A high-performance Co-MOF non-enzymatic electrochemical sensor for glucose detection
Ma, Zhen-Zhen; Ma, Yao; Liu, Bing; Xu, Ling; Jiao, Huan; New Journal of Chemistry 45 (2021) 21350–21358; doi:10.1039/D1NJ04480J

data_7061059
_publ_section_title
;
 A high-performance Co-MOF non-enzymatic electrochemical sensor for
 glucose detection
;
_journal_issue                   45
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              21350
_journal_page_last               21358
_journal_paper_doi               10.1039/D1NJ04480J
_journal_volume                  45
_journal_year                    2021
_chemical_formula_sum            'C48 H60 Co3 N6 O20'
_chemical_formula_weight         1217.81
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_block_doi                 10.5517/ccdc.csd.cc28stc8
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-10-19 deposited with the CCDC.	2021-10-21 downloaded from the CCDC.
;
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_cell_angle_beta                 93.6060(10)
_cell_angle_gamma                90
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_cell_length_b                   9.70870(10)
_cell_length_c                   18.40350(10)
_cell_measurement_reflns_used    21138
_cell_measurement_temperature    179.99(10)
_cell_measurement_theta_max      75.8790
_cell_measurement_theta_min      2.6830
_cell_volume                     5857.02(8)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      179.99(10)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'XtaLAB Synergy R, HyPix'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0308
_diffrn_reflns_av_unetI/netI     0.0211
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_limit_h_max       40
_diffrn_reflns_limit_h_min       -41
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_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.577
_diffrn_reflns_theta_min         1.242
_exptl_absorpt_coefficient_mu    0.914
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.381
_exptl_crystal_description       block
_exptl_crystal_F_000             2524
_exptl_crystal_size_max          0.03
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.01
_refine_diff_density_max         1.369
_refine_diff_density_min         -0.763
_refine_diff_density_rms         0.170
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
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_refine_ls_restrained_S_all      1.134
_refine_ls_R_factor_all          0.0834
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1260P)^2^+58.7195P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2371
_refine_ls_wR_factor_ref         0.2399
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5676
_reflns_number_total             6002
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1nj04480j2.cif
_cod_data_source_block           15
_cod_depositor_comments
'Adding full bibliography for 7061058--7061059.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7061059
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              68126