Osmium(0)-Catalyzed C-C Coupling of Ethylene and α-Olefins with Diols, Ketols, or Hydroxy Esters via Transfer Hydrogenation.
Park, Boyoung Y.; Luong, Tom; Sato, Hiroki; Krische, Michael J.; The Journal of organic chemistry 81 (2016) 8585–8594; doi:10.1021/acs.joc.6b01923

data_4032052
_publ_section_title
;
 Osmium(0)-Catalyzed C-C Coupling of Ethylene and \a-Olefins with Diols,
 Ketols, or Hydroxy Esters via Transfer Hydrogenation.
;
_journal_issue                   18
_journal_name_full               'The Journal of organic chemistry'
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_journal_page_last               8594
_journal_paper_doi               10.1021/acs.joc.6b01923
_journal_volume                  81
_journal_year                    2016
_chemical_formula_moiety         'C33 H49 P, 3 Os, 11 C O'
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SUPERFLIP.  Palatinus, L. and Chapuis, G., J. Appl. Cryst. 40, 786-790.
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CrysAlisPro 1.171.38.27t (Agilent, 2015)
Numerical absorption correction based on gaussian integration over
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Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0178P)^2^+11.8122P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
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The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Gaussian' changed to
'gaussian' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 4032052--4032053.cif.
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_cod_database_code               4032052
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