LMucko/crystallography-open-database huggingface dataset:
Thermal and Light-Induced Two-step Spin Transition in a Novel Fe(II) 3D Polymer with Strong Metallophilic Interactions: Diffraction, Magnetic, Calorimetric and Visible Absorption Spectroscopic Studies of {Fe(pmd)[Ag(CN)2][Ag2(CN)3]}.
Niel, Virginie; Thompson, Amber L.; Goeta, Andrés E.; Enachescu, Cristian; Hauser, Andreas; Galet, Ana; Muñoz, M. Carmen; Real, José A; Organometallics  (2004) –; doi:10.1021/om0342053

data_4062561
_publ_section_title
;
Thermal and Light-Induced Two-step Spin Transition in a Novel Fe(II) 3D
Polymer with Strong Metallophilic Interactions: Diffraction, Magnetic,
Calorimetric and Visible Absorption Spectroscopic Studies of
{Fe(pmd)[Ag(CN)2][Ag2(CN)3]}.
;
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om0342053
_journal_year                    2004
_chemical_formula_sum            'C9 H4 Ag3 Fe N7'
_chemical_formula_weight         589.65
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 96.875(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   17.2561(10)
_cell_length_b                   29.5042(18)
_cell_length_c                   11.9308(7)
_cell_measurement_temperature    170(2)
_cell_volume                     6030.6(10)
_diffrn_ambient_temperature      170(2)
_exptl_crystal_density_diffrn    2.597
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062561
Thermal and Light-Induced Two-step Spin Transition in a Novel Fe(II) 3D Polymer with Strong Metallophilic Interactions: Diffraction, Magnetic, Calorimetric and Visible Absorption Spectroscopic Studies of {Fe(pmd)[Ag(CN)2][Ag2(CN)3]}.
Niel, Virginie; Thompson, Amber L.; Goeta, Andrés E.; Enachescu, Cristian; Hauser, Andreas; Galet, Ana; Muñoz, M. Carmen; Real, José A; Organometallics  (2004) –; doi:10.1021/om0342053

data_4062562
_publ_section_title
;
Thermal and Light-Induced Two-step Spin Transition in a Novel Fe(II) 3D
Polymer with Strong Metallophilic Interactions: Diffraction, Magnetic,
Calorimetric and Visible Absorption Spectroscopic Studies of
{Fe(pmd)[Ag(CN)2][Ag2(CN)3]}.
;
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om0342053
_journal_year                    2004
_chemical_formula_sum            'C9 H4 Ag3 Fe N7'
_chemical_formula_weight         589.65
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 97.051(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   17.1761(10)
_cell_length_b                   29.2567(17)
_cell_length_c                   11.5799(7)
_cell_measurement_temperature    90(2)
_cell_volume                     5775.1(10)
_diffrn_ambient_temperature      90(2)
_exptl_crystal_density_diffrn    2.712
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062562
Thermal and Light-Induced Two-step Spin Transition in a Novel Fe(II) 3D Polymer with Strong Metallophilic Interactions: Diffraction, Magnetic, Calorimetric and Visible Absorption Spectroscopic Studies of {Fe(pmd)[Ag(CN)2][Ag2(CN)3]}.
Niel, Virginie; Thompson, Amber L.; Goeta, Andrés E.; Enachescu, Cristian; Hauser, Andreas; Galet, Ana; Muñoz, M. Carmen; Real, José A; Organometallics  (2004) –; doi:10.1021/om0342053

data_4062563
_publ_section_title
;
Thermal and Light-Induced Two-step Spin Transition in a Novel Fe(II) 3D
Polymer with Strong Metallophilic Interactions: Diffraction, Magnetic,
Calorimetric and Visible Absorption Spectroscopic Studies of
{Fe(pmd)[Ag(CN)2][Ag2(CN)3]}.
;
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om0342053
_journal_year                    2004
_chemical_formula_sum            'C9 H4 Ag3 Fe N7'
_chemical_formula_weight         589.65
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 97.015(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   17.214(3)
_cell_length_b                   29.252(5)
_cell_length_c                   11.559(2)
_cell_measurement_temperature    30(2)
_cell_volume                     5777(3)
_diffrn_ambient_temperature      30(2)
_exptl_crystal_density_diffrn    2.712
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062563
Thermal and Light-Induced Two-step Spin Transition in a Novel Fe(II) 3D Polymer with Strong Metallophilic Interactions: Diffraction, Magnetic, Calorimetric and Visible Absorption Spectroscopic Studies of {Fe(pmd)[Ag(CN)2][Ag2(CN)3]}.
Niel, Virginie; Thompson, Amber L.; Goeta, Andrés E.; Enachescu, Cristian; Hauser, Andreas; Galet, Ana; Muñoz, M. Carmen; Real, José A; Organometallics  (2004) –; doi:10.1021/om0342053

