Substituent effects of N4 Schiff base ligands on the formation of fluoride-bridged dicobalt(ii) complexes via B-F abstraction: structures and magnetism.
Cho, Yae In; Ward, Meredith L.; Rose, Michael J.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 13466–13476; doi:10.1039/c6dt02104b

data_7040158
_publ_section_title
;
 Substituent effects of N4 Schiff base ligands on the formation of
 fluoride-bridged dicobalt(ii) complexes via B-F abstraction: structures
 and magnetism.
;
_journal_issue                   34
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13466
_journal_page_last               13476
_journal_paper_doi               10.1039/c6dt02104b
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C20 H30 Cl2 Co N6 O10'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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;
2016-07-25 deposited with the CCDC.
2016-08-01 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker Nonius Kappa CCD'
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_diffrn_reflns_Laue_measured_fraction_full 0.998
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_exptl_absorpt_coefficient_mu    0.884
_exptl_crystal_colour            'reddish pink'
_exptl_crystal_density_diffrn    1.561
_exptl_crystal_description       needles
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_exptl_crystal_size_max          0.2
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_exptl_crystal_size_min          0.2
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0319P)^2^+2.9486P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                4824
_reflns_number_total             6205
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           5-ClO4
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'Adding full bibliography for 7040154--7040158.cif.'
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