A Sterically Enforced Bent Form of an Edge-Sharing Dipalladium(II) Complex Attained by a Linked-Bisphosphido Bridge
Tsutomu Mizuta; Shizuka Aoki; Koji Nakayama; Katsuhiko Miyoshi; Inorganic Chemistry 38 (1999) 4361–4364; doi:10.1021/ic990032r

data_4322449
_publ_contact_author
;
Katsuhiko Miyoshi
Department of Chemistry, Faculty of Science, Hiroshima University
Kagamiyama 1-3, Higashi-Hiroshima, Hiroshima, JAPAN
739-8526
;
_publ_contact_author_email       ' mizuta@sci.hiroshima-u.ac.jp '
_publ_contact_author_fax         ' +82-824-24-0729 '
_publ_contact_author_phone       ' +82-824-24-7423 '
_publ_section_title
;
 A Sterically Enforced Bent Form of an Edge-Sharing Dipalladium(II)
 Complex Attained by a Linked-Bisphosphido Bridge
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4361
_journal_page_last               4364
_journal_paper_doi               10.1021/ic990032r
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C67.5 H65 Cl5 P6 Pd2'
_chemical_formula_weight         1452.16
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             'Thu Dec  3 23:56:30 1998'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 92.492(1)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   12.3700(2)
_cell_length_b                   24.2300(2)
_cell_length_c                   45.1860(6)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    200.2
_cell_measurement_theta_max      0.0
_cell_measurement_theta_min      0.0
_cell_volume                     13530.6(3)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
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_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
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_diffrn_radiation_detector       'Imaging Plate'
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_diffrn_reflns_limit_l_max       53
_diffrn_reflns_limit_l_min       -53
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_diffrn_reflns_reduction_process 'Lp corrections applied'
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_refine_ls_structure_factor_coef F
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_reflns_number_observed          20018
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_reflns_observed_criterion       >3.0sigma(I)
_cod_data_source_file            ic990032r_2.cif
_cod_data_source_block           A_TEXRAY.INF_file_is_not_p
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'P 21/n '
_cod_original_formula_sum        'C67.50 H65 Cl5 P6 Pd2 '
_cod_database_code               4322449