Oxidation Reactions of Dithiocarbamate Complexes of Ruthenium(II)
Wa-Hung Leung; Joyce L. C. Chim; Hongwei Hou; Tom S. M. Hun; Ian D. Williams; Wing-Tak Wong; Inorganic Chemistry 36 (1997) 4432–4437; doi:10.1021/ic970053q

data_4323585
_publ_section_title
;
 Oxidation Reactions of Dithiocarbamate Complexes of Ruthenium(II)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4432
_journal_page_last               4437
_journal_paper_doi               10.1021/ic970053q
_journal_volume                  36
_journal_year                    1997
_chemical_formula_moiety         'C17 H28 N2 S4 Ru '
_chemical_formula_sum            'C17 H28 N2 Ru S4'
_chemical_formula_weight         489.73
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Sat Aug  9 01:57:55 2026'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                103.69(2)
_cell_angle_beta                 93.54(2)
_cell_angle_gamma                100.61(2)
_cell_formula_units_Z            2
_cell_length_a                   7.316(1)
_cell_length_b                   10.346(1)
_cell_length_c                   15.123(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      19.0
_cell_measurement_theta_min      12.0
_cell_volume                     1086.5(3)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_diffrn_ambient_temperature      296.2
_diffrn_measurement_device       unknown
_diffrn_measurement_method       'omega/2-theta scans'
_diffrn_orient_matrix_UB_11      0.00823
_diffrn_orient_matrix_UB_12      0.02553
_diffrn_orient_matrix_UB_13      -0.05962
_diffrn_orient_matrix_UB_21      0.11773
_diffrn_orient_matrix_UB_22      0.06821
_diffrn_orient_matrix_UB_23      0.02645
_diffrn_orient_matrix_UB_31      0.07514
_diffrn_orient_matrix_UB_32      -0.07089
_diffrn_orient_matrix_UB_33      -0.02085
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  1.62
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            3105
_diffrn_reflns_theta_max         22.47
_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.108
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.843
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   psi-scan
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.497
_exptl_crystal_description       block
_exptl_crystal_F_000             504.00
_exptl_crystal_size_max          0.350
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.250
_refine_diff_density_max         0.80
_refine_diff_density_min         -0.55
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_obs   3.056
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     217
_refine_ls_number_reflns         2586
_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0271
_refine_ls_shift/esd_max         0.0093
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0349
_reflns_number_observed          2586
_reflns_number_total             2837
_reflns_observed_criterion       3.00
_cod_data_source_file            ic970053q_1.cif
_cod_data_source_block           WTW198_WHL135_RU(NBD)(DTC)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C17 H28 N2 S4 Ru '
_cod_database_code               4323585