Reactivity patterns for the activation of CO<sub>2</sub> and CS<sub>2</sub> with alumoxane and aluminum hydrides.
González-Gallardo, Sandra; Jancik, Vojtech; Díaz-Gómez, Dalia G; Cortés-Guzmán, Fernando; Hernández-Balderas, Uvaldo; Moya-Cabrera, Mónica; Dalton transactions (Cambridge, England : 2003) 48 (2019) 5595–5603; doi:10.1039/c9dt00515c

data_7049596
_publ_section_title
;
 Reactivity patterns for the activation of CO<sub>2</sub> and
 CS<sub>2</sub> with alumoxane and aluminum hydrides.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5595
_journal_page_last               5603
_journal_paper_doi               10.1039/c9dt00515c
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C46 H58 Al2 N4 O S'
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_chemical_properties_physical    ', Moisture-sensitive'
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_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_audit_update_record
;
2017-03-07 deposited with the CCDC.    2019-03-22 downloaded from the CCDC.
;
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_cell_measurement_theta_max      25.37
_cell_measurement_theta_min      2.21
_cell_volume                     1049.1(3)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      173(2)
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker Smart Apex CCD diffractometer'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0323
_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_limit_l_min       -16
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_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.250
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_exptl_crystal_colour            colourless
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_exptl_crystal_description       prism
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_exptl_crystal_size_max          0.334
_exptl_crystal_size_mid          0.226
_exptl_crystal_size_min          0.194
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.134
_refine_ls_R_factor_all          0.0568
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0383P)^2^+0.7843P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1179
_refine_ls_wR_factor_ref         0.1208
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3415
_reflns_number_total             3787
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt00515c2.cif
_cod_data_source_block           6
_cod_depositor_comments
'Adding full bibliography for 7049595--7049598.cif.'
_cod_database_code               7049596
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.949
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