Rational ligand design for the arylation of hindered primary amines guided by reaction progress kinetic analysis.
Ruiz-Castillo, Paula; Blackmond, Donna G.; Buchwald, Stephen L.; Journal of the American Chemical Society 137 (2015) 3085–3092; doi:10.1021/ja512903g

data_4123462
_publ_section_title
;
 Rational ligand design for the arylation of hindered primary amines
 guided by reaction progress kinetic analysis.
;
_journal_issue                   8
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3085
_journal_page_last               3092
_journal_paper_doi               10.1021/ja512903g
_journal_volume                  137
_journal_year                    2015
_chemical_formula_sum            'C33 H37 Br N3 P Pd'
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_chemical_name_systematic
; 
 ? 
;
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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'I\mS micro-focus sealed tube, multilayer optics'
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; 
 w=1/[\s^2^(Fo^2^)+(0.0389P)^2^+5.4519P] 
 where P=(Fo^2^+2Fc^2^)/3 
;
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 4123462--4123463.cif.'
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