data_4062564
_publ_section_title
;
Thermal and Light-Induced Two-step Spin Transition in a Novel Fe(II) 3D
Polymer with Strong Metallophilic Interactions: Diffraction, Magnetic,
Calorimetric and Visible Absorption Spectroscopic Studies of
{Fe(pmd)[Ag(CN)2][Ag2(CN)3]}.
;
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om0342053
_journal_year                    2004
_chemical_formula_sum            'C9 H4 Ag3 Fe N7'
_chemical_formula_weight         589.65
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 97.228(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   17.6506(19)
_cell_length_b                   29.281(3)
_cell_length_c                   12.2184(14)
_cell_measurement_temperature    30(2)
_cell_volume                     6264.7(12)
_diffrn_ambient_temperature      30(2)
_exptl_crystal_density_diffrn    2.501
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062564
Silicon-carbon Unsaturated Compounds. 69. Reactions of Silenes Produced Thermally from Pivaloyl- and Adamantoyltris(trimethylsilyl)silane with Silyl-substituted Butadiynes and Enynes
Naka, Akinobu; Ohnishi, Hidenobu; Miyahara, Ikuko; Hirotsu, Ken; Shiota, Yoshihito; Yoshizawa, Kazunari; Ishikawa, Mitsuo; Organometallics 23 (2004) 4277–4287; doi:10.1021/om034213j

data_4062565
_publ_section_title
;
Silicon-carbon Unsaturated Compounds. 69. Reactions of Silenes Produced 
Thermally from Pivaloyl- and Adamantoyltris(trimethylsilyl)silane with 
Silyl-substituted Butadiynes and Enynes
;
_journal_issue                   18
_journal_name_full               Organometallics
_journal_page_first              4277
_journal_page_last               4287
_journal_paper_doi               10.1021/om034213j
_journal_volume                  23
_journal_year                    2004
_chemical_formula_moiety         'C36 H72 O Si6'
_chemical_formula_sum            'C36 H72 O Si6'
_chemical_formula_weight         689.48
_chemical_melting_point          435.6(5)
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 109.361(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   16.638(8)
_cell_length_b                   10.989(5)
_cell_length_c                   24.76(1)
_cell_measurement_temperature    293.1
_cell_volume                     4270(3)
_exptl_crystal_density_diffrn    1.074
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value '162-163_C' was changed to '435.6(5)'
- it was converted from degrees Celsius(C) to Kelvins(K), the average
value was taken and precision was estimated.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062565
Bistable Photochromic 'Organometallics' Based on Linkage Isomerism: Photochemistry of Dicarbonyl(eta-5-methylcyclopentadienyl)manganese(I) derivatives with a Bifunctional, Non-chelating Ligand
Theodore J. Burkey; Tung T. To; Barnes, Craig E.; Organometallics  (2004) –; doi:10.1021/om0342356

data_4062566
_publ_section_title
;
Bistable Photochromic 'Organometallics' Based on Linkage Isomerism:
Photochemistry of Dicarbonyl(eta-5-methylcyclopentadienyl)manganese(I)
derivatives with a Bifunctional, Non-chelating Ligand
;
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om0342356
_journal_year                    2004
_chemical_formula_moiety         'C15 H13 Mn N2 O2'
_chemical_formula_sum            'C15 H13 Mn N2 O2'
_chemical_formula_weight         308.21
_chemical_melting_point          '[put melting point here]'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 100.850(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.575(4)
_cell_length_b                   7.225(2)
_cell_length_c                   10.537(2)
_cell_measurement_temperature    173(2)
_cell_volume                     1388.8(5)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.474
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062566
; Organometallics  (2004) –; doi:10.1021/om034236y

data_4062567
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om034236y
_journal_year                    2004
_chemical_formula_sum            'C64 H56 F20 I N P2 Pd2'
_chemical_formula_weight         1620.74
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                101.2700(10)
_cell_angle_beta                 99.1020(10)
_cell_angle_gamma                107.689(2)
_cell_formula_units_Z            2
_cell_length_a                   11.9793(9)
_cell_length_b                   13.6815(10)
_cell_length_c                   22.1965(16)
_cell_measurement_temperature    293(2)
_cell_volume                     3305.6(4)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.628
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062567
; Organometallics  (2004) –; doi:10.1021/om034238i

