An Isolable Bis-Silylene Oxide ("Disilylenoxane") and Its Metal Coordination
Wenyuan Wang; Shigeyoshi Inoue; Shenglai Yao; Matthias Driess; Journal of the American Chemical Society 132 (2010) 15890–15892; doi:10.1021/ja106458p

data_4103505
_publ_contact_author_address
;Technische Universitaet Berlin
Institute of Chemistry: Metalorganics and Inorganic Materials 
Sekretariat C2  Strasse des 17. Juni 135
10623 Berlin Germany
;
_publ_contact_author_email       matthias.driess@tu-berlin.de
_publ_contact_author_fax         +49(0)30-314-29732
_publ_contact_author_name        'Matthias Driess'
_publ_contact_author_phone       +49(0)30-314-29731
_publ_section_title
;
 An Isolable Bis-Silylene Oxide ("Disilylenoxane") and Its Metal
 Coordination
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              15890
_journal_page_last               15892
_journal_paper_doi               10.1021/ja106458p
_journal_volume                  132
_journal_year                    2010
_chemical_formula_sum            'C30 H46 N4 O Si2'
_chemical_formula_weight         534.89
_chemical_name_systematic
;
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;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
(compiled Jan 12 2007,17:49:11)
;
_computing_data_collection
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CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
(compiled Jan 12 2007,17:49:11)
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_computing_data_reduction
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CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.8 (release 12-01-2007 CrysAlis171 .NET)
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_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
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_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device_type  'Oxford Diffraction Xcalibur S Sapphire'
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_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
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CrysAlisPro, Oxford Diffraction Ltd.,
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empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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_exptl_crystal_colour            yellow
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_exptl_crystal_description       stick
_exptl_crystal_F_000             4640
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.10(11)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0156P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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