Reversible Oxidation State Change in Germanium(tetraphenylporphyrin) Induced by a Dative Ligand: Aromatic GeII(TPP) and Antiaromatic GeIV(TPP)(pyridine)2
Julie A. Cissell; Thomas P. Vaid; Glenn P. A. Yap; Journal of the American Chemical Society 129 (2007) 7841–7847; doi:10.1021/ja070794i

data_4109553
_publ_section_title
;
 Reversible Oxidation State Change in Germanium(tetraphenylporphyrin)
 Induced by a Dative Ligand: Aromatic GeII(TPP) and Antiaromatic
 GeIV(TPP)(pyridine)2
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              7841
_journal_page_last               7847
_journal_paper_doi               10.1021/ja070794i
_journal_volume                  129
_journal_year                    2007
_chemical_formula_moiety         'C54 H38 Ge N6, C5 H5 N'
_chemical_formula_sum            'C59 H43 Ge N7'
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_chemical_name_systematic
; 
 ? 
;
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_cell_measurement_temperature    120(2)
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_computing_cell_refinement       'SAINT (Bruker, 2002)'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
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_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.909
_diffrn_measurement_device_type  'Bruker AXS APEX diffractometer'
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_diffrn_reflns_theta_max         28.24
_diffrn_reflns_theta_min         1.76
_diffrn_standards_decay_%        1
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
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_refine_ls_R_factor_all          0.0476
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0434P)^2^+1.5530P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja070794isi20070203_052839.cif
_cod_data_source_block           tomv005
_cod_original_cell_volume        2236.3(12)
_cod_database_code               4109553