Amidinatogermylene Metal Complexes as Homogeneous Catalysts in Alcoholic Media
Álvarez-Rodríguez, Lucía; Cabeza, Javier A.; Fernández-Colinas, José M.; García-Álvarez, Pablo; Polo, Diego; Organometallics 35 (2016) 2516–; doi:10.1021/acs.organomet.6b00426

data_4086677
_publ_section_title
;
 Amidinatogermylene Metal Complexes as Homogeneous Catalysts in Alcoholic
 Media
;
_journal_issue                   15
_journal_name_full               Organometallics
_journal_page_first              2516
_journal_paper_doi               10.1021/acs.organomet.6b00426
_journal_volume                  35
_journal_year                    2016
_chemical_formula_moiety         'C27 H44 Cl Ge N2 Rh'
_chemical_formula_sum            'C27 H44 Cl Ge N2 Rh'
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_chemical_name_systematic
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 ?
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_atom_sites_solution_hydrogens   geom
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
(compiled May 22 2014,16:03:01)
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_computing_molecular_graphics    'X-SEED (Barbour, 1999)'
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_diffrn_measurement_device_type  'Xcalibur, Ruby, Gemini'
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_diffrn_reflns_av_unetI/netI     0.0395
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_diffrn_reflns_theta_full        90.000
_diffrn_reflns_theta_max         31.502
_diffrn_reflns_theta_min         3.317
_diffrn_source                   'Enhance (Mo) X-ray Source'
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.34 (release 22-05-2014 CrysAlis171 .NET)
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Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.466
_exptl_crystal_description       fragment
_exptl_crystal_F_000             1256
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_exptl_crystal_size_mid          0.1325
_exptl_crystal_size_min          0.1044
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_refine_ls_number_restraints     0
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0189P)^2^+1.7253P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0577
_refine_ls_wR_factor_ref         0.0626
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7168
_reflns_number_total             8550
_reflns_threshold_expression     'I > 2\s(I)'
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_shelxl_version_number           2014-3
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