Complexes of the tripodal phosphine ligands PhSi(XPPh2)3 (X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2.
Aloisi, Alicia; Berthet, Jean-Claude; Genre, Caroline; Thuéry, Pierre; Cantat, Thibault; Dalton transactions (Cambridge, England : 2003) 45 (2016) 14774–14788; doi:10.1039/c6dt02135b

data_7039920
_publ_section_title
;
 Complexes of the tripodal phosphine ligands PhSi(XPPh2)3 (X = CH2, O):
 synthesis, structure and catalytic activity in the hydroboration of CO2.
;
_journal_issue                   37
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'Dalton transactions (Cambridge, England : 2003)'
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_journal_paper_doi               10.1039/c6dt02135b
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_journal_year                    2016
_chemical_formula_sum            'C54 H45 Cl Cu O6 P3 Si3'
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;
2016-06-21 deposited with the CCDC.
2016-07-15 downloaded from the CCDC.
;
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'Nonius Kappa-CCD area-detector diffractometer'
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'two \f and one \w scans with 2\% steps (190 frames)'
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'w=1/[\s^2^(Fo^2^)+(0.0626P)^2^+6.1654P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7039913--7039920.cif.'
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