Phase pure Ni3S2 and NiS from bis(N′-ethyl-N-piperazinylcarbodithioato-S,S′)‒nickel(ii) via solvent thermolysis and aerosol assisted chemical vapour deposition
Gervas, Charles; Mlowe, Sixberth; Akerman, Matthew P.; Revaprasadu, Neerish; New Journal of Chemistry 42 (2018) 6203–; doi:10.1039/C8NJ00092A

data_7057110
_publ_section_title
;
 Phase pure Ni3S2 and NiS from
 bis(N&#x2032;-ethyl-N-piperazinylcarbodithioato-S,S&#x2032;)--nickel(ii)
 via solvent thermolysis and aerosol assisted chemical vapour deposition
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              6203
_journal_paper_doi               10.1039/C8NJ00092A
_journal_volume                  42
_journal_year                    2018
_chemical_formula_moiety         'C14 H26 N4 Ni S4'
_chemical_formula_sum            'C14 H26 N4 Ni S4'
_chemical_formula_weight         437.32
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_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-10-12 deposited with the CCDC.
2018-03-06 downloaded from the CCDC.
;
_cell_angle_alpha                84.185(2)
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_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       '\w and \f-scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_theta_max         28.019
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_exptl_crystal_description       needle
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_exptl_crystal_preparation       ', Magnetic properties'
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'Re-crystallisation from solvent: Chloroform'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0218P)^2^+0.2396P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             2259
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7057110.cif.'
_cod_database_code               7057110
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_shelx_estimated_absorpt_t_min   0.844
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