Conversion of oxido-bridged dinuclear ruthenium complex to dicationic dinitrosyl ruthenium complex using proton and nitric oxide: Completion of NO reduction cycle.
Arikawa, Yasuhiro; Matsumoto, Naoki; Asayama, Taiki; Umakoshi, Keisuke; Onishi, Masayoshi; Dalton transactions (Cambridge, England : 2003) 40 (2011) 2148–2150; doi:10.1039/c0dt01002b

data_7014603
_publ_section_title
;
 Conversion of oxido-bridged dinuclear ruthenium complex to dicationic
 dinitrosyl ruthenium complex using proton and nitric oxide: Completion
 of NO reduction cycle.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2148
_journal_page_last               2150
_journal_paper_doi               10.1039/c0dt01002b
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety
'C21 H24 B2 Cl N14 O Ru2, B F4, C4 H10 O, C3 H6 O'
_chemical_formula_sum            'C28 H40 B3 Cl F4 N14 O3 Ru2'
_chemical_formula_weight         966.73
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      12
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 97.1150(11)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   26.8810(17)
_cell_length_b                   14.7534(8)
_cell_length_c                   10.1208(8)
_cell_measurement_reflns_used    4628
_cell_measurement_temperature    296.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     3982.9(5)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR2004
_diffrn_ambient_temperature      296.1
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.021
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            15144
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.894
_exptl_absorpt_correction_T_max  0.836
_exptl_absorpt_correction_T_min  0.729
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            'dark red brown'
_exptl_crystal_density_diffrn    1.612
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1944.00
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.82
_refine_diff_density_min         -0.63
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    mixed
_refine_ls_number_parameters     286
_refine_ls_number_reflns         4622
_refine_ls_R_factor_gt           0.0438
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0001Fo^2^ + 3.0000?(Fo^2^) + 0.5000]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0846
_reflns_number_gt                3868
_reflns_number_total             4622
_reflns_threshold_expression     F^2^>2.0?(F^2^)
_cod_data_source_file            C0DT01002B.TXT
_cod_data_source_block           '__0729a'
_cod_original_formula_sum        'C28 H40 B3 Cl F4 N14 O3 Ru2 '
_cod_database_code               7014603