Mechanistic Investigations of Water Oxidation by a Molecular Cobalt Oxide Analogue: Evidence for a Highly Oxidized Intermediate and Exclusive Terminal Oxo Participation.
Nguyen, Andy I.; Ziegler, Micah S.; Oña-Burgos, Pascual; Sturzbecher-Hohne, Manuel; Kim, Wooyul; Bellone, Donatela E.; Tilley, T. Don; Journal of the American Chemical Society 137 (2015) 12865–12872; doi:10.1021/jacs.5b08396

data_4124554
_publ_section_title
;
 Mechanistic Investigations of Water Oxidation by a Molecular Cobalt Oxide
 Analogue: Evidence for a Highly Oxidized Intermediate and Exclusive
 Terminal Oxo Participation.
;
_journal_issue                   40
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              12865
_journal_page_last               12872
_journal_paper_doi               10.1021/jacs.5b08396
_journal_volume                  137
_journal_year                    2015
_chemical_formula_moiety         'C28 H33 Co4 N4 O12, P F6, 1.5(O), C Cl2'
_chemical_formula_sum            'C29 H33 Cl2 Co4 F6 N4 O13.5 P'
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_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0155P)^2^+211.9211P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 4124554--4124556.cif.'
_cod_original_formula_sum        'C29 H33 Cl2 Co4 F6 N4 O13.50 P'
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