Tris[triphenylantimony(V)]hexa(μ-oxido)tellurium(VI): a molecular complex with six Te—O—Sb bridges
Domasevitch, Kostiantyn V.; Senchyk, Ganna A.; Acta Crystallographica Section E 77 (2021) 1229–1233; doi:10.1107/S2056989021011294

data_2243974
_publ_section_title
;
 Tris[triphenylantimony(V)]hexa(\m-oxido)tellurium(VI): a molecular
 complex with six Te---O---Sb bridges
;
_journal_coeditor_code           CQ2048
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              1229
_journal_page_last               1233
_journal_paper_doi               10.1107/S2056989021011294
_journal_volume                  77
_journal_year                    2021
_chemical_formula_iupac          '[Sb3 Te (C6 H5)9 O6]'
_chemical_formula_moiety         'C54 H45 O6 Sb3 Te'
_chemical_formula_sum            'C54 H45 O6 Sb3 Te'
_chemical_formula_weight         1282.75
_chemical_name_common
;
Tris[triphenylantimony(V)]-hexa-(\m-oxido)tellurate(VI)
;
_chemical_name_systematic
Hexa-\m-oxido-1:2\k^4^<i>O</i>:<i>O</i>;1:3\k^4^<i>O</i>:<i>O</i>;1:4\k^4^<i>O</i>:<i>O</i>-nonaphenyl-2\k^3^<i>C</i>,3\k^3^<i>C</i>,4\k^3^<i>C</i>-triantimony(V)tellurium(VI)
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
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_cell_angle_gamma                90
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_cell_measurement_temperature    173(2)
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_computing_cell_refinement
;
<i>IPDS Software</i> (Stoe & Cie, 2000)
;
_computing_data_collection
;
<i>IPDS Software</i> (Stoe & Cie, 2000)
;
_computing_data_reduction
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<i>IPDS Software</i> (Stoe & Cie, 2000)
;
_computing_molecular_graphics
;
DIAMOND  (Brandenburg, 1999)
;
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WinGX (Farrugia, 2012)
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<i>SHELXL2018/1</i> (Sheldrick, 2015)
;
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;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.997
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_diffrn_measurement_device_type  'Stoe IPDS'
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;
[X-RED (Stoe & Cie, 2001) and X-SHAPE (Stoe & Cie, 1999)]
;
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_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.210
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_refine_ls_number_restraints     0
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0636P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_refine_ls_wR_factor_ref         0.0963
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            cq2048sup1.cif
_cod_data_source_block           I
_cod_original_cell_volume        9672.9(8)
_cod_original_sg_symbol_H-M      'C 2/c'
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_shelx_estimated_absorpt_t_min   0.565
_shelx_estimated_absorpt_t_max   0.643
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