Cu(ii) complexes of N-rich aroylhydrazone: magnetism and catalytic activity towards microwave-assisted oxidation of xylenes.
Sutradhar, Manas; Roy Barman, Tannistha; Alegria, Elisabete C. B. A.; Guedes da Silva, M Fátima C; Liu, Cai-Ming; Kou, Hui-Zhong; Pombeiro, Armando J. L.; Dalton transactions (Cambridge, England : 2003) 48 (2019) 12839–12849; doi:10.1039/c9dt02196e

data_7700565
_publ_section_title
;
 Cu(ii) complexes of N-rich aroylhydrazone: magnetism and catalytic
 activity towards microwave-assisted oxidation of xylenes.
;
_journal_issue                   34
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12839
_journal_page_last               12849
_journal_paper_doi               10.1039/c9dt02196e
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C16 H17 Cu3 N11 O19'
_chemical_formula_sum            'C16 H17 Cu3 N11 O19'
_chemical_formula_weight         858.02
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2019-05-23 deposited with the CCDC.    2019-07-15 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_diffrn_measurement_device_type  'Bruker APEX-II PHOTON 100 detector'
_diffrn_measurement_method       '\f and \w scans'
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_refine_ls_matrix_type           full
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_refine_ls_R_factor_all          0.0260
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0248P)^2^+2.0364P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0514
_refine_ls_wR_factor_ref         0.0533
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7935
_reflns_number_total             8740
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt02196e2.cif
_cod_data_source_block           shelx_CCDC1
_cod_depositor_comments
'Adding full bibliography for 7700564--7700566.cif.'
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