Terphenyl(bisamino)phosphines: electron-rich ligands for gold-catalysis.
Siewert, Jan-Erik; Schumann, André; Fischer, Malte; Schmidt, Christoph; Taeufer, Tobias; Hering-Junghans, Christian; Dalton transactions (Cambridge, England : 2003) 49 (2020) 12354–12364; doi:10.1039/d0dt02435j

data_7705207
_publ_section_title
;
 Terphenyl(bisamino)phosphines: electron-rich ligands for gold-catalysis.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12354
_journal_page_last               12364
_journal_paper_doi               10.1039/d0dt02435j
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C33 H45 Au F3 N2 O3 P S'
_chemical_formula_sum            'C33 H45 Au F3 N2 O3 P S'
_chemical_formula_weight         834.70
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-07-07 deposited with the CCDC.	2020-08-18 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_cell_length_c                   16.3034(6)
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_cell_measurement_theta_min      2.44
_cell_volume                     6765.2(5)
_computing_cell_refinement       'SAINT (Bruker, 2013)'
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_diffrn_ambient_temperature      150(2)
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_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0142
_diffrn_reflns_Laue_measured_fraction_full 0.999
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_diffrn_source                   'fine-focus sealed tube'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2014)'
_exptl_crystal_colour            colorless
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_exptl_crystal_description       block
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
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_refine_ls_restrained_S_all      1.043
_refine_ls_R_factor_all          0.0188
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0188P)^2^+7.1019P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0382
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_reflns_number_gt                9016
_reflns_number_total             9877
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt02435j2.cif
_cod_data_source_block           ax1665_TerP_NEt2_2_Au_OTf_cmp3b
_cod_depositor_comments
'Adding full bibliography for 7705201--7705209.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
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_shelx_res_checksum              68281