Utilization of new gold/schiff-base iron(III) complex composite as highly sensitive voltammetric sensor for determination of epinephrine in the presence of ascorbic acid
Gorczyński, Adam; Kubicki, Maciej; Szymkowiak, Klaudia; Łuczak, Teresa; Patroniak, Violetta; RSC Adv.  (2016) –; doi:10.1039/C6RA22028B

data_7226828
_publ_section_title
;
 Utilization of new gold/schiff-base iron(III) complex composite as highly
 sensitive voltammetric sensor for determination of epinephrine in the
 presence of ascorbic acid
;
_journal_name_full               'RSC Adv.'
_journal_paper_doi               10.1039/C6RA22028B
_journal_year                    2016
_chemical_formula_sum            'C32 H38 Cl2 N8 O9.5'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2016-05-29 deposited with the CCDC.
2016-10-19 downloaded from the CCDC.
;
_cell_angle_alpha                90.991(3)
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_computing_cell_refinement       'CrysAlis Pro (Agilent Technologies (2011))'
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_computing_molecular_graphics    'Mercury (MacRae et al., 2009)'
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_computing_structure_refinement  'SHELXL (Sheldrick, 2015)'
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_diffrn_measurement_device_type  'SuperNova, Single source at offset), Atlas'
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.21t (release 14-08-2012 CrysAlis171 .NET)
(compiled Aug 14 2012,18:12:40)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0600P)^2^+7.0900P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2313
_refine_ls_wR_factor_ref         0.2603
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7644
_reflns_number_total             12871
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6ra22028b2.cif
_cod_data_source_block           1
_cod_depositor_comments
;
2017-03-01
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum        'C64 H76 Cl4 N16 O19'
_cod_original_formula_units_Z    2
_cod_original_formula_weight     1515.20
_cod_database_code               7226828
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              65633