Synthesis and reactivity of ruthenium(II) complexes containing hemilabile phosphine‒thiophene ligands
Clot, Olivier; Wolf, Michael O.; Yap, Glenn P. A.; Patrick, Brian O.; Journal of the Chemical Society, Dalton Transactions  (2000) 2729–; doi:10.1039/b001898h

data_7009560
_publ_section_title
;
 Synthesis and reactivity of ruthenium(II) complexes containing
 hemilabile phosphine--thiophene ligands
;
_journal_issue                   16
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2729
_journal_paper_doi               10.1039/b001898h
_journal_year                    2000
_chemical_formula_sum            'C52 H45 Cl8 P3 Ru S3'
_chemical_formula_weight         1243.72
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             1999-08-18
_audit_creation_method           'by teXsan v1.8'
_audit_update_record
;
?
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.7595(6)
_cell_length_b                   15.5059(5)
_cell_length_c                   22.323(1)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    173.2
_cell_measurement_theta_max      0.0
_cell_measurement_theta_min      0.0
_cell_volume                     5444.8(4)
_computing_cell_refinement       'd*TREK (MSC, 1996-1998)'
_computing_data_collection       'd*TREK (MSC, 1996-1998)'
_computing_data_reduction        'd*TREK (MSC, 1996-1998)'
_computing_publication_material  'teXsan (MSC, 1992-1997)'
_computing_structure_refinement  'teXsan (MSC, 1992-1997)'
_computing_structure_solution
;
SIR97 (Altomare, et. al. 1998)
;
_diffrn_ambient_temperature      173.2
_diffrn_detector_area_resol_mean 11.76
_diffrn_measurement_device_type  'Rigaku/ADSC CCD'
_diffrn_measurement_method       'area detector'
_diffrn_orient_matrix_UB_11      0.00000
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_diffrn_orient_matrix_UB_32      0.00000
_diffrn_orient_matrix_UB_33      0.00000
_diffrn_radiation_detector       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.04582
_diffrn_reflns_av_sigmaI/netI    0.080
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            46513
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         27.85
_diffrn_reflns_theta_min         2.90
_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 0
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_exptl_absorpt_correction_T_min  1.000
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_exptl_crystal_colour            red
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_exptl_crystal_size_max          0.40
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_refine_diff_density_max         2.32
_refine_diff_density_min         -1.12
_refine_ls_extinction_method     none
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_refine_ls_goodness_of_fit_ref   1.855
_refine_ls_hydrogen_treatment    noref
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_refine_ls_R_factor_all          0.0763
_refine_ls_shift/su_max          0.0746
_refine_ls_shift/su_mean         0.1640
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo^2^)]'
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_reflns_threshold_expression     I>0.00\s(I)
_cod_data_source_file            b001898h.txt
_cod_data_source_block           '[RuCl2(dppm)(dppterth)]'
_cod_original_cell_volume        5444.8(3)
_cod_original_sg_symbol_H-M      'P 21/n     '
_cod_original_formula_sum        'C52 H45 Cl8 P3 S3 Ru '
_cod_database_code               7009560