Analysis of an Unprecedented Mechanism for the Catalytic Hydrosilylation of Carbonyl Compounds
Kristine A. Nolin; Jennifer R. Krumper; Michael D. Pluth; Robert G. Bergman; F. Dean Toste; Journal of the American Chemical Society 129 (2007) 14684–14696; doi:10.1021/ja074477n

data_4110242
_publ_section_title
;
 Analysis of an Unprecedented Mechanism for the Catalytic Hydrosilylation
 of Carbonyl Compounds
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              14684
_journal_page_last               14696
_journal_paper_doi               10.1021/ja074477n
_journal_volume                  129
_journal_year                    2007
_chemical_formula_sum            'C51 H48 Cl4 I O2 P2 Re Si'
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_computing_data_collection
'MSC_computing_cell_refinement    SAINT v6.40'
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_refine_ls_extinction_coef       0.0012(2)
_refine_ls_extinction_method     'Zachariasen(1967) type 2 gaussian isotropic'
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00022|Fo|^2^]'
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