Unsymmetrical α-diimine palladium catalysts and their properties in olefin (co)polymerization
Sui, Xuelin; Hong, Changwen; Pang, Wenmin; Chen, Changle; Materials Chemistry Frontiers 1 (2017) 967–; doi:10.1039/C6QM00235H

data_1553412
_publ_section_title
;
 Unsymmetrical \a-diimine palladium catalysts and their properties in
 olefin (co)polymerization
;
_journal_issue                   5
_journal_name_full               'Materials Chemistry Frontiers'
_journal_page_first              967
_journal_paper_doi               10.1039/C6QM00235H
_journal_volume                  1
_journal_year                    2017
_chemical_formula_sum            'C47 H47 Cl N2 Pd'
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_audit_update_record
;
2016-07-27 deposited with the CCDC.
2016-12-07 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Gemini S Ultra, Agilent Technologies'
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_diffrn_source                   'Enhance Ultra (Cu) X-ray Source'
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_exptl_absorpt_correction_T_min  0.14956
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_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    1.198
_exptl_crystal_description       block
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_platon_squeeze_details
;
;
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_refine_ls_restrained_S_all      1.079
_refine_ls_R_factor_all          0.1046
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0921P)^2^+11.3667P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2273
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_reflns_threshold_expression     'I > 2\s(I)'
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