Selective hydrosiloxane synthesis via dehydrogenative coupling of silanols with hydrosilanes catalysed by Fe complexes bearing a tetradentate PNNP ligand.
Takeshita, Tomohiro; Sato, Kazuhiko; Nakajima, Yumiko; Dalton transactions (Cambridge, England : 2003) 47 (2018) 17004–17010; doi:10.1039/c8dt04168g

data_7048023
_publ_section_title
;
 Selective hydrosiloxane synthesis via dehydrogenative coupling of
 silanols with hydrosilanes catalysed by Fe complexes bearing a
 tetradentate PNNP ligand.
;
_journal_issue                   47
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              17004
_journal_page_last               17010
_journal_paper_doi               10.1039/c8dt04168g
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C39 H30 Fe N2 O P2'
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_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-09-10 deposited with the CCDC.
2018-11-12 downloaded from the CCDC.
;
_cell_angle_alpha                82.081(11)
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_computing_molecular_graphics    'ORTEP3 for windows'
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_computing_structure_solution    SIR97
_diffrn_ambient_temperature      93(2)
_diffrn_measured_fraction_theta_full 0.960
_diffrn_measured_fraction_theta_max 0.936
_diffrn_measurement_device_type  'Rigaku XtaLAB P200'
_diffrn_measurement_method       'profile data from \w-scans'
_diffrn_radiation_type           MoK\a
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_diffrn_source                   'Rotating Anode'
_exptl_absorpt_coefficient_mu    0.627
_exptl_crystal_colour            green
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0700P)^2^+2.0077P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_total             6630
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           take140
_cod_depositor_comments
'Adding full bibliography for 7048021--7048028.cif.'
_cod_database_code               7048023
_shelx_shelxl_version_number     2014/7
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