Kinetic and Computational Study of Dissociative Substitution and Phosphine Exchange at Tetrahedrally Distorted cis-Pt(SiMePh2)2(PMe2Ph)2
Ola F. Wendt; Robert J. Deeth; Lars I. Elding; Inorganic Chemistry 39 (2000) 5271–5276; doi:10.1021/ic000492g

data_4321548
_publ_section_title
;
 Kinetic and Computational Study of Dissociative Substitution and
 Phosphine Exchange at Tetrahedrally Distorted cis-Pt(SiMePh2)2(PMe2Ph)2
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5271
_journal_page_last               5276
_journal_paper_doi               10.1021/ic000492g
_journal_volume                  39
_journal_year                    2000
_chemical_compound_source        'see text'
_chemical_formula_sum            'C42 H48 P2 Pt Si2'
_chemical_formula_weight         866.05
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_creation_date             'Thu Sep  4 16:42:23 1997'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 105.252(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.504(1)
_cell_length_b                   14.662(1)
_cell_length_c                   17.868(1)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    298
_cell_measurement_theta_max      26.3
_cell_measurement_theta_min      17
_cell_volume                     3918.7(4)
_computing_cell_refinement       'CAD-4-Express Software'
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_computing_data_reduction        teXsan
_computing_publication_material  teXsan
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_diffrn_measurement_device       CAD4
_diffrn_measurement_method       '\w-2\Q scan'
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_diffrn_orient_matrix_UB_12      -0.05486
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_diffrn_orient_matrix_UB_23      -0.02977
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_diffrn_orient_matrix_UB_32      -0.01887
_diffrn_orient_matrix_UB_33      0.04971
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_l_max       22
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_diffrn_standards_interval_count 120
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_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.875
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   'North, Phillips & Matthews (1968)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.468
_exptl_crystal_density_meas      0.000
_exptl_crystal_description       prism
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_refine_ls_structure_factor_coef F
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_cod_data_source_file            ic000492g.cif
_cod_data_source_block           C42H48P2PtSi2
_cod_original_cell_volume        3918.5(5)
_cod_original_sg_symbol_H-M      'C 2/c '
_cod_database_code               4321548