A disguised hydride in a butylmagnesium cation.
Banerjee, Sumanta; Ankur, ?; Andrews, Alex; Venugopal, Ajay; Chemical communications (Cambridge, England) 54 (2018) 5788–5791; doi:10.1039/c8cc03127d

data_7121666
_publ_section_title
;
 A disguised hydride in a butylmagnesium cation.
;
_journal_issue                   45
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              5788
_journal_page_last               5791
_journal_paper_doi               10.1039/c8cc03127d
_journal_volume                  54
_journal_year                    2018
_chemical_formula_moiety         'C34 H78 Mg2 N8 O4, 2(C24 B F20)'
_chemical_formula_sum            'C82 H78 B2 F40 Mg2 N8 O4'
_chemical_formula_weight         2069.76
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_audit_update_record
;
2018-04-16 deposited with the CCDC.
2018-05-11 downloaded from the CCDC.
;
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'ORTEP3 (Farrugia, 1997) and Mercury (Bruno et al., 2002)'
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_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker KAPPA APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0250P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7121665--7121667.cif.'
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