Structurally similar triphenylphosphine-stabilized undecagolds, Au11(PPh3)7Cl3 and [Au11(PPh3)8Cl2]Cl, exhibit distinct ligand exchange pathways with glutathione.
McKenzie, Lallie C.; Zaikova, Tatiana O.; Hutchison, James E.; Journal of the American Chemical Society 136 (2014) 13426–13435; doi:10.1021/ja5075689

data_4122613
_publ_section_title
;
 Structurally similar triphenylphosphine-stabilized undecagolds,
 Au11(PPh3)7Cl3 and [Au11(PPh3)8Cl2]Cl, exhibit distinct ligand exchange
 pathways with glutathione.
;
_journal_issue                   38
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13426
_journal_page_last               13435
_journal_paper_doi               10.1021/ja5075689
_journal_volume                  136
_journal_year                    2014
_chemical_formula_sum            'C154 H148 Au11 Cl7 O4 P8'
_chemical_formula_weight         4725.27
_chemical_name_systematic
; 
 ? 
;
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_cell_angle_gamma                90.00
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_computing_cell_refinement       'Bruker SMART'
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_computing_molecular_graphics    'Bruker SHELXTL'
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_computing_structure_solution    'Bruker SHELXTL'
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_diffrn_measured_fraction_theta_full 0.945
_diffrn_measured_fraction_theta_max 0.945
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_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_theta_max         28.32
_diffrn_reflns_theta_min         1.18
_exptl_absorpt_coefficient_mu    11.760
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.463
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    2.242
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0434P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1045
_refine_ls_wR_factor_ref         0.1144
_reflns_number_gt                20978
_reflns_number_total             32960
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_cod_data_source_file            ja5075689_si_003.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4122612--4122613.cif.
;
_cod_original_cell_volume        13997.4(16)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4122613