Coordination assembly enables highly selective catalytic hydroaminomethylation of olefins
Qian, Chun; Zheng, Qingshu; Chen, Jie; Tu, Bo; Tu, Tao; Green Chemistry 25 (2023) 1368–1379; doi:10.1039/D2GC04195B

data_7245935
_publ_section_title
;
 Coordination assembly enables highly selective catalytic
 hydroaminomethylation of olefins
;
_journal_issue                   4
_journal_name_full               'Green Chemistry'
_journal_page_first              1368
_journal_page_last               1379
_journal_paper_doi               10.1039/D2GC04195B
_journal_volume                  25
_journal_year                    2023
_chemical_formula_sum            'C127 H147 B2 Cl9 F8 N8 Rh2'
_chemical_formula_weight         2484.01
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2022-05-04 deposited with the CCDC.	2022-11-21 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_cell_measurement_temperature    175(2)
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_cell_measurement_theta_min      3.72
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_computing_cell_refinement       'Bruker SAINT'
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_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      175(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_av_R_equivalents  0.0653
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_diffrn_reflns_Laue_measured_fraction_full 0.990
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_exptl_absorpt_correction_T_max  0.751
_exptl_absorpt_correction_T_min  0.454
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.233
_exptl_crystal_description       block
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_refine_ls_restrained_S_all      1.095
_refine_ls_R_factor_all          0.1326
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0750P)^2^+137.7965P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3036
_refine_ls_wR_factor_ref         0.3069
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_reflns_number_gt                22839
_reflns_number_total             26519
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d2gc04195b2.cif
_cod_data_source_block           platon_sq
_cod_depositor_comments
'Adding full bibliography for 7245933--7245935.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7245935
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.546
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_shelx_res_checksum              43401
_shelx_fab_checksum              41176