[<i>N</i>,<i>N</i>'-Bis(3-methoxy-2-oxidobenzylidene)cyclohexane-1,2-diaminium-κ^4^<i>O</i>,<i>O</i>',<i>O</i>'',<i>O</i>''']tris(nitrato-κ^2^<i>O</i>,<i>O</i>')europium(III) methanol monosolvate
Yan, Peng-Fei; Bao, Yan; Li, Guang-Ming; Li, Jing-Ya; Chen, Peng; Acta Crystallographica Section E 66 (2010) m1650–; doi:10.1107/S1600536810046076

data_2228318
_publ_section_title
;
 [<i>N</i>,<i>N</i>'-Bis(3-methoxy-2-oxidobenzylidene)cyclohexane-1,2-diaminium-\k^4^<i>O</i>,<i>O</i>',<i>O</i>'',<i>O</i>''']tris(nitrato-\k^2^<i>O</i>,<i>O</i>')europium(III)
 methanol monosolvate
;
_journal_coeditor_code           GK2295
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1650
_journal_paper_doi               10.1107/S1600536810046076
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Eu (N O3)3 (C22 H26 N2 O4)], C H4 O'
_chemical_formula_moiety         'C22 H26 Eu N5 O13, C H4 O'
_chemical_formula_sum            'C23 H30 Eu N5 O14'
_chemical_formula_weight         752.48
_chemical_name_systematic
;
[<i>N</i>,<i>N</i>'-Bis(3-methoxy-2-oxidobenzylidene)cyclohexane-1,2-diaminium-
\k^4^<i>O</i>,<i>O</i>',<i>O</i>'',<i>O</i>''']tris(nitrato-
\k^2^<i>O</i>,<i>O</i>')europium(III) methanol monosolvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                78.7980(10)
_cell_angle_beta                 68.4920(10)
_cell_angle_gamma                81.6710(10)
_cell_formula_units_Z            2
_cell_length_a                   9.7718(4)
_cell_length_b                   12.8560(6)
_cell_length_c                   13.0567(6)
_cell_measurement_reflns_used    21234
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      28.2550
_cell_measurement_theta_min      2.5441
_cell_volume                     1492.09(12)
_computing_cell_refinement       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_collection       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_reduction        'RAPID-AUTO (Rigaku, 1998)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      291(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0109
_diffrn_reflns_av_sigmaI/netI    0.0234
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            8377
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         2.66
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.176
_exptl_absorpt_correction_T_max  0.670
_exptl_absorpt_correction_T_min  0.476
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.675
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             756
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.759
_refine_diff_density_min         -0.721
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     390
_refine_ls_number_reflns         5185
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.0294
_refine_ls_R_factor_gt           0.0250
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0397P)^2^+0.6408P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0650
_refine_ls_wR_factor_ref         0.0675
_reflns_number_gt                4683
_reflns_number_total             5185
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            gk2295.cif
_cod_data_source_block           I
_cod_database_code               2228318
_cod_database_fobs_code          2228318