<i>catena</i>-Poly[[silver(I)-μ-[9,10-bis(1<i>H</i>-benzimidazol-1-ylmethyl)anthracene]-κ^2^<i>N</i>^3^:<i>N</i>^3'^] bis(nitrato-κ<i>O</i>)silver(I)]
Du, Jian-Long; Zhu, Xiao-Long; Li, Pei; Acta Crystallographica Section C 68 (2012) m281–m283; doi:10.1107/S0108270112035846

data_2018653
_publ_section_title
;
 <i>catena</i>-Poly[[silver(I)-\m-[9,10-bis(1<i>H</i>-benzimidazol-1-ylmethyl)anthracene]-\k^2^<i>N</i>^3^:<i>N</i>^3'^]
 bis(nitrato-\k<i>O</i>)silver(I)]
;
_journal_coeditor_code           SF3177
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m281
_journal_page_last               m283
_journal_paper_doi               10.1107/S0108270112035846
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Ag (C30 H22 N4)] [Ag (N O3)2]'
_chemical_formula_moiety         'C30 H22 Ag N4 +, Ag N2 O6 -'
_chemical_formula_sum            'C30 H22 Ag2 N6 O6'
_chemical_formula_weight         778.28
_chemical_name_systematic
;
<i>catena</i>-Poly[[silver(I)-\m-[9,10-bis(1<i>H</i>-benzimidazol-1-
ylmethyl)anthracene]-\k^2^<i>N</i>^3^:<i>N</i>^3'^]
bis(nitrato-\k<i>O</i>)silver(I)]
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 103.96(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   24.980(5)
_cell_length_b                   6.5472(13)
_cell_length_c                   17.278(4)
_cell_measurement_reflns_used    10039
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.2
_cell_volume                     2742.3(11)
_computing_cell_refinement       'SAINT (Bruker, 2000)'
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 1999)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0878
_diffrn_reflns_av_sigmaI/netI    0.0683
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            10890
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         3.22
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.487
_exptl_absorpt_correction_T_max  0.7969
_exptl_absorpt_correction_T_min  0.7261
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.885
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1544
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.697
_refine_diff_density_min         -0.430
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.110
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     201
_refine_ls_number_reflns         2415
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.110
_refine_ls_R_factor_all          0.1018
_refine_ls_R_factor_gt           0.0605
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0306P)^2^+4.9608P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0927
_refine_ls_wR_factor_ref         0.1030
_reflns_number_gt                1697
_reflns_number_total             2415
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            sf3177.cif
_cod_data_source_block           I
_cod_original_cell_volume        2742.3(10)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2018653
_cod_database_fobs_code          2018653