Di-μ-chlorido-bis-(chlorido-{N'-[phen-yl(pyridin-2-yl-κN)methyl-idene]pyridine-2-carbohydrazide-κ(2) N',O}cadmium).
Akkurt, Mehmet; Khandar, Ali Akbar; Tahir, Muhammad Nawaz; Afkhami, Farhad Akbari; Yazdi, Seyed Abolfazl Hosseini; Acta crystallographica. Section E, Structure reports online 70 (2014) m213–4; doi:10.1107/S1600536814010630

data_2311239
_publ_section_title
;
 Di-\m-chlorido-bis-(chlorido-{N'-[phen-yl(pyridin-2-yl-\kN)methyl-idene]pyridine-2-carbohydrazide-\k(2)
 N',O}cadmium).
;
_journal_coeditor_code           RZ5124
_journal_issue                   'Pt 6'
_journal_name_full
'Acta crystallographica. Section E, Structure reports online'
_journal_page_first              m213
_journal_page_last               4
_journal_paper_doi               10.1107/S1600536814010630
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac          '[Cd2 Cl4 (C18 H14 N4 O)2]'
_chemical_formula_moiety         'C36 H28 Cd2 Cl4 N8 O2'
_chemical_formula_sum            'C36 H28 Cd2 Cl4 N8 O2'
_chemical_formula_weight         971.28
_chemical_name_systematic
Di-\m-chlorido-bis(chlorido{<i>N</i>'-[phenyl(pyridin-2-yl-\k<i>N</i>)methylidene]pyridine-2-carbohydrazide-\k^2^<i>N</i>',<i>O</i>}cadmium)
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90
_cell_angle_beta                 104.6670(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.3215(4)
_cell_length_b                   14.4905(4)
_cell_length_c                   17.5457(5)
_cell_measurement_reflns_used    310
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      18.2
_cell_measurement_theta_min      3.5
_cell_volume                     3768.49(18)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'APEX2 (Bruker, 2009)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics
'ORTEP-3 for Windows (Farrugia, 2012) and PLATON (Spek, 2009)'
_computing_publication_material
'WinGX (Farrugia, 2012) and PLATON (Spek, 2009)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker Kappa APEXII CCD'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0657
_diffrn_reflns_av_sigmaI/netI    0.0734
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            36565
_diffrn_reflns_reduction_process
;
;
_diffrn_reflns_theta_full        28.37
_diffrn_reflns_theta_max         28.37
_diffrn_reflns_theta_min         1.85
_exptl_absorpt_coefficient_mu    1.457
_exptl_absorpt_correction_T_max  0.769
_exptl_absorpt_correction_T_min  0.722
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2005)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.712
_exptl_crystal_density_method    'Not Measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1920
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.470
_refine_diff_density_min         -0.426
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.981
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     469
_refine_ls_number_reflns         9369
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.981
_refine_ls_R_factor_all          0.0951
_refine_ls_R_factor_gt           0.0438
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0251P)^2^]         where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0690
_refine_ls_wR_factor_ref         0.0826
_reflns_number_gt                5625
_reflns_number_total             9369
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            rz5124sup1.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2311239