Magnetic structures of Fe<sub>32+δ</sub>Ge<sub>33</sub>As<sub>2</sub> and Fe<sub>32+δ'</sub>Ge<sub>35-x</sub>P<sub>x</sub> intermetallic compounds: a neutron diffraction and <sup>57</sup>Fe Mössbauer spectroscopy study.
Khalaniya, R. A.; Sobolev, A. V.; Verchenko, V. Yu; Tsirlin, A. A.; Senyshyn, A.; Damay, F.; Presniakov, I. A.; Shevelkov, A. V.; Dalton transactions (Cambridge, England : 2003) 50 (2021) 2210–2220; doi:10.1039/d0dt03923c

data_7706504
_publ_section_title
;
 Magnetic structures of Fe<sub>32+\d</sub>Ge<sub>33</sub>As<sub>2</sub>
 and Fe<sub>32+\d'</sub>Ge<sub>35-x</sub>P<sub>x</sub> intermetallic
 compounds: a neutron diffraction and <sup>57</sup>Fe M\"ossbauer
 spectroscopy study.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2210
_journal_page_last               2220
_journal_paper_doi               10.1039/d0dt03923c
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'Fe32.447 Ge32.489 P2.511'
_chemical_formula_sum            'Fe32.447 Ge32.489 P2.511'
_chemical_formula_weight         4248.2
_space_group_IT_number           191
_space_group_name_Hall           '-P 6 2'
_space_group_name_H-M_alt        'P 6/m m m'
_symmetry_cell_setting           hexagonal
_symmetry_Int_Tables_number      191
_symmetry_space_group_name_Hall  '-P 6 2'
_symmetry_space_group_name_H-M   'P 6/m m m'
_audit_creation_method           'Jana2006 Version : 25/04/2020'
_audit_update_record
;
2020-11-10 deposited with the CCDC.	2021-01-11 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            1
_cell_length_a                   11.88568(8)
_cell_length_b                   11.88568(8)
_cell_length_c                   7.50310(8)
_cell_measurement_temperature    150
_cell_volume                     917.951(13)
_diffrn_ambient_temperature      150
_diffrn_detector_type            '80 position-sensitive 3He tubes'
_diffrn_measurement_device       'high resolution powder diffractometer'
_diffrn_measurement_device_type  'SPODI high resolution powder diffractometer'
_diffrn_radiation_monochromator  'Ge (551) monochromator'
_diffrn_radiation_probe          neutron
_diffrn_radiation_type           neutron
_diffrn_radiation_wavelength     1.5482
_exptl_absorpt_coefficient_mu    0.015
_exptl_crystal_density_diffrn    7.6849
_exptl_crystal_description       powder
_exptl_crystal_F_000             585.429
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.05
_pd_meas_2theta_range_max        151.900
_pd_meas_2theta_range_min        0.950
_pd_meas_number_of_points        3020
_pd_proc_2theta_range_inc        0.05
_pd_proc_2theta_range_max        151.9
_pd_proc_2theta_range_min        6.05
_pd_proc_ls_background_function  '10 Legendre polynoms'
_pd_proc_ls_pref_orient_corr     none
_pd_proc_ls_profile_function     Gaussian
_pd_proc_ls_prof_R_factor        0.0312
_pd_proc_ls_prof_wR_expected     0.0145
_pd_proc_ls_prof_wR_factor       0.0387
_refine_ls_goodness_of_fit_all   2.66
_refine_ls_number_constraints    0
_refine_ls_number_parameters     62
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0223
_refine_ls_R_factor_gt           0.0222
_refine_ls_shift/su_max          0.0091
_refine_ls_shift/su_mean         0.0007
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0278
_refine_ls_wR_factor_gt          0.0278
_cod_data_source_file            d0dt03923c2.cif
_cod_data_source_block           Fe32p5Ge32P3_150K
_cod_depositor_comments
'Adding full bibliography for 7706499--7706504.cif.'
_cod_original_cell_volume        917.950(13)
_cod_original_sg_symbol_Hall     '-P 6;-2'
_cod_database_code               7706504