Cyaphide group transfer from covalent metal complexes: contrasting pathways to transmetallation.
Yang, Eric S.; Goicoechea, Jose M.; Chemical communications (Cambridge, England) 61 (2025) 725–727; doi:10.1039/d4cc06131d

data_7134036
_publ_section_title
;
 Cyaphide group transfer from covalent metal complexes: contrasting
 pathways to transmetallation.
;
_journal_issue                   4
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              725
_journal_page_last               727
_journal_paper_doi               10.1039/d4cc06131d
_journal_volume                  61
_journal_year                    2025
_chemical_formula_moiety         'C42 H96 Au2 Fe2 P10, 2(C6 H6)'
_chemical_formula_sum            'C54 H108 Au2 Fe2 P10'
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_chemical_name_systematic
;
 [AuFe(dppe)2(CP)]2*2C6H6
;
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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;
2024-11-14 deposited with the CCDC.	2024-12-06 downloaded from the CCDC.
;
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_diffrn_source                   'micro-focus sealed X-ray tube'
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;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0380P)^2^+3.9292P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                6453
_reflns_number_total             6750
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7134035--7134036.cif.'
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_shelx_shelxl_version_number     2018/1
_shelx_estimated_absorpt_t_min   0.182
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_shelx_hkl_checksum              14295