Metal thiophosphonates and related compounds: an emerging area of supramolecular coordination chemistry.
Shi, Weifeng; Shafaei-Fallah, Maryam; Anson, Christopher E.; Rothenberger, Alexander; Dalton transactions (Cambridge, England : 2003)  (2006) 3257–3262; doi:10.1039/b603764j

data_7007334
_publ_section_title
;
 Metal thiophosphonates and related compounds: an emerging area of
 supramolecular coordination chemistry.
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3257
_journal_page_last               3262
_journal_paper_doi               10.1039/b603764j
_journal_year                    2006
_chemical_formula_sum            'C80 H78 Cu4 O2 P6 S6'
_chemical_formula_weight         1703.76
_chemical_name_systematic
;
?
;
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_atom_sites_solution_secondary   difmap
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_cell_angle_beta                 101.470(7)
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_cell_length_b                   13.4796(12)
_cell_length_c                   13.6857(12)
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_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28
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_computing_cell_refinement       'stoe winexpose'
_computing_data_collection       'stoe winexpose'
_computing_data_reduction        'stoe winexpose'
_computing_molecular_graphics    'SHELXL-97 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
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_diffrn_measured_fraction_theta_full 0.940
_diffrn_measured_fraction_theta_max 0.921
_diffrn_measurement_device_type  'stoe ipds 2'
_diffrn_measurement_method       'area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_limit_h_max       14
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_diffrn_reflns_limit_l_min       -18
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_diffrn_reflns_theta_min         1.59
_exptl_absorpt_coefficient_mu    1.421
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_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.467
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         8709
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_refine_ls_R_factor_all          0.0806
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0596P)^2^+1.1404P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1197
_refine_ls_wR_factor_ref         0.1323
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_cod_data_source_file            b603764j.txt
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_cod_database_code               7007334