Oxidations of (R3tach)M(CO)3 Complexes [M = Cr, Mo, W; R3tach = 1,3,5-Trialkyl-1,3,5-triazacyclohexane (R =t-Bu, Bn)]. Crystal Structures of (t-Bu3tach)MO3.15H2O (M = Mo, W)
Murray V. Baker; Michael R. North; Brian W. Skelton; Allan H. White; Inorganic Chemistry 38 (1999) 4515–4521; doi:10.1021/ic990031z

data_4322252
_publ_contact_author
;
     M.V.Baker
     University of Western Australia
     Department of Chemistry
     Nedlands  6907
     Western Australia
     Australia 
;
_publ_contact_author_email       mvb@chem.uwa.edu.au
_publ_contact_author_fax         (61)_8_9380-1005
_publ_contact_author_phone       (61)_8_9380-2576
_publ_section_title
;
 Oxidations of (R3tach)M(CO)3 Complexes [M = Cr, Mo, W; R3tach =
 1,3,5-Trialkyl-1,3,5-triazacyclohexane (R =t-Bu, Bn)]. Crystal Structures
 of (t-Bu3tach)MO3.15H2O (M = Mo, W)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4515
_journal_page_last               4521
_journal_paper_doi               10.1021/ic990031z
_journal_volume                  38
_journal_year                    1999
_chemical_formula_analytical     'C15 H63 N3 O18 W'
_chemical_formula_structural     (C15H33N3)WO3.15H2O
_chemical_formula_sum            'C15 H63 N3 O18 W'
_chemical_formula_weight         757.52
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_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  'R 3 -2"c'
_symmetry_space_group_name_H-M   'R 3 c :H'
_audit_creation_date             98-07-09
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_cell_angle_beta                 90.00000
_cell_angle_gamma                120.0000
_cell_formula_units_Z            6
_cell_length_a                   21.011(3)
_cell_length_b                   21.011(3)
_cell_length_c                   13.390(3)
_cell_measurement_reflns_used    5835
_cell_measurement_temperature    298
_cell_measurement_theta_max      28.0
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_computing_cell_refinement       'Bruker SAINT software'
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_diffrn_measurement_device       'area detector'
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_extinction_expression Eq22_p292_"Cryst._Comp."_Munksgaard_1970
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_refine_ls_shift/esd_max         .021
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_refine_ls_structure_factor_coef F
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_refine_ls_wR_factor_obs         .019
_reflns_d_resolution_high        .731
_reflns_d_resolution_low         10.483
_reflns_limit_h_max              24
_reflns_limit_h_min              0
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_cod_data_source_file            ic990031z_1.cif
_cod_data_source_block           n3wo3
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_cod_original_sg_symbol_Hall     r_3_-2"c
_cod_original_sg_symbol_H-M      'R 3 c'
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