<i>catena</i>-Poly[[silver(I)-μ-1-phenylsulfanyl-2-(2-pyridylsulfanyl)ethane-κ^2^<i>S</i>^1^:<i>N</i>^2^] tetrafluoroborate]
Xie, Chuang; Zhou, Li-Na; Hou, Bao-Hong; Wang, Jing-Kang; Chen, Wei; Acta Crystallographica Section E 61 (2005) m2095–m2096; doi:10.1107/S1600536805025146

data_2206967
_publ_section_title
;<i>catena</i>-Poly[[silver(I)-\m-1-phenylsulfanyl-2-(2-pyridylsulfanyl)ethane-\k^2^<i>S</i>^1^:<i>N</i>^2^]
 tetrafluoroborate]
;
_journal_coeditor_code           HG6219
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2095
_journal_page_last               m2096
_journal_paper_doi               10.1107/S1600536805025146
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Ag (C13 H13 N S2)] B1 F4'
_chemical_formula_moiety         'C13 H13 Ag N S2 +, B1 F4 -'
_chemical_formula_sum            'C13 H13 Ag B F4 N S2'
_chemical_formula_weight         442.04
_chemical_name_systematic
;
catena-Poly[[silver(I)-\m-1-phenylsulfanyl-2-(2-pyridylsulfanyl)ethane-
\k^2^S^1^:N^2^] tetrafluoroborate]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 116.227(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.252(3)
_cell_length_b                   13.999(4)
_cell_length_c                   11.315(3)
_cell_measurement_reflns_used    1006
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.78
_cell_measurement_theta_min      3.61
_cell_volume                     1598.8(8)
_computing_cell_refinement       'SMART '
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics    'SHELXTL (Bruker, 1998)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0363
_diffrn_reflns_av_sigmaI/netI    0.0438
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            9039
_diffrn_reflns_theta_full        26.39
_diffrn_reflns_theta_max         26.39
_diffrn_reflns_theta_min         2.02
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.555
_exptl_absorpt_correction_T_max  0.883
_exptl_absorpt_correction_T_min  0.643
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.836
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             872
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.516
_refine_diff_density_min         -0.387
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.989
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     235
_refine_ls_number_reflns         3260
_refine_ls_number_restraints     20
_refine_ls_restrained_S_all      1.016
_refine_ls_R_factor_all          0.0637
_refine_ls_R_factor_gt           0.0361
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0437P)^2^+0.3971P] where P = (Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0777
_refine_ls_wR_factor_ref         0.0877
_reflns_number_gt                2324
_reflns_number_total             3260
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hg6219.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               2206967
_cod_database_fobs_code          2206967