Homolytic cleavage of peroxide bonds via a single electron transfer of a frustrated Lewis pair.
Liu, Liu Leo; Cao, Levy L.; Zhu, Diya; Zhou, Jiliang; Stephan, Douglas W.; Chemical communications (Cambridge, England) 54 (2018) 7431–7434; doi:10.1039/c8cc03522a

data_7121658
_publ_section_title
;
 Homolytic cleavage of peroxide bonds via a single electron transfer of a
 frustrated Lewis pair.
;
_journal_issue                   54
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              7431
_journal_page_last               7434
_journal_paper_doi               10.1039/c8cc03522a
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C52 H39 B F15 O2 P'
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-02-27 deposited with the CCDC.
2018-05-14 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      150(2)
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_diffrn_reflns_av_unetI/netI     0.0579
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_diffrn_reflns_theta_full        25.242
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         9152
_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.1141
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0796P)^2^+6.2957P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7121658--7121660.cif.'
_cod_database_code               7121658
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              24239