Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na4(H2O)14}{Cu(gly)}2][TeMo6O24] and [{Cu(en)2}3{TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines.
Dutta, Daipayan; Jana, Atish D.; Debnath, Mainak; Bhaumik, Asim; Marek, Jaromir; Ali, Mahammad; Dalton transactions (Cambridge, England : 2003) 39 (2010) 11551–11559; doi:10.1039/c0dt00426j

data_7026443
_publ_section_title
;
 Robust 1D open rack-like architecture in coordination polymers of
 Anderson POMs [{Na4(H2O)14}{Cu(gly)}2][TeMo6O24] and
 [{Cu(en)2}3{TeW6O24}]: synthesis, characterization and heterogeneous
 catalytic epoxidation of olefines.
;
_journal_issue                   48
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11551
_journal_page_last               11559
_journal_paper_doi               10.1039/c0dt00426j
_journal_volume                  39
_journal_year                    2010
_chemical_formula_moiety         'C4 H32 Cu2 Mo6 N2 Na4 O42 Te'
_chemical_formula_sum            'C4 H32 Cu2 Mo6 N2 Na4 O42 Te'
_chemical_formula_weight         1702.60
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                73.573(5)
_cell_angle_beta                 78.822(5)
_cell_angle_gamma                78.197(5)
_cell_formula_units_Z            1
_cell_length_a                   7.1526(5)
_cell_length_b                   10.6481(6)
_cell_length_c                   14.2288(9)
_cell_measurement_reflns_used    6731
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      32.1632
_cell_measurement_theta_min      3.7613
_cell_volume                     1006.74(11)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 8.3611
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'KUMA + CCD'
_diffrn_measurement_method       'rotation method, \w--scan'
_diffrn_radiation_monochromator  'Enhance (Oxford Diffraction)'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0159
_diffrn_reflns_av_sigmaI/netI    0.0144
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            6905
_diffrn_reflns_theta_full        25.04
_diffrn_reflns_theta_max         25.04
_diffrn_reflns_theta_min         3.78
_exptl_absorpt_coefficient_mu    3.720
_exptl_absorpt_correction_T_max  0.69258
_exptl_absorpt_correction_T_min  0.31866
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.29.9 (release 23-03-2006 CrysAlis171 .NET)
(compiled Mar 23 2006,23:39:28)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    2.808
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             812
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.863
_refine_diff_density_min         -0.808
_refine_diff_density_rms         0.133
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.902
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     323
_refine_ls_number_reflns         3549
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      0.901
_refine_ls_R_factor_all          0.0265
_refine_ls_R_factor_gt           0.0246
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0350P)^2^+7.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0624
_refine_ls_wR_factor_ref         0.0636
_reflns_number_gt                3348
_reflns_number_total             3549
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt00426j.txt
_cod_data_source_block           in73
_cod_database_code               7026443