On the σ-complex character of bis(gallyl)/digallane transition metal species.
Kalkuhl, Till L.; Qin, Lei; Zhao, Lili; Frenking, Gernot; Hadlington, Terrance J.; Chemical science 14 (2023) 11088–11095; doi:10.1039/d3sc03772j

data_1569927
_publ_section_title
;
 On the &#x3c3;-complex character of bis(gallyl)/digallane transition
 metal species.
;
_journal_issue                   40
_journal_name_full               'Chemical science'
_journal_page_first              11088
_journal_page_last               11095
_journal_paper_doi               10.1039/d3sc03772j
_journal_volume                  14
_journal_year                    2023
_chemical_formula_moiety         'C62 H86 Cl2 Ga2 N2 Ni P2 Si2, C9 H20'
_chemical_formula_sum            'C71 H106 Cl2 Ga2 N2 Ni P2 Si2'
_chemical_formula_weight         1374.74
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_space_group_name_Hall           '-P 2a 2bc'
_space_group_name_H-M_alt        'P n n a'
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_audit_update_record
;
2023-05-30 deposited with the CCDC.	2023-09-22 downloaded from the CCDC.
;
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_refine_ls_R_factor_all          0.1045
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0720P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1192
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_reflns_number_gt                4198
_reflns_number_total             7142
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3sc03772j2.cif
_cod_data_source_block           compound_3
_cod_depositor_comments
'Adding full bibliography for 1569923--1569928.cif.'
_cod_database_code               1569927
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              67419
_shelx_hkl_checksum              98113