Polyoxometalate-based room-temperature phosphorescent materials induced by anion-π interactions.
Wu, Xiao-Yuan; Zhang, Hai-Long; Wang, Sa-Sa; Wu, Weiming; Lin, Lang; Jiang, Xiao-Yu; Lu, Can-Zhong; Dalton transactions (Cambridge, England : 2003) 49 (2020) 3408–3412; doi:10.1039/d0dt00159g

data_7703582
_publ_section_title
;
 Polyoxometalate-based room-temperature phosphorescent materials induced
 by anion-\p interactions.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3408
_journal_page_last               3412
_journal_paper_doi               10.1039/d0dt00159g
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C67 H101 Gd N10 O62 Si W12'
_chemical_formula_sum            'C67 H101 Gd N10 O62 Si W12'
_chemical_formula_weight         4430.11
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_space_group_name_Hall           '-P 1'
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_audit_update_record
;
2020-01-08 deposited with the CCDC.	2020-02-20 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
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_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, Atlas'
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_exptl_absorpt_correction_T_min  0.27761
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.46e (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            pale-yellow
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_refine_ls_R_factor_gt           0.0308
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0237P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0641
_refine_ls_wR_factor_ref         0.0684
_reflns_Friedel_coverage         0.000
_reflns_number_gt                22728
_reflns_number_total             26483
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt00159g2.cif
_cod_data_source_block           Gd
_cod_depositor_comments
'Adding full bibliography for 7703577--7703585.cif.'
_cod_original_cell_volume        5110.2(2)
_cod_database_code               7703582
_shelx_shelxl_version_number     2018/1
_shelx_estimated_absorpt_t_min   0.210
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_shelx_res_checksum              23666