Stabilization of bis(chlorogermyliumylidene)s within bifunctional PNNP ligand frameworks and their reactivity studies.
Sahoo, Padmini; Raut, Ravindra K.; Maurya, Devesh; Kumar, Vikas; Rani, Pooja; Gonnade, Rajesh G.; Majumdar, Moumita; Dalton transactions (Cambridge, England : 2003) 48 (2019) 7344–7351; doi:10.1039/c9dt00109c

data_7049288
_publ_section_title
;
 Stabilization of bis(chlorogermyliumylidene)s within bifunctional PNNP
 ligand frameworks and their reactivity studies.
;
_journal_issue                   21
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7344
_journal_page_last               7351
_journal_paper_doi               10.1039/c9dt00109c
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C42 H38 Cl9 F3 Ga2 N2 O3 P2 S'
_chemical_formula_weight         1228.23
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-01-08 deposited with the CCDC.    2019-03-07 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_length_c                   12.6639(4)
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_cell_measurement_temperature    100(2)
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_cell_measurement_theta_min      2.35
_cell_volume                     5006.4(3)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.1643
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_diffrn_reflns_Laue_measured_fraction_full 0.991
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_diffrn_reflns_number            48512
_diffrn_reflns_point_group_measured_fraction_full 0.991
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_diffrn_reflns_theta_max         66.859
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_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            block
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_refine_ls_extinction_coef       0.00041(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.040
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_refine_ls_number_reflns         8803
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.040
_refine_ls_R_factor_all          0.1182
_refine_ls_R_factor_gt           0.0746
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1089P)^2^+14.2295P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1899
_refine_ls_wR_factor_ref         0.2193
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5713
_reflns_number_total             8803
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt00109c5.cif
_cod_data_source_block           5
_cod_depositor_comments
'Adding full bibliography for 7049285--7049289.cif.'
_cod_database_code               7049288
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              31820