Dinuclear Co<sup>II</sup>Y<sup>III</sup>vs. tetranuclear CoY complexes: the effect of increasing molecular size on magnetic anisotropy and relaxation dynamics.
Masegosa, Alberto; Palacios, María A; Ruiz, Eliseo; Gómez-Coca, Silvia; Krzystek, J.; Moreno, José M; Colacio, Enrique; Dalton transactions (Cambridge, England : 2003) 48 (2019) 14873–14884; doi:10.1039/c9dt02969a

data_7701116
_publ_section_title
;
 Dinuclear Co<sup>II</sup>Y<sup>III</sup>vs. tetranuclear CoY complexes:
 the effect of increasing molecular size on magnetic anisotropy and
 relaxation dynamics.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14873
_journal_page_last               14884
_journal_paper_doi               10.1039/c9dt02969a
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C54 H86 Co2 N8 O24 Y2'
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'Olex2 1.2 (compiled 2017.03.28 svn.r3405 for OlexSys, GUI svn.r5337)'
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
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_audit_update_record
;
2019-09-03 deposited with the CCDC.    2019-09-09 downloaded from the CCDC.
;
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_cell_length_c                   19.345(4)
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_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
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_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
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_diffrn_measured_fraction_theta_max 0.996
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_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
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;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0536 before and 0.0290 after correction.
The Ratio of minimum to maximum transmission is 0.8075.
The \l/2 correction factor is 0.00150.
;
_exptl_crystal_colour            pink
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0265P)^2^+4.8892P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                5534
_reflns_number_total             6376
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt02969a2.cif
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_cod_depositor_comments          'Adding full bibliography for 7701116.cif.'
_cod_original_cell_volume        3097.9(11)
_cod_database_code               7701116
_shelx_shelxl_version_number     2018/1
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_shelx_res_checksum              55252