Toward new organometallic architectures: synthesis of carbene-centered rhodium and palladium bisphosphine complexes. stability and reactivity of [PC(BIm)PRh(L)][PF6] pincers.
Plikhta, Andriy; Pöthig, Alexander; Herdtweck, Eberhardt; Rieger, Bernhard; Inorganic chemistry 54 (2015) 9517–9528; doi:10.1021/acs.inorgchem.5b01428

data_4346414
_publ_section_title
;
 Toward new organometallic architectures: synthesis of carbene-centered
 rhodium and palladium bisphosphine complexes. stability and reactivity of
 [PC(BIm)PRh(L)][PF6] pincers.
;
_journal_issue                   19
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9517
_journal_page_last               9528
_journal_paper_doi               10.1021/acs.inorgchem.5b01428
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'C33 H29 N2 P2, F6 P'
_chemical_formula_sum            'C33 H29 F6 N2 P3'
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_cell_angle_alpha                75.565(2)
_cell_angle_beta                 72.988(1)
_cell_angle_gamma                82.484(2)
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_cell_length_b                   13.3209(5)
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_cell_measurement_temperature    123
_cell_measurement_theta_max      25.3427
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_computing_cell_refinement       'SAINT (Bruker, 2012)'
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_computing_molecular_graphics    'PLATON (Spek, 2011)'
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'SHELXL2013 (Sheldrick, 2013), SHELXLE (Huebschle, 2011)'
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_diffrn_ambient_temperature      123
_diffrn_detector                 ' CCD plate '
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_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       ' \k-geometry diffractometer '
_diffrn_measurement_device_type  ' Bruker APEX-II CCD '
_diffrn_measurement_method       ' phi- and omega-rotation '
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_diffrn_radiation_source         'fine-focus sealed tube'
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_diffrn_reflns_limit_l_min       -22
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_diffrn_reflns_reduction_process
;
;
_diffrn_reflns_theta_full        25.24
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_refine_ls_structure_factor_coef Fsqd
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'W=1/[\S^2^(FO^2^)+(0.0350P)^2^+1.6662P] WHERE P=(FO^2^+2FC^2^)/3'
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