Insight into the stereoelectronic parameters of N-triphos ligands via coordination to tungsten(0).
Phanopoulos, Andreas; White, Andrew J. P.; Long, Nicholas J.; Miller, Philip W.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 5536–5548; doi:10.1039/c6dt00170j

data_7038479
_publ_section_title
;
 Insight into the stereoelectronic parameters of N-triphos ligands via
 coordination to tungsten(0).
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5536
_journal_page_last               5548
_journal_paper_doi               10.1039/c6dt00170j
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C37 H60 N O5 P3 W'
_chemical_formula_sum            'C37 H60 N O5 P3 W'
_chemical_formula_weight         875.62
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           'P 2c -2n'
_space_group_name_H-M_alt        'P n a 21'
_symmetry_space_group_name_Hall  'P 2c -2n'
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;
2015-07-13 deposited with the CCDC.
2016-02-19 downloaded from the CCDC.
;
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_diffrn_source                   'Enhance Ultra (Cu) X-ray Source'
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33a (release 28-03-2014 CrysAlis171 .NET)
(compiled Mar 28 2014,12:25:20)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'Pale yellow'
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_exptl_crystal_size_mid          0.28
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_refine_ls_abs_structure_details
;
 Classical Flack method preferred over Parsons because s.u. lower.
;
_refine_ls_abs_structure_Flack   -0.023(19)
_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0705P)^2^+3.7556P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                3938
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt00170j2.cif
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_cod_depositor_comments
'Adding full bibliography for 7038473--7038480.cif.'
_cod_original_cell_volume        3780.39(14)
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_shelxl_version_number           2013-4