Bis(triphenylphosphine-κ<i>P</i>)(tropolonato-κ^2^<i>O</i>,<i>O</i>')silver(I) dichloromethane solvate
Steyl, Gideon; Hill, Tania N.; Acta Crystallographica Section E 65 (2009) m233–; doi:10.1107/S1600536809002785

data_2220838
_publ_section_title
;Bis(triphenylphosphine-\k<i>P</i>)(tropolonato-\k^2^<i>O</i>,<i>O</i>')silver(I)
 dichloromethane solvate
;
_journal_coeditor_code           HY2179
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m233
_journal_paper_doi               10.1107/S1600536809002785
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac          '[Ag (C7 H5 O2) (C18 H15 P)2], C H2 Cl2'
_chemical_formula_moiety         'C43 H35 Ag O2 P2, C H2 Cl2'
_chemical_formula_sum            'C44 H37 Ag Cl2 O2 P2'
_chemical_formula_weight         838.45
_chemical_name_systematic
;Bis(triphenylphosphine-\k<i>P</i>)(tropolonato-\k^2^<i>O</i>,<i>O</i>')silver(I)
dichloromethane
 solvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.487(2)
_cell_angle_beta                 93.760(2)
_cell_angle_gamma                116.8090(10)
_cell_formula_units_Z            2
_cell_length_a                   12.0175(3)
_cell_length_b                   12.9925(4)
_cell_length_c                   13.8394(7)
_cell_measurement_reflns_used    9106
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.29
_cell_measurement_theta_min      2.34
_cell_volume                     1869.34(12)
_computing_cell_refinement       'SAINT-Plus (Bruker, 2007)'
_computing_data_collection       'APEX2 (Bruker, 2007)'
_computing_data_reduction        'SAINT-Plus (Bruker, 2007)'
_computing_molecular_graphics    'DIAMOND (Brandenburg & Putz, 1999)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0460
_diffrn_reflns_av_sigmaI/netI    0.0448
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            33544
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         1.81
_exptl_absorpt_coefficient_mu    0.806
_exptl_absorpt_correction_T_max  0.9384
_exptl_absorpt_correction_T_min  0.8620
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2001)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.490
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       cuboid
_exptl_crystal_F_000             856
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.509
_refine_diff_density_min         -0.411
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         8178
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0399
_refine_ls_R_factor_gt           0.0300
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0283P)^2^+0.6452P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0652
_refine_ls_wR_factor_ref         0.0701
_reflns_number_gt                6931
_reflns_number_total             8178
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hy2179.cif
_cod_data_source_block           I
_cod_original_cell_volume        1869.33(12)
_cod_database_code               2220838
_cod_database_fobs_code          2220838