Construction of three coordination polymers based on tetranuclear copper(ii) clusters: syntheses, structures and photocatalytic properties
Liu, Lu; Peng, Yan-Fen; Lv, Xiu-Xiu; Li, Ke; Li, Bao-Long; Wu, Bing; CrystEngComm 18 (2016) 2490–; doi:10.1039/C5CE02492G

data_7224509
_publ_section_title
;
 Construction of three coordination polymers based on tetranuclear
 copper(ii) clusters: syntheses, structures and photocatalytic properties
;
_journal_issue                   14
_journal_name_full               CrystEngComm
_journal_page_first              2490
_journal_paper_doi               10.1039/C5CE02492G
_journal_volume                  18
_journal_year                    2016
_chemical_formula_moiety         'C34 H30 Cu4 N10 O14, 2(C2 H6 O), 2(H2 O)'
_chemical_formula_sum            'C38 H46 Cu4 N10 O18'
_chemical_formula_weight         1185.01
_chemical_name_systematic
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 ? 
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_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
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2015-11-26 deposited with the CCDC.
2016-03-04 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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_computing_molecular_graphics    'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            'clear light blue'
_exptl_crystal_density_diffrn    1.766
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_exptl_crystal_description       block
_exptl_crystal_F_000             1208
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0413P)^2^+1.2211P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0832
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_reflns_number_gt                3902
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_cod_data_source_file            c5ce02492g2.cif
_cod_data_source_block           CuitpbtcEtOH
_cod_depositor_comments
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The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7224508--7224510.cif.
;
_cod_original_cell_volume        2228.40(18)
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7224509