Evidence of proton-coupled mixed-valency by electrochemical behavior on transition metal complex dimers bridged by two Ag<sup>+</sup> ions.
Tadokoro, Makoto; Isogai, Kazuo; Harada, Shohei; Kouchi, Takaya; Yamane, Takeshi; Sugaya, Tomoaki; Kamebuchi, Hajime; Dalton transactions (Cambridge, England : 2003) 48 (2019) 535–546; doi:10.1039/c8dt03962c

data_7048324
_publ_section_title
;
 Evidence of proton-coupled mixed-valency by electrochemical behavior on
 transition metal complex dimers bridged by two Ag<sup>+</sup> ions.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              535
_journal_page_last               546
_journal_paper_doi               10.1039/c8dt03962c
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C144 H282 Cl12 N24 Os6 P12'
_chemical_formula_weight         4288.16
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2018-11-01 deposited with the CCDC.
2018-11-15 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 104.095(2)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   45.768(5)
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_cell_length_c                   33.927(4)
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_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      23.75
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_computing_cell_refinement       'Bruker SAINT'
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_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      273(2)
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_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0810
_diffrn_reflns_av_unetI/netI     0.1100
_diffrn_reflns_Laue_measured_fraction_full 0.999
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_diffrn_reflns_number            119850
_diffrn_reflns_point_group_measured_fraction_full 0.999
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_exptl_crystal_colour            purple
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_exptl_crystal_description       block
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0438P)^2^+496.0577P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                27425
_reflns_number_total             43447
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt03962c2.cif
_cod_data_source_block           OsPPr3Cl2Hbim_dimer_100
_cod_depositor_comments
'Adding full bibliography for 7048323--7048326.cif.'
_cod_original_cell_volume        38264(7)
_cod_database_code               7048324
_shelx_estimated_absorpt_t_min   0.481
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