Dinuclear Nickel(II) Complexes of an Unsymmetric "End-Off" Compartmental Ligand: Conversion of Urea into Cyanate at a Dinuclear Nickel Core
Syunsuke Uozumi; Hideki Furutachi; Masaaki Ohba; Hisashi Ōkawa; David E. Fenton; Kenji Shindo; Susumu Murata; David J. Kitko; Inorganic Chemistry 37 (1998) 6281–6287; doi:10.1021/ic9807689

data_4323192
_publ_section_title
;
 Dinuclear Nickel(II) Complexes of an Unsymmetric "End-Off" Compartmental
 Ligand: Conversion of Urea into Cyanate at a Dinuclear Nickel Core
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6281
_journal_page_last               6287
_journal_paper_doi               10.1021/ic9807689
_journal_volume                  37
_journal_year                    1998
_chemical_formula_sum            'C53 H76 F12 N10 Ni4 O12 P2'
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      60
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_audit_creation_date             'Mon Feb 23 15:18:17 1998'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8.00
_cell_length_a                   19.056(5)
_cell_length_b                   18.997(4)
_cell_length_c                   19.919(6)
_cell_measurement_reflns_used    23
_cell_measurement_temperature    23.0
_cell_measurement_theta_max      29.98
_cell_measurement_theta_min      29.68
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_computing_cell_refinement       'MSC/AFC Diffractometer Control'
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_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
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_diffrn_ambient_temperature      23.0
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
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_diffrn_orient_matrix_UB_12      -0.05067
_diffrn_orient_matrix_UB_13      -0.00963
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_diffrn_orient_matrix_UB_32      -0.00049
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_diffrn_radiation_monochromator  graphite
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_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.831
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            green
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_refine_ls_structure_factor_coef F
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_cod_data_source_file            ic9807689_3.cif
_cod_data_source_block           '[{Ni2(L)(OH)(MeOH)}2(CO3)](PF6)2'
_cod_original_cell_volume        7211(5)
_cod_original_sg_symbol_H-M      'P b c n '
_cod_original_formula_sum        'C53 H76 O12 N10 P2 F12 Ni4'
_cod_database_code               4323192