Phenanthroline ligands are biologically more active than their corresponding ruthenium(ii) arene complexes.
Valladolid, Jesús; Hortigüela, Carlos; Busto, Natalia; Espino, Gustavo; Rodríguez, Ana M; Leal, José M; Jalón, Félix A; Manzano, Blanca R.; Carbayo, Arancha; García, Begoña; Dalton transactions (Cambridge, England : 2003) 43 (2014) 2629–2645; doi:10.1039/c3dt52743c

data_7028745
_publ_section_title
;
 Phenanthroline ligands are biologically more active than their
 corresponding ruthenium(ii) arene complexes.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2629
_journal_page_last               2645
_journal_paper_doi               10.1039/c3dt52743c
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C22 H22 B Cl F4 N2 O Ru'
_chemical_formula_sum            'C22 H22 B Cl F4 N2 O Ru'
_chemical_formula_weight         553.75
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.644(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   17.274(6)
_cell_length_b                   16.130(6)
_cell_length_c                   16.903(6)
_cell_measurement_reflns_used    9958
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      23.341
_cell_measurement_theta_min      2.193
_cell_volume                     4678(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1085
_diffrn_reflns_av_sigmaI/netI    0.0667
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            43230
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.19
_exptl_absorpt_coefficient_mu    0.833
_exptl_absorpt_correction_T_max  0.7765
_exptl_absorpt_correction_T_min  0.7265
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.572
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2224
_exptl_crystal_size_max          0.41
_exptl_crystal_size_mid          0.41
_exptl_crystal_size_min          0.32
_refine_diff_density_max         1.577
_refine_diff_density_min         -0.900
_refine_diff_density_rms         0.100
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     621
_refine_ls_number_reflns         8237
_refine_ls_number_restraints     54
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0815
_refine_ls_R_factor_gt           0.0591
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0828P)^2^+3.0614P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1517
_refine_ls_wR_factor_ref         0.1624
_reflns_number_gt                5785
_reflns_number_total             8237
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt52743c.txt
_cod_data_source_block           '[2a]BF4'
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7028745