New Neutral Nickel and Palladium Sandwich Catalysts: Synthesis of Ultra-High Molecular Weight Polyethylene (UHMWPE) via Highly Controlled Polymerization and Mechanistic Studies of Chain Propagation.
Tran, Quan H.; Brookhart, Maurice; Daugulis, Olafs; Journal of the American Chemical Society 142 (2020) 7198–7206; doi:10.1021/jacs.0c02045

data_4134600
_publ_section_title
;
 New Neutral Nickel and Palladium Sandwich Catalysts: Synthesis of
 Ultra-High Molecular Weight Polyethylene (UHMWPE) via Highly Controlled
 Polymerization and Mechanistic Studies of Chain Propagation.
;
_journal_issue                   15
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              7198
_journal_page_last               7206
_journal_paper_doi               10.1021/jacs.0c02045
_journal_volume                  142
_journal_year                    2020
_chemical_formula_sum            'C42.5 H32 Cl5 F3 N2 O Pd'
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.43(2)
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0257P)^2^+1.8439P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_file            ja0c02045_si_003.cif
_cod_data_source_block           QT14-27-1_XW231_sq
_cod_depositor_comments
'Adding full bibliography for 4134600--4134602.cif.'
_cod_original_formula_sum        'C42.50 H32 Cl5 F3 N2 O Pd'
_cod_database_code               4134600
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.802
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_shelx_res_checksum              26651
_shelx_hkl_checksum              47552
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