Prototypical Phosphine Complexes of Antimony(III).
Chitnis, Saurabh S.; Burford, Neil; McDonald, Robert; Ferguson, Michael J.; Inorganic chemistry 53 (2014) 5359–5372; doi:10.1021/ic500723y

data_4338245
_publ_section_title
;
 Prototypical Phosphine Complexes of Antimony(III).
;
_journal_issue                   10
_journal_name_full               'Inorganic chemistry'
_journal_page_first              5359
_journal_page_last               5372
_journal_paper_doi               10.1021/ic500723y
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety         'C12 H18 Mg N6, 2(C3 H9 Cl4 P Sb)'
_chemical_formula_sum            'C18 H36 Cl8 Mg N6 P2 Sb2'
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_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           19
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_number            34105
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_diffrn_reflns_theta_min         1.27
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_exptl_absorpt_correction_T_min  0.5453
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            colourless
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       fragment
_exptl_crystal_F_000             1864
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_R_factor_all          0.0423
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_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0322P)^2^+2.6236P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0768
_refine_ls_wR_factor_ref         0.0797
_reflns_number_gt                8153
_reflns_number_total             8876
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            ic500723y_si_013.cif
_cod_data_source_block           vic1273
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4338238--4338252.cif.
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_cod_original_cell_volume        3870.7(9)
_cod_database_code               4338245