Platinum-Mediated Dinitrogen Liberation from 2-Picolyl Azide through a Putative Pt=N Double Bond Containing Intermediate
Balazs Pinter; Damijana Urankar; Andrej Pevec; Frank De Proft; Janez Košmrlj; Inorganic Chemistry 52 (2013) 4528–4533; doi:10.1021/ic302834e

data_4334494
_publ_contact_author_address
;
Faculty of Chemistry and Chemical Technology
University of Ljubljana
A\<sker\<ceva 5, P. O. Box 537
1000 Ljubljana
Slovenia
;
_publ_contact_author_email       andrej.pevec@fkkt.uni-lj.si
_publ_contact_author_name        'Andrej Pevec'
_publ_section_title
;
 Platinum-Mediated Dinitrogen Liberation from 2-Picolyl Azide through a
 Putative Pt=N Double Bond Containing Intermediate
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4528
_journal_page_last               4533
_journal_paper_doi               10.1021/ic302834e
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'C6 H6 Cl2 N2 Pt'
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_chemical_name_systematic
;
 ?
;
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_computing_cell_refinement
'DENZO and SCALEPACK (Otwinowski & Minor, 1997)'
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_computing_publication_material  'WinGX (Farrugia, 1999)'
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_diffrn_ambient_temperature      293(2)
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_diffrn_measured_fraction_theta_max 0.997
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Nonius KappaCCD area-detector diffractometer
;
_diffrn_measurement_method       '\w scans and \f scans'
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_diffrn_reflns_theta_max         27.47
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_exptl_absorpt_correction_T_min  0.0992
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_exptl_absorpt_process_details   'SCALEPACK (Otwinowski & Minor, 1997)'
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_refine_ls_shift/su_mean         0.0001
_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0309P)^2^+0.2480P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_database_code               4334494