A facile method for the synthesis of trifluoromethylthio-/chloro-homoallylic alcohols from methylenecyclopropanes
Chen, Mintao; Wei, Yin; Shi, Min; Organic Chemistry Frontiers 5 (2018) 2030–; doi:10.1039/C8QO00386F

data_1554328
_publ_section_title
;
 A facile method for the synthesis of
 trifluoromethylthio-/chloro-homoallylic alcohols from
 methylenecyclopropanes
;
_journal_issue                   13
_journal_name_full               'Organic Chemistry Frontiers'
_journal_page_first              2030
_journal_paper_doi               10.1039/C8QO00386F
_journal_volume                  5
_journal_year                    2018
_chemical_formula_sum            'C16 H15 Cl O'
_chemical_formula_weight         258.73
_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           '-P 2n 2ab'
_space_group_name_H-M_alt        'P b c n'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2017-12-21 deposited with the CCDC.
2018-05-14 downloaded from the CCDC.
;
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_cell_volume                     2690.46(16)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.811
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0886
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_diffrn_reflns_point_group_measured_fraction_full 0.811
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_exptl_absorpt_correction_T_min  0.5892
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_exptl_crystal_description       prismatic
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_refine_ls_extinction_coef       0.0060(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_R_factor_all          0.0589
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0439P)^2^+2.2919P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                1676
_reflns_number_total             1959
_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_estimated_absorpt_t_min   0.943
_shelx_estimated_absorpt_t_max   0.974
_shelxl_version_number           2013-4
_shelx_res_checksum              2067
_shelx_hkl_checksum              50274