Synthesis of Cyclopentadienols by Rhodium-Catalyzed C–H Activation of 8-Formylquinolines and [2+2+1] Carbocyclization with Alkynes
Li, Xingwei; Yang, Xifa; Qi, Zisong; ACS Catalysis 6 (2016) 6372–; doi:10.1021/acscatal.6b01936

data_4516700
_publ_section_title
;
 Synthesis of Cyclopentadienols by Rhodium-Catalyzed C--H Activation of
 8-Formylquinolines and [2+2+1] Carbocyclization with Alkynes
;
_journal_issue                   10
_journal_name_full               'ACS Catalysis'
_journal_page_first              6372
_journal_paper_doi               10.1021/acscatal.6b01936
_journal_volume                  6
_journal_year                    2016
_chemical_formula_sum            'C38 H27 N O'
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_cell_measurement_temperature    293(2)
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_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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_refine_ls_restrained_S_all      0.966
_refine_ls_R_factor_all          0.1525
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0940P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_database_code               4516700
_shelx_estimated_absorpt_t_min   0.984
_shelx_estimated_absorpt_t_max   0.990
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_shelx_res_checksum              32590
_shelx_hkl_checksum              66449