LMucko/crystallography-open-database huggingface dataset:
EXAFS and XRD investigations of zeunerite and meta-zeunerite
Hennig, C.; Reck, G.; Reich, T.; Robberg, A.; Kraus, W.; Sieler, J.; Zeitschrift fur Kristallographie 218 (2003) 37–45; doi:

data_9011525
_publ_section_title
;
 EXAFS and XRD investigations of zeunerite and meta-zeunerite
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              37
_journal_page_last               45
_journal_volume                  218
_journal_year                    2003
_chemical_compound_source        Synthetic
_chemical_formula_sum            'As2 Cu H12.656 O24 U2'
_chemical_name_mineral           Zeunerite
_space_group_IT_number           139
_symmetry_space_group_name_Hall  '-I 4 2'
_symmetry_space_group_name_H-M   'I 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   7.1751
_cell_length_b                   7.1751
_cell_length_c                   20.8728
_cell_volume                     1074.575
_database_code_amcsd             0011096
_exptl_crystal_density_diffrn    3.357
_cod_original_formula_sum        'Cu U2 As2 O24 H12.656'
_cod_database_code               9011525
EXAFS and XRD investigations of zeunerite and meta-zeunerite Sample: Ordered
Hennig, C.; Reck, G.; Reich, T.; Robberg, A.; Kraus, W.; Sieler, J.; Zeitschrift fur Kristallographie 218 (2003) 37–45; doi:

data_9011526
_publ_section_title
;
 EXAFS and XRD investigations of zeunerite and meta-zeunerite
 Sample: Ordered
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              37
_journal_page_last               45
_journal_volume                  218
_journal_year                    2003
_chemical_compound_source        Synthetic
_chemical_formula_sum            'As Cu0.5 H4 O10 U'
_chemical_name_mineral           Metazeunerite
_space_group_IT_number           130
_symmetry_space_group_name_Hall  '-P 4a 2ac'
_symmetry_space_group_name_H-M   'P 4/n c c :2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.1065
_cell_length_b                   7.1065
_cell_length_c                   17.4195
_cell_volume                     879.726
_database_code_amcsd             0011097
_exptl_crystal_density_diffrn    3.841
_cod_original_sg_symbol_H-M      'P 4/n c c'
_cod_original_formula_sum        'Cu.5 U As O10 H4'
_cod_database_code               9011526
EXAFS and XRD investigations of zeunerite and meta-zeunerite Sample: Disordered
Hennig, C.; Reck, G.; Reich, T.; Robberg, A.; Kraus, W.; Sieler, J.; Zeitschrift fur Kristallographie 218 (2003) 37–45; doi:

data_9011527
_publ_section_title
;
 EXAFS and XRD investigations of zeunerite and meta-zeunerite
 Sample: Disordered
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              37
_journal_page_last               45
_journal_volume                  218
_journal_year                    2003
_chemical_compound_source        Synthetic
_chemical_formula_sum            'As Cu0.5 H8 O10 U'
_chemical_name_mineral           Metazeunerite
_space_group_IT_number           129
_symmetry_space_group_name_Hall  '-P 4a 2a'
_symmetry_space_group_name_H-M   'P 4/n m m :2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   7.1065
_cell_length_b                   7.1065
_cell_length_c                   8.7095
_cell_volume                     439.850
_database_code_amcsd             0011098
_exptl_crystal_density_diffrn    3.872
_cod_original_sg_symbol_H-M      'P 4/n m m'
_cod_original_formula_sum        'Cu.5 U As O10 H8'
_cod_database_code               9011527
Natural and synthetic compounds with krohnkite-type chains. An update
Fleck, M.; Kolitsch, U.; Zeitschrift fur Kristallographie 218 (2003) 553–567; doi:10.1524/zkri.218.8.553.20689

