One-pot chemoselective aerobic synthesis of allyl-aryl sulfinyls by photoinduced Na<sub>2</sub> - eosin Y.
Ballanki, Trinadh; Subramanian, Aishwarya; Viswambharan, Baby; Organic & biomolecular chemistry 23 (2025) 4152–4160; doi:10.1039/d5ob00181a

data_7160436
_publ_section_title
;
 One-pot chemoselective aerobic synthesis of allyl-aryl sulfinyls by
 photoinduced Na<sub>2</sub> - eosin Y.
;
_journal_issue                   17
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              4152
_journal_page_last               4160
_journal_paper_doi               10.1039/d5ob00181a
_journal_volume                  23
_journal_year                    2025
_chemical_formula_moiety         'C19 H20 O3 S'
_chemical_formula_sum            'C19 H20 O3 S'
_chemical_formula_weight         328.41
_space_group_crystal_system      monoclinic
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_space_group_name_H-M_alt        'P 1 21/c 1'
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_audit_creation_method           SHELXL-2019/1
_audit_update_record
;
2024-10-08 deposited with the CCDC.	2025-03-20 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_diffrn_ambient_temperature      300(2)
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_diffrn_measured_fraction_theta_max 0.994
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'Bruker D8 QUEST diffractometer with PHOTON II detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_T_min  0.6700
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_exptl_crystal_colour            colourless
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_exptl_crystal_size_min          0.103
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_refine_ls_extinction_method     none
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_refine_ls_restrained_S_all      1.060
_refine_ls_R_factor_all          0.0919
_refine_ls_R_factor_gt           0.0510
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0498P)^2^+0.8540P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1182
_refine_ls_wR_factor_ref         0.1484
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2778
_reflns_number_total             4259
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5ob00181a3.cif
_cod_data_source_block           257_200924_0m_a
_cod_depositor_comments          'Adding full bibliography for 7160436.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7160436
_shelx_shelxl_version_number     2019/1
_shelx_estimated_absorpt_t_min   0.937
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_shelx_res_checksum              9005