Dichlorido(4-methylaniline-κ<i>N</i>)[<i>N</i>-(4-methylphenyl)-1-(thiophen-2-yl)methanimine-κ<i>N</i>]palladium(II)
Butcher, Ray J.; Singh, Puspendra; Shabbani, Gulam; Acta Crystallographica Section E 78 (2022) 1–0; doi:10.1107/S2056989022004960

data_2244098
_publ_section_title
;
 Dichlorido(4-methylaniline-\k<i>N</i>)[<i>N</i>-(4-methylphenyl)-1-(thiophen-2-yl)methanimine-\k<i>N</i>]palladium(II)
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_journal_coeditor_code           TX2049
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              1
_journal_page_last               0
_journal_paper_doi               10.1107/S2056989022004960
_journal_volume                  78
_journal_year                    2022
_chemical_formula_iupac          '[Pd Cl2 (C7 H9 N1) (C12 H11 N1 S1)]'
_chemical_formula_moiety         'C19 H20 Cl2 N2 Pd S'
_chemical_formula_sum            'C19 H20 Cl2 N2 Pd S'
_chemical_formula_weight         485.73
_chemical_name_systematic
Dichlorido(4-methylaniline-\k<i>N</i>)[<i>N</i>-(4-methylphenyl)-1-(thiophen-2-yl)methanimine-\k<i>N</i>]palladium(II)
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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_cell_measurement_theta_max      31.60
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;
SAINT (Bruker, 2002)
;
_computing_data_collection
;
APEX2 (Bruker, 2005)
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SAINT (Bruker, 2002)
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SHELXTL (Sheldrick, 2008)
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SHELXTL (Sheldrick, 2008)
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<i>SHELXL2018/3</i> (Sheldrick, 2015b)
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SHELXT (Sheldrick, 2015a)
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_diffrn_reflns_limit_l_min       -19
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_diffrn_reflns_theta_max         33.228
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_exptl_absorpt_process_details
;
(SADABS; Krause <i>et al.</i>,  2015)
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_exptl_crystal_colour            red-orange
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0211P)^2^+0.1526P] where P=(Fo^2^+2Fc^2^)/3'
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_refine_ls_wR_factor_ref         0.0897
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_reflns_threshold_expression     'I > 2\s(I)'
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