Factors involved in the nuclearity of silver thiosemicarbazone clusters: cocrystallization of two different sized tetranuclear silver(I) clusters derived from a phosphinothiosemicarbazone ligand.
Castiñeiras, Alfonso; Pedrido, Rosa; Inorganic chemistry 47 (2008) 5534–5536; doi:10.1021/ic800178v

data_4338689
_publ_section_title
;
 Factors involved in the nuclearity of silver thiosemicarbazone clusters:
 cocrystallization of two different sized tetranuclear silver(I) clusters
 derived from a phosphinothiosemicarbazone ligand.
;
_journal_issue                   13
_journal_name_full               'Inorganic chemistry'
_journal_page_first              5534
_journal_page_last               5536
_journal_paper_doi               10.1021/ic800178v
_journal_volume                  47
_journal_year                    2008
_chemical_formula_moiety         'C104 H84 Ag4 N12 P4 S4, 4(C H4 O)'
_chemical_formula_sum            'C108 H100 Ag4 N12 O4 P4 S4'
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_chemical_name_systematic
; 
 ? 
;
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_cell_length_b                   16.1237(3)
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_cell_measurement_theta_min      2.2875
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_computing_cell_refinement       'APEX2 Software (Bruker, 2005)'
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_computing_data_reduction        'APEX2 Software (Bruker, 2005)'
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_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
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_diffrn_ambient_temperature      100(2)
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_diffrn_measurement_device_type  'Bruker X8 KappaAPEXII'
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_diffrn_standards_decay_%        0
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_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0484P)^2^+8.3283P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            2.cif
_cod_data_source_block           07rp09
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/automatic-downloads/retrospective/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Empirical'
changed to 'empirical' according to
/usr/data/users/saulius/automatic-downloads/retrospective/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        5010.33(18)
_cod_original_sg_symbol_H-M      'P -1 (No. 2)'
_cod_database_code               4338689