A thiol‒ene click reaction with preservation of the Si‒H bond: a new approach for the synthesis of functional organosilicon compounds
Anisimov, Anton A.; Temnikov, Maxim N.; Krizhanovskiy, Ilya; Timoshina, Ekaterina I.; Milenin, Sergey A.; Peregudov, Alexander S.; Dolgushin, Fedor M.; Muzafarov, Aziz M.; New Journal of Chemistry 45 (2021) 5764–5769; doi:10.1039/D1NJ00411E

data_7060421
_publ_section_title
;
 A thiol--ene click reaction with preservation of the Si--H bond: a new
 approach for the synthesis of functional organosilicon compounds
;
_journal_issue                   13
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              5764
_journal_page_last               5769
_journal_paper_doi               10.1039/D1NJ00411E
_journal_volume                  45
_journal_year                    2021
_chemical_formula_moiety         'C27 H34 S3 Si'
_chemical_formula_sum            'C27 H34 S3 Si'
_chemical_formula_weight         482.81
_space_group_crystal_system      hexagonal
_space_group_IT_number           176
_space_group_name_Hall           '-P 6c'
_space_group_name_H-M_alt        'P 63/m'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-11-30 deposited with the CCDC.	2021-02-18 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
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_cell_formula_units_Z            2
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_cell_length_c                   6.9649(3)
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_cell_measurement_temperature    120(2)
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_cell_measurement_theta_min      2.77
_cell_volume                     1301.97(8)
_computing_cell_refinement       'Bruker SAINT'
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_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0230
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_exptl_absorpt_coefficient_mu    0.344
_exptl_absorpt_correction_T_max  0.934
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         1364
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0330
_refine_ls_R_factor_gt           0.0324
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0320P)^2^+0.8527P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0838
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_reflns_number_gt                1332
_reflns_number_total             1364
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           sad
_cod_depositor_comments          'Adding full bibliography for 7060421.cif.'
_cod_original_cell_volume        1301.97(10)
_cod_database_code               7060421
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              86617