An open route to asymmetric substituted Al-Al bonds using Al(i)- and Al(iii)-precursors.
Li, Bin; Kundu, Subrata; Zhu, Hongping; Keil, Helena; Herbst-Irmer, Regine; Stalke, Dietmar; Frenking, Gernot; Andrada, Diego M.; Roesky, Herbert W.; Chemical communications (Cambridge, England) 53 (2017) 2543–2546; doi:10.1039/c7cc00325k

data_7119555
_publ_section_title
;
 An open route to asymmetric substituted Al-Al bonds using Al(i)- and
 Al(iii)-precursors.
;
_journal_issue                   17
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              2543
_journal_page_last               2546
_journal_paper_doi               10.1039/c7cc00325k
_journal_volume                  53
_journal_year                    2017
_chemical_formula_moiety         '2(C49 H72 Al2 I3 N3), 3(C7 H8)'
_chemical_formula_sum            'C59.5 H84 Al2 I3 N3'
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2017-01-04 deposited with the CCDC.
2017-01-27 downloaded from the CCDC.
;
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'SHELXT(G.M.Sheldrick,Acta Cryst.(2015)A71,3-8)'
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'w=1/[\s^2^(Fo^2^)+(0.0271P)^2^+8.0058P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7119554--7119556.cif.'
_cod_original_formula_sum        'C59.50 H84 Al2 I3 N3'
_cod_database_code               7119555
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