<i>catena</i>-Poly[silver(I)-μ-[1-(pyridin-2-ylmethyl-κ<i>N</i>)-3-(3-sulfonatopropyl)imidazolin-2-ylidene]-κ<i>C</i>^2^]
Rietzler, Barbara; Laus, Gerhard; Kahlenberg, Volker; Schottenberger, Herwig; IUCrData 1 (2016) x160245–; doi:10.1107/S2414314616002455

data_1542513
_publ_section_title
;
 <i>catena</i>-Poly[silver(I)-\m-[1-(pyridin-2-ylmethyl-\k<i>N</i>)-3-(3-sulfonatopropyl)imidazolin-2-ylidene]-\k<i>C</i>^2^]
;
_journal_coeditor_code           HB4016
_journal_issue                   2
_journal_name_full               IUCrData
_journal_page_first              x160245
_journal_paper_doi               10.1107/S2414314616002455
_journal_volume                  1
_journal_year                    2016
_chemical_formula_iupac          '[Ag (C12 H14 N3 O3 S)]'
_chemical_formula_moiety         'C12 H14 Ag N3 O3 S'
_chemical_formula_sum            'C12 H14 Ag N3 O3 S'
_chemical_formula_weight         388.19
_chemical_name_systematic
<i>catena</i>-Poly[silver(I)-\m-[1-(pyridin-2-ylmethyl-\k<i>N</i>)-3-(3-sulfonatopropyl)imidazolin-2-ylidene]-\k<i>C</i>^2^]
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 107.055(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.1568(6)
_cell_length_b                   9.7852(4)
_cell_length_c                   12.5715(6)
_cell_measurement_reflns_used    2698
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.153
_cell_measurement_theta_min      3.573
_cell_volume                     1312.09(13)
_computing_cell_refinement
;
CrysAlis PRO (Agilent, 2014)
;
_computing_data_collection
;
CrysAlis PRO (Agilent, 2014)
;
_computing_data_reduction
;
CrysAlis PRO (Agilent, 2014)
;
_computing_publication_material
;
ORTEP-3 for Windows (Farrugia, 2012) and
Mercury (Macrae <i>et al.</i>, 2006)
;
_computing_structure_refinement
;
SHELXL97 (Sheldrick, 2008)
;
_computing_structure_solution
;
SIR2002 (Burla <i>et al.</i>,  2003)
;
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 10.3575
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Agilent Xcalibur Ruby Gemini ultra'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0454
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            8214
_diffrn_reflns_theta_full        25.35
_diffrn_reflns_theta_max         25.35
_diffrn_reflns_theta_min         2.82
_exptl_absorpt_coefficient_mu    1.706
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.9364
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Agilent, 2014)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.965
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       fragment
_exptl_crystal_F_000             776
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_refine_diff_density_max         0.449
_refine_diff_density_min         -0.377
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     181
_refine_ls_number_reflns         2398
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0464
_refine_ls_R_factor_gt           0.0315
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0243P)^2^+0.5800P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0605
_refine_ls_wR_factor_ref         0.0657
_reflns_number_gt                1921
_reflns_number_total             2398
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb4016sup1.cif
_cod_data_source_block           I
_cod_depositor_comments          'Adding full bibliography for 1542513.cif.'
_cod_original_cell_volume        1312.09(12)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1542513
_cod_database_fobs_code          1542513