Prototypical Phosphine Complexes of Antimony(III).
Chitnis, Saurabh S.; Burford, Neil; McDonald, Robert; Ferguson, Michael J.; Inorganic chemistry 53 (2014) 5359–5372; doi:10.1021/ic500723y

data_4338244
_publ_section_title
;
 Prototypical Phosphine Complexes of Antimony(III).
;
_journal_issue                   10
_journal_name_full               'Inorganic chemistry'
_journal_page_first              5359
_journal_page_last               5372
_journal_paper_doi               10.1021/ic500723y
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety         'C3 H9 Cl3 P Sb'
_chemical_formula_sum            'C3 H9 Cl3 P Sb'
_chemical_formula_weight         304.17
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
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_cell_angle_gamma                90.00
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_cell_length_a                   7.9261(11)
_cell_length_b                   19.089(3)
_cell_length_c                   13.1115(18)
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_cell_measurement_temperature    173(2)
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_cell_measurement_theta_min      2.66
_cell_volume                     1948.3(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
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_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXD (Schneider & Sheldrick, 2002)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
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_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15231
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_diffrn_reflns_theta_max         27.57
_diffrn_reflns_theta_min         1.91
_exptl_absorpt_coefficient_mu    3.738
_exptl_absorpt_correction_T_max  0.8236
_exptl_absorpt_correction_T_min  0.3579
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.074
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
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_exptl_crystal_size_max          0.35
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_refine_diff_density_max         0.473
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     151
_refine_ls_number_reflns         4446
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_gt           0.0259
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0174P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0476
_refine_ls_wR_factor_ref         0.0513
_reflns_number_gt                3667
_reflns_number_total             4446
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            ic500723y_si_009.cif
_cod_data_source_block           vic1315
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4338238--4338252.cif.
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4338244