Constructing Highly Conducting Metal-Metal Bonded Solids by Electrocrystallization of [PtII2(RCS2)4] (RCS2-= Dithiocarboxylato, R = Methyl or Ethyl)
Minoru Mitsumi; Hidekazu Ueda; Kazumi Furukawa; Yoshiki Ozawa; Koshiro Toriumi; Mohamedally Kurmoo; Journal of the American Chemical Society 130 (2008) 14102–14104; doi:10.1021/ja805794a

data_4108558
_publ_contact_author_address
; 
Department of Material Science
Graduate School of Material Science
University of Hyogo
3-2-1 Kouto, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan 
;
_publ_contact_author_email       mitsumi@sci.u-hyogo.ac.jp
_publ_contact_author_fax         +81-791-58-0154
_publ_contact_author_name        'Mitsumi, Minoru'
_publ_contact_author_phone       +81-791-58-0153
_publ_section_title
;
 Constructing Highly Conducting Metal-Metal Bonded Solids by
 Electrocrystallization of [PtII2(RCS2)4] (RCS2-= Dithiocarboxylato, R =
 Methyl or Ethyl)
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              14102
_journal_page_last               14104
_journal_paper_doi               10.1021/ja805794a
_journal_volume                  130
_journal_year                    2008
_chemical_formula_moiety         'C67 H73 Cl N5 O4 Pt8 S32'
_chemical_formula_sum            'C67 H73 Cl N5 O4 Pt8 S32'
_chemical_formula_weight         3634.55
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                69.383(3)
_cell_angle_beta                 85.262(4)
_cell_angle_gamma                87.001(4)
_cell_formula_units_Z            1
_cell_length_a                   11.613(1)
_cell_length_b                   12.790(1)
_cell_length_c                   18.008(1)
_cell_measurement_reflns_used    11660
_cell_measurement_temperature    204(1)
_cell_measurement_theta_max      23.78
_cell_measurement_theta_min      0.763
_cell_volume                     2494.1(3)
_computing_cell_refinement       'SCALEPACK (Otwinoski & Minor,1997)'
_computing_data_collection       'DENZO (Otwinoski & Minor,1997)'
_computing_data_reduction        'teXsan Ver. 1.11 (MSC, 1985 & 1999)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR-97 (A. Altomare, 1999)'
_diffrn_ambient_temperature      204(1)
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.763
_diffrn_measured_fraction_theta_max 0.763
_diffrn_measurement_device_type  'oscillation IP camera'
_diffrn_measurement_method       'phi-axis oscillation'
_diffrn_radiation_monochromator  'Si 311'
_diffrn_radiation_source         'SPring-8 8GeV synchrotron'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.5640(5)
_diffrn_reflns_av_R_equivalents  0.0544
_diffrn_reflns_av_sigmaI/netI    0.1440
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            18403
_diffrn_reflns_theta_full        23.78
_diffrn_reflns_theta_max         23.78
_diffrn_reflns_theta_min         1.91
_exptl_absorpt_coefficient_mu    6.170
_exptl_absorpt_correction_T_max  0.76338
_exptl_absorpt_correction_T_min  0.66642
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'PLATON-MULABS (A. L. Spek, 2003)'
_exptl_crystal_colour            'dark green'
_exptl_crystal_density_diffrn    2.420
_exptl_crystal_description       plate
_exptl_crystal_F_000             1695
_exptl_crystal_size_max          0.353
_exptl_crystal_size_mid          0.088
_exptl_crystal_size_min          0.008
_refine_diff_density_max         2.401
_refine_diff_density_min         -1.924
_refine_diff_density_rms         0.179
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     492
_refine_ls_number_reflns         11660
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0770
_refine_ls_R_factor_gt           0.0545
_refine_ls_shift/su_max          0.016
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0469P)^2^+7.6139P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1299
_refine_ls_wR_factor_ref         0.1398
_reflns_number_gt                8485
_reflns_number_total             11660
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja805794a_si_002.cif
_cod_data_source_block           '[Pt2(MeCS2)4]4ClO4.5PhCN_204K'
_cod_database_code               4108558