Structural, Thermodynamic, and Mesomorphic Consequences of Replacing Nitrates with Trifluoroacetate Counteranions in Ternary Lanthanide Complexes with Hexacatenar Tridentate Ligands
Nozary, Homayoun; Torelli, Stéphane; Guénée, Laure; Terazzi, Emmanuel; Bernardinelli, Gérald; Donnio, Bertrand; Guillon, Daniel; Piguet, Claude; Inorganic Chemistry 45 (2006) 2989–3003; doi:10.1021/ic052017u

data_4332005
_publ_contact_author
;
     Dr Gerald Bernardinelli
     Laboratory of X-ray Crystallography
     University of Geneva
     24, quai E. Ansermet
     CH - 1211 Geneva 4
     Switzerland
;
_publ_section_title
;
 Structural, Thermodynamic, and Mesomorphic Consequences of Replacing
 Nitrates with Trifluoroacetate Counteranions in Ternary Lanthanide
 Complexes with Hexacatenar Tridentate Ligands
;
_journal_issue                   7
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2989
_journal_page_last               3003
_journal_paper_doi               10.1021/ic052017u
_journal_volume                  45
_journal_year                    2006
_chemical_formula_moiety
;
 (C37 H29 N5 O4)2 , (C2 F3 O2)6 , Lu2
;
_chemical_formula_sum            'C86 H58 F18 Lu2 N10 O20'
_chemical_formula_weight         2243.4
_space_group_IT_number           2
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_symmetry_space_group_name_Hall  '-P 1'
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_diffrn_measurement_device_type  'Stoe Ipds'
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_exptl_absorpt_coefficient_mu    2.422
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_refine_ls_structure_factor_coef F
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_refine_ls_weighting_scheme      calc
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_reflns_number_gt                6665
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_reflns_threshold_expression     'refl observed if Fo > 3.99 \s(Fo)'
_cod_data_source_file            ic052017usup1.cif
_cod_data_source_block           NOHO
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not_measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        2130.2(4)
_cod_database_code               4332005