Taming a silyldiium cation and its reactivity towards sodium phosphaethynolate.
Hermannsdorfer, André; Stephan, Douglas W.; Driess, Matthias; Chemical communications (Cambridge, England) 54 (2018) 13523–13526; doi:10.1039/c8cc07632d

data_7122577
_publ_section_title
;
 Taming a silyldiium cation and its reactivity towards sodium
 phosphaethynolate.
;
_journal_issue                   96
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              13523
_journal_page_last               13526
_journal_paper_doi               10.1039/c8cc07632d
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C46 H53 F3 N5 O3 P S Si'
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
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;
2018-09-07 deposited with the CCDC.
2018-11-09 downloaded from the CCDC.
;
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;
CrysAlisPro 1.171.38.43c (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
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'Re-crystallisation from solvent: Acetonitrile'
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'w=1/[\s^2^(Fo^2^)+(0.0709P)^2^+4.9396P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7122574--7122577.cif.'
_cod_database_code               7122577
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_oxdiff_exptl_absorpt_empirical_full_min 0.744
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;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_shelx_res_checksum              3974
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