Reducing hybrid ligand-based alane and chasing aluminium(I): dialane and unusual transient dialumene.
Wang, Xiaobai; Ligorio, Raphael F.; Rüttger, Franziska; Krengel, David M. J.; Graw, Nico; Herbst-Irmer, Regine; Krawczuk, Anna; Stalke, Dietmar; Dalton transactions (Cambridge, England : 2003) 53 (2024) 15441–15450; doi:10.1039/d4dt01798f

data_7716775
_publ_section_title
;
 Reducing hybrid ligand-based alane and chasing aluminium(I): dialane and
 unusual transient dialumene.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15441
_journal_page_last               15450
_journal_paper_doi               10.1039/d4dt01798f
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         'C50 H64 Al2 N4'
_chemical_formula_sum            'C50 H64 Al2 N4'
_chemical_formula_weight         775.01
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2023-12-12 deposited with the CCDC.	2024-07-29 downloaded from the CCDC.
;
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_cell_volume                     4567.9(11)
_computing_cell_refinement       'Bruker SAINT V8.40A'
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_diffrn_detector_type            'Bruker Photon III C7 CMOS'
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker Smart APEX II Quazar'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0318
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_diffrn_reflns_theta_min         1.495
_diffrn_source                   'Incoatec Microsource'
_exptl_absorpt_coefficient_mu    0.101
_exptl_absorpt_correction_T_max  0.745757
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'TWINABS 2012/1'
_exptl_crystal_colour            red
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     533
_refine_ls_number_reflns         11820
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.111
_refine_ls_R_factor_all          0.0572
_refine_ls_R_factor_gt           0.0408
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0507P)^2^+1.0115P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1023
_refine_ls_wR_factor_ref         0.1079
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9251
_reflns_number_total             11820
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4dt01798f2.cif
_cod_data_source_block           2_WXB100
_cod_depositor_comments
'Adding full bibliography for 7716775--7716778.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7716775
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_shelx_res_checksum              20876
_shelx_hkl_checksum              37779