Metallophilic interactions: observations of the shortest metallophilicinteractions between closed shell (d<sup>10</sup>d<sup>10</sup>, d<sup>10</sup>d<sup>8</sup>, d<sup>8</sup>d<sup>8</sup>) metal ions [MM' M = Hg(ii) and Pd(ii) and M' = Cu(i), Ag(i), Au(i), and Pd(ii)].
Raju, Saravanan; Singh, Harkesh B.; Butcher, Ray J.; Dalton transactions (Cambridge, England : 2003) 49 (2020) 9099–9117; doi:10.1039/d0dt01008a

data_7704625
_publ_section_title
;
 Metallophilic interactions: observations of the shortest
 metallophilicinteractions between closed shell
 (d<sup>10</sup>d<sup>10</sup>, d<sup>10</sup>d<sup>8</sup>,
 d<sup>8</sup>d<sup>8</sup>) metal ions [MM' M = Hg(ii) and Pd(ii) and M'
 = Cu(i), Ag(i), Au(i), and Pd(ii)].
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9099
_journal_page_last               9117
_journal_paper_doi               10.1039/d0dt01008a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety
;
C42 H38 Ag2 Cl Hg2 N6 O6, Cl O4
;
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;
2019-02-21 deposited with the CCDC.	2020-06-03 downloaded from the CCDC.
;
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Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
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_exptl_crystal_colour            'clear intense colourless'
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_exptl_crystal_size_mid          0.058
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0256P)^2^+8.7988P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                11305
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'Adding full bibliography for 7704622--7704632.cif.'
_cod_database_code               7704625
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