Rhodium-Catalyzed Hydrocarbonylation of a Homoallylamine via N–H Activation and Application for Synthesis of Yohimbane Alkaloids
Chiou, Wen-Hua; Wang, Yu-Wei; Kao, Chien-Lun; Chen, Po-Chou; Wu, Chen-Chang; Organometallics 33 (2014) 4240–; doi:10.1021/om500498u

data_4084197
_publ_section_title
;
 Rhodium-Catalyzed Hydrocarbonylation of a Homoallylamine via N--H
 Activation and Application for Synthesis of Yohimbane Alkaloids
;
_journal_issue                   16
_journal_name_full               Organometallics
_journal_page_first              4240
_journal_paper_doi               10.1021/om500498u
_journal_volume                  33
_journal_year                    2014
_chemical_formula_moiety         'C19 H24 N2, C H4 O'
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CrysAlis RED, Oxford Diffraction Ltd., 
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CrysAlis CCD, Oxford Diffraction Ltd., 
Version 1.171.32.29 (release 10-06-2008 CrysAlis171 .NET) 
(compiled Jun 10 2008,16:49:55) 
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CrysAlis RED, Oxford Diffraction Ltd., 
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CrysAlisPro, Oxford Diffraction Ltd., 
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Empirical absorption correction using spherical harmonics, 
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.188
_exptl_crystal_density_method    'not measured'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0585P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0969
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_reflns_number_gt                2854
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_cod_depositor_comments          'Adding full bibliography for 4084197.cif.'
_cod_original_cell_volume        873.75(13)
_cod_database_code               4084197