Phosphido pincer complexes of platinum: synthesis, structure and reactivity.
Mazzeo, Mina; Strianese, Maria; Kühl, Olaf; Peters, Jonas C.; Dalton transactions (Cambridge, England : 2003) 40 (2011) 9026–9033; doi:10.1039/c1dt10825e

data_7016545
_publ_section_title
;
 Phosphido pincer complexes of platinum: synthesis, structure and
 reactivity.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9026
_journal_page_last               9033
_journal_paper_doi               10.1039/c1dt10825e
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C24 H36 Cl P3 Pt'
_chemical_formula_sum            'C24 H36 Cl P3 Pt'
_chemical_formula_weight         647.98
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.196(17)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   11.612(2)
_cell_length_b                   14.046(2)
_cell_length_c                   30.941(5)
_cell_measurement_reflns_used    21280
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      36.17
_cell_measurement_theta_min      1.59
_cell_volume                     5042.8(14)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.879
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0712
_diffrn_reflns_av_sigmaI/netI    0.0626
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       46
_diffrn_reflns_limit_l_min       -41
_diffrn_reflns_number            89412
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         36.17
_diffrn_reflns_theta_min         1.59
_exptl_absorpt_coefficient_mu    5.871
_exptl_absorpt_correction_T_max  0.375
_exptl_absorpt_correction_T_min  0.248
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing 1995'
_exptl_crystal_density_diffrn    1.707
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2560
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.17
_refine_diff_density_max         3.982
_refine_diff_density_min         -6.829
_refine_diff_density_rms         0.257
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.504
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     539
_refine_ls_number_reflns         21280
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.504
_refine_ls_R_factor_all          0.0792
_refine_ls_R_factor_gt           0.0551
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0881
_refine_ls_wR_factor_ref         0.0925
_reflns_number_gt                15846
_reflns_number_total             21280
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt10825e.txt
_cod_data_source_block           mm2ct
_cod_original_cell_volume        5042.7(14)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7016545