Synthesis of Heterodinuclear (Carbene)platinum (or palladium) Complex That Gives μ-Alkenyl-Type Complex by Deprotonation
Tanaka, Shin-ichi; Komine, Nobuyuki; Hirano, Masafumi; Komiya, Sanshiro; Organometallics 28 (2009) 5368–; doi:10.1021/om900421k

data_4069805
_publ_section_title
;
 Synthesis of Heterodinuclear (Carbene)platinum (or palladium) Complex
 That Gives \m-Alkenyl-Type Complex by Deprotonation
;
_journal_issue                   18
_journal_name_full               Organometallics
_journal_page_first              5368
_journal_paper_doi               10.1021/om900421k
_journal_volume                  28
_journal_year                    2009
_chemical_formula_moiety         'C31 H28 Cl Co N O4 P Pt '
_chemical_formula_sum            'C31 H28 Cl Co N O4 P Pt'
_chemical_formula_weight         799.02
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 95.394(19)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            8
_cell_length_a                   32.165(6)
_cell_length_b                   9.543(7)
_cell_length_c                   20.395(7)
_cell_measurement_reflns_used    22
_cell_measurement_temperature    200.1
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.5
_cell_volume                     6233(5)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.123
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       -41
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            7256
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_standards_decay_%        -3.39
_diffrn_standards_interval_count 0
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.171
_exptl_absorpt_correction_T_max  0.356
_exptl_absorpt_correction_T_min  0.227
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.703
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needles
_exptl_crystal_F_000             3120.00
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.05
_refine_diff_density_max         3.14
_refine_diff_density_min         -3.40
_refine_ls_extinction_coef       0.00010(6)
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.957
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     363
_refine_ls_number_reflns         7131
_refine_ls_R_factor_gt           0.0628
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.1086P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1978
_reflns_number_gt                3599
_reflns_number_total             7131
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om900421k_si_004.cif
_cod_data_source_block           complex_1
_cod_original_cell_volume        6232(5)
_cod_original_formula_sum        'C31 H28 Cl Co N O4 P Pt '
_cod_database_code               4069805