Regio- and stereospecific assembly of dispiro[indoline-3,3'-pyrrolizine-1',5''-thiazolidines] from simple precursors using a one-pot procedure: synthesis, spectroscopic and structural characterization, and a proposed mechanism of formation
Romo, Pablo; Quiroga, Jairo; Cobo, Justo; Glidewell, Christopher; Acta Crystallographica Section C 76 (2020) –; doi:10.1107/S2053229620009791

data_2022198
_publ_section_title
;
 Regio- and stereospecific assembly of
 dispiro[indoline-3,3'-pyrrolizine-1',5''-thiazolidines] from simple
 precursors using a one-pot procedure: synthesis, spectroscopic and
 structural characterization, and a proposed mechanism of formation
;
_journal_coeditor_code           KY3198
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_journal_name_full               'Acta Crystallographica Section C'
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;
;
_journal_paper_doi               10.1107/S2053229620009791
_journal_volume                  76
_journal_year                    2020
_chemical_formula_iupac          'C30 H26 Cl N3 O2 S2'
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_chemical_formula_sum            'C30 H26 Cl N3 O2 S2'
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_chemical_name_systematic
;
(3<i>RS</i>,1'<i>SR</i>,2'<i>SR</i>,7a'<i>SR</i>)-2'-(4-Chlorophenyl)-1-\
benzyl-5-methyl-2''-sulfanylidene-5',6',7',7a'-tetrahydro-2'<i>H</i>-\
dispiro[indoline-3,3'-pyrrolizine-1',5''-thiazolidine]-2,4''-dione
;
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;
SAINT(Bruker, 2017)
;
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APEX3 (Bruker, 2018)
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SAINT (Bruker, 2017)
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PLATON (Spek, 2020)
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SHELXL2014 (Sheldrick, 2015b) and PLATON (Spek, 2020)
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SHELXL2014 (Sheldrick, 2015b)
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SHELXT2014 (Sheldrick, 2015a)
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'INCOATEC high brilliance microfocus sealed tube'
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;
(SADABS; Bruker, 2016)
;
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;
Flack <i>x</i> determined using 2956 quotients [(I+)-(I-)]/[(I+)+(I-)]
(Parsons <i>et al.</i>,  2013)
;
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'w=1/[\s^2^(Fo^2^)+(0.0258P)^2^+0.6579P] where P=(Fo^2^+2Fc^2^)/3'
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