Frustrated N-heterocyclic carbene-silylium ion Lewis pairs.
Silva Valverde, Miguel F.; Theuergarten, Eileen; Bannenberg, Thomas; Freytag, Matthias; Jones, Peter G.; Tamm, Matthias; Dalton transactions (Cambridge, England : 2003) 44 (2015) 9400–9408; doi:10.1039/c5dt01362c

data_7034865
_publ_section_title
;
 Frustrated N-heterocyclic carbene-silylium ion Lewis pairs.
;
_journal_issue                   20
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9400
_journal_page_last               9408
_journal_paper_doi               10.1039/c5dt01362c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C22 H42 F3 N3 O4 S Si'
_chemical_formula_weight         529.74
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-03-05 deposited with the CCDC.
2015-04-20 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 110.952(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   18.8522(4)
_cell_length_b                   20.4483(3)
_cell_length_c                   15.2041(3)
_cell_measurement_reflns_used    44360
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      76.8780
_cell_measurement_theta_min      3.7560
_cell_volume                     5473.58(19)
_computing_cell_refinement
; 
CrysAlisPro, Agilent Technologies, 
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET) 
(compiled Feb  1 2013,16:14:44) 
;
_computing_data_collection
; 
CrysAlisPro, Agilent Technologies, 
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET) 
(compiled Feb  1 2013,16:14:44) 
;
_computing_data_reduction
; 
CrysAlisPro, Agilent Technologies, 
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET) 
(compiled Feb  1 2013,16:14:44) 
;
_computing_molecular_graphics    'Bruker XP'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.3543
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Oxford Difraction Xcalibur, Atlas, Nova'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'Nova (Cu) X-ray Source'
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0549
_diffrn_reflns_av_sigmaI/netI    0.0237
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            103018
_diffrn_reflns_theta_full        75.00
_diffrn_reflns_theta_max         77.07
_diffrn_reflns_theta_min         3.31
_exptl_absorpt_coefficient_mu    1.926
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.29625
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
CrysAlisPro, Agilent Technologies, 
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET) 
(compiled Feb  1 2013,16:14:44) 
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.286
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2272
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.523
_refine_diff_density_min         -0.454
_refine_diff_density_rms         0.049
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     674
_refine_ls_number_reflns         11498
_refine_ls_number_restraints     85
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0428
_refine_ls_R_factor_gt           0.0382
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0487P)^2^+3.0850P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0970
_refine_ls_wR_factor_ref         0.1003
_reflns_number_gt                10409
_reflns_number_total             11498
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5dt01362c3.cif
_cod_data_source_block           eileen63
_cod_depositor_comments
'Adding full bibliography for 7034861--7034869.cif.'
_cod_original_cell_volume        5473.57(18)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7034865
_refine_instructions_details
;
TITL eileen63 in P2(1)/c
CELL 1.54184  18.852181  20.448292  15.204133  90.0000 110.9523  90.0000
ZERR    8.00   0.000400   0.000300   0.000300   0.0000   0.0020   0.0000
LATT   1
SYMM  - X, 1/2 + Y, 1/2 - Z
SFAC  C    H    N    O    F    SI   S
UNIT  176  336  24  32  24  8  8
MERG   2
FMAP   2
 
ACTA 150
CONF
 
TEMP -173
 
PLAN   10
L.S.   30
WGHT    0.048700    3.085000
