Reductive Elimination of Hypersilyl Halides from Zinc(II) Complexes. Implications for Electropositive Metal Thin Film Growth.
Sirimanne, Chatu T.; Kerrigan, Marissa M.; Martin, Philip D.; Kanjolia, Ravindra K.; Elliott, Simon D.; Winter, Charles H.; Inorganic chemistry 54 (2015) 7–9; doi:10.1021/ic502184f

data_4341926
_publ_section_title
;
 Reductive Elimination of Hypersilyl Halides from Zinc(II) Complexes.
 Implications for Electropositive Metal Thin Film Growth.
;
_journal_issue                   1
_journal_name_full               'Inorganic chemistry'
_journal_page_first              7
_journal_page_last               9
_journal_paper_doi               10.1021/ic502184f
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'C26 H70 I2 O2 Si8 Zn2'
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;
 ?
;
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_exptl_absorpt_coefficient_mu    2.520
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_exptl_crystal_F_000             2080
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_refine_ls_R_factor_all          0.0879
_refine_ls_R_factor_gt           0.0619
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0950P)^2^+62.0115P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                19810
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 4341924--4341926.cif.'
_cod_original_cell_volume        4772(3)
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