Emergence of complex chiral coordination clusters {CuNa<sub>12</sub>} by using multiple ligands under oxidizing conditions.
Meng, Wei; Ye, Hongfang; Liu, Shuai; Xu, Feng; Xu, Weijian; Dalton transactions (Cambridge, England : 2003) 48 (2019) 3204–3208; doi:10.1039/c9dt00209j

data_7049041
_publ_section_title
;
 Emergence of complex chiral coordination clusters {CuNa<sub>12</sub>} by
 using multiple ligands under oxidizing conditions.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3204
_journal_page_last               3208
_journal_paper_doi               10.1039/c9dt00209j
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C63 H45 Cu24 Na6 O118 P'
_chemical_formula_weight         4383.86
_space_group_crystal_system      hexagonal
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_space_group_name_Hall           'P 6c 2c'
_space_group_name_H-M_alt        'P 63 2 2'
_symmetry_space_group_name_Hall  'P 6c 2c'
_symmetry_space_group_name_H-M   'P 63 2 2'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2019-01-29 deposited with the CCDC.
2019-02-11 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
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_exptl_crystal_description       needle
_exptl_crystal_F_000             8576
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.47(3)
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1307P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1563
_refine_ls_wR_factor_ref         0.1781
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_reflns_number_gt                5844
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           d_sq
_cod_depositor_comments
'Adding full bibliography for 7049041--7049042.cif.'
_cod_original_cell_volume        22745.3(18)
_cod_database_code               7049041
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