Adducts of Acetylene and Dimethylacetylenedicarboxylate at Sulfurs in Sulfur-Bridged Incomplete Cubane-Type Tungsten Clusters
Yasuhiro Ide; Makoto Sasaki; Masataka Maeyama; Takashi Shibahara; Inorganic Chemistry 43 (2004) 602–612; doi:10.1021/ic0349860

data_4310436
_publ_contact_author_address
;
    Department of Chemistry
    Okayama University of Science
    Ridai-cho, Okayama 700-0005
    Japan
;
_publ_contact_author_email       shiba@chem.ous.ac.jp
_publ_contact_author_fax         +81-86-256-9443
_publ_contact_author_name        'Takashi Shibahara'
_publ_contact_author_phone       +81-86-256-9443
_publ_section_title
;
 Adducts of Acetylene and Dimethylacetylenedicarboxylate at Sulfurs in
 Sulfur-Bridged Incomplete Cubane-Type Tungsten Clusters
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              602
_journal_page_last               612
_journal_paper_doi               10.1021/ic0349860
_journal_volume                  43
_journal_year                    2004
_chemical_formula_moiety         'C27 H46 N O16 P3 S10 W3 '
_chemical_formula_sum            'C27 H46 N O16 P3 S10 W3'
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_audit_creation_date             'Tue Aug  5 15:21:23 2003'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                102.606(2)
_cell_angle_beta                 100.461(2)
_cell_angle_gamma                108.053(3)
_cell_formula_units_Z            2
_cell_length_a                   13.163(2)
_cell_length_b                   14.100(3)
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_cell_measurement_reflns_used    11810
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_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      5.8
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_computing_cell_refinement       CRYSTALCLEAR
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_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       \w
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_exptl_absorpt_correction_T_min  0.4049
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Jacobson, 1998)'
_exptl_crystal_colour            Brown
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_exptl_crystal_density_meas      ?
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_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.03400(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     F^2^>2.0\s(F^2^)
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_cod_data_source_block           11.CH3CN
_cod_original_cell_volume        2432.4(7)
_cod_original_sg_symbol_H-M      'P -1 '
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_cod_database_code               4310436