Divergent Synthesis of 2-Aminofurans via Palladium-Catalyzed Acetoxylative, Alkoxylative, and Hydroxylative Cycloisomerization of Homoallenyl Amides.
Cheng, Cungui; Liu, Shuiyou; Zhu, Gangguo; The Journal of organic chemistry 80 (2015) 7604–7612; doi:10.1021/acs.joc.5b01182

data_4031284
_publ_section_title
;
 Divergent Synthesis of 2-Aminofurans via Palladium-Catalyzed
 Acetoxylative, Alkoxylative, and Hydroxylative Cycloisomerization of
 Homoallenyl Amides.
;
_journal_issue                   15
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              7604
_journal_page_last               7612
_journal_paper_doi               10.1021/acs.joc.5b01182
_journal_volume                  80
_journal_year                    2015
_chemical_formula_moiety         C18H25NO4S
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_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
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_exptl_crystal_colour            colourless
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1845
_refine_ls_wR_factor_ref         0.2045
_reflns_number_gt                3154
_reflns_number_total             4428
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            jo5b01182_si_003.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 4031283--4031284.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4031284