Catalysis of chlorosilane on the ring-expansion of cyclic acetals bearing a carbene precursor. Lewis acid–base effect on the oxonium ylide intermediate
Mori, Takashi; Oku, Akira; Chemical Communications  (1999) 1339–; doi:10.1039/a903928g

data_7110592
_publ_section_title
;
 Catalysis of chlorosilane on the ring-expansion of cyclic acetals bearing
 a carbene precursor. Lewis acid--base effect on the oxonium ylide
 intermediate
;
_journal_issue                   14
_journal_name_full               'Chemical Communications'
_journal_page_first              1339
_journal_paper_doi               10.1039/a903928g
_journal_year                    1999
_chemical_formula_moiety         'C7 H10 O3 '
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_symmetry_space_group_name_H-M   'P 1 21/a 1'
_cell_angle_alpha                90
_cell_angle_beta                 117.924(3)
_cell_angle_gamma                90
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_cell_length_c                   14.108(2)
_cell_measurement_temperature    296.2
_cell_volume                     721.8(2)
_computing_cell_refinement
;

R-AXIS IV Data Processing Software (Rigaku, 1996)

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_computing_data_collection
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R-AXIS IV Data Processing Software (Rigaku, 1996)

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_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00078|Fo|^2^]'
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