Au → M bonds promote catalytic alkyne hydrofunctionalisation.
Eltester, M. Alexander; Gildenast, Hans; Rabatinová, Kristína; Pütz, Christopher; Cremer, Christopher; Lanzerath, Patrick; Schroers, Julian P.; Tauchert, Michael E.; Chemical communications (Cambridge, England) 59 (2023) 5459–5462; doi:10.1039/d3cc01008b

data_7131549
_publ_section_title
;
 Au &#x2192; M bonds promote catalytic alkyne hydrofunctionalisation.
;
_journal_issue                   36
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              5459
_journal_page_last               5462
_journal_paper_doi               10.1039/d3cc01008b
_journal_volume                  59
_journal_year                    2023
_chemical_formula_moiety         'C42 H36 Au Cl Cu N4 P2, C F3 O3 S, C4 H8 O'
_chemical_formula_sum            'C47 H44 Au Cl Cu F3 N4 O4 P2 S'
_chemical_formula_weight         1175.82
_chemical_name_common            11
_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_Hall           '-P 2ac 2n'
_space_group_name_H-M_alt        'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2023-02-27 deposited with the CCDC.	2023-04-12 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'CCD area detector'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w=1/[\s^2^(Fo^2^)] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7131547--7131553.cif.'
_cod_original_cell_volume        4691.3(10)
_cod_database_code               7131549
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