Formation of a dimeric tungsten(i) complex via C-H activation.
Noor, Awal; Qayyum, Sadaf; Schwarz, Stefan; Dietel, Thomas; Kempe, Rhett; Dalton transactions (Cambridge, England : 2003) 49 (2020) 1992–1996; doi:10.1039/c9dt04847b

data_7703299
_publ_section_title
;
 Formation of a dimeric tungsten(i) complex via C-H activation.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1992
_journal_page_last               1996
_journal_paper_doi               10.1039/c9dt04847b
_journal_volume                  49
_journal_year                    2020
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_audit_update_record
;
2019-10-22 deposited with the CCDC.	2020-01-15 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  STOE-STADIVARI
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.51(3)
_refine_ls_extinction_coef       0.0062(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2016/6 (Sheldrick 2016)'
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_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.1214
_refine_ls_R_factor_gt           0.0858
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1160P)^2^+26.1994P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2061
_refine_ls_wR_factor_ref         0.2335
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_reflns_Friedel_fraction_full    0.994
_reflns_Friedel_fraction_max     0.994
_reflns_number_gt                10611
_reflns_number_total             14747
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7703297--7703299.cif.'
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