Alkylzinc diorganophosphates: synthesis, structural diversity and unique ability to incorporate zincoxane units.
Wolska-Pietkiewicz, Małgorzata; Swierkosz, Adam; Justyniak, Iwona; Grala, Agnieszka; Sokołowski, Kamil; Lewiński, Janusz; Dalton transactions (Cambridge, England : 2003) 45 (2016) 18813–18816; doi:10.1039/c6dt03324e

data_7040979
_publ_section_title
;
 Alkylzinc diorganophosphates: synthesis, structural diversity and unique
 ability to incorporate zincoxane units.
;
_journal_issue                   47
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18813
_journal_page_last               18816
_journal_paper_doi               10.1039/c6dt03324e
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C27.5 H64 O16 P4 Zn4'
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_space_group_name_Hall           '-P 1'
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_audit_update_record
;
2016-08-18 deposited with the CCDC.
2016-10-19 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.962
_diffrn_measured_fraction_theta_max 0.960
_diffrn_measurement_device_type  'Nonius Kappa-CCD'
_diffrn_measurement_method       'area detector \w scans'
_diffrn_radiation_source         'fine-focus sealed tube'
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_diffrn_radiation_wavelength     0.71073
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_exptl_absorpt_process_details   'Scalepak (Otwinowski, Minor, 1997)'
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.077
_refine_ls_R_factor_all          0.0457
_refine_ls_R_factor_gt           0.0399
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0331P)^2^+9.4968P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0948
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_reflns_number_gt                17951
_reflns_number_total             19914
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt03324e2.cif
_cod_data_source_block           shelx_comp2
_cod_depositor_comments
'Adding full bibliography for 7040978--7040981.cif.'
_cod_database_code               7040979
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