Directed <i>cis</i>-hydrosilylation of borylalkynes to borylsilylalkenes.
Stefanowska, Kinga; Sokolnicki, Tomasz; Walkowiak, Jędrzej; Czapik, Agnieszka; Franczyk, Adrian; Chemical communications (Cambridge, England) 58 (2022) 12046–12049; doi:10.1039/d2cc04318a

data_7130862
_publ_section_title
;
 Directed <i>cis</i>-hydrosilylation of borylalkynes to borylsilylalkenes.
;
_journal_issue                   86
_journal_name_full               'Chemical communications (Cambridge, England)'
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_journal_page_last               12049
_journal_paper_doi               10.1039/d2cc04318a
_journal_volume                  58
_journal_year                    2022
_chemical_formula_moiety         'C32 H68 B2 O5 Si4'
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_audit_update_record
;
2021-09-02 deposited with the CCDC.	2022-09-23 downloaded from the CCDC.
;
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.110a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0647P)^2^+1.9023P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1051
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_reflns_number_gt                3670
_reflns_number_total             4300
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d2cc04318a2.cif
_cod_data_source_block           DATA-II
_cod_depositor_comments
'Adding full bibliography for 7130861--7130865.cif.'
_cod_original_cell_volume        4181.33(7)
_cod_original_sg_symbol_H-M      'I 2/a'
_cod_database_code               7130862
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