Deprotonation Attempts on Imidazolium Salt Tethered by Substituted Phenol and Construction of Its Magnesium Complex by Transmetalation
Zhang, Dao; Kawaguchi, Hiroyuki; Organometallics 25 (2006) 5506–5509; doi:10.1021/om060691t

data_4074484
_publ_section_title
;
 Deprotonation Attempts on Imidazolium Salt Tethered by Substituted Phenol
 and Construction of Its Magnesium Complex by Transmetalation
;
_journal_coden_ASTM              ORGND7
_journal_issue                   22
_journal_name_full               Organometallics
_journal_page_first              5506
_journal_page_last               5509
_journal_paper_doi               10.1021/om060691t
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C46 H70 N4 Na2 O4 '
_chemical_formula_sum            'C23 H35 N2 Na O2'
_chemical_formula_weight         394.53
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                80.204(13)
_cell_angle_beta                 65.035(9)
_cell_angle_gamma                64.229(11)
_cell_formula_units_Z            4
_cell_length_a                   12.712(2)
_cell_length_b                   14.622(3)
_cell_length_c                   15.029(4)
_cell_measurement_reflns_used    5605
_cell_measurement_temperature    123.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     2280.3(9)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 3.5.1'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.9165
_diffrn_measured_fraction_theta_max 0.9182
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.032
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            34794
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.089
_exptl_absorpt_correction_T_max  0.987
_exptl_absorpt_correction_T_min  0.879
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.149
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             856.00
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.51
_refine_diff_density_min         -0.44
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     575
_refine_ls_number_reflns         9620
_refine_ls_R_factor_gt           0.0550
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0015Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1640
_reflns_number_gt                5293
_reflns_number_total             9621
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om060691tsi20060731_100417.cif
_cod_data_source_block           '_Na2[CO]2(THF)2'
_cod_original_sg_symbol_H-M      'P -1       '
_cod_original_formula_sum        'C46 H70 N4 Na2 O4 '
_cod_database_code               4074484