A facile iodide-controlled fluorescent switch based on the interconversion between two- and three-coordinate copper(I) complexes.
Chou, Chang-Chuan; Liu, Hsueh-Ju; Hung-Chieh Chao, Lucas; Chemical communications (Cambridge, England)  (2009) 6382–6384; doi:10.1039/b908765f

data_7104953
_publ_section_title
;
 A facile iodide-controlled fluorescent switch based on the
 interconversion between two- and three-coordinate copper(I) complexes.
;
_journal_issue                   42
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              6382
_journal_page_last               6384
_journal_paper_doi               10.1039/b908765f
_journal_year                    2009
_chemical_formula_moiety         'C30 H32 Cl2 Cu I N6'
_chemical_formula_sum            'C30 H32 Cl2 Cu I N6'
_chemical_formula_weight         737.96
_chemical_name_systematic
;
?
;
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_atom_sites_solution_hydrogens   geom
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_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.0690(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.2775(5)
_cell_length_b                   15.5804(6)
_cell_length_c                   14.6968(6)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      0
_cell_measurement_theta_min      0
_cell_volume                     3002.3(2)
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1986)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_sigmaI/netI    0.0386
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
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_diffrn_reflns_limit_l_min       -11
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_diffrn_reflns_theta_max         25.03
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_exptl_absorpt_correction_T_max  0.9081
_exptl_absorpt_correction_T_min  0.5463
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.633
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1480
_exptl_crystal_size_max          0.35
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_exptl_crystal_size_min          0.05
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_refine_ls_R_factor_all          0.0746
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_refine_ls_shift/su_max          0.050
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1026P)^2^+5.5093P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1476
_refine_ls_wR_factor_ref         0.1747
_reflns_number_gt                4131
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b908765f.txt
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_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7104953