Intra-complex energy transfer of europium(III) complexes containing anthracene and phenanthrene moieties.
Osawa, Masahisa; Hoshino, Mikio; Wada, Tatsuo; Hayashi, Fumi; Osanai, Shuichi; The journal of physical chemistry. A 113 (2009) 10895–10902; doi:10.1021/jp905160w

data_1516356
_publ_section_title
;
 Intra-complex energy transfer of europium(III) complexes containing
 anthracene and phenanthrene moieties.
;
_journal_issue                   41
_journal_name_full               'The journal of physical chemistry. A'
_journal_page_first              10895
_journal_page_last               10902
_journal_paper_doi               10.1021/jp905160w
_journal_volume                  113
_journal_year                    2009
_chemical_formula_moiety         'C55 H49 Eu F18 O8 P2 '
_chemical_formula_sum            'C55 H49 Eu F18 O8 P2'
_chemical_formula_weight         1393.87
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                71.639(4)
_cell_angle_beta                 70.877(4)
_cell_angle_gamma                73.768(4)
_cell_formula_units_Z            2
_cell_length_a                   12.9551(8)
_cell_length_b                   15.8320(10)
_cell_length_c                   16.3342(9)
_cell_measurement_reflns_used    12780
_cell_measurement_temperature    90.1
_cell_measurement_theta_max      32.4
_cell_measurement_theta_min      1.4
_cell_volume                     2945.6(3)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SIR2004
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.040
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            48822
_diffrn_reflns_theta_full        30.04
_diffrn_reflns_theta_max         30.04
_exptl_absorpt_coefficient_mu    1.224
_exptl_absorpt_correction_T_max  0.907
_exptl_absorpt_correction_T_min  0.798
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
    Higashi, T. (1999). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.571
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1396.00
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_refine_diff_density_max         2.68
_refine_diff_density_min         -1.49
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     758
_refine_ls_number_reflns         17119
_refine_ls_R_factor_gt           0.0480
_refine_ls_shift/su_max          0.0020
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0686P)^2^+4.8024P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1244
_reflns_number_gt                15398
_reflns_number_total             17119
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            jp905160w_si_003.cif
_cod_data_source_block           '__Eu_phen2_'
_cod_original_formula_sum        'C55 H49 Eu F18 O8 P2 '
_cod_database_code               1516356