Carbonyl-κ<i>C</i>-[tris(diphenylphosphinoyl)methanido-κ^2^<i>O</i>,<i>O</i>'][tris(<i>o</i>-tolyl)phosphine-κ<i>P</i>]rhodium(I), [Rh(C{P(O)Ph~2~}~3~)(CO){P(<i>o</i>-Tol)~3~}]
Smit, D. M. C.; Basson, S. S.; Roodt, A.; Steynberg, E. C.; Acta Crystallographica Section C 51 (1995) 1278–1280; doi:10.1107/S0108270195000515

data_2003704
_publ_section_title
;Carbonyl-\k<i>C</i>-[tris(diphenylphosphinoyl)methanido-\k^2^<i>O</i>,<i>O</i>'][tris(<i>o</i>-tolyl)phosphine-\k<i>P</i>]rhodium(I),
 [Rh(C{P(O)Ph~2~}~3~)(CO){P(<i>o</i>-Tol)~3~}]
;
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1278
_journal_page_last               1280
_journal_paper_doi               10.1107/S0108270195000515
_journal_volume                  51
_journal_year                    1995
_chemical_compound_source        'see text'
_chemical_formula_sum            'C59 H51 O4 P4 Rh'
_chemical_formula_weight         1050.78
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_type_scat_source           IntTabC
_cell_angle_alpha                81.64(2)
_cell_angle_beta                 105.19(2)
_cell_angle_gamma                94.05(2)
_cell_formula_units_Z            2
_cell_length_a                   11.069(2)
_cell_length_b                   14.426(3)
_cell_length_c                   16.561(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      40
_cell_measurement_theta_min      30
_cell_volume                     2523.5(10)
_diffrn_measurement_device       'Syntex P-1'
_diffrn_measurement_method       \q/2\q
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.5418
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0165
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            6574
_diffrn_reflns_theta_max         57.46
_diffrn_reflns_theta_min         2.79
_diffrn_standards_decay_%        <1
_diffrn_standards_interval_count 100
_diffrn_standards_interval_time  60
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.309
_exptl_absorpt_correction_T_max  0.7031
_exptl_absorpt_correction_T_min  0.3792
_exptl_absorpt_correction_type
;based on \DF (CSD; Akselrud, Grin, Zavalii, Pecharsky &
Fundamensky, 1989)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.383
_exptl_crystal_density_meas      1.372
_exptl_crystal_density_method    'flotation in aqueous NaI'
_exptl_crystal_description       rectangular
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.82
_refine_diff_density_min         -0.98
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.044
_refine_ls_goodness_of_fit_obs   1.044
_refine_ls_hydrogen_treatment    'H atoms treated using a riding model'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     617
_refine_ls_number_reflns         6471
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.044
_refine_ls_restrained_S_obs      1.044
_refine_ls_R_factor_all          0.0359
_refine_ls_R_factor_obs          0.0359
_refine_ls_shift/esd_max         0.335
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_scheme
;calc w = 1/[\s^2^(F~o~^2^)+(0.0700P)^2^+1.2000P] where P =
(F~o~^2^+2F~c~^2^)/3
;
_refine_ls_wR_factor_all         0.0973
_refine_ls_wR_factor_obs         0.0973
_reflns_number_observed          6471
_reflns_number_total             6574
_reflns_observed_criterion       I>2\s(I)
_cod_data_source_file            mu1160.cif
_cod_data_source_block           mu1160a
_cod_original_cell_volume        2523.5(9)
_cod_database_code               2003704