Solvent-free ageing reactions of rare earth element oxides: from geomimetic synthesis of new metal‒organic materials towards a simple, environmentally friendly separation of scandium
Huskić, Igor; Arhangelskis, Mihails; Friščić, Tomislav; Green Chemistry 22 (2020) 4364–4375; doi:10.1039/D0GC00454E

data_7240494
_publ_section_title
;
 Solvent-free ageing reactions of rare earth element oxides: from
 geomimetic synthesis of new metal--organic materials towards a simple,
 environmentally friendly separation of scandium
;
_journal_issue                   13
_journal_name_full               'Green Chemistry'
_journal_page_first              4364
_journal_page_last               4375
_journal_paper_doi               10.1039/D0GC00454E
_journal_volume                  22
_journal_year                    2020
_chemical_compound_source        synthetic
_chemical_formula_sum            'C6 H6 Gd K3 O15'
_chemical_formula_weight         592.66
_chemical_name_systematic        'Tripotassium gadolinium oxalate trihydrate'
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_audit_update_record
;
2019-11-04 deposited with the CCDC.	2020-05-08 downloaded from the CCDC.
;
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_cell_measurement_temperature    100(2)
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_cell_volume                     759.45(12)
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_diffrn_measurement_method       'omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_source                   'sealed x-ray tube'
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_refine_ls_R_factor_all          0.0210
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0178P)^2^+0.2778P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0369
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                5474
_reflns_number_total             5886
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0gc00454e1.cif
_cod_data_source_block           K3GdOx3
_cod_depositor_comments
;Adding full bibliography for 7240489--7240496.cif.

 Adding full bibliography for 7240489--7240496.cif.
;
_cod_database_code               7240494
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              31086