Reversible Photoelectronic Signal Conversion Based on Photoisomerization-Controlled Coordination Change of Azobenzene-bipyridine Ligands to Copper
Shoko Kume; Masaki Murata; Tomoji Ozeki; Hiroshi Nishihara; Journal of the American Chemical Society 127 (2005) 490–491; doi:10.1021/ja045093p

data_4111388
_publ_section_title
;
 Reversible Photoelectronic Signal Conversion Based on
 Photoisomerization-Controlled Coordination Change of
 Azobenzene-bipyridine Ligands to Copper
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              490
_journal_page_last               491
_journal_paper_doi               10.1021/ja045093p
_journal_volume                  127
_journal_year                    2005
_chemical_formula_moiety         'C84 H80 B Cl2 Cu F4 N4 '
_chemical_formula_sum            'C84 H80 B Cl2 Cu F4 N4'
_chemical_formula_weight         1366.84
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.533(6)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.242(6)
_cell_length_b                   19.819(9)
_cell_length_c                   25.943(12)
_cell_measurement_reflns_used    11487
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     7309(6)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 3.5.1'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.9958
_diffrn_measured_fraction_theta_max 0.9958
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.088
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            116462
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.429
_exptl_absorpt_correction_T_max  0.918
_exptl_absorpt_correction_T_min  0.751
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.242
_exptl_crystal_description       chip
_exptl_crystal_F_000             2864.00
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         2.42
_refine_diff_density_min         -0.72
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   6.848
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     494
_refine_ls_number_reflns         5317
_refine_ls_R_factor_gt           0.0960
_refine_ls_shift/su_max          0.0010
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/\s^2^(Fo)'
_refine_ls_weighting_scheme      sigma
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_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ja045093psi20040814_071644.cif
_cod_data_source_block           '__Cu(oph)2'
_cod_original_cell_volume        7309.0(57)
_cod_original_formula_sum        'C84 H80 B Cl2 Cu F4 N4 '
_cod_database_code               4111388