Two luminescent film sensors constructed from new lanthanide coordination polymers for ratiometric detection of Zn2+ and NH3 in water and their white emission properties
Wang, Hui; Li, Xuan; Cheng, Hao; Li, Ya-Jun; Song, Xue-Qin; Wang, Li; Polymer Chemistry 13 (2022) 778–793; doi:10.1039/D1PY01492G

data_1565843
_publ_section_title
;
 Two luminescent film sensors constructed from new lanthanide coordination
 polymers for ratiometric detection of Zn2+ and NH3 in water and their
 white emission properties
;
_journal_issue                   6
_journal_name_full               'Polymer Chemistry'
_journal_page_first              778
_journal_page_last               793
_journal_paper_doi               10.1039/D1PY01492G
_journal_volume                  13
_journal_year                    2022
_chemical_formula_moiety         'C51 H46 N7 O15 Tb'
_chemical_formula_sum            'C51 H46 N7 O15 Tb'
_chemical_formula_weight         1155.87
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
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;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2020-01-29 deposited with the CCDC.	2021-12-27 downloaded from the CCDC.
;
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_cell_measurement_reflns_used    9948
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_cell_measurement_theta_min      2.78
_cell_volume                     5731.6(2)
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
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_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_diffrn_ambient_temperature      273.15
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0524
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_diffrn_reflns_theta_max         27.543
_diffrn_reflns_theta_min         2.439
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.301
_exptl_absorpt_correction_type   none
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0406P)^2^+3.2650P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0806
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                10140
_reflns_number_total             13198
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1py01492g2.cif
_cod_data_source_block           mo_20180925a_1_0m_sq_s
_cod_depositor_comments
'Adding full bibliography for 1565841--1565843.cif.'
_cod_database_code               1565843
_shelx_shelxl_version_number     2014/7
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H) groups
2.a Secondary CH2 refined with riding coordinates:
 C2(H2A,H2B), C3(H3A,H3B), C4(H4A,H4B), C17(H17A,H17B), C31(H31A,H31B),
 C45(H45A,H45B)
2.b Aromatic/amide H refined with riding coordinates:
 C6(H6), C7(H7), C8(H8), C9(H9), C11(H11), C12(H12), C13(H13), C14(H14),
 C19(H19), C20(H20), C21(H21), C22(H22), C23(H23), C25(H25), C26(H26), C27(H27),
  C28(H28), C33(H33), C34(H34), C35(H35), C36(H36), C37(H37), C39(H39),
 C40(H40), C41(H41), C42(H42), C47(H47), C48(H48), C49(H49), C50(H50), C51(H51),
  N2(H2), N3(H3), N4(H4)
;
_shelx_res_checksum              97498
_shelx_fab_checksum              26153
_olex2_submission_special_instructions 'No special instructions were received'