Bench-stable frustrated Lewis pair chemistry: fluoroborate salts as precatalysts for the C-H borylation of heteroarenes.
Légaré, Marc-André; Rochette, Étienne; Légaré Lavergne, Julien; Bouchard, Nicolas; Fontaine, Frédéric-Georges; Chemical communications (Cambridge, England) 52 (2016) 5387–5390; doi:10.1039/c6cc01267a

data_7124594
_publ_section_title
;
 Bench-stable frustrated Lewis pair chemistry: fluoroborate salts as
 precatalysts for the C-H borylation of heteroarenes.
;
_journal_issue                   31
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              5387
_journal_page_last               5390
_journal_paper_doi               10.1039/c6cc01267a
_journal_volume                  52
_journal_year                    2016
_chemical_formula_sum            'C15 H23 B F3 N'
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_space_group_IT_number           14
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2015-12-04 deposited with the CCDC.
2016-03-14 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      150(2)
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_diffrn_reflns_av_unetI/netI     0.0341
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.947
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_Friedel_coverage         0.000
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_reflns_threshold_expression     'I > 2\s(I)'
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