Laser printing of optically resonant hollow crystalline carbon nanostructures from 1D and 2D metal-organic frameworks.
Mingabudinova, Leila R.; Zalogina, Anastasiia S.; Krasilin, Andrei A.; Petrova, Margarita I.; Trofimov, Pavel; Mezenov, Yuri A.; Ubyivovk, Evgeniy V.; Lönnecke, Peter; Nominé, Alexandre; Ghanbaja, Jaafar; Belmonte, Thierry; Milichko, Valentin A.; Nanoscale 11 (2019) 10155–10159; doi:10.1039/c9nr02167a

data_1550891
_publ_section_title
;
 Laser printing of optically resonant hollow crystalline carbon
 nanostructures from 1D and 2D metal-organic frameworks.
;
_journal_issue                   21
_journal_name_full               Nanoscale
_journal_page_first              10155
_journal_page_last               10159
_journal_paper_doi               10.1039/c9nr02167a
_journal_volume                  11
_journal_year                    2019
_chemical_formula_sum            'C32 H44 Cu N10 O10'
_chemical_formula_weight         792.31
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
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_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2019-01-30 deposited with the CCDC.    2019-04-15 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90.224(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_c                   15.7761(4)
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_cell_measurement_temperature    130(2)
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_computing_cell_refinement
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
        (compiled Aug 13 2014,18:06:01)
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
        (compiled Aug 13 2014,18:06:01)
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_computing_data_reduction
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
        (compiled Aug 13 2014,18:06:01)
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_computing_molecular_graphics
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 ORTEP3 for Windows
 L. J. Farrugia, J. Appl. Crystallogr. 1997, 30, 565.
;
_computing_publication_material
;
 WINGX
 L.J. Farrugia,
 J. Appl. Cryst., 2012, 45, 849-854.
;
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution
;
 SHELXT-2014
 Program for Crystal Structure Analysis (Release 2014-4)
 G. M. Sheldrick, Instit\"ut f\"ur Anorganische Chemie der Universit\"at,
 Tammanstrasse 4, D-3400 G\"ottingen, Germany.
 G. M. Sheldrick, Acta. Cryst., 2015, A71, 3 - 8
;
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_diffrn_reflns_theta_full        28.285
_diffrn_reflns_theta_max         30.517
_diffrn_reflns_theta_min         2.267
_diffrn_source                   'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.649
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_exptl_absorpt_correction_T_min  0.81877
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
        (compiled Aug 13 2014,18:06:01)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear intense blue'
_exptl_crystal_density_diffrn    1.401
_exptl_crystal_description       plate
_exptl_crystal_F_000             1660
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.03
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_restrained_S_all      1.155
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_refine_ls_R_factor_gt           0.0632
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_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0381P)^2^+9.8541P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1511
_refine_ls_wR_factor_ref         0.1655
_reflns_Friedel_coverage         0
_reflns_number_gt                7142
_reflns_number_total             10516
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9nr02167a2.cif
_cod_data_source_block           x2501fin
_cod_depositor_comments
'Adding full bibliography for 1550890--1550891.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1550891
_shelx_title                     ' x2501fin in P2(1)/n'
_shelx_refln_list_code           4
_shelx_f_calc_maximum            310.44
_shelx_f_squared_multiplier      1.000