Synthesis of Ketonylplatinum(III) Dinuclear Complexes: Observation of the Competitive Radical vs Electrophilic Displacement in Pt(III)-Promoted C-H Bond Activation of Ketones
Yong-Shou Lin; Hanae Misawa; Jun Yamada; Kazuko Matsumoto; Journal of the American Chemical Society 123 (2001) 569–575; doi:10.1021/ja9943041

data_4115431
_publ_section_title
;
 Synthesis of Ketonylplatinum(III) Dinuclear Complexes: Observation of the
 Competitive Radical vs Electrophilic Displacement in Pt(III)-Promoted C-H
 Bond Activation of Ketones
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              569
_journal_page_last               575
_journal_paper_doi               10.1021/ja9943041
_journal_volume                  123
_journal_year                    2001
_chemical_formula_sum            'C26 H47 N9 O13 Pt2'
_chemical_formula_weight         1083.89
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_symmetry_cell_setting           monoclinic
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_cell_angle_beta                 90.86(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.133(2)
_cell_length_b                   9.684(2)
_cell_length_c                   38.10(1)
_cell_measurement_reflns_used    21
_cell_measurement_temperature    298.2
_cell_measurement_theta_max      12.3
_cell_measurement_theta_min      10.1
_cell_volume                     3738.3(15)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    'DIRDIF94 (PATTY)'
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.067
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_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    7.517
_exptl_absorpt_correction_T_max  0.222
_exptl_absorpt_correction_T_min  0.118
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details   '(Walker & Stuart, 1983)'
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_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_refine_diff_density_max         1.39
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_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.554
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_refine_ls_shift/su_max          0.0360
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00040|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0723
_reflns_number_gt                3390
_reflns_number_total             0
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ja9943041_1.cif
_cod_data_source_block           C26H47N9O13Pt2
_cod_original_cell_volume        3738(1)
_cod_original_formula_sum        'C26 H47 N9 O13 Pt2 '
_cod_database_code               4115431