Systematic reductive oligomerization of isocyanides with a vanadium(ii) complex.
Hasegawa, Sui; Ishida, Yutaka; Kawaguchi, Hiroyuki; Chemical communications (Cambridge, England) 57 (2021) 8296–8299; doi:10.1039/d1cc03463d

data_7128705
_publ_section_title
;
 Systematic reductive oligomerization of isocyanides with a vanadium(ii)
 complex.
;
_journal_issue                   67
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              8296
_journal_page_last               8299
_journal_paper_doi               10.1039/d1cc03463d
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C57 H64 N3 O4 V'
_chemical_formula_sum            'C57 H64 N3 O4 V'
_chemical_formula_weight         906.05
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
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_audit_update_record
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2021-04-06 deposited with the CCDC.	2021-07-21 downloaded from the CCDC.
;
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_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  t~exp~   \w     \q     \k     \f   Frames
  1  \w    -37.00  43.00   0.50    0.40    --   38.95 -37.00  51.00  160
  2  \w     53.00  80.00   0.50    0.40    --   38.95 -99.00   0.00   54
  3  \w     91.00 121.00   0.50    0.40    --   38.95-178.00-150.00   60
  4  \w     45.00  80.00   0.50    0.40    --   38.95-178.00-150.00   70
  5  \w     34.00 108.00   0.50    1.62    --  113.00-111.00-120.00  148
  6  \w     74.00 107.00   0.50    1.62    --  113.00-111.00-180.00   66
  7  \w     74.00 106.00   0.50    1.62    --  113.00-111.00-150.00   64
  8  \w     69.00 101.00   0.50    1.62    --  113.00 -94.00 -60.00   64
  9  \w     70.00 103.00   0.50    1.62    --  113.00 -94.00 -30.00   66
 10  \w     75.00 105.00   0.50    1.62    --  113.00 -94.00  30.00   60
 11  \w     75.00 105.00   0.50    1.62    --  113.00-111.00  30.00   60
 12  \w     64.00 109.00   0.50    1.62    --  113.00 -77.00  30.00   90
 13  \w     72.00 103.00   0.50    1.62    --  113.00 -94.00  90.00   62
 14  \w     54.00 101.00   0.50    1.62    --  113.00 -94.00 120.00   94
 15  \w     45.00  70.00   0.50    1.62    --  113.00 -61.00   0.00   50
 16  \w     40.00  66.00   0.50    1.62    --  113.00 -94.00 -60.00   52
 17  \w     38.00  75.00   0.50    1.62    --  113.00 -61.00 -60.00   74
 18  \w     56.00  93.00   0.50    1.62    --  113.00 -94.00-120.00   74
 19  \w     38.00  64.00   0.50    1.62    --  113.00-111.00-180.00   52
 20  \w     40.00  75.00   0.50    1.62    --  113.00 -61.00-180.00   70
 21  \w     41.00 104.00   0.50    1.62    --  113.00 -94.00 -90.00  126
 22  \w     35.00  65.00   0.50    1.62    --  113.00 -94.00  30.00   60
 23  \w     38.00  69.00   0.50    1.62    --  113.00 -61.00  90.00   62
 24  \w     39.00  75.00   0.50    1.62    --  113.00 -61.00 120.00   72
 25  \w     39.00  75.00   0.50    1.62    --  113.00 -61.00  30.00   72
 26  \w     57.00  83.00   0.50    1.62    --  113.00  15.00 -60.00   52
 27  \w     84.00 176.00   0.50    1.62    --  113.00  45.00 -90.00  184
 28  \w    136.00 177.00   0.50    1.62    --  113.00  61.00 -30.00   82
 29  \w    124.00 176.00   0.50    1.62    --  113.00  45.00 -60.00  104
 30  \w    128.00 164.00   0.50    1.62    --  113.00  37.00-153.00   72
 31  \w    127.00 153.00   0.50    1.62    --  113.00  15.00 -60.00   52
 32  \w     96.00 122.00   0.50    1.62    --  113.00  45.00 -60.00   52
 33  \w     99.00 142.00   0.50    1.62    --  113.00  45.00 -30.00   86
 34  \w     87.00 175.00   0.50    1.62    --  113.00  45.00  60.00  176
 35  \w    130.00 170.00   0.50    1.62    --  113.00  30.00 120.00   80
 36  \w     89.00 129.00   0.50    1.62    --  113.00  61.00 -30.00   80
 37  \w    129.00 177.00   0.50    1.62    --  113.00 111.00 -60.00   96
 38  \w     96.00 121.00   0.50    0.40    --   38.95 178.00-180.00   50
 39  \w     52.00  78.00   0.50    0.40    --   38.95 178.00-180.00   52
 40  \w     61.00 117.00   0.50    0.40    --   38.95 178.00   0.00  112
 41  \w     48.00 120.00   0.50    0.40    --   38.95 178.00  30.00  144
 42  \w     75.00 121.00   0.50    1.62    --  113.00 178.00  90.00   92
 43  \w     88.00 166.00   0.50    1.62    --  113.00  61.00 150.00  156
 44  \w     91.00 176.00   0.50    1.62    --  113.00  61.00  90.00  170
 45  \w     83.00 114.00   0.50    1.62    --  113.00  30.00 120.00   62
 46  \w     84.00 178.00   0.50    1.62    --  113.00  45.00  30.00  188
 47  \w     92.00 118.00   0.50    1.62    --  113.00  37.00-153.00   52
 48  \w     16.00 120.00   0.50    0.40    --   38.95  37.00-153.00  208
 49  \w     34.00 107.00   0.50    1.62    --  113.00-111.00 -60.00  146
 50  \w    -15.00  41.00   0.50    0.40    --   38.95 -99.00   0.00  112
 51  \w      3.00  29.00   0.50    0.40    --  -38.95  19.00   0.00   52
 52  \w    -32.00  41.00   0.50    0.40    --  -38.95  37.00-153.00  146
 53  \w    -47.00 -22.00   0.50    0.40    --  -38.95 -37.00  51.00   50
 54  \w    -67.00 -28.00   0.50    1.62    -- -102.00  61.00  60.00   78
 55  \w    -47.00 -22.00   0.50    1.62    -- -102.00 111.00 -60.00   50
 56  \w    -64.00 -39.00   0.50    1.62    -- -102.00 111.00-180.00   50
 57  \w   -108.00 -82.00   0.50    1.62    -- -102.00 111.00-180.00   52
 58  \w   -108.00 -83.00   0.50    1.62    -- -102.00 111.00 -60.00   50
 59  \w   -108.00 -71.00   0.50    1.62    -- -102.00 111.00  90.00   74
 60  \w   -147.00-122.00   0.50    1.62    -- -102.00 -37.00  51.00   50
 61  \w   -113.00 -75.00   0.50    0.40    --  -38.95 -37.00  51.00   76
;
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'CrysAlisPro convention (1999,Acta A55,543-557)'
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;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0540P)^2^+0.4840P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 7128700--7128707.cif.'
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