Isomeric Complexes of [RuII(trpy)(L)Cl] (trpy = 2,2':6',2''-Terpyridine and HL = Quinaldic Acid): Preference of Isomeric Structural Form in Catalytic Chemoselective Epoxidation Process
Abhishek Dutta Chowdhury; Amit Das; Irshad K; Shaikh M. Mobin; Goutam Kumar Lahiri; Inorganic Chemistry 50 (2011) 1775–1785; doi:10.1021/ic102195w

data_4324510
_publ_section_title
;
 Isomeric Complexes of [RuII(trpy)(L)Cl] (trpy = 2,2':6',2''-Terpyridine
 and HL = Quinaldic Acid): Preference of Isomeric Structural Form in
 Catalytic Chemoselective Epoxidation Process
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1775
_journal_page_last               1785
_journal_paper_doi               10.1021/ic102195w
_journal_volume                  50
_journal_year                    2011
_chemical_formula_sum            'C56 H40 Cl2 N11 O16 Ru2'
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_chemical_name_systematic
;
 ?
;
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_atom_sites_solution_secondary   difmap
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_computing_cell_refinement       'CrysAlis RED, Oxford Diffraction Ltd.,'
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_computing_data_reduction        'CrysAlis RED, Oxford Diffraction Ltd.,'
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_diffrn_measurement_device_type  'OXFORD DIFFRACTION XCALIBUR-S'
_diffrn_measurement_method       \w/q-scan
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;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            black
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_refine_ls_number_reflns         10827
_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0948
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1528P)^2^+0.3498P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_database_code               4324510