Organocatalytic CS<sub>2</sub> insertion into epoxides in neat conditions: a straightforward approach for the efficient synthesis of Di- and tri-thiocarbonates.
López-Aguilar, Marcos; Ríos-Lombardía, Nicolás; Gallegos, Miguel; Barrena-Espés, Daniel; García-Álvarez, Joaquín; Concellón, Carmen; Del Amo, Vicente; Chemical communications (Cambridge, England) 61 (2025) 3488–3491; doi:10.1039/d4cc05154h

data_7134072
_publ_section_title
;
 Organocatalytic CS<sub>2</sub> insertion into epoxides in neat
 conditions: a straightforward approach for the efficient synthesis of Di-
 and tri-thiocarbonates.
;
_journal_issue                   17
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              3488
_journal_page_last               3491
_journal_paper_doi               10.1039/d4cc05154h
_journal_volume                  61
_journal_year                    2025
_chemical_formula_sum            'C14 H16 O S3'
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_chemical_name_systematic
trans,cis-4-(Benzyloxy)hexahydrobenzo[d][1,3]dithiolane-2-thione
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_audit_update_record
;
2024-09-25 deposited with the CCDC.	2024-12-20 downloaded from the CCDC.
;
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'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
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'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
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'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
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'MERCURY (Cambridge Crystallographic Data Centre: Cambridge, UK, 2024)'
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;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear intense yellow'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0626P)^2^+0.3416P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7134071--7134073.cif.'
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