Phosphasilene mediated CO activation and deoxygenative homo coupling of CO molecules in reactions with metal carbonyls.
Hendi, Zohreh; Pradhan, Renuka; Rachuy, Katharina; Mahmoudi, Soheil; Pandey, Madhusudan K.; Kushvaha, Saroj Kumar; Herbst-Irmer, Regine; Lourderaj, Upakarasamy; Stalke, Dietmar; Roesky, Herbert W.; Chemical science 15 (2024) 18888–18895; doi:10.1039/d4sc05491a

data_1572867
_publ_section_title
;
 Phosphasilene mediated CO activation and deoxygenative homo coupling of
 CO molecules in reactions with metal carbonyls.
;
_journal_issue                   45
_journal_name_full               'Chemical science'
_journal_page_first              18888
_journal_page_last               18895
_journal_paper_doi               10.1039/d4sc05491a
_journal_volume                  15
_journal_year                    2024
_chemical_formula_moiety         'C36 H61 N2 P Si2'
_chemical_formula_sum            'C36 H61 N2 P Si2'
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_audit_update_record
;
2023-11-30 deposited with the CCDC.	2024-10-09 downloaded from the CCDC.
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0538P)^2^+0.8813P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4sc05491a2.cif
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_cod_depositor_comments
'Adding full bibliography for 1572866--1572869.cif.'
_cod_original_cell_volume        3789.7(11)
_cod_original_sg_symbol_H-M      'P 21/n'
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