Catalytic Enantioselective Desymmetrization of Norbornenoquinones via C(sp<sup>2</sup>)-H Alkylation.
Sarkar, Rahul; Mukherjee, Santanu; Organic letters 18 (2016) 6160–6163; doi:10.1021/acs.orglett.6b03168

data_1555952
_publ_section_title
;
 Catalytic Enantioselective Desymmetrization of Norbornenoquinones via
 C(sp<sup>2</sup>)-H Alkylation.
;
_journal_issue                   23
_journal_name_full               'Organic letters'
_journal_page_first              6160
_journal_page_last               6163
_journal_paper_doi               10.1021/acs.orglett.6b03168
_journal_volume                  18
_journal_year                    2016
_chemical_absolute_configuration syn
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  Olex2 1.2
  (compiled 2012.05.09 svn.r2324, GUI svn.r4230)
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_computing_cell_refinement       'Bruker SAINT'
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_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
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 Refined as an inversion twin.
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'w=1/[\s^2^(Fo^2^)+(0.0288P)^2^+2.5439P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_block           8
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_chemical_absolute_configuration' value 'Syn' was changed
to 'syn' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        3324.4(5)
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