Striking transformations of the hydroborylene ligand in a HB:\ρightarrow Ni<sup>II</sup> complex with isocyanides and CO.
Hadlington, T. J.; Szilvási, T; Driess, M.; Chemical science 9 (2018) 2595–2600; doi:10.1039/c7sc04792d

data_1548870
_publ_section_title
;
 Striking transformations of the hydroborylene ligand in a HB:\\rightarrow
 Ni<sup>II</sup> complex with isocyanides and CO.
;
_journal_issue                   9
_journal_name_full               'Chemical science'
_journal_page_first              2595
_journal_page_last               2600
_journal_paper_doi               10.1039/c7sc04792d
_journal_volume                  9
_journal_year                    2018
_chemical_formula_moiety         'C33 H59 B Cl N5 O'
_chemical_formula_sum            'C33 H59 B Cl N5 O'
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_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           '-P 2ac 2ab'
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_symmetry_space_group_name_Hall  '-P 2ac 2ab'
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_audit_update_record
;
2017-10-10 deposited with the CCDC.
2018-02-05 downloaded from the CCDC.
;
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_diffrn_measurement_method       '\w scans'
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43c (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1134P)^2^+3.7558P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1842
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_reflns_number_gt                5544
_reflns_number_total             6743
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7sc04792d2.cif
_cod_data_source_block           compound_4-Cy
_cod_depositor_comments
'Adding full bibliography for 1548865--1548871.cif.'
_cod_database_code               1548870
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.727
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_shelx_res_checksum              12211