LMucko/crystallography-open-database huggingface dataset:
The crystal structure of potassium hexatitanate K2Ti6O13
Cid-Dresdner H; Buerger, M. J.; Zeitschrift fur Kristallographie 117 (1962) 411–430; doi:

data_9008090
_publ_section_title
;
 The crystal structure of potassium hexatitanate K2Ti6O13
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              411
_journal_page_last               430
_journal_volume                  117
_journal_year                    1962
_chemical_compound_source        Synthetic
_chemical_formula_sum            'K2 O13 Ti6'
_chemical_name_mineral           Jeppeite
_space_group_IT_number           12
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_cell_angle_alpha                90
_cell_angle_beta                 99.764
_cell_angle_gamma                90
_cell_length_a                   15.582
_cell_length_b                   3.82
_cell_length_c                   9.112
_cell_formula_units_Z            2
_cell_volume                     534.519
_database_code_amcsd             0010602
_exptl_crystal_density_diffrn    3.563
_cod_original_formula_sum        'K2 Ti6 O13'
_cod_database_code               9008090
The crystal structure of the anhydrous stannous sulphate
Rentzeperis, P. J.; Zeitschrift fur Kristallographie 117 (1962) 431–436; doi:

data_9008091
_publ_section_title
;
 The crystal structure of the anhydrous stannous sulphate
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              431
_journal_page_last               436
_journal_volume                  117
_journal_year                    1962
_chemical_formula_structural     SnSO4
_chemical_formula_sum            'O4 S Sn'
_space_group_IT_number           62
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   8.799
_cell_length_b                   5.319
_cell_length_c                   7.115
_cell_formula_units_Z            4
_cell_volume                     332.995
_database_code_amcsd             0010603
_exptl_crystal_density_diffrn    4.284
_cod_original_formula_sum        'Sn S O4'
_cod_database_code               9008091
_amcsd_formula_title             SnSO4
Die struktur des hochquarzes Note: sample is at T = 650 deg C Note: symmetry constraints on the temperature factors were applied incorrectly
Arnold, H.; Zeitschrift fur Kristallographie 117 (1962) 467–469; doi:

data_9008092
_publ_section_title
;Die struktur des hochquarzes Note: sample is at T = 650 deg C Note: symmetry
 constraints on the temperature factors were applied incorrectly
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              467
_journal_page_last               469
_journal_volume                  117
_journal_year                    1962
_chemical_formula_sum            'O2 Si'
_chemical_name_mineral           Quartz
_space_group_IT_number           180
_symmetry_space_group_name_Hall  'P 62 2 (0 0 4)'
_symmetry_space_group_name_H-M   'P 62 2 2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   5.01
_cell_length_b                   5.01
_cell_length_c                   5.47
_cell_formula_units_Z            3
_cell_volume                     118.903
_database_code_amcsd             0010604
_diffrn_ambient_temperature      923.15
_exptl_crystal_density_diffrn    2.517
_cod_original_formula_sum        'Si O2'
_cod_database_code               9008092
Die struktur des hochquarzes Note: sample is at T = 650 deg C, under the false assumption that it is twinned
Arnold, H.; Zeitschrift fur Kristallographie 117 (1962) 467–469; doi:

data_9008093
_publ_section_title
;Die struktur des hochquarzes Note: sample is at T = 650 deg C, under the
 false assumption that it is twinned
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              467
_journal_page_last               469
_journal_volume                  117
_journal_year                    1962
_chemical_formula_sum            'O2 Si'
_chemical_name_mineral           Quartz
_space_group_IT_number           152
_symmetry_space_group_name_Hall  'P 31 2"'
_symmetry_space_group_name_H-M   'P 31 2 1'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   5.01
_cell_length_b                   5.01
_cell_length_c                   5.47
_cell_formula_units_Z            3
_cell_volume                     118.903
_database_code_amcsd             0010605
_diffrn_ambient_temperature      923.15
_exptl_crystal_density_diffrn    2.517
_cod_original_formula_sum        'Si O2'
_cod_database_code               9008093
Strukturuntersuchungen im system Al2O3-Cr2O3
Saalfeld, H.; Zeitschrift fur Kristallographie 120 (1964) 342–348; doi:

