Structures of substituted pyridine <i>N</i>-oxide with manganese(II) acetate
Lynch, Will; Lynch, Genevieve; Sheriff, Kirk; Padgett, Clifford; Acta Crystallographica Section E 74 (2018) 1405–1410; doi:10.1107/S205698901801232X

data_2242631
_publ_section_title
;
 Structures of substituted pyridine <i>N</i>-oxide with manganese(II)
 acetate
;
_journal_coeditor_code           ZL2728
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              1405
_journal_page_last               1410
_journal_paper_doi               10.1107/S205698901801232X
_journal_volume                  74
_journal_year                    2018
_chemical_formula_iupac          '[Mn4 (C2 H3 O2)8 (C5 H5 N O)2 (H2 O)2]'
_chemical_formula_moiety         'C26 H38 Mn4 N2 O20'
_chemical_formula_sum            'C26 H38 Mn4 N2 O20'
_chemical_formula_weight         918.3396
_chemical_name_systematic
;<i>catena</i>-Poly[manganese(II)-\m~3~-acetato-di-\m~2~-acetato-[aquamanganese(II)]-\m~2~-acetato-\m-(pyridine <i>N</i>-oxide)-manganese(II)-\m~3~-acetato-\m~2~-acetato-\m-(pyridine
<i>N</i>-oxide)-[aquamanganese(II)]-di-\m~2~-acetato]
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
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_symmetry_space_group_name_Hall  '-C 2yc'
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Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
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;
CrystalClear (Rigaku, 2009)
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CrystalClear (Rigaku, 2009)
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CrystalClear (Rigaku, 2009)
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<i>OLEX2</i>  (Dolomanov <i>et al.</i>,  2009)
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<i>OLEX2</i>  (Dolomanov <i>et al.</i>,  2009)
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ShelXL (Sheldrick, 2015b)
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ShelXT (Sheldrick, 2015a)
;
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku XtaLAB mini'
_diffrn_measurement_method       'profile data from \w-scans'
_diffrn_radiation_monochromator  'Graphite Monochromator'
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;
(<i>REQAB</i>; Rigaku, 1998)
;
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_exptl_crystal_description       Prism
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
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;
SHELXL-2018/1 (Sheldrick 2015)
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0348P)^2^+3.1638P] where P=(Fo^2^+2Fc^2^)/3'
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_refine_ls_wR_factor_ref         0.0828
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_cod_data_source_block           I
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_shelx_estimated_absorpt_t_min   0.609
_shelx_estimated_absorpt_t_max   0.770
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