A short platinum to silver dative bond and its application in the construction of extended structures: syntheses and structures of Ag2[Pt(ox)2]·2H2O and [Ag(H2O)]2[Ag2(CF3SO3)4][Pt(acac)2]2
Yamaguchi, Tadashi; Yamazaki, Fumie; Ito, Tasuku; Journal of the Chemical Society, Dalton Transactions  (1999) 273–; doi:10.1039/a808678h

data_7027167
_publ_section_title
;
 A short platinum to silver dative bond and its application in the
 construction of extended structures: syntheses and structures of
 Ag2[Pt(ox)2]&#x00B7;2H2O and [Ag(H2O)]2[Ag2(CF3SO3)4][Pt(acac)2]2
;
_journal_issue                   3
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              273
_journal_paper_doi               10.1039/a808678h
_journal_year                    1999
_chemical_formula_moiety         'C24 H32 Ag4 F12 O22 Pt2 S4 '
_chemical_formula_sum            'C24 H32 Ag4 F12 O22 Pt2 S4'
_chemical_formula_weight         1850.38
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 102.90(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   13.039(7)
_cell_length_b                   12.287(3)
_cell_length_c                   15.000(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      14.9
_cell_measurement_theta_min      14.1
_cell_volume                     2342.5(15)
_computing_cell_refinement       'Rigaku/AFC Diffractometer Control'
_computing_data_collection       'Rigaku/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    DIRDIF91_PATTY
_diffrn_ambient_temperature      296.2
_diffrn_measurement_device_type  'Rigaku AFC7S'
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      -0.03233
_diffrn_orient_matrix_UB_12      -0.00321
_diffrn_orient_matrix_UB_13      0.05445
_diffrn_orient_matrix_UB_21      0.07153
_diffrn_orient_matrix_UB_22      -0.00749
_diffrn_orient_matrix_UB_23      0.04096
_diffrn_orient_matrix_UB_31      0.00534
_diffrn_orient_matrix_UB_32      0.08098
_diffrn_orient_matrix_UB_33      0.00595
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.026
_diffrn_reflns_av_sigmaI/netI    0.112
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            5872
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.16
_diffrn_standards_decay_%        -1.86
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    7.860
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.596
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details   '(Walker & Stuart, 1983)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.623
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1736.00
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_refine_diff_density_max         1.29
_refine_diff_density_min         -1.07
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_obs   1.926
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     307
_refine_ls_number_reflns         2985
_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0455
_refine_ls_shift/su_max          0.1746
_refine_ls_shift/su_mean         0.0225
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00000|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_obs         0.0370
_reflns_number_observed          2985
_reflns_number_total             5635
_reflns_threshold_expression     >3.0sigma(I)
_cod_data_source_file            808678hsup1.cif
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:
'_reflns_observed_expression' tag replaced with
'_reflns_threshold_expression' tag as specified in the replacement
file
'cod-tools/trunk/perl-scripts/inputs/replacement_tags.lst'.

'_atom_site_calc_flags'
tag replaced with '_atom_site_calc_flag' tag as specified in the
replacement file
'cod-tools/trunk/perl-scripts/inputs/replacement_tags.lst'.

'_atom_type_scat_imag'
tag replaced with '_atom_type_scat_dispersion_imag' tag as specified
in the replacement file
'cod-tools/trunk/perl-scripts/inputs/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 3137 2015-03-23 15:08:43Z antanas 
;
_cod_original_cell_volume        2342(1)
_cod_original_sg_symbol_H-M      'P 21/n       '
_cod_original_formula_sum        'C24 H32 Ag4 F12 O22 Pt2 S4 '
_cod_database_code               7027167