Synthesis and coordination chemistry of the PPN ligand 2-[bis(diisopropylphosphanyl)methyl]-6-methylpyridine
Han, Delong; Andres, Benjamin; Spannenberg, Anke; Beweries, Torsten; Acta Crystallographica Section C 73 (2017) 917–922; doi:10.1107/S205322961701261X

data_2020932
_publ_section_title
;
 Synthesis and coordination chemistry of the PPN ligand
 2-[bis(diisopropylphosphanyl)methyl]-6-methylpyridine
;
_journal_coeditor_code           OV3095
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              917
_journal_page_last               922
_journal_paper_doi               10.1107/S205322961701261X
_journal_volume                  73
_journal_year                    2017
_chemical_formula_iupac          'C19 H35 N P2'
_chemical_formula_moiety         'C19 H35 N P2'
_chemical_formula_sum            'C19 H35 N P2'
_chemical_formula_weight         339.42
_chemical_name_systematic
;
2-[Bis(diisopropylphosphanyl)methyl]-6-methylpyridine
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yc'
_space_group_name_H-M_alt        'P 1 2/c 1'
_symmetry_space_group_name_Hall  '-P 2yc'
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;
SAINT (Bruker, 2013)
;
_computing_data_collection
;
APEX2 (Bruker, 2014)
;
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SAINT (Bruker, 2013)
;
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XP in SHELXTL (Sheldrick, 2015)
;
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publCIF (Westrip, 2010)
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SHELXL-2014/7 (Sheldrick, 2015)
;
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SHELXS97 (Sheldrick, 2015)
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_exptl_absorpt_process_details
;
(SADABS; Bruker, 2014)
;
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_refine_ls_R_factor_all          0.0429
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w = 1/[\s^2^(Fo^2^)+(0.0487P)^2^+0.9053P] where P=(Fo^2^+2Fc^2^)/3'
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