Catalyst-free amination of α-cyanoarylacetates enabled by single-electron transfer
Zhang, Wei; Zheng, Han-Liang; Liu, Yang; Yu, Ao; Yang, Chen; Li, Xin; Cheng, Jin-Pei; Organic Chemistry Frontiers 6 (2019) 1900–; doi:10.1039/C9QO00346K

data_1554870
_publ_section_title
;
 Catalyst-free amination of \a-cyanoarylacetates enabled by
 single-electron transfer
;
_journal_issue                   11
_journal_name_full               'Organic Chemistry Frontiers'
_journal_page_first              1900
_journal_paper_doi               10.1039/C9QO00346K
_journal_volume                  6
_journal_year                    2019
_chemical_formula_sum            'C19 H18 N2 O4'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
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_audit_creation_method           SHELXL-2014/8
_audit_update_record
;
2018-06-24 deposited with the CCDC.	2019-04-15 downloaded from the CCDC.
;
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_computing_publication_material  'Bruker SHELXTL'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
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_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0670P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                5990
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           shelxl
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        3430.8(12)
_cod_original_sg_symbol_H-M      'P 21/c'
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_shelx_estimated_absorpt_t_max   0.989
_shelx_res_checksum              40701
_shelx_hkl_checksum              5508