{Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ^3^<i>P</i>,<i>P</i>',<i>P</i>''}[(<i>Z</i>)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate
Zhao, Shu-Bin; Wang, Rui-Yao; Gagné, Michel R.; Acta Crystallographica Section E 67 (2011) m972–; doi:10.1107/S1600536811023853

data_2230756
_publ_section_title
;
 {Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-\k^3^<i>P</i>,<i>P</i>',<i>P</i>''}[(<i>Z</i>)-8-mesitylcyclooct-4-en-1-yl]platinum(II)
 tetrafluoridoborate dichloromethane disolvate
;
_journal_coeditor_code           JH2297
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m972
_journal_paper_doi               10.1107/S1600536811023853
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac
'[Pt (C17 H23) (C34 H33 P3)] (B F4), 2C H2 Cl2'
_chemical_formula_moiety         'C51 H56 P3 Pt +, B F4 -, C2 H4 Cl4'
_chemical_formula_structural     'C53 H60 B Cl4 F4 P3 Pt'
_chemical_formula_sum            'C53 H60 B Cl4 F4 P3 Pt'
_chemical_formula_weight         1213.62
_chemical_name_systematic
;
{Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-
\k^3^<i>P</i>,<i>P</i>',<i>P</i>''}[(<i>Z</i>)-8-mesitylcyclooct-4-en-1-
yl]platinum(II) tetrafluoridoborate dichloromethane disolvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                69.4850(10)
_cell_angle_beta                 77.7980(10)
_cell_angle_gamma                87.5160(10)
_cell_formula_units_Z            2
_cell_length_a                   10.1347(2)
_cell_length_b                   14.0808(3)
_cell_length_c                   19.8975(4)
_cell_measurement_reflns_used    9914
_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      27.08
_cell_measurement_theta_min      2.61
_cell_volume                     2597.84(9)
_computing_cell_refinement       'SAINT (Bruker, 2005)'
_computing_data_collection       'APEX2 (Bruker, 2005)'
_computing_data_reduction        'SAINT (Bruker, 2005)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution
'XPREP (Bruker, 2005) and SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      180(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed X-ray tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0173
_diffrn_reflns_av_sigmaI/netI    0.0261
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            18596
_diffrn_reflns_reduction_process '(SAINT; Bruker, 2005)'
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.13
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.049
_exptl_absorpt_correction_T_max  0.7502
_exptl_absorpt_correction_T_min  0.5161
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(XSHELL; Bruker, 1999)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.551
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1220
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.850
_refine_diff_density_min         -0.692
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     655
_refine_ls_number_reflns         10061
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.0244
_refine_ls_R_factor_gt           0.0217
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0239P)^2^+2.7018P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0514
_refine_ls_wR_factor_ref         0.0528
_reflns_number_gt                9410
_reflns_number_total             10061
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            jh2297.cif
_cod_data_source_block           I
_cod_database_code               2230756
_cod_database_fobs_code          2230756