Rearrangement of an aniline linked perylene bisimide under acidic conditions and visible to near-infrared emission from intramolecular charge-transfer state of its fused derivatives
Kojima, Mitsuru; Tamoto, Akira; Aratani, Naoki; Yamada, Hiroko; Chem. Commun.  (2017) –; doi:10.1039/C7CC01520H

data_7119976
_publ_section_title
;
 Rearrangement of an aniline linked perylene bisimide under acidic
 conditions and visible to near-infrared emission from intramolecular
 charge-transfer state of its fused derivatives
;
_journal_name_full               'Chem. Commun.'
_journal_paper_doi               10.1039/C7CC01520H
_journal_year                    2017
_chemical_formula_moiety         'C64 H56 N4 O4'
_chemical_formula_sum            'C64 H56 N4 O4'
_chemical_formula_weight         945.12
_chemical_name_systematic
'N,N'-bis(2,6-diisopropylphenyl)-4,13-bis(dimethylamino)- benzo[a,j]coronene-1,8,9,16-tetracarboxylic acid bisimide'
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_symmetry_space_group_name_Hall  'P 2yb'
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_audit_update_record
;
2017-02-23 deposited with the CCDC.
2017-04-18 downloaded from the CCDC.
;
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;
SADABS Sheldrick 1996
;
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_exptl_crystal_recrystallization_method 'Vapour deposition'
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;
 Refined as an inversion twin.
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1462P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_platon_squeeze_void_probe_radius 1.20