data_9008094
_publ_section_title
;
 Strukturuntersuchungen im system Al2O3-Cr2O3
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              342
_journal_page_last               348
_journal_volume                  120
_journal_year                    1964
_chemical_formula_sum            'Al1.82 Cr0.18 O3'
_chemical_name_mineral           Corundum
_space_group_IT_number           167
_symmetry_space_group_name_Hall  '-P 3* 2n'
_symmetry_space_group_name_H-M   'R -3 c :R'
_cell_angle_alpha                55.27
_cell_angle_beta                 55.27
_cell_angle_gamma                55.27
_cell_length_a                   5.128
_cell_length_b                   5.128
_cell_length_c                   5.128
_cell_formula_units_Z            2
_cell_volume                     84.870
_database_code_amcsd             0010607
_exptl_crystal_density_diffrn    4.166
_cod_original_sg_symbol_H-M      'R -3 c'
_cod_original_formula_sum        '(Al1.82 Cr.18) O3'
_cod_database_code               9008094
Strukturuntersuchungen im system Al2O3-Cr2O3
Saalfeld, H.; Zeitschrift fur Kristallographie 120 (1964) 342–348; doi:

data_9008095
_publ_section_title
;
 Strukturuntersuchungen im system Al2O3-Cr2O3
;
_journal_name_full               'Zeitschrift fur Kristallographie '
_journal_page_first              342
_journal_page_last               348
_journal_volume                  120
_journal_year                    1964
_chemical_formula_sum            'Cr2 O3'
_chemical_name_mineral           Eskolaite
_space_group_IT_number           167
_symmetry_space_group_name_Hall  '-P 3* 2n'
_symmetry_space_group_name_H-M   'R -3 c :R'
_cell_angle_alpha                55.13
_cell_angle_beta                 55.13
_cell_angle_gamma                55.13
_cell_length_a                   5.359
_cell_length_b                   5.359
_cell_length_c                   5.359
_cell_formula_units_Z            2
_cell_volume                     96.502
_database_code_amcsd             0010608
_exptl_crystal_density_diffrn    5.231
_cod_original_sg_symbol_H-M      'R -3 c'
_cod_database_code               9008095
Strukturdaten von gahnit, ZnAl2O4
Saalfeld, H.; Zeitschrift fur Kristallographie 120 (1964) 476–478; doi:

data_9008096
_publ_section_title
;
 Strukturdaten von gahnit, ZnAl2O4
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              476
_journal_page_last               478
_journal_volume                  120
_journal_year                    1964
_chemical_compound_source        'Falun, Sweden'
_chemical_formula_sum            'Al1.9 Fe0.075 Mg0.235 O4 Zn0.79'
_chemical_name_mineral           Gahnite
_space_group_IT_number           227
_symmetry_space_group_name_Hall  'F 4d 2 3 -1d'
_symmetry_space_group_name_H-M   'F d -3 m :1'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   8.099
_cell_length_b                   8.099
_cell_length_c                   8.099
_cell_volume                     531.244
_database_code_amcsd             0010609
_exptl_crystal_density_diffrn    4.422
_cod_original_sg_symbol_H-M      'F d 3 m'
_cod_original_formula_sum        'Zn.79 Mg.235 Al1.9 Fe.075 O4'
_cod_database_code               9008096
The crystal structure of arsenic triiodide, AsI3
Trotter, J.; Zeitschrift fur Kristallographie 121 (1965) 81–86; doi:

data_9008097
_publ_section_title
;
 The crystal structure of arsenic triiodide, AsI3
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              81
_journal_page_last               86
_journal_volume                  121
_journal_year                    1965
_chemical_formula_structural     AsI3
_chemical_formula_sum            'As I3'
_space_group_IT_number           148
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_length_a                   7.208
_cell_length_b                   7.208
_cell_length_c                   21.436
_cell_formula_units_Z            6
_cell_volume                     964.504
_database_code_amcsd             0010610
_exptl_crystal_density_diffrn    4.707
_cod_original_sg_symbol_H-M      'R -3'
_cod_database_code               9008097
_amcsd_formula_title             AsI3
The crystal structure of arsenic triiodide, AsI3
Trotter, J.; Zeitschrift fur Kristallographie 121 (1965) 81–86; doi:

