Building blocks for the chemistry of perfluorinated alkoxyaluminates [Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>]<sup>-</sup>: simplified preparation and characterization of Li<sup>+</sup>-Cs<sup>+</sup>, Ag<sup>+</sup>, NH<sub>4</sub><sup>+</sup>, N<sub>2</sub>H<sub>5</sub><sup>+</sup> and N<sub>2</sub>H<sub>7</sub><sup>+</sup> salts.
Malinowski, Przemysław J; Jaroń, Tomasz; Domańska, Małgorzata; Slattery, John M.; Schmitt, Manuel; Krossing, Ingo; Dalton transactions (Cambridge, England : 2003) 49 (2020) 7766–7773; doi:10.1039/d0dt00592d

data_7704010
_publ_section_title
;
 Building blocks for the chemistry of perfluorinated alkoxyaluminates
 [Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>]<sup>-</sup>: simplified
 preparation and characterization of Li<sup>+</sup>-Cs<sup>+</sup>,
 Ag<sup>+</sup>, NH<sub>4</sub><sup>+</sup>,
 N<sub>2</sub>H<sub>5</sub><sup>+</sup> and
 N<sub>2</sub>H<sub>7</sub><sup>+</sup> salts.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7766
_journal_page_last               7773
_journal_paper_doi               10.1039/d0dt00592d
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C24 Al1.5 Cs1.5 F54 O6'
_chemical_formula_weight         1650.07
_space_group_crystal_system      triclinic
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_space_group_name_Hall           'P 1'
_space_group_name_H-M_alt        'P 1'
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-03-31 deposited with the CCDC.	2020-04-06 downloaded from the CCDC.
;
_cell_angle_alpha                105.940(2)
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_cell_length_b                   17.4964(18)
_cell_length_c                   18.6544(19)
_cell_measurement_reflns_used    5086
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_computing_molecular_graphics    ShelxLe-1008
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_computing_structure_solution    'SHELXS in SHELXTL Version 2014/3'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.872
_diffrn_measured_fraction_theta_max 0.801
_diffrn_measurement_device_type  'Bruker Smart Apex II Quazar'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0754
_diffrn_reflns_Laue_measured_fraction_full 0.872
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_diffrn_reflns_limit_k_min       -21
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_diffrn_reflns_point_group_measured_fraction_full 0.724
_diffrn_reflns_point_group_measured_fraction_max 0.622
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_diffrn_source                   'INCOATEC Mo Microsource'
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'TWINABS 2012/1, Sheldrick, University of Goettingen, Germany'
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_refine_ls_abs_structure_details
;
 Classical Flack method preferred over Parsons because s.u. lower.
;
_refine_ls_abs_structure_Flack   0.340(8)
_refine_ls_extinction_method     none
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_refine_ls_restrained_S_all      0.777
_refine_ls_R_factor_all          0.0804
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_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0442P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1071
_refine_ls_wR_factor_ref         0.1304
_reflns_Friedel_coverage         0.554
_reflns_Friedel_fraction_full    0.576
_reflns_Friedel_fraction_max     0.444
_reflns_number_gt                14867
_reflns_number_total             23969
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt00592d3.cif
_cod_data_source_block           twin5
_cod_depositor_comments
'Adding full bibliography for 7704008--7704017.cif.'
_cod_original_cell_volume        4472.2(8)
_cod_original_formula_sum        'C24 Al1.50 Cs1.50 F54 O6'
_cod_database_code               7704010
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.750
_shelx_estimated_absorpt_t_max   0.888
_shelx_res_checksum              86221