Phosphine control of the oxidative addition chemistry of tetrathiocins to palladium(0): characterization of mono-, di-, and hexanuclear palladium(II) dithiolate complexes.
Wrixon, Justin D.; Hayward, John J.; Rawson, Jeremy M.; Inorganic chemistry 54 (2015) 9384–9386; doi:10.1021/acs.inorgchem.5b01555

data_4346467
_publ_section_title
;
 Phosphine control of the oxidative addition chemistry of tetrathiocins to
 palladium(0): characterization of mono-, di-, and hexanuclear
 palladium(II) dithiolate complexes.
;
_journal_issue                   19
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9384
_journal_page_last               9386
_journal_paper_doi               10.1021/acs.inorgchem.5b01555
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'C33 H30 O2 P2 Pd S2, C H2 Cl2'
_chemical_formula_sum            'C34 H32 Cl2 O2 P2 Pd S2'
_chemical_formula_weight         775.95
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX2 CCD'
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_exptl_absorpt_process_details
;
SADABS 2012/1 Bruker AXS Madison, WI, USA
;
_exptl_crystal_colour            red
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0318P)^2^+30.0980P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           JW017
_cod_original_sg_symbol_H-M      'P 21/c'
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_shelx_estimated_absorpt_t_min   0.833
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