Development of a novel Cd(ii) metal complex for solvent-sensitive detection of Zn(ii) and Mg(ii) with the formation of Cd(ii)–Zn(ii)/Cd(ii)–Mg(ii) complexes and their application in effective Schottky devices
Sathapat, Dibyendu; Das, Mainak; Das, Manik; Das, Uttam Kumar; Bag, Arijit; Laha, Soumik; Ray, Partha Pratim; Samanta, Bidhan Chandra; Maity, Tithi; New Journal of Chemistry 48 (2024) 1837–1849; doi:10.1039/D3NJ04660E

data_7062926
_publ_section_title
;
 Development of a novel Cd(ii) metal complex for solvent-sensitive
 detection of Zn(ii) and Mg(ii) with the formation of
 Cd(ii)--Zn(ii)/Cd(ii)--Mg(ii) complexes and their application in
 effective Schottky devices
;
_journal_issue                   4
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              1837
_journal_page_last               1849
_journal_paper_doi               10.1039/D3NJ04660E
_journal_volume                  48
_journal_year                    2024
_chemical_formula_moiety         'C20 H24 Cd I2 N2 O4'
_chemical_formula_sum            'C20 H24 Cd I2 N2 O4'
_chemical_formula_weight         722.61
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_space_group_name_Hall           '-P 2yac'
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_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2023-03-04 deposited with the CCDC.	2023-12-20 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 3
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'BRUKER CCD AREA DETECTOR'
_diffrn_measurement_method       'PHI-OMEGA SCAN'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0243
_diffrn_reflns_Laue_measured_fraction_full 0.996
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_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
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_diffrn_reflns_point_group_measured_fraction_full 0.996
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_exptl_absorpt_coefficient_mu    3.636
_exptl_absorpt_correction_T_max  0.7459
_exptl_absorpt_correction_T_min  0.6080
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0127P)^2^+1.1447P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0493
_refine_ls_wR_factor_ref         0.0547
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2631
_reflns_number_total             3200
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3nj04660e2.cif
_cod_data_source_block           shelx
_cod_depositor_comments
'Adding full bibliography for 7062926--7062927.cif.'
_cod_original_cell_volume        1158.2(4)
_cod_original_sg_symbol_H-M      'P 2/n'
_cod_database_code               7062926
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.6080
_shelx_estimated_absorpt_t_max   0.7459
_shelx_res_checksum              60232