data_4062568
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om034238i
_journal_year                    2004
_chemical_formula_sum            'C46 H64 O2 P4 Pt'
_chemical_formula_weight         967.94
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                90.549(5)
_cell_angle_beta                 109.599(4)
_cell_angle_gamma                106.104(5)
_cell_formula_units_Z            2
_cell_length_a                   11.077(3)
_cell_length_b                   14.132(4)
_cell_length_c                   15.845(5)
_cell_measurement_temperature    173(2)
_cell_volume                     2230.4(11)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.441
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062568
Neutron and X-ray Diffraction Studies and DFT Calculations of Asymmetric Bis(silyl) Niobocene Hydrides
Dorogov, Konstantin Yu.; Dumont, Elise; Ho, Nam-Nhat; Churakov, Andrei V.; Kuzmina, Lyudmila G.; Poblet, Josep-Maria; Schultz, Arthur J.; Howard, Judith A. K.; Bau, Robert; Lledos, Agusti; Nikonov, Georgii I.; Organometallics 23 (2004) 2845–2847; doi:10.1021/om034239a

data_4062572
_publ_contact_author
; Dr Georgii I. Nikonov
  Department of Chemistry, Moscow State University
  Vorob'evy Gory, Moscow 119899, Russia
;
_publ_section_title
'Neutron and X-ray Diffraction Studies and DFT Calculations of Asymmetric Bis(silyl) Niobocene Hydrides'
_journal_issue                   12
_journal_name_full               Organometallics
_journal_page_first              2845
_journal_page_last               2847
_journal_paper_doi               10.1021/om034239a
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C14.01 H23.03 Cl Nb Si2'
_chemical_formula_weight         376.00
_chemical_name_common
;  
(dimethylsilyl)(dimethylchlorosilyl)niobocene hydrid 
;
_chemical_name_systematic
;  
bis(cyclopentadienyl)(dimethylsilyl)
(dimethylchlorosilyl)(hydrido) niobium (V) 
;
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_date             2004-04-16T09:30
_audit_creation_method           'from EXP file using GSAS2CIF'
_audit_update_record
' 2004-04-16T09:30  Initial CIF as created by GSAS2CIF'
_cell_angle_alpha                90.0
_cell_angle_beta                 93.6270(20)
_cell_angle_gamma                90.0
_cell_formula_units_Z            4
_cell_length_a                   13.6876(4)
_cell_length_b                   8.57670(30)
_cell_length_c                   14.5354(4)
_cell_volume                     1702.96(9)
_computing_structure_refinement  GSAS
_pd_block_id
2004-04-16T09:30|NBH100_phase1|Arthur_J._Schultz||
_pd_phase_name                   'NbH 100 K'
_refine_ls_goodness_of_fit_all   1.43
_refine_ls_matrix_type           full
_refine_ls_number_parameters     294
_refine_ls_number_restraints     22
_refine_ls_shift/su_max          0.03
_refine_ls_shift/su_mean         0.00
_cod_data_source_file            om034239asi20040421_035914-EDITED.cif
_cod_data_source_block           NBH100_phase_1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_geom_angle_publ_flag' value 'N' was changed to 'n' in
accordance with the built-in table derived from the CIF Core
dictionary named 'cif_core.dic' version 2.4.5 last updated on
2014-11-21 (93 times).

data item '_geom_bond_publ_flag' value 'N' was changed to 'n' in
accordance with the built-in table derived from the CIF Core
dictionary named 'cif_core.dic' version 2.4.5 last updated on
2014-11-21 (144 times).

