Stepwise syntheses and supramolecular assemblies of a series of polyoxovanadate hybrids with various architectures
Huang, Bo; Wang, Nan; Yang, Kang; Ke, Degang; Fang, Yajun; Hu, Xunliang; Wu, Baolin; Xiao, Zicheng; Wu, Pingfan; Wei, Yongge; New Journal of Chemistry 42 (2018) 5853–; doi:10.1039/C7NJ04727D

data_7057100
_publ_section_title
;
 Stepwise syntheses and supramolecular assemblies of a series of
 polyoxovanadate hybrids with various architectures
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              5853
_journal_paper_doi               10.1039/C7NJ04727D
_journal_volume                  42
_journal_year                    2018
_chemical_formula_sum            'C66 H116 N4 O25 V6'
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_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-05-03 deposited with the CCDC.
2018-02-26 downloaded from the CCDC.
;
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_cell_angle_gamma                104.66(3)
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
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_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       '\w scans'
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_diffrn_reflns_Laue_measured_fraction_full 0.988
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_diffrn_reflns_limit_h_max       13
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_diffrn_reflns_point_group_measured_fraction_full 0.988
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_diffrn_reflns_theta_full        25.242
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_exptl_absorpt_coefficient_mu    0.756
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.406
_exptl_crystal_description       block
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_exptl_crystal_size_min          0.24
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1755P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.2798
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4460
_reflns_number_total             7302
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7nj04727d2.cif
_cod_data_source_block           lbzda
_cod_depositor_comments
'Adding full bibliography for 7057098--7057101.cif.'
_cod_original_cell_volume        1974.0(8)
_cod_database_code               7057100
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              28546