Preparation and characterization of palladium and platinum complexes bearing 1,8-bis[(diphenylphosphino)methyl]naphthalene
Yamamoto, Yasuhiro; Fukui, Yasushi; Matsubara, Katsuaki; Takeshima, Hiroya; Miyauchi, Fumiyoshi; Tanase, Tomoaki; Yamamoto, Gaku; Journal of the Chemical Society, Dalton Transactions  (2001) 1773–; doi:10.1039/b100860i

data_7010597
_publ_section_title
;
 Preparation and characterization of palladium and platinum complexes
 bearing 1,8-bis[(diphenylphosphino)methyl]naphthalene
;
_journal_issue                   11
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1773
_journal_paper_doi               10.1039/b100860i
_journal_year                    2001
_chemical_formula_moiety         '[Pt2(1,8-dpmn)(MesNC)4](PF6)2'
_chemical_formula_sum            'C76 H74 F12 N4 P4 Pt2'
_chemical_formula_weight         1785.50
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      4
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_audit_creation_date             'Thu Nov 16 17:13:06 2000'
_cell_angle_alpha                90.00(5)
_cell_angle_beta                 108.1(1)
_cell_angle_gamma                90.0(1)
_cell_formula_units_Z            2
_cell_length_a                   11.06(5)
_cell_length_b                   25.823(10)
_cell_length_c                   14.292(10)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    300.2
_cell_measurement_theta_max      11.1
_cell_measurement_theta_min      7.7
_cell_volume                     3880(18)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 1.9466
_diffrn_measured_fraction_theta_max 1.9466
_diffrn_measurement_device_type  'Rigaku AFC5S'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.039
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            14429
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_standards_decay_%        5.01
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.740
_exptl_absorpt_correction_T_max  0.473
_exptl_absorpt_correction_T_min  0.327
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.528
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_refine_diff_density_max         1.35
_refine_diff_density_min         -1.19
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.402
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     411
_refine_ls_number_reflns         3887
_refine_ls_R_factor_gt           0.0778
_refine_ls_shift/su_max          0.4014
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.06000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1671
_reflns_number_gt                3887
_reflns_number_total             13638
_reflns_threshold_expression     F^2^2.0\s(F^2^)
_cod_data_source_file            b100860i.txt
_cod_data_source_block           afc5s.xtl_master_file
_cod_original_cell_volume        3881(12)
_cod_original_formula_sum        'C76 H74 F12 N4 P4 Pt2 '
_cod_database_code               7010597