[<i>N</i>,<i>N</i>'-Bis(3-phenylprop-2-enylidene)ethylenediamine-κ^2^<i>N</i>,<i>N</i>']bis(triphenylphosphine-κ<i>P</i>)silver(I) nitrate 1.36-acetonitrile 1.64-methanol 0.53-diethyl ether solvate
Aliakbar Dehno Khalaji; Mehdi Amirnasr; Schenk, Kurt J.; Acta Crystallographica Section E 63 (2007) m1684–m1686; doi:10.1107/S1600536807022143

data_2213664
_publ_section_title
;[<i>N</i>,<i>N</i>'-Bis(3-phenylprop-2-enylidene)ethylenediamine-\k^2^<i>N</i>,<i>N</i>']bis(triphenylphosphine-\k<i>P</i>)silver(I)
 nitrate 1.36-acetonitrile 1.64-methanol 0.53-diethyl ether solvate
;
_journal_coeditor_code           BG2030
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1684
_journal_page_last               m1686
_journal_paper_doi               10.1107/S1600536807022143
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac
'[Ag (C20 H20 N2) (C18 H15 P)2] N O3, 1.36C2 H3 N1, 1.64C H4 O, 0.53C4 H10 O'
_chemical_formula_moiety
'C56 H50 Ag N2 P2 +, N O3 -, 1.362(C2 H3 N), 0.533(C4 H10 O), 1.638(C H4 O)'
_chemical_formula_sum            'C62.49 H65.97 Ag N4.36 O5.17 P2'
_chemical_formula_weight         1130.66
_chemical_name_systematic
;
[N,N'-Bis(3-phenylprop-2-enylidene)ethylenediamine-
\k^2^N,N']bis(triphenylphosphine-\kP)silver(I) nitrate
1.36-acetonitrile 1.64-methanol 0.53-diethyl ether solvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                80.578(5)
_cell_angle_beta                 82.201(5)
_cell_angle_gamma                64.867(4)
_cell_formula_units_Z            2
_cell_length_a                   13.5727(9)
_cell_length_b                   14.9626(10)
_cell_length_c                   15.7828(11)
_cell_measurement_reflns_used    5484
_cell_measurement_temperature    140.0(10)
_cell_measurement_theta_max      29.66
_cell_measurement_theta_min      1.72
_cell_volume                     2854.7(3)
_computing_cell_refinement       X-AREA
_computing_data_collection       'X-AREA (Stoe & Cie , 2006)'
_computing_data_reduction        'X-RED32 (Stoe & Cie, 2005)'
_computing_molecular_graphics
'SHELXTL (Sheldrick, 1996) and ATOMS (Dowty, 2006)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF (Beurskens <i>et al.</i>,  1996)'
_diffrn_ambient_temperature      140.0(10)
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.939
_diffrn_measured_fraction_theta_max 0.906
_diffrn_measurement_device       '2-circle goniometer'
_diffrn_measurement_device_type  'Stoe IPDS2'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  'plane graphite'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0262
_diffrn_reflns_av_sigmaI/netI    0.0274
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            27609
_diffrn_reflns_theta_full        25.0
_diffrn_reflns_theta_max         29.36
_diffrn_reflns_theta_min         1.73
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.461
_exptl_absorpt_correction_T_max  0.9137
_exptl_absorpt_correction_T_min  0.8041
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   '(X-RED32; Stoe & Cie, 2005)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.315
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1179.6
_exptl_crystal_size_max          0.71
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.23
_refine_diff_density_max         1.194
_refine_diff_density_min         -1.413
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.121
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     735
_refine_ls_number_reflns         14231
_refine_ls_number_restraints     17
_refine_ls_restrained_S_all      1.123
_refine_ls_R_factor_all          0.0616
_refine_ls_R_factor_gt           0.0547
_refine_ls_shift/su_max          0.021
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0456P)^2^+4.8514P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1322
_refine_ls_wR_factor_ref         0.1370
_reflns_number_gt                12840
_reflns_number_total             14231
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            bg2030.cif
_cod_data_source_block           I
_cod_original_cell_volume        2854.7(4)
_cod_database_code               2213664
_cod_database_fobs_code          2213664