Inorganic clusters as metalloligands: ligand effects on the synthesis and properties of ternary nanopropeller clusters.
Kephart, Jonathan A.; Boggiano, Andrew C.; Kaminsky, Werner; Velian, Alexandra; Dalton transactions (Cambridge, England : 2003) 49 (2020) 16464–16473; doi:10.1039/d0dt02416c

data_7705267
_publ_section_title
;
 Inorganic clusters as metalloligands: ligand effects on the synthesis and
 properties of ternary nanopropeller clusters.
;
_journal_issue                   45
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              16464
_journal_page_last               16473
_journal_paper_doi               10.1039/d0dt02416c
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C12 H22 Co N O3 P'
_chemical_formula_sum            'C12 H22 Co N O3 P'
_chemical_formula_weight         318.2
_chemical_name_systematic        '[Co(CO)3(iPr2PNHiPr)]2'
_space_group_IT_number           205
_space_group_name_Hall           '-P 2ac 2ab 3'
_space_group_name_H-M_alt        'P a -3'
_symmetry_cell_setting           cubic
_symmetry_Int_Tables_number      205
_symmetry_space_group_name_Hall  '-P 2ac 2ab 3'
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_audit_update_record
;
2020-07-06 deposited with the CCDC.	2020-08-25 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
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_cell_length_b                   14.6369(9)
_cell_length_c                   14.6369(9)
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_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.33
_cell_measurement_theta_min      1.39
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_diffrn_source                   'fine-focus sealed tube'
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_exptl_crystal_description       shard
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_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.05
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_refine_ls_R_factor_all          0.1349
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_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0738P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0983
_refine_ls_wR_factor_ref         0.1479
_reflns_Friedel_coverage         0
_reflns_number_gt                589
_reflns_number_total             1306
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7705267--7705273.cif.'
_cod_original_cell_volume        3135.8(6)
_cod_database_code               7705267
_shelx_estimated_absorpt_t_min   0.921
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