Selective dimerization of a trinuclear mixed-metal sandwich complex: construction of an axially chiral metal skeleton.
Yamaura, Hiroshige; Yamamoto, Koji; Murahashi, Tetsuro; Chemical communications (Cambridge, England) 57 (2021) 9120–9123; doi:10.1039/d1cc03719f

data_7128855
_publ_section_title
;
 Selective dimerization of a trinuclear mixed-metal sandwich complex:
 construction of an axially chiral metal skeleton.
;
_journal_issue                   72
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              9120
_journal_page_last               9123
_journal_paper_doi               10.1039/d1cc03719f
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C36 H40 N4 Pd4 Pt2, 2(B F4)'
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Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
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2021-07-05 deposited with the CCDC.	2021-08-09 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0333P)^2^+8.0476P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7128853--7128856.cif.'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C7(H7), C8(H8), C9(H9),
 C10(H10), C11(H11), C12(H12), C13(H13), C14(H14), C15(H15), C16(H16), C17(H17),
  C18(H18), C19(H19), C20(H20), C21(H21), C22(H22), C23(H23), C24(H24),
 C25(H25), C26(H26), C27(H27), C28(H28)
2.b Idealised Me refined as rotating group:
 C30(H30A,H30B,H30C), C32(H32A,H32B,H32C), C34(H34A,H34B,H34C), C36(H36A,H36B,
 H36C)
;
_smtbx_masks_void_probe_radius   1.2
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_olex2_submission_special_instructions 'No special instructions were received'