Dinuclear Pd(I)-Pd(I) and Pt(II)...Pt(II) Complexes Supported by Tridentate Pyphos Ligands (Pyphos = 6-(Diphenylphosphino)-2-pyridonate)
Kazushi Mashima; Mitsuhiro Tanaka; Kazuhide Tani; Hiroshi Nakano; Akira Nakamura; Inorganic Chemistry 35 (1996) 5244–5248; doi:10.1021/ic951658u

data_4323884
_publ_section_title
;
 Dinuclear Pd(I)-Pd(I) and Pt(II)...Pt(II) Complexes Supported by
 Tridentate Pyphos Ligands (Pyphos = 6-(Diphenylphosphino)-2-pyridonate)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5244
_journal_page_last               5248
_journal_paper_doi               10.1021/ic951658u
_journal_volume                  35
_journal_year                    1996
_chemical_formula_sum            'C71 H58 Cl6 N4 O4 P4 Pd2'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_creation_date             'Sat Jan 13 10:46:08 1996'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 107.65(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4.00
_cell_length_a                   19.794(7)
_cell_length_b                   14.753(7)
_cell_length_c                   25.626(5)
_cell_measurement_reflns_used    18
_cell_measurement_temperature    23.0
_cell_measurement_theta_max      29.96
_cell_measurement_theta_min      29.10
_cell_volume                     7131(5)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_diffrn_ambient_temperature      23.0
_diffrn_measurement_device       AFC5R
_diffrn_measurement_method       'omega scans with profile analysis'
_diffrn_orient_matrix_UB_11      -0.02968
_diffrn_orient_matrix_UB_12      -0.00146
_diffrn_orient_matrix_UB_13      -0.03928
_diffrn_orient_matrix_UB_21      0.04020
_diffrn_orient_matrix_UB_22      -0.02821
_diffrn_orient_matrix_UB_23      -0.01016
_diffrn_orient_matrix_UB_31      -0.01770
_diffrn_orient_matrix_UB_32      -0.06161
_diffrn_orient_matrix_UB_33      0.00558
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_type           MoKalpha
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_diffrn_reflns_limit_h_max       0
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_exptl_absorpt_coefficient_mu_cm 8.609
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.845
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            red
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_exptl_crystal_description       undefined
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_refine_ls_number_restraints     0
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
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_cod_data_source_file            ic951658u_1.cif
_cod_data_source_block           Pd2(pyphos)2(pyphosH)2
_cod_original_cell_volume        7131(4)
_cod_original_sg_symbol_H-M      'C 2/c '
_cod_original_formula_sum        'C71 H58 O4 N4 P4 Pd2 Cl6'
_cod_database_code               4323884