Sequential Bi-C bond activation reactions of BiEt3via insertion reactions of RE {R = HC[C(Me)N(2,6-i-Pr2C6H3)]2; E = Al, Ga, In}
C. Ganesamoorthy; D. Blaser; C. Wolper; S. Schulz; Chem.Commun. 50 (2014) 12382–; doi:10.1039/C4cc05028B

data_7115746
_publ_section_title
;
 Sequential Bi-C bond activation reactions of BiEt3via insertion reactions
 of RE {R = HC[C(Me)N(2,6-i-Pr2C6H3)]2; E = Al, Ga, In}
;
_journal_name_full               Chem.Commun.
_journal_page_first              12382
_journal_paper_doi               10.1039/C4cc05028B
_journal_volume                  50
_journal_year                    2014
_chemical_formula_moiety         'C35 H56 Bi In N2'
_chemical_formula_sum            'C35 H56 Bi In N2'
_chemical_formula_weight         828.61
_chemical_name_systematic
;
 ?
;
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_cell_length_c                   19.0397(9)
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_computing_cell_refinement       'BRUKER D8 KAPPA APEX 2 Vers. 3.0-2009'
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_computing_structure_solution    'BRUKER D8 KAPPA APEX 2 Vers. 3.0-2009'
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; 
 Bruker D8 KAPPA series II with APEX II area detector system
;
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;
 Data collection strategy APEX 2/COSMO
;
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_diffrn_source                   'sealed X-RAY tube'
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; 
 BRUKER AXS SMART APEX 2 Vers. 3.0-2009
 R.H. Blessing, Acta Cryst. (1995) A51 33-38 
;
_exptl_crystal_colour            yellow
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_exptl_crystal_size_min          0.227
_refine_diff_density_max         3.281
_refine_diff_density_min         -1.236
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0197P)^2^+7.5304P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0603
_refine_ls_wR_factor_ref         0.0631
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10388
_reflns_number_total             11625
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c4cc05028b2.cif
_cod_data_source_block           cg_010x
_cod_database_code               7115746
_shelx_estimated_absorpt_t_min   0.261
_shelx_estimated_absorpt_t_max   0.359
_shelxl_version_number           2013-4
_shelx_res_checksum              43972