Magnesium Imide: Synthesis and Structure Determination of an Unconventional Alkaline Earth Imide from Decomposition of Magnesium Amide
Francesco Dolci; Emilio Napolitano; Eveline Weidner; Stefano Enzo; Pietro Moretto; Michela Brunelli; Thomas Hansen; Maximilian Fichtner; Wiebke Lohstroh; Inorganic Chemistry 50 (2011) 1116–1122; doi:10.1021/ic1023778

data_4324382
_publ_contact_author_address
;European Commission -  JRC Institute for Energy

Cleaner Energy Unit

Westerduinweg 3

NL-1755 ZG Petten

The Netherlands
;
_publ_contact_author_email       francesco.dolci@ec.europa.eu
_publ_contact_author_fax         +31-(0)22456-5623
_publ_contact_author_name        'Francesco Dolci'
_publ_contact_author_phone       +31-(0)22456-5261
_publ_section_title
;
 Magnesium Imide: Synthesis and Structure Determination of an
 Unconventional Alkaline Earth Imide from Decomposition of Magnesium Amide
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1116
_journal_page_last               1122
_journal_paper_doi               10.1021/ic1023778
_journal_volume                  50
_journal_year                    2011
_chemical_formula_moiety         'H1 Mg1 N1'
_chemical_formula_structural     'D Mg N'
_chemical_formula_sum            'H Mg N'
_chemical_formula_weight         40.33
_chemical_name_common            'Magnesium imide'
_chemical_name_systematic        'Magnesium imide'
_space_group_IT_number           175
_symmetry_cell_setting           hexagonal
_symmetry_Int_Tables_number      175
_symmetry_space_group_name_Hall  '-P 6'
_symmetry_space_group_name_H-M   'P 6/m'
_cell_angle_alpha                90.0
_cell_angle_beta                 90.0
_cell_angle_gamma                120
_cell_formula_units_Z            12
_cell_length_a                   11.57961(3)
_cell_length_b                   11.57961(3)
_cell_length_c                   3.6811(1)
_cell_measurement_temperature    300
_cell_volume                     427.461(12)
_computing_structure_refinement  MAUD
_diffrn_ambient_temperature      300
_diffrn_measurement_device_type  'D20 instrument, ILL'
_diffrn_radiation_probe          neutron
_diffrn_radiation_type           neutron
_diffrn_radiation_wavelength     1.868
_diffrn_source                   'nuclear reactor'
_diffrn_source_type              'D20 instrument, ILL'
_exptl_crystal_density_diffrn    1.833
_pd_meas_2theta_range_max        140
_pd_meas_2theta_range_min        5
_pd_meas_number_of_points        1352
_pd_proc_ls_prof_wR_factor       0.024426367
_pd_spec_mount_mode              transmission
_pd_spec_shape                   cylinder
_refine_ls_d_res_high            1.00072
_refine_ls_d_res_low             10.02823
_refine_ls_goodness_of_fit_all   1.94
_refine_ls_number_parameters     35
_refine_ls_R_I_factor            0.017678035
_cod_data_source_file            ic1023778_si_001.cif
_cod_data_source_block           MgNH
_cod_depositor_comments
;
The following automatic conversions were performed:

'_geom_bond_publ_flag' value 'N' changed to 'n' according to the
built-in table from CIF Core dictionary named 'cif_core.dic' version
2.4.1 from 2010-06-29 (51 time).

'_geom_angle_publ_flag' value 'N'
changed to 'n' according to the built-in table from CIF Core
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29 (93
times).

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        427.463
_cod_original_formula_sum        'H1 Mg1 N1'
_cod_database_code               4324382