LMucko/crystallography-open-database huggingface dataset:
Structural chemistry and magnetic properties of hexagonal perovskites Ba Irx Mn1-x O3 , x = 0.3, 0.4, 0.5
Jordan, N.A.; Battle, P.D.; Journal of Materials Chemistry 13 (2003) 2220–2226; doi:

data_7222341
_publ_section_title
;
 Structural chemistry and magnetic properties of hexagonal perovskites Ba
 Irx Mn1-x O3 , x = 0.3, 0.4, 0.5
;
_journal_name_full               'Journal of Materials Chemistry'
_journal_page_first              2220
_journal_page_last               2226
_journal_volume                  13
_journal_year                    2003
_chemical_formula_sum            'Ba Ir0.5 Mn0.5 O3'
_chemical_name_systematic        'Ba (Ir0.5 Mn0.5 O3)'
_space_group_IT_number           166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            9
_cell_length_a                   5.72021
_cell_length_b                   5.72021
_cell_length_c                   21.5196
_cell_volume                     609.802
_citation_journal_id_ASTM        JMACEP
_cod_data_source_file            Jordan_JMACEP_2003_787.cif
_cod_data_source_block           Ba1Ir0.5Mn0.5O3
_cod_original_cell_volume        609.8019
_cod_original_formula_sum        'Ba1 Ir0.5 Mn0.5 O3'
_cod_database_code               7222341
Sm - Ru - Ge system at 1070 K
Morozkin, A.V.; Seropegin, Yu.D.; Journal of Alloys Compd. 365 (2004) 168–172; doi:

data_1532935
_publ_section_title
;
 Sm - Ru - Ge system at 1070 K
;
_journal_name_full               'Journal of Alloys Compd.'
_journal_page_first              168
_journal_page_last               172
_journal_volume                  365
_journal_year                    2004
_chemical_formula_sum            'Ge2 Ru Sm2'
_chemical_name_systematic        'Sm2 Ru Ge2'
_space_group_IT_number           12
_symmetry_space_group_name_Hall  '-B 2'
_symmetry_space_group_name_H-M   'B 1 1 2/m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                123.23
_cell_formula_units_Z            4
_cell_length_a                   10.948
_cell_length_b                   10.839
_cell_length_c                   4.302
_cell_volume                     427.020
_citation_journal_id_ASTM        JALCEU
_cod_data_source_file            Morozkin_JALCEU_2004_1368.cif
_cod_data_source_block           Ge2Ru1Sm2
_cod_original_cell_volume        427.0204
_cod_original_sg_symbol_Hall     '-C 2y (-x,z,y)'
_cod_original_formula_sum        'Ge2 Ru1 Sm2'
_cod_database_code               1532935
Sm - Ru - Ge system at 1070 K
Morozkin, A.V.; Seropegin, Yu.D.; Journal of Alloys Compd. 365 (2004) 168–172; doi:

data_1532936
_publ_section_title
;
 Sm - Ru - Ge system at 1070 K
;
_journal_name_full               'Journal of Alloys Compd.'
_journal_page_first              168
_journal_page_last               172
_journal_volume                  365
_journal_year                    2004
_chemical_formula_sum            'Ge Ru Sm'
_chemical_name_systematic        'Sm Ru Ge'
_space_group_IT_number           62
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.165
_cell_length_b                   4.476
_cell_length_c                   7.152
_cell_volume                     229.369
_citation_journal_id_ASTM        JALCEU
_cod_data_source_file            Morozkin_JALCEU_2004_1369.cif
_cod_data_source_block           Ge1Ru1Sm1
_cod_original_cell_volume        229.3685
_cod_original_formula_sum        'Ge1 Ru1 Sm1'
_cod_database_code               1532936
Crystal structure of the sodium cobaltate deuterate superconductor Nax Co O2 * 4x(D2 O)
Jorgensen, J.D.; Avdeev, M.; Hinks, D.G.; Short, S.; Burley, J.C.; Physical Review, Serie 3. B - Condensed Matter (18,1978-) 68 (2003) 214517-1–214517-10; doi:

