Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer.
Kamio, Shintaro; Kageyuki, Ikuo; Osaka, Itaru; Hatano, Sayaka; Abe, Manabu; Yoshida, Hiroto; Chemical communications (Cambridge, England) 54 (2018) 9290–9293; doi:10.1039/c8cc05645e

data_7122059
_publ_section_title
;
 Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective
 B(aam) transfer.
;
_journal_issue                   67
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              9290
_journal_page_last               9293
_journal_paper_doi               10.1039/c8cc05645e
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C13 H18 B2 N2 O3'
_chemical_formula_weight         271.91
_chemical_name_common            (pin)B-B(aam)
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_update_record
;
2018-03-28 deposited with the CCDC.
2018-07-27 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 99.3700(10)
_cell_angle_gamma                90
_cell_formula_units_Z            8
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_cell_length_b                   17.9941(15)
_cell_length_c                   12.3197(10)
_cell_measurement_reflns_used    3437
_cell_measurement_temperature    173.0
_cell_measurement_theta_max      23.2156
_cell_measurement_theta_min      2.3607
_cell_volume                     2967.6(4)
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_diffrn_ambient_temperature      173.0
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker D8 goniometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  'multilayered conforcal mirror'
_diffrn_radiation_type           MoKa
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0291
_diffrn_reflns_av_unetI/netI     0.0333
_diffrn_reflns_limit_h_max       15
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_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -12
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_diffrn_reflns_theta_max         23.25
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_diffrn_source                   'rotating-anode X-ray tube'
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_exptl_absorpt_coefficient_mu    0.084
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_exptl_crystal_colour            colourless
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0579P)^2^+1.8782P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7122059--7122060.cif.'
_cod_database_code               7122059
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