<i>catena</i>-Poly[[[(2-pyridone-κ<i>O</i>)silver(I)]-μ-2-pyridone-κ^2^<i>O</i>:<i>O</i>] hexafluoridophosphate]
Arman, Hadi D.; Miller, Tyler; Tiekink, Edward R. T.; Acta Crystallographica Section E 66 (2010) m1212–; doi:10.1107/S1600536810035348

data_2227521
_publ_section_title
;
 <i>catena</i>-Poly[[[(2-pyridone-\k<i>O</i>)silver(I)]-\m-2-pyridone-\k^2^<i>O</i>:<i>O</i>]
 hexafluoridophosphate]
;
_journal_coeditor_code           HB5626
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1212
_journal_paper_doi               10.1107/S1600536810035348
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Ag (C5 H5 N O)2] P F6'
_chemical_formula_moiety         'C20 H20 Ag N4 O4 +, F6 P -'
_chemical_formula_sum            'C20 H20 Ag F6 N4 O4 P'
_chemical_formula_weight         633.24
_chemical_name_systematic
;
<i>catena</i>-Poly[[[(2-pyridone-\k<i>O</i>)silver(I)]-\m-2-pyridone-
\k^2^<i>O</i>:<i>O</i>] hexafluoridophosphate]
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 96.918(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.519(5)
_cell_length_b                   24.187(9)
_cell_length_c                   7.301(3)
_cell_measurement_reflns_used    4745
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      40.6
_cell_measurement_theta_min      3.1
_cell_volume                     2369.9(16)
_computing_cell_refinement
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_data_collection
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_data_reduction
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku AFC12\K/SATURN724'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.033
_diffrn_reflns_av_sigmaI/netI    0.029
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            8382
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         3.1
_diffrn_standards_decay_%        '< 1'
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.001
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.535
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.775
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1264
_exptl_crystal_size_max          0.48
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.14
_refine_diff_density_max         0.78
_refine_diff_density_min         -0.47
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.14
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     165
_refine_ls_number_reflns         2703
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.14
_refine_ls_R_factor_all          0.033
_refine_ls_R_factor_gt           0.031
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_max_lt       0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.036P)^2^+3.3853P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.078
_refine_ls_wR_factor_ref         0.080
_reflns_number_gt                2573
_reflns_number_total             2703
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb5626.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2227521
_cod_database_fobs_code          2227521