Triphenylamine–boron complexes: molecular thermometry and alkyl chain controlled molecular fluorescent liquids
Gayathri, Parthasarathy; Ravi, Sasikala; Karthikeyan, Subramanian; Mohitkar, Anuradha; Jayanty, Subbalakshmi; Pannipara, Mehboobali; Al-Sehemi, Abdullah G.; Moon, Dohyun; Anthony, Savarimuthu Philip; New Journal of Chemistry 47 (2023) 7288–7298; doi:10.1039/D2NJ04474A

data_7062358
_publ_section_title
;
 Triphenylamine--boron complexes: molecular thermometry and alkyl chain
 controlled molecular fluorescent liquids
;
_journal_issue                   15
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              7288
_journal_page_last               7298
_journal_paper_doi               10.1039/D2NJ04474A
_journal_volume                  47
_journal_year                    2023
_chemical_formula_moiety         'C23 H23 B F2 N2 O'
_chemical_formula_sum            'C23 H23 B F2 N2 O'
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2022-08-03 deposited with the CCDC.	2023-03-07 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_cell_length_c                   24.294(5)
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_cell_measurement_temperature    220(2)
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_computing_cell_refinement       '<i>HKL3000sm</i>(Otwinowski & Minor, 1997)'
_computing_data_collection
'<i>PAL BL2D-SMDC Program</i>(Shin et.al, 2016)'
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_computing_molecular_graphics    '<i>DIAMOND 4</i>(Putx&Brandenburg, 2014)'
_computing_publication_material  '<i>publCIF</i>(Westrip, 2010)'
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_computing_structure_solution    '<i>SHELXT-2018</i>(Sheldrick, 2018)'
_diffrn_ambient_temperature      220(2)
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_diffrn_measured_fraction_theta_max 0.947
_diffrn_measurement_device_type  'Rayonix MX225HS CCD area detector'
_diffrn_measurement_method       'omega scan'
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'<i>HKL3000sm Scalepack</i>(Otwinowski et.al,2003)'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1517P)^2^+0.4653P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                3793
_reflns_number_total             5336
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d2nj04474a2.cif
_cod_data_source_block           SPA508
_cod_depositor_comments          'Adding full bibliography for 7062358.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7062358
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_shelx_estimated_absorpt_t_min   0.995
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_shelx_res_checksum              19251