Salts of highly fluorinated weakly coordinating anions as versatile precursors towards hydrogen storage materials.
Starobrat, A.; Tyszkiewicz, M. J.; Wegner, W.; Pancerz, D.; Orłowski, P A; Leszczyński, P J; Fijalkowski, K. J.; Jaroń, T; Grochala, W.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 19469–19477; doi:10.1039/c5dt02005k

data_7036083
_publ_section_title
;
 Salts of highly fluorinated weakly coordinating anions as versatile
 precursors towards hydrogen storage materials.
;
_journal_issue                   45
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              19469
_journal_page_last               19477
_journal_paper_doi               10.1039/c5dt02005k
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C24 H20 P, B4 Eu H16'
_chemical_formula_sum            'C24 H36 B4 Eu P'
_chemical_formula_weight         550.71
_chemical_name_systematic        ' ?'
_space_group_IT_number           88
_symmetry_cell_setting           tetragonal
_symmetry_Int_Tables_number      88
_symmetry_space_group_name_Hall  'I 4bw -1bw'
_symmetry_space_group_name_H-M   'I 41/a :1'
_audit_update_record
;
2015-05-28 deposited with the CCDC.
2015-07-22 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.406(2)
_cell_length_b                   14.406(2)
_cell_length_c                   13.590(3)
_cell_measurement_temperature    298
_cell_volume                     2820.4(8)
_diffrn_ambient_temperature      298
_diffrn_detector                 one-dimensional
_diffrn_detector_type            LYNXEYE
_diffrn_measurement_device_type  'Bruker D8 Discover'
_diffrn_radiation_monochromator  none
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.5418
_exptl_absorpt_coefficient_mu    16.484
_exptl_crystal_density_diffrn    1.297
_exptl_crystal_F_000             80
_pd_char_colour                  white
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.014
_pd_meas_2theta_range_max        80.003
_pd_meas_2theta_range_min        6.000
_pd_meas_number_of_points        5168
_pd_meas_scan_method             cont
_pd_prep_temperature             298
_pd_proc_2theta_range_inc        0.014
_pd_proc_2theta_range_max        80.003
_pd_proc_2theta_range_min        6
_pd_proc_ls_background_function  '26 Legendre polynoms'
_pd_proc_ls_pref_orient_corr     none
_pd_proc_ls_profile_function     Pseudo-Voigt
_pd_proc_ls_prof_R_factor        0.0066
_pd_proc_ls_prof_wR_expected     0.0072
_pd_proc_ls_prof_wR_factor       0.0088
_pd_spec_mounting                'quartz capillary'
_pd_spec_mount_mode              transmission
_pd_spec_shape                   cylinder
_pd_spec_size_axial              18
_pd_spec_size_equat              1
_refine_ls_goodness_of_fit_all   1.21
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_constraints    0
_refine_ls_number_parameters     98
_refine_ls_number_restraints     36
_refine_ls_R_factor_all          0.0603
_refine_ls_R_factor_gt           0.0559
_refine_ls_shift/su_max          0.0345
_refine_ls_shift/su_mean         0.0064
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0400
_refine_ls_wR_factor_gt          0.0396
_cod_data_source_file            c5dt02005k1.cif
_cod_data_source_block           I
_cod_depositor_comments
'Adding full bibliography for 7036082--7036084.cif.'
_cod_original_cell_volume        2820.4(10)
_cod_original_sg_symbol_H-M      'I 41/a:1'
_cod_original_formula_sum        'C24 H36 B4 Eu1 P1'
_cod_database_code               7036083