Silver(I) Complex Assemblies with Nonplanar Aromatic Compounds
Megumu Munakata; Liang Ping Wu; Kunihisa Sugimoto; Takayoshi Kuroda-Sowa; Masahiko Maekawa; Yusaku Suenaga; Naoto Maeno; Motoshi Fujita; Inorganic Chemistry 38 (1999) 5674–5680; doi:10.1021/ic990391m

data_4322497
_publ_section_title
;
 Silver(I) Complex Assemblies with Nonplanar Aromatic Compounds
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5674
_journal_page_last               5680
_journal_paper_doi               10.1021/ic990391m
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C74 H58 Ag3 Cl3 O12'
_chemical_formula_weight         1569.23
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      9
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.72(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   37.951(4)
_cell_length_b                   8.047(4)
_cell_length_c                   20.882(5)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      6.5
_cell_measurement_theta_min      3.6
_cell_volume                     6364(4)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.023
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            7418
_diffrn_standards_decay_%        2.72
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.103
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.839
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.638
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       brick
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.80
_refine_diff_density_min         -0.81
_refine_ls_abs_structure_Flack   -0.15(7)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.994
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     750
_refine_ls_number_reflns         5089
_refine_ls_R_factor_gt           0.0542
_refine_ls_shift/su_max          0.0070
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00022|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0670
_reflns_number_gt                5089
_reflns_number_total             0
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic990391m_1.cif
_cod_data_source_block           ag-tpty-clo4
_cod_original_cell_volume        6363(3)
_cod_original_formula_sum        'C74 H58 Ag3 Cl3 O12 '
_cod_database_code               4322497