Organic Triplet Emissions of Arylacetylide Moieties Harnessed through Coordination to [Au(PCy3)]+. Effect of Molecular Structure upon Photoluminescent Properties
Hsiu-Yi Chao; Wei Lu; Yanqin Li; Michael C. W. Chan; Chi-Ming Che; Kung-Kai Cheung; Nianyong Zhu; Journal of the American Chemical Society 124 (2002) 14696–14706; doi:10.1021/ja0209417

data_4115358
_publ_section_title
;
 Organic Triplet Emissions of Arylacetylide Moieties Harnessed through
 Coordination to [Au(PCy3)]+. Effect of Molecular Structure upon
 Photoluminescent Properties
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              14696
_journal_page_last               14706
_journal_paper_doi               10.1021/ja0209417
_journal_volume                  124
_journal_year                    2002
_chemical_formula_moiety         'C27 H40 Au P '
_chemical_formula_sum            'C27 H40 Au P'
_chemical_formula_weight         592.55
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_date             'Mon Aug 28 14:29:33 2000'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 97.83(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.062(2)
_cell_length_b                   16.782(3)
_cell_length_c                   12.667(2)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    301.2
_cell_measurement_theta_max      0.0
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_cell_volume                     2540.2(7)
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_computing_data_collection       'MAR Data Collection Software & DENZO'
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_computing_publication_material  teXsan
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_computing_structure_solution    'DIRDIF92 (PATTY)'
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_diffrn_measurement_method       oscillation
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_diffrn_orient_matrix_UB_22      0.00000
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_diffrn_standards_decay_%        0.00
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_exptl_absorpt_coefficient_mu    5.885
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.549
_exptl_crystal_density_meas      0.000
_exptl_crystal_description       prism
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_refine_ls_hydrogen_treatment    noref
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_refine_ls_number_restraints     0
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_refine_ls_shift/esd_max         0.0470
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
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_reflns_number_observed          4186
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_reflns_observed_criterion       3.00
_cod_data_source_file            ja0209417_03.cif
_cod_data_source_block           ip853_C27H44P1Au1_15082000_Compound_1d
_cod_original_sg_symbol_H-M      'P 21/c '
_cod_original_formula_sum        'C27 H40 Au P '
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