Synthesis of a μ,η2-Disulfide-Bridged Hexanuclear RuII-Na Cluster Formed from the Reductive Coupling of a μ,η1-Disulfide-Bridged Dinuclear RuIII Complex
Kazuko Matsumoto; Yoichi Sano; Inorganic Chemistry 36 (1997) 4405–4407; doi:10.1021/ic961015u

data_4323580
_publ_section_title
;
 Synthesis of a \m,\h2-Disulfide-Bridged Hexanuclear RuII-Na Cluster
 Formed from the Reductive Coupling of a \m,\h1-Disulfide-Bridged
 Dinuclear RuIII Complex
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4405
_journal_page_last               4407
_journal_paper_doi               10.1021/ic961015u
_journal_volume                  36
_journal_year                    1997
_chemical_formula_sum            'C28 H80 Cl6 Na2 O25 P8 Ru4 S4'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Tue May 13 13:26:24 1997'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                93.81(3)
_cell_angle_beta                 94.73(2)
_cell_angle_gamma                69.24(2)
_cell_formula_units_Z            2
_cell_length_a                   14.927(3)
_cell_length_b                   21.063(7)
_cell_length_c                   11.802(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    21.0
_cell_measurement_theta_max      25.01
_cell_measurement_theta_min      20.17
_cell_volume                     3455.1(18)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_computing_structure_solution    SHELXS86
_diffrn_ambient_temperature      21.0
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
_diffrn_orient_matrix_UB_11      -0.00110
_diffrn_orient_matrix_UB_12      -0.04667
_diffrn_orient_matrix_UB_13      0.00817
_diffrn_orient_matrix_UB_21      0.04363
_diffrn_orient_matrix_UB_22      -0.01743
_diffrn_orient_matrix_UB_23      -0.06377
_diffrn_orient_matrix_UB_31      0.05700
_diffrn_orient_matrix_UB_32      -0.01001
_diffrn_orient_matrix_UB_33      0.05574
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  6.13
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_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu_cm 14.730
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_correction_T_min  0.868
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            orange
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_refine_ls_R_factor_obs          0.0620
_refine_ls_shift/esd_max         0.1210
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
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_cod_data_source_file            ic961015u.cif
_cod_data_source_block           C28H80O25Ru4Cl6S4Na2P8
_cod_original_cell_volume        3455(1)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C28 H80 O25 Ru4 Cl6 S4 Na2 P8'
_cod_database_code               4323580