Bis[μ-<i>N</i>-(pyridin-2-ylmethyl)pyridin-3-amine-κ^2^<i>N</i>:<i>N</i>']disilver(I) bis(perchlorate) dimethyl sulfoxide disolvate
Moon, Suk-Hee; Park, Ki-Min; Acta Crystallographica Section E 69 (2013) m575–m576; doi:10.1107/S1600536813026585

data_2238784
_publ_section_title
;
 Bis[\m-<i>N</i>-(pyridin-2-ylmethyl)pyridin-3-amine-\k^2^<i>N</i>:<i>N</i>']disilver(I)
 bis(perchlorate) dimethyl sulfoxide disolvate
;
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m575
_journal_page_last               m576
_journal_paper_doi               10.1107/S1600536813026585
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          '[Ag2 (C11 H11 N3)2] (Cl O4)2, 2C2 H6 O S'
_chemical_formula_moiety         'C22 H22 Ag2 N6 2+, 2(Cl O4 -), 2(C2 H6 O S)'
_chemical_formula_sum            'C26 H34 Ag2 Cl2 N6 O10 S2'
_chemical_formula_weight         941.35
_chemical_name_systematic
;Bis[\m-<i>N</i>-(pyridin-2-ylmethyl)pyridin-3-amine-\k^2^<i>N</i>:<i>N</i>']disilver(I) bis(perchlorate) dimethyl sulfoxide
disolvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXTL
_cell_angle_alpha                90.00
_cell_angle_beta                 95.3280(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   7.3620(3)
_cell_length_b                   11.1227(5)
_cell_length_c                   21.1248(10)
_cell_measurement_reflns_used    7360
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      2.67
_cell_volume                     1722.34(13)
_computing_cell_refinement       '<i>SAINT-Plus</i> (Bruker, 2000)'
_computing_data_collection       '<i>SMART</i> (Bruker, 2000)'
_computing_data_reduction        '<i>SAINT-Plus</i> (Bruker, 2000)'
_computing_molecular_graphics    '<i>DIAMOND</i> (Brandenburg, 2005)'
_computing_publication_material  '<i>SHELXTL</i> (Sheldrick, 2008)'
_computing_structure_refinement  '<i>SHELXL97</i> (Sheldrick, 2008)'
_computing_structure_solution    '<i>SHELXS97</i> (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0490
_diffrn_reflns_av_sigmaI/netI    0.0323
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            9537
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.94
_exptl_absorpt_coefficient_mu    1.475
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.815
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             944
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.610
_refine_diff_density_min         -0.646
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     217
_refine_ls_number_reflns         3367
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.0358
_refine_ls_R_factor_gt           0.0325
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0399P)^2^+3.5438P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0833
_refine_ls_wR_factor_ref         0.0855
_reflns_number_gt                3096
_reflns_number_total             3367
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            sj5353.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2238784