Rhodium(I) Complexes of the Conformationally Rigid IBioxMe4 Ligand: Isolation of a Stable Low-Coordinate T-Shaped Complex
Chaplin, Adrian B.; Organometallics 33 (2014) 624–; doi:10.1021/om401223w

data_4089653
_publ_section_title
;
 Rhodium(I) Complexes of the Conformationally Rigid IBioxMe4 Ligand:
 Isolation of a Stable Low-Coordinate T-Shaped Complex
;
_journal_issue                   3
_journal_name_full               Organometallics
_journal_page_first              624
_journal_paper_doi               10.1021/om401223w
_journal_volume                  33
_journal_year                    2014
_chemical_formula_moiety
'C33 H48 N6 O6 Rh, C32 H12 B F24, 0.5(C H2 Cl2)'
_chemical_formula_sum            'C65.5 H61 B Cl F24 N6 O6 Rh'
_chemical_formula_weight         1633.37
_chemical_melting_point          ?
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2013-10-28
_audit_creation_method
;
  Olex2 1.2
  (compiled 2013.03.22 svn.r2654, GUI svn.r4446)
;
_cell_angle_alpha                99.6629(16)
_cell_angle_beta                 91.5109(16)
_cell_angle_gamma                107.2813(19)
_cell_formula_units_Z            4
_cell_length_a                   14.6083(3)
_cell_length_b                   18.2307(4)
_cell_length_c                   28.3089(5)
_cell_measurement_reflns_used    37230
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      31.8426
_cell_measurement_theta_min      2.8980
_cell_volume                     7073.4(3)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.21 (release 14-08-2012 CrysAlis171 .NET)
(compiled Sep 14 2012,17:21:16)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.21 (release 14-08-2012 CrysAlis171 .NET)
(compiled Sep 14 2012,17:21:16)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.21 (release 14-08-2012 CrysAlis171 .NET)
(compiled Sep 14 2012,17:21:16)
;
_computing_molecular_graphics
;
Ortep-3 for Windows: L. J. Farrugia, J. Appl. Cryst (1997), 30, 565.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement
;
SHELX, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution
;
SHELX, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 10.2833
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_details
;
  1 omega  -55.00   44.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718  -57.0000    0.0000 99

  2 omega   35.00  101.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718  178.0000  -60.0000 66

  3 omega   39.00   65.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718  178.0000   30.0000 26

  4 omega    5.00   93.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718   38.0000  150.0000 88

  5 omega   46.00   80.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718  178.0000  -90.0000 34

  6 omega  -16.00   10.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718   77.0000 -120.0000 26

  7 omega   45.00   81.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718   77.0000 -120.0000 36

  8 omega  -20.00    6.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.4093  -99.0000   90.0000 26

  9 omega  -25.00   20.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.4093  -99.0000  -90.0000 45

 10 omega  -12.00   91.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718   57.0000   30.0000 103

 11 omega  -25.00   42.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718  -99.0000 -120.0000 67

 12 omega   35.00  107.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718  178.0000 -150.0000 72

 13 omega   -9.00   83.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       17.4718   38.0000  150.0000 92
;
_diffrn_measurement_device_type  'Oxford Diffraction: Xcalibur, Ruby, Gemini'
_diffrn_measurement_method       '\w scans'
_diffrn_orient_matrix_UB_11      -0.0030833000
_diffrn_orient_matrix_UB_12      0.0202673000
_diffrn_orient_matrix_UB_13      0.0232955000
_diffrn_orient_matrix_UB_21      -0.0239789000
_diffrn_orient_matrix_UB_22      0.0228791000
_diffrn_orient_matrix_UB_23      -0.0102579000
_diffrn_orient_matrix_UB_31      -0.0449258000
_diffrn_orient_matrix_UB_32      -0.0280047000
_diffrn_orient_matrix_UB_33      0.0015312000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0543
_diffrn_reflns_av_unetI/netI     0.0507
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            151329
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        29.575
_diffrn_reflns_theta_max         29.575
_diffrn_reflns_theta_min         2.930
_diffrn_source                   'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.397
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.83521
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.21 (release 14-08-2012 CrysAlis171 .NET)
(compiled Sep 14 2012,17:21:16)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.534
_exptl_crystal_density_meas      ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3308
_exptl_crystal_recrystallization_method
'Crystals grown from CH2Cl2-Heptane at 293 K'
_exptl_crystal_size_max          0.9
_exptl_crystal_size_mid          0.5
_exptl_crystal_size_min          0.5
_refine_diff_density_max         1.005
_refine_diff_density_min         -0.850
_refine_diff_density_rms         0.081
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     2194
_refine_ls_number_reflns         39653
_refine_ls_number_restraints     1122
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0683
_refine_ls_R_factor_gt           0.0507
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0596P)^2^+4.6995P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1213
_refine_ls_wR_factor_ref         0.1307
_reflns_Friedel_coverage         0.000
_reflns_number_gt                31130
_reflns_number_total             39653
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            om401223w_si_002.cif
_cod_data_source_block           0019abc13
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_chemical_melting_point' value 'not measured' was changed
to '?' -- the value is undefined or not given.

