Synthesis and Structure of New Binuclear Organopalladium Macrocyclic Complexes
Tsubomura, Taro; Tanihata, Takayuki; Yamakawa, Tetsuya; Ohmi, Rakuko; Tamane, Tsuyoshi; Higuchi, Akon; Katoh, Akira; Sakai, Ken; Organometallics 20 (2001) 3833–; doi:10.1021/om0103862

data_4077366
_publ_section_title
;
 Synthesis and Structure of New Binuclear Organopalladium Macrocyclic
 Complexes
;
_journal_issue                   18
_journal_name_full               Organometallics
_journal_page_first              3833
_journal_paper_doi               10.1021/om0103862
_journal_volume                  20
_journal_year                    2001
_chemical_formula_moiety         'C26 H38 Br2 N4 Pd2 '
_chemical_formula_sum            'C26 H38 Br2 N4 Pd2'
_chemical_formula_weight         779.22
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_cell_angle_alpha                90
_cell_angle_beta                 104.77(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   16.545(7)
_cell_length_b                   10.210(3)
_cell_length_c                   8.428(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      14.9
_cell_measurement_theta_min      14.2
_cell_volume                     1376.7(9)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 1.0503
_diffrn_measured_fraction_theta_max 1.0503
_diffrn_measurement_device_type  'Rigaku AFC5S'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.082
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            8300
_diffrn_reflns_theta_full        29.99
_diffrn_reflns_theta_max         29.99
_diffrn_standards_decay_%        3.67
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.241
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_correction_T_min  0.768
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            pale
_exptl_crystal_density_diffrn    1.880
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.62
_refine_diff_density_min         -1.85
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.975
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     154
_refine_ls_number_reflns         4010
_refine_ls_R_factor_gt           0.0439
_refine_ls_shift/su_max          0.0089
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.04000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1027
_reflns_number_gt                2282
_reflns_number_total             4215
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om0103862.cif
_cod_data_source_block           '[PdBr2L]_Z-shape'
_cod_original_cell_volume        1376.6(9)
_cod_original_formula_sum        'C26 H38 Br2 N4 Pd2 '
_cod_database_code               4077366