Oxidative Addition Versus Substitution Reactions of Group 14 Dialkylamino Metalylenes with Pentafluoropyridine
Prinson P. Samuel; Amit Pratap Singh; Sankaranarayana Pillai Sarish; Julia Matussek; Ina Objartel; Herbert W. Roesky; Dietmar Stalke; Inorganic Chemistry 52 (2013) 1544–1549; doi:10.1021/ic302344a

data_4333727
_publ_section_title
;
 Oxidative Addition Versus Substitution Reactions of Group 14 Dialkylamino
 Metalylenes with Pentafluoropyridine
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1544
_journal_page_last               1549
_journal_paper_doi               10.1021/ic302344a
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'C22 H29 F5 N4 Si'
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_cell_angle_beta                 92.283(10)
_cell_angle_gamma                115.677(10)
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_cell_length_b                   10.2020(10)
_cell_length_c                   13.9106(10)
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_cell_measurement_theta_min      2.223
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_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker Smart Apex II with D8-Goniometer'
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_diffrn_reflns_limit_l_min       -18
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_reflns_theta_min         1.471
_exptl_absorpt_coefficient_mu    0.156
_exptl_absorpt_correction_T_max  0.7456
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_refine_diff_density_min         -0.269
_refine_diff_density_rms         0.045
_refine_ls_extinction_method     none
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_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0433
_refine_ls_R_factor_gt           0.0358
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0378P)^2^+0.5990P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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_cod_database_code               4333727
_diffrn_reflns_sigmai/neti       0.0247
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_shelx_res_checksum              87399