Poly[(μ~2~-2,2'-bipyridine-κ^2^<i>N</i>:<i>N</i>')bis(μ~3~-2,2,2-trifluoroacetato-κ^3^<i>O</i>:<i>O</i>:<i>O</i>')disilver(I)]
Arman, Hadi D.; Miller, Tyler; Tiekink, Edward R. T.; Acta Crystallographica Section E 66 (2010) m1209–m1210; doi:10.1107/S1600536810035282

data_2227517
_publ_section_title
;
 Poly[(\m~2~-2,2'-bipyridine-\k^2^<i>N</i>:<i>N</i>')bis(\m~3~-2,2,2-trifluoroacetato-\k^3^<i>O</i>:<i>O</i>:<i>O</i>')disilver(I)]
;
_journal_coeditor_code           HB5622
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1209
_journal_page_last               m1210
_journal_paper_doi               10.1107/S1600536810035282
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Ag2 (C2 F3 O2)2 (C10 H8 N2)]'
_chemical_formula_moiety         'C14 H8 Ag2 F6 N2 O4'
_chemical_formula_sum            'C14 H8 Ag2 F6 N2 O4'
_chemical_formula_weight         597.96
_chemical_name_systematic
;
Poly[(\m~2~-2,2'-bipyridine-\k^2^<i>N</i>:<i>N'</i>)bis(\m~3~-2,2,2-
trifluoroacetato-\k^3^<i>O</i>:<i>O</i>:<i>O</i>')disilver(I)]
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 116.029(4)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   24.597(6)
_cell_length_b                   6.8474(14)
_cell_length_c                   21.253(5)
_cell_measurement_reflns_used    8570
_cell_measurement_temperature    98(2)
_cell_measurement_theta_max      40.5
_cell_measurement_theta_min      1.8
_cell_volume                     3216.5(13)
_computing_cell_refinement
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_data_collection
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_data_reduction
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_molecular_graphics
'ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      98(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku AFC12\K/SATURN724'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.037
_diffrn_reflns_av_sigmaI/netI    0.043
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            10231
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         1.8
_diffrn_standards_decay_%        '< 1'
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.528
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.619
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.470
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2288
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.29
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.66
_refine_diff_density_min         -0.65
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.09
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     253
_refine_ls_number_reflns         3661
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.09
_refine_ls_R_factor_all          0.033
_refine_ls_R_factor_gt           0.031
_refine_ls_shift/su_max_lt       0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0473P)^2^+8.2186P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.089
_refine_ls_wR_factor_ref         0.091
_reflns_number_gt                3469
_reflns_number_total             3662
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb5622.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2227517
_cod_database_fobs_code          2227517