Coordination of two different metal ions as reason for N-chirality in μ-amide complexes.
Brandi-Blanco, Pilar; Miguel, Pablo J Sanz; Lippert, Bernhard; Dalton transactions (Cambridge, England : 2003) 40 (2011) 10316–10318; doi:10.1039/c1dt10585j

data_7016666
_publ_section_title
;
 Coordination of two different metal ions as reason for N-chirality in
 \m-amide complexes.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10316
_journal_page_last               10318
_journal_paper_doi               10.1039/c1dt10585j
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C12 H30 N10 Pd2 Pt, 2(N O3)'
_chemical_formula_sum            'C12 H30 N12 O6 Pd2 Pt'
_chemical_formula_weight         846.37
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_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2009-10-27T16:08:18-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 114.114(6)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.7994(8)
_cell_length_b                   10.6355(4)
_cell_length_c                   15.0356(8)
_cell_measurement_reflns_used    4665
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      29.012
_cell_measurement_theta_min      2.3719
_cell_volume                     2306.0(2)
_computing_cell_refinement       'CrysAlis RED (Oxford Diffraction, 2010)'
_computing_data_collection       'CrysAlis CCD (Oxford Diffraction, 2010)'
_computing_data_reduction        'CrysAlis RED (Oxford Diffraction, 2010)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1
_diffrn_measured_fraction_theta_max 0.853
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0323
_diffrn_reflns_av_unetI/netI     0.0718
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            10493
_diffrn_reflns_theta_full        25
_diffrn_reflns_theta_max         29.08
_diffrn_reflns_theta_min         2.38
_exptl_absorpt_coefficient_mu    7.651
_exptl_absorpt_correction_T_max  0.465
_exptl_absorpt_correction_T_min  0.393
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.438
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prisms
_exptl_crystal_F_000             1616
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_refine_diff_density_max         1.044
_refine_diff_density_min         -1.158
_refine_diff_density_rms         0.171
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.827
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     300
_refine_ls_number_reflns         5276
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.827
_refine_ls_R_factor_all          0.0487
_refine_ls_R_factor_gt           0.0267
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0324
_refine_ls_wR_factor_ref         0.0337
_reflns_number_gt                3613
_reflns_number_total             5276
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt10585j.txt
_cod_data_source_block           1
_cod_original_cell_volume        2306.02(19)
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7016666