Thioantimonate(III) anions acting as bridging ligands in neutral transition metal complexes: solvothermal synthesis and characterisation of the two novel compounds [Co(C6H18N4)]2Sb4S8 and [Co(C6H18N4)]2Sb2S5 containing [Sb4S8]4‒ and [Sb2S5]4‒ anions
Stähler, Ralph; Bensch, Wolfgang; Journal of the Chemical Society, Dalton Transactions  (2001) 2518–; doi:10.1039/b102273n

data_7010681
_publ_section_title
;
 Thioantimonate(III) anions acting as bridging ligands in neutral
 transition metal complexes: solvothermal synthesis and
 characterisation of the two novel compounds [Co(C6H18N4)]2Sb4S8 and
 [Co(C6H18N4)]2Sb2S5 containing [Sb4S8]4-- and [Sb2S5]4-- anions
;
_journal_issue                   17
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2518
_journal_paper_doi               10.1039/b102273n
_journal_year                    2001
_chemical_formula_sum            'C12 H36 Co2 N8 S5 Sb2'
_chemical_formula_weight         814.15
_space_group_IT_number           15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.68(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   30.157(6)
_cell_length_b                   7.7196(15)
_cell_length_c                   22.875(5)
_cell_measurement_temperature    293(2)
_cell_volume                     5307.5(19)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0412
_diffrn_reflns_av_sigmaI/netI    0.0264
_diffrn_reflns_limit_h_max       39
_diffrn_reflns_limit_h_min       -39
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            24623
_diffrn_reflns_theta_full        28.01
_diffrn_reflns_theta_max         28.01
_diffrn_reflns_theta_min         2.33
_exptl_absorpt_coefficient_mu    3.653
_exptl_crystal_density_diffrn    2.038
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3200
_refine_diff_density_max         0.586
_refine_diff_density_min         -0.808
_refine_diff_density_rms         0.092
_refine_ls_extinction_coef       0.00049(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     263
_refine_ls_number_reflns         6230
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.013
_refine_ls_R_factor_all          0.0311
_refine_ls_R_factor_gt           0.0235
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0367P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0561
_refine_ls_wR_factor_ref         0.0586
_reflns_number_gt                5248
_reflns_number_total             6230
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b102273n.txt
_cod_data_source_block           rs201
_cod_original_cell_volume        5307.6(18)
_cod_database_code               7010681