Synthesis of functionalized cyclopropylboronic esters based on a 1,2-metallate rearrangement of cyclopropenylboronate.
Mizoguchi, Haruki; Seriu, Masaya; Sakakura, Akira; Chemical communications (Cambridge, England) 56 (2020) 15545–15548; doi:10.1039/d0cc07134j

data_7127456
_publ_section_title
;
 Synthesis of functionalized cyclopropylboronic esters based on a
 1,2-metallate rearrangement of cyclopropenylboronate.
;
_journal_issue                   99
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              15545
_journal_page_last               15548
_journal_paper_doi               10.1039/d0cc07134j
_journal_volume                  56
_journal_year                    2020
_chemical_formula_moiety         'C30 H35 B O3 Se'
_chemical_formula_sum            'C30 H35 B O3 Se'
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_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2020-08-25 deposited with the CCDC.	2020-11-17 downloaded from the CCDC.
;
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_cell_angle_beta                 82.10(3)
_cell_angle_gamma                86.46(4)
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_computing_structure_solution    'SIR2014 (Burla, et al., 2014)'
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_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       \w
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_exptl_crystal_density_method    'not measured'
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_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
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'w = 1/[\s^2^(Fo^2^)+(0.1065P)^2^+1.0529P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1563
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_cod_depositor_comments          'Adding full bibliography for 7127456.cif.'
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