data item '_exptl_crystal_density_meas' value 'not measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_formula_sum        'C65.50 H61 B Cl F24 N6 O6 Rh'
_cod_database_code               4089653
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 O39A-C38C \\sim O39A-C38A
 with sigma of 0.01
 C38C-C37A \\sim C37A-C38A
 with sigma of 0.01
 C37A-C43A \\sim C43C-C37A \\sim C37A-C44A \\sim C44C-C37A
 with sigma of 0.01
 C38C-C43C \\sim C38C-C44C \\sim C38A-C43A \\sim C38A-C44A
 with sigma of 0.01
 C43A-C44A \\sim C43C-C44C
 with sigma of 0.01
 O27-C26B \\sim O27-C26
 with sigma of 0.01
 C26B-C25 \\sim C26-C25
 with sigma of 0.01
 C30-C25 \\sim C30B-C25 \\sim C25-C31 \\sim C31B-C25
 with sigma of 0.01
 C26B-C30B \\sim C26B-C31B \\sim C30-C26 \\sim C26-C31
 with sigma of 0.01
 C30-C31 \\sim C30B-C31B
 with sigma of 0.01
 C207-F1 \\sim C207-F2 \\sim C207-F3 \\sim C207-F101 \\sim C207-F102 \\sim
C207-F103
 with sigma of 0.01
 F1-F2 \\sim F2-F3 \\sim F3-F1 \\sim F101-F102 \\sim F102-F103 \\sim F103-F101
 with sigma of 0.01
 C203-F1 \\sim C203-F2 \\sim C203-F3 \\sim C203-F101 \\sim C203-F102 \\sim
C203-F103
 with sigma of 0.01
 C216-F10 \\sim C216-F11 \\sim C216-F12 \\sim C216-F110 \\sim C216-F111 \\sim
C216-F112
 with sigma of 0.01
 F10-F11 \\sim F11-F12 \\sim F12-F10 \\sim F110-F111 \\sim F111-F112 \\sim
F112-F110
 with sigma of 0.01
 C213-F10 \\sim C213-F11 \\sim C213-F12 \\sim C213-F110 \\sim C213-F111 \\sim
C213-F112
 with sigma of 0.01
 C232-F122 \\sim C232-F123 \\sim C232-F124 \\sim C232-F22 \\sim C232-F23 \\sim
C232-F24
 with sigma of 0.01
 F122-F123 \\sim F123-F124 \\sim F124-F122 \\sim F22-F23 \\sim F23-F24 \\sim
F24-F22
 with sigma of 0.01
 C229-F122 \\sim C229-F123 \\sim C229-F124 \\sim C229-F22 \\sim C229-F23 \\sim
C229-F24
 with sigma of 0.01
 C308-F304 \\sim C308-F305 \\sim C308-F306 \\sim C308-F404 \\sim C308-F405
\\sim C308-F406
 with sigma of 0.01
 F304-F305 \\sim F305-F306 \\sim F306-F304 \\sim F404-F405 \\sim F405-F406
\\sim F406-F404
 with sigma of 0.01
 C305-F304 \\sim C305-F305 \\sim C305-F306 \\sim C305-F404 \\sim C305-F405
\\sim C305-F406
 with sigma of 0.01
 C323-F313 \\sim C323-F314 \\sim C323-F315 \\sim C323-F413 \\sim C323-F414
\\sim C323-F415
 with sigma of 0.01
 F313-F314 \\sim F314-F315 \\sim F315-F313 \\sim F413-F414 \\sim F414-F415
\\sim F415-F413
 with sigma of 0.01
