A novel CdII-based metal‒organic framework as a multi-responsive luminescent sensor for Fe3+, MnO4−, Cr2O72−, salicylaldehyde and ethylenediamine detection with high selectivity and sensitivity
Wu, Lin-Hui; Yao, Shu-Li; Li, Jing; Xu, Hui; Zheng, Teng-Fei; Liu, Sui-Jun; Chen, Jing-Lin; Wen, He-Rui; CrystEngComm 23 (2021) 482–491; doi:10.1039/D0CE01575J

data_7241447
_publ_section_title
;
 A novel CdII-based metal--organic framework as a multi-responsive
 luminescent sensor for Fe3+, MnO4&#x2212;, Cr2O72&#x2212;,
 salicylaldehyde and ethylenediamine detection with high selectivity and
 sensitivity
;
_journal_issue                   2
_journal_name_full               CrystEngComm
_journal_page_first              482
_journal_page_last               491
_journal_paper_doi               10.1039/D0CE01575J
_journal_volume                  23
_journal_year                    2021
_chemical_formula_sum            'C33 H31 Cd N5 O5'
_chemical_formula_weight         690.04
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2020-08-20 deposited with the CCDC.	2020-11-19 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_cell_length_c                   13.2675(9)
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_cell_measurement_theta_min      2.87
_cell_volume                     3068.2(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0489
_diffrn_reflns_av_unetI/netI     0.0325
_diffrn_reflns_Laue_measured_fraction_full 0.999
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_diffrn_reflns_limit_h_min       -12
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_reflns_theta_max         25.009
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_exptl_absorpt_coefficient_mu    0.761
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
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_exptl_crystal_description       block
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_refine_diff_density_max         1.215
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0636
_refine_ls_R_factor_gt           0.0533
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0396P)^2^+15.6589P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1207
_refine_ls_wR_factor_ref         0.1268
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4684
_reflns_number_total             5393
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0ce01575j2.cif
_cod_data_source_block           WLH38_a
_cod_depositor_comments
'Adding full bibliography for 7241447--7241448.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7241447
_shelx_shelxl_version_number     2017/1
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