Steric and electronic effects on acetate-assisted cyclometallation of 2-phenylpyridines at [MCl<sub>2</sub>Cp*]<sub>2</sub> (M = Ir, Rh).
Davies, David L.; Singh, Kuldip; Tamosiunaite, Neringa; Dalton transactions (Cambridge, England : 2003) 49 (2020) 2680–2686; doi:10.1039/c9dt04581c

data_7703476
_publ_section_title
;
 Steric and electronic effects on acetate-assisted cyclometallation of
 2-phenylpyridines at [MCl<sub>2</sub>Cp*]<sub>2</sub> (M = Ir, Rh).
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2680
_journal_page_last               2686
_journal_paper_doi               10.1039/c9dt04581c
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C22 H22 Cl F3 Ir N'
_chemical_formula_sum            'C22 H22 Cl F3 Ir N'
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_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
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;
2020-02-04 deposited with the CCDC.	2020-02-06 downloaded from the CCDC.
;
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_diffrn_radiation_type           MoK\a
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;
absoprtion correction based on 6957 reflections(SADABS);Rint 0.1340 before
correction and 0.0708 after.
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0368P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0959
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7703476--7703478.cif.'
_cod_original_cell_volume        1984.3(17)
_cod_original_sg_symbol_H-M      'P 21/c'
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