 C319-F313 \\sim C319-F314 \\sim C319-F315 \\sim C319-F413 \\sim C319-F414
\\sim C319-F415
 with sigma of 0.01
 C332-F322 \\sim C332-F323 \\sim C332-F324 \\sim C332-F422 \\sim C332-F423
\\sim C332-F424
 with sigma of 0.01
 F322-F323 \\sim F323-F324 \\sim F324-F322 \\sim F422-F423 \\sim F423-F424
\\sim F424-F422
 with sigma of 0.01
 C329-F322 \\sim C329-F323 \\sim C329-F324 \\sim C329-F422 \\sim C329-F423
\\sim C329-F424
 with sigma of 0.01
 C315-F307 \\sim C315-F308 \\sim C315-F309 \\sim C315-F407 \\sim C315-F408
\\sim C315-F409
 with sigma of 0.01
 F307-F308 \\sim F308-F309 \\sim F309-F307 \\sim F407-F408 \\sim F408-F409
\\sim F409-F407
 with sigma of 0.01
 C311-F307 \\sim C311-F308 \\sim C311-F309 \\sim C311-F407 \\sim C311-F408
\\sim C311-F409
 with sigma of 0.01
 C215-F7 \\sim C215-F8 \\sim C215-F9 \\sim C215-F107 \\sim C215-F108 \\sim
C215-F109
 with sigma of 0.01
 F7-F8 \\sim F8-F9 \\sim F9-F7 \\sim F107-F108 \\sim F108-F109 \\sim F109-F107
 with sigma of 0.01
 C211-F7 \\sim C211-F8 \\sim C211-F9 \\sim C211-F107 \\sim C211-F108 \\sim
C211-F109
 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
C38A \\sim C38C \\sim C43A \\sim C43C \\sim C44C \\sim C44A: within 1.7A with
sigma of 0.01 and sigma for terminal atoms of 0.02
C26B \\sim C26 \\sim C30 \\sim C30B \\sim C31 \\sim C31B: within 1.7A with
sigma of 0.01 and sigma for terminal atoms of 0.02
F1 \\sim F2 \\sim F3 \\sim F4 \\sim F5 \\sim F6 \\sim F7 \\sim F8 \\sim F9
\\sim F10 \\sim F11 \\sim F12 \\sim F13 \\sim F14 \\sim F15 \\sim F16 \\sim F17
\\sim F18 \\sim F19 \\sim F20 \\sim F21 \\sim F22 \\sim F23 \\sim F24 \\sim
F101 \\sim F102 \\sim F103 \\sim F107 \\sim F108 \\sim F109 \\sim F110 \\sim
F111 \\sim F112 \\sim F122 \\sim F123 \\sim F124 \\sim F301 \\sim F302 \\sim
F303 \\sim F304 \\sim F305 \\sim F306 \\sim F307 \\sim F308 \\sim F309 \\sim
F310 \\sim F311 \\sim F312 \\sim F313 \\sim F314 \\sim F315 \\sim F316 \\sim
F317 \\sim F318 \\sim F319 \\sim F320 \\sim F321 \\sim F322 \\sim F323 \\sim
F324 \\sim F404 \\sim F405 \\sim F406 \\sim F407 \\sim F408 \\sim F409 \\sim
F413 \\sim F414 \\sim F415 \\sim F422 \\sim F423 \\sim F424: within 1.7A with
sigma of 0.007 and sigma for terminal atoms of 0.02
Uanis(Cl1B) \\sim Ueq, Uanis(Cl1A) \\sim Ueq, Uanis(C80B) \\sim Ueq,
Uanis(C80A) \\sim Ueq, Uanis(Cl2B) \\sim Ueq, Uanis(Cl2A) \\sim Ueq: with sigma
of 0.01 and sigma for terminal atoms of 0.02
