A new series of pillared uranyl-vanadates based on uranophane-type sheets in the uranium-vanadium-linear alkyl diamine systems
Jouffret, Laurent; Rivenet, Murielle; Abraham, Francis; Journal of Solid State Chemistry 183 (2010) 84–92; doi:10.1016/j.jssc.2009.10.020

data_1563769
_publ_section_title
;
 A new series of pillared uranyl-vanadates based on uranophane-type sheets
 in the uranium-vanadium-linear alkyl diamine systems
;
_journal_issue                   1
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              84
_journal_page_last               92
_journal_paper_doi               10.1016/j.jssc.2009.10.020
_journal_volume                  183
_journal_year                    2010
_chemical_formula_sum            'C3 H16 N2 O28 U5 V4'
_chemical_formula_weight         1922.1
_space_group_IT_number           36
_space_group_name_Hall           'C 2c -2'
_space_group_name_H-M_alt        'C m c 21'
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'C 2c -2'
_symmetry_space_group_name_H-M   'C m c 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.2754(2)
_cell_length_b                   14.1374(2)
_cell_length_c                   13.6609(2)
_cell_measurement_temperature    100
_cell_measurement_theta_max      31.05
_cell_measurement_theta_min      1.96
_cell_volume                     2950.13(7)
_computing_publication_material
'Jana2000 (Petricek, Dusek & Palatinus, 2000)'
_computing_structure_refinement
'Jana2000 (Petricek, Dusek & Palatinus, 2000)'
_diffrn_ambient_temperature      100
_diffrn_measured_fraction_theta_full 1.00
_diffrn_measured_fraction_theta_max 0.99
_diffrn_measurement_device_type  SMART-1K-CCD
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0891
_diffrn_reflns_av_sigmaI/netI    0.0752
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            27953
_diffrn_reflns_theta_full        27.04
_diffrn_reflns_theta_max         31.05
_diffrn_reflns_theta_min         1.96
_exptl_absorpt_coefficient_mu    28.649
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.462
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    4.32606
_exptl_crystal_description       plate
_exptl_crystal_F_000             3231
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.020
_exptl_crystal_size_min          0.006
_refine_diff_density_max         4.04
_refine_diff_density_min         -4.64
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_gt    1.82
_refine_ls_goodness_of_fit_ref   1.71
_refine_ls_hydrogen_treatment    undef
_refine_ls_number_parameters     117
_refine_ls_number_reflns         4556
_refine_ls_R_factor_all          0.0656
_refine_ls_R_factor_gt           0.0526
_refine_ls_shift/su_max          0.0424
_refine_ls_shift/su_mean         0.0078
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     w=1/\s^2^(F)
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_gt          0.0555
_refine_ls_wR_factor_ref         0.0570
_reflns_number_gt                3806
_reflns_number_total             4556
_reflns_threshold_expression     I>3\s(I)
_cod_data_source_file            JSSC-2010-183-84.cif
_cod_data_source_block           1
_cod_original_sg_symbol_Hall     'C -2x;-2yc;2zc'
_cod_database_code               1563769