Synthetic and reactivity studies of hetero-tri-anionic sodium zincates.
Francos, Javier; Kennedy, Alan R.; O'Hara, Charles T; Dalton transactions (Cambridge, England : 2003) 45 (2016) 6222–6233; doi:10.1039/c5dt04329h

data_7037489
_publ_section_title
;
 Synthetic and reactivity studies of hetero-tri-anionic sodium zincates.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6222
_journal_page_last               6233
_journal_paper_doi               10.1039/c5dt04329h
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C21 H50 N3 Na Zn'
_chemical_formula_weight         433.00
_chemical_name_systematic
;
 ?
;
_chemical_properties_physical
'Air-sensitive, Moisture-sensitive, Oxygen-sensitive'
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_symmetry_space_group_name_Hall  '-P 2yn'
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;
2015-11-02 deposited with the CCDC.
2015-11-30 downloaded from the CCDC.
;
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_cell_angle_gamma                90.00
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_cell_measurement_theta_min      3.2689
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_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.924
_diffrn_measurement_device_type  'Oxford Diffraction Xcalibur E'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.40 (release 27-08-2010 CrysAlis171 .NET)
(compiled Aug 27 2010,11:50:40)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_exptl_crystal_F_000             952
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0957
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0367P)^2^+1.5084P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            c5dt04329h2.cif
_cod_data_source_block           jfnazntbu2nbu
_cod_depositor_comments
'Adding full bibliography for 7037489--7037496.cif.'
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               7037489