data_1532937
_publ_section_title
;
 Crystal structure of the sodium cobaltate deuterate superconductor Nax Co
 O2 * 4x(D2 O)
;
_journal_name_full
'Physical Review, Serie 3. B - Condensed Matter (18,1978-)'
_journal_page_first              214517-1
_journal_page_last               214517-10
_journal_volume                  68
_journal_year                    2003
_chemical_formula_sum            'Co Na0.61 O2'
_chemical_name_systematic        'Na0.61 (Co O2)'
_space_group_IT_number           194
_symmetry_space_group_name_Hall  '-P 6c 2c'
_symmetry_space_group_name_H-M   'P 63/m m c'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            2
_cell_length_a                   2.83176
_cell_length_b                   2.83176
_cell_length_c                   10.8431
_cell_volume                     75.300
_citation_journal_id_ASTM        PRBMDO
_cod_data_source_file            Jorgensen_PRBMDO_2003_1978.cif
_cod_data_source_block           Co1Na0.61O2
_cod_original_cell_volume        75.30034
_cod_original_formula_sum        'Co1 Na0.61 O2'
_cod_database_code               1532937
Sm - Ru - Ge system at 1070 K
Morozkin, A.V.; Seropegin, Yu.D.; Journal of Alloys Compd. 365 (2004) 168–172; doi:

data_1532938
_publ_section_title
;
 Sm - Ru - Ge system at 1070 K
;
_journal_name_full               'Journal of Alloys Compd.'
_journal_page_first              168
_journal_page_last               172
_journal_volume                  365
_journal_year                    2004
_chemical_formula_sum            'Ge2 Ru2 Sm3'
_chemical_name_systematic        'Sm3 Ru2 Ge2'
_space_group_IT_number           57
_symmetry_space_group_name_Hall  '-P 2c 2b'
_symmetry_space_group_name_H-M   'P b c m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.62
_cell_length_b                   7.808
_cell_length_c                   13.567
_cell_volume                     595.333
_citation_journal_id_ASTM        JALCEU
_cod_data_source_file            Morozkin_JALCEU_2004_1370.cif
_cod_data_source_block           Ge2Ru2Sm3
_cod_database_code               1532938
Crystal structure of the sodium cobaltate deuterate superconductor Nax Co O2 * 4x(D2 O)
Jorgensen, J.D.; Burley, J.C.; Avdeev, M.; Hinks, D.G.; Short, S.; Physical Review, Serie 3. B - Condensed Matter (18,1978-) 68 (2003) 214517-1–214517-10; doi:

data_1532939
_publ_section_title
;
 Crystal structure of the sodium cobaltate deuterate superconductor Nax Co
 O2 * 4x(D2 O)
;
_journal_name_full
'Physical Review, Serie 3. B - Condensed Matter (18,1978-)'
_journal_page_first              214517-1
_journal_page_last               214517-10
_journal_volume                  68
_journal_year                    2003
_chemical_formula_sum            'Co Na0.57 O2'
_chemical_name_systematic        'Na0.57 (Co O2)'
_space_group_IT_number           194
_symmetry_space_group_name_Hall  '-P 6c 2c'
_symmetry_space_group_name_H-M   'P 63/m m c'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            2
_cell_length_a                   2.83287
_cell_length_b                   2.83287
_cell_length_c                   10.8969
_cell_volume                     75.733
_citation_journal_id_ASTM        PRBMDO
_cod_data_source_file            Jorgensen_PRBMDO_2003_1979.cif
_cod_data_source_block           Co1Na0.57O2
_cod_original_cell_volume        75.7333
_cod_original_formula_sum        'Co1 Na0.57 O2'
_cod_database_code               1532939
Sm - Ru - Ge system at 1070 K
Morozkin, A.V.; Seropegin, Yu.D.; Journal of Alloys Compd. 365 (2004) 168–172; doi:

