Dimetallagermanes of molybdenum and tungsten: synthesis, structure and reactions
Filippou, Alexander C.; Winter, Johannes G.; Kociok-Köhn, Gabriele; Hinz, Isolde; Journal of the Chemical Society, Dalton Transactions  (1998) 2029–; doi:10.1039/a801380b

data_7027906
_publ_contact_author
;
    Alexander C. Filippou
    Institut f\"ur Anorganische und Allgemeine Chemie der
    Humboldt Universit\"at zu Berlin
    Hessische Strasse 1-2
    10115 Berlin
    Bundesrepublik Deutschland
;
_publ_section_title
;
 Dimetallagermanes of molybdenum and tungsten: synthesis, structure and
 reactions&#x200A;
;
_journal_issue                   12
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2029
_journal_paper_doi               10.1039/a801380b
_journal_year                    1998
_chemical_formula_moiety         'C16 H10 Cl2 Ge O6 W2'
_chemical_formula_structural     '[(C5 H5) W (C O)3)]2 Ge Cl2'
_chemical_formula_sum            'C16 H10 Cl2 Ge O6 W2'
_chemical_formula_weight         809.45
_chemical_name_systematic
; 
 ? 
;
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_cell_angle_gamma                90.00
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_cell_length_a                   11.370(3)
_cell_length_b                   14.848(4)
_cell_length_c                   23.811(9)
_cell_measurement_reflns_used    46
_cell_measurement_temperature    293(2)
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_cell_volume                     4020(2)
_computing_cell_refinement       'STADI4 (STOE, 1995)'
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_computing_data_reduction        'X-RED, (STOE, 1995)'
_computing_molecular_graphics
;
  L.Zsolnai, H.Pritzkow, ZORTEP, ORTEP program for PC,
  Universit\"at Heidelberg 1994
;
_computing_publication_material  'SHELXL-93 (Sheldrick, 1993)'
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_diffrn_ambient_temperature      293(2)
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_diffrn_measurement_method       \w-2\q
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_diffrn_standards_interval_time  120
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_exptl_absorpt_correction_type   none
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_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0704P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1092
_refine_ls_wR_factor_obs         0.0969
_reflns_number_observed          2979
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_cod_data_source_file            B801380sup1.cif
_cod_data_source_block           hansi14
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0704P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0704P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        4019.8(21)
_cod_database_code               7027906