Stereoselective Preparation, Structures, and Reactivities of Phosphine-Bridged Mixed-Metal Trinuclear and Pentanuclear Complexes with Tris[2-(diphenylphosphino)ethyl]phosphine
Aizawa, Sen-ichi; Saito, Kenji; Kawamoto, Tatsuya; Matsumoto, Emi; Inorganic Chemistry 45 (2006) 4859–4866; doi:10.1021/ic060277l

data_4332358
_publ_section_title
;
 Stereoselective Preparation, Structures, and Reactivities of
 Phosphine-Bridged Mixed-Metal Trinuclear and Pentanuclear Complexes with
 Tris[2-(diphenylphosphino)ethyl]phosphine
;
_journal_issue                   12
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4859
_journal_page_last               4866
_journal_paper_doi               10.1021/ic060277l
_journal_volume                  45
_journal_year                    2006
_chemical_formula_moiety         'C92 H98 Cl6 N4 O P8 Pd2 Pt '
_chemical_formula_sum            'C92 H98 Cl6 N4 O P8 Pd2 Pt'
_chemical_formula_weight         2144.21
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 114.06(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   20.121(6)
_cell_length_b                   27.80(1)
_cell_length_c                   18.758(5)
_cell_measurement_reflns_used    20
_cell_measurement_temperature    296.1
_cell_measurement_theta_max      13.9
_cell_measurement_theta_min      12.7
_cell_volume                     9581(5)
_computing_cell_refinement       WinAFC
_computing_data_collection       WinAFC
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_computing_publication_material  'CrystalStructure Ver. 3.5.1'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SHELXS86
_diffrn_measured_fraction_theta_full 0.8146
_diffrn_measured_fraction_theta_max 0.8146
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
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_diffrn_standards_interval_count 150
_diffrn_standards_number         3
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_exptl_absorpt_correction_T_min  0.579
_exptl_absorpt_correction_type   psi-scans
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.487
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       diamond-shap
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_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.25
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_cod_original_cell_volume        9579(5)
_cod_original_formula_sum        'C92 H98 Cl6 N4 O P8 Pd2 Pt '
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