Addition of Small Electrophiles to N-Heterocyclic-Carbene-Stabilized Disilicon(0): A Revisit of the Isolobal Concept in Low-Valent Silicon Chemistry.
Arz, Marius I.; Straßmann, Martin; Geiß, Daniel; Schnakenburg, Gregor; Filippou, Alexander C.; Journal of the American Chemical Society 138 (2016) 4589–4600; doi:10.1021/jacs.6b01018

data_4124999
_publ_section_title
;
 Addition of Small Electrophiles to N-Heterocyclic-Carbene-Stabilized
 Disilicon(0): A Revisit of the Isolobal Concept in Low-Valent Silicon
 Chemistry.
;
_journal_issue                   13
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              4589
_journal_page_last               4600
_journal_paper_doi               10.1021/jacs.6b01018
_journal_volume                  138
_journal_year                    2016
_chemical_formula_sum            'C88 H89 B F24 N4 Si2'
_chemical_formula_weight         1725.62
_chemical_name_systematic
; 
 ? 
;
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_diffrn_detector                 'image plate (34 cm diameter)'
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_diffrn_measurement_device       '2-circle goniometer'
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_diffrn_measurement_method       'rotation method'
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'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
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_exptl_crystal_colour            red
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0710P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1277
_reflns_number_gt                12870
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_cod_depositor_comments
'Adding full bibliography for 4124995--4124999.cif.'
_cod_original_cell_volume        4326.2(2)
_cod_database_code               4124999