Probing the role of secondary versus tertiary amine donor ligands for indium catalysts in lactide polymerization.
Osten, Kimberly M.; Aluthge, Dinesh C.; Patrick, Brian O.; Mehrkhodavandi, Parisa; Inorganic chemistry 53 (2014) 9897–9906; doi:10.1021/ic501529f

data_4340955
_publ_section_title
;
 Probing the role of secondary versus tertiary amine donor ligands for
 indium catalysts in lactide polymerization.
;
_journal_issue                   18
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9897
_journal_page_last               9906
_journal_paper_doi               10.1021/ic501529f
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C62 H99 Cl3 In2 N4 O3'
_chemical_formula_weight         1284.44
_chemical_name_systematic
;
 ?
;
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_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
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_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.994
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_diffrn_reflns_Laue_measured_fraction_max 0.994
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_diffrn_reflns_limit_k_min       -24
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_diffrn_reflns_limit_l_min       -22
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_diffrn_reflns_point_group_measured_fraction_full 0.971
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_exptl_crystal_description       Needle
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_refine_ls_abs_structure_details
;
 Flack x determined using 7731 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   0.02(2)
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.1332P)^2^+30.6661P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2044
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 4340954--4340957.cif.'
_cod_original_cell_volume        6244(2)
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_shelx_estimated_absorpt_t_min   0.602
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_shelx_res_checksum              94336
_shelx_hkl_checksum              67003