From phosphanylphosphaalkenes to coordination copper and silver polymers containing P-P bonds.
Ziółkowska, Aleksandra; Prześniak-Welenc, Marta; Kruczyński, Tomasz; Gamer, Michael; Ponikiewski, Łukasz; Dalton transactions (Cambridge, England : 2003) 53 (2024) 9350–9357; doi:10.1039/d4dt00987h

data_7715971
_publ_section_title
;
 From phosphanylphosphaalkenes to coordination copper and silver polymers
 containing P-P bonds.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9350
_journal_page_last               9357
_journal_paper_doi               10.1039/d4dt00987h
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         'C25 H33 Ag Cl P2 S'
_chemical_formula_sum            'C25 H33 Ag Cl P2 S'
_chemical_formula_weight         570.83
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_space_group_name_Hall           '-I 2ya'
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_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-I 2ya'
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_audit_update_record
;
2024-04-02 deposited with the CCDC.	2024-05-07 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 98.631(7)
_cell_angle_gamma                90
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_cell_length_b                   9.7516(6)
_cell_length_c                   18.3994(14)
_cell_measurement_reflns_used    6750
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      26.12
_cell_measurement_theta_min      2.84
_cell_measurement_wavelength     0.71073
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_computing_molecular_graphics    'Ortep for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'
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_diffrn_measurement_details      ' 264 frames, detector distance = 40 mm'
_diffrn_measurement_device       'Eulerian 4-circle diffractometer'
_diffrn_measurement_device_type  'STOE STADIVARI'
_diffrn_measurement_method       'rotation method, \w scans'
_diffrn_radiation_collimation    '1.2 0.6 mm diameter'
_diffrn_radiation_monochromator  'Graded multilayer mirror'
_diffrn_radiation_polarisn_norm  270
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.827
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -37
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_diffrn_reflns_limit_k_min       -10
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_diffrn_reflns_point_group_measured_fraction_full 0.992
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_diffrn_source                   Axo_Mo
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_exptl_absorpt_process_details
;
STOE X-Red32, absorption correction by Gaussian integration, analogous to
P. Coppens, "The Evaluation of Absorption and Extinction in Single-Crystal
Structure Analysis", published in
F. R. Ahmed (Editor), "Crystallographic Computing",
Munksgaard, Copenhagen (1970), 255 - 270
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.458
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       fragment
_exptl_crystal_F_000             2344
_exptl_crystal_size_max          0.041
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_refine_diff_density_max         1.534
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0740P)^2^+11.3233P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1436
_refine_ls_wR_factor_ref         0.1964
_reflns_Friedel_coverage         0
_reflns_number_gt                2551
_reflns_number_total             6290
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4dt00987h2.cif
_cod_data_source_block           poly_3c_Ag_SS
_cod_depositor_comments
'Adding full bibliography for 7715966--7715972.cif.'
_cod_original_cell_volume        5201.9(7)
_cod_original_sg_symbol_H-M      'I 2/a'
_cod_database_code               7715971
_shelx_res_checksum              93383