Self-assembly of the unique heterotrimetallic Cu/Co/M complexes possessing triangular antiferromagnetic {Cu2CoPb}2 and linear ferromagnetic {Cu2CoCd2} cores.
Nesterov, Dmytro S.; Kokozay, Volodymyr N.; Skelton, Brian W.; Jezierska, Julia; Ozarowski, Andrew; Dalton transactions (Cambridge, England : 2003)  (2007) 558–564; doi:10.1039/b612788f

data_7004888
_publ_section_title
;
 Self-assembly of the unique heterotrimetallic Cu/Co/M complexes
 possessing triangular antiferromagnetic {Cu2CoPb}2 and linear
 ferromagnetic {Cu2CoCd2} cores.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              558
_journal_page_last               564
_journal_paper_doi               10.1039/b612788f
_journal_year                    2007
_chemical_formula_moiety         'C18 H48 Cd2 Cl6 Co Cu2 N4 O6'
_chemical_formula_sum            'C18 H48 Cd2 Cl6 Co Cu2 N4 O6'
_chemical_formula_weight         1040.25
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00000
_cell_angle_beta                 109.099(7)
_cell_angle_gamma                90.00000
_cell_formula_units_Z            2
_cell_length_a                   8.125(3)
_cell_length_b                   20.612(8)
_cell_length_c                   11.551(4)
_cell_measurement_reflns_used    1957
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.44
_cell_measurement_theta_min      2.65
_cell_volume                     1828.0(12)
_computing_cell_refinement       'Siemens SAINT (Siemens, 1995)'
_computing_data_collection       'Siemens SMART (Siemens, 1995)'
_computing_data_reduction        'Siemens SAINT'
_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  'xtal CRYLSQ'
_computing_structure_solution    xtal
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1.0
_diffrn_measured_fraction_theta_max 1.0
_diffrn_measurement_device_type
;
Bruker SMART CCD diffractometer
;
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_detector       'CCD area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .084
_diffrn_reflns_av_sigmaI/netI    .116
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            16632
_diffrn_reflns_theta_full        25.0
_diffrn_reflns_theta_max         25.0
_diffrn_reflns_theta_min         1.98
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.207
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  .77
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS; Sheldrick, 1996
;
_exptl_crystal_colour            dark_green
_exptl_crystal_density_diffrn    1.89
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       bar
_exptl_crystal_F_000             1030
_exptl_crystal_size_max          .09
_exptl_crystal_size_mid          .03
_exptl_crystal_size_min          .02
_refine_diff_density_max         2.353
_refine_diff_density_min         -1.658
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_gt    1.228
_refine_ls_goodness_of_fit_ref   1.204
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     178
_refine_ls_number_reflns         3186
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .112
_refine_ls_R_factor_gt           .073
_refine_ls_shift/su_max          .002
_refine_ls_shift/su_mean         .0003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         .19
_reflns_d_resolution_high        .84
_reflns_d_resolution_low         10.285
_reflns_Friedel_coverage         0
_reflns_limit_h_max              9
_reflns_limit_h_min              0
_reflns_limit_k_max              24
_reflns_limit_k_min              0
_reflns_limit_l_max              12
_reflns_limit_l_min              -13
_reflns_number_gt                2259
_reflns_number_total             3186
_reflns_threshold_expression     'I > 2.00 sig(I)'
_cod_data_source_file            b612788f.txt
_cod_data_source_block           h556
_cod_original_sg_symbol_Hall     -p_2ybc
_cod_original_sg_symbol_H-M      P_1_21/c_1
_cod_original_formula_sum        'C18 H48 Cd2 Cl6 Co1 Cu2 N4 O6'
_cod_database_code               7004888
_refine_ls_wr_factor_gtf         .142