An iron-containing POM-based hybrid compound as a heterogeneous catalyst for one-step hydroxylation of benzene to phenol.
Li, Si-Man; Wang, Ji-Lei; Zhou, Jiu-Lin; Xiang, Xin-Ying; Yu, Ya-Ting; Chen, Qun; Mei, Hua; Xu, Yan; Dalton transactions (Cambridge, England : 2003) 53 (2024) 1058–1065; doi:10.1039/d3dt03560c

data_7714613
_publ_section_title
;
 An iron-containing POM-based hybrid compound as a heterogeneous catalyst
 for one-step hydroxylation of benzene to phenol.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1058
_journal_page_last               1065
_journal_paper_doi               10.1039/d3dt03560c
_journal_volume                  53
_journal_year                    2024
_chemical_formula_sum            'C50 H45 Fe2 Mo11 N12 O45 P V3'
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2023-07-17 deposited with the CCDC.	2023-12-05 downloaded from the CCDC.
;
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_computing_structure_solution    'SHELXT 2018/3 (Sheldrick, 2018)'
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_diffrn_measurement_device_type  'Bruker Apex2 CCD'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0814P)^2^+4.9998P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3dt03560c2.cif
_cod_data_source_block           a0
_cod_depositor_comments          'Adding full bibliography for 7714613.cif.'
_cod_original_cell_volume        1992.8(9)
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