Facile construction of an Ag0-doped Ag(i)-based coordination polymer via a self-photoreduction strategy for enhanced visible light driven photocatalysis
Jiang, Wei; Lv, Mengying; Gao, Baihui; Liu, Bo; Yan, Guosong; Zhou, Shi; Liu, Chunbo; Xie, Wei; Che, Guangbo; CrystEngComm 23 (2021) 5397–5402; doi:10.1039/D1CE00699A

data_7243135
_publ_section_title
;
 Facile construction of an Ag0-doped Ag(i)-based coordination polymer via
 a self-photoreduction strategy for enhanced visible light driven
 photocatalysis
;
_journal_issue                   31
_journal_name_full               CrystEngComm
_journal_page_first              5397
_journal_page_last               5402
_journal_paper_doi               10.1039/D1CE00699A
_journal_volume                  23
_journal_year                    2021
_chemical_formula_sum            'C32 H30 Ag2 N7 O8.5'
_chemical_formula_weight         864.37
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-04-25 deposited with the CCDC.	2021-06-29 downloaded from the CCDC.
;
_cell_angle_alpha                100.520(5)
_cell_angle_beta                 109.121(5)
_cell_angle_gamma                97.132(5)
_cell_formula_units_Z            2
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_cell_length_b                   12.621(3)
_cell_length_c                   14.493(4)
_cell_measurement_reflns_used    1173
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      19.85
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_cell_volume                     1896.7(9)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_diffrn_reflns_limit_h_max       14
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_diffrn_reflns_limit_l_max       16
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_diffrn_reflns_number            13005
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.152
_diffrn_reflns_theta_min         1.531
_exptl_absorpt_coefficient_mu    1.088
_exptl_crystal_colour            yellow
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_exptl_crystal_description       block
_exptl_crystal_F_000             866
_refine_diff_density_max         0.691
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
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_refine_ls_number_reflns         8311
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0339P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1149
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_reflns_number_gt                4088
_reflns_number_total             8311
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1ce00699a2.cif
_cod_data_source_block           shelx
_cod_depositor_comments          'Adding full bibliography for 7243135.cif.'
_cod_original_cell_volume        1896.8(8)
_cod_original_formula_sum        'C32 H30 Ag2 N7 O8.50'
_cod_database_code               7243135
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              12678
_shelx_hkl_checksum              26902
_platon_squeeze_void_probe_radius 1.20