Highly efficient temperature-dependent chiral separation with a nucleotide-based coordination polymer.
Bruno, Rosaria; Marino, Nadia; Bartella, Lucia; Di Donna, Leonardo; De Munno, Giovanni; Pardo, Emilio; Armentano, Donatella; Chemical communications (Cambridge, England) 54 (2018) 6356–6359; doi:10.1039/c8cc03544j

data_7121771
_publ_section_title
;
 Highly efficient temperature-dependent chiral separation with a
 nucleotide-based coordination polymer.
;
_journal_issue                   49
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              6356
_journal_page_last               6359
_journal_paper_doi               10.1039/c8cc03544j
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C112 H172 Cu7 N31 O89 P4'
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_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2018-05-02 deposited with the CCDC.
2018-05-29 downloaded from the CCDC.
;
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_computing_cell_refinement       'Bruker APEX'
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0782
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'single crystal to single crystal transformation soaking in saturated solution'
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;
;
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;
 Classical Flack method preferred over Parsons because s.u. lower.
;
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'w=1/[\s^2^(Fo^2^)+(0.1240P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7121770--7121771.cif.'
_cod_original_cell_volume        9028.2(11)
_cod_database_code               7121771
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_shelx_res_checksum              86346