An acylamide metal‒organic framework with an unprecedented four-connecting trinodal topology and amide oxygen coordination
Li, Jian-Qiang; Wu, Xiao-Liu; Liu, Shu-Juan; Luo, Ming-Biao; Acta Crystallographica Section C Structural Chemistry 70 (2014) –; doi:10.1107/S205322961401451X

data_2019613
_publ_section_title
;
 An acylamide metal--organic framework with an unprecedented
 four-connecting trinodal topology and amide oxygen coordination
;
_journal_coeditor_code           BG3173
_journal_issue                   8
_journal_name_full
'Acta Crystallographica Section C Structural Chemistry'
_journal_paper_doi               10.1107/S205322961401451X
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac          '[Zn2 (C8 H4 O4)2 (C27 H24 N6 O3)], H2 O'
_chemical_formula_moiety         'C43 H32 N6 O11 Zn2, H2 O'
_chemical_formula_sum            'C43 H34 N6 O12 Zn2'
_chemical_formula_weight         957.50
_chemical_name_systematic
'Poly[[bis(\m~2~-benzene-1,4-dicarboxylato){\m~4~-<i>N</i>^1^,<i>N</i>^3^,<i>N</i>^5^-tris[(pyridin-3-yl)methyl]benzene-1,3,5-tricarboxamide}dizinc(II)] 0.22-hydrate]'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
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_refine_ls_number_reflns         7130
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_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0476
_refine_ls_R_factor_gt           0.0344
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0449P)^2^+1.2809P] where P=(Fo^2^+2Fc^2^)/3'
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