LMucko/crystallography-open-database huggingface dataset:
Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
Wang, Baiquan; Zhu, Bolin; Zhang, Jianyong; Xu, Shansheng; Zhou, Xiuzhong; Weng, Linhong; Organometallics 22 (2003) 5543–5555; doi:10.1021/om030364a

data_4062208
_publ_section_title
;
 Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
;
_journal_coden_ASTM              ORGND7
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              5543
_journal_page_last               5555
_journal_paper_doi               10.1021/om030364a
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C29 H22 Fe2 O4 Si'
_chemical_formula_weight         574.26
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                72.204(7)
_cell_angle_beta                 79.040(7)
_cell_angle_gamma                88.160(7)
_cell_formula_units_Z            2
_cell_length_a                   8.394(4)
_cell_length_b                   10.097(4)
_cell_length_c                   16.130(7)
_cell_measurement_temperature    293(2)
_cell_volume                     1277.4(9)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.493
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

 Updated bibliographical information.

 Antanas Vaitkus,
 2019-09-11
;
_cod_database_code               4062208
Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
Wang, Baiquan; Zhu, Bolin; Zhang, Jianyong; Xu, Shansheng; Zhou, Xiuzhong; Weng, Linhong; Organometallics 22 (2003) 5543–5555; doi:10.1021/om030364a

data_4062209
_publ_section_title
;
 Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
;
_journal_coden_ASTM              ORGND7
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              5543
_journal_page_last               5555
_journal_paper_doi               10.1021/om030364a
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C22 H22 Fe2 N0 O4 Si'
_chemical_formula_weight         490.19
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.006(4)
_cell_length_b                   12.069(5)
_cell_length_c                   17.325(8)
_cell_measurement_temperature    273(2)
_cell_volume                     2092.2(16)
_diffrn_ambient_temperature      273(2)
_exptl_crystal_density_diffrn    1.556
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

 Updated bibliographical information.

 Antanas Vaitkus,
 2019-09-11
;
_cod_database_code               4062209
Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
Wang, Baiquan; Zhu, Bolin; Zhang, Jianyong; Xu, Shansheng; Zhou, Xiuzhong; Weng, Linhong; Organometallics 22 (2003) 5543–5555; doi:10.1021/om030364a

data_4062210
_publ_section_title
;
 Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
;
_journal_coden_ASTM              ORGND7
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              5543
_journal_page_last               5555
_journal_paper_doi               10.1021/om030364a
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C22 H22 Fe2 O4 Si'
_chemical_formula_weight         490.19
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 109.990(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.505(3)
_cell_length_b                   17.433(6)
_cell_length_c                   13.441(5)
_cell_measurement_temperature    273(2)
_cell_volume                     2092.9(12)
_diffrn_ambient_temperature      273(2)
_exptl_crystal_density_diffrn    1.556
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

 Updated bibliographical information.

 Antanas Vaitkus,
 2019-09-11
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062210
Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
Wang, Baiquan; Zhu, Bolin; Zhang, Jianyong; Xu, Shansheng; Zhou, Xiuzhong; Weng, Linhong; Organometallics 22 (2003) 5543–5555; doi:10.1021/om030364a

data_4062211
_publ_section_title
;
 Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
;
_journal_coden_ASTM              ORGND7
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              5543
_journal_page_last               5555
_journal_paper_doi               10.1021/om030364a
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C22 H22 Fe2 Ge O4'
_chemical_formula_weight         534.69
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.937(3)
_cell_length_b                   12.085(4)
_cell_length_c                   17.485(5)
_cell_measurement_temperature    293(2)
_cell_volume                     2099.8(11)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.691
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

 Updated bibliographical information.

 Antanas Vaitkus,
 2019-09-11
;
_cod_database_code               4062211
Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
Wang, Baiquan; Zhu, Bolin; Zhang, Jianyong; Xu, Shansheng; Zhou, Xiuzhong; Weng, Linhong; Organometallics 22 (2003) 5543–5555; doi:10.1021/om030364a

data_4062212
_publ_section_title
;
 Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
;
_journal_coden_ASTM              ORGND7
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              5543
_journal_page_last               5555
_journal_paper_doi               10.1021/om030364a
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C18 H16 Fe2 O5 Si'
_chemical_formula_weight         452.10
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                104.962(12)
_cell_angle_beta                 90.808(13)
_cell_angle_gamma                105.267(13)
_cell_formula_units_Z            2
_cell_length_a                   7.895(6)
_cell_length_b                   8.874(6)
_cell_length_c                   13.927(10)
_cell_measurement_temperature    273(2)
_cell_volume                     905.8(11)
_diffrn_ambient_temperature      273(2)
_exptl_crystal_density_diffrn    1.658
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

 Updated bibliographical information.

