Catalyst-free insertion of carbon monoxide into terminal Mg-C(sp3) bonds
Kubisz, Malte; Hadlington, Terrance John; Fernandez, Israel; Chemical Communications  (2026) –; doi:10.1039/D6CC00736H

data_7135599
_publ_section_title
;
 Catalyst-free insertion of carbon monoxide into terminal
 Mg-C(sp<sup>3</sup>) bonds.
;
_journal_issue                   29
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              7519
_journal_page_last               7523
_journal_paper_doi               10.1039/d6cc00736h
_journal_volume                  62
_journal_year                    2026
_chemical_formula_moiety         'C40 H72 Mg N O P Si, 0.5(C8 H10)'
_chemical_formula_sum            'C44 H77 Mg N O P Si'
_chemical_formula_weight         719.43
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_audit_update_record
;
2026-02-03 deposited with the CCDC.	2026-03-09 downloaded from the CCDC.
;
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_diffrn_radiation_type           'Mo K\a'
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_diffrn_source                   'Genix 3D HF Mo'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'STOE X-AREA 1.76'
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0759P)^2^+1.0197P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                7786
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7135594--7135603.cif.'
_cod_database_code               7135599
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