data_1532940
_publ_section_title
;
 Sm - Ru - Ge system at 1070 K
;
_journal_name_full               'Journal of Alloys Compd.'
_journal_page_first              168
_journal_page_last               172
_journal_volume                  365
_journal_year                    2004
_chemical_formula_sum            'Ge0.46 Ru1.54 Sm'
_chemical_name_systematic        'Sm Ru1.54 Ge0.46'
_space_group_IT_number           227
_symmetry_space_group_name_Hall  'F 4d 2 3 -1d'
_symmetry_space_group_name_H-M   'F d -3 m :1'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   7.557
_cell_length_b                   7.557
_cell_length_c                   7.557
_cell_volume                     431.567
_citation_journal_id_ASTM        JALCEU
_cod_data_source_file            Morozkin_JALCEU_2004_1371.cif
_cod_data_source_block           Ge0.46Ru1.54Sm1
_cod_original_cell_volume        431.5671
_cod_original_sg_symbol_Hall     '-F 4vw 2vw 3 (x+1/8,y+1/8,z+1/8)'
_cod_original_formula_sum        'Ge0.46 Ru1.54 Sm1'
_cod_database_code               1532940
Crystal structure of the sodium cobaltate deuterate superconductor Nax Co O2 * 4x(D2 O)
Jorgensen, J.D.; Avdeev, M.; Short, S.; Burley, J.C.; Hinks, D.G.; Physical Review, Serie 3. B - Condensed Matter (18,1978-) 68 (2003) 214517-1–214517-10; doi:

data_1532941
_publ_section_title
;
 Crystal structure of the sodium cobaltate deuterate superconductor Nax Co
 O2 * 4x(D2 O)
;
_journal_name_full
'Physical Review, Serie 3. B - Condensed Matter (18,1978-)'
_journal_page_first              214517-1
_journal_page_last               214517-10
_journal_volume                  68
_journal_year                    2003
_chemical_formula_sum            'Co D2.5 Na0.31 O3.25'
_chemical_name_systematic        'Na0.31 (Co O2) (D2 O)1.25'
_space_group_IT_number           194
_symmetry_space_group_name_Hall  '-P 6c 2c'
_symmetry_space_group_name_H-M   'P 63/m m c'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            2
_cell_length_a                   2.81693
_cell_length_b                   2.81693
_cell_length_c                   19.6449
_cell_volume                     135.000
_citation_journal_id_ASTM        PRBMDO
_cod_data_source_file            Jorgensen_PRBMDO_2003_1980.cif
_cod_data_source_block           D2.5Co1Na0.31O3.25
_cod_original_cell_volume        134.9996
_cod_original_formula_sum        'D2.5 Co1 Na0.31 O3.25'
_cod_database_code               1532941
Sm - Ru - Ge system at 1070 K
Morozkin, A.V.; Seropegin, Yu.D.; Journal of Alloys Compd. 365 (2004) 168–172; doi:

data_1532942
_publ_section_title
;
 Sm - Ru - Ge system at 1070 K
;
_journal_name_full               'Journal of Alloys Compd.'
_journal_page_first              168
_journal_page_last               172
_journal_volume                  365
_journal_year                    2004
_chemical_formula_sum            'Ge4 Ru2 Sm3'
_chemical_name_systematic        'Sm3 Ru2 Ge4'
_space_group_IT_number           12
_symmetry_space_group_name_Hall  '-B 2'
_symmetry_space_group_name_H-M   'B 1 1 2/m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                109.29
_cell_formula_units_Z            2
_cell_length_a                   10.899
_cell_length_b                   8.139
_cell_length_c                   4.319
_cell_volume                     361.616
_citation_journal_id_ASTM        JALCEU
_cod_data_source_file            Morozkin_JALCEU_2004_1372.cif
_cod_data_source_block           Ge4Ru2Sm3
_cod_original_cell_volume        361.6161
_cod_original_sg_symbol_Hall     '-C 2y (-x,z,y)'
_cod_database_code               1532942
Crystal structure of the sodium cobaltate deuterate superconductor Nax Co O2 * 4x(D2 O)
Jorgensen, J.D.; Avdeev, M.; Hinks, D.G.; Burley, J.C.; Short, S.; Physical Review, Serie 3. B - Condensed Matter (18,1978-) 68 (2003) 214517-1–214517-10; doi:

