Copper-catalyzed regio and diastereoselective three component C–N, C–C and C–O bond forming reaction: oxidative sp3C–H functionalization
Gupta, Kankatala S. V.; Ramana, Daggupati V.; Vinayak, Botla; Sridhar, Balasubramanian; Chandrasekharam, Malapaka; New J. Chem. 40 (2016) 6389–; doi:10.1039/C5NJ03707G

data_7055558
_publ_section_title
;
 Copper-catalyzed regio and diastereoselective three component C--N, C--C
 and C--O bond forming reaction: oxidative sp3C--H functionalization
;
_journal_issue                   7
_journal_name_full               'New J. Chem.'
_journal_page_first              6389
_journal_paper_doi               10.1039/C5NJ03707G
_journal_volume                  40
_journal_year                    2016
_chemical_formula_moiety         'C27 H23 N O'
_chemical_formula_sum            'C27 H23 N O'
_chemical_formula_weight         377.46
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-11-02 deposited with the CCDC.
2016-05-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_volume                     2019.0(2)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
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_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'Bruker SMART APEX CCD area-detector'
_diffrn_measurement_method       \w
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0688P)^2^+0.3748P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1306
_refine_ls_wR_factor_ref         0.1405
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_reflns_number_gt                3834
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5nj03707g2.cif
_cod_data_source_block           BB34m
_cod_depositor_comments          'Adding full bibliography for 7055558.cif.'
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