The anionic coordination polymer {K~2~[Pt^II^~2~Ag^I^~8~(2,2'-bipyridine)~2~(O~2~CCF~3~)~14~]}~<i>n~</i>
Hudson, Zachary M.; Sun, Yi; Ross, Bryan; Wang, Rui-Yao; Wang, Suning; Acta Crystallographica Section C 65 (2009) m328–m330; doi:10.1107/S010827010902839X

data_2017251
_publ_section_title
;
 The anionic coordination polymer
 {K~2~[Pt^II^~2~Ag^I^~8~(2,2'-bipyridine)~2~(O~2~CCF~3~)~14~]}~<i>n~</i>
;
_journal_coeditor_code           GZ3165
_journal_issue                   8
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m328
_journal_page_last               m330
_journal_paper_doi               10.1107/S010827010902839X
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac          'K2 [Pt2 Ag8 (C10 H8 N2)2 (C2 F3 O2)14]'
_chemical_formula_moiety         '2K + , C48 H16 Ag8 F42 N4 O28 Pt2 -'
_chemical_formula_sum            'C48 H16 Ag8 F42 K2 N4 O28 Pt2'
_chemical_formula_weight         3225.98
_chemical_name_systematic
;<i>catena</i>-poly[dipotassium(I)
[bis(2,2'-bipyridine)di-\m~3~-trifluoroacetato-dodeca-\m~2~-trifluoroacetato-\
diplatinum(II)octasilver(I)]]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                77.3780(10)
_cell_angle_beta                 70.1320(10)
_cell_angle_gamma                86.3050(10)
_cell_formula_units_Z            1
_cell_length_a                   11.9829(6)
_cell_length_b                   12.4737(6)
_cell_length_c                   14.4368(7)
_cell_measurement_reflns_used    9980
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.91
_cell_measurement_theta_min      2.36
_cell_volume                     1980.28(17)
_computing_cell_refinement       'SMART (Bruker, 2007)'
_computing_data_collection       'SMART (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics
;
SHELXTL (Sheldrick, 2008) and Mercury (Macrae <i>et al.</i>,
2006)
;
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0184
_diffrn_reflns_av_sigmaI/netI    0.0214
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            20732
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.53
_exptl_absorpt_coefficient_mu    5.731
_exptl_absorpt_correction_T_max  0.7626
_exptl_absorpt_correction_T_min  0.5980
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2008)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.705
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1504
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.972
_refine_diff_density_min         -1.244
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     609
_refine_ls_number_reflns         7748
_refine_ls_number_restraints     112
_refine_ls_restrained_S_all      1.082
_refine_ls_R_factor_all          0.0270
_refine_ls_R_factor_gt           0.0242
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0247P)^2^+5.4864P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0565
_refine_ls_wR_factor_ref         0.0578
_reflns_number_gt                7189
_reflns_number_total             7748
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            gz3165.cif
_cod_data_source_block           I
_cod_database_code               2017251
_cod_database_fobs_code          2017251