Reversible α-elimination in the conversion of N‒CH3 to N‒CHIr by double C‒H activation
Lee, Dong-Heon; Chen, Junyi; Faller, Jack W.; Crabtree, Robert H.; Chemical Communications  (2001) 213–; doi:10.1039/b007679l

data_7111144
_publ_contact_author
;
        ' Jack Faller
   Department of Chemistry, Yale University, 
   225 Prospect St, New Haven, CT 06520-8107 U.S.A. '
;
_publ_section_title
;
 Reversible \a-elimination in the conversion of N--CH3 to N--CH&#xE006;Ir
 by double C--H activation
;
_journal_issue                   2
_journal_name_full               'Chemical Communications'
_journal_page_first              213
_journal_paper_doi               10.1039/b007679l
_journal_year                    2001
_chemical_formula_sum            'C49 H52 B F4 Ir N2 O2 P2'
_chemical_formula_weight         1041.93
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             'Mon Sep 12 17:03:43 2000'
_audit_creation_method           'from TEXRAY.INF file'
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_cell_length_c                   22.8912(7)
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_cell_measurement_temperature    183.2
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_diffrn_measurement_device       KappaCCD
_diffrn_orient_matrix_UB_11      0.00000
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_diffrn_orient_matrix_UB_33      0.00000
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  7.01
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_diffrn_standards_decay_%        0.00
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_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.000
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.486
_exptl_crystal_description       plate
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_exptl_crystal_size_max          0.024
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_refine_ls_structure_factor_coef F
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_cod_data_source_file            b007679lsup1.cif
_cod_data_source_block           2059_Ir(pyNMeCH2)P2Hacetone_6_ChemComm
_cod_original_sg_symbol_H-M      'P 21/n     '
_cod_original_formula_sum        'C49 H52 B F4 Ir N2 O2 P2 '
_cod_database_code               7111144