Silane‒Allyl Coupling Reactions of Cp*(iPr2MeP)Fe(η3-C3H5) and Synthetic Access to the Hydrido‒Dinitrogen Complex Cp*(iPr2MeP)FeH(N2)
Smith, Patrick W.; Tilley, T. Don; Organometallics 34 (2015) 2134–; doi:10.1021/acs.organomet.5b00184

data_4085761
_publ_section_title
;
 Silane--Allyl Coupling Reactions of Cp*(iPr2MeP)Fe(\h3-C3H5) and
 Synthetic Access to the Hydrido--Dinitrogen Complex Cp*(iPr2MeP)FeH(N2)
;
_journal_issue                   11
_journal_name_full               Organometallics
_journal_page_first              2134
_journal_paper_doi               10.1021/acs.organomet.5b00184
_journal_volume                  34
_journal_year                    2015
_chemical_formula_moiety         'C17 H33 Fe N2 P'
_chemical_formula_sum            'C17 H33 Fe N2 P'
_chemical_formula_weight         352.27
_chemical_name_common            'Compound 5'
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
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Olex2 1.2
(compiled 2014.12.23 svn.r3118 for OlexSys, GUI svn.r4975)
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'w=1/[\s^2^(Fo^2^)+(0.1500P)^2^+60.0000P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 4085759--4085762.cif.'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C15(H15), C12(H12)
2.b Idealised Me refined as rotating group:
 C8(H8A,H8B,H8C), C6(H6A,H6B,H6C), C11(H11A,H11B,H11C), C17(H17A,H17B,H17C),
 C16(H16A,H16B,H16C), C13(H13A,H13B,H13C), C14(H14A,H14B,H14C), C7(H7A,H7B,H7C),
  C9(H9A,H9B,H9C), C10(H10A,H10B,H10C)
;
_shelx_res_checksum              85824
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_olex2_submission_special_instructions 'No special instructions were received'