Synthesis of Structurally Diverse 3-, 4-, 5-, and 6-Membered Heterocycles from Diisopropyl Iminomalonates and Soft C-Nucleophiles.
Kattamuri, Padmanabha V.; Bhakta, Urmibhusan; Siriwongsup, Surached; Kwon, Doo-Hyun; Alemany, Lawrence B.; Yousufuddin, Muhammed; Ess, Daniel H.; Kürti, László; The Journal of organic chemistry 84 (2019) 7066–7099; doi:10.1021/acs.joc.9b00681

data_4033592
_publ_section_title
;
 Synthesis of Structurally Diverse 3-, 4-, 5-, and 6-Membered Heterocycles
 from Diisopropyl Iminomalonates and Soft C-Nucleophiles.
;
_journal_issue                   11
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              7066
_journal_page_last               7099
_journal_paper_doi               10.1021/acs.joc.9b00681
_journal_volume                  84
_journal_year                    2019
_chemical_formula_moiety         'C23 H27 N O5'
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_diffrn_measurement_device_type  'Bruker D8 Quest'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_theta_max         25.027
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_exptl_absorpt_coefficient_mu    0.082
_exptl_absorpt_correction_type   none
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_exptl_crystal_description       prism
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1240P)^2^+0.1745P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2050
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_reflns_number_gt                3546
_reflns_number_total             7969
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           pvkv26
_cod_depositor_comments          'Adding full bibliography for 4033592.cif.'
_cod_original_cell_volume        2254.9(9)
_cod_database_code               4033592
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              92457
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