Bridged poly(1-imidazolyl)borate silver(I) complexes containing tertiary mono(phosphine) ligands. The first structurally authenticated bis(imidazolyl)borate metal complex †
Gioia Lobbia, Giancarlo; Pellei, Maura; Pettinari, Claudio; Santini, Carlo; Skelton, Brian W.; White, Allan H.; Journal of the Chemical Society, Dalton Transactions  (2001) 528–; doi:10.1039/b008135n

data_7010346
_publ_section_title
;
 Bridged poly(1-imidazolyl)borate silver(I) complexes containing
 tertiary mono(phosphine) ligands. The first structurally authenticated
 bis(imidazolyl)borate metal complex&#x200A;&#x2020;
;
_journal_issue                   5
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              528
_journal_paper_doi               10.1039/b008135n
_journal_year                    2001
_chemical_formula_sum            'C98 H159 Ag2 B2 N17 P4'
_chemical_formula_weight         1936.72
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                112.26(2)
_cell_angle_beta                 102.07(2)
_cell_angle_gamma                99.520(10)
_cell_formula_units_Z            2
_cell_length_a                   18.313(2)
_cell_length_b                   13.177(3)
_cell_length_c                   12.025(4)
_cell_measurement_reflns_used    8
_cell_measurement_temperature    293
_cell_measurement_theta_max      17.1
_cell_measurement_theta_min      14.0
_cell_volume                     2528.4(12)
_computing_cell_refinement       'Enraf Nonius software'
_computing_data_collection       'Enraf Nonius software'
_computing_data_reduction        xtal
_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  xtal
_computing_structure_solution    xtal
_diffrn_ambient_temperature      293
_diffrn_measurement_device_type
;
 CAD4 diffractometer
;
_diffrn_measurement_method       '2\q-\w scans'
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            8890
_diffrn_reflns_theta_max         25.0
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  60
_diffrn_standards_number         8
_exptl_absorpt_coefficient_mu    .504
_exptl_absorpt_correction_T_max  .86
_exptl_absorpt_correction_T_min  .74
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
 XTAL absorb                
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.272
_exptl_crystal_description       block
_exptl_crystal_F_000             1030
_exptl_crystal_size_max          .38
_exptl_crystal_size_mid          .66
_exptl_crystal_size_min          .42
_refine_diff_density_max         .78
_refine_diff_density_min         -.54
_refine_ls_goodness_of_fit_all   1.71
_refine_ls_goodness_of_fit_ref   1.84
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           atomblock
_refine_ls_number_constraints    0
_refine_ls_number_parameters     576
_refine_ls_number_reflns         7060
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .054
_refine_ls_R_factor_gt           .044
_refine_ls_shift/su_max          .099
_refine_ls_shift/su_mean         .0029
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         .052
_refine_ls_wR_factor_ref         .050
_reflns_limit_h_max              21
_reflns_limit_h_min              0
_reflns_limit_k_max              15
_reflns_limit_k_min              -15
_reflns_limit_l_max              12
_reflns_limit_l_min              -13
_reflns_number_gt                7060
_reflns_number_observed          7060
_reflns_number_total             8890
_reflns_threshold_expression     'I    > 3.00 sig(I   )'
_cod_data_source_file            b008135n.txt
_cod_data_source_block           cpztp
_cod_depositor_comments
;
The following automatic conversions were performed:
'_refine_ls_matrix_type' value 'atom-block' changed to 'atomblock'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_Hall     -p_1
_cod_original_sg_symbol_H-M      P_-1
_cod_database_code               7010346