Critical Role of Anions in Platinum(II) Precursors upon the Structural Motifs of Six-Membered Cycloplatinated <i>N</i>,<i>N</i>',<i>N</i>″-Triarylguanidines.
Mishra, Vishwesh; Thirupathi, Natesan; ACS omega 3 (2018) 6075–6090; doi:10.1021/acsomega.8b00782

data_4516049
_publ_section_title
;
 Critical Role of Anions in Platinum(II) Precursors upon the Structural
 Motifs of Six-Membered Cycloplatinated
 <i>N</i>,<i>N</i>',<i>N</i>&#x2033;-Triarylguanidines.
;
_journal_issue                   6
_journal_name_full               'ACS omega'
_journal_page_first              6075
_journal_page_last               6090
_journal_paper_doi               10.1021/acsomega.8b00782
_journal_volume                  3
_journal_year                    2018
_chemical_formula_moiety         'C57 H64 Cl2 N6 Pt2'
_chemical_formula_sum            'C57 H64 Cl2 N6 Pt2'
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_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2017/1
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_cell_angle_beta                 105.146(2)
_cell_angle_gamma                106.101(2)
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_cell_length_c                   16.1768(3)
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_cell_measurement_theta_min      3.2040
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_computing_cell_refinement       'CrysAlisPro, Oxford Diffraction Ltd.'
_computing_data_collection       'CrysAlisPro, Oxford Diffraction Ltd.'
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_computing_molecular_graphics    Olex2
_computing_publication_material  'WINGX 2014'
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_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 15.9853
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0337
_diffrn_reflns_av_unetI/netI     0.0384
_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_limit_k_min       -18
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Green
_exptl_crystal_density_diffrn    1.697
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0370P)^2^+4.7513P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_original_cell_volume        2532.70(10)
_cod_database_code               4516049
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_shelx_estimated_absorpt_t_min   0.895
_shelx_estimated_absorpt_t_max   0.972
_shelx_res_checksum              68090
_shelx_hkl_checksum              17888