Exploring a novel preparation method of 1D metal organic frameworks based on supercritical CO2.
López-Periago, A; Vallcorba, O.; Frontera, C.; Domingo, C.; Ayllón, J A; Dalton transactions (Cambridge, England : 2003) 44 (2015) 7548–7553; doi:10.1039/c5dt00521c

data_7034322
_publ_section_title
;
 Exploring a novel preparation method of 1D metal organic frameworks based
 on supercritical CO2.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7548
_journal_page_last               7553
_journal_paper_doi               10.1039/c5dt00521c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C20 H10 Cu F12 N2 O4'
_chemical_formula_sum            'C20 H10 Cu F12 N2 O4'
_chemical_formula_weight         633.85
_chemical_name_common
;
copper(II) hexafluoroacetylacetonate bipyridine [Cu(hfacac)2(bpy)]
;
_space_group_crystal_system      tetragonal
_space_group_IT_number           92
_space_group_name_Hall           'P 4abw 2nw'
_space_group_name_H-M_alt        'P 41 21 2'
_symmetry_Int_Tables_number      92
_symmetry_space_group_name_Hall  'P 4abw 2nw'
_symmetry_space_group_name_H-M   'P 41 21 2'
_audit_update_record
;
2015-02-27 deposited with the CCDC.
2015-03-09 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   7.8882(2)
_cell_length_b                   7.8882(2)
_cell_length_c                   38.0767(7)
_cell_measurement_temperature    298
_cell_volume                     2369.27(10)
_computing_data_reduction        'DAJUST (Vallcorba et al., 2012)'
_computing_publication_material  'PLATON (Spek, 2003)'
_computing_structure_refinement  'RIBOLS (Rius, 2012)'
_computing_structure_solution    'TALP (Vallcorba et al., 2012)'
_diffrn_ambient_temperature      298
_diffrn_detector                 MYTHEN-II
_diffrn_radiation_monochromator  'Si (111)'
_diffrn_radiation_type           Synchrotron
_diffrn_radiation_wavelength     0.61978
_exptl_absorpt_coefficient_mu    0.484
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.777
_exptl_crystal_F_000             1252
_pd_char_colour                  green
_pd_instr_location
;
'BL04-MSPD, ALBA Synchrotron Light Source (SPAIN)'
;
_pd_meas_2theta_range_inc        0.006
_pd_meas_2theta_range_max        65.094
_pd_meas_2theta_range_min        1.026
_pd_meas_number_of_points        10679
_pd_proc_2theta_range_inc        0.006
_pd_proc_2theta_range_max        39.996
_pd_proc_2theta_range_min        3.000
_pd_proc_ls_background_function
'linear extrapolation of automatically determined points'
_pd_proc_ls_profile_function     Pseudo-Voigt
_pd_proc_ls_prof_wR_factor       0.056
_pd_proc_number_of_points        6167
_pd_spec_mounting                'glass capillary'
_pd_spec_mount_mode              transmission
_refine_diff_density_max         0.711
_refine_diff_density_min         -0.223
_refine_diff_density_rms         0.154
_refine_ls_goodness_of_fit_all   5.309
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     67
_refine_ls_number_reflns         1082
_refine_ls_number_restraints     64
_refine_ls_R_I_factor            0.028
_refine_ls_shift/su_max          0.090
_refine_ls_shift/su_mean         0.062
_refine_ls_weighting_details     1/Yobs
_refine_ls_weighting_scheme      calc
_cod_data_source_file            c5dt00521c2.cif
_cod_data_source_block           '[Cu(hfacac)2(bpy)]'
_cod_depositor_comments          'Adding full bibliography for 7034322.cif.'
_cod_original_cell_volume        2369.27(13)
_cod_database_code               7034322