The Stannylphosphide Anion Reagent Sodium Bis(triphenylstannyl) Phosphide: Synthesis, Structural Characterization, and Reactions with Indium, Tin, and Gold Electrophiles.
Cummins, Christopher C.; Huang, Chao; Miller, Tabitha J.; Reintinger, Markus W.; Stauber, Julia M.; Tannou, Isabelle; Tofan, Daniel; Toubaei, Abouzar; Velian, Alexandra; Wu, Gang; Inorganic chemistry 53 (2014) 3678–; doi:10.1021/ic403178j

data_4338023
_publ_section_title
;
 The Stannylphosphide Anion Reagent Sodium Bis(triphenylstannyl)
 Phosphide: Synthesis, Structural Characterization, and Reactions with
 Indium, Tin, and Gold Electrophiles.
;
_journal_issue                   7
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3678
_journal_paper_doi               10.1021/ic403178j
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C54 H45 Au P2 Sn2'
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_chemical_name_systematic
;
 ?
;
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_symmetry_space_group_name_Hall  '-P 1'
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_cell_angle_gamma                104.3400(10)
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_cell_length_b                   20.2016(6)
_cell_length_c                   24.7100(8)
_cell_measurement_temperature    100(2)
_cell_volume                     9152.1(5)
_computing_structure_refinement  'SHELXL-2012 (Sheldrick, 2012)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.980
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_av_unetI/netI     0.0995
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_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -24
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_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       30
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_diffrn_reflns_point_group_measured_fraction_full 0.982
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_exptl_absorpt_coefficient_mu    4.387
_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_F_000             4624
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_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
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_exptl_transmission_factor_min   0.6249
_refine_diff_density_max         3.260
_refine_diff_density_min         -2.621
_refine_diff_density_rms         0.177
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_R_factor_gt           0.0448
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0358P)^2^]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1027
_refine_ls_wR_factor_ref         0.1106
_reflns_Friedel_coverage         0.000
_reflns_number_gt                25347
_reflns_number_total             36663
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ic403178j_si_002.cif
_cod_data_source_block           early_a
_cod_depositor_comments
'Adding full bibliography for 4338021--4338024.cif.'
_cod_database_code               4338023
_shelx_estimated_absorpt_t_min   0.407
_shelx_estimated_absorpt_t_max   0.668
_shelxl_version_number           2012-9
_shelx_res_checksum              79352
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