data_9008098
_publ_section_title
;
 The crystal structure of arsenic triiodide, AsI3
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              81
_journal_page_last               86
_journal_volume                  121
_journal_year                    1965
_chemical_formula_structural     AsI3
_chemical_formula_sum            'As I3'
_space_group_IT_number           148
_symmetry_space_group_name_Hall  '-P 3*'
_symmetry_space_group_name_H-M   'R -3 :R'
_cell_angle_alpha                51.683
_cell_angle_beta                 51.683
_cell_angle_gamma                51.685
_cell_length_a                   8.269
_cell_length_b                   8.269
_cell_length_c                   8.269
_cell_formula_units_Z            2
_cell_volume                     321.561
_database_code_amcsd             0010611
_exptl_crystal_density_diffrn    4.706
_cod_original_cell_volume        321.562
_cod_original_sg_symbol_H-M      'R -3'
_cod_database_code               9008098
_amcsd_formula_title             AsI3
Determination and refinement of the crystal structure of turquois, CuAl6(PO4)4(OH)8*4H2O Locality: Virginia, USA
Cid-Dresdner H; Zeitschrift fur Kristallographie 121 (1965) 87–113; doi:10.1524/zkri.1965.121.2-4.87

data_9008099
_publ_section_title
;Determination and refinement of the crystal structure of turquois,
 CuAl6(PO4)4(OH)8*4H2O Locality: Virginia, USA
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              87
_journal_page_last               113
_journal_paper_doi               10.1524/zkri.1965.121.2-4.87
_journal_volume                  121
_journal_year                    1965
_chemical_compound_source        'Virginia, USA'
_chemical_formula_sum            'Al6 Cu H16 O28 P4'
_chemical_name_mineral           Turquoise
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                68.61
_cell_angle_beta                 69.71
_cell_angle_gamma                65.08
_cell_length_a                   7.424
_cell_length_b                   7.629
_cell_length_c                   9.910
_cell_formula_units_Z            1
_cell_volume                     461.403
_database_code_amcsd             0010612
_exptl_crystal_density_diffrn    2.927
_cod_original_formula_sum        'Cu P4 Al6 O28 H16'
_cod_database_code               9008099
Die struktur von Na2S*9H2O und Na2Se*9H2O
Bedlivy, D.; Preisinger, A.; Zeitschrift fur Kristallographie 121 (1965) 114–130; doi:

data_9008100
_publ_section_title
;
 Die struktur von Na2S*9H2O und Na2Se*9H2O
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              114
_journal_page_last               130
_journal_volume                  121
_journal_year                    1965
_chemical_formula_structural     Na2S*9H2O
_chemical_formula_sum            'H18 Na2 O9 S'
_space_group_IT_number           95
_symmetry_space_group_name_Hall  'P 4cw 2c'
_symmetry_space_group_name_H-M   'P 43 2 2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   9.331
_cell_length_b                   9.331
_cell_length_c                   12.850
_cell_volume                     1118.818
_cell_formula_units_Z            4
_cod_depositor_comments
;
    Z value inserted to be consistent with given formula
    Renamed water oxygens so that they are recognized as oxygens.
                               miguel
;
_exptl_crystal_density_diffrn    1.426
_cod_original_formula_sum        'Na2 S (O9 H18)'
_cod_database_code               9008100
_database_code_amcsd 0010613
Die struktur von Na2S*9H2O und Na2Se*9H2O
Bedlivy, D.; Preisinger, A.; Zeitschrift fur Kristallographie 121 (1965) 114–130; doi:

data_9008101
_publ_section_title
;
 Die struktur von Na2S*9H2O und Na2Se*9H2O
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              114
_journal_page_last               130
_journal_volume                  121
_journal_year                    1965
_chemical_formula_structural     Na2Se*9H2O
_chemical_formula_sum            'H18 Na2 O9 Se'
_space_group_IT_number           95
_symmetry_space_group_name_Hall  'P 4cw 2c'
_symmetry_space_group_name_H-M   'P 43 2 2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.496
_cell_length_b                   9.496
_cell_length_c                   13.057
_cell_volume                     1177.402
_database_code_amcsd             0010614
_exptl_crystal_density_diffrn    1.620
_cod_original_formula_sum        'Na2 Se (O9 H18)'
_cod_database_code               9008101
_amcsd_formula_title             Na2Se*9H2O
Die kristallstruktur von Na2S*5H2O, Na2Se*5H2O und Na2Te*5H2O
Bedlivy, D.; Preisinger, A.; Zeitschrift fur Kristallographie 121 (1965) 131–144; doi:

