1-arylvinyl)anilines with CS<sub>2</sub> for the synthesis of quinoline-2-thiones.
Wang, Tong-Lin; Liu, Xiao-Jun; Huo, Cong-De; Wang, Xi-Cun; Quan, Zheng-Jun; Chemical communications (Cambridge, England) 54 (2018) 499–502; doi:10.1039/c7cc07633a

data_7120964
_publ_section_title
;
 Base-catalyzed thio-lactamization of 2-(1-arylvinyl)anilines with
 CS<sub>2</sub> for the synthesis of quinoline-2-thiones.
;
_journal_issue                   5
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              499
_journal_page_last               502
_journal_paper_doi               10.1039/c7cc07633a
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C16 H13 N S'
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2017-09-30 deposited with the CCDC.
2017-12-07 downloaded from the CCDC.
;
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_cell_volume                     2604.9(3)
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_diffrn_measured_fraction_theta_full 0.988
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34139
_diffrn_reflns_av_R_equivalents  0.0647
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_diffrn_reflns_point_group_measured_fraction_full 0.988
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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_refine_ls_number_reflns         4577
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.013
_refine_ls_R_factor_all          0.1165
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0821P)^2^+6.9266P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2270
_refine_ls_wR_factor_ref         0.2422
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3189
_reflns_number_total             4577
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7120964.cif.'
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