A Non-Heme Iron(III) Complex with Porphyrin-like Properties That Catalyzes Asymmetric Epoxidation
Takashi Niwa; Masahisa Nakada; Journal of the American Chemical Society 134 (2012) 13538–13541; doi:10.1021/ja304219s

data_4118516
_publ_section_title
;
 A Non-Heme Iron(III) Complex with Porphyrin-like Properties That
 Catalyzes Asymmetric Epoxidation
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13538
_journal_page_last               13541
_journal_paper_doi               10.1021/ja304219s
_journal_volume                  134
_journal_year                    2012
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_chemical_formula_sum            'C36 H34 Cl2 Fe N3 O2'
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_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
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_cell_length_c                   27.499(5)
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_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
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_computing_structure_solution    'SIR92 (Altomare, et al., 1994)'
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_diffrn_detector_area_resol_mean 10.000
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_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
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_exptl_absorpt_coefficient_mu    0.577
_exptl_absorpt_correction_T_max  0.841
_exptl_absorpt_correction_T_min  0.438
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            green
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_exptl_crystal_description       platelet
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_exptl_crystal_size_min          0.300
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'Flack, H. D. (1983), Acta Cryst. A39, 876-881.  7600 Friedel Pairs'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.1680P)^2^+2.7574P] where P=(Fo^2^+2Fc^2^)/3'
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