Bis(2,2'-bipyridine-κ^2^<i>N</i>,<i>N</i>')platinum(II) bis(perchlorate)
Clare, Bronya R.; McInnes, Claire S.; Blackman, Allan G.; Acta Crystallographica Section E 61 (2005) m2042–m2043; doi:10.1107/S1600536805029089

data_2207078
_publ_section_title
;
 Bis(2,2'-bipyridine-\k^2^<i>N</i>,<i>N</i>')platinum(II)
 bis(perchlorate)
;
_journal_coeditor_code           TK6260
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2042
_journal_page_last               m2043
_journal_paper_doi               10.1107/S1600536805029089
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Pt (C10 H8 N2)2] (Cl O4)2'
_chemical_formula_moiety         'C20 H16 N4 Pt 2+, 2Cl O4 -'
_chemical_formula_sum            'C20 H16 Cl2 N4 O8 Pt'
_chemical_formula_weight         706.35
_chemical_name_systematic
;
bis(2,2'-bipyridine-\k^2^N,N')platinum(II) bis(perchlorate)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                72.972(5)
_cell_angle_beta                 86.553(5)
_cell_angle_gamma                64.960(5)
_cell_formula_units_Z            1
_cell_length_a                   7.811(5)
_cell_length_b                   8.621(5)
_cell_length_c                   9.054(5)
_cell_measurement_reflns_used    5644
_cell_measurement_temperature    85(2)
_cell_measurement_theta_max      33.0
_cell_measurement_theta_min      2.4
_cell_volume                     526.7(5)
_computing_cell_refinement       'APEX-II and SAINT (Bruker, 2001)'
_computing_data_collection       'APEX-II (Bruker, 2004)'
_computing_data_reduction        SAINT
_computing_molecular_graphics
'ORTEP-3 (Farrugia, 1997 and SHELXTL (Bruker, 2001)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      85(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.747
_diffrn_measurement_device_type  'Bruker Kappa-APEX-II area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.028
_diffrn_reflns_av_sigmaI/netI    0.024
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            11349
_diffrn_reflns_theta_full        25.0
_diffrn_reflns_theta_max         33.2
_diffrn_reflns_theta_min         2.4
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.974
_exptl_absorpt_correction_T_max  0.572
_exptl_absorpt_correction_T_min  0.361
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2001)'
_exptl_crystal_colour            pale-yellow
_exptl_crystal_density_diffrn    2.227
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             340
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.19
_refine_diff_density_min         -1.34
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.08
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     160
_refine_ls_number_reflns         3010
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.08
_refine_ls_R_factor_all          0.014
_refine_ls_R_factor_gt           0.014
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0182P)^2^+0.2101P] where P = (Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.036
_refine_ls_wR_factor_ref         0.036
_reflns_number_gt                3010
_reflns_number_total             3010
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            tk6260.cif
_cod_data_source_block           I
_cod_database_code               2207078
_cod_database_fobs_code          2207078