Homolytic cleavage of diboron(4) compounds using diazabutadiene derivatives.
Verma, Piyush Kumar; Meher, Naresh Kumar; Geetharani, K.; Chemical communications (Cambridge, England) 57 (2021) 7886–7889; doi:10.1039/d1cc02881b

data_7128686
_publ_section_title
;
 Homolytic cleavage of diboron(4) compounds using diazabutadiene
 derivatives.
;
_journal_issue                   64
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              7886
_journal_page_last               7889
_journal_paper_doi               10.1039/d1cc02881b
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C38 H42 B2 N2 O4'
_chemical_formula_sum            'C38 H42 B2 N2 O4'
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_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-04-30 deposited with the CCDC.	2021-07-14 downloaded from the CCDC.
;
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_cell_volume                     3491.4(2)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      296(2)
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_diffrn_measurement_device_type  APEX-II
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_diffrn_reflns_theta_min         1.795
_diffrn_source                   'fine focus sealed tube'
_exptl_absorpt_coefficient_mu    0.074
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.165
_exptl_crystal_density_meas      1.16
_exptl_crystal_description       cube
_exptl_crystal_F_000             1304
_exptl_crystal_size_max          0.300
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1430P)^2^+2.9047P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1781
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                3797
_reflns_number_total             5258
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cc02881b2.cif
_cod_data_source_block           shelx_CCDC1
_cod_depositor_comments
'Adding full bibliography for 7128685--7128687.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7128686
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.000
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_shelx_res_checksum              97427