Guilty on Two Counts: Stepwise Coordination of Two Fluoride Anions to the Antimony Atom of a Noninnocent Stibine Ligand
Jones, James S.; Wade, Casey R.; Gabba\?ï, François P.; Organometallics 34 (2015) 2647–; doi:10.1021/om501291g

data_4085563
_publ_section_title
;
 Guilty on Two Counts: Stepwise Coordination of Two Fluoride Anions to the
 Antimony Atom of a Noninnocent Stibine Ligand
;
_journal_issue                   11
_journal_name_full               Organometallics
_journal_page_first              2647
_journal_paper_doi               10.1021/om501291g
_journal_volume                  34
_journal_year                    2015
_chemical_formula_sum            'C63 H55 Cl6 F12 N P3 Pt Sb3'
_chemical_formula_weight         1920.03
_chemical_name_systematic
; 
 ? 
;
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_cell_length_b                   15.673(2)
_cell_length_c                   20.636(3)
_cell_measurement_reflns_used    9995
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_cell_measurement_theta_min      2.32
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_computing_cell_refinement       'Bruker SMART'
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_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      110(2)
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_diffrn_reflns_theta_min         1.63
_exptl_absorpt_coefficient_mu    3.621
_exptl_absorpt_correction_T_max  0.5780
_exptl_absorpt_correction_T_min  0.3812
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.882
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1852
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1164P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1740
_refine_ls_wR_factor_ref         0.1836
_reflns_number_gt                13386
_reflns_number_total             15563
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om501291g_si_004.cif
_cod_data_source_block           y
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 4085560--4085564.cif.
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_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4085563