[Bis(diphenylphosphino)methane-κ^2^<i>P</i>,<i>P</i>'][bis(diphenylthiophosphinyl)methane-κ^2^<i>S</i>,<i>S</i>']platinum(II) bis(perchlorate) acetone solvate
Alkan, Leman; İrişli, Sevil; Acta Crystallographica Section E 61 (2005) m2706–m2708; doi:10.1107/S1600536805038304

data_2207632
_publ_section_title
;[Bis(diphenylphosphino)methane-\k^2^<i>P</i>,<i>P</i>'][bis(diphenylthiophosphinyl)methane-\k^2^<i>S</i>,<i>S</i>']platinum(II)
 bis(perchlorate) acetone solvate
;
_journal_coeditor_code           RZ6143
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2706
_journal_page_last               m2708
_journal_paper_doi               10.1107/S1600536805038304
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac
'[Pt (C25 H22 P2) (C25 H22 P2 S2)] (Cl O4)2, C3 H6 O'
_chemical_formula_moiety         'C50 H44 P4 Pt S2 2+, 2Cl O4 -, C3 H6 O'
_chemical_formula_sum            'C53 H50 Cl2 O9 P4 Pt S2'
_chemical_formula_weight         1284.92
_chemical_name_systematic
;
[Bis(diphenylphosphino)methane-\k^2^P,P'][bis(diphenylthiophosphinyl)methane-
\k^2^S,S']platinum(II) bis(perchlorate) acetone solvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.686(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.888(2)
_cell_length_b                   11.8633(14)
_cell_length_c                   23.109(3)
_cell_measurement_reflns_used    6151
_cell_measurement_temperature    297(2)
_cell_measurement_theta_max      25.14
_cell_measurement_theta_min      2.33
_cell_volume                     5455.8(11)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2001)'
_diffrn_ambient_temperature      297(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0505
_diffrn_reflns_av_sigmaI/netI    0.0461
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            42618
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         1.57
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.918
_exptl_absorpt_correction_T_max  0.371
_exptl_absorpt_correction_T_min  0.300
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2001)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.564
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2576
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.39
_exptl_crystal_size_min          0.34
_refine_diff_density_max         2.945
_refine_diff_density_min         -2.963
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.255
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     642
_refine_ls_number_reflns         11149
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.255
_refine_ls_R_factor_all          0.0834
_refine_ls_R_factor_gt           0.0763
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0387P)^2^+42.6288P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1584
_refine_ls_wR_factor_ref         0.1616
_reflns_number_gt                10211
_reflns_number_total             11149
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            rz6143.cif
_cod_data_source_block           I
_cod_original_cell_volume        5455.7(11)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2207632
_cod_database_fobs_code          2207632