Solvent-free copper-catalyzed trisilylation of alkynes: a practical and atom-economical approach for accessing 1,1,1-trisilylalkanes
Li, Jia; Ge, Shaozhong; Green Chemistry 26 (2024) 6032–6038; doi:10.1039/D4GC00220B

data_7248495
_publ_section_title
;
 Solvent-free copper-catalyzed trisilylation of alkynes: a practical and
 atom-economical approach for accessing 1,1,1-trisilylalkanes
;
_journal_issue                   10
_journal_name_full               'Green Chemistry'
_journal_page_first              6032
_journal_page_last               6038
_journal_paper_doi               10.1039/D4GC00220B
_journal_volume                  26
_journal_year                    2024
_chemical_formula_sum            'C30 H32 Fe Si3'
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_atom_sites_solution_primary     'Dual Space'
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_audit_update_record
;
2023-01-11 deposited with the CCDC.	2024-03-21 downloaded from the CCDC.
;
_cell_angle_alpha                105.8200(10)
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_diffrn_ambient_temperature      100(2)
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_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_point_group_measured_fraction_full 0.997
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_diffrn_source                   'Microfocus Sealed Tube'
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_exptl_crystal_colour            Gold
_exptl_crystal_density_diffrn    1.319
_exptl_crystal_density_meas      ?
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_exptl_crystal_description       Block
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_refine_ls_number_reflns         8199
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0286P)^2^+0.5733P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0704
_refine_ls_wR_factor_ref         0.0744
_reflns_Friedel_coverage         0.000
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4gc00220b2.cif
_cod_data_source_block           L166
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_exptl_crystal_density_meas' value 'Not Measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 

 Adding full bibliography for 7248495.cif.
;
_cod_original_cell_volume        1340.96(7)
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_shelx_shelxl_version_number     2018/3
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_shelx_res_checksum              11239
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