Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction.
Shintani, Ryo; Kishikawa, Shinnosuke; Nakamura, Kimihiro; Tsuda, Tomohiro; Nozaki, Kyoko; Chemical communications (Cambridge, England)  (2019) –; doi:10.1039/c8cc09943j

data_7122769
_publ_section_title
;
 Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by
 rhodium-catalyzed stitching reaction.
;
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_paper_doi               10.1039/c8cc09943j
_journal_year                    2019
_chemical_formula_sum            'C30 H38 O2 S Si2'
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_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2018-12-08 deposited with the CCDC.
2018-12-28 downloaded from the CCDC.
;
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_computing_cell_refinement
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Rigaku CrystalClear-SM Expert 2.0 r3
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_computing_data_collection
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Rigaku CrystalClear-SM Expert 2.0 r3
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Rigaku CrystalClear-SM Expert 2.0 r3
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Rigaku CrystalClear-SM Expert 2.0 r3
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_diffrn_measurement_method       'profile data from \w-scans'
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_diffrn_source                   'Rotating Anode'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0366P)^2^+1.0590P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0874
_refine_ls_wR_factor_ref         0.0884
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4741
_reflns_number_total             4927
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8cc09943j2.cif
_cod_data_source_block           ydkr_CCDC1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 
;
_cod_database_code               7122769
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.930
_shelx_estimated_absorpt_t_max   0.957
_shelx_res_checksum              79580