Olefin Substitution in (silox)3M(olefin) (silox =tBu3SiO; M = Nb, Ta): The Role of Density of States in Second vs Third Row Transition Metal Reactivity
Kurt F. Hirsekorn; Elliott B. Hulley; Peter T. Wolczanski; Thomas R. Cundari; Journal of the American Chemical Society 130 (2008) 1183–1196; doi:10.1021/ja074972j

data_4107342
_publ_section_title
;
 Olefin Substitution in (silox)3M(olefin) (silox =tBu3SiO; M = Nb, Ta):
 The Role of Density of States in Second vs Third Row Transition Metal
 Reactivity
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              1183
_journal_page_last               1196
_journal_paper_doi               10.1021/ja074972j
_journal_volume                  130
_journal_year                    2008
_chemical_formula_sum            'C38 H85 Nb O3 Si3'
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_chemical_name_systematic
; 
 ? 
;
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
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