Regioselective Access to α-Vinylsilanes and α-Vinylgermanes by Cobalt-Catalyzed Migratory Hydrofunctionalization of 2-Alkynes
Sahoo, Manoj Kumar; Kim, Dongwook; Chang, Sukbok; Park, Jung-Woo; ACS Catalysis 11 (2021) 12777–12784; doi:10.1021/acscatal.1c03769

data_4519101
_publ_section_title
;
 Regioselective Access to \a-Vinylsilanes and \a-Vinylgermanes by
 Cobalt-Catalyzed Migratory Hydrofunctionalization of 2-Alkynes
;
_journal_issue                   20
_journal_name_full               'ACS Catalysis'
_journal_page_first              12777
_journal_page_last               12784
_journal_paper_doi               10.1021/acscatal.1c03769
_journal_volume                  11
_journal_year                    2021
_chemical_formula_sum            'C30 H55 Co P2'
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_diffrn_source                   'I&#x00CE;&#x00BC;S 3.0 Microfocus'
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_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            brown
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0615P)^2^+23.7564P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3143
_refine_ls_wR_factor_ref         0.3252
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4076
_reflns_number_total             5145
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            cs1c03769_si_002.cif
_cod_data_source_block           A21025_002_tw
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 
;
_cod_original_cell_volume        1451.8(5)
_cod_database_code               4519101
_shelx_shelxl_version_number     2018/3
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_shelx_estimated_absorpt_t_max   0.973
_shelx_res_checksum              53312
_shelx_hkl_checksum              41786