Two pure MOF-photocatalysts readily prepared for the degradation of methylene blue dye under visible light.
Zhang, Ming; Wang, Liwen; Zeng, Tianyu; Shang, Qigao; Zhou, Hong; Pan, Zhiquan; Cheng, Qingrong; Dalton transactions (Cambridge, England : 2003) 47 (2018) 4251–4258; doi:10.1039/c8dt00156a

data_7045532
_publ_section_title
;
 Two pure MOF-photocatalysts readily prepared for the degradation of
 methylene blue dye under visible light.
;
_journal_issue                   12
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4251
_journal_page_last               4258
_journal_paper_doi               10.1039/c8dt00156a
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C12 H10 Cl0 Co N2 O4'
_chemical_formula_weight         305.15
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_space_group_name_Hall           'P 4nw 2abw'
_space_group_name_H-M_alt        'P 43 21 2'
_symmetry_space_group_name_Hall  'P 4nw 2abw'
_symmetry_space_group_name_H-M   'P 43 21 2'
_atom_sites_solution_hydrogens   geom
_audit_block_doi                 10.5517/ccdc.csd.cc1ps0t9
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-12-06 deposited with the CCDC.
2018-02-05 downloaded from the CCDC.
;
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_cell_measurement_theta_min      2.81
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_computing_cell_refinement       'Bruker SMART'
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_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
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_diffrn_ambient_temperature      173(2)
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_diffrn_measurement_device_type  'PHOTON 100 CMOS detector'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0520
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_diffrn_reflns_theta_max         26.318
_diffrn_reflns_theta_min         2.809
_diffrn_source                   'fine-focus sealed tube'
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.02(4)
_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         1117
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_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.0501
_refine_ls_R_factor_gt           0.0354
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0312P)^2^+0.0775P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0674
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_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                951
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt00156a2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7045532--7045533.cif.'
_cod_original_cell_volume        1106.35(15)
_cod_database_code               7045532
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_shelx_res_checksum              71258