Synthesis of trifluoromethyl γ-aminophosphonates by nucleophilic aziridine ring opening.
Cytlak, T.; Saweliew, M.; Kubicki, M.; Koroniak, H.; Organic & biomolecular chemistry 13 (2015) 10050–10059; doi:10.1039/c5ob01411e

data_7154640
_publ_section_title
;
 Synthesis of trifluoromethyl \g-aminophosphonates by nucleophilic
 aziridine ring opening.
;
_journal_issue                   39
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              10050
_journal_page_last               10059
_journal_paper_doi               10.1039/c5ob01411e
_journal_volume                  13
_journal_year                    2015
_chemical_formula_sum            'C21 H27 F3 N O4 P S'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2014-03-09 deposited with the CCDC.
2015-08-13 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'SuperNova, Single source at offset), Atlas'
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_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.988
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.21t (release 14-08-2012 CrysAlis171 .NET)
(compiled Aug 14 2012,18:12:40)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_number_reflns         4918
_refine_ls_number_restraints     2
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0762P)^2^+0.8478P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1367
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                4091
_reflns_number_total             4918
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5ob01411e2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7154640--7154641.cif.'
_cod_database_code               7154640
_shelxl_version_number           2013-4
_shelx_res_checksum              82382