Hydrosilylative reduction of carbon dioxide by a homoleptic lanthanum aryloxide catalyst with high activity and selectivity.
Chang, Kejian; Del Rosal, Iker; Zheng, Xizhou; Maron, Laurent; Xu, Xin; Dalton transactions (Cambridge, England : 2003) 50 (2021) 7804–7809; doi:10.1039/d1dt01074c

data_7707360
_publ_section_title
;
 Hydrosilylative reduction of carbon dioxide by a homoleptic lanthanum
 aryloxide catalyst with high activity and selectivity.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7804
_journal_page_last               7809
_journal_paper_doi               10.1039/d1dt01074c
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C86 H126 La2 O10'
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_audit_creation_method           SHELXL-2013
_audit_update_record
;
2020-07-28 deposited with the CCDC.	2021-05-03 downloaded from the CCDC.
;
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_cell_volume                     2002.6(4)
_computing_cell_refinement       'Bruker SAINT'
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      120(2)
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_diffrn_reflns_av_R_equivalents  0.0559
_diffrn_reflns_av_unetI/netI     0.0346
_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_diffrn_reflns_theta_max         27.565
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_exptl_crystal_description       BLOCK
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0408
_refine_ls_R_factor_gt           0.0297
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0521P)^2^+1.4354P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0786
_refine_ls_wR_factor_ref         0.0913
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8135
_reflns_number_total             9231
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1dt01074c2.cif
_cod_data_source_block           mo_20190406C_0m_a
_cod_depositor_comments          'Adding full bibliography for 7707360.cif.'
_cod_database_code               7707360
_shelx_estimated_absorpt_t_min   0.851
_shelx_estimated_absorpt_t_max   0.917
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_shelx_res_checksum              60430