Molecular precursor-mediated facile synthesis of phase pure metal-rich digenite (Cu<sub>1.8</sub>S) nanocrystals: an efficient anode for lithium-ion batteries.
Karmakar, Gourab; Tyagi, Adish; Halankar, Kruti K.; Nigam, Sandeep; Mandal, B. P.; Wadawale, A. P.; Kedarnath, G.; Debnath, Anil K.; Dalton transactions (Cambridge, England : 2003) 52 (2023) 1461–1475; doi:10.1039/d2dt03757b

data_7711990
_publ_section_title
;
 Molecular precursor-mediated facile synthesis of phase pure metal-rich
 digenite (Cu<sub>1.8</sub>S) nanocrystals: an efficient anode for
 lithium-ion batteries.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1461
_journal_page_last               1475
_journal_paper_doi               10.1039/d2dt03757b
_journal_volume                  52
_journal_year                    2023
_chemical_formula_sum            'C42 H37 Cl Cu N2 P2 S'
_chemical_formula_weight         762.72
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/6
_audit_update_record
;
2022-03-10 deposited with the CCDC.	2022-12-20 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku AFC7S'
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_exptl_absorpt_correction_type   psi-scan
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0464P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                3639
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7711990.cif.'
_cod_original_cell_volume        3815.8(10)
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