Cationic Rare-Earth Metal Trimethylsilylmethyl Complexes Supported by THF and 12-Crown-4 Ligands: Synthesis and Structural Characterization
Benjamin R. Elvidge; Stefan Arndt; Peter M. Zeimentz; Thomas P. Spaniol; Jun Okuda; Inorganic Chemistry 44 (2005) 6777–6788; doi:10.1021/ic0511165

data_4309624
_publ_contact_author
;       Jun Okuda
        Institute of Inorganic Chemistry
        RWTH Aachen University
        Landoltweg 1
        D-52074 Aachen
        Germany
;
_publ_contact_author_email       jun.okuda@ac.rwth-aachen.de
_publ_contact_author_fax         '+49 241 8092644'
_publ_contact_author_phone       '+49 241 8094645'
_publ_section_title
;
Cationic Rare-Earth Metal Trimethylsilylmethyl Complexes Supported by THF
and 12-Crown-4 Ligands: Synthesis and Structural Characterization
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6777
_journal_page_last               6788
_journal_paper_doi               10.1021/ic0511165
_journal_volume                  44
_journal_year                    2005
_chemical_formula_sum            'C76 H99 B2 O8 Si Y'
_chemical_formula_weight         1279.17
_chemical_name_systematic
;
 ?
;
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_cell_angle_gamma                90.00
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_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'ORTEP-III (Farrugia, 1999)'
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_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full 0.996
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_exptl_absorpt_coefficient_mu    0.926
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_exptl_absorpt_correction_T_min  0.6250
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_exptl_crystal_colour            colourless
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1062P)^2^+4.6635P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1695
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_reflns_number_gt                10432
_reflns_number_total             17042
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0511165si20050706_021518_1.cif
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;
The following automatic conversions were performed:
data name '_publ_contact_autor' replaced with '_publ_contact_author'
as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 4998 2017-03-02 13:24:31Z antanas 
;
_cod_original_sg_symbol_H-M      'P 21/c'
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