Metal-ligand cooperative transformation of alkyl azide to isocyanate occurring at a Co-Si moiety.
So, Jongho; Kim, Seji; Cho, Kyung-Bin; Lee, Yunho; Chemical communications (Cambridge, England) 57 (2021) 3219–3222; doi:10.1039/d0cc08012h

data_7127968
_publ_section_title
;
 Metal-ligand cooperative transformation of alkyl azide to isocyanate
 occurring at a Co-Si moiety.
;
_journal_issue                   26
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3219
_journal_page_last               3222
_journal_paper_doi               10.1039/d0cc08012h
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C35 H57 Co N2 P2 Si'
_chemical_formula_sum            'C35 H57 Co N2 P2 Si'
_chemical_formula_weight         654.78
_chemical_name_systematic        (MeSiP2)Co(CNtBu)2
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2019-09-19 deposited with the CCDC.	2021-02-19 downloaded from the CCDC.
;
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_computing_cell_refinement       'Bruker SMART'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0615P)^2^+1.1553P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                5915
_reflns_number_total             7500
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0cc08012h2.cif
_cod_data_source_block           0849A-1_a
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_crystal_density_meas' value 'not measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7127967--7127973.cif.
;
_cod_original_cell_volume        3654.7(12)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7127968
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              80654
_shelx_hkl_checksum              6895