Synthesis and Reactivity of a Bis(disulfide)-Bridged RuMo3S4 Double-Cubane Cluster: A New Family of Nona- or Decanuclear Mixed-Metal Sulfide Clusters with Two RuMo3S4 Units
Izuru Takei; Koji Kobayashi; Keita Dohki; Masanobu Hidai; Inorganic Chemistry 46 (2007) 1045–1047; doi:10.1021/ic0621953

data_4307700
_publ_section_title
;
Synthesis and Reactivity of a Bis(disulfide)-Bridged RuMo3S4 Double-Cubane
Cluster: A New Family of Nona- or Decanuclear Mixed-Metal Sulfide
Clusters with Two RuMo3S4 Units
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1045
_journal_page_last               1047
_journal_paper_doi               10.1021/ic0621953
_journal_volume                  46
_journal_year                    2007
_chemical_formula_moiety         'C82 H116 Cl8 F12 Mo6 P3 Pd Ru2 S11 '
_chemical_formula_sum            'C82 H116 Cl8 F12 Mo6 P3 Pd Ru2 S11'
_chemical_formula_weight         2943.18
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                95.954(2)
_cell_angle_beta                 100.126(3)
_cell_angle_gamma                97.109(2)
_cell_formula_units_Z            2
_cell_length_a                   11.4628(7)
_cell_length_b                   18.1960(9)
_cell_length_c                   26.855(2)
_cell_measurement_reflns_used    9894
_cell_measurement_temperature    293.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     5426.4(6)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.6.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.4997
_diffrn_measured_fraction_theta_max 0.4997
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       w
_diffrn_radiation_type           'Mo Ka'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.033
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            40016
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_exptl_absorpt_coefficient_mu    1.612
_exptl_absorpt_correction_T_max  0.724
_exptl_absorpt_correction_T_min  0.524
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            'dark brown'
_exptl_crystal_density_diffrn    1.801
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2918.00
_exptl_crystal_size_max          0.80
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.28
_refine_diff_density_min         -0.95
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     1070
_refine_ls_number_reflns         12093
_refine_ls_R_factor_gt           0.0680
_refine_ls_shift/su_max          0.0070
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details
'w = 1/[0.0010Fo^2^ + 1.5000sigma(Fo^2^) + 0.1500]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0840
_reflns_number_gt                10291
_reflns_number_total             23850
_reflns_threshold_expression     F^2^>2.0sigma(F^2^)
_cod_data_source_file            ic0621953si20061117_025250.cif
_cod_data_source_block           '__clust3'
_cod_original_cell_volume        5426.3(5)
_cod_original_formula_sum        'C82 H116 Cl8 F12 Mo6 P3 Pd Ru2 S11 '
_cod_database_code               4307700