Rh-catalyzed sequential oxidative C-h and N-N bond activation: conversion of azines into isoquinolines with air at room temperature.
Han, Wenjia; Zhang, Guoying; Li, Guangxing; Huang, Hanmin; Organic letters 16 (2014) 3532–3535; doi:10.1021/ol501483k

data_1516664
_publ_section_title
;
 Rh-catalyzed sequential oxidative C-h and N-N bond activation: conversion
 of azines into isoquinolines with air at room temperature.
;
_journal_issue                   13
_journal_name_full               'Organic letters'
_journal_page_first              3532
_journal_page_last               3535
_journal_paper_doi               10.1021/ol501483k
_journal_volume                  16
_journal_year                    2014
_chemical_formula_moiety         'C22 H17 N'
_chemical_formula_sum            'C22 H17 N'
_chemical_formula_weight         295.36
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
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_symmetry_space_group_name_Hall  '-C 2yc'
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
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_computing_publication_material
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
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SHELX, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
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_diffrn_source                   'SuperNova (Mo) X-ray Source'
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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 w=1/[\s^2^(Fo^2^)+(0.0523P)^2^+1.7172P]
 where P=(Fo^2^+2Fc^2^)/3
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_refine_ls_weighting_scheme      calc
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_cod_depositor_comments          'Adding full bibliography for 1516664.cif.'
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_olex2_refinement_description
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1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C12(H12), C13(H13), C14(H14), C15(H15),
 C16(H16), C18(H18), C19(H19), C20(H20), C21(H21), C22(H22)
2.b Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C)
;
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