Diastereotopos-Differentiation in the Rh-Catalyzed Amination of Benzylic Methylene Groups in the α-Position to a Stereogenic Center
Anike Nörder; Sarah A. Warren; Eberhardt Herdtweck; Stefan M. Huber; Thorsten Bach; Journal of the American Chemical Society 134 (2012) 13524–13531; doi:10.1021/ja3066682

data_4118512
_publ_contact_author_address
;
       Department Chemie,
       Lehrstuhl f\"ur Anorganische Chemie,
       Technische Universit\"at M\"unchen,
       Lichtenbergstrasse 4,
       D-85747 Garching bei M\"unchen,
       Germany.
;
_publ_contact_author_email       eberhardt.herdtweck@ch.tum.de
_publ_contact_author_fax         '+49(0)89 289 13473'
_publ_contact_author_name
;
       Dr. Eberhardt Herdtweck
;
_publ_contact_author_phone       '+49(0)89 289 13143'
_publ_section_title
;
 Diastereotopos-Differentiation in the Rh-Catalyzed Amination of Benzylic
 Methylene Groups in the \a-Position to a Stereogenic Center
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13524
_journal_page_last               13531
_journal_paper_doi               10.1021/ja3066682
_journal_volume                  134
_journal_year                    2012
_chemical_formula_moiety         'C15 H18 Cl3 N O6 S'
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_audit_update_record
;
   28-Jan-11  Updated by the Author E.H.
              Text writing by E.H.
              Checkcif    OK
   22-Feb-12  Updated by the Author E.H.
;
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'w=1/[\s^2^(Fo^2^)+(0.0359P)^2^+0.6953P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        915.32(5)
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