Organic Vapor Triggered Repeatable On-Off Crystalline-State Luminescence Switching
Kensuke Naka; Takuji Kato; Seiji Watase; Kimihiro Matsukawa; Inorganic Chemistry 51 (2012) 4420–4422; doi:10.1021/ic300173t

data_4328979
_publ_contact_author_email       naka@chem.kit.ac.jp
_publ_contact_author_fax         +81-75-724-7534
_publ_contact_author_name        'Kensuke Naka'
_publ_contact_author_phone       +81-75-724-7534
_publ_section_title
;
 Organic Vapor Triggered Repeatable On-Off Crystalline-State Luminescence
 Switching
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4420
_journal_page_last               4422
_journal_paper_doi               10.1021/ic300173t
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C54 H88 As4 Cl4 I2 O16 Pt '
_chemical_formula_sum            'C54 H88 As4 Cl4 I2 O16 Pt'
_chemical_formula_weight         1883.68
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                69.0746(12)
_cell_angle_beta                 68.9500(11)
_cell_angle_gamma                88.8248(13)
_cell_formula_units_Z            1
_cell_length_a                   10.6133(4)
_cell_length_b                   13.4145(6)
_cell_length_c                   14.3814(5)
_cell_measurement_reflns_used    17776
_cell_measurement_temperature    296.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     1771.15(12)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.044
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            17082
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_exptl_absorpt_coefficient_mu    4.908
_exptl_absorpt_correction_T_max  0.479
_exptl_absorpt_correction_T_min  0.281
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
    Higashi, T. (1999). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.766
_exptl_crystal_description       block
_exptl_crystal_F_000             924.00
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.23
_refine_diff_density_min         -1.21
_refine_ls_extinction_coef       9(5)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   1.015
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     397
_refine_ls_number_reflns         6127
_refine_ls_R_factor_gt           0.0421
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0010Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0966
_reflns_number_gt                6100
_reflns_number_total             8044
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic300173t_si_003_2.cif
_cod_data_source_block           '_trans-PtI2(cis-DHDAtBu)2_including_CH2Cl2'
_cod_original_formula_sum        'C54 H88 As4 Cl4 I2 O16 Pt '
_cod_database_code               4328979