Preparation, structure and analysis of the bonding in the molecular entity (OSO)2Li{[AlF(ORF)3]Li[Al(ORF)4]} (RF = C(CF3)3).
Cameron, T. Stanley; Nikiforov, Grigory B.; Passmore, Jack; Rautiainen, J. Mikko; Dalton transactions (Cambridge, England : 2003) 39 (2010) 2587–2596; doi:10.1039/b923291e

data_7024953
_publ_section_title
;
 Preparation, structure and analysis of the bonding in the molecular
 entity (OSO)2Li{[AlF(ORF)3]Li[Al(ORF)4]} (RF = C(CF3)3).
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2587
_journal_page_last               2596
_journal_paper_doi               10.1039/b923291e
_journal_volume                  39
_journal_year                    2010
_chemical_formula_moiety         'C28 Al2 F64 Li2 O11 S2 '
_chemical_formula_sum            'C28 Al2 F64 Li2 O11 S2'
_chemical_formula_weight         1860.16
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 96.8520(16)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   10.4808(3)
_cell_length_b                   17.0263(3)
_cell_length_c                   31.0222(9)
_cell_measurement_reflns_used    41052
_cell_measurement_temperature    100.1
_cell_measurement_theta_max      72.5
_cell_measurement_theta_min      2.3
_cell_volume                     5496.3(2)
_computing_cell_refinement       PROCESS
_computing_data_collection       PROCESS
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.923
_diffrn_measurement_device_type  'Rigaku RAXIS-UNKNOWN'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.063
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       77
_diffrn_reflns_limit_l_min       -78
_diffrn_reflns_number            125943
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         35.66
_exptl_absorpt_coefficient_mu    0.400
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.248
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3584.00
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.17
_refine_diff_density_max         1.40
_refine_diff_density_min         -0.72
_refine_ls_extinction_coef       129(38)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   0.972
_refine_ls_number_parameters     1037
_refine_ls_number_reflns         11129
_refine_ls_R_factor_gt           0.0524
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details
'w = 1/[0.0010Fo^2^ + 3.0000\s(Fo^2^) + 0.5000]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0702
_reflns_number_gt                11129
_reflns_number_total             15899
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b923291e.txt
_cod_data_source_block           Icec
_cod_original_formula_sum        'C28 Al2 F64 Li2 O11 S2 '
_cod_database_code               7024953