An unexpected oxidation: NaK~5~Cl~2~(S~2~O~6~)~2~ revisited
Harrison, William T. A.; Plater, M. John; Acta Crystallographica Section E 73 (2017) 188–191; doi:10.1107/S2056989017000494

data_2242020
_publ_section_title
;
 An unexpected oxidation: NaK~5~Cl~2~(S~2~O~6~)~2~ revisited
;
_journal_coeditor_code           WM5357
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              188
_journal_page_last               191
_journal_paper_doi               10.1107/S2056989017000494
_journal_volume                  73
_journal_year                    2017
_chemical_formula_iupac          'Na K5 Cl2 (S2 O6)2'
_chemical_formula_moiety         'Na K5 Cl2 (S2 O6)2'
_chemical_formula_sum            'Cl2 K5 Na O12 S4'
_chemical_formula_weight         609.63
_chemical_name_systematic
;
Sodium pentapotassium dichloride bis(dithionate)
;
_space_group_crystal_system      tetragonal
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_space_group_name_Hall           '-P 4a'
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_symmetry_space_group_name_Hall  '-P 4a'
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_computing_cell_refinement
;
CrystalClear (Rigaku, 2010)
;
_computing_data_collection
;
CrystalClear (Rigaku, 2010)
;
_computing_data_reduction
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CrystalClear (Rigaku, 2010)
;
_computing_molecular_graphics
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ORTEP-3 for Windows (Farrugia, 2012) and ATOMS (Dowty, 1999)
;
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SHELXL2014 (Sheldrick, 2015b)
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SHELXL2014 (Sheldrick, 2015b)
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SHELXT (Sheldrick, 2015a)
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_exptl_absorpt_process_details
;
(SADABS; Sheldrick, 2004)
;
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0242P)^2^+0.4886P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_database_fobs_code 2242020