Rhodium Complexes Containing a Tridentate Bis(8-quinolyl)methylsilyl Ligand: Synthesis and Reactivity
Sangtrirutnugul, Preeyanuch; Stradiotto, Mark; Tilley, T. Don; Organometallics 25 (2006) 1607–; doi:10.1021/om050859v

data_4074754
_publ_section_title
;
 Rhodium Complexes Containing a Tridentate Bis(8-quinolyl)methylsilyl
 Ligand:&#x00A0; Synthesis and Reactivity
;
_journal_issue                   7
_journal_name_full               Organometallics
_journal_page_first              1607
_journal_paper_doi               10.1021/om050859v
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C25 H24 N5 Rh Si, 2(C F3 O3 S)'
_chemical_formula_sum            'C27 H24 F6 N5 O6 Rh S2 Si'
_chemical_formula_weight         823.62
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_audit_creation_date             'Mon Oct  3 13:44:19 2005'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90.000(1)
_cell_angle_beta                 91.318(1)
_cell_angle_gamma                90.000(1)
_cell_formula_units_Z            4
_cell_length_a                   15.2590(5)
_cell_length_b                   12.4368(3)
_cell_length_c                   17.4895(5)
_cell_measurement_reflns_used    5749
_cell_measurement_temperature    140.2
_cell_measurement_theta_max      24.8
_cell_measurement_theta_min      1.8
_cell_volume                     3318.16(17)
_computing_cell_refinement       'Bruker-AXS SAINT v6.40'
_computing_data_collection       'Bruker-AXS SMART v5.054'
_computing_data_reduction        'Bruker-AXS SAINT v6.40'
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    SIR97
_diffrn_measured_fraction_theta_full 0.9666
_diffrn_measured_fraction_theta_max 0.9666
_diffrn_measurement_device_type  'Bruker SMART 1000'
_diffrn_measurement_method       \w-scans
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.048
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            14834
_diffrn_reflns_theta_full        24.71
_diffrn_reflns_theta_max         24.71
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.757
_exptl_absorpt_correction_T_max  0.930
_exptl_absorpt_correction_T_min  0.750
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.649
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1656.00
_exptl_crystal_size_max          0.260
_exptl_crystal_size_mid          0.210
_exptl_crystal_size_min          0.110
_refine_diff_density_max         0.59
_refine_diff_density_min         -1.47
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.664
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     433
_refine_ls_number_reflns         3357
_refine_ls_R_factor_all          0.0456
_refine_ls_R_factor_gt           0.0456
_refine_ls_shift/su_max          0.0011
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00022|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0472
_refine_ls_wR_factor_ref         0.0472
_reflns_number_gt                3357
_reflns_number_total             5465
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            om050859vsi20051005_011150.cif
_cod_data_source_block           nuch14
_cod_original_cell_volume        3318.2(2)
_cod_original_sg_symbol_H-M      'P 21/a '
_cod_original_formula_sum        'C27 H24 F6 N5 O6 Rh S2 Si '
_cod_database_code               4074754