Synthesis, characterization and magnetism of metal-organic compounds: role of the positions of the coordinating groups of a meso-flexible ligand in placing anisotropy to exhibit spin-canting behaviour.
Manna, Paulami; Tripuramallu, Bharat Kumar; Bommakanti, Suresh; Das, Samar K.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 2852–2864; doi:10.1039/c4dt03468f

data_7033337
_publ_section_title
;
 Synthesis, characterization and magnetism of metal-organic compounds:
 role of the positions of the coordinating groups of a meso-flexible
 ligand in placing anisotropy to exhibit spin-canting behaviour.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2852
_journal_page_last               2864
_journal_paper_doi               10.1039/c4dt03468f
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C42 H37 Co N6 O6'
_chemical_formula_sum            'C42 H37 Co N6 O6'
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_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
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_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-07-28 deposited with the CCDC.
2014-12-05 downloaded from the CCDC.
;
_cell_angle_alpha                115.27(3)
_cell_angle_beta                 92.53(3)
_cell_angle_gamma                110.65(3)
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_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
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_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_l_min       -17
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0658P)^2^+0.6782P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt03468f2.cif
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_cod_depositor_comments
'Adding full bibliography for 7033337--7033339.cif.'
_cod_original_cell_volume        1811.1(6)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7033337