Valorisation of mixtures of linear alkenes using cobalt-mediated isomerisation and hydroformylation chemistries
Martínez-Carrión, Alicia; Romero-Navarro, Andrés; Núñez-Rico, José Luis; Gutiérrez, Albert; Grabulosa, Arnald; Vidal-Ferran, Anton; Catalysis Science & Technology 12 (2022) 3219–3227; doi:10.1039/D1CY01754C

data_1566680
_publ_section_title
;
 Valorisation of mixtures of linear alkenes using cobalt-mediated
 isomerisation and hydroformylation chemistries
;
_journal_issue                   10
_journal_name_full               'Catalysis Science &amp; Technology'
_journal_page_first              3219
_journal_page_last               3227
_journal_paper_doi               10.1039/D1CY01754C
_journal_volume                  12
_journal_year                    2022
_chemical_formula_sum            'C50.5 H47 Co O3 P2'
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_audit_update_record
;
2021-08-08 deposited with the CCDC.	2022-03-22 downloaded from the CCDC.
;
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_computing_molecular_graphics
'shelXle (H\"ubschle, Sheldrick and Dittirch, 2011)'
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_diffrn_measured_fraction_theta_max 0.948
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_diffrn_measurement_method
;
 Fullsphere data collection, phi and omega scans
;
_diffrn_radiation_monochromator  'Confocal Max Flux optic'
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_diffrn_reflns_number            76515
_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_reflns_theta_full        25.242
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_exptl_absorpt_process_details
;
 CrysAlisPro 1.171.40.35a (Rigaku Oxford Diffraction, 2018)
 Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_R_factor_all          0.1079
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0651P)^2^+1.7686P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1233
_refine_ls_wR_factor_ref         0.1468
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_reflns_number_gt                10104
_reflns_number_total             17442
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cy01754c2.cif
_cod_data_source_block           Complex_C1
_cod_depositor_comments
'Adding full bibliography for 1566680--1566681.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C50.50 H47 Co O3 P2'
_cod_database_code               1566680
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              16128