Preparation and Thermal Reaction of Tetrastannapalladacyclopentane. Sn−Sn Bond Formation and Cleavage
Tanabe, Makoto; Hanzawa, Masaya; Osakada, Kohtaro; Organometallics 29 (2010) 3535–; doi:10.1021/om100281t

data_4066081
_publ_section_title
;
 Preparation and Thermal Reaction of Tetrastannapalladacyclopentane.
 Sn&#x2212;Sn Bond Formation and Cleavage
;
_journal_issue                   16
_journal_name_full               Organometallics
_journal_page_first              3535
_journal_paper_doi               10.1021/om100281t
_journal_volume                  29
_journal_year                    2010
_chemical_formula_moiety         'C24 H56 P8 Pd2 '
_chemical_formula_sum            'C24 H56 P8 Pd2'
_chemical_formula_weight         805.30
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 92.983(3)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            2
_cell_length_a                   11.778(3)
_cell_length_b                   11.869(3)
_cell_length_c                   14.363(3)
_cell_measurement_reflns_used    5469
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.2
_cell_volume                     2005.1(8)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SIR97
_diffrn_ambient_temperature      113(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.935
_diffrn_measured_fraction_theta_max 0.935
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.016
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            12680
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    1.229
_exptl_absorpt_correction_T_max  0.863
_exptl_absorpt_correction_T_min  0.775
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.334
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             824.00
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.11
_refine_diff_density_min         -0.66
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     173
_refine_ls_number_reflns         4304
_refine_ls_R_factor_all          0.0366
_refine_ls_R_factor_gt           0.0344
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0625P)^2^+2.4545P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0947
_refine_ls_wR_factor_ref         0.0966
_reflns_number_gt                4071
_reflns_number_total             4304
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om100281t_si_001.cif
_cod_data_source_block           '__Pd(dmpe)n'
_cod_original_cell_volume        2005.1(7)
_cod_original_formula_sum        'C24 H56 P8 Pd2 '
_cod_database_code               4066081