Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synthesis and Reaction of ε-Oxoallylstannanes
Eiji Shirakawa; Yoshiaki Nakao; Hiroto Yoshida; Tamejiro Hiyama; Journal of the American Chemical Society 122 (2000) 9030–9031; doi:10.1021/ja0020409

data_4116134
_publ_contact_author_address
;
Graduate School of Materials Science, Japan Advanced Institute of Science and 
Technology, Asahidai, Tatsunokuchi, Ishikawa 923-1292, Japan
;
_publ_contact_author_email       ' shira@jaist.ac.jp '
_publ_contact_author_fax         ' +81-761-51-1635 '
_publ_contact_author_name        ' Eiji  Shirakawa'
_publ_contact_author_phone       ' +81-761-51-1631 '
_publ_section_title
;
 Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synthesis and Reaction
 of \e-Oxoallylstannanes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              9030
_journal_page_last               9031
_journal_paper_doi               10.1021/ja0020409
_journal_volume                  122
_journal_year                    2000
_chemical_formula_moiety         'C21 H24 O2 '
_chemical_formula_sum            'C21 H24 O2'
_chemical_formula_weight         308.42
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   23.807(5)
_cell_length_b                   13.334(4)
_cell_length_c                   11.354(6)
_cell_measurement_reflns_used    20
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      10.8
_cell_measurement_theta_min      9.4
_cell_volume                     3604(2)
_diffrn_ambient_temperature      296.2
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      0.03442
_diffrn_orient_matrix_UB_12      -0.01693
_diffrn_orient_matrix_UB_13      0.04639
_diffrn_orient_matrix_UB_21      0.02406
_diffrn_orient_matrix_UB_22      0.02208
_diffrn_orient_matrix_UB_23      -0.06738
_diffrn_orient_matrix_UB_31      0.00074
_diffrn_orient_matrix_UB_32      0.06964
_diffrn_orient_matrix_UB_33      0.03264
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.00000
_diffrn_reflns_av_sigmaI/netI    0.198
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            4635
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         2.51
_diffrn_standards_decay_%        0.11
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.071
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.137
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1328.00
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.30
_refine_diff_density_max         0.14
_refine_diff_density_min         -0.14
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.780
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     304
_refine_ls_number_reflns         1183
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           0.0430
_refine_ls_shift/su_max          0.2300
_refine_ls_shift/su_mean         0.0117
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00000|Fo|^2^]'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0260
_reflns_number_gt                1183
_reflns_number_total             4635
_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            ja0020409.cif
_cod_data_source_block           global
_cod_original_sg_symbol_H-M      'P b c a '
_cod_original_formula_sum        'C21 H24 O2 '
_cod_database_code               4116134