Stabilization of a bismuth-bismuth double bond by anionic N-heterocyclic carbenes.
Ho, Luong Phong; Tamm, Matthias; Dalton transactions (Cambridge, England : 2003) 50 (2021) 1202–1205; doi:10.1039/d1dt00140j

data_7706447
_publ_section_title
;
 Stabilization of a bismuth-bismuth double bond by anionic N-heterocyclic
 carbenes.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               1205
_journal_paper_doi               10.1039/d1dt00140j
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C45 H35 B Bi F15 N2, C6 H6'
_chemical_formula_sum            'C51 H41 B Bi F15 N2'
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;
2020-12-14 deposited with the CCDC.	2021-01-18 downloaded from the CCDC.
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'SHELXT-2014/5 (G. M. Sheldrick, Acta Cryst., 2015, A71, 3-8)'
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;
CrysAlisPro 1.171.40.59a (Rigaku Oxford Diffraction, 2019)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear purple'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0717P)^2^+10.2226P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7706446--7706447.cif.'
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