Are ionic liquids and liquid coordination complexes really different? - Synthesis, characterization, and catalytic activity of AlCl<sub>3</sub>/base catalysts.
Kore, Rajkumar; Kelley, Steven P.; Sawant, Anand D.; Mishra, Manish Kumar; Rogers, Robin D.; Chemical communications (Cambridge, England) 56 (2020) 5362–5365; doi:10.1039/d0cc01452d

data_7126284
_publ_section_title
;
 Are ionic liquids and liquid coordination complexes really different? -
 Synthesis, characterization, and catalytic activity of
 AlCl<sub>3</sub>/base catalysts.
;
_journal_issue                   40
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              5362
_journal_page_last               5365
_journal_paper_doi               10.1039/d0cc01452d
_journal_volume                  56
_journal_year                    2020
_chemical_formula_sum            'C16 H22 Al1.33 Cl4 N2 O2'
_chemical_formula_weight         452.13
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2019-12-11 deposited with the CCDC.	2020-03-27 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 93.890(6)
_cell_angle_gamma                90
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_cell_length_c                   24.213(13)
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_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.999
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_cell_volume                     6834(6)
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 0.3
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'bruker siemens'
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_diffrn_reflns_av_unetI/netI     0.1461
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       27
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_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.318
_exptl_crystal_description       Block
_exptl_crystal_F_000             2800
_exptl_crystal_size_max          0.150
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_refine_diff_density_max         1.166
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3377
_refine_ls_wR_factor_ref         0.3950
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2584
_reflns_number_total             6707
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0cc01452d2.cif
_cod_data_source_block           LC
_cod_depositor_comments
'Adding full bibliography for 7126284--7126285.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7126284
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.918
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_shelx_res_checksum              8253