<i>catena</i>-Poly[[trimethyltin(IV)]-μ-4-[1-(2-hydroxyphenyl)ethylideneaminomethyl]cyclohexanecarboxylato-κ^2^<i>O</i>:<i>O</i>']
Shaukat Shuja; Saqib Ali; Nasir Khalid; Broker, Grant A.; Tiekink, Edward R. T.; Acta Crystallographica Section E 63 (2007) m1025–m1026; doi:10.1107/S1600536807010902

data_2212972
_publ_section_title
<i>catena</i>-Poly[[trimethyltin(IV)]-\m-4-[1-(2-hydroxyphenyl)ethylideneaminomethyl]cyclohexanecarboxylato-\k^2^<i>O</i>:<i>O</i>']
_journal_coeditor_code           NG2228
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1025
_journal_page_last               m1026
_journal_paper_doi               10.1107/S1600536807010902
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Sn (C H3)3 (C16 H20 N O3)]'
_chemical_formula_moiety         'C19 H29 N O3 Sn'
_chemical_formula_sum            'C19 H29 N O3 Sn'
_chemical_formula_weight         438.12
_chemical_name_systematic
;
catena-Poly[[trimethyltin(IV)]-\m-4-[1-(2-
hydroxyphenyl)ethylideneaminomethyl]cyclohexanecarboxylato-\k^2^O:O']
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 106.00(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   16.173(3)
_cell_length_b                   9.987(2)
_cell_length_c                   12.728(3)
_cell_measurement_reflns_used    6143
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      30.4
_cell_measurement_theta_min      2.7
_cell_volume                     1976.2(8)
_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku/MSC, 2005)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics
'ORTEPII (Johnson, 1976) and DIAMOND (Brandenburg, 2006)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Rigaku AFC12\K/SATURN724'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.049
_diffrn_reflns_av_sigmaI/netI    0.043
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            14354
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         2.6
_diffrn_standards_decay_%        '< 1'
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.308
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.829
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.472
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             896
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.19
_refine_diff_density_max         0.73
_refine_diff_density_min         -0.70
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.11
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     218
_refine_ls_number_reflns         4433
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.11
_refine_ls_R_factor_all          0.046
_refine_ls_R_factor_gt           0.042
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0281P)^2^+3.8568P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.091
_refine_ls_wR_factor_ref         0.093
_reflns_number_gt                4154
_reflns_number_total             4433
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            ng2228.cif
_cod_data_source_block           I
_cod_original_cell_volume        1976.3(7)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2212972
_cod_database_fobs_code          2212972