Synthesis of acetic acid from CO<sub>2</sub>, CH<sub>3</sub>I and H<sub>2</sub> using a water-soluble electron storage catalyst.
Yatabe, Takeshi; Kamitakahara, Kazuki; Higashijima, Kaede; Ando, Tatsuya; Matsumoto, Takahiro; Yoon, Ki-Seok; Enomoto, Takao; Ogo, Seiji; Chemical communications (Cambridge, England) 57 (2021) 4772–4774; doi:10.1039/d1cc01611c

data_7128274
_publ_section_title
;
 Synthesis of acetic acid from CO<sub>2</sub>, CH<sub>3</sub>I and
 H<sub>2</sub> using a water-soluble electron storage catalyst.
;
_journal_issue                   39
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              4772
_journal_page_last               4774
_journal_paper_doi               10.1039/d1cc01611c
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C23 H20 F6 I N5 P Rh'
_chemical_formula_sum            'C23 H20 F6 I N5 P Rh'
_chemical_formula_weight         741.22
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2021-01-06 deposited with the CCDC.	2021-04-26 downloaded from the CCDC.
;
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_cell_angle_beta                 96.143(9)
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_cell_formula_units_Z            2
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_cell_measurement_theta_max      27.40
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'CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)'
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_computing_structure_solution    'SIR92 (Altomare, et al., 1994)'
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_diffrn_measured_fraction_theta_full 0.964
_diffrn_measured_fraction_theta_max 0.940
_diffrn_measurement_device_type  'Rigaku XtaLAB P200'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_limit_k_min       -15
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_diffrn_reflns_point_group_measured_fraction_max 0.940
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_diffrn_reflns_theta_min         3.122
_diffrn_standards_number         0
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_exptl_crystal_colour            orange
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_exptl_crystal_description       block
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.1000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1116
_refine_ls_wR_factor_ref         0.1183
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3831
_reflns_number_total             5326
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
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_cod_depositor_comments
'Adding full bibliography for 7128273--7128275.cif.'
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