Synthesis and structures of ruthenium di- and tricarbonyl complexes derived from 4,5-diazafluoren-9-one
Jimenez, Jorge; Chakraborty, Indranil; Mascharak, Pradip; Acta Crystallographica Section C 71 (2015) –; doi:10.1107/S2053229615018100

data_2020211
_publ_section_title
;
 Synthesis and structures of ruthenium di- and tricarbonyl complexes
 derived from 4,5-diazafluoren-9-one
;
_journal_coeditor_code           OV3067
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229615018100
_journal_volume                  71
_journal_year                    2015
_chemical_formula_iupac          '[Ru Cl2 (C11 H6 N2 O) (C O)2]'
_chemical_formula_moiety         'C13 H6 Cl2 N2 O3 Ru'
_chemical_formula_sum            'C13 H6 Cl2 N2 O3 Ru'
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_chemical_name_systematic
<i>trans</i>-Dicarbonyldichlorido(4,5-diazafluoren-9-one-\k^2^<i>N</i>,<i>N</i>')ruthenium(II)
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
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_computing_cell_refinement
;
SAINT (Bruker, 2008)
;
_computing_data_collection
;
APEX2 (Bruker, 2008)
;
_computing_data_reduction
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SAINT (Bruker, 2008)
;
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SHELXTL (Bruker 2008) and OLEX2 (Dolomanov <i>et al.</i>, 2009)
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publCIF (Westrip, 2010)
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SHELXL2014 (Sheldrick, 2015)
;
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;
SHELXS97 (Sheldrick, 2008)
;
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_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
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;
(SADABS; Bruker, 2008)
;
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_refine_ls_R_factor_all          0.0314
_refine_ls_R_factor_gt           0.0290
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0393P)^2^+1.2351P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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