Heterometallic one-dimensional chain with tetradeca metal repetition constructed by amidate bridged dirhodium and pivalate bridged diplatinum complexes influenced by hydrogen bonding.
Yamada, Tomofumi; Ebihara, Masahiro; Uemura, Kazuhiro; Dalton transactions (Cambridge, England : 2003) 45 (2016) 12322–12328; doi:10.1039/c6dt01601d

data_7039524
_publ_section_title
;
 Heterometallic one-dimensional chain with tetradeca metal repetition
 constructed by amidate bridged dirhodium and pivalate bridged diplatinum
 complexes influenced by hydrogen bonding.
;
_journal_issue                   31
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12322
_journal_page_last               12328
_journal_paper_doi               10.1039/c6dt01601d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C32 H76 Cl4 N12 O32 Pt4 Rh3'
_chemical_formula_weight         2371.94
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-03-16 deposited with the CCDC.
2016-06-10 downloaded from the CCDC.
;
_cell_angle_alpha                92.394(6)
_cell_angle_beta                 113.9144(15)
_cell_angle_gamma                112.016(5)
_cell_formula_units_Z            2
_cell_length_a                   14.835(7)
_cell_length_b                   16.985(8)
_cell_length_c                   17.058(8)
_cell_measurement_reflns_used    8267
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.4846
_cell_measurement_theta_min      3.0058
_cell_volume                     3546(3)
_computing_cell_refinement       CRYSTALCLEAR
_computing_data_collection       CRYSTALCLEAR
_computing_data_reduction        CRYSTALCLEAR
_computing_molecular_graphics
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_publication_material
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 14.6199
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  'Graphite Monochromator'
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.1005
_diffrn_reflns_av_sigmaI/netI    0.1739
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            28943
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.01
_exptl_absorpt_coefficient_mu    8.774
_exptl_absorpt_correction_T_max  0.8441
_exptl_absorpt_correction_T_min  0.1656
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    2.221
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2246
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.02
_refine_diff_density_max         3.195
_refine_diff_density_min         -3.252
_refine_diff_density_rms         0.300
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     893
_refine_ls_number_reflns         16060
_refine_ls_number_restraints     170
_refine_ls_restrained_S_all      1.001
_refine_ls_R_factor_all          0.1470
_refine_ls_R_factor_gt           0.0842
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0630P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1815
_refine_ls_wR_factor_ref         0.2229
_reflns_number_gt                8434
_reflns_number_total             16060
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6dt01601d2.cif
_cod_data_source_block           complex4
_cod_depositor_comments          'Adding full bibliography for 7039524.cif.'
_cod_database_code               7039524