Alkali counterions tune diruthenium(iii,iii)-based ferrimagnetic chain structured antiferromagnets exhibiting step-like hysteresis loops.
Fan, Xiao-Meng; Li, Jing-Yu; Wang, Lin-Lin; Zhou, Zi-Qin; Tian, Yu-Chen; Yang, Jian-Hui; Liu, Bin; Dalton transactions (Cambridge, England : 2003) 48 (2019) 8039–8043; doi:10.1039/c9dt01295h

data_7049933
_publ_section_title
;
 Alkali counterions tune diruthenium(iii,iii)-based ferrimagnetic chain
 structured antiferromagnets exhibiting step-like hysteresis loops.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8039
_journal_page_last               8043
_journal_paper_doi               10.1039/c9dt01295h
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'Cu H14 O22 P4 Ru2, 2(H2 O), 2(Cs)'
_chemical_formula_sum            'Cs2 Cu H18 O24 P4 Ru2'
_chemical_formula_weight         1057.52
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2019-04-29 deposited with the CCDC.    2019-04-30 downloaded from the CCDC.
;
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_cell_length_c                   9.314(5)
_cell_measurement_reflns_used    310
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      18.56
_cell_measurement_theta_min      3.22
_cell_volume                     547.9(5)
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_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0432
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_exptl_absorpt_coefficient_mu    5.996
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.1187
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0770P)^2^+55.9104P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2264
_refine_ls_wR_factor_ref         0.2445
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1289
_reflns_number_total             1897
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt01295h2.cif
_cod_data_source_block           xb1139_0m
_cod_depositor_comments
'Adding full bibliography for 7049930--7049933.cif.'
_cod_original_cell_volume        547.9(4)
_cod_original_formula_sum        'Cs2 H18 Cu O24 P4 Ru2'
_cod_database_code               7049933
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_shelx_estimated_absorpt_t_min   0.215
_shelx_estimated_absorpt_t_max   0.316
_shelx_res_checksum              64013