A dicopper(i)-dimesoionic carbene complex as a click catalyst: mechanistic implications.
Beerhues, Julia; Fauché, Kevin; Cisnetti, Federico; Sarkar, Biprajit; Gautier, Arnaud; Dalton transactions (Cambridge, England : 2003) 48 (2019) 8931–8936; doi:10.1039/c9dt01882d

data_7700082
_publ_section_title
;
 A dicopper(i)-dimesoionic carbene complex as a click catalyst:
 mechanistic implications.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8931
_journal_page_last               8936
_journal_paper_doi               10.1039/c9dt01882d
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C32.5 H26 Cl Cu2 F3 N6 O5 S'
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_space_group_name_Hall           'P 2c -2ac'
_space_group_name_H-M_alt        'P c a 21'
_symmetry_space_group_name_Hall  'P 2c -2ac'
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_audit_update_record
;
2018-11-20 deposited with the CCDC.    2019-05-24 downloaded from the CCDC.
;
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_cell_volume                     7321.3(9)
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_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'omega + phi scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_l_min       -24
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.172(13)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0601P)^2^+6.3075P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0951
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_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     0.996
_reflns_number_gt                11969
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt01882d2.cif
_cod_data_source_block           bip398_OP_a
_cod_depositor_comments          'Adding full bibliography for 7700082.cif.'
_cod_original_formula_sum        'C32.50 H26 Cl Cu2 F3 N6 O5 S'
_cod_database_code               7700082
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_shelx_res_checksum              13833
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