A dinuclear Ru(ii) complex capable of photoinduced ligand exchange at both metal centers.
Albani, B. A.; Peña, B; Saha, S.; White, J. K.; Schaeffer, A. M.; Dunbar, K. R.; Turro, C.; Chemical communications (Cambridge, England) 51 (2015) 16522–16525; doi:10.1039/c5cc04913j

data_7118046
_publ_section_title
;
 A dinuclear Ru(ii) complex capable of photoinduced ligand exchange at
 both metal centers.
;
_journal_issue                   92
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              16522
_journal_page_last               16525
_journal_paper_doi               10.1039/c5cc04913j
_journal_volume                  51
_journal_year                    2015
_chemical_formula_sum            'C38 H37 F24 N13 P4 Ru2'
_chemical_formula_weight         1457.82
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-05-08 deposited with the CCDC.
2015-09-18 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 109.970(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.831(3)
_cell_length_b                   16.614(3)
_cell_length_c                   21.526(4)
_cell_measurement_temperature    110(2)
_cell_volume                     5321.3(17)
_computing_cell_refinement       'Bruker APEXII v2013.10-0'
_computing_data_collection       'Bruker APEXII v2013.10-0'
_computing_data_reduction        'Bruker APEXII v2013.10-0'
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_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'profile data from \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0569
_diffrn_reflns_av_unetI/netI     0.0465
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            61008
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.548
_diffrn_reflns_theta_min         1.586
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.817
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6718
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS v2.03 (Bruker, 2003)'
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.820
_exptl_crystal_description       needle
_exptl_crystal_F_000             2880
_exptl_crystal_size_max          0.387
_exptl_crystal_size_mid          0.078
_exptl_crystal_size_min          0.077
_refine_diff_density_max         2.178
_refine_diff_density_min         -1.342
_refine_diff_density_rms         0.122
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     711
_refine_ls_number_reflns         12228
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0712
_refine_ls_R_factor_gt           0.0526
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0579P)^2^+21.2189P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1263
_refine_ls_wR_factor_ref         0.1385
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9619
_reflns_number_total             12228
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5cc04913j2.cif
_cod_data_source_block           p21_n
_cod_original_cell_volume        5321.1(17)
_cod_database_code               7118046
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.743
_shelx_estimated_absorpt_t_max   0.940
_shelx_res_checksum              37997