A Homoleptic Uranium(III) Tris(aryl) Complex.
Boreen, Michael A.; Parker, Bernard F.; Lohrey, Trevor D.; Arnold, John; Journal of the American Chemical Society 138 (2016) 15865–15868; doi:10.1021/jacs.6b11182

data_4125322
_publ_section_title
;
 A Homoleptic Uranium(III) Tris(aryl) Complex.
;
_journal_issue                   49
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              15865
_journal_page_last               15868
_journal_paper_doi               10.1021/jacs.6b11182
_journal_volume                  138
_journal_year                    2016
_chemical_formula_moiety         'C78 H87 U'
_chemical_formula_sum            'C87 H108 U'
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_chemical_name_systematic
'Tris[2,6-bis(4-tert-butylphenyl)phenyl] uranium(III) '
_chemical_properties_physical
', Air-sensitive,Moisture-sensitive,Heat-sensitive,Oxygen-sensitive'
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
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_symmetry_space_group_name_Hall  '-C 2yc'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_exptl_absorpt_correction_type   multi-scan
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'Re-crystallisation from solvent: n-hexane/HMDSO'
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_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0375
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0256P)^2^+58.9857P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 4125321--4125322.cif.'
_cod_original_cell_volume        14601.9(10)
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