data_1532943
_publ_section_title
;
 Crystal structure of the sodium cobaltate deuterate superconductor Nax Co
 O2 * 4x(D2 O)
;
_journal_name_full
'Physical Review, Serie 3. B - Condensed Matter (18,1978-)'
_journal_page_first              214517-1
_journal_page_last               214517-10
_journal_volume                  68
_journal_year                    2003
_chemical_formula_sum            'Co D2.86 Na0.35 O3.43'
_chemical_name_systematic        'Na0.35 (Co O2) (D2 O)1.43'
_space_group_IT_number           194
_symmetry_space_group_name_Hall  '-P 6c 2c'
_symmetry_space_group_name_H-M   'P 63/m m c'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            2
_cell_length_a                   2.82166
_cell_length_b                   2.82166
_cell_length_c                   19.7681
_cell_volume                     136.303
_citation_journal_id_ASTM        PRBMDO
_cod_data_source_file            Jorgensen_PRBMDO_2003_1981.cif
_cod_data_source_block           D2.86Co1Na0.35O3.43
_cod_original_cell_volume        136.3029
_cod_original_formula_sum        'D2.86 Co1 Na0.35 O3.43'
_cod_database_code               1532943
Structures of three polymorphs of the complex oxide K5 Yb (Mo O4)4
Morozov, V.A.; van Tendeloo, G.; Lazoryak, B.I.; Lebedev, O.I.; Amelinckx, S.; Journal of Solid State Chemistry 176 (2003) 76–87; doi:

data_1532944
_publ_section_title
;
 Structures of three polymorphs of the complex oxide K5 Yb (Mo O4)4
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              76
_journal_page_last               87
_journal_volume                  176
_journal_year                    2003
_chemical_formula_sum            'K2.5 Mo2 O8 Yb0.5'
_chemical_name_systematic        'K2 (K0.5 Yb0.5) (Mo O4)2'
_space_group_IT_number           166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   6.0372
_cell_length_b                   6.0372
_cell_length_c                   20.4045
_cell_volume                     644.062
_citation_journal_id_ASTM        JSSCBI
_cod_data_source_file            Morozov_JSSCBI_2003_258.cif
_cod_data_source_block           K2.5Mo2O8Yb0.5
_cod_database_code               1532944
Neutron diffraction study of the magnetic structures of one-dimensional M2 Tb F6 (M = Li, K, Rb) fluorides: frustration, incommensurability and magnetic interactions
Josse, M.; Dubois, M.; El Ghozzi, M.; Andre, G.; Avignant, D.; Guillot, M.; Bouree, F.; Journal of Alloys Compd. 374 (2004) 207–212; doi:

data_1532945
_publ_section_title
;
 Neutron diffraction study of the magnetic structures of one-dimensional
 M2 Tb F6 (M = Li, K, Rb) fluorides: frustration, incommensurability and
 magnetic interactions
;
_journal_name_full               'Journal of Alloys Compd.'
_journal_page_first              207
_journal_page_last               212
_journal_volume                  374
_journal_year                    2004
_chemical_formula_sum            'F6 K2 Tb'
_chemical_name_systematic        'K2 (Tb F6)'
_space_group_IT_number           15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 90.502
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.5909
_cell_length_b                   11.4135
_cell_length_c                   7.1235
_cell_volume                     535.846
_citation_journal_id_ASTM        JALCEU
_cod_data_source_file            Josse_JALCEU_2004_1501.cif
_cod_data_source_block           F6K2Tb1
_cod_original_cell_volume        535.8464
_cod_original_formula_sum        'F6 K2 Tb1'
_cod_database_code               1532945
Structures of three polymorphs of the complex oxide K5 Yb (Mo O4)4
Morozov, V.A.; Lazoryak, B.I.; Amelinckx, S.; Lebedev, O.I.; van Tendeloo, G.; Journal of Solid State Chemistry 176 (2003) 76–87; doi:

