Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex with mutual Jahn-Teller effect.
Hamazawa, Rika Tanaka; Nishioka, Takanori; Kinoshita, Isamu; Takui, Takeji; Santo, Ryoko; Ichimura, Akio; Dalton transactions (Cambridge, England : 2003)  (2006) 1374–1376; doi:10.1039/b515926a

data_7006957
_publ_section_title
;
 Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex
 with mutual Jahn-Teller effect.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1374
_journal_page_last               1376
_journal_paper_doi               10.1039/b515926a
_journal_year                    2006
_chemical_formula_moiety         'C80 H64 B2 N8 O4 S6 Rh '
_chemical_formula_sum            'C80 H64 B2 N8 O4 Rh S6'
_chemical_formula_weight         1518.32
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                90.304(13)
_cell_angle_beta                 104.791(12)
_cell_angle_gamma                118.129(12)
_cell_formula_units_Z            2
_cell_length_a                   13.4562(9)
_cell_length_b                   14.0801(10)
_cell_length_c                   22.273(2)
_cell_measurement_reflns_used    8675
_cell_measurement_temperature    193.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      4.1
_cell_volume                     3558.9(7)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.943
_diffrn_measured_fraction_theta_max 0.943
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.072
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            35358
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.474
_exptl_absorpt_correction_T_max  0.931
_exptl_absorpt_correction_T_min  0.907
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
Higashi, T. (1999). Program for Absorption Correction.
Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.417
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1566.00
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.61
_refine_diff_density_min         -1.43
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     977
_refine_ls_number_reflns         15413
_refine_ls_R_factor_gt           0.0675
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0008Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1385
_reflns_number_gt                9235
_reflns_number_total             15413
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b515926a.txt
_cod_data_source_block           2bNM-RhIITpy2BPh4
_cod_original_cell_volume        3558.8(5)
_cod_original_formula_sum        'C80 H64 B2 N8 O4 S6 Rh '
_cod_database_code               7006957