C-H Bond Activation by Unsymmetrical 2-(N-Arylimino)pyrrolide Pt Complexes: Geometric Effects on Reactivity
Carl N. Iverson; Charles A. G. Carter; R. Tom Baker; John D. Scollard; Jay A. Labinger; John E. Bercaw; Journal of the American Chemical Society 125 (2003) 12674–12675; doi:10.1021/ja036511d

data_4114276
_publ_section_title
;
 C-H Bond Activation by Unsymmetrical 2-(N-Arylimino)pyrrolide Pt
 Complexes: Geometric Effects on Reactivity
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              12674
_journal_page_last               12675
_journal_paper_doi               10.1021/ja036511d
_journal_volume                  125
_journal_year                    2003
_chemical_formula_sum            'C16 H16 F6 N2 Pt S'
_chemical_formula_weight         577.46
_chemical_name_systematic
;
  ?
;
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_atom_sites_solution_hydrogens   geom
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_cell_angle_beta                 92.254(2)
_cell_angle_gamma                90.00
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_computing_cell_refinement       'Bruker SAINT v6.02'
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_diffrn_measured_fraction_theta_max 0.948
_diffrn_measurement_device_type  'Bruker SMART 1000 ccd'
_diffrn_measurement_method       '\w scans at 5 fixed \f values'
_diffrn_radiation_monochromator  graphite
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_diffrn_standards_decay_%        'within counting statistics'
_diffrn_standards_interval_time  'first 100 scans recollected at end of runs'
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_exptl_absorpt_correction_T_min  0.232
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_exptl_crystal_colour            'pale yellow'
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_exptl_crystal_description       needle
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
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_refine_ls_number_reflns         4320
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.211
_refine_ls_R_factor_all          0.0447
_refine_ls_R_factor_gt           0.0296
_refine_ls_shift/su_max          0.066
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     w=1/\s^2^(Fo^2^)
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_gt          0.0456
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja036511dsi20030610_080743.cif
_cod_data_source_block           cis-2c
_cod_original_cell_volume        1798.3(3)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4114276