Gold(I) and platinum(II) complexes with a new diphosphine ligand based on the cyclotriphosphazene platform.
Ainscough, Eric W.; Brodie, Andrew M.; Chaplin, Adrian B.; O'Connor, Joy M; Otter, Carl A.; Dalton transactions (Cambridge, England : 2003)  (2006) 1264–1266; doi:10.1039/b517309b

data_7007094
_publ_section_title
;
 Gold(I) and platinum(II) complexes with a new diphosphine ligand based
 on the cyclotriphosphazene platform.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1264
_journal_page_last               1266
_journal_paper_doi               10.1039/b517309b
_journal_year                    2006
_chemical_formula_sum            'C62.7 H46.7 Au2 Cl10.1 N3 O6 P5'
_chemical_formula_weight         1845.06
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.237(1)
_cell_angle_beta                 104.527(1)
_cell_angle_gamma                100.185(1)
_cell_formula_units_Z            2
_cell_length_a                   13.8387(2)
_cell_length_b                   14.0919(1)
_cell_length_c                   18.3886(1)
_cell_measurement_temperature    83(2)
_cell_volume                     3397.49(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      356(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Brucker P4'
_diffrn_measurement_method       'Area detector /w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0627
_diffrn_reflns_av_sigmaI/netI    0.0831
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            30919
_diffrn_reflns_theta_full        25.86
_diffrn_reflns_theta_max         25.86
_diffrn_reflns_theta_min         1.15
_exptl_absorpt_coefficient_mu    4.880
_exptl_absorpt_correction_T_max  0.4088
_exptl_absorpt_correction_T_min  0.2358
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, Acta Cryst., 1995, A51, 33-38'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.803
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1485
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.24
_refine_diff_density_max         3.690
_refine_diff_density_min         -3.577
_refine_diff_density_rms         0.195
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.950
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     703
_refine_ls_number_reflns         12898
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.950
_refine_ls_R_factor_all          0.0667
_refine_ls_R_factor_gt           0.0498
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0715P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1213
_refine_ls_wR_factor_ref         0.1295
_reflns_number_gt                9596
_reflns_number_total             12898
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b517309b.txt
_cod_data_source_block           cao376
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7007094