Preparation and Structure of New Phenylplatinum Complexes Containing Silsesquioxane as a Monodentate or Bidentate Ligand
Mintcheva, Neli; Tanabe, Makoto; Osakada, Kohtaro; Organometallics 25 (2006) 3776–; doi:10.1021/om060192s

data_4075297
_publ_section_title
;
 Preparation and Structure of New Phenylplatinum Complexes Containing
 Silsesquioxane as a Monodentate or Bidentate Ligand
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              3776
_journal_paper_doi               10.1021/om060192s
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C48 H42 O2 P2 Pt2 '
_chemical_formula_sum            'C48 H42 O2 P2 Pt2'
_chemical_formula_weight         1102.98
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 100.397(3)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            2
_cell_length_a                   8.792(3)
_cell_length_b                   14.694(4)
_cell_length_c                   15.298(4)
_cell_measurement_reflns_used    4768
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     1943.9(10)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SHELXS97
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.059
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            14334
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_exptl_absorpt_coefficient_mu    7.283
_exptl_absorpt_correction_T_max  0.695
_exptl_absorpt_correction_T_min  0.512
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.884
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1064.00
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.51
_refine_diff_density_min         -1.84
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.943
_refine_ls_hydrogen_treatment    mixed
_refine_ls_number_parameters     268
_refine_ls_number_reflns         4416
_refine_ls_R_factor_gt           0.0346
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0001Fo^2^ + 0.7000\s(Fo^2^) + 0.5000]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0864
_reflns_number_gt                2963
_reflns_number_total             4416
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om060192ssi20060228_042848.cif
_cod_data_source_block           form_4
_cod_original_cell_volume        1943.8(10)
_cod_original_formula_sum        'C48 H42 O2 P2 Pt2 '
_cod_database_code               4075297