Ethylene-Triggered Regioselectivity Switch of Dimethylbutadiene in Their Copolymerization: Formation of “Plastic” Rubber and Mechanism
Huang, Lixian; Liu, Zhaohe; Zhang, Yixin; Wu, Chunji; Cui, Dongmei; ACS Catalysis  (2021) 953–962; doi:10.1021/acscatal.1c04976

data_4519228
_publ_section_title
;
 Ethylene-Triggered Regioselectivity Switch of Dimethylbutadiene in Their
 Copolymerization: Formation of &#x201C;Plastic&#x201D; Rubber and
 Mechanism
;
_journal_name_full               'ACS Catalysis'
_journal_page_first              953
_journal_page_last               962
_journal_paper_doi               10.1021/acscatal.1c04976
_journal_year                    2021
_chemical_formula_sum            'C26 H40 N Sc Si2'
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_computing_structure_refinement  'Bruker SHELXTL'
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_diffrn_ambient_temperature      153(2)
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_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
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_exptl_absorpt_coefficient_mu    0.365
_exptl_absorpt_correction_type   none
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_exptl_crystal_description       block
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0854P)^2^+0.3369P] where P=(Fo^2^+2Fc^2^)/3'
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