Ti(II) and Rh(I) Complexes as Reagents toward a Thapsigargin Core.
Sanogo, Youssouf; Othman, Raja Ben; Dhambri, Sabrina; Selkti, Mohamed; Jeuken, Alan; Prunet, Joëlle; Férézou, Jean-Pierre; Ardisson, Janick; Lannou, Marie-Isabelle; Sorin, Geoffroy; The Journal of organic chemistry 84 (2019) 5821–5830; doi:10.1021/acs.joc.8b03249

data_4034343
_publ_section_title
;
 Ti(II) and Rh(I) Complexes as Reagents toward a Thapsigargin Core.
;
_journal_issue                   9
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              5821
_journal_page_last               5830
_journal_paper_doi               10.1021/acs.joc.8b03249
_journal_volume                  84
_journal_year                    2019
_chemical_formula_moiety         'C19 H24 O5'
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'Rigaku confocal double bounce MaxFlux multilayer'
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_diffrn_source                   'microfocus sealed X-ray tube'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.32e (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'pale yellow'
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_refine_ls_extinction_method     none
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_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0642
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0778P)^2^+0.0586P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1317
_refine_ls_wR_factor_ref         0.1430
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3579
_reflns_number_total             4746
_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_shelxl_version_number     2016/6
_shelx_res_checksum              96565
_shelx_hkl_checksum              95817