Synthesis, structural characterization and magnetic behaviour of a family of [CoLn] butterfly compounds.
Funes, Alejandro V.; Carrella, Luca; Rechkemmer, Yvonne; van Slageren, Joris; Rentschler, Eva; Alborés, Pablo; Dalton transactions (Cambridge, England : 2003) 46 (2017) 3400–3409; doi:10.1039/c6dt04713k

data_7042247
_publ_section_title
;
 Synthesis, structural characterization and magnetic behaviour of a family
 of [CoLn] butterfly compounds.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               3409
_journal_paper_doi               10.1039/c6dt04713k
_journal_volume                  46
_journal_year                    2017
_chemical_formula_sum            'C45 H90 Co2 Gd2 N2 O21'
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_space_group_name_Hall           '-P 1'
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2017-02-01 deposited with the CCDC.
2017-02-16 downloaded from the CCDC.
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_cell_angle_alpha                76.602(7)
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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_computing_molecular_graphics    'ORTEPIII (Burnett & Johnson, 1996)'
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_diffrn_reflns_av_R_equivalents  0.0561
_diffrn_reflns_av_unetI/netI     0.0660
_diffrn_reflns_Laue_measured_fraction_full 0.997
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_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.997
_diffrn_reflns_theta_min         3.579
_diffrn_source                   'Enhance (Mo) X-ray Source'
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_exptl_absorpt_correction_T_max  1.00000
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.499
_exptl_crystal_description       block
_exptl_crystal_F_000             1448
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_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.221
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
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_refine_ls_number_reflns         13655
_refine_ls_number_restraints     905
_refine_ls_restrained_S_all      1.084
_refine_ls_R_factor_all          0.0600
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0297P)^2^+0.1144P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0780
_refine_ls_wR_factor_ref         0.0923
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10291
_reflns_number_total             13655
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt04713k2.cif
_cod_data_source_block           6
_cod_depositor_comments
'Adding full bibliography for 7042243--7042247.cif.'
_cod_database_code               7042247
_shelx_shelxl_version_number     2014/7
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