FVAR       1.84370   0.87148
SI    6    0.225477    0.378697    0.391602    11.00000    0.01998    0.01541 =
         0.01772    0.00045    0.00758    0.00299
O1    4    0.280018    0.309754    0.424042    11.00000    0.01612    0.01511 =
         0.01491   -0.00031    0.00669    0.00145
N1    3    0.427325    0.215208    0.455236    11.00000    0.01151    0.01622 =
         0.01515   -0.00019    0.00398    0.00041
N2    3    0.322113    0.156751    0.401943    11.00000    0.01383    0.01364 =
         0.01524   -0.00010    0.00444    0.00045
N3    3    0.296309    0.300712    0.283796    11.00000    0.01621    0.01663 =
         0.01562    0.00023    0.00752    0.00150
C1    1    0.350995    0.217946    0.409812    11.00000    0.01234    0.01612 =
         0.01259   -0.00027    0.00465    0.00065
C2    1    0.447399    0.149494    0.473371    11.00000    0.01676    0.01833 =
         0.01698    0.00045    0.00504    0.00456
C3    1    0.382550    0.113538    0.440537    11.00000    0.01993    0.01470 =
         0.01799    0.00080    0.00539    0.00400
C4    1    0.484533    0.270990    0.487908    11.00000    0.01252    0.02087 =
         0.02019   -0.00199    0.00410   -0.00388
C5    1    0.539672    0.266339    0.434596    11.00000    0.01912    0.03990 =
         0.02874   -0.00277    0.01154   -0.00677
AFIX 137
H5A   2    0.559850    0.221764    0.439698    11.00000   -1.50000
H5B   2    0.581616    0.297176    0.461884    11.00000   -1.50000
H5C   2    0.512804    0.277101    0.368120    11.00000   -1.50000
AFIX   0
C6    1    0.524102    0.264798    0.595141    11.00000    0.01930    0.03006 =
         0.02057   -0.00470    0.00266   -0.00328
AFIX 137
H6A   2    0.485993    0.266292    0.625183    11.00000   -1.50000
H6B   2    0.560001    0.300999    0.618552    11.00000   -1.50000
H6C   2    0.551549    0.223155    0.610084    11.00000   -1.50000
AFIX   0
C7    1    0.447883    0.338577    0.470192    11.00000    0.01945    0.01897 =
         0.03636   -0.00096    0.00178   -0.00454
AFIX 137
H7A   2    0.422064    0.345155    0.402331    11.00000   -1.50000
H7B   2    0.487148    0.372084    0.495122    11.00000   -1.50000
H7C   2    0.410890    0.341914    0.501744    11.00000   -1.50000
AFIX   0
C8    1    0.524810    0.119931    0.519046    11.00000    0.01831    0.02518 =
         0.02618    0.00047    0.00250    0.00808
AFIX 137
H8A   2    0.528736    0.100339    0.579435    11.00000   -1.50000
H8B   2    0.563520    0.154031    0.529727    11.00000   -1.50000
H8C   2    0.532719    0.086119    0.477799    11.00000   -1.50000
AFIX   0
C9    1    0.380829    0.040472    0.447478    11.00000    0.02832    0.01581 =
         0.03226    0.00263    0.00791    0.00410
AFIX 137
H9A   2    0.420756    0.021588    0.428140    11.00000   -1.50000
H9B   2    0.331206    0.024185    0.406161    11.00000   -1.50000
H9C   2    0.389399    0.027873    0.512670    11.00000   -1.50000
AFIX   0
C10   1    0.239303    0.134200    0.361530    11.00000    0.01377    0.01798 =
         0.01764   -0.00230    0.00531   -0.00383
C11   1    0.222632    0.096282    0.439078    11.00000    0.02506    0.02723 =
         0.02578    0.00322    0.00920   -0.00783
AFIX 137
H11A  2    0.235237    0.123602    0.495575    11.00000   -1.50000
H11B  2    0.253367    0.056338    0.454072    11.00000   -1.50000
H11C  2    0.168647    0.084695    0.417109    11.00000   -1.50000
AFIX   0
C12   1    0.228071    0.092223    0.274219    11.00000    0.02051    0.02910 =
         0.02556   -0.01138    0.00698   -0.00407
AFIX 137
H12A  2    0.181320    0.066586    0.259414    11.00000   -1.50000
H12B  2    0.271425    0.062602    0.286557    11.00000   -1.50000
H12C  2    0.224277    0.120604    0.220785    11.00000   -1.50000
AFIX   0
C13   1    0.183288    0.190683    0.333405    11.00000    0.01244    0.02153 =
         0.02747   -0.00028    0.00691   -0.00117
AFIX 137
