Diamminebis[dimethylglyoximato(1‒)]cobalt(III) Fluoborate and Perchlorate
Xu, L.; Xu, D.; Xu, Y.; Gu, J.; Acta Crystallographica Section C 52 (1996) 1119–1122; doi:10.1107/S010827019501568X

data_2004832
_publ_section_title
;
 Diamminebis[dimethylglyoximato(1--)]cobalt(III) Fluoborate and
 Perchlorate
;
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1119
_journal_page_last               1122
_journal_paper_doi               10.1107/S010827019501568X
_journal_volume                  52
_journal_year                    1996
_chemical_formula_iupac          'Co (C4 H7 N2 O2)2 (N H3)2] B F4'
_chemical_formula_moiety         'C8 H20 Co N6 O4 , B F4'
_chemical_formula_sum            'C8 H20 B Co F4 N6 O4'
_chemical_formula_weight         410.02
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_type_scat_source           IntTabIV
_cell_angle_alpha                90.
_cell_angle_beta                 112.54(2)
_cell_angle_gamma                90.
_cell_formula_units_Z            4
_cell_length_a                   21.526(6)
_cell_length_b                   6.447(1)
_cell_length_c                   12.479(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296
_cell_measurement_theta_max      14
_cell_measurement_theta_min      13
_cell_volume                     1599.5(6)
_computing_cell_refinement       'CAD-4 Software'
_computing_data_collection       'CAD-4 Software (Enraf-Nonius, 1989)'
_computing_data_reduction
'TEXSAN (Molecular Structure Corporation, 1989)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_structure_refinement  'TEXSAN '
_computing_structure_solution    TEXSAN
_diffrn_measurement_device       'Enraf-Nonius CAD4'
_diffrn_measurement_method       \w/2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.028
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            1588
_diffrn_reflns_theta_max         25
_diffrn_standards_decay_%        2.9
_diffrn_standards_interval_count 300
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.138
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7176
_exptl_absorpt_correction_type   'empirical via \y scans'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.70
_exptl_crystal_description       Prism
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.51
_refine_diff_density_min         -0.38
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_obs   1.48
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     111
_refine_ls_number_reflns         1279
_refine_ls_R_factor_obs          0.035
_refine_ls_shift/esd_max         0.02
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.049
_reflns_number_observed          1279
_reflns_number_total             1543
_reflns_observed_criterion       I>3\s(I)
_cod_data_source_file            bk1127.cif
_cod_data_source_block           1
_cod_original_cell_volume        1599.0(10)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C8 H20 Co B F4 N6 O4'
_cod_database_code               2004832