LMucko/crystallography-open-database huggingface dataset:
Reactions of Phenyllithium with the Stannylene Ar*SnPh (Ar* = C6H3-2,6-Trip2; Trip = C6H2-2,4,6-Pri3) and the Synthesis of the Distannylstannylene Sn(SnPh2Ar*)2: Contrasting Behavior in Methyl and Phenyl Derivatives
Eichler, Barrett E.; Phillips, Andrew D.; Power, Philip P.; Organometallics 22 (2003) 5423–5426; doi:10.1021/om034092n

data_4062439
_publ_section_title
;
 Reactions of Phenyllithium with the Stannylene Ar*SnPh (Ar* = C6H3-2,6-Trip2;
 Trip = C6H2-2,4,6-Pri3) and the Synthesis of the Distannylstannylene
 Sn(SnPh2Ar*)2: Contrasting Behavior in Methyl and Phenyl Derivatives
;
_journal_coden_ASTM              ORGND7
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              5423
_journal_page_last               5426
_journal_paper_doi               10.1021/om034092n
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C117 H139 Sn3'
_chemical_formula_weight         1901.35
_chemical_name_common            Sn(SnPh2Bert*)2.3.5benzene
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                71.3700(10)
_cell_angle_beta                 74.9120(10)
_cell_angle_gamma                80.5750(10)
_cell_formula_units_Z            2
_cell_length_a                   15.9150(5)
_cell_length_b                   15.9963(5)
_cell_length_c                   21.5430(7)
_cell_measurement_temperature    90(2)
_cell_volume                     4998.4(3)
_diffrn_ambient_temperature      90(2)
_exptl_crystal_density_diffrn    1.263
_cod_depositor_comments
;
 Updated bibliographical information.

 Antanas Vaitkus,
 2019-09-11
;
_cod_database_code               4062439
Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actinide-Mediated Intramolecular Hydroamination
Stubbert, Bryan D.; Stern, Charlotte L.; Marks, Tobin J.; Organometallics 22 (2003) 4836–4838; doi:10.1021/om034093f

data_4062440
_publ_section_title
;
 Synthesis and Catalytic Characteristics of Novel Constrained-Geometry
 Organoactinide Catalysts. The First Example of Actinide-Mediated
 Intramolecular Hydroamination
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4836
_journal_page_last               4838
_journal_paper_doi               10.1021/om034093f
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C19 H39 N3 Si Th'
_chemical_formula_weight         569.66
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 101.099(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   9.1808(8)
_cell_length_b                   33.296(4)
_cell_length_c                   15.1855(19)
_cell_measurement_temperature    153(2)
_cell_volume                     4555.1(9)
_diffrn_ambient_temperature      153(2)
_exptl_crystal_density_diffrn    1.671
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062440
Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actinide-Mediated Intramolecular Hydroamination
Stubbert, Bryan D.; Stern, Charlotte L.; Marks, Tobin J.; Organometallics 22 (2003) 4836–4838; doi:10.1021/om034093f

data_4062441
_publ_section_title
;
 Synthesis and Catalytic Characteristics of Novel Constrained-Geometry
 Organoactinide Catalysts. The First Example of Actinide-Mediated
 Intramolecular Hydroamination
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4836
_journal_page_last               4838
_journal_paper_doi               10.1021/om034093f
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C19 H39 N3 Si U'
_chemical_formula_weight         575.65
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                90.554(16)
_cell_angle_beta                 110.215(14)
_cell_angle_gamma                104.660(17)
_cell_formula_units_Z            2
_cell_length_a                   9.3063(15)
_cell_length_b                   10.624(3)
_cell_length_c                   13.063(3)
_cell_measurement_temperature    153(2)
_cell_volume                     1165.8(4)
_diffrn_ambient_temperature      153(2)
_exptl_crystal_density_diffrn    1.640
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062441
Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actinide-Mediated Intramolecular Hydroamination
Stubbert, Bryan D.; Stern, Charlotte L.; Marks, Tobin J.; Organometallics 22 (2003) 4836–4838; doi:10.1021/om034093f

data_4062442
_publ_section_title
;
 Synthesis and Catalytic Characteristics of Novel Constrained-Geometry
 Organoactinide Catalysts. The First Example of Actinide-Mediated
 Intramolecular Hydroamination
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4836
_journal_page_last               4838
_journal_paper_doi               10.1021/om034093f
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C21 H43 N3 Si U'
_chemical_formula_weight         603.70
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 93.826(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.2361(19)
_cell_length_b                   9.268(2)
_cell_length_c                   16.843(3)
_cell_measurement_temperature    153(2)
_cell_volume                     2528.9(7)
_diffrn_ambient_temperature      153(2)
_exptl_crystal_density_diffrn    1.586
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062442
Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actinide-Mediated Intramolecular Hydroamination
Stubbert, Bryan D.; Stern, Charlotte L.; Marks, Tobin J.; Organometallics 22 (2003) 4836–4838; doi:10.1021/om034093f