 Antanas Vaitkus,
 2019-09-11
;
_cod_database_code               4062212
Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
Wang, Baiquan; Zhu, Bolin; Zhang, Jianyong; Xu, Shansheng; Zhou, Xiuzhong; Weng, Linhong; Organometallics 22 (2003) 5543–5555; doi:10.1021/om030364a

data_4062213
_publ_section_title
;
 Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
;
_journal_coden_ASTM              ORGND7
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              5543
_journal_page_last               5555
_journal_paper_doi               10.1021/om030364a
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C17 H14 Fe2 O4 Si'
_chemical_formula_weight         422.07
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 113.149(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.300(4)
_cell_length_b                   11.905(5)
_cell_length_c                   9.169(4)
_cell_measurement_temperature    273(2)
_cell_volume                     833.1(6)
_diffrn_ambient_temperature      273(2)
_exptl_crystal_density_diffrn    1.683
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

 Updated bibliographical information.

 Antanas Vaitkus,
 2019-09-11
;
_cod_original_sg_symbol_H-M      'P 21/m'
_cod_database_code               4062213
Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
Wang, Baiquan; Zhu, Bolin; Zhang, Jianyong; Xu, Shansheng; Zhou, Xiuzhong; Weng, Linhong; Organometallics 22 (2003) 5543–5555; doi:10.1021/om030364a

data_4062214
_publ_section_title
;
 Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
;
_journal_coden_ASTM              ORGND7
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              5543
_journal_page_last               5555
_journal_paper_doi               10.1021/om030364a
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C36 H32 Fe4 Ge2 O10'
_chemical_formula_weight         993.20
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 106.506(12)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.092(4)
_cell_length_b                   12.968(5)
_cell_length_c                   29.395(10)
_cell_measurement_temperature    293(2)
_cell_volume                     3688(2)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.789
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

 Updated bibliographical information.

 Antanas Vaitkus,
 2019-09-11
;
_cod_original_sg_symbol_H-M      'P 2/c'
_cod_database_code               4062214
Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
Wang, Baiquan; Zhu, Bolin; Zhang, Jianyong; Xu, Shansheng; Zhou, Xiuzhong; Weng, Linhong; Organometallics 22 (2003) 5543–5555; doi:10.1021/om030364a

data_4062215
_publ_section_title
;
 Reactions of Doubly Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl
;
_journal_coden_ASTM              ORGND7
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              5543
_journal_page_last               5555
_journal_paper_doi               10.1021/om030364a
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C17 H14 Fe2 Ge O4'
_chemical_formula_weight         466.57
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 104.543(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.147(4)
_cell_length_b                   13.971(5)
_cell_length_c                   12.300(5)
_cell_measurement_temperature    293(2)
_cell_volume                     1687.9(11)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.836
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

 Updated bibliographical information.

 Antanas Vaitkus,
 2019-09-11
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062215
Dicopper(I) Oxalate Complexes Stabilized by Lewis Bases: Potential Precursors for Copper Deposition
Köhler, Katrin; Eichhorn, Jens; Meyer, Franc; Vidovic, Denis; Organometallics 22 (2003) 4426–4432; doi:10.1021/om0303653

data_4062216
_publ_section_title
;
 Dicopper(I) Oxalate Complexes Stabilized by Lewis Bases: Potential Precursors
 for Copper Deposition
;
_journal_issue                   22
_journal_name_full               Organometallics
_journal_page_first              4426
_journal_page_last               4432
_journal_paper_doi               10.1021/om0303653
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C18 H36 Cu2 O4 Si4'
_chemical_formula_weight         555.91
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 100.02(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.435(3)
_cell_length_b                   9.6089(19)
_cell_length_c                   18.519(4)
_cell_measurement_temperature    133(2)
_cell_volume                     2704.7(9)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.365
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4062216
Dicopper(I) Oxalate Complexes Stabilized by Lewis Bases: Potential Precursors for Copper Deposition
Köhler, Katrin; Eichhorn, Jens; Meyer, Franc; Vidovic, Denis; Organometallics 22 (2003) 4426–4432; doi:10.1021/om0303653

