Optical properties of trinuclear metal chalcogenolate complexes - room temperature NIR fluorescence in [Cu2Ti(SPh)6(PPh3)2].
Kühn, Michael; Lebedkin, Sergei; Weigend, Florian; Eichhöfer, Andreas; Dalton transactions (Cambridge, England : 2003) 46 (2017) 1502–1509; doi:10.1039/c6dt04287b

data_7041623
_publ_section_title
;
 Optical properties of trinuclear metal chalcogenolate complexes - room
 temperature NIR fluorescence in [Cu2Ti(SPh)6(PPh3)2].
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1502
_journal_page_last               1509
_journal_paper_doi               10.1039/c6dt04287b
_journal_volume                  46
_journal_year                    2017
_chemical_formula_sum            'C72 H60 Ag2 P2 S6 Sn'
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_chemical_name_systematic
; 
 ? 
;
_chemical_properties_physical
', Air-sensitive,Moisture-sensitive,Oxygen-sensitive'
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_space_group_IT_number           148
_space_group_name_Hall           '-R 3'
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_audit_update_record
;
2016-06-22 deposited with the CCDC.
2017-01-05 downloaded from the CCDC.
;
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_exptl_absorpt_correction_T_min  0.8299
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0243P)^2^+4.4530P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt04287b19.cif
_cod_data_source_block           r-3_sq
_cod_depositor_comments
'Adding full bibliography for 7041622--7041623.cif.'
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_cod_database_code               7041623
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