Arylation of gold nanoclusters and insights into structure-related CO2 reduction reaction performances
Zhu, Chen; Li, Bo; Li, Chen; Lu, Luyao; Li, Hao; Yuan, Xinhua; Kang, Xi; Jiang, De-en; Zhu, Manzhou; Chemical Science 16 (2025) 10273–10281; doi:10.1039/D5SC01200G

data_1574606
_publ_section_title
;
 Arylation of gold nanoclusters and insights into structure-related CO2
 reduction reaction performances
;
_journal_issue                   23
_journal_name_full               'Chemical Science'
_journal_page_first              10273
_journal_page_last               10281
_journal_paper_doi               10.1039/D5SC01200G
_journal_volume                  16
_journal_year                    2025
_chemical_formula_moiety         'C148 H120 Au15 F2 O3 P6 S4, C24 H16 B F4'
_chemical_formula_sum            'C172 H136 Au15 B F6 O3 P6 S4'
_chemical_formula_weight         5644.17
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2023-09-19
_audit_creation_method
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_audit_update_record
;
2025-04-10 deposited with the CCDC.	2025-05-06 downloaded from the CCDC.
;
_cell_angle_alpha                99.314(7)
_cell_angle_beta                 101.816(7)
_cell_angle_gamma                97.815(7)
_cell_formula_units_Z            2
_cell_length_a                   16.7395(14)
_cell_length_b                   22.413(2)
_cell_length_c                   23.670(2)
_cell_measurement_reflns_used    10134
_cell_measurement_temperature    120
_cell_measurement_theta_max      68.79
_cell_measurement_theta_min      2.76
_cell_volume                     8445.3(13)
_computing_cell_refinement
;
X-Area Recipe 1.37.0.0 (STOE, 2021)
;
_computing_data_collection
;
X-Area Pilatus3_SV 1.31.175.0 (STOE, 2021)
;
_computing_data_reduction
;
X-Area Integrate 2.5.1.0 (STOE, 2021)
X-Area LANA 2.6.2.0 (STOE, 2021)
;
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material
;
STOE & Cie GmbH, X-Area, software package for collecting single-crystal or
multi-domain crystal data on STOE area-detector diffractometers, for image 
processing, for the correction and scaling of reflection intensities and 
for outlier rejection, version 2.0, Darmstadt 2021
;
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      120
_diffrn_detector                 Pilatus300K
_diffrn_detector_area_resol_mean 5.81
_diffrn_detector_type            'DECTRIS PILATUS 300K'
_diffrn_measured_fraction_theta_full 0.955
_diffrn_measured_fraction_theta_max 0.955
_diffrn_measurement_details      '1465 frames, detector distance = 60 mm'
_diffrn_measurement_device       'Eulerian 4-circle diffractometer'
_diffrn_measurement_device_type  'STOE STADIVARI'
_diffrn_measurement_method       'rotation method, \w scans'
_diffrn_radiation_collimation    '1.2 mm, 0.6 diameter'
_diffrn_radiation_monochromator  'Graded multilayer mirror'
_diffrn_radiation_polarisn_norm  270
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54186
_diffrn_reflns_av_R_equivalents  0.0890
_diffrn_reflns_av_unetI/netI     0.0986
_diffrn_reflns_Laue_measured_fraction_full 0.955
_diffrn_reflns_Laue_measured_fraction_max 0.955
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            50636
_diffrn_reflns_point_group_measured_fraction_full 0.955
_diffrn_reflns_point_group_measured_fraction_max 0.955
_diffrn_reflns_theta_full        62.498
_diffrn_reflns_theta_max         62.498
_diffrn_reflns_theta_min         4.208
_diffrn_source                   'GeniX 3D HF Cu'
_diffrn_source_current           0.600
_diffrn_source_power             0.030
_diffrn_source_voltage           50
_exptl_absorpt_coefficient_mu    25.249
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  1.0000
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
STOE LANA, absorption correction by scaling of reflection intensities.
