Probing the donor strength of yldiide ligands: synthesis, structure and reactivity of rhodium complexes with a PC<sub>ylide</sub>N pincer ligand.
Lapointe, Sébastien; Duari, Prakash; Gessner, Viktoria H.; Chemical science 14 (2023) 3816–3825; doi:10.1039/d2sc06759e

data_1568649
_publ_section_title
;
 Probing the donor strength of yldiide ligands: synthesis, structure and
 reactivity of rhodium complexes with a PC<sub>ylide</sub>N pincer ligand.
;
_journal_issue                   14
_journal_name_full               'Chemical science'
_journal_page_first              3816
_journal_page_last               3825
_journal_paper_doi               10.1039/d2sc06759e
_journal_volume                  14
_journal_year                    2023
_chemical_formula_sum            'C55 H65 Cl N2 O P3 Rh'
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;
2022-11-19 deposited with the CCDC.	2023-03-13 downloaded from the CCDC.
;
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;
CrysAlisPro 1.171.40.20a (Rigaku Oxford Diffraction, 2018)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
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_exptl_crystal_description       plate
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0461P)^2^+0.9766P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           SL-198
_cod_depositor_comments
'Adding full bibliography for 1568644--1568653.cif.'
_cod_original_cell_volume        2584.42(5)
_cod_database_code               1568649
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.552
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_shelx_res_checksum              38332
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