Electrochemical dehydrogenative α-vinylation and α-allylation of cyclic β-ketoesters.
Wu, Hao-Ze; Zhai, Jing-Qi; Sun, Jun-Xi; Liu, Ying-Pin; Tu, Man-Su; Hao, Wen-Juan; Jiang, Bo; Chemical communications (Cambridge, England) 61 (2025) 15187–15190; doi:10.1039/d5cc03082j

data_7134932
_publ_section_title
;
 Electrochemical dehydrogenative &#x3b1;-vinylation and &#x3b1;-allylation
 of cyclic &#x3b2;-ketoesters.
;
_journal_issue                   78
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              15187
_journal_page_last               15190
_journal_paper_doi               10.1039/d5cc03082j
_journal_volume                  61
_journal_year                    2025
_chemical_formula_sum            'C25 H20 O3'
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2025-05-22 deposited with the CCDC.	2025-09-02 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_limit_h_max       11
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_exptl_absorpt_coefficient_mu    0.082
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0801P)^2^+0.2491P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7134932.cif.'
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