Structural insights and <i>in vitro</i> and <i>in vivo</i> anticancer evaluation of dithiocarbamate-based metal complexes against murine lymphoma.
Singh, Anupam; Patel, Riya; Daripa, Samrat; Bharty, M. K.; Butcher, R. J.; Hira, Sumit Kumar; Prasad, Lal Bahadur; Dalton transactions (Cambridge, England : 2003) 54 (2025) 9187–9200; doi:10.1039/d5dt00666j

data_7718646
_publ_section_title
;
 Structural insights and <i>in vitro</i> and <i>in vivo</i> anticancer
 evaluation of dithiocarbamate-based metal complexes against murine
 lymphoma.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9187
_journal_page_last               9200
_journal_paper_doi               10.1039/d5dt00666j
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C28 H34 Cl2 Cu N2 S4'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2024-11-05 deposited with the CCDC.	2025-05-06 downloaded from the CCDC.
;
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_computing_data_collection       'CrysAlisPro 1.171.42.90a (Rigaku OD, 2023)'
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_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
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_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix3000'
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_exptl_absorpt_correction_T_min  0.83112
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Brown
_exptl_crystal_density_diffrn    1.457
_exptl_crystal_description       Needle
_exptl_crystal_F_000             343
_exptl_crystal_size_max          0.34
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_exptl_crystal_size_min          0.24
_refine_diff_density_max         0.863
_refine_diff_density_min         -0.382
_refine_diff_density_rms         0.073
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
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_refine_ls_number_reflns         2894
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0521
_refine_ls_R_factor_gt           0.0461
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0941P)^2^+0.2886P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1467
_refine_ls_wR_factor_ref         0.1535
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2482
_reflns_number_total             2894
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7718644--7718650.cif.'
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