Synthesis and Catalytic Evaluation in Olefin Metathesis of a Second-Generation Homobimetallic Ruthenium‒Arene Complex Bearing a Vinylidene Ligand
Borguet, Yannick; Sauvage, Xavier; Zaragoza, Guillermo; Demonceau, Albert; Delaude, Lionel; Organometallics 30 (2011) 2730–; doi:10.1021/om2001074

data_4064435
_publ_section_title
;
 Synthesis and Catalytic Evaluation in Olefin Metathesis of a
 Second-Generation Homobimetallic Ruthenium--Arene Complex Bearing a
 Vinylidene Ligand
;
_journal_issue                   10
_journal_name_full               Organometallics
_journal_page_first              2730
_journal_paper_doi               10.1021/om2001074
_journal_volume                  30
_journal_year                    2011
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C32 H38 Cl4 N2 O Ru2, 0.5(C0.50 H Cl)'
_chemical_formula_sum            'C32.25 H38.5 Cl4.5 N2 O Ru2'
_chemical_formula_weight         831.82
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-I 2ya'
_symmetry_space_group_name_H-M   'I 1 2/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.3
_audit_creation_date             2011-02-02T11:03:30-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 109.228(5)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   18.424(2)
_cell_length_b                   14.331(2)
_cell_length_c                   27.579(4)
_cell_measurement_reflns_used    494
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      15.36
_cell_measurement_theta_min      2.74
_cell_measurement_wavelength     0.71073
_cell_volume                     6875.6(16)
_computing_cell_refinement       'APPEX2 (BRUKER AXS, 2005)'
_computing_data_collection       'APPEX2 (BRUKER AXS, 2005)'
_computing_data_reduction        'APPEX2 (BRUKER AXS, 2005)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR2004 (Giacovazzo et al, 2004)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'BRUKER APPEX-II CCD'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.2185
_diffrn_reflns_av_unetI/netI     0.1246
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            31059
_diffrn_reflns_theta_full        19.78
_diffrn_reflns_theta_max         19.78
_diffrn_reflns_theta_min         1.62
_exptl_absorpt_coefficient_mu    1.256
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.762
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'BRUKER SADABS'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.607
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3348
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.271
_refine_diff_density_min         -0.827
_refine_diff_density_rms         0.16
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     393
_refine_ls_number_reflns         3098
_refine_ls_number_restraints     198
_refine_ls_restrained_S_all      0.994
_refine_ls_R_factor_all          0.1272
_refine_ls_R_factor_gt           0.0649
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0892P)^2^+46.9033P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.147
_refine_ls_wR_factor_ref         0.182
_reflns_number_gt                1864
_reflns_number_total             3098
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            om2001074_si_003.cif
_cod_data_source_block           Complex_7
_cod_original_cell_volume        6875.2(16)
_cod_original_sg_symbol_H-M      I2/a
_cod_original_formula_sum        'C32.25 H38.50 Cl4.50 N2 O Ru2'
_cod_database_code               4064435