Pd-catalyzed C-H carbonylation of (hetero)arenes with formates and intramolecular dehydrogenative coupling: a shortcut to indolo[3,2-c]coumarins.
Wu, Jie; Lan, Jingbo; Guo, Siyuan; You, Jingsong; Organic letters 16 (2014) 5862–5865; doi:10.1021/ol502749b

data_1518179
_publ_section_title
;
 Pd-catalyzed C-H carbonylation of (hetero)arenes with formates and
 intramolecular dehydrogenative coupling: a shortcut to
 indolo[3,2-c]coumarins.
;
_journal_issue                   22
_journal_name_full               'Organic letters'
_journal_page_first              5862
_journal_page_last               5865
_journal_paper_doi               10.1021/ol502749b
_journal_volume                  16
_journal_year                    2014
_chemical_formula_moiety         'C22 H17 N O2'
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CrysAlisPro, Agilent Technologies,
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  6 omega   20.00  104.00   1.0000    1.0100
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  9 omega   91.00  176.00   1.0000    4.0400
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 10 omega  100.00  178.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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 11 omega   39.00  109.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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 12 omega   38.00   91.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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 13 omega   39.00  109.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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 14 omega   40.00   98.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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 15 omega   91.00  176.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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 16 omega   40.00   98.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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 17 omega   38.00   91.00   1.0000    4.0400
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 18 omega    1.00   27.00   1.0000    1.0100
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 19 omega   20.00  104.00   1.0000    1.0100
omega____ theta____ kappa____ phi______ frames
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 20 omega  -33.00   55.00   1.0000    1.0100
omega____ theta____ kappa____ phi______ frames
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 21 omega   20.00  104.00   1.0000    1.0100
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 22 omega  -33.00   55.00   1.0000    1.0100
omega____ theta____ kappa____ phi______ frames
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 23 omega   10.00  104.00   1.0000    1.0100
omega____ theta____ kappa____ phi______ frames
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 24 omega    1.00   75.00   1.0000    1.0100
omega____ theta____ kappa____ phi______ frames
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 25 omega   81.00  176.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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 26 omega   91.00  176.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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 27 omega   87.00  145.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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 28 omega   70.00  178.00   1.0000    4.0400
omega____ theta____ kappa____ phi______ frames
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1. Fixed Uiso
 At 1.2 times of:
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 C20, C19
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3.a Secondary CH2 refined with riding coordinates:
 C10(H10A,H10B)
3.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C5(H5), C6(H6), C7(H7), C8(H8), C12(H12), C13(H13), C14(H14),
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