Photoswitchable organoplatinum complexes with an azobenzene derivative of di-2-pyridylamine
Moustafa, Mohamed E.; Boyle, Paul D.; Puddephatt, Richard J.; New Journal of Chemistry 44 (2020) 2882–2889; doi:10.1039/C9NJ05313A

data_7059269
_publ_section_title
;
 Photoswitchable organoplatinum complexes with an azobenzene derivative of
 di-2-pyridylamine
;
_journal_issue                   7
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              2882
_journal_page_last               2889
_journal_paper_doi               10.1039/C9NJ05313A
_journal_volume                  44
_journal_year                    2020
_chemical_formula_sum            'C24 H23 I2 N5 Pt'
_chemical_formula_weight         830.36
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_block_doi                 10.5517/ccdc.csd.cc23clbf
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2020-01-19 deposited with the CCDC.	2020-01-31 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_computing_molecular_graphics    NRCVAX
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_computing_structure_solution    SHELXT
_diffrn_ambient_temperature      223
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            'Bruker Apex2'
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device       '\k-geometry diffractometer'
_diffrn_measurement_device_type  'Bruker Kappa Axis Apex2'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0398
_diffrn_reflns_av_unetI/netI     0.0370
_diffrn_reflns_Laue_measured_fraction_full 0.997
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_diffrn_reflns_theta_max         32.164
_diffrn_reflns_theta_min         3.112
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    8.163
_exptl_absorpt_correction_T_max  0.7463
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.222
_exptl_crystal_description       rectangular
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0136P)^2^+16.4042P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0528
_refine_ls_wR_factor_ref         0.0593
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5869
_reflns_number_total             8658
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9nj05313a1.cif
_cod_data_source_block           3
_cod_depositor_comments
;Adding full bibliography for 7059267--7059270.cif.

 Adding full bibliography for 7059267--7059270.cif.
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7059269
_shelx_estimated_absorpt_t_min   0.302
_shelx_estimated_absorpt_t_max   0.662
_shelx_res_checksum              29187