Regio- and Stereoselective Insertion Reactions of Thiiranes into Pt-Mn (or Re) Bond in Organoplatinum-Manganese or -Rhenium Heterodinuclear Complexes as Intermediates toward Desulfurization Reaction
Sanshiro Komiya; Shin-ya Muroi; Masaki Furuya; Masafumi Hirano; Journal of the American Chemical Society 122 (2000) 170–171; doi:10.1021/ja993185m

data_4115872
_publ_contact_author_address
;
Department of Applied Chemistry
Tokyo University of Agriculture and Technology
2-24-16 Nakacho, Koganei, Tokyo 184-8588, Japan
;
_publ_contact_author_email       ' komiya@cc.tuat.ac.jp '
_publ_contact_author_fax         ' +81-42-387-7500 '
_publ_contact_author_name        ' Sanshiro Komiya'
_publ_contact_author_phone       ' +81-42-388-7043 '
_publ_section_title
;
 Regio- and Stereoselective Insertion Reactions of Thiiranes into Pt-Mn
 (or Re) Bond in Organoplatinum-Manganese or -Rhenium Heterodinuclear
 Complexes as Intermediates toward Desulfurization Reaction
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              170
_journal_page_last               171
_journal_paper_doi               10.1021/ja993185m
_journal_volume                  122
_journal_year                    2000
_chemical_formula_sum            'C32 H27 Mn O5 P2 Pt'
_chemical_formula_weight         803.54
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                102.01(2)
_cell_angle_beta                 91.19(4)
_cell_angle_gamma                88.27(6)
_cell_formula_units_Z            4
_cell_length_a                   16.12(1)
_cell_length_b                   16.238(7)
_cell_length_c                   12.232(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293.2
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.9
_cell_volume                     3130(2)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    'DIRDIF92 (PATTY)'
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.046
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            14856
_diffrn_standards_decay_%        0.06
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.989
_exptl_absorpt_correction_T_max  0.997
_exptl_absorpt_correction_T_min  0.685
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.705
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.420
_exptl_crystal_size_mid          0.350
_exptl_crystal_size_min          0.250
_refine_diff_density_max         1.75
_refine_diff_density_min         -1.34
_refine_ls_extinction_coef       0.00000
_refine_ls_extinction_method     'Zachariasen(1967) type 2 gaussian isotropic'
_refine_ls_goodness_of_fit_ref   1.205
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     0
_refine_ls_number_reflns         10634
_refine_ls_R_factor_gt           0.0440
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w =3D 1/[\s^2^(Fo) + 0.00203|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0730
_reflns_number_gt                10634
_reflns_number_total             0
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ja993185m_2.cif
_cod_data_source_block           Complex1a
_cod_original_cell_volume        3130(3)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C32 H27 Mn O5 P2 Pt '
_cod_database_code               4115872