Bis(formylpyrrolyl) cobalt complexes as mediators in the reversible-deactivation radical polymerization of styrene and methyl methacrylate
Cruz, Tiago F. C.; Machado, Pedro M. M.; Gomes, Clara S. B.; Ascenso, José R.; Lemos, M. Amélia N. D. A.; Bordado, João C.; Gomes, Pedro T.; New Journal of Chemistry 42 (2018) 5900–; doi:10.1039/C8NJ00350E

data_7057071
_publ_section_title
;
 Bis(formylpyrrolyl) cobalt complexes as mediators in the
 reversible-deactivation radical polymerization of styrene and methyl
 methacrylate
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              5900
_journal_paper_doi               10.1039/C8NJ00350E
_journal_volume                  42
_journal_year                    2018
_chemical_formula_moiety         'C16 H26 Co N2 O2 P2, Br,H2 O'
_chemical_formula_sum            'C16 H28 Br Co N2 O3 P2'
_chemical_formula_weight         497.18
_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/1
_audit_update_record
;
2018-02-19 deposited with the CCDC.
2018-02-27 downloaded from the CCDC.
;
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_diffrn_source                   'fine-focus sealed tube'
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;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.366(14)
_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0200P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0584
_refine_ls_wR_factor_ref         0.0625
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_reflns_number_gt                3124
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_cod_depositor_comments
'Adding full bibliography for 7057071--7057073.cif.'
_cod_original_cell_volume        2150.6(8)
_cod_database_code               7057071
_shelx_shelxl_version_number     2018/1
_shelx_estimated_absorpt_t_min   0.728
_shelx_estimated_absorpt_t_max   0.896
_shelx_res_checksum              68034