N-Alkylfluorenyl-substituted N-heterocyclic carbenes as bimodal pincers.
Teci, Matthieu; Brenner, Eric; Matt, Dominique; Gourlaouen, Christophe; Toupet, Loïc; Dalton transactions (Cambridge, England : 2003) 44 (2015) 9260–9268; doi:10.1039/c5dt00980d

data_7035006
_publ_section_title
;
 N-Alkylfluorenyl-substituted N-heterocyclic carbenes as bimodal pincers.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9260
_journal_page_last               9268
_journal_paper_doi               10.1039/c5dt00980d
_journal_volume                  44
_journal_year                    2015
_chemical_absolute_configuration ad
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_space_group_name_H-M_alt        'P 21 21 21'
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;
2015-04-09 deposited with the CCDC.
2015-04-16 downloaded from the CCDC.
;
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'CrysAlis RED, Oxford Diffraction Ltd.,Version 1.171.37.35'
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'CrysAlis CCD, Oxford Diffraction Ltd.,Version 1.171.37.35'
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'CrysAlis RED, Oxford Diffraction Ltd.,Version 1.171.37.35'
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD Saphire 3 Xcalibur'
_diffrn_measurement_method       'omega scan'
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;
 Flack x determined using 2708 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.016(9)
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0293P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                6467
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'Adding full bibliography for 7035005--7035007.cif.'
_cod_database_code               7035006
_audit_block_doi                 10.5517/ccz81lv
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