J. Koziskova, F. Hahn, J. Richter, J. Kozisek, "Comparison of different
absorption corrections on the model structure of tetrakis(\m~2~-acetato)-
diaqua-di-copper(II)", Acta Chimica Slovaca, vol. 9, no. 2, 2016, pp. 136 - 140.
;
_exptl_crystal_colour            'metallic blackish black'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   blackish
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    2.220
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       cube
_exptl_crystal_F_000             5180
_refine_diff_density_max         4.857
_refine_diff_density_min         -2.679
_refine_diff_density_rms         0.325
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.941
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1532
_refine_ls_number_reflns         25743
_refine_ls_number_restraints     2065
_refine_ls_restrained_S_all      0.912
_refine_ls_R_factor_all          0.1101
_refine_ls_R_factor_gt           0.0746
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1244P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1878
_refine_ls_wR_factor_ref         0.2040
_reflns_Friedel_coverage         0.000
_reflns_number_gt                15498
_reflns_number_total             25743
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5sc01200g2.cif
_cod_data_source_block           1_CCDC1
_cod_depositor_comments
'Adding full bibliography for 1574605--1574607.cif.'
_cod_original_cell_volume        8445.0(13)
_cod_database_code               1574606
_shelx_shelxl_version_number     2018/3
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Rigid bond restraints
 C56, F30
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
3. Uiso/Uaniso restraints and constraints
C00V \\sim C00X \\sim C00Y \\sim C00Z \\sim C010 \\sim C011 \\sim C012 \\sim
C013 \\sim C014 \\sim C015 \\sim C016 \\sim C017 \\sim C018 \\sim C019 \\sim
C01A \\sim C01B \\sim C01C \\sim C01D \\sim C01E \\sim C01F \\sim C01G \\sim
C01H \\sim C01I \\sim C01J \\sim C01K \\sim C01L \\sim C01M \\sim C01N \\sim
C01O \\sim C01P \\sim C01Q \\sim C01R \\sim C01S \\sim C01T \\sim C01U \\sim
C01V \\sim C01W \\sim C01X \\sim C01Y \\sim C01Z \\sim C020 \\sim C021 \\sim
C022 \\sim C023 \\sim C024 \\sim C025 \\sim C026 \\sim C027 \\sim C028 \\sim
C029 \\sim C02A \\sim C02B \\sim C02C \\sim C02D \\sim C02E \\sim C02F \\sim
C02G \\sim C02H \\sim C02I \\sim C02J \\sim C02K \\sim C02L \\sim C02M \\sim
C02N \\sim C02O \\sim C02P \\sim C02Q \\sim C02R \\sim C02S \\sim C02T \\sim
