Reactions of Amides with Organoaluminum Compounds: Factors Affecting the Coordination Mode of Aluminum Amidates
Bor-Hunn Huang; Te-Liang Yu; Yi-Lun Huang; Bao-Tsan Ko; Chu-Chieh Lin; Inorganic Chemistry 41 (2002) 2987–2994; doi:10.1021/ic011072+

data_4327513
_publ_section_title
;
 Reactions of Amides with Organoaluminum Compounds: Factors Affecting the
 Coordination Mode of Aluminum Amidates
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2987
_journal_page_last               2994
_journal_paper_doi               10.1021/ic011072+
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C26 H36 Al2 F4 N2 O2'
_chemical_formula_weight         538.52
_chemical_name_systematic
;
  ?
;
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_cell_angle_alpha                90.00
_cell_angle_beta                 102.454(2)
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_cell_formula_units_Z            2
_cell_length_a                   9.2799(9)
_cell_length_b                   9.0514(8)
_cell_length_c                   17.9334(17)
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_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.013
_cell_measurement_theta_min      2.534
_cell_volume                     1470.9(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0213
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_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -11
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_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       22
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_diffrn_reflns_theta_max         26.04
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_exptl_absorpt_coefficient_mu    0.148
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.658
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            colorless
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_exptl_crystal_description       parallelpiped
_exptl_crystal_F_000             568
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_exptl_crystal_size_mid          0.63
_exptl_crystal_size_min          0.37
_refine_diff_density_max         0.244
_refine_diff_density_min         -0.191
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         2893
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_refine_ls_restrained_S_all      1.147
_refine_ls_R_factor_all          0.0558
_refine_ls_R_factor_gt           0.0436
_refine_ls_shift/su_max          0.108
_refine_ls_shift/su_mean         0.013
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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