Heterobimetallic alkoxysilyl cationic complexes: investigations into the displacement of a μ-η2-Si,O bridge by functional phosphine ligands
Blin, Joël; Braunstein, Pierre; Fischer, Jean; Kickelbick, Guido; Knorr, Michael; Morise, Xavier; Wirth, Tobias; Journal of the Chemical Society, Dalton Transactions  (1999) 2159–; doi:10.1039/a900390h

data_7027251
_publ_section_title
;
 Heterobimetallic alkoxysilyl cationic complexes: investigations into the
 displacement of a \m-\h2-Si,O bridge by functional phosphine ligands
;
_journal_issue                   13
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2159
_journal_paper_doi               10.1039/a900390h
_journal_year                    1999
_chemical_formula_moiety         'C51 H47 Cl F6 O P4 Pd'
_chemical_formula_sum            'C51 H47 Cl F6 O P4 Pd'
_chemical_formula_weight         1055.68
_chemical_name_systematic        ' ?'
_space_group_IT_number           14
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_cell_length_c                   21.055(6)
_cell_measurement_reflns_used    24
_cell_measurement_temperature    294
_cell_measurement_theta_max      19.5
_cell_measurement_theta_min      18.0
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_exptl_absorpt_correction_type   psi_scan_(North,_Phillips,_Mathews,_1968)
_exptl_crystal_colour            yellow
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_refine_ls_shift/su_max          0.018
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 4Fo^2^/(\s^2^(Fo^2^) + 0.0064 Fo^4^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.139
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_reflns_number_gt                8137
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_reflns_threshold_expression     >3.0\s(I)
_cod_data_source_file            900390hsup1.cif
_cod_data_source_block           st17
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value '4Fo^2^/(\s^2^(Fo^2^) + 0.0064
Fo^4^)' was changed to 'calc'. New tag '_refine_ls_weighting_details'
was created. The value of the new tag was set to 'w =
4Fo^2^/(\s^2^(Fo^2^) + 0.0064 Fo^4^)'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        4991(4)
_cod_database_code               7027251