Synthesis, structure, and reactivity of a pyridine-stabilized silanonetungsten complex.
Muraoka, Takako; Tsuchimoto, Masato; Ueno, Keiji; Dalton transactions (Cambridge, England : 2003) 49 (2020) 5100–5107; doi:10.1039/d0dt00497a

data_7703864
_publ_section_title
;
 Synthesis, structure, and reactivity of a pyridine-stabilized
 silanonetungsten complex.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5100
_journal_page_last               5107
_journal_paper_doi               10.1039/d0dt00497a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C36 H55 O3 P Si2 W'
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;
2019-08-06 deposited with the CCDC.	2020-03-05 downloaded from the CCDC.
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CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)
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_computing_data_collection
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CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)
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CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)
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Rigaku Pilatus 200K
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;
 Flack x determined using 3184 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   0.000(5)
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0217P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_refine_ls_wR_factor_ref         0.0654
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_reflns_number_gt                7579
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_cod_data_source_file            d0dt00497a2.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7703862--7703864.cif.
;
_cod_original_cell_volume        7434.2(12)
_cod_database_code               7703864
_shelxl_version_number           2013-4
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