Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl Backbones: Synthesis of Three Different Motifs and Their Application in Enantioselective Diels–Alder Reactions
Rohde, Volker H. G.; Müller, Maria F.; Oestreich, Martin; Organometallics 34 (2015) 3358–; doi:10.1021/acs.organomet.5b00351

data_4085949
_publ_section_title
;
 Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl
 Backbones: Synthesis of Three Different Motifs and Their Application in
 Enantioselective Diels--Alder Reactions
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3358
_journal_paper_doi               10.1021/acs.organomet.5b00351
_journal_volume                  34
_journal_year                    2015
_chemical_absolute_configuration ad
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
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CrysAlisPro, Agilent Technologies,
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(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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_exptl_crystal_colour            colourless
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         6699
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_refine_ls_R_factor_all          0.0867
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0496P)^2^+0.4244P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1141
_refine_ls_wR_factor_ref         0.1341
_reflns_number_gt                4976
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_cod_data_source_file            om5b00351_si_002.cif
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_cod_depositor_comments
'Adding full bibliography for 4085948--4085949.cif.'
_cod_original_cell_volume        2463.43(14)
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