Dipalladium complexes with bridging diorganosilyl ligands. Synthesis, structure, and properties of [LPd(μ-SiH(R)Ph)]2 (R = Ph or Me; L = PMe3, PEt3 or PMePh2)
Kim, Yong-Joo; Lee, Sang-Chul; Park, Jong-Il; Osakada, Kohtaro; Choi, Jun-Chul; Yamamoto, Takakazu; Journal of the Chemical Society, Dalton Transactions  (2000) 417–; doi:10.1039/a907745f

data_7008981
_publ_section_title
;
 Dipalladium complexes with bridging diorganosilyl ligands. Synthesis,
 structure, and properties of [LPd(\m-SiH(R)Ph)]2 (R&#x2005;=&#x2005;Ph
 or Me; L&#x2005;=&#x2005;PMe3, PEt3 or PMePh2)
;
_journal_issue                   3
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              417
_journal_paper_doi               10.1039/a907745f
_journal_year                    2000
_chemical_formula_sum            'C20 H36 P2 Pd2 Si2'
_chemical_formula_weight         607.46
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 108.58(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   8.419(4)
_cell_length_b                   16.222(4)
_cell_length_c                   10.240(4)
_cell_measurement_reflns_used    20
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      16.7
_cell_measurement_theta_min      13.7
_cell_volume                     1325.6(9)
_diffrn_ambient_temperature      296.2
_diffrn_measurement_device       'Rigaku AFC5R'
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      0.03509
_diffrn_orient_matrix_UB_12      0.05090
_diffrn_orient_matrix_UB_13      0.05700
_diffrn_orient_matrix_UB_21      0.11974
_diffrn_orient_matrix_UB_22      -0.01779
_diffrn_orient_matrix_UB_23      0.02551
_diffrn_orient_matrix_UB_31      0.01151
_diffrn_orient_matrix_UB_32      0.02988
_diffrn_orient_matrix_UB_33      -0.08193
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            3319
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.56
_exptl_absorpt_coefficient_mu    1.572
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.856
_exptl_absorpt_correction_type
;
\y scans (North,Phillips & Matthews, 1968)
;
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.522
_exptl_crystal_density_meas      ?
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             616.00
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.2
_refine_diff_density_max         0.6165
_refine_diff_density_min         -0.6323
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     118
_refine_ls_number_reflns         2114
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           0.0330
_refine_ls_shift/su_max          0.0280
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     unit
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_reflns_number_gt                2114
_reflns_number_total             3152
_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            a907745f.txt
_cod_data_source_block           form2
_cod_original_cell_volume        1325.7(9)
_cod_original_sg_symbol_H-M      'P 21/n     '
_cod_original_formula_sum        'C20 H36 P2 Pd2 Si2 '
_cod_database_code               7008981