Bis(μ-azido-κ^2^<i>N</i>^1^:<i>N</i>^1^)bis{(acetato-κ^2^<i>O</i>,<i>O</i>')[2,4,6-tris(2-pyridyl)-1,3,5-triazine-κ^3^<i>N</i>^2^,<i>N</i>^1^,<i>N</i>^6^]lead(II)}
Dayani, Milad; Ghaemi, Akbar; Ng, Seik Weng; Tiekink, Edward R. T.; Acta Crystallographica Section E 67 (2011) m1419–; doi:10.1107/S1600536811038116

data_2231903
_publ_section_title
;
 Bis(\m-azido-\k^2^<i>N</i>^1^:<i>N</i>^1^)bis{(acetato-\k^2^<i>O</i>,<i>O</i>')[2,4,6-tris(2-pyridyl)-1,3,5-triazine-\k^3^<i>N</i>^2^,<i>N</i>^1^,<i>N</i>^6^]lead(II)}
;
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1419
_journal_paper_doi               10.1107/S1600536811038116
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Pb2 (C2 H3 O2)2 (N3)2 (C18 H12 N6)2]'
_chemical_formula_moiety         'C40 H30 N18 O4 Pb2'
_chemical_formula_sum            'C40 H30 N18 O4 Pb2'
_chemical_formula_weight         1241.22
_chemical_name_systematic
;
Bis(\m-azido-\k^2^<i>N</i>^1^:<i>N</i>^1^)bis{(acetato-
\k^2^<i>O</i>,<i>O</i>')[2,4,6-tris(2-pyridyl)-1,3,5-triazine-
\k^3^<i>N</i>^2^,<i>N</i>^1^,<i>N</i>^6^]lead(II)}
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                86.739(4)
_cell_angle_beta                 70.928(4)
_cell_angle_gamma                70.100(4)
_cell_formula_units_Z            1
_cell_length_a                   8.5529(4)
_cell_length_b                   11.0080(5)
_cell_length_c                   11.8617(5)
_cell_measurement_reflns_used    5891
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.2154
_cell_measurement_theta_min      2.5950
_cell_volume                     990.60(9)
_computing_cell_refinement       'CrysAlis PRO (Agilent, 2010)'
_computing_data_collection       'CrysAlis PRO (Agilent, 2010)'
_computing_data_reduction        'CrysAlis PRO (Agilent, 2010)'
_computing_molecular_graphics
;
ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)
;
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.4041
_diffrn_measured_fraction_theta_full 0.959
_diffrn_measured_fraction_theta_max 0.959
_diffrn_measurement_device_type
'Agilent SuperNova Dual diffractometer with Atlas detector'
_diffrn_measurement_method       '\w scan'
_diffrn_radiation_monochromator  Mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0594
_diffrn_reflns_av_sigmaI/netI    0.0646
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            7814
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.60
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    8.557
_exptl_absorpt_correction_T_max  0.4816
_exptl_absorpt_correction_T_min  0.2794
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrysAlis PRO; Agilent, 2010)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.081
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             592
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.007
_refine_diff_density_min         -2.137
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.969
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     290
_refine_ls_number_reflns         4358
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.969
_refine_ls_R_factor_all          0.0351
_refine_ls_R_factor_gt           0.0242
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0106P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0466
_refine_ls_wR_factor_ref         0.0492
_reflns_number_gt                4046
_reflns_number_total             4358
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb6410.cif
_cod_data_source_block           I
_cod_original_cell_volume        990.60(8)
_cod_database_code               2231903
_cod_database_fobs_code          2231903