C‒H Activation of Fluoroarenes: Synthesis, Structure, and Luminescence Properties of Copper(I) and Gold(I) Complexes Bearing 2-Phenylpyridine Ligands
Molteni, Roberto; Edkins, Katharina; Haehnel, Martin; Steffen, Andreas; Organometallics 35 (2016) 629–; doi:10.1021/acs.organomet.5b00904

data_4088167
_publ_section_title
;
 C--H Activation of Fluoroarenes: Synthesis, Structure, and Luminescence
 Properties of Copper(I) and Gold(I) Complexes Bearing 2-Phenylpyridine
 Ligands
;
_journal_issue                   5
_journal_name_full               Organometallics
_journal_page_first              629
_journal_paper_doi               10.1021/acs.organomet.5b00904
_journal_volume                  35
_journal_year                    2016
_chemical_formula_moiety         'C32 H25 Au F4 N P'
_chemical_formula_sum            'C32 H25 Au F4 N P'
_chemical_formula_weight         727.46
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_atom_sites_solution_secondary   iterative
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 105.953(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.5942(5)
_cell_length_b                   12.8526(5)
_cell_length_c                   18.8541(7)
_cell_measurement_reflns_used    3978
_cell_measurement_temperature    100(2)
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_cell_measurement_theta_min      2.25
_cell_volume                     2701.35(19)
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_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'CCD area detector (Apex2)'
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_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker X8-APEX II'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_limit_l_min       -23
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_diffrn_source                   'rotating anode (Nonius FR-591)'
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         5314
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0231P)^2^+4.6629P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_block           MaHa079_multiscan
_cod_original_sg_symbol_H-M      'P 21/n'
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_shelx_estimated_absorpt_t_max   0.623
_shelx_res_checksum              16982