Expanding the reactivity of Rosenthal's reagent to cyclopropenes and allenes.
Eilers, Marcel; Geik, Dennis; Schmidtmann, Marc; Doye, Sven; Beckhaus, Rüdiger; Dalton transactions (Cambridge, England : 2003) 55 (2026) 5151–5160; doi:10.1039/d6dt00059b

data_7720293
_publ_section_title
;
 Expanding the reactivity of Rosenthal's reagent to cyclopropenes and
 allenes.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5151
_journal_page_last               5160
_journal_paper_doi               10.1039/d6dt00059b
_journal_volume                  55
_journal_year                    2026
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_space_group_name_H-M_alt        'P n a 21'
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_audit_update_record
;
2025-07-07 deposited with the CCDC.	2026-02-18 downloaded from the CCDC.
;
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_exptl_crystal_description       rod
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.492(13)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+7.5000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                10941
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d6dt00059b2.cif
_cod_data_source_block           5t
_cod_depositor_comments
'Adding full bibliography for 7720284--7720301.cif.'
_cod_original_cell_volume        6062.0(9)
_cod_database_code               7720293
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.734
_shelx_estimated_absorpt_t_max   0.906
_shelx_res_checksum              57706
_shelx_hkl_checksum              90862