3D Coordination Networks Based on Supramolecular Chains as Building Units: Synthesis and Crystal Structures of Two Silver(I) Pyridyldiethynides
Tianle Zhang; Jianxi Kong; Yuejie Hu; Xianggao Meng; Hongbing Yin; Dongshuang Hu; Changpeng Ji; Inorganic Chemistry 47 (2008) 3144–3149; doi:10.1021/ic702230h

data_4304671
_publ_section_title
;
3D Coordination Networks Based on Supramolecular Chains as Building Units:
Synthesis and Crystal Structures of Two Silver(I) Pyridyldiethynides
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3144
_journal_page_last               3149
_journal_paper_doi               10.1021/ic702230h
_journal_volume                  47
_journal_year                    2008
_chemical_formula_sum            'C34 H22 Ag12 F24 N2 O24'
_chemical_formula_weight         2592.98
_chemical_name_common            CF3CO2Ag-3,5-pyridyldiethynide
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                89.0940(10)
_cell_angle_beta                 87.4250(10)
_cell_angle_gamma                78.4400(10)
_cell_formula_units_Z            2
_cell_length_a                   10.8001(8)
_cell_length_b                   11.6288(8)
_cell_length_c                   25.3183(18)
_cell_measurement_temperature    293(2)
_cell_volume                     3112.1(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device_type  'Bruker Smart Apex II CCD'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0172
_diffrn_reflns_av_sigmaI/netI    0.0366
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            17985
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.40
_exptl_absorpt_coefficient_mu    3.829
_exptl_absorpt_correction_T_max  0.5147
_exptl_absorpt_correction_T_min  0.2608
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS,Sheldrick,1997
_exptl_crystal_colour            pale-yellow
_exptl_crystal_density_diffrn    2.767
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2424
_exptl_crystal_size_max          0.48
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.20
_refine_diff_density_max         2.400
_refine_diff_density_min         -2.529
_refine_diff_density_rms         0.181
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     883
_refine_ls_number_reflns         11987
_refine_ls_number_restraints     27
_refine_ls_restrained_S_all      1.040
_refine_ls_R_factor_all          0.0691
_refine_ls_R_factor_gt           0.0582
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0805P)^2^+29.6067P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1613
_refine_ls_wR_factor_ref         0.1677
_reflns_number_gt                9843
_reflns_number_total             11987
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic702230h-file003.cif
_cod_data_source_block           70511ztl_0m
_cod_database_code               4304671