Pd(OAc)2/o-chloranil/M(OTf)n: a catalyst for the direct C-H arylation of polycyclic aromatic hydrocarbons with boryl-, silyl-, and unfunctionalized arenes.
Kawasumi, Katsuaki; Mochida, Kenji; Kajino, Tomonori; Segawa, Yasutomo; Itami, Kenichiro; Organic letters 14 (2012) 418–421; doi:10.1021/ol203235w

data_1503582
_publ_section_title
;
 Pd(OAc)2/o-chloranil/M(OTf)n: a catalyst for the direct C-H arylation of
 polycyclic aromatic hydrocarbons with boryl-, silyl-, and
 unfunctionalized arenes.
;
_journal_issue                   1
_journal_name_full               'Organic letters'
_journal_page_first              418
_journal_page_last               421
_journal_paper_doi               10.1021/ol203235w
_journal_volume                  14
_journal_year                    2012
_chemical_formula_sum            'C26 H16'
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_cell_length_c                   27.417(11)
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_computing_cell_refinement       'RIGAKU CrystalClear'
_computing_data_collection       'RIGAKU CrystalClear'
_computing_data_reduction        'RIGAKU CrystalClear'
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_diffrn_measured_fraction_theta_max 0.997
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;
Saturn70 CCD (4x4 bin mode) with MicroMax-007
;
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_exptl_crystal_colour            Colorless
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Platelet
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1270P)^2^+0.6107P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                1515
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ol203235w_si_001.cif
_cod_data_source_block           3j
_cod_depositor_comments
;
The following automatic conversions were performed:
'_atom_site_symetry_multiplicity' tag replaced with
'_atom_site_symmetry_multiplicity'.

Automatic conversion script
Id: cif_correct_tags 1440 2010-10-19 06:21:57Z saulius 

The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1663.7(11)
_cod_original_sg_symbol_H-M      P21/a
_cod_database_code               1503582