Ethylene in Organic Synthesis. Repetitive Hydrovinylation of Alkenes for Highly Enantioselective Syntheses of Pseudopterosins
Daniel J. Mans; G. Adam Cox; T. V. RajanBabu; Journal of the American Chemical Society 133 (2011) 5776–5779; doi:10.1021/ja201321v

data_4105996
_publ_section_title
;
 Ethylene in Organic Synthesis. Repetitive Hydrovinylation of Alkenes for
 Highly Enantioselective Syntheses of Pseudopterosins
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5776
_journal_page_last               5779
_journal_paper_doi               10.1021/ja201321v
_journal_volume                  133
_journal_year                    2011
_chemical_absolute_configuration syn
_chemical_compound_source        'synthesis as described'
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_cell_measurement_temperature    180(2)
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'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
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_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
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_diffrn_ambient_temperature      180(2)
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_diffrn_orient_matrix_UB_13      -0.124603
_diffrn_orient_matrix_UB_21      -0.155485E-1
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_diffrn_orient_matrix_UB_32      0.40403E-2
_diffrn_orient_matrix_UB_33      0.302996E-1
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.030
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_diffrn_reflns_theta_max         27.45
_diffrn_reflns_theta_min         3.22
_diffrn_source                   'Enraf Nonius FR590'
_exptl_absorpt_coefficient_mu    0.081
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
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_exptl_crystal_description       'rectangular rod'
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_exptl_crystal_size_min          0.19
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_refine_ls_extinction_method     none
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_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0497
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_refine_ls_shift/su_max          0.049
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0542P)^2^+0.1831P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0915
_refine_ls_wR_factor_ref         0.0982
_reflns_number_gt                3069
_reflns_number_total             3625
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja201321v_si_002.cif
_cod_data_source_block           RajanBabu1584
_cod_database_code               4105996