Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO<sub>2</sub> reduction and enhanced proton reduction.
Gerschel, P.; Warm, K.; Farquhar, E. R.; Englert, U.; Reback, M. L.; Siegmund, D.; Ray, K.; Apfel, U.-P.; Dalton transactions (Cambridge, England : 2003) 48 (2019) 5923–5932; doi:10.1039/c8dt04740e

data_7048472
_publ_section_title
;
 Sulfur substitution in a Ni(cyclam) derivative results in lower
 overpotential for CO<sub>2</sub> reduction and enhanced proton reduction.
;
_journal_issue                   18
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5923
_journal_page_last               5932
_journal_paper_doi               10.1039/c8dt04740e
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C14 H28 Cl2 N4 Ni O9 S2'
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_space_group_name_Hall           '-I 2ya'
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_symmetry_space_group_name_Hall  '-I 2ya'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2017-03-21 deposited with the CCDC.
2018-12-26 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0754P)^2^+94.9081P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt04740e2.cif
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_cod_depositor_comments          'Adding full bibliography for 7048472.cif.'
_cod_database_code               7048472
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