Chiral discrimination in solid-state interactions of cobalt(iii)–polyamine complex cations with tris-(dipicolinato)lanthanate(iii) anions
Harrowfield, Jack M.; Kim, Yang; Skelton, Brian W.; Sobolev, Alexandre N.; White, Allan H.; CrystEngComm 19 (2017) 2372–; doi:10.1039/C6CE02573K

data_7228010
_publ_section_title
;
 Chiral discrimination in solid-state interactions of
 cobalt(iii)--polyamine complex cations with
 tris-(dipicolinato)lanthanate(iii) anions
;
_journal_issue                   17
_journal_name_full               CrystEngComm
_journal_page_first              2372
_journal_paper_doi               10.1039/C6CE02573K
_journal_volume                  19
_journal_year                    2017
_chemical_formula_moiety         'C21 H9 La N3 O12, C6 H24 Co N6, 4(H2 O)'
_chemical_formula_sum            'C27 H41 Co La N9 O16'
_chemical_formula_weight         945.53
_chemical_name_common            '[La(dipic)3] [CoEn3] * 4(H2O)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-03-15 deposited with the CCDC.
2017-03-29 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.995
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_diffrn_measurement_method       '\w scans'
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'SADABS - Bruker area detector absorption corrections'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0410P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                6795
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7228006--7228011.cif.'
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