Synthesis of silyl aziridines and alpha-amino acylsilanes with silyldibromomethyllithium.
Yagi, Kazunari; Shinokubo, Hiroshi; Oshima, Koichiro; Organic letters 6 (2004) 4339–4341; doi:10.1021/ol048092a

data_1506935
_publ_section_title
;
 Synthesis of silyl aziridines and alpha-amino acylsilanes with
 silyldibromomethyllithium.
;
_journal_issue                   23
_journal_name_full               'Organic letters'
_journal_page_first              4339
_journal_page_last               4341
_journal_paper_doi               10.1021/ol048092a
_journal_volume                  6
_journal_year                    2004
_chemical_formula_moiety         'C26 H31 N Si '
_chemical_formula_sum            'C26 H31 N Si'
_chemical_formula_weight         385.62
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   11.17(1)
_cell_length_b                   16.42(1)
_cell_length_c                   24.14(2)
_cell_measurement_reflns_used    30081
_cell_measurement_temperature    123.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     4428(6)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.6.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9959
_diffrn_measured_fraction_theta_max 0.9959
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.030
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            40818
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.117
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.157
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1664.00
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.50
_exptl_crystal_size_min          0.30
_refine_diff_density_max         4.40
_refine_diff_density_min         -4.09
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.168
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     284
_refine_ls_number_reflns         21704
_refine_ls_R_factor_gt           0.0540
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details
'w = 1/[0.0010Fo^2^ + 3.0000\s(Fo^2^) + 0.5000]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0680
_reflns_number_gt                21704
_reflns_number_total             38586
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ol048092asi20040918_042504.cif
_cod_data_source_block           '_silylaziridine'
_cod_original_cell_volume        4425(6)
_cod_original_formula_sum        'C26 H31 N Si '
_cod_database_code               1506935