C02U \\sim C02V \\sim C02W \\sim C02X \\sim C02Y \\sim C02Z \\sim C030 \\sim
C031 \\sim C032 \\sim C033 \\sim C034 \\sim C035 \\sim C036 \\sim C037 \\sim
C038 \\sim C039 \\sim C03A \\sim C03B \\sim C03D \\sim C03E \\sim C03F \\sim
C03G \\sim C03H \\sim C03I \\sim C03J \\sim C03K \\sim C03L \\sim C03M \\sim
C03N \\sim C03O \\sim C03P \\sim C03Q \\sim C03R \\sim C03S \\sim C03T \\sim
C03U \\sim C03V \\sim C03W \\sim C03X \\sim C03Y \\sim C03Z \\sim C040 \\sim
C041 \\sim C042 \\sim C043 \\sim C044 \\sim C045 \\sim C046 \\sim C047 \\sim
C048 \\sim C04C \\sim C04D \\sim C04F \\sim C04G \\sim C04H \\sim C04I \\sim
C04J \\sim C04K \\sim C04P \\sim C04R \\sim C051 \\sim C24 \\sim C26 \\sim C27
\\sim C5 \\sim C29 \\sim C32 \\sim C33 \\sim C36 \\sim C37 \\sim C39 \\sim C40
\\sim C41 \\sim C42 \\sim C45 \\sim C50 \\sim C54 \\sim C55 \\sim C60 \\sim C61
\\sim C62 \\sim C68 \\sim C81 \\sim C82 \\sim C95 \\sim C101 \\sim C138 \\sim
C139 \\sim C155 \\sim C38 \\sim C56 \\sim C87 \\sim C99 \\sim C44 \\sim C49
\\sim C2 \\sim C4 \\sim C179 \\sim C48 \\sim C1 \\sim C3 \\sim C51: within 2A
with sigma of 0.01 and sigma for terminal atoms of 0.02 within 2A
Uanis(C00V) \\sim Ueq, Uanis(C00X) \\sim Ueq, Uanis(C00Y) \\sim Ueq,
Uanis(C00Z) \\sim Ueq, Uanis(C010) \\sim Ueq, Uanis(C011) \\sim Ueq,
Uanis(C012) \\sim Ueq, Uanis(C013) \\sim Ueq, Uanis(C014) \\sim Ueq,
Uanis(C015) \\sim Ueq, Uanis(C016) \\sim Ueq, Uanis(C017) \\sim Ueq,
Uanis(C018) \\sim Ueq, Uanis(C019) \\sim Ueq, Uanis(C01A) \\sim Ueq,
Uanis(C01B) \\sim Ueq, Uanis(C01C) \\sim Ueq, Uanis(C01D) \\sim Ueq,
Uanis(C01E) \\sim Ueq, Uanis(C01F) \\sim Ueq, Uanis(C01G) \\sim Ueq,
Uanis(C01H) \\sim Ueq, Uanis(C01I) \\sim Ueq, Uanis(C01J) \\sim Ueq,
Uanis(C01K) \\sim Ueq, Uanis(C01L) \\sim Ueq, Uanis(C01M) \\sim Ueq,
Uanis(C01N) \\sim Ueq, Uanis(C01O) \\sim Ueq, Uanis(C01P) \\sim Ueq,
Uanis(C01Q) \\sim Ueq, Uanis(C01R) \\sim Ueq, Uanis(C01S) \\sim Ueq,
Uanis(C01T) \\sim Ueq, Uanis(C01U) \\sim Ueq, Uanis(C01V) \\sim Ueq,
Uanis(C01W) \\sim Ueq, Uanis(C01X) \\sim Ueq, Uanis(C01Y) \\sim Ueq,
Uanis(C01Z) \\sim Ueq, Uanis(C020) \\sim Ueq, Uanis(C021) \\sim Ueq,
Uanis(C022) \\sim Ueq, Uanis(C023) \\sim Ueq, Uanis(C024) \\sim Ueq,
Uanis(C025) \\sim Ueq, Uanis(C026) \\sim Ueq, Uanis(C027) \\sim Ueq,
Uanis(C028) \\sim Ueq, Uanis(C029) \\sim Ueq, Uanis(C02A) \\sim Ueq,
Uanis(C02B) \\sim Ueq, Uanis(C02C) \\sim Ueq, Uanis(C02D) \\sim Ueq,
Uanis(C02E) \\sim Ueq, Uanis(C02F) \\sim Ueq, Uanis(C02G) \\sim Ueq,
Uanis(C02H) \\sim Ueq, Uanis(C02I) \\sim Ueq, Uanis(C02J) \\sim Ueq,
