Synthesis of new photosensitive H2BBQ(2+)[ZnCl4](2-)/[(ZnCl)2(μ-BBH)] complexes, through selective oxidation of H2O to H2O2.
Stylianou, M.; Hadjiadamou, I.; Drouza, C.; Hayes, S. C.; Lariou, E.; Tantis, I.; Lianos, P.; Tsipis, A. C.; Keramidas, A. D.; Dalton transactions (Cambridge, England : 2003) 46 (2017) 3688–3699; doi:10.1039/c6dt04643f

data_7042187
_publ_section_title
;
 Synthesis of new photosensitive H2BBQ(2+)[ZnCl4](2-)/[(ZnCl)2(\m-BBH)]
 complexes, through selective oxidation of H2O to H2O2.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3688
_journal_page_last               3699
_journal_paper_doi               10.1039/c6dt04643f
_journal_volume                  46
_journal_year                    2017
_chemical_formula_sum            'C15 H26.5 Cl2 N3 O6.83'
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_chemical_name_systematic
;
 ?
;
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_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2016-12-08 deposited with the CCDC.
2017-02-21 downloaded from the CCDC.
;
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_computing_cell_refinement
;
'Wed Jul 29 17:01:44 2015'
;
_computing_data_collection
;
'Wed Jul 29 17:01:44 2015'
;
_computing_data_reduction
;
'Wed Jul 29 17:01:44 2015'
;
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
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_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
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_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            6436
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_diffrn_source                   'sealed X-ray tube'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
'Wed Jul 29 17:01:44 2015'
;
_exptl_crystal_colour            brown
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_exptl_crystal_description
;
'Wed Jul 29 17:01:44 2015'
;
_exptl_crystal_F_000             452
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_refine_ls_number_reflns         3870
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_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0775
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0952P)^2^+4.0765P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1960
_refine_ls_wR_factor_ref         0.2006
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3524
_reflns_number_total             3870
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt04643f2.cif
_cod_data_source_block           shelx
_cod_depositor_comments
'Adding full bibliography for 7042187--7042190.cif.'
_cod_original_formula_sum        'C15 H26.50 Cl2 N3 O6.83'
_cod_database_code               7042187
_shelxl_version_number           2014-3
_shelx_res_checksum              45370