Synthesis and Characterization of Siloxy, Aminoxy, and Oxo Complexes from the Reaction of a Tantalum Amide Silyl Complex with Oxygen
He Qiu; Shu-Jian Chen; Chang-Sheng Wang; Yun-Dong Wu; Ilia A. Guzei; Xue-Tai Chen; Zi-Ling Xue; Inorganic Chemistry 48 (2009) 3073–3079; doi:10.1021/ic802380u

data_4301871
_publ_contact_author_address
;
Department of Chemistry
University of Wisconsin-Madison
1101 University Ave
Madison, WI  53706
USA
;
_publ_contact_author_email       iguzei@chem.wisc.edu
_publ_contact_author_fax         608-262-0381
_publ_contact_author_name
;
Guzei, Ilia A. 
;
_publ_contact_author_phone       608-263-4694
_publ_section_title
;
Synthesis and Characterization of Siloxy, Aminoxy, and Oxo Complexes from
the Reaction of a Tantalum Amide Silyl Complex with Oxygen
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3073
_journal_page_last               3079
_journal_paper_doi               10.1021/ic802380u
_journal_volume                  48
_journal_year                    2009
_chemical_formula_moiety         'C46 H76 Cl4 N6 O4 Si2 Ta2'
_chemical_formula_sum            'C46 H76 Cl4 N6 O4 Si2 Ta2'
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_symmetry_space_group_name_Hall  '-P 1'
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_audit_creation_method
;
manual editing of the CIF file 
created by SHELXTL Ver. 6.10
and processed with modiCIfer-03272007. 
;
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_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker CCD-1000 area detector'
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_diffrn_reflns_theta_min         1.16
_exptl_absorpt_coefficient_mu    4.276
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;
SADABS  (Bruker-AXS, 2007)
;
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0401P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     I>2\s(I)
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_cod_database_code               4301871