Octahedral manganese(i) and ruthenium(ii) complexes containing 2-(methylamido)pyridine-borane as a tripod κ(3)N,H,H-ligand.
Brugos, Javier; Cabeza, Javier A.; García-Álvarez, Pablo; Pérez-Carreño, Enrique; Van der Maelen, Juan F.; Dalton transactions (Cambridge, England : 2003) 46 (2017) 4009–4017; doi:10.1039/c7dt00378a

data_7042231
_publ_section_title
;
 Octahedral manganese(i) and ruthenium(ii) complexes containing
 2-(methylamido)pyridine-borane as a tripod \k(3)N,H,H-ligand.
;
_journal_issue                   12
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4009
_journal_page_last               4017
_journal_paper_doi               10.1039/c7dt00378a
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C9 H10 B Mn N2 O3'
_chemical_formula_sum            'C9 H10 B Mn N2 O3'
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_chemical_name_systematic
;
 ?
;
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_space_group_name_Hall           '-C 2yc'
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_symmetry_space_group_name_Hall  '-C 2yc'
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_atom_sites_solution_hydrogens   mixed
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;
2017-01-31 deposited with the CCDC.
2017-02-27 downloaded from the CCDC.
;
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;
'CrysAlisPro 1.171.38.43 (Rigaku OD, 2015)'
;
_computing_data_collection
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'CrysAlisPro 1.171.38.43 (Rigaku OD, 2015)'
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'CrysAlisPro 1.171.38.43 (Rigaku OD, 2015)'
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'MERCURY (Cambridge Crystallographic Data Centre: Cambridge, UK, 2016)'
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_computing_structure_solution    'SIR-97 (Giacovazzo, 1999)'
_diffrn_ambient_temperature      145(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Xcalibur, Onyx, Nova'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_Laue_measured_fraction_max 0.974
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_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
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_diffrn_reflns_point_group_measured_fraction_full 0.995
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;
CrysAlisPro 1.171.38.43 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0457P)^2^+1.0887P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                1950
_reflns_number_total             2059
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7042231--7042232.cif.'
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