data_4062217
_publ_section_title
;
 Dicopper(I) Oxalate Complexes Stabilized by Lewis Bases: Potential Precursors
 for Copper Deposition
;
_journal_issue                   22
_journal_name_full               Organometallics
_journal_page_first              4426
_journal_page_last               4432
_journal_paper_doi               10.1021/om0303653
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C14 H20 Cu2 O4'
_chemical_formula_weight         379.38
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 108.10(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   9.837(2)
_cell_length_b                   5.3678(11)
_cell_length_c                   15.316(3)
_cell_measurement_temperature    133(2)
_cell_volume                     768.7(3)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.639
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062217
Yttrium Alkyl and Hydrido Complexes Containing a Tridentate Linked Amido-Cyclopentadienyl Ligand
Voth, Peter; Spaniol, Thomas P.; Okuda, Jun; Organometallics  (2003) –; doi:

data_4062218
_publ_section_title
;
Yttrium Alkyl and Hydrido Complexes Containing a Tridentate Linked
Amido-Cyclopentadienyl Ligand
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C24 H49 N2 O Si2 Y'
_chemical_formula_weight         526.75
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.2000(7)
_cell_length_b                   17.6770(10)
_cell_length_c                   18.0300(10)
_cell_measurement_temperature    193(2)
_cell_volume                     2932.2(3)
_diffrn_ambient_temperature      193(2)
_exptl_crystal_density_diffrn    1.193
_cod_database_code               4062218
Yttrium Alkyl and Hydrido Complexes Containing a Tridentate Linked Amido-Cyclopentadienyl Ligand
Voth, Peter; Spaniol, Thomas P.; Okuda, Jun; Organometallics  (2003) –; doi:

data_4062219
_publ_section_title
;
Yttrium Alkyl and Hydrido Complexes Containing a Tridentate Linked
Amido-Cyclopentadienyl Ligand
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C32 H62 N4 Si2 Y2'
_chemical_formula_weight         736.86
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 96.942(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.8129(2)
_cell_length_b                   17.3648(5)
_cell_length_c                   21.0539(5)
_cell_measurement_temperature    193(2)
_cell_volume                     3924.18(16)
_diffrn_ambient_temperature      193(2)
_exptl_crystal_density_diffrn    1.247
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062219
Yttrium Alkyl and Hydrido Complexes Containing a Tridentate Linked Amido-Cyclopentadienyl Ligand
Voth, Peter; Spaniol, Thomas P.; Okuda, Jun; Organometallics  (2003) –; doi:

data_4062220
_publ_section_title
;
Yttrium Alkyl and Hydrido Complexes Containing a Tridentate Linked
Amido-Cyclopentadienyl Ligand
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C24 H39 N2 Si Y'
_chemical_formula_weight         472.58
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 102.14(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.10(2)
_cell_length_b                   10.710(10)
_cell_length_c                   13.89(2)
_cell_measurement_temperature    250(2)
_cell_volume                     2632(5)
_diffrn_ambient_temperature      250(2)
_exptl_crystal_density_diffrn    1.192
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062220
Carbon-Oxygen Bond Cleavage Promoted by a Scandium Borohydride Complex
Basuli, Falguni; Tomaszewski, John; Huffman, John C.; Mindiola, Daniel J.; Organometallics 22 (2003) 4705–4714; doi:10.1021/om030374b

data_4062221
_publ_section_title
;
 Carbon-Oxygen Bond Cleavage Promoted by a Scandium Borohydride Complex
;
_journal_issue                   23
_journal_name_full               Organometallics
_journal_page_first              4705
_journal_page_last               4714
_journal_paper_doi               10.1021/om030374b
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C45 H67 Cl N3 O Sc'
_chemical_formula_weight         746.43
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 93.4750(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.1239(5)
_cell_length_b                   17.0782(7)
_cell_length_c                   20.3922(8)
_cell_measurement_temperature    128(2)
_cell_volume                     4214.5(3)
_diffrn_ambient_temperature      128(2)
_exptl_crystal_density_diffrn    1.176
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062221
Carbon-Oxygen Bond Cleavage Promoted by a Scandium Borohydride Complex
Basuli, Falguni; Tomaszewski, John; Huffman, John C.; Mindiola, Daniel J.; Organometallics 22 (2003) 4705–4714; doi:10.1021/om030374b

data_4062222
_publ_section_title
;
 Carbon-Oxygen Bond Cleavage Promoted by a Scandium Borohydride Complex
;
_journal_issue                   23
_journal_name_full               Organometallics
_journal_page_first              4705
_journal_page_last               4714
_journal_paper_doi               10.1021/om030374b
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C47 H75 B N3 Sc'
_chemical_formula_weight         737.87
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 91.6940(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.3666(6)
_cell_length_b                   17.6914(9)
_cell_length_c                   22.4483(12)
_cell_measurement_temperature    128(2)
_cell_volume                     4512.2(4)
_diffrn_ambient_temperature      128(2)
_exptl_crystal_density_diffrn    1.086
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062222