A new type of photomagnetic system: photoinduced charge transfer in polyoxometalate-based organic-inorganic hybrid.
Gao, Qiao; Li, Fengyan; Sun, Zhixia; Xu, Lin; Sun, Minghui; Dalton transactions (Cambridge, England : 2003) 45 (2016) 2422–2425; doi:10.1039/c5dt03748d

data_7037860
_publ_section_title
;
 A new type of photomagnetic system: photoinduced charge transfer in
 polyoxometalate-based organic-inorganic hybrid.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2422
_journal_page_last               2425
_journal_paper_doi               10.1039/c5dt03748d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C12 H106 Mo12 N12 O79 V2'
_chemical_formula_weight         2936.25
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
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_audit_creation_method           SHELXL-97
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;
2015-12-23 deposited with the CCDC.
2016-01-05 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
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_cell_length_b                   28.1745(14)
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_cell_volume                     16611.1(14)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
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_diffrn_radiation_source         'fine-focus sealed tube'
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_diffrn_reflns_av_unetI/netI     0.0918
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_exptl_absorpt_coefficient_mu    2.090
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2002)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.348
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             11552
_exptl_crystal_size_max          0.6
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;
;
_refine_diff_density_max         4.517
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0940P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1626
_refine_ls_wR_factor_ref         0.1774
_reflns_number_gt                20085
_reflns_number_total             33646
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5dt03748d2.cif
_cod_data_source_block           x
_cod_depositor_comments          'Adding full bibliography for 7037860.cif.'
_cod_database_code               7037860
_shelx_res_checksum              37742
_platon_squeeze_void_probe_radius 1.20