Monodentate and bridging behaviour of the sulfur-containing ligand 4'-[4-(methylsulfanyl)phenyl]-4,2':6',4''-terpyridine in two discrete zinc(II) complexes with acetylacetonate
Granifo, Juan; Gaviño, Rubén; Freire, Eleonora; Baggio, Ricardo; Acta Crystallographica Section C 68 (2012) m269–m274; doi:10.1107/S010827011203483X

data_2018616
_publ_section_title
;
 Monodentate and bridging behaviour of the sulfur-containing ligand
 4'-[4-(methylsulfanyl)phenyl]-4,2':6',4''-terpyridine in two discrete
 zinc(II) complexes with acetylacetonate
;
_journal_coeditor_code           FA3281
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m269
_journal_page_last               m274
_journal_paper_doi               10.1107/S010827011203483X
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Zn2 (C5 H7 O2)4 (C22 H17 N3 S)]'
_chemical_formula_moiety         'C42 H45 N3 O8 S Zn2'
_chemical_formula_sum            'C42 H45 N3 O8 S Zn2'
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_chemical_name_systematic
;
{\m-4'-[4-(methylsulfanyl)phenyl]-4,2':6',4''-terpyridine-
\k^2^<i>N</i>^1^:<i>N</i>^1''^}bis[bis(acetylacetonato-
\k^2^<i>O</i>,<i>O</i>')zinc(II)]
;
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'SHELXL97 (Sheldrick, 2008) and PLATON (Spek, 2009)'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0451P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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