Mixed noble metal-oxo clusters: platinum(IV)-gold(III) oxoanion [Pt<sup>IV</sup><sub>2</sub>Au<sup>III</sup><sub>3</sub>O<sub>6</sub>((CH<sub>3</sub>)<sub>2</sub>AsO<sub>2</sub>)<sub>6</sub>]<sup/>.
Zhang, Jiayao; Bhattacharya, Saurav; Müller, Anja B; Kiss, Levente; Silvestru, Cristian; Kuhnert, Nikolai; Kortz, Ulrich; Chemical communications (Cambridge, England) 59 (2023) 5918–5921; doi:10.1039/d3cc00243h

data_7131565
_publ_section_title
;
 Mixed noble metal-oxo clusters: platinum(IV)-gold(III) oxoanion
 [Pt<sup>IV</sup><sub>2</sub>Au<sup>III</sup><sub>3</sub>O<sub>6</sub>((CH<sub>3</sub>)<sub>2</sub>AsO<sub>2</sub>)<sub>6</sub>]<sup/>.
;
_journal_issue                   39
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              5918
_journal_page_last               5921
_journal_paper_doi               10.1039/d3cc00243h
_journal_volume                  59
_journal_year                    2023
_chemical_formula_sum            'C14 H64 As7 Au3 Cl K3 O31 Pt2'
_chemical_formula_weight         2386.92
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2023-04-07 deposited with the CCDC.	2023-04-13 downloaded from the CCDC.
;
_cell_angle_alpha                75.614(3)
_cell_angle_beta                 66.913(3)
_cell_angle_gamma                85.534(3)
_cell_formula_units_Z            2
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_cell_length_b                   14.1105(16)
_cell_length_c                   16.6726(19)
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_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.790
_cell_measurement_theta_min      2.970
_cell_volume                     2841.1(6)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
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_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0896
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_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
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_diffrn_reflns_limit_l_max       20
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_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.790
_diffrn_reflns_theta_min         2.970
_exptl_absorpt_coefficient_mu    17.013
_exptl_absorpt_correction_T_max  0.762
_exptl_absorpt_correction_T_min  0.494
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Orange
_exptl_crystal_density_diffrn    2.790
_exptl_crystal_description       Block
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_exptl_crystal_size_mid          0.035
_exptl_crystal_size_min          0.016
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_refine_diff_density_rms         0.323
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
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_refine_ls_number_reflns         10846
_refine_ls_number_restraints     33
_refine_ls_restrained_S_all      0.967
_refine_ls_R_factor_all          0.0785
_refine_ls_R_factor_gt           0.0490
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0500P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1077
_refine_ls_wR_factor_ref         0.1212
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7702
_reflns_number_total             10846
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3cc00243h2.cif
_cod_data_source_block           K-1
_cod_depositor_comments
'Adding full bibliography for 7131563--7131565.cif.'
_cod_database_code               7131565
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              56357
_shelx_hkl_checksum              41449
_shelx_fab_checksum              91389