Bidentate (P^N) Au(iii)–azide complexes: synthesis and reductive elimination studies
Urvashi,; Patil, Nitin T.; Chemical Communications 61 (2025) 7297–7300; doi:10.1039/D5CC01179E

data_7134801
_publ_section_title
;
 Bidentate (P^N) Au(iii)--azide complexes: synthesis and reductive
 elimination studies
;
_journal_issue                   40
_journal_name_full               'Chemical Communications'
_journal_page_first              7297
_journal_page_last               7300
_journal_paper_doi               10.1039/D5CC01179E
_journal_volume                  61
_journal_year                    2025
_chemical_formula_sum            'C68 H90 Au2 F12 N8 P2 Sb2'
_chemical_formula_weight         1946.85
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2025-02-21 deposited with the CCDC.	2025-04-14 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_computing_cell_refinement       'Bruker SAINT'
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
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_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1871
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_diffrn_reflns_limit_l_min       -40
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_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.996
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_diffrn_reflns_theta_max         26.408
_diffrn_reflns_theta_min         1.919
_exptl_absorpt_coefficient_mu    4.784
_exptl_crystal_colour            WHITE
_exptl_crystal_density_diffrn    1.744
_exptl_crystal_description       SQUARE
_exptl_crystal_F_000             3808
_exptl_crystal_recrystallization_method 'Vapor Diffusion'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0514P)^2^+34.0892P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           platon_sq
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