Dichloro(propane-1,3-diamine-κ^2^<i>N</i>,<i>N</i>')platinum(II), dichloro(propane-1,3-diamine-κ^2^<i>N</i>,<i>N</i>')palladium(II) and μ-4,9-diazadodecane-1,12-diamine-κ^2^<i>N</i>^1^,<i>N</i>^4^:κ^2^<i>N</i>^9^,<i>N</i>^12^-bis[dichloroplatinum(II)]
Odoko, Mamiko; Okabe, Nobuo; Acta Crystallographica Section C 62 (2006) m136–m139; doi:10.1107/S010827010600610X

data_2015265
_publ_section_title
;Dichloro(propane-1,3-diamine-\k^2^<i>N</i>,<i>N</i>')platinum(II),
 dichloro(propane-1,3-diamine-\k^2^<i>N</i>,<i>N</i>')palladium(II) and
 \m-4,9-diazadodecane-1,12-diamine-\k^2^<i>N</i>^1^,<i>N</i>^4^:\k^2^<i>N</i>^9^,<i>N</i>^12^-bis[dichloroplatinum(II)]
;
_journal_coeditor_code           OB1247
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m136
_journal_page_last               m139
_journal_paper_doi               10.1107/S010827010600610X
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          '[Pd Cl2 (C3 H10 N2)]'
_chemical_formula_moiety         'C3 H10 Cl2 N2 Pd'
_chemical_formula_sum            'C3 H10 Cl2 N2 Pd'
_chemical_formula_weight         251.45
_chemical_name_systematic
;
dichloro(propane-1,3-diamine-\k^2^N,N')palladium(II)
;
_space_group_IT_number           57
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2c 2b'
_symmetry_space_group_name_H-M   'P b c m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.386(7)
_cell_length_b                   7.167(5)
_cell_length_c                   12.880(10)
_cell_measurement_reflns_used    5562
_cell_measurement_temperature    296
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      3.2
_cell_volume                     774.1(10)
_computing_cell_refinement       RAPID-AUTO
_computing_data_collection       'RAPID-AUTO (Rigaku Corporation, 1998)'
_computing_data_reduction
'CrystalStructure (Rigaku/MSC, 2005) and CRYSTALS (Watkin <i>et al.</i>, 1996)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material  CrystalStructure
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare <i>et al.</i>,  1999)'
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9962
_diffrn_measured_fraction_theta_max 0.9962
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.022
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            7656
_diffrn_reflns_theta_full        27.45
_diffrn_reflns_theta_max         27.45
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.995
_exptl_absorpt_correction_T_max  0.861
_exptl_absorpt_correction_T_min  0.645
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.158
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             488.00
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.26
_refine_diff_density_min         -0.60
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     41
_refine_ls_number_reflns         923
_refine_ls_R_factor_gt           0.0170
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0243P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0430
_reflns_number_gt                650
_reflns_number_total             923
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ob1247.cif
_cod_data_source_block           II
_cod_database_code               2015265
_cod_database_fobs_code          2015265