Chiral oxime ethers in asymmetric synthesis. Part 4. Asymmetric synthesis of N-protected amines and β-amino acids by the addition of organometallic reagents to ROPHy/SOPHy-derived aldoximes
Hunt, James C. A.; Lloyd, Cephas; Moody, Christopher J.; Slawin, Alexandra M. Z.; Takle, Andrew K.; Journal of the Chemical Society, Perkin Transactions 1  (1999) 3443–; doi:10.1039/a907186e

data_7213169
_publ_section_title
;
 Chiral oxime ethers in asymmetric synthesis. Part 4. Asymmetric synthesis
 of N-protected amines and \b-amino acids by the addition of
 organometallic reagents to ROPHy/SOPHy-derived aldoximes
;
_journal_issue                   23
_journal_name_full
'Journal of the Chemical Society, Perkin Transactions 1'
_journal_page_first              3443
_journal_paper_doi               10.1039/a907186e
_journal_year                    1999
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_cell_length_b                   7.841(4)
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;
SIR92 (Altomare, et. al. 1993)
;
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;
\DF (DIFABS; Walker & Stuart, 1983)
;
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_refine_ls_extinction_expression 'equ(3) Acta Cryst.(1968) A24, p213.'
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00000|Fo|^2^]'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0254
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_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            907186esup1.cif
_cod_data_source_block           cmex5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'w = 1/[\s^2^(Fo) +
0.00000|Fo|^2^]' was changed to 'calc'. New tag
'_refine_ls_weighting_details' was created. The value of the new tag
was set to 'w = 1/[\s^2^(Fo) + 0.00000|Fo|^2^]'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        703.6(4)
_cod_original_sg_symbol_H-M      'P 21       '
_cod_original_formula_sum        'C14 H16 N2 O S '
_cod_database_code               7213169