Bulky 2,6-disubstituted aryl siloxanes and a disilanamine
Marszaukowski, Flavia; Wohnrath, Karen; Boeré, René T.; Acta Crystallographica Section E 76 (2020) 318–323; doi:10.1107/S2056989020001413

data_2243273
_publ_section_title
;
 Bulky 2,6-disubstituted aryl siloxanes and a disilanamine
;
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              318
_journal_page_last               323
_journal_paper_doi               10.1107/S2056989020001413
_journal_volume                  76
_journal_year                    2020
_chemical_formula_iupac          'C18 H35 N Si2'
_chemical_formula_moiety         'C18 H35 N Si2'
_chemical_formula_sum            'C18 H35 N Si2'
_chemical_formula_weight         321.65
_chemical_name_systematic
<i>N</i>-(2,6-Diisopropylphenyl)-1,1,1-trimethyl-<i>N</i>-(trimethylsilyl)silanamine
_space_group_crystal_system      orthorhombic
_space_group_IT_number           63
_space_group_name_Hall           '-C 2c 2'
_space_group_name_H-M_alt        'C m c m'
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Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
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SAINT (Bruker, 2014)
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_computing_data_collection
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APEX2 (Bruker, 2014)
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_computing_data_reduction
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SAINT (Bruker, 2014)
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_computing_molecular_graphics
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<i>OLEX2</i> (Dolomanov <i>et al.</i>,  2009)
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publCIF (Westrip, 2010)
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_computing_structure_refinement
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ShelXL (Sheldrick, 2015b)
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ShelXT (Sheldrick, 2015a)
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_diffrn_ambient_temperature      173.15
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_diffrn_reflns_theta_max         27.584
_diffrn_reflns_theta_min         2.372
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.166
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6669
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2014)
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_exptl_crystal_colour            'clear colourless'
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_refine_ls_R_factor_all          0.0588
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0516P)^2^+2.3874P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            hb7886sup1.cif
_cod_data_source_block           III
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_cod_database_code               2243273
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_shelx_estimated_absorpt_t_min   0.970
_shelx_estimated_absorpt_t_max   0.984
_shelx_res_checksum              88281