Iron(II)‒alkoxide and ‒aryloxide complexes of a tris(thioether)borate ligand: synthesis, molecular structures, and implications on the origin of instability of their iron(II)‒catecholate counterpart
Wang, Peng; Yap, Glenn P. A.; Riordan, Charles G.; Acta Crystallographica Section C 77 (2021) –; doi:10.1107/S2053229621008500

data_2022424
_publ_section_title
;
 Iron(II)--alkoxide and --aryloxide complexes of a tris(thioether)borate
 ligand: synthesis, molecular structures, and implications on the origin
 of instability of their iron(II)--catecholate counterpart
;
_journal_coeditor_code           YO3080
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_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229621008500
_journal_volume                  77
_journal_year                    2021
_chemical_formula_iupac          '[Fe2 (C21 H38 B S3)2 (C6 H5 O)2], 2C7 H8'
_chemical_formula_moiety         'C54 H86 B2 Fe2 O2 S6, 2(C7 H8)'
_chemical_formula_sum            'C68 H102 B2 Fe2 O2 S6'
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_chemical_name_systematic
;Bis{\m-tris[(<i>tert</i>-butylsulfanyl)methyl]phenylborato-\k^3^<i>S</i>,<i>S</i>':<i>S</i>''}bis[(phenolato-\k<i>O</i>)iron(II)]
toluene disolvate
;
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;
Olex2 1.3
(compiled 2020.01.31 svn.r88ba2a32 for OlexSys, GUI svn.r6032)
;
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SAINT (Bruker, 2002)
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SMART (Bruker, 2002)
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SAINT (Bruker, 2002)
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OLEX2 (Dolomanov <i>et al.</i>, 2009)
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OLEX2 (Dolomanov <i>et al.</i>, 2009)
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SHELXL2018 (Sheldrick, 2015<i>b</i>)
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SHELXS1997 (Sheldrick, 2008)
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;
(SADABS; Bruker, 2007)
;
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'w=1/[\s^2^(Fo^2^)+(0.0938P)^2^+0.6253P] where P=(Fo^2^+2Fc^2^)/3'
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