Synthesis and reactivity of a terminal aluminium-imide bond.
Anker, Mathew D.; Schwamm, Ryan J.; Coles, Martyn P.; Chemical communications (Cambridge, England) 56 (2020) 2288–2291; doi:10.1039/c9cc09214e

data_7125830
_publ_section_title
;
 Synthesis and reactivity of a terminal aluminium-imide bond.
;
_journal_issue                   15
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              2288
_journal_page_last               2291
_journal_paper_doi               10.1039/c9cc09214e
_journal_volume                  56
_journal_year                    2020
_chemical_formula_moiety         'C76 H114 Al2 K2 N6 O6 Si4'
_chemical_formula_sum            'C76 H114 Al2 K2 N6 O6 Si4'
_chemical_formula_weight         1452.25
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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;
2019-11-25 deposited with the CCDC.	2020-01-20 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 93.9074(5)
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_cell_measurement_reflns_used    17361
_cell_measurement_temperature    120.01(10)
_cell_measurement_theta_max      73.417
_cell_measurement_theta_min      4.329
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_computing_cell_refinement       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
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_diffrn_ambient_temperature      120.01(10)
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'CrysAlisPro convention (1999,Acta A55,543-557)'
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_diffrn_orient_matrix_UB_13      0.0961181
_diffrn_orient_matrix_UB_21      -0.0655586
_diffrn_orient_matrix_UB_22      0.0483641
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_diffrn_reflns_Laue_measured_fraction_full 1
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_diffrn_reflns_point_group_measured_fraction_full 1
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_diffrn_reflns_theta_max         73.4097
_diffrn_reflns_theta_min         4.335
_diffrn_source                   'micro-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    2.183
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_exptl_absorpt_process_details
;
        CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Numerical absorption correction based on gaussian integration over
                        a multifaceted crystal model
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.173
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1560
_exptl_crystal_size_max          0.341
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_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0328P)^2^+1.8119P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0732
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_reflns_number_gt                7685
_reflns_number_total             8233
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9cc09214e2.cif
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_cod_depositor_comments
'Adding full bibliography for 7125829--7125830.cif.'
_cod_database_code               7125830