A new heteroleptic cuprous polymer constructed by a cyanopyridine ligand exhibiting a supramolecular framework structure and luminescence
Kong, Yu-Jie; Wang, Jian-Teng; Song, Li; Acta Crystallographica Section C 78 (2022) –; doi:10.1107/S2053229622009809

data_2022688
_publ_section_title
;
 A new heteroleptic cuprous polymer constructed by a cyanopyridine ligand
 exhibiting a supramolecular framework structure and luminescence
;
_journal_coeditor_code           OV3163
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229622009809
_journal_volume                  78
_journal_year                    2022
_chemical_formula_iupac
'[Cu (C6 H4 N2) (C39 H32 O P2)] P F6, 3C H2 Cl2'
_chemical_formula_moiety         'C45 H36 Cu N2 O P2 +, F6 P -, 3(C H2 Cl2)'
_chemical_formula_sum            'C48 H42 Cl6 Cu F6 N2 O P3'
_chemical_formula_weight         1145.98
_chemical_name_systematic
'<i>catena</i>-Poly[[[(9,9-dimethyl-9<i>H</i>-xanthene-4,5-diyl)bis(diphenylphosphane)-\k^2^<i>P</i>,<i>P</i>'](pyridine-3-carbonitrile-\k<i>N</i>^3^)copper(I)] hexafluorophosphate dichloromethane trisolvate]'
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
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Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6392)
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CrysAlis PRO (Agilent, 2011)
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CrysAlis PRO (Agilent, 2011)
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CrysAlis PRO (Agilent, 2011)
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OLEX2 (Dolomanov <i>et al.</i>, 2009)
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OLEX2 (Dolomanov <i>et al.</i>, 2009)
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SHELXL2018 (Sheldrick, 2015)
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SHELXS (Sheldrick, 2008)
;
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;
(CrysAlis PRO; Agilent, 2011)
;
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'w=1/[\s^2^(Fo^2^)+(0.0634P)^2^+0.8921P] where P=(Fo^2^+2Fc^2^)/3'
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