Synthesis and properties of antimony(III) and bismuth(III) halide complexes of diphosphines and diarsines. Crystal structures of [Bi2I6{o-C6H4(AsMe2)2}2], [Sb2Br6{o-C6H4(PPh2)2}2], [Sb2Cl6{o-C6H4(AsMe2)2}], and [BiCl3{o-C6H4(P(O)Ph2)2}(thf)]
Genge, Anthony R. J.; Hill, Nicholas J.; Levason, William; Reid, Gillian; Journal of the Chemical Society, Dalton Transactions  (2001) 1007–; doi:10.1039/b010179f

data_7010534
_publ_section_title
;
 Synthesis and properties of antimony(III) and bismuth(III) halide
 complexes of diphosphines and diarsines. Crystal structures of
 [Bi2I6{o-C6H4(AsMe2)2}2], [Sb2Br6{o-C6H4(PPh2)2}2],
 [Sb2Cl6{o-C6H4(AsMe2)2}], and [BiCl3{o-C6H4(P(O)Ph2)2}(thf)]
;
_journal_issue                   7
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1007
_journal_paper_doi               10.1039/b010179f
_journal_year                    2001
_chemical_formula_moiety         'C10 H16 As2 Bi I3 '
_chemical_formula_structural     '[Bi2I6{o-C6H4(AsMe2)2}2]'
_chemical_formula_sum            'C10 H16 As2 Bi I3'
_chemical_formula_weight         875.77
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             19101-01-03
_audit_creation_method           'by teXsan v1.8'
_cell_angle_alpha                90
_cell_angle_beta                 90.98(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.009(5)
_cell_length_b                   12.620(4)
_cell_length_c                   16.765(3)
_cell_measurement_reflns_used    20
_cell_measurement_temperature    150.0(1)
_cell_measurement_theta_max      8.9
_cell_measurement_theta_min      7.3
_cell_volume                     1905.8(13)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan (MSC, 1992-1997)'
_computing_publication_material  'teXsan (MSC, 1992-1997)'
_computing_structure_refinement  'teXsan (MSC, 1992-1997)'
_computing_structure_solution
;
DIRDIF92 PATTY (Beurskens, 1992)
;
_diffrn_ambient_temperature      150.0(1)
_diffrn_measurement_device_type  'Rigaku AFC7S'
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      0.02447
_diffrn_orient_matrix_UB_12      -0.04741
_diffrn_orient_matrix_UB_13      -0.04572
_diffrn_orient_matrix_UB_21      -0.06425
_diffrn_orient_matrix_UB_22      -0.05673
_diffrn_orient_matrix_UB_23      0.02270
_diffrn_orient_matrix_UB_31      -0.08716
_diffrn_orient_matrix_UB_32      0.02851
_diffrn_orient_matrix_UB_33      -0.03087
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.12269
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            3754
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.02
_diffrn_standards_decay_%        1.59
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    17.459
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.622
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
DIFABS (Walker & Stuart, 1983)
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    3.052
_exptl_crystal_density_meas      ?
_exptl_crystal_description       lathe
_exptl_crystal_F_000             1536.00
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.21
_refine_diff_density_min         -1.09
_refine_ls_abs_structure_details -
_refine_ls_abs_structure_Flack   -
_refine_ls_extinction_coef       -
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.128
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     145
_refine_ls_number_reflns         1941
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           0.0349
_refine_ls_shift/su_max          0.0160
_refine_ls_shift/su_mean         0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00008|Fo|^2^]'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0375
_reflns_number_gt                1941
_reflns_number_total             3522
_reflns_threshold_expression     I>2.00\s(I)
_cod_data_source_file            b010179f.txt
_cod_data_source_block           bidiars_BiI3_+_diars
_cod_original_cell_volume        1906(1)
_cod_original_sg_symbol_H-M      'P 21/n     '
_cod_original_formula_sum        'C10 H16 As2 Bi I3 '
_cod_database_code               7010534