Synthesis of Benzo[c]thiophenes by Rhodium(III)-Catalyzed Dehydrogenative Annulation.
Fukuzumi, Keita; Unoh, Yuto; Nishii, Yuji; Satoh, Tetsuya; Hirano, Koji; Miura, Masahiro; The Journal of organic chemistry 81 (2016) 2474–2481; doi:10.1021/acs.joc.6b00030

data_4036612
_publ_section_title
;
 Synthesis of Benzo[c]thiophenes by Rhodium(III)-Catalyzed Dehydrogenative
 Annulation.
;
_journal_issue                   6
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              2474
_journal_page_last               2481
_journal_paper_doi               10.1021/acs.joc.6b00030
_journal_volume                  81
_journal_year                    2016
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.0000
_cell_angle_beta                 92.968(7)
_cell_angle_gamma                90.0000
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_cell_measurement_temperature    293
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      3.10
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_computing_cell_refinement       'CrystalClear-SM Expert 2.0 r15'
_computing_data_collection       'CrystalClear-SM Expert 2.0 r15 (Rigaku, 2011)'
_computing_data_reduction        'CrystalClear-SM Expert 2.0 r15'
_computing_molecular_graphics    'CrystalStructure 4.0'
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_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293
_diffrn_detector_area_resol_mean 6.827
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Rigaku XtaLAB mini'
_diffrn_measurement_method       \w
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_exptl_crystal_density_method    'not measured'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0315P)^2^+1.3052P] where P=(Fo^2^+2Fc^2^)/3'
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