Homoleptic quasilinear metal(i/ii) silylamides of Cr-Co with phenyl and allyl functions - impact of the oxidation state on secondary ligand interactions.
Weller, Ruth; Ruppach, Lutz; Shlyaykher, Alena; Tambornino, Frank; Werncke, C. Gunnar; Dalton transactions (Cambridge, England : 2003) 50 (2021) 10947–10963; doi:10.1039/d1dt01543e

data_7707902
_publ_section_title
;
 Homoleptic quasilinear metal(i/ii) silylamides of Cr-Co with phenyl and
 allyl functions - impact of the oxidation state on secondary ligand
 interactions.
;
_journal_issue                   31
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10947
_journal_page_last               10963
_journal_paper_doi               10.1039/d1dt01543e
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C40 H56 Li2 N2 Si2'
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Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
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2021-06-12 deposited with the CCDC.	2021-07-07 downloaded from the CCDC.
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;
X-Area X-Red32 1.63.4.0 (STOE, 2017)  Statistics over combined scale factors for x file reflections:
       min. = 0.736 (run 2)   max. = 1.151 (run 2)    spread = 0.4
;
_exptl_crystal_colour            'clear colourless'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0490P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                2591
_reflns_number_total             3939
_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7707896--7707917.cif.'
_cod_database_code               7707902
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_max   0.977
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;
;
_shelx_res_checksum              20231
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_olex2_submission_special_instructions 'No special instructions were received'