Synthesis of N-[(dialkylamino)methyl]acrylamides and N-[(dialkylamino)methyl]methacrylamides from Schiff base salts: useful building blocks for smart polymers.
Alzahrani, Abdullah; Mirallai, Styliana I.; Chalmers, Benjamin A.; McArdle, Patrick; Aldabbagh, Fawaz; Organic & biomolecular chemistry 16 (2018) 4108–4116; doi:10.1039/c8ob00811f

data_7156262
_publ_section_title
;
 Synthesis of N-[(dialkylamino)methyl]acrylamides and
 N-[(dialkylamino)methyl]methacrylamides from Schiff base salts: useful
 building blocks for smart polymers.
;
_journal_issue                   22
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              4108
_journal_page_last               4116
_journal_paper_doi               10.1039/c8ob00811f
_journal_volume                  16
_journal_year                    2018
_chemical_formula_sum            'C8 H18 Cl N O'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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;
2018-01-24 deposited with the CCDC.
2018-05-09 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_measurement_temperature    150.0(1)
_cell_measurement_theta_max      28.0840
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; 
crysalispro, agilent technologies, 
version 1.171.37.35 (release 13-08-2014 crysalis171 .net) 
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;
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crysalispro, agilent technologies, 
version 1.171.37.35 (release 13-08-2014 crysalis171 .net) 
(compiled aug 13 2014,18:06:01) 
;
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; 
crysalispro, agilent technologies, 
version 1.171.37.35 (release 13-08-2014 crysalis171 .net) 
(compiled aug 13 2014,18:06:01) 
;
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'ORTEX - P. McArdle, J.Appl.Cryst.,1995,28,65-65.'
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'Oscail - P. McArdle, J.Appl.Cryst.,2017,50,320-326.'
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_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0709
_diffrn_reflns_av_unetI/netI     0.0725
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; 
crysalispro, agilent technologies, 
version 1.171.37.35 (release 13-08-2014 crysalis171 .net) 
(compiled aug 13 2014,18:06:01) 
;
_exptl_crystal_colour            Colourless
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_exptl_crystal_description       Parallelepiped
_exptl_crystal_F_000             392
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_refine_ls_number_reflns         2345
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0600P)^2^+2.5766P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2083
_refine_ls_wR_factor_ref         0.2182
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1949
_reflns_number_total             2345
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8ob00811f2.cif
_cod_data_source_block           azosm
_cod_depositor_comments
'Adding full bibliography for 7156261--7156262.cif.'
_cod_database_code               7156262
_shelx_shelxl_version_number     2017/1
_shelx_estimated_absorpt_t_min   0.846
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_shelx_res_checksum              36724