Effective CO<sub>2</sub> and CO Separation Using [M<sub>2</sub>(DOBDC)] (M = Mg, Co, Ni) with Unsaturated Metal Sites and Excavation of Their Adsorption Sites.
Kim, Hyunuk; Sohail, Muhammad; Yim, Kanghoon; Park, Young Cheol; Chun, Dong Hyuk; Kim, Hak Joo; Han, Seong Ok; Moon, Jong-Ho; ACS applied materials & interfaces 11 (2019) 7014–7021; doi:10.1021/acsami.8b20450

data_4514549
_publ_section_title
;
 Effective CO<sub>2</sub> and CO Separation Using [M<sub>2</sub>(DOBDC)]
 (M = Mg, Co, Ni) with Unsaturated Metal Sites and Excavation of Their
 Adsorption Sites.
;
_journal_issue                   7
_journal_name_full               'ACS applied materials &amp; interfaces'
_journal_page_first              7014
_journal_page_last               7021
_journal_paper_doi               10.1021/acsami.8b20450
_journal_volume                  11
_journal_year                    2019
_chemical_formula_sum            'C14 H20.33 Co2 O12.33'
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_space_group_name_Hall           '-R 3'
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_symmetry_space_group_name_Hall  '-R 3'
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_cell_length_b                   26.070(4)
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_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'ADSC Q210 CCD area detector'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_type           synchrotron
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_diffrn_reflns_av_unetI/netI     0.0362
_diffrn_reflns_Laue_measured_fraction_full 0.999
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_diffrn_reflns_theta_min         2.315
_diffrn_source                   'PLSII 2D bending magnet'
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_exptl_absorpt_correction_T_min  0.760
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'HKL3000sm Scalepack (Otwinowski & Minor, 1997)'
_exptl_crystal_colour            purple
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1024P)^2^+32.8268P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_block           r-3_twin
_cod_original_cell_volume        7958(3)
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_shelx_estimated_absorpt_t_min   0.708
_shelx_estimated_absorpt_t_max   0.964
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