Energy transfer luminescence of Tb3+ ion complexed with calix[4]arenetetrasulfonate and the thia and sulfonyl analogue. The effect of bridging groupsElectronic supplementary information (ESI) available: emission spectra of Sm3+ and Dy3+ ions complexed with 2; emission spectra of Sm3+, Eu3+ and Dy3+ complexed with 3; continuous variation curves for the Tb3+ complexes with 2 and 3. See http://www.rsc.org/suppdata/p2/b0/b009151k/
Iki, Nobuhiko; Horiuchi, Takayuki; Oka, Hiromi; Koyama, Katsuyoshi; Morohashi, Naoya; Kabuto, Chizuko; Miyano, Sotaro; Journal of the Chemical Society, Perkin Transactions 2  (2001) 2219–; doi:10.1039/b009151k

data_7216963
_publ_section_title
;
 Energy transfer luminescence of Tb3+ ion complexed with
 calix[4]arenetetrasulfonate and the thia and sulfonyl analogue. The
 effect of bridging groupsElectronic supplementary information (ESI)
 available: emission spectra of Sm3+ and Dy3+ ions complexed with 2;
 emission spectra of Sm3+, Eu3+ and Dy3+ complexed with 3; continuous
 variation curves for the Tb3+ complexes with 2 and 3. See
 http://www.rsc.org/suppdata/p2/b0/b009151k/
;
_journal_issue                   11
_journal_name_full
'Journal of the Chemical Society, Perkin Transactions 2'
_journal_page_first              2219
_journal_paper_doi               10.1039/b009151k
_journal_year                    2001
_chemical_formula_sum            'C26 H35 Na5 O34 S8'
_chemical_formula_weight         1262.97
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 90.4770(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.9774(9)
_cell_length_b                   25.096(1)
_cell_length_c                   14.9633(5)
_cell_measurement_reflns_used    9448
_cell_measurement_temperature    180.2
_cell_measurement_theta_max      27.4
_cell_volume                     4497.6(4)
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 0.9075
_diffrn_measured_fraction_theta_max 0.9075
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.033
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            36087
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.556
_exptl_absorpt_correction_T_max  0.920
_exptl_absorpt_correction_T_min  0.786
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Jacobson, 1998)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.865
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.150
_refine_diff_density_max         0.45
_refine_diff_density_min         -0.66
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     655
_refine_ls_number_reflns         7401
_refine_ls_R_factor_gt           0.0567
_refine_ls_shift/su_max          0.0068
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      unit
_refine_ls_wR_factor_ref         0.0655
_reflns_number_gt                7401
_reflns_number_total             9352
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            b009151k.txt
_cod_data_source_block           EtOH-Na5
_cod_original_cell_volume        4497.5(4)
_cod_original_formula_sum        'C26 H35 Na5 O34 S8 '
_cod_database_code               7216963