Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction.
Smirnov, Vladimir O.; Maslov, Anton S.; Kokorekin, Vladimir A.; Korlyukov, Alexander A.; Dilman, Alexander D.; Chemical communications (Cambridge, England) 54 (2018) 2236–2239; doi:10.1039/c8cc00245b

data_7121241
_publ_section_title
;
 Photoredox generation of the trifluoromethyl radical from borate
 complexes via single electron reduction.
;
_journal_issue                   18
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              2236
_journal_page_last               2239
_journal_paper_doi               10.1039/c8cc00245b
_journal_volume                  54
_journal_year                    2018
_chemical_formula_moiety         'C8 H7 B F5 N O3'
_chemical_formula_sum            'C8 H7 B F5 N O3'
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
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_atom_sites_solution_primary     dual
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Olex2 1.2
(compiled 2017.07.20 svn.r3457 for OlexSys, GUI svn.r5370)
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_audit_update_record
;
2018-01-10 deposited with the CCDC.
2018-02-05 downloaded from the CCDC.
;
_cell_angle_alpha                92.0770(10)
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_cell_angle_gamma                104.5810(10)
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_diffrn_radiation_type           MoK\a
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'SADABS-2014/5 (Bruker,2014/5) was used for absorption correction. wR2(int) was 0.1100 before and 0.0350 after correction. The Ratio of minimum to maximum transmission is 0.9105. The \l/2 correction factor is 0.00150.'
_exptl_crystal_colour            colourless
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0488P)^2^+0.1626P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7121241--7121242.cif.'
_cod_database_code               7121241
_shelxl_version_number           2014/6
_shelx_estimated_absorpt_t_max   0.949
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_olex2_refinement_description
;
;
_shelx_res_checksum              82560
_olex2_submission_special_instructions 'No special instructions were received'