Synthesis and characterization of novel simultaneous C and O-coordinated and nitrate-bridged complexes of silver(I) with carbonyl-stabilized sulfonium ylides and their antibacterial activities.
Sabounchei, Seyyed Javad; Akhlaghi Bagherjeri, Fateme; Mozafari, Zeinab; Boskovic, Colette; Gable, Robert W.; Karamian, Roya; Asadbegy, Mostafa; Dalton transactions (Cambridge, England : 2003) 42 (2013) 2520–2529; doi:10.1039/c2dt31902k

data_7022156
_publ_section_title
;
 Synthesis and characterization of novel simultaneous C and O-coordinated
 and nitrate-bridged complexes of silver(I) with carbonyl-stabilized
 sulfonium ylides and their antibacterial activities.
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2520
_journal_page_last               2529
_journal_paper_doi               10.1039/c2dt31902k
_journal_volume                  42
_journal_year                    2013
_chemical_formula_sum            'C20 H22 Ag N3 O7 S2'
_chemical_formula_weight         588.40
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                70.686(3)
_cell_angle_beta                 68.015(3)
_cell_angle_gamma                88.073(2)
_cell_formula_units_Z            3
_cell_length_a                   11.7239(4)
_cell_length_b                   12.3813(3)
_cell_length_c                   15.3188(4)
_cell_measurement_temperature    293(2)
_cell_volume                     1935.53(11)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.881
_diffrn_measured_fraction_theta_max 0.881
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0299
_diffrn_reflns_av_sigmaI/netI    0.0473
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            21179
_diffrn_reflns_theta_full        30.06
_diffrn_reflns_theta_max         30.06
_diffrn_reflns_theta_min         2.85
_exptl_absorpt_coefficient_mu    0.985
_exptl_crystal_density_diffrn    1.514
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             894
_refine_diff_density_max         0.940
_refine_diff_density_min         -0.642
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.852
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     522
_refine_ls_number_reflns         10020
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.852
_refine_ls_R_factor_all          0.0539
_refine_ls_R_factor_gt           0.0365
_refine_ls_shift/su_max          0.022
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1051
_refine_ls_wR_factor_ref         0.1258
_reflns_number_gt                7955
_reflns_number_total             10020
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt31902k.txt
_cod_data_source_block           fa-asng
_cod_original_cell_volume        1935.54(10)
_cod_database_code               7022156