Asymmetric Catalytic Enantio- and Diastereoselective Boron Conjugate Addition Reactions of α-Functionalized α,β-Unsaturated Carbonyl Substrates.
Xie, Jian-Bo; Lin, Siqi; Qiao, Shuo; Li, Guigen; Organic letters 18 (2016) 3926–3929; doi:10.1021/acs.orglett.6b01998

data_1555674
_publ_section_title
;
 Asymmetric Catalytic Enantio- and Diastereoselective Boron Conjugate
 Addition Reactions of \a-Functionalized \a,\b-Unsaturated Carbonyl
 Substrates.
;
_journal_issue                   15
_journal_name_full               'Organic letters'
_journal_page_first              3926
_journal_page_last               3929
_journal_paper_doi               10.1021/acs.orglett.6b01998
_journal_volume                  18
_journal_year                    2016
_chemical_absolute_configuration ad
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_exptl_absorpt_correction_T_max  0.7456
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;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.3789(13)
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_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0366P)^2^+2.2029P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_database_code               1555674
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