Diastereoselective Simmons-Smith cyclopropanations of allylic amines and carbamates.
Davies, Stephen G; Ling, Kenneth B; Roberts, Paul M; Russell, Angela J; Thomson, James E; Chemical communications (Cambridge, England)  (2007) 4029–4031; doi:10.1039/b711358g

data_7102175
_publ_section_title
;
 Diastereoselective Simmons-Smith cyclopropanations of allylic amines
 and carbamates.
;
_journal_issue                   39
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              4029
_journal_page_last               4031
_journal_paper_doi               10.1039/b711358g
_journal_year                    2007
_chemical_formula_moiety         'C15 H15 N1 O2'
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_cell_angle_gamma                90
_cell_formula_units_Z            2
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_cell_length_b                   7.0349(3)
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_cell_measurement_temperature    190
_cell_measurement_theta_max      27
_cell_measurement_theta_min      5
_cell_volume                     604.10(4)
_computing_cell_refinement       'DENZO/SCALEPACK (Otwinowski & Minor, 1997)'
_computing_data_collection       'COLLECT. Nonius (1997-2001).'
_computing_data_reduction        'DENZO/SCALEPACK (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'CAMERON (Watkin et al., 1996)'
_computing_publication_material  'CRYSTALS (Betteridge et al., 2003)'
_computing_structure_refinement  'CRYSTALS (Betteridge et al., 2003)'
_computing_structure_solution    'SIR92 (Altomare et al., 1994)'
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_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
w=1/[\s^2^(F^2^) + ( 0.04P)^2^ + 1.06P]
where P=(max(Fo^2^,0) + 2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.2144
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_refine_ls_wR_factor_ref         0.2144
_reflns_limit_h_max              10
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_cod_original_sg_symbol_H-M      'P 21/m'
_cod_original_formula_sum        'C15 H15 N1 O2'
_cod_database_code               7102175