Di-μ-iodido-bis[bis(cyclohexyldiphenylphosphine-κ<i>P</i>)silver(I)]
Young, John F.; Yap, Glenn P. A.; Acta Crystallographica Section E 63 (2007) m1943–m1943; doi:10.1107/S1600536807029042

data_2214078
_publ_section_title
;
 Di-\m-iodido-bis[bis(cyclohexyldiphenylphosphine-\k<i>P</i>)silver(I)]
;
_journal_coeditor_code           BR2047
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1943
_journal_page_last               m1943
_journal_paper_doi               10.1107/S1600536807029042
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ag2 I2 (C18 H21 P)4]'
_chemical_formula_moiety         'C72 H84 Ag2 I2 P4'
_chemical_formula_sum            'C72 H84 Ag2 I2 P4'
_chemical_formula_weight         1542.81
_chemical_name_systematic
;
Di-\m-iodido-bis[bis(cyclohexyldiphenylphosphine-\kP)silver(I)]
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.474(13)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   27.805(4)
_cell_length_b                   13.3327(17)
_cell_length_c                   17.598(4)
_cell_measurement_reflns_used    934
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      22.08
_cell_measurement_theta_min      2.67
_cell_volume                     6511.9(19)
_computing_cell_refinement       'SAINT (Bruker, 2002)'
_computing_data_collection       'SMART (Bruker, 2002)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL (Bruker, 2002)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 836.6
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0989
_diffrn_reflns_av_sigmaI/netI    0.0701
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            30202
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.03
_diffrn_standards_decay_%        1
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.689
_exptl_absorpt_correction_T_max  0.7629
_exptl_absorpt_correction_T_min  0.5556
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2002)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.574
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       tabular
_exptl_crystal_F_000             3104
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.938
_refine_diff_density_min         -0.497
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         5724
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.054
_refine_ls_R_factor_all          0.0571
_refine_ls_R_factor_gt           0.0394
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0207P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0814
_refine_ls_wR_factor_ref         0.0898
_reflns_number_gt                4448
_reflns_number_total             5724
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            br2047.cif
_cod_data_source_block           I
_cod_original_cell_volume        6511.8(19)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2214078
_cod_database_fobs_code          2214078