Tuning Triplet Energy Transfer of Hydroxamates as the Nitrene Precursor for Intramolecular C(sp<sup>3</sup>)-H Amidation.
Jung, Hoimin; Keum, Hyeyun; Kweon, Jeonguk; Chang, Sukbok; Journal of the American Chemical Society 142 (2020) 5811–5818; doi:10.1021/jacs.0c00868

data_4134412
_publ_section_title
;
 Tuning Triplet Energy Transfer of Hydroxamates as the Nitrene Precursor
 for Intramolecular C(sp<sup>3</sup>)-H Amidation.
;
_journal_issue                   12
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5811
_journal_page_last               5818
_journal_paper_doi               10.1021/jacs.0c00868
_journal_volume                  142
_journal_year                    2020
_chemical_formula_sum            'C24 H15 F6 N O4'
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_atom_sites_solution_hydrogens   mixed
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_diffrn_measurement_method       'omega scan'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0987P)^2^+4.7230P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             3760
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           PO19149_015
_cod_depositor_comments
'Adding full bibliography for 4134411--4134413.cif.'
_cod_original_cell_volume        4186.2(15)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4134412
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.993
_shelx_estimated_absorpt_t_max   0.998
_shelx_res_checksum              8856
_shelx_hkl_checksum              18521