Heterobimetallic contacts in statistical co-crystals of homoleptic coordination compounds with ligand-encoded H⋯F bonds: structure, photophysics and mechano-responsive properties.
Theiss, Tobias; Buss, Stefan; Maisuls, Iván; Block, Theresa; Kösters, Jutta; Pöttgen, Rainer; Strassert, Cristian A.; Chemical communications (Cambridge, England) 61 (2025) 1387–1390; doi:10.1039/d4cc03784g

data_7134092
_publ_section_title
;
 Heterobimetallic contacts in statistical co-crystals of homoleptic
 coordination compounds with ligand-encoded H&#x22ef;F bonds: structure,
 photophysics and mechano-responsive properties.
;
_journal_issue                   7
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              1387
_journal_page_last               1390
_journal_paper_doi               10.1039/d4cc03784g
_journal_volume                  61
_journal_year                    2025
_chemical_formula_sum            'C34 H29 F4 N5 O2 Pd0.73 Pt0.27'
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2023-10-25 deposited with the CCDC.	2024-11-26 downloaded from the CCDC.
;
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_diffrn_measurement_method       'rotation method'
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_exptl_absorpt_correction_T_max  0.9943
_exptl_absorpt_correction_T_min  0.9202
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'STOE X-RED'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.706
_exptl_crystal_description       plate
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_refine_ls_R_factor_all          0.1179
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1421P)^2^+18.5850P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2082
_refine_ls_wR_factor_ref         0.2455
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_reflns_number_gt                4394
_reflns_number_total             6931
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4cc03784g2.cif
_cod_data_source_block           SjS3_c2c_a
_cod_depositor_comments
'Adding full bibliography for 7134091--7134093.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7134092
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.607
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_shelx_res_checksum              8732
_shelx_hkl_checksum              69010