H13A  2    0.189984    0.218300    0.388479    11.00000   -1.50000
H13B  2    0.131344    0.173478    0.309239    11.00000   -1.50000
H13C  2    0.192412    0.216699    0.284358    11.00000   -1.50000
AFIX   0
C14   1    0.307660    0.278292    0.364575    11.00000    0.01100    0.01493 =
         0.01678   -0.00109    0.00494    0.00009
C15   1    0.318426    0.276126    0.204995    11.00000    0.01618    0.01816 =
         0.00939   -0.00033    0.00567    0.00320
C16   1    0.363108    0.211614    0.220214    11.00000    0.02682    0.02571 =
         0.01988   -0.00058    0.01203    0.00433
AFIX 137
H16A  2    0.411908    0.216861    0.272046    11.00000   -1.50000
H16B  2    0.372085    0.200030    0.162519    11.00000   -1.50000
H16C  2    0.333813    0.176830    0.235779    11.00000   -1.50000
AFIX   0
C17   1    0.362894    0.331134    0.181486    11.00000    0.02769    0.03012 =
         0.02250    0.00244    0.01259    0.00034
AFIX 137
H17A  2    0.334185    0.372034    0.173615    11.00000   -1.50000
H17B  2    0.371106    0.320773    0.122918    11.00000   -1.50000
H17C  2    0.412063    0.336062    0.232766    11.00000   -1.50000
AFIX   0
C18   1    0.241584    0.267009    0.123101    11.00000    0.02400    0.03182 =
         0.01608   -0.00215    0.00691    0.00098
AFIX 137
H18A  2    0.212577    0.232156    0.139035    11.00000   -1.50000
H18B  2    0.250821    0.255171    0.065661    11.00000   -1.50000
H18C  2    0.212679    0.307927    0.112733    11.00000   -1.50000
AFIX   0
C19   1    0.277060    0.445662    0.359365    11.00000    0.04079    0.01869 =
         0.03565   -0.00044    0.02174    0.00006
AFIX 137
H19A  2    0.325974    0.452589    0.410374    11.00000   -1.50000
H19B  2    0.246861    0.485854    0.349119    11.00000   -1.50000
H19C  2    0.285752    0.434124    0.301474    11.00000   -1.50000
AFIX   0
C20   1    0.209877    0.399200    0.501801    11.00000    0.02638    0.02105 =
         0.02301   -0.00135    0.01067    0.00471
AFIX 137
H20A  2    0.182347    0.363440    0.518322    11.00000   -1.50000
H20B  2    0.180016    0.439524    0.492779    11.00000   -1.50000
H20C  2    0.259004    0.405499    0.552683    11.00000   -1.50000
AFIX   0
C21   1    0.135458    0.359392    0.294412    11.00000    0.02651    0.02670 =
         0.02529    0.00059    0.00650    0.00958
AFIX 137
H21A  2    0.146636    0.342400    0.240505    11.00000   -1.50000
H21B  2    0.104691    0.399153    0.275701    11.00000   -1.50000
H21C  2    0.107386    0.326402    0.315570    11.00000   -1.50000
AFIX   0
 
SAME S" > F3"
SADI S O2 S O3 S O4
SADI O2 O3 O3 O4 O4 O2
SADI C22 F1 C22 F2 C22 F3
SADI F1 F2 F2 F3 F3 F1
SIMU 0.02 0.04 0.9 S > F3"
 
PART1 21
S     7    0.475571    0.453961    0.747689    21.00000    0.02058    0.02399 =
         0.03516    0.00383    0.01144    0.00050
O2    4    0.509505    0.392353    0.739303    21.00000    0.03093    0.02262 =
         0.06003    0.00553    0.01990    0.00746
O3    4    0.513401    0.489509    0.832569    21.00000    0.06085    0.04919 =
         0.02512   -0.00330    0.00405   -0.01014
O4    4    0.393519    0.454055    0.717875    21.00000    0.02039    0.03044 =
         0.06598    0.00672    0.02005    0.00101
C22   1    0.492336    0.503929    0.657691    21.00000    0.02833    0.03316 =
         0.03475    0.00609    0.01770    0.01114
F1    5    0.456164    0.480747    0.571910    21.00000    0.12974    0.06748 =
         0.02925   -0.00403    0.03008    0.01396
F2    5    0.565603    0.507580    0.671212    21.00000    0.04125    0.07878 =
         0.13439    0.06628    0.06176    0.03147
F3    5    0.469021    0.565238    0.657496    21.00000    0.03906    0.02750 =
         0.05817    0.01741    0.02753    0.00909
PART2 -21
S"    7    0.468218    0.453011    0.744908   -21.00000    0.00962
O2"   4    0.513156    0.395065    0.771174   -21.00000    0.02095
O3"   4    0.474361    0.490143    0.825082   -21.00000    0.04556