Uanis(C02K) \\sim Ueq, Uanis(C02L) \\sim Ueq, Uanis(C02M) \\sim Ueq,
Uanis(C02N) \\sim Ueq, Uanis(C02O) \\sim Ueq, Uanis(C02P) \\sim Ueq,
Uanis(C02Q) \\sim Ueq, Uanis(C02R) \\sim Ueq, Uanis(C02S) \\sim Ueq,
Uanis(C02T) \\sim Ueq, Uanis(C02U) \\sim Ueq, Uanis(C02V) \\sim Ueq,
Uanis(C02W) \\sim Ueq, Uanis(C02X) \\sim Ueq, Uanis(C02Y) \\sim Ueq,
Uanis(C02Z) \\sim Ueq, Uanis(C030) \\sim Ueq, Uanis(C031) \\sim Ueq,
Uanis(C032) \\sim Ueq, Uanis(C033) \\sim Ueq, Uanis(C034) \\sim Ueq,
Uanis(C035) \\sim Ueq, Uanis(C036) \\sim Ueq, Uanis(C037) \\sim Ueq,
Uanis(C038) \\sim Ueq, Uanis(C039) \\sim Ueq, Uanis(C03A) \\sim Ueq,
Uanis(C03B) \\sim Ueq, Uanis(C03D) \\sim Ueq, Uanis(C03E) \\sim Ueq,
Uanis(C03F) \\sim Ueq, Uanis(C03G) \\sim Ueq, Uanis(C03H) \\sim Ueq,
Uanis(C03I) \\sim Ueq, Uanis(C03J) \\sim Ueq, Uanis(C03K) \\sim Ueq,
Uanis(C03L) \\sim Ueq, Uanis(C03M) \\sim Ueq, Uanis(C03N) \\sim Ueq,
Uanis(C03O) \\sim Ueq, Uanis(C03P) \\sim Ueq, Uanis(C03Q) \\sim Ueq,
Uanis(C03R) \\sim Ueq, Uanis(C03S) \\sim Ueq, Uanis(C03T) \\sim Ueq,
Uanis(C03U) \\sim Ueq, Uanis(C03V) \\sim Ueq, Uanis(C03W) \\sim Ueq,
Uanis(C03X) \\sim Ueq, Uanis(C03Y) \\sim Ueq, Uanis(C03Z) \\sim Ueq,
Uanis(C040) \\sim Ueq, Uanis(C041) \\sim Ueq, Uanis(C042) \\sim Ueq,
Uanis(C043) \\sim Ueq, Uanis(C044) \\sim Ueq, Uanis(C045) \\sim Ueq,
Uanis(C046) \\sim Ueq, Uanis(C047) \\sim Ueq, Uanis(C048) \\sim Ueq,
Uanis(C04C) \\sim Ueq, Uanis(C04D) \\sim Ueq, Uanis(C04F) \\sim Ueq,
Uanis(C04G) \\sim Ueq, Uanis(C04H) \\sim Ueq, Uanis(C04I) \\sim Ueq,
Uanis(C04J) \\sim Ueq, Uanis(C04K) \\sim Ueq, Uanis(C04P) \\sim Ueq,
Uanis(C04R) \\sim Ueq, Uanis(C051) \\sim Ueq, Uanis(C24) \\sim Ueq, Uanis(C26)
\\sim Ueq, Uanis(C27) \\sim Ueq, Uanis(C5) \\sim Ueq, Uanis(C29) \\sim Ueq,
Uanis(C32) \\sim Ueq, Uanis(C33) \\sim Ueq, Uanis(C36) \\sim Ueq, Uanis(C37)
\\sim Ueq, Uanis(C39) \\sim Ueq, Uanis(C40) \\sim Ueq, Uanis(C41) \\sim Ueq,
Uanis(C42) \\sim Ueq, Uanis(C45) \\sim Ueq, Uanis(C50) \\sim Ueq, Uanis(C54)
\\sim Ueq, Uanis(C55) \\sim Ueq, Uanis(C60) \\sim Ueq, Uanis(C61) \\sim Ueq,
Uanis(C62) \\sim Ueq, Uanis(C68) \\sim Ueq, Uanis(C81) \\sim Ueq, Uanis(C82)
\\sim Ueq, Uanis(C95) \\sim Ueq, Uanis(C101) \\sim Ueq, Uanis(C138) \\sim Ueq,
Uanis(C139) \\sim Ueq, Uanis(C155) \\sim Ueq, Uanis(C38) \\sim Ueq, Uanis(C56)
\\sim Ueq, Uanis(C87) \\sim Ueq, Uanis(C99) \\sim Ueq, Uanis(C44) \\sim Ueq,
Uanis(C49) \\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C4) \\sim Ueq, Uanis(C179)
\\sim Ueq, Uanis(C48) \\sim Ueq, Uanis(C1) \\sim Ueq, Uanis(C3) \\sim Ueq,
