Crystal growth of novel 3D skeleton uranyl germanium complexes: influence of synthetic conditions on crystal structures.
Li, Haijian; Kegler, Philip; Alekseev, Evgeny V.; Dalton transactions (Cambridge, England : 2003) 49 (2020) 2244–2257; doi:10.1039/c9dt04750f

data_7703366
_publ_section_title
;
 Crystal growth of novel 3D skeleton uranyl germanium complexes: influence
 of synthetic conditions on crystal structures.
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2244
_journal_page_last               2257
_journal_paper_doi               10.1039/c9dt04750f
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'Ge2 O14 Rb2 U3'
_chemical_formula_weight         1254.21
_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_Hall           '-P 2ac 2n'
_space_group_name_H-M_alt        'P n m a'
_audit_creation_method           SHELXL-2018/1
_audit_update_record
;
2019-12-05 deposited with the CCDC.	2020-01-24 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean '\w scans'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  graphite
_diffrn_measurement_method       'SuperNova, Dual, Cu at zero, Eos'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0276
_diffrn_reflns_Laue_measured_fraction_full 0.999
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_diffrn_reflns_limit_h_max       13
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_reflns_theta_max         28.276
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_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    50.395
_exptl_absorpt_correction_T_max  0
_exptl_absorpt_correction_T_min  0
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Green
_exptl_crystal_density_diffrn    6.547
_exptl_crystal_description       Column
_exptl_crystal_F_000             2104
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_exptl_crystal_size_mid          0.200
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_refine_diff_density_max         1.538
_refine_diff_density_min         -1.155
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_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0144P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0358
_refine_ls_wR_factor_ref         0.0374
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1504
_reflns_number_total             1697
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt04750f2.cif
_cod_data_source_block           Rb2(UO2)3(GeO4)2
_cod_depositor_comments
'Adding full bibliography for 7703362--7703366.cif.'
_cod_original_cell_volume        1272.46(7)
_cod_database_code               7703366
_shelx_shelxl_version_number     2018/1
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_shelx_res_checksum              42987