Catalytic hydroboration of aldehydes and ketones with an electron-rich acyclic metallasilylene.
Kapp, Leon; Wölper, Christoph; Siera, Hannah; Haberhauer, Gebhard; Schulz, Stephan; Chemical science 15 (2024) 4161–4170; doi:10.1039/d3sc06842k

data_1570976
_publ_section_title
;
 Catalytic hydroboration of aldehydes and ketones with an electron-rich
 acyclic metallasilylene.
;
_journal_issue                   11
_journal_name_full               'Chemical science'
_journal_page_first              4161
_journal_page_last               4170
_journal_paper_doi               10.1039/d3sc06842k
_journal_volume                  15
_journal_year                    2024
_chemical_formula_sum            'C58 H83 Cl Ga N4 O Si'
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_audit_update_record
;
2023-06-19 deposited with the CCDC.	2024-02-12 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker D8 Venture (Photon II detector)'
_diffrn_measurement_method       'Data collection strategy APEX 3/Queen'
_diffrn_radiation_monochromator  'multilayer mirror'
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_source                   'micro-focus sealed tube'
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_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0536P)^2^+2.1634P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1064
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 1570976--1570977.cif.'
_cod_database_code               1570976
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_shelx_estimated_absorpt_t_min   0.764
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_shelx_res_checksum              62051