Photo-activation of d(0) niobium imido azides: en route to nitrido complexes.
Camp, Clément; Grant, Lauren N.; Bergman, Robert G.; Arnold, John; Chemical communications (Cambridge, England) 52 (2016) 5538–5541; doi:10.1039/c6cc02081j

data_7124623
_publ_section_title
;
 Photo-activation of d(0) niobium imido azides: en route to nitrido
 complexes.
;
_journal_issue                   32
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              5538
_journal_page_last               5541
_journal_paper_doi               10.1039/c6cc02081j
_journal_volume                  52
_journal_year                    2016
_chemical_formula_moiety         'C57 H54 B F15 N4 Nb, C4 H12 N, C6 H6'
_chemical_formula_sum            'C67 H72 B F15 N5 Nb'
_chemical_formula_weight         1336.01
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-03-08 deposited with the CCDC.
2016-03-23 downloaded from the CCDC.
;
_cell_angle_alpha                84.127(3)
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_cell_angle_gamma                73.602(3)
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_cell_measurement_theta_min      2.29
_cell_volume                     6241.6(7)
_computing_cell_refinement       'Bruker SAINT'
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_computing_structure_solution    SIR-2014
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_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0857P)^2^+14.4699P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_res_checksum              21681
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