A concise synthesis of (E)-3-aryl-2,3,4,5-tetrahydro-1H-3-benzazonines by aryne induced [2,3] Stevens rearrangement of 1,2,3,4-tetrahydroisoquinolines.
Pan, Xuan; Ma, Yantao; Liu, Zhanzhu; Organic & biomolecular chemistry 16 (2018) 7393–7399; doi:10.1039/c8ob02099j

data_7156440
_publ_section_title
;
 A concise synthesis of (E)-3-aryl-2,3,4,5-tetrahydro-1H-3-benzazonines by
 aryne induced [2,3] Stevens rearrangement of
 1,2,3,4-tetrahydroisoquinolines.
;
_journal_issue                   40
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              7393
_journal_page_last               7399
_journal_paper_doi               10.1039/c8ob02099j
_journal_volume                  16
_journal_year                    2018
_chemical_formula_moiety         'C20 H20 N2'
_chemical_formula_sum            'C20 H20 N2'
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2018-09-13 deposited with the CCDC.
2018-09-19 downloaded from the CCDC.
;
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
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'A short history of SHELX (Sheldrick, 2007)/Bruker'
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;
  1 omega  -47.00   45.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       18.7335  -77.0000    0.0000 92

  2 omega   59.00   84.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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  3 omega  -36.00   33.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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  4 omega   10.00   77.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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  5 omega   58.00   85.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       18.7335  178.0000 -150.0000 27

  6 omega   -8.00   85.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
    -       18.7335   77.0000  120.0000 93
;
_diffrn_measurement_device       'four-circle diffractometer'
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_diffrn_source                   'Enhance (Mo) X-ray Source'
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    1.228
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'calc w=1/[\s^2^(Fo^2^)+(0.0480P)^2^+0.2440P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments          'Adding full bibliography for 7156440.cif.'
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