Simple and easy functionalization of <i>para</i>-hydroxy POCOP-M (M = Ni(II), Pd(II)) pincer complexes: synthesis of multimetallic species.
Serrano-García, Juan S; García-Eleno, Marco Antonio; Arenaza-Corona, Antonino; Rufino-Felipe, Ernesto; Valdés, Hugo; Hernandez-Ortega, Simon; Morales-Morales, David; Dalton transactions (Cambridge, England : 2003) 54 (2025) 694–699; doi:10.1039/d4dt02841d

data_7717501
_publ_section_title
;
 Simple and easy functionalization of <i>para</i>-hydroxy POCOP-M (M =
 Ni(II), Pd(II)) pincer complexes: synthesis of multimetallic species.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              694
_journal_page_last               699
_journal_paper_doi               10.1039/d4dt02841d
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C47 H76 Cl3 N3 Ni0.52 O6 P4 Pd1.48'
_chemical_formula_sum            'C47 H76 Cl3 N3 Ni0.52 O6 P4 Pd1.48'
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_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_audit_update_record
;
2024-08-27 deposited with the CCDC.	2024-11-14 downloaded from the CCDC.
;
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'Bruker Smart Apex CCD diffractometer 01-670-01'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Sheldrick, 2008)'
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_exptl_crystal_description       'platy prism'
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_exptl_crystal_size_max          0.205
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1177P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                5392
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4dt02841d2.cif
_cod_data_source_block           Compound_3-NiPd
_cod_depositor_comments
'Adding full bibliography for 7717499--7717502.cif.'
_cod_database_code               7717501
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