Reversible metathesis of ammonia in an acyclic germylene–Ni0 complex
Keil, Philip M.; Szilvási, Tibor; Hadlington, Terrance J.; Chemical Science 12 (2021) 5582–5590; doi:10.1039/D1SC00450F

data_1560848
_publ_section_title
;
 Reversible metathesis of ammonia in an acyclic germylene--Ni0 complex
;
_journal_issue                   15
_journal_name_full               'Chemical Science'
_journal_page_first              5582
_journal_page_last               5590
_journal_paper_doi               10.1039/D1SC00450F
_journal_volume                  12
_journal_year                    2021
_chemical_formula_moiety         'C34 H46 Cl Ge N P Si'
_chemical_formula_sum            'C34 H46 Cl Ge N P Si'
_chemical_formula_weight         635.82
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-01-19 deposited with the CCDC.	2021-03-05 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_diffrn_measurement_device_type  'STOE StadiVari'
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_diffrn_radiation_collimation    '0.6 mm diameter'
_diffrn_radiation_monochromator  'Graded multilayer mirror'
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_source                   'Genix 3D HF Mo'
_diffrn_source_current           1.000
_diffrn_source_power             0.050
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_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'STOE X-AREA 1.76'
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_exptl_crystal_description       block
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_refine_ls_matrix_type           full
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_refine_ls_restrained_S_all      1.010
_refine_ls_R_factor_all          0.1437
_refine_ls_R_factor_gt           0.0570
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0419P)^2^+3.4583P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0974
_refine_ls_wR_factor_ref         0.1237
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_reflns_number_gt                8305
_reflns_number_total             15430
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1sc00450f2.cif
_cod_data_source_block           compound_1b
_cod_depositor_comments
'Adding full bibliography for 1560843--1560857.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1560848
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              82035
_shelx_hkl_checksum              17313