Bromoargentate/g-C3N4 heterojunction by in situ growth: 2-D bromoargentate framework with a transition metal complex linker and cocatalyst for enhanced photocatalytic activity via g-C3N4 hybrid
Tian, Yiming; Ren, Taohong; Zhu, Hongjin; Jia, Dingxian; CrystEngComm 26 (2024) 3911–3919; doi:10.1039/D4CE00510D

data_7248938
_publ_section_title
;
 Bromoargentate/g-C3N4 heterojunction by in situ growth: 2-D
 bromoargentate framework with a transition metal complex linker and
 cocatalyst for enhanced photocatalytic activity via g-C3N4 hybrid
;
_journal_issue                   29
_journal_name_full               CrystEngComm
_journal_page_first              3911
_journal_page_last               3919
_journal_paper_doi               10.1039/D4CE00510D
_journal_volume                  26
_journal_year                    2024
_chemical_formula_sum            'C24 H18 Ag3 Br5 Cu2 N4 O2'
_chemical_formula_weight         1244.66
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2024-04-12 deposited with the CCDC.	2024-07-02 downloaded from the CCDC.
;
_cell_angle_alpha                110.378(4)
_cell_angle_beta                 107.663(4)
_cell_angle_gamma                92.224(5)
_cell_formula_units_Z            2
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_cell_length_b                   10.9876(15)
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_cell_measurement_temperature    296(2)
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_cell_volume                     1459.0(4)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 14.63
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1263
_diffrn_reflns_av_unetI/netI     0.0553
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
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_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            53670
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.350
_diffrn_reflns_theta_min         2.146
_exptl_absorpt_coefficient_mu    10.290
_exptl_absorpt_correction_T_max  0.4260
_exptl_absorpt_correction_T_min  0.2331
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    2.833
_exptl_crystal_description       rod
_exptl_crystal_F_000             1160
_exptl_crystal_size_max          0.300
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_refine_diff_density_max         1.573
_refine_diff_density_min         -1.229
_refine_diff_density_rms         0.318
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         5325
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.093
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_refine_ls_R_factor_gt           0.0482
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0898P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1311
_refine_ls_wR_factor_ref         0.1428
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4323
_reflns_number_total             5325
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4ce00510d2.cif
_cod_data_source_block           a2
_cod_depositor_comments          'Adding full bibliography for 7248938.cif.'
_cod_database_code               7248938
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.233
_shelx_estimated_absorpt_t_max   0.426
_shelx_res_checksum              6095