Structural variation of transition metal-organic frameworks using deep eutectic solvents with different hydrogen bond donors.
Zhao, Ming-Yu; Zhu, Jian-Nan; Li, Peng; Li, Wei; Cai, Ting; Cheng, Fang-Fang; Xiong, Wei-Wei; Dalton transactions (Cambridge, England : 2003) 48 (2019) 10199–10209; doi:10.1039/c9dt01050e

data_7701614
_publ_section_title
;
 Structural variation of transition metal-organic frameworks using deep
 eutectic solvents with different hydrogen bond donors.
;
_journal_issue                   27
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10199
_journal_page_last               10209
_journal_paper_doi               10.1039/c9dt01050e
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         '(C5 H N2 O4 Mn), K0.63, N0.37 H1.48'
_chemical_formula_sum            'C5 H K0.63 Mn N2.37 O4'
_chemical_formula_weight         237.91
_space_group_crystal_system      tetragonal
_space_group_IT_number           135
_space_group_name_Hall           '-P 4c 2ab'
_space_group_name_H-M_alt        'P 42/m b c'
_atom_sites_solution_hydrogens   difmap
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2019-05-22 deposited with the CCDC.	2019-06-03 downloaded from the CCDC.
;
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_cell_measurement_theta_min      4.0070
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_diffrn_ambient_temperature      293(2)
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_diffrn_measured_fraction_theta_max 0.936
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       '\w scans'
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_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_theta_max         29.231
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_exptl_absorpt_correction_T_max  1.00000
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0586
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0286P)^2^+1.5361P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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