New sterically-hindered o-quinones annelated with metal-dithiolates: regiospecificity in oxidative addition reactions of a bifacial ligand to the Pd and Pt complexes.
Martyanov, K. A.; Cherkasov, V. K.; Abakumov, G. A.; Samsonov, M. A.; Khrizanforova, V. V.; Budnikova, Y. H.; Kuropatov, V. A.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 7400–7405; doi:10.1039/c6dt00769d

data_7038933
_publ_section_title
;
 New sterically-hindered o-quinones annelated with metal-dithiolates:
 regiospecificity in oxidative addition reactions of a bifacial ligand to
 the Pd and Pt complexes.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7400
_journal_page_last               7405
_journal_paper_doi               10.1039/c6dt00769d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C50 H48 O2 P2 Pd S2'
_chemical_formula_weight         913.34
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-03-11 deposited with the CCDC.
2016-03-11 downloaded from the CCDC.
;
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_computing_structure_solution    'SHELXT-2014/4 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker D8 Quest CMOS'
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_diffrn_reflns_point_group_measured_fraction_full 0.996
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0294P)^2^+3.6066P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7038933--7038935.cif.'
_cod_original_cell_volume        4258.0(6)
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_shelx_res_checksum              34533