Intramolecular Schmidt reaction of acyl chlorides with alkyl azides: preparation of pyrrolizine by intramolecular capture of intermediates with alkenes or alkynes.
Wang, Bao-Juan; Xue, Ping; Gu, Peiming; Chemical communications (Cambridge, England) 51 (2015) 2277–2279; doi:10.1039/c4cc07166b

data_7116270
_publ_section_title
;
 Intramolecular Schmidt reaction of acyl chlorides with alkyl azides:
 preparation of pyrrolizine by intramolecular capture of intermediates
 with alkenes or alkynes.
;
_journal_issue                   12
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              2277
_journal_page_last               2279
_journal_paper_doi               10.1039/c4cc07166b
_journal_volume                  51
_journal_year                    2015
_chemical_formula_moiety         'C14 H15 N O'
_chemical_formula_sum            'C14 H15 N O'
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2014-08-26 deposited with the CCDC.
2014-12-16 downloaded from the CCDC.
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Superflip (Palatinus & Chapuis, 2007;Palatinus & van der Lee, 2008;
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Empirical absorption correction using spherical harmonics,
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
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2.a Ternary CH refined with riding coordinates:
 C4(H4)
2.b Secondary CH2 refined with riding coordinates:
 C5(H5A,H5B), C1(H1A,H1B), C3(H3A,H3B), C2(H2A,H2B)
2.c Aromatic/amide H refined with riding coordinates:
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;
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