Systematic reductive oligomerization of isocyanides with a vanadium(ii) complex.
Hasegawa, Sui; Ishida, Yutaka; Kawaguchi, Hiroyuki; Chemical communications (Cambridge, England) 57 (2021) 8296–8299; doi:10.1039/d1cc03463d

data_7128701
_publ_section_title
;
 Systematic reductive oligomerization of isocyanides with a vanadium(ii)
 complex.
;
_journal_issue                   67
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              8296
_journal_page_last               8299
_journal_paper_doi               10.1039/d1cc03463d
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C108 H138 K2 N4 O8 V2, 3.5(C7 H8)'
_chemical_formula_sum            'C132.5 H166 K2 N4 O8 V2'
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Olex2 1.3
(compiled Nov 21 2019 18:26:39 for OlexSys, GUI svn.r6003)
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2021-04-06 deposited with the CCDC.	2021-07-21 downloaded from the CCDC.
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List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  t~exp~   \w     \q     \k     \f   Frames
  1  \w   -120.00  60.00   0.50    2.00    --  -30.00  45.00   0.00  360
  2  \w   -120.00  60.00   0.50    2.00    --  -30.00  45.00  90.00  360
  3  \w   -120.00  60.00   0.50    2.00    --  -30.00  45.00 180.00  360
;
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'CrysAlisPro convention (1999,Acta A55,543-557)'
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_diffrn_source                   'rotating anode X-ray generator'
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;
CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'yellowish green'
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The unit cell contains twelve molecules which have been 
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without specific atom positions by SQEEZE/PLATON.
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'w=1/[\s^2^(Fo^2^)+(0.0663P)^2^+26.1810P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7128700--7128707.cif.'
_cod_original_cell_volume        23797.8(8)
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