Mixed-Ligand Molecular Paneling: Dodecanuclear Cuboctahedral Coordination Cages Based on a Combination of Edge-Bridging and Face-Capping Ligands
Nawal K. Al-Rasbi; Ian S. Tidmarsh; Stephen P. Argent; Harry Adams; Lindsay P. Harding; Michael D. Ward; Journal of the American Chemical Society 130 (2008) 11641–11649; doi:10.1021/ja803847w

data_4108280
_publ_contact_author
; 
        Prof. Mike Ward
        Department of Chemistry
        University of Sheffield
        SHEFFIELD
        S3 7HF
;
_publ_contact_author_email       m.d.ward@sheffield.ac.uk
_publ_contact_author_fax         '0114 2229346'
_publ_section_title
;
 Mixed-Ligand Molecular Paneling: Dodecanuclear Cuboctahedral Coordination
 Cages Based on a Combination of Edge-Bridging and Face-Capping Ligands
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11641
_journal_page_last               11649
_journal_paper_doi               10.1021/ja803847w
_journal_volume                  130
_journal_year                    2008
_chemical_formula_sum            'C433 H375 Cd12 Cl24 N109 O98'
_chemical_formula_weight         10873.02
_chemical_name_systematic
;
 ?
;
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_cell_measurement_theta_max      22.45
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_computing_cell_refinement       'Bruker SMART'
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_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
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_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_theta_min         3.32
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_exptl_absorpt_correction_T_min  0.92
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         102364
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_database_code               4108280