Di-μ~2~-acetato-1:2κ^2^<i>O</i>:<i>O</i>';2:3κ^2^<i>O</i>:<i>O</i>'-bis(<i>N</i>,<i>N</i>'-dimethylformamide)-1κ<i>O</i>,3κ<i>O</i>-bis{μ~2~-2,2'-[propane-1,3-diylbis(iminomethylene)]diphenolato-1κ^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>':2κ^2^<i>O</i>,<i>O</i>';2κ^2^<i>O</i>,<i>O</i>':3κ^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>'-1,3-dinickel(II)-2-cadmium(II)
Tatar Yıldırım, Leyla; Atakol, Orhan; Acta Crystallographica, Section E 64 (2008) m291–m292; doi:10.1107/S1600536807067724

data_2217579
_publ_section_title
Di-\m~2~-acetato-1:2\k^2^<i>O</i>:<i>O</i>';2:3\k^2^<i>O</i>:<i>O</i>'-bis(<i>N</i>,<i>N</i>'-dimethylformamide)-1\k<i>O</i>,3\k<i>O</i>-bis{\m~2~-2,2'-[propane-1,3-diylbis(iminomethylene)]diphenolato-1\k^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>':2\k^2^<i>O</i>,<i>O</i>';2\k^2^<i>O</i>,<i>O</i>':3\k^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>'-1,3-dinickel(II)-2-cadmium(II)
_journal_coeditor_code           LH2581
_journal_issue                   2
_journal_name_full               'Acta Crystallographica, Section E'
_journal_page_first              m291
_journal_page_last               m292
_journal_paper_doi               10.1107/S1600536807067724
_journal_volume                  64
_journal_year                    2008
_chemical_formula_iupac
'[Ni2 Cd (C17 H16 N2 O2)2 (C2 H3 O2)2 (C3 H7 N O)2]'
_chemical_formula_moiety         'C44 H60 Cd1 N6 Ni2 O10'
_chemical_formula_sum            'C44 H60 Cd N6 Ni2 O10'
_chemical_formula_weight         1062.77
_chemical_name_systematic
;
Di-\m~2~-acetato-1:2\k^2^O:O';2:3\k^2^O:O'-bis(N,N'-dimethylformamide)-
1\kO,3\kO-bis{\m~2~-2,2'-[propane-1,3-diylbis(iminomethylene)]diphenolato-
1\k^4^O,N,N',O':2\k^2^O,O';2\k^2^O,O':3\k^4^O,N,N',O'-1,3-dinickel(II)-
2-cadmium(II)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geomtr
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 92.12(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.285(3)
_cell_length_b                   18.040(5)
_cell_length_c                   12.590(3)
_cell_measurement_reflns_used    15
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      11.06
_cell_measurement_theta_min      9.96
_cell_volume                     2334.4(11)
_computing_cell_refinement       'CAD-4 EXPRESS (Enraf--Nonius, 1994)'
_computing_data_collection       'CAD-4 EXPRESS (Enraf--Nonius, 1994)'
_computing_data_reduction        'XCAD4 (Harms & Wocadlo, 1995)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_measured_fraction_theta_full 0.874
_diffrn_measured_fraction_theta_max 0.874
_diffrn_measurement_device       '\k-geometry diffractometer'
_diffrn_measurement_device_type  'Enraf--Nonius TurboCAD-4'
_diffrn_measurement_method       'non-profiled \w'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0758
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            3960
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         2.51
_diffrn_standards_decay_%        1
_diffrn_standards_interval_time  120
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.311
_exptl_absorpt_correction_T_max  0.877
_exptl_absorpt_correction_T_min  0.854
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North <i>et al.</i>,  1968)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.512
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1100
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_refine_diff_density_max         0.882
_refine_diff_density_min         -1.514
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     287
_refine_ls_number_reflns         3612
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_gt           0.0715
_refine_ls_shift/su_max          0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1184P)^2^+12.1765P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2394
_reflns_number_gt                1997
_reflns_number_total             3612
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            lh2581.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2217579