Syntheses and Physical Properties of Quasi-One-Dimensional Halogen-Bridged CuII-PtIV Mixed-Metal Complexes [Cu(chxn)2][PtX2(chxn)2]X4
Takuya Kawashima; Kenzi Takai; Hidemitsu Aso; Toshio Manabe; Kouichi Takizawa; Chihiro Kachi-Terajima; Tomohiko Ishii; Hitoshi Miyasaka; Hiroyuki Matsuzaka; Masahiro Yamashita; Hiroshi Okamoto; Hiroshi Kitagawa; Motoo Shiro; Koshiro Toriumi; Inorganic Chemistry 40 (2001) 6651–6655; doi:10.1021/ic010341t

data_4320688
_publ_section_title
;
 Syntheses and Physical Properties of Quasi-One-Dimensional
 Halogen-Bridged CuII-PtIV Mixed-Metal Complexes
 [Cu(chxn)2][PtX2(chxn)2]X4
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6651
_journal_page_last               6655
_journal_paper_doi               10.1021/ic010341t
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C24 H56 Cl6 Cu N8 Pt'
_chemical_formula_weight         928.11
_space_group_IT_number           23
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'I 2 2'
_symmetry_space_group_name_H-M   'I 2 2 2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   24.237(1)
_cell_length_b                   5.103(1)
_cell_length_c                   6.854(1)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      12.5
_cell_volume                     847.7(2)
_computing_molecular_graphics    ORTEP
_computing_structure_refinement  RADIEL(Coppens,1976)
_diffrn_measurement_device_type  CAD4_Nonius
_diffrn_measurement_method       \q/2q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            1466
_diffrn_reflns_theta_max         30
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 100
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.486
_exptl_absorpt_correction_T_max  0.727
_exptl_absorpt_correction_T_min  0.576
_exptl_absorpt_correction_type   gaussian
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    1.816
_exptl_crystal_description       squareplate
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.78
_refine_diff_density_min         -0.36
_refine_ls_goodness_of_fit_ref   1.138
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     79
_refine_ls_number_reflns         1243
_refine_ls_R_factor_gt           0.019
_refine_ls_shift/su_max          0.088
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     W~-1~=[\s(F)+(0.015*F)^2^]
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0236
_reflns_number_gt                1243
_reflns_number_total             1243
_reflns_threshold_expression     u(F)
_cod_data_source_file            ic010341t_2.cif
_cod_data_source_block           ?
_cod_original_sg_symbol_H-M      'I 2 2 2 '
_cod_original_formula_sum        'C24 H56 Cl6 Cu  N8 Pt '
_cod_database_code               4320688