A dicationic iminophosphane.
Loh, Ying Kai; Gurnani, Chitra; Ganguly, Rakesh; Vidović, Dragoslav; Inorganic chemistry 54 (2015) 3087–3089; doi:10.1021/acs.inorgchem.5b00003

data_4346016
_publ_section_title
;
 A dicationic iminophosphane.
;
_journal_issue                   7
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3087
_journal_page_last               3089
_journal_paper_doi               10.1021/acs.inorgchem.5b00003
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'C207 H224 Cl18 F48 N12 P12 Sb8'
_chemical_formula_weight         5775.71
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_cell_angle_alpha                90
_cell_angle_beta                 91.183(3)
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   11.8727(6)
_cell_length_b                   19.4927(8)
_cell_length_c                   25.2042(13)
_cell_measurement_reflns_used    3968
_cell_measurement_temperature    103.(2)
_cell_measurement_theta_max      20.0600
_cell_measurement_theta_min      2.3329
_cell_volume                     5831.8(5)
_computing_cell_refinement       'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_data_collection       'APEX2 (Bruker AXS Inc., 2014)'
_computing_data_reduction        'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_molecular_graphics    'XP (Bruker AXS Inc., 2014)'
_computing_publication_material  'APEX2 (Bruker AXS Inc., 2014)'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_diffrn_ambient_temperature      103.(2)
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1695
_diffrn_reflns_av_unetI/netI     0.1302
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            68534
_diffrn_reflns_theta_full        26.11
_diffrn_reflns_theta_max         26.11
_diffrn_reflns_theta_min         1.93
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    1.291
_exptl_absorpt_correction_T_max  0.95
_exptl_absorpt_correction_T_min  0.81
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2014/4 (Bruker AXS Inc.)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.645
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2876
_exptl_crystal_size_max          0.060
_exptl_crystal_size_mid          0.040
_exptl_crystal_size_min          0.040
_refine_diff_density_max         1.076
_refine_diff_density_min         -0.979
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     742
_refine_ls_number_reflns         11566
_refine_ls_number_restraints     245
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.1387
_refine_ls_R_factor_gt           0.0564
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0368P)^2^+15.5287P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1033
_refine_ls_wR_factor_ref         0.1328
_reflns_number_gt                6521
_reflns_number_total             11566
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ic5b00003_si_001.cif
_cod_data_source_block           I
_cod_database_code               4346016
_shelx_res_checksum              54975
_shelx_hkl_checksum              37650