E-Selective Allyl Transfer Reaction in a μ-η1:η2-Crotylplatinum−Cobalt Complex
Komine, Nobuyuki; Hirota, Takuma; Hirano, Masafumi; Komiya, Sanshiro; Organometallics 27 (2008) 2145–; doi:10.1021/om701062g

data_4070834
_publ_section_title
;
 E-Selective Allyl Transfer Reaction in a
 \m-\h1:\h2-Crotylplatinum&#x2212;Cobalt Complex
;
_journal_issue                   9
_journal_name_full               Organometallics
_journal_page_first              2145
_journal_paper_doi               10.1021/om701062g
_journal_volume                  27
_journal_year                    2008
_chemical_formula_moiety         'C50 H33 Co O3 P2 Pt '
_chemical_formula_sum            'C50 H33 Co O3 P2 Pt'
_chemical_formula_weight         997.78
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 101.71(5)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   12.745(10)
_cell_length_b                   19.220(13)
_cell_length_c                   18.529(7)
_cell_measurement_reflns_used    12
_cell_measurement_temperature    200.1
_cell_measurement_theta_max      14.7
_cell_measurement_theta_min      14.2
_cell_volume                     4444(5)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.277
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            10629
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_standards_decay_%        -0.94
_diffrn_standards_interval_count 0
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.617
_exptl_absorpt_correction_T_max  0.485
_exptl_absorpt_correction_T_min  0.328
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.491
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1968.00
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         12.90
_refine_diff_density_min         -21.10
_refine_ls_extinction_coef       15(3)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   0.973
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     403
_refine_ls_number_reflns         10629
_refine_ls_R_factor_gt           0.0551
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w = 1/[1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1155
_reflns_number_gt                4154
_reflns_number_total             10181
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om701062g-file003.cif
_cod_data_source_block           3a
_cod_original_formula_sum        'C50 H33 Co O3 P2 Pt '
_cod_database_code               4070834