Re-evaluating selectivity as a determining factor in peroxidative methane oxidation by multimetallic copper complexes
Palomas, David; Kalamaras, Christos; Haycock, Peter; White, Andrew J. P.; Hellgardt, Klaus; Horton, Andrew; Crimmin, Mark R.; Catal. Sci. Technol. 5 (2015) 4108–; doi:10.1039/C5CY00462D

data_1520579
_publ_section_title
;
 Re-evaluating selectivity as a determining factor in peroxidative methane
 oxidation by multimetallic copper complexes
;
_journal_issue                   8
_journal_name_full               'Catal. Sci. Technol.'
_journal_page_first              4108
_journal_paper_doi               10.1039/C5CY00462D
_journal_volume                  5
_journal_year                    2015
_chemical_formula_moiety         'C24 H52 B4 Cu4 N4 O17, 2(B F4)'
_chemical_formula_sum            'C24 H52 B6 Cu4 F8 N4 O17'
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;
 ?
;
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2014-10-08 deposited with the CCDC.
2015-06-18 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.33a (release 28-03-2014 CrysAlis171 .NET)
(compiled Mar 28 2014,12:25:20)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Green
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0363P)^2^+11.7959P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                3590
_reflns_number_total             4161
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 1520578--1520579.cif.'
_cod_database_code               1520579
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