Coordination polymer complexes of 4,4'-Dipyridyldisulfide and AgX (X=PF6-, C104-,OTs-,NO3-,BF4-) with twisted rhomboid network, 2-D sheet, and 1-D chain structures
Ryo Horikoshi; Tomoyuki Mochida; Noriko Maki; Sachiko Yamada; Hiroshi Moriyama; Journal of the Chemical Society, Dalton Transactions  (2002) 28–33; doi:10.1039/B106032P

data_7702325
_publ_section_title
;
 Coordination polymer complexes of 4,4'-Dipyridyldisulfide and AgX
 (X=PF6-, C104-,OTs-,NO3-,BF4-) with twisted rhomboid network, 2-D sheet,
 and 1-D chain structures
;
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              28
_journal_page_last               33
_journal_paper_doi               10.1039/B106032P
_journal_year                    2002
_chemical_formula_moiety         'C10 H8 Ag Cl N2 O2 S2 '
_chemical_formula_sum            'C20 H16 Ag Cl N4 O4 S4'
_chemical_formula_weight         647.93
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 92.29(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.739(3)
_cell_length_b                   19.527(1)
_cell_length_c                   11.208(1)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.8
_cell_volume                     2348.4(7)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SHELXS97
_diffrn_measured_fraction_theta_full 1.0403
_diffrn_measured_fraction_theta_max 1.0403
_diffrn_measurement_device_type  'Rigaku AFC5S'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.040
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            2929
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_standards_decay_%        0.65
_diffrn_standards_interval_count 300
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.362
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.952
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.832
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.500
_exptl_crystal_size_min          0.300
_refine_diff_density_max         0.60
_refine_diff_density_min         -0.72
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.530
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     155
_refine_ls_number_reflns         2847
_refine_ls_R_factor_gt           0.0298
_refine_ls_shift/su_max          0.0005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1059
_reflns_number_gt                2554
_reflns_number_total             2816
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b106032p.cif
_cod_data_source_block           compound_2
_cod_original_formula_sum        'C20 H16 Ag Cl N4 O4 S4 '
_cod_database_code               7702325