Aerobic addition of secondary phosphine oxides to vinyl sulfides: a shortcut to 1-hydroxy-2-(organosulfanyl)ethyl(diorganyl)phosphine oxides.
Malysheva, Svetlana F.; Artem'ev, Alexander V.; Gusarova, Nina K.; Belogorlova, Nataliya A.; Albanov, Alexander I.; Liu, C. W.; Trofimov, Boris A.; Beilstein journal of organic chemistry 11 (2015) 1985–1990; doi:10.3762/bjoc.11.214

data_4031721
_publ_section_title
;
 Aerobic addition of secondary phosphine oxides to vinyl sulfides: a
 shortcut to 1-hydroxy-2-(organosulfanyl)ethyl(diorganyl)phosphine oxides.
;
_journal_name_full               'Beilstein journal of organic chemistry'
_journal_page_first              1985
_journal_page_last               1990
_journal_paper_doi               10.3762/bjoc.11.214
_journal_volume                  11
_journal_year                    2015
_chemical_formula_sum            'C24 H27 O2 P S'
_chemical_formula_weight         410.48
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
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_cell_angle_gamma                90
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_cell_length_c                   14.5754(6)
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_cell_measurement_theta_min      2.38
_cell_volume                     2187.94(16)
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_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0546
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_exptl_absorpt_coefficient_mu    0.238
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_refine_ls_R_factor_all          0.0901
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0326P)^2^+0.6493P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           1
_cod_depositor_comments          'Adding full bibliography for 4031721.cif.'
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