Oxidative addition of cyanogen bromide to <i>C</i>,<i>N</i>-chelated and Lappert's stannylenes.
Švec, Petr; Samsonov, Maksim A.; RůŽičková, Zdeňka; Brus, Jiří; RůŽička, Aleš; Dalton transactions (Cambridge, England : 2003) 50 (2021) 5519–5529; doi:10.1039/d1dt00704a

data_7706889
_publ_section_title
;
 Oxidative addition of cyanogen bromide to <i>C</i>,<i>N</i>-chelated and
 Lappert's stannylenes.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5519
_journal_page_last               5529
_journal_paper_doi               10.1039/d1dt00704a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C12 H36 Br2 N2 Si4 Sn'
_chemical_formula_weight         599.30
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2020-07-07 deposited with the CCDC.	2021-03-16 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 109.413(6)
_cell_angle_gamma                90
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'COLLECT (Hooft, 1998) and DENZO (Otwinowski & Minor, 1997)'
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_diffrn_measurement_device_type  'Bruker Nonius KappaCCD area detector'
_diffrn_measurement_method       '\f and \w scans to fill the Ewald sphere'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
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_diffrn_reflns_point_group_measured_fraction_max 0.968
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_diffrn_reflns_theta_max         27.498
_diffrn_reflns_theta_min         2.589
_exptl_absorpt_coefficient_mu    4.433
_exptl_absorpt_correction_T_max  0.7456
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_exptl_absorpt_process_details
;
Gaussian integration (Coppens, 1970)
;
_exptl_crystal_colour            colorless
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0201P)^2^+1.2351P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                2477
_reflns_number_total             2761
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1dt00704a2.cif
_cod_data_source_block           ps160520Sn1
_cod_depositor_comments
'Adding full bibliography for 7706886--7706890.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7706889
_shelx_shelxl_version_number     2017/1
_shelx_estimated_absorpt_t_min   0.398
_shelx_estimated_absorpt_t_max   0.496
_shelx_res_checksum              71375