Magnetic sponge phenomena associated with interchain dipole-dipole interactions in a series of ferrimagnetic chain compounds doped with minor diamagnetic species.
Nishio, Masaki; Miyasaka, Hitoshi; Inorganic chemistry 53 (2014) 4716–4723; doi:10.1021/ic500413j

data_4338169
_publ_section_title
;
 Magnetic sponge phenomena associated with interchain dipole-dipole
 interactions in a series of ferrimagnetic chain compounds doped with
 minor diamagnetic species.
;
_journal_issue                   9
_journal_name_full               'Inorganic chemistry'
_journal_page_first              4716
_journal_page_last               4723
_journal_paper_doi               10.1021/ic500413j
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety         'C44 H24 Cl4 N8 O12 Ru2 S2'
_chemical_formula_sum            'C44 H24 Cl4 N8 O12 Ru2 S2'
_chemical_formula_weight         1264.79
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                114.00(3)
_cell_angle_beta                 94.84(5)
_cell_angle_gamma                93.09(5)
_cell_formula_units_Z            1
_cell_length_a                   10.544(11)
_cell_length_b                   10.858(9)
_cell_length_c                   11.739(10)
_cell_measurement_reflns_used    3818
_cell_measurement_temperature    93
_cell_measurement_theta_max      27.21
_cell_measurement_theta_min      3.34
_cell_volume                     1218(2)
_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'CrystalStructure 4.0'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'DIRDIF99-PATTY (Gould, et al., 1999)'
_diffrn_ambient_temperature      93
_diffrn_detector_area_resol_mean 7.111
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0342
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            7944
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.995
_exptl_absorpt_correction_T_max  0.972
_exptl_absorpt_correction_T_min  0.873
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.725
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             628.00
_exptl_crystal_size_max          0.107
_exptl_crystal_size_mid          0.031
_exptl_crystal_size_min          0.029
_refine_diff_density_max         1.330
_refine_diff_density_min         -0.890
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     325
_refine_ls_number_reflns         4180
_refine_ls_number_restraints     287
_refine_ls_R_factor_gt           0.0724
_refine_ls_shift/su_max          0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0915P)^2^+5.2401P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1907
_reflns_number_gt                3117
_reflns_number_total             4180
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic500413j_si_002.cif
_cod_data_source_block           1-D_Ru-BTDA-TCNQ_1-dry_hm
_cod_depositor_comments          'Adding full bibliography for 4338169.cif.'
_cod_original_cell_volume        1217.7(19)
_cod_database_code               4338169