Nucleophilic reactivity of the gold atom in a diarylborylgold(i) complex toward polar multiple bonds.
Suzuki, Akane; Guo, Xueying; Lin, Zhenyang; Yamashita, Makoto; Chemical science 12 (2020) 917–928; doi:10.1039/d0sc05478j

data_1559586
_publ_section_title
;
 Nucleophilic reactivity of the gold atom in a diarylborylgold(i) complex
 toward polar multiple bonds.
;
_journal_issue                   3
_journal_name_full               'Chemical science'
_journal_page_first              917
_journal_page_last               928
_journal_paper_doi               10.1039/d0sc05478j
_journal_volume                  12
_journal_year                    2020
_chemical_formula_moiety         'C59 H68 Au B N4, C4 H10 O'
_chemical_formula_sum            'C63 H78 Au B N4 O'
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;
2020-07-30 deposited with the CCDC.	2020-11-25 downloaded from the CCDC.
;
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CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
;
_computing_data_collection
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CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
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CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
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_diffrn_ambient_temperature      93(2)
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_diffrn_source                   'micro-focus sealed X-ray tube'
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;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
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_exptl_crystal_description       plate
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_refine_ls_R_factor_all          0.0543
_refine_ls_R_factor_gt           0.0344
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0238P)^2^+6.6398P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                12869
_reflns_number_total             16189
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0sc05478j3.cif
_cod_data_source_block           5
_cod_depositor_comments
;Adding full bibliography for 1559577--1559587.cif.

 Adding full bibliography for 1559577--1559587.cif.
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1559586
_shelx_shelxl_version_number     2018/1
_oxdiff_exptl_absorpt_empirical_full_min 0.917
_oxdiff_exptl_absorpt_empirical_full_max 1.095
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- B-factor correction
;
_shelx_res_checksum              8474