The coordination chemistry of phosphinidene sulfides. Synthesis and catalytic properties of Pd<sub>4</sub> and Pt<sub>4</sub> clusters.
Chai, Jinkui; Tian, Rongqiang; Wu, Di; Wei, Donghui; Xu, Qun; Duan, Zheng; Mathey, François; Dalton transactions (Cambridge, England : 2003) 47 (2018) 13342–13344; doi:10.1039/c8dt02648c

data_7047487
_publ_section_title
;
 The coordination chemistry of phosphinidene sulfides. Synthesis and
 catalytic properties of Pd<sub>4</sub> and Pt<sub>4</sub> clusters.
;
_journal_issue                   38
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13342
_journal_page_last               13344
_journal_paper_doi               10.1039/c8dt02648c
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C72 H60 P6 Pt4 S3'
_chemical_formula_weight         1987.56
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2018-08-16 deposited with the CCDC.
2018-09-10 downloaded from the CCDC.
;
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_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      70.506
_cell_measurement_theta_min      3.974
_cell_volume                     3770.42(14)
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_av_R_equivalents  0.0280
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_diffrn_reflns_Laue_measured_fraction_full 0.986
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_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
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_diffrn_reflns_point_group_measured_fraction_full 0.986
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_exptl_absorpt_coefficient_mu    15.823
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_exptl_absorpt_correction_T_min  0.187
_exptl_absorpt_correction_type   gaussian
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.751
_exptl_crystal_description       prism
_exptl_crystal_F_000             1884
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_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef Fsqd
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;
 w=1/[\s^2^(Fo^2^)+(0.0537P)^2^+4.6482P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                11588
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7047486--7047489.cif.'
_cod_database_code               7047487
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