Silylation of N-heterocyclic carbene with aminochlorosilane and -disilane: dehydrohalogenation vs. Si-Si bond cleavage.
Cui, Haiyan; Cui, Chunming; Dalton transactions (Cambridge, England : 2003) 40 (2011) 11937–11940; doi:10.1039/c1dt11592h

data_7017463
_publ_section_title
;
 Silylation of N-heterocyclic carbene with aminochlorosilane and
 -disilane: dehydrohalogenation vs. Si-Si bond cleavage.
;
_journal_issue                   44
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11937
_journal_page_last               11940
_journal_paper_doi               10.1039/c1dt11592h
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C26 H46 Cl N3 Si2'
_chemical_formula_sum            'C26 H46 Cl N3 Si2'
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_cell_length_a                   10.3126(17)
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_diffrn_ambient_temperature      113(2)
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_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Rigaku Saturn 724CCD camera'
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_diffrn_reflns_theta_min         1.74
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
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_exptl_absorpt_process_details   Crystalclear
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.145
_exptl_crystal_density_method    'not measured'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0485P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        2856.4(8)
_cod_original_sg_symbol_H-M      P2(1)/n
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