data_1532946
_publ_section_title
;
 Structures of three polymorphs of the complex oxide K5 Yb (Mo O4)4
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              76
_journal_page_last               87
_journal_volume                  176
_journal_year                    2003
_chemical_formula_sum            'K5 Mo4 O16 Yb'
_chemical_name_systematic        'K5 Yb (Mo O4)4'
_space_group_IT_number           15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 114.559
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.8236
_cell_length_b                   12.1293
_cell_length_c                   10.5151
_cell_volume                     1719.577
_citation_journal_id_ASTM        JSSCBI
_cod_data_source_file            Morozov_JSSCBI_2003_259.cif
_cod_data_source_block           K5Mo4O16Yb1
_cod_original_formula_sum        'K5 Mo4 O16 Yb1'
_cod_database_code               1532946
Neutron diffraction study of the magnetic structures of one-dimensional M2 Tb F6 (M = Li, K, Rb) fluorides: frustration, incommensurability and magnetic interactions
Josse, M.; Dubois, M.; El Ghozzi, M.; Guillot, M.; Avignant, D.; Bouree, F.; Andre, G.; Journal of Alloys Compd. 374 (2004) 207–212; doi:

data_1532947
_publ_section_title
;
 Neutron diffraction study of the magnetic structures of one-dimensional
 M2 Tb F6 (M = Li, K, Rb) fluorides: frustration, incommensurability and
 magnetic interactions
;
_journal_name_full               'Journal of Alloys Compd.'
_journal_page_first              207
_journal_page_last               212
_journal_volume                  374
_journal_year                    2004
_chemical_formula_sum            'F6 Rb2 Tb'
_chemical_name_systematic        'Rb2 (Tb F6)'
_space_group_IT_number           15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 91.358
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.8298
_cell_length_b                   11.8385
_cell_length_c                   7.2013
_cell_volume                     582.095
_citation_journal_id_ASTM        JALCEU
_cod_data_source_file            Josse_JALCEU_2004_1502.cif
_cod_data_source_block           F6Rb2Tb1
_cod_original_cell_volume        582.0946
_cod_original_formula_sum        'F6 Rb2 Tb1'
_cod_database_code               1532947
Crystal structure refinement of Cux Ag1-x In Te2 bulk material determined from X-ray powder diffraction data using the Rietveld method
Moustafa, A.M.; El-Sayad, E.A.; Sakr, G.B.; Crystal Research and Technology 39 (2004) 266–273; doi:

data_1532948
_publ_section_title
;
 Crystal structure refinement of Cux Ag1-x In Te2 bulk material determined
 from X-ray powder diffraction data using the Rietveld method
;
_journal_name_full               'Crystal Research and Technology'
_journal_page_first              266
_journal_page_last               273
_journal_volume                  39
_journal_year                    2004
_chemical_formula_sum            'Cu1.05 In1.03 Te1.92'
_space_group_IT_number           122
_symmetry_space_group_name_Hall  'I -4 2bw'
_symmetry_space_group_name_H-M   'I -4 2 d'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.19288
_cell_length_b                   6.19288
_cell_length_c                   12.42323
_cell_volume                     476.453
_citation_journal_id_ASTM        CRTEDF
_cod_data_source_file            Moustafa_CRTEDF_2004_1253.cif
_cod_data_source_block           Cu1.05In1.03Te1.92
_cod_original_cell_volume        476.4528
_cod_database_code               1532948
Synthesis and crystal structures of new mixed-valence terbium (III/IV) fluorides with a random distribution between Tb(3+) and Tb(4+)
Josse, M.; Dubois, M.; El Ghozzi, M.; Avignant, D.; Journal of Alloys Compd. 374 (2004) 213–218; doi:

