Crystal structure of bis[μ-chloro(2,2'-bipyridine-N,N')(μ- 2-chlorobenzoato)lead(II)], [Pb(Cl)(C~10~H~8~N~2~)(ClC~6~H~4~COO)] ~2~
B.-S. Zhang; Zeitschrift für Kristallographie - New Crystal Structures 220 (2005) 73–74; doi:

data_8101701
_publ_section_title
;
Crystal structure of bis[\m-chloro(2,2'-bipyridine-N,N')(\m-
2-chlorobenzoato)lead(II)], [Pb(Cl)(C~10~H~8~N~2~)(ClC~6~H~4~COO)]
~2~
;
_journal_issue                   1
_journal_name_full
'Zeitschrift f\"ur Kristallographie - New Crystal Structures'
_journal_page_first              73
_journal_page_last               74
_journal_volume                  220
_journal_year                    2005
_chemical_formula_sum            'C17 H12 Cl2 N2 O2 Pb'
_chemical_formula_weight         554.38
_chemical_name_systematic
; 
 bis[mue-chloro(2,2'-bipyridine-N,N')(2-chloro-benzoato)lead(II)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.55(3)
_cell_angle_beta                 91.46(3)
_cell_angle_gamma                92.36(3)
_cell_formula_units_Z            2
_cell_length_a                   8.5229(17)
_cell_length_b                   9.5084(19)
_cell_length_c                   10.709(2)
_cell_measurement_temperature    293(2)
_cell_volume                     862.7(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.956
_diffrn_measured_fraction_theta_max 0.956
_diffrn_measurement_device_type  'Bruker SMART APEX CCD II'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0288
_diffrn_reflns_av_sigmaI/netI    0.0344
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            14933
_diffrn_reflns_theta_full        30.52
_diffrn_reflns_theta_max         30.52
_diffrn_reflns_theta_min         2.39
_exptl_absorpt_coefficient_mu    10.099
_exptl_absorpt_correction_T_max  0.3072
_exptl_absorpt_correction_T_min  0.1629
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.134
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             520
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.997
_refine_diff_density_min         -0.993
_refine_diff_density_rms         0.108
_refine_ls_extinction_coef       0.0003(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     218
_refine_ls_number_reflns         5055
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0334
_refine_ls_R_factor_gt           0.0253
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0285P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0548
_refine_ls_wR_factor_ref         0.0565
_reflns_number_gt                4310
_reflns_number_total             5055
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            1267-1431.cff
_cod_data_source_block           shx97
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               8101701