The syntheses and photophysical properties of PNP-based Au(i) complexes with strong intramolecular AuAu interactions.
Kathewad, Neha; Kumar, Nandha; Dasgupta, Rajarshi; Ghosh, Moushakhi; Pal, Shiv; Khan, Shabana; Dalton transactions (Cambridge, England : 2003) 48 (2019) 7274–7280; doi:10.1039/c8dt04471f

data_7048856
_publ_section_title
;
 The syntheses and photophysical properties of PNP-based Au(i) complexes
 with strong intramolecular AuAu interactions.
;
_journal_issue                   21
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7274
_journal_page_last               7280
_journal_paper_doi               10.1039/c8dt04471f
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C32 H29 Au Cl N P2'
_chemical_formula_sum            'C32 H29 Au Cl N P2'
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_H-M   'P -1'
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_audit_update_record
;
2019-01-25 deposited with the CCDC.
2019-02-04 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      150(2)
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_av_unetI/netI     0.0433
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_exptl_absorpt_coefficient_mu    5.485
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_exptl_absorpt_process_details
'Sheldrick,G.M(2012)SADABS.Bruker AXS Inc.,Madison,Wisconsin,USA.'
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.712
_exptl_crystal_description       Block
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_refine_ls_R_factor_all          0.0334
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0144P)^2^+2.7370P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0521
_refine_ls_wR_factor_ref         0.0551
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8775
_reflns_number_total             10140
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt04471f2.cif
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7048855--7048857.cif.
;
_cod_database_code               7048856
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              98646