Two new members in the quaternary Cs-Ag-As-S family with different arrangements of Ag-S and As-S asymmetric building units: syntheses, structures, and theoretical studies.
Yan, Dongming; Xiao, Yu; Liu, Chang; Hou, Peipei; Chai, Wenxiang; Hosono, Hideo; Lin, Hua; Liu, Yi; Dalton transactions (Cambridge, England : 2003) 49 (2020) 9743–9750; doi:10.1039/d0dt01375g

data_7704691
_publ_section_title
;
 Two new members in the quaternary Cs-Ag-As-S family with different
 arrangements of Ag-S and As-S asymmetric building units: syntheses,
 structures, and theoretical studies.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9743
_journal_page_last               9750
_journal_paper_doi               10.1039/d0dt01375g
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'Ag As4 Cs3 S8'
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_space_group_name_Hall           '-C 2yc'
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_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-03-12 deposited with the CCDC.	2020-06-22 downloaded from the CCDC.
;
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_exptl_crystal_colour            YELLOW
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_exptl_crystal_description       PLATE
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt01375g2.cif
_cod_data_source_block           Cs3AgAs4S8
_cod_depositor_comments
'Adding full bibliography for 7704690--7704691.cif.'
_cod_original_cell_volume        3586.7(14)
_cod_original_sg_symbol_H-M      'C 2/c'
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