Fixation of atmospheric CO<sub>2</sub> as C1-feedstock by nickel(ii) complexes.
Muthuramalingam, Sethuraman; Velusamy, Marappan; Mayilmurugan, Ramasamy; Dalton transactions (Cambridge, England : 2003) 50 (2021) 7984–7994; doi:10.1039/d0dt03887c

data_7707196
_publ_section_title
;
 Fixation of atmospheric CO<sub>2</sub> as C1-feedstock by nickel(ii)
 complexes.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7984
_journal_page_last               7994
_journal_paper_doi               10.1039/d0dt03887c
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety
'C27 H43 N7 Ni2 O4, 2(C24 H20 B), C2 H3 N [+ solvent]'
_chemical_formula_sum            'C77 H86 B2 N8 Ni2 O4'
_chemical_formula_weight         1326.57
_chemical_name_common
'(mu2-carbonatato)-acetonitrile-aqua-bis[1-methyl-4-(2-pyridin-2-ylmethyl)-1,4-diazepane-N,N',N"]-di-nickel(II) bis(tetraphenylborate) acetonitrile solvate hydrate'
_chemical_name_systematic
'(mu2-carbonatato)-acetonitrile-aqua-bis[1-methyl-4-(2-pyridin-2-ylmethyl)-1,4-diazepane-N,N',N"]-di-nickel(II) bis(tetraphenylborate) acetonitrile solvate hydrate'
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;
2021-04-23 deposited with the CCDC.	2021-04-26 downloaded from the CCDC.
;
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omega____ theta____ kappa____ phi______ frames
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  2 omega  -48.00   45.00   1.0000    1.6200
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omega____ theta____ kappa____ phi______ frames
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omega____ theta____ kappa____ phi______ frames
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  8 omega   57.00   82.00   1.0000    1.6200
omega____ theta____ kappa____ phi______ frames
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  9 omega  -23.00   27.00   1.0000    1.6200
omega____ theta____ kappa____ phi______ frames
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 10 omega   45.00   72.00   1.0000    1.6200
omega____ theta____ kappa____ phi______ frames
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 11 omega   67.00   92.00   1.0000    1.6200
omega____ theta____ kappa____ phi______ frames
    -       22.7184   57.0000  120.0000 25

;
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
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'w=1/[\s^2^(Fo^2^)+(0.0390P)^2^+1.2535P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7707193--7707196.cif.'
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