Germanium hydrides as an efficient hydrogen-storage material operated by an iron catalyst.
Kobayashi, Yoshinao; Sunada, Yusuke; Chemical science 14 (2023) 1065–1071; doi:10.1039/d2sc06011f

data_1568317
_publ_section_title
;
 Germanium hydrides as an efficient hydrogen-storage material operated by
 an iron catalyst.
;
_journal_issue                   5
_journal_name_full               'Chemical science'
_journal_page_first              1065
_journal_page_last               1071
_journal_paper_doi               10.1039/d2sc06011f
_journal_volume                  14
_journal_year                    2023
_chemical_absolute_configuration 'CHOOSE rm ad rmad syn or unk'
_chemical_formula_moiety         'C74 H90 Fe Ge4 N4 O2'
_chemical_formula_sum            'C74 H90 Fe Ge4 N4 O2'
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_audit_update_record
;
2022-09-01 deposited with the CCDC.	2022-12-30 downloaded from the CCDC.
;
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;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.403
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
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;
 Flack x determined using 4190 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.010(6)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0401P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0996
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_cod_depositor_comments
'Adding full bibliography for 1568315--1568318.cif.'
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