Crystal structure of a seven-coordinate manganese(II) complex with tris(pyridin-2-ylmethyl)amine (TMPA)
Frey, Steven T.; Ramirez, Hillary A.; Kaur, Manpreet; Jasinski, Jerry P.; Acta Crystallographica Section E 74 (2018) 1075–1078; doi:10.1107/S2056989018009611

data_2242555
_publ_section_title
;
 Crystal structure of a seven-coordinate manganese(II) complex with
 tris(pyridin-2-ylmethyl)amine (TMPA)
;
_journal_coeditor_code           TX2006
_journal_issue                   8
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              1075
_journal_page_last               1078
_journal_paper_doi               10.1107/S2056989018009611
_journal_volume                  74
_journal_year                    2018
_chemical_formula_iupac
'[Mn (C2 H3 O2) (C18 H18 N4) (C H4 O)] (C24 H20 B)'
_chemical_formula_moiety         'C21 H25 Mn N4 O3 +, C24 H20 B -'
_chemical_formula_sum            'C45 H45 B Mn N4 O3'
_chemical_formula_weight         755.60
_chemical_name_systematic
;(Acetato-\k^2^<i>O</i>,<i>O</i>')(methanol-\k<i>O</i>)[tris(pyridin-2-ylmethyl)amine-\k^4^<i>N</i>,<i>N</i>',<i>N</i>'',<i>N</i>''']manganese(II)
tetraphenylborate
;
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Olex2 1.2
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CrysAlis PRO (Agilent, 2014)
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CrysAlis PRO (Agilent, 2014)
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CrysAlis PRO (Agilent, 2014)
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<i>OLEX2</i> (Dolomanov et al., 2009)
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<i>OLEX2</i> (Dolomanov et al., 2009)
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SHELXL2014 (Sheldrick, 2015b)
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SHELXT (Sheldrick, 2015a)
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;
(CrysAlis PRO; Agilent, 2014)
;
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'w=1/[\s^2^(Fo^2^)+(0.0476P)^2^+0.5222P] where P=(Fo^2^+2Fc^2^)/3'
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