Developing strongly luminescent platinum(iv) complexes: facile synthesis of bis-cyclometalated neutral emitters.
Juliá, Fabio; Bautista, Delia; González-Herrero, Pablo; Chemical communications (Cambridge, England) 52 (2016) 1657–1660; doi:10.1039/c5cc09566b

data_7118512
_publ_section_title
;
 Developing strongly luminescent platinum(iv) complexes: facile synthesis
 of bis-cyclometalated neutral emitters.
;
_journal_issue                   8
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              1657
_journal_page_last               1660
_journal_paper_doi               10.1039/c5cc09566b
_journal_volume                  52
_journal_year                    2016
_chemical_formula_sum            'C25 H23 Cl N2 O2 Pt'
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_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-11-06 deposited with the CCDC.
2015-12-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_diffrn_measurement_device_type  'Bruker D8 QUEST'
_diffrn_measurement_method       'w and phi scans'
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_exptl_absorpt_process_details   SADABS
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_refine_diff_density_rms         0.170
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0049P)^2^+7.5525P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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