Complexes of the tripodal phosphine ligands PhSi(XPPh2)3 (X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2.
Aloisi, Alicia; Berthet, Jean-Claude; Genre, Caroline; Thuéry, Pierre; Cantat, Thibault; Dalton transactions (Cambridge, England : 2003) 45 (2016) 14774–14788; doi:10.1039/c6dt02135b

data_7039916
_publ_section_title
;
 Complexes of the tripodal phosphine ligands PhSi(XPPh2)3 (X = CH2, O):
 synthesis, structure and catalytic activity in the hydroboration of CO2.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               14788
_journal_paper_doi               10.1039/c6dt02135b
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C42 H35 Cl2 Co O3 P3 Si'
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_atom_sites_solution_hydrogens   mixed
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;
2016-06-21 deposited with the CCDC.
2016-07-15 downloaded from the CCDC.
;
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'Nonius Kappa-CCD area-detector diffractometer'
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'two \f and five \w scans with 2\% steps (489 frames)'
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'w=1/[\s^2^(Fo^2^)+(0.0466P)^2^+2.2366P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7039913--7039920.cif.'
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