Phosphido-bis(borane) complexes of the alkaline earth metals.
Izod, Keith; Watson, James M.; Harrington, Ross W.; Clegg, William; Dalton transactions (Cambridge, England : 2003) 50 (2021) 1019–1024; doi:10.1039/d0dt03895d

data_7706211
_publ_section_title
;
 Phosphido-bis(borane) complexes of the alkaline earth metals.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               1024
_journal_paper_doi               10.1039/d0dt03895d
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety
'C24 H48 Mg O6 2+,2 C13 H30 B2 P Si2 -,C4 H8 O'
_chemical_formula_sum            'C54 H116 B4 Mg O7 P2 Si4'
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2020-12-03 deposited with the CCDC.	2020-12-14 downloaded from the CCDC.
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_cell_volume                     3415.8(2)
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.66 (release 28-04-2010 CrysAlis171 .NET)
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CrysAlisPro, Oxford Diffraction Ltd.,
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CrysAlisPro, Oxford Diffraction Ltd.,
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'Oxford Diffraction Gemini A Ultra diffractometer'
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.66 (release 28-04-2010 CrysAlis171 .NET)
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.088
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1228
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: toluene and THF'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0469P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_refine_ls_wR_factor_gt          0.0822
_refine_ls_wR_factor_ref         0.0861
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4568
_reflns_number_total             6567
_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7706210--7706214.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7706211
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.946
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