Synthesis of heteroleptic gallium-substituted antimony hydrides by stepwise β-H elimination.
Helling, Christoph; Wölper, Christoph; Schulz, Stephan; Dalton transactions (Cambridge, England : 2003) 49 (2020) 11835–11842; doi:10.1039/d0dt01937b

data_7704820
_publ_section_title
;
 Synthesis of heteroleptic gallium-substituted antimony hydrides by
 stepwise \b-H elimination.
;
_journal_issue                   34
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11835
_journal_page_last               11842
_journal_paper_doi               10.1039/d0dt01937b
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'B3 Ba2 Cd O9 Sc'
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;
2020-04-28 deposited with the CCDC.	2020-07-08 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_diffrn_reflns_theta_min         2.518
_exptl_absorpt_coefficient_mu    12.375
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_exptl_crystal_description       block
_exptl_crystal_F_000             536
_refine_diff_density_max         0.847
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_refine_diff_density_rms         0.147
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.098
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     145
_refine_ls_number_reflns         1954
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.098
_refine_ls_R_factor_all          0.0167
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0166P)^2^+0.8997P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                1869
_reflns_number_total             1954
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt01937b2.cif
_cod_data_source_block           Ba2CdScB3O9
_cod_depositor_comments
'Adding full bibliography for 7704820--7704822.cif.'
_cod_database_code               7704820
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              41542
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