Double addition of H2 to transition metalborane complexes: a hydride shuttle process between boron and transition metal centres
Nikolaos Tsoureas; Yu-Ying Kuo; Mairi Haddow; Gareth Owen; Chem.Commun. 47 (2011) 484–; doi:10.1039/c0cc02245d

data_7105784
_publ_section_title
;
Double addition of H2 to transition metal&#x0096;borane complexes: 
a &#x0091;hydride shuttle&#x0092; process between boron and 
transition metal centres
;
_journal_name_full               Chem.Commun.
_journal_page_first              484
_journal_paper_doi               10.1039/c0cc02245d
_journal_volume                  47
_journal_year                    2011
_chemical_formula_moiety         'C31 H33 B N6 P Rh'
_chemical_formula_sum            'C31 H33 B N6 P Rh'
_chemical_formula_weight         634.32
_chemical_name_systematic
;
?
;
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_cell_angle_beta                 71.6660(10)
_cell_angle_gamma                77.102(2)
_cell_formula_units_Z            2
_cell_length_a                   9.9941(3)
_cell_length_b                   11.5950(3)
_cell_length_c                   13.1114(3)
_cell_measurement_reflns_used    9950
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.41
_cell_measurement_theta_min      2.31
_cell_volume                     1405.51(7)
_computing_cell_refinement       'Bruker Apex II'
_computing_data_collection       'Bruker Apex II'
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_computing_molecular_graphics    'Bruker ShelXTL'
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_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_h_max       13
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_diffrn_reflns_limit_k_min       -15
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_diffrn_reflns_theta_max         27.58
_diffrn_reflns_theta_min         1.64
_exptl_absorpt_coefficient_mu    0.697
_exptl_absorpt_correction_T_max  0.7546
_exptl_absorpt_correction_T_min  0.6674
_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.499
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_exptl_crystal_description       plate
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_refine_ls_R_factor_all          0.0321
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0272P)^2^+0.8724P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_database_code               7105784