Crystal Structures and Vibrational and Solution and Solid-State (CPMAS) NMR Spectroscopic Studies in Triphenyl Phosphine, Arsine, and Stibine Silver(I) Bromate Systems, (R3E)xAgBrO3 (E = P, As, Sb;x= 1-4)
Augusto Cingolani; Effendy; John V. Hanna; Maura Pellei; Claudio Pettinari; Carlo Santini; Brian W. Skelton; Allan H. White; Inorganic Chemistry 42 (2003) 4938–4948; doi:10.1021/ic034243e

data_4313955
_publ_contact_author_address
;
   Department of Chemistry
   University of Western Australia
   35 Stirling Highway
   Crawley
   Western Australia 6009
   Australia
;
_publ_contact_author_email       bws@crystal.uwa.edu.au
_publ_contact_author_fax         (+61)_08_9380_1118
_publ_contact_author_name        'Skelton, B. W.'
_publ_contact_author_phone       (+61)_08-9380_3481
_publ_section_title
;
 Crystal Structures and Vibrational and Solution and Solid-State (CPMAS)
 NMR Spectroscopic Studies in Triphenyl Phosphine, Arsine, and Stibine
 Silver(I) Bromate Systems, (R3E)xAgBrO3 (E = P, As, Sb;x= 1-4)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4938
_journal_page_last               4948
_journal_paper_doi               10.1021/ic034243e
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C72 H62 Ag2 As2 Br2 O7 P2'
_chemical_formula_weight         1626.62
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
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_audit_creation_date             03-02-28
_audit_creation_method           Xtal3.6
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_cell_length_c                   13.3979(9)
_cell_measurement_reflns_used    8353
_cell_measurement_temperature    150
_cell_measurement_theta_max      33.65
_cell_measurement_theta_min      2.21
_cell_volume                     1607.46(18)
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_computing_data_reduction        'xtal ADDREF SORTRF'
_computing_molecular_graphics    xtal
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_diffrn_measurement_device_type
;
Bruker SMART CCD diffractometer
;
_diffrn_measurement_method       '\w scans'
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_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_limit_h_min       -16
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_diffrn_reflns_limit_l_max       21
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_diffrn_reflns_theta_max         34.65
_diffrn_reflns_theta_min         1.76
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    2.978
_exptl_absorpt_correction_T_max  1
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS; Sheldrick, 1996
;
_exptl_crystal_colour            of-white
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_exptl_crystal_description       prism
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_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .08
_refine_ls_R_factor_gt           .045
_refine_ls_shift/su_max          .045
_refine_ls_shift/su_mean         .001
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         .078
_refine_ls_wR_factor_ref         .069
_reflns_d_resolution_high        .625
_reflns_d_resolution_low         11.525
_reflns_Friedel_coverage         0
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_reflns_limit_k_max              20
_reflns_limit_k_min              -17
_reflns_limit_l_max              21
_reflns_limit_l_min              -18
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_reflns_threshold_expression     'F    > 4.00 sig(F   )'
_cod_data_source_file            ic034243esi20030306_065015.cif
_cod_data_source_block           cppas
_cod_original_sg_symbol_Hall     -p_1
_cod_database_code               4313955