Divergent Approach to Thiazolylidene Derivatives: A Perspective on the Synthesis of a Heterocyclic Skeleton from β-Amidothioamides Reactivity.
Santeusanio, Stefania; Majer, Roberta; Perrulli, Francesca Romana; De Crescentini, Lucia; Favi, Gianfranco; Giorgi, Gianluca; Mantellini, Fabio; The Journal of organic chemistry 82 (2017) 9773–9778; doi:10.1021/acs.joc.7b02135

data_4033065
_publ_section_title
;
 Divergent Approach to Thiazolylidene Derivatives: A Perspective on the
 Synthesis of a Heterocyclic Skeleton from \b-Amidothioamides Reactivity.
;
_journal_issue                   18
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              9773
_journal_page_last               9778
_journal_paper_doi               10.1021/acs.joc.7b02135
_journal_volume                  82
_journal_year                    2017
_chemical_formula_moiety         'C18 H16 N4 O8 S, C H4 O'
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;
(Z)-ethyl 3-((methoxycarbonyl)amino)-4-methyl-2-(3-(4-nitrophenyl)-
5-oxoisoxazol-4(5H)-ylidene)-2,3-dihydrothiazole-5-carboxylate 
compound with methanol (1:1)
;
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CrysAlisPro, Oxford Diffraction Ltd.,
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            'pale yellow'
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'w=1/[\s^2^(Fo^2^)+(0.0618P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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