<i>catena</i>-Poly[[[bis(methanol-κ<i>O</i>)lead(II)]-μ-<i>N</i>'-[1-(pyridin-2-yl-κ<i>N</i>)ethylidene]isonicotinohydrazidato-κ^3^<i>N</i>',<i>O</i>:<i>N</i>^1^] perchlorate]
Shahverdizadeh, Gholam Hossein; Tiekink, Edward R. T.; Mirtamizdoust, Babak; Acta Crystallographica Section E 67 (2011) m1729–m1730; doi:10.1107/S1600536811046769

data_2232760
_publ_section_title
;
 <i>catena</i>-Poly[[[bis(methanol-\k<i>O</i>)lead(II)]-\m-<i>N</i>'-[1-(pyridin-2-yl-\k<i>N</i>)ethylidene]isonicotinohydrazidato-\k^3^<i>N</i>',<i>O</i>:<i>N</i>^1^]
 perchlorate]
;
_journal_coeditor_code           HG5133
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1729
_journal_page_last               m1730
_journal_paper_doi               10.1107/S1600536811046769
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Pb (C13 H11 N4 O) (C H4 O)2] Cl O4'
_chemical_formula_moiety         'C15 H19 N4 O3 Pb +, Cl O4 -'
_chemical_formula_sum            'C15 H19 Cl N4 O7 Pb'
_chemical_formula_weight         609.98
_chemical_name_systematic
;
<i>catena</i>-Poly[[[bis(methanol-\k<i>O</i>)lead(II)]-\m-
<i>N</i>'-[1-(pyridin-2-yl-\k<i>N</i>)ethylidene]isonicotinohydrazidato-
\k^3^<i>N</i>',<i>O</i>:<i>N</i>^1^] perchlorate]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.906(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.2122(14)
_cell_length_b                   13.4644(17)
_cell_length_c                   14.1451(18)
_cell_measurement_reflns_used    4546
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.04
_cell_measurement_theta_min      2.17
_cell_volume                     1981.2(4)
_computing_cell_refinement       'SAINT (Bruker, 2007)'
_computing_data_collection       'SMART (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics
;
ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)
;
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0271
_diffrn_reflns_av_sigmaI/netI    0.0292
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            10367
_diffrn_reflns_theta_full        25.04
_diffrn_reflns_theta_max         25.04
_diffrn_reflns_theta_min         1.96
_exptl_absorpt_coefficient_mu    8.695
_exptl_absorpt_correction_T_max  0.1412
_exptl_absorpt_correction_T_min  0.1084
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.045
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1168
_exptl_crystal_size_max          0.46
_exptl_crystal_size_mid          0.43
_exptl_crystal_size_min          0.37
_refine_diff_density_max         0.966
_refine_diff_density_min         -0.981
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     255
_refine_ls_number_reflns         3492
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0378
_refine_ls_R_factor_gt           0.0237
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0282P)^2^+6.1832P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0591
_refine_ls_wR_factor_ref         0.0656
_reflns_number_gt                2641
_reflns_number_total             3492
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hg5133.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2232760
_cod_database_fobs_code          2232760