Reducing hybrid ligand-based alane and chasing aluminium(I): dialane and unusual transient dialumene.
Wang, Xiaobai; Ligorio, Raphael F.; Rüttger, Franziska; Krengel, David M. J.; Graw, Nico; Herbst-Irmer, Regine; Krawczuk, Anna; Stalke, Dietmar; Dalton transactions (Cambridge, England : 2003) 53 (2024) 15441–15450; doi:10.1039/d4dt01798f

data_7716776
_publ_section_title
;
 Reducing hybrid ligand-based alane and chasing aluminium(I): dialane and
 unusual transient dialumene.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15441
_journal_page_last               15450
_journal_paper_doi               10.1039/d4dt01798f
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         'C75 H93 Al2 N6 Na, 2(C6 H14)'
_chemical_formula_sum            'C87 H121 Al2 N6 Na'
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_audit_update_record
;
2023-12-12 deposited with the CCDC.	2024-07-29 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker Smart APEX II Quazar'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_theta_full        25.242
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.014
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_refine_ls_number_reflns         29029
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_refine_ls_restrained_S_all      1.289
_refine_ls_R_factor_all          0.1011
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0509P)^2^+4.2791P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1169
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                18841
_reflns_number_total             29029
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           Al
_cod_depositor_comments
'Adding full bibliography for 7716775--7716778.cif.'
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