Hypoelectronic isomeric diiridaboranes [(Cp*Ir)2B6H6]: the "Rule-Breakers"(Cp* = η(5)-C5Me5).
Borthakur, Rosmita; Mondal, Bijan; Nandi, Purbasha; Ghosh, Sundargopal; Chemical communications (Cambridge, England) 52 (2016) 3199–3202; doi:10.1039/c5cc09606e

data_7118381
_publ_section_title
;
 Hypoelectronic isomeric diiridaboranes [(Cp*Ir)2B6H6]: the
 &quot;Rule-Breakers&quot;(Cp* = \h(5)-C5Me5).
;
_journal_issue                   15
_journal_name_full
'Chemical communications (Cambridge, England)'
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_journal_paper_doi               10.1039/c5cc09606e
_journal_volume                  52
_journal_year                    2016
_chemical_formula_sum            'C20 H36 B6 Ir2'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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;
2015-10-03 deposited with the CCDC.
2016-01-06 downloaded from the CCDC.
;
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_computing_molecular_graphics
'ORTEP3 (Farrugia, 1997) and Mercury (Bruno et al., 2002)'
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_diffrn_ambient_temperature      293(2)
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_diffrn_measurement_device_type  'SuperNova, Dual, Mo at zero, Eos'
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1483P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 7118379--7118381.cif.'
_cod_database_code               7118381
_audit_block_doi                 10.5517/cc1jzb2x
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