Rigid versus semi-rigid bis(imidazole) ligands in the assembly of two Co(ii) coordination polymers: structural variability, electrochemical properties and photocatalytic behavior.
Cui, Jing-Wang; Hou, Suo-Xia; Van Hecke, Kristof; Cui, Guang-Hua; Dalton transactions (Cambridge, England : 2003) 46 (2017) 2892–2903; doi:10.1039/c6dt04626f

data_7041919
_publ_section_title
;
 Rigid versus semi-rigid bis(imidazole) ligands in the assembly of two
 Co(ii) coordination polymers: structural variability, electrochemical
 properties and photocatalytic behavior.
;
_journal_issue                   9
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2892
_journal_page_last               2903
_journal_paper_doi               10.1039/c6dt04626f
_journal_volume                  46
_journal_year                    2017
_chemical_formula_sum            'C34 H52 Co5 N4 O28'
_chemical_formula_weight         1259.44
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-11-08 deposited with the CCDC.
2017-01-31 downloaded from the CCDC.
;
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_cell_angle_gamma                81.4270(10)
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_cell_volume                     1065.61(18)
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_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine--focus sealed tube'
_diffrn_radiation_type           MoK\a
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0560P)^2^+0.5600P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0942
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_reflns_number_gt                4091
_reflns_number_total             4715
_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7041919--7041920.cif.'
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