Porous Co3O4 materials prepared by solid-state thermolysis of a novel Co-MOF crystal and their superior energy storage performances for supercapacitors
Meng, Fanli; Fang, Zhiguo; Li, Zuoxi; Xu, Weiwei; Wang, Mengjiao; Liu, Yanping; Zhang, Ji; Wang, Wanren; Zhao, Dongyuan; Guo, Xiaohui; Journal of Materials Chemistry A 1 (2013) 7235–; doi:10.1039/c3ta11054k

data_7239524
_publ_section_title
;
 Porous Co3O4 materials prepared by solid-state thermolysis of a novel
 Co-MOF crystal and their superior energy storage performances for
 supercapacitors
;
_journal_issue                   24
_journal_name_full               'Journal of Materials Chemistry A'
_journal_page_first              7235
_journal_paper_doi               10.1039/c3ta11054k
_journal_volume                  1
_journal_year                    2013
_chemical_formula_sum            'C60 H42 Co3 N9 O23'
_chemical_formula_weight         1433.82
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.208(2)
_cell_angle_beta                 99.762(2)
_cell_angle_gamma                108.660(2)
_cell_formula_units_Z            2
_cell_length_a                   11.4215(12)
_cell_length_b                   13.8731(15)
_cell_length_c                   20.777(2)
_cell_measurement_temperature    296(2)
_cell_volume                     3004.7(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.965
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0287
_diffrn_reflns_av_sigmaI/netI    0.0728
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            16360
_diffrn_reflns_theta_full        26.18
_diffrn_reflns_theta_max         26.18
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    0.910
_exptl_absorpt_correction_T_max  0.8786
_exptl_absorpt_correction_T_min  0.7707
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.585
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1460
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.322
_refine_diff_density_min         -0.552
_refine_diff_density_rms         0.137
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.978
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     870
_refine_ls_number_reflns         11614
_refine_ls_number_restraints     7
_refine_ls_restrained_S_all      0.979
_refine_ls_R_factor_all          0.0893
_refine_ls_R_factor_gt           0.0570
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.6454P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1493
_refine_ls_wR_factor_ref         0.1796
_reflns_number_gt                7876
_reflns_number_total             11614
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ta11054k.txt
_cod_data_source_block           xb6086_0m
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7239524