Synthesis and Characterization of a Family of Systematically Varied Tris(2-pyridyl)methoxymethane Ligands: Copper(I) and Copper(II) Complexes
Robert T. Jonas; T. D. P. Stack; Inorganic Chemistry 37 (1998) 6615–6629; doi:10.1021/ic9713487

data_4323229
_publ_contact_author
;
T. D. P. Stack
Department of Chemistry
Stanford University
Stanford, CA 94305
;
_publ_contact_author_email       ' STACK@LELAND.STANFORD.EDU '
_publ_contact_author_fax         ' (650) 725-0259 '
_publ_contact_author_phone       ' (650) 725-8736 '
_publ_section_title
;
 Synthesis and Characterization of a Family of Systematically Varied
 Tris(2-pyridyl)methoxymethane Ligands: Copper(I) and Copper(II) Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6615
_journal_page_last               6629
_journal_paper_doi               10.1021/ic9713487
_journal_volume                  37
_journal_year                    1998
_chemical_formula_moiety         'C36 H30 '
_chemical_formula_sum            'C36 H30 Cu F6 N6 O8 S2'
_chemical_formula_weight         462.63
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
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_symmetry_space_group_name_Hall  '-P 1'
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_cell_angle_alpha                73.58(1)
_cell_angle_beta                 68.07(1)
_cell_angle_gamma                86.24(1)
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_cell_length_a                   8.5700
_cell_length_b                   10.3400
_cell_length_c                   11.7900
_cell_measurement_reflns_used    23
_cell_measurement_temperature    476.4
_cell_measurement_theta_max      18.5
_cell_measurement_theta_min      18.0
_cell_volume                     928.69(8)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution
;
SAPI91 (Fan, 1991)
;
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_diffrn_orient_matrix_UB_32      0.02022
_diffrn_orient_matrix_UB_33      -0.09483
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7109
_diffrn_reflns_av_R_equivalents  0.00010
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_diffrn_reflns_limit_h_min       100
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_diffrn_reflns_limit_l_max       -100
_diffrn_reflns_limit_l_min       100
_diffrn_reflns_number            3423
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         24.98
_diffrn_reflns_theta_min         0.00
_diffrn_standards_decay_%        -1.78
_diffrn_standards_interval_count 200
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.047
_exptl_absorpt_correction_T_max  0.998
_exptl_absorpt_correction_T_min  0.921
_exptl_absorpt_correction_type   psi-scans
_exptl_crystal_colour            blue
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_exptl_crystal_density_meas      ?
_exptl_crystal_description       block
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_refine_diff_density_max         0.58
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_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   4.530
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     268
_refine_ls_number_reflns         2889
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           0.0380
_refine_ls_shift/su_max          0.0200
_refine_ls_shift/su_mean         0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00002|Fo|^2^]'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0490
_reflns_number_gt                2889
_reflns_number_total             3249
_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            ic9713487_08.cif
_cod_data_source_block           '__[(L0)2Cu](OTf)2'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        928.69(6)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C36 H30 '
_cod_database_code               4323229