data_9011528
_publ_section_title
;
 Natural and synthetic compounds with krohnkite-type chains. An update
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              553
_journal_page_last               567
_journal_paper_doi               10.1524/zkri.218.8.553.20689
_journal_volume                  218
_journal_year                    2003
_chemical_formula_structural     K2Mg(CrO4)2*2H2O
_chemical_formula_sum            'Cr2 H4 K2 Mg O10'
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                110.38
_cell_angle_beta                 95.24
_cell_angle_gamma                109.86
_cell_formula_units_Z            1
_cell_length_a                   5.674
_cell_length_b                   6.462
_cell_length_c                   7.517
_cell_volume                     236.026
_database_code_amcsd             0011100
_exptl_crystal_density_diffrn    2.607
_cod_original_formula_sum        'K2 Mg Cr2 O10 H4'
_cod_database_code               9011528
_amcsd_formula_title             K2Mg(CrO4)2*2H2O
Natural and synthetic compounds with krohnkite-type chains. An update
Fleck, M.; Kolitsch, U.; Zeitschrift fur Kristallographie 218 (2003) 553–567; doi:10.1524/zkri.218.8.553.20689

data_9011529
_publ_section_title
;
 Natural and synthetic compounds with krohnkite-type chains. An update
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              553
_journal_page_last               567
_journal_paper_doi               10.1524/zkri.218.8.553.20689
_journal_volume                  218
_journal_year                    2003
_chemical_formula_structural     K2Mg(MoO4)2*2H2O
_chemical_formula_sum            'H4 K2 Mg Mo2 O10'
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                111.67
_cell_angle_beta                 96.59
_cell_angle_gamma                108.62
_cell_formula_units_Z            1
_cell_length_a                   5.884
_cell_length_b                   6.491
_cell_length_c                   7.700
_cell_volume                     249.795
_database_code_amcsd             0011101
_exptl_crystal_density_diffrn    3.047
_cod_original_formula_sum        'K2 Mg Mo2 O10 H4'
_cod_database_code               9011529
_amcsd_formula_title             K2Mg(MoO4)2*2H2O
Natural and synthetic compounds with krohnkite-type chains. An update
Fleck, M.; Kolitsch, U.; Zeitschrift fur Kristallographie 218 (2003) 553–567; doi:10.1524/zkri.218.8.553.20689

data_9011530
_publ_section_title
;
 Natural and synthetic compounds with krohnkite-type chains. An update
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              553
_journal_page_last               567
_journal_paper_doi               10.1524/zkri.218.8.553.20689
_journal_volume                  218
_journal_year                    2003
_chemical_formula_structural     K2Mn(SeO4)2*2H2O
_chemical_formula_sum            'H4 K2 Mn O10 Se2'
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                110.31
_cell_angle_beta                 95.69
_cell_angle_gamma                108.35
_cell_formula_units_Z            1
_cell_length_a                   5.674
_cell_length_b                   6.608
_cell_length_c                   7.523
_cell_volume                     244.099
_database_code_amcsd             0011102
_exptl_crystal_density_diffrn    3.096
_cod_original_formula_sum        'K2 Mn Se2 O10 H4'
_cod_database_code               9011530
_amcsd_formula_title             K2Mn(SeO4)2*2H2O
Natural and synthetic compounds with krohnkite-type chains. An update
Fleck, M.; Kolitsch, U.; Zeitschrift fur Kristallographie 218 (2003) 553–567; doi:10.1524/zkri.218.8.553.20689

data_9011531
_publ_section_title
;
 Natural and synthetic compounds with krohnkite-type chains. An update
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              553
_journal_page_last               567
_journal_paper_doi               10.1524/zkri.218.8.553.20689
_journal_volume                  218
_journal_year                    2003
_chemical_compound_source
'"Leithorizont M", Messel oil shale, near Darmstadt, Germany'
_chemical_formula_sum            'Ca2 Fe0.89 H4 Mg0.11 O10 P2'
_chemical_name_mineral           Messelite
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                90.18
_cell_angle_beta                 102.62
_cell_angle_gamma                108.45
_cell_formula_units_Z            1
_cell_length_a                   5.480
_cell_length_b                   5.759
_cell_length_c                   6.569
_cell_volume                     191.320
_database_code_amcsd             0011103
_exptl_crystal_density_diffrn    3.112
_cod_original_formula_sum        'Ca2 (Fe.89 Mg.11) P2 O10 H4'
_cod_database_code               9011531
Natural and synthetic compounds with krohnkite-type chains. An update
Fleck, M.; Kolitsch, U.; Zeitschrift fur Kristallographie 218 (2003) 553–567; doi:10.1524/zkri.218.8.553.20689

