Direct Observation of Oxidative Cyclization of η2-Alkene and η2-Aldehyde on Ni(0) Center. Significant Acceleration by Addition of Me3SiOTf
Sensuke Ogoshi; Masa-aki Oka; Hideo Kurosawa; Journal of the American Chemical Society 126 (2004) 11802–11803; doi:10.1021/ja0460716

data_4112962
_publ_section_title
;
 Direct Observation of Oxidative Cyclization of \h2-Alkene and
 \h2-Aldehyde on Ni(0) Center. Significant Acceleration by Addition of
 Me3SiOTf
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11802
_journal_page_last               11803
_journal_paper_doi               10.1021/ja0460716
_journal_volume                  126
_journal_year                    2004
_chemical_formula_moiety         'C27 H52 F3 O4 Ni P S Si '
_chemical_formula_sum            'C27 H52 F3 Ni O4 P S Si'
_chemical_formula_weight         647.52
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_symmetry_cell_setting           monoclinic
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_cell_angle_beta                 88.445(2)
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_cell_length_b                   17.639(1)
_cell_length_c                   13.8433(8)
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_cell_measurement_temperature    273.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.2
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_computing_cell_refinement       PROCESS-AUTO
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_computing_publication_material  'CrystalStructure 3.6.0'
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_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
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_diffrn_reflns_theta_max         27.49
_exptl_absorpt_coefficient_mu    0.764
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_exptl_crystal_description       block
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_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.15
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_refine_diff_density_min         -0.62
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    noref
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_refine_ls_structure_factor_coef F
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