Unusual nucleophilic reactivity of a dithiolene-based N-heterocyclic silane.
Tran, Phuong M.; Wang, Yuzhong; Lahm, Mitchell E.; Wei, Pingrong; Schaefer, 3rd, Henry F; Robinson, Gregory H.; Dalton transactions (Cambridge, England : 2003) 53 (2024) 6178–6183; doi:10.1039/d3dt03843b

data_7715508
_publ_section_title
;
 Unusual nucleophilic reactivity of a dithiolene-based N-heterocyclic
 silane.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6178
_journal_page_last               6183
_journal_paper_doi               10.1039/d3dt03843b
_journal_volume                  53
_journal_year                    2024
_chemical_formula_sum            'C53 H70 B2 I6 N4 S3 Si'
_chemical_formula_weight         1670.42
_space_group_crystal_system      monoclinic
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2024-01-23 deposited with the CCDC.	2024-03-20 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker D8 Quest PHOTON 100 CMOS'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0742P)^2^+159.7453P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7715503--7715508.cif.'
_cod_original_cell_volume        6317.8(8)
_cod_original_sg_symbol_H-M      'P 21/n'
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