Stoichiometric and Catalytic Reactions Involving Si−H Bond Activations by Rh and Ir Complexes Containing a Pyridylindolide Ligand
Karshtedt, Dmitry; Bell, Alexis T.; Tilley, T. Don; Organometallics 25 (2006) 4471–; doi:10.1021/om060492+

data_4083835
_publ_section_title
;
 Stoichiometric and Catalytic Reactions Involving Si&#x2212;H Bond
 Activations by Rh and Ir Complexes Containing a Pyridylindolide Ligand
;
_journal_issue                   19
_journal_name_full               Organometallics
_journal_page_first              4471
_journal_paper_doi               10.1021/om060492+
_journal_volume                  25
_journal_year                    2006
_chemical_formula_sum            'C21 H22 N2 Rh'
_chemical_formula_weight         405.32
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             'Tue Oct 14 14:47:13 2003'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90
_cell_angle_beta                 93.879(1)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   12.3332(9)
_cell_length_b                   10.7187(8)
_cell_length_c                   24.159(2)
_cell_measurement_reflns_used    3425
_cell_measurement_temperature    119.2
_cell_measurement_theta_max      24.4
_cell_measurement_theta_min      2.5
_cell_volume                     3186.4(4)
_computing_cell_refinement       'Bruker SAINT v5.04'
_computing_data_collection       'Bruker SMART v5.0'
_computing_data_reduction        'Bruker SAINT v5.04'
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    SIR97
_diffrn_measured_fraction_theta_full 0.9718
_diffrn_measured_fraction_theta_max 0.9718
_diffrn_measurement_device_type  'SMART CCD'
_diffrn_measurement_method       \w-scan
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.049
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            5591
_diffrn_reflns_theta_full        24.70
_diffrn_reflns_theta_max         24.70
_exptl_absorpt_coefficient_mu    1.073
_exptl_absorpt_correction_T_max  0.938
_exptl_absorpt_correction_T_min  0.572
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.690
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       tablet
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.210
_exptl_crystal_size_min          0.060
_refine_diff_density_max         1.02
_refine_diff_density_min         -0.94
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.270
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     433
_refine_ls_number_reflns         3336
_refine_ls_R_factor_gt           0.0368
_refine_ls_shift/su_max          0.0007
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00022|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0388
_reflns_number_gt                3336
_reflns_number_total             5278
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            om060492%2Bsi20060605_025608.cif
_cod_data_source_block           n2rhcod_for_Dmitry_Karshte
_cod_original_sg_symbol_H-M      'P 21/n     '
_cod_original_formula_sum        'C21 H22 N2 Rh '
_cod_database_code               4083835