Highly Regio- and Enantioselective Pd-Catalyzed Allylic Alkylation and Amination of Monosubstituted Allylic Acetates with Novel Ferrocene P,N-Ligands
Shu-Li You; Xia-Zhen Zhu; Yu-Mei Luo; Xue-Long Hou; Li-Xin Dai; Journal of the American Chemical Society 123 (2001) 7471–7472; doi:10.1021/ja016121w

data_4115635
_publ_section_title
;
 Highly Regio- and Enantioselective Pd-Catalyzed Allylic Alkylation and
 Amination of Monosubstituted Allylic Acetates with Novel Ferrocene
 P,N-Ligands
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              7471
_journal_page_last               7472
_journal_paper_doi               10.1021/ja016121w
_journal_volume                  123
_journal_year                    2001
_chemical_formula_sum            'C41 H43 Fe N2 O3 P'
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      4
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_audit_creation_date             'Thu Nov 10 15:53:37 2000'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 103.18(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2.00
_cell_length_a                   11.146(3)
_cell_length_b                   14.417(2)
_cell_length_c                   11.537(3)
_cell_measurement_reflns_used    21
_cell_measurement_temperature    20.0
_cell_measurement_theta_max      21.65
_cell_measurement_theta_min      14.59
_cell_volume                     1805.1(7)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
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_diffrn_measurement_device       AFC7R
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_exptl_absorpt_coefficient_mu_cm 5.020
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.812
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   psi-scan
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_refine_ls_number_restraints     0
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_refine_ls_shift/esd_max         0.0300
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
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_cod_data_source_block           master_file_afc7*.xtl
_cod_original_sg_symbol_H-M      'P 21 '
_cod_original_formula_sum        'C41 H43 O3 N2 P Fe'
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