data_9011532
_publ_section_title
;
 Natural and synthetic compounds with krohnkite-type chains. An update
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              553
_journal_page_last               567
_journal_paper_doi               10.1524/zkri.218.8.553.20689
_journal_volume                  218
_journal_year                    2003
_chemical_formula_structural     K2Zn(Cr2O7)2*2H2O
_chemical_formula_sum            'Cr4 H4 K2 O16 Zn'
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                88.97
_cell_angle_beta                 80.90
_cell_angle_gamma                64.57
_cell_formula_units_Z            1
_cell_length_a                   6.794
_cell_length_b                   7.735
_cell_length_c                   7.834
_cell_volume                     366.545
_database_code_amcsd             0011104
_exptl_crystal_density_diffrn    2.771
_cod_original_formula_sum        'K2 Zn Cr4 O16 H4'
_cod_database_code               9011532
_amcsd_formula_title             K2Zn(Cr2O7)2*2H2O
The crystal structure of CaSiO3-walstromite, a special isomorph of wollastonite-II
Joswig, W.; Paulus, E. F.; Winkler, B.; Milman, V.; Zeitschrift fur Kristallographie 218 (2003) 811–818; doi:

data_9011533
_publ_section_title
;The crystal structure of CaSiO3-walstromite, a special isomorph of
 wollastonite-II
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              811
_journal_page_last               818
_journal_volume                  218
_journal_year                    2003
_chemical_formula_sum            'Ca O3 Si'
_chemical_name_mineral           Walstromite
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                83.75
_cell_angle_beta                 77.28
_cell_angle_gamma                70.07
_cell_length_a                   6.596
_cell_length_b                   9.223
_cell_length_c                   6.554
_cell_formula_units_Z            6
_cell_volume                     365.385
_database_code_amcsd             0011105
_exptl_crystal_density_diffrn    3.167
_cod_original_formula_sum        'Ca Si O3'
_cod_database_code               9011533
Crystal structure of dicalcium (cobalt,magnesium) diarsenate dihydrate, Ca2(Co0.532Mg0.468)[AsO4]2*2H2O, hydrogen bonding in talmessite Locality: Bou-Azzer, Morocco
Joswig, W.; Paulus, E. F.; Liebscher, B.; Zeitschrift fur Kristallographie 219 (2004) 341–342; doi:

data_9011534
_publ_section_title
;
 Crystal structure of dicalcium (cobalt,magnesium) diarsenate dihydrate,
 Ca2(Co0.532Mg0.468)[AsO4]2*2H2O, hydrogen bonding in talmessite
 Locality: Bou-Azzer, Morocco
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              341
_journal_page_last               342
_journal_volume                  219
_journal_year                    2004
_chemical_formula_sum            'As2 Ca2 Co0.532 H4 Mg0.468 O10'
_chemical_name_mineral           Beta-roselite
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                97.33
_cell_angle_beta                 108.93
_cell_angle_gamma                108.18
_cell_formula_units_Z            1
_cell_length_a                   5.884
_cell_length_b                   6.981
_cell_length_c                   5.564
_cell_volume                     198.627
_exptl_crystal_density_diffrn    3.651
_cod_original_formula_sum        'Ca2 (Co.532 Mg.468) As2 O10 H4'
_cod_database_code               9011534
_cod_duplicate_entry 8100226
Single crystal structure refinement of tetramethylammonium-hectorite Note: isostructural with hectorite Note: anisoU's and H data from ICSD
Seidl, W.; Breu, J.; Zeitschrift fur Kristallographie 220 (2005) 169–176; doi:

