Mixing and matching <i>N</i>,<i>N</i>- and <i>N</i>,<i>O</i>-chelates in anionic Mg(I) compounds: synthesis and reactivity with RNCNR and CO.
O'Reilly, Andrea; Haynes, Matthew D.; Turner, Zoë R; McMullin, Claire L.; Harder, Sjoerd; O'Hare, Dermot; Fulton, J. Robin; Coles, Martyn P.; Chemical communications (Cambridge, England) 60 (2024) 7204–7207; doi:10.1039/d4cc02594f

data_7133228
_publ_section_title
;
 Mixing and matching <i>N</i>,<i>N</i>- and <i>N</i>,<i>O</i>-chelates in
 anionic Mg(I) compounds: synthesis and reactivity with
 RN&#xe001;C&#xe001;NR and CO.
;
_journal_issue                   56
_journal_name_full               'Chemical communications (Cambridge, England)'
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_journal_paper_doi               10.1039/d4cc02594f
_journal_volume                  60
_journal_year                    2024
_chemical_formula_moiety         'C66  H112  N4  O6  Mg2  Si4  K2'
_chemical_formula_sum            'C66 H112 K2 Mg2 N4 O6 Si4'
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;
2024-06-14 deposited with the CCDC.	2024-06-16 downloaded from the CCDC.
;
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'CrysAlisPro convention (1999,Acta A55,543-557)'
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_source                   'micro-focus sealed X-ray tube'
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;
        CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
        Numerical absorption correction based on gaussian integration over
                        a multifaceted crystal model
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.179
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
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_exptl_crystal_size_max          0.263
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1099P)^2^+7.6776P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7133226--7133229.cif.'
_cod_original_cell_volume        3653.35(17)
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