Pd-Catalyzed Dehydrogenative Aryl-Aryl Bond Formation via Double C(sp(2))-H Bond Activation: Efficient Synthesis of [3,4]-Fused Oxindoles.
Bunescu, Ala; Piou, Tiffany; Wang, Qian; Zhu, Jieping; Organic letters 17 (2015) 334–337; doi:10.1021/ol503442n

data_1518614
_publ_section_title
;
 Pd-Catalyzed Dehydrogenative Aryl-Aryl Bond Formation via Double
 C(sp(2))-H Bond Activation: Efficient Synthesis of [3,4]-Fused Oxindoles.
;
_journal_issue                   2
_journal_name_full               'Organic letters'
_journal_page_first              334
_journal_page_last               337
_journal_paper_doi               10.1021/ol503442n
_journal_volume                  17
_journal_year                    2015
_chemical_formula_moiety         'C22 H16 F N O'
_chemical_formula_sum            'C22 H16 F N O'
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2014-08-11 # Formatted by publCIF

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CrysAlisPro, Agilent Technologies, 
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET) 
(compiled Feb  1 2013,16:14:44) 
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CrysAlisPro, Agilent Technologies, 
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET) 
(compiled Feb  1 2013,16:14:44) 
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CrysAlisPro, Agilent Technologies, 
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET) 
(compiled Feb  1 2013,16:14:44) 
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_computing_molecular_graphics    'Bruker SHELXTL'
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CrysAlisPro, Agilent Technologies, 
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET) 
(compiled Feb  1 2013,16:14:44) 
Analytical numeric absorption correction using a multifaceted crystal 
model based on expressions derived by R.C. Clark & J.S. Reid. 
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897) 
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_exptl_crystal_colour            'clear light colourless'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.095
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_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0432
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0507P)^2^+0.6862P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2sigma(I)
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_cod_original_cell_volume        1596.05(14)
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