An indenide-tethered N-heterocyclic stannylene
Bischof, Tobias; Evans, Kieren J.; Haddow, Mairi F.; Mansell, Stephen M.; Acta Crystallographica Section E 76 (2020) 254–256; doi:10.1107/S205698902000047X

data_2243260
_publ_section_title
;
 An indenide-tethered N-heterocyclic stannylene
;
_journal_coeditor_code           FF2165
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              254
_journal_page_last               256
_journal_paper_doi               10.1107/S205698902000047X
_journal_volume                  76
_journal_year                    2020
_chemical_formula_iupac          '[Li Sn (C8 H16 O4) (C25 H32 N2)]'
_chemical_formula_moiety         'C33 H47 Li N2 O4 Sn'
_chemical_formula_sum            'C33 H47 Li N2 O4 Sn'
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_chemical_name_systematic
;
(\m-1\k<i>N</i>:2(\h^2^),\k^2^<i>N</i>,<i>N</i>'-(2-{[2,6-Bis(propan-2-yl)\
phenyl]azanidyl}ethyl)[2-(1<i>H</i>-inden-1-yl)ethyl]azanido)(1,4,7,10,13,16-\
hexaoxacyclooctadecane-1\k^6^<i>O</i>)lithiumtin
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
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Olex2 1.2
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SAINT (Bruker, 2013)
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APEX2 (Bruker, 2013)
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SAINT (Bruker, 2013)
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<i>OLEX2</i> (Dolomanov <i>et al.</i>,  2009)
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<i>OLEX2</i> (Dolomanov <i>et al.</i>,  2009)
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SHELXL (Sheldrick, 2015b)
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SHELXT (Sheldrick, 2015a)
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;
(SADABS; Bruker, 2015)
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_exptl_crystal_colour            'Pale yellow'
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_refine_ls_extinction_method     none
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_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0811
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0367P)^2^+2.6456P] where P=(Fo^2^+2Fc^2^)/3'
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