Novel tetracyanoplatinates with the larger Ln3+ ions: Synthesis, structures, and photoluminescence properties of KLn[Pt(CN)4]2.8.75H2O (Ln = La, Pr, Nd)
Nicholas J. Robinson; Philip A. Smith; Sabrina Grant; Kendra Whitehead; Carlos Crawford; Zerihun Assefa; Richard E. Sykora; Inorganica Chimica Acta 394 (2013) 459–465; doi:10.1016/j.ica.2012.08.031

data_1512773
_publ_section_title
;
 Novel tetracyanoplatinates with the larger Ln3+ ions: Synthesis,
 structures, and photoluminescence properties of KLn[Pt(CN)4]2.8.75H2O (Ln
 = La, Pr, Nd)
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              459
_journal_page_last               465
_journal_paper_doi               10.1016/j.ica.2012.08.031
_journal_volume                  394
_journal_year                    2013
_chemical_formula_sum            'C8 H17.5 K N8 Nd O8.75 Pt2'
_chemical_formula_weight         939.32
_space_group_IT_number           43
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'F 2 -2d'
_symmetry_space_group_name_H-M   'F d d 2'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            32
_cell_length_a                   19.4281(4)
_cell_length_b                   26.8587(7)
_cell_length_c                   34.7270(7)
_cell_measurement_reflns_used    7931
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      25.6263
_cell_measurement_theta_min      3.0554
_cell_volume                     18121.0(7)
_computing_cell_refinement
'<i>CrysAlisPro</i> Oxford Diffraction, (2010)'
_computing_data_collection
'<i>CrysAlisPro</i> Oxford Diffraction, (2010)'
_computing_data_reduction
'<i>CrysAlisPro</i> Oxford Diffraction, (2010)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      295(2)
_diffrn_detector_area_resol_mean 16.0514
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Varian Oxford Xcalibur, Eos'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0343
_diffrn_reflns_av_sigmaI/netI    0.0439
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       42
_diffrn_reflns_limit_l_min       -42
_diffrn_reflns_number            18895
_diffrn_reflns_theta_full        25.68
_diffrn_reflns_theta_max         25.68
_diffrn_reflns_theta_min         3.06
_exptl_absorpt_coefficient_mu    14.815
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.62370
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   CrysAlisPro
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.754
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             13648
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.338
_refine_diff_density_min         -1.068
_refine_diff_density_rms         0.174
_refine_ls_abs_structure_details
;
Flack H D (1983), Acta Cryst. A39, 876-881
3758 Friedel pairs measured
;
_refine_ls_abs_structure_Flack   0.00(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.965
_refine_ls_matrix_type           full
_refine_ls_number_parameters     521
_refine_ls_number_reflns         8146
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      0.965
_refine_ls_R_factor_all          0.0472
_refine_ls_R_factor_gt           0.0308
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0208P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0593
_refine_ls_wR_factor_ref         0.0613
_reflns_number_gt                6153
_reflns_number_total             8146
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            ICA-2013-394-459-465-2.cif
_cod_data_source_block           NdPt
_cod_original_formula_sum        'C8 H17.50 K N8 Nd O8.75 Pt2'
_cod_database_code               1512773