Complexation-assisted reduction: complexes of glutaroimide-dioxime with tetravalent actinides (Np(iv) and Th(iv)).
Zhang, Zhicheng; Parker, Bernard F.; Lohrey, Trevor D.; Teat, Simon J.; Arnold, John; Rao, Linfeng; Dalton transactions (Cambridge, England : 2003) 47 (2018) 8134–8141; doi:10.1039/c8dt01191e

data_7046433
_publ_section_title
;
 Complexation-assisted reduction: complexes of glutaroimide-dioxime with
 tetravalent actinides (Np(iv) and Th(iv)).
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8134
_journal_page_last               8141
_journal_paper_doi               10.1039/c8dt01191e
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C20 H29 Cl3 N8 Np O5'
_chemical_formula_weight         804.86
_chemical_name_systematic        '[AO]2NpCl2'
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_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2018-03-07 deposited with the CCDC.
2018-05-22 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker D8 with PHOTON 100 detector'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'TWINABS 2012/1 Bruker AXS Madison WI USA'
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'Re-crystallisation from solvent: Pyridine/Water'
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_refine_ls_R_factor_all          0.0380
_refine_ls_R_factor_gt           0.0308
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0339P)^2^+11.2888P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                4744
_reflns_number_total             5375
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt01191e2.cif
_cod_data_source_block           twin4_a
_cod_depositor_comments
'Adding full bibliography for 7046433--7046435.cif.'
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