Rhenium(i) sapphyrins: remarkable difference between the C<sub>6</sub>F<sub>5</sub> and CF<sub>3</sub>-substituted derivatives.
Yadav, Pinky; Fridman, Natalia; Mizrahi, Amir; Gross, Zeev; Chemical communications (Cambridge, England) 56 (2020) 980–983; doi:10.1039/c9cc08877f

data_7125656
_publ_section_title
;
 Rhenium(i) sapphyrins: remarkable difference between the
 C<sub>6</sub>F<sub>5</sub> and CF<sub>3</sub>-substituted derivatives.
;
_journal_issue                   6
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              980
_journal_page_last               983
_journal_paper_doi               10.1039/c9cc08877f
_journal_volume                  56
_journal_year                    2020
_chemical_formula_moiety         'C31 H12 F12 N5 O3 Re'
_chemical_formula_sum            'C31 H12 F12 N5 O3 Re'
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_chemical_name_common            'Gross254b (Pinky)'
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2019-08-25 deposited with the CCDC.	2019-12-16 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_volume                     2917.5(4)
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_diffrn_ambient_temperature      200(2)
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_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'APEX2 (Bruker AXS)'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_process_details   'SADABS V2008/1 (Bruker AXS)'
_exptl_crystal_colour            'dark brown'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0320P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                4216
_reflns_number_total             5076
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9cc08877f2.cif
_cod_data_source_block           Gross254b
_cod_depositor_comments
'Adding full bibliography for 7125655--7125656.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7125656
_shelx_shelxl_version_number     2018/3
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_shelx_res_checksum              92920