data_4062443
_publ_section_title
;
 Synthesis and Catalytic Characteristics of Novel Constrained-Geometry
 Organoactinide Catalysts. The First Example of Actinide-Mediated
 Intramolecular Hydroamination
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              4836
_journal_page_last               4838
_journal_paper_doi               10.1021/om034093f
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C23 H47 N3 Si U'
_chemical_formula_weight         631.76
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 98.634(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.0990(9)
_cell_length_b                   17.5757(16)
_cell_length_c                   15.7388(15)
_cell_measurement_temperature    153(2)
_cell_volume                     2761.9(4)
_diffrn_ambient_temperature      153(2)
_exptl_crystal_density_diffrn    1.519
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062443
Influence of Both Steric Effects and Te···N Intramolecular Nonbonded Interactions on the Stabilization of Organotellurium Compounds Incorporating [2-[1-(3,5-Dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]
Kandasamy, Karuppasamy; Kumar, Sangit; Singh, Harkesh B.; Wolmershäuser, Gotthelf; Organometallics 22 (2003) 5069–5078; doi:10.1021/om0340948

data_4062444
_publ_section_title
;
 Influence of Both Steric Effects and Te&#x00B7;&#x00B7;&#x00B7;N
 Intramolecular Nonbonded Interactions on the Stabilization of Organotellurium
 Compounds Incorporating
 [2-[1-(3,5-Dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              5069
_journal_page_last               5078
_journal_paper_doi               10.1021/om0340948
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C53 H51 N2 O2 Te2'
_chemical_formula_weight         1003.16
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 102.266(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   26.369(2)
_cell_length_b                   10.3905(6)
_cell_length_c                   17.0929(15)
_cell_measurement_temperature    293(2)
_cell_volume                     4576.4(6)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.456
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4062444
Influence of Both Steric Effects and Te···N Intramolecular Nonbonded Interactions on the Stabilization of Organotellurium Compounds Incorporating [2-[1-(3,5-Dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]
Kandasamy, Karuppasamy; Kumar, Sangit; Singh, Harkesh B.; Wolmershäuser, Gotthelf; Organometallics 22 (2003) 5069–5078; doi:10.1021/om0340948

data_4062445
_publ_section_title
;
 Influence of Both Steric Effects and Te&#x00B7;&#x00B7;&#x00B7;N
 Intramolecular Nonbonded Interactions on the Stabilization of Organotellurium
 Compounds Incorporating
 [2-[1-(3,5-Dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              5069
_journal_page_last               5078
_journal_paper_doi               10.1021/om0340948
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C23 H22 Cl N O Te'
_chemical_formula_weight         491.47
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 93.532(9)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.5012(8)
_cell_length_b                   9.7805(7)
_cell_length_c                   18.4007(14)
_cell_measurement_temperature    293(2)
_cell_volume                     2065.9(3)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.580
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062445
Influence of Both Steric Effects and Te···N Intramolecular Nonbonded Interactions on the Stabilization of Organotellurium Compounds Incorporating [2-[1-(3,5-Dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]
Kandasamy, Karuppasamy; Kumar, Sangit; Singh, Harkesh B.; Wolmershäuser, Gotthelf; Organometallics 22 (2003) 5069–5078; doi:10.1021/om0340948

data_4062446
_publ_section_title
;
 Influence of Both Steric Effects and Te&#x00B7;&#x00B7;&#x00B7;N
 Intramolecular Nonbonded Interactions on the Stabilization of Organotellurium
 Compounds Incorporating
 [2-[1-(3,5-Dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              5069
_journal_page_last               5078
_journal_paper_doi               10.1021/om0340948
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C23 H22 Cl3 N O Te'
_chemical_formula_weight         562.37
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 104.857(9)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.0971(9)
_cell_length_b                   20.6226(14)
_cell_length_c                   11.5861(9)
_cell_measurement_temperature    293(2)
_cell_volume                     2331.9(3)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.602
_exptl_crystal_F_000             1112
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062446
Influence of Both Steric Effects and Te···N Intramolecular Nonbonded Interactions on the Stabilization of Organotellurium Compounds Incorporating [2-[1-(3,5-Dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]
Kandasamy, Karuppasamy; Kumar, Sangit; Singh, Harkesh B.; Wolmershäuser, Gotthelf; Organometallics 22 (2003) 5069–5078; doi:10.1021/om0340948

data_4062447
_publ_section_title
;
 Influence of Both Steric Effects and Te&#x00B7;&#x00B7;&#x00B7;N
 Intramolecular Nonbonded Interactions on the Stabilization of Organotellurium
 Compounds Incorporating
 [2-[1-(3,5-Dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              5069
_journal_page_last               5078
_journal_paper_doi               10.1021/om0340948
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C23 H22 Br N O Te'
_chemical_formula_weight         535.93
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 91.723(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.6776(9)
_cell_length_b                   9.8397(6)
_cell_length_c                   18.3471(12)
_cell_measurement_temperature    293(2)
_cell_volume                     2107.2(2)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.689
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062447
Influence of Both Steric Effects and Te···N Intramolecular Nonbonded Interactions on the Stabilization of Organotellurium Compounds Incorporating [2-[1-(3,5-Dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]
Kandasamy, Karuppasamy; Kumar, Sangit; Singh, Harkesh B.; Wolmershäuser, Gotthelf; Organometallics 22 (2003) 5069–5078; doi:10.1021/om0340948

