C-C Coupling of a Permetalated Ethene, (μ4-C=C)Ru2(FeCp*)2(CO)10, with Alkynes, and Isolation of a Labile MeCN Adduct, (μ4-C\δb C)Ru2(FeCp*)2(CO)8(NCMe)2
Gou Higashihara; Masako Terada; Akiko Inagaki; Munetaka Akita; Organometallics 26 (2007) 439–444; doi:10.1021/om0609160

data_4063289
_publ_section_title
;
 C-C Coupling of a Permetalated Ethene, (\m4-C\\db C)Ru2(FeCp*)2(CO)10,
 with Alkynes, and Isolation of a Labile MeCN Adduct, (\m4-C\\db
 C)Ru2(FeCp*)2(CO)8(NCMe)2
;
_journal_name_full               Organometallics
_journal_page_first              439
_journal_page_last               444
_journal_paper_doi               10.1021/om0609160
_journal_volume                  26
_journal_year                    2007
_chemical_formula_moiety         'C70 H64 Cl2 Fe2 O7 Ru2 Si2 '
_chemical_formula_sum            'C70 H64 Cl2 Fe2 O7 Ru2 Si2'
_chemical_formula_weight         1458.18
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 113.3986(9)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   30.9399(4)
_cell_length_b                   11.5905(2)
_cell_length_c                   40.1255(6)
_cell_measurement_reflns_used    41444
_cell_measurement_temperature    213
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.4
_cell_volume                     13206.0(4)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  SHELXL97
_computing_structure_solution    'DIRDIF94 (PATTY)'
_diffrn_ambient_temperature      213
_diffrn_detector_area_resol_mean 10.00
_diffrn_measurement_device_type  'Rigaku RAXIS-IV Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.000
_diffrn_reflns_limit_h_max       40
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       47
_diffrn_reflns_limit_l_min       -49
_diffrn_reflns_number            46723
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    1.048
_exptl_absorpt_correction_T_max  0.901
_exptl_absorpt_correction_T_min  0.679
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            unknown
_exptl_crystal_density_diffrn    1.467
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       unknown
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.56
_refine_diff_density_min         -0.96
_refine_ls_extinction_coef       0.0000
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.721
_refine_ls_number_parameters     778
_refine_ls_number_reflns         8889
_refine_ls_R_factor_gt           0.0487
_refine_ls_shift/su_max          0.0290
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1364
_reflns_number_gt                8889
_reflns_number_total             14112
_reflns_threshold_expression     >2.0sigma(I)
_cod_original_formula_sum        'C70 H64 Cl2 Fe2 O7 Ru2 Si2 '
_cod_database_code               4063289