Nitrido-ruthenium(VI) and -osmium(VI) complexes containing chelating multianionic (N, O) ligands. Synthesis, crystal structures and reactions with triphenylphosphine
Chan, Pui-Ming; Yu, Wing-Yiu; Che, Chi-Ming; Cheung, Kung-Kai; Journal of the Chemical Society, Dalton Transactions  (1998) 3183–; doi:10.1039/a804204g

data_7028133
_publ_contact_author
;
    ENTER NAME
 ENTER ADDRESS
;
_publ_section_title
;
 Nitrido-ruthenium(VI) and -osmium(VI) complexes containing chelating
 multianionic (N, O) ligands. Synthesis, crystal structures and reactions
 with triphenylphosphine
;
_journal_issue                   19
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              3183
_journal_paper_doi               10.1039/a804204g
_journal_year                    1998
_chemical_formula_moiety         'C18 H21 Cl3 N5 O2 Os '
_chemical_formula_sum            'C18 H21 Cl3 N5 O2 Os'
_chemical_formula_weight         635.96
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             'Mon Jun  8 17:55:45 1998'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 100.952(7)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.825(2)
_cell_length_b                   10.276(4)
_cell_length_c                   19.011(1)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    301.2
_cell_measurement_theta_max      41.1
_cell_measurement_theta_min      35.7
_cell_volume                     2268.0(10)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    'DIRDIF92 (PATTY)'
_diffrn_ambient_temperature      301.2
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega scans with profile analysis'
_diffrn_orient_matrix_UB_11      -0.03200
_diffrn_orient_matrix_UB_12      0.00121
_diffrn_orient_matrix_UB_13      -0.05261
_diffrn_orient_matrix_UB_21      -0.02925
_diffrn_orient_matrix_UB_22      -0.09074
_diffrn_orient_matrix_UB_23      0.00304
_diffrn_orient_matrix_UB_31      -0.07443
_diffrn_orient_matrix_UB_32      0.03514
_diffrn_orient_matrix_UB_33      0.00965
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  3.17
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            4464
_diffrn_reflns_theta_max         25.00
_diffrn_standards_decay_%        -1.68
_diffrn_standards_interval_count 300
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.996
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.884
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   psi-scan
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.862
_exptl_crystal_density_meas      0.000
_exptl_crystal_description       prism
_exptl_crystal_F_000             1228.00
_exptl_crystal_size_max          0.450
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.250
_refine_diff_density_max         0.88
_refine_diff_density_min         -0.70
_refine_ls_extinction_coef       0.50006
_refine_ls_extinction_method     Zachariasen_type_2_Gaussian_isotropic
_refine_ls_goodness_of_fit_obs   1.331
_refine_ls_matrix_type           full
_refine_ls_number_parameters     265
_refine_ls_number_reflns         2944
_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0278
_refine_ls_shift/esd_max         0.0290
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0304
_reflns_number_observed          2944
_reflns_number_total             4247
_reflns_observed_criterion       3.00
_cod_data_source_file            g804204sup1.cif
_cod_data_source_block           Complex_5b
_cod_original_cell_volume        2267.9(8)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_original_formula_sum        'C18 H21 Cl3 N5 O2 Os '
_cod_database_code               7028133