Influence of the supported ionic-liquid layer thickness on Z-selectivity in 1-alkyne hydrosilylation under continuous flow
Böth, André; Kaltwasser, Florian; Priedigkeit, Christian; Atwi, Boshra; Frey, Wolfgang; Buchmeiser, Michael R.; Tallarek, Ulrich; Catalysis Science & Technology 15 (2025) 4012–4023; doi:10.1039/D5CY00436E

data_1574743
_publ_section_title
;
 Influence of the supported ionic-liquid layer thickness on Z-selectivity
 in 1-alkyne hydrosilylation under continuous flow
;
_journal_issue                   13
_journal_name_full               'Catalysis Science &amp; Technology'
_journal_page_first              4012
_journal_page_last               4023
_journal_paper_doi               10.1039/D5CY00436E
_journal_volume                  15
_journal_year                    2025
_chemical_formula_moiety         'C18 H29 N3 Rh, B F4'
_chemical_formula_sum            'C18 H29 B F4 N3 Rh'
_chemical_formula_weight         477.16
_chemical_name_common            Rh-2
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           'C 2y'
_space_group_name_H-M_alt        'C 1 2 1'
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_audit_update_record
;
2025-04-04 deposited with the CCDC.	2025-05-28 downloaded from the CCDC.
;
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_cell_measurement_temperature    100(2)
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_cell_volume                     2304.9(4)
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.51(7)
_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0359
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0265P)^2^+4.8546P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                5151
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 1574743--1574744.cif.'
_cod_original_cell_volume        2304.9(3)
_cod_original_sg_symbol_H-M      'C 2'
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_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              32962
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