Unprecedented Formation of μ-Vinylidene Complexes from Phospharuthenocene and Acyl Chloride via Activation of the CO Double Bond
Ogasawara, Masamichi; Sakamoto, Takeshi; Ito, Azumi; Ge, Yonghui; Nakajima, Kiyohiko; Takahashi, Tamotsu; Hayashi, Tamio; Organometallics 26 (2007) 6698–; doi:10.1021/om701063k

data_4074102
_publ_section_title
;
 Unprecedented Formation of \m-Vinylidene Complexes from
 Phospharuthenocene and Acyl Chloride via Activation of the C&#xE5FB;O
 Double Bond
;
_journal_issue                   27
_journal_name_full               Organometallics
_journal_page_first              6698
_journal_paper_doi               10.1021/om701063k
_journal_volume                  26
_journal_year                    2007
_chemical_formula_moiety         'C30 H45 O2 P Ru '
_chemical_formula_sum            'C30 H45 O2 P Ru'
_chemical_formula_weight         569.73
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                69.891(12)
_cell_angle_beta                 81.569(13)
_cell_angle_gamma                62.002(11)
_cell_formula_units_Z            4
_cell_length_a                   13.829(4)
_cell_length_b                   13.881(3)
_cell_length_c                   18.137(7)
_cell_measurement_reflns_used    23050
_cell_measurement_temperature    298.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     2886.3(16)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.953
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.027
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            26965
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.622
_exptl_absorpt_correction_T_max  0.883
_exptl_absorpt_correction_T_min  0.688
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
    Higashi, T. (1995). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.311
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1200.00
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.34
_refine_diff_density_min         -1.48
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.460
_refine_ls_number_parameters     635
_refine_ls_number_reflns         12587
_refine_ls_R_factor_gt           0.0537
_refine_ls_shift/su_max          0.0091
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details
'w = 1/[0.0030Fo^2^ + 1.0000\s(Fo^2^) + 2.0000]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1218
_reflns_number_gt                10156
_reflns_number_total             12587
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om701063k-file003.cif
_cod_data_source_block           '_tt34'
_cod_original_cell_volume        2886.2(16)
_cod_original_formula_sum        'C30 H45 O2 P Ru '
_cod_database_code               4074102