Iminyl-radicals by electrochemical decarboxylation of α-imino-oxy acids: construction of indole-fused polycyclics.
Wan, Jin-Lin; Cui, Jian-Feng; Zhong, Wei-Qiang; Huang, Jing-Mei; Chemical communications (Cambridge, England) 57 (2021) 10242–10245; doi:10.1039/d1cc03891e

data_7128949
_publ_section_title
;
 Iminyl-radicals by electrochemical decarboxylation of \a-imino-oxy acids:
 construction of indole-fused polycyclics.
;
_journal_issue                   79
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              10242
_journal_page_last               10245
_journal_paper_doi               10.1039/d1cc03891e
_journal_volume                  57
_journal_year                    2021
_chemical_formula_sum            'C23 H18 N2 O2 S'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2021-04-29 deposited with the CCDC.	2021-09-08 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      213(2)
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_av_R_equivalents  0.0252
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_diffrn_reflns_Laue_measured_fraction_full 0.995
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_diffrn_reflns_point_group_measured_fraction_full 0.995
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_diffrn_reflns_theta_max         25.996
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_exptl_absorpt_coefficient_mu    0.194
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6630
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
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_exptl_crystal_description       prismatic
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_refine_ls_extinction_method     none
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.040
_refine_ls_R_factor_all          0.0430
_refine_ls_R_factor_gt           0.0360
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0407P)^2^+0.8117P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0893
_refine_ls_wR_factor_ref         0.0954
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3222
_reflns_number_total             3683
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cc03891e2.cif
_cod_data_source_block           mo_d8v21277_0m
_cod_depositor_comments          'Adding full bibliography for 7128949.cif.'
_cod_original_cell_volume        1881.79(8)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7128949
_shelx_estimated_absorpt_t_min   0.962
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_shelxl_version_number           2013-4
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