Coordination behaviour of a hybrid phosphinoguanidine ligand
Leitner, Zdeněk; Císařová, Ivana; Štěpnička, Petr; New Journal of Chemistry 46 (2022) 1060–1071; doi:10.1039/D1NJ05237C

data_7061103
_publ_section_title
;
 Coordination behaviour of a hybrid phosphinoguanidine ligand
;
_journal_issue                   3
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              1060
_journal_page_last               1071
_journal_paper_doi               10.1039/D1NJ05237C
_journal_volume                  46
_journal_year                    2022
_chemical_formula_moiety         'C33 H42 Cl N3 P Pt, Cl, 2(C3 H6 O)'
_chemical_formula_sum            'C39 H54 Cl2 N3 O2 P Pt'
_chemical_formula_weight         893.81
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2021-11-01 deposited with the CCDC.	2021-12-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.53
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_cell_volume                     4075.2(4)
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_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 VENTURE Kappa Duo PHOTON 100 CMOS'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  'Quazar Mo multilayer optic'
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_diffrn_reflns_av_R_equivalents  0.0412
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_diffrn_reflns_limit_l_min       -17
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0179P)^2^+8.3746P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                8089
_reflns_number_total             9374
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           zl32
_cod_depositor_comments
'Adding full bibliography for 7061094--7061104.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7061103
_shelx_shelxl_version_number     2017/1
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_shelx_estimated_absorpt_t_max   0.839
_shelx_res_checksum              49005