Reactivity of the carbodiphosphorane, (Ph<sub>3</sub>P)<sub>2</sub>C, towards main group metal alkyl compounds: coordination and cyclometalation.
Quinlivan, Patrick J.; Shlian, Daniel G.; Amemiya, Erika; Parkin, Gerard; Dalton transactions (Cambridge, England : 2003) 48 (2019) 9139–9151; doi:10.1039/c9dt00678h

data_7700123
_publ_section_title
;
 Reactivity of the carbodiphosphorane, (Ph<sub>3</sub>P)<sub>2</sub>C,
 towards main group metal alkyl compounds: coordination and
 cyclometalation.
;
_journal_issue                   25
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9139
_journal_page_last               9151
_journal_paper_doi               10.1039/c9dt00678h
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C43 H47 Mg N P2 Si2'
_chemical_formula_weight         720.24
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-02-13 deposited with the CCDC.    2019-04-29 downloaded from the CCDC.
;
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_cell_angle_gamma                73.912(3)
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      130(2)
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
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_refine_ls_shift/su_mean         0.005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0497P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1479
_refine_ls_wR_factor_ref         0.1513
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6217
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7700119--7700124.cif.'
_cod_original_cell_volume        2060.9(7)
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_shelx_res_checksum              3355