<i>catena</i>-Poly[[dichloridomercury(II)]-μ-1,4-bis[(pyridin-2-yl)methoxy]benzene-κ^2^<i>N</i>:<i>N</i>']
Liu, Ying; Zhang, Hong-Sen; Hu, Ming-Xing; Hou, Guang-Feng; Gao, Jin-Sheng; Acta Crystallographica Section E 67 (2011) m1427–; doi:10.1107/S1600536811038323

data_2231927
_publ_section_title
;
 <i>catena</i>-Poly[[dichloridomercury(II)]-\m-1,4-bis[(pyridin-2-yl)methoxy]benzene-\k^2^<i>N</i>:<i>N</i>']
;
_journal_coeditor_code           HY2469
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1427
_journal_paper_doi               10.1107/S1600536811038323
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Hg Cl2 (C18 H16 N2 O2)]'
_chemical_formula_moiety         'C18 H16 Cl2 Hg N2 O2'
_chemical_formula_sum            'C18 H16 Cl2 Hg N2 O2'
_chemical_formula_weight         563.82
_chemical_name_common
;
<i>catena</i>-Poly[[dichloridomercury(II)]-\m-1,4-bis[(pyridin-2-
yl)methoxy]benzene-\k^2^<i>N</i>:<i>N</i>']
;
_chemical_name_systematic
;
 <i>catena</i>-Poly[dichlorido{\m-1,4-bis[(pyridin-2-yl)methoxy]benzene-\
\k^2^<i>N</i>:<i>N</i>'}mercury(II)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                86.11(2)
_cell_angle_beta                 66.51(2)
_cell_angle_gamma                73.860(18)
_cell_formula_units_Z            2
_cell_length_a                   9.201(5)
_cell_length_b                   10.335(5)
_cell_length_c                   11.040(6)
_cell_measurement_reflns_used    8238
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.52
_cell_measurement_theta_min      3.61
_cell_volume                     923.8(9)
_computing_cell_refinement       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_collection       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_reduction        'CrystalStructure (Rigaku/MSC, 2002)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 1999)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       '\w scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0509
_diffrn_reflns_av_sigmaI/netI    0.0692
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            9080
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.61
_exptl_absorpt_coefficient_mu    8.633
_exptl_absorpt_correction_T_max  0.3249
_exptl_absorpt_correction_T_min  0.2880
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.027
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             536
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.17
_refine_diff_density_max         1.556
_refine_diff_density_min         -1.735
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.164
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     226
_refine_ls_number_reflns         4179
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.164
_refine_ls_R_factor_all          0.0436
_refine_ls_R_factor_gt           0.0357
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0627P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1041
_refine_ls_wR_factor_ref         0.1217
_reflns_number_gt                3688
_reflns_number_total             4179
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            hy2469.cif
_cod_data_source_block           I
_cod_database_code               2231927
_cod_database_fobs_code          2231927