data_4062448
_publ_section_title
;
 Influence of Both Steric Effects and Te&#x00B7;&#x00B7;&#x00B7;N
 Intramolecular Nonbonded Interactions on the Stabilization of Organotellurium
 Compounds Incorporating
 [2-[1-(3,5-Dimethylphenyl)-2-naphthyl]-4,5-dihydro-4,4-dimethyloxazole]
;
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              5069
_journal_page_last               5078
_journal_paper_doi               10.1021/om0340948
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C23 H22 I N O Te'
_chemical_formula_weight         582.92
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.962(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.7944(10)
_cell_length_b                   9.8566(6)
_cell_length_c                   18.3522(15)
_cell_measurement_temperature    293(2)
_cell_volume                     2133.2(3)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.815
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062448
Facile Isomerization of a Tungsten Silyl Complex to a Base-Stabilized Silylene Complex via 1,2-Migration of an Aryl Group
Okazaki, Masaaki; Suzuki, Eiji; Miyajima, Norito; Tobita, Hiromi; Ogino, Hiroshi; Organometallics 22 (2003) 4633–4635; doi:10.1021/om034106p

data_4062449
_publ_section_title
;
 Facile Isomerization of a Tungsten Silyl Complex to a Base-Stabilized
 Silylene Complex via 1,2-Migration of an Aryl Group
;
_journal_issue                   23
_journal_name_full               Organometallics
_journal_page_first              4633
_journal_page_last               4635
_journal_paper_doi               10.1021/om034106p
_journal_volume                  22
_journal_year                    2003
_chemical_formula_moiety         'C22 H31 N O2 Si W '
_chemical_formula_sum            'C22 H31 N O2 Si W'
_chemical_formula_weight         553.43
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_cell_angle_alpha                90
_cell_angle_beta                 94.782(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.610(1)
_cell_length_b                   15.180(1)
_cell_length_c                   13.4861(9)
_cell_measurement_temperature    150.2
_cell_volume                     2164.6(3)
_exptl_crystal_density_diffrn    1.698
_cod_original_sg_symbol_H-M      'C c'
_cod_original_formula_sum        'C22 H31 N O2 Si W '
_cod_database_code               4062449
Exploration of the Suitability of Bicyclic Guanidinates as Ligands in Catalytic Chemistry Mediated by Titanium
Coles, Martyn P.; Hitchcock, Peter B.; Organometallics 22 (2003) 5201–5211; doi:10.1021/om0341092

data_4062450
_publ_section_title
;
 Exploration of the Suitability of Bicyclic Guanidinates as Ligands in Catalytic
 Chemistry Mediated by Titanium
;
_journal_coden_ASTM              ORGND7
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              5201
_journal_page_last               5211
_journal_paper_doi               10.1021/om0341092
_journal_volume                  22
_journal_year                    2003
_chemical_formula_moiety         'C14 H24 Cl6 N6 Ti2'
_chemical_formula_structural     'C14 H24 Cl6 N6 Ti2'
_chemical_formula_sum            'C14 H24 Cl6 N6 Ti2'
_chemical_formula_weight         584.89
_space_group_IT_number           14
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 90.799(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.2379(6)
_cell_length_b                   11.3740(8)
_cell_length_c                   10.6759(8)
_cell_measurement_temperature    173(2)
_cell_volume                     1121.63(14)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.732
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062450
Exploration of the Suitability of Bicyclic Guanidinates as Ligands in Catalytic Chemistry Mediated by Titanium
Coles, Martyn P.; Hitchcock, Peter B.; Organometallics 22 (2003) 5201–5211; doi:10.1021/om0341092

data_4062451
_publ_section_title
;
 Exploration of the Suitability of Bicyclic Guanidinates as Ligands in Catalytic
 Chemistry Mediated by Titanium
;
_journal_coden_ASTM              ORGND7
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              5201
_journal_page_last               5211
_journal_paper_doi               10.1021/om0341092
_journal_volume                  22
_journal_year                    2003
_chemical_formula_moiety         'C28 H38 N6 Ti1'
_chemical_formula_structural     'C28 H38 N6 TI'
_chemical_formula_sum            'C28 H38 N6 Ti'
_chemical_formula_weight         506.54
_chemical_name_common            '[Ti(Ch2Ph)2(C7H12N3)2]'
_space_group_IT_number           76
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      76
_symmetry_space_group_name_Hall  'P 4w'
_symmetry_space_group_name_H-M   'P 41'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.3107(3)
_cell_length_b                   9.3107(3)
_cell_length_c                   30.4556(11)
_cell_measurement_temperature    173(2)
_cell_volume                     2640.17(15)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.274
_cod_database_code               4062451