Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl Backbones: Synthesis of Three Different Motifs and Their Application in Enantioselective Diels–Alder Reactions
Rohde, Volker H. G.; Müller, Maria F.; Oestreich, Martin; Organometallics 34 (2015) 3358–; doi:10.1021/acs.organomet.5b00351

data_4085948
_publ_section_title
;
 Intramolecularly Sulfur-Stabilized Silicon Cations with Chiral Binaphthyl
 Backbones: Synthesis of Three Different Motifs and Their Application in
 Enantioselective Diels--Alder Reactions
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3358
_journal_paper_doi               10.1021/acs.organomet.5b00351
_journal_volume                  34
_journal_year                    2015
_chemical_absolute_configuration ad
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            colourless
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_refine_ls_number_reflns         5157
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0564P)^2^+0.0980P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0866
_reflns_number_gt                4980
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_cod_data_source_file            om5b00351_si_002.cif
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_cod_depositor_comments
'Adding full bibliography for 4085948--4085949.cif.'
_cod_original_cell_volume        2093.63(5)
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