Reductive nitrosylation of nickel(ii) complex by nitric oxide followed by nitrous oxide release.
Ghosh, Somnath; Deka, Hemanta; Dangat, Yuvraj B.; Saha, Soumen; Gogoi, Kuldeep; Vanka, Kumar; Mondal, Biplab; Dalton transactions (Cambridge, England : 2003) 45 (2016) 10200–10208; doi:10.1039/c6dt00826g

data_7039345
_publ_section_title
;
 Reductive nitrosylation of nickel(ii) complex by nitric oxide followed by
 nitrous oxide release.
;
_journal_issue                   25
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10200
_journal_page_last               10208
_journal_paper_doi               10.1039/c6dt00826g
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C26 H44 Cl2 N8 Ni O2'
_chemical_formula_weight         630.30
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-04-29 deposited with the CCDC.
2016-05-06 downloaded from the CCDC.
;
_cell_angle_alpha                85.293(5)
_cell_angle_beta                 77.072(5)
_cell_angle_gamma                73.587(7)
_cell_formula_units_Z            2
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_computing_cell_refinement       'Bruker SMART'
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_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.1400P)^2^+0.0800P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6dt00826g2.cif
_cod_data_source_block           complex_1
_cod_depositor_comments
'Adding full bibliography for 7039345--7039347.cif.'
_cod_original_cell_volume        1626.57(19)
_cod_database_code               7039345