Syntheses and Luminescent Properties of 3,5-Diphenylpyrazolato-Bridged Heteropolynuclear Platinum Complexes. The Influence of Chloride Ligands on the Emission Energy Revealed by the Systematic Replacement of Chloride Ligands by 3,5-Dimethylpyrazolate
Seiji Akatsu; Yasunori Kanematsu; Taka-aki Kurihara; Shota Sueyoshi; Yasuhiro Arikawa; Masayoshi Onishi; Shoji Ishizaka; Noboru Kitamura; Yoshihide Nakao; Shigeyoshi Sakaki; Keisuke Umakoshi; Inorganic Chemistry 51 (2012) 7977–7992; doi:10.1021/ic202663q

data_4329784
_publ_contact_author_address
;
        Division of Chemistry and Materials Science
    Graduate School of Engineering
    Nagasaki University
    Bunkyo-machi, Nagasaki 852-8521
    Japan
;
_publ_contact_author_email       ' kumks@nagasaki-u.ac.jp '
_publ_contact_author_fax         ' +81-95-819-2672 '
_publ_contact_author_name        ' Prof. Keisuke Umakoshi '
_publ_contact_author_phone       ' +81-95-819-2672 '
_publ_section_title
;
 Syntheses and Luminescent Properties of 3,5-Diphenylpyrazolato-Bridged
 Heteropolynuclear Platinum Complexes. The Influence of Chloride Ligands
 on the Emission Energy Revealed by the Systematic Replacement of Chloride
 Ligands by 3,5-Dimethylpyrazolate
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7977
_journal_page_last               7992
_journal_paper_doi               10.1021/ic202663q
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C100 H80 Ag4 N16 Pt2'
_chemical_formula_sum            'C100 H80 Ag4 N16 Pt2'
_chemical_formula_weight         2327.49
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                95.221(3)
_cell_angle_beta                 92.255(3)
_cell_angle_gamma                112.527(4)
_cell_formula_units_Z            2
_cell_length_a                   14.5440(14)
_cell_length_b                   14.7510(15)
_cell_length_c                   22.0631(15)
_cell_measurement_reflns_used    7448
_cell_measurement_temperature    296
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.01
_cell_volume                     4339.9(7)
_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'CrystalStructure 4.0'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'DIRDIF94 (PATTY)'
_diffrn_ambient_temperature      296
_diffrn_detector_area_resol_mean 14.71
_diffrn_measured_fraction_theta_full 0.927
_diffrn_measured_fraction_theta_max 0.927
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0606
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            32572
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.48
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.139
_exptl_absorpt_correction_T_max  0.191
_exptl_absorpt_correction_T_min  0.083
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.781
_exptl_crystal_description       block
_exptl_crystal_F_000             2272.00
_exptl_crystal_size_max          0.800
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.400
_refine_diff_density_max         6.180
_refine_diff_density_min         -3.510
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     1103
_refine_ls_number_reflns         18453
_refine_ls_number_restraints     96
_refine_ls_R_factor_gt           0.0967
_refine_ls_shift/su_max          0.020
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.1374P)^2^+125.2979P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.3018
_reflns_number_gt                14424
_reflns_number_total             18453
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic202663q_si_002_1.cif
_cod_data_source_block           '[Pt2Ag4(dmpz)2(dppz)6]'
_cod_database_code               4329784