3-NO2-5,10,15-triarylcorrolato-Cu as a versatile platform for synthesis of novel 3-functionalized corrole derivatives.
Stefanelli, M.; Mancini, M.; Raggio, M.; Nardis, S.; Fronczek, F. R.; McCandless, G. T.; Smith, K. M.; Paolesse, R.; Organic & biomolecular chemistry 12 (2014) 6200–6207; doi:10.1039/c4ob01247j

data_7153940
_publ_section_title
;
 3-NO2-5,10,15-triarylcorrolato-Cu as a versatile platform for synthesis
 of novel 3-functionalized corrole derivatives.
;
_journal_issue                   32
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              6200
_journal_page_last               6207
_journal_paper_doi               10.1039/c4ob01247j
_journal_volume                  12
_journal_year                    2014
_chemical_formula_moiety         'C51 H50 Cu N5 O'
_chemical_formula_sum            'C51 H50 Cu N5 O'
_chemical_formula_weight         812.50
_chemical_name_common            3-CH3C(O)NH-TtBuCorrCu
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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;
2014-04-15 # Formatted by publCIF

;
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_cell_volume                     2125.1(6)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_measurement_device_type
;
Bruker Kappa D8 APEX-II DUO CCD diffractometer (with an Oxford Cryosystems
cryostream cooler)
;
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  'HELIOS optics'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_av_unetI/netI     0.0331
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0871P)^2^+7.1859P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1866
_refine_ls_wR_factor_ref         0.1892
_reflns_Friedel_coverage         0.000
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_reflns_number_total             7465
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