Comparing the reactivity of isomeric phosphinoferrocene nitrile and isocyanide in Pd(ii) complexes: synthesis of simple coordination compounds vs. preparation of P-chelated insertion products and Fischer-type carbenes.
Škoch, Karel; Císařová, Ivana; Uhlík, Filip; Štěpnička, Petr; Dalton transactions (Cambridge, England : 2003) 47 (2018) 16082–16101; doi:10.1039/c8dt03564d

data_7047632
_publ_section_title
;
 Comparing the reactivity of isomeric phosphinoferrocene nitrile and
 isocyanide in Pd(ii) complexes: synthesis of simple coordination
 compounds vs. preparation of P-chelated insertion products and
 Fischer-type carbenes.
;
_journal_issue                   45
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              16082
_journal_page_last               16101
_journal_paper_doi               10.1039/c8dt03564d
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety
;
C40 H35 Fe N O2 P2 Pd, H2 O, 1.5(C4 H8 O2)
;
_chemical_formula_sum            'C46 H49 Fe N O6 P2 Pd'
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_audit_update_record
;
2018-07-23 deposited with the CCDC.
2018-09-21 downloaded from the CCDC.
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0262P)^2^+1.2516P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7047627--7047638.cif.'
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