Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for Alkene Hydrosilylation with Tertiary Silanes
Schuster, Christopher H.; Diao, Tianning; Pappas, Iraklis; Chirik, Paul J.; ACS Catalysis 6 (2016) 2632–; doi:10.1021/acscatal.6b00304

data_4513848
_publ_section_title
;
 Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for
 Alkene Hydrosilylation with Tertiary Silanes
;
_journal_issue                   4
_journal_name_full               'ACS Catalysis'
_journal_page_first              2632
_journal_paper_doi               10.1021/acscatal.6b00304
_journal_volume                  6
_journal_year                    2016
_chemical_formula_moiety         'C23 H33 Co N3 O4'
_chemical_formula_sum            'C23 H33 Co N3 O4'
_chemical_formula_weight         474.45
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'BRUKER APEX2 CCD'
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_exptl_absorpt_correction_T_min  0.6446
_exptl_absorpt_correction_type   multi-scan
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0673
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0943P)^2^+12.0359P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             5493
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 4513848--4513849.cif.'
_cod_original_cell_volume        2386.241(304)
_cod_database_code               4513848
_shelxl_version_number           2014-3
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