Ligand-enabled multiple absolute stereocontrol in metal-catalysed cycloaddition for construction of contiguous all-carbon quaternary stereocentres.
Ohmatsu, Kohsuke; Imagawa, Naomichi; Ooi, Takashi; Nature chemistry 6 (2014) 47–51; doi:10.1038/nchem.1796

data_1513787
_publ_section_title
;
 Ligand-enabled multiple absolute stereocontrol in metal-catalysed
 cycloaddition for construction of contiguous all-carbon quaternary
 stereocentres.
;
_journal_issue                   1
_journal_name_full               'Nature chemistry'
_journal_page_first              47
_journal_page_last               51
_journal_paper_doi               10.1038/nchem.1796
_journal_volume                  6
_journal_year                    2014
_chemical_absolute_configuration S,R,S
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_computing_cell_refinement       'Bruker SMART'
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_computing_molecular_graphics    'Bruker SHELXTL'
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_exptl_crystal_density_method    'not measured'
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0673P)^2^+0.3279P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/Nature/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Empirical'
changed to 'empirical' according to
/usr/data/users/saulius/automatic-downloads/current/Nature/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)
_cod_database_code               1513787