Dehydropolymerisation of methylamine borane using highly active rhodium(iii) bis(thiophosphinite) pincer complexes: catalytic and mechanistic insights
Hasche, Patrick; Haak, Julia; Anke, Felix; Kubis, Christoph; Baumann, Wolfgang; Drexler, Hans-Joachim; Jiao, Haijun; Beweries, Torsten; Catalysis Science & Technology 11 (2021) 3514–3526; doi:10.1039/D1CY00124H

data_1561514
_publ_section_title
;
 Dehydropolymerisation of methylamine borane using highly active
 rhodium(iii) bis(thiophosphinite) pincer complexes: catalytic and
 mechanistic insights
;
_journal_issue                   10
_journal_name_full               'Catalysis Science &amp; Technology'
_journal_page_first              3514
_journal_page_last               3526
_journal_paper_doi               10.1039/D1CY00124H
_journal_volume                  11
_journal_year                    2021
_chemical_formula_sum            'C18 H32 Cl P2 Rh S2'
_chemical_formula_weight         512.85
_chemical_properties_physical
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2020-01-21 deposited with the CCDC.	2021-03-30 downloaded from the CCDC.
;
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_cell_volume                     2278.00(16)
_computing_cell_refinement       'SAINT (Bruker, 2013)'
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_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_diffrn_reflns_limit_l_min       -23
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_exptl_crystal_colour            orange
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_exptl_crystal_description       'part of prism'
_exptl_crystal_F_000             1056
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0277P)^2^+1.9633P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0582
_refine_ls_wR_factor_ref         0.0619
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5657
_reflns_number_total             6390
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cy00124h2.cif
_cod_data_source_block           AX1722abs
_cod_depositor_comments
'Adding full bibliography for 1561513--1561515.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
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_shelx_res_checksum              20700