A bis(thiosemicarbazonato)-copper complex, a new catalyst for electro- and photo-reduction of CO2 to methanol
Jiang, Wen-Xing; Liu, Wei-Xia; Wang, Chun-Li; Zhan, Shu-Zhong; Wu, Song-Ping; New Journal of Chemistry 44 (2020) 2721–2726; doi:10.1039/C9NJ05672F

data_7059247
_publ_section_title
;
 A bis(thiosemicarbazonato)-copper complex, a new catalyst for electro-
 and photo-reduction of CO2 to methanol
;
_journal_issue                   7
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              2721
_journal_page_last               2726
_journal_paper_doi               10.1039/C9NJ05672F
_journal_volume                  44
_journal_year                    2020
_chemical_formula_moiety         'C8 H15 Cu N6 S2'
_chemical_formula_sum            'C8 H15 Cu N6 S2'
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_chemical_name_systematic        CuATSM
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           'C -2yc'
_space_group_name_H-M_alt        'C 1 c 1'
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_audit_update_record
;
2019-12-11 deposited with the CCDC.	2020-01-21 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_radiation_type           MoK\a
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_diffrn_source                   'fine-focus sealed X-ray tube'
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_refine_ls_abs_structure_details
;
 Classical Flack method preferred over Parsons because s.u. lower.
;
_refine_ls_abs_structure_Flack   0.19(8)
_refine_ls_extinction_method     none
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_refine_ls_R_factor_gt           0.0423
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_refine_ls_shift/su_mean         0.010
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0116P)^2^]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9nj05672f2.cif
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_cod_depositor_comments
;Adding full bibliography for 7059247.cif.

 Adding full bibliography for 7059247.cif.
;
_cod_original_sg_symbol_H-M      'C c'
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