A highly pure red luminescent europium(III) complex with a Schiff base zinc(II) complex as a neutral ligand
Shimin Wang; Bin Zhang; Yanhui Hou; Chenxia Du; Yangjie Wu; Journal of Materials Chemistry C 1 (2013) 406–409; doi:10.1039/C2TC00279E

data_7233082
_publ_section_title
;
 A highly pure red luminescent europium(III) complex with a Schiff base
 zinc(II) complex as a neutral ligand
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              406
_journal_page_last               409
_journal_paper_doi               10.1039/C2TC00279E
_journal_volume                  1
_journal_year                    2013
_chemical_formula_moiety         'C35 H24 Eu F9 N2 O8 S2 Zn'
_chemical_formula_sum            'C35 H24 Eu F9 N2 O8 S2 Zn'
_chemical_formula_weight         1053.01
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                72.23(3)
_cell_angle_beta                 79.69(3)
_cell_angle_gamma                75.14(3)
_cell_formula_units_Z            2
_cell_length_a                   10.581(2)
_cell_length_b                   11.669(2)
_cell_length_c                   17.239(3)
_cell_measurement_temperature    291(2)
_cell_volume                     1947.4(7)
_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution
'A short history of SHELX (Sheldrick, 2007)/Bruker'
_diffrn_ambient_temperature      291.0
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0662
_diffrn_reflns_av_unetI/netI     0.0889
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            21958
_diffrn_reflns_theta_full        26.50
_diffrn_reflns_theta_max         26.50
_diffrn_reflns_theta_min         2.24
_exptl_absorpt_coefficient_mu    2.414
_exptl_absorpt_correction_T_max  0.7943
_exptl_absorpt_correction_T_min  0.5312
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.796
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1036
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.663
_refine_diff_density_min         -0.683
_refine_diff_density_rms         0.102
_refine_ls_extinction_coef       0.0003(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    fixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     548
_refine_ls_number_reflns         7971
_refine_ls_number_restraints     90
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.1055
_refine_ls_R_factor_gt           0.0690
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0618P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1371
_refine_ls_wR_factor_ref         0.1558
_reflns_number_gt                5338
_reflns_number_total             7971
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            J-Mat-Chem-C-2013-1-406.cif
_cod_data_source_block           p-1
_cod_original_cell_volume        1947.5(7)
_cod_database_code               7233082