N,N,N',N'-Tetrakis(2-pyridylmethyl)ethylenediamine and Its Analogues as Hypodentate Ligands. Synthesis and Characterization of the Rhodium(III), Ruthenium(II), and Palladium(II) Complexes
Maxim Sokolov; Keisuke Umakoshi; Yoichi Sasaki; Inorganic Chemistry 41 (2002) 6237–6243; doi:10.1021/ic0203264

data_4318892
_publ_contact_author_address
;
      Division of Chemistry, Graduate School of Science
     Hokkaido University
     Kita-ku, Sapporo 060-0810
     Japan
;
_publ_contact_author_email       ysasaki@science.hokudai.ac.jp
_publ_contact_author_fax         ' 81-11-706-3447 '
_publ_contact_author_name        ' Yoichi Sasaki'
_publ_contact_author_phone       ' 81-11-706-3817 '
_publ_section_title
;
 N,N,N',N'-Tetrakis(2-pyridylmethyl)ethylenediamine and Its Analogues as
 Hypodentate Ligands. Synthesis and Characterization of the Rhodium(III),
 Ruthenium(II), and Palladium(II) Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6237
_journal_page_last               6243
_journal_paper_doi               10.1021/ic0203264
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C28 H31 Cl F12 N7 P2 Rh'
_chemical_formula_weight         893.89
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                99.43(1)
_cell_angle_beta                 93.89(1)
_cell_angle_gamma                80.10(1)
_cell_formula_units_Z            2
_cell_length_a                   11.430(1)
_cell_length_b                   19.234(3)
_cell_length_c                   8.101(1)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      16.5
_cell_measurement_theta_min      15.1
_cell_volume                     1729.3(4)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 0.9999
_diffrn_measured_fraction_theta_max 0.9999
_diffrn_measurement_device_type  'Rigaku AFC5R'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.017
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            8482
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_standards_decay_%        0.41
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.760
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.919
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            'colourless '
_exptl_crystal_density_diffrn    1.717
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.67
_refine_diff_density_min         -0.46
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    'H atoms riding with U(H) = 1.2Ueq(C)'
_refine_ls_number_parameters     460
_refine_ls_number_reflns         6066
_refine_ls_R_factor_gt           0.0476
_refine_ls_shift/su_max          0.0009
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00216|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0641
_reflns_number_gt                6066
_reflns_number_total             7924
_reflns_threshold_expression     I>2.0sigma(I)
_cod_data_source_file            ic0203264_3.cif
_cod_data_source_block           '[RhCl(tpen)](PF6)2.CH3CN'
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C28 H31 Cl F12 N7 P2 Rh '
_cod_database_code               4318892