Stepwise cyclopalladation of 2-phenacylthiopyridine to give C,C,N-pincer complexes.
Chicote, María-Teresa; Rubio, Concepción; Bautista, Delia; Vicente, José; Dalton transactions (Cambridge, England : 2003) 43 (2014) 15170–15182; doi:10.1039/c4dt02085e

data_7032011
_publ_section_title
;
 Stepwise cyclopalladation of 2-phenacylthiopyridine to give C,C,N-pincer
 complexes.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15170
_journal_page_last               15182
_journal_paper_doi               10.1039/c4dt02085e
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C30 H26 N2 O6 Pd2 S2'
_chemical_formula_weight         787.44
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
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_diffrn_measurement_device_type  'Bruker D8 QUEST'
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_diffrn_reflns_limit_h_max       45
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_diffrn_source                   'high brilliance microfocus sealed tube '
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_refine_ls_structure_factor_coef Fsqd
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;
 w=1/[\s^2^(Fo^2^)+(0.0167P)^2^+25.3554P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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_reflns_number_total             7352
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c4dt02085e2.cif
_cod_data_source_block           f71b_omsp
_cod_depositor_comments
;
Adding full bibliography for 7032009--7032011.cif.

2018-01-27
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C15 H13 N O3 Pd S'
_cod_original_formula_weight         393.72
_cod_original_formula_units_Z            16
_cod_original_cell_volume        5932.6(10)
_cod_database_code               7032011
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_shelx_estimated_absorpt_t_max   0.797
_shelxl_version_number           2013-2
_shelx_res_checksum              53978