Interaction of copper(II) (3 + 2) N-chelating complexes with DNA and BSA: hydrolytic DNA cleavage and ROS-mediated apoptosis.
Murali, Mariappan; Kanchana Mala, Anbarasu; Sangeetha, Somasundaram; Selvakumaran, Balasubramaniam; Arul Prakash, Pitchan; Shanmugavadivel, Selvaraj; Ajay Kamal, Tamilarasan; Mohamed Jaabir, Mohamed Sultan; Dalton transactions (Cambridge, England : 2003)  (2026) –; doi:10.1039/d5dt02476e

data_7720841
_publ_section_title
;
 Interaction of copper(II) (3 + 2) N-chelating complexes with DNA and BSA:
 hydrolytic DNA cleavage and ROS-mediated apoptosis.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5466
_journal_page_last               5484
_journal_paper_doi               10.1039/d5dt02476e
_journal_volume                  55
_journal_year                    2026
_chemical_formula_sum            'C26 H23 Cl2 Cu N5 O8'
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_audit_update_record
;
2022-01-19 deposited with the CCDC.	2026-03-19 downloaded from the CCDC.
;
_cell_angle_alpha                90
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'ORTEP3 (Farrugia, 1997) and Mercury (Bruno et al., 2002)'
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_diffrn_measurement_device_type  'Bruker axs kappa apex2 CCD Diffractometer'
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0507
_refine_ls_R_factor_gt           0.0397
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0434P)^2^+3.4215P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0994
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           NEW
_cod_depositor_comments          'Adding full bibliography for 7720841.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
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_shelx_res_checksum              11714