Exploring Steric Effects in Diastereoselective Synthesis of Chiral Aminophenolate Zinc Complexes and Stereoselective Ring-Opening Polymerization of rac-Lactide.
Wang, Haobing; Yang, Yang; Ma, Haiyan; Inorganic chemistry 55 (2016) 7356–7372; doi:10.1021/acs.inorgchem.6b00378

data_4347601
_publ_section_title
;
 Exploring Steric Effects in Diastereoselective Synthesis of Chiral
 Aminophenolate Zinc Complexes and Stereoselective Ring-Opening
 Polymerization of rac-Lactide.
;
_journal_issue                   15
_journal_name_full               'Inorganic chemistry'
_journal_page_first              7356
_journal_page_last               7372
_journal_paper_doi               10.1021/acs.inorgchem.6b00378
_journal_volume                  55
_journal_year                    2016
_chemical_formula_sum            'C59 H71 N3 O Si2 Zn'
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_cell_angle_gamma                116.379(2)
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_cell_length_c                   21.951(2)
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_diffrn_ambient_temperature      140(2)
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_diffrn_measured_fraction_theta_max 0.992
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_diffrn_reflns_av_R_equivalents  0.0356
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_diffrn_reflns_Laue_measured_fraction_full 0.991
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_exptl_crystal_description       prism
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0212P)^2^+24.3350P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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