Synthesis, structure and magnetic properties of La3Co2SbO9: A double perovskite with competing antiferromagnetic and ferromagnetic interactions
Franco, D.G.; Fuertes, V.C.; Blanco, M.C.; Fernández-Díaz, M.T.; Sánchez, R.D.; Carbonio, R.E.; Journal of Solid State Chemistry 194 (2012) 385–391; doi:10.1016/j.jssc.2012.05.045

data_1562939
_publ_section_title
;
 Synthesis, structure and magnetic properties of La3Co2SbO9: A double
 perovskite with competing antiferromagnetic and ferromagnetic
 interactions
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              385
_journal_page_last               391
_journal_paper_doi               10.1016/j.jssc.2012.05.045
_journal_volume                  194
_journal_year                    2012
_chemical_formula_moiety         (Co2La3O9Sb)0.3333
_chemical_formula_structural     (La3Co2SbO9)0.3333
_chemical_formula_sum            'Co0.6666 La0.9999 O2.9997 Sb0.3333'
_chemical_name_common
'Cobalt Lanthanum Antimony Oxide(0.67/1/0.33/3)'
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00000
_cell_angle_beta                 89.995(3)
_cell_angle_gamma                90.00000
_cell_formula_units_Z            4
_cell_length_a                   5.60457(16)
_cell_length_b                   5.66639(15)
_cell_length_c                   7.9448(2)
_cell_measurement_temperature    300
_cell_volume                     252.308(12)
_computing_structure_refinement  FULLPROF
_diffrn_ambient_temperature      300
_diffrn_measurement_method       'neutron diffraction'
_diffrn_radiation_type           'Constant Wavelength Neutron Diffraction'
_diffrn_radiation_wavelength     1.59400
_diffrn_source                   'nuclear reactor'
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.050016
_pd_meas_2theta_range_max        158.64999
_pd_meas_2theta_range_min        0.10000
_pd_meas_number_of_points        3172
_pd_prep_pressure                101.3
_pd_prep_temperature             1673
_pd_proc_2theta_range_inc        0.050016
_pd_proc_2theta_range_max        158.5260
_pd_proc_2theta_range_min        -0.0240
_pd_proc_ls_pref_orient_corr     ' ?'
_pd_proc_ls_prof_R_factor        3.0134
_pd_proc_ls_prof_wR_expected     2.0913
_pd_proc_ls_prof_wR_factor       4.0339
_pd_proc_wavelength              1.594000
_pd_spec_mounting                ' ?'
_refine_ls_number_parameters     40
_refine_ls_number_reflns         489
_refine_ls_number_restraints     0
_refine_ls_R_I_factor            4.8591
_cod_data_source_file            JSSC-2012-194-385.cif
_cod_data_source_block           La3Co2SbO9-300K
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        (Co2La3O9Sb)0.3333
_cod_database_code               1562939
_chemical_formula_density        7.022
_pd_proc_ls_prof_cr_factor       13.6033
_pd_proc_ls_prof_cwr_factor      12.7623
_pd_proc_ls_prof_cwr_expected    6.6165
_pd_proc_ls_prof_chi2            3.7205
_pd_proc_ls_prof_echi2           3.8016