Reducing CO2 to Methanol Using Frustrated Lewis Pairs: On the Mechanism of Phosphine-Borane-Mediated Hydroboration of CO2.
Courtemanche, Marc-André; Légaré, Marc-André; Maron, Laurent; Fontaine, Frédéric-Georges; Journal of the American Chemical Society 136 (2014) 10708–10717; doi:10.1021/ja5047846

data_4122270
_publ_section_title
;
 Reducing CO2 to Methanol Using Frustrated Lewis Pairs: On the Mechanism
 of Phosphine-Borane-Mediated Hydroboration of CO2.
;
_journal_issue                   30
_journal_name_full               'Journal of the American Chemical Society'
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_journal_page_last               10717
_journal_paper_doi               10.1021/ja5047846
_journal_volume                  136
_journal_year                    2014
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;
 Flack x determined using 1972 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   -0.01(3)
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0526P)^2^+0.3167P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments          'Adding full bibliography for 4122270.cif.'
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