A homoleptic Ag<sup>III</sup> complex stabilized by succinimidate ligands.
Larsen, Emil Mickey Hilligsøe; Brock-Nannestad, Theis; Skibsted, Jørgen; Reinholdt, Anders; Bendix, Jesper; Chemical science 15 (2024) 18067–18075; doi:10.1039/d4sc04843a

data_1572714
_publ_section_title
;
 A homoleptic Ag<sup>III</sup> complex stabilized by succinimidate
 ligands.
;
_journal_issue                   43
_journal_name_full               'Chemical science'
_journal_page_first              18067
_journal_page_last               18075
_journal_paper_doi               10.1039/d4sc04843a
_journal_volume                  15
_journal_year                    2024
_chemical_formula_moiety         'C16 H18 Ag2 N4 O9, 4(H2 O)'
_chemical_formula_sum            'C16 H26 Ag2 N4 O13'
_chemical_formula_weight         698.15
_space_group_crystal_system      tetragonal
_space_group_IT_number           87
_space_group_name_Hall           '-I 4'
_space_group_name_H-M_alt        'I 4/m'
_atom_sites_solution_hydrogens   mixed
_audit_creation_date             2023-05-06
_audit_creation_method
;
Olex2 1.2
(compiled 2015.09.30 svn.r3233 for OlexSys, GUI svn.r5103)
;
_audit_update_record
;
2024-06-26 deposited with the CCDC.	2024-09-17 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   11.321(3)
_cell_length_b                   11.321
_cell_length_c                   9.154(3)
_cell_measurement_reflns_used    4822
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.610
_cell_measurement_theta_min      2.542
_cell_volume                     1173.2(5)
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_diffrn_ambient_temperature      293.15
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 1.001
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0228
_diffrn_reflns_av_unetI/netI     0.0200
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 1.001
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            3315
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 1.001
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         29.545
_diffrn_reflns_theta_min         2.544
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.742
_exptl_absorpt_correction_T_max  0.7459
_exptl_absorpt_correction_T_min  0.5526
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.1316 before and 0.0621 after correction.
The Ratio of minimum to maximum transmission is 0.7408.
The \l/2 correction factor is Not present.
;
_exptl_crystal_colour            'clear yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.976
_exptl_crystal_description       block
_exptl_crystal_F_000             696
_exptl_crystal_size_max          0.244
_exptl_crystal_size_mid          0.078
_exptl_crystal_size_min          0.058
_refine_diff_density_max         0.437
_refine_diff_density_min         -1.554
_refine_diff_density_rms         0.110
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.149
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     54
_refine_ls_number_reflns         876
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.148
_refine_ls_R_factor_all          0.0299
_refine_ls_R_factor_gt           0.0293
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0493P)^2^+1.2702P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0811
_refine_ls_wR_factor_ref         0.0817
_reflns_Friedel_coverage         0.000
_reflns_number_gt                857
_reflns_number_total             876
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4sc04843a2.cif
_cod_data_source_block           mo_d8v1592_0m-test
_cod_depositor_comments
'Adding full bibliography for 1572714--1572719.cif.'
_cod_original_cell_volume        1173.2(8)
_cod_database_code               1572714
_shelxl_version_number           2013-3
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H,H) groups
2. Restrained distances
 O2-H2
 1.07 with sigma of 0.01
 Ag2-H2
 0.89 with sigma of 0.01
3. Others
 Fixed Sof: Ag2(0.125) O2(0.125) H2(0.25)
 Fixed Uiso: H2(0.09)
4.a Secondary CH2 refined with riding coordinates:
 C2(H2A,H2B)
;
_shelx_res_checksum              25055
_shelx_hkl_checksum              74776
_olex2_submission_special_instructions 'No special instructions were received'