A dimer-to-dimer metal‒metal linear aggregate from a (µ-1,3-NO3)2 double-bridged cis-(2,2'-bipyridine)palladium(ii) cofacial dimer
Yu, Shu-Yan; Fujita, Makoto; Yamaguchi, Kentaro; Journal of the Chemical Society, Dalton Transactions  (2001) 3415–; doi:10.1039/b108470b

data_7011173
_publ_section_title
;
 A dimer-to-dimer metal--metal linear aggregate from a
 (&#x00B5;-1,3-NO3)2 double-bridged cis-(2,2'-bipyridine)palladium(ii)
 cofacial dimer
;
_journal_issue                   23
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              3415
_journal_paper_doi               10.1039/b108470b
_journal_year                    2001
_chemical_formula_sum            'C24 H26 F6 N9 O11 P Pd2'
_chemical_formula_weight         974.29
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                113.32(6)
_cell_angle_beta                 97.29(4)
_cell_angle_gamma                69.43(3)
_cell_formula_units_Z            2
_cell_length_a                   13.18(1)
_cell_length_b                   13.64(1)
_cell_length_c                   11.68(1)
_cell_measurement_reflns_used    3
_cell_measurement_temperature    110.2
_cell_measurement_theta_max      14.0
_cell_volume                     1805(3)
_computing_cell_refinement       PROCESS
_computing_data_collection       PROCESS
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SAPI91
_diffrn_detector_area_resol_mean 0.010000
_diffrn_measured_fraction_theta_full 0.7413
_diffrn_measured_fraction_theta_max 0.7413
_diffrn_measurement_device_type  'Rigaku RAXIS-II Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            5388
_diffrn_reflns_theta_full        26.33
_diffrn_reflns_theta_max         26.33
_exptl_absorpt_coefficient_mu    1.137
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.792
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.150
_refine_diff_density_max         1.30
_refine_diff_density_min         -1.29
_refine_ls_extinction_coef       0.017(2)
_refine_ls_extinction_method     'Zachariasen(1967) type 2 Gaussian isotropic'
_refine_ls_goodness_of_fit_ref   2.880
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     479
_refine_ls_number_reflns         4415
_refine_ls_R_factor_gt           0.0717
_refine_ls_shift/su_max          2.5443
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00051|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0919
_reflns_number_gt                4415
_reflns_number_total             5388
_reflns_threshold_expression     F^2^>4.0\s(F^2^)
_cod_data_source_file            b108470b.txt
_cod_data_source_block           Dimer_2
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C24 H26 F6 N9 O11 P Pd2 '
_cod_database_code               7011173