Highly Efficient and Selective Hydrogenation of Aldehydes: A Well-Defined Fe(II) Catalyst Exhibits Noble-Metal Activity.
Gorgas, Nikolaus; Stöger, Berthold; Veiros, Luis F.; Kirchner, Karl; ACS catalysis 6 (2016) 2664–2672; doi:10.1021/acscatal.6b00436

data_4513854
_publ_section_title
;
 Highly Efficient and Selective Hydrogenation of Aldehydes: A Well-Defined
 Fe(II) Catalyst Exhibits Noble-Metal Activity.
;
_journal_issue                   4
_journal_name_full               'ACS catalysis'
_journal_page_first              2664
_journal_page_last               2672
_journal_paper_doi               10.1021/acscatal.6b00436
_journal_volume                  6
_journal_year                    2016
_chemical_formula_sum            'C20 H39 Fe N3 O P2'
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_chemical_name_systematic        ' ?'
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_diffrn_reflns_theta_max         35.02
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_exptl_absorpt_coefficient_mu    0.807
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_exptl_absorpt_correction_T_min  0.71
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
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_exptl_crystal_description       plate
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_refine_ls_hydrogen_treatment    mixed
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_refine_ls_shift/su_max          0.0217
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     w=1/(\s^2^(F)+0.0001F^2^)
_refine_ls_weighting_scheme      sigma
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_refine_ls_wR_factor_ref         0.0406
_reflns_number_gt                7395
_reflns_number_total             10156
_reflns_threshold_expression     I>3\s(I)
_cod_data_source_file            cs6b00436_si_002.cif
_cod_data_source_block           Fe_PNP_CO_H2
_cod_depositor_comments
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The following automatic conversions were performed:

'_diffrn_radiation_probe' value 'X-ray' changed to 'x-ray' according
to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 4513853--4513854.cif.

 Adding full bibliography for 4513853--4513854.cif.
;
_cod_original_sg_symbol_Hall     '-P 2ycb'
_cod_original_formula_sum        'C20 H39 Fe1 N3 O1 P2'
_cod_database_code               4513854