An Azobenzenyl Anion Radical Complex of Magnesium: Synthesis, Structure, and Reactivity Studies.
Ren, Wenshan; Gu, Defa; Inorganic chemistry 55 (2016) 11962–11970; doi:10.1021/acs.inorgchem.6b02114

data_4349220
_publ_section_title
;
 An Azobenzenyl Anion Radical Complex of Magnesium: Synthesis, Structure,
 and Reactivity Studies.
;
_journal_issue                   22
_journal_name_full               'Inorganic chemistry'
_journal_page_first              11962
_journal_page_last               11970
_journal_paper_doi               10.1021/acs.inorgchem.6b02114
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         'C66 H100 Mg2 N8 Si2'
_chemical_formula_sum            'C66 H100 Mg2 N8 Si2'
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Olex2 1.2
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
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;
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
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  1 omega  -31.00   53.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
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  5 omega   10.00  104.00   1.0000    1.0000
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  6 omega  -31.00   53.00   1.0000    1.0000
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  7 omega   57.00  109.00   1.0000    1.0000
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  8 omega    1.00   76.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
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  9 omega   38.00   91.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
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 10 omega   40.00   98.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -45.0000   30.0000 58

 11 omega   91.00  176.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
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 12 omega   40.00   98.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -45.0000   90.0000 58

 13 omega   40.00   98.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
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 14 omega   38.00   91.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
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 15 omega   40.00   98.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000  -45.0000 -180.0000 58

 16 omega   38.00  116.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000 -112.0000 -180.0000 78

 17 omega   70.00  178.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
    -      108.0000   15.0000  150.0000 108

 18 omega    1.00   27.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.7203   93.0000   13.2294 26

 19 omega   20.00  104.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.7203   57.0000  -30.0000 84

 20 omega   20.00  104.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.7203   57.0000   60.0000 84

 21 omega   20.00  104.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.7203   57.0000  150.0000 84

 22 omega  -32.00   56.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.7203  -38.0000   90.0000 88

 23 omega  -31.00   53.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.7203  -57.0000 -180.0000 84

 24 omega   10.00  104.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.7203   77.0000   60.0000 94

 25 omega    2.00   29.00   1.0000    1.0000
omega____ theta____ kappa____ phi______ frames
    -       36.7203   91.0000  137.7788 27

 26 omega   70.00  119.00   1.0000    5.0000
omega____ theta____ kappa____ phi______ frames
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
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Empirical absorption correction using spherical harmonics,
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;
1. Fixed Uiso
 At 1.2 times of:
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 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C8(H8), C11(H11), C25(H25), C28(H28)
2.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C16(H16), C20(H20), C21(H21), C22(H22)
2.c Idealised Me refined as rotating group:
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_olex2_submission_special_instructions 'No special instructions were received'