Direct C-C coupling of two Ni-salphen complexes to yield dinickel-disalphen complexes with symmetric and non-symmetric substitution-patterns.
Bugenhagen, B. E. C.; Prosenc, M. H.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 7460–7468; doi:10.1039/c5dt04612b

data_7038824
_publ_section_title
;
 Direct C-C coupling of two Ni-salphen complexes to yield
 dinickel-disalphen complexes with symmetric and non-symmetric
 substitution-patterns.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7460
_journal_page_last               7468
_journal_paper_doi               10.1039/c5dt04612b
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C28 H29 Br N2 Ni O2'
_chemical_formula_sum            'C28 H29 Br N2 Ni O2'
_chemical_formula_weight         564.15
_chemical_name_common            ditBuBrSalphNi
_chemical_name_systematic
N-(3,5-ditert-Butylsalicyliden)-N'-(5-pinacolboronylsalicyliden)-phenylendiaminatonickel(II)
_space_group_crystal_system      monoclinic
_space_group_IT_number           13
_space_group_name_Hall           '-P 2yc'
_space_group_name_H-M_alt        'P 1 2/c 1'
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;
Olex2 1.2
(compiled 2015.01.26 svn.r3151 for OlexSys, GUI svn.r4998)
;
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;
2015-03-12 deposited with the CCDC.
2016-03-16 downloaded from the CCDC.
;
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'SADABS-2013/2 (Bruker,2013) was used for absorption correction. wR2(int) was 0.1039 before and 0.0337 after correction. The Ratio of minimum to maximum transmission is 0.7724. The \l/2 correction factor is 0.0000.'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0379P)^2^+2.5809P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           ditbu-br-salph-ni-thf_mf21
_cod_depositor_comments
'Adding full bibliography for 7038824--7038828.cif.'
_cod_original_cell_volume        5125.61(10)
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