Cis–trans isomerization of {RuNO}6-type nitrosylruthenium complexes containing 2-pyridinecarboxylate and structural characterization of a µ-H3O2 bridged dinuclear nitrosylruthenium complex
Hirano, Toshiyuki; Kuroda, Mai; Takeda, Naoko; Hayashi, Mitsunori; Mukaida, Masao; Oi, Takao; Nagao, Hirotaka; Journal of the Chemical Society, Dalton Transactions  (2002) 2158–; doi:10.1039/b200417h

data_7011475
_publ_section_title
;
 Cis--trans isomerization of {RuNO}6-type nitrosylruthenium complexes
 containing 2-pyridinecarboxylate and structural characterization of a
 &#x00B5;-H3O2 bridged dinuclear nitrosylruthenium complex
;
_journal_issue                   10
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2158
_journal_paper_doi               10.1039/b200417h
_journal_year                    2002
_chemical_formula_sum            'C14 H15 N3 O7 Ru'
_chemical_formula_weight         438.36
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                91.963(7)
_cell_angle_beta                 103.913(6)
_cell_angle_gamma                97.687(10)
_cell_formula_units_Z            2
_cell_length_a                   8.120(1)
_cell_length_b                   15.082(3)
_cell_length_c                   7.009(1)
_cell_measurement_reflns_used    5677
_cell_measurement_temperature    173.2
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      3.0
_cell_volume                     823.7(2)
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.020
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            6734
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.995
_exptl_absorpt_correction_T_max  0.844
_exptl_absorpt_correction_T_min  0.694
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.767
_exptl_crystal_description       block
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.170
_refine_diff_density_max         0.46
_refine_diff_density_min         -1.39
_refine_ls_goodness_of_fit_ref   1.444
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     226
_refine_ls_number_reflns         3374
_refine_ls_R_factor_gt           0.0352
_refine_ls_shift/su_max          0.0014
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00250|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0729
_reflns_number_total             3510
_cod_data_source_file            b200417h.txt
_cod_data_source_block           '[Ru(NO)(OCH3)(pyca)2]CH3OH'
_cod_original_cell_volume        823.8(2)
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C14 H15 N3 O7 Ru '
_cod_database_code               7011475