Monofunctional platinum(ii) anticancer complexes based on multidentate phenanthridine-containing ligand frameworks.
Lozada, Issiah B.; Huang, Bin; Stilgenbauer, Morgan; Beach, Travis; Qiu, Zihan; Zheng, Yaorong; Herbert, David E.; Dalton transactions (Cambridge, England : 2003) 49 (2020) 6557–6560; doi:10.1039/d0dt01275k

data_7704129
_publ_section_title
;
 Monofunctional platinum(ii) anticancer complexes based on multidentate
 phenanthridine-containing ligand frameworks.
;
_journal_issue                   20
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6557
_journal_page_last               6560
_journal_paper_doi               10.1039/d0dt01275k
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C23 H24 Cl4 N2 O Pt'
_chemical_formula_weight         681.33
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2019-10-16 deposited with the CCDC.	2020-04-15 downloaded from the CCDC.
;
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_cell_measurement_reflns_used    9886
_cell_measurement_temperature    150(2)
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_cell_volume                     2365.24(15)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX3'
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      150(2)
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 QUEST ECO CMOS'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_T_min  0.5807
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2014/5 (Bruker AXS Inc.)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.913
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_refine_ls_restrained_S_all      1.075
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0268P)^2^+5.2752P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0632
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_reflns_number_total             5419
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt01275k2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7704128--7704129.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7704129
_shelx_shelxl_version_number     2016/6
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_shelx_res_checksum              40017