Active control of forward/backward charge transfer in Z-scheme water splitting: manipulating electrostatic affinity/repulsion between photocatalyst surface and electron mediator.
Itagaki, Ren; Nakada, Akinobu; Suzuki, Hajime; Tomita, Osamu; Abe, Ryu; Chemical science 17 (2026) 6379–6389; doi:10.1039/d5sc10049f

data_1576566
_publ_section_title
;
 Active control of forward/backward charge transfer in Z-scheme water
 splitting: manipulating electrostatic affinity/repulsion between
 photocatalyst surface and electron mediator.
;
_journal_issue                   13
_journal_name_full               'Chemical science'
_journal_page_first              6379
_journal_page_last               6389
_journal_paper_doi               10.1039/d5sc10049f
_journal_volume                  17
_journal_year                    2026
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;
2026-02-03 deposited with the CCDC.	2026-02-16 downloaded from the CCDC.
;
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;
CrysAlisPro 1.171.39.46e (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1110P)^2^+14.6416P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5sc10049f2.cif
_cod_data_source_block           itagaki2d_a
_cod_depositor_comments          'Adding full bibliography for 1576566.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C12.50 H13 Cl0.50 Co0.50 N2 O3.50'
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