3d-Metal Induced Magnetic Ordering on U(IV) Atoms as a Route toward U(IV) Magnetic Materials.
Klepov, Vladislav V.; Pace, Kristen A.; Calder, Stuart; Felder, Justin B.; Loye, Hans-Conrad Zur; Journal of the American Chemical Society 141 (2019) 3838–3842; doi:10.1021/jacs.9b00345

data_4128524
_publ_section_title
;
 3d-Metal Induced Magnetic Ordering on U(IV) Atoms as a Route toward U(IV)
 Magnetic Materials.
;
_journal_issue                   9
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3838
_journal_page_last               3842
_journal_paper_doi               10.1021/jacs.9b00345
_journal_volume                  141
_journal_year                    2019
_chemical_formula_sum            'Cs2 F16 Mn U3'
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_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0063
_diffrn_reflns_Laue_measured_fraction_full 0.990
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_diffrn_reflns_limit_l_min       -17
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_diffrn_reflns_point_group_measured_fraction_full 0.990
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_diffrn_reflns_theta_max         27.493
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 Reference: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10.
;
_exptl_crystal_colour            green
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_exptl_crystal_description       block
_exptl_crystal_F_000             1110
_exptl_crystal_size_max          0.040
_exptl_crystal_size_mid          0.030
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/1 (Sheldrick 2018)'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0030P)^2^+10.2897P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0277
_refine_ls_wR_factor_ref         0.0277
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_reflns_number_gt                356
_reflns_number_total             356
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja9b00345_si_004.cif
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_cod_database_code               4128524
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