Photochemistry and photophysics of the tetrahedral silver(I) complex with diphosphine ligands: [Ag(dppb)2]PF6 (dppb = 1, 2-bis[diphenylphosphino]benzene).
Osawa, Masahisa; Hoshino, Mikio; Chemical communications (Cambridge, England)  (2008) 6384–6386; doi:10.1039/b813844c

data_7103593
_publ_section_title
;
 Photochemistry and photophysics of the tetrahedral silver(I) complex
 with diphosphine ligands: [Ag(dppb)2]PF6 (dppb = 1,
 2-bis[diphenylphosphino]benzene).
;
_journal_issue                   47
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              6384
_journal_page_last               6386
_journal_paper_doi               10.1039/b813844c
_journal_year                    2008
_chemical_formula_moiety         'C60 H48 Ag P4, F6 P'
_chemical_formula_sum            'C60 H48 Ag F6 P5'
_chemical_formula_weight         1145.77
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 124.9197(17)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            8
_cell_length_a                   27.151(3)
_cell_length_b                   25.983(3)
_cell_length_c                   18.573(2)
_cell_measurement_reflns_used    16946
_cell_measurement_temperature    130.1
_cell_measurement_theta_max      32.6
_cell_measurement_theta_min      1.2
_cell_volume                     10743(2)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SIR2004
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.056
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       36
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            55504
_diffrn_reflns_theta_full        30.01
_diffrn_reflns_theta_max         30.01
_exptl_absorpt_coefficient_mu    0.583
_exptl_absorpt_correction_T_max  0.976
_exptl_absorpt_correction_T_min  0.878
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
Higashi, T. (1999). Program for Absorption Correction.
Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.417
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             4672.00
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.09
_refine_diff_density_min         -0.93
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.109
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     651
_refine_ls_number_reflns         15648
_refine_ls_R_factor_gt           0.0541
_refine_ls_shift/su_max          0.0010
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0443P)^2^+10.1584P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1194
_reflns_number_gt                12389
_reflns_number_total             15648
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b813844c.txt
_cod_data_source_block           AgT2
_cod_original_formula_sum        'C60 H48 Ag F6 P5 '
_cod_database_code               7103593