Oxidative Addition, Reduction and Reductive Coupling: The Versatile Reactivity of Subvalent Gallium Cations.
Schorpp, Marcel; Tamim, Razan; Krossing, Ingo; Dalton Transactions  (2021) –; doi:10.1039/D1DT02682H

data_7708278
_publ_section_title
;
 Oxidative Addition, Reduction and Reductive Coupling: The Versatile
 Reactivity of Subvalent Gallium Cations.
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D1DT02682H
_journal_year                    2021
_chemical_formula_moiety         '	C16 Al F36 O4, C36 H30 P3'
_chemical_formula_sum            'C52 H30 Al F36 O4 P3'
_chemical_formula_weight         1522.65
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_audit_creation_method
;
FinalCif V59 by Daniel Kratzert, Freiburg 2019,
https://github.com/dkratzert/FinalCif
;
_audit_update_record
;
2021-09-03 deposited with the CCDC.	2021-09-08 downloaded from the CCDC.
;
_cell_angle_alpha                90
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'Bruker BIS 2015.5.1.2/11-Jun-2015 P2 && APEX2_2014.11-0'
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_diffrn_measurement_device       'three-circle diffractometer'
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_diffrn_reflns_limit_l_min       -33
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_diffrn_source                   'microfocus sealed X-ray tube'
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_exptl_absorpt_correction_T_min  0.6799
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 - Bruker AXS area detector scaling and absorption correction:
Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D., J. Appl. Cryst. 48
(2015) 3-10
;
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1569P)^2^+9.6803P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2246
_refine_ls_wR_factor_ref         0.2477
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9244
_reflns_number_total             12243
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1dt02682h2.cif
_cod_data_source_block           P21n_a
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7708278
_shelx_shelxl_version_number     2018/3
_olex2_diffrn_ambient_temperature_device 'Oxford Cryostream 800'
_shelx_res_checksum              36051