N-H cleavage vs. Werner complex formation: reactivity of cationic group 14 tetrelenes towards amines.
Do, Dinh Cao Huan; Protchenko, Andrey V.; Fuentes, M Ángeles; Hicks, Jamie; Vasko, Petra; Aldridge, Simon; Chemical communications (Cambridge, England) 56 (2020) 4684–4687; doi:10.1039/d0cc00875c

data_7126219
_publ_section_title
;
 N-H cleavage vs. Werner complex formation: reactivity of cationic group
 14 tetrelenes towards amines.
;
_journal_issue                   34
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              4684
_journal_page_last               4687
_journal_paper_doi               10.1039/d0cc00875c
_journal_volume                  56
_journal_year                    2020
_chemical_formula_moiety         'C31 H47 N4 Si, C16 Al F36 O4'
_chemical_formula_sum            'C47 H47 Al F36 N4 O4 Si'
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_audit_update_record
;
2020-02-01 deposited with the CCDC.	2020-03-16 downloaded from the CCDC.
;
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43b (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1604P)^2^+10.9465P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7126216--7126223.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7126219
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.391
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_shelx_res_checksum              43879