Photoluminescence Switching of Azobenzene-Conjugated Pt(II) Terpyridine Complexes by Trans-Cis Photoisomerization
Tomona Yutaka; Ichiro Mori; Masato Kurihara; Jun Mizutani; Naoto Tamai; Tsuyoshi Kawai; Masahiro Irie; Hiroshi Nishihara; Inorganic Chemistry 41 (2002) 7143–7150; doi:10.1021/ic0260116

data_4319091
_publ_section_title
;
 Photoluminescence Switching of Azobenzene-Conjugated Pt(II) Terpyridine
 Complexes by Trans-Cis Photoisomerization
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7143
_journal_page_last               7150
_journal_paper_doi               10.1021/ic0260116
_journal_volume                  41
_journal_year                    2002
_chemical_formula_moiety         'C80 H64 B2 N6 Pt '
_chemical_formula_sum            'C80 H64 B2 N6 Pt'
_chemical_formula_weight         1326.14
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             2001-07-16
_audit_creation_method           'by CrystalStructure v2.00'
_cell_angle_alpha                93.119(11)
_cell_angle_beta                 95.885(5)
_cell_angle_gamma                100.354(2)
_cell_formula_units_Z            2
_cell_length_a                   10.932(2)
_cell_length_b                   11.586(3)
_cell_length_c                   25.709(13)
_cell_measurement_reflns_used    7627
_cell_measurement_temperature    173.1
_cell_measurement_theta_max      13.7
_cell_measurement_theta_min      0.8
_cell_volume                     3177.5(19)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 2.00'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 7.32
_diffrn_measured_fraction_theta_full 0.8463
_diffrn_measured_fraction_theta_max 0.6971
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.076
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            17010
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    2.250
_exptl_absorpt_correction_T_max  0.000
_exptl_absorpt_correction_T_min  0.000
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.386
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         2.25
_refine_diff_density_min         -3.54
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   3.627
_refine_ls_number_parameters     782
_refine_ls_number_reflns         8031
_refine_ls_R_factor_gt           0.1040
_refine_ls_shift/su_max          0.0860
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/\s^2^(Fo)'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.1480
_reflns_number_gt                7830
_reflns_number_total             10157
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic0260116_1.cif
_cod_data_source_block           '__PttpytpyAB.inf(JA027282I)'
_cod_original_cell_volume        3177.5(16)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C80 H64 B2 N6 Pt '
_cod_database_code               4319091