Reactions of Ruthenium Complexes Having Pyridyl-Containing Ligands, 2-Pyridinecarboxylato and 2,2'-Bipyridine, with an Azide Ion: Formation of Nitrido-Bridged Diruthenium Complexes
Sayuri Matsumura; Kazunori Shikano; Takao Oi; Noriyuki Suzuki; Hirotaka Nagao; Inorganic Chemistry 47 (2008) 9125–9127; doi:10.1021/ic801070a

data_4306158
_publ_contact_author_email       h-nagao@sophia.ac.jp
_publ_contact_author_name        'HIROTAKA NAGAO'
_publ_section_title
;
Reactions of Ruthenium Complexes Having Pyridyl-Containing Ligands,
2-Pyridinecarboxylato and 2,2'-Bipyridine, with an Azide Ion: Formation
of Nitrido-Bridged Diruthenium Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9125
_journal_page_last               9127
_journal_paper_doi               10.1021/ic801070a
_journal_volume                  47
_journal_year                    2008
_chemical_formula_moiety         'C34 H30 N7 O6 Ru2, F6 P 2(H2 O) '
_chemical_formula_sum            'C34 H34 F6 N7 O8 P Ru2'
_chemical_formula_weight         1015.79
_chemical_name_systematic
;
bis(2,2'-bipyridinemethoxo(2-pyridinecarboxylato)ruthenium(IV))
(mu-nitrido) hexafurorophosphate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 92.3280(11)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   14.743(4)
_cell_length_b                   12.996(4)
_cell_length_c                   19.824(6)
_cell_measurement_reflns_used    7531
_cell_measurement_temperature    93.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     3795.1(19)
_diffrn_ambient_temperature      93.1
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.048
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            29195
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.929
_exptl_absorpt_correction_T_max  0.946
_exptl_absorpt_correction_T_min  0.663
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.778
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       chip
_exptl_crystal_F_000             2032.00
_exptl_crystal_preparation       water-acetonitrile-ether
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.83
_refine_diff_density_min         -1.50
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.173
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     524
_refine_ls_number_reflns         8683
_refine_ls_R_factor_gt           0.0648
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0195P)^2^+29.4352P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1371
_reflns_number_gt                7702
_reflns_number_total             8683
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic801070a_si_002.cif
_cod_data_source_block
;
;
_cod_original_cell_volume        3795.1(20)
_cod_original_formula_sum        'C34 H34 F6 N7 O8 P Ru2 '
_cod_database_code               4306158