Crystallographic evidence for a continuum and reversal of roles in primary-secondary interactions in antimony Lewis acids: applications in carbonyl activation.
Sharma, Deepti; Benny, Annabel; Gupta, Radhika; Jemmis, Eluvathingal D.; Venugopal, Ajay; Chemical communications (Cambridge, England) 58 (2022) 11009–11012; doi:10.1039/d2cc04027a

data_7130675
_publ_section_title
;
 Crystallographic evidence for a continuum and reversal of roles in
 primary-secondary interactions in antimony Lewis acids: applications in
 carbonyl activation.
;
_journal_issue                   78
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              11009
_journal_page_last               11012
_journal_paper_doi               10.1039/d2cc04027a
_journal_volume                  58
_journal_year                    2022
_chemical_formula_moiety         'C18 H23 Cl N Sb'
_chemical_formula_sum            'C18 H23 Cl N Sb'
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_space_group_crystal_system      monoclinic
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_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2022-08-23 deposited with the CCDC.	2022-09-05 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker KAPPA APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_refine_ls_R_factor_all          0.0325
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0222P)^2^+2.1361P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0566
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           1A
_cod_depositor_comments
'Adding full bibliography for 7130672--7130679.cif.'
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_cod_database_code               7130675
_shelx_shelxl_version_number     2018/3
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_shelx_res_checksum              52324
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