Regio- and Stereoselective Insertion Reactions of Thiiranes into Pt-Mn (or Re) Bond in Organoplatinum-Manganese or -Rhenium Heterodinuclear Complexes as Intermediates toward Desulfurization Reaction
Sanshiro Komiya; Shin-ya Muroi; Masaki Furuya; Masafumi Hirano; Journal of the American Chemical Society 122 (2000) 170–171; doi:10.1021/ja993185m

data_4115873
_publ_contact_author_address
;
Department of Applied Chemistry
Tokyo University of Agriculture and Technology
2-24-16 Nakacho, Koganei, Tokyo 184-8588, Japan
;
_publ_contact_author_email       ' komiya@cc.tuat.ac.jp '
_publ_contact_author_fax         ' +81-42-387-7500 '
_publ_contact_author_name        ' Sanshiro Komiya'
_publ_contact_author_phone       ' +81-42-388-7043 '
_publ_section_title
;
 Regio- and Stereoselective Insertion Reactions of Thiiranes into Pt-Mn
 (or Re) Bond in Organoplatinum-Manganese or -Rhenium Heterodinuclear
 Complexes as Intermediates toward Desulfurization Reaction
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              170
_journal_page_last               171
_journal_paper_doi               10.1021/ja993185m
_journal_volume                  122
_journal_year                    2000
_chemical_formula_sum            'C39 H38 Mn O5 P2 Pt S'
_chemical_formula_weight         930.76
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Sun May 30 13:02:49 1999'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                106.7(4)
_cell_angle_beta                 103.9(4)
_cell_angle_gamma                84.8(4)
_cell_formula_units_Z            2
_cell_length_a                   13.09(6)
_cell_length_b                   14.23(7)
_cell_length_c                   10.79(5)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    113.2
_cell_measurement_theta_max      15.3
_cell_measurement_theta_min      14.2
_cell_volume                     1868(16)
_computing_cell_refinement       'Rigaku/AFC Diffractometer Control'
_computing_data_collection       'Rigaku/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    'DIRDIF92 (PATTY)'
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_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
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_diffrn_orient_matrix_UB_13      -0.02444
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_diffrn_orient_matrix_UB_33      0.09534
_diffrn_radiation_detector       'scintillation counter'
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_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_av_R_equivalents  0.061
_diffrn_reflns_av_sigmaI/netI    0.069
_diffrn_reflns_limit_h_max       16
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_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
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_diffrn_reflns_reduction_process 'Lp corrections applied'
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_diffrn_reflns_theta_min         2.82
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_exptl_absorpt_coefficient_mu    4.244
_exptl_absorpt_correction_T_max  0.998
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_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            yellow
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_exptl_crystal_description       prismatic
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_exptl_crystal_size_mid          0.020
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_refine_diff_density_min         -5.30
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.780
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
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_refine_ls_R_factor_all          0.0789
_refine_ls_R_factor_gt           0.0789
_refine_ls_shift/su_max          10.2910
_refine_ls_shift/su_mean         0.0300
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w =3D 1/[\s^2^(Fo) + 0.00230|Fo|^2^]'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                6475
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_reflns_threshold_expression     >2.0sigma(I)
_cod_data_source_file            ja993185m_3.cif
_cod_data_source_block           cis-10
_cod_original_cell_volume        1869(16)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C39 H38 Mn O5 P2 Pt S '
_cod_database_code               4115873