Tetravalent Titanium, Zirconium, and Cerium Oxo and Peroxo Complexes Containing an Imidodiphosphinate Ligand
Guo-Cang Wang; Herman H. Y. Sung; Ian D. Williams; Wa-Hung Leung; Inorganic Chemistry 51 (2012) 3640–3647; doi:10.1021/ic202564h

data_4328656
_publ_contact_author_name
;
;
_publ_section_title
;
 Tetravalent Titanium, Zirconium, and Cerium Oxo and Peroxo Complexes
 Containing an Imidodiphosphinate Ligand
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3640
_journal_page_last               3647
_journal_paper_doi               10.1021/ic202564h
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C36 H84 Ce Cl N3 O6 P6'
_chemical_formula_sum            'C36 H84 Ce Cl N3 O6 P6'
_chemical_formula_weight         1016.45
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 ? 
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CrysAlisPro, Oxford Diffraction Ltd.,
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CrysAlisPro, Oxford Diffraction Ltd.,
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
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XL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
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  1 omega   40.00   73.00   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -50.0000   30.0000 55

  2 omega   41.00   71.60   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000  150.0000 51

  3 omega  -22.00   43.40   0.6000    3.0000
omega____ theta____ kappa____ phi______ frames
    -        0.0000 -101.0000   37.0000 109

  4 omega  -64.00  -22.60   0.6000    3.0000
omega____ theta____ kappa____ phi______ frames
    -        0.0000  -77.0000  -30.0000 69

  5 omega   25.00  120.40   0.6000   10.0000
omega____ theta____ kappa____ phi______ frames
    -       55.0000   77.0000   60.0000 159

  6 omega  -10.00   81.80   0.6000   10.0000
omega____ theta____ kappa____ phi______ frames
    -       55.0000  -77.0000  -60.0000 153

  7 omega  -16.00   10.40   0.6000   10.0000
omega____ theta____ kappa____ phi______ frames
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  8 omega -136.00  -87.40   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      -64.0000  -25.0000   30.0000 81

  9 omega   38.00   72.20   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000 -180.0000 57

 10 omega   40.00   73.00   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000  120.0000 55

 11 omega   46.00   83.80   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -50.0000  -30.0000 63

 12 omega   40.00   73.00   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -50.0000  -90.0000 55

 13 omega   40.00   71.80   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000    0.0000 53

 14 omega   39.00   73.20   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000   30.0000 57

 15 omega   40.00   70.00   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000   60.0000 50

 16 omega   43.00   79.00   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -50.0000  -60.0000 60

 17 omega   39.00   73.20   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000   90.0000 57

 18 omega   41.00   78.80   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000 -154.0000  -17.0000 63

 19 omega   39.00  148.80   0.6000   28.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -93.0000  -57.0000 183
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_diffrn_source_power             2.0
_diffrn_source_target            Cu
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CrysAlisPro, Oxford Diffraction Ltd.,
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(compiled Oct 25 2010,18:11:34)
empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            yellow
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'calc w=1/[\s^2^(Fo^2^)+(0.0508P)^2^+1.9955P] where P=(Fo^2^+2Fc^2^)/3'
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