<i>catena</i>-Poly[[(<i>N</i>,<i>N</i>-dimethylformamide-κ<i>O</i>)(nitrato-κ<i>O</i>)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ^2^<i>P</i>:<i>P</i>'] at 100 and 293K: temperature effects on the volume of the solvent pocket
Menezes Vicenti, Juliano R. de; Burrow, Robert A.; Acta Crystallographica Section C 63 (2007) m88–m90; doi:10.1107/S010827010700306X

data_2015854
_publ_section_title
;<i>catena</i>-Poly[[(<i>N</i>,<i>N</i>-dimethylformamide-\k<i>O</i>)(nitrato-\k<i>O</i>)silver(I)]-\m-1,2-bis(diphenylphosphino)ethane-\k^2^<i>P</i>:<i>P</i>']
 at 100 and 293K: temperature effects on the volume of the solvent pocket
;
_journal_coeditor_code           GD3080
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m88
_journal_page_last               m90
_journal_paper_doi               10.1107/S010827010700306X
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ag (N O3) (C3 H7 N O) (C26 H24 P2)]'
_chemical_formula_moiety         'C29 H31 Ag N2 O4 P2'
_chemical_formula_sum            'C29 H31 Ag N2 O4 P2'
_chemical_formula_weight         641.37
_chemical_name_systematic
;
catena-Poly[[(N,N-dimethylformamide-\kO)(nitrato-\k^2^O:O')silver(I)]-
\m-1,2-bis(diphenylphosphino)ethane-\k^2^P:P']
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                112.2010(10)
_cell_angle_beta                 102.2000(10)
_cell_angle_gamma                106.8560(10)
_cell_formula_units_Z            2
_cell_length_a                   11.1758(3)
_cell_length_b                   12.1731(3)
_cell_length_c                   13.0499(3)
_cell_measurement_reflns_used    5132
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      22.58
_cell_measurement_theta_min      2.72
_cell_volume                     1466.34(7)
_computing_cell_refinement       'SAINT (Bruker, 2006)'
_computing_data_collection       'APEX2, BIS and COSMO (Bruker, 2006)'
_computing_data_reduction        'SAINT and SADABS (Bruker, 2006)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXTL (Bruker, 2006)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0528
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            35945
_diffrn_reflns_theta_full        29.98
_diffrn_reflns_theta_max         29.98
_diffrn_reflns_theta_min         2.96
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.832
_exptl_absorpt_correction_T_max  0.95064
_exptl_absorpt_correction_T_min  0.89766
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
Bruker APEX2 routines (using XPREP and SADABS) were used to perform
the Gaussian face-indexed numerical absorption correction.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.453
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             656
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.661
_refine_diff_density_min         -0.534
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     345
_refine_ls_number_reflns         8523
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0785
_refine_ls_R_factor_gt           0.0444
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0474P)^2^+0.249P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0971
_refine_ls_wR_factor_ref         0.1109
_reflns_number_gt                5657
_reflns_number_total             8523
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            gd3080.cif
_cod_data_source_block           I_293K
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               2015854
_cod_database_fobs_code          2015854