<i>catena</i>-Poly[[bis(acetato-κ^2^<i>O</i>,<i>O</i>')cobalt(II)]-μ-4,4'-bis(benzimidazol-1-yl)biphenyl-κ^2^<i>N</i>^3^:<i>N</i>^3'^]
Huang, Ping-Yun; Wang, Jin-Guo; Acta Crystallographica Section E 66 (2010) m1638–; doi:10.1107/S160053681004715X

data_2228334
_publ_section_title
;
 <i>catena</i>-Poly[[bis(acetato-\k^2^<i>O</i>,<i>O</i>')cobalt(II)]-\m-4,4'-bis(benzimidazol-1-yl)biphenyl-\k^2^<i>N</i>^3^:<i>N</i>^3'^]
;
_journal_coeditor_code           HB5708
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1638
_journal_paper_doi               10.1107/S160053681004715X
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Co (C2 H3 O2)2 (C26 H18 N4)]'
_chemical_formula_moiety         'C30 H24 Co N4 O4'
_chemical_formula_sum            'C30 H24 Co N4 O4'
_chemical_formula_weight         563.46
_chemical_name_systematic
;
<i>catena</i>-Poly[[bis(acetato-\k^2^<i>O</i>,<i>O</i>')cobalt(II)]-\m-
4,4'-bis(benzimidazol-1-yl)biphenyl-\k^2^<i>N</i>^3^:<i>N</i>^3'^]
;
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.078(3)
_cell_length_b                   16.348(3)
_cell_length_c                   11.354(2)
_cell_measurement_reflns_used    6002
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.90
_cell_measurement_theta_min      1.99
_cell_volume                     2427.5(8)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC, 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC, 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC, 2005)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku CCD area-detector'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0383
_diffrn_reflns_av_sigmaI/netI    0.0164
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            21778
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.68
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_exptl_absorpt_coefficient_mu    0.754
_exptl_absorpt_correction_T_max  0.873
_exptl_absorpt_correction_T_min  0.828
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrystalClear; Rigaku/MSC, 2005)'
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.542
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1164
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.271
_refine_diff_density_min         -0.410
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.102
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     178
_refine_ls_number_reflns         2150
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.102
_refine_ls_R_factor_all          0.0359
_refine_ls_R_factor_gt           0.0348
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0367P)^2^+2.7447P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0820
_refine_ls_wR_factor_ref         0.0829
_reflns_number_gt                2101
_reflns_number_total             2150
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb5708.cif
_cod_data_source_block           I
_cod_database_code               2228334
_cod_database_fobs_code          2228334