Poly[[bis[μ~2~-<i>N</i>,<i>N</i>'-bis(2-pyridylmethyl)oxalamide-κ^4^<i>N</i>,<i>O</i>:<i>N</i>',<i>O</i>'][μ~2~-<i>N</i>,<i>N</i>'-bis(2-pyridylmethyl)oxalamide-κ^2^<i>N</i>:<i>N</i>']disilver(I)] bis(trifluoromethanesulfonate)]
Arman, Hadi D.; Miller, Tyler; Poplaukhin, Pavel; Tiekink, Edward R. T.; Acta Crystallographica Section E 66 (2010) m1167–m1168; doi:10.1107/S1600536810033611

data_2227916
_publ_section_title
;
 Poly[[bis[\m~2~-<i>N</i>,<i>N</i>'-bis(2-pyridylmethyl)oxalamide-\k^4^<i>N</i>,<i>O</i>:<i>N</i>',<i>O</i>'][\m~2~-<i>N</i>,<i>N</i>'-bis(2-pyridylmethyl)oxalamide-\k^2^<i>N</i>:<i>N</i>']disilver(I)]
 bis(trifluoromethanesulfonate)]
;
_journal_coeditor_code           PV2322
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1167
_journal_page_last               m1168
_journal_paper_doi               10.1107/S1600536810033611
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Ag (C14 H14 N4 O2)1.5] (C F3 S O3)'
_chemical_formula_moiety         'C21 H21 Ag N6 O3 +, C F3 O3 S -'
_chemical_formula_sum            'C22 H21 Ag F3 N6 O6 S'
_chemical_formula_weight         662.38
_chemical_name_systematic
;
Poly[[bis[\m~2~-<i>N</i>,<i>N</i>'-bis(2-pyridylmethyl)oxalamide-
\k^4^<i>N</i>,<i>O</i>:<i>N</i>',<i>O</i>'][\m~2~-<i>N</i>,<i>N</i>'-
bis(2-pyridylmethyl)oxalamide-\k^2^<i>N</i>:<i>N</i>']disilver(I)]
bis(trifluoromethanesulfonate)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.9770(10)
_cell_angle_beta                 105.948(2)
_cell_angle_gamma                107.017(3)
_cell_formula_units_Z            2
_cell_length_a                   8.7242(14)
_cell_length_b                   11.1762(17)
_cell_length_c                   14.210(2)
_cell_measurement_reflns_used    5470
_cell_measurement_temperature    98(2)
_cell_measurement_theta_max      40.5
_cell_measurement_theta_min      2.7
_cell_volume                     1247.9(3)
_computing_cell_refinement
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_data_collection
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_data_reduction
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_molecular_graphics
'ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      98(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku AFC12\K/SATURN724'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.029
_diffrn_reflns_av_sigmaI/netI    0.043
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            10177
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         2.0
_diffrn_standards_decay_%        '< 1'
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.966
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.868
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.763
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             666
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.67
_refine_diff_density_min         -1.05
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.05
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     352
_refine_ls_number_reflns         5688
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.05
_refine_ls_R_factor_all          0.036
_refine_ls_R_factor_gt           0.034
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0295P)^2^+1.3977P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.077
_refine_ls_wR_factor_ref         0.079
_reflns_number_gt                5438
_reflns_number_total             5688
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            pv2322.cif
_cod_data_source_block           I
_cod_original_formula_sum        'C22 H21 Ag F3 N6 O6 S '
_cod_database_code               2227916
_cod_database_fobs_code          2227916