Diverse reactivity of a cationic N-heterocyclic phosphenium complex towards anionic substrates - substitution <i>vs.</i> reduction.
Feil, Christoph M.; Goerigk, Florian; Stöckl, Yannick; Nieger, Martin; Gudat, Dietrich; Dalton transactions (Cambridge, England : 2003) 54 (2025) 1806–1814; doi:10.1039/d4dt03352c

data_7718223
_publ_section_title
;
 Diverse reactivity of a cationic N-heterocyclic phosphenium complex
 towards anionic substrates - substitution <i>vs.</i> reduction.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1806
_journal_page_last               1814
_journal_paper_doi               10.1039/d4dt03352c
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C53 H65 B Fe N2 O3 P2, 0.5(C6 H14)'
_chemical_formula_sum            'C56 H72 B Fe N2 O3 P2'
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_secondary   difmap
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_audit_update_record
;
2024-10-30 deposited with the CCDC.	2025-01-06 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      135(2)
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_diffrn_measurement_method       'Omega and phi scans'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0440P)^2^+0.4343P] where P=(Fo^2^+2Fc^2^)/3'
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