Gallium(iii)-polypyridyl complexes as anti-osteosarcoma stem cell agents.
Robin, Perrine; Singh, Kuldip; Suntharalingam, Kogularamanan; Chemical communications (Cambridge, England) 56 (2020) 1509–1512; doi:10.1039/c9cc08962d

data_7125697
_publ_section_title
;
 Gallium(iii)-polypyridyl complexes as anti-osteosarcoma stem cell agents.
;
_journal_issue                   10
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              1509
_journal_page_last               1512
_journal_paper_doi               10.1039/c9cc08962d
_journal_volume                  56
_journal_year                    2020
_chemical_formula_moiety         'C32 H32 Cl2 Ga N4, Cl4 Ga,2C H3 C N'
_chemical_formula_sum            'C36 H38 Cl6 Ga2 N6'
_chemical_formula_weight         906.86
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2019-08-17 deposited with the CCDC.	2019-12-27 downloaded from the CCDC.
;
_cell_angle_alpha                76.662(5)
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_cell_angle_gamma                86.074(5)
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_cell_volume                     3904.6(19)
_computing_cell_refinement       'Bruker SMART'
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_computing_molecular_graphics    'Bruker SHELXTL'
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_computing_structure_solution    'Bruker SHELXTL'
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_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_type   empirical
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;
absoprtion correction based on 8245 reflections(SADABS);Rint 0.0921
before correction and 0.0441 after.
;
_exptl_crystal_colour            colourless
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_exptl_crystal_description       block
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         15153
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.782
_refine_ls_R_factor_all          0.1140
_refine_ls_R_factor_gt           0.0604
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0670P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1253
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_reflns_number_gt                8130
_reflns_number_total             15153
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7125697.cif.'
_cod_database_code               7125697
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