Extremely bulky secondary phosphinoamines as substituents for sterically hindered aminosilanes.
Böttcher, Tobias; Jones, Cameron; Dalton transactions (Cambridge, England : 2003) 44 (2015) 14842–14853; doi:10.1039/c5dt02504d

data_7035933
_publ_section_title
;
 Extremely bulky secondary phosphinoamines as substituents for sterically
 hindered aminosilanes.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14842
_journal_page_last               14853
_journal_paper_doi               10.1039/c5dt02504d
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C54 H49 Cl9 N P Si5'
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_audit_update_record
;
2015-05-18 deposited with the CCDC.
2015-07-22 downloaded from the CCDC.
;
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_cell_angle_gamma                99.88(3)
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_computing_publication_material  CifTAB
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
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_diffrn_measurement_device_type  'ADSC Quantum 210r'
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_diffrn_radiation_type           Synchrotron
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0706P)^2^+1.0669P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7035922--7035934.cif.'
_cod_original_cell_volume        2898.3(10)
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