Evidence for Direct Transmetalation of Au<sup>III</sup>-F with Boronic Acids.
Kumar, Roopender; Linden, Anthony; Nevado, Cristina; Journal of the American Chemical Society 138 (2016) 13790–13793; doi:10.1021/jacs.6b07763

data_4130884
_publ_section_title
;
 Evidence for Direct Transmetalation of Au<sup>III</sup>-F with Boronic
 Acids.
;
_journal_issue                   42
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13790
_journal_page_last               13793
_journal_paper_doi               10.1021/jacs.6b07763
_journal_volume                  138
_journal_year                    2016
_chemical_formula_moiety         'C20 H12 Au Br F7 N'
_chemical_formula_sum            'C20 H12 Au Br F7 N'
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_cell_measurement_temperature    160(2)
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'DENZO-SMN and SCALEPACK (Otwinowski & Minor, 1997)'
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'Nonius KappaCCD area-detector diffractometer'
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_diffrn_reflns_theta_max         30.063
_diffrn_reflns_theta_min         2.359
_diffrn_standards_decay_%        0
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_exptl_crystal_size_min          0.28
_refine_diff_density_max         1.817
_refine_diff_density_min         -1.967
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014 (Sheldrick 2015)'
_refine_ls_goodness_of_fit_ref   1.068
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_refine_ls_number_reflns         5820
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0456P)^2^+3.9518P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                5454
_reflns_number_total             5820
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           NV1315
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_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              67882
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