Epimerization of glucose over ionic liquid/phosphomolybdate hybrids: structure‒activity relationship
Megías-Sayago, Cristina; Álvarez, Eleuterio; Ivanova, Svetlana; Odriozola, José Antonio; Green Chemistry 20 (2018) 1042–; doi:10.1039/C7GC03738D

data_7230014
_publ_section_title
;
 Epimerization of glucose over ionic liquid/phosphomolybdate hybrids:
 structure--activity relationship
;
_journal_issue                   5
_journal_name_full               'Green Chemistry'
_journal_page_first              1042
_journal_paper_doi               10.1039/C7GC03738D
_journal_volume                  20
_journal_year                    2018
_chemical_formula_moiety         'Mo12 O40 P, 3(C8 H15 N2)'
_chemical_formula_sum            'C24 H45 Mo12 N6 O40 P'
_chemical_formula_weight         2239.91
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2017-12-08 deposited with the CCDC.
2018-01-24 downloaded from the CCDC.
;
_cell_angle_alpha                95.876(2)
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_cell_angle_gamma                101.080(2)
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_cell_measurement_temperature    193(2)
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_cell_volume                     5553.7(4)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_measurement_device_type
;
 Bruker-Nonius X8kappa APEX II CCD area detector
;
_diffrn_measurement_method       'phi and omega scans with narrow frames'
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;
program SADABS, Bruker (2001).
;
_exptl_crystal_colour            green
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+118.7740P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1109
_refine_ls_wR_factor_ref         0.1156
_reflns_Friedel_coverage         0.000
_reflns_number_gt                17233
_reflns_number_total             20090
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           C4mimPMo
_cod_depositor_comments
'Adding full bibliography for 7230013--7230015.cif.'
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_shelx_res_checksum              93015