Isolation of a uranyl amide by "ate" complex formation.
Seaman, Lani A.; Schnaars, David D.; Wu, Guang; Hayton, Trevor W.; Dalton transactions (Cambridge, England : 2003) 39 (2010) 6635–6637; doi:10.1039/c001976c

data_7025595
_publ_section_title
;
 Isolation of a uranyl amide by &quot;ate&quot; complex formation.
;
_journal_issue                   29
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6635
_journal_page_last               6637
_journal_paper_doi               10.1039/c001976c
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C45 H97 Cl Li3 N6 O10 U2'
_chemical_formula_weight         1414.62
_chemical_name_systematic
;
Complex 1
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                83.505(2)
_cell_angle_beta                 73.948(2)
_cell_angle_gamma                77.607(2)
_cell_formula_units_Z            2
_cell_length_a                   12.5313(12)
_cell_length_b                   12.7238(13)
_cell_length_c                   19.6221(19)
_cell_measurement_temperature    150(2)
_cell_volume                     2931.8(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0819
_diffrn_reflns_av_sigmaI/netI    0.0791
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            25453
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         1.08
_exptl_absorpt_coefficient_mu    5.615
_exptl_absorpt_correction_T_max  0.402
_exptl_absorpt_correction_T_min  0.309
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'psi scan'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.602
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1398
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.3
_refine_diff_density_max         3.568
_refine_diff_density_min         -1.460
_refine_diff_density_rms         0.191
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     611
_refine_ls_number_reflns         11708
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0635
_refine_ls_R_factor_gt           0.0441
_refine_ls_shift/su_max          0.100
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0664P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1106
_refine_ls_wR_factor_ref         0.1234
_reflns_number_gt                8776
_reflns_number_total             11708
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c001976c.txt
_cod_data_source_block           g:\lani\ls_3_5\work\ls_3_51m
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7025595