From lamellar net to bilayered-lamella and to porous pillared-bilayer: reversible crystal-to-crystal transformation, CO<sub>2</sub> adsorption, and fluorescence detection of Fe<sup>3+</sup>, Al<sup>3+</sup>, Cr<sup>3+</sup>, MnO<sub>4</sub><sup>-</sup>, and Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup> in water.
Zhang, Jia-Rong; Lee, Jey-Jau; Su, Chun-Hao; Tsai, Meng-Jung; Li, Chih-Yu; Wu, Jing-Yun; Dalton transactions (Cambridge, England : 2003) 49 (2020) 14201–14215; doi:10.1039/d0dt02606a

data_7705467
_publ_section_title
;
 From lamellar net to bilayered-lamella and to porous pillared-bilayer:
 reversible crystal-to-crystal transformation, CO<sub>2</sub> adsorption,
 and fluorescence detection of Fe<sup>3+</sup>, Al<sup>3+</sup>,
 Cr<sup>3+</sup>, MnO<sub>4</sub><sup>-</sup>, and
 Cr<sub>2</sub>O<sub>7</sub><sup>2-</sup> in water.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14201
_journal_page_last               14215
_journal_paper_doi               10.1039/d0dt02606a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C41 H30 N6 O11 Zn2'
_chemical_formula_weight         913.45
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-03-19 deposited with the CCDC.	2020-09-21 downloaded from the CCDC.
;
_cell_angle_alpha                90.000(5)
_cell_angle_beta                 101.547(5)
_cell_angle_gamma                90.000(5)
_cell_formula_units_Z            2
_cell_length_a                   19.898(5)
_cell_length_b                   7.618(5)
_cell_length_c                   16.128(5)
_cell_measurement_reflns_used    9948
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      26.38
_cell_measurement_theta_min      3.06
_cell_volume                     2395.3(18)
_computing_cell_refinement       'Bruker D8 Venture'
_computing_data_collection       'Bruker D8 Venture'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SIR92 (Giacovazzo et al, 1993)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Photon 100 CMOS detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0593
_diffrn_reflns_av_unetI/netI     0.0390
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            29909
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.394
_diffrn_reflns_theta_min         2.968
_exptl_absorpt_coefficient_mu    1.059
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.267
_exptl_crystal_description       plate
_exptl_crystal_F_000             932
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.546
_refine_diff_density_min         -0.877
_refine_diff_density_rms         0.199
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     240
_refine_ls_number_reflns         4892
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.113
_refine_ls_R_factor_all          0.1095
_refine_ls_R_factor_gt           0.0911
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1170P)^2^+27.2125P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2483
_refine_ls_wR_factor_ref         0.2654
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4015
_reflns_number_total             4892
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt02606a2.cif
_cod_data_source_block           shelx
_cod_depositor_comments
'Adding full bibliography for 7705466--7705467.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7705467
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              23885