data_1532949
_publ_section_title
;
 Synthesis and crystal structures of new mixed-valence terbium (III/IV)
 fluorides with a random distribution between Tb(3+) and Tb(4+)
;
_journal_name_full               'Journal of Alloys Compd.'
_journal_page_first              213
_journal_page_last               218
_journal_volume                  374
_journal_year                    2004
_chemical_formula_sum            'Al F16 Rb2 Tb3'
_chemical_name_systematic        'Rb2 Al (Tb3 F16)'
_space_group_IT_number           194
_symmetry_space_group_name_Hall  '-P 6c 2c'
_symmetry_space_group_name_H-M   'P 63/m m c'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            2
_cell_length_a                   7.556
_cell_length_b                   7.556
_cell_length_c                   12.397
_cell_volume                     612.959
_citation_journal_id_ASTM        JALCEU
_cod_data_source_file            Josse_JALCEU_2004_1503.cif
_cod_data_source_block           Al1F16Rb2Tb3
_cod_original_cell_volume        612.9586
_cod_original_formula_sum        'Al1 F16 Rb2 Tb3'
_cod_database_code               1532949
Ca2 Ir D5: an order-disorder transition
Moyer, R.O.jr.; Toby, B.H.; Journal of Alloys Compd. 363 (2004) 99–103; doi:

data_1532950
_publ_section_title
;
 Ca2 Ir D5: an order-disorder transition
;
_journal_name_full               'Journal of Alloys Compd.'
_journal_page_first              99
_journal_page_last               103
_journal_volume                  363
_journal_year                    2004
_chemical_formula_sum            'Ca2 D5.12 Ir'
_chemical_name_systematic        'Ca2 Ir D5.12'
_space_group_IT_number           225
_symmetry_space_group_name_Hall  '-F 4 2 3'
_symmetry_space_group_name_H-M   'F m -3 m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.2479
_cell_length_b                   7.2479
_cell_length_c                   7.2479
_cell_volume                     380.747
_citation_journal_id_ASTM        JALCEU
_cod_data_source_file            Moyer_JALCEU_2004_1341.cif
_cod_data_source_block           D5.12Ca2Ir1
_cod_original_cell_volume        380.7471
_cod_original_formula_sum        'D5.12 Ca2 Ir1'
_cod_database_code               1532950
Synthesis and crystal structures of new mixed-valence terbium(III/IV) fluorides with a random distribution between Tb(3+) and Tb(4+)
Josse, M.; Dubois, M.; El Ghozzi, M.; Avignant, D.; Journal of Alloys Compd. 374 (2004) 213–218; doi:

data_1532951
_publ_section_title
;
 Synthesis and crystal structures of new mixed-valence terbium(III/IV)
 fluorides with a random distribution between Tb(3+) and Tb(4+)
;
_journal_name_full               'Journal of Alloys Compd.'
_journal_page_first              213
_journal_page_last               218
_journal_volume                  374
_journal_year                    2004
_chemical_formula_sum            'Al2 F22 Rb Tb4'
_chemical_name_systematic        'Rb Al2 (Tb4 F22)'
_space_group_IT_number           139
_symmetry_space_group_name_Hall  '-I 4 2'
_symmetry_space_group_name_H-M   'I 4/m m m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.662
_cell_length_b                   10.662
_cell_length_c                   6.911
_cell_volume                     785.630
_citation_journal_id_ASTM        JALCEU
_cod_data_source_file            Josse_JALCEU_2004_1505.cif
_cod_data_source_block           Al2F22Rb1Tb4
_cod_original_cell_volume        785.6302
_cod_original_formula_sum        'Al2 F22 Rb1 Tb4'
_cod_database_code               1532951