The oxotungsten(IV) complex [WOCl(Ph~2~PCH~2~CH~2~PPh~2~)~2~]PF~6~^.^CHCl~3~
Llusar, R.; Mata, J.; Peris, E.; Köckerling, M.; Acta Crystallographica Section C 55 (1999) 506–508; doi:10.1107/S0108270198015856

data_2008371
_publ_section_title
;
 The oxotungsten(IV) complex
 [WOCl(Ph~2~PCH~2~CH~2~PPh~2~)~2~]PF~6~^.^CHCl~3~
;
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              506
_journal_page_last               508
_journal_paper_doi               10.1107/S0108270198015856
_journal_volume                  55
_journal_year                    1999
_chemical_formula_iupac          '[W O Cl (C26 H24 P2)2] PF6, CH Cl3'
_chemical_formula_moiety         'C53 H49 Cl4 F6 O P5 W'
_chemical_formula_sum            'C53 H49 Cl4 F6 O P5 W'
_chemical_formula_weight         1296.491
_chemical_name_systematic
;
Chlorobis-[1,2-bis(diphenylphosphino)ethane]oxotungsten(IV)
hexafluorophospate chloroform solvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
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_atom_type_scat_source           'SHELXTL-Plus (Sheldrick, 1990)'
_cell_angle_alpha                105.790(10)
_cell_angle_beta                 106.850(10)
_cell_angle_gamma                91.360(10)
_cell_formula_units_Z            2
_cell_length_a                   11.684(2)
_cell_length_b                   14.943(3)
_cell_length_c                   16.749(3)
_cell_measurement_reflns_used    46
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      22.2
_cell_measurement_theta_min      2.2
_cell_volume                     2676.4(9)
_computing_cell_refinement       XSCANS
_computing_data_collection       'XSCANS (Siemens, 1994)'
_computing_data_reduction        XSCANS
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_computing_publication_material  SHELXTL-Plus
_computing_structure_refinement  SHELXTL-Plus
_computing_structure_solution    'SHELXTL-Plus (Sheldrick, 1990)'
_diffrn_measurement_device_type  'Siemens P4'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_standards_decay_%        none
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_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    2.566
_exptl_absorpt_correction_T_max  0.989
_exptl_absorpt_correction_T_min  0.513
_exptl_absorpt_correction_type   '\y scan'
_exptl_absorpt_process_details   '(SHELXTL-Plus; Sheldrick, 1990)'
_exptl_crystal_colour            orange
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(F) + 0.0001F^2^]'
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_reflns_threshold_expression     F>4\s(F)
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_cod_original_cell_volume        2676.0(10)
_cod_database_code               2008371