Mechanistic Characterization of Aerobic Alcohol Oxidation Catalyzed by Pd(OAc)2/Pyridine Including Identification of the Catalyst Resting State and the Origin of Nonlinear [Catalyst] Dependence
Bradley A. Steinhoff; Ilia A. Guzei; Shannon S. Stahl; Journal of the American Chemical Society 126 (2004) 11268–11278; doi:10.1021/ja049962m

data_4112942
_publ_contact_author_address
;
   2124 Chemistry Department
   University of Wisconsin-Madison
   1101 University Ave
   Madison, WI  53706
   USA
;
_publ_contact_author_email       iguzei@chem.wisc.edu
_publ_contact_author_fax         608-262-0381
_publ_contact_author_name
;
Ilia A. Guzei
;
_publ_contact_author_phone       608-263-4694
_publ_section_title
;
 Mechanistic Characterization of Aerobic Alcohol Oxidation Catalyzed by
 Pd(OAc)2/Pyridine Including Identification of the Catalyst Resting State
 and the Origin of Nonlinear [Catalyst] Dependence
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11268
_journal_page_last               11278
_journal_paper_doi               10.1021/ja049962m
_journal_volume                  126
_journal_year                    2004
_chemical_formula_sum            'C20 H43 N O4'
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_chemical_name_systematic
; 
 ? 
;
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_computing_cell_refinement       'Bruker SMART'
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_diffrn_ambient_temperature      100(2)
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_diffrn_measurement_device_type  'CCD area detector'
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_diffrn_radiation_monochromator  graphite
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0293P)^2^+0.6724P] where P=(Fo^2^+2Fc^2^)/3'
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