Fabrication of Schottky barrier diodes utilizing carboxylate bridged trinuclear mixed valence cobalt(iii/ii/iii) complexes of tetradentate N2O2 donor reduced Schiff base ligands
Bhunia, Sudip; Das, Pubali; Banerjee, Snehasis; Gomila, Rosa M.; Drew, Michael G. B.; Frontera, Antonio; Ray, Partha Pratim; Chattopadhyay, Shouvik; New Journal of Chemistry 47 (2023) 14202–14216; doi:10.1039/D3NJ01829F

data_7062590
_publ_section_title
;
 Fabrication of Schottky barrier diodes utilizing carboxylate bridged
 trinuclear mixed valence cobalt(iii/ii/iii) complexes of tetradentate
 N2O2 donor reduced Schiff base ligands
;
_journal_issue                   30
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              14202
_journal_page_last               14216
_journal_paper_doi               10.1039/D3NJ01829F
_journal_volume                  47
_journal_year                    2023
_chemical_formula_sum            'C62.5 H77.5 Cl1.5 Co3 N4 O16.5 S1.5'
_chemical_formula_weight         1426.84
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2023-06-15 deposited with the CCDC.	2023-06-20 downloaded from the CCDC.
;
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'Ortep-3 for Windows (Farrugia, 1999) and CAMERON (Watkin et al., 1993)'
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 QUEST area detector'
_diffrn_measurement_method       '\f and \w scans'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0883P)^2^+17.1374P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7062588--7062590.cif.'
_cod_original_cell_volume        6766.6(9)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C62.50 H77.50 Cl1.50 Co3 N4 O16.50 S1.50'
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