Metallation of a gold(I) metalloligand with P,C-bridging phosphinoferrocenyl groups enables the construction of defined multimetallic arrays.
Schulz, Jiří; Císařová, Ivana; Gyepes, Róbert; Štěpnička, Petr; Dalton transactions (Cambridge, England : 2003)  (2022) –; doi:10.1039/d2dt00850e

data_7709953
_publ_section_title
;
 Metallation of a gold(I) metalloligand with P,C-bridging
 phosphinoferrocenyl groups enables the construction of defined
 multimetallic arrays.
;
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_paper_doi               10.1039/d2dt00850e
_journal_year                    2022
_chemical_formula_moiety
;
C88 H72 Au6 Fe4 P4, 2(Cl O4), C2 H3 N, 4(C H2 Cl2)
;
_chemical_formula_sum            'C94 H83 Au6 Cl10 Fe4 N O8 P4'
_chemical_formula_weight         3238.19
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
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_atom_sites_solution_secondary   difmap
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_audit_update_record
;
2021-11-27 deposited with the CCDC.	2022-03-25 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.996
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_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_limit_l_min       -43
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0287P)^2^+36.0270P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             23310
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_original_cell_volume        10139.9(10)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7709953
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.155
_shelx_estimated_absorpt_t_max   0.448
_shelx_res_checksum              29071
_shelx_fab_checksum              74185