Single Component Iron Catalysts for Atom Transfer and Organometallic Mediated Radical Polymerizations: Mechanistic Studies and Reaction Scope
Allan, Laura E. N.; MacDonald, Jarret P.; Nichol, Gary S.; Shaver, Michael P.; Macromolecules 47 (2014) 1249–; doi:10.1021/ma402381x

data_1513350
_publ_section_title
;
 Single Component Iron Catalysts for Atom Transfer and Organometallic
 Mediated Radical Polymerizations: Mechanistic Studies and Reaction Scope
;
_journal_issue                   4
_journal_name_full               Macromolecules
_journal_page_first              1249
_journal_paper_doi               10.1021/ma402381x
_journal_volume                  47
_journal_year                    2014
_chemical_formula_sum            'C50 H53.08 Cl10 Fe1.46 Li2 N4 O4'
_chemical_formula_weight         1223.92
_chemical_name_systematic
; 
 ? 
;
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_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
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_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_exptl_absorpt_correction_type   gaussian
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_exptl_crystal_colour            colourless
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_refine_ls_extinction_method     none
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_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0484
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0440P)^2^+13.0628P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1115
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_original_cell_volume        5431.47(14)
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_shelx_estimated_absorpt_t_min   0.231
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