Visible Light Enhanced Selective Reductive Elimination of a Methylmanganese Complex from a Heterodinuclear Dimethylphenyl(4,4′-di-tert-butyl-2,2′-bipyridine)platinum−Pentacarbonylmanganese Complex
Komiya, Sanshiro; Ezumi, Sei; Komine, Nobuyuki; Hirano, Masafumi; Organometallics 28 (2009) 3608–; doi:10.1021/om900319a

data_4069633
_publ_section_title
;
 Visible Light Enhanced Selective Reductive Elimination of a
 Methylmanganese Complex from a Heterodinuclear
 Dimethylphenyl(4,4&#x2032;-di-tert-butyl-2,2&#x2032;-bipyridine)platinum&#x2212;Pentacarbonylmanganese
 Complex
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3608
_journal_paper_doi               10.1021/om900319a
_journal_volume                  28
_journal_year                    2009
_chemical_formula_moiety         'C18 H17 Mn N2 O5 Pt '
_chemical_formula_sum            'C18 H17 Mn N2 O5 Pt'
_chemical_formula_weight         591.37
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 103.415(14)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   13.574(3)
_cell_length_b                   10.5780(17)
_cell_length_c                   13.601(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    200.1
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.9
_cell_volume                     1899.6(7)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.024
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            4523
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 0
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    8.023
_exptl_absorpt_correction_T_max  0.448
_exptl_absorpt_correction_T_min  0.264
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    2.068
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1128.00
_exptl_crystal_size_max          0.46
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.51
_refine_diff_density_min         -1.96
_refine_ls_extinction_coef       0.00194(15)
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.936
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     246
_refine_ls_number_reflns         4340
_refine_ls_R_factor_gt           0.0292
_refine_ls_shift/su_max          0.0010
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0445P)^2^+1.1111P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0816
_reflns_number_gt                3584
_reflns_number_total             4340
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om900319a_si_001.cif
_cod_data_source_block           '_(bpy)Me3Pt-Mn(CO)5'
_cod_original_cell_volume        1899.6(6)
_cod_original_formula_sum        'C18 H17 Mn N2 O5 Pt '
_cod_database_code               4069633