A zinc(II) metal‒organic framework with a novel topology formed from 4,4',4''-nitrilotribenzoate and 4,4'-bipyridine ligands
Zhao, Meng; Su, Jian; Zhang, Jun; Wu, Jie-Ying; Tian, Yu-Peng; Acta Crystallographica Section C 71 (2015) –; doi:10.1107/S2053229615014813

data_2020088
_publ_section_title
;
 A zinc(II) metal--organic framework with a novel topology formed from
 4,4',4''-nitrilotribenzoate and 4,4'-bipyridine ligands
;
_journal_coeditor_code           YO3010
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229615014813
_journal_volume                  71
_journal_year                    2015
_chemical_formula_iupac
'[Zn3 (C21 H12 N1 O6)2 (C10 H8 N2)1.5 (C3 H7 N1 O1)2]'
_chemical_formula_moiety         'C63 H50 N7 O14 Zn3'
_chemical_formula_sum            'C63 H50 N7 O14 Zn3'
_chemical_formula_weight         1325.21
_chemical_name_systematic
Poly[sesqui(\m~2~-4,4'-bipyridine)bis(dimethylformamide)bis(\m~4~-4,4',4''-nitrilotribenzoato)trizinc(II)]
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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;
SMART (Bruker, 2000)
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SMART (Bruker, 2000)
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SAINT (Bruker, 2000)
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SHELXTL (Sheldrick, 2008)
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SHELXTL (Sheldrick, 2008)
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SHELXL2013 (Sheldrick, 2015)
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SHELXS97 (Sheldrick, 2008)
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(SADABS; Bruker, 2000)
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_refine_ls_R_factor_all          0.1003
_refine_ls_R_factor_gt           0.0709
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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;
w = 1/[\s^2^(Fo^2^)+(0.1184P)^2^] where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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