Formoxyboranes as hydroborane surrogates for the catalytic reduction of carbonyls through transfer hydroboration
Durin, Gabriel; Romero, R. Martin; Godou, Timothé; Chauvier, Clément; Thuéry, Pierre; Nicolas, Emmanuel; Cantat, Thibault; Catalysis Science & Technology 14 (2024) 1848–1853; doi:10.1039/D3CY01702H

data_1571020
_publ_section_title
;
 Formoxyboranes as hydroborane surrogates for the catalytic reduction of
 carbonyls through transfer hydroboration
;
_journal_issue                   7
_journal_name_full               'Catalysis Science &amp; Technology'
_journal_page_first              1848
_journal_page_last               1853
_journal_paper_doi               10.1039/D3CY01702H
_journal_volume                  14
_journal_year                    2024
_chemical_formula_sum            'C94 H170 B6 O16'
_chemical_formula_weight         1621.15
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2023-07-25 deposited with the CCDC.	2024-02-13 downloaded from the CCDC.
;
_cell_angle_alpha                97.730(3)
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_cell_volume                     2500.0(2)
_computing_cell_refinement       'HKL2000 (Otwinowski & Minor, 1997)'
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'SHELXTL (Sheldrick, 2008); PLATON (Spek, 2003)'
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_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      200(2)
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Nonius Kappa-CCD area-detector diffractometer'
_diffrn_measurement_method
'2 \f and 11 \w scans with 2\% steps (672 frames)'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_Laue_measured_fraction_full 0.995
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_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
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_refine_diff_density_min         -0.484
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_refine_ls_extinction_method     none
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_refine_ls_restrained_S_all      1.150
_refine_ls_R_factor_all          0.0833
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1126P)^2^+0.5003P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 1571020--1571024.cif.'
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