Sterically induced transmutations in cobalt amine chemistry
Geue, Rodney J.; Jin Qin, C.; Ralph, Stephen F.; Sargeson, Alan M.; Skelton, Brian W.; White, Allan H.; Willis, Anthony C.; Chemical Communications  (1999) 2351–2352; doi:10.1039/a907237c

data_7110709
_publ_section_title
;
 Sterically induced transmutations in cobalt amine chemistry
;
_journal_coden_ASTM              CHCOFS
_journal_issue                   23
_journal_name_full               'Chemical Communications'
_journal_page_first              2351
_journal_page_last               2352
_journal_paper_doi               10.1039/a907237c
_journal_year                    1999
_chemical_formula_moiety         'C25 H54 Co N6, (Cl4 Zn)'
_chemical_formula_sum            'C25 H54 Cl4 Co N6 Zn'
_chemical_formula_weight         704.87
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      60
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_audit_creation_date             1999-09-13
_audit_creation_method           'by teXsan v1.8'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.733(4)
_cell_length_b                   19.038(4)
_cell_length_c                   15.678(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      15.8
_cell_measurement_theta_min      10.9
_cell_volume                     3203.6(16)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan (MSC, 1992-1997)'
_computing_publication_material  'teXsan (MSC, 1992-1997)'
_computing_structure_refinement  'teXsan (MSC, 1992-1997)'
_computing_structure_solution
;
SHELXS86 (Sheldrick, 1985)
;
_diffrn_ambient_temperature      296.2
_diffrn_measurement_device_type  'Rigaku AFC6S'
_diffrn_measurement_method       \w-2\q
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_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_av_R_equivalents  0.00000
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_diffrn_reflns_limit_k_min       0
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_diffrn_reflns_limit_l_min       -18
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_diffrn_reflns_theta_max         25.04
_diffrn_reflns_theta_min         1.89
_diffrn_standards_decay_%        -1.97
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_exptl_absorpt_process_details
;
analytical (de Meulenaer & Tompa, 1965)
;
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_refine_ls_structure_factor_coef F
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_cod_data_source_block           cjq14
_cod_depositor_comments
;
 Updated bibliographic information.

 Antanas Vaitkus,
 2020-10-02

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'w = 1/[\s^2^(Fo) +
0.000006|Fo|^2^]' was changed to 'calc'. New tag
'_refine_ls_weighting_details' was created. The value of the new tag
was set to 'w = 1/[\s^2^(Fo) + 0.000006|Fo|^2^]'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        3204(3)
_cod_original_sg_symbol_H-M      'P b c n    '
_cod_original_formula_sum        'C25 H54 Cl4 Co N6 Zn '
_cod_database_code               7110709