Syntheses and Characterizations of Three Low-Dimensional Chloride-Rich Zincophosphates Assembled about [d-Co(en)3]3+ and [dl-Co(en)3]3+ Complex Cations
Peng Chen; Jiyang Li; Fangzheng Duan; Jihong Yu; Ruren Xu; Raj Pal Sharma; Inorganic Chemistry 46 (2007) 6683–6687; doi:10.1021/ic062103+

data_4327233
_publ_section_title
;
 Syntheses and Characterizations of Three Low-Dimensional Chloride-Rich
 Zincophosphates Assembled about [d-Co(en)3]3+ and [dl-Co(en)3]3+ Complex
 Cations
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6683
_journal_page_last               6687
_journal_paper_doi               10.1021/ic062103+
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C24 H108 Cl16 Co4 N24 O32 P8 Zn8'
_chemical_formula_weight         2818.98
_chemical_name_systematic
; 
 ? 
;
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_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.43(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   31.103(6)
_cell_length_b                   9.0456(18)
_cell_length_c                   16.499(3)
_cell_measurement_temperature    293(2)
_cell_volume                     4565.2(16)
_computing_cell_refinement       'Rigaku R-AXIS RAPID'
_computing_data_collection       'Rigaku R-AXIS RAPID'
_computing_data_reduction        'Rigaku R-AXIS RAPID'
_computing_molecular_graphics    SHELXP-97
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_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.2520
_diffrn_reflns_av_sigmaI/netI    0.3649
_diffrn_reflns_limit_h_max       40
_diffrn_reflns_limit_h_min       -40
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_diffrn_reflns_limit_k_min       -11
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_diffrn_reflns_theta_max         27.47
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_exptl_absorpt_coefficient_mu    3.457
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_exptl_crystal_F_000             2832
_refine_diff_density_max         1.243
_refine_diff_density_min         -1.237
_refine_diff_density_rms         0.186
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.01(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.810
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_refine_ls_number_reflns         10113
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_refine_ls_R_factor_all          0.1685
_refine_ls_R_factor_gt           0.0860
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_refine_ls_shift/su_mean         0.059
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0001P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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