Platinum trimethyl bipyridyl thiolates ‒ new, tunable, red- to near IR emitting luminophores for bioimaging applications
Harriet L. Steel; Sarah L. Allinson; Jane Andre; Michael P. Coogan; James A. Platts; Chem.Commun. 51 (2015) 11441–; doi:10.1039/C5cc04003E

data_7117421
_publ_section_title
;
 Platinum trimethyl bipyridyl thiolates -- new, tunable, red- to near IR
 emitting luminophores for bioimaging applications
;
_journal_name_full               Chem.Commun.
_journal_page_first              11441
_journal_paper_doi               10.1039/C5cc04003E
_journal_volume                  51
_journal_year                    2015
_chemical_formula_moiety         'C25 H27 N2 O6 Pt S'
_chemical_formula_sum            'C25 H27 N2 O6 Pt S'
_chemical_formula_weight         678.65
_chemical_name_common            10
_chemical_name_systematic        10
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_primary     iterative
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_audit_creation_method
;
Olex2 1.2
(compiled 2015.01.19 svn.r3143 for OlexSys, GUI svn.r4992)
;
_audit_update_record
;
2015-01-23 deposited with the CCDC.
2015-06-10 downloaded from the CCDC.
;
_cell_angle_alpha                70.675(5)
_cell_angle_beta                 80.551(6)
_cell_angle_gamma                84.130(6)
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_cell_length_b                   13.2276(9)
_cell_length_c                   14.0336(10)
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_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
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_computing_structure_solution    'olex2.solve (Bourhis et al., 2013)'
_diffrn_ambient_temperature      100
_diffrn_measured_fraction_theta_full 0.9918
_diffrn_measured_fraction_theta_max 0.9918
_diffrn_radiation_type           'Mo K\a'
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_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
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_exptl_crystal_description       plate
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_limit_h_max              9
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_reflns_threshold_expression     I>=2u(I)
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_cod_data_source_block           2014ncs0620
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_olex2_refinement_description
;
;
_olex2_submission_special_instructions 'No special instructions were received'