Photo- and Metallo-responsive N-Alkyl α-Bisimines as Orthogonally Addressable Main-Chain Functional Groups in Metathesis Polymers.
Greb, Lutz; Mutlu, Hatice; Barner-Kowollik, Christopher; Lehn, Jean-Marie; Journal of the American Chemical Society 138 (2016) 1142–1145; doi:10.1021/jacs.5b12198

data_4129957
_publ_section_title
;
 Photo- and Metallo-responsive N-Alkyl \a-Bisimines as Orthogonally
 Addressable Main-Chain Functional Groups in Metathesis Polymers.
;
_journal_issue                   4
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              1142
_journal_page_last               1145
_journal_paper_doi               10.1021/jacs.5b12198
_journal_volume                  138
_journal_year                    2016
_chemical_formula_sum            'C61.5 H68 Cl11.5 N4 O8 Pd2'
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_cell_length_b                   29.393(4)
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_diffrn_measurement_device_type  'STOE IPDS 2T'
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_diffrn_radiation_type           MoK\a
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_diffrn_source
'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
_exptl_absorpt_coefficient_mu    0.891
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_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   XRED32
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1476P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                9607
_reflns_number_total             14538
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           p21n_sq
_cod_original_cell_volume        7901.2(19)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C61.50 H68 Cl11.50 N4 O8 Pd2'
_cod_database_code               4129957
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_shelx_res_checksum              3875
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