Bulky N-Phosphino-Functionalized N-Heterocyclic Carbene Ligands: Synthesis, Ruthenium Coordination Chemistry, and Ruthenium Alkylidene Complexes for Olefin Metathesis.
Brown, Christopher C.; Rominger, Frank; Limbach, Michael; Hofmann, Peter; Inorganic chemistry 54 (2015) 10126–10140; doi:10.1021/acs.inorgchem.5b00513

data_4346145
_publ_section_title
;
 Bulky N-Phosphino-Functionalized N-Heterocyclic Carbene Ligands:
 Synthesis, Ruthenium Coordination Chemistry, and Ruthenium Alkylidene
 Complexes for Olefin Metathesis.
;
_journal_issue                   21
_journal_name_full               'Inorganic chemistry'
_journal_page_first              10126
_journal_page_last               10140
_journal_paper_doi               10.1021/acs.inorgchem.5b00513
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'C18 H37 Cl6 N2 P Ru Si'
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_chemical_name_common            'in manuscript 5a'
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
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_space_group_name_H-M_alt        'P 1 21/n 1'
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_diffrn_ambient_temperature      200(2)
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_diffrn_measurement_device_type  'Bruker APEX-II Quazar'
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_diffrn_source                   'ImuS microsource'
_exptl_absorpt_coefficient_mu    1.184
_exptl_absorpt_correction_T_max  0.9132
_exptl_absorpt_correction_T_min  0.7581
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Sheldrick, G. M. (2008). <i>SADABS</i>. University of G\"ottingen, Germany.
;
_exptl_crystal_colour            green
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0487P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_original_cell_volume        2938.8(7)
_cod_original_sg_symbol_H-M      'P 21/n'
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_shelx_estimated_absorpt_t_min   0.881
_shelx_estimated_absorpt_t_max   0.891
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