Organoplatinum Chemistry with a Dicarboxamide‒Diphosphine Ligand: Hydrogen Bonding, Cyclometalation, and a Complex with Two Metal‒Metal Donor‒Acceptor Bonds
Nasser, Nasser; Boyle, Paul D.; Puddephatt, Richard J.; Organometallics 32 (2013) 5504–; doi:10.1021/om400780q

data_4089615
_publ_section_title
;
 Organoplatinum Chemistry with a Dicarboxamide--Diphosphine Ligand:
 Hydrogen Bonding, Cyclometalation, and a Complex with Two Metal--Metal
 Donor--Acceptor Bonds
;
_journal_issue                   19
_journal_name_full               Organometallics
_journal_page_first              5504
_journal_paper_doi               10.1021/om400780q
_journal_volume                  32
_journal_year                    2013
_chemical_formula_sum            'C78 H82 Cl6 N4 O4 P4 Pt2'
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_space_group_name_Hall           '-P 1'
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_diffrn_measurement_device_type  'Bruker Kappa Axis Apex2'
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_diffrn_reflns_limit_l_min       -25
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_diffrn_reflns_theta_min         2.556
_diffrn_source                   'sealed tube'
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_number_restraints     0
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_refine_ls_R_factor_gt           0.0502
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0345P)^2^]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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_cod_database_code               4089615
_shelx_estimated_absorpt_t_min   0.546
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_shelxl_version_number           2012-9
_shelx_res_checksum              96374
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