Bridged poly(1-imidazolyl)borate silver(I) complexes containing tertiary mono(phosphine) ligands. The first structurally authenticated bis(imidazolyl)borate metal complex †
Gioia Lobbia, Giancarlo; Pellei, Maura; Pettinari, Claudio; Santini, Carlo; Skelton, Brian W.; White, Allan H.; Journal of the Chemical Society, Dalton Transactions  (2001) 528–; doi:10.1039/b008135n

data_7010348
_publ_section_title
;
 Bridged poly(1-imidazolyl)borate silver(I) complexes containing
 tertiary mono(phosphine) ligands. The first structurally authenticated
 bis(imidazolyl)borate metal complex&#x200A;&#x2020;
;
_journal_issue                   5
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              528
_journal_paper_doi               10.1039/b008135n
_journal_year                    2001
_chemical_formula_sum            'C98 H102 Ag2 B2 Cl6 N8 P4'
_chemical_formula_weight         1965.92
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                76.5380(10)
_cell_angle_beta                 87.0050(10)
_cell_angle_gamma                72.3830(10)
_cell_formula_units_Z            1
_cell_length_a                   11.5870(10)
_cell_length_b                   14.0740(10)
_cell_length_c                   16.4250(10)
_cell_measurement_reflns_used    8192
_cell_measurement_temperature    293
_cell_measurement_theta_max      27.2
_cell_measurement_theta_min      2
_cell_volume                     2482.3(3)
_computing_cell_refinement       'Siemens SAINT (Siemens, 1995)'
_computing_data_collection       'Siemens SMART (Siemens, 1995)'
_computing_data_reduction        'xtal ADDREF'
_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  'xtal CRYLSQ'
_computing_structure_solution    xtal
_diffrn_ambient_temperature      293
_diffrn_measurement_device_type
;
Bruker SMART CCD diffractometer
;
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_detector       'CCD area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .014
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            23998
_diffrn_reflns_theta_max         29.19
_diffrn_reflns_theta_min         1.28
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    .668
_exptl_absorpt_correction_T_max  .89
_exptl_absorpt_correction_T_min  .74
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS; Sheldrick, 1996
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.315
_exptl_crystal_description       blcok
_exptl_crystal_F_000             1012
_exptl_crystal_size_max          .56
_exptl_crystal_size_mid          .4
_exptl_crystal_size_min          .23
_refine_diff_density_max         .806
_refine_diff_density_min         -.727
_refine_ls_goodness_of_fit_all   1.599
_refine_ls_goodness_of_fit_ref   1.783
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     541
_refine_ls_number_reflns         9008
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .059
_refine_ls_R_factor_gt           .041
_refine_ls_shift/su_max          .07
_refine_ls_shift/su_mean         .002
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         .053
_refine_ls_wR_factor_ref         .051
_reflns_d_resolution_high        .729
_reflns_d_resolution_low         15.971
_reflns_limit_h_max              15
_reflns_limit_h_min              0
_reflns_limit_k_max              19
_reflns_limit_k_min              -17
_reflns_limit_l_max              22
_reflns_limit_l_min              -21
_reflns_number_gt                9008
_reflns_number_total             11918
_reflns_threshold_expression     'F    > 4.00 sig(F   )'
_cod_data_source_file            b008135n.txt
_cod_data_source_block           imptol
_cod_original_sg_symbol_Hall     -p_1
_cod_original_sg_symbol_H-M      P_-1
_cod_database_code               7010348