Conversion of [Pt(SRf)2(PPh2 ? n(C6F5)n + 1)2] ( n = 0 or 1, Rf?C6HF4-4) through carbon?fluorine bond activation to [Pt(SRf)2(1,2-C6F4(SRf)-(PPh2))] and chiral [Pt(SRf)2(1,2-C6F4(SRf)(PPh(C6F5)))]Electronic Supplementary Information (ESI) available: experimental procedures and spectral data for all new compounds and crystallographic data for 5, 8 and 10. http://www.rsc.org/suppdata/cc/b4/b407328b/
Villanueva, Luis; Arroyo, Maribel; Bern�s, Sylvain; Torrens, Hugo; Chemical Communications  (2004) 1942–1943; doi:10.1039/b407328b

data_7111363
_publ_section_title
;
 Conversion of [Pt(SRf)2(PPh2 ? n(C6F5)n + 1)2] ( n = 0 or 1, Rf?C6HF4-4)
 through carbon?fluorine bond activation to
 [Pt(SRf)2(1,2-C6F4(SRf)-(PPh2))] and chiral
 [Pt(SRf)2(1,2-C6F4(SRf)(PPh(C6F5)))]Electronic Supplementary Information
 (ESI) available: experimental procedures and spectral data for all new
 compounds and crystallographic data for 5, 8 and 10.
 http://www.rsc.org/suppdata/cc/b4/b407328b/
;
_journal_issue                   17
_journal_name_full               'Chemical Communications'
_journal_page_first              1942
_journal_page_last               1943
_journal_paper_doi               10.1039/b407328b
_journal_year                    2004
_chemical_formula_moiety         'C36 H13 F16 P Pt S3'
_chemical_formula_sum            'C36 H13 F16 P Pt S3'
_chemical_formula_weight         1071.70
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2003-06-02
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.108(10)
_cell_angle_beta                 102.397(17)
_cell_angle_gamma                105.499(14)
_cell_formula_units_Z            2
_cell_length_a                   11.945(3)
_cell_length_b                   12.0754(14)
_cell_length_c                   13.4898(18)
_cell_measurement_reflns_used    40
_cell_measurement_temperature    293(1)
_cell_measurement_theta_max      11.93
_cell_measurement_theta_min      2.12
_cell_volume                     1756.0(6)
_computing_cell_refinement       'XSCAnS 2.21 (Fait, 1996)'
_computing_data_collection       'XSCAnS 2.21 (Fait, 1996)'
_computing_data_reduction        'XSCAnS 2.21 (Fait, 1996)'
_computing_molecular_graphics    'SHELXTL 5.10 (Sheldrick, 1998)'
_computing_publication_material  'SHELX97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELX97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXTL 5.10 (Sheldrick, 1998)'
_diffrn_ambient_temperature      293(1)
_diffrn_detector                 'Scintillation counter'
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       '2\q/\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0334
_diffrn_reflns_av_sigmaI/netI    0.0710
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -1
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            7081
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.61
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_current           30
_diffrn_source_power             1.5
_diffrn_source_voltage           50
_diffrn_standards_decay_%        6.92
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.334
_exptl_absorpt_correction_T_max  0.531
_exptl_absorpt_correction_T_min  0.449
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '23 psi scans with XSCAnS 2.21 (Fait, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.027
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1028
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_refine_diff_density_max         1.266
_refine_diff_density_min         -0.542
_refine_diff_density_rms         0.137
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.167
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     514
_refine_ls_number_reflns         6109
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.167
_refine_ls_R_factor_all          0.0713
_refine_ls_R_factor_gt           0.0431
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0352P)^2^+0.1215P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0807
_refine_ls_wR_factor_ref         0.1023
_reflns_number_gt                4627
_reflns_number_total             6109
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            b407328bsup1.cif
_cod_data_source_block           lv34
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        1755.9(5)
_cod_database_code               7111363