Interaction of hydroperoxopalladium complexes, (TpR)(py)Pd?OOH, with hydroxo-nickel and -cobalt complexes, [(�-OH)(MTpR?)]2 (M = Ni, Co), leading to oxidative dehydrogenation of the saturated hydrocarbyl moiety in the ancillary ligand (TpiPr2)Electronic supplementary information (ESI) available: Fig. 4: 1H NMR monitoring of the reaction of 2iPr2 and 4iPr2(Ni) at ?20 �C. See http://www.rsc.org/suppdata/dt/b3/b307262m/
Kujime, Masato; Hikichi, Shiro; Akita, Munetaka; Dalton Transactions  (2003) 3506–; doi:10.1039/b307262m

data_7013378
_publ_section_title
;
 Interaction of hydroperoxopalladium complexes, (TpR)(py)Pd?OOH, with
 hydroxo-nickel and -cobalt complexes, [(&#xFFFD;-OH)(MTpR?)]2 (M = Ni,
 Co), leading to oxidative dehydrogenation of the saturated hydrocarbyl
 moiety in the ancillary ligand (TpiPr2)Electronic supplementary
 information (ESI) available: Fig. 4: 1H NMR monitoring of the reaction
 of 2iPr2 and 4iPr2(Ni) at ?20 &#xFFFD;C. See
 http://www.rsc.org/suppdata/dt/b3/b307262m/
;
_journal_issue                   18
_journal_name_full               'Dalton Transactions'
_journal_page_first              3506
_journal_paper_doi               10.1039/b307262m
_journal_year                    2003
_chemical_formula_moiety         'C50 H80 B2 N16 O2 Ni Pd '
_chemical_formula_sum            'C50 H80 B2 N16 Ni O2 Pd'
_chemical_formula_weight         1124.01
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Thu Jul 17 20:22:46 2003'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                101.662(4)
_cell_angle_beta                 112.767(3)
_cell_angle_gamma                89.006(5)
_cell_formula_units_Z            2
_cell_length_a                   13.254(1)
_cell_length_b                   21.125(2)
_cell_length_c                   12.1299(8)
_cell_measurement_reflns_used    9023
_cell_measurement_temperature    213.2
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      1.7
_cell_volume                     3060.0(4)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  SHELXL97
_computing_structure_solution    DirectMethod
_diffrn_detector_area_resol_mean 10.00
_diffrn_measurement_device_type  'Rigaku RAXIS-IV Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.000
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            22208
_diffrn_reflns_theta_max         27.49
_exptl_absorpt_coefficient_mu    0.650
_exptl_absorpt_correction_T_max  0.937
_exptl_absorpt_correction_T_min  0.780
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            unknown
_exptl_crystal_density_diffrn    1.220
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       unknown
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.60
_refine_diff_density_min         -2.00
_refine_ls_extinction_coef       0.0000
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.217
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     657
_refine_ls_number_reflns         8286
_refine_ls_R_factor_gt           0.0786
_refine_ls_shift/su_max          0.0010
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2083
_reflns_number_gt                8286
_reflns_number_total             12561
_reflns_threshold_expression     >2.0sigma(I)
_cod_data_source_file            b307262m.txt
_cod_data_source_block           compound_5b(Ni)
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C50 H80 B2 N16 O2 Ni Pd '
_cod_database_code               7013378