Syntheses, Characterization, and Reactivity of Diruthenium Hydrido Complexes
Wiltse, Heather R.; Johnson, Alyssa N.; Durand, Raphael J.; Brennessel, William; Chin, Robert M.; Organometallics 35 (2016) 1079–; doi:10.1021/acs.organomet.6b00067

data_4086455
_publ_section_title
;
 Syntheses, Characterization, and Reactivity of Diruthenium Hydrido
 Complexes
;
_journal_issue                   8
_journal_name_full               Organometallics
_journal_page_first              1079
_journal_paper_doi               10.1021/acs.organomet.6b00067
_journal_volume                  35
_journal_year                    2016
_chemical_formula_moiety         'C56 H72 N6 Ru2, 2(C F3 O3 S), C2 H3 N'
_chemical_formula_sum            'C60 H75 F6 N7 O6 Ru2 S2'
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_chemical_name_common            unimc30
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
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_cell_length_b                   17.1285(15)
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_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      35.37
_cell_measurement_theta_min      2.19
_cell_volume                     6271.2(9)
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_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type  'Bruker SMART APEX II CCD platform'
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_diffrn_source                   'fine-focus sealed tube'
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_refine_ls_extinction_method     none
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_refine_ls_number_restraints     19
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.0754
_refine_ls_R_factor_gt           0.0412
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0399P)^2^+2.0965P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                23759
_reflns_number_total             34762
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           unimc30
_cod_depositor_comments
'Adding full bibliography for 4086455--4086457.cif.'
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