Regulating iminophosphorane PN bond reactivity through geometric constraints with cage-shaped triarylphosphines.
Hu, Lei; Chakraborty, Sayandip; Tumanov, Nikolay; Wouters, Johan; Robiette, Raphaël; Berionni, Guillaume; Chemical communications (Cambridge, England) 60 (2024) 7073–7076; doi:10.1039/d4cc01868k

data_7133211
_publ_section_title
;
 Regulating iminophosphorane P&#xe001;N bond reactivity through geometric
 constraints with cage-shaped triarylphosphines.
;
_journal_issue                   55
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              7073
_journal_page_last               7076
_journal_paper_doi               10.1039/d4cc01868k
_journal_volume                  60
_journal_year                    2024
_chemical_formula_moiety         '2(C19 H13 O P), H2 O'
_chemical_formula_sum            'C38 H28 O3 P2'
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_chemical_name_common            '9-phosphatriptycene oxide hemihydrate'
_chemical_name_systematic        '9-phosphatriptycene oxide hemihydrate'
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_space_group_name_Hall           '-P 2ac 2ab'
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;
2024-04-10 deposited with the CCDC.	2024-04-28 downloaded from the CCDC.
;
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;
Krause, L., Herbst-Irmer, R., Sheldrick, G. M., Stalke, D. (2015).
"Comparison of silver and molybdenum microfocus X-ray sources for
single-crystal structure determination"
J. Appl. Cryst. 48, 3-10.
doi:10.1107/S1600576714022985
;
_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0708P)^2^+3.7545P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7133202--7133219.cif.'
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