Migratory insertion of isocyanide into a ketenyl-tungsten bond as key step in cyclization reactions.
Timmermann, Christopher; Thiem, Paula; Wanitschke, Dominik; Hüttenschmidt, Mareike; Romischke, Johanna; Villinger, Alexander; Seidel, Wolfram W.; Chemical science 13 (2021) 123–132; doi:10.1039/d1sc06149f

data_1565569
_publ_section_title
;
 Migratory insertion of isocyanide into a ketenyl-tungsten bond as key
 step in cyclization reactions.
;
_journal_issue                   1
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_journal_page_last               132
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'[Carbonyl-chlorido-\h2-C,C?-ethinylethylether-hydridotris(3,4,5-trimethylpyrazolyl)borato-tungsten(II)]'
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;
2021-02-04 deposited with the CCDC.	2021-11-22 downloaded from the CCDC.
;
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'w=1/[\s^2^(Fo^2^)+(0.0327P)^2^+7.4348P] where P=(Fo^2^+2Fc^2^)/3'
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