Catalytic Ugi-Type Condensation of α-Isocyanoacetamide and Chiral Cyclic Imine: Access to Asymmetric Construction of Several Heterocycles
Liang Xia; Sheng Li; Ruijiao Chen; Kai Liu; Xiaochuan Chen; Journal of Organic Chemistry 78 (2013) 3120–3131; doi:10.1021/jo4000702

data_4028093
_publ_contact_author_name
;
;
_publ_section_title
;
 Catalytic Ugi-Type Condensation of \a-Isocyanoacetamide and Chiral Cyclic
 Imine: Access to Asymmetric Construction of Several Heterocycles
;
_journal_name_full               'Journal of Organic Chemistry'
_journal_page_first              3120
_journal_page_last               3131
_journal_paper_doi               10.1021/jo4000702
_journal_volume                  78
_journal_year                    2013
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C0.5 H Cl, C25 H29 N3 O4'
_chemical_formula_sum            'C25.5 H30 Cl N3 O4'
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 ? 
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_symmetry_space_group_name_Hall  'C 2y'
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
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SHELXL, G.M. Sheldrick, Acta Cryst.
2008). A64, 112-122
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SHELXS, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
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  1 omega  -15.00   22.00   1.0000   23.0000
omega____ theta____ kappa____ phi______ frames
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  2 omega  -86.00    3.00   1.0000   23.0000
omega____ theta____ kappa____ phi______ frames
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  3 omega  -89.00    9.00   1.0000   23.0000
omega____ theta____ kappa____ phi______ frames
    -      -16.8924  -38.0000  120.0000 98
  4 omega    5.00   30.00   1.0000   23.0000
omega____ theta____ kappa____ phi______ frames
    -       19.8611 -138.0000  -75.0000 25
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CrysAlisPro, Agilent Technologies,
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empirical absorption correction using spherical harmonics,
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'calc w=1/[\s^2^(Fo^2^)+(0.0319P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_file            jo4000702_si_002.cif
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_cod_original_cell_volume        2355.4(2)
_cod_original_formula_sum        'C25.50 H30 Cl N3 O4'
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