Probing the non-innocent nature of an amino-functionalised β-diketiminate ligand in silylene/iminosilane systems.
Do, Dinh Cao Huan; Vasko, Petra; Fuentes, M Ángeles; Hicks, Jamie; Aldridge, Simon; Dalton transactions (Cambridge, England : 2003) 49 (2020) 8701–8709; doi:10.1039/d0dt01447h

data_7704658
_publ_section_title
;
 Probing the non-innocent nature of an amino-functionalised
 \b-diketiminate ligand in silylene/iminosilane systems.
;
_journal_issue                   25
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               8709
_journal_paper_doi               10.1039/d0dt01447h
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C37 H65 N5 Si3'
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;
2020-04-09 deposited with the CCDC.	2020-06-10 downloaded from the CCDC.
;
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43b (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0433P)^2^+0.8974P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt01447h2.cif
_cod_data_source_block           (2-Dipp)Si(NDipp)(N(SiMe3)2)
_cod_depositor_comments
'Adding full bibliography for 7704658--7704661.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7704658
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              75377