Assembling silver(i) coordination polymers of an NS4-macrocycle via an endo/exocyclic coordination mode
Kim, Seulgi; Lee, Shim Sung; Kim, Joon Rae; Lee, Eunji; CrystEngComm 25 (2023) 6096–6101; doi:10.1039/D3CE00886J

data_7247493
_publ_section_title
;
 Assembling silver(i) coordination polymers of an NS4-macrocycle via an
 endo/exocyclic coordination mode
;
_journal_issue                   43
_journal_name_full               CrystEngComm
_journal_page_first              6096
_journal_page_last               6101
_journal_paper_doi               10.1039/D3CE00886J
_journal_volume                  25
_journal_year                    2023
_chemical_formula_moiety         'C38 H46 Ag3 N2 S8, 3(F6 P), 2(C H2 Cl2)'
_chemical_formula_sum            'C40 H50 Ag3 Cl4 F18 N2 P3 S8'
_chemical_formula_weight         1715.62
_space_group_crystal_system      orthorhombic
_space_group_IT_number           57
_space_group_name_Hall           '-P 2c 2b'
_space_group_name_H-M_alt        'P b c m'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2023-10-06 deposited with the CCDC.	2023-10-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.900
_exptl_crystal_description       Needle
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0545P)^2^+80.0465P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1562
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           aaa
_cod_depositor_comments
'Adding full bibliography for 7247493--7247495.cif.'
_cod_original_cell_volume        5998.62(17)
_cod_database_code               7247493
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