Tetrahedral M(II) based binuclear double-stranded helicates: single-ion-magnet and fluorescence behaviour.
Mondal, Amit Kumar; Parmar, Vijay Singh; Biswas, Soumava; Konar, Sanjit; Dalton transactions (Cambridge, England : 2003) 45 (2016) 4548–4557; doi:10.1039/c5dt04173b

data_7038130
_publ_section_title
;
 Tetrahedral M(II) based binuclear double-stranded helicates:
 single-ion-magnet and fluorescence behaviour.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4548
_journal_page_last               4557
_journal_paper_doi               10.1039/c5dt04173b
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C52 H36 Co2 N4 O6, 2(C2 H3 N)'
_chemical_formula_sum            'C56 H42 Co2 N6 O6'
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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;
2015-12-29 deposited with the CCDC.
2016-01-25 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_theta_max         25.134
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_exptl_absorpt_correction_T_max  0.896
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_exptl_absorpt_process_details   MULTI-SCAN
_exptl_crystal_colour            red
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_exptl_crystal_description       block
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_refine_ls_number_restraints     0
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0362P)^2^+1.1301P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0772
_refine_ls_wR_factor_ref         0.0833
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6916
_reflns_number_total             8495
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt04173b2.cif
_cod_data_source_block           AMCo1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7038130--7038133.cif.
;
_cod_database_code               7038130
_shelxl_version_number           2014/6
_shelx_res_checksum              86115