Deposition of metallic silver coatings by Aerosol Assisted MOCVD using two new silver β-Diketonate adduct metalorganic precursors
Liu, Hongjun; Battiato, Sergio; Pellegrino, Anna Lucia; Paoli, Paola; Jiménez, Carmen; Rossi, Patrizia; Malandrino, Graziella; Muñoz-Rojas, David; Dalton Trans.  (2017) –; doi:10.1039/C7DT01647F

data_7043670
_publ_section_title
;
 Deposition of metallic silver coatings by Aerosol Assisted MOCVD using
 two new silver \b-Diketonate adduct metalorganic precursors
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT01647F
_journal_year                    2017
_chemical_formula_sum            'C17 H9 Ag F6 N2 O2'
_chemical_formula_weight         495.13
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   difmap
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2017-06-12 deposited with the CCDC.
2017-07-17 downloaded from the CCDC.
;
_cell_angle_alpha                102.579(4)
_cell_angle_beta                 105.172(4)
_cell_angle_gamma                103.608(4)
_cell_formula_units_Z            2
_cell_length_a                   7.4309(3)
_cell_length_b                   9.2288(4)
_cell_length_c                   13.1426(6)
_cell_measurement_reflns_used    5861
_cell_measurement_temperature    100
_cell_measurement_theta_max      71.8270
_cell_measurement_theta_min      5.1440
_cell_volume                     807.10(7)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35g (release 09-12-2014 CrysAlis171 .NET)
(compiled Dec  9 2014,15:38:47)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35g (release 09-12-2014 CrysAlis171 .NET)
(compiled Dec  9 2014,15:38:47)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35g (release 09-12-2014 CrysAlis171 .NET)
(compiled Dec  9 2014,15:38:47)
;
_computing_molecular_graphics    'ORTEP-3 (Farruggia, 1997)'
_computing_publication_material  'PARST97 (Nardelli, 1995)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2014)'
_computing_structure_solution    'Sir2004 (Burla, 2004)'
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean 8.1241
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.954
_diffrn_measurement_device_type  'Xcalibur, Onyx'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0617
_diffrn_reflns_av_unetI/netI     0.0569
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.954
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            8748
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.954
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         72.336
_diffrn_reflns_theta_min         5.165
_exptl_absorpt_coefficient_mu    10.823
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.09227
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35g (release 09-12-2014 CrysAlis171 .NET)
(compiled Dec  9 2014,15:38:47)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.037
_exptl_crystal_description       prism
_exptl_crystal_F_000             484
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.081
_refine_diff_density_min         -1.261
_refine_diff_density_rms         0.206
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.115
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     295
_refine_ls_number_reflns         3045
_refine_ls_number_restraints     46
_refine_ls_restrained_S_all      1.110
_refine_ls_R_factor_all          0.0565
_refine_ls_R_factor_gt           0.0407
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0452P)^2^+4.2951P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0934
_refine_ls_wR_factor_ref         0.1169
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2573
_reflns_number_total             3045
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7dt01647f2.cif
_cod_data_source_block           AgP
_cod_original_cell_volume        807.10(6)
_cod_database_code               7043670
_shelxl_version_number           2014-1
_shelx_res_checksum              42299