Synthesis and Structural Characterization of Cationic Rhenium(V) and Technetium(V) Dioxo Complexes Containing Four N-Heterocyclic Carbene Ligands
Henrik Braband; Theresa I. Zahn; Ulrich Abram; Inorganic Chemistry 42 (2003) 6160–6162; doi:10.1021/ic0348345

data_4314390
_publ_contact_author
;
      Ulrich Abram
      Free University of Berlin     
      Institute of Chemistry             
      Fabeckstrasse 34-36                     
      D-14195 Berlin         
      Germany                          
;
_publ_contact_author_email       abram@chemie.fu-berlin.de
_publ_contact_author_fax         '0049 (0)30 838 52676'
_publ_contact_author_phone       '0049 (0)30 838 54002'
_publ_section_title
;
 Synthesis and Structural Characterization of Cationic Rhenium(V) and
 Technetium(V) Dioxo Complexes Containing Four N-Heterocyclic Carbene
 Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6160
_journal_page_last               6162
_journal_paper_doi               10.1021/ic0348345
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C44 H80 F6 N8 O2 P Re'
_chemical_formula_weight         1084.33
_chemical_name_systematic
;
Tetrakis(1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene)dioxorhenium(V) 
hexafluorophosphate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.84(1)
_cell_angle_beta                 104.02(1)
_cell_angle_gamma                93.62(1)
_cell_formula_units_Z            2
_cell_length_a                   12.425(3)
_cell_length_b                   12.914(4)
_cell_length_c                   16.605(5)
_cell_measurement_temperature    153(2)
_cell_volume                     2489.1(12)
_computing_cell_refinement       SAINT
_computing_data_collection       'BRUKER SMART'
_computing_data_reduction        SAINT
_computing_molecular_graphics    ORTEP
_computing_publication_material  WINGX
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SHELXS
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'BRUKER SMART'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0191
_diffrn_reflns_av_sigmaI/netI    0.0359
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            26261
_diffrn_reflns_theta_full        30.53
_diffrn_reflns_theta_max         30.53
_diffrn_reflns_theta_min         2.21
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  10sec/frame
_exptl_absorpt_coefficient_mu    2.539
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.858477
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.447
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1120
_exptl_crystal_size_max          .4
_exptl_crystal_size_mid          .4
_exptl_crystal_size_min          .2
_refine_diff_density_max         6.790
_refine_diff_density_min         -0.945
_refine_diff_density_rms         0.196
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    'riding model'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     559
_refine_ls_number_reflns         14929
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0529
_refine_ls_R_factor_gt           0.0450
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0774P)^2^+12.9612P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1262
_refine_ls_wR_factor_ref         0.1325
_reflns_number_gt                13164
_reflns_number_total             14929
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0348345si20030716_125321_1.cif
_cod_data_source_block           reocarb
_cod_original_cell_volume        2489(1)
_cod_database_code               4314390