Reactions of quadruply chelated silyl- and germyl-molybdenum hydrido complexes with isocyanides: observation of the trans-influence on the silyl ligand
Minato, Makoto; Nishiuchi, Jun-ya; Kakeya, Masaki; Matsumoto, Takaomi; Yamaguchi, Yoshitaka; Ito, Takashi; Dalton Transactions  (2003) 483–; doi:10.1039/b209624m

data_7012285
_publ_section_title
;
 Reactions of quadruply chelated silyl- and germyl-molybdenum hydrido
 complexes with isocyanides: observation of the trans-influence on the
 silyl ligand
;
_journal_issue                   3
_journal_name_full               'Dalton Transactions'
_journal_page_first              483
_journal_paper_doi               10.1039/b209624m
_journal_year                    2003
_chemical_formula_sum            'C70 H69 Mo N P4 Si'
_chemical_formula_weight         1172.24
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Tue Feb 27 16:27:52 2001'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90.50(2)
_cell_angle_beta                 109.72(5)
_cell_angle_gamma                76.78(7)
_cell_formula_units_Z            2
_cell_length_a                   14.42(2)
_cell_length_b                   17.611(5)
_cell_length_c                   13.275(4)
_cell_measurement_temperature    218.2
_cell_volume                     3081(5)
_computing_cell_refinement       PROCESS
_computing_data_collection       PROCESS
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.6976
_diffrn_measured_fraction_theta_max 0.6976
_diffrn_measurement_device_type  'Rigaku RAXIS-IV Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            9993
_diffrn_reflns_theta_full        27.63
_diffrn_reflns_theta_max         27.63
_exptl_absorpt_coefficient_mu    0.377
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.263
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.35
_refine_diff_density_min         -2.44
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   3.384
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     638
_refine_ls_number_reflns         9993
_refine_ls_R_factor_gt           0.1316
_refine_ls_shift/su_max          0.0040
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.3214
_reflns_number_gt                8760
_reflns_number_total             9993
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b209624m.txt
_cod_data_source_block           nij121/ito_lab/YNU
_cod_original_cell_volume        3081.4299
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C70 H69 N Mo P4 Si '
_cod_database_code               7012285