O4"   4    0.395368    0.446225    0.674083   -21.00000    0.04054
C22"  1    0.516688    0.504151    0.686285   -21.00000    0.02744
F1"   5    0.524044    0.473052    0.613025   -21.00000    0.04318
F2"   5    0.586337    0.517816    0.743899   -21.00000    0.03847
F3"   5    0.477256    0.558345    0.653489   -21.00000    0.05742
PART0
 
SI'   6    0.744548    0.114520    0.878694    11.00000    0.02283    0.01679 =
         0.01783    0.00073    0.00493   -0.00529
O1'   4    0.788116    0.188435    0.913223    11.00000    0.01679    0.01559 =
         0.01525    0.00092    0.00670   -0.00203
N1'   3    0.811128    0.345516    0.894463    11.00000    0.01420    0.01440 =
         0.01565   -0.00064    0.00627   -0.00080
N2'   3    0.922554    0.296051    0.948061    11.00000    0.01206    0.01729 =
         0.01545   -0.00140    0.00521   -0.00189
N3'   3    0.800778    0.204497    0.772312    11.00000    0.01413    0.01700 =
         0.01520   -0.00006    0.00560   -0.00141
C1'   1    0.847260    0.287475    0.900192    11.00000    0.01210    0.01531 =
         0.01359   -0.00062    0.00534   -0.00114
C2'   1    0.865967    0.392746    0.937140    11.00000    0.02061    0.01585 =
         0.01945   -0.00387    0.01066   -0.00499
C3'   1    0.934460    0.362277    0.971372    11.00000    0.01776    0.01862 =
         0.01894   -0.00415    0.00879   -0.00574
C4'   1    0.725914    0.360732    0.851997    11.00000    0.01379    0.01796 =
         0.01901    0.00225    0.00638    0.00365
C5'   1    0.711065    0.402379    0.763689    11.00000    0.02635    0.02722 =
         0.02331    0.00945    0.00858    0.00528
AFIX 137
H5'1  2    0.722508    0.376761    0.715924    11.00000   -1.50000
H5'2  2    0.743538    0.441288    0.779604    11.00000   -1.50000
H5'3  2    0.657630    0.415784    0.738934    11.00000   -1.50000
AFIX   0
C6'   1    0.703005    0.396096    0.926984    11.00000    0.02191    0.02717 =
         0.02610   -0.00218    0.01146    0.00514
AFIX 137
H6'1  2    0.648615    0.406212    0.901151    11.00000   -1.50000
H6'2  2    0.732071    0.436769    0.945305    11.00000   -1.50000
H6'3  2    0.713719    0.367860    0.982317    11.00000   -1.50000
AFIX   0
C7'   1    0.676871    0.299536    0.825385    11.00000    0.01284    0.02269 =
         0.02206    0.00057    0.00496    0.00074
AFIX 137
H7'1  2    0.623126    0.311996    0.802398    11.00000   -1.50000
H7'2  2    0.687865    0.271351    0.880812    11.00000   -1.50000
H7'3  2    0.688047    0.275862    0.775812    11.00000   -1.50000
AFIX   0
C8'   1    0.855784    0.465030    0.943930    11.00000    0.02795    0.01667 =
         0.03567   -0.00544    0.01662   -0.00315
AFIX 137
H8'1  2    0.861625    0.476459    1.008750    11.00000   -1.50000
H8'2  2    0.804954    0.477655    0.901343    11.00000   -1.50000
H8'3  2    0.894114    0.488241    0.926137    11.00000   -1.50000
AFIX   0
C9'   1    1.007528    0.396554    1.023581    11.00000    0.02011    0.02607 =
         0.02933   -0.00754    0.00709   -0.00982
AFIX 137
H9'1  2    1.028922    0.414262    0.978535    11.00000   -1.50000
H9'2  2    1.043471    0.365514    1.065589    11.00000   -1.50000
H9'3  2    0.998070    0.432346    1.060830    11.00000   -1.50000
AFIX   0
C10'  1    0.986366    0.245114    0.978875    11.00000    0.01167    0.02186 =
         0.01896    0.00100    0.00417    0.00189
C11'  1    1.049001    0.266631    0.943109    11.00000    0.01999    0.03540 =
         0.03342    0.00873    0.01572    0.00671
AFIX 137
H11D  2    1.088748    0.233113    0.958694    11.00000   -1.50000
H11E  2    1.070896    0.308038    0.973080    11.00000   -1.50000
H11F  2    1.027462    0.272520    0.874654    11.00000   -1.50000
AFIX   0
C12'  1    1.014124    0.239960    1.086437    11.00000    0.02047    0.04083 =
         0.01855    0.00325    0.00465    0.00532
AFIX 137
H12D  2    0.973379    0.222276    1.105290    11.00000   -1.50000
