Generating Active "L-Pd(0)" via Neutral or Cationic π-Allylpalladium Complexes Featuring Biaryl/Bipyrazolylphosphines: Synthetic, Mechanistic, and Structure-Activity Studies in Challenging Cross-Coupling Reactions.
DeAngelis, A. J.; Gildner, Peter G.; Chow, Ruishan; Colacot, Thomas J.; The Journal of organic chemistry 80 (2015) 6794–6813; doi:10.1021/acs.joc.5b01005

data_4031114
_publ_section_title
;
 Generating Active &quot;L-Pd(0)&quot; via Neutral or Cationic
 \p-Allylpalladium Complexes Featuring Biaryl/Bipyrazolylphosphines:
 Synthetic, Mechanistic, and Structure-Activity Studies in Challenging
 Cross-Coupling Reactions.
;
_journal_issue                   13
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              6794
_journal_page_last               6813
_journal_paper_doi               10.1021/acs.joc.5b01005
_journal_volume                  80
_journal_year                    2015
_chemical_formula_sum            'C35 H54 F3 O5 P Pd S'
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_chemical_name_systematic
; 
 ? 
;
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_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
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; 
 Refined as an inversion twin. 
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; 
 w=1/[\s^2^(Fo^2^)+(0.0243P)^2^+0.7152P] 
 where P=(Fo^2^+2Fc^2^)/3 
;
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'Adding full bibliography for 4031112--4031118.cif.'
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