Bis([μ-bis(diphenylphosphino)methane-1:2κ^2^<i>P</i>:<i>P</i>']nonacarbonyl-1κ^3^<i>C</i>,2κ^3^<i>C</i>,3κ^3^<i>C</i>-{tris[4-(methylsulfanyl)phenyl]arsine-3κ<i>As</i>}-<i>triangulo</i>-triruthenium(0)) dichloromethane monosolvate
bin Shawkataly, Omar; Khan, Imthyaz Ahmed; Sirat, Siti Syaida; Yeap, Chin Sing; Fun, Hoong-Kun; Acta Crystallographica Section E 66 (2010) m1150–m1151; doi:10.1107/S160053681003093X

data_2227663
_publ_section_title
;
 Bis([\m-bis(diphenylphosphino)methane-1:2\k^2^<i>P</i>:<i>P</i>']nonacarbonyl-1\k^3^<i>C</i>,2\k^3^<i>C</i>,3\k^3^<i>C</i>-{tris[4-(methylsulfanyl)phenyl]arsine-3\k<i>As</i>}-<i>triangulo</i>-triruthenium(0))
 dichloromethane monosolvate
;
_journal_coeditor_code           IS2583
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1150
_journal_page_last               m1151
_journal_paper_doi               10.1107/S160053681003093X
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac
'2[Ru3 (C21 H21 As S3) (C25 H22 P2) (C O)9], C H2 Cl2'
_chemical_formula_moiety         '2(C55 H43 As O9 P2 Ru3 S3), C H2 Cl2'
_chemical_formula_sum            'C111 H88 As2 Cl2 O18 P4 Ru6 S6'
_chemical_formula_weight         2853.21
_chemical_name_systematic
;
Bis([\m-bis(diphenylphosphino)methane-1:2\k^2^<i>P</i>:<i>P</i>']nonacarbonyl-
1\k^3^<i>C</i>,2\k^3^<i>C</i>,3\k^3^<i><i>C</i></i>-
{tris[4-(methylsulfanyl)phenyl]arsine-3\k<i>As</i>}-<i>triangulo</i>-
triruthenium(0)) dichloromethane monosolvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.5390(10)
_cell_angle_beta                 98.2280(10)
_cell_angle_gamma                103.2120(10)
_cell_formula_units_Z            1
_cell_length_a                   10.80770(10)
_cell_length_b                   12.6180(2)
_cell_length_c                   20.9478(3)
_cell_measurement_reflns_used    9102
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      34.91
_cell_measurement_theta_min      2.34
_cell_volume                     2733.84(7)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'APEX2 (Bruker, 2009)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material
;
SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009)
;
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      100
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type
;
Bruker SMART APEXII CCD area-detector diffractometer
;
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0361
_diffrn_reflns_av_sigmaI/netI    0.0197
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            305620
_diffrn_reflns_theta_full        35.19
_diffrn_reflns_theta_max         35.19
_diffrn_reflns_theta_min         1.67
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.697
_exptl_absorpt_correction_T_max  0.7861
_exptl_absorpt_correction_T_min  0.5826
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(<i>SADABS</i>; Bruker, 2009)'
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.733
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1418
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.496
_refine_diff_density_min         -1.343
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.076
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     679
_refine_ls_number_reflns         24183
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.076
_refine_ls_R_factor_all          0.0423
_refine_ls_R_factor_gt           0.0312
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0210P)^2^+4.6125P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0641
_refine_ls_wR_factor_ref         0.0701
_reflns_number_gt                20753
_reflns_number_total             24183
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            is2583.cif
_cod_data_source_block           I
_cod_original_cell_volume        2733.83(6)
_cod_database_code               2227663
_cod_database_fobs_code          2227663