Versatile Behavior of [Pt2Ag4(C⋮C-t-Bu)8]: Synthesis, Structures, and Properties of [{Pt2Ag4(C⋮C-t-Bu)8}{Ag(bipy)}]4+and an Unprecedented Chain Polymeric Cocrystallization Adduct with a 2,2‘-bipy Ligand
Ara, Irene; Forniés, Juan; Gómez, Julio; Lalinde, Elena; Moreno, M. Teresa; Organometallics 19 (2000) 3137–; doi:10.1021/om0001570

data_4077500
_publ_section_title
;
 Versatile Behavior of [Pt2Ag4(C&#x22EE;C-t-Bu)8]:&#x00A0; Synthesis,
 Structures, and Properties of [{Pt2Ag4(C&#x22EE;C-t-Bu)8}{Ag(bipy)}]4+and
 an Unprecedented Chain Polymeric Cocrystallization Adduct with a
 2,2&#x2018;-bipy Ligand
;
_journal_issue                   16
_journal_name_full               Organometallics
_journal_page_first              3137
_journal_paper_doi               10.1021/om0001570
_journal_volume                  19
_journal_year                    2000
_chemical_formula_sum            'C96 H132 Ag6 N2 Pt2'
_chemical_formula_weight         2351.44
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                73.8580(14)
_cell_angle_beta                 77.3460(15)
_cell_angle_gamma                87.2350(13)
_cell_formula_units_Z            1
_cell_length_a                   10.8920(3)
_cell_length_b                   11.8610(3)
_cell_length_c                   12.7780(3)
_cell_measurement_temperature    293(2)
_cell_volume                     1547.05(7)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0553
_diffrn_reflns_av_sigmaI/netI    0.0705
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            13224
_diffrn_reflns_theta_full        29.14
_diffrn_reflns_theta_max         29.14
_diffrn_reflns_theta_min         3.07
_exptl_absorpt_coefficient_mu    6.424
_exptl_crystal_density_diffrn    2.524
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1160
_refine_diff_density_max         1.329
_refine_diff_density_min         -1.825
_refine_diff_density_rms         0.189
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.214
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     310
_refine_ls_number_reflns         8226
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.214
_refine_ls_R_factor_all          0.0662
_refine_ls_R_factor_gt           0.0534
_refine_ls_shift/su_max          1.693
_refine_ls_shift/su_mean         0.411
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0809P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1407
_refine_ls_wR_factor_ref         0.1579
_reflns_number_gt                6861
_reflns_number_total             8226
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om0001570.cif
_cod_data_source_block           3
_cod_database_code               4077500