A zigzag-type one-dimensional coordination polymer formed by (2,2-dimethyl-1,3-propanediamine)bis(isonicotinato)platinum(II) and copper nitrate
Song, Rita; Kim, Kwan Mook; Sohn, Youn Soo; Acta Crystallographica Section C 56 (2000) e447–e447; doi:10.1107/S0108270100012488

data_2011442
_publ_section_title
;
 A zigzag-type one-dimensional coordination polymer formed by
 (2,2-dimethyl-1,3-propanediamine)bis(isonicotinato)platinum(II) and
 copper nitrate
;
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              e447
_journal_page_last               e447
_journal_paper_doi               10.1107/S0108270100012488
_journal_volume                  56
_journal_year                    2000
_chemical_formula_iupac
'[Cu Pt (C6 H4 N O2)2 (C5 H14 N2) (H2 O)3] (N O3)2'
_chemical_formula_moiety         'C17 H28 Cu1 N4 O9 Pt1 2+, 2N1 O3 1-'
_chemical_formula_sum            'C17 H28 Cu N6 O15 Pt'
_chemical_formula_weight         819.12
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 103.29(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.105(3)
_cell_length_b                   18.133(3)
_cell_length_c                   15.590(5)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      14.23
_cell_measurement_theta_min      9.37
_cell_volume                     2780.1(13)
_computing_cell_refinement       CAD-4-VAX
_computing_data_collection       'CAD-4-VAX (Enraf-Nonius, 1981)'
_computing_data_reduction        'SDP (Frenz, 1985)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full .987
_diffrn_measured_fraction_theta_max .987
_diffrn_measurement_device_type  'Enraf-Nonius CAD-4'
_diffrn_measurement_method       \w/2\q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .0347
_diffrn_reflns_av_sigmaI/netI    .0343
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            6863
_diffrn_reflns_theta_full        24.97
_diffrn_reflns_theta_max         24.97
_diffrn_reflns_theta_min         1.75
_diffrn_standards_decay_%        9.6
_diffrn_standards_interval_time  120
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.870
_exptl_absorpt_correction_T_max  .128
_exptl_absorpt_correction_T_min  .058
_exptl_absorpt_correction_type   '\y scan'
_exptl_absorpt_process_details   '(North et al., 1968)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.957
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1612
_exptl_crystal_size_max          .55
_exptl_crystal_size_mid          .40
_exptl_crystal_size_min          .35
_refine_diff_density_max         2.342
_refine_diff_density_min         -1.292
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         4819
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.073
_refine_ls_R_factor_all          .043
_refine_ls_R_factor_gt           .034
_refine_ls_shift/su_max          .011
_refine_ls_shift/su_mean         .000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0497P)^2^+7.8145P] where P = (Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         .091
_reflns_number_gt                4175
_reflns_number_total             4819
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            qa0355.cif
_cod_data_source_block           I
_cod_original_cell_volume        2780.1(12)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C17 H28 Cu1 N6 O15 Pt1'
_cod_database_code               2011442
_cod_database_fobs_code          2011442