Reactivity of a new aryl cycloplatinated(ii) complex containing rollover 2,2′-bipyridine N-oxide toward a series of diphosphine ligands
Shahsavari, Hamid R.; Babadi Aghakhanpour, Reza; Hossein-Abadi, Mojdeh; Kia, Reza; Halvagar, Mohammad Reza; Raithby, Paul R.; New Journal of Chemistry 42 (2018) 9159–; doi:10.1039/C8NJ00713F

data_7057289
_publ_section_title
;
 Reactivity of a new aryl cycloplatinated(ii) complex containing rollover
 2,2&#x2032;-bipyridine N-oxide toward a series of diphosphine ligands
;
_journal_issue                   11
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              9159
_journal_paper_doi               10.1039/C8NJ00713F
_journal_volume                  42
_journal_year                    2018
_chemical_formula_moiety         'C42 H36 N2 O P2 Pt'
_chemical_formula_sum            'C42 H36 N2 O P2 Pt'
_chemical_formula_weight         841.76
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-04-10 deposited with the CCDC.
2018-04-13 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, EosS2'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_av_R_equivalents  0.0579
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
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_exptl_crystal_description       block
_exptl_crystal_F_000             836
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_refine_diff_density_min         -3.766
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0655P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1032
_refine_ls_wR_factor_ref         0.1043
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6418
_reflns_number_total             6653
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8nj00713f2.cif
_cod_data_source_block           2a
_cod_depositor_comments
'Adding full bibliography for 7057288--7057291.cif.'
_cod_database_code               7057289
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.418
_shelx_estimated_absorpt_t_max   0.620
_shelx_res_checksum              42273