A π-conjugated inorganic polymer constructed from boron difluoride formazanates and platinum(ii) diynes.
Dhindsa, Jasveer S.; Maar, Ryan R.; Barbon, Stephanie M.; Olivia Avilés, María; Powell, Zachary K.; Lagugné-Labarthet, François; Gilroy, Joe B.; Chemical communications (Cambridge, England) 54 (2018) 6899–6902; doi:10.1039/c8cc02424c

data_7121737
_publ_section_title
;
 A \p-conjugated inorganic polymer constructed from boron difluoride
 formazanates and platinum(ii) diynes.
;
_journal_issue                   50
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              6899
_journal_page_last               6902
_journal_paper_doi               10.1039/c8cc02424c
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C66 H82 B2 F4 N8 P2 Pt'
_chemical_formula_weight         1342.04
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2018-03-08 deposited with the CCDC.
2018-05-17 downloaded from the CCDC.
;
_cell_angle_alpha                106.564(16)
_cell_angle_beta                 90.122(12)
_cell_angle_gamma                95.097(16)
_cell_formula_units_Z            1
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_cell_measurement_temperature    110
_cell_measurement_theta_max      35.15
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_cell_volume                     1633.7(9)
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_computing_structure_refinement  SHELXL
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_diffrn_ambient_temperature      110
_diffrn_detector                 'CCD plate'
_diffrn_detector_type            'Bruker Apex2'
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.887
_diffrn_measurement_device       '\k-geometry diffractometer'
_diffrn_measurement_device_type  'Bruker Kappa Axis Apex2'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0363
_diffrn_reflns_av_unetI/netI     0.0700
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_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -16
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_diffrn_reflns_point_group_measured_fraction_max 0.887
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_diffrn_reflns_theta_max         41.581
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_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    2.253
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            blue
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_exptl_crystal_description       block
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_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
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_refine_ls_number_reflns         19782
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.003
_refine_ls_R_factor_all          0.0550
_refine_ls_R_factor_gt           0.0414
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0302P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0642
_refine_ls_wR_factor_ref         0.0676
_reflns_Friedel_coverage         0.000
_reflns_number_gt                16988
_reflns_number_total             19782
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8cc02424c2.cif
_cod_data_source_block           3
_cod_depositor_comments          'Adding full bibliography for 7121737.cif.'
_cod_original_cell_volume        1633.7(10)
_cod_database_code               7121737
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.623
_shelx_estimated_absorpt_t_max   0.882
_shelx_res_checksum              6228