<i>catena</i>-Poly[[lead(II)-bis(μ~2~-quinolin-8-olato)-κ^3^<i>N</i>,<i>O</i>:<i>O</i>;κ^3^<i>O</i>:<i>N</i>,<i>O</i>] <i>N</i>,<i>N</i>-dimethylformamide hemisolvate]
Ghaemi, Akbar; Dadkhah, Zohreh; Ng, Seik Weng; Tiekink, Edward R. T.; Acta Crystallographica Section E 68 (2012) m210–; doi:10.1107/S1600536812002796

data_2233499
_publ_section_title
;
 <i>catena</i>-Poly[[lead(II)-bis(\m~2~-quinolin-8-olato)-\k^3^<i>N</i>,<i>O</i>:<i>O</i>;\k^3^<i>O</i>:<i>N</i>,<i>O</i>]
 <i>N</i>,<i>N</i>-dimethylformamide hemisolvate]
;
_journal_coeditor_code           HG5166
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m210
_journal_paper_doi               10.1107/S1600536812002796
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Pb (C9 H6 N O)2] , 0.5C3 H7 N O'
_chemical_formula_moiety         'C18 H12 N2 O2 Pb2, 0.5(C3 H7 N O)'
_chemical_formula_sum            'C19.5 H15.5 N2.5 O2.5 Pb'
_chemical_formula_weight         532.04
_chemical_name_systematic
;
<i>catena</i>-Poly[[lead(II)-bis(\m~2~-quinolin-8-olato)-
\k^3^<i>N</i>,<i>O</i>:<i>O</i>;\k^3^<i>O</i>:<i>N</i>,<i>O</i>]
<i>N</i>,<i>N</i>-dimethylformamide hemisolvate]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                96.683(3)
_cell_angle_beta                 98.277(2)
_cell_angle_gamma                94.225(3)
_cell_formula_units_Z            2
_cell_length_a                   8.1841(2)
_cell_length_b                   9.6606(3)
_cell_length_c                   10.8619(3)
_cell_measurement_reflns_used    8798
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.5001
_cell_measurement_theta_min      2.5205
_cell_volume                     840.48(4)
_computing_cell_refinement       'CrysAlis PRO (Agilent, 2010)'
_computing_data_collection       'CrysAlis PRO (Agilent, 2010)'
_computing_data_reduction        'CrysAlis PRO (Agilent, 2010)'
_computing_molecular_graphics
;
ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)
;
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.4041
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type
'Agilent SuperNova Dual diffractometer with Atlas detector'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  Mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0355
_diffrn_reflns_av_sigmaI/netI    0.0367
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            13299
_diffrn_reflns_theta_full        27.56
_diffrn_reflns_theta_max         27.56
_diffrn_reflns_theta_min         2.53
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    10.057
_exptl_absorpt_correction_T_max  0.6891
_exptl_absorpt_correction_T_min  0.1523
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrysAlis PRO; Agilent, 2010)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.102
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             504
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.225
_refine_diff_density_min         -0.711
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     272
_refine_ls_number_reflns         3866
_refine_ls_number_restraints     36
_refine_ls_restrained_S_all      1.002
_refine_ls_R_factor_all          0.0243
_refine_ls_R_factor_gt           0.0212
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0245P)^2^+0.0115P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0468
_refine_ls_wR_factor_ref         0.0485
_reflns_number_gt                3613
_reflns_number_total             3866
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hg5166.cif
_cod_data_source_block           I
_cod_database_code               2233499
_cod_database_fobs_code          2233499