[{(PhSn)<sub>3</sub>SnS<sub>6</sub>}{(MCp)<sub>3</sub>S<sub>4</sub>}] (M = W, Mo): Minimal Molecular Models of the Covalent Attachment of Metal Chalcogenide Clusters on Doped Transition Metal Dichalcogenide Layers.
Dornsiepen, Eike; Pieck, Fabian; Tonner, Ralf; Dehnen, Stefanie; Journal of the American Chemical Society 141 (2019) 16494–16500; doi:10.1021/jacs.9b09209

data_4127655
_publ_section_title
;
 [{(PhSn)<sub>3</sub>SnS<sub>6</sub>}{(MCp)<sub>3</sub>S<sub>4</sub>}] (M
 = W, Mo): Minimal Molecular Models of the Covalent Attachment of Metal
 Chalcogenide Clusters on Doped Transition Metal Dichalcogenide Layers.
;
_journal_issue                   41
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              16494
_journal_page_last               16500
_journal_paper_doi               10.1021/jacs.9b09209
_journal_volume                  141
_journal_year                    2019
_chemical_formula_sum            'C33 H30 Cl Mo3 S9 Sn4'
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_space_group_name_Hall           '-P 3 2"c'
_space_group_name_H-M_alt        'P -3 c 1'
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_exptl_absorpt_correction_T_min  0.0013
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_exptl_crystal_colour            red
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_exptl_crystal_size_rad          0.06
_refine_diff_density_max         1.206
_refine_diff_density_min         -0.804
_refine_diff_density_rms         0.155
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0776P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                2575
_reflns_number_total             2963
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja9b09209_si_003.cif
_cod_data_source_block           ed077x
_cod_original_cell_volume        4669.27(9)
_cod_database_code               4127655
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