[Co{1,4-C(6)H(4)(CN)(2)}(2){NTf(2)}(2)][SnI{Co(CO)(4)}(3)](2)- a 2D coordination network with an intercalated carbonyl cluster.
Wolf, Silke; Feldmann, Claus; Dalton transactions (Cambridge, England : 2003) 41 (2012) 8455–8459; doi:10.1039/c2dt30411b

data_7019459
_publ_section_title
;
 [Co{1,4-C(6)H(4)(CN)(2)}(2){NTf(2)}(2)][SnI{Co(CO)(4)}(3)](2)- a 2D
 coordination network with an intercalated carbonyl cluster.
;
_journal_issue                   27
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8455
_journal_page_last               8459
_journal_paper_doi               10.1039/c2dt30411b
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C44 H8 Co7 F12 I2 N6 O32 S4 Sn2'
_chemical_formula_weight         2392.49
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.02(3)
_cell_angle_beta                 94.88(3)
_cell_angle_gamma                99.91(3)
_cell_formula_units_Z            1
_cell_length_a                   11.826(2)
_cell_length_b                   11.991(2)
_cell_length_c                   13.470(3)
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      58.53
_cell_measurement_theta_min      2.29
_cell_volume                     1817.9(7)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.942
_diffrn_measured_fraction_theta_max 0.911
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0591
_diffrn_reflns_av_sigmaI/netI    0.0912
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            17631
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         29.26
_diffrn_reflns_theta_min         1.56
_exptl_absorpt_coefficient_mu    3.310
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.185
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1137
_exptl_crystal_size_max          0.0950
_exptl_crystal_size_mid          0.0715
_exptl_crystal_size_min          0.0560
_refine_diff_density_max         0.911
_refine_diff_density_min         -1.265
_refine_diff_density_rms         0.131
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.122
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     493
_refine_ls_number_reflns         9038
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.122
_refine_ls_R_factor_all          0.0925
_refine_ls_R_factor_gt           0.0448
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0100P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0722
_refine_ls_wR_factor_ref         0.0790
_reflns_number_gt                5098
_reflns_number_total             9038
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt30411b.txt
_cod_data_source_block           p-1
_cod_original_cell_volume        1817.9(6)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7019459