Diastereoselective formation of a dipalladium(I) complex supported by a bridging tetradentate ligand, and oxidative addition of RS‒H across a phosphine-bridged Pd^I^‒Pd^I^ bond
Foo, S. Jo Ling; Jones, Nathan D.; Patrick, Brian O.; James, Brian R.; Chemical Communications (Cambridge, United Kingdom)  (2003) 988–989; doi:10.1039/b300177f

data_7104071
_publ_section_title
;
 Diastereoselective formation of a dipalladium(I) complex supported by a
 bridging tetradentate ligand, and oxidative addition of RS--H across a
 phosphine-bridged Pd^I^--Pd^I^ bond
;
_journal_coden_ASTM              CHCOFS
_journal_issue                   8
_journal_name_full
;
 Chemical Communications (Cambridge, United Kingdom)
;
_journal_page_first              988
_journal_page_last               989
_journal_paper_doi               10.1039/b300177f
_journal_year                    2003
_chemical_formula_sum            'C35 H44 Cl8 N4 P2 Pd2'
_chemical_formula_weight         1079.13
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_symmetry_cell_setting           monoclinic
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_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
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_audit_update_record
;
?
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_computing_cell_refinement       'd*TREK (MSC, 1996-1998)'
_computing_data_collection       'd*TREK (MSC, 1996-1998)'
_computing_data_reduction        'd*TREK (MSC, 1996-1998)'
_computing_publication_material  'teXsan (MSC, 1992-1997)'
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_computing_structure_solution
;
SIR97 (Altomare, et. al. 1998)
;
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_diffrn_radiation_detector       CCD
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_diffrn_reflns_limit_l_min       -26
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_diffrn_standards_decay_%        0.00
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_exptl_crystal_density_meas      ?
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_refine_ls_goodness_of_fit_ref   1.393
_refine_ls_hydrogen_treatment    noref
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_refine_ls_R_factor_gt           0.060
_refine_ls_shift/su_max          0.0010
_refine_ls_shift/su_mean         0.0010
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo^2^)]'
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_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            b300177f.txt
_cod_data_source_block           bj333/NDJ6/1
_cod_original_sg_symbol_H-M      'C 2/c      '
_cod_original_formula_sum        'C35 H44 Cl8 N4 P2 Pd2 '
_cod_database_code               7104071