Two isostructural Zn/Co-MOFs with penetrating structures: multifunctional properties of both luminescence sensing and conversion of CO<sub>2</sub> into cyclic carbonates.
Liu, Nana; Liu, Tingting; Liu, Guangning; Mi, Xiuna; Li, Yunwu; Yang, Lu; Zhou, Zhen; Wang, Suna; Dalton transactions (Cambridge, England : 2003) 53 (2024) 3654–3665; doi:10.1039/d3dt03466f

data_7714857
_publ_section_title
;
 Two isostructural Zn/Co-MOFs with penetrating structures: multifunctional
 properties of both luminescence sensing and conversion of CO<sub>2</sub>
 into cyclic carbonates.
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3654
_journal_page_last               3665
_journal_paper_doi               10.1039/d3dt03466f
_journal_volume                  53
_journal_year                    2024
_chemical_formula_sum            'C28 H22 Co N2 O7'
_chemical_formula_weight         557.40
_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           'P 2 2ab'
_space_group_name_H-M_alt        'P 21 21 2'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2023-10-15 deposited with the CCDC.	2023-12-28 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
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_cell_length_c                   10.0776(9)
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_cell_measurement_temperature    298(2)
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_cell_measurement_theta_min      2.3905
_cell_volume                     2999.2(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
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_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      298(2)
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0437
_diffrn_reflns_av_unetI/netI     0.0545
_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_limit_k_min       -20
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_exptl_crystal_description       crystal
_exptl_crystal_F_000             1148
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.48(2)
_refine_ls_extinction_method     none
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_refine_ls_number_reflns         5279
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0002P)^2^+2.0453P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0624
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_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                4110
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7714857--7714858.cif.'
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