Synthesis, Structures, and Magnetic Properties of Heterodimetal Bis(μ-hydroxo)chromium(III)nickel(II) Complexes with Tpa Derivatives Having Sterically Bulky Substituents
Kazushi Shiren; Shuhei Fujinami; Masatatsu Suzuki; Akira Uehara; Inorganic Chemistry 41 (2002) 1598–1605; doi:10.1021/ic010568o

data_4317680
_publ_contact_author_address
;
Department of Chemistry, Faculty of Science, Kanazawa University, Kakuma-
machi, Kanazawa 920-1192, Japan
;
_publ_contact_author_email       ' suzuki@cacheibm.s.kanazawa-u.ac.jp '
_publ_contact_author_fax         ' +81-76-264-5742 '
_publ_contact_author_name        ' M. Suzuki'
_publ_contact_author_phone       ' +81-76-264-5701 '
_publ_section_title
;
 Synthesis, Structures, and Magnetic Properties of Heterodimetal
 Bis(\m-hydroxo)chromium(III)nickel(II) Complexes with Tpa Derivatives
 Having Sterically Bulky Substituents
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1598
_journal_page_last               1605
_journal_paper_doi               10.1021/ic010568o
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C43 H42.25 Cl3 Cr N8 Ni O16.25'
_chemical_formula_weight         1148.16
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                104.367(8)
_cell_angle_beta                 91.308(9)
_cell_angle_gamma                94.444(8)
_cell_formula_units_Z            2
_cell_length_a                   13.881(1)
_cell_length_b                   14.565(2)
_cell_length_c                   13.379(2)
_cell_measurement_temperature    293.2
_cell_volume                     2610.0(6)
_computing_cell_refinement       P
_computing_data_collection       P
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SHELXS86
_diffrn_measured_fraction_theta_full 0.8558
_diffrn_measured_fraction_theta_max 0.8558
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            8447
_diffrn_reflns_theta_full        25.66
_diffrn_reflns_theta_max         25.66
_exptl_absorpt_coefficient_mu    0.796
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.461
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.84
_refine_diff_density_min         -0.48
_refine_ls_extinction_coef       0.005(2)
_refine_ls_extinction_method     'Zachariasen(1967) type 2 Gaussian isotropic'
_refine_ls_goodness_of_fit_ref   2.140
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     665
_refine_ls_number_reflns         6882
_refine_ls_R_factor_gt           0.0861
_refine_ls_shift/su_max          0.0156
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00240|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1349
_reflns_number_gt                6882
_reflns_number_total             8447
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            ic010568o_1.cif
_cod_data_source_block           DC12-7
_cod_original_cell_volume        2609.9(5)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C43 H42.25 Cl3 Cr N8 O16.25 Ni '
_cod_database_code               4317680