Conformational Effects on Glycoside Reactivity: Study of the High Reactive Conformer of Glucose
Ciaran McDonnell; Oscar López; Paul Murphy; José G. Fernández Bolaños; Rita Hazell; Mikael Bols; Journal of the American Chemical Society 126 (2004) 12374–12385; doi:10.1021/ja047476t

data_4113006
_publ_section_title
;
 Conformational Effects on Glycoside Reactivity: Study of the High
 Reactive Conformer of Glucose
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              12374
_journal_page_last               12385
_journal_paper_doi               10.1021/ja047476t
_journal_volume                  126
_journal_year                    2004
_chemical_absolute_configuration syn
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_chemical_name_systematic
;
Pent-4'-enyl-3,6-anhydro-2,4-di-O-benzyl-\b-D-glucopyranoside
;
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;
       ORTEP-III (Burnett & Johnson,  1996), KRYSTAL
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;
      SIR97 (Altomare et al., 1997 ), KRYSTAL
;
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_diffrn_measurement_device       'Siemens SMART CCD diffractometer'
_diffrn_measurement_method       '\w rotation scans with narrow frames'
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;
  Type 1 Lorentzian isotropic ( Becker and Coppens, 1974)
;
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;
w= 1/{[\s~cs~(F^2^)+1.03F^2^]^1/2^- |F|}^2^
;
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