<i>catena</i>-Poly[[[(2,2'-bipyridine-κ^2^<i>N</i>,<i>N</i>')(dimethyl sulfoxide-κ<i>O</i>)(nitrato-κ^2^<i>O</i>,<i>O</i>')bismuth(III)]-μ-5-carboxybenzene-1,3-dicarboxylato-κ^4^<i>O</i>^1^<i>,O</i>^1'^<i>:O</i>^3^<i>,O</i>^3'^] dimethyl sulfoxide monosolvate]
Pasdar, Hoda; Namegh, Marjan; Aghabozorg, Hossein; Notash, Behrouz; Acta Crystallographica Section E 67 (2011) m353–m354; doi:10.1107/S1600536811005745

data_2229330
_publ_section_title
;
 <i>catena</i>-Poly[[[(2,2'-bipyridine-\k^2^<i>N</i>,<i>N</i>')(dimethyl
 sulfoxide-\k<i>O</i>)(nitrato-\k^2^<i>O</i>,<i>O</i>')bismuth(III)]-\m-5-carboxybenzene-1,3-dicarboxylato-\k^4^<i>O</i>^1^<i>,O</i>^1'^<i>:O</i>^3^<i>,O</i>^3'^]
 dimethyl sulfoxide monosolvate]
;
_journal_coeditor_code           BT5453
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m353
_journal_page_last               m354
_journal_paper_doi               10.1107/S1600536811005745
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac
'[Bi (C9 H4 O6) (N O3) (C10 H8 N2) (C2 H6 O S)], C2 H6 O S'
_chemical_formula_moiety         'C21 H18 Bi N3 O10 S, C2 H6 O S'
_chemical_formula_sum            'C23 H24 Bi N3 O11 S2'
_chemical_formula_weight         791.57
_chemical_name_systematic
;
<i>catena</i>-Poly[[[(2,2'-bipyridine-\k^2^<i>N</i>,<i>N</i>')(dimethyl
sulfoxide-\k<i>O</i>)(nitrato-\k^2^<i>O</i>,<i>O</i>')bismuth(III)]-
\m-5-carboxybenzene-1,3-dicarboxylato-\k^4^<i>O</i>^1^<i>,O</i>^1'^<i>:
O</i>^3^<i>,O</i>^3'^] dimethyl sulfoxide monosolvate]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                89.78(3)
_cell_angle_beta                 76.22(3)
_cell_angle_gamma                84.80(3)
_cell_formula_units_Z            2
_cell_length_a                   8.9562(18)
_cell_length_b                   9.882(2)
_cell_length_c                   16.111(3)
_cell_measurement_reflns_used    7396
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      29.25
_cell_measurement_theta_min      2.35
_cell_volume                     1378.9(5)
_computing_cell_refinement       'X-AREA (Stoe & Cie, 2005)'
_computing_data_collection       'X-AREA (Stoe & Cie, 2005)'
_computing_data_reduction        'X-AREA (Stoe & Cie, 2005)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_detector_area_resol_mean '0.15 mm'
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'STOE IPDS II'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1239
_diffrn_reflns_av_sigmaI/netI    0.1050
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            15461
_diffrn_reflns_theta_full        29.25
_diffrn_reflns_theta_max         29.25
_diffrn_reflns_theta_min         2.35
_exptl_absorpt_coefficient_mu    6.608
_exptl_absorpt_correction_T_max  0.515
_exptl_absorpt_correction_T_min  0.455
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
[shape of crystal determined optically
(X-SHAPE and X-RED32; Stoe & Cie (2005)]
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.906
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             772.0
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_refine_diff_density_max         2.246
_refine_diff_density_min         -2.567
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.131
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     373
_refine_ls_number_reflns         7396
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.131
_refine_ls_R_factor_all          0.0929
_refine_ls_R_factor_gt           0.0720
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0865P)^2^+12.3704P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1803
_refine_ls_wR_factor_ref         0.1951
_reflns_number_gt                6043
_reflns_number_total             7396
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            bt5453.cif
_cod_data_source_block           I
_cod_database_code               2229330
_cod_database_fobs_code          2229330