Synthesis and Characterization of Adducts between SF<sub>4</sub> and Oxygen Bases: Examples of O···S(IV) Chalcogen Bonding.
Goettel, James T.; Gerken, Michael; Inorganic chemistry 55 (2016) 12441–12450; doi:10.1021/acs.inorgchem.6b02373

data_4349312
_publ_section_title
;
 Synthesis and Characterization of Adducts between SF<sub>4</sub> and
 Oxygen Bases: Examples of O&#x00B7;&#x00B7;&#x00B7;S(IV) Chalcogen
 Bonding.
;
_journal_issue                   23
_journal_name_full               'Inorganic chemistry'
_journal_page_first              12441
_journal_page_last               12450
_journal_paper_doi               10.1021/acs.inorgchem.6b02373
_journal_volume                  55
_journal_year                    2016
_chemical_formula_sum            'C8 H16 F4 O2 S'
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_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_device_type  'Bruker Smart Apex II'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_limit_h_min       -14
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_diffrn_reflns_limit_k_min       -17
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_diffrn_source                   'fine-focus sealed tube'
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_exptl_absorpt_correction_T_max  0.7456
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_exptl_absorpt_process_details
; 
SADABS (Sheldrick, 2004)
;
_exptl_crystal_colour            colourless
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_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0558P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_total             10599
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ic6b02373_si_002.cif
_cod_data_source_block           twin
_cod_original_cell_volume        2320.9(11)
_cod_database_code               4349312
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