Polymeric cobalt(ii) thiolato complexes - syntheses, structures and properties of [Co(SMes)2] and [Co(SPh)2NH3].
Eichhöfer, Andreas; Buth, Gernot; Dalton transactions (Cambridge, England : 2003) 45 (2016) 17382–17391; doi:10.1039/c6dt03098j

data_7040750
_publ_section_title
;
 Polymeric cobalt(ii) thiolato complexes - syntheses, structures and
 properties of [Co(SMes)2] and [Co(SPh)2NH3].
;
_journal_issue                   43
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              17382
_journal_page_last               17391
_journal_paper_doi               10.1039/c6dt03098j
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C18 H22 Co S2'
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_chemical_name_systematic
; 
 ? 
;
_chemical_properties_physical
', Air-sensitive,Moisture-sensitive,Oxygen-sensitive'
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_space_group_name_Hall           '-I 4'
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_symmetry_space_group_name_Hall  '-I 4'
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_audit_update_record
;
2016-06-06 deposited with the CCDC.
2016-09-27 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
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_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_measurement_method       'rotation method'
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_diffrn_reflns_av_R_equivalents  0.0567
_diffrn_reflns_av_unetI/netI     0.0412
_diffrn_reflns_Laue_measured_fraction_full 0.976
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_diffrn_reflns_point_group_measured_fraction_full 0.976
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_diffrn_source
'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
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_exptl_absorpt_correction_type   integration
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_exptl_crystal_description       needle
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_exptl_crystal_preparation       ', Magnetic properties'
_exptl_crystal_recrystallization_method 'from reaction solution'
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_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0450
_refine_ls_R_factor_gt           0.0374
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0437P)^2^+3.2692P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0894
_refine_ls_wR_factor_ref         0.0925
_reflns_Friedel_coverage         0.000
_reflns_number_gt                885
_reflns_number_total             1025
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt03098j2.cif
_cod_data_source_block           i4m_sq
_cod_depositor_comments
;Adding full bibliography for 7040748--7040750.cif.

 Adding full bibliography for 7040748--7040750.cif.
;
_cod_original_cell_volume        1918.3(2)
_cod_database_code               7040750
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