Bis[(4-methylphenyl)diphenylphosphane-κ<i>P</i>](nitrato-κ^2^<i>O</i>,<i>O</i>')silver(I)
Malan, Frederick P.; Potgieter, Kariska; Meijboom, Reinout; IUCrData 7 (2022) x221045–; doi:10.1107/S2414314622010458

data_1567933
_publ_section_title
;
 Bis[(4-methylphenyl)diphenylphosphane-\k<i>P</i>](nitrato-\k^2^<i>O</i>,<i>O</i>')silver(I)
;
_journal_coeditor_code           TK4086
_journal_issue                   11
_journal_name_full               IUCrData
_journal_page_first              x221045
_journal_paper_doi               10.1107/S2414314622010458
_journal_volume                  7
_journal_year                    2022
_chemical_formula_iupac          '[Ag (N O3) {C19 H17 P1)2]'
_chemical_formula_moiety         'C38 H34 Ag N O3 P2'
_chemical_formula_sum            'C38 H34 Ag N O3 P2'
_chemical_formula_weight         722.47
_chemical_name_systematic
Bis[(4-methylphenyl)diphenylphosphane-\k<i>P</i>](nitrato-\k^2^<i>O</i>,<i>O</i>')silver(I)
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_method
;
Olex2 1.3-ac4
(compiled 2018.12.18 svn.r3554 for Rigaku Oxford Diffraction, GUI svn.r1)
;
_cell_angle_alpha                90
_cell_angle_beta                 104.849(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   18.1290(6)
_cell_length_b                   11.0936(5)
_cell_length_c                   17.9971(7)
_cell_measurement_reflns_used    14857
_cell_measurement_temperature    150.00(10)
_cell_measurement_theta_max      78.5030
_cell_measurement_theta_min      4.6730
_cell_volume                     3498.6(2)
_computing_cell_refinement
;
CrysAlisPro (Rigaku OD, 2022)
;
_computing_data_collection
;
CrysAlisPro (Rigaku OD, 2022)
;
_computing_data_reduction
;
CrysAlisPro (Rigaku OD, 2022)
;
_computing_molecular_graphics
;
Olex2 (Dolomanov <i>et al.</i>,  2009)
;
_computing_publication_material
;
Olex2 (Dolomanov <i>et al.</i>,  2009)
;
_computing_structure_refinement
;
SHELXL (Sheldrick, 2015<i>b</i>)
;
_computing_structure_solution
;
SHELXT (Sheldrick, 2015<i>a</i>)
;
_diffrn_ambient_temperature      150.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0823
_diffrn_reflns_av_unetI/netI     0.0415
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            20162
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         79.230
_diffrn_reflns_theta_min         4.718
_diffrn_source                   'Rotating-anode X-ray tube'
_exptl_absorpt_coefficient_mu    5.772
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.34430
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(CrysAlisPro; Rigaku OD, 2022)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.372
_exptl_crystal_description       blade
_exptl_crystal_F_000             1480
_exptl_crystal_size_max          0.214
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.095
_refine_diff_density_max         0.596
_refine_diff_density_min         -1.135
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     206
_refine_ls_number_reflns         3668
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0559
_refine_ls_R_factor_gt           0.0475
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0290P)^2^+20.5034P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1066
_refine_ls_wR_factor_ref         0.1090
_reflns_number_gt                3383
_reflns_number_total             3668
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            tk4086.cif
_cod_data_source_block           I
_cod_database_code               1567933
_shelx_hkl_checksum              42926
_shelx_res_checksum              28918
_shelxl_version_number           2.013