Two-dimensional rare-earth-metal coordination polymers based on biphenyl-3,3',5,5'-tetracarboxylic acid displaying luminescence
Zhou, Juan; Zhang, Xinlei; Zi, Wenwen; Zhou, Lian; Acta Crystallographica Section C 78 (2022) –; doi:10.1107/S2053229622005678

data_2022618
_publ_section_title
;
 Two-dimensional rare-earth-metal coordination polymers based on
 biphenyl-3,3',5,5'-tetracarboxylic acid displaying luminescence
;
_journal_coeditor_code           OC3015
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229622005678
_journal_volume                  78
_journal_year                    2022
_chemical_formula_iupac
'[Ho4 (C16 H6 O8)2 (C2 H3 O2)4 (C4 H9 N O)4], 5H2 O'
_chemical_formula_moiety         'C56 H60 Ho4 N4 O28, 5(H2 O)'
_chemical_formula_sum            'C56 H70 Ho4 N4 O33'
_chemical_formula_weight         1986.88
_chemical_name_systematic
'Poly[[tetra-\m~2~-acetato-bis(\m~6~-biphenyl-3,3',5,5'-tetracarboxylato)tetrakis(dimethylacetamide)tetraholmium(III)] pentahydrate]'
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
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Olex2 1.2-beta
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
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CrysAlis PRO (Rigaku OD, 2015)
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CrysAlis PRO (Rigaku OD, 2015)
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CrysAlis PRO (Rigaku OD, 2015)
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OLEX2 (Dolomanov <i>et al.</i>, 2009)
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OLEX2 (Dolomanov <i>et al.</i>, 2009)
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SHELXL2018 (Sheldrick, 2015<i>b</i>)
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SHELXT2014 (Sheldrick, 2015<i>a</i>)
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'Rigaku OD SuperNova Dual source diffractometer with an EosS2 detector'
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_diffrn_reflns_limit_k_min       -21
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_diffrn_source                   'micro-focus sealed X-ray tube'
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;
(CrysAlis PRO; Rigaku OD, 2015)
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_exptl_crystal_size_min          0.1
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_refine_diff_density_min         -0.552
_refine_ls_extinction_method     none
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'w=1/[\s^2^(Fo^2^)+(0.0350P)^2^+0.7624P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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