Interaction of dicoordinate phosphorus with boranes: chemistry of 3a,6a-diaza-1,4-diphosphapentalene as masked phosphinidene.
Panova, Yulia; Khristolyubova, Alexandra; Zolotareva, Natalia; Sushev, Vyacheslav; Galperin, Vadim; Rumyantcev, Roman; Fukin, Georgy; Kornev, Alexander; Dalton transactions (Cambridge, England : 2003) 50 (2021) 5890–5898; doi:10.1039/d1dt00747e

data_7707080
_publ_section_title
;
 Interaction of dicoordinate phosphorus with boranes: chemistry of
 3a,6a-diaza-1,4-diphosphapentalene as masked phosphinidene.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5890
_journal_page_last               5898
_journal_paper_doi               10.1039/d1dt00747e
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C30.5 H19 B Cl F15 N2 O P2'
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_space_group_name_Hall           '-P 1'
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_audit_update_record
;
2020-06-29 deposited with the CCDC.	2021-04-08 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker D8 Quest CMOS'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
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_refine_ls_R_factor_all          0.0650
_refine_ls_R_factor_gt           0.0467
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0242P)^2^+1.7200P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                6092
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1dt00747e2.cif
_cod_data_source_block           pnnpbphfm_a
_cod_depositor_comments
'Adding full bibliography for 7707078--7707081.cif.'
_cod_original_formula_sum        'C30.50 H19 B Cl F15 N2 O P2'
_cod_database_code               7707080
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