Towards accurate and precise positions of hydrogen atoms bonded to heavy metal atoms.
Woińska, Magdalena; Chodkiewicz, Michał L; Woźniak, Krzysztof; Chemical communications (Cambridge, England) 57 (2021) 3652–3655; doi:10.1039/d0cc07661a

data_7128089
_publ_section_title
;
 Towards accurate and precise positions of hydrogen atoms bonded to heavy
 metal atoms.
;
_journal_issue                   30
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3652
_journal_page_last               3655
_journal_paper_doi               10.1039/d0cc07661a
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C24 H47 B Cl O2 P2 Rh'
_chemical_formula_sum            'C24 H47 B Cl O2 P2 Rh'
_chemical_formula_weight         578.769
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_Int_Tables_number      14
_audit_creation_date             2021-02-16
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Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6226)
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_audit_update_record
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2021-03-08 deposited with the CCDC.	2021-03-17 downloaded from the CCDC.
;
_cell_angle_alpha                90
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'SADABS (G.M.Sheldrick,1998); R(int)=0.059 before correction'
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'w=1/[\s^2^(Fo^2^)+(0.0238P)^2^+1.9702P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_file            d0cc07661a2.cif
_cod_data_source_block           SITKUB_IAM
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_crystal_density_meas' value 'not measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7128081--7128095.cif.
;
_cod_database_code               7128089
_olex2_refinement_description
;
1.a Riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C7(H7), C10(H10), C13(H13), C16(H16),
 C19(H19), C22(H22)
1.b Rotating group with stretchable bonds:
 C8(H8a,H8b,H8c), C9(H9a,H9b,H9c), C11(H11a,H11b,H11c), C12(H12a,H12b,H12c),
 C14(H14a,H14b,H14c), C15(H15a,H15b,H15c), C17(H17a,H17b,H17c), C18(H18a,H18b,
 H18c), C20(H20a,H20b,H20c), C21(H21a,H21b,H21c), C23(H23a,H23b,H23c), C24(H24a,
 H24b,H24c)
;
_olex2_submission_special_instructions 'No special instructions were received'