A Boron Activating Effect Enables Cobalt-Catalyzed Asymmetric Hydrogenation of Sterically Hindered Alkenes.
Viereck, Peter; Krautwald, Simon; Pabst, Tyler P.; Chirik, Paul J.; Journal of the American Chemical Society 142 (2020) 3923–3930; doi:10.1021/jacs.9b12214

data_4134167
_publ_section_title
;
 A Boron Activating Effect Enables Cobalt-Catalyzed Asymmetric
 Hydrogenation of Sterically Hindered Alkenes.
;
_journal_issue                   8
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3923
_journal_page_last               3930
_journal_paper_doi               10.1021/jacs.9b12214
_journal_volume                  142
_journal_year                    2020
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;
 Flack x determined using 4516 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0760P)^2^+0.8550P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 4134166--4134167.cif.'
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