Rhodium(III)-Catalyzed Activation and Functionalization of Pyridine C‒H Bond by Exploring a Unique Double Role of “N-Heterocyclic Carbene‒Pyridyl” Ligand Platform
Thenarukandiyil, Ranjeesh; Choudhury, Joyanta; Organometallics 34 (2015) 1890–; doi:10.1021/acs.organomet.5b00157

data_4085866
_publ_section_title
;
 Rhodium(III)-Catalyzed Activation and Functionalization of Pyridine C--H
 Bond by Exploring a Unique Double Role of &#x201C;N-Heterocyclic
 Carbene--Pyridyl&#x201D; Ligand Platform
;
_journal_issue                   10
_journal_name_full               Organometallics
_journal_page_first              1890
_journal_paper_doi               10.1021/acs.organomet.5b00157
_journal_volume                  34
_journal_year                    2015
_chemical_formula_sum            'C70 H66 Cl2 F12 N6 O12 Rh2 S4'
_chemical_formula_weight         1816.24
_chemical_name_systematic
;
 ?
;
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_diffrn_measured_fraction_theta_full 0.908
_diffrn_measured_fraction_theta_max 1.000
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_diffrn_reflns_theta_min         1.664
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    0.675
_exptl_absorpt_process_details   SADABS
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_exptl_crystal_description       rectangular
_exptl_crystal_F_000             1840
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.2690
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1442P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.3422
_reflns_Friedel_coverage         0.000
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_reflns_number_total             6547
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            om5b00157_si_002.cif
_cod_data_source_block           t2
_cod_depositor_comments
'Adding full bibliography for 4085861--4085866.cif.'
_cod_database_code               4085866
_shelx_estimated_absorpt_t_min   0.871
_shelx_estimated_absorpt_t_max   0.936
_shelxl_version_number           2014-3
_shelx_res_checksum              89088
_shelx_hkl_checksum              42537