Synthesis of Trienes by Rhodium-Catalyzed Assembly and Disassembly of Non-Acceptor Cyclopropanes
Mato, Mauro; García-Morales, Cristina; Echavarren, Antonio M.; ACS Catalysis  (2020) 3564–; doi:10.1021/acscatal.0c00006

data_4517457
_publ_section_title
;
 Synthesis of Trienes by Rhodium-Catalyzed Assembly and Disassembly of
 Non-Acceptor Cyclopropanes
;
_journal_name_full               'ACS Catalysis'
_journal_page_first              3564
_journal_paper_doi               10.1021/acscatal.0c00006
_journal_year                    2020
_chemical_formula_sum            'C20 H26'
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_computing_cell_refinement       'Bruker APEX2 v2014.9-0'
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_computing_data_reduction        'Bruker APEX2 v2014.9-0'
_computing_molecular_graphics
'shelXle (H&#x00FC;bschle, Sheldrick and Dittirch, 2011)'
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;
 Fullsphere data collection, phi and omega scans
;
_diffrn_radiation_monochromator  'Quazar MX Multilayer Optics'
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_diffrn_source_size              '0.2 mm x 0.2 mm fine focus'
_diffrn_source_type              'Bruker APEX DUO'
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_description       block
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_exptl_crystal_size_mid          0.100
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0907P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                2725
_reflns_number_total             3741
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            cs0c00006_si_002.cif
_cod_data_source_block           mo_MM261-05
_cod_original_sg_symbol_H-M      'P 21/c'
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_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.988
_shelx_estimated_absorpt_t_max   0.997
_shelx_res_checksum              20728
_shelx_hkl_checksum              18887