Utilization of new gold/schiff-base iron(III) complex composite as highly sensitive voltammetric sensor for determination of epinephrine in the presence of ascorbic acid
Gorczyński, Adam; Kubicki, Maciej; Szymkowiak, Klaudia; Łuczak, Teresa; Patroniak, Violetta; RSC Adv.  (2016) –; doi:10.1039/C6RA22028B

data_7226827
_publ_section_title
;
 Utilization of new gold/schiff-base iron(III) complex composite as highly
 sensitive voltammetric sensor for determination of epinephrine in the
 presence of ascorbic acid
;
_journal_name_full               'RSC Adv.'
_journal_paper_doi               10.1039/C6RA22028B
_journal_year                    2016
_chemical_formula_moiety         'C60 H74 Fe2 N16 O6, 4(Cl O4)'
_chemical_formula_sum            'C60 H74 Cl4 Fe2 N16 O22'
_chemical_formula_weight         1624.85
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2016-02-22 deposited with the CCDC.
2016-10-19 downloaded from the CCDC.
;
_cell_angle_alpha                66.459(15)
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_cell_measurement_reflns_used    426
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_cell_measurement_theta_min      3.3790
_cell_volume                     2077.2(6)
_computing_cell_refinement       'CrysAlis Pro (Agilent Technologies (2011))'
_computing_data_collection       'CrysAlis Pro (Agilent Technologies (2011))'
_computing_data_reduction        'CrysAlis Pro (Agilent Technologies (2011))'
_computing_molecular_graphics    'Mercury (MacRae et al., 2009)'
_computing_publication_material  'SHELXL-2013 (Sheldrick, 2013)'
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_computing_structure_solution    'SIR92 (Altomare et al., 1993)'
_diffrn_ambient_temperature      100(1)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.1544
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device       'four-circle diffractometer'
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_diffrn_measurement_method       \w-scan
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_av_R_equivalents  0.1394
_diffrn_reflns_av_unetI/netI     0.3131
_diffrn_reflns_Laue_measured_fraction_full 0.997
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_diffrn_reflns_limit_l_min       -19
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_diffrn_reflns_theta_max         24.999
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_diffrn_source                   'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.552
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_exptl_absorpt_correction_T_min  0.95696
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.299
_exptl_crystal_description       prism
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_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.06
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_platon_squeeze_details
;
;
_refine_diff_density_max         0.801
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0150P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1547
_refine_ls_wR_factor_ref         0.1833
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2549
_reflns_number_total             7301
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6ra22028b2.cif
_cod_data_source_block           1
_cod_database_code               7226827
_shelxl_version_number           2013-4
_shelx_res_checksum              22024