Construction of a series of lanthanide metal‒organic frameworks: synthesis, structure, luminescence and white light emission
Shen, Lanlan; Yang, Lu; Fan, Yong; Wang, Li; Xu, Jianing; CrystEngComm 17 (2015) 9363–; doi:10.1039/C5CE01718A

data_7223146
_publ_section_title
;
 Construction of a series of lanthanide metal--organic frameworks:
 synthesis, structure, luminescence and white light emission
;
_journal_issue                   48
_journal_name_full               CrystEngComm
_journal_page_first              9363
_journal_paper_doi               10.1039/C5CE01718A
_journal_volume                  17
_journal_year                    2015
_chemical_formula_sum            'C21 H21 N3 O21 Tb2'
_chemical_formula_weight         969.27
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-08-21 deposited with the CCDC.
2015-11-04 downloaded from the CCDC.
;
_cell_angle_alpha                90.16(3)
_cell_angle_beta                 111.68(3)
_cell_angle_gamma                89.29(3)
_cell_formula_units_Z            4
_cell_length_a                   9.5570(19)
_cell_length_b                   13.361(3)
_cell_length_c                   23.414(6)
_cell_measurement_temperature    293(2)
_cell_volume                     2778.0(12)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0391
_diffrn_reflns_av_sigmaI/netI    0.0410
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            15435
_diffrn_reflns_theta_full        25.15
_diffrn_reflns_theta_max         25.15
_diffrn_reflns_theta_min         1.79
_exptl_absorpt_coefficient_mu    5.154
_exptl_absorpt_correction_T_max  0.6267
_exptl_absorpt_correction_T_min  0.6267
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS,1997
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.317
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1864
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.996
_refine_diff_density_min         -1.508
_refine_diff_density_rms         0.157
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     472
_refine_ls_number_reflns         4908
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.044
_refine_ls_R_factor_all          0.0315
_refine_ls_R_factor_gt           0.0263
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0360P)^2^+2.6010P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0659
_refine_ls_wR_factor_ref         0.0692
_reflns_number_gt                4355
_reflns_number_total             4908
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5ce01718a2.cif
_cod_data_source_block           s
_cod_depositor_comments
'Adding full bibliography for 7223145--7223147.cif.'
_cod_original_cell_volume        2778.0(11)
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7223146