Electron rich bidentate phosphinimine-imine ligands: synthesis and reactivity of late transition metal complexes.
Wallis, Christopher J.; Kraft, Ira L.; Patrick, Brian O.; Mehrkhodavandi, Parisa; Dalton transactions (Cambridge, England : 2003) 39 (2010) 541–547; doi:10.1039/b912783f

data_7024209
_publ_section_title
;
 Electron rich bidentate phosphinimine-imine ligands: synthesis and
 reactivity of late transition metal complexes.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              541
_journal_page_last               547
_journal_paper_doi               10.1039/b912783f
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C38 H31 Cl2 Co N2 P'
_chemical_formula_weight         676.45
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                118.200(10)
_cell_angle_beta                 94.80(2)
_cell_angle_gamma                95.250(10)
_cell_formula_units_Z            2
_cell_length_a                   10.935(4)
_cell_length_b                   13.014(3)
_cell_length_c                   13.330(4)
_cell_measurement_reflns_used    9970
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.74
_cell_measurement_theta_min      2.38
_cell_volume                     1647.3(9)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'Bruker X8 APEX II'
_diffrn_measurement_method       'area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0302
_diffrn_reflns_av_sigmaI/netI    0.0276
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            31548
_diffrn_reflns_theta_full        27.84
_diffrn_reflns_theta_max         27.84
_diffrn_reflns_theta_min         1.75
_exptl_absorpt_coefficient_mu    0.761
_exptl_absorpt_correction_T_max  0.846
_exptl_absorpt_correction_T_min  0.788
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.364
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             698
_exptl_crystal_size_max          0.51
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.358
_refine_diff_density_min         -0.283
_refine_diff_density_rms         0.047
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     398
_refine_ls_number_reflns         7627
_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0368
_refine_ls_R_factor_gt           0.0284
_refine_ls_shift/su_max          0.034
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0290P)^2^+0.7006P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0681
_refine_ls_wR_factor_ref         0.0722
_reflns_number_gt                6505
_reflns_number_total             7627
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b912783f.txt
_cod_data_source_block           pm038
_cod_original_cell_volume        1647.3(8)
_cod_database_code               7024209