Retention of Configuration on the Oxidative Addition of P-H Bond to Platinum (0) Complexes: The First Straightforward Synthesis of Enantiomerically Pure P-Chiral Alkenylphosphinates via Palladium-Catalyzed Stereospecific Hydrophosphinylation of Alkynes
Li-Biao Han; Chang-Qiu Zhao; Shun-ya Onozawa; Midori Goto; Masato Tanaka; Journal of the American Chemical Society 124 (2002) 3842–3843; doi:10.1021/ja025816+

data_4114738
_publ_contact_author_address
;
     1-1-1
 Higashi
 central 5
 National  Institute
 of Advanced Industrial Science
 and Technology
;
_publ_contact_author_email       ' libiao-han@aist.go.jp '
_publ_contact_author_fax         ' 81-298-61-4511 '
_publ_contact_author_name        'Li-Biao Han'
_publ_contact_author_phone       ' 81-298-61-4855 '
_publ_section_title
;
 Retention of Configuration on the Oxidative Addition of P-H Bond to
 Platinum (0) Complexes: The First Straightforward Synthesis of
 Enantiomerically Pure P-Chiral Alkenylphosphinates via
 Palladium-Catalyzed Stereospecific Hydrophosphinylation of Alkynes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3842
_journal_page_last               3843
_journal_paper_doi               10.1021/ja025816+
_journal_volume                  124
_journal_year                    2002
_chemical_formula_sum            'C27 H37 O2 P'
_chemical_formula_weight         424.56
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      4
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_audit_creation_date             'Thu Aug 31 00:49:30 2000'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 91.87(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.155(2)
_cell_length_b                   17.610(4)
_cell_length_c                   17.818(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    223.2
_cell_measurement_theta_max      12.7
_cell_measurement_theta_min      7.1
_cell_volume                     2557.5(9)
_computing_cell_refinement       'Rigaku/AFC Diffractometer Control'
_computing_data_collection       'Rigaku/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_diffrn_ambient_temperature      223.2
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      -0.04153
_diffrn_orient_matrix_UB_12      -0.05308
_diffrn_orient_matrix_UB_13      -0.00669
_diffrn_orient_matrix_UB_21      0.11185
_diffrn_orient_matrix_UB_22      -0.02013
_diffrn_orient_matrix_UB_23      0.01332
_diffrn_orient_matrix_UB_31      -0.02850
_diffrn_orient_matrix_UB_32      -0.00158
_diffrn_orient_matrix_UB_33      0.05412
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.056
_diffrn_reflns_av_sigmaI/netI    0.090
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            16872
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.56
_diffrn_standards_decay_%        -2.80
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.126
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.103
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             920.00
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.17
_refine_diff_density_min         -0.20
_refine_ls_abs_structure_details Flack
_refine_ls_abs_structure_Flack   -0.03(7)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.361
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     542
_refine_ls_number_reflns         7889
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0443
_refine_ls_R_factor_gt           0.0443
_refine_ls_shift/su_max          0.1130
_refine_ls_shift/su_mean         0.0210
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00040|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0542
_refine_ls_wR_factor_ref         0.0542
_reflns_number_gt                7889
_reflns_number_total             11569
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ja0258162B_s2_1.cif
_cod_data_source_block           the_vinylphosphinate_C27H37O2P1
_cod_original_cell_volume        2557.5(8)
_cod_original_sg_symbol_H-M      'P 21 '
_cod_original_formula_sum        'C27 H37 O2 P1 '
_cod_database_code               4114738