Two types of heterometallic one-dimensional alignment composed of acetamidate-bridged dirhodium and pivalamidate-bridged diplatinum complexes.
Uemura, Kazuhiro; Kanbara, Toru; Ebihara, Masahiro; Inorganic chemistry 53 (2014) 4621–4628; doi:10.1021/ic500305n

data_4338209
_publ_section_title
;
 Two types of heterometallic one-dimensional alignment composed of
 acetamidate-bridged dirhodium and pivalamidate-bridged diplatinum
 complexes.
;
_journal_issue                   9
_journal_name_full               'Inorganic chemistry'
_journal_page_first              4621
_journal_page_last               4628
_journal_paper_doi               10.1021/ic500305n
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C26 H48 F6 N10 O12 Pt2 Rh2'
_chemical_formula_weight         1402.74
_chemical_name_systematic
; 
 ? 
;
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_symmetry_space_group_name_H-M   'P 21 21 21'
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_computing_cell_refinement       CRYSTALCLEAR
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_computing_molecular_graphics
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
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'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
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_diffrn_ambient_temperature      123(2)
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_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  'Graphite Monochromator'
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_h_max       14
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_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            36719
_diffrn_reflns_theta_full        27.50
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_exptl_absorpt_correction_T_max  0.7214
_exptl_absorpt_correction_T_min  0.2740
_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.065
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2680
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_number_reflns         10332
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_refine_ls_R_factor_all          0.0924
_refine_ls_R_factor_gt           0.0725
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0404P)^2^+64.0538P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                8251
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic500305n_si_003.cif
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_cod_depositor_comments
'Adding full bibliography for 4338208--4338209.cif.'
_cod_original_cell_volume        4511.1(19)
_cod_database_code               4338209