Ligand substituents modulate excited-state lifetime and energy-transfer reactivity in Cu(i) photosensitizers supported by salicylaldimine and isocyanide ligands.
Chakraborty, Soumi; Agyekum, Kianna; Kim, Dooyoung; Teets, Thomas S.; Chemical science 16 (2025) 22527–22535; doi:10.1039/d5sc07286g

data_1576084
_publ_section_title
;
 Ligand substituents modulate excited-state lifetime and energy-transfer
 reactivity in Cu(i) photosensitizers supported by salicylaldimine and
 isocyanide ligands.
;
_journal_issue                   47
_journal_name_full               'Chemical science'
_journal_page_first              22527
_journal_page_last               22535
_journal_paper_doi               10.1039/d5sc07286g
_journal_volume                  16
_journal_year                    2025
_chemical_formula_sum            'C25 H25 Cu N2 O'
_chemical_formula_weight         433.01
_space_group_crystal_system      triclinic
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2025-05-23 deposited with the CCDC.	2025-10-17 downloaded from the CCDC.
;
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_exptl_absorpt_coefficient_mu    0.995
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0339P)^2^+0.3229P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           Cu3
_cod_depositor_comments
'Adding full bibliography for 1576081--1576086.cif.'
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