CO<sub>2</sub> activation by manganese pincer complexes through different modes of metal-ligand cooperation.
Kumar, Amit; Daw, Prosenjit; Espinosa-Jalapa, Noel Angel; Leitus, Gregory; Shimon, Linda J. W.; Ben-David, Yehoshoa; Milstein, David; Dalton transactions (Cambridge, England : 2003) 48 (2019) 14580–14584; doi:10.1039/c9dt03088c

data_7701025
_publ_section_title
;
 CO<sub>2</sub> activation by manganese pincer complexes through different
 modes of metal-ligand cooperation.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14580
_journal_page_last               14584
_journal_paper_doi               10.1039/c9dt03088c
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C22 H36 Mn N2 O4 P'
_chemical_formula_sum            'C22 H36 Mn N2 O4 P'
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_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2019-08-27 deposited with the CCDC.    2019-09-04 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker KappaApex CCD'
_diffrn_measurement_method       'phi and omega scans'
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_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.0415
_refine_ls_R_factor_gt           0.0294
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0357P)^2^+0.9343P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0681
_refine_ls_wR_factor_ref         0.0725
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4333
_reflns_number_total             5257
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt03088c2.cif
_cod_data_source_block           Complex_5'
_cod_depositor_comments
'Adding full bibliography for 7701025--7701028.cif.'
_cod_original_cell_volume        2381.3(9)
_cod_database_code               7701025
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              87025