Highly Selective Construction of Medium-Sized Lactams by Palladium-Catalyzed Intramolecular Hydroaminocarbonylation of Aminoalkynes.
Hu, Yue; Huang, Hanmin; Organic letters 19 (2017) 5070–5073; doi:10.1021/acs.orglett.7b02284

data_1547226
_publ_section_title
;
 Highly Selective Construction of Medium-Sized Lactams by
 Palladium-Catalyzed Intramolecular Hydroaminocarbonylation of
 Aminoalkynes.
;
_journal_issue                   19
_journal_name_full               'Organic letters'
_journal_page_first              5070
_journal_page_last               5073
_journal_paper_doi               10.1021/acs.orglett.7b02284
_journal_volume                  19
_journal_year                    2017
_chemical_formula_moiety         'C24 H21 N O'
_chemical_formula_sum            'C24 H21 N O'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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  1 omega  -94.00  -55.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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  2 omega   -7.00   57.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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omega____ theta____ kappa____ phi______ frames
    -       22.7867   19.0000  150.0000 120
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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'w=1/[\s^2^(Fo^2^)+(0.0348P)^2^+0.8822P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 1547225--1547231.cif.'
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;
1. Fixed Uiso
 At 1.2 times of:
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2.a Secondary CH2 refined with riding coordinates:
 C4(H4A,H4B), C7(H7A,H7B), C18(H18A,H18B)
2.b Aromatic/amide H refined with riding coordinates:
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