Catalytic Access to Bridged Sila- N-heterocycles from Piperidines via Cascade sp<sup>3</sup> and sp<sup>2</sup> C-Si Bond Formation.
Zhang, Jianbo; Park, Sehoon; Chang, Sukbok; Journal of the American Chemical Society 140 (2018) 13209–13213; doi:10.1021/jacs.8b08733

data_4133157
_publ_section_title
;
 Catalytic Access to Bridged Sila- N-heterocycles from Piperidines via
 Cascade sp<sup>3</sup> and sp<sup>2</sup> C-Si Bond Formation.
;
_journal_issue                   41
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13209
_journal_page_last               13213
_journal_paper_doi               10.1021/jacs.8b08733
_journal_volume                  140
_journal_year                    2018
_chemical_formula_sum            'C26 H29 N Si'
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_diffrn_measurement_device_type  'Photon 100 CMOS detector'
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_diffrn_source                   'fine-focus sealed tube'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0649P)^2^+0.2694P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1184
_refine_ls_wR_factor_ref         0.1260
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5438
_reflns_number_total             6400
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja8b08733_si_004.cif
_cod_data_source_block           A081_002
_cod_depositor_comments
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The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_database_code               4133157
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.949
_shelx_estimated_absorpt_t_max   0.972
_shelx_res_checksum              8726
_shelx_hkl_checksum              86016