Studies of the Ligand Effect on the Synthesis of Dialuminoxanes by Various β-Diketiminato Ligands
Ying Yang; Haipu Li; Chen Wang; Herbert W. Roesky; Inorganic Chemistry 51 (2012) 2204–2211; doi:10.1021/ic2021879

data_4328328
_publ_contact_author
;
Herbert W. ROESKY
;
_publ_contact_author_address
;
Institut fuer Anorganische Chemie
Universitaet Goettingen
Tammannstrasse 4, 37077 Goettingen (Germany)
;
_publ_contact_author_email       hroesky@gwdg.de
_publ_section_title
;
 Studies of the Ligand Effect on the Synthesis of Dialuminoxanes by
 Various \b-Diketiminato Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2204
_journal_page_last               2211
_journal_paper_doi               10.1021/ic2021879
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C132 H183 Al4 N4 O8'
_chemical_formula_weight         2061.74
_chemical_name_common            iPr_LAl(OH)(mu-O)Al(OAr*)2
_chemical_name_systematic
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 ? 
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CrysAlisPro, Oxford Diffraction Ltd.,
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.44 (release 25-10-2010 CrysAlis171 .NET)
(compiled Oct 25 2010,18:11:34)
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.44 (release 25-10-2010 CrysAlis171 .NET)
(compiled Oct 25 2010,18:11:34)
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_computing_molecular_graphics    'Bruker SHELXTL'
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_diffrn_ambient_temperature      173(2)
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_diffrn_measured_fraction_theta_max 0.998
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_diffrn_reflns_av_sigmaI/netI    0.0489
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CrysAlisPro, Oxford Diffraction Ltd.,
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empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.089
_exptl_crystal_description       block
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_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.338
_refine_diff_density_min         -0.561
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_refine_ls_number_reflns         11048
_refine_ls_number_restraints     40
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_refine_ls_R_factor_all          0.0850
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0659P)^2^+4.0439P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1425
_refine_ls_wR_factor_ref         0.1539
_reflns_number_gt                8542
_reflns_number_total             11048
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic2021879_si_002_01.cif
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