Step-by-Step Introduction of Silazane Moieties at Ruthenium: Different Extents of Ru-H-Si Bond Activation
Katharine A. Smart; Mary Grellier; Laure Vendier; Sax A. Mason; Silvia C. Capelli; Alberto Albinati; Sylviane Sabo-Etienne; Inorganic Chemistry 52 (2013) 2654–2661; doi:10.1021/ic302682f

data_4334041
_publ_contact_author
;
Sylviane Sabo-Etienne
;
_publ_contact_author_address
;
Laboratoire de Chimie de Coordination
205 Route de Narbonne
31077 Toulouse Cedex 04
;
_publ_contact_author_email       Sylviane.Sabo@lcc-toulouse.fr
_publ_section_title
;
 Step-by-Step Introduction of Silazane Moieties at Ruthenium: Different
 Extents of Ru-H-Si Bond Activation
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2654
_journal_page_last               2661
_journal_paper_doi               10.1021/ic302682f
_journal_volume                  52
_journal_year                    2013
_chemical_absolute_configuration unk
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C32 H56 N8 Ru2 Si4 '
_chemical_formula_sum            'C32 H56 N8 Ru2 Si4'
_chemical_formula_weight         867.35
_chemical_name_systematic
;
 ?
;
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_symmetry_Int_Tables_number      94
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_cell_measurement_theta_min      3.5494
_cell_measurement_wavelength     0.71073
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        CrysAlisPro, Oxford Diffraction Ltd.,
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        (compiled Apr 28 2010,14:27:37)
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        CrysAlisPro, Oxford Diffraction Ltd.,
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        (compiled Apr 28 2010,14:27:37)
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        CrysAlisPro, Oxford Diffraction Ltd.,
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        (compiled Apr 28 2010,14:27:37)
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_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
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_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 16.1978
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini ultra'
_diffrn_measurement_method       '\w scans'
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_diffrn_orient_matrix_UB_21      0.0142121
_diffrn_orient_matrix_UB_22      -0.0498675
_diffrn_orient_matrix_UB_23      0.0220649
_diffrn_orient_matrix_UB_31      -0.0250137
_diffrn_orient_matrix_UB_32      -0.0267583
_diffrn_orient_matrix_UB_33      -0.0419314
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0244
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_exptl_absorpt_coefficient_mu    0.897
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;
        CrysAlisPro, Oxford Diffraction Ltd.,
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        empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'red orange'
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_exptl_crystal_description       plate
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_refine_diff_density_max         0.329
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         2076
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0224P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0352
_refine_ls_wR_factor_ref         0.0356
_reflns_number_gt                1895
_reflns_number_total             2076
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            ic302682f_si_002_2.cif
_cod_data_source_block           KSO231110
_cod_original_formula_sum        'C32 H56 N8 Ru2 Si4 '
_cod_database_code               4334041