data_9011535
_publ_section_title
;
 Single crystal structure refinement of tetramethylammonium-hectorite
 Note: isostructural with hectorite
 Note: anisoU's and H data from ICSD
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              169
_journal_page_last               176
_journal_volume                  220
_journal_year                    2005
_chemical_compound_source        Synthetic
_chemical_formula_structural     C2.8N.7H9Mg2.4Li.6Si4O10F2
_chemical_formula_sum
'C2.784 H9.112 F2 Li0.618 Mg2.382 N0.696 O10 Si4'
_space_group_IT_number           12
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_cell_angle_alpha                90
_cell_angle_beta                 97.69
_cell_angle_gamma                90
_cell_length_a                   5.2735
_cell_length_b                   9.1165
_cell_length_c                   13.561
_cell_formula_units_Z            2
_cell_volume                     646.093
_database_code_amcsd             0011128
_exptl_crystal_density_diffrn    2.184
_cod_original_formula_sum
'(Mg2.382 Li.618) Si4 O10 N.696 C2.784 H9.112 F2'
_cod_database_code               9011535
_amcsd_formula_title             C2.8N.7H9Mg2.4Li.6Si4O10F2
The crystal structure of podlesnoite, BaCa2(CO3)2F2
Zubkova, N. V.; Pushcharovsky, D. Y.; Pekov, I. V.; Rabadanov, M. K.; Zeitschrift fur Kristallographie 222 (2007) 474–476; doi:

data_9011536
_publ_section_title
;
 The crystal structure of podlesnoite, BaCa2(CO3)2F2
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              474
_journal_page_last               476
_journal_volume                  222
_journal_year                    2007
_chemical_compound_source
'Kirovskii mine, Khibiny alkaline massif, Kola Peninsula, Russia'
_chemical_formula_sum            'C2 Ba Ca2 F2 O6'
_chemical_name_mineral           Podlesnoite
_space_group_IT_number           63
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   12.501
_cell_length_b                   5.846
_cell_length_c                   9.443
_cell_formula_units_Z            4
_cell_volume                     690.102
_database_code_amcsd             0011129
_exptl_crystal_density_diffrn    3.614
_cod_original_formula_sum        'Ba Ca2 C2 O6 F2'
_cod_database_code               9011536
Second edition. Interscience Publishers, New York, New York Note: cadmium chloride structure
Wyckoff, R. W. G.; Crystal Structures 1 (1963) 239–444; doi:

data_9011537
_publ_section_title
;
 Second edition. Interscience Publishers, New York, New York
 Note: cadmium chloride structure
;
_journal_name_full               'Crystal Structures'
_journal_page_first              239
_journal_page_last               444
_journal_volume                  1
_journal_year                    1963
_chemical_formula_structural     NiCl2
_chemical_formula_sum            'Cl2 Ni'
_space_group_IT_number           166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   3.543
_cell_length_b                   3.543
_cell_length_c                   17.335
_cell_formula_units_Z            3
_cell_volume                     188.450
_database_code_amcsd             0011811
_exptl_crystal_density_diffrn    3.426
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_original_formula_sum        'Ni Cl2'
_cod_database_code               9011537
_cod_duplicate_entry 9009132
Second edition. Interscience Publishers, New York, New York Note: cadmium chloride structure
Wyckoff, R. W. G.; Crystal Structures 1 (1963) 239–444; doi:

data_9011538
_publ_section_title
;
 Second edition. Interscience Publishers, New York, New York
 Note: cadmium chloride structure
;
_journal_name_full               'Crystal Structures'
_journal_page_first              239
_journal_page_last               444
_journal_volume                  1
_journal_year                    1963
_chemical_formula_structural     NiI2
_chemical_formula_sum            'I2 Ni'
_space_group_IT_number           166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   3.892
_cell_length_b                   3.892
_cell_length_c                   19.634
_cell_formula_units_Z            3
_cell_volume                     257.564
_database_code_amcsd             0011812
_exptl_crystal_density_diffrn    6.044
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_original_formula_sum        'Ni I2'
_cod_database_code               9011538
_cod_duplicate_entry 9009133
Second edition. Interscience Publishers, New York, New York Note: the gamma phase Note: cadmium chloride structure
Wyckoff, R. W. G.; Crystal Structures 1 (1963) 239–444; doi:

