Rapid synthesis of azepinoindole derivatives from tryptamine sulfonamides and bromoallyl sulfones <i>via</i> an acid-mediated cyclization and rearrangement.
Gurram, Ravikumar; Nanubolu, Jagadeesh Babu; Menon, Rajeev S.; Chemical communications (Cambridge, England) 57 (2021) 635–638; doi:10.1039/d0cc06991d

data_7127583
_publ_section_title
;
 Rapid synthesis of azepinoindole derivatives from tryptamine sulfonamides
 and bromoallyl sulfones <i>via</i> an acid-mediated cyclization and
 rearrangement.
;
_journal_issue                   5
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              635
_journal_page_last               638
_journal_paper_doi               10.1039/d0cc06991d
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C21 H24 N2 O4 S2'
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_audit_update_record
;
2020-08-26 deposited with the CCDC.	2020-12-14 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0618P)^2^+0.9197P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1306
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_reflns_number_gt                4496
_reflns_number_total             4850
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0cc06991d2.cif
_cod_data_source_block           BE40M
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7127582--7127583.cif.
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7127583
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_shelx_res_checksum              7547