Synthesis and crystal structures of boryl <i>ortho</i>-silylaryl tri-fluoro-methane-sulfonates.
Barnå, Fredrik; Hribersek, Matic; Orthaber, Andreas; Pilarski, Lukasz T.; Acta crystallographica. Section E, Crystallographic communications 80 (2024) 143–147; doi:10.1107/S2056989024000264

data_2023009
_publ_section_title
;
 Synthesis and crystal structures of boryl <i>ortho</i>-silylaryl
 tri-fluoro-methane-sulfonates.
;
_journal_coeditor_code           DJ2074
_journal_issue                   'Pt 2'
_journal_name_full
'Acta crystallographica. Section E, Crystallographic communications'
_journal_page_first              143
_journal_page_last               147
_journal_paper_doi               10.1107/S2056989024000264
_journal_volume                  80
_journal_year                    2024
_chemical_formula_iupac          'C17 H26 B F3 O5 S Si'
_chemical_formula_moiety         'C17 H26 B F3 O5 S Si'
_chemical_formula_sum            'C17 H26 B F3 O5 S Si'
_chemical_formula_weight         438.34
_chemical_name_systematic
'2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6-(trimethylsilyl)phenyl trifluoromethanesulfonate'
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
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Olex2 1.5
(compiled 2023.08.24 svn.re1ec1418 for OlexSys, GUI svn.r6817)
;
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SAINT v8.34A (Bruker, 2013)
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APEX2 (Bruker, 2013)
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SAINT v8.34A (Bruker, 2013)
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Olex2 1.5 (Dolomanov <i>et al.</i>,  2009)
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Olex2 1.5 (Dolomanov <i>et al.</i>,  2009)
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<i>SHELXL2018/3</i> (Sheldrick, 2015b)
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<i>SHELXT2014/4</i> (Sheldrick, 2015a)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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;
(SADABS; Krause <i>et al.</i>,  2015)
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0509P)^2^+12.3091P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 2023007--2023009.cif.'
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