Rhodium-complex-catalyzed addition reactions of chloroacetyl chlorides to alkynes.
Kashiwabara, Taigo; Fuse, Kouichiro; Hua, Ruimao; Tanaka, Masato; Organic letters 10 (2008) 5469–5472; doi:10.1021/ol802260w

data_1504967
_publ_section_title
;
 Rhodium-complex-catalyzed addition reactions of chloroacetyl chlorides to
 alkynes.
;
_journal_issue                   23
_journal_name_full               'Organic letters'
_journal_page_first              5469
_journal_page_last               5472
_journal_paper_doi               10.1021/ol802260w
_journal_volume                  10
_journal_year                    2008
_chemical_formula_moiety         'C10 H8 Cl2 O '
_chemical_formula_sum            'C10 H8 Cl2 O'
_chemical_formula_weight         215.08
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 98.276(12)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   3.910(4)
_cell_length_b                   24.54(2)
_cell_length_c                   9.892(9)
_cell_measurement_reflns_used    2873
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.2
_cell_volume                     939.3(15)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.023
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -3
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            6476
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.641
_exptl_absorpt_correction_T_max  0.880
_exptl_absorpt_correction_T_min  0.753
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.521
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             440.00
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
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_refine_diff_density_min         -0.28
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    refall
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[0.0009Fo^2^ + 1.0000\s(Fo^2^)]'
_refine_ls_weighting_scheme      calc
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_cod_data_source_block           '__(Z)-3aI'
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_cod_original_formula_sum        'C10 H8 Cl2 O '
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