Bi(OTf)<sub>3</sub>-Catalyzed Diastereoselective One-Pot Synthesis of 1,3-Diamines with Three Continuous Stereogenic Centers.
Halli, Juliette; Kramer, Philipp; Grimmer, Jennifer; Bolte, Michael; Manolikakes, Georg; The Journal of organic chemistry 83 (2018) 12007–12022; doi:10.1021/acs.joc.8b01925

data_4035230
_publ_section_title
;
 Bi(OTf)<sub>3</sub>-Catalyzed Diastereoselective One-Pot Synthesis of
 1,3-Diamines with Three Continuous Stereogenic Centers.
;
_journal_issue                   19
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              12007
_journal_page_last               12022
_journal_paper_doi               10.1021/acs.joc.8b01925
_journal_volume                  83
_journal_year                    2018
_chemical_formula_moiety         'C29.33 H27.33 Cl F N2 O3'
_chemical_formula_sum            'C29.33 H27.33 Cl F N2 O3'
_chemical_formula_weight         510.31
_space_group_crystal_system      trigonal
_space_group_IT_number           148
_space_group_name_Hall           '-R 3'
_space_group_name_H-M_alt        'R -3 :H'
_atom_sites_solution_hydrogens   mixed
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_cell_length_b                   22.0812(19)
_cell_length_c                   28.205(3)
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_cell_measurement_theta_max      22.73
_cell_measurement_theta_min      3.59
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_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'STOE IPDS II two-circle-diffractometer'
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_diffrn_reflns_av_unetI/netI     0.0653
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_diffrn_source                   'Genix 3D I\mS microfocus X-ray source'
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_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1382P)^2^+9.5865P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_estimated_absorpt_t_min   0.968
_shelx_estimated_absorpt_t_max   0.976
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_shelx_hkl_checksum              57985