data_9011539
_publ_section_title
;
 Second edition. Interscience Publishers, New York, New York
 Note: the gamma phase
 Note: cadmium chloride structure
;
_journal_name_full               'Crystal Structures'
_journal_page_first              239
_journal_page_last               444
_journal_volume                  1
_journal_year                    1963
_chemical_formula_structural     TaS2
_chemical_formula_sum            'S2 Ta'
_space_group_IT_number           166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   3.32
_cell_length_b                   3.32
_cell_length_c                   18.29
_cell_formula_units_Z            3
_cell_volume                     174.590
_exptl_crystal_density_diffrn    6.993
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_original_formula_sum        'Ta S2'
_cod_database_code               9011539
_cod_duplicate_entry 9009134
Second edition. Interscience Publishers, New York, New York Note: cadmium chloride structure
Wyckoff, R. W. G.; Crystal Structures 1 (1963) 239–444; doi:

data_9011540
_publ_section_title
;
 Second edition. Interscience Publishers, New York, New York
 Note: cadmium chloride structure
;
_journal_name_full               'Crystal Structures'
_journal_page_first              239
_journal_page_last               444
_journal_volume                  1
_journal_year                    1963
_chemical_formula_structural     ZnBr2
_chemical_formula_sum            'Br2 Zn'
_space_group_IT_number           166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   3.92
_cell_length_b                   3.92
_cell_length_c                   18.73
_cell_formula_units_Z            3
_cell_volume                     249.253
_database_code_amcsd             0011814
_exptl_crystal_density_diffrn    4.501
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_original_formula_sum        'Zn Br2'
_cod_database_code               9011540
_cod_duplicate_entry 9009135
Second edition. Interscience Publishers, New York, New York Note: cadmium chloride structure
Wyckoff, R. W. G.; Crystal Structures 1 (1963) 239–444; doi:

data_9011541
_publ_section_title
;
 Second edition. Interscience Publishers, New York, New York
 Note: cadmium chloride structure
;
_journal_name_full               'Crystal Structures'
_journal_page_first              239
_journal_page_last               444
_journal_volume                  1
_journal_year                    1963
_chemical_formula_structural     ZnCl2
_chemical_formula_sum            'Cl2 Zn'
_space_group_IT_number           166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   3.774
_cell_length_b                   3.774
_cell_length_c                   17.765
_cell_formula_units_Z            3
_cell_volume                     219.129
_database_code_amcsd             0011815
_exptl_crystal_density_diffrn    3.099
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_original_formula_sum        'Zn Cl2'
_cod_database_code               9011541
_cod_duplicate_entry 9009136
Second edition. Interscience Publishers, New York, New York
Wyckoff, R. W. G.; Crystal Structures 1 (1963) 239–444; doi:

data_9011542
_publ_section_title
;
 Second edition. Interscience Publishers, New York, New York
;
_journal_name_full               'Crystal Structures'
_journal_page_first              239
_journal_page_last               444
_journal_volume                  1
_journal_year                    1963
_chemical_formula_structural     Cd(OH)Cl
_chemical_formula_sum            'Cd Cl H O'
_space_group_IT_number           186
_symmetry_space_group_name_Hall  'P 6c -2c'
_symmetry_space_group_name_H-M   'P 63 m c'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            2
_cell_length_a                   3.66
_cell_length_b                   3.66
_cell_length_c                   10.27
_cell_volume                     119.142
_database_code_amcsd             0011818
_exptl_crystal_density_diffrn    4.596
_cod_duplicate_entry             9009139
_cod_original_formula_sum        'Cd Cl (O H)'
_cod_database_code               9011542
Second edition. Interscience Publishers, New York, New York
Wyckoff, R. W. G.; Crystal Structures 1 (1963) 282–287; doi:

data_9011543
_publ_section_title
;
 Second edition. Interscience Publishers, New York, New York
;
_journal_name_full               'Crystal Structures'
_journal_page_first              282
_journal_page_last               287
_journal_volume                  1
_journal_year                    1963
_chemical_formula_structural     Zn(OH)Cl
_chemical_formula_sum            'Cl H O Zn'
_space_group_IT_number           61
_symmetry_space_group_name_Hall  '-P 2bc 2ac'
_symmetry_space_group_name_H-M   'P c a b'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   5.86
_cell_length_b                   6.58
_cell_length_c                   11.33
_cell_volume                     436.871
_cod_data_source_file            10794.cif
_cod_data_source_block           global
_cod_original_formula_sum        'Zn O Cl H'
_cod_database_code               9011543
_cod_duplicate_entry 9009149