Synthesis of a diferrocenylvinylidene complex by migration of a ferrocenyl substituent.
Korb, Marcus; Moggach, Stephen A.; Low, Paul J.; Chemical communications (Cambridge, England) 57 (2021) 4251–4254; doi:10.1039/d1cc00605c

data_7128064
_publ_section_title
;
 Synthesis of a diferrocenylvinylidene complex by migration of a
 ferrocenyl substituent.
;
_journal_issue                   35
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              4251
_journal_page_last               4254
_journal_paper_doi               10.1039/d1cc00605c
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C57 H47 Fe P2 Ru, C32 H12 B F24'
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_audit_update_record
;
2021-01-17 deposited with the CCDC.	2021-03-25 downloaded from the CCDC.
;
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'XtaLAB Synergy, Single source at home/near, HyPix'
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;
CrysAlisPro 1.171.40.75a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange-red
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0814P)^2^+3.8924P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1390
_reflns_Friedel_coverage         0.000
_reflns_number_gt                13824
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cc00605c2.cif
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_cod_depositor_comments
'Adding full bibliography for 7128064--7128069.cif.'
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_shelx_shelxl_version_number     2018/3
_oxdiff_exptl_absorpt_empirical_full_min 0.572
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_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_shelx_res_checksum              96214
_shelx_hkl_checksum              5750