Facile assembly of 1D multinuclear Agn (n = 11, 11, 12) alkynly chains with CF3COO‒/CH3COO‒ as auxiliary ligand
Zhou, Kun; Qin, Chao; Yan, Li-Kai; Wang, Fang-Ming; Su, Zhong-Min; RSC Adv.  (2014) –; doi:10.1039/C4RA09876E

data_7218600
_publ_section_title
;
 Facile assembly of 1D multinuclear Agn (n = 11, 11, 12) alkynly chains
 with CF3COO--/CH3COO-- as auxiliary ligand
;
_journal_name_full               'RSC Adv.'
_journal_paper_doi               10.1039/C4RA09876E
_journal_year                    2014
_chemical_formula_sum            'C47 H58 Ag11 F15 O11'
_chemical_formula_weight         2266.47
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                110.957(4)
_cell_angle_beta                 92.602(4)
_cell_angle_gamma                117.093(3)
_cell_formula_units_Z            2
_cell_length_a                   14.551(4)
_cell_length_b                   14.805(4)
_cell_length_c                   18.520(7)
_cell_measurement_reflns_used    15742
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.00
_cell_measurement_theta_min      1.62
_cell_volume                     3211.2(17)
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0573
_diffrn_reflns_av_sigmaI/netI    0.1671
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            15742
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.62
_exptl_absorpt_coefficient_mu    3.367
_exptl_absorpt_correction_T_max  0.5246
_exptl_absorpt_correction_T_min  0.5114
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.344
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2152
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.22
_refine_diff_density_max         1.596
_refine_diff_density_min         -0.899
_refine_diff_density_rms         0.200
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.950
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     492
_refine_ls_number_reflns         11016
_refine_ls_number_restraints     65
_refine_ls_restrained_S_all      0.949
_refine_ls_R_factor_all          0.1989
_refine_ls_R_factor_gt           0.0781
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1667
_refine_ls_wR_factor_ref         0.2233
_reflns_number_gt                4624
_reflns_number_total             11016
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            c4ra09876e2.cif
_cod_data_source_block           926484
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7218600