Synthesis and reactivity of boryloxorhodium complexes. Relevance to intermolecular transmetalation from boron to rhodium in Rh-catalyzed reactions.
Nishihara, Yasushi; Nishide, Yasuhiro; Osakada, Kohtaro; Dalton transactions (Cambridge, England : 2003) 50 (2021) 3610–3615; doi:10.1039/d1dt00440a

data_7706636
_publ_section_title
;
 Synthesis and reactivity of boryloxorhodium complexes. Relevance to
 intermolecular transmetalation from boron to rhodium in Rh-catalyzed
 reactions.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3610
_journal_page_last               3615
_journal_paper_doi               10.1039/d1dt00440a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C28 H48 B2 O6 Rh2'
_chemical_formula_sum            'C28 H48 B2 O6 Rh2'
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_space_group_name_Hall           '-C 2yc'
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_audit_update_record
;
2020-05-05 deposited with the CCDC.	2021-02-17 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
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_cell_measurement_theta_max      10.55
_cell_measurement_theta_min      9.46
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_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control (Rigaku, 1998)'
_computing_data_reduction        'MSC/AFC Diffractometer Control'
_computing_molecular_graphics    'CrystalStructure 4.2.5'
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_diffrn_reflns_theta_min         2.523
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;
\y scans (North,Phillips & Matthews, 1968)
;
_exptl_crystal_colour            'pale yellow'
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_refine_ls_shift/su_max          0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0010Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0939
_reflns_number_gt                2314
_reflns_number_total             2676
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            d1dt00440a2.cif
_cod_data_source_block           nsd047
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'psi scan' was
changed to 'psi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7706636--7706638.cif.
;
_cod_original_cell_volume        3033.6(12)
_cod_database_code               7706636