Alkyl and Hydrido Complexes of Platinum(IV) Supported by the Bis(8-quinolyl)methylsilyl Ligand
Sangtrirutnugul, Preeyanuch; Tilley, T. Don; Organometallics 27 (2008) 2223–; doi:10.1021/om701162h

data_4070973
_publ_section_title
;
 Alkyl and Hydrido Complexes of Platinum(IV) Supported by the
 Bis(8-quinolyl)methylsilyl Ligand
;
_journal_issue                   10
_journal_name_full               Organometallics
_journal_page_first              2223
_journal_paper_doi               10.1021/om701162h
_journal_volume                  27
_journal_year                    2008
_chemical_formula_moiety         'C38 H30 N4 Pd Si2, 2(C4 H8 O), C3 O'
_chemical_formula_sum            'C49 H46 N4 O3 Pd Si2'
_chemical_formula_weight         901.50
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      60
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_audit_creation_date             'Thu May 31 11:18:53 2007'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90.000
_cell_angle_beta                 90.000
_cell_angle_gamma                90.000
_cell_formula_units_Z            4
_cell_length_a                   8.8297(2)
_cell_length_b                   27.9592(6)
_cell_length_c                   18.1044(4)
_cell_measurement_reflns_used    5784
_cell_measurement_temperature    151.2
_cell_measurement_theta_max      24.8
_cell_measurement_theta_min      1.8
_cell_volume                     4469.46(17)
_computing_cell_refinement       'Bruker-AXS SAINT v6.40'
_computing_data_collection       'Bruker-AXS SMART v5.054'
_computing_data_reduction        'Bruker-AXS SAINT v6.40'
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    SAPI91
_diffrn_measured_fraction_theta_full 1.3591
_diffrn_measured_fraction_theta_max 1.3591
_diffrn_measurement_device_type  'Bruker SMART 1000'
_diffrn_measurement_method       \w-scans
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.057
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            20032
_diffrn_reflns_theta_full        24.73
_diffrn_reflns_theta_max         24.73
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.512
_exptl_absorpt_correction_T_max  0.940
_exptl_absorpt_correction_T_min  0.880
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.340
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1864.00
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.160
_exptl_crystal_size_min          0.140
_refine_diff_density_max         1.15
_refine_diff_density_min         -0.57
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.363
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     265
_refine_ls_number_reflns         2547
_refine_ls_R_factor_all          0.0985
_refine_ls_R_factor_gt           0.0468
_refine_ls_shift/su_max          0.0004
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00022|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0705
_refine_ls_wR_factor_ref         0.0604
_reflns_number_gt                2547
_reflns_number_total             3804
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            om701162h-file003.cif
_cod_data_source_block           nuch7
_cod_original_sg_symbol_Hall     '-P 2n 2ab    '
_cod_original_sg_symbol_H-M      'P b c n    '
_cod_original_formula_sum        'C49 H46 N4 O3 Pd Si2 '
_cod_database_code               4070973