Photoactive Ru(II) Complexes With Dioxinophenanthroline Ligands Are Potent Cytotoxic Agents.
Hidayatullah, Achmad N.; Wachter, Erin; Heidary, David K.; Parkin, Sean; Glazer, Edith C.; Inorganic chemistry 53 (2014) 10030–10032; doi:10.1021/ic5017164

data_4341101
_publ_section_title
;
 Photoactive Ru(II) Complexes With Dioxinophenanthroline Ligands Are
 Potent Cytotoxic Agents.
;
_journal_issue                   19
_journal_name_full               'Inorganic chemistry'
_journal_page_first              10030
_journal_page_last               10032
_journal_paper_doi               10.1021/ic5017164
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety         'C42 H34 N6 O2 Ru, 2(F6 P)'
_chemical_formula_sum            'C42 H34 F12 N6 O2 P2 Ru'
_chemical_formula_weight         1045.76
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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_cell_angle_beta                 73.470(1)
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_cell_measurement_temperature    180(2)
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_computing_cell_refinement       'APEX2 (Bruker-AXS, 2006)'
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'SHELX (Sheldrick, 2008) and CIFFIX (Parkin, 2013)'
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_diffrn_ambient_temperature      180(2)
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_diffrn_measurement_device_type  'Bruker X8 Proteum diffractometer'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           CuK\a
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_diffrn_source                   'fine-focus rotating anode'
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1528P)^2^+10.3564P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_total             19088
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 4341099--4341101.cif.'
_cod_original_cell_volume        5467.85(18)
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