New Pt→M (M = Ag or Tl) complexes based on anionic cyclometalated Pt(ii) complexes.
Campillo, David; Belío, Úrsula; Martín, Antonio; Dalton transactions (Cambridge, England : 2003) 48 (2019) 3270–3283; doi:10.1039/c9dt00121b

data_7048941
_publ_section_title
;
 New Pt\\rightarrow M (M = Ag or Tl) complexes based on anionic
 cyclometalated Pt(ii) complexes.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3270
_journal_page_last               3283
_journal_paper_doi               10.1039/c9dt00121b
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C72 H52 Ag2 N4 P2 Pt2, C H2 Cl2'
_chemical_formula_sum            'C73 H54 Ag2 Cl2 N4 P2 Pt2'
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_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
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_atom_sites_solution_hydrogens   geom
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2018-11-06 deposited with the CCDC.
2019-02-08 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
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  1 omega   -8.00   56.00   1.0000   16.5900
omega____ theta____ kappa____ phi______ frames
    -       24.2116  -37.0000 -180.0000 64

  2 omega  -28.00   82.00   1.0000   16.5900
omega____ theta____ kappa____ phi______ frames
    -       24.2116   19.0000   60.0000 110

  3 omega  -26.00   32.00   1.0000   16.5900
omega____ theta____ kappa____ phi______ frames
    -       24.2116  -77.0000 -180.0000 58

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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0435
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_diffrn_reflns_limit_l_max       26
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_diffrn_reflns_number            27936
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.879
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         29.697
_diffrn_reflns_theta_min         4.242
_exptl_absorpt_coefficient_mu    5.321
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.83444
_exptl_absorpt_correction_type   multi-scan
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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_exptl_crystal_colour            'translucent light red'
_exptl_crystal_density_diffrn    1.854
_exptl_crystal_description       block
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_refine_diff_density_rms         0.200
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_refine_ls_number_reflns         15404
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0706
_refine_ls_R_factor_gt           0.0478
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0264P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0850
_refine_ls_wR_factor_ref         0.0949
_reflns_Friedel_coverage         0.000
_reflns_number_gt                11806
_reflns_number_total             15404
_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7048938--7048945.cif.'
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