Group IV heteroadamantanes: synthesis of Si<sub>6</sub>Sn<sub>4</sub> and site-selective derivatization of Si<sub>6</sub>Ge<sub>4</sub>.
Köstler, Benedikt; Gilmer, Jannik; Bolte, Michael; Virovets, Alexander; Lerner, Hans-Wolfram; Albert, Philipp; Fantuzzi, Felipe; Wagner, Matthias; Chemical communications (Cambridge, England) 59 (2023) 2295–2298; doi:10.1039/d2cc06697a

data_7131250
_publ_section_title
;
 Group IV heteroadamantanes: synthesis of Si<sub>6</sub>Sn<sub>4</sub> and
 site-selective derivatization of Si<sub>6</sub>Ge<sub>4</sub>.
;
_journal_issue                   16
_journal_name_full               'Chemical communications (Cambridge, England)'
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_journal_paper_doi               10.1039/d2cc06697a
_journal_volume                  59
_journal_year                    2023
_chemical_formula_moiety         'C20 H60 Cl4 Ge4 Si10'
_chemical_formula_sum            'C20 H60 Cl4 Ge4 Si10'
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;
2023-01-10 deposited with the CCDC.	2023-01-30 downloaded from the CCDC.
;
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;
CrysAlisPro 1.171.42.43a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0402P)^2^+14.0828P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 7131246--7131250.cif.'
_cod_original_cell_volume        9445.5(4)
_cod_database_code               7131250
_shelx_shelxl_version_number     2018/3
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