Reactions of a persistent phosphinyl radical/diphosphine with heteroallenes.
Giffin, Nick A.; Hendsbee, Arthur D.; Masuda, Jason D.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 12636–12638; doi:10.1039/c6dt02790c

data_7040033
_publ_section_title
;
 Reactions of a persistent phosphinyl radical/diphosphine with
 heteroallenes.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12636
_journal_page_last               12638
_journal_paper_doi               10.1039/c6dt02790c
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C59 H81 N5 P2 S'
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_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_audit_update_record
;
2016-07-14 deposited with the CCDC.
2016-07-15 downloaded from the CCDC.
;
_cell_angle_alpha                86.729(7)
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_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device_type  'Siemens/Bruker APEXII'
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_diffrn_reflns_theta_max         24.997
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_exptl_absorpt_coefficient_mu    0.161
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5617
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS: Bruker; 2008)'
_exptl_crystal_colour            yellow
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_exptl_crystal_description       block
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_exptl_crystal_size_max          .118
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0799P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1989
_refine_ls_wR_factor_ref         0.3029
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2618
_reflns_number_total             9374
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt02790c2.cif
_cod_data_source_block           NG128_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-Scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7040032--7040034.cif.
;
_cod_database_code               7040033
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              12477