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 
;
_cod_original_cell_volume        1702.9574
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062572
; Organometallics  (2004) –; doi:10.1021/om034248j

data_4062573
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om034248j
_journal_year                    2004
_chemical_formula_moiety         '(C24 H20 B)-, (C9 H9 N2)+'
_chemical_formula_sum            'C33 H29 B N2'
_chemical_formula_weight         464.39
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 95.701(19)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.606(6)
_cell_length_b                   8.780(4)
_cell_length_c                   20.378(2)
_cell_measurement_temperature    140(2)
_cell_volume                     2600.4(16)
_diffrn_ambient_temperature      140(2)
_exptl_crystal_density_diffrn    1.186
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062573
; Organometallics  (2004) –; doi:10.1021/om034248j

data_4062574
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om034248j
_journal_year                    2004
_chemical_formula_sum            'C37 H37 B N2'
_chemical_formula_weight         520.50
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 92.631(12)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.7263(16)
_cell_length_b                   17.092(2)
_cell_length_c                   16.239(2)
_cell_measurement_temperature    140(2)
_cell_volume                     2974.1(7)
_diffrn_ambient_temperature      140(2)
_exptl_crystal_density_diffrn    1.162
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062574
; Organometallics  (2004) –; doi:10.1021/om034248j

data_4062575
_journal_name_full               Organometallics
_journal_paper_doi               10.1021/om034248j
_journal_year                    2004
_chemical_formula_moiety
'C25 H17 Co4 N2 O12, C24 H20 B, C H2 Cl2, H2 O'
_chemical_formula_sum            'C50 H41 B Cl2 Co4 N2 O13'
_chemical_formula_weight         1195.28
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 110.76(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   35.331(18)
_cell_length_b                   19.2780(17)
_cell_length_c                   16.489(9)
_cell_measurement_temperature    140(2)
_cell_volume                     10502(8)
_diffrn_ambient_temperature      140(2)
_exptl_crystal_density_diffrn    1.512
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4062575
Cationic Carboxylato Complexes of Dirhodium(II) with Oxo Thioethers: Promising Catalysts with Unusual Coordination Modes
Basato, Marino; Biffis, Andrea; Martinati, Gianluca; Zecca, Marco; Ganis, Paolo; Benetollo, Franco; Aronica, Laura A.; Caporusso, Anna M.; Organometallics 23 (2004) 1947–1952; doi:10.1021/om0342560

data_4062576
_publ_section_title
;
 Cationic Carboxylato Complexes of Dirhodium(II) with Oxo Thioethers:
 Promising Catalysts with Unusual Coordination Modes
;
_journal_coden_ASTM              ORGND7
_journal_issue                   8
_journal_name_full               Organometallics
_journal_page_first              1947
_journal_page_last               1952
_journal_paper_doi               10.1021/om0342560
_journal_volume                  23
_journal_year                    2004
_chemical_formula_moiety         '[Rh~2~(OAc)~4~(MeSCH~2~C(O)OEt)~2~]'
_chemical_formula_sum            'C18 H32 O12 Rh2 S2'
_chemical_formula_weight         710.38
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-I 2ya'
_symmetry_space_group_name_H-M   'I 1 2/a 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 106.32(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.622(3)
_cell_length_b                   8.535(2)
_cell_length_c                   18.667(3)
_cell_measurement_temperature    293(2)
_cell_volume                     2694.5(9)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.751
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' tag value 'monclinic' was replaced with
'monoclinic' value.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_sg_symbol_H-M      'I 2/a'
_cod_database_code               4062576
Cationic Carboxylato Complexes of Dirhodium(II) with Oxo Thioethers: Promising Catalysts with Unusual Coordination Modes
Basato, Marino; Biffis, Andrea; Martinati, Gianluca; Zecca, Marco; Ganis, Paolo; Benetollo, Franco; Aronica, Laura A.; Caporusso, Anna M.; Organometallics 23 (2004) 1947–1952; doi:10.1021/om0342560

data_4062577
_publ_section_title
;
 Cationic Carboxylato Complexes of Dirhodium(II) with Oxo Thioethers:
 Promising Catalysts with Unusual Coordination Modes
;
_journal_coden_ASTM              ORGND7
_journal_issue                   8
_journal_name_full               Organometallics
_journal_page_first              1947
_journal_page_last               1952
_journal_paper_doi               10.1021/om0342560
_journal_volume                  23
_journal_year                    2004
_chemical_formula_moiety
'[Rh~2~(OAc)C3~(MeSCH~2~C(O)OEt)~2~](BF~4~)^.^(0.25H~2~O)'
_chemical_formula_sum            'C16 H29.5 B F4 O10.25 Rh2 S2'
_chemical_formula_weight         742.65
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C 2y'
_symmetry_space_group_name_H-M   'C 1 2 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 93.08(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   30.225(5)
_cell_length_b                   14.103(3)
_cell_length_c                   13.148(3)
_cell_measurement_temperature    293(2)
_cell_volume                     5596(2)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.763
_cod_original_sg_symbol_H-M      'C 2'
_cod_database_code               4062577