Asymmetric diosmium sawhorse complexes
Wilson, Kylie M.; Swartout, John W.; Touchton, Henry A.; Lambert, Erica N.; Johnstone, James E.; Archambeau, Ashley K.; Marolf, David M.; Mikeska, Emily R.; Lynch, Vincent M.; Nesterov, Vladimir N.; Reinheimer, Eric W.; Powell, Gregory L.; Powell, Cynthia B.; Acta Crystallographica Section C 75 (2019) 529–537; doi:10.1107/S2053229619004236

data_2021585
_publ_section_title
;
 Asymmetric diosmium sawhorse complexes
;
_journal_coeditor_code           YP3178
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              529
_journal_page_last               537
_journal_paper_doi               10.1107/S2053229619004236
_journal_volume                  75
_journal_year                    2019
_chemical_formula_iupac          '[Os2 (C3 H5 O2)2 (C21 H21 P1) (C O)5]'
_chemical_formula_moiety         'C32 H31 O9 Os2 P'
_chemical_formula_sum            'C32 H31 O9 Os2 P'
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Pentacarbonyl-1\k^2^<i>C</i>,2\k^3^<i>C</i>-bis(\m-propanoato-1\k<i>O</i>:2\k<i>O</i>')[tris(4-methylphenyl)phosphane-1\k<i>P</i>]diosmium(<i>Os</i>---<i>Os</i>)
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_space_group_name_Hall           '-P 1'
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Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
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CrysAlis PRO (Rigaku OD, 2015)
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CrysAlis PRO (Rigaku OD, 2015)
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CrysAlis PRO (Rigaku OD, 2015)
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<i>OLEX2</i> (Dolomanov <i>et al.</i>, 2009)
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<i>OLEX2</i> (Dolomanov <i>et al.</i>, 2009)
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SHELXL2018 (Sheldrick, 2015b)
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SHELXT (Sheldrick, 2015a)
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CrysAlisPro (Rigaku OD, 2015)
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'w=1/[\s^2^(Fo^2^)+(0.0202P)^2^+1.4592P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 2021580--2021587.cif.'
_cod_original_cell_volume        1614.12(6)
_cod_database_code               2021585
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_shelx_estimated_absorpt_t_min   0.140
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