[μ-1,2-Bis(diphenylphosphino)methane-κ^2^<i>P</i>:<i>P</i>']bis{[(<i>Z</i>)-<i>O</i>-ethyl <i>N</i>-(4-nitrophenyl)thiocarbamato-κ<i>S</i>]gold(I)}
Ho, Soo Yei; Tiekink, Edward R. T.; Acta Crystallographica Section E 66 (2010) m622–m623; doi:10.1107/S1600536810016326

data_2226134
_publ_section_title
;
 [\m-1,2-Bis(diphenylphosphino)methane-\k^2^<i>P</i>:<i>P</i>']bis{[(<i>Z</i>)-<i>O</i>-ethyl
 <i>N</i>-(4-nitrophenyl)thiocarbamato-\k<i>S</i>]gold(I)}
;
_journal_coeditor_code           HB5435
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m622
_journal_page_last               m623
_journal_paper_doi               10.1107/S1600536810016326
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Au2 (C9 H9 N2 O3 S1)2 (C25 H22 P2)]'
_chemical_formula_moiety         'C43 H40 Au2 N4 O6 P2 S2'
_chemical_formula_sum            'C43 H40 Au2 N4 O6 P2 S2'
_chemical_formula_weight         1228.83
_chemical_name_systematic
;
[\m-1,2-Bis(diphenylphosphino)methane-
\k^2^<i>P</i>:<i>P</i>']bis{[(<i>Z</i>)-<i>O</i>-ethyl
<i>N</i>-(4-nitrophenyl)thiocarbamato-\k<i>S</i>]gold(I)}
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-I 2ya'
_symmetry_space_group_name_H-M   'I 1 2/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 110.252(9)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   24.400(3)
_cell_length_b                   16.1419(16)
_cell_length_c                   24.594(2)
_cell_measurement_reflns_used    5597
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      24.2
_cell_measurement_theta_min      2.5
_cell_volume                     9087.8(17)
_computing_cell_refinement       'SAINT (Bruker, 2000)'
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics
'ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution
'PATTY in DIRDIF92 (Beurskens <i>et al.</i>,  1992)'
_diffrn_ambient_temperature      223(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART CCD'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.053
_diffrn_reflns_av_sigmaI/netI    0.062
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            31967
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         1.5
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.662
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.445
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.796
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4751
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.52
_refine_diff_density_min         -1.19
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.02
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     549
_refine_ls_number_reflns         10427
_refine_ls_number_restraints     28
_refine_ls_restrained_S_all      1.02
_refine_ls_R_factor_all          0.059
_refine_ls_R_factor_gt           0.039
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0567P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.091
_refine_ls_wR_factor_ref         0.110
_reflns_number_gt                7923
_reflns_number_total             10427
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb5435.cif
_cod_data_source_block           I
_cod_original_cell_volume        9087.9(16)
_cod_original_sg_symbol_H-M      'I 2/a'
_cod_database_code               2226134
_cod_database_fobs_code          2226134