A simple one-pot route to stable formamidinatoiodidolanthanoid(III) complexes from lanthanoid metals.
Guo, Zhifang; Blair, Victoria L.; Deacon, Glen B.; Junk, Peter C.; Chemical communications (Cambridge, England) 57 (2021) 11513–11516; doi:10.1039/d1cc04080d

data_7129075
_publ_section_title
;
 A simple one-pot route to stable formamidinatoiodidolanthanoid(III)
 complexes from lanthanoid metals.
;
_journal_issue                   87
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              11513
_journal_page_last               11516
_journal_paper_doi               10.1039/d1cc04080d
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C34 H30 F8 I Lu N4 O2'
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Olex2 1.3
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2021-10-04 deposited with the CCDC.	2021-10-08 downloaded from the CCDC.
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_diffrn_ambient_temperature      100(2)
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_exptl_crystal_colour            colourless
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
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_exptl_crystal_size_max          0.2
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0439P)^2^+8.7855P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                4461
_reflns_number_total             4760
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_cod_data_source_block           1
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The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-Scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7129070--7129084.cif.
;
_cod_original_cell_volume        3358.2(13)
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1. Others
 Fixed Sof: Lu1(0.5) I1(0.5)
 Fixed U12: Lu1(0) I1(0)
 Fixed U23: Lu1(0) I1(0)
 Fixed Uiso: H12(0.029) H7(0.024) H11(0.031) H16A(0.037) H16B(0.037) H10(0.03)
 H4(0.038) H14A(0.033) H14B(0.033) H17A(0.032) H17B(0.032) H2(0.038) H3(0.041)
 H15A(0.043) H15B(0.043)
 Fixed X: Lu1(0.5) H12(0.49764) H7(0.413082) H11(0.349869) H16A(0.261629)
 H16B(0.209856) H10(0.250034) H4(0.556016) H14A(0.271396) H14B(0.287277)
 H17A(0.3741) H17B(0.316386) H2(0.299739) H3(0.415345) H15A(0.167202)
 H15B(0.166815) I1(0.5)
 Fixed Y: H12(1.012923) H7(0.58497) H11(1.051874) H16A(0.697853)
 H16B(0.656306) H10(0.902277) H4(0.152539) H14A(0.388613) H14B(0.48627)
 H17A(0.630233) H17B(0.524169) H2(0.237896) H3(0.112409) H15A(0.570189)
 H15B(0.489606)
 Fixed Z: Lu1(0.75) H12(0.663215) H7(0.549896) H11(0.600239) H16A(0.732146)
 H16B(0.790349) H10(0.563512) H4(0.520861) H14A(0.697402) H14B(0.642457)
 H17A(0.831003) H17B(0.844051) H2(0.440192) H3(0.444373) H15A(0.657171)
 H15B(0.726954) I1(0.75)
;
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_shelx_hkl_checksum              30665
_olex2_submission_special_instructions 'No special instructions were received'