Regioselective Intramolecular Markovnikov and Anti-Markovnikov Hydrofunctionalization of Alkenes via Photoredox Catalysis
Wang, Hongyu; Man, Yunquan; Xiang, Yanan; Wang, Kaiye; Li, Na; Tang, Bo; Chemical Communications  (2019) –; doi:10.1039/C9CC05902D

data_7124060
_publ_section_title
;
 Regioselective Intramolecular Markovnikov and Anti-Markovnikov
 Hydrofunctionalization of Alkenes via Photoredox Catalysis
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/C9CC05902D
_journal_year                    2019
_chemical_formula_sum            'C17 H18 F6 N2 O'
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_audit_update_record
;
2019-06-23 deposited with the CCDC.    2019-08-26 downloaded from the CCDC.
;
_cell_angle_alpha                89.020(15)
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_cell_length_b                   9.7743(19)
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_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
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_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_av_R_equivalents  0.0437
_diffrn_reflns_av_unetI/netI     0.0576
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.965
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -10
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_diffrn_reflns_theta_max         71.264
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_refine_ls_number_reflns         3221
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_refine_ls_R_factor_all          0.1104
_refine_ls_R_factor_gt           0.0858
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.1274P)^2^+1.0887P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_database_code               7124060
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_shelx_res_checksum              6707