(5-Methylpyrazine-2-carboxylato-κ^2^<i>N</i>^1^,<i>O</i>)bis[2-(4-methylpyridin-2-yl-κ<i>N</i>)-3,5-bis(trifluoromethyl)phenyl-κ<i>C</i>^1^]iridium(III) chloroform hemisolvate
Kim, Young-Inn; Song, Young-Kwang; Kang, Sung Kwon; Acta Crystallographica Section E 70 (2014) m34–; doi:10.1107/S1600536813034727

data_2239026
_publ_section_title
;
 (5-Methylpyrazine-2-carboxylato-\k^2^<i>N</i>^1^,<i>O</i>)bis[2-(4-methylpyridin-2-yl-\k<i>N</i>)-3,5-bis(trifluoromethyl)phenyl-\k<i>C</i>^1^]iridium(III)
 chloroform hemisolvate
;
_journal_coeditor_code           TK5282
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m34
_journal_paper_doi               10.1107/S1600536813034727
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac
'[Ir (C14 H8 F6 N)2 (C6 H5 N2 O2)], 0.5C H Cl3'
_chemical_formula_moiety         'C34 H21 F12 Ir N4 O2, 0.5(C H Cl3)'
_chemical_formula_sum            'C34.5 H21.5 Cl1.5 F12 Ir N4 O2'
_chemical_formula_weight         997.43
_chemical_name_systematic
'(5-Methylpyrazine-2-carboxylato-\k^2^<i>N</i>^1^,<i>O</i>)bis[2-(4-methylpyridin-2-yl-\k<i>N</i>)-3,5-bis(trifluoromethyl)phenyl-\k<i>C</i>^1^]iridium(III) chloroform hemisolvate'
_space_group_IT_number           2
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_R_factor_gt           0.025
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0400P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     I>2\s(I)
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