Metal nitrene-like reactivity of a Si[double bond, length as m-dash]N bond towards CO<sub>2</sub>.
Hadlington, Terrance J.; Szilvási, Tibor; Driess, Matthias; Chemical communications (Cambridge, England) 54 (2018) 9352–9355; doi:10.1039/c8cc05238g

data_7122055
_publ_section_title
;
 Metal nitrene-like reactivity of a Si[double bond, length as m-dash]N
 bond towards CO<sub>2</sub>.
;
_journal_issue                   67
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              9352
_journal_page_last               9355
_journal_paper_doi               10.1039/c8cc05238g
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C39 H66 Cl N5 Ni O5 Si2'
_chemical_formula_weight         835.30
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_space_group_name_Hall           'P 1'
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_audit_update_record
;
2018-06-25 deposited with the CCDC.
2018-07-27 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43c (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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;
 Classical Flack method preferred over Parsons because s.u. lower.
;
_refine_ls_abs_structure_Flack   0.13(3)
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1285P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_fraction_full    0.174
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_reflns_number_gt                7845
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8cc05238g2.cif
_cod_data_source_block           compound_3
_cod_depositor_comments
'Adding full bibliography for 7122053--7122058.cif.'
_cod_original_cell_volume        2265.5(2)
_cod_database_code               7122055
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.469
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_shelx_res_checksum              81622