Room temperature olefination of methane with titanium-carbon multiple bonds.
Kurogi, Takashi; Won, Joonghee; Park, Bohyun; Trofymchuk, Oleksandra S.; Carroll, Patrick J.; Baik, Mu-Hyun; Mindiola, Daniel J.; Chemical science 9 (2018) 3376–3385; doi:10.1039/c7sc05238c

data_1548907
_publ_section_title
;
 Room temperature olefination of methane with titanium-carbon multiple
 bonds.
;
_journal_issue                   13
_journal_name_full               'Chemical science'
_journal_page_first              3376
_journal_page_last               3385
_journal_paper_doi               10.1039/c7sc05238c
_journal_volume                  9
_journal_year                    2018
_chemical_formula_moiety         'C46 H57 N5 P2 Ti, C10 H8 N2'
_chemical_formula_sum            'C56 H65 N7 P2 Ti'
_chemical_formula_weight         945.99
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_atom_sites_solution_hydrogens   mixed
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_atom_sites_solution_secondary   direct
_audit_creation_date             2017-09-23
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;
Olex2 1.2
(compiled 2017.07.20 svn.r3457 for OlexSys, GUI svn.r5370)
;
_audit_update_record
;
2017-12-08 deposited with the CCDC.
2018-02-13 downloaded from the CCDC.
;
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'w=1/[\s^2^(Fo^2^)+(0.0401P)^2^+3.4070P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 1548906--1548907.cif.'
_cod_original_cell_volume        4978.4(16)
_cod_database_code               1548907
_shelx_shelxl_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'