Synthesis and reactivity of an osmium(iii) aminoguanidine complex.
Xiang, Jing; Su, Qian-Qian; Luo, Li-Juan; Lau, Tai-Chu; Dalton transactions (Cambridge, England : 2003) 48 (2019) 11404–11410; doi:10.1039/c9dt01711a

data_7700383
_publ_section_title
;
 Synthesis and reactivity of an osmium(iii) aminoguanidine complex.
;
_journal_issue                   30
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11404
_journal_page_last               11410
_journal_paper_doi               10.1039/c9dt01711a
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C42 H38 N8 O3 Os P'
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_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'
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_audit_update_record
;
2019-06-11 deposited with the CCDC.    2019-06-27 downloaded from the CCDC.
;
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_cell_volume                     4002.63(7)
_computing_cell_refinement       'Bruker FRAMBO'
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_diffrn_radiation_type           CuK\a
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_diffrn_reflns_limit_l_min       -24
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_abs_structure_details
;
 Flack x determined using 2952 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.038(6)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0464P)^2^+1.3355P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7700382--7700383.cif.'
_cod_original_cell_volume        4002.62(7)
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_shelx_estimated_absorpt_t_min   0.496
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_shelx_res_checksum              53027