Low-Valent Vanadium Complexes of a Pyrrolide-Based Ligand. Electronic Structure of a Dimeric V(I) Complex with a Short and Weak Metal-Metal Bond
Sougandi Ilango; Balamurugan Vidjayacoumar; Sandro Gambarotta; Serge I. Gorelsky; Inorganic Chemistry 47 (2008) 3265–3273; doi:10.1021/ic702280g

data_4304718
_publ_section_title
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Low-Valent Vanadium Complexes of a Pyrrolide-Based Ligand. Electronic
Structure of a Dimeric V(I) Complex with a Short and Weak Metal-Metal Bond
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_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3265
_journal_page_last               3273
_journal_paper_doi               10.1021/ic702280g
_journal_volume                  47
_journal_year                    2008
_chemical_formula_sum            'C32 H46 N2 O3 V'
_chemical_formula_weight         557.65
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
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_cell_angle_gamma                90.00
_cell_formula_units_Z            2
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_cell_length_c                   11.341(6)
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_cell_measurement_temperature    203(2)
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_computing_molecular_graphics    'SHELXTL, Bruker (2000)'
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
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_diffrn_ambient_temperature      203(2)
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_diffrn_measured_fraction_theta_max 0.982
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            brown
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_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'calc w=1/[\s^2^(Fo^2^)+(0.0522P)^2^]'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                4099
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_cod_depositor_comments
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The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'n/a' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
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_cod_original_cell_volume        1449.0(13)
_cod_database_code               4304718