Sensitization of Lanthanoid Luminescence by Organic and Inorganic Ligands in Lanthanoid-Organic-Polyoxometalates
Chris Ritchie; Valérie Baslon; Evan G. Moore; Christian Reber; Colette Boskovic; Inorganic Chemistry 51 (2012) 1142–1151; doi:10.1021/ic202349u

data_4328055
_publ_contact_author_address
'School of Chemistry, University of Melbourne, Victoria 3010, Australia'
_publ_contact_author_email       c.boskovic@unimelb.edu.au
_publ_contact_author_fax         '+61 3 9347 5180'
_publ_contact_author_name        'Dr. Colette Boskovic'
_publ_contact_author_phone       '+61 3 8344 4971'
_publ_section_title
;
 Sensitization of Lanthanoid Luminescence by Organic and Inorganic Ligands
 in Lanthanoid-Organic-Polyoxometalates
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1142
_journal_page_last               1151
_journal_paper_doi               10.1021/ic202349u
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C72 H204 As4 Eu9.67 K7 N12 O231.75 W38'
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 ?
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_data_collection
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_molecular_graphics    'Diamond 3.2g'
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_diffrn_ambient_temperature      130(2)
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_exptl_absorpt_correction_T_max  1.00000
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CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.15 (release 10-01-2008 CrysAlis171 .NET)
(compiled Jan 10 2008,16:37:18)
empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    3.169
_exptl_crystal_description       Rod
_exptl_crystal_F_000             25040
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_exptl_crystal_size_mid          0.1040
_exptl_crystal_size_min          0.0380
_refine_diff_density_max         2.508
_refine_diff_density_min         -2.361
_refine_diff_density_rms         0.387
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.712
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     802
_refine_ls_number_reflns         15569
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.712
_refine_ls_R_factor_all          0.1739
_refine_ls_R_factor_gt           0.0598
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0341P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1151
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_cod_data_source_file            ic202349u_si_002_3.cif
_cod_data_source_block           compound3
_cod_original_cell_volume        29293(4)
_cod_database_code               4328055