Reduction of (imine)Pt(IV) to (imine)Pt(II) Complexes with Carbonyl-Stabilized Phosphorus Ylides
Gabriele Wagner; Tatyana B. Pakhomova; Nadezhda A. Bokach; João J. R. Fraústo da Silva; Jose Vicente; Armando J. L. Pombeiro; Vadim Yu. Kukushkin; Inorganic Chemistry 40 (2001) 1683–1689; doi:10.1021/ic000769c

data_4319441
_publ_section_title
;
 Reduction of (imine)Pt(IV) to (imine)Pt(II) Complexes with
 Carbonyl-Stabilized Phosphorus Ylides
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1683
_journal_page_last               1689
_journal_paper_doi               10.1021/ic000769c
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C23 H23 Cl3 N O2 P Pt'
_chemical_formula_weight         677.9
_space_group_IT_number           33
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      33
_symmetry_space_group_name_Hall  'P 2c -2n'
_symmetry_space_group_name_H-M   'P n a 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.
_cell_angle_beta                 90.
_cell_angle_gamma                90.
_cell_formula_units_Z            4
_cell_length_a                   19.661(7)
_cell_length_b                   12.486(4)
_cell_length_c                   10.149(3)
_cell_measurement_radiation      MoK\a
_cell_measurement_reflns_used    24
_cell_measurement_temperature    293
_cell_measurement_theta_max      17
_cell_measurement_theta_min      12
_cell_measurement_wavelength     .71069
_cell_volume                     2491.5(14)
_computing_molecular_graphics    'CSD (Axelrud al.)'
_computing_publication_material
;
(Axelrud,Grin,Zavalii,Pecharsky, Fundamensky, CSD-universal program 
pakage for single crystal and/or powder structure data treatment.
Collected Abstracts, 12 European Crystallographic Meeting, 
Moscow, Aug 1989, USSR Academy of Sciences, Moscow, 1989; p. 155)
;
_computing_structure_refinement  'CSD (Axelrud al.)'
_computing_structure_solution    'CSD (Axelrud al.)'
_diffrn_ambient_temperature      293
_diffrn_measurement_device       'Syntex P21'
_diffrn_measurement_method       omega-scan
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71069
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       10
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -6
_diffrn_reflns_theta_max         18
_diffrn_reflns_theta_min         10
_diffrn_standards_decay_%        2
_diffrn_standards_interval_count 49
_diffrn_standards_number         1
_exptl_absorpt_coefficient_mu    6.33
_exptl_absorpt_correction_type   DIFABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.807
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1312
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_obs   2.840
_refine_ls_hydrogen_treatment    Biso
_refine_ls_matrix_type           full
_refine_ls_number_parameters     372
_refine_ls_number_reflns         1377
_refine_ls_R_factor_obs          0.0379
_refine_ls_shift/esd_max         '0.02_refine_ls_shift/esd_mean 0.005'
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     W=1.0/sig(F)^2+0.0008(Fobs)^2
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_obs         0.0410
_reflns_limit_h_max              26
_reflns_limit_h_min              -26
_reflns_limit_k_max              17
_reflns_limit_k_min              0
_reflns_limit_l_max              13
_reflns_limit_l_min              0
_reflns_number_observed          1401
_reflns_number_total             1491
_reflns_observed_criterion       ' F >4.0 sigma(F) '
_cod_data_source_file            ic000769c_2.cif
_cod_data_source_block           765
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_matrix_type' value 'Full' changed to 'full' according to
the built-in table from CIF Core dictionary named 'cif_core.dic'
version 2.4.1 from 2010-06-29.

'_atom_site_thermal_displace_type'
value 'bani' changed to 'Bani' according to the built-in table from
CIF Core dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29 (31 time).

'_atom_site_thermal_displace_type' value
'biso' changed to 'Biso' according to the built-in table from CIF
Core dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29
(23 times).

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'W=1.0/sig(F)^2+0.0008(Fobs)^2'
was changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'W=1.0/sig(F)^2+0.0008(Fobs)^2'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2492(3)
_cod_original_formula_sum        H23C23NO2PCl3Pt
_cod_database_code               4319441