The Electronic Nature of Terminal Oxo Ligands in Transition-Metal Complexes: Ambiphilic Reactivity of Oxorhenium Species
Jessica L. Smeltz; Cassandra P. Lilly; Paul D. Boyle; Elon A. Ison; Journal of the American Chemical Society 135 (2013) 9433–9441; doi:10.1021/ja401390v

data_4119964
_publ_section_title
;
 The Electronic Nature of Terminal Oxo Ligands in Transition-Metal
 Complexes: Ambiphilic Reactivity of Oxorhenium Species
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              9433
_journal_page_last               9441
_journal_paper_doi               10.1021/ja401390v
_journal_volume                  135
_journal_year                    2013
_chemical_formula_sum            'C37 H16 B Cl2 F25 N3 O Re'
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_chemical_name_systematic
; 
 ? 
;
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_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.829
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_diffrn_radiation_type           MoK\a
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_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            green
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0356P)^2^+0.5517P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_file            ja401390v_si_001_1.cif
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