Rh(III)-Catalyzed Regio- and Chemoselective [4 + 1]-Annulation of Azoxy Compounds with Diazoesters for the Synthesis of 2H-Indazoles: Roles of the Azoxy Oxygen Atom.
Long, Zhen; Wang, Zhigang; Zhou, Danni; Wan, Danyang; You, Jingsong; Organic letters 19 (2017) 2777–2780; doi:10.1021/acs.orglett.7b00631

data_1546236
_publ_section_title
;
 Rh(III)-Catalyzed Regio- and Chemoselective [4 + 1]-Annulation of Azoxy
 Compounds with Diazoesters for the Synthesis of 2H-Indazoles: Roles of
 the Azoxy Oxygen Atom.
;
_journal_issue                   11
_journal_name_full               'Organic letters'
_journal_page_first              2777
_journal_page_last               2780
_journal_paper_doi               10.1021/acs.orglett.7b00631
_journal_volume                  19
_journal_year                    2017
_chemical_formula_moiety         'C22 H24 Cl N2 O Rh'
_chemical_formula_sum            'C22 H24 Cl N2 O Rh'
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
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CrysAlisPro, Agilent Technologies,
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  1 omega   18.00  106.00   1.0000    3.7800
omega____ theta____ kappa____ phi______ frames
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  2 omega  -35.00   66.00   1.0000    3.7800
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  3 omega  -31.00   53.00   1.0000    3.7800
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  5 omega    1.00   75.00   1.0000    3.7800
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  6 omega   23.00   90.00   1.0000    3.7800
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  7 omega   38.00   91.00   1.0000   15.1200
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  8 omega   40.00   98.00   1.0000   15.1200
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  9 omega   38.00   91.00   1.0000   15.1200
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 10 omega   87.00  178.00   1.0000   15.1200
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 11 omega   39.00  109.00   1.0000   15.1200
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 12 omega   38.00  116.00   1.0000   15.1200
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 13 omega  100.00  178.00   1.0000   15.1200
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 14 omega   38.00   91.00   1.0000   15.1200
omega____ theta____ kappa____ phi______ frames
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 15 omega   57.00  150.00   1.0000   15.1200
omega____ theta____ kappa____ phi______ frames
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 16 omega   18.00   56.00   1.0000    3.7800
omega____ theta____ kappa____ phi______ frames
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 17 omega   10.00  104.00   1.0000    3.7800
omega____ theta____ kappa____ phi______ frames
    -       36.4171   77.0000  -30.0000 94
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_diffrn_radiation_monochromator  graphite
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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'w=1/[\s^2^(Fo^2^)+(0.1041P)^2^+0.0173P] where P=(Fo^2^+2Fc^2^)/3'
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;
1. Fixed Uiso
 At 1.2 times of:
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 At 1.5 times of:
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2.a Aromatic/amide H refined with riding coordinates:
 C00B(H00B), C00E(H00E), C00F(H00F), C00G(H00G), C00I(H00I), C00J(H00J),
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2.b Idealised Me refined as rotating group:
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;
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_olex2_submission_special_instructions 'No special instructions were received'