Highly enantioselective reaction of lithiated N-Boc-thiazolidine: a new chiral formyl anion equivalent
Wang, Libo; Nakamura, Shuichi; Toru, Takeshi; Organic & Biomolecular Chemistry 2 (2004) 2168–2169; doi:10.1039/b408509d

data_7153531
_publ_section_title
;
 Highly enantioselective reaction of lithiated N-Boc-thiazolidine: a new
 chiral formyl anion equivalent
;
_journal_issue                   15
_journal_name_full               'Organic &amp;  Biomolecular Chemistry'
_journal_page_first              2168
_journal_page_last               2169
_journal_paper_doi               10.1039/b408509d
_journal_volume                  2
_journal_year                    2004
_chemical_formula_moiety         'C17 H23 N O4 S '
_chemical_formula_sum            'C17 H23 N O4 S'
_chemical_formula_weight         337.43
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_audit_creation_date             2004-06-16
_audit_creation_method           'by CrystalStructure 3.6.0'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.23(1)
_cell_length_b                   9.09(2)
_cell_length_c                   22.57(4)
_cell_measurement_reflns_used    23425
_cell_measurement_temperature    82.0
_cell_measurement_theta_max      68.1
_cell_measurement_theta_min      5.2
_cell_volume                     1688(5)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.6.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    DirectMethod
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9537
_diffrn_measured_fraction_theta_max 0.9537
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.5419
_diffrn_reflns_av_R_equivalents  0.058
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            31284
_diffrn_reflns_theta_full        68.19
_diffrn_reflns_theta_max         68.19
_exptl_absorpt_coefficient_mu    1.871
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.326
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             720.00
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.56
_refine_diff_density_min         -0.69
_refine_ls_abs_structure_details
'Flack, H. D. (1983), Acta Cryst. A39, 876-881.  1155 Friedel Pairs'
_refine_ls_abs_structure_Flack   0.24(5)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   4.581
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     232
_refine_ls_number_reflns         2394
_refine_ls_R_factor_gt           0.0660
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1.0'
_refine_ls_weighting_scheme      unit
_refine_ls_wR_factor_ref         0.0680
_reflns_number_gt                2394
_reflns_number_total             2887
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b408509dsup1.cif
_cod_data_source_block           compound_1
_cod_original_cell_volume        1689(4)
_cod_original_formula_sum        'C17 H23 N O4 S '
_cod_database_code               7153531