Synthesis and structural characterization of one- and two-dimensional coordination polymers based on platinum-silver metallic backbones.
Liu, Fenghui; Chen, Wanzhi; Wang, Daqi; Dalton transactions (Cambridge, England : 2003)  (2006) 3015–3024; doi:10.1039/b514757c

data_7006847
_publ_section_title
;
 Synthesis and structural characterization of one- and two-dimensional
 coordination polymers based on platinum-silver metallic backbones.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3015
_journal_page_last               3024
_journal_paper_doi               10.1039/b514757c
_journal_year                    2006
_chemical_formula_sum            'C10 H28 Ag Cl N4 O7 Pt'
_chemical_formula_weight         654.77
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.550(11)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.753(14)
_cell_length_b                   11.156(9)
_cell_length_c                   11.221(9)
_cell_measurement_temperature    293(2)
_cell_volume                     2062(3)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.818
_diffrn_measured_fraction_theta_max 0.818
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0535
_diffrn_reflns_av_sigmaI/netI    0.0752
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            5205
_diffrn_reflns_theta_full        23.75
_diffrn_reflns_theta_max         23.75
_diffrn_reflns_theta_min         4.73
_exptl_absorpt_coefficient_mu    7.892
_exptl_absorpt_correction_T_max  0.4510
_exptl_absorpt_correction_T_min  0.1534
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.110
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1256
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.12
_refine_diff_density_max         5.628
_refine_diff_density_min         -2.221
_refine_diff_density_rms         0.358
_refine_ls_extinction_coef       0.0013(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.080
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     254
_refine_ls_number_reflns         2578
_refine_ls_number_restraints     230
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.1024
_refine_ls_R_factor_gt           0.0870
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1855P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2470
_refine_ls_wR_factor_ref         0.2613
_reflns_number_gt                1876
_reflns_number_total             2578
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b514757c.txt
_cod_data_source_block           ag
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7006847