Lanthanide metalloligand strategy toward d-f heterometallic metal-organic frameworks: magnetism and symmetric-dependent luminescent properties.
Huang, Xiao-feng; Ma, Jing-xin; Liu, Wei-sheng; Inorganic chemistry 53 (2014) 5922–5930; doi:10.1021/ic403080n

data_4350646
_publ_section_title
;
 Lanthanide metalloligand strategy toward d-f heterometallic metal-organic
 frameworks: magnetism and symmetric-dependent luminescent properties.
;
_journal_issue                   12
_journal_name_full               'Inorganic chemistry'
_journal_page_first              5922
_journal_page_last               5930
_journal_paper_doi               10.1021/ic403080n
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C24 H30 Co3 Er2 O42'
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_cell_length_c                   25.5382(8)
_cell_measurement_temperature    296(2)
_cell_volume                     16656.0(9)
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      296(2)
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_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_av_unetI/netI     0.0098
_diffrn_reflns_Laue_measured_fraction_full 0.927
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_exptl_absorpt_coefficient_mu    5.292
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     58
_refine_ls_number_reflns         756
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0329P)^2^+427.6400P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             756
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ic403080n_si_002.cif
_cod_data_source_block           1c
_cod_original_cell_volume        16656.0(16)
_cod_original_sg_symbol_Hall     '-F 4cvw 2vw 3'
_cod_original_sg_symbol_H-M      'F d -3 c'
_cod_database_code               4350646
_shelx_estimated_absorpt_t_min   0.053
_shelx_estimated_absorpt_t_max   0.071
_shelxl_version_number           2013-4
_shelx_res_checksum              49332
_shelx_hkl_checksum              28507