Highly luminescent lanthanide complexes sensitised by tertiary amide-linked carbostyril antennae.
Kovacs, Daniel; Phipps, Dulcie; Orthaber, Andreas; Borbas, K. Eszter; Dalton transactions (Cambridge, England : 2003) 47 (2018) 10702–10714; doi:10.1039/c8dt01270a

data_7046671
_publ_section_title
;
 Highly luminescent lanthanide complexes sensitised by tertiary
 amide-linked carbostyril antennae.
;
_journal_issue                   31
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10702
_journal_page_last               10714
_journal_paper_doi               10.1039/c8dt01270a
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C26 H40 N6 O4'
_chemical_formula_sum            'C26 H40 N6 O4'
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_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/1
_audit_update_record
;
2018-03-27 deposited with the CCDC.
2018-06-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_computing_molecular_graphics    ' ORTEP for Windows (Farugia, 1997)'
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_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device_type  'BrukerAPEX II with CCD'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_exptl_absorpt_coefficient_mu    0.085
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_exptl_absorpt_process_details   'Sadabs (Sheldrick, 1996)'
_exptl_crystal_colour            'dark brown'
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_exptl_crystal_description       block
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_exptl_crystal_size_min          0.1
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         5479
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.1098
_refine_ls_R_factor_gt           0.0618
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0634P)^2^+1.8694P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1482
_refine_ls_wR_factor_ref         0.1759
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3307
_reflns_number_total             5479
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7046671--7046672.cif.'
_cod_database_code               7046671
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