Photo-release of acetonitrile in ruthenium(II) complexes with various substituted terpyridine ligands.
Mudrak, Vladyslav; Lacroix, Pascal G.; Labra-Vázquez, Pablo; Tassé, Marine; Mallet-Ladeira, Sonia; Malfant, Isabelle; Dalton transactions (Cambridge, England : 2003) 54 (2025) 9021–9031; doi:10.1039/d5dt00734h

data_7718624
_publ_section_title
;
 Photo-release of acetonitrile in ruthenium(II) complexes with various
 substituted terpyridine ligands.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9021
_journal_page_last               9031
_journal_paper_doi               10.1039/d5dt00734h
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         '2(C29 H27 N4 O3 Ru), 2(F6 P), C4 H10 O'
_chemical_formula_sum            'C62 H64 F12 N8 O7 P2 Ru2'
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_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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;
2025-03-24 deposited with the CCDC.	2025-05-02 downloaded from the CCDC.
;
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.120a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.591
_exptl_crystal_description       plate
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0778P)^2^+1.4293P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1253
_refine_ls_wR_factor_ref         0.1281
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_reflns_number_gt                5675
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           VM-PLV-26plate
_cod_depositor_comments
'Adding full bibliography for 7718624--7718627.cif.'
_cod_database_code               7718624
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              58722
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