Four-coordinate triarylborane synthesis <i>via</i> cascade B-Cl/C-B cross-metathesis and C-H bond borylation.
Yang, Kai; Zhang, Guan; Song, Qiuling; Chemical science 9 (2018) 7666–7672; doi:10.1039/c8sc02281j

data_1549783
_publ_section_title
;
 Four-coordinate triarylborane synthesis <i>via</i> cascade B-Cl/C-B
 cross-metathesis and C-H bond borylation.
;
_journal_issue                   39
_journal_name_full               'Chemical science'
_journal_page_first              7666
_journal_page_last               7672
_journal_paper_doi               10.1039/c8sc02281j
_journal_volume                  9
_journal_year                    2018
_chemical_formula_moiety         'C17 H14 B F N2'
_chemical_formula_sum            'C17 H14 B F N2'
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Olex2 1.2
(compiled 2014.03.20 svn.r2914 for OlexSys, GUI svn.r4816)
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2018-01-17 deposited with the CCDC.
2018-08-13 downloaded from the CCDC.
;
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'CrysAlisPro convention (1999,Acta A55,543-557)'
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;
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
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'w=1/[\s^2^(Fo^2^)+(0.0449P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 1549782--1549783.cif.'
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;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 N3(H3), C7(H7), C8(H8), C10(H10), C11(H11), C12(H12), C13(H13), C15(H15),
 C16(H16), C17(H17), C18(H18), C19(H19), C20(H20), C21(H21)
;
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Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
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