Mediating Oxidation States in Decamethyleuropocene Complexes. The Role of the Diazabutadiene Fragment
Moore, Jennifer A.; Cowley, Alan H.; Gordon, John C.; Organometallics 25 (2006) 5207–; doi:10.1021/om060793j

data_4074565
_publ_section_title
;
 Mediating Oxidation States in Decamethyleuropocene Complexes. The Role of
 the Diazabutadiene Fragment
;
_journal_issue                   22
_journal_name_full               Organometallics
_journal_page_first              5207
_journal_paper_doi               10.1021/om060793j
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C24 H40 Eu O'
_chemical_formula_sum            'C24 H40 Eu O'
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;
manual editing of the .cif file 
created by SHELXTL Ver. 6.10 
;
_cell_angle_alpha                90
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_cell_length_c                   18.541(5)
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_computing_cell_refinement       'Collect software, Nonius B.V. 1998'
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;
DENZO and Scalepack (Otwinoski and Minor, 1997)
;
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_computing_structure_solution
;
SIR97 - Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C., 
Guagliardi A., Moliterni A.G.G., Polidori G.,Spagna R.
;
_diffrn_ambient_temperature      153(2)
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_diffrn_measurement_method       \w-scan
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_exptl_absorpt_correction_type   multi-scan
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'DENZO and Scalepack (Otwinoski and Minor, 1997)'
_exptl_crystal_colour            red
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_exptl_crystal_F_000             1020
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0399P)^2^+0.8145P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om060793jsi20060831_010133.cif
_cod_data_source_block           (C5Me5)2EuOEt2.
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_Hall     P2ac2ab
_cod_original_sg_symbol_H-M      P212121
_cod_database_code               4074565