Modular Two-Step Approach for the Stereodivergent Synthesis of 1,3-Diamines with Three Continuous Stereocenters.
Halli, Juliette; Bolte, Michael; Bats, Jan; Manolikakes, Georg; Organic letters 19 (2017) 674–677; doi:10.1021/acs.orglett.6b03841

data_1556005
_publ_section_title
;
 Modular Two-Step Approach for the Stereodivergent Synthesis of
 1,3-Diamines with Three Continuous Stereocenters.
;
_journal_issue                   3
_journal_name_full               'Organic letters'
_journal_page_first              674
_journal_page_last               677
_journal_paper_doi               10.1021/acs.orglett.6b03841
_journal_volume                  19
_journal_year                    2017
_chemical_formula_moiety         'C26 H30 N2 O3'
_chemical_formula_sum            'C26 H30 N2 O3'
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_cell_length_c                   13.8674(9)
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_cell_measurement_theta_min      3.16
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_diffrn_ambient_temperature      173(2)
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_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'STOE IPDS II two-circle-diffractometer'
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_diffrn_reflns_theta_min         3.241
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_exptl_absorpt_correction_T_max  1.000
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_exptl_absorpt_process_details   'X-Area (Stoe & Cie, 2001)'
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.090
_refine_ls_R_factor_all          0.0586
_refine_ls_R_factor_gt           0.0455
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0563P)^2^+0.4521P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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