Photoswitchable organoplatinum complexes with an azobenzene derivative of di-2-pyridylamine
Moustafa, Mohamed E.; Boyle, Paul D.; Puddephatt, Richard J.; New Journal of Chemistry 44 (2020) 2882–2889; doi:10.1039/C9NJ05313A

data_7059270
_publ_section_title
;
 Photoswitchable organoplatinum complexes with an azobenzene derivative of
 di-2-pyridylamine
;
_journal_issue                   7
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              2882
_journal_page_last               2889
_journal_paper_doi               10.1039/C9NJ05313A
_journal_volume                  44
_journal_year                    2020
_chemical_formula_sum            'C32.5 H33 Br N5 O0.5 Pt'
_chemical_formula_weight         776.64
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_block_doi                 10.5517/ccdc.csd.cc23clcg
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2019-08-16 deposited with the CCDC.	2020-01-31 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.086(4)
_cell_length_b                   10.722(4)
_cell_length_c                   25.681(10)
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_cell_volume                     2995(2)
_computing_cell_refinement       SAINT
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_computing_data_reduction        SAINT
_computing_molecular_graphics    NRCVAX
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_computing_structure_solution    SHELXT
_diffrn_ambient_temperature      110
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.943
_diffrn_measurement_device_type  'Bruker Kappa Axis Apex2'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0550
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_diffrn_reflns_limit_h_max       18
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_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       42
_diffrn_reflns_limit_l_min       -43
_diffrn_reflns_number            99130
_diffrn_reflns_point_group_measured_fraction_full 0.997
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_diffrn_reflns_theta_max         37.753
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_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    6.050
_exptl_absorpt_correction_T_max  0.7474
_exptl_absorpt_correction_T_min  0.5316
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.722
_exptl_crystal_description       prism
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_refine_ls_shift/su_max          0.002
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0375P)^2^+4.1243P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0823
_refine_ls_wR_factor_ref         0.0946
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9922
_reflns_number_total             15135
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9nj05313a1.cif
_cod_data_source_block           5
_cod_depositor_comments
;Adding full bibliography for 7059267--7059270.cif.

 Adding full bibliography for 7059267--7059270.cif.
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C32.50 H33 Br N5 O0.50 Pt'
_cod_database_code               7059270
_shelx_estimated_absorpt_t_min   0.242
_shelx_estimated_absorpt_t_max   0.621
_shelxl_version_number           2014-3
_shelx_res_checksum              23675