Sm(II) reduction chemistry of heteroalkynes: stable adducts, reductive coupling, reductive C-C/C-N bond cleavage and trapping of the tert-butyl fragment with bulky nitriles, phosphaalkynes and isonitriles.
Gardiner, Michael G.; James, Adam N.; Jones, Cameron; Schulten, Christian; Dalton transactions (Cambridge, England : 2003) 39 (2010) 6864–6870; doi:10.1039/c002778b

data_7025680
_publ_section_title
;
 Sm(II) reduction chemistry of heteroalkynes: stable adducts, reductive
 coupling, reductive C-C/C-N bond cleavage and trapping of the tert-butyl
 fragment with bulky nitriles, phosphaalkynes and isonitriles.
;
_journal_issue                   29
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6864
_journal_page_last               6870
_journal_paper_doi               10.1039/c002778b
_journal_volume                  39
_journal_year                    2010
_chemical_formula_moiety         '(C117 H162 N15 Sm3), (C6 H6)'
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;
?
;
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;
'X-SEED (Barbour, 2008) and ORTEPIII (Farrugia, 1998)'
;
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'calc w=1/[\s^2^(Fo^2^)+(0.1150P)^2^+139.0356P] where P=(Fo^2^+2Fc^2^)/3'
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;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Trigonal' changed to 'trigonal'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
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