Auto-oxidation promoted sp<sup>3</sup> C-H arylation of glycine derivatives.
Wei, Yuanyuan; Wang, Jie; Wang, Yajun; Yao, Xiaoqiang; Yang, Caixia; Huo, Congde; Organic & biomolecular chemistry 16 (2018) 4985–4989; doi:10.1039/c8ob01068d

data_7156291
_publ_section_title
;
 Auto-oxidation promoted sp<sup>3</sup> C-H arylation of glycine
 derivatives.
;
_journal_issue                   27
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              4985
_journal_page_last               4989
_journal_paper_doi               10.1039/c8ob01068d
_journal_volume                  16
_journal_year                    2018
_chemical_formula_sum            'C21 H28 N2 O2'
_chemical_formula_weight         340.45
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2018-01-30 deposited with the CCDC.
2018-06-19 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_measurement_temperature    293(2)
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
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_refine_diff_density_max         0.418
_refine_diff_density_min         -0.155
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_refine_ls_extinction_coef       0.0070(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   0.986
_refine_ls_hydrogen_treatment    constr
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_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.986
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0847P)^2^+2.5696P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                2980
_reflns_number_total             3877
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8ob01068d2.cif
_cod_data_source_block           1
_cod_depositor_comments          'Adding full bibliography for 7156291.cif.'
_cod_database_code               7156291
_shelx_shelxl_version_number     2014/7
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