Synthesis and structures of [S[double bond, length as m-dash](H)P(μ-NR)]2, potential building blocks for inorganic phosphorus-sulfur macrocycles.
Benson, Callum G. M.; Vasilenko, Vladislav; García-Rodríguez, Raúl; Bond, Andrew D.; González Calera, Silvia; Gade, Lutz H.; Wright, Dominic S.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 14242–14247; doi:10.1039/c5dt02069g

data_7035698
_publ_section_title
;
 Synthesis and structures of [S[double bond, length as
 m-dash](H)P(\m-NR)]2, potential building blocks for inorganic
 phosphorus-sulfur macrocycles.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14242
_journal_page_last               14247
_journal_paper_doi               10.1039/c5dt02069g
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C8 H20 N2 P2 S2'
_chemical_formula_sum            'C8 H20 N2 P2 S2'
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_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2015-04-30 deposited with the CCDC.
2015-07-07 downloaded from the CCDC.
;
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_cell_volume                     699.27(4)
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_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor, 1997)'
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_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       '\w and \f-scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.967
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_diffrn_reflns_point_group_measured_fraction_full 0.967
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'Re-crystallisation from solvent: Toluene'
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_refine_ls_R_factor_all          0.0305
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0220P)^2^+0.2619P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7035698--7035700.cif.'
_cod_database_code               7035698
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_shelx_estimated_absorpt_t_max   0.923
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