Preparation and Structure of New Phenylplatinum Complexes Containing Silsesquioxane as a Monodentate or Bidentate Ligand
Mintcheva, Neli; Tanabe, Makoto; Osakada, Kohtaro; Organometallics 25 (2006) 3776–; doi:10.1021/om060192s

data_4075293
_publ_section_title
;
 Preparation and Structure of New Phenylplatinum Complexes Containing
 Silsesquioxane as a Monodentate or Bidentate Ligand
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              3776
_journal_paper_doi               10.1021/om060192s
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C53 H100 O12 P2 Pt Si7 '
_chemical_formula_sum            'C53 H100 O12 P2 Pt Si7'
_chemical_formula_weight         1383.00
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 91.964(2)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   11.3362(17)
_cell_length_b                   26.444(4)
_cell_length_c                   21.509(3)
_cell_measurement_reflns_used    18087
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     6444.1(16)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.062
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            47857
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    2.403
_exptl_absorpt_correction_T_max  0.866
_exptl_absorpt_correction_T_min  0.687
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.425
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2880.00
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_refine_diff_density_max         2.03
_refine_diff_density_min         -1.42
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.939
_refine_ls_hydrogen_treatment    mixed
_refine_ls_number_parameters     782
_refine_ls_number_reflns         14542
_refine_ls_R_factor_gt           0.0368
_refine_ls_shift/su_max          0.0004
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0005Fo^2^ + 0.5000\s(Fo^2^) + 0.5000]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1017
_reflns_number_gt                9084
_reflns_number_total             14542
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om060192ssi20060228_042848.cif
_cod_data_source_block           form1a
_cod_original_formula_sum        'C53 H100 O12 P2 Pt Si7 '
_cod_database_code               4075293