Reactivity of [K3(phen)8][Cu(NPh2)2]3-a possible intermediate in the copper(i)-catalyzed N-arylation of N-phenylaniline.
Tseng, Chia-Kai; Lee, Chi-Rung; Tseng, Mei-Chun; Han, Chien-Chung; Shyu, Shin-Guang; Dalton transactions (Cambridge, England : 2003) 43 (2014) 7020–7027; doi:10.1039/c4dt00051j

data_7029824
_publ_section_title
;
 Reactivity of [K3(phen)8][Cu(NPh2)2]3-a possible intermediate in the
 copper(i)-catalyzed N-arylation of N-phenylaniline.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7020
_journal_page_last               7027
_journal_paper_doi               10.1039/c4dt00051j
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C168 H124 Cu3 K3 N22'
_chemical_formula_sum            'C168 H124 Cu3 K3 N22'
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_cell_length_a                   14.0666(3)
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_diffrn_ambient_temperature      100.0(1)
_diffrn_measured_fraction_theta_full 1
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_diffrn_radiation_monochromator  graphite
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_exptl_absorpt_coefficient_mu    0.644
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.396
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_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0598P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_file            c4dt00051j2.cif
_cod_data_source_block           i11702
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for
 ./tmp-cod-update-bibliographies-12899/cifs/7029824.cif.
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7029824