Crystal and molecular structures of two silver(I) amidinates, including an unexpected co-crystal with a lithium amidinate
Wang, Sida; Harmgarth, Nicole; Liebing, Phil; Edelmann, Frank T.; Acta Crystallographica Section E 72 (2016) 1786–1790; doi:10.1107/S2056989016017680

data_2241951
_publ_section_title
;
 Crystal and molecular structures of two silver(I) amidinates, including
 an unexpected co-crystal with a lithium amidinate
;
_journal_coeditor_code           WM5332
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              1786
_journal_page_last               1790
_journal_paper_doi               10.1107/S2056989016017680
_journal_volume                  72
_journal_year                    2016
_chemical_formula_iupac          '[Ag2 (C13 H19 N2)2]'
_chemical_formula_moiety         'C26 H38 Ag2 N4'
_chemical_formula_sum            'C26 H38 Ag2 N4'
_chemical_formula_weight         622.34
_chemical_name_systematic
Bis[\m-<i>N</i>^1^,<i>N</i>^2^-bis(propan-2-yl)benzamidinato-\k^2^<i>N</i>^1^:<i>N</i>^2^]disilver(I)
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
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;
X-AREA (Stoe & Cie, 2002)
;
_computing_data_collection
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X-AREA (Stoe & Cie, 2002)
;
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X-AREA and X-RED (Stoe & Cie, 2002)
;
_computing_molecular_graphics
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DIAMOND (Brandenburg, 1999)
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publCIF (Westrip, 2010)
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SHELXL2016 (Sheldrick, 2015b)
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SHELXT2013 (Sheldrick, 2015a)
;
_diffrn_ambient_temperature      153(2)
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Stoe IPDS 2T'
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;
(<i>X-AREA</i> and <i>X-RED</i>; Stoe & Cie, 2002)
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;
SHELXL2016 (Sheldrick, 2015b)
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_refine_ls_R_factor_gt           0.0238
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0238P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_database_fobs_code          2241951
_shelx_estimated_absorpt_t_min   0.734
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