<i>catena</i>-Poly[[[bis(cyclohexyldiphenylphosphine-κ<i>P</i>)silver(I)]-μ-cyano-κ^2^<i>N</i>:<i>C</i>-silver(I)-μ-cyano-κ^2^<i>C</i>:<i>N</i>] dichloromethane solvate]
Xie, Xiaocong; Saparov, Bayrammurad; Yap, Glenn P. A.; Acta Crystallographica Section E 63 (2007) m1902–m1903; doi:10.1107/S1600536807028607

data_2214077
_publ_section_title
;<i>catena</i>-Poly[[[bis(cyclohexyldiphenylphosphine-\k<i>P</i>)silver(I)]-\m-cyano-\k^2^<i>N</i>:<i>C</i>-silver(I)-\m-cyano-\k^2^<i>C</i>:<i>N</i>]
 dichloromethane solvate]
;
_journal_coeditor_code           BR2046
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1902
_journal_page_last               m1903
_journal_paper_doi               10.1107/S1600536807028607
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ag2 (C N)2 (C16 H21 P1)2], C H2 Cl2'
_chemical_formula_moiety         'C38 H42 Ag2 N2 P2, C H2 Cl2'
_chemical_formula_sum            'C39 H44 Ag2 Cl2 N2 P2'
_chemical_formula_weight         889.34
_chemical_name_systematic
;
<i>catena</i>-Poly[[[bis(cyclohexyldiphenylphosphine-\kP)silver(I)]-\m-cyano-
\k^2^N:C-silver(I)-\m-cyano-\k^2^C:N] dichloromethane solvate]
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.285(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   10.0007(12)
_cell_length_b                   14.7062(18)
_cell_length_c                   13.5338(17)
_cell_measurement_reflns_used    7412
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      2.48
_cell_volume                     1969.7(4)
_computing_cell_refinement       'SAINT (Bruker, 2002)'
_computing_data_collection       'SMART (Bruker, 2002)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL (Bruker 2002)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 836.6
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device_type  'Bruker APEX'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0214
_diffrn_reflns_av_sigmaI/netI    0.0277
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            22828
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         28.27
_diffrn_reflns_theta_min         2.06
_diffrn_standards_decay_%        1
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.240
_exptl_absorpt_correction_T_max  0.8987
_exptl_absorpt_correction_T_min  0.7839
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2002)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.500
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             900
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.09
_refine_diff_density_max         0.869
_refine_diff_density_min         -0.534
_refine_ls_abs_structure_details 'Flack (1983), 4318 Friedel pairs'
_refine_ls_abs_structure_Flack   0.087(16)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     434
_refine_ls_number_reflns         9243
_refine_ls_number_restraints     9
_refine_ls_restrained_S_all      1.137
_refine_ls_R_factor_all          0.0263
_refine_ls_R_factor_gt           0.0250
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0222P)^2^+1.1832P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0570
_refine_ls_wR_factor_ref         0.0581
_reflns_number_gt                8980
_reflns_number_total             9243
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            br2046.cif
_cod_data_source_block           I
_cod_original_sg_symbol_Hall     'p 2yb'
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               2214077
_cod_database_fobs_code          2214077