Palladium-Catalyzed Enantioselective Cyclization of Silyloxy-1,6-Enynes
Britton K. Corkey; F. Dean Toste; Journal of the American Chemical Society 129 (2007) 2764–2765; doi:10.1021/ja068723r

data_4109154
_publ_section_title
;
 Palladium-Catalyzed Enantioselective Cyclization of Silyloxy-1,6-Enynes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              2764
_journal_page_last               2765
_journal_paper_doi               10.1021/ja068723r
_journal_volume                  129
_journal_year                    2007
_chemical_formula_moiety         'C16 H21 Br O '
_chemical_formula_sum            'C16 H21 Br O'
_chemical_formula_weight         309.25
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      4
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_audit_creation_date             'Thu Aug 24 11:15:51 2006'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90
_cell_angle_beta                 93.678(6)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.060(4)
_cell_length_b                   7.049(3)
_cell_length_c                   10.340(4)
_cell_measurement_temperature    273.2
_cell_volume                     731.7(5)
_computing_cell_refinement       'Rigaku/AFC Diffractometer Control'
_computing_data_collection       'Rigaku/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    SIR97
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_diffrn_measured_fraction_theta_max 1.5618
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_av_R_equivalents  0.051
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       12
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_diffrn_reflns_theta_full        26.36
_diffrn_reflns_theta_max         26.36
_exptl_absorpt_coefficient_mu    2.804
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            unknown
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_exptl_crystal_description       unknown
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_exptl_crystal_size_mid          0.000
_exptl_crystal_size_min          0.000
_refine_diff_density_max         0.98
_refine_diff_density_min         -0.51
_refine_ls_abs_structure_Flack   0.12(5)
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_R_factor_all          0.1289
_refine_ls_R_factor_gt           0.0667
_refine_ls_shift/su_max          0.9226
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00022|Fo|^2^]'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0829
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_reflns_threshold_expression     F^2^>3.0\s(F^2^)
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_cod_data_source_block           laure
_cod_original_sg_symbol_H-M      'P 21 '
_cod_original_formula_sum        'C16 H21 Br O '
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