Field-induced slow magnetic relaxation in pseudooctahedral cobalt(ii) complexes with positive axial and large rhombic anisotropy.
Switlicka, Anna; Palion-Gazda, Joanna; Machura, Barbara; Cano, Joan; Lloret, Francesc; Julve, Miguel; Dalton transactions (Cambridge, England : 2003) 48 (2019) 1404–1417; doi:10.1039/c8dt03965h

data_7048491
_publ_section_title
;
 Field-induced slow magnetic relaxation in pseudooctahedral cobalt(ii)
 complexes with positive axial and large rhombic anisotropy.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1404
_journal_page_last               1417
_journal_paper_doi               10.1039/c8dt03965h
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C48 H40 Co N14'
_chemical_formula_sum            'C48 H40 Co N14'
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-09-14 deposited with the CCDC.
2018-12-26 downloaded from the CCDC.
;
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_cell_measurement_temperature    295(2)
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_cell_measurement_theta_min      3.8900
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_computing_data_reduction        'CrysAlis RED v. 1.163 (UNIL IC & KUMA 2000)'
_computing_molecular_graphics
'Mercury (Macrae, J.Appl.Cryst. 41 (2008) 466-470'
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_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0584P)^2^+0.1332P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 7048490--7048491.cif.'
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