Redox-Initiated Reactivity of Dinuclear β-Diketiminatoniobium Imido Complexes.
Kriegel, Benjamin M.; Naested, Lara C. E.; Nocton, Grégory; Lakshmi, K. V.; Lohrey, Trevor D.; Bergman, Robert G.; Arnold, John; Inorganic chemistry 56 (2017) 1626–1637; doi:10.1021/acs.inorgchem.6b02735

data_4345454
_publ_section_title
;
 Redox-Initiated Reactivity of Dinuclear \b-Diketiminatoniobium Imido
 Complexes.
;
_journal_issue                   3
_journal_name_full               'Inorganic chemistry'
_journal_page_first              1626
_journal_page_last               1637
_journal_paper_doi               10.1021/acs.inorgchem.6b02735
_journal_volume                  56
_journal_year                    2017
_chemical_formula_sum            'C36 H53 Cl2 N4 Nb O'
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_chemical_name_systematic
; 
 ? 
;
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_diffrn_measurement_device_type  'Bruker APEX-I CCD'
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_diffrn_reflns_theta_max         25.329
_diffrn_reflns_theta_min         1.773
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.506
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_exptl_absorpt_process_details   SADABS
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_refine_ls_number_reflns         6661
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_refine_ls_R_factor_all          0.0236
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_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0229P)^2^+1.7024P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_estimated_absorpt_t_min   0.823
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