Anisotropic Templating Effect in the Formation of Two-Dimensional Anionic Cadmium-Thiocyanate Coordination Solids [(12C4)2Cd][Cd2(SCN)6] and [(12C4)2Cd][Cd3(SCN)8] with Checkerboard and Herringbone Patterns, Respectively
Hong Zhang; Ximin Wang; H. Zhu; W. Xiao; Kecong Zhang; Boon K. Teo; Inorganic Chemistry 38 (1999) 886–892; doi:10.1021/ic980387v

data_4321805
_publ_contact_author
; Prof. Boon K. Teo
 Department of Chemistry
 University of Illinois at Chicago
 Chicago, Il 60607
;
_publ_contact_author_email       ' boonkteo@uic.edu '
_publ_contact_author_fax         ' 312-996-9422* '
_publ_contact_author_phone       ' 312-996-9422 '
_publ_section_title
;
 Anisotropic Templating Effect in the Formation of Two-Dimensional Anionic
 Cadmium-Thiocyanate Coordination Solids [(12C4)2Cd][Cd2(SCN)6] and
 [(12C4)2Cd][Cd3(SCN)8] with Checkerboard and Herringbone Patterns,
 Respectively
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              886
_journal_page_last               892
_journal_paper_doi               10.1021/ic980387v
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C22 H32 Cd3 N6 O8 S6'
_chemical_formula_weight         1038.12
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 90.20(1)
_cell_angle_gamma                90
_cell_formula_units_Z            8.00
_cell_length_a                   16.297(3)
_cell_length_b                   26.267(3)
_cell_length_c                   16.296(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    298
_cell_measurement_theta_max      15.00
_cell_measurement_theta_min      8.00
_cell_volume                     6975.8(17)
_diffrn_ambient_temperature      23.0
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            7288
_diffrn_reflns_theta_max         26
_diffrn_standards_decay_%        0.10
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.2256
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_correction_T_min  0.757
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   psi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.977
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             4080.00
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.130
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.84400
_refine_diff_density_min         -2.24980
_refine_ls_extinction_coef       0.00000
_refine_ls_extinction_method     Zachariasen_type_2_Gaussian_isotropic
_refine_ls_goodness_of_fit_obs   2.970
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     407
_refine_ls_number_reflns         5818
_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0390
_refine_ls_shift/esd_max         0.0040
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0410
_cod_data_source_file            ic980387v_1.cif
_cod_data_source_block           '[(12C4)2Cd][Cd2(SCN)6]'
_cod_original_cell_volume        6975(1)
_cod_original_sg_symbol_H-M      'C 2/c '
_cod_original_formula_sum        'Cd3 S6 N6 O8 C22 H32'
_cod_database_code               4321805