Syntheses and Structures of Mixed-Metal Sulfido Clusters Containing Trimetallic M2M'S4 (M = Mo, W; M' = Pd, Pt) and Tetrametallic Cubane-Type Mo2Pd2S4 Cores
Tomotake Ikada; Shigeki Kuwata; Yasushi Mizobe; Masanobu Hidai; Inorganic Chemistry 37 (1998) 5793–5797; doi:10.1021/ic980133+

data_4327689
_publ_contact_author
;
    Masanobu Hidai
 Department of Chemstry and Biotechnology, Graduate Scool of Engineering,
The University of Tokyo, Hongo, Tokyo 113-8656, Japan
;
_publ_contact_author_fax         ' 81-3-5800-6945 '
_publ_contact_author_phone       ' 81-3-5800-6945 '
_publ_section_title
;
 Syntheses and Structures of Mixed-Metal Sulfido Clusters Containing
 Trimetallic M2M'S4 (M = Mo, W; M' = Pd, Pt) and Tetrametallic Cubane-Type
 Mo2Pd2S4 Cores
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5793
_journal_page_last               5797
_journal_paper_doi               10.1021/ic980133+
_journal_volume                  37
_journal_year                    1998
_chemical_formula_sum            'C30 H37 N2 P Pt S W2'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_creation_date             'Tue Mar 18 21:27:40 1997'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 95.24(1)
_cell_angle_gamma                90
_cell_formula_units_Z            8.00
_cell_length_a                   13.718(3)
_cell_length_b                   12.795(2)
_cell_length_c                   43.798(2)
_cell_measurement_reflns_used    21
_cell_measurement_temperature    23.0
_cell_measurement_theta_max      29.90
_cell_measurement_theta_min      29.16
_cell_volume                     7655(2)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_computing_structure_solution    'DIRDIF92 (PATTY)'
_diffrn_ambient_temperature      23.0
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
_diffrn_orient_matrix_UB_11      -0.02716
_diffrn_orient_matrix_UB_12      -0.03782
_diffrn_orient_matrix_UB_13      -0.01887
_diffrn_orient_matrix_UB_21      0.03797
_diffrn_orient_matrix_UB_22      0.04689
_diffrn_orient_matrix_UB_23      -0.01282
_diffrn_orient_matrix_UB_31      0.05639
_diffrn_orient_matrix_UB_32      -0.04980
_diffrn_orient_matrix_UB_33      0.00226
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  8.59
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -1
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_limit_l_min       -45
_diffrn_reflns_number            14476
_diffrn_reflns_theta_max         27.4925
_diffrn_standards_decay_%        -0.08
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu_cm 101.347
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_correction_T_min  0.241
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            purple
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_exptl_crystal_description       plate
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_refine_diff_density_max         -1.86660
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_refine_ls_extinction_coef       0.00000
_refine_ls_extinction_method     Zachariasen_type_2_gaussian_isotropic
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         4420
_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0520
_refine_ls_shift/esd_max         0.2260
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0380
_cod_data_source_file            ic9801332B.cif
_cod_data_source_block           '[Pt(PPh3)(m2-S)2{W(S2CNEt2)2}2(m2-S)2]'
_cod_original_cell_volume        7654(1)
_cod_original_sg_symbol_H-M      'C 2/c '
_cod_original_formula_sum        'C30 H37 N2 P S Pt W2'
_cod_database_code               4327689