Strongly luminescent 5d/4f heterometal-organic macrocycles with open metal sites: post-assembly modification and sensing.
Zhu, Qiang-Yu; Zhou, Li-Peng; Sun, Qing-Fu; Dalton transactions (Cambridge, England : 2003) 48 (2019) 4479–4483; doi:10.1039/c9dt00710e

data_7049235
_publ_section_title
;
 Strongly luminescent 5d/4f heterometal-organic macrocycles with open
 metal sites: post-assembly modification and sensing.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4479
_journal_page_last               4483
_journal_paper_doi               10.1039/c9dt00710e
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C104 H136 Cl6 La2 N16 O34 Pt2'
_chemical_formula_weight         3034.98
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2018-11-24 deposited with the CCDC.    2019-03-04 downloaded from the CCDC.
;
_cell_angle_alpha                73.946(3)
_cell_angle_beta                 71.033(3)
_cell_angle_gamma                88.863(3)
_cell_formula_units_Z            1
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_cell_length_b                   15.5448(10)
_cell_length_c                   18.1762(12)
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_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      24.76
_cell_measurement_theta_min      2.26
_cell_volume                     3626.1(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0903
_diffrn_reflns_av_unetI/netI     0.0511
_diffrn_reflns_Laue_measured_fraction_full 0.997
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_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
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_diffrn_reflns_point_group_measured_fraction_full 0.997
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_diffrn_reflns_theta_full        24.782
_diffrn_reflns_theta_max         24.782
_diffrn_reflns_theta_min         2.386
_exptl_absorpt_coefficient_mu    2.680
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.390
_exptl_crystal_description       block
_exptl_crystal_F_000             1516
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_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
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_refine_diff_density_min         -1.133
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_refine_ls_extinction_method     none
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_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.079
_refine_ls_R_factor_all          0.0703
_refine_ls_R_factor_gt           0.0514
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0756P)^2^+2.8010P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1301
_refine_ls_wR_factor_ref         0.1402
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9308
_reflns_number_total             12437
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt00710e2.cif
_cod_data_source_block           mo_156_11_0m_a_sq_d
_cod_depositor_comments
'Adding full bibliography for 7049235--7049237.cif.'
_cod_database_code               7049235
_shelx_shelxl_version_number     2016/6
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