H12E  2    1.028458    0.283454    1.114178    11.00000   -1.50000
H12F  2    1.058288    0.210854    1.108644    11.00000   -1.50000
AFIX   0
C13'  1    0.960829    0.177206    0.939303    11.00000    0.01924    0.02216 =
         0.03832   -0.00267    0.00059    0.00511
AFIX 137
H13D  2    0.942101    0.178873    0.870342    11.00000   -1.50000
H13E  2    0.920091    0.162102    0.960185    11.00000   -1.50000
H13F  2    1.003846    0.146902    0.961893    11.00000   -1.50000
AFIX   0
C14'  1    0.811035    0.224950    0.853684    11.00000    0.01064    0.01463 =
         0.01701    0.00052    0.00452   -0.00012
C15'  1    0.818683    0.233594    0.693025    11.00000    0.01305    0.01738 =
         0.00970    0.00040    0.00517   -0.00130
C16'  1    0.865006    0.297274    0.712598    11.00000    0.02349    0.02596 =
         0.01936    0.00175    0.01029   -0.00358
AFIX 137
H16D  2    0.838601    0.330654    0.735595    11.00000   -1.50000
H16E  2    0.870664    0.312564    0.654372    11.00000   -1.50000
H16F  2    0.915297    0.289219    0.760312    11.00000   -1.50000
AFIX   0
C17'  1    0.741016    0.245399    0.614700    11.00000    0.02173    0.03180 =
         0.01614    0.00211    0.00630   -0.00161
AFIX 137
H17D  2    0.710883    0.205139    0.603648    11.00000   -1.50000
H17E  2    0.748648    0.258233    0.556614    11.00000   -1.50000
H17F  2    0.714109    0.280336    0.634013    11.00000   -1.50000
AFIX   0
C18'  1    0.860857    0.179983    0.661023    11.00000    0.02969    0.03124 =
         0.02216   -0.00164    0.01425    0.00180
AFIX 137
H18D  2    0.911350    0.173637    0.709164    11.00000   -1.50000
H18E  2    0.866091    0.192989    0.601604    11.00000   -1.50000
H18F  2    0.832105    0.139030    0.651832    11.00000   -1.50000
AFIX   0
C19'  1    0.722106    0.090557    0.983060    11.00000    0.02535    0.02174 =
         0.02763    0.00499    0.01050   -0.00330
AFIX 137
H19D  2    0.769067    0.088728    1.038401    11.00000   -1.50000
H19E  2    0.697790    0.047446    0.972383    11.00000   -1.50000
H19F  2    0.687564    0.122794    0.993726    11.00000   -1.50000
AFIX   0
C20'  1    0.810968    0.055423    0.858498    11.00000    0.04649    0.01901 =
         0.02861   -0.00207    0.01639   -0.00277
AFIX 137
H20D  2    0.821933    0.068399    0.802623    11.00000   -1.50000
H20E  2    0.788018    0.011761    0.848695    11.00000   -1.50000
H20F  2    0.858268    0.054689    0.913437    11.00000   -1.50000
AFIX   0
C21'  1    0.656900    0.123766    0.774065    11.00000    0.03101    0.03532 =
         0.02893    0.00729    0.00189   -0.01629
AFIX 137
H21D  2    0.623234    0.155502    0.787651    11.00000   -1.50000
H21E  2    0.631050    0.081442    0.758317    11.00000   -1.50000
H21F  2    0.669949    0.139256    0.720755    11.00000   -1.50000
AFIX   0
C22'  1   -0.015791    0.468361    0.648826    11.00000    0.02118    0.03479 =
         0.02673    0.00176    0.00751    0.00222
S'    7    0.001133    0.461962    0.774169    11.00000    0.03750    0.02776 =
         0.02403    0.00442    0.01162    0.01161
O2'   4    0.063600    0.506417    0.815611    11.00000    0.07032    0.04323 =
         0.03544   -0.01198   -0.00320   -0.01062
O3'   4   -0.069959    0.481588    0.780000    11.00000    0.06559    0.06231 =
         0.05447    0.02374    0.04212    0.04054
O4'   4    0.020190    0.394306    0.794321    11.00000    0.03428    0.03043 =
         0.04818    0.01583    0.01655    0.01263
F1'   5    0.043232    0.446872    0.628365    11.00000    0.03273    0.06460 =
         0.03836   -0.00189    0.01983    0.00530
F2'   5   -0.029593    0.529492    0.618077    11.00000    0.05753    0.04941 =
         0.04591    0.02679    0.02021    0.01517
F3'   5   -0.075647    0.432084    0.598688    11.00000    0.03262    0.07959 =
         0.03667   -0.01045   -0.00074   -0.01649
 
HKLF    4
;