Ruthenium Catalyzed Diastereo- and Enantioselective Coupling of Propargyl Ethers with Alcohols: Siloxy-Crotylation via Hydride Shift Enabled Conversion of Alkynes to π-Allyls.
Liang, Tao; Zhang, Wandi; Chen, Te-Yu; Nguyen, Khoa D.; Krische, Michael J.; Journal of the American Chemical Society 137 (2015) 13066–13071; doi:10.1021/jacs.5b08019

data_4129548
_publ_section_title
;
 Ruthenium Catalyzed Diastereo- and Enantioselective Coupling of Propargyl
 Ethers with Alcohols: Siloxy-Crotylation via Hydride Shift Enabled
 Conversion of Alkynes to \p-Allyls.
;
_journal_issue                   40
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13066
_journal_page_last               13071
_journal_paper_doi               10.1021/jacs.5b08019
_journal_volume                  137
_journal_year                    2015
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C11 H15 Br O2'
_chemical_formula_sum            'C11 H15 Br O2'
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;

SUPERFLIP.  Palatinus, L. and Chapuis, G., J. Appl. Cryst. 40, 786-790.
;
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_diffrn_measurement_method       '\w and \f-scans'
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_diffrn_reflns_av_unetI/netI     0.0479
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_exptl_absorpt_process_details
;
SADABS.
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_exptl_crystal_colour            colorless
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;
 Refined as an inversion twin.
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0221P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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