Redox properties and electron transfer in a triarylamine-substituted HS-Co(2+)/LS-Co(3+) redox couple.
Schnaubelt, Linda; Petzold, Holm; Speck, J Matthäus; Dmitrieva, Evgenia; Rosenkranz, Marco; Korb, Marcus; Dalton transactions (Cambridge, England : 2003) 46 (2017) 2690–2698; doi:10.1039/c6dt04748c

data_7041860
_publ_section_title
;
 Redox properties and electron transfer in a triarylamine-substituted
 HS-Co(2+)/LS-Co(3+) redox couple.
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2690
_journal_page_last               2698
_journal_paper_doi               10.1039/c6dt04748c
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C74 H56 Co N8 O2, 2(B F4)'
_chemical_formula_sum            'C74 H56 B2 Co F8 N8 O2'
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2016-11-27 deposited with the CCDC.
2017-01-27 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.31 (release 14-01-2014 CrysAlis171 .NET)
(compiled Jan 14 2014,18:38:05)
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CrysAlisPro, Agilent Technologies,
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(compiled Jan 14 2014,18:38:05)
Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.114
_exptl_crystal_description       plate
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_refine_ls_extinction_method     none
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_refine_ls_number_restraints     40
_refine_ls_restrained_S_all      1.082
_refine_ls_R_factor_all          0.0643
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0862P)^2^+2.2443P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1437
_refine_ls_wR_factor_ref         0.1504
_reflns_Friedel_coverage         0.000
_reflns_number_gt                12885
_reflns_number_total             15448
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7041860.cif.'
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