A new, general method for the synthesis of carbasugar-sugar pseudodisaccharides.
Afarinkia, Kamyar; Abdullahi, Mohamed Haji; Scowen, Ian J.; Organic letters 11 (2009) 5182–5184; doi:10.1021/ol901960y

data_1504213
_publ_section_title
;
 A new, general method for the synthesis of carbasugar-sugar
 pseudodisaccharides.
;
_journal_issue                   22
_journal_name_full               'Organic letters'
_journal_page_first              5182
_journal_page_last               5184
_journal_paper_doi               10.1021/ol901960y
_journal_volume                  11
_journal_year                    2009
_chemical_formula_sum            'C21 H28 O10'
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_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
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_cell_length_a                   10.0245(6)
_cell_length_b                   12.5364(8)
_cell_length_c                   17.6378(11)
_cell_measurement_reflns_used    5686
_cell_measurement_temperature    296(2)
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_cell_measurement_theta_min      2.31
_cell_volume                     2216.6(2)
_computing_cell_refinement       'Bruker SAINT'
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_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
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_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_limit_k_max       16
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_diffrn_reflns_limit_l_min       -22
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_diffrn_reflns_theta_max         28.02
_diffrn_reflns_theta_min         1.99
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_exptl_absorpt_coefficient_mu    0.105
_exptl_absorpt_correction_T_max  0.9707
_exptl_absorpt_correction_T_min  0.9448
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    1.320
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             936
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0626
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0527P)^2^+0.2583P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1004
_refine_ls_wR_factor_ref         0.1095
_reflns_number_gt                3884
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ol901960y_si_002.cif
_cod_data_source_block           mha407f4a_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P2(1)2(1)2(1)
_cod_database_code               1504213