Water oxidation catalysed by a mononuclear Co(II) polypyridine complex; possible reaction intermediates and the role of the chloride ligand.
Das, Biswanath; Orthaber, Andreas; Ott, Sascha; Thapper, Anders; Chemical communications (Cambridge, England) 51 (2015) 13074–13077; doi:10.1039/c5cc04148a

data_7117626
_publ_section_title
;
 Water oxidation catalysed by a mononuclear Co(II) polypyridine complex;
 possible reaction intermediates and the role of the chloride ligand.
;
_journal_issue                   66
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              13074
_journal_page_last               13077
_journal_paper_doi               10.1039/c5cc04148a
_journal_volume                  51
_journal_year                    2015
_chemical_formula_sum            'C27 H21 B0 Cl Co F0 N4 O2'
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_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           '-P 2c 2b'
_space_group_name_H-M_alt        'P b c m'
_symmetry_space_group_name_Hall  '-P 2c 2b'
_symmetry_space_group_name_H-M   'P b c m'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2015-05-19 deposited with the CCDC.
2015-06-11 downloaded from the CCDC.
;
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'w=1/[\s^2^(Fo^2^)+(0.1475P)^2^+20.8833P] where P=(Fo^2^+2Fc^2^)/3'
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