First Structurally Characterized Silver(I) Derivatives with Nonfluorinated β-Diketones
Augusto Cingolani; Effendy; Fabio Marchetti; Claudio Pettinari; Riccardo Pettinari; Brian W. Skelton; Allan H. White; Inorganic Chemistry 41 (2002) 1151–1161; doi:10.1021/ic0109391

data_4317630
_publ_contact_author_address
;
    Department of Chemistry
    University of Western Australia
    Nedlands
    Western Australia 6907
    Australia
;
_publ_contact_author_email       bws@crystal.uwa.edu.au
_publ_contact_author_fax         (+61)_08_9380_1118
_publ_contact_author_name        'Skelton, B. W.'
_publ_contact_author_phone       (+61)_08-9380_3481
_publ_section_title
;
 First Structurally Characterized Silver(I) Derivatives with
 Nonfluorinated \b-Diketones
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1151
_journal_page_last               1161
_journal_paper_doi               10.1021/ic0109391
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C53 H44 Ag N2 O2.5 P2'
_chemical_formula_weight         918.75
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.00000
_cell_angle_beta                 100.02(3)
_cell_angle_gamma                90.00000
_cell_formula_units_Z            8
_cell_length_a                   16.193(8)
_cell_length_b                   13.859(7)
_cell_length_c                   39.306(7)
_cell_measurement_reflns_used    12
_cell_measurement_temperature    293
_cell_measurement_theta_max      13.8
_cell_measurement_theta_min      12.9
_cell_volume                     8686(6)
_computing_cell_refinement       'Enraf Nonius software'
_computing_data_collection       'Enraf Nonius software'
_computing_data_reduction        xtal
_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  xtal
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_diffrn_measurement_device_type
;
  CAD4 diffractometer
;
_diffrn_measurement_method       '2\q-\w scans'
_diffrn_radiation_detector       'CCD area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .119
_diffrn_reflns_av_sigmaI/netI    .139
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -19
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_diffrn_reflns_limit_k_min       -16
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_diffrn_reflns_limit_l_min       -46
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_diffrn_reflns_theta_min         1.95
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  60
_diffrn_standards_number         12
_exptl_absorpt_coefficient_mu    .584
_exptl_absorpt_correction_T_max  .95
_exptl_absorpt_correction_T_min  .87
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
  XTAL absorb
;
_exptl_crystal_colour            yellow
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_exptl_crystal_description       fragment
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_exptl_crystal_size_mid          .25
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_refine_diff_density_max         .59
_refine_diff_density_min         -.48
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_refine_ls_goodness_of_fit_ref   1.14
_refine_ls_hydrogen_treatment    noref
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_refine_ls_R_factor_gt           .054
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
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_reflns_d_resolution_high        .842
_reflns_d_resolution_low         10.46
_reflns_limit_h_max              19
_reflns_limit_h_min              0
_reflns_limit_k_max              16
_reflns_limit_k_min              0
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_reflns_limit_l_min              -46
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_reflns_threshold_expression     'I    > 3.00 sig(I   )'
_cod_data_source_file            ic0109391_2.cif
_cod_data_source_block           '[Ag(Q1)(Ph3P)2].1/2H2O'
_cod_original_sg_symbol_Hall     -c_2yc
_cod_original_formula_sum        'C53 H44 Ag1 N2 O2.5 P2'
_cod_database_code               4317630