Regioselective π-extension of indoles with rhodium enalcarbenoids - synthesis of substituted carbazoles.
Rathore, Kuldeep Singh; Harode, Mandeep; Katukojvala, Sreenivas; Organic & biomolecular chemistry 12 (2014) 8641–8645; doi:10.1039/c4ob01693a

data_7154037
_publ_section_title
;
 Regioselective \p-extension of indoles with rhodium enalcarbenoids -
 synthesis of substituted carbazoles.
;
_journal_issue                   43
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              8641
_journal_page_last               8645
_journal_paper_doi               10.1039/c4ob01693a
_journal_volume                  12
_journal_year                    2014
_chemical_formula_moiety         'C16 H13 N O4'
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      261(2)
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_exptl_absorpt_coefficient_mu    0.107
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_exptl_absorpt_correction_T_min  0.9707
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_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.470
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0177P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1300
_refine_ls_wR_factor_ref         0.1825
_reflns_number_gt                1072
_reflns_number_total             2953
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4ob01693a5.cif
_cod_data_source_block           R6
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 7154036--7154038.cif.

The following automatic conversions were performed:

data name '_iucr_refine_instruction_details' was replaced with
'_iucr_refine_instructions_details' as specified in the replacement
file 'data/replacement-values/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 9268 2022-04-12 08:56:07Z antanas 
;
_cod_original_cell_volume        2560.3(10)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7154037