Synthesis of 3,3'-Diaryl-Substituted 2,2'-Diamino-1,1'-binaphthyl and Its Derivatives
Masahiro Yoshimura; Toshimitsu Muraoka; Hiroshi Nakatsuka; Hanmin Huang; Masato Kitamura; Journal of Organic Chemistry 75 (2010) 4315–4318; doi:10.1021/jo100638j

data_4025495
_publ_section_title
;
 Synthesis of 3,3'-Diaryl-Substituted 2,2'-Diamino-1,1'-binaphthyl and Its
 Derivatives
;
_journal_name_full               'Journal of Organic Chemistry'
_journal_page_first              4315
_journal_page_last               4318
_journal_paper_doi               10.1021/jo100638j
_journal_volume                  75
_journal_year                    2010
_chemical_formula_moiety         'C32 H24 N2 '
_chemical_formula_sum            'C32 H24 N2'
_chemical_formula_weight         436.55
_space_group_IT_number           73
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      73
_symmetry_space_group_name_Hall  '-I 2b 2c'
_symmetry_space_group_name_H-M   'I b c a'
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_formula_units_Z            8
_cell_length_a                   6.790(14)
_cell_length_b                   20.97(5)
_cell_length_c                   35.56(9)
_cell_measurement_reflns_used    99
_cell_measurement_temperature    173.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      5.7
_cell_volume                     5063(2)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.940
_diffrn_measured_fraction_theta_max 0.940
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.032
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -46
_diffrn_reflns_number            8525
_diffrn_reflns_theta_full        27.44
_diffrn_reflns_theta_max         27.44
_exptl_absorpt_coefficient_mu    0.067
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.145
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1840.00
_exptl_crystal_size_max          1.00
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.57
_refine_diff_density_min         -0.77
_refine_ls_extinction_coef       -40(2)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   5.230
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     175
_refine_ls_number_reflns         4856
_refine_ls_R_factor_gt           0.0790
_refine_ls_shift/su_max          4.5210
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/\s^2^(Fo)'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0620
_reflns_number_gt                1711
_reflns_number_total             2728
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            jo100638j_si_002.cif
_cod_data_source_block           '__racemic-ph-BINAINe'
_cod_original_cell_volume        5063(21)
_cod_original_sg_symbol_Hall     '-I 2b 2b'
_cod_original_sg_symbol_H-M      'I c m a'
_cod_original_formula_sum        'C32 H24 N2 '
_cod_database_code               4025495