General Approach to Nitrogen-Bridged Bicyclic Frameworks by Rh-Catalyzed Formal Carbenoid Insertion into an Amide C-N Bond.
Harada, Shingo; Kono, Masato; Nozaki, Tomoyuki; Menjo, Yasuhiro; Nemoto, Tetsuhiro; Hamada, Yasumasa; The Journal of organic chemistry 80 (2015) 10317–10333; doi:10.1021/acs.joc.5b01954

data_4031555
_publ_section_title
;
 General Approach to Nitrogen-Bridged Bicyclic Frameworks by Rh-Catalyzed
 Formal Carbenoid Insertion into an Amide C-N Bond.
;
_journal_issue                   20
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              10317
_journal_page_last               10333
_journal_paper_doi               10.1021/acs.joc.5b01954
_journal_volume                  80
_journal_year                    2015
_chemical_formula_moiety         'C16 H23 N O3'
_chemical_formula_sum            'C16 H23 N O3'
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_atom_sites_solution_secondary   difmap
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_cell_angle_gamma                90.0000
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_cell_length_a                   7.0120(2)
_cell_length_b                   9.5343(3)
_cell_length_c                   21.2709(8)
_cell_measurement_reflns_used    3345
_cell_measurement_temperature    93
_cell_measurement_theta_max      68.20
_cell_measurement_theta_min      4.17
_cell_volume                     1419.49(8)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
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_computing_molecular_graphics    'CrystalStructure 4.0'
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_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'Il Milione (Burla, et al., 2007)'
_diffrn_ambient_temperature      93
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54187
_diffrn_reflns_av_R_equivalents  0.0662
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_diffrn_reflns_theta_max         68.20
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_exptl_absorpt_correction_T_max  0.931
_exptl_absorpt_correction_T_min  0.714
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.298
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
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_exptl_crystal_size_mid          0.160
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_refine_ls_shift/su_max          0.000
_refine_ls_structure_factor_coef Fsqd
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'w = 1/[\s^2^(Fo^2^)+(0.0541P)^2^+0.3302P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1191
_reflns_number_gt                2145
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_cod_data_source_block           140806harada02
_cod_depositor_comments
'Adding full bibliography for 4031554--4031556.cif.'
_cod_original_cell_volume        1419.51(8)
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