Selective Conversion of Carbon Dioxide to Formaldehyde via a Bis(silyl)acetal: Incorporation of Isotopically Labeled C<sub>1</sub> Moieties Derived from Carbon Dioxide into Organic Molecules.
Rauch, Michael; Strater, Zack; Parkin, Gerard; Journal of the American Chemical Society  (2019) –; doi:10.1021/jacs.9b08342

data_4127297
_publ_section_title
;
 Selective Conversion of Carbon Dioxide to Formaldehyde via a
 Bis(silyl)acetal: Incorporation of Isotopically Labeled C<sub>1</sub>
 Moieties Derived from Carbon Dioxide into Organic Molecules.
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_paper_doi               10.1021/jacs.9b08342
_journal_year                    2019
_chemical_formula_sum            'C37 H32 O2 Si2'
_chemical_formula_weight         564.80
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_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
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_diffrn_ambient_temperature      190(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6231
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_exptl_absorpt_process_details   sadabs
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_refine_ls_R_factor_all          0.0890
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0601P)^2^+1.2784P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.941
_shelx_estimated_absorpt_t_max   0.996
_shelx_res_checksum              40850
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