Challenging conventional f-element separation chemistry - reversing uranyl(VI)/lanthanide(III) solvent extraction selectivity
C. A. Hawkins; C. G. Bustillos; R. Copping; B. L. Scott; I. May; M. Nilsson; Chem.Commun. 50 (2014) 8670–; doi:10.1039/C4cc03031A

data_7115360
_publ_section_title
;
 Challenging conventional f-element separation chemistry - reversing
 uranyl(VI)/lanthanide(III) solvent extraction selectivity
;
_journal_name_full               Chem.Commun.
_journal_page_first              8670
_journal_paper_doi               10.1039/C4cc03031A
_journal_volume                  50
_journal_year                    2014
_chemical_formula_sum            'C16 H32 N2 Na2 O20 S2 U'
_chemical_formula_weight         920.57
_chemical_name_systematic
; 
 ? 
;
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_cell_angle_gamma                72.240(1)
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_cell_length_b                   9.3646(12)
_cell_length_c                   19.946(3)
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_computing_data_collection       'APEX II, v. 7.0 (Bruker AXS, 2009)'
_computing_data_reduction        'SAINT+, v. 7.66a (Bruker AXS, 2009)'
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_diffrn_ambient_temperature      140(1)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.914
_diffrn_measurement_device_type  'Bruker D8 with APEXII CCD'
_diffrn_measurement_method       '\w scans'
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_exptl_crystal_colour            orange
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0244P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_file            c4cc03031a2.cif
_cod_data_source_block           apx1733
_cod_original_cell_volume        1497.6(3)
_cod_database_code               7115360