Lutidine-Derived Ru-CNC Hydrogenation Pincer Catalysts with Versatile Coordination Properties
Filonenko, Georgy A.; Cosimi, Elena; Lefort, Laurent; Conley, Matthew P.; Copéret, Christophe; Lutz, Martin; Hensen, Emiel J. M.; Pidko, Evgeny A.; ACS Catalysis 4 (2014) 2667–; doi:10.1021/cs500720y

data_4511610
_publ_section_title
;
 Lutidine-Derived Ru-CNC Hydrogenation Pincer Catalysts with Versatile
 Coordination Properties
;
_journal_issue                   8
_journal_name_full               'ACS Catalysis'
_journal_page_first              2667
_journal_paper_doi               10.1021/cs500720y
_journal_volume                  4
_journal_year                    2014
_chemical_formula_moiety         'C34 H37 N6 O Ru, B F4'
_chemical_formula_sum            'C34 H37 B F4 N6 O Ru'
_chemical_formula_weight         733.57
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;
 ?
;
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_diffrn_ambient_temperature      150(2)
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_diffrn_source                   'sealed tube'
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         9089
_refine_ls_number_restraints     142
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0262
_refine_ls_R_factor_gt           0.0229
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0257P)^2^+1.0207P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0583
_refine_ls_wR_factor_ref         0.0597
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_reflns_number_gt                8311
_reflns_number_total             9089
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            cs500720y_si_002.cif
_cod_data_source_block           l0493a
_cod_depositor_comments
'Adding full bibliography for 4511609--4511614.cif.'
_cod_database_code               4511610
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