DNA targeting half sandwich Ru(II)-<i>p</i>-cymene-N^N complexes as cancer cell imaging and terminating agents: influence of regioisomers in cytotoxicity.
Mondal, Ashaparna; Sen, Utsav; Roy, Nilmadhab; Muthukumar, Venkatesan; Sahoo, Suban Kumar; Bose, Bipasha; Paira, Priyankar; Dalton transactions (Cambridge, England : 2003) 50 (2021) 979–997; doi:10.1039/d0dt03107k

data_7705925
_publ_section_title
;
 DNA targeting half sandwich Ru(II)-<i>p</i>-cymene-N^N complexes as
 cancer cell imaging and terminating agents: influence of regioisomers in
 cytotoxicity.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              979
_journal_page_last               997
_journal_paper_doi               10.1039/d0dt03107k
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C18 H11 Cl N2 S'
_chemical_formula_sum            'C18 H11 Cl N2 S'
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
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_audit_block_doi                 10.5517/ccdc.csd.cc24v1tw
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-03-18 deposited with the CCDC.	2020-12-07 downloaded from the CCDC.
;
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_cell_measurement_temperature    296(2)
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'ORTEP3 (Farrugia, 1997) and Mercury (Bruno et al., 2002)'
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_diffrn_measurement_device_type  'Bruker axs kappa apex2 Diffractometer'
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_diffrn_radiation_monochromator  graphite
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0422P)^2^+0.4745P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0946
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                2871
_reflns_number_total             5814
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt03107k2.cif
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_cod_depositor_comments          'Adding full bibliography for 7705925.cif.'
_cod_original_cell_volume        1461.5(6)
_cod_original_sg_symbol_H-M      'P 21/c'
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_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.942
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_shelx_res_checksum              38230