Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds
Ochiai, Mitsuyoshi; Hashimoto, Hisako; Tobita, Hiromi; Dalton Transactions  (2009) 1812–1814; doi:10.1039/b819229b

data_7000651
_publ_section_title
;
 Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl
 compounds
;
_journal_issue                   10
_journal_name_full               'Dalton Transactions'
_journal_page_first              1812
_journal_page_last               1814
_journal_paper_doi               10.1039/b819229b
_journal_year                    2009
_chemical_formula_moiety         'C34 H54 O2 Ru Si4'
_chemical_formula_sum            'C34 H54 O2 Ru Si4'
_chemical_formula_weight         708.20
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                75.303(5)
_cell_angle_beta                 79.313(5)
_cell_angle_gamma                87.413(3)
_cell_formula_units_Z            4
_cell_length_a                   9.6657(4)
_cell_length_b                   19.8503(16)
_cell_length_c                   20.2818(17)
_cell_measurement_reflns_used    19708
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.1
_cell_volume                     3698.8(5)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_molecular_graphics    ORTEP
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.830
_diffrn_measured_fraction_theta_max 0.830
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0703
_diffrn_reflns_av_sigmaI/netI    0.0566
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            27413
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         1.06
_exptl_absorpt_coefficient_mu    0.581
_exptl_absorpt_correction_T_max  0.8360
_exptl_absorpt_correction_T_min  0.8138
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   'NUMABS (Higashi, 1999)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.272
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1496
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.37
_exptl_crystal_size_min          0.32
_refine_diff_density_max         6.823
_refine_diff_density_min         -2.224
_refine_diff_density_rms         0.250
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.190
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     767
_refine_ls_number_reflns         14088
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.190
_refine_ls_R_factor_all          0.1482
_refine_ls_R_factor_gt           0.1316
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0834P)^2^+99.7863P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3149
_refine_ls_wR_factor_ref         0.3256
_reflns_number_gt                12097
_reflns_number_total             14088
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b819229b.txt
_cod_data_source_block           ochiai30
_cod_original_sg_symbol_H-M      'P -1 '
_cod_database_code               7000651