Cobalt(II) Coordination Polymer as a Precatalyst for Selective Hydroboration of Aldehydes, Ketones, and Imines.
Wu, Jing; Zeng, Haisu; Cheng, Jessica; Zheng, Shengping; Golen, James A.; Manke, David R.; Zhang, Guoqi; The Journal of organic chemistry 83 (2018) 9442–9448; doi:10.1021/acs.joc.8b01094

data_4035345
_publ_section_title
;
 Cobalt(II) Coordination Polymer as a Precatalyst for Selective
 Hydroboration of Aldehydes, Ketones, and Imines.
;
_journal_issue                   16
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              9442
_journal_page_last               9448
_journal_paper_doi               10.1021/acs.joc.8b01094
_journal_volume                  83
_journal_year                    2018
_chemical_formula_moiety         'C46 H40 Cl2 Co N8'
_chemical_formula_sum            'C46 H40 Cl2 Co N8'
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_exptl_crystal_colour            Orange
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0472P)^2^+4.0671P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0895
_refine_ls_wR_factor_ref         0.0948
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9668
_reflns_number_total             11905
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            jo8b01094_si_002.cif
_cod_data_source_block           JF2547FMI_SQ
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_database_code               4035345
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_shelx_fab_checksum              90268