Facile C-N coupling of coordinated ammonia and labile carbonyl or acetonitrile promoted by a thiolate-bridged dicobalt reaction scaffold.
Li, Jianzhe; Yang, Dawei; Tong, Peng; Wang, Baomin; Qu, Jingping; Dalton transactions (Cambridge, England : 2003) 49 (2020) 11260–11267; doi:10.1039/d0dt02133d

data_7704856
_publ_section_title
;
 Facile C-N coupling of coordinated ammonia and labile carbonyl or
 acetonitrile promoted by a thiolate-bridged dicobalt reaction scaffold.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11260
_journal_page_last               11267
_journal_paper_doi               10.1039/d0dt02133d
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C26 H45 B0 Co2 F6 N2 P S2'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-07-10 deposited with the CCDC.	2020-07-15 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'CCD area detector'
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_exptl_absorpt_correction_type   empirical
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_refine_ls_matrix_type           full
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0567P)^2^+6.0928P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1110
_refine_ls_wR_factor_ref         0.1138
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_reflns_number_total             5508
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt02133d2.cif
_cod_data_source_block           1_CCDC3
_cod_depositor_comments
'Adding full bibliography for 7704853--7704856.cif.'
_cod_original_cell_volume        3128.9(13)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7704856
_shelx_shelxl_version_number     2014/7
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