<i>catena</i>-Poly[[(acetonitrile-κ<i>N</i>)silver(I)]-di-μ-trifluoromethanesulfonato-κ^4^<i>O</i>:<i>O</i>'-[(acetonitrile-κ<i>N</i>)silver(I)]-μ-tetraphenyldiphosphine-κ^2^<i>P</i>:<i>P</i>']
Carson, Cody E.; Feazell, Rodney P.; Klausmeyer, Kevin K.; Acta Crystallographica Section E 63 (2007) m2395–m2395; doi:10.1107/S1600536807040597

data_2214970
_publ_section_title
<i>catena</i>-Poly[[(acetonitrile-\k<i>N</i>)silver(I)]-di-\m-trifluoromethanesulfonato-\k^4^<i>O</i>:<i>O</i>'-[(acetonitrile-\k<i>N</i>)silver(I)]-\m-tetraphenyldiphosphine-\k^2^<i>P</i>:<i>P</i>']
_journal_coeditor_code           BH2125
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2395
_journal_page_last               m2395
_journal_paper_doi               10.1107/S1600536807040597
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ag2 (C F3 S O3)2 (C28 H26 N2 P2)]'
_chemical_formula_moiety         'C15 H13 Ag F3 N O3 P S'
_chemical_formula_sum            'C15 H13 Ag F3 N O3 P S'
_chemical_formula_weight         483.16
_chemical_name_systematic
;
<i>catena</i>-Poly[[(acetonitrile-\kN)silver(I)]-di-\m-
trifluoromethanesulfonato-\k^4^O:O'-[(acetonitrile-\kN)silver(I)]-\m-
tetraphenyldiphosphine-\k^2^P:P']
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.5990(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.1128(2)
_cell_length_b                   17.4753(3)
_cell_length_c                   10.5053(2)
_cell_measurement_reflns_used    8448
_cell_measurement_temperature    105(2)
_cell_measurement_theta_max      27.99
_cell_measurement_theta_min      2.33
_cell_volume                     1811.84(6)
_computing_cell_refinement       'APEX2 (Bruker, 2003)'
_computing_data_collection       'APEX2 (Bruker, 2003)'
_computing_data_reduction        'SAINT-Plus (Bruker, 2003)'
_computing_molecular_graphics    'SHELXTL (Bruker, 2003)'
_computing_publication_material  'SHELXTL (Bruker, 2003)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      105(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker X8 APEX'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0302
_diffrn_reflns_av_sigmaI/netI    0.0200
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            28681
_diffrn_reflns_theta_full        28.33
_diffrn_reflns_theta_max         28.33
_diffrn_reflns_theta_min         2.33
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.359
_exptl_absorpt_correction_T_max  0.873
_exptl_absorpt_correction_T_min  0.760
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.771
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             956
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.167
_exptl_crystal_size_min          0.098
_refine_diff_density_max         1.469
_refine_diff_density_min         -0.228
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     227
_refine_ls_number_reflns         4502
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0527
_refine_ls_R_factor_gt           0.0396
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0619P)^2^+1.0373P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1025
_refine_ls_wR_factor_ref         0.1121
_reflns_number_gt                3588
_reflns_number_total             4502
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            bh2125.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2214970
_cod_database_fobs_code          2214970