Stepwise synthesis, characterization, DNA binding properties and cytotoxicity of diruthenium oligopyridine compounds conjugated with peptides.
Ypsilantis, Konstantinos; Plakatouras, John C.; Manos, Manolis J.; Kourtellaris, Andreas; Markopoulos, Georgios; Kolettas, Evangelos; Garoufis, Achilleas; Dalton transactions (Cambridge, England : 2003) 47 (2018) 3549–3567; doi:10.1039/c7dt04639a

data_7045430
_publ_section_title
;
 Stepwise synthesis, characterization, DNA binding properties and
 cytotoxicity of diruthenium oligopyridine compounds conjugated with
 peptides.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3549
_journal_page_last               3567
_journal_paper_doi               10.1039/c7dt04639a
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C61 H41 F24 N12 O2 P4 Ru2'
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2017-12-04 deposited with the CCDC.
2018-01-29 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_source                   'SuperNova (Mo) X-ray Source'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.626
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_refine_ls_R_factor_all          0.0762
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_refine_ls_shift/su_max          2.271
_refine_ls_shift/su_mean         0.026
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0674P)^2^+22.7774P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                6309
_reflns_number_total             8542
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7dt04639a2.cif
_cod_data_source_block           ru2g_sq
_cod_depositor_comments
'Adding full bibliography for 7045428--7045430.cif.'
_cod_original_cell_volume        7172.6(13)
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