Metal‒organic gels of silver salts with an α,β-unsaturated ketone: the influence of anions and solvents on gelation
Das, Debarati; Biradha, Kumar; Inorganic Chemistry Frontiers 4 (2017) 1365–; doi:10.1039/C7QI00328E

data_4349749
_publ_section_title
;
 Metal--organic gels of silver salts with an \a,\b-unsaturated ketone: the
 influence of anions and solvents on gelation
;
_journal_issue                   8
_journal_name_full               'Inorganic Chemistry Frontiers'
_journal_page_first              1365
_journal_paper_doi               10.1039/C7QI00328E
_journal_volume                  4
_journal_year                    2017
_chemical_formula_sum            'C18 H19 Ag F6 N3 O2 Sb'
_chemical_formula_weight         652.98
_space_group_crystal_system      monoclinic
_space_group_IT_number           8
_space_group_name_Hall           'C -2y'
_space_group_name_H-M_alt        'C 1 m 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/8
_audit_update_record
;
2017-04-29 deposited with the CCDC.
2017-06-26 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 108.868(14)
_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_b                   17.444(7)
_cell_length_c                   7.132(3)
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_computing_structure_refinement  'SHELXL-2014/8 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.966
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_device_type  'Bruker APEX-2 CCD'
_diffrn_measurement_method       hemispehere
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0998
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_diffrn_reflns_Laue_measured_fraction_full 0.966
_diffrn_reflns_Laue_measured_fraction_max 0.967
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -20
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_diffrn_reflns_point_group_measured_fraction_full 0.967
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_diffrn_reflns_theta_max         25.499
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_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
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_exptl_crystal_description       cubic
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.17(12)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1699
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_reflns_number_gt                2401
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7qi00328e2.cif
_cod_data_source_block           CP2
_cod_original_cell_volume        2447.6(18)
_cod_original_sg_symbol_H-M      'C m'
_cod_database_code               4349749
_shelx_shelxl_version_number     2014/8
_shelx_res_checksum              3708
_shelx_hkl_checksum              44850