Simple Access to Elusive α-Boryl Carbanions and Their Alkylation: An Umpolung Construction for Organic Synthesis.
Hong, Kai; Liu, Xun; Morken, James P.; Journal of the American Chemical Society 136 (2014) 10581–10584; doi:10.1021/ja505455z

data_4122271
_publ_section_title
;
 Simple Access to Elusive \a-Boryl Carbanions and Their Alkylation: An
 Umpolung Construction for Organic Synthesis.
;
_journal_issue                   30
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              10581
_journal_page_last               10584
_journal_paper_doi               10.1021/ja505455z
_journal_volume                  136
_journal_year                    2014
_chemical_formula_moiety         'C23 H29 B O3'
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_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
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;
Sheldrick, G.M. (2013). SADABS. Bruker AXS Inc. Madison, WI USA.
;
_exptl_crystal_colour            colorless
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'w=1/[\s^2^(Fo^2^)+(0.0473P)^2^+0.6998P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_file            ja505455z_si_003.cif
_cod_data_source_block           C23H29BO3
_cod_depositor_comments
;Adding full bibliography for 4122271.cif.

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_database_code               4122271
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_shelx_hkl_checksum              4180