Effect of synergic cooperation on optical and photoelectrochemical properties of CeO2‒MnO composite thin films
Mansoor, Muhammad Adil; Mazhar, Muhammad; Ebadi, Mehdi; Ming, Huang Nay; Mat Teridi, Mohd Asri; Kong Mun, Lo; New J. Chem. 40 (2016) 5177–; doi:10.1039/C5NJ03446A

data_7055450
_publ_section_title
;
 Effect of synergic cooperation on optical and photoelectrochemical
 properties of CeO2--MnO composite thin films
;
_journal_issue                   6
_journal_name_full               'New J. Chem.'
_journal_page_first              5177
_journal_paper_doi               10.1039/C5NJ03446A
_journal_volume                  40
_journal_year                    2016
_chemical_formula_sum            'C12 H12 Ce F12 N O9'
_chemical_formula_weight         682.35
_chemical_name_systematic
'N,N-dimethylethanol ammonium tetrakis(trifluoroacetato)cerate'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/6
_audit_update_record
;
2015-08-27 deposited with the CCDC.
2016-04-04 downloaded from the CCDC.
;
_cell_angle_alpha                109.6251(17)
_cell_angle_beta                 101.8129(15)
_cell_angle_gamma                104.2412(17)
_cell_formula_units_Z            2
_cell_length_a                   8.7485(9)
_cell_length_b                   11.5996(13)
_cell_length_c                   12.3113(13)
_cell_measurement_reflns_used    3327
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.39
_cell_measurement_theta_min      2.63
_cell_volume                     1082.6(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2014/6 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0162
_diffrn_reflns_av_unetI/netI     0.0360
_diffrn_reflns_Laue_measured_fraction_full 0.977
_diffrn_reflns_Laue_measured_fraction_max 0.965
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            5938
_diffrn_reflns_point_group_measured_fraction_full 0.977
_diffrn_reflns_point_group_measured_fraction_max 0.965
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.500
_diffrn_reflns_theta_min         1.850
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    2.249
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6801
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.093
_exptl_crystal_description       block
_exptl_crystal_F_000             658
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: toluene'
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.055
_refine_diff_density_min         -1.178
_refine_diff_density_rms         0.126
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     315
_refine_ls_number_reflns         4329
_refine_ls_number_restraints     5
_refine_ls_restrained_S_all      1.063
_refine_ls_R_factor_all          0.0372
_refine_ls_R_factor_gt           0.0333
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0409P)^2^+2.7173P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0798
_refine_ls_wR_factor_ref         0.0823
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3954
_reflns_number_total             4329
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5nj03446a2.cif
_cod_data_source_block           LKM5195_0m
_cod_depositor_comments          'Adding full bibliography for 7055450.cif.'
_cod_database_code               7055450
_shelxl_version_number           2014/6
_shelx_res_checksum              67651