data_9008102
_publ_section_title
;
 Die kristallstruktur von Na2S*5H2O, Na2Se*5H2O und Na2Te*5H2O
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              131
_journal_page_last               144
_journal_volume                  121
_journal_year                    1965
_chemical_formula_structural     Na2S*5H2O
_chemical_formula_sum            'H10 Na2 O5 S'
_space_group_IT_number           63
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   6.475
_cell_length_b                   12.545
_cell_length_c                   8.655
_cell_volume                     703.036
_cell_formula_units_Z            4
_cod_depositor_comments
;
    Z value inserted to be consistent with given formula
    Renamed water oxygens so that they are recognized as oxygens.
                               miguel
;
_exptl_crystal_density_diffrn    1.588
_cod_original_formula_sum        'Na2 S (O5 H10)'
_cod_database_code               9008102
_database_code_amcsd 0010615
Die kristallstruktur von Na2S*5H2O, Na2Se*5H2O und Na2Te*5H2O
Bedlivy, D.; Preisinger, A.; Zeitschrift fur Kristallographie 121 (1965) 131–144; doi:

data_9008103
_publ_section_title
;
 Die kristallstruktur von Na2S*5H2O, Na2Se*5H2O und Na2Te*5H2O
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              131
_journal_page_last               144
_journal_volume                  121
_journal_year                    1965
_chemical_formula_structural     Na2Se(H2O)5
_chemical_formula_sum            'H10 Na2 O5 Se'
_space_group_IT_number           63
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.569
_cell_length_b                   12.873
_cell_length_c                   8.912
_cell_volume                     753.623
_database_code_amcsd             0010616
_exptl_crystal_density_diffrn    1.895
_cod_original_formula_sum        'Na2 Se (O5 H10)'
_cod_database_code               9008103
_amcsd_formula_title             Na2Se(H2O)5
Die kristallstruktur von Na2S*5H2O, Na2Se*5H2O und Na2Te*5H2O
Bedlivy, D.; Preisinger, A.; Zeitschrift fur Kristallographie 121 (1965) 131–144; doi:

data_9008104
_publ_section_title
;
 Die kristallstruktur von Na2S*5H2O, Na2Se*5H2O und Na2Te*5H2O
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              131
_journal_page_last               144
_journal_volume                  121
_journal_year                    1965
_chemical_formula_structural     Na2Te(H2O)5
_chemical_formula_sum            'H10 Na2 O5 Te'
_space_group_IT_number           63
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.735
_cell_length_b                   13.469
_cell_length_c                   9.219
_cell_volume                     836.290
_database_code_amcsd             0010617
_exptl_crystal_density_diffrn    2.094
_cod_original_formula_sum        'Na2 Te (O5 H10)'
_cod_database_code               9008104
_amcsd_formula_title             Na2Te(H2O)5
A neutron crystallographic investigation of lead molybdenum oxide, PbMoO4
Leciejewicz, J.; Zeitschrift fur Kristallographie 121 (1965) 158–164; doi:

data_9008105
_publ_section_title
;
 A neutron crystallographic investigation of lead molybdenum oxide, PbMoO4
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              158
_journal_page_last               164
_journal_volume                  121
_journal_year                    1965
_chemical_compound_source        'Los Lamentos, Mexico'
_chemical_formula_sum            'Mo O4 Pb'
_chemical_name_mineral           Wulfenite
_space_group_IT_number           88
_symmetry_space_group_name_Hall  '-I 4ad'
_symmetry_space_group_name_H-M   'I 41/a :2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   5.4312
_cell_length_b                   5.4312
_cell_length_c                   12.1065
_cell_formula_units_Z            4
_cell_volume                     357.117
_database_code_amcsd             0010618
_exptl_crystal_density_diffrn    6.829
_cod_original_sg_symbol_H-M      'I 41/a'
_cod_original_formula_sum        'Pb Mo O4'
_cod_database_code               9008105
Refinement of the structure of celestite SrSO4
Garske, D.; Peacor, D. R.; Zeitschrift fur Kristallographie 121 (1965) 204–210; doi:

