Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds.
Lin, Hsiu-Jung; Lutz, Sean; O'Kane, Catherine; Zeller, Matthias; Chen, Chun-Hsing; Al Assil, Talal; Lee, Wei-Tsung; Dalton transactions (Cambridge, England : 2003) 47 (2018) 3243–3247; doi:10.1039/c7dt04928e

data_7045408
_publ_section_title
;
 Synthesis and characterization of an iron complex bearing a hemilabile
 NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3243
_journal_page_last               3247
_journal_paper_doi               10.1039/c7dt04928e
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C40 H62 Fe N5 O2 Si2'
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_audit_update_record
;
2017-01-06 deposited with the CCDC.
2018-01-26 downloaded from the CCDC.
;
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;  
SHELXL-2014/7 (Sheldrick, 2014), 
SHELXLE Rev714 (H\"ubschle et al., 2011)
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w=1/[\s^2^(Fo^2^)] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7dt04928e2.cif
_cod_data_source_block           Quest15mz331_0m
_cod_depositor_comments
'Adding full bibliography for 7045406--7045408.cif.'
_cod_original_cell_volume        4217.3(9)
_cod_database_code               7045408
_shelx_shelxl_version_number     2014/7
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_shelx_estimated_absorpt_t_max   0.969
_shelx_res_checksum              18353