Gold-catalyzed intermolecular addition of alcohols toward the allenic bond of 4-vinylidene-2-oxazolidinones
Horino, Yoshikazu; Takata, Yasushi; Hashimoto, Ken; Kuroda, Shigeyasu; Kimura, Masanari; Tamaru, Yoshinao; Organic & Biomolecular Chemistry 6 (2008) 4105–4107; doi:10.1039/b808921c

data_7150994
_publ_section_title
;
 Gold-catalyzed intermolecular addition of alcohols toward the allenic
 bond of 4-vinylidene-2-oxazolidinones
;
_journal_issue                   22
_journal_name_full               'Organic &amp; Biomolecular Chemistry'
_journal_page_first              4105
_journal_page_last               4107
_journal_paper_doi               10.1039/b808921c
_journal_volume                  6
_journal_year                    2008
_chemical_formula_moiety         'C16 H19 N O5 S '
_chemical_formula_sum            'C16 H19 N O5 S'
_chemical_formula_weight         337.39
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                83.827(8)
_cell_angle_beta                 80.863(9)
_cell_angle_gamma                79.643(9)
_cell_formula_units_Z            2
_cell_length_a                   7.6397(9)
_cell_length_b                   10.614(1)
_cell_length_c                   10.778(1)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.7
_cell_volume                     846.00(15)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 2.0'
_computing_publication_material  'teXsan Ver. 2.0'
_computing_structure_refinement  'teXsan Ver. 2.0'
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 1.0024
_diffrn_measured_fraction_theta_max 1.0024
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.010
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            5175
_diffrn_reflns_theta_full        30.01
_diffrn_reflns_theta_max         30.01
_diffrn_standards_decay_%        0.43
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.215
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.324
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             356.00
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.250
_refine_diff_density_max         0.26
_refine_diff_density_min         -0.33
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.894
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     208
_refine_ls_number_reflns         2716
_refine_ls_R_factor_gt           0.0502
_refine_ls_shift/su_max          0.0002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1437
_reflns_number_gt                2716
_reflns_number_total             5175
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            b808921c.txt
_cod_data_source_block           horino071225
_cod_original_cell_volume        846.0(2)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C16 H19 N O5 S '
_cod_database_code               7150994