Uanis(C38A) \\sim Ueq, Uanis(C38C) \\sim Ueq, Uanis(C43A) \\sim Ueq,
Uanis(C43C) \\sim Ueq, Uanis(C44C) \\sim Ueq, Uanis(C44A) \\sim Ueq: with sigma
of 0.005 and sigma for terminal atoms of 0.02
Uanis(C26B) \\sim Ueq, Uanis(C26) \\sim Ueq, Uanis(C30) \\sim Ueq, Uanis(C30B)
\\sim Ueq, Uanis(C31) \\sim Ueq, Uanis(C31B) \\sim Ueq: with sigma of 0.005 and
sigma for terminal atoms of 0.02
Uanis(F1) \\sim Ueq, Uanis(F2) \\sim Ueq, Uanis(F3) \\sim Ueq, Uanis(F4) \\sim
Ueq, Uanis(F5) \\sim Ueq, Uanis(F6) \\sim Ueq, Uanis(F7) \\sim Ueq, Uanis(F8)
\\sim Ueq, Uanis(F9) \\sim Ueq, Uanis(F10) \\sim Ueq, Uanis(F11) \\sim Ueq,
Uanis(F12) \\sim Ueq, Uanis(F13) \\sim Ueq, Uanis(F14) \\sim Ueq, Uanis(F15)
\\sim Ueq, Uanis(F16) \\sim Ueq, Uanis(F17) \\sim Ueq, Uanis(F18) \\sim Ueq,
Uanis(F19) \\sim Ueq, Uanis(F20) \\sim Ueq, Uanis(F21) \\sim Ueq, Uanis(F22)
\\sim Ueq, Uanis(F23) \\sim Ueq, Uanis(F24) \\sim Ueq, Uanis(F101) \\sim Ueq,
Uanis(F102) \\sim Ueq, Uanis(F103) \\sim Ueq, Uanis(F107) \\sim Ueq,
Uanis(F108) \\sim Ueq, Uanis(F109) \\sim Ueq, Uanis(F110) \\sim Ueq,
Uanis(F111) \\sim Ueq, Uanis(F112) \\sim Ueq, Uanis(F122) \\sim Ueq,
Uanis(F123) \\sim Ueq, Uanis(F124) \\sim Ueq, Uanis(F301) \\sim Ueq,
Uanis(F302) \\sim Ueq, Uanis(F303) \\sim Ueq, Uanis(F304) \\sim Ueq,
Uanis(F305) \\sim Ueq, Uanis(F306) \\sim Ueq, Uanis(F307) \\sim Ueq,
Uanis(F308) \\sim Ueq, Uanis(F309) \\sim Ueq, Uanis(F310) \\sim Ueq,
Uanis(F311) \\sim Ueq, Uanis(F312) \\sim Ueq, Uanis(F313) \\sim Ueq,
Uanis(F314) \\sim Ueq, Uanis(F315) \\sim Ueq, Uanis(F316) \\sim Ueq,
Uanis(F317) \\sim Ueq, Uanis(F318) \\sim Ueq, Uanis(F319) \\sim Ueq,
Uanis(F320) \\sim Ueq, Uanis(F321) \\sim Ueq, Uanis(F322) \\sim Ueq,
Uanis(F323) \\sim Ueq, Uanis(F324) \\sim Ueq, Uanis(F404) \\sim Ueq,
Uanis(F405) \\sim Ueq, Uanis(F406) \\sim Ueq, Uanis(F407) \\sim Ueq,
Uanis(F408) \\sim Ueq, Uanis(F409) \\sim Ueq, Uanis(F413) \\sim Ueq,
Uanis(F414) \\sim Ueq, Uanis(F415) \\sim Ueq, Uanis(F422) \\sim Ueq,
Uanis(F423) \\sim Ueq, Uanis(F424) \\sim Ueq: with sigma of 0.007 and sigma for
terminal atoms of 0.02
Uanis(Cl1B) = Uanis(Cl1A)
Uanis(Cl2B) = Uanis(Cl2A)
Uanis(C80B) = Uanis(C80A)
Uanis(C30B) = Uanis(C30)
4. Others
 Sof(Cl1B)=Sof(Cl2B)=Sof(C80B)=Sof(H80C)=Sof(H80D)=1-FVAR(1)
 Sof(Cl1A)=Sof(Cl2A)=Sof(C80A)=Sof(H80A)=Sof(H80B)=FVAR(1)
 Sof(C38C)=Sof(H38C)=Sof(H38D)=Sof(C43C)=Sof(H43D)=Sof(H43E)=Sof(H43F)=
