A Photomagnetic Sponge: High-Temperature Light-Induced Ferrimagnet Controlled by Water Sorption.
Magott, Michał; Reczyński, Mateusz; Gaweł, Bartłomiej; Sieklucka, Barbara; Pinkowicz, Dawid; Journal of the American Chemical Society 140 (2018) 15876–15882; doi:10.1021/jacs.8b09322

data_4133291
_publ_section_title
;
 A Photomagnetic Sponge: High-Temperature Light-Induced Ferrimagnet
 Controlled by Water Sorption.
;
_journal_issue                   46
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              15876
_journal_page_last               15882
_journal_paper_doi               10.1021/jacs.8b09322
_journal_volume                  140
_journal_year                    2018
_chemical_formula_moiety         '{Mn(imidazole)}2, {[W(IV)(CN)8]'
_chemical_formula_sum            'C14 H8 Mn2 N12 W'
_chemical_formula_weight         638.04
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                103.871(3)
_cell_angle_beta                 103.223(3)
_cell_angle_gamma                95.421(4)
_cell_formula_units_Z            2
_cell_length_a                   9.9810(5)
_cell_length_b                   10.8463(5)
_cell_length_c                   9.8571(5)
_cell_measurement_temperature    293
_cell_volume                     995.85(9)
_diffrn_ambient_temperature      293
_diffrn_measurement_device_type  Panalytical
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Co K\a'
_diffrn_radiation_wavelength     1.5418
_exptl_absorpt_coefficient_mu    20.855
_exptl_crystal_density_diffrn    2.128
_exptl_crystal_F_000             600
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.013
_pd_meas_2theta_range_max        49.993
_pd_meas_2theta_range_min        5.010
_pd_meas_number_of_points        3427
_pd_proc_2theta_range_inc        0.013
_pd_proc_2theta_range_max        49.993
_pd_proc_2theta_range_min        5.01
_pd_proc_ls_background_function  '9 Legendre polynoms'
_pd_proc_ls_pref_orient_corr     none
_pd_proc_ls_profile_function     Pseudo-Voigt
_pd_proc_ls_prof_R_factor        0.0322
_pd_proc_ls_prof_wR_expected     0.0225
_pd_proc_ls_prof_wR_factor       0.0412
_refine_ls_goodness_of_fit_all   1.83
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_constraints    0
_refine_ls_number_parameters     71
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0299
_refine_ls_R_factor_gt           0.0296
_refine_ls_shift/su_max          0.019041
_refine_ls_shift/su_mean         0.01384
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0363
_refine_ls_wR_factor_gt          0.0363
_cod_data_source_file            ja8b09322_si_003.cif
_cod_data_source_block           Mn2W
_cod_depositor_comments
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The following automatic conversions were performed:

data item '_diffrn_radiation_probe' value 'X-ray' was changed to
'x-ray' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_formula_sum        'C14 H8 Mn2 N12 W1'
_cod_database_code               4133291