Reactions of metalloalkynes. New C2 bonding mode in a trimetallic complex.
Griffith, Christopher S.; Koutsantonis, George A.; Skelton, Brian W.; White, Allan H.; Chemical communications (Cambridge, England)  (2002) 2174–2175; doi:10.1039/b110930h

data_7125549
_publ_section_title
;
 Reactions of metalloalkynes. New C2 bonding mode in a trimetallic
 complex.
;
_journal_issue                   18
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              2174
_journal_page_last               2175
_journal_paper_doi               10.1039/b110930h
_journal_year                    2002
_chemical_formula_sum            'C23 H15 B F4 O6 Ru3'
_chemical_formula_weight         777.38
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             01-11-29
_audit_creation_method           Xtal3.6
_cell_angle_alpha                93.04(3)
_cell_angle_beta                 103.04(2)
_cell_angle_gamma                107.29(2)
_cell_formula_units_Z            2
_cell_length_a                   14.292(3)
_cell_length_b                   10.397(3)
_cell_length_c                   9.281(3)
_cell_measurement_reflns_used    8
_cell_measurement_temperature    293
_cell_measurement_theta_max      25.9
_cell_measurement_theta_min      18.9
_cell_volume                     1272.1(7)
_computing_cell_refinement       'Enraf Nonius Software'
_computing_data_collection       'Enraf Nonius Software'
_computing_data_reduction        xtal
_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  xtal
_computing_structure_solution    xtal
_diffrn_ambient_temperature      293
_diffrn_measurement_device_type
;
CAD4  diffractometer
;
_diffrn_measurement_method       '2\q-\w scans'
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .048
_diffrn_reflns_av_sigmaI/netI    0
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       5
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            9772
_diffrn_reflns_reduction_process equatorial_monochr_Lp
_diffrn_reflns_theta_max         28.03
_diffrn_reflns_theta_min         1.54
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  60
_diffrn_standards_number         8
_exptl_absorpt_coefficient_mu    1.824
_exptl_absorpt_correction_T_max  .75
_exptl_absorpt_correction_T_min  .58
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
Xtal absorb                
;
_exptl_crystal_colour            dark
_exptl_crystal_density_diffrn    2.029
_exptl_crystal_description       prism
_exptl_crystal_F_000             748
_exptl_crystal_size_max          .75
_exptl_crystal_size_mid          .28
_exptl_crystal_size_min          .18
_refine_diff_density_max         1.185
_refine_diff_density_min         -1.281
_refine_ls_goodness_of_fit_all   1.818
_refine_ls_goodness_of_fit_ref   1.901
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     335
_refine_ls_number_reflns         5065
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .075
_refine_ls_R_factor_gt           .06
_refine_ls_shift/su_max          .049
_refine_ls_shift/su_mean         .002
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         .071
_refine_ls_wR_factor_ref         .071
_reflns_d_resolution_high        .756
_reflns_d_resolution_low         13.167
_reflns_limit_h_max              17
_reflns_limit_h_min              -18
_reflns_limit_k_max              13
_reflns_limit_k_min              -13
_reflns_limit_l_max              12
_reflns_limit_l_min              0
_reflns_number_gt                5065
_reflns_number_observed          5065
_reflns_number_total             6140
_reflns_threshold_expression     'I    > 3.00 sig(I   )'
_cod_data_source_file            b110930h.txt
_cod_data_source_block           global
_cod_original_sg_symbol_Hall     -p_1
_cod_original_sg_symbol_H-M      P_-1
_cod_original_formula_sum        'C23 H15 B1 F4 O6 Ru3'
_cod_database_code               7125549