Isocanthine Synthesis via Rh(III)-Catalyzed Intramolecular C─H Functionalization.
Chen, Anthony Y.; Lu, Qianqian; Fu, Yao; Sarpong, Richmond; Stoltz, Brian M.; Zhang, Haiming; The Journal of organic chemistry  (2017) –; doi:10.1021/acs.joc.7b02731

data_4033260
_publ_section_title
;
 Isocanthine Synthesis via Rh(III)-Catalyzed Intramolecular C&#x2500;H
 Functionalization.
;
_journal_name_full               'The Journal of organic chemistry'
_journal_paper_doi               10.1021/acs.joc.7b02731
_journal_year                    2017
_chemical_formula_sum            'C22 H22 N2 O'
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_diffrn_measurement_device_type  'Bruker APEX-I CCD'
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_diffrn_reflns_theta_max         25.352
_diffrn_reflns_theta_min         1.680
_diffrn_source                   'fine focus sealed tube'
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_exptl_absorpt_correction_T_max  0.928
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_exptl_absorpt_process_details   SADABS
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_refine_ls_number_reflns         3049
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0542
_refine_ls_R_factor_gt           0.0399
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0536P)^2^+0.2824P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            jo7b02731_si_003.cif
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_shelx_estimated_absorpt_t_min   0.990
_shelx_estimated_absorpt_t_max   0.997
_shelxl_version_number           2014/6
_shelx_res_checksum              885
_shelx_hkl_checksum              22660