Thermodynamics of N-H bond formation in bis(phosphine) molybdenum(ii) diazenides and the influence of the trans ligand.
Bezdek, Máté J; Chirik, Paul J.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 15922–15930; doi:10.1039/c6dt01932c

data_7039748
_publ_section_title
;
 Thermodynamics of N-H bond formation in bis(phosphine) molybdenum(ii)
 diazenides and the influence of the trans ligand.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15922
_journal_page_last               15930
_journal_paper_doi               10.1039/c6dt01932c
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C99 H74 B F30 Mo N3 P4'
_chemical_formula_weight         2106.24
_chemical_name_systematic        '[(dppe)(3,5-(CF3)2C6H3CN)Mo(NNCy)][BArF24]'
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2016-05-15 deposited with the CCDC.
2016-06-29 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_limit_l_min       -24
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0853P)^2^+3.6516P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7039747--7039749.cif.'
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