The crystal structure of ((cyclohexylamino){(<i>Z</i>)-2-[(<i>E</i>)-5-methoxy-3-nitro-2-oxidobenzylidene-κ<i>O</i>]hydrazin-1-ylidene-κ<i>N</i>^2^}methanethiolato-κ<i>S</i>)(dimethyl sulfoxide-κ<i>S</i>)platinum(II): a supramolecular two-dimensional network
Arafath, Md. Azharul; Kwong, Huey Chong; Adam, Farook; Acta Crystallographica Section E 75 (2019) 1486–1489; doi:10.1107/S2056989019012623

data_2243613
_publ_section_title
;
 The crystal structure of
 ((cyclohexylamino){(<i>Z</i>)-2-[(<i>E</i>)-5-methoxy-3-nitro-2-oxidobenzylidene-\k<i>O</i>]hydrazin-1-ylidene-\k<i>N</i>^2^}methanethiolato-\k<i>S</i>)(dimethyl
 sulfoxide-\k<i>S</i>)platinum(II): a supramolecular two-dimensional
 network
;
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              1486
_journal_page_last               1489
_journal_paper_doi               10.1107/S2056989019012623
_journal_volume                  75
_journal_year                    2019
_chemical_formula_iupac          '[Pt (C15 H18 N4 O4 S) (C2 H6 O S)]'
_chemical_formula_moiety         'C17 H24 N4 O5 Pt S2'
_chemical_formula_sum            'C17 H24 N4 O5 Pt S2'
_chemical_formula_weight         623.61
_chemical_name_systematic
'((Cyclohexylamino){(<i>Z</i>)-2-[(<i>E</i>)-5-methoxy-3-nitro-2-oxidobenzylidene-\k<i>O</i>]hydrazin-1-ylidene-\k<i>N</i>^2^}methanethiolato-\k<i>S</i>)(dimethyl sulfoxide-\k<i>S</i>)platinum(II)'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                82.2280(10)
_cell_angle_beta                 87.0740(10)
_cell_angle_gamma                74.7390(10)
_cell_formula_units_Z            2
_cell_length_a                   6.5264(3)
_cell_length_b                   8.9024(3)
_cell_length_c                   18.9261(7)
_cell_measurement_reflns_used    9889
_cell_measurement_temperature    296
_cell_measurement_theta_max      30.22
_cell_measurement_theta_min      2.39
_cell_volume                     1050.96(7)
_computing_cell_refinement
;
SAINT (Bruker, 2012)
;
_computing_data_collection
;
APEX2 (Bruker, 2012)
;
_computing_data_reduction
;
SAINT (Bruker, 2012)
;
_computing_molecular_graphics
;
Mercury (Macrae <i>et al.</i>, 2008)
;
_computing_publication_material
;
SHELXL2013 (Sheldrick, 2015) and PLATON (Spek, 2009)
;
_computing_structure_refinement
;
SHELXL2013 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      296
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX Duo CCD area detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0302
_diffrn_reflns_av_unetI/netI     0.0196
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            41144
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.348
_diffrn_reflns_theta_min         2.172
_exptl_absorpt_coefficient_mu    6.911
_exptl_absorpt_correction_T_max  0.0923
_exptl_absorpt_correction_T_min  0.0393
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2012)
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.971
_exptl_crystal_description       Block
_exptl_crystal_F_000             608
_exptl_crystal_size_max          0.485
_exptl_crystal_size_mid          0.205
_exptl_crystal_size_min          0.145
_refine_diff_density_max         0.979
_refine_diff_density_min         -0.801
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     269
_refine_ls_number_reflns         6285
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.085
_refine_ls_R_factor_all          0.0214
_refine_ls_R_factor_gt           0.0186
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0179P)^2^+0.4664P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0410
_refine_ls_wR_factor_ref         0.0420
_reflns_number_gt                5899
_reflns_number_total             6285
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            su5513sup1.cif
_cod_data_source_block           I
_cod_database_code               2243613
_shelx_estimated_absorpt_t_min   0.134
_shelx_estimated_absorpt_t_max   0.434
_shelx_hkl_checksum              48045
_shelx_res_checksum              16719
_cod_database_fobs_code 2243613