Linear Trinuclear Pt...Mo-Mo Complexes [Mo2PtX2(pyphos)2(O2CR)2]2 (X = Cl, Br, I; R = CH3, C(CH3)3; pyphos = 6-(Diphenylphosphino)-2-pyridonate) with an Axial Interaction between the Quadruply Bonded Mo2 Moiety and the Platinum Atom
Hiroshi Nakano; Akira Nakamura; Kazushi Mashima; Inorganic Chemistry 35 (1996) 4007–4012; doi:10.1021/ic950988b

data_4323837
_publ_section_title
;
 Linear Trinuclear Pt...Mo-Mo Complexes [Mo2PtX2(pyphos)2(O2CR)2]2 (X =
 Cl, Br, I; R = CH3, C(CH3)3; pyphos = 6-(Diphenylphosphino)-2-pyridonate)
 with an Axial Interaction between the Quadruply Bonded Mo2 Moiety and the
 Platinum Atom
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4007
_journal_page_last               4012
_journal_paper_doi               10.1021/ic950988b
_journal_volume                  35
_journal_year                    1996
_chemical_formula_sum            'C45 H46 Cl2 I2 Mo2 N2 O6 P2 Pt'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             'Wed Nov  1 16:02:59 1995'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 107.97(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4.00
_cell_length_a                   13.359(4)
_cell_length_b                   19.685(3)
_cell_length_c                   20.392(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    23.0
_cell_measurement_theta_max      39.54
_cell_measurement_theta_min      35.11
_cell_volume                     5101(2)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_computing_structure_solution    'DIRDIF92 (PATTY)'
_diffrn_ambient_temperature      23.0
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
_diffrn_orient_matrix_UB_11      -0.02714
_diffrn_orient_matrix_UB_12      0.03153
_diffrn_orient_matrix_UB_13      0.02904
_diffrn_orient_matrix_UB_21      -0.05388
_diffrn_orient_matrix_UB_22      -0.03451
_diffrn_orient_matrix_UB_23      0.00204
_diffrn_orient_matrix_UB_31      0.05052
_diffrn_orient_matrix_UB_32      -0.01987
_diffrn_orient_matrix_UB_33      0.04255
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.00
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            12558
_diffrn_reflns_theta_max         27.5063
_diffrn_standards_decay_%        -4.03
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu_cm 46.318
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.605
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.933
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             2840.00
_exptl_crystal_size_max          0.400
_exptl_crystal_size_min          0.300
_refine_diff_density_max         -1.72090
_refine_diff_density_min         1.60810
_refine_ls_extinction_coef       0.35685
_refine_ls_extinction_method     Zachariasen_type_2_Gaussian_isotropic
_refine_ls_goodness_of_fit_obs   2.070
_refine_ls_matrix_type           full
_refine_ls_number_parameters     560
_refine_ls_number_reflns         8421
_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0390
_refine_ls_shift/esd_max         6.1220
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0310
_cod_data_source_file            ic950988b_3.cif
_cod_data_source_block           Mo2Pt(pyphos)2(O2CCMe3)2I2.(CH2Cl2)
_cod_original_cell_volume        5101(1)
_cod_original_sg_symbol_H-M      'P 21/n '
_cod_original_formula_sum        'C45 H46 O6 N2 Cl2 I2 P2 Mo2 Pt'
_cod_database_code               4323837