Electron transfer within β-diketiminato nickel bromide and cobaltocene redox couples activating CO<sub>2</sub>.
Zimmermann, Philipp; Kilpatrick, Alexander F. R.; Ar, Deniz; Demeshko, Serhiy; Cula, Beatrice; Limberg, Christian; Chemical communications (Cambridge, England) 57 (2021) 875–878; doi:10.1039/d0cc06983c

data_7127607
_publ_section_title
;
 Electron transfer within \b-diketiminato nickel bromide and cobaltocene
 redox couples activating CO<sub>2</sub>.
;
_journal_issue                   7
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              875
_journal_page_last               878
_journal_paper_doi               10.1039/d0cc06983c
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C35 H53 Br N2 Ni, C20 H30 Co, 3(C7 H8)'
_chemical_formula_sum            'C76 H107 Br Co N2 Ni'
_chemical_formula_weight         1246.18
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-12-09 deposited with the CCDC.	2020-12-11 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_measurement_theta_max      24.98
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_computing_cell_refinement       'Bruker SAINT'
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_computing_publication_material  'PLATON (Spek 2009)'
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker D8 VENTURE'
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            'dark brown'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0277P)^2^+22.8759P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7127607--7127609.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
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_shelx_res_checksum              46927