Synthesis of Heterodinuclear (Carbene)platinum (or palladium) Complex That Gives μ-Alkenyl-Type Complex by Deprotonation
Tanaka, Shin-ichi; Komine, Nobuyuki; Hirano, Masafumi; Komiya, Sanshiro; Organometallics 28 (2009) 5368–; doi:10.1021/om900421k

data_4069804
_publ_section_title
;
 Synthesis of Heterodinuclear (Carbene)platinum (or palladium) Complex
 That Gives \m-Alkenyl-Type Complex by Deprotonation
;
_journal_issue                   18
_journal_name_full               Organometallics
_journal_page_first              5368
_journal_paper_doi               10.1021/om900421k
_journal_volume                  28
_journal_year                    2009
_chemical_absolute_configuration 'CHOOSE rm ad rmad syn or unk'
_chemical_formula_moiety         'C26 H27 Mo O4 P Pt '
_chemical_formula_sum            'C26 H27 Mo O4 P Pt'
_chemical_formula_weight         725.50
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      9
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 112.18(5)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            8
_cell_length_a                   33.381(17)
_cell_length_b                   9.06(3)
_cell_length_c                   18.360(18)
_cell_measurement_reflns_used    24
_cell_measurement_temperature    200.1
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.4
_cell_volume                     5142(18)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.068
_diffrn_reflns_limit_h_max       43
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            5966
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_standards_decay_%        -3.71
_diffrn_standards_interval_count 0
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.989
_exptl_absorpt_correction_T_max  0.302
_exptl_absorpt_correction_T_min  0.108
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.873
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             2800.00
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.11
_refine_diff_density_max         9.01
_refine_diff_density_min         -6.47
_refine_ls_abs_structure_details
'Flack, H. D. (1983), Acta Cryst. A39, 876-881.  96 Friedel Pairs'
_refine_ls_abs_structure_Flack   0.27(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.408
_refine_ls_number_parameters     224
_refine_ls_number_reflns         5965
_refine_ls_R_factor_gt           0.1283
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.3691
_reflns_number_gt                4057
_reflns_number_total             5965
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om900421k_si_003.cif
_cod_data_source_block           complex_11
_cod_original_cell_volume        5144(18)
_cod_original_formula_sum        'C26 H27 Mo O4 P Pt '
_cod_database_code               4069804