An efficient CO2 fixation reaction with epoxides catalysed by in situ formed blue vanadium catalyst from dioxovanadium(+5) complex: moisture enhanced and atmospheric oxygen retarded catalytic activity
Borah, Rakhimoni; Deori, Naranarayan; Brahma, Sanfaori; New Journal of Chemistry 44 (2020) 2547–2554; doi:10.1039/C9NJ04606B

data_7059196
_publ_section_title
;
 An efficient CO2 fixation reaction with epoxides catalysed by in situ
 formed blue vanadium catalyst from dioxovanadium(+5) complex: moisture
 enhanced and atmospheric oxygen retarded catalytic activity
;
_journal_issue                   6
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              2547
_journal_page_last               2554
_journal_paper_doi               10.1039/C9NJ04606B
_journal_volume                  44
_journal_year                    2020
_chemical_formula_moiety         C9H9N2O4V
_chemical_formula_sum            'C9 H9 N2 O4 V'
_chemical_formula_weight         260.12
_space_group_crystal_system      monoclinic
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_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2019-07-03 deposited with the CCDC.	2020-01-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0394
_diffrn_reflns_Laue_measured_fraction_full 0.999
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_diffrn_reflns_theta_min         3.106
_exptl_absorpt_coefficient_mu    1.026
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_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0308P)^2^+2.4912P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0956
_refine_ls_wR_factor_ref         0.1039
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1603
_reflns_number_total             1896
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9nj04606b2.cif
_cod_data_source_block           shelx_CCDC1
_cod_depositor_comments
;Adding full bibliography for 7059195--7059196.cif.

 Adding full bibliography for 7059195--7059196.cif.
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7059196
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              47510