Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: a novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ions.
Luo, Geng-Geng; Lin, Li-Rong; Huang, Rong-Bin; Zheng, Lan-Sun; Dalton transactions (Cambridge, England : 2003)  (2007) 3868–3870; doi:10.1039/b708799c

data_7006076
_publ_section_title
;
 Synthesis, crystal structure and optical properties of
 [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: a novel compound containing
 closed-shell 3d10, 4d10 and 5d10 metal ions.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3868
_journal_page_last               3870
_journal_paper_doi               10.1039/b708799c
_journal_year                    2007
_chemical_formula_moiety         'Ag U3 O6 (OAc)9 Zn (H2O)4 (CH3CH2OH)2 '
_chemical_formula_sum            'C22 H47 Ag O30 U3 Zn'
_chemical_formula_weight         1678.93
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 119.901(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.909(7)
_cell_length_b                   13.973(4)
_cell_length_c                   16.233(5)
_cell_measurement_reflns_used    3566
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      24.679
_cell_measurement_theta_min      2.582
_cell_volume                     4505(2)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        'SAINT (Bruker, 2001)'
_computing_molecular_graphics    'ORTEP II (Johnson, 1976)'
_computing_publication_material  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      298(2)
_diffrn_detector_area_resol_mean none
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker Smart APEX CCD diffractometer'
_diffrn_measurement_method       '\f and \w scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0683
_diffrn_reflns_av_sigmaI/netI    0.0825
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            11699
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.78
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  .
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    11.791
_exptl_absorpt_correction_T_max  0.2708
_exptl_absorpt_correction_T_min  0.2014
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2001)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.476
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plates
_exptl_crystal_F_000             3088
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.339
_refine_diff_density_min         -1.683
_refine_diff_density_rms         0.266
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.960
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     261
_refine_ls_number_reflns         4343
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.960
_refine_ls_R_factor_all          0.0712
_refine_ls_R_factor_gt           0.0551
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0643P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1205
_refine_ls_wR_factor_ref         0.1259
_reflns_number_gt                3288
_reflns_number_total             4343
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            b708799c.txt
_cod_data_source_block           p
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7006076