 Sof(C44C)=Sof(H44D)=Sof(H44E)=Sof(H44F)=1-FVAR(2)
 Sof(C38A)=Sof(H38A)=Sof(H38B)=Sof(C43A)=Sof(H43A)=Sof(H43B)=Sof(H43C)=
 Sof(C44A)=Sof(H44A)=Sof(H44B)=Sof(H44C)=FVAR(2)
 Sof(C26B)=Sof(H26C)=Sof(H26D)=Sof(C30B)=Sof(H30D)=Sof(H30E)=Sof(H30F)=
 Sof(C31B)=Sof(H31G)=Sof(H31H)=Sof(H31I)=1-FVAR(3)
 Sof(C26)=Sof(H26E)=Sof(H26F)=Sof(C30)=Sof(H30G)=Sof(H30H)=Sof(H30I)=Sof(C31)=
 Sof(H31D)=Sof(H31E)=Sof(H31F)=FVAR(3)
 Sof(F122)=Sof(F123)=Sof(F124)=1-FVAR(4)
 Sof(F22)=Sof(F23)=Sof(F24)=FVAR(4)
 Sof(F110)=Sof(F111)=Sof(F112)=1-FVAR(5)
 Sof(F10)=Sof(F11)=Sof(F12)=FVAR(5)
 Sof(F101)=Sof(F102)=Sof(F103)=1-FVAR(6)
 Sof(F1)=Sof(F2)=Sof(F3)=FVAR(6)
 Sof(F404)=Sof(F405)=Sof(F406)=1-FVAR(7)
 Sof(F304)=Sof(F305)=Sof(F306)=FVAR(7)
 Sof(F413)=Sof(F414)=Sof(F415)=1-FVAR(8)
 Sof(F313)=Sof(F314)=Sof(F315)=FVAR(8)
 Sof(F422)=Sof(F423)=Sof(F424)=1-FVAR(9)
 Sof(F322)=Sof(F323)=Sof(F324)=FVAR(9)
 Sof(F107)=Sof(F108)=Sof(F109)=1-FVAR(10)
 Sof(F7)=Sof(F8)=Sof(F9)=FVAR(10)
 Sof(F407)=Sof(F408)=Sof(F409)=1-FVAR(11)
 Sof(F307)=Sof(F308)=Sof(F309)=FVAR(11)
5.a Secondary CH2 refined with riding coordinates:
 C8A(H8AA,H8AB), C11A(H11A,H11B), C23A(H23A,H23B), C26A(H26A,H26B), C38A(H38A,
 H38B), C38C(H38C,H38D), C41A(H41A,H41B), C8(H8A,H8B), C11(H11C,H11D), C23(H23C,
 H23D), C26(H26E,H26F), C26B(H26C,H26D), C38(H38E,H38F), C41(H41C,H41D),
 C80A(H80A,H80B), C80B(H80C,H80D)
5.b Aromatic/amide H refined with riding coordinates:
 C202(H202), C204(H204), C206(H206), C210(H210), C212(H212), C214(H214),
 C218(H218), C220(H220), C222(H222), C226(H226), C228(H228), C230(H230),
 C302(H302), C304(H304), C306(H306), C310(H310), C312(H312), C314(H314),
 C318(H318), C320(H320), C322(H322), C326(H326), C328(H328), C330(H330)
5.c Idealised Me refined as rotating group:
 C13A(H13A,H13B,H13C), C14A(H14A,H14B,H14C), C15A(H15A,H15B,H15C), C16A(H16A,
 H16B,H16C), C28A(H28A,H28B,H28C), C29A(H29A,H29B,H29C), C30A(H30A,H30B,H30C),
 C31A(H31A,H31B,H31C), C43A(H43A,H43B,H43C), C43C(H43D,H43E,H43F), C44A(H44A,
 H44B,H44C), C44C(H44D,H44E,H44F), C45A(H45A,H45B,H45C), C46A(H46A,H46B,H46C),
 C13(H13D,H13E,H13F), C14(H14D,H14E,H14F), C15(H15D,H15E,H15F), C16(H16D,H16E,
 H16F), C28(H28D,H28E,H28F), C29(H29D,H29E,H29F), C30(H30G,H30H,H30I),
 C30B(H30D,H30E,H30F), C31(H31D,H31E,H31F), C31B(H31G,H31H,H31I), C43(H43G,H43H,
 H43I), C44(H44G,H44H,H44I), C45(H45D,H45E,H45F), C46(H46D,H46E,H46F)
;