The first example of a silver‒manganese‒rhenium cluster complex: heptacarbonyl-1κ^3^<i>C</i>,2κ^4^<i>C</i>-μ-dicyclohexylphosphido-1:2κ^2^<i>P</i>-bis(triphenylphosphine)-1κ<i>P</i>,3κ<i>P</i>-<i>triangulo</i>-manganeserheniumsilver with disordered solvent
Flörke, Ulrich; Petters, Dina; Acta Crystallographica Section C 57 (2001) 1044–1045; doi:10.1107/S0108270101009696

data_2012225
_publ_section_title
;The first example of a silver--manganese--rhenium cluster complex:
 heptacarbonyl-1\k^3^<i>C</i>,2\k^4^<i>C</i>-\m-dicyclohexylphosphido-1:2\k^2^<i>P</i>-bis(triphenylphosphine)-1\k<i>P</i>,3\k<i>P</i>-<i>triangulo</i>-manganeserheniumsilver
 with disordered solvent
;
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1044
_journal_page_last               1045
_journal_paper_doi               10.1107/S0108270101009696
_journal_volume                  57
_journal_year                    2001
_chemical_formula_iupac          '[ReMnAg(C12 H22 P)(C18 H15 P)2 (CO)7 ]'
_chemical_formula_moiety         'C55 H52 Ag Mn O7 P3 Re'
_chemical_formula_sum            'C55 H52 Ag Mn O7 P3 Re'
_chemical_formula_weight         1266.89
_chemical_name_systematic
;
 (\m-dicyclohexylphosphine)-heptacarbonyl-eq-triphenylphosphine-
 triphenylphosphine-silver-manganese-rhenium
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.700(10)
_cell_angle_beta                 98.760(10)
_cell_angle_gamma                113.200(10)
_cell_formula_units_Z            2
_cell_length_a                   11.5830(10)
_cell_length_b                   12.842(2)
_cell_length_c                   20.728(3)
_cell_measurement_reflns_used    31
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      17.505
_cell_measurement_theta_min      7.401
_cell_volume                     2747.4(7)
_computing_cell_refinement       'XSCANS (Bruker, 1996)'
_computing_data_collection       'XSCANS (Bruker, 1996)'
_computing_data_reduction        'SHELXTL (Bruker, 1998)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    SHELXTL
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full .995
_diffrn_measured_fraction_theta_max .995
_diffrn_measurement_device       'Bruker P4'
_diffrn_measurement_method       omega
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .0219
_diffrn_reflns_av_sigmaI/netI    .0597
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -1
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            14452
_diffrn_reflns_theta_full        27.51
_diffrn_reflns_theta_max         27.51
_diffrn_reflns_theta_min         2.00
_diffrn_standards_decay_%        <1
_diffrn_standards_interval_count 397
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.912
_exptl_absorpt_correction_T_max  .844
_exptl_absorpt_correction_T_min  .508
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North et al., 1968)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.531
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1260
_exptl_crystal_size_max          .42
_exptl_crystal_size_mid          .22
_exptl_crystal_size_min          .08
_refine_diff_density_max         .740
_refine_diff_density_min         -.924
_refine_ls_extinction_coef       .00034(7)
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   .893
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     614
_refine_ls_number_reflns         12576
_refine_ls_number_restraints     949
_refine_ls_restrained_S_all      .866
_refine_ls_R_factor_all          .0671
_refine_ls_R_factor_gt           .0383
_refine_ls_shift/su_max          .001
_refine_ls_shift/su_mean         .000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0436P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         .0866
_reflns_number_gt                8862
_reflns_number_total             12576
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            sk1486.cif
_cod_data_source_block           I
_cod_original_cell_volume        2747.4(6)
_cod_database_code               2012225