Reactivity of platinum alkyne complexes towards N-fluorobenzenesulfonimide: formation of platinum compounds bearing a β-fluorovinyl ligand.
Berger, Josefine; Braun, Thomas; Herrmann, Roy; Braun, Beatrice; Dalton transactions (Cambridge, England : 2003) 44 (2015) 19553–19565; doi:10.1039/c5dt02306h

data_7036274
_publ_section_title
;
 Reactivity of platinum alkyne complexes towards
 N-fluorobenzenesulfonimide: formation of platinum compounds bearing a
 \b-fluorovinyl ligand.
;
_journal_issue                   45
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              19553
_journal_page_last               19565
_journal_paper_doi               10.1039/c5dt02306h
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C26 H34 F4 N O2 P Pt'
_chemical_formula_sum            'C26 H34 F4 N O2 P Pt'
_chemical_formula_weight         694.60
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2015-03-19 deposited with the CCDC.
2015-08-06 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 122.476(6)
_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_b                   16.0871(16)
_cell_length_c                   16.4945(16)
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_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.65
_cell_measurement_theta_min      2.37
_cell_volume                     2643.0(5)
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Stoe IPDS2theta'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0543
_diffrn_reflns_av_unetI/netI     0.0362
_diffrn_reflns_laue_measured_fraction_full 0.999
_diffrn_reflns_laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            33481
_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.426
_diffrn_reflns_theta_min         2.171
_exptl_absorpt_coefficient_mu    5.421
_exptl_absorpt_correction_T_max  0.272
_exptl_absorpt_correction_T_min  0.118
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'PLATON, Spek 2003'
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.746
_exptl_crystal_description       block
_exptl_crystal_F_000             1368
_exptl_crystal_size_max          0.420
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_exptl_crystal_size_min          0.240
_refine_diff_density_max         0.780
_refine_diff_density_min         -2.377
_refine_diff_density_rms         0.138
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     322
_refine_ls_number_reflns         7288
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.920
_refine_ls_R_factor_all          0.0428
_refine_ls_R_factor_gt           0.0265
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0357P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0551
_refine_ls_wR_factor_ref         0.0596
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5391
_reflns_number_total             7288
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt02306h1.cif
_cod_data_source_block           complex9_fz27_2
_cod_depositor_comments
'Adding full bibliography for 7036273--7036275.cif.'
_cod_database_code               7036274
_shelx_estimated_absorpt_t_min   0.209
_shelx_estimated_absorpt_t_max   0.356
_shelxl_version_number           2013-4
_shelx_res_checksum              94077