N-Benzoylbenzamidinate complexes of aluminium: highly efficient initiators for the ring-opening polymerization of ε-caprolactone.
Bakthavachalam, K.; Rajagopal, Ashwene; Dastagiri Reddy, N.; Dalton transactions (Cambridge, England : 2003) 43 (2014) 14816–14823; doi:10.1039/c4dt02026j

data_7031990
_publ_section_title
;
 N-Benzoylbenzamidinate complexes of aluminium: highly efficient
 initiators for the ring-opening polymerization of \e-caprolactone.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14816
_journal_page_last               14823
_journal_paper_doi               10.1039/c4dt02026j
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C28 H33 Al N2 O'
_chemical_formula_weight         440.54
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-I 2ya'
_space_group_name_H-M_alt        'I 1 2/a 1'
_symmetry_space_group_name_Hall  '-I 2ya'
_symmetry_space_group_name_H-M   'I 1 2/a 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
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_cell_angle_gamma                90
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_computing_cell_refinement
;
'Mon Oct 21 17:49:17 2013'
;
_computing_data_collection
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'Mon Oct 21 17:49:17 2013'
;
_computing_data_reduction
;
'Mon Oct 21 17:49:17 2013'
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_computing_molecular_graphics    ORTEP-III
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_computing_structure_solution    SHELX-2013
_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0477
_diffrn_reflns_av_unetI/netI     0.0473
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.877
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -27
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_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            17036
_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_reflns_theta_max         29.220
_diffrn_reflns_theta_min         2.730
_exptl_absorpt_coefficient_mu    0.103
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.56564
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
'Mon Oct 21 17:49:17 2013'
;
_exptl_crystal_colour            colorless
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_exptl_crystal_size_max          0.3
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_exptl_crystal_size_min          0.1
_refine_diff_density_max         0.533
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_refine_ls_number_reflns         5948
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_refine_ls_restrained_S_all      1.040
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0833P)^2^+3.0357P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                4642
_reflns_number_total             5948
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c4dt02026j2.cif
_cod_data_source_block           Compound1
_cod_depositor_comments
'Adding full bibliography for 7031990--7031992.cif.'
_cod_database_code               7031990