Catalytic hydroboration of aldehydes and ketones with an electron-rich acyclic metallasilylene.
Kapp, Leon; Wölper, Christoph; Siera, Hannah; Haberhauer, Gebhard; Schulz, Stephan; Chemical science 15 (2024) 4161–4170; doi:10.1039/d3sc06842k

data_1570977
_publ_section_title
;
 Catalytic hydroboration of aldehydes and ketones with an electron-rich
 acyclic metallasilylene.
;
_journal_issue                   11
_journal_name_full               'Chemical science'
_journal_page_first              4161
_journal_page_last               4170
_journal_paper_doi               10.1039/d3sc06842k
_journal_volume                  15
_journal_year                    2024
_chemical_formula_sum            'C55 H88 Cl Ga N4 O Si'
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_space_group_name_Hall           '-P 1'
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_audit_update_record
;
2023-06-19 deposited with the CCDC.	2024-02-12 downloaded from the CCDC.
;
_cell_angle_alpha                101.433(3)
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_cell_angle_gamma                111.151(2)
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_diffrn_measurement_device_type  'Bruker D8 KAPPA II (APEX II detector)'
_diffrn_measurement_method       'Data collection strategy APEX 3/Queen'
_diffrn_radiation_monochromator  'Triumph Goebel mirror'
_diffrn_radiation_type           MoK\a
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_exptl_crystal_colour            colourless
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0429P)^2^+0.9959P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 1570976--1570977.cif.'
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