Synthesis, characterization and structural investigation of new rhenium-oxo complexes containing bidentate phosphine ligands: an exploration of chirality and conformation in chelate rings of small and large bite angle ligands
Parr, Maria L.; Perez-Acosta, Carmen; Faller, J. W.; New Journal of Chemistry 29 (2005) 613–; doi:10.1039/b412818d

data_7050043
_publ_section_title
;
 Synthesis, characterization and structural investigation of new
 rhenium-oxo complexes containing bidentate phosphine ligands: an
 exploration of chirality and conformation in chelate rings of small
 and large bite angle ligands
;
_journal_issue                   4
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              613
_journal_paper_doi               10.1039/b412818d
_journal_volume                  29
_journal_year                    2005
_chemical_formula_moiety         'C39 H32 Cl3 O2 P2 Re '
_chemical_formula_sum            'C39 H32 Cl3 O2 P2 Re'
_chemical_formula_weight         887.19
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_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
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;
?
;
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_cell_angle_beta                 90
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_cell_length_a                   17.2122(2)
_cell_length_b                   14.1969(2)
_cell_length_c                   28.0146(5)
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_cell_measurement_temperature    183.2
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_computing_cell_refinement       Denzo-SMN
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_computing_publication_material  'teXsan for Windows v. 1.06 (MSC 1999)'
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;
SIR92 (Altomare, et. al. 1994)
;
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_diffrn_measurement_device       'Nonius Kappa CCD'
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_diffrn_reflns_reduction_process 'Lp corrections applied'
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;
multi-scan from symmetry-related measurements (Blessing 1995)
SORTAV  R.H Blessing,  Acta Cryst., A51, 33-37 (1995),
J. Appl. Cryst., 30, 421-426 (1997).
;
_exptl_crystal_colour            green
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00002|Fo|^2^]'
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_reflns_threshold_expression     I>2.00\s(I)
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_cod_data_source_block           2325ReXant
_cod_original_cell_volume        6845.6(2)
_cod_original_sg_symbol_H-M      'P b c a    '
_cod_original_formula_sum        'C39 H32 Cl3 O2 P2 Re '
_cod_database_code               7050043