Rhodium-complex-catalyzed addition reactions of chloroacetyl chlorides to alkynes.
Kashiwabara, Taigo; Fuse, Kouichiro; Hua, Ruimao; Tanaka, Masato; Organic letters 10 (2008) 5469–5472; doi:10.1021/ol802260w

data_1504969
_publ_section_title
;
 Rhodium-complex-catalyzed addition reactions of chloroacetyl chlorides to
 alkynes.
;
_journal_issue                   23
_journal_name_full               'Organic letters'
_journal_page_first              5469
_journal_page_last               5472
_journal_paper_doi               10.1021/ol802260w
_journal_volume                  10
_journal_year                    2008
_chemical_formula_moiety         'C29 H28 Cl3 O2 P2 Rh '
_chemical_formula_sum            'C29 H28 Cl3 O2 P2 Rh'
_chemical_formula_weight         679.75
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_formula_units_Z            8
_cell_length_a                   16.4539(15)
_cell_length_b                   13.1086(15)
_cell_length_c                   26.120(2)
_cell_measurement_reflns_used    8665
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     5633.8(9)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.965
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.043
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            39704
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    1.029
_exptl_absorpt_correction_T_max  0.814
_exptl_absorpt_correction_T_min  0.626
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.603
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2752.00
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.25
_refine_diff_density_max         2.42
_refine_diff_density_min         -3.01
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.290
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     335
_refine_ls_number_reflns         6231
_refine_ls_R_factor_gt           0.0682
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1878
_reflns_number_gt                5197
_reflns_number_total             6231
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ol802260w_si_002.cif
_cod_data_source_block           '__8-PMePh2'
_cod_original_formula_sum        'C29 H28 Cl3 O2 P2 Rh '
_cod_database_code               1504969