Concomitance of octamolybdate isomers in metastable crystal structures isolated using homoleptic Co^II^/Co^III^ complexes as structure-directing templates
Atencio, Reinaldo; Briceño, Alexander; Bruno-Colmenarez, Julia; Silva, Pedro; Rodríguez, Laura; Sosa, Eleida; Limones, Erick; Pacheco, Yesenia; Cáceres, Julio; Vielma, Joel; Acta Crystallographica Section B 77 (2021) 99–114; doi:10.1107/S2052520620015905

data_2108748
_publ_section_title
;
 Concomitance of octamolybdate isomers in metastable crystal structures
 isolated using homoleptic Co^II^/Co^III^ complexes as structure-directing
 templates
;
_journal_coeditor_code           UM5046
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              99
_journal_page_last               114
_journal_paper_doi               10.1107/S2052520620015905
_journal_volume                  77
_journal_year                    2021
_chemical_formula_iupac          '[Co (C10 H8 N2)2 {Mo8 O26}0.5]'
_chemical_formula_moiety         'C20 H16 Co Mo4 N4 O13'
_chemical_formula_sum            'C20 H16 Co Mo4 N4 O13'
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_chemical_name_systematic
;
Bis(2,2'-bipyridine)hemi(octamolybdate)cobaltate(II) 
;
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Olex2 1.3
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MSC/AFC Diffractometer Control Software (Molecular Structure Corporation, 1991)
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MSC/AFC Diffractometer Control Software (Molecular Structure Corporation, 1991)
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TEXSAN (Molecular Structure Corporation, 1999)
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'w=1/[\s^2^(Fo^2^)+(0.1038P)^2^+4.7663P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 2108746--2108748.cif.'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
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2. Rigid body (RIGU) restrains
 N5, C15, C14, C13, C12, C11, C16, C17, C18, C19, C20, N4, N1, C5, C4, C3, C2,
 C1, C6, C7, C8, C9, C10, N2
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
3.a Aromatic/amide H refined with riding coordinates:
 C20(H20), C8(H8), C7(H7), C9(H9), C17(H17), C10(H10), C5(H5), C14(H14),
 C12(H12), C15(H15), C2(H2), C13(H13), C4(H4), C19(H19), C18(H18), C3(H3)
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