Uanis(C51) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
4.a Aromatic/amide H refined with riding coordinates:
 C026(H026), C03P(H03P), C03D(H03D), C020(H020), C01I(H01I), C01E(H01E),
 C02X(H02X), C019(H019), C031(H031), C03E(H03E), C032(H032), C04G(H04G),
 C03G(H03G), C015(H015), C037(H037), C03Q(H03Q), C043(H043), C00Z(H00Z),
 C010(H010), C03X(H03X), C03B(H03B), C02T(H02T), C01H(H01H), C04D(H04D),
 C27(H27), C028(H028), C01R(H01R), C02L(H02L), C02Y(H02Y), C02H(H02H),
 C029(H029), C02C(H02C), C01Y(H01Y), C021(H021), C012(H012), C018(H018),
 C01A(H01A), C045(H045), C03N(H03N), C044(H044), C03F(H03F), C02A(H02A),
 C040(H040), C02Q(H02Q), C01P(H01P), C025(H025), C02M(H02M), C03H(H03H),
 C051(H051), C04P(H04P), C03T(H03T), C02E(H02E), C01B(H01B), C01F(H01F),
 C022(H022), C02G(H02G), C01K(H01K), C03L(H03L), C02V(H02V), C04H(H04H),
 C02I(H02I), C01N(H01N), C01M(H01M), C01G(H01G), C02D(H02D), C03I(H03I),
 C01D(H01D), C01Z(H01Z), C03V(H03V), C03M(H03M), C03Z(H03Z), C03J(H03J),
 C048(H048), C02J(H02K), C033(H033), C016(H016), C32(H32), C046(H046), C42(H42),
  C33(H33), C03S(H03S), C039(H039), C02O(H02O), C03Y(H03Y), C038(H038),
 C03A(H03O), C02R(H02R), C03K(H03R), C04I(H04I), C5(H5), C24(H24), C39(H39),
 C87(H87), C40(H40), C36(H36), C041(H041), C60(H60), C034(H034), C02F(H02N),
 C04C(H04E), C138(H138), C99(H99), C139(H139), C41(H41), C04R(H04R), C03U(H03U),
  C62(H62), C101(H101), C95(H95), C55(H55), C68(H68), C38(H38), C29(H29),
 C2(H2), C155(H155), C44(H44), C036(H036), C02P(H02P), C04F(H04F), C49(H49),
 C179(H179), C48(H48), C3(H3), C51(H51)
4.b Fitted hexagon refined as free rotating group:
 C00Y(C026,C03P,C03D,C020,C01X), C011(C01I,C01E,C02X,C019,C031), C013(C03E,
 C032,C04G,C03G,C015), C014(C01U,C037,C03Q,C043,C00Z), C01J(C010,C03X,C04J,C03B,
 C02T), C01O(C00X,C01H,C04D,C27,C028), C01R(C02L,C02Y,C01T,C02H,C029),
 C01S(C02C,C01Y,C021,C012,C018), C01V(C01A,C045,C03N,C044,C03F), C024(C02A,C040,
 C02Q,C01P,C025), C02B(C02M,C03H,C051,C04P,C03T), C02E(C01C,C01B,C01F,C027,
 C022), C02G(C017,C01K,C03L,C02V,C04H), C02I(C01N,C030,C01M,C01G,C03R),
 C02N(C02D,C03I,C01D,C01Z,C02K), C02W(C03V,C03M,C01L,C03Z,C03J), C02Z(C048,C02J,
 C033,C016,C01W), C03O(C32,C046,C42,C33,C03W), C03S(C039,C02O,C03Y,C038,C01Q),
 C042(C03A,C02R,C00V,C03K,C04I), C5(C24,C26,C39,C87,C40), C36(C041,C45,C60,C034,
 C023), C54(C02F,C04C,C138,C99,C139), C61(C41,C04R,C50,C03U,C62), C101(C95,C82,
 C55,C68,C04K), C56(C38,C29,C37,C2,C155), C44(C02S,C036,C02P,C04F,C49), C4(C179,
