Multi-electron reduction of sulfur and carbon disulfide using binuclear uranium(iii) borohydride complexes
Arnold, Polly L.; Stevens, Charlotte J.; Bell, Nicola L.; Lord, Rianne M.; Goldberg, Jonathan M.; Nichol, Gary S.; Love, Jason B.; Chem. Sci. 8 (2017) 3609–; doi:10.1039/C7SC00382J

data_1545553
_publ_section_title
;
 Multi-electron reduction of sulfur and carbon disulfide using binuclear
 uranium(iii) borohydride complexes
;
_journal_issue                   5
_journal_name_full               'Chem. Sci.'
_journal_page_first              3609
_journal_paper_doi               10.1039/C7SC00382J
_journal_volume                  8
_journal_year                    2017
_chemical_formula_moiety         'C102 H122 B N8 Na O4 U2, 2(C4 H8 O)'
_chemical_formula_sum            'C110 H138 B N8 Na O6 U2'
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 ?
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2016-05-16 deposited with the CCDC.
2017-03-02 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
(compiled Dec  3 2012,18:21:49)
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
(compiled Dec  3 2012,18:21:49)
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_diffrn_source                   'Enhance (Mo) X-ray Source'
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CrysAlisPro, Agilent Technologies,
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Analytical numeric absorption correction using a multifaceted crystal
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(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            BROWN
_exptl_crystal_density_diffrn    1.376
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_refine_ls_restrained_S_all      1.077
_refine_ls_R_factor_all          0.0948
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0270P)^2^+78.9178P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0996
_refine_ls_wR_factor_ref         0.1078
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5446
_reflns_number_total             7555
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7sc00382j2.cif
_cod_data_source_block           shelx_2-Na
_cod_depositor_comments
'Adding full bibliography for 1545549--1545553.cif.'
_cod_database_code               1545553
_shelxl_version_number           2014-3
_shelx_res_checksum              53498