Rhodium-catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines
Nakao, Yoshiaki; Takeda, Masahide; Chen, Jinshui; Hiyama, Tamejiro; Ichikawa, Yoshitaka; Shintani, Ryo; Hayashi, Tamio; Chemistry Letters 37 (2008) 290–; doi:10.1246/cl.2008.290

data_8000183
_publ_section_title
;
 Rhodium-catalyzed Addition of
 Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines
;
_journal_issue                   3
_journal_name_full               'Chemistry Letters'
_journal_page_first              290
_journal_paper_doi               10.1246/cl.2008.290
_journal_volume                  37
_journal_year                    2008
_chemical_absolute_configuration 'CHOOSE rm ad rmad syn or unk'
_chemical_formula_moiety         'C16 H16 N2 O4 S '
_chemical_formula_sum            'C16 H16 N2 O4 S'
_chemical_formula_weight         332.37
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   6.882(6)
_cell_length_b                   10.123(6)
_cell_length_c                   22.22(3)
_cell_measurement_reflns_used    1705
_cell_measurement_temperature    123.1
_cell_measurement_theta_max      26.4
_cell_measurement_theta_min      3.1
_cell_volume                     1548(3)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 5.00
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.048
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            14586
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_exptl_absorpt_coefficient_mu    0.231
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.426
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             696.00
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.32
_refine_diff_density_min         -2.19
_refine_ls_abs_structure_details
'Flack, H. D. (1983), Acta Cryst. A39, 876-881.  1472 Friedel Pairs'
_refine_ls_abs_structure_Flack   0.01(5)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     228
_refine_ls_number_reflns         11866
_refine_ls_R_factor_gt           0.0435
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details
;
    Chebychev polynomial with 3 parameters (Carruthers & Watkin, 1979)
    46.0713    60.6799    19.8729
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0486
_reflns_number_gt                11819
_reflns_number_total             3513
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            37-290sup1.cif
_cod_data_source_block           '_71018yuki'
_cod_original_cell_volume        1548(2)
_cod_original_formula_sum        'C16 H16 N2 O4 S '
_cod_database_code               8000183