Silver(I) complexes with <i>N</i>-methylphenothiazine as potential antimicrobial agents with a multi-target mode of action.
Andrejević, Tina P; Branković, Jovica; Ilic-Tomic, Tatjana; Stevanović, Nevena; Pantović, Bojana; Ašanin, Darko P; Nikodinovic-Runic, Jasmina; Petrović, Vladimir P; Marković, Violeta R; Glišić, Biljana Đ; Dalton transactions (Cambridge, England : 2003) 55 (2026) 3460–3474; doi:10.1039/d5dt02898a

data_7720095
_publ_section_title
;
 Silver(I) complexes with <i>N</i>-methylphenothiazine as potential
 antimicrobial agents with a multi-target mode of action.
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3460
_journal_page_last               3474
_journal_paper_doi               10.1039/d5dt02898a
_journal_volume                  55
_journal_year                    2026
_chemical_formula_sum            'C53 H44.67 Ag F3 N4 O3.33 S5'
_chemical_formula_weight         1116.09
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2019/3
_audit_update_record
;
2026-01-16 deposited with the CCDC.	2026-01-21 downloaded from the CCDC.
;
_cell_angle_alpha                78.6520(17)
_cell_angle_beta                 76.3114(17)
_cell_angle_gamma                87.9851(14)
_cell_formula_units_Z            2
_cell_length_a                   12.1078(2)
_cell_length_b                   12.8639(2)
_cell_length_c                   16.6110(4)
_cell_measurement_reflns_used    46307
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.3930
_cell_measurement_theta_min      2.7090
_cell_volume                     2464.42(8)
_computing_cell_refinement       'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.49 (Rigaku OD, 2022)'
_computing_structure_refinement  'SHELXL-2019/2 (Sheldrick, 2019)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 16.3280
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0370
_diffrn_reflns_av_unetI/netI     0.0162
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            103061
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.372
_diffrn_reflns_theta_min         2.251
_diffrn_source                   'fine-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    0.682
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.86328
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
CrysAlisPro 1.171.42.49 (Rigaku Oxford Diffraction, 2022) 
Empirical absorption correction using spherical harmonics, 
implemented in SCALE3 ABSPACK scaling algorithm. 
;
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.504
_exptl_crystal_description       plate
_exptl_crystal_F_000             1143
_exptl_crystal_size_max          0.862
_exptl_crystal_size_mid          0.618
_exptl_crystal_size_min          0.180
_refine_diff_density_max         1.003
_refine_diff_density_min         -0.607
_refine_diff_density_rms         0.052
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     731
_refine_ls_number_reflns         10084
_refine_ls_number_restraints     14
_refine_ls_restrained_S_all      1.013
_refine_ls_R_factor_all          0.0476
_refine_ls_R_factor_gt           0.0387
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0529P)^2^+1.8222P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0999
_refine_ls_wR_factor_ref         0.1064
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8510
_reflns_number_total             10084
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5dt02898a2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7720093--7720095.cif.'
_cod_original_cell_volume        2464.41(9)
_cod_database_code               7720095
_shelx_shelxl_version_number     2019/3
_shelx_estimated_absorpt_t_min   0.591
_shelx_estimated_absorpt_t_max   0.887
_shelx_res_checksum              84827