Synthesis of homometallic divalent lanthanide organoimides from benzyl complexes.
Wolf, Benjamin M.; Stuhl, Christoph; Anwander, Reiner; Chemical communications (Cambridge, England) 54 (2018) 8826–8829; doi:10.1039/c8cc05234d

data_7121961
_publ_section_title
;
 Synthesis of homometallic divalent lanthanide organoimides from benzyl
 complexes.
;
_journal_issue                   64
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              8826
_journal_page_last               8829
_journal_paper_doi               10.1039/c8cc05234d
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C64 H100 Eu4 N4 O4'
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_chemical_properties_physical    Air-sensitive,Moisture-sensitive
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_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_symmetry_space_group_name_Hall  'P 2yb'
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_audit_update_record
;
2018-06-28 deposited with the CCDC.
2018-07-12 downloaded from the CCDC.
;
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_computing_structure_solution
'XT, VERSION 2014/5,SHELXS-13 (Sheldrick 2008)'
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_diffrn_radiation_monochromator  triumph
_diffrn_radiation_source         'fine-focus sealed tube'
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_exptl_crystal_colour            orange
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.034(10)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0218P)^2^+2.8372P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                16082
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_cod_data_source_file            c8cc05234d2.cif
_cod_data_source_block           2-Eu_bw429_0mp21_sqCili
_cod_depositor_comments
'Adding full bibliography for 7121956--7121961.cif.'
_cod_original_cell_volume        3697.61(10)
_cod_database_code               7121961
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.379
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_shelx_res_checksum              62749
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