Actinide Hydride Complexes as Multielectron Reductants: Analogous Reduction Chemistry from [(C5Me5)2UH]2, [(C5Me5)2UH2]2, and [(C5Me5)2ThH2]2
Evans, William J.; Miller, Kevin A.; Kozimor, Stosh A.; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.; Organometallics 26 (2007) 3568–; doi:10.1021/om7003139

data_4073409
_publ_section_title
;
 Actinide Hydride Complexes as Multielectron Reductants:&#x00A0; Analogous
 Reduction Chemistry from [(C5Me5)2UH]2, [(C5Me5)2UH2]2, and
 [(C5Me5)2ThH2]2
;
_journal_issue                   14
_journal_name_full               Organometallics
_journal_page_first              3568
_journal_paper_doi               10.1021/om7003139
_journal_volume                  26
_journal_year                    2007
_chemical_formula_sum            'C32 H40 S2 Th'
_chemical_formula_weight         720.80
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           170
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_cell_angle_beta                 90.00
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_cell_length_c                   32.450(3)
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_computing_cell_refinement       'Bruker SMART/SAINT'
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_computing_structure_refinement  'Bruker SHELXTL'
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_diffrn_ambient_temperature      163(2)
_diffrn_measured_fraction_theta_full 0.999
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_diffrn_radiation_monochromator  graphite
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_diffrn_standards_decay_%        '< 1.0'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SADABS'
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_exptl_crystal_description       hexagon
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0059P)^2^+1.3233P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0454
_refine_ls_wR_factor_ref         0.0462
_reflns_number_gt                6673
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om7003139-file005.cif
_cod_data_source_block           kam17
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'n/a' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P6(5)
_cod_database_code               4073409