Cationic tetrakis(nucleobase)complexes of PtII as metalloligands and potential building blocks for molecular architectures.
Sanz Miguel, Pablo J.; Lippert, Bernhard; Dalton transactions (Cambridge, England : 2003)  (2005) 1679–1686; doi:10.1039/b502251g

data_7008389
_publ_section_title
;
 Cationic tetrakis(nucleobase)complexes of PtII as metalloligands and
 potential building blocks for molecular architectures.
;
_journal_issue                   9
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1679
_journal_page_last               1686
_journal_paper_doi               10.1039/b502251g
_journal_year                    2005
_chemical_formula_moiety         'C24 H38 Cl3 Cu1.50 N18 O29 Pt'
_chemical_formula_sum            'C24 H38 Cl3 Cu1.5 N18 O29 Pt'
_chemical_formula_weight         1439.47
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             2005-03-11T10:42:38-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                89.50(3)
_cell_angle_beta                 75.92(3)
_cell_angle_gamma                87.81(3)
_cell_formula_units_Z            2
_cell_length_a                   11.211(2)
_cell_length_b                   11.605(2)
_cell_length_c                   18.442(4)
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27
_cell_measurement_theta_min      3
_cell_volume                     2325.6(8)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_measured_fraction_theta_full 0.928
_diffrn_measured_fraction_theta_max 0.928
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            9909
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         2.28
_exptl_absorpt_coefficient_mu    3.973
_exptl_absorpt_correction_T_max  0.8261
_exptl_absorpt_correction_T_min  0.6921
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.056
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prisms
_exptl_crystal_F_000             1425
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.968
_refine_diff_density_min         -1.058
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.926
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     681
_refine_ls_number_reflns         9909
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.926
_refine_ls_R_factor_gt           0.0534
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0733P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1354
_reflns_number_gt                5780
_reflns_number_total             9909
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b502251g.txt
_cod_data_source_block           1
_cod_original_cell_volume        2325.5(8)
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C24 H38 Cl3 Cu1.50 N18 O29 Pt'
_cod_database_code               7008389