Absolute Asymmetric Phthalide Synthesis via the Solid-State Photoreaction of N,N-Disubstituted 2-Benzoylbenzamides Involving a Radical Pair Intermediate
Masami Sakamoto; Norio Sekine; Hiroko Miyoshi; Takashi Mino; Tsutomu Fujita; Journal of the American Chemical Society 122 (2000) 10210–10211; doi:10.1021/ja001064c

data_4116181
_publ_section_title
;
 Absolute Asymmetric Phthalide Synthesis via the Solid-State Photoreaction
 of N,N-Disubstituted 2-Benzoylbenzamides Involving a Radical Pair
 Intermediate
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              10210
_journal_page_last               10211
_journal_paper_doi               10.1021/ja001064c
_journal_volume                  122
_journal_year                    2000
_chemical_formula_sum            'C16 H15 N O2'
_chemical_formula_weight         253.00
_space_group_IT_number           19
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_symmetry_space_group_name_Hall  'P 2ac 2ab'
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_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.420(2)
_cell_length_b                   17.208(4)
_cell_length_c                   7.519(2)
_cell_measurement_reflns_used    22
_cell_measurement_temperature    298(2)
_cell_volume                     1348.2(5)
_computing_cell_refinement       'MXC(MAC Science)'
_computing_data_collection       'MXC(MAC Science)'
_computing_data_reduction        'maXusBruker SAINTL'
_computing_molecular_graphics    maXus
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_computing_structure_refinement  maXus
_computing_structure_solution    maXus
_diffrn_ambient_temperature      298(2)
_diffrn_measurement_device_type  'Mac Science MXC18'
_diffrn_measurement_method       theta/2theta
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.5418
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
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_diffrn_reflns_theta_max         53.80
_diffrn_reflns_theta_min         1
_exptl_absorpt_coefficient_mu    0.6614
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
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_exptl_crystal_description       cube
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_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.30
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_refine_diff_density_min         -0.14
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_refine_ls_shift/su_max          0.6447
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                1156
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_reflns_threshold_expression     >3sigma(I)
_cod_data_source_file            ja001064c_1.cif
_cod_data_source_block           C~16~H~15~O~2~N
_cod_original_cell_volume        1348.3(6)
_cod_original_formula_sum        'C16 H15 O2 N'
_cod_database_code               4116181