 C48,C1,C3,C51)
4.c Idealised Me refined as rotating group:
 C02U(H02B,H02F,H02J), C035(H03A,H03C,H03K), C047(H04A,H04B,H04C), C81(H81A,
 H81B,H81C)
;
_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_shelx_res_checksum              33869
_shelx_fab_checksum              45078
_olex2_submission_special_instructions 'No special instructions were received'
_stoe_detector_distance          '60.0 mm'
_stoe_detector_pixelsize_x       '0.172 mm'
_stoe_detector_pixelsize_y       '0.172 mm'
_stoe_detector_size_x            '8.4 cm'
_stoe_detector_size_y            '10.6 cm'
_stoe_evaluation_integration_a   6.0
_stoe_evaluation_integration_b   0.5
_stoe_evaluation_integration_ems 0.010
_stoe_evaluation_lana_bis_l_even_max -
_stoe_evaluation_lana_bis_l_odd_max -
_stoe_evaluation_lana_bos_l_even_max 4
_stoe_evaluation_lana_bos_l_odd_max 1
_stoe_evaluation_lana_completeness 91.4
_stoe_evaluation_lana_dxs_max_order 3
_stoe_evaluation_lana_dys_max_order 3
_stoe_evaluation_lana_fs_max_order 3
_stoe_evaluation_lana_max_2theta_available 139.9
_stoe_evaluation_lana_max_2theta_desired 139.9
_stoe_evaluation_lana_mean_redundancy 1.9
_stoe_evaluation_lana_number_refls_after_or 56176
_stoe_evaluation_lana_number_refls_outliers 3859
_stoe_evaluation_lana_number_refls_total 60035
_stoe_evaluation_lana_number_refls_unique 29237
_stoe_evaluation_lana_number_refls_written 56176
_stoe_evaluation_lana_or_c1      0.035
_stoe_evaluation_lana_or_c2      0
_stoe_evaluation_lana_or_c3      0
_stoe_evaluation_lana_or_c4      0.7
_stoe_evaluation_lana_point_group -1
_stoe_evaluation_lana_table
;
2Theta          14.9   29.7   44.5   59.3   74.1   88.9  103.7  118.5  133.3
<Resolution>    4.89   2.88   2.01   1.55   1.26   1.10   0.98   0.90   0.85
N(total)         299   1442   2747   3535  10981  12778  12476  10714   5063
<Redundancy>     1.3    1.5    1.4    1.2    2.4    2.3    2.1    1.9    1.6
Complet. [%%]    82.6   95.0   92.3   89.7   94.9   98.9   97.8   95.8   67.2
<I/sigma>       40.3   36.6   31.4   10.5    6.2    3.7    2.3    2.9    2.3
R(int)         0.102  0.066  0.062  0.091  0.070  0.094  0.152  0.128  0.177
;
_stoe_measurement_identifier     1
_stoe_measurement_max_exposure_per_frame '35.0 s'
_stoe_measurement_mean_exposure_per_frame '28.7 s'
_stoe_measurement_min_exposure_per_frame '5.0 s'
_stoe_measurement_total_exposure_time '11.7 h'
_stoe_measurement_total_frame_number 1465
_stoe_measurement_total_run_number 30
_stoe_measurement_tube_power     '30.0 W'