Geometry-dependent divergence in the gold-catalyzed redox cascade cyclization of o-alkynylaryl ketoximes and nitrones leading to isoindoles
Yeom, Hyun-Suk; Lee, Youngun; Lee, Ji-Eun; Shin, Seunghoon; Organic & Biomolecular Chemistry 7 (2009) 4744–4752; doi:10.1039/b910757f

data_7153547
_publ_section_title
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 Geometry-dependent divergence in the gold-catalyzed redox cascade
 cyclization of o-alkynylaryl ketoximes and nitrones leading to isoindoles
;
_journal_issue                   22
_journal_name_full               'Organic &amp; Biomolecular Chemistry'
_journal_page_first              4744
_journal_page_last               4752
_journal_paper_doi               10.1039/b910757f
_journal_volume                  7
_journal_year                    2009
_chemical_formula_sum            'C19 H19 N O'
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_cell_angle_beta                 101.820(2)
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_cell_length_b                   16.6385(9)
_cell_length_c                   16.9325(7)
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_diffrn_reflns_theta_max         28.41
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_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0910P)^2^+1.5886P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1878
_refine_ls_wR_factor_ref         0.2197
_reflns_number_gt                8950
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b910757fsup1.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        2992.1(2)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7153547