Dipalladium complexes with bridging diorganosilyl ligands. Synthesis, structure, and properties of [LPd(μ-SiH(R)Ph)]2 (R = Ph or Me; L = PMe3, PEt3 or PMePh2)
Kim, Yong-Joo; Lee, Sang-Chul; Park, Jong-Il; Osakada, Kohtaro; Choi, Jun-Chul; Yamamoto, Takakazu; Journal of the Chemical Society, Dalton Transactions  (2000) 417–; doi:10.1039/a907745f

data_7008980
_publ_section_title
;
 Dipalladium complexes with bridging diorganosilyl ligands. Synthesis,
 structure, and properties of [LPd(\m-SiH(R)Ph)]2 (R&#x2005;=&#x2005;Ph
 or Me; L&#x2005;=&#x2005;PMe3, PEt3 or PMePh2)
;
_journal_issue                   3
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              417
_journal_paper_doi               10.1039/a907745f
_journal_year                    2000
_chemical_formula_sum            'C36 H52 P2 Pd2 Si2'
_chemical_formula_weight         815.36
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                112.13(5)
_cell_angle_beta                 115.65(6)
_cell_angle_gamma                78.56(6)
_cell_formula_units_Z            1
_cell_length_a                   10.242(9)
_cell_length_b                   11.447(6)
_cell_length_c                   9.725(8)
_cell_measurement_reflns_used    20
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      19.10
_cell_measurement_theta_min      13.96
_cell_volume                     951.2(14)
_diffrn_ambient_temperature      296.2
_diffrn_measurement_device       'Rigaku AFC5R'
_diffrn_orient_matrix_UB_11      0.02804
_diffrn_orient_matrix_UB_12      0.08868
_diffrn_orient_matrix_UB_13      0.03483
_diffrn_orient_matrix_UB_21      -0.07792
_diffrn_orient_matrix_UB_22      0.03169
_diffrn_orient_matrix_UB_23      0.04274
_diffrn_orient_matrix_UB_31      0.06997
_diffrn_orient_matrix_UB_32      -0.00641
_diffrn_orient_matrix_UB_33      0.10749
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.07137
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            3544
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         24.99
_diffrn_reflns_theta_min         2.79
_exptl_absorpt_coefficient_mu    1.116
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.793
_exptl_absorpt_correction_type
;
\y scans (North,Phillips & Matthews, 1968)
;
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.424
_exptl_crystal_density_meas      ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             418.00
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.55
_refine_diff_density_min         -0.98
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   2.570
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     194
_refine_ls_number_reflns         2835
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           0.0380
_refine_ls_shift/su_max          0.228
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     unit
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0450
_reflns_number_gt                2835
_reflns_number_total             3340
_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            a907745f.txt
_cod_data_source_block           form1
_cod_original_cell_volume        951(1)
_cod_original_sg_symbol_H-M      'P -1     '
_cod_original_formula_sum        'C36 H52 P2 Pd2 Si2 '
_cod_database_code               7008980