Regioisomers containing triarylboron-based motifs as multi-functional photoluminescent materials: from dual-mode delayed emission to pH-switchable room-temperature phosphorescence.
Arumugam, Ramar; Muhammed Munthasir, Akkarakkaran Thayyil; Kannan, Ramkumar; Banerjee, Dipanjan; Sudhakar, Pagidi; Soma, Venugopal Rao; Thilagar, Pakkirisamy; Chandrasekhar, Vadapalli; Chemical science 15 (2024) 18364–18378; doi:10.1039/d4sc05656f

data_1572832
_publ_section_title
;
 Regioisomers containing triarylboron-based motifs as multi-functional
 photoluminescent materials: from dual-mode delayed emission to
 pH-switchable room-temperature phosphorescence.
;
_journal_issue                   44
_journal_name_full               'Chemical science'
_journal_page_first              18364
_journal_page_last               18378
_journal_paper_doi               10.1039/d4sc05656f
_journal_volume                  15
_journal_year                    2024
_chemical_formula_moiety         'C31 H37 B N, C F3 O3 S, 2(C H2 Cl2)'
_chemical_formula_sum            'C34 H41 B Cl4 F3 N O3 S'
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_space_group_name_Hall           '-I 2ya'
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_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2024-05-27 deposited with the CCDC.	2024-10-07 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      100(2)
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_diffrn_measurement_device_type  'XtaLAB AFC12 (RINC): Kappa single'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.29d (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.393
_exptl_crystal_description       Block
_exptl_crystal_F_000             3136
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1070P)^2^+27.0341P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2016
_refine_ls_wR_factor_ref         0.2146
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7829
_reflns_number_total             10077
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4sc05656f2.cif
_cod_data_source_block           C3
_cod_depositor_comments
'Adding full bibliography for 1572830--1572832.cif.'
_cod_original_sg_symbol_H-M      'I 2/a'
_cod_database_code               1572832
_shelx_shelxl_version_number     2018/3
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_shelx_res_checksum              4060
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