Abnormal carbene-silicon halide complexes.
Wang, Yuzhong; Xie, Yaoming; Wei, Pingrong; Schaefer, Henry F.; Robinson, Gregory H.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 5941–5944; doi:10.1039/c5dt03894d

data_7037438
_publ_section_title
;
 Abnormal carbene-silicon halide complexes.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5941
_journal_page_last               5944
_journal_paper_doi               10.1039/c5dt03894d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C31 H43 Cl3 N2 O Si'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yac'
_space_group_name_H-M_alt        'P 1 2/n 1'
_symmetry_space_group_name_Hall  '-P 2yac'
_symmetry_space_group_name_H-M   'P 1 2/n 1'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2015-09-17 deposited with the CCDC.
2015-11-17 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX-II CCD'
_diffrn_measurement_method       'OMEGA SCAN'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0854
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_exptl_absorpt_process_details   'BRUKER SADABS'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0824P)^2^+1.9503P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7037438--7037440.cif.'
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