A simple zinc(ii) complex that features multi-functional luminochromism induced by reversible ligand dissociation.
Tsukamoto, Takamasa; Aoki, Risa; Sakamoto, Ryota; Toyoda, Ryojun; Shimada, Masaki; Hattori, Yohei; Asaoka, Mizuki; Kitagawa, Yasutaka; Nishibori, Eiji; Nakano, Masayoshi; Nishihara, Hiroshi; Chemical communications (Cambridge, England) 53 (2017) 3657–3660; doi:10.1039/c6cc10190a

data_7119578
_publ_section_title
;
 A simple zinc(ii) complex that features multi-functional luminochromism
 induced by reversible ligand dissociation.
;
_journal_issue                   26
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3657
_journal_page_last               3660
_journal_paper_doi               10.1039/c6cc10190a
_journal_volume                  53
_journal_year                    2017
_chemical_formula_analytical     'C37 H30 N4 O4 Zn'
_chemical_formula_moiety         'C37 H30 N4 O4 Zn'
_chemical_formula_structural     'C37 H30 N4 O4 Zn'
_chemical_formula_sum            'C37 H30 N4 O4 Zn'
_chemical_formula_weight         660.04
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_update_record
;
2015-11-11 deposited with the CCDC.
2017-01-19 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 102.222(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_c                   10.7218(3)
_cell_measurement_temperature    100
_cell_volume                     3055.39(17)
_computing_cell_refinement       'SP (Nishibori et al., 2007)'
_computing_data_collection       'local software (Nishibori et al., 2001)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SP (Nishibori et al., 2007)'
_computing_structure_solution    'GAIA (Nishibori et al., 2008<i>a</i>)'
_diffrn_ambient_temperature      100
_diffrn_detector                 'imaging plate'
_diffrn_detector_type            'FUJIFILM BAS-MS2040'
_diffrn_measurement_device_type  'large Debye-Scherrer camera'
_diffrn_radiation_monochromator  Si(111)
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.79683
_diffrn_source                   synchrotron
_diffrn_source_type              'SPring-8 BL02B2'
_exptl_absorpt_coefficient_mu    1.155
_exptl_crystal_density_diffrn    1.435
_exptl_crystal_F_000             1368.0
_pd_char_colour                  orange
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_pd_proc_wavelength              0.79683
_pd_spec_mounting                capillary
_pd_spec_mount_mode              transmission
_pd_spec_shape                   cylinder
_pd_spec_size_axial              3
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_R_factor_all          0.040
_refine_ls_R_Fsqd_factor         0.048
_refine_ls_R_I_factor            0.048
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_cod_depositor_comments
'Adding full bibliography for 7119577--7119579.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7119578
_publcif_datablock.id            {b088c260-3a07-4250-840b-a689d3928537}
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