Directed Formation of a Ferrocenyl-Decorated Organotin Sulfide Complex and Its Controlled Degradation
Zhiliang You; Stefanie Dehnen; Inorganic Chemistry 52 (2013) 12332–12334; doi:10.1021/ic4022992

data_4336671
_publ_contact_author
;
Dehnen, Stefanie

Fachbereich Chemie der Philipps-Universitaet
Hans-Meerwein-Str.
D-35043 Marburg, Germany
;
_publ_contact_author_email       dehnen@chemie.uni-marburg.de
_publ_contact_author_fax         +6421-2825653
_publ_contact_author_phone       +6421-2825751
_publ_section_title
;
 Directed Formation of a Ferrocenyl-Decorated Organotin Sulfide Complex
 and Its Controlled Degradation
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              12332
_journal_page_last               12334
_journal_paper_doi               10.1021/ic4022992
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         'C36 H46 Fe2 N4 S5 Sn3, 3(C H2 Cl2)'
_chemical_formula_sum            'C39 H52 Cl6 Fe2 N4 S5 Sn3'
_chemical_formula_weight         1417.62
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                65.48(0)
_cell_angle_beta                 78.88(0)
_cell_angle_gamma                61.08(0)
_cell_formula_units_Z            2
_cell_length_a                   14.477(1)
_cell_length_b                   14.948(1)
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_cell_measurement_reflns_used    41642
_cell_measurement_temperature    103(2)
_cell_measurement_theta_max      27.27
_cell_measurement_theta_min      1.41
_cell_volume                     2742.2(3)
_computing_cell_refinement       'XAREA 1.54'
_computing_data_collection       'XAREA 1.54'
_computing_data_reduction        'STOE X-RED'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    Sir-92
_diffrn_ambient_temperature      103(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_theta_max         26.72
_diffrn_reflns_theta_min         1.41
_exptl_absorpt_coefficient_mu    2.377
_exptl_absorpt_correction_T_max  0.4815
_exptl_absorpt_correction_T_min  0.4498
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Stoe, X-area ver. 1.54'
_exptl_crystal_colour            orange
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0927P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1013
_refine_ls_wR_factor_ref         0.1040
_reflns_number_gt                9289
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_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            ic4022992_si_004.cif
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_cod_database_code               4336671