Investigations on the catalytic carboxylation of olefins with CO2 towards α,β-unsaturated carboxylic acid salts: characterization of intermediates and ligands as well as substrate effects.
Jevtovikj, Ivana; Manzini, Simone; Hanauer, Matthias; Rominger, Frank; Schaub, Thomas; Dalton transactions (Cambridge, England : 2003) 44 (2015) 11083–11094; doi:10.1039/c5dt01040c

data_7034854
_publ_section_title
;
 Investigations on the catalytic carboxylation of olefins with CO2 towards
 \a,\b-unsaturated carboxylic acid salts: characterization of
 intermediates and ligands as well as substrate effects.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11083
_journal_page_last               11094
_journal_paper_doi               10.1039/c5dt01040c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C31 H54 Ni O2 P2'
_chemical_formula_weight         579.39
_chemical_name_common            '4c in manuscript'
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           '-P 2ac 2n'
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_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
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;
2015-03-05 deposited with the CCDC.
2015-05-05 downloaded from the CCDC.
;
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_diffrn_source                   'ImuS microsource'
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;
Sheldrick, G. M. (2008). <i>SADABS</i>. University of G\"ottingen, Germany.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0630P)^2^+20.3407P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7034853--7034856.cif.'
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