Palladium-Catalyzed Synthesis of Spiro[2.4]heptanes: Ligand-Dependent Position Control in the Nucleophilic Attack to a π-Allylpalladium Intermediate
Ryo Shintani; Soyoung Park; Tamio Hayashi; Journal of the American Chemical Society 129 (2007) 14866–14867; doi:10.1021/ja077236o

data_4110267
_publ_section_title
;
 Palladium-Catalyzed Synthesis of Spiro[2.4]heptanes: Ligand-Dependent
 Position Control in the Nucleophilic Attack to a \p-Allylpalladium
 Intermediate
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              14866
_journal_page_last               14867
_journal_paper_doi               10.1021/ja077236o
_journal_volume                  129
_journal_year                    2007
_chemical_formula_moiety         'C21 H22 O4 '
_chemical_formula_sum            'C21 H22 O4'
_chemical_formula_weight         338.40
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_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
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_cell_angle_gamma                90.0000
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_cell_length_b                   11.794(5)
_cell_length_c                   16.099(7)
_cell_measurement_reflns_used    12191
_cell_measurement_temperature    123.1
_cell_measurement_theta_max      27.6
_cell_measurement_theta_min      3.1
_cell_volume                     3416(3)
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_computing_publication_material  'CrystalStructure 3.8.0'
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_diffrn_detector_area_resol_mean 10.00
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_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details
'w = 1/[0.0010Fo^2^ + 3.0000\s(Fo^2^) + 0.5000]'
_refine_ls_weighting_scheme      calc
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