<i>catena</i>-Poly[[bis[4-(dimethylamino)pyridine-κ<i>N</i>^1^]cobalt(II)]-di-μ-azido-κ^4^<i>N</i>^1^:<i>N</i>^3^]
Guenifa, Fatiha; Zeghouan, Ouahida; Hadjadj, Nasreddine; Bendjeddou, Lamia; Merazig, Hocine; Acta Crystallographica Section E 69 (2013) m175–; doi:10.1107/S1600536813005205

data_2237573
_publ_section_title
;
 <i>catena</i>-Poly[[bis[4-(dimethylamino)pyridine-\k<i>N</i>^1^]cobalt(II)]-di-\m-azido-\k^4^<i>N</i>^1^:<i>N</i>^3^]
;
_journal_coeditor_code           VM2189
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m175
_journal_paper_doi               10.1107/S1600536813005205
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          '[Co (N3)2 (C7 H10 N2)2]'
_chemical_formula_moiety         'C14 H20 Co N10'
_chemical_formula_structural     'C14 H20 Co N10'
_chemical_formula_sum            'C14 H20 Co N10'
_chemical_formula_weight         387.33
_chemical_name_systematic
<i>catena</i>-Poly[[bis[4-(dimethylamino)pyridine-\k<i>N</i>^1^]cobalt(II)]-di-\m-azido-\k^4^<i>N</i>^1^,<i>N</i>^3^]
_space_group_IT_number           63
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-C 2c 2'
_symmetry_space_group_name_H-M   'C m c m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.622(5)
_cell_length_b                   18.404(5)
_cell_length_c                   9.734(5)
_cell_measurement_reflns_used    1393
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30.04
_cell_measurement_theta_min      3.05
_cell_volume                     1723.7(13)
_computing_cell_refinement       'SAINT (Bruker, 2006)'
_computing_data_collection       'APEX2 (Bruker, 2006)'
_computing_data_reduction        'SAINT (Bruker, 2006)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 2012)'
_computing_publication_material
;
WinGX (Farrugia, 2012),
Mercury (Macrae <i>et al.</i>, 2006) and <i>POVRay</i>
(Persistence of Vision Team, 2004)
;
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR2002 (Burla <i>et al.</i>, 2003)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.99
_diffrn_measured_fraction_theta_max 0.99
_diffrn_measurement_device       'Bruker APEXII'
_diffrn_measurement_method       \f
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0312
_diffrn_reflns_av_sigmaI/netI    0.033
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            5192
_diffrn_reflns_theta_full        30.04
_diffrn_reflns_theta_max         30.04
_diffrn_reflns_theta_min         3.05
_exptl_absorpt_coefficient_mu    1.016
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            ' pink'
_exptl_crystal_density_diffrn    1.493
_exptl_crystal_density_method    'Not Measured'
_exptl_crystal_description       ' needle'
_exptl_crystal_F_000             804
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.427
_refine_diff_density_min         -0.372
_refine_ls_extinction_method     ' none'
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     79
_refine_ls_number_reflns         1393
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.073
_refine_ls_R_factor_all          0.0479
_refine_ls_R_factor_gt           0.032
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0383P)^2^+1.0521P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.077
_refine_ls_wR_factor_ref         0.0862
_reflns_number_gt                1099
_reflns_number_total             1393
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            vm2189.cif
_cod_data_source_block           I
_cod_database_code               2237573
_cod_database_fobs_code          2237573