Sequential Pd-Catalyzed Asymmetric Allene Diboration/α-Aminoallylation
Joshua D. Sieber; James P. Morken; Journal of the American Chemical Society 128 (2006) 74–75; doi:10.1021/ja057020r

data_4110348
_publ_section_title
;
 Sequential Pd-Catalyzed Asymmetric Allene Diboration/\a-Aminoallylation
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              74
_journal_page_last               75
_journal_paper_doi               10.1021/ja057020r
_journal_volume                  128
_journal_year                    2006
_chemical_formula_moiety         'C22 H28 B N O2 '
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_cell_angle_gamma                90.0
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_cell_length_c                   8.4376(6)
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_cell_measurement_temperature    173
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_diffrn_measurement_device       'Bruker SMART 1K'
_diffrn_measurement_method       Omegas
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_diffrn_reflns_av_R_equivalents  0.037
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_diffrn_reflns_limit_k_max       22
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_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         0.00
_exptl_absorpt_coefficient_mu    0.073
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.166
_exptl_crystal_description       needle
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_exptl_crystal_size_min          0.02
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_refine_diff_density_min         -0.31
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_refine_ls_R_factor_all          0.161
_refine_ls_R_factor_gt           0.071
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     1/(\s^2^(F)+0.0004F^2^)
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'Inet > 2.5\s(Inet)'
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_cod_data_source_block           c05203
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C22 H28 B N O2 '
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