Redox non-innocence permits catalytic nitrene carbonylation by (dadi)TiNAd (Ad = adamantyl)
Heins, Spencer P.; Wolczanski, Peter T.; Cundari, Thomas R.; MacMillan, Samantha N.; Chem. Sci. 8 (2017) 3410–; doi:10.1039/C6SC05610E

data_1545512
_publ_section_title
;
 Redox non-innocence permits catalytic nitrene carbonylation by
 (dadi)Ti&#xE001;NAd (Ad = adamantyl)
;
_journal_issue                   5
_journal_name_full               'Chem. Sci.'
_journal_page_first              3410
_journal_paper_doi               10.1039/C6SC05610E
_journal_volume                  8
_journal_year                    2017
_chemical_formula_sum            'C46 H55 N4 P Ti'
_chemical_formula_weight         742.81
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-12-13 deposited with the CCDC.
2017-03-06 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0657P)^2^+0.8509P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 1545511--1545513.cif.'
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