Synthesis, properties and structures of complexes of platinum metal halides and Group 11 metals with two distibinomethane ligands, R2SbCH2SbR2 (R = Me or Ph)
Even, Tina; Genge, Anthony R. J.; Hill, Angela M.; Holmes, Nicholas J.; Levason, William; Webster, Michael; Journal of the Chemical Society, Dalton Transactions  (2000) 655–; doi:10.1039/a908296d

data_7009037
_publ_section_title
;
 Synthesis, properties and structures of complexes of platinum metal
 halides and Group 11 metals with two distibinomethane ligands,
 R2SbCH2SbR2 (R&#x2005;=&#x2005;Me or Ph)
;
_journal_issue                   5
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              655
_journal_paper_doi               10.1039/a908296d
_journal_year                    2000
_chemical_formula_moiety         'C50 H44 Br4 Pd2 Sb4, 2(C1 H2 Cl2)'
_chemical_formula_sum            'C52 H48 Br4 Cl4 Pd2 Sb4'
_chemical_formula_weight         1834.18
_chemical_name_systematic
; 
 Tetrabromodi(\m-bisdiphenylstibinomethane)dipalladium(II).2dichloromethane
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
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_audit_creation_date             1999-09-21
_audit_creation_method           'teXsan v. 1.8'
_audit_update_record
;
?
;
_cell_angle_alpha                109.18(2)
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_cell_angle_gamma                79.65(2)
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_cell_length_a                   15.953(5)
_cell_length_b                   17.000(4)
_cell_length_c                   11.943(3)
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_cell_measurement_temperature    150
_cell_measurement_theta_max      8.1
_cell_measurement_theta_min      7.0
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_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
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_computing_structure_solution
;
DIRDIF92 PATTY (Beurskens, 1992)
;
_diffrn_ambient_temperature      150
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_diffrn_measurement_method       \w-2\q
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_diffrn_reflns_limit_k_min       -19
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_exptl_absorpt_process_details
;
(North,Phillips & Matthews, 1968)
;
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_refine_diff_density_min         -1.32
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00002|Fo|^2^]'
_refine_ls_weighting_scheme      sigma
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_reflns_number_total             10080
_reflns_threshold_expression     I>2.00\s(I)
_cod_data_source_file            a908296d.txt
_cod_data_source_block           tepdbr
_cod_original_cell_volume        2867(1)
_cod_original_sg_symbol_H-M      'P -1       '
_cod_database_code               7009037