data_9008106
_publ_section_title
;
 Refinement of the structure of celestite SrSO4
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              204
_journal_page_last               210
_journal_volume                  121
_journal_year                    1965
_chemical_compound_source
'France Stone Company's quarry near Waterville, Ohio, USA'
_chemical_formula_sum            'O4 S Sr'
_chemical_name_mineral           Celestine
_space_group_IT_number           62
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   8.377
_cell_length_b                   5.350
_cell_length_c                   6.873
_cell_formula_units_Z            4
_cell_volume                     308.027
_database_code_amcsd             0010619
_exptl_crystal_density_diffrn    3.961
_cod_original_formula_sum        'Sr S O4'
_cod_database_code               9008106
The crystal structure of taramellite Ba2(Fe,Ti,Mg)2H2(O2(Si4O12))
Mazzi, F.; Rossi, G.; Zeitschrift fur Kristallographie 121 (1965) 243–257; doi:

data_9008107
_publ_section_title
;
 The crystal structure of taramellite Ba2(Fe,Ti,Mg)2H2(O2(Si4O12))
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              243
_journal_page_last               257
_journal_volume                  121
_journal_year                    1965
_chemical_compound_source        'Fresno County, California, USA'
_chemical_formula_sum            'Ba Fe0.5 O7 Si2 Ti0.5'
_chemical_name_mineral           Taramellite
_space_group_IT_number           59
_symmetry_space_group_name_Hall  '-P 2ab 2a'
_symmetry_space_group_name_H-M   'P m m n :2'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   13.95
_cell_length_b                   12.21
_cell_length_c                   7.15
_cell_formula_units_Z            8
_cell_volume                     1217.856
_database_code_amcsd             0010620
_exptl_crystal_density_diffrn    3.898
_cod_original_sg_symbol_H-M      'P m m n'
_cod_original_formula_sum        'Ba (Fe.5 Ti.5) Si2 O7'
_cod_database_code               9008107
The crystal structure of hutchinsonite, (Tl,Pb)2As5S9
Takeuchi, Y.; Ghose, S.; Nowacki, W.; Zeitschrift fur Kristallographie 121 (1965) 321–348; doi:

data_9008108
_publ_section_title
;
 The crystal structure of hutchinsonite, (Tl,Pb)2As5S9
;
_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              321
_journal_page_last               348
_journal_volume                  121
_journal_year                    1965
_chemical_compound_source        'Lengenbach, Binnatal, Valais, Switzerland'
_chemical_formula_sum            'As5 Pb S9 Tl'
_chemical_name_mineral           Hutchinsonite
_space_group_IT_number           61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   10.81
_cell_length_b                   35.36
_cell_length_c                   8.16
_cell_formula_units_Z            8
_cell_volume                     3119.091
_database_code_amcsd             0010621
_exptl_crystal_density_diffrn    4.578
_cod_original_formula_sum        '(Pb Tl) As5 S9'
_cod_database_code               9008108
The crystal structure of dalyite
Fleet, S. G.; Zeitschrift fur Kristallographie 121 (1965) 349–368; doi:10.1524/zkri.1965.121.5.349

data_9008109
_publ_section_title
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 The crystal structure of dalyite
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_journal_name_full               'Zeitschrift fur Kristallographie'
_journal_page_first              349
_journal_page_last               368
_journal_paper_doi               10.1524/zkri.1965.121.5.349
_journal_volume                  121
_journal_year                    1965
_chemical_formula_sum            'K1.7 Na0.3 O15 Si6 Zr'
_chemical_name_mineral           Dalyite
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                106.23
_cell_angle_beta                 111.45
_cell_angle_gamma                100.00
_cell_length_a                   7.371
_cell_length_b                   7.730
_cell_length_c                   6.912
_cell_formula_units_Z            1
_cell_volume                     334.757
_database_code_amcsd             0010622
_exptl_crystal_density_diffrn    2.843
_cod_original_formula_sum        '(K1.7 Na.3) Zr Si6 O15'
_cod_database_code               9008109