Photoinduced Intramolecular Cyclization of o-Ethenylaryl Isocyanides with Organic Disulfides Mediated by Diphenyl Ditelluride
Takenori Mitamura; Kimiyo Iwata; Akiya Ogawa; Journal of Organic Chemistry 76 (2011) 3880–3887; doi:10.1021/jo200299d

data_4026294
_publ_section_title
;
 Photoinduced Intramolecular Cyclization of o-Ethenylaryl Isocyanides with
 Organic Disulfides Mediated by Diphenyl Ditelluride
;
_journal_name_full               'Journal of Organic Chemistry'
_journal_page_first              3880
_journal_page_last               3887
_journal_paper_doi               10.1021/jo200299d
_journal_volume                  76
_journal_year                    2011
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_chemical_formula_sum            'C15 H12 N2 S'
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_cell_angle_gamma                90.0000
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_cell_length_b                   8.5647(4)
_cell_length_c                   14.0767(6)
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_cell_measurement_theta_min      3.05
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_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics    'CrystalStructure 4.0'
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_computing_structure_solution    'SIR92 (Altomare, et al., 1994)'
_diffrn_ambient_temperature      123
_diffrn_detector_area_resol_mean 10.000
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0209
_diffrn_reflns_limit_h_max       13
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_diffrn_reflns_limit_k_min       -10
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_diffrn_reflns_limit_l_min       -16
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_diffrn_reflns_theta_full        25.31
_diffrn_reflns_theta_max         25.31
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.234
_exptl_absorpt_correction_T_max  0.959
_exptl_absorpt_correction_T_min  0.819
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.304
_exptl_crystal_description       block
_exptl_crystal_F_000             528.00
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.180
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_refine_ls_shift/su_max          0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0292P)^2^+0.5787P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0706
_reflns_number_gt                2123
_reflns_number_total             2337
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            jo200299d_si_003.cif
_cod_data_source_block           tm101111
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