Pd-Catalyzed double carbopalladation/<i>syn</i>-insertion cascade reactions toward medium-size sulfoximine heterocycles.
Dai, Longji; Yuan, Jianjun; Wu, Cui; Chen, Zhiyuan; Chemical communications (Cambridge, England) 57 (2021) 4271–4274; doi:10.1039/d1cc00846c

data_7128120
_publ_section_title
;
 Pd-Catalyzed double carbopalladation/<i>syn</i>-insertion cascade
 reactions toward medium-size sulfoximine heterocycles.
;
_journal_issue                   35
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              4271
_journal_page_last               4274
_journal_paper_doi               10.1039/d1cc00846c
_journal_volume                  57
_journal_year                    2021
_chemical_formula_sum            'C29 H21 N O S'
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_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-01-27 deposited with the CCDC.	2021-03-22 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0560P)^2^+2.1216P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             7834
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cc00846c2.cif
_cod_data_source_block           1
_cod_depositor_comments
;
         Adding full bibliography for 7128120.cif.

2024-09-02
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C58 H42 N2 O2 S2'
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_cod_original_formula_units_Z            4
_cod_original_sg_symbol_H-M      'P 21/n'
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_shelx_estimated_absorpt_t_max   0.956
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