The templated synthesis of a unique type of tetra-nuclear uranyl-mediated two-fold interpenetrating uranyl-organic framework.
An, Shu-Wen; Mei, Lei; Hu, Kong-Qiu; Xia, Chuan-Qin; Chai, Zhi-Fang; Shi, Wei-Qun; Chemical communications (Cambridge, England) 52 (2016) 1641–1644; doi:10.1039/c5cc09314g

data_7118510
_publ_section_title
;
 The templated synthesis of a unique type of tetra-nuclear uranyl-mediated
 two-fold interpenetrating uranyl-organic framework.
;
_journal_issue                   8
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              1641
_journal_page_last               1644
_journal_paper_doi               10.1039/c5cc09314g
_journal_volume                  52
_journal_year                    2016
_chemical_formula_sum            'C55 H29 N2 O28 S3 U4'
_chemical_formula_weight         2214.10
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-10-14 deposited with the CCDC.
2015-11-23 downloaded from the CCDC.
;
_cell_angle_alpha                90.81(3)
_cell_angle_beta                 92.91(3)
_cell_angle_gamma                92.71(3)
_cell_formula_units_Z            2
_cell_length_a                   10.523(2)
_cell_length_b                   11.866(2)
_cell_length_c                   29.288(6)
_cell_measurement_temperature    293(2)
_cell_volume                     3647.8(12)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.909
_diffrn_measured_fraction_theta_max 0.909
_diffrn_measurement_device_type  marccd
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0372
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            8689
_diffrn_reflns_theta_full        22.50
_diffrn_reflns_theta_max         22.50
_diffrn_reflns_theta_min         1.39
_exptl_absorpt_coefficient_mu    9.014
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.016
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2026
_exptl_crystal_preparation       Luminescent
_refine_diff_density_max         2.051
_refine_diff_density_min         -3.227
_refine_diff_density_rms         0.178
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.121
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     768
_refine_ls_number_reflns         8689
_refine_ls_number_restraints     130
_refine_ls_restrained_S_all      1.145
_refine_ls_R_factor_all          0.0660
_refine_ls_R_factor_gt           0.0513
_refine_ls_shift/su_max          0.059
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0725P)^2^+35.9390P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1400
_refine_ls_wR_factor_ref         0.1494
_reflns_number_gt                6815
_reflns_number_total             8689
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5cc09314g2.cif
_cod_data_source_block           compound-2
_cod_original_cell_volume        3647.8(13)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7118510