<i>catena</i>-Poly[silver(I)-μ-(cyano-<i>C</i>:<i>N</i>)-<i>cis</i>-bis(2,2'-bipyridine-<i>N</i>,<i>N</i>')copper(II)-μ-(cyano-<i>N</i>:<i>C</i>)] dicyanoargentate(I) monohydrate
Černák, J.; Gérard, F.; Chomič, J.; Acta Crystallographica Section C 49 (1993) 1294–1296; doi:10.1107/S010827019300037X

data_2001506
_publ_section_title
;<i>catena</i>-Poly[silver(I)-\m-(cyano-<i>C</i>:<i>N</i>)-<i>cis</i>-bis(2,2'-bipyridine-<i>N</i>,<i>N</i>')copper(II)-\m-(cyano-<i>N</i>:<i>C</i>)]
 dicyanoargentate(I) monohydrate
;
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1294
_journal_page_last               1296
_journal_paper_doi               10.1107/S010827019300037X
_journal_volume                  49
_journal_year                    1993
_chemical_formula_moiety         'C20 H16 Cu1 N4 , 2Ag1 C2 N2 , H2 O1'
_chemical_formula_sum            'C24 H18 Ag2 Cu N8 O'
_chemical_formula_weight         713.74
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_type_scat_source           'SHELX76 (C, H, N, O), IntTabIV (Cu, Ag)'
_cell_angle_alpha                97.09(2)
_cell_angle_beta                 109.44(2)
_cell_angle_gamma                77.890(10)
_cell_formula_units_Z            2
_cell_length_a                   11.302(2)
_cell_length_b                   11.8140(10)
_cell_length_c                   10.4570(10)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    295
_cell_measurement_theta_max      14.90
_cell_measurement_theta_min      10.80
_cell_volume                     1285.2(3)
_diffrn_measurement_device       CAD-4L
_diffrn_measurement_method       \w
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.7093
_diffrn_reflns_av_R_equivalents  0.0199
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            5169
_diffrn_reflns_theta_max         27.5
_diffrn_standards_decay_%        <=+-2
_diffrn_standards_interval_count 100
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.35
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.844
_exptl_crystal_density_meas      1.85(2)
_exptl_crystal_density_method    flotation?
_exptl_crystal_description       parallelepiped
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_refine_diff_density_max         '1.14 (see below), 0.34'
_refine_diff_density_min         -0.45
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_obs   1.1911
_refine_ls_hydrogen_treatment    refU
_refine_ls_number_parameters     344
_refine_ls_number_reflns         4308
_refine_ls_R_factor_obs          0.0291
_refine_ls_shift/esd_max         0.111
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 0.7148/[\s^2^(F~o~)]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_obs         0.0387
_reflns_number_observed          4308
_reflns_number_total             4891
_reflns_observed_criterion       F~o~>=4\s(F~o~)
_cod_data_source_file            ka1014.cif
_cod_data_source_block           ka1014_structure_1_of_1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'w = 0.7148/[\s^2^(F~o~)]' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to 'w =
0.7148/[\s^2^(F~o~)]'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        1285.2(5)
_cod_original_formula_sum        'C24 H18 Ag2 Cu1 N8 O1'
_cod_database_code               2001506