Phosphorous(v) Lewis acids: water/base tolerant P<sub>3</sub>-trimethylated trications.
Bayne, J. M.; Fasano, V.; Szkop, K. M.; Ingleson, M. J.; Stephan, D. W.; Chemical communications (Cambridge, England) 54 (2018) 12467–12470; doi:10.1039/c8cc06564k

data_7122448
_publ_section_title
;
 Phosphorous(v) Lewis acids: water/base tolerant
 P<sub>3</sub>-trimethylated trications.
;
_journal_issue                   88
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              12467
_journal_page_last               12470
_journal_paper_doi               10.1039/c8cc06564k
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C40 H43 F9 O10 P3 S3'
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-08-11 deposited with the CCDC.
2018-10-12 downloaded from the CCDC.
;
_cell_angle_alpha                87.306(6)
_cell_angle_beta                 60.676(6)
_cell_angle_gamma                88.417(6)
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_cell_measurement_temperature    150(2)
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_computing_cell_refinement       'Bruker SAINT'
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_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0499
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_diffrn_reflns_limit_h_min       -17
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_diffrn_reflns_point_group_measured_fraction_full 0.996
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_exptl_absorpt_coefficient_mu    0.352
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
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_exptl_crystal_description       shard
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_refine_ls_R_factor_all          0.0889
_refine_ls_R_factor_gt           0.0543
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0738P)^2^+1.9962P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1368
_refine_ls_wR_factor_ref         0.1534
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6645
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8cc06564k2.cif
_cod_data_source_block           jb013_0m
_cod_depositor_comments
'Adding full bibliography for 7122448--7122449.cif.'
_cod_original_cell_volume        2330.2(5)
_cod_database_code               7122448
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_shelx_res_checksum              72464