Highly selective synthesis of substituted (E)-alkenylsilatranes via catalytic trans-silylation and mechanistic implications.
Sztorch, Bogna; Frąckowiak, Dawid; Pyziak, Jadwiga; Czapik, Agnieszka; Hoffmann, Marcin; Marciniec, Bogdan; Dalton transactions (Cambridge, England : 2003) 46 (2017) 4975–4981; doi:10.1039/c7dt00201g

data_7042514
_publ_section_title
;
 Highly selective synthesis of substituted (E)-alkenylsilatranes via
 catalytic trans-silylation and mechanistic implications.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4975
_journal_page_last               4981
_journal_paper_doi               10.1039/c7dt00201g
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C43 H42 Cl N O4 P2 Ru Si'
_chemical_formula_sum            'C43 H42 Cl N O4 P2 Ru Si'
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_space_group_name_Hall           '-P 1'
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;
2016-12-22 deposited with the CCDC.
2017-03-16 downloaded from the CCDC.
;
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;
CrysAlisPro 1.171.38.43 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0375P)^2^+1.3546P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7042512--7042514.cif.'
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_shelx_shelxl_version_number     2014/7
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