Palladium-Catalyzed Enantioselective Cyclization of Silyloxy-1,6-Enynes
Britton K. Corkey; F. Dean Toste; Journal of the American Chemical Society 129 (2007) 2764–2765; doi:10.1021/ja068723r

data_4109155
_publ_section_title
;
 Palladium-Catalyzed Enantioselective Cyclization of Silyloxy-1,6-Enynes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              2764
_journal_page_last               2765
_journal_paper_doi               10.1021/ja068723r
_journal_volume                  129
_journal_year                    2007
_chemical_formula_sum            'C55 H46 Cl6 F6 O8 P2 Pd S2'
_chemical_formula_weight         1394.14
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      4
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_audit_creation_date             'Wed Oct  4 10:24:41 2006'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90
_cell_angle_beta                 107.734(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.940(2)
_cell_length_b                   19.177(4)
_cell_length_c                   16.000(3)
_cell_measurement_reflns_used    3786
_cell_measurement_temperature    153.2
_cell_measurement_theta_max      26.5
_cell_measurement_theta_min      3.5
_cell_volume                     2905.0(10)
_computing_cell_refinement       'Bruker-AXS SAINT v6.40'
_computing_data_collection       'Bruker-AXS SMART v5.054'
_computing_data_reduction        'Bruker-AXS SAINT v6.40'
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
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_diffrn_measured_fraction_theta_max 1.5873
_diffrn_measurement_device_type  'Bruker SMART 1000'
_diffrn_measurement_method       \w-scans
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
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_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       18
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_diffrn_reflns_theta_full        26.45
_diffrn_reflns_theta_max         26.45
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
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_exptl_absorpt_coefficient_mu    0.794
_exptl_absorpt_correction_T_max  0.953
_exptl_absorpt_correction_T_min  0.877
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            colorless
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_exptl_crystal_description       bladelike
_exptl_crystal_F_000             1408.00
_exptl_crystal_size_max          0.410
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.060
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_refine_diff_density_min         -0.37
_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00022|Fo|^2^]'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            ja068723rsi20061214_085832.cif
_cod_data_source_block           Britt_Corkey_Pd_(superliga
_cod_original_sg_symbol_H-M      'P 21 '
_cod_original_formula_sum        'C55 H46 Cl6 F6 O8 P2 Pd S2 '
_cod_database_code               4109155