A Total Synthesis of Paeoveitol.
Xu, Lun; Liu, Fengyi; Xu, Li-Wen; Gao, Ziwei; Zhao, Yu-Ming; Organic letters 18 (2016) 3698–3701; doi:10.1021/acs.orglett.6b01736

data_1543628
_publ_section_title
;
 A Total Synthesis of Paeoveitol.
;
_journal_issue                   15
_journal_name_full               'Organic letters'
_journal_page_first              3698
_journal_page_last               3701
_journal_paper_doi               10.1021/acs.orglett.6b01736
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C24 H22 O5 S'
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_computing_data_collection       'APEX2 (Bruker, 2010)'
_computing_data_reduction        'SAINT (Bruker, 2009);XPREP(Sheldrick,2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      153(2)
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_diffrn_measurement_device_type  'Bruker D8 Request'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.988
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_diffrn_reflns_theta_max         26.458
_diffrn_reflns_theta_min         2.191
_exptl_absorpt_coefficient_mu    0.192
_exptl_crystal_colour            colorous
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_exptl_crystal_description       needle
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_refine_diff_density_max         0.575
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_refine_diff_density_rms         0.048
_refine_ls_extinction_method     none
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_refine_ls_number_reflns         4167
_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0391
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0477P)^2^+0.7217P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0991
_refine_ls_wR_factor_ref         0.1009
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_reflns_number_gt                3934
_reflns_number_total             4167
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 1543628--1543629.cif.'
_cod_database_code               1543628
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