Radical Mechanisms in the Reaction of Organic Halides with Diiminepyridine Cobalt Complexes
Zhu, Di; Korobkov, Ilia; Budzelaar, Peter H. M.; Organometallics 31 (2012) 3958–; doi:10.1021/om300182c

data_4078270
_publ_section_title
;
 Radical Mechanisms in the Reaction of Organic Halides with
 Diiminepyridine Cobalt Complexes
;
_journal_issue                   10
_journal_name_full               Organometallics
_journal_page_first              3958
_journal_paper_doi               10.1021/om300182c
_journal_volume                  31
_journal_year                    2012
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C37 H53 Co I2 N3'
_chemical_formula_sum            'C37 H53 Co I2 N3'
_chemical_formula_weight         852.55
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           19
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_cell_measurement_theta_min      2.29
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_diffrn_ambient_temperature      200(2)
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_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            71802
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_diffrn_reflns_theta_max         28.34
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_exptl_absorpt_correction_T_max  0.7351
_exptl_absorpt_correction_T_min  0.6178
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker (2003)'
_exptl_crystal_colour            purple
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_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1716
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0648P)^2^+1.0841P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                8231
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_cod_data_source_file            om300182c_si_001.cif
_cod_data_source_block           sg173
_cod_depositor_comments
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The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'n/a' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_database_code               4078270