Mixed ligand Cu(II) complexes as new precursors for the synthesis of CuO nanomaterials: development of homogeneous and heterogeneous catalysts for styrene epoxidation and phenol hydroxylation under mild conditions.
Sharma, Mitu; Sharma, Mukesh; Sultana, Sazida Yasmin; Palaniandavar, Mallayan; Islam, Nashreen S.; Dalton transactions (Cambridge, England : 2003) 54 (2025) 15561–15580; doi:10.1039/d5dt01420d

data_7719498
_publ_section_title
;
 Mixed ligand Cu(II) complexes as new precursors for the synthesis of CuO
 nanomaterials: development of homogeneous and heterogeneous catalysts for
 styrene epoxidation and phenol hydroxylation under mild conditions.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15561
_journal_page_last               15580
_journal_paper_doi               10.1039/d5dt01420d
_journal_volume                  54
_journal_year                    2025
_chemical_formula_sum            'C20 H22 Cu N4 O7'
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_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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_audit_creation_method           SHELXL-2014
_audit_update_record
;
2019-11-18 deposited with the CCDC.	2025-09-16 downloaded from the CCDC.
;
_cell_angle_alpha                101.903(16)
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_cell_volume                     1049(2)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_source                   'fine-focus sealed tube'
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_exptl_absorpt_process_details   SADABS
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_exptl_crystal_description       BLOCK
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_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0826
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0467P)^2^+1.1116P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1232
_refine_ls_wR_factor_ref         0.1414
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2667
_reflns_number_total             3691
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5dt01420d2.cif
_cod_data_source_block           AA
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 

 Adding full bibliography for 7719497--7719498.cif.
;
_cod_database_code               7719498
_shelx_estimated_absorpt_t_min   0.734
_shelx_estimated_absorpt_t_max   0.827
_shelxl_version_number           2014-3
_shelx_res_checksum              23330