Fabrication of Schottky barrier diodes utilizing carboxylate bridged trinuclear mixed valence cobalt(iii/ii/iii) complexes of tetradentate N2O2 donor reduced Schiff base ligands
Bhunia, Sudip; Das, Pubali; Banerjee, Snehasis; Gomila, Rosa M.; Drew, Michael G. B.; Frontera, Antonio; Ray, Partha Pratim; Chattopadhyay, Shouvik; New Journal of Chemistry 47 (2023) 14202–14216; doi:10.1039/D3NJ01829F

data_7062588
_publ_section_title
;
 Fabrication of Schottky barrier diodes utilizing carboxylate bridged
 trinuclear mixed valence cobalt(iii/ii/iii) complexes of tetradentate
 N2O2 donor reduced Schiff base ligands
;
_journal_issue                   30
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              14202
_journal_page_last               14216
_journal_paper_doi               10.1039/D3NJ01829F
_journal_volume                  47
_journal_year                    2023
_chemical_formula_sum            'C46 H65.333 Co3 N4 O14.667'
_chemical_formula_weight         1085.899
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2023-06-15 deposited with the CCDC.	2023-06-20 downloaded from the CCDC.
;
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_cell_volume                     1335.6(2)
_computing_cell_refinement       'SAINT (Bruker, 2000)'
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_computing_molecular_graphics
'Ortep-3 for Windows (Farrugia, 1999) and CAMERON (Watkin et al., 1993)'
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_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker D8 QUEST area detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.997
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_diffrn_reflns_limit_h_max       11
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_diffrn_reflns_point_group_measured_fraction_full 0.997
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0559P)^2^+0.8278P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1010
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_reflns_number_total             4724
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7062588--7062590.cif.'
_cod_database_code               7062588
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