Evidence of the facile hydride and enolate addition to the imine bond of an aluminum-salophen complex.
Cametti, Massimo; Dalla Cort, Antonella; Colapietro, Marcello; Portalone, Gustavo; Russo, Luca; Rissanen, Kari; Inorganic chemistry 46 (2007) 9057–9059; doi:10.1021/ic701521s

data_4338952
_publ_section_title
;
 Evidence of the facile hydride and enolate addition to the imine bond of
 an aluminum-salophen complex.
;
_journal_issue                   22
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9057
_journal_page_last               9059
_journal_paper_doi               10.1021/ic701521s
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C24 H22 Al N2 O5'
_chemical_formula_weight         445.42
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                86.1385(34)
_cell_angle_beta                 69.3368(34)
_cell_angle_gamma                78.0562(37)
_cell_formula_units_Z            2
_cell_length_a                   9.13560(50)
_cell_length_b                   11.40230(80)
_cell_length_c                   11.64000(80)
_cell_measurement_reflns_used    7707
_cell_measurement_temperature    173.0(1)
_cell_measurement_theta_max      25.000
_cell_measurement_theta_min      2.546
_cell_volume                     1109.92(13)
_computing_data_collection       'Collect (Bruker AXS BV, 1997-2004)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device       '95mm CCD camera on \k-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  'horizonally mounted graphite crystal'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0586
_diffrn_reflns_av_sigmaI/netI    0.0922
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            6226
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.61
_exptl_absorpt_coefficient_mu    0.130
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.333
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             466
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.645
_refine_diff_density_min         -0.347
_refine_diff_density_rms         0.075
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     298
_refine_ls_number_reflns         3899
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.1277
_refine_ls_R_factor_gt           0.0753
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0740P)^2^+2.2383P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1662
_refine_ls_wR_factor_ref         0.2053
_reflns_number_gt                2508
_reflns_number_total             3899
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic701521s-file001.cif
_cod_data_source_block           3
_cod_original_cell_volume        1109.921(128)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4338952