Regioselective carbolithiation of o-amino-(E)-stilbenes: cascade route to the quinoline scaffold.
Hogan, Anne-Marie L; O'Shea, Donal F; Organic letters 8 (2006) 3769–3772; doi:10.1021/ol061348n

data_1506131
_publ_section_title
;
 Regioselective carbolithiation of o-amino-(E)-stilbenes: cascade route to
 the quinoline scaffold.
;
_journal_issue                   17
_journal_name_full               'Organic letters'
_journal_page_first              3769
_journal_page_last               3772
_journal_paper_doi               10.1021/ol061348n
_journal_volume                  8
_journal_year                    2006
_chemical_formula_sum            'C24 H31 N O3'
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_cell_angle_gamma                90.00
_cell_formula_units_Z            8
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_cell_length_c                   23.271(5)
_cell_measurement_reflns_used    3148
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_cell_volume                     4191.4(16)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.968
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type  'CCD area detector'
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_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_theta_max         20.86
_diffrn_reflns_theta_min         1.75
_exptl_absorpt_coefficient_mu    0.079
_exptl_absorpt_correction_T_max  0.9961
_exptl_absorpt_correction_T_min  0.6600
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_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.209
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0332P)^2^+1.3109P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0791
_refine_ls_wR_factor_ref         0.0881
_reflns_number_gt                1644
_reflns_number_total             2140
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ol061348nsi20060602_082131.cif
_cod_data_source_block           osh25
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        4191.5(16)
_cod_database_code               1506131