1,1-Phosphaboration of C[triple bond, length as m-dash]C and C[double bond, length as m-dash]C bonds at gold.
Theulier, Cyril A.; García-Rodeja, Yago; Saffon-Merceron, Nathalie; Miqueu, Karinne; Bouhadir, Ghenwa; Bourissou, Didier; Chemical communications (Cambridge, England) 57 (2021) 347–350; doi:10.1039/d0cc06978g

data_7127523
_publ_section_title
;
 1,1-Phosphaboration of C[triple bond, length as m-dash]C and C[double
 bond, length as m-dash]C bonds at gold.
;
_journal_issue                   3
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              347
_journal_page_last               350
_journal_paper_doi               10.1039/d0cc06978g
_journal_volume                  57
_journal_year                    2021
_chemical_formula_sum            'C39 H36 Au B F12 N P'
_chemical_formula_weight         985.43
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     'dual space'
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-10-06 deposited with the CCDC.	2020-12-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_cell_length_b                   17.7379(9)
_cell_length_c                   29.4924(17)
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_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      27.05
_cell_measurement_theta_min      3.03
_cell_volume                     7951.6(7)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      193(2)
_diffrn_detector_area_resol_mean 10.4167
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker D8-Venture CMOS detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_av_unetI/netI     0.0406
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       21
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_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            112297
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.342
_diffrn_reflns_theta_min         2.860
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    3.826
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6437
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_exptl_crystal_colour            colourless
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_refine_ls_R_factor_all          0.0698
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_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0168P)^2^+21.1946P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0531
_refine_ls_wR_factor_ref         0.0627
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7092
_reflns_number_total             9900
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0cc06978g3.cif
_cod_data_source_block           7
_cod_depositor_comments
'Adding full bibliography for 7127521--7127526.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7127523
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.515
_shelx_estimated_absorpt_t_max   0.580
_exptl_absorpt_special_details
;
SADABS-2016/2 Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_shelx_res_checksum              14192