1-(7-Chloro-1,4-dihydroquinolin-4-ylidene)thiosemicarbazide and its hydrochloride: evidence for the existence of a stable imine tautomer in the solid state of 4-aminoquinoline free bases, an anomalous case in nitrogen heterocycles
Machado, Rafael C.; Grazul, Richard M.; Diniz, Renata; Acta Crystallographica Section C 71 (2015) –; doi:10.1107/S2053229615010311

data_2019989
_publ_section_title
;
 1-(7-Chloro-1,4-dihydroquinolin-4-ylidene)thiosemicarbazide and its
 hydrochloride: evidence for the existence of a stable imine tautomer in
 the solid state of 4-aminoquinoline free bases, an anomalous case in
 nitrogen heterocycles
;
_journal_coeditor_code           FN3197
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_journal_name_full               'Acta Crystallographica Section C'
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;
;
_journal_paper_doi               10.1107/S2053229615010311
_journal_volume                  71
_journal_year                    2015
_chemical_formula_iupac          '2C10 H9 Cl N4 S , C H4 O , H2 O'
_chemical_formula_moiety         '2(C10 H9 Cl N4 S), C H4 O, H2 O'
_chemical_formula_sum            'C10.5 H12 Cl N4 O S'
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;
1-(7-Chloroquinolin-4-yl)thiosemicarbazide--methanol--water (2/1/1)
;
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;
CrysAlis PRO (Agilent, 2014)
;
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CrysAlis PRO (Agilent, 2014)
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;
CrysAlis PRO (Agilent, 2014)
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Mercury (Macrae <i>et al.</i>,  2008) and ORTEP-3 for Windows (Farrugia,
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WinGX (Farrugia, 2012)
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SHELXL2013 (Sheldrick, 2015)
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SHELXS2013 (Sheldrick, 2015)
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;
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'W = 1/[\S^2^(FO^2^)+(0.0498P)^2^] where P=(FO^2^+2FC^2^)/3'
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