Dimer formation upon deprotonation: synthesis and structure of a m-terphenyl substituted (R,S)-dilithium disiloxanolate disilanol.
Čas, Daniel; Hurkes, Natascha; Spirk, Stefan; Belaj, Ferdinand; Bruhn, Clemens; Rechberger, Gerald N.; Pietschnig, Rudolf; Dalton transactions (Cambridge, England : 2003) 44 (2015) 12818–12823; doi:10.1039/c5dt01992c

data_7035427
_publ_section_title
;
 Dimer formation upon deprotonation: synthesis and structure of a
 m-terphenyl substituted (R,S)-dilithium disiloxanolate disilanol.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12818
_journal_page_last               12823
_journal_paper_doi               10.1039/c5dt01992c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C96 H106 Na2 O10 Si4, 0.5(C6 H6)'
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_chemical_properties_physical    'Air-sensitive, Hygroscopic'
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-04-29 deposited with the CCDC.
2015-06-12 downloaded from the CCDC.
;
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_diffrn_measurement_details      ' 1797 frames, detector distance = 80 mm'
_diffrn_measurement_method       'rotation method'
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_diffrn_radiation_monochromator  'Graded multilayer mirror'
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_diffrn_radiation_type           'Cu K\a'
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_diffrn_source                   Cu-Genix
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'Re-crystallisation from solvent: Benzene'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0356P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_file            c5dt01992c2.cif
_cod_data_source_block           sv0027a
_cod_depositor_comments
'Adding full bibliography for 7035423--7035427.cif.'
_cod_original_cell_volume        17281.9(16)
_cod_database_code               7035427
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_shelx_res_checksum              60742