Carboxymethylation of Cage Amines: Control of Alkylation by Metal Ion Coordination
Paul S. Donnelly; Jack M. Harrowfield; Brian W. Skelton; Allan H. White; Inorganic Chemistry 39 (2000) 5817–5830; doi:10.1021/ic000346a

data_4321631
_publ_contact_author_address
;
   Department of Chemistry
   University of Western Australia
   Nedlands
   Western Australia 6907
   Australia
;
_publ_contact_author_email       bws@crystal.uwa.edu.au
_publ_contact_author_fax         (+61)_08_9380_1118
_publ_contact_author_name        'Skelton, B. W.'
_publ_contact_author_phone       (+61)_08-9380_3481
_publ_section_title
;
 Carboxymethylation of Cage Amines: Control of Alkylation by Metal Ion
 Coordination
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5817
_journal_page_last               5830
_journal_paper_doi               10.1021/ic000346a
_journal_volume                  39
_journal_year                    2000
_chemical_formula_sum            'C20 H42 Cl2 Cu N8 O7.888'
_chemical_formula_weight         655.26
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_cell_length_c                   19.288(7)
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_cell_measurement_theta_max      28
_cell_measurement_theta_min      2
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_diffrn_measurement_device_type
;
Bruker SMART CCD diffractometer
;
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_diffrn_reflns_theta_min         1.76
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    1.03
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_exptl_absorpt_process_details
;
 SADABS; Sheldrick, 1996
;
_exptl_crystal_colour            blue
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_exptl_crystal_description       plate
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_refine_diff_density_min         -.461
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      calc
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_reflns_d_resolution_high        .73
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_reflns_limit_k_min              0
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_reflns_threshold_expression     'F    > 4.00 sig(F   )'
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_cod_original_sg_symbol_Hall     -p_2yn
_cod_original_formula_sum        'C20 H42 Cl2 Cu1 N8 O7.888'
_cod_database_code               4321631