Amine-Functionalized Indazolin-3-ylidene Complexes of Palladium(II) by Postmodification of a Single Precursor
Bernhammer, Jan C.; Singh, Harvenjit; Huynh, Han Vinh; Organometallics 33 (2014) 4295–; doi:10.1021/om5006275

data_4084233
_publ_section_title
;
 Amine-Functionalized Indazolin-3-ylidene Complexes of Palladium(II) by
 Postmodification of a Single Precursor
;
_journal_issue                   16
_journal_name_full               Organometallics
_journal_page_first              4295
_journal_paper_doi               10.1021/om5006275
_journal_volume                  33
_journal_year                    2014
_chemical_formula_sum            'C19 H30 Br2 N4 O2 Pd'
_chemical_formula_weight         612.69
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_diffrn_ambient_temperature      100(2)
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_diffrn_reflns_theta_full        25.242
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_exptl_absorpt_coefficient_mu    4.441
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_density_meas      ?
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0258P)^2^+1.8149P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            om5006275_si_002.cif
_cod_data_source_block           E158
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4084233--4084235.cif.

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'Not Measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        2228.2(5)
_cod_database_code               4084233
_shelx_estimated_absorpt_t_min   0.234
_shelx_estimated_absorpt_t_max   0.470
_shelxl_version_number           2013-4
_shelx_res_checksum              64694
_shelx_hkl_checksum              30466