Mechanism of Copper-Catalyzed Hydroalkylation of Alkynes: An Unexpected Role of Dinuclear Copper Complexes.
Suess, Alison M.; Uehling, Mycah R.; Kaminsky, Werner; Lalic, Gojko; Journal of the American Chemical Society 137 (2015) 7747–7753; doi:10.1021/jacs.5b03086

data_4123831
_publ_section_title
;
 Mechanism of Copper-Catalyzed Hydroalkylation of Alkynes: An Unexpected
 Role of Dinuclear Copper Complexes.
;
_journal_issue                   24
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              7747
_journal_page_last               7753
_journal_paper_doi               10.1021/jacs.5b03086
_journal_volume                  137
_journal_year                    2015
_chemical_absolute_configuration unk
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_chemical_formula_moiety         'C38 H51 Cu N2'
_chemical_formula_sum            'C38 H51 Cu N2'
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_chemical_name_common            Mu_09_130
_chemical_name_systematic
;
 Mu_09_130_0ma
;
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_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      20
_cell_measurement_theta_min      3
_cell_measurement_wavelength     0.71073
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_computing_cell_refinement       'SAINT (Bruker, 2007)'
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_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
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_diffrn_radiation_monochromator  graphite
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_exptl_crystal_colour            colourless
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_exptl_crystal_description       prism
_exptl_crystal_F_000             644
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0308P)^2^+0.0225P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0656
_refine_ls_wR_factor_ref         0.0698
_reflns_number_gt                7656
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_cod_depositor_comments
'Adding full bibliography for 4123829--4123832.cif.'
_cod_database_code               4123831