<i>catena</i>-Poly[[tetra-μ-acetato-κ^8^<i>O</i>:<i>O</i>'-dinickel(II)]-μ-2,3'-dipyridylamine-κ^2^<i>N</i>:<i>N</i>']
Ling Zhang; Acta Crystallographica Section E 63 (2007) m2950–m2950; doi:10.1107/S1600536807055353

data_2216410
_publ_contact_author_address
;
Department of Chemistry, Lishui University,
323000 Lishui, Zhejiang, People's
Republic of China
;
_publ_contact_author_email       zjlsxyzl@126.com
_publ_contact_author_fax         0578-323118
_publ_contact_author_name        'Ling Zhang'
_publ_contact_author_phone       0578-323118
_publ_section_title
<i>catena</i>-Poly[[tetra-\m-acetato-\k^8^<i>O</i>:<i>O</i>'-dinickel(II)]-\m-2,3'-dipyridylamine-\k^2^<i>N</i>:<i>N</i>']
_journal_coeditor_code           DN2259
_journal_date_accepted           2007-11-01
_journal_date_recd_electronic    2007-10-24
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2950
_journal_page_last               m2950
_journal_paper_category          QM
_journal_paper_doi               10.1107/S1600536807055353
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ni2 (C2 H3 O2)4 (C10 H7 N3) ]'
_chemical_formula_moiety         'C18 H19 N3 Ni2 O8'
_chemical_formula_sum            'C18 H19 N3 Ni2 O8'
_chemical_formula_weight         522.78
_chemical_name_common
;
Poly[(2,3'-dipyridylamine)(tetraacetyl)dinickel(II)]
;
_chemical_name_systematic
;
Poly[(tetraacetyl-\k^2^N:N')dinickel(II)-\m-2,3'-dipyridylamine-\k^2^O:O']
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.191(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.4008(13)
_cell_length_b                   8.4880(9)
_cell_length_c                   20.112(2)
_cell_measurement_reflns_used    1973
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.19
_cell_measurement_theta_min      2.87
_cell_volume                     2196.9(4)
_computing_cell_refinement       'SAINT (Bruker, 2004)'
_computing_data_collection       'APEX2 (Bruker, 2004)'
_computing_data_reduction        'SAINT (Bruker, 2004)'
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  'SHELXTL (Bruker, 1997)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      298(2)
_diffrn_detector_area_resol_mean 0
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEXII area-detector diffractometer'
_diffrn_measurement_method       '\f and \w scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0946
_diffrn_reflns_av_sigmaI/netI    0.1248
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            5441
_diffrn_reflns_theta_full        25.19
_diffrn_reflns_theta_max         25.19
_diffrn_reflns_theta_min         2.87
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.762
_exptl_absorpt_correction_T_max  0.7658
_exptl_absorpt_correction_T_min  0.6476
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2004)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.581
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1072
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.567
_refine_diff_density_min         -0.454
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.999
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     147
_refine_ls_number_reflns         1973
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.999
_refine_ls_R_factor_all          0.1231
_refine_ls_R_factor_gt           0.0541
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0465P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1117
_refine_ls_wR_factor_ref         0.1323
_reflns_number_gt                1098
_reflns_number_total             1973
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            dn2259.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2216410
_cod_database_fobs_code          2216410