Reactivity of an anionic Pd(II) metallacycle with CH2X2 (X=Cl, Br, I): formal insertion of methylene into a Pd-C(aryl) bond.
Cámpora, Juan; Palma, Pilar; del Río, Diego; López, Jorge A; Valerga, Pedro; Chemical communications (Cambridge, England)  (2004) 1490–1491; doi:10.1039/b403411b

data_7102710
_publ_section_title
;
 Reactivity of an anionic Pd(II) metallacycle with CH2X2 (X=Cl, Br, I):
 formal insertion of methylene into a Pd-C(aryl) bond.
;
_journal_issue                   13
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              1490
_journal_page_last               1491
_journal_paper_doi               10.1039/b403411b
_journal_year                    2004
_chemical_formula_moiety         'C20 H24 B Br N6 Pd'
_chemical_formula_sum            'C20 H24 B Br N6 Pd'
_chemical_formula_weight         545.56
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
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_audit_creation_date             'Tue May 18 13:05:04 1999'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                107.20(2)
_cell_angle_beta                 115.02(2)
_cell_angle_gamma                75.17(2)
_cell_formula_units_Z            2
_cell_length_a                   10.307(3)
_cell_length_b                   11.881(3)
_cell_length_c                   10.056(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    290.2
_cell_measurement_theta_max      18.1
_cell_measurement_theta_min      12.5
_cell_volume                     1053.8(6)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
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_diffrn_ambient_temperature      290.2
_diffrn_measurement_device       AFC6S
_diffrn_measurement_method       'omega/2-theta scans'
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_diffrn_orient_matrix_UB_12      -0.00429
_diffrn_orient_matrix_UB_13      0.01802
_diffrn_orient_matrix_UB_21      -0.05970
_diffrn_orient_matrix_UB_22      -0.00717
_diffrn_orient_matrix_UB_23      -0.10971
_diffrn_orient_matrix_UB_31      0.02545
_diffrn_orient_matrix_UB_32      -0.08874
_diffrn_orient_matrix_UB_33      -0.01617
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoKalpha
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_diffrn_reflns_limit_l_min       -10
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_diffrn_source                   'X-ray tube'
_diffrn_standards_decay_%        -0.30
_diffrn_standards_interval_count 100
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.795
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_exptl_absorpt_correction_T_min  0.709
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   psi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.719
_exptl_crystal_description       irregular
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
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_reflns_number_observed          2895
_reflns_number_total             3714
_reflns_observed_criterion       ' I>3\s(I) '
_cod_data_source_file            b403411b.txt
_cod_data_source_block           '[TpPd(CH2C(Me)2(C6H4)CH2)]'
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_cod_database_code               7102710