Rapid synthesis of polysubstituted phenanthridines from simple aliphatic/aromatic nitriles and iodo arenes via Pd(ii) catalyzed domino C-C/C-C/C-N bond formation.
Jaiswal, Yogesh; Kumar, Yogesh; Pal, Jagannath; Subramanian, Ranga; Kumar, Amit; Chemical communications (Cambridge, England) 54 (2018) 7207–7210; doi:10.1039/c8cc03556c

data_7121801
_publ_section_title
;
 Rapid synthesis of polysubstituted phenanthridines from simple
 aliphatic/aromatic nitriles and iodo arenes via Pd(ii) catalyzed domino
 C-C/C-C/C-N bond formation.
;
_journal_issue                   52
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              7207
_journal_page_last               7210
_journal_paper_doi               10.1039/c8cc03556c
_journal_volume                  54
_journal_year                    2018
_chemical_formula_moiety         C20H15NO
_chemical_formula_sum            'C20 H15 N O'
_chemical_formula_weight         285.33
_chemical_name_common            phenanthridine
_chemical_name_systematic        6-(4-methoxyphenyl)phenanthridine
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
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;
2018-01-15 deposited with the CCDC.
2018-06-04 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      273(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0655
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_diffrn_reflns_Laue_measured_fraction_full 0.984
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_diffrn_reflns_number            29074
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'Re-crystallisation from solvent: Ethyl acetate'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0597P)^2^+0.3631P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                1629
_reflns_number_total             2948
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           yogesh_a
_cod_depositor_comments          'Adding full bibliography for 7121801.cif.'
_cod_database_code               7121801
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.984
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_shelx_res_checksum              56970