CS2 activation at uranium(iii) siloxide ate complexes: the effect of a Lewis acidic site.
Camp, Clément; Cooper, Oliver; Andrez, Julie; Pécaut, Jacques; Mazzanti, Marinella; Dalton transactions (Cambridge, England : 2003) 44 (2015) 2650–2656; doi:10.1039/c4dt02585g

data_7033091
_publ_section_title
;
 CS2 activation at uranium(iii) siloxide ate complexes: the effect of a
 Lewis acidic site.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2650
_journal_page_last               2656
_journal_paper_doi               10.1039/c4dt02585g
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'U(Si O4 C12 H27)4 (CS3)K2(O6 C12 H24)2'
_chemical_formula_sum            'C101 H188 K2 O28 S3 Si4 U'
_chemical_formula_weight         2375.27
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; 
 ? 
;
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Agilent Technologies, (2013), CrysAlisPro Software system, 
version 1.171. 37.31, Agilent Technologies UK Ltd, Oxford, UK
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Agilent Technologies, (2013), CrysAlisPro Software system, 
version 1.171.37.31, Agilent Technologies UK Ltd, Oxford, UK
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Agilent Technologies, (2013), CrysAlisPro Software system, 
version 1.171. 37.31, Agilent Technologies UK Ltd, Oxford, UK
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Mercury 3.1 New software for searching the Cambridge Structural Database 
and visualizing crystal structures (I.J. Bruno, J.C. Cole, P.R. Edgington, 
M. Kessler, C.F. Macrae, P. McCabe, J. Pearson, R. Taylor, 
Acta Cryst., 2002, B58, 389-397)
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OLEX2: a complete structure solution, refinement and analysis program 
(O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and 
H. Puschmann. J. Appl. Cryst. 2009, 42, 339-34).
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SUPERFLIP program (Palatinus, L. & Chapuis, G. J. Appl. Cryst., 2007,
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_diffrn_ambient_temperature      150(2)
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;
  1 omega    3.00   96.00   1.0000   10.0000
omega____ theta____ kappa____ phi______ frames
    -       25.5614   77.0000 -150.0000 93

  2 omega  -57.00   41.00   1.0000   10.0000
omega____ theta____ kappa____ phi______ frames
    -      -27.1239   77.0000  120.0000 98

  3 omega  -92.00    0.00   1.0000   10.0000
omega____ theta____ kappa____ phi______ frames
    -      -27.1239  -77.0000    0.0000 92

  4 omega  -97.00   -4.00   1.0000   10.0000
omega____ theta____ kappa____ phi______ frames
    -      -27.1239  -77.0000  -90.0000 93

  5 omega   34.00   68.00   1.0000   10.0000
omega____ theta____ kappa____ phi______ frames
    -       25.5614  179.0000  120.0000 34

  6 omega  -53.00   45.00   1.0000   10.0000
omega____ theta____ kappa____ phi______ frames
    -      -27.1239   37.0000  -30.0000 98

;
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
(compiled Dec  3 2012,18:21:49)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'translucent light brown'
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_exptl_crystal_size_mid          0.440
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A.L.Spek, Acta Cryst. 2009, D65, 148-155
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_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0698P)^2^+30.7734P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7033089--7033091.cif.'
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