Both magnetic relaxation and luminescence of Zn2Dy2 cluster complexes regulated by the bis-imine chain in Schiff base ligands
Liu, Cai-Ming; Zhang, De-Qing; Zhang, Yi-Quan; Li, Miao; Zhu, Dao-Ben; New Journal of Chemistry 43 (2019) 14502–; doi:10.1039/C9NJ03659H

data_7058765
_publ_section_title
;
 Both magnetic relaxation and luminescence of Zn2Dy2 cluster complexes
 regulated by the bis-imine chain in Schiff base ligands
;
_journal_issue                   36
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              14502
_journal_paper_doi               10.1039/C9NJ03659H
_journal_volume                  43
_journal_year                    2019
_chemical_formula_sum            'C65 H64 Cl2 Dy2 N8 O19 Zn2'
_chemical_formula_weight         1787.88
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2019-07-29 deposited with the CCDC.    2019-08-19 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 98.26(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_c                   27.641(6)
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_cell_measurement_theta_min      1.4003
_cell_volume                     6598(2)
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean '15x15 microns'
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'CCD area dtetector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0614
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_diffrn_reflns_limit_l_min       -35
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_diffrn_reflns_theta_max         27.495
_diffrn_reflns_theta_min         2.482
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    3.118
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_exptl_crystal_colour            'light yellow'
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_exptl_crystal_preparation       'Magnetic properties,Luminescent'
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0393P)^2^+20.3499P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                13828
_reflns_number_total             15051
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7058765--7058766.cif.'
_cod_database_code               7058765
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