Cerium(iv) complexes with guanidinate ligands: intense colors and anomalous electronic structures.
Qiao, Yusen; Yin, Haolin; Moreau, Liane M.; Feng, Rulin; Higgins, Robert F.; Manor, Brian C.; Carroll, Patrick J.; Booth, Corwin H.; Autschbach, Jochen; Schelter, Eric J.; Chemical science 12 (2020) 3558–3567; doi:10.1039/d0sc05193d

data_1559748
_publ_section_title
;
 Cerium(iv) complexes with guanidinate ligands: intense colors and
 anomalous electronic structures.
;
_journal_issue                   10
_journal_name_full               'Chemical science'
_journal_page_first              3558
_journal_page_last               3567
_journal_paper_doi               10.1039/d0sc05193d
_journal_volume                  12
_journal_year                    2020
_chemical_formula_moiety         'C32 H82 Ce N7 Si6, C32 H12 B F24'
_chemical_formula_sum            'C64 H94 B Ce F24 N7 Si6'
_chemical_formula_weight         1736.93
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
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;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2020-10-23 deposited with the CCDC.	2020-12-09 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0699P)^2^+37.0141P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0sc05193d2.cif
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_cod_depositor_comments
;Adding full bibliography for 1559747--1559748.cif.

 Adding full bibliography for 1559747--1559748.cif.
;
_cod_original_cell_volume        9038.9(14)
_cod_database_code               1559748
_shelx_shelxl_version_number     2018/3