Sterically-directed disassembly of diruthenium(II,III) tetraacetate using substituted and unsubstituted 2,2'-bipyridines and 1,10-phenanthrolines
Luc J. Boudreau; Terri L. Clarke; Adrian H. Murray; Katherine N. Robertson; T. Stanley Cameron; Manuel A.S. Aquino; Inorganica Chimica Acta 393 (2012) 152–158; doi:

data_1512711
_publ_section_title
;
 Sterically-directed disassembly of diruthenium(II,III) tetraacetate using
 substituted and unsubstituted 2,2'-bipyridines and 1,10-phenanthrolines
;
_journal_name_full
;
Inorganica Chimica Acta
;
_journal_page_first              152
_journal_page_last               158
_journal_volume                  393
_journal_year                    2012
_chemical_formula_moiety         'C27 H31 F6 N4 O3 P Ru '
_chemical_formula_sum            'C27 H31 F6 N4 O3 P Ru'
_chemical_formula_weight         705.60
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 118.3799(12)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   14.5527(18)
_cell_length_b                   14.5492(16)
_cell_length_c                   15.2941(19)
_cell_measurement_reflns_used    343
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      35.0
_cell_measurement_theta_min      1.4
_cell_volume                     2849.0(6)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_ambient_temperature      113.1
_diffrn_detector_area_resol_mean 14.63
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.029
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            51467
_diffrn_reflns_theta_full        35.00
_diffrn_reflns_theta_max         35.00
_exptl_absorpt_coefficient_mu    0.683
_exptl_absorpt_correction_T_max  0.921
_exptl_absorpt_correction_T_min  0.659
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            'red (deep red)'
_exptl_crystal_density_diffrn    1.645
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       parallelapiped
_exptl_crystal_F_000             1432.00
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.12
_refine_diff_density_max         2.35
_refine_diff_density_min         -1.59
_refine_ls_extinction_coef       91(11)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     410
_refine_ls_number_reflns         8612
_refine_ls_R_factor_gt           0.0605
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details
;
    Chebychev polynomial with 3 parameters (Carruthers & Watkin, 1979)
    11.2245    0.2264    5.9815
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0666
_reflns_number_gt                8612
_reflns_number_total             12467
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ICA-2013-394-152-158-1.cif
_cod_data_source_block           Complex-4
_cod_original_formula_sum        'C27 H31 F6 N4 O3 P Ru '
_cod_database_code               1512711