Stereodivergent Intramolecular C(sp(3))-H Functionalization of Azavinyl Carbenes: Synthesis of Saturated Heterocycles and Fused N-Heterotricycles.
Lindsay, Vincent N. G.; Viart, Hélène M-F; Sarpong, Richmond; Journal of the American Chemical Society 137 (2015) 8368–8371; doi:10.1021/jacs.5b04295

data_4123877
_publ_section_title
;
 Stereodivergent Intramolecular C(sp(3))-H Functionalization of Azavinyl
 Carbenes: Synthesis of Saturated Heterocycles and Fused
 N-Heterotricycles.
;
_journal_issue                   26
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_journal_paper_doi               10.1021/jacs.5b04295
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_journal_year                    2015
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0251P)^2^+1.7954P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1231
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja5b04295_si_002.cif
_cod_data_source_block           sarpong91
_cod_depositor_comments
;Adding full bibliography for 4123875--4123877.cif.

The following automatic conversions were performed:

'_space_group.centring_type' value 'primitive' was replaced with the
value 'P' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_values.lst'.

Automatic conversion script
Id: cif_fix_values 5642 2017-10-24 12:04:52Z antanas 
;
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