A method for accessing sulfanylfurans from homopropargylic alcohols and sulfonyl hydrazides.
Yang, Xiaodong; Yan, Rulong; Organic & biomolecular chemistry 15 (2017) 3571–3574; doi:10.1039/c7ob00566k

data_7155550
_publ_section_title
;
 A method for accessing sulfanylfurans from homopropargylic alcohols and
 sulfonyl hydrazides.
;
_journal_issue                   17
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              3571
_journal_page_last               3574
_journal_paper_doi               10.1039/c7ob00566k
_journal_volume                  15
_journal_year                    2017
_chemical_formula_moiety         'C22 H15 F O S'
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Olex2 1.2
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2017-03-31 deposited with the CCDC.
2017-04-03 downloaded from the CCDC.
;
_cell_angle_alpha                92.050(14)
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
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;
  1 omega   -5.00   91.00   2.0000    3.5000
omega____ theta____ kappa____ phi______ frames
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  2 omega   37.00   93.00   2.0000    3.5000
omega____ theta____ kappa____ phi______ frames
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  3 omega  -46.00   44.00   2.0000    3.5000
omega____ theta____ kappa____ phi______ frames
    -       20.5854  -38.0000  -60.0000 45

  4 omega  -19.00   21.00   2.0000    3.5000
omega____ theta____ kappa____ phi______ frames
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  5 omega  -15.00   17.00   2.0000    3.5000
omega____ theta____ kappa____ phi______ frames
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omega____ theta____ kappa____ phi______ frames
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_diffrn_source                   'SuperNova (Mo) X-ray Source'
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            'clear light colourless'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0470P)^2^+0.0221P] where P=(Fo^2^+2Fc^2^)/3'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C22(H22), C3(H3), C6(H6), C16(H16), C18(H18), C15(H15), C10(H10), C20(H20),
 C12(H12), C13(H13), C19(H19), C14(H14), C7(H7), C8(H8), C9(H9)
;
_olex2_date_sample_data_collection 2016-04-29
_olex2_submission_special_instructions 'No special instructions were received'