Hydrosilylative reduction of primary amides to primary amines catalyzed by a terminal [Ni-OH] complex.
Pandey, Pragati; Bera, Jitendra K.; Chemical communications (Cambridge, England) 57 (2021) 9204–9207; doi:10.1039/d1cc03537a

data_7128847
_publ_section_title
;
 Hydrosilylative reduction of primary amides to primary amines catalyzed
 by a terminal [Ni-OH] complex.
;
_journal_issue                   73
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              9204
_journal_page_last               9207
_journal_paper_doi               10.1039/d1cc03537a
_journal_volume                  57
_journal_year                    2021
_chemical_absolute_configuration unk
_chemical_formula_sum            'C36 H48 F6 N6 Ni O5 S2'
_chemical_formula_weight         881.63
_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2019-09-08 deposited with the CCDC.	2021-08-16 downloaded from the CCDC.
;
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_source                   'fine-focus sealed tube'
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_exptl_crystal_description       block
_exptl_crystal_F_000             1840
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.016(15)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0376P)^2^+1.6541P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0890
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_reflns_Friedel_fraction_max     0.999
_reflns_number_gt                8063
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cc03537a2.cif
_cod_data_source_block           Complex1
_cod_depositor_comments
'Adding full bibliography for 7128847--7128851.cif.'
_cod_database_code               7128847
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_exptl_absorpt_special_details   SADABS
_shelx_res_checksum              68701