Preparation of a uranium metallacyclocumulene and its reactivity towards unsaturated organic molecules.
Zhang, Lei; Hou, Guohua; Zi, Guofu; Ding, Wanjian; Walter, Marc D.; Dalton transactions (Cambridge, England : 2003) 46 (2017) 3716–3728; doi:10.1039/c7dt00396j

data_7042329
_publ_section_title
;
 Preparation of a uranium metallacyclocumulene and its reactivity towards
 unsaturated organic molecules.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3716
_journal_page_last               3728
_journal_paper_doi               10.1039/c7dt00396j
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C42 H52 U'
_chemical_formula_sum            'C42 H52 U'
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_chemical_name_systematic
; 
 ? 
;
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_space_group_name_Hall           'I -4 2bw'
_space_group_name_H-M_alt        'I -4 2 d'
_symmetry_space_group_name_Hall  'I -4 2bw'
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_audit_update_record
;
2017-01-24 deposited with the CCDC.
2017-02-28 downloaded from the CCDC.
;
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_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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; 
 Refined as an inversion twin. 
;
_refine_ls_abs_structure_Flack   0.53(2)
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0441P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7042322--7042330.cif.'
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