<i>cis</i>-Dichloro(<i>C</i>-<i>rac</i>-5,12-dimethyl-1,4,8,11-tetraazacyclotetradecane-<i>N</i>,<i>N</i>',<i>N</i>'',<i>N</i>''')cobalt(III) chloride, [CoCl~2~(C~12~H~28~N~4~)]Cl
Tahirov, T.H.; Lu, T.-H.; Chen, B-H.; Chi, T.-Y.; Chung, C.-S.; Acta Crystallographica Section C 50 (1994) 1686–1687; doi:10.1107/S0108270194004610

data_2010146
_publ_section_title
;<i>cis</i>-Dichloro(<i>C</i>-<i>rac</i>-5,12-dimethyl-1,4,8,11-tetraazacyclotetradecane-<i>N</i>,<i>N</i>',<i>N</i>'',<i>N</i>''')cobalt(III)
 chloride, [CoCl~2~(C~12~H~28~N~4~)]Cl
;
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1686
_journal_page_last               1687
_journal_paper_doi               10.1107/S0108270194004610
_journal_volume                  50
_journal_year                    1994
_chemical_formula_sum            'C12 H28 Cl3 Co N4'
_chemical_formula_weight         393.67
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_type_scat_source           IntTabIV
_cell_angle_alpha                90.
_cell_angle_beta                 90.96(2)
_cell_angle_gamma                90.
_cell_formula_units_Z            4
_cell_length_a                   9.1780(10)
_cell_length_b                   11.722(2)
_cell_length_c                   16.100(5)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    298(3)
_cell_measurement_theta_max      17.5
_cell_measurement_theta_min      7.42
_cell_volume                     1731.9(6)
_diffrn_measurement_device       'Nonius CAD-4'
_diffrn_measurement_method       \q/2\q
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.019
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            2663
_diffrn_reflns_theta_max         29.9
_diffrn_standards_decay_%        +-0.5
_diffrn_standards_interval_time  60
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.45
_exptl_absorpt_correction_T_max  0.9998
_exptl_absorpt_correction_T_min  0.8725
_exptl_absorpt_correction_type   'empirical (North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            'deep violet'
_exptl_crystal_density_diffrn    1.510
_exptl_crystal_description       parallelepiped
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.28
_refine_diff_density_max         0.53(8)
_refine_diff_density_min         -0.40(8)
_refine_ls_extinction_coef       '0.21(1) mm'
_refine_ls_extinction_method     'Zachariasen (1968)'
_refine_ls_goodness_of_fit_obs   1.78
_refine_ls_hydrogen_treatment    refU
_refine_ls_number_parameters     118
_refine_ls_number_reflns         2071
_refine_ls_R_factor_obs          0.045
_refine_ls_shift/esd_max         0.059
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      unit
_refine_ls_wR_factor_obs         0.049
_reflns_number_observed          2071
_reflns_number_total             2521
_reflns_observed_criterion       I>=2.5(I)
_cod_data_source_file            as1107.cif
_cod_data_source_block           as1107_structure_1_of_1
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2010146