Asymmetric Reduction of Imines with Trichlorosilane, Catalyzed by Sigamide, an Amino Acid-Derived Formamide: Scope and Limitations
Andrei V. Malkov; Kvetoslava Vranková; Sigitas Stončius; Pavel Kočovský; Journal of Organic Chemistry 74 (2009) 5839–5849; doi:10.1021/jo900561h

data_4024739
_publ_section_title
;
Asymmetric Reduction of Imines with Trichlorosilane, Catalyzed by Sigamide,
an Amino Acid-Derived Formamide: Scope and Limitations
;
_journal_name_full               'Journal of Organic Chemistry'
_journal_page_first              5839
_journal_page_last               5849
_journal_paper_doi               10.1021/jo900561h
_journal_volume                  74
_journal_year                    2009
_chemical_formula_moiety         'C16 H24 N2 O2'
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_cell_measurement_theta_min      3
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_computing_cell_refinement       'Bruker Saint'
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_diffrn_ambient_temperature      100
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_diffrn_standards_interval_time  0
_diffrn_standards_number         0
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_exptl_absorpt_process_details   'SADABS (Siemens, 1996)'
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_exptl_crystal_density_diffrn    1.151
_exptl_crystal_description       block
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(F^2^) + 0.06 + 0.00P] 
where P=(max(Fo^2^,0) + 2Fc^2^)/3 
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1135
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_reflns_limit_h_max              19
_reflns_limit_h_min              -19
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_reflns_limit_k_min              0
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_reflns_threshold_expression     I>2.00u(I)
_oxford_diffrn_Wilson_B_factor   1.32
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_oxford_refine_ls_scale          0.6103(10)
_oxford_structure_analysis_title 'sx001 in P2(1)/c'
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_cod_data_source_block           CRYSTALS_cif
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 1 21/c 1 '
_cod_database_code               4024739