Asymmetric total synthesis and stereochemical elucidation of the antitumor agent PM-94128.
Patel, Samir K.; Murat, Karine; Py, Sandrine; Vallée, Yannick; Organic letters 5 (2003) 4081–4084; doi:10.1021/ol035470n

data_1507374
_publ_section_title
;
 Asymmetric total synthesis and stereochemical elucidation of the
 antitumor agent PM-94128.
;
_journal_issue                   22
_journal_name_full               'Organic letters'
_journal_page_first              4081
_journal_page_last               4084
_journal_paper_doi               10.1021/ol035470n
_journal_volume                  5
_journal_year                    2003
_chemical_formula_moiety         'C23 H N O7 '
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_computing_publication_material  'teXsan (MSC, 1992-1997)'
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_refine_ls_extinction_expression 'equ(3) Acta Cryst.(1968) A24, p213.'
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00076|Fo|^2^]'
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_reflns_threshold_expression     I>2.00\s(I)
_cod_data_source_file            ol035470nsi20030902_092010.cif
_cod_data_source_block           GR3
_cod_depositor_comments
;
 Changing the values of _atom_site_label and _atom_site_aniso_label
 data items to match the ones in related data items
 (e. g. _geom_angle_atom_site_label_*).

 Antanas Vaitkus,
 2017-01-06

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        1186.7(9)
_cod_original_sg_symbol_H-M      'P 21       '
_cod_original_formula_sum        'C23 H N O7 '
_cod_database_code               1507374