Luminescence properties of some monomeric and dimeric cycloplatinated(ii) complexes containing biphosphine ligands.
Aghakhanpour, Reza Babadi; Nabavizadeh, S. Masoud; Rashidi, Mehdi; Kubicki, Maciej; Dalton transactions (Cambridge, England : 2003) 44 (2015) 15829–15842; doi:10.1039/c5dt02450a

data_7035982
_publ_section_title
;
 Luminescence properties of some monomeric and dimeric cycloplatinated(ii)
 complexes containing biphosphine ligands.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15829
_journal_page_last               15842
_journal_paper_doi               10.1039/c5dt02450a
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C38 H34 N P2 Pt, Cl'
_chemical_formula_sum            'C38 H34 Cl N P2 Pt'
_chemical_formula_weight         797.14
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           60
_space_group_name_Hall           '-P 2n 2ab'
_space_group_name_H-M_alt        'P b c n'
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_atom_sites_solution_hydrogens   geom
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;
2015-07-24 deposited with the CCDC.
2015-07-29 downloaded from the CCDC.
;
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SHELXTL (Sheldrick, 2008), Mercury (Macrae et al., 2008)
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_diffrn_measurement_device_type  'SuperNova, Single source at offset), Atlas'
_diffrn_measurement_method       '/w scan'
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_diffrn_reflns_av_unetI/netI     0.0230
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.21t (release 14-08-2012 CrysAlis171 .NET)
(compiled Aug 14 2012,18:12:40)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.612
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_exptl_crystal_size_min          0.1
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_refine_ls_restrained_S_all      1.060
_refine_ls_R_factor_all          0.0359
_refine_ls_R_factor_gt           0.0322
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0530P)^2^+4.8890P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0890
_refine_ls_wR_factor_ref         0.0913
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_reflns_number_gt                5600
_reflns_number_total             6230
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7035981--7035984.cif.'
_cod_database_code               7035982
_shelxl_version_number           2013-4
_shelx_res_checksum              79035