Developing strongly luminescent platinum(iv) complexes: facile synthesis of bis-cyclometalated neutral emitters.
Juliá, Fabio; Bautista, Delia; González-Herrero, Pablo; Chemical communications (Cambridge, England) 52 (2016) 1657–1660; doi:10.1039/c5cc09566b

data_7118511
_publ_section_title
;
 Developing strongly luminescent platinum(iv) complexes: facile synthesis
 of bis-cyclometalated neutral emitters.
;
_journal_issue                   8
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              1657
_journal_page_last               1660
_journal_paper_doi               10.1039/c5cc09566b
_journal_volume                  52
_journal_year                    2016
_chemical_formula_sum            'C42 H37 Cl3 N2 Pt'
_chemical_formula_weight         871.17
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-11-06 deposited with the CCDC.
2015-12-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
_cell_formula_units_Z            4
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker D8 QUEST'
_diffrn_measurement_method       'w-scans  and phi scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_l_min       -26
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_exptl_absorpt_process_details   SADABS
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
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_refine_ls_number_reflns         11032
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0158P)^2^+3.8877P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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