Synthesis, Physical Properties, and Theoretical Study of R~16~Mo~21~O~56~ Compounds (R = La, Ce, Pr, and Nd) Containing Bioctahedral Mo~10~ Clusters and Single Mo Atoms
Philippe Gall; Régis Gautier; Jean-François Halet; Patrick Gougeon; Inorganic Chemistry 38 (1999) 4455–4461; doi:10.1021/ic981234a

data_4322249
_publ_contact_author_address
;
Laboratoire de Chimie du Solide et Inorganique Mol\'eculaire
URA CNRS No. 1495
Universit\'e de Rennes I
Avenue du G\'en\'eral Leclerc
35042 Rennes CEDEX
France
;
_publ_contact_author_email       Patrick.Gougeon@univ-rennes1.fr
_publ_contact_author_fax         '(33) 2 99 63 57 04'
_publ_contact_author_name        ' Gougeon, P.'
_publ_contact_author_phone       '(33) 2 99 28 62 54'
_publ_section_title
;
 Synthesis, Physical Properties, and Theoretical Study of R~16~Mo~21~O~56~
 Compounds (R = La, Ce, Pr, and Nd) Containing Bioctahedral Mo~10~
 Clusters and Single Mo Atoms
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4455
_journal_page_last               4461
_journal_paper_doi               10.1021/ic981234a
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'La16 Mo21 O56'
_chemical_formula_weight         5133.30
_chemical_name_systematic
; 

 ? 

;
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_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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_refine_ls_R_factor_all          0.0375
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_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0186P)^2^+17.3751P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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