Substitution effect on the photocatalytic degradation by the series AxBi26-xMo10O68+0.5y (A = Ba, y = 0; A = Bi, La, y = 2): a kinetic study.
Muktha, B.; Aarthi, T.; Madras, Giridhar; Guru Row, T. N.; The journal of physical chemistry. B 110 (2006) 10280–10286; doi:10.1021/jp060945o

data_1505744
_publ_section_title
;
 Substitution effect on the photocatalytic degradation by the series
 AxBi26-xMo10O68+0.5y (A = Ba, y = 0; A = Bi, La, y = 2): a kinetic study.
;
_journal_issue                   21
_journal_name_full               'The journal of physical chemistry. B'
_journal_page_first              10280
_journal_page_last               10286
_journal_paper_doi               10.1021/jp060945o
_journal_volume                  110
_journal_year                    2006
_chemical_formula_sum            'Ba0.5 Bi6 Mo2.5 O17'
_chemical_formula_weight         1834.4
_chemical_name_systematic        ' ?'
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 101.838
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.6887
_cell_length_b                   5.8139
_cell_length_c                   24.7151
_cell_volume                     1643.841
_computing_publication_material  '(Jana2000; Petricek and Dusek, 2000)'
_computing_structure_refinement  '(Jana2000; Petricek and Dusek, 2000)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.95
_diffrn_measurement_device_type  'Bruker SMART CCD area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0690
_diffrn_reflns_av_sigmaI/netI    0.0827
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            12447
_diffrn_reflns_theta_full        27.56
_diffrn_reflns_theta_max         27.92
_diffrn_reflns_theta_min         1.68
_exptl_absorpt_coefficient_mu    67.081
_exptl_absorpt_correction_T_max  0.0621
_exptl_absorpt_correction_T_min  0.0029
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
'Interpolation using  Int.Tab. Vol. C (1992) p. 523,Tab. 6.3.3.3'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    7.4097
_exptl_crystal_description       cylindrical
_exptl_crystal_F_000             3068
_exptl_crystal_size_max          0.248
_exptl_crystal_size_mid          0.131
_exptl_crystal_size_min          0.086
_exptl_crystal_size_rad          0.198
_refine_diff_density_max         6.225
_refine_diff_density_min         -4.41
_refine_ls_goodness_of_fit_gt    1.24
_refine_ls_goodness_of_fit_ref   1.24
_refine_ls_number_parameters     76
_refine_ls_number_reflns         2942
_refine_ls_R_factor_all          0.0558
_refine_ls_R_factor_gt           0.0558
_refine_ls_shift/su_max          0.0011
_refine_ls_shift/su_mean         0.0001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     w=1/\s^2^(I)
_refine_ls_weighting_scheme      sigma
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