Reductive Coupling of Metal Triangles in Sandwich Complexes
Tetsuro Murahashi; Yasuhiro Hashimoto; Koji Chiyoda; Mayu Fujimoto; Tomohito Uemura; Ryou Inoue; Sensuke Ogoshi; Hideo Kurosawa; Journal of the American Chemical Society 130 (2008) 8586–8587; doi:10.1021/ja802624p

data_4107986
_publ_section_title
;
 Reductive Coupling of Metal Triangles in Sandwich Complexes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              8586
_journal_page_last               8587
_journal_paper_doi               10.1021/ja802624p
_journal_volume                  130
_journal_year                    2008
_chemical_formula_sum            'C28 H41 B2 F8 N3 Pd3'
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_symmetry_cell_setting           monoclinic
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_cell_angle_beta                 95.791(1)
_cell_angle_gamma                90
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_cell_length_c                   22.2397(7)
_cell_measurement_reflns_used    44661
_cell_measurement_temperature    123.2
_cell_measurement_theta_max      30.5
_cell_measurement_theta_min      3.0
_cell_volume                     3462.2(2)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
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_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_theta_max         30.51
_exptl_absorpt_coefficient_mu    1.608
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            red
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_refine_diff_density_max         0.76
_refine_diff_density_min         -0.58
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    noref
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_refine_ls_R_factor_gt           0.0510
_refine_ls_shift/su_max          0.3134
_refine_ls_structure_factor_coef F
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_reflns_number_gt                6280
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_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            ja802624p-file005.cif
_cod_data_source_block           071019-2
_cod_original_formula_sum        'C28 H41 B2 F8 N3 Pd3 '
_cod_database_code               4107986