An Organometallic Methodology Affording Dinuclear Copper(I) Complexes
Euro Solari; Mario Latronico; Philippe Blech; Carlo Floriani; Angiola Chiesi-Villa; Corrado Rizzoli; Inorganic Chemistry 35 (1996) 4526–4528; doi:10.1021/ic960072k

data_4323859
_publ_contact_author
;
     Dr. Corrado Rizzoli
     Dipartimento di Chimica Generale ed Inorganica, 
     Chimica Analitica, Chimica Fisica
     Viale delle Scienze 78
     I-43100 Parma
     Italy
;
_publ_contact_author_email       rizzoli@at@ipruniv.cce.unipr.it
_publ_contact_author_fax         '[039]521 905 556'
_publ_contact_author_phone       '[039]521 905 449'
_publ_section_title
;
 An Organometallic Methodology Affording Dinuclear Copper(I) Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4526
_journal_page_last               4528
_journal_paper_doi               10.1021/ic960072k
_journal_volume                  35
_journal_year                    1996
_chemical_formula_sum            'C91 H86 Cu2 O2 P4'
_chemical_formula_weight         1490.68
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   calculated
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'PARSTCIF: on Quansan Personal Computer'
_cell_angle_alpha                90.00
_cell_angle_beta                 99.05(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2.00
_cell_length_a                   18.612(2)
_cell_length_b                   14.341(1)
_cell_length_c                   14.840(1)
_cell_measurement_radiation      MoK\a
_cell_measurement_reflns_used    25
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      16.6
_cell_measurement_theta_min      11.6
_cell_measurement_wavelength     0.71069
_cell_volume                     3911.7(6)
_computing_cell_refinement       'Belletti et al., 1993'
_computing_data_collection       'Belletti, Cantoni & Pasquinelli,1993'
_computing_data_reduction        'DIFAU (Belletti et al.)'
_computing_structure_refinement  'SHELX76 (Sheldrick,1976)'
_diffrn_ambient_temperature      295(2)
_diffrn_measurement_device       'Philips PW1100 diffractometer'
_diffrn_measurement_method       'profile data from omega/2theta scans'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0152
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            5966
_diffrn_reflns_theta_max         23.0
_diffrn_reflns_theta_min         3.0
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count 100
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.6725
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.2656
_exptl_crystal_description       prism
_exptl_crystal_F_000             1560.0
_exptl_crystal_size_max          0.67
_exptl_crystal_size_mid          0.64
_exptl_crystal_size_min          0.37
_refine_diff_density_max         0.50
_refine_diff_density_min         -0.23
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_obs   0.850
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           fullcycle
_refine_ls_number_parameters     372
_refine_ls_number_reflns         3452
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0523
_refine_ls_R_factor_obs          0.0480
_refine_ls_shift/esd_max         0.35
_refine_ls_shift/esd_mean        0.06
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      unit
_reflns_number_observed          3452
_reflns_number_total             5508
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic960072k_1.cif
_cod_data_source_block           COMPLEX4
_cod_original_cell_volume        3911.71(58)
_cod_database_code               4323859