New Ag<sub>8</sub>PtO<sub>6</sub>: synthesis, crystal structure, physical properties and theoretical analyses.
Thakur, Gohil Singh; Reuter, Hans; Rosner, Helge; Fecher, Gerhard H.; Felser, Claudia; Jansen, Martin; Dalton transactions (Cambridge, England : 2003) 48 (2019) 5058–5063; doi:10.1039/c8dt05081c

data_7049343
_publ_section_title
;
 New Ag<sub>8</sub>PtO<sub>6</sub>: synthesis, crystal structure, physical
 properties and theoretical analyses.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5058
_journal_page_last               5063
_journal_paper_doi               10.1039/c8dt05081c
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'Ag8 O6 Pt'
_chemical_formula_weight         1154.05
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                87.373(2)
_cell_angle_beta                 85.141(2)
_cell_angle_gamma                71.754(2)
_cell_formula_units_Z            2
_cell_length_a                   6.1929(2)
_cell_length_b                   6.9679(3)
_cell_length_c                   10.3926(4)
_cell_measurement_reflns_used    9256
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      30.48
_cell_measurement_theta_min      3.62
_cell_volume                     424.29(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0495
_diffrn_reflns_av_unetI/netI     0.0154
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            53858
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.991
_diffrn_reflns_theta_min         3.079
_exptl_absorpt_coefficient_mu    34.446
_exptl_absorpt_correction_T_max  0.379
_exptl_absorpt_correction_T_min  0.069
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SADABS'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    9.033
_exptl_crystal_description       needle
_exptl_crystal_F_000             1004
_exptl_crystal_size_max          0.167
_exptl_crystal_size_mid          0.067
_exptl_crystal_size_min          0.035
_refine_diff_density_max         1.399
_refine_diff_density_min         -1.302
_refine_diff_density_rms         0.203
_refine_ls_extinction_coef       0.00989(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.141
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     140
_refine_ls_number_reflns         2467
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.141
_refine_ls_R_factor_all          0.0143
_refine_ls_R_factor_gt           0.0139
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0096P)^2^+1.1785P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0293
_refine_ls_wR_factor_ref         0.0294
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2421
_reflns_number_total             2467
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt05081c1.cif
_cod_data_source_block           GT_150_0m_a
_cod_depositor_comments          'Adding full bibliography for 7049343.cif.'
_cod_database_code               7049343
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.069
_shelx_estimated_absorpt_t_max   0.379
_shelx_res_checksum              30383
_shelx_hkl_checksum              21390