Crystal structures of two platinum(II) complexes containing ethyl eugenoxyacetate and 2-aminopyridine
Le Thi Hong, Hai; Nguyen Thu, Thao; Nguyen, Hien; Van Meervelt, Luc; Acta Crystallographica Section E 73 (2017) 573–578; doi:10.1107/S2056989017004285

data_2242098
_publ_section_title
;
 Crystal structures of two platinum(II) complexes containing ethyl
 eugenoxyacetate and 2-aminopyridine
;
_journal_coeditor_code           RZ5208
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              573
_journal_page_last               578
_journal_paper_doi               10.1107/S2056989017004285
_journal_volume                  73
_journal_year                    2017
_chemical_formula_iupac          '[Pt (C14 H17 O4) Cl (C5 H6 N2)]'
_chemical_formula_moiety         'C19 H23 Cl N2 O4 Pt'
_chemical_formula_sum            'C19 H23 Cl N2 O4 Pt'
_chemical_formula_weight         573.93
_chemical_name_systematic
(2-Aminopyridine-\k<i>N</i>)chlorido{5-ethoxycarbonylmethoxy-4-methoxy-1-[(2,3-\h)-prop-2-en-1-yl]phenyl-\k<i>C</i>^1^}platinum(II)
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
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;
Olex2 1.2
(compiled 2015.09.30 svn.r3233 for OlexSys, GUI svn.r5103)
;
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_cell_length_b                   10.0855(2)
_cell_length_c                   14.1855(4)
_cell_measurement_reflns_used    14326
_cell_measurement_temperature    100.01(10)
_cell_measurement_theta_max      29.1110
_cell_measurement_theta_min      3.2230
_cell_volume                     1921.72(12)
_computing_cell_refinement
;
CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
;
_computing_data_collection
;
CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
;
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CrysAlis PRO (Rigaku Oxford Diffraction, 2015)
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OLEX2 (Dolomanov <i>et al.</i>,  2009)
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OLEX2 (Dolomanov <i>et al.</i>,  2009)
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_computing_structure_refinement
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SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_solution
;
SUPERFLIP (Palatinus & Chapuis, 2007)
;
_diffrn_ambient_temperature      100.01(10)
_diffrn_detector_area_resol_mean 15.9631
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type
'Agilent SuperNova diffractometer (single source at offset, Eos detector)'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0334
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
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_diffrn_reflns_theta_full        25.214
_diffrn_reflns_theta_max         26.342
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;
(CrysAlis PRO; Rigaku Oxford Diffraction, 2015)
;
_exptl_crystal_colour            white
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_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.2
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_refine_diff_density_min         -1.035
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_refine_ls_number_reflns         3928
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0178
_refine_ls_R_factor_gt           0.0162
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0159P)^2^+1.3858P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           II
_cod_original_cell_volume        1921.72(11)
_cod_database_code               2242098
_cod_database_fobs_code 2242098