Regioselective electrophilic borylation of haloarenes.
Del Grosso, Alessandro; Ayuso Carrillo, Josue; Ingleson, Michael J.; Chemical communications (Cambridge, England) 51 (2015) 2878–; doi:10.1039/c4cc10153g

data_7116288
_publ_section_title
;
 Regioselective electrophilic borylation of haloarenes.
;
_journal_issue                   14
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              2878
_journal_paper_doi               10.1039/c4cc10153g
_journal_volume                  51
_journal_year                    2015
_chemical_formula_moiety         'C5 H3 B Cl4 N, Al Cl4'
_chemical_formula_sum            'C5 H3 Al B Cl8 N'
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 ?
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_symmetry_space_group_name_Hall  '-P 2yn'
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2014-12-10 deposited with the CCDC.
2015-01-02 downloaded from the CCDC.
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
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_computing_publication_material
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
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SHELXL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
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SHELXS, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
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  1 omega  -30.00    6.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
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  2 omega  -50.00   52.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
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  3 omega  -19.00   24.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
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  4 omega    0.00   53.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       18.6526   57.0000 -150.0000 53
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_diffrn_source                   'SuperNova (Mo) X-ray Source'
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            colourless
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'w=1/[\s^2^(Fo^2^)+(0.0399P)^2^+0.6699P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7116287--7116290.cif.'
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_cod_database_code               7116288
_chemical_oxdiff_formula         C5H3Al1B1Cl8N1
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_olex2_refinement_description
;
1. Others
 Fixed Uiso: H2(0.032) H4(0.031) H3(0.032)
 Fixed X: H2(0.8143) H4(0.498) H3(0.5342)
 Fixed Y: H2(0.0522) H4(0.2821) H3(0.1394)
 Fixed Z: H2(0.3349) H4(0.3965) H3(0.3124)
;
_olex2_date_sample_data_collection 1387270310.0
_olex2_submission_special_instructions 'No special instructions were received'
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