Biological evaluation of optically pure chiral binuclear copper(ii) complexes based on a rosin derivative as highly potential anticancer agents.
Fei, Bao-Li; Tu, Shuangyan; Wei, Zuzhuang; Wang, Pingping; Long, Jian-Ying; Qiao, Chunhua; Chen, Zhen-Feng; Dalton transactions (Cambridge, England : 2003) 48 (2019) 15646–15656; doi:10.1039/c9dt01942a

data_7700878
_publ_section_title
;
 Biological evaluation of optically pure chiral binuclear copper(ii)
 complexes based on a rosin derivative as highly potential anticancer
 agents.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15646
_journal_page_last               15656
_journal_paper_doi               10.1039/c9dt01942a
_journal_volume                  48
_journal_year                    2019
_chemical_absolute_configuration rm
_chemical_formula_moiety         'C54 H62 Cl2 Cu2 N8 O2 S2'
_chemical_formula_sum            'C54 H62 Cl2 Cu2 N8 O2 S2'
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_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
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_audit_update_record
;
2019-08-15 deposited with the CCDC.    2019-08-20 downloaded from the CCDC.
;
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_cell_volume                     5810.9(5)
_computing_cell_refinement       'Bruker SAINT '
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.05(2)
_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0707P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                7241
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7700877--7700878.cif.'
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