Photoluminescence Switching of Azobenzene-Conjugated Pt(II) Terpyridine Complexes by Trans-Cis Photoisomerization
Tomona Yutaka; Ichiro Mori; Masato Kurihara; Jun Mizutani; Naoto Tamai; Tsuyoshi Kawai; Masahiro Irie; Hiroshi Nishihara; Inorganic Chemistry 41 (2002) 7143–7150; doi:10.1021/ic0260116

data_4319092
_publ_section_title
;
 Photoluminescence Switching of Azobenzene-Conjugated Pt(II) Terpyridine
 Complexes by Trans-Cis Photoisomerization
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7143
_journal_page_last               7150
_journal_paper_doi               10.1021/ic0260116
_journal_volume                  41
_journal_year                    2002
_chemical_formula_moiety         'C35 H37 Cl F6 N7 O2 P Pt '
_chemical_formula_sum            'C35 H37 Cl F6 N7 O2 P Pt'
_chemical_formula_weight         963.23
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             2001-10-30
_audit_creation_method           'by CrystalStructure v2.00'
_cell_angle_alpha                113.45(3)
_cell_angle_beta                 91.95(1)
_cell_angle_gamma                92.37(2)
_cell_formula_units_Z            2
_cell_length_a                   7.13(5)
_cell_length_b                   16.28(2)
_cell_length_c                   17.06(3)
_cell_measurement_reflns_used    20996
_cell_measurement_temperature    293.1
_cell_measurement_theta_max      13.7
_cell_measurement_theta_min      1.5
_cell_volume                     1812(13)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 2.00'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SHELXS97
_diffrn_detector_area_resol_mean 14.63
_diffrn_measured_fraction_theta_full 0.9477
_diffrn_measured_fraction_theta_max 0.9477
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.033
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            14387
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    4.046
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.764
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.54
_refine_diff_density_min         -1.07
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   3.892
_refine_ls_number_parameters     218
_refine_ls_number_reflns         6416
_refine_ls_R_factor_gt           0.0810
_refine_ls_shift/su_max          0.0040
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/\s^2^(Fo)'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0930
_reflns_number_gt                6416
_reflns_number_total             7887
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic0260116_2.cif
_cod_data_source_block           '__PtCltpyAB.inf'
_cod_original_cell_volume        1813.1(89)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C35 H37 Cl F6 N7 O2 P Pt '
_cod_database_code               4319092