Robust bi-directional photoswitching of thiomethyl substituted arylazopyrazoles under visible light.
Bhunia, Supriya; Dolai, Anirban; Samanta, Subhas; Chemical communications (Cambridge, England) 56 (2020) 10247–10250; doi:10.1039/d0cc04098c

data_7127001
_publ_section_title
;
 Robust bi-directional photoswitching of thiomethyl substituted
 arylazopyrazoles under visible light.
;
_journal_issue                   70
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              10247
_journal_page_last               10250
_journal_paper_doi               10.1039/d0cc04098c
_journal_volume                  56
_journal_year                    2020
_chemical_formula_moiety         'C13 H16 N4 S'
_chemical_formula_sum            'C13 H16 N4 S'
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_chemical_properties_physical    Photo-sensitive
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
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;
2020-07-10 deposited with the CCDC.	2020-07-17 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker-AXS SMART APEXII diffractometer'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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'Re-crystallisation from solvent: Methanol-Diethyl ether'
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'w=1/[\s^2^(Fo^2^)+(0.1672P)^2^+0.0736P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7127000--7127001.cif.'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C6(H6), C3(H3), C5(H5), C4(H4)
2.b Idealised Me refined as rotating group:
 C11(H11A,H11B,H11C), C13(H13A,H13B,H13C), C14(H14A,H14B,H14C), C12(H12A,H12B,
 H12C)
;
_shelx_res_checksum              49830
_olex2_submission_special_instructions 'No special instructions were received'