Construction of polyoxometalates from dynamic lacunary polyoxotungstate building blocks and lanthanide linkers.
Li, Lu-Lu; Han, Hua-Yan; Wang, Yong-Hui; Tan, Hua-Qiao; Zang, Hong-Ying; Li, Yang-Guang; Dalton transactions (Cambridge, England : 2003) 44 (2015) 11429–11436; doi:10.1039/c5dt00686d

data_7035272
_publ_section_title
;
 Construction of polyoxometalates from dynamic lacunary polyoxotungstate
 building blocks and lanthanide linkers.
;
_journal_issue                   25
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11429
_journal_page_last               11436
_journal_paper_doi               10.1039/c5dt00686d
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C12 H118 Ho4 Li17 N2 Na7 O199 Sb10 W36'
_chemical_formula_weight         12249.81
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2015-04-17 deposited with the CCDC.
2015-05-11 downloaded from the CCDC.
;
_cell_angle_alpha                72.271(2)
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_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.1336
_cell_measurement_theta_min      2.1871
_cell_volume                     5662.9(10)
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        SAINT
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0721
_diffrn_reflns_av_unetI/netI     0.1400
_diffrn_reflns_laue_measured_fraction_full 0.973
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_diffrn_reflns_limit_h_max       17
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_diffrn_reflns_number            32895
_diffrn_reflns_point_group_measured_fraction_full 0.973
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_diffrn_reflns_theta_full        25.242
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_diffrn_source                   'fine-focus sealed tube'
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_exptl_absorpt_correction_T_max  0.097
_exptl_absorpt_correction_T_min  0.082
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    3.592
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_exptl_crystal_size_max          0.240
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_platon_squeeze_details
;
;
_refine_diff_density_max         4.069
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_refine_ls_R_factor_all          0.0933
_refine_ls_R_factor_gt           0.0605
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0400P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1485
_refine_ls_wR_factor_ref         0.1588
_reflns_Friedel_coverage         0.000
_reflns_number_gt                12547
_reflns_number_total             19926
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt00686d2.cif
_cod_data_source_block           Ho-5
_cod_depositor_comments
'Adding full bibliography for 7035268--7035272.cif.'
_cod_database_code               7035272
_audit_block_doi                 10.5517/cc13z4t1
_shelx_estimated_absorpt_t_min   0.082
_shelx_estimated_absorpt_t_max   0.097
_shelxl_version_number           2014-3
_shelx_res_checksum              93166