Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex
David M. Jenkins; Theodore A. Betley; Jonas C. Peters; Journal of the American Chemical Society 124 (2002) 11238–11239; doi:10.1021/ja026852b

data_4115167
_publ_section_title
;
 Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido
 Complex
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11238
_journal_page_last               11239
_journal_paper_doi               10.1021/ja026852b
_journal_volume                  124
_journal_year                    2002
_chemical_formula_sum            'C53 H47 B Co O2 P3'
_chemical_formula_weight         878.56
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           88
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
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_cell_length_a                   37.276(5)
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_cell_length_c                   12.423(2)
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_cell_measurement_temperature    98(2)
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_cell_measurement_theta_min      2.31
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_computing_cell_refinement       'Bruker SAINT v6.022'
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_diffrn_ambient_temperature      98(2)
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_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_device_type  'Bruker SMART 1000'
_diffrn_measurement_method       '\w scans at 5 \f settings'
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_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_min         1.55
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_exptl_absorpt_correction_T_max  0.9603
_exptl_absorpt_correction_T_min  0.8873
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     w=1/s^2^(Fo^2^)
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_gt          0.0970
_refine_ls_wR_factor_ref         0.1072
_reflns_number_gt                4979
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_cod_data_source_file            ja026852b_s3_3.cif
_cod_data_source_block           dmj10
_cod_depositor_comments
;
The following automatic conversions were performed:

'_atom_sites_solution_primary' value 'direct methods' was changed to
'direct'.

'_atom_sites_solution_secondary' value 'Difference Fourier map' was
changed to 'difmap'.

'_atom_sites_solution_hydrogens' value 'Geometric positions' was
changed to 'geom'.

Automatic conversion script
Id: cif_fix_values 6452 2018-10-05 10:23:21Z andrius 
;
_cod_original_cell_volume        17261(5)
_cod_original_sg_symbol_H-M      'I 41/a'
_cod_database_code               4115167