<i>catena</i>-Poly[[bis(<i>N</i>-ethylethylenediamine-κ^2^<i>N</i>,<i>N</i>')copper(II)]-μ-cyanido-κ^2^<i>N</i>:<i>C</i>-[dicyanido-κ^2^<i>C</i>-palladium(II)]-μ-cyanido-κ^2^<i>C</i>:<i>N</i>]
Akitsu, Takashiro; Endo, Yuki; Acta Crystallographica Section E 65 (2009) m406–m407; doi:10.1107/S160053680900885X

data_2221262
_publ_section_title
<i>catena</i>-Poly[[bis(<i>N</i>-ethylethylenediamine-\k^2^<i>N</i>,<i>N</i>')copper(II)]-\m-cyanido-\k^2^<i>N</i>:<i>C</i>-[dicyanido-\k^2^<i>C</i>-palladium(II)]-\m-cyanido-\k^2^<i>C</i>:<i>N</i>]
_journal_coeditor_code           BG2245
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m406
_journal_page_last               m407
_journal_paper_doi               10.1107/S160053680900885X
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac          '[Cu Pd (C N)4 (C4 H12 N2)2]'
_chemical_formula_moiety         'C12 H24 Cu N8 Pd'
_chemical_formula_sum            'C12 H24 Cu N8 Pd'
_chemical_formula_weight         450.33
_chemical_name_systematic
;
<i>catena</i>-Poly[[bis(<i>N</i>-ethylethylenediamine-
\k^2^<i>N</i>,<i>N</i>')copper(II)]-\m-cyanido-\k^2^<i>N</i>:<i>C</i>-
[dicyanido-\k^2^C-palladium(II)]-\m-cyanido-\k^2^<i>C</i>:<i>N</i>]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                69.091(5)
_cell_angle_beta                 72.490(6)
_cell_angle_gamma                89.680(6)
_cell_formula_units_Z            1
_cell_length_a                   7.360(4)
_cell_length_b                   7.567(4)
_cell_length_c                   9.061(4)
_cell_measurement_reflns_used    1805
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.53
_cell_measurement_theta_min      2.54
_cell_volume                     446.6(4)
_computing_cell_refinement       'SAINT (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Altomare <i>et al.</i>,  1994)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.943
_diffrn_measurement_device_type  'Brruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0271
_diffrn_reflns_av_sigmaI/netI    0.0473
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -4
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_number            2943
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.54
_exptl_absorpt_coefficient_mu    2.206
_exptl_absorpt_correction_T_max  0.8063
_exptl_absorpt_correction_T_min  0.6618
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 1998)'
_exptl_crystal_colour            'blue violet'
_exptl_crystal_density_diffrn    1.674
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             227
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.240
_refine_diff_density_min         -1.284
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.850
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     105
_refine_ls_number_reflns         1934
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.850
_refine_ls_R_factor_all          0.0369
_refine_ls_R_factor_gt           0.0339
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0980
_refine_ls_wR_factor_ref         0.1052
_reflns_number_gt                1763
_reflns_number_total             1934
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            bg2245.cif
_cod_data_source_block           I
_cod_database_code               2221262
_cod_database_fobs_code          2221262