Harnessing phosphorus-centered radicals for the synthesis of cyclopenta[b]indole and pyrrolo[1,2-a]indole frameworks
Ghosh, Palash; Das, Pralay; Mainkar, Prathama S.; Madhavachary, Rudrakshula; Chandrasekhar, Srivari; Chemical Communications 61 (2025) 7807–7810; doi:10.1039/D5CC00906E

data_7134383
_publ_section_title
;
 Harnessing phosphorus-centered radicals for the synthesis of
 cyclopenta[b]indole and pyrrolo[1,2-a]indole frameworks
;
_journal_issue                   43
_journal_name_full               'Chemical Communications'
_journal_page_first              7807
_journal_page_last               7810
_journal_paper_doi               10.1039/D5CC00906E
_journal_volume                  61
_journal_year                    2025
_chemical_formula_moiety         'C27 H26 N O3 P'
_chemical_formula_sum            'C27 H26 N O3 P'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2025-02-10 deposited with the CCDC.	2025-03-25 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker D8 QUEST PHOTON-100'
_diffrn_measurement_method       '\w and \f'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0426P)^2^+0.7343P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                4068
_reflns_number_total             5732
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           KB1471_0m
_cod_depositor_comments          'Adding full bibliography for 7134383.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
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