Cooperative N-H bond activation by amido-Ge(ii) cations.
Zhou, Xueer; Vasko, Petra; Hicks, Jamie; Fuentes, M Ángeles; Heilmann, Andreas; Kolychev, Eugene L.; Aldridge, Simon; Dalton transactions (Cambridge, England : 2003) 49 (2020) 9495–9504; doi:10.1039/d0dt01960g

data_7704710
_publ_section_title
;
 Cooperative N-H bond activation by amido-Ge(ii) cations.
;
_journal_issue                   27
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               9504
_journal_paper_doi               10.1039/d0dt01960g
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C18 H26 Ge N3, C16 Al F36 O4'
_chemical_formula_sum            'C34 H26 Al F36 Ge N3 O4'
_chemical_formula_weight         1324.15
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_audit_update_record
;
2019-09-07 deposited with the CCDC.	2020-06-25 downloaded from the CCDC.
;
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43b (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_restrained_S_all      1.123
_refine_ls_R_factor_all          0.1096
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1518P)^2^+17.2616P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                7840
_reflns_number_total             9656
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt01960g2.cif
_cod_data_source_block           099xzjh17_a
_cod_depositor_comments
'Adding full bibliography for 7704706--7704714.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7704710
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              39583
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