Mixed-Metal Sulfido Clusters Containing Noble Metals and Group 15 Metals. Stepwise Construction of Bimetallic and Trimetallic Ru2MS2(M = Sb, Bi), Ru2PdSbS2, and Ru2Pd2SbS2Cores
Amitsuka, Takahiko; Seino, Hidetake; Hidai, Masanobu; Mizobe, Yasushi; Organometallics 25 (2006) 3034–; doi:10.1021/om060071s

data_4075150
_publ_section_title
;
 Mixed-Metal Sulfido Clusters Containing Noble Metals and Group 15 Metals.
 Stepwise Construction of Bimetallic and Trimetallic Ru2MS2(M = Sb, Bi),
 Ru2PdSbS2, and Ru2Pd2SbS2Cores
;
_journal_issue                   12
_journal_name_full               Organometallics
_journal_page_first              3034
_journal_paper_doi               10.1021/om060071s
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C58 H64 Cl3 P2 Pd2 S2 Ru2 Sb '
_chemical_formula_sum            'C58 H64 Cl3 P2 Pd2 Ru2 S2 Sb'
_chemical_formula_weight         1530.26
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 106.638(3)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   25.40(3)
_cell_length_b                   12.198(12)
_cell_length_c                   38.82(4)
_cell_measurement_reflns_used    3909
_cell_measurement_temperature    293.1
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      3.1
_cell_volume                     11524(2)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.6.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.8930
_diffrn_measured_fraction_theta_max 0.8930
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.054
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       51
_diffrn_reflns_limit_l_min       -51
_diffrn_reflns_number            29673
_diffrn_reflns_theta_full        27.88
_diffrn_reflns_theta_max         27.88
_exptl_absorpt_coefficient_mu    1.891
_exptl_absorpt_correction_T_max  0.685
_exptl_absorpt_correction_T_min  0.464
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.764
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             6048.00
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.69
_refine_diff_density_min         -1.05
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     695
_refine_ls_number_reflns         12406
_refine_ls_R_factor_gt           0.0500
_refine_ls_shift/su_max          0.0020
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0010Fo^2^ + 0.8000\s(Fo^2^) + 0.1000]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1590
_reflns_number_gt                8593
_reflns_number_total             12406
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om060071ssi20060417_110316.cif
_cod_data_source_block           '__[(Cp^Ru)2{Pd(PPh3)}2(SbCl2)S2Cl]_(5)'
_cod_original_cell_volume        11522(20)
_cod_original_formula_sum        'C58 H64 Cl3 P2 Pd2 S2 Ru2 Sb '
_cod_database_code               4075150