Trialkylphosphonium oxoborates as C(sp<sup>3</sup>)-H oxyanion holes and their application in catalytic chemoselective acetalization.
Leung, Vincent Ming-Yau; Wong, Hong-Chai Fabio; Pook, Chun-Man; Tse, Ying-Lung Steve; Yeung, Ying-Yeung; Chemical science 14 (2023) 12684–12692; doi:10.1039/d3sc03081d

data_1570158
_publ_section_title
;
 Trialkylphosphonium oxoborates as C(sp<sup>3</sup>)-H oxyanion holes and
 their application in catalytic chemoselective acetalization.
;
_journal_issue                   44
_journal_name_full               'Chemical science'
_journal_page_first              12684
_journal_page_last               12692
_journal_paper_doi               10.1039/d3sc03081d
_journal_volume                  14
_journal_year                    2023
_chemical_formula_sum            'C18 H33 B F3 O P'
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_space_group_name_Hall           '-P 2yn'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2022-09-27 deposited with the CCDC.	2023-10-16 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'BRUKER D8VENTURE DIFFRACTOMETER'
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1070P)^2^+0.9096P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_block           vinn142
_cod_depositor_comments          'Adding full bibliography for 1570158.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1570158
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