A combined kinetico-mechanistic and computational study on the competitive formation of seven- versus five-membered platinacycles; the relevance of spectator halide ligands.
Aullón, Gabriel; Crespo, Margarita; Font-Bardia, Mercè; Jover, Jesús; Martínez, Manuel; Pike, Jack; Dalton transactions (Cambridge, England : 2003) 44 (2015) 17968–17979; doi:10.1039/c5dt02657a

data_7036386
_publ_section_title
;
 A combined kinetico-mechanistic and computational study on the
 competitive formation of seven- versus five-membered platinacycles; the
 relevance of spectator halide ligands.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              17968
_journal_page_last               17979
_journal_paper_doi               10.1039/c5dt02657a
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C25 H28 Br F N2 Pt, C H2 Cl2 '
_chemical_formula_sum            'C26 H30 Br Cl2 F N2 Pt'
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_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
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_symmetry_space_group_name_Hall  '-C 2yc'
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;
2015-02-25 deposited with the CCDC.
2015-09-03 downloaded from the CCDC.
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0173P)^2^+217.6773P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1050
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_reflns_number_gt                5462
_reflns_number_total             6599
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt02657a2.cif
_cod_data_source_block           mo_IAJSB71_0m_a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 7036385--7036387.cif.
;
_cod_original_cell_volume        5308.4(7)
_cod_database_code               7036386