Two new cobalt(II) rhodamine 6G hydrazone complexes: structure, fluorescence and magnetism
Yuan, Juan; Wang, Xia; Zhang, Nan; Liu, Mei-Jiao; Kou, Hui-Zhong; Acta Crystallographica Section C 74 (2018) –; doi:10.1107/S2053229618015541

data_2021338
_publ_section_title
;
 Two new cobalt(II) rhodamine 6G hydrazone complexes: structure,
 fluorescence and magnetism
;
_journal_coeditor_code           CU3135
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229618015541
_journal_volume                  74
_journal_year                    2018
_chemical_formula_iupac
'[Co (C32 H30 Br1 N5 O2)2] (B F4)2, C H2 Cl2, 2C H4 O'
_chemical_formula_moiety
'C64 H60 Br2 Co N10 O4 2+, 2(B F4 -), C H2 Cl2, 2(C H4 O)'
_chemical_formula_sum            'C67 H70 B2 Br2 Cl2 Co F8 N10 O6'
_chemical_formula_weight         1574.60
_chemical_name_common
;Bis(6-bromopyridine-2-carbaldehyde rhodamine 6G hydrazone)cobalt(II)
bis(tetrafluoridoborate)--dichloromethane--methanol (1/1/2)
;
_chemical_name_systematic
;Bis{<i>N</i>-[(6-bromopyridin-2-yl)methylidene]-2-[6-ethylamino-3-(ethyliminiumyl)-2,7-dimethyl-3<i>H</i>-xanthen-9-yl]benzene-1-carbohydrazonate}cobalt(II) bis(tetrafluoridoborate)--dichloromethane--methanol
(1/1/2)
;
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
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;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
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_cell_length_c                   17.7898(3)
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_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2017)
;
_computing_data_reduction
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CrysAlis PRO (Rigaku OD, 2017)
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_computing_molecular_graphics
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OLEX2 (Dolomanov <i>et al.</i>,  2009) and
DIAMOND (Brandenburg, 2005)
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OLEX2 (Dolomanov <i>et al.</i>,  2009)
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SHELXL2014 (Sheldrick, 2015b)
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SHELXT (Sheldrick, 2015a)
;
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_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device       'four-circle diffractometer'
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'Rigaku OD SuperNova Dual source diffractometer with an AtlasS2 detector'
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;
(CrysAlis PRO; Rigaku OD, 2017)
;
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_exptl_crystal_size_mid          0.2
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_refine_diff_density_min         -1.158
_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0767P)^2^+4.2094P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_database_code               2021338
_cod_database_fobs_code          2021338