Phosphido pincer complexes of platinum: synthesis, structure and reactivity.
Mazzeo, Mina; Strianese, Maria; Kühl, Olaf; Peters, Jonas C.; Dalton transactions (Cambridge, England : 2003) 40 (2011) 9026–9033; doi:10.1039/c1dt10825e

data_7016546
_publ_section_title
;
 Phosphido pincer complexes of platinum: synthesis, structure and
 reactivity.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9026
_journal_page_last               9033
_journal_paper_doi               10.1039/c1dt10825e
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C25 H39 P3 Pt'
_chemical_formula_sum            'C25 H39 P3 Pt'
_chemical_formula_weight         627.56
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.280(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   11.7084(6)
_cell_length_b                   13.9668(7)
_cell_length_c                   31.1141(16)
_cell_measurement_reflns_used    20231
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      42.99
_cell_measurement_theta_min      1.60
_cell_volume                     5086.8(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.538
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1043
_diffrn_reflns_av_sigmaI/netI    0.1548
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       59
_diffrn_reflns_limit_l_min       -41
_diffrn_reflns_number            56422
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         42.99
_diffrn_reflns_theta_min         1.60
_exptl_absorpt_coefficient_mu    5.715
_exptl_absorpt_correction_T_max  0.353
_exptl_absorpt_correction_T_min  0.220
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_density_diffrn    1.639
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2496
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.18
_refine_diff_density_max         3.595
_refine_diff_density_min         -3.282
_refine_diff_density_rms         0.294
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.872
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     541
_refine_ls_number_reflns         20231
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.872
_refine_ls_R_factor_all          0.1245
_refine_ls_R_factor_gt           0.0527
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0432P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1013
_refine_ls_wR_factor_ref         0.1199
_reflns_number_gt                10073
_reflns_number_total             20231
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt10825e.txt
_cod_data_source_block           mm05
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7016546