The trinuclear platinum(ii) complex in Vèzes' red salt as a building block of coordination polymers.
Hoshino, Norihisa; Fujita, Sena; Akutagawa, Tomoyuki; Dalton transactions (Cambridge, England : 2003) 48 (2018) 176–181; doi:10.1039/c8dt04121k

data_7048259
_publ_section_title
;
 The trinuclear platinum(ii) complex in V\`ezes' red salt as a building
 block of coordination polymers.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              176
_journal_page_last               181
_journal_paper_doi               10.1039/c8dt04121k
_journal_volume                  48
_journal_year                    2018
_chemical_formula_moiety         'C15 H30 Ag2 N6 O20 Pt3'
_chemical_formula_sum            'C15 H30 Ag2 N6 O20 Pt3'
_chemical_formula_weight         1415.46
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-10-15 deposited with the CCDC.
2018-11-27 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 92.200(7)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.1780(2)
_cell_length_b                   21.7158(4)
_cell_length_c                   18.2590(4)
_cell_measurement_reflns_used    30721
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      68.40
_cell_measurement_theta_min      3.16
_cell_volume                     3240.26(12)
_computing_cell_refinement       'RAPID AUTO (Rigaku, 2015)'
_computing_data_collection       'RAPID AUTO (Rigaku, 2015)'
_computing_data_reduction        'RAPID AUTO (Rigaku, 2015)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 2012)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SIR2004 (Spagna, 2004)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54187
_diffrn_reflns_av_R_equivalents  0.0811
_diffrn_reflns_av_unetI/netI     0.0574
_diffrn_reflns_Laue_measured_fraction_full 0.988
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            58098
_diffrn_reflns_point_group_measured_fraction_full 0.988
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_theta_full        67.687
_diffrn_reflns_theta_max         68.252
_diffrn_reflns_theta_min         3.164
_diffrn_source                   'rotating-anode X-ray tube'
_exptl_absorpt_coefficient_mu    33.959
_exptl_absorpt_correction_T_max  0.6831
_exptl_absorpt_correction_T_min  0.3280
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'NUMABS (Rigaku, 2011)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.902
_exptl_crystal_description       rod
_exptl_crystal_F_000             2600
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.050
_refine_diff_density_max         1.653
_refine_diff_density_min         -2.010
_refine_diff_density_rms         0.258
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.165
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     417
_refine_ls_number_reflns         5850
_refine_ls_number_restraints     31
_refine_ls_restrained_S_all      1.176
_refine_ls_R_factor_all          0.0610
_refine_ls_R_factor_gt           0.0439
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0599P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1121
_refine_ls_wR_factor_ref         0.1251
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4467
_reflns_number_total             5850
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt04121k2.cif
_cod_data_source_block           4
_cod_depositor_comments
'Adding full bibliography for 7048256--7048259.cif.'
_cod_database_code               7048259
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.056
_shelx_estimated_absorpt_t_max   0.282
_shelx_res_checksum              12491