Activation of metal hydride complexes by tri-tert-butylphosphine-platinum and -palladium groups.
Adams, Richard D.; Captain, Burjor; Trufan, Eszter; Zhu, Lei; Journal of the American Chemical Society 129 (2007) 7545–7556; doi:10.1021/ja070617h

data_4119115
_publ_section_title
;
 Activation of metal hydride complexes by tri-tert-butylphosphine-platinum
 and -palladium groups.
;
_journal_issue                   24
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              7545
_journal_page_last               7556
_journal_paper_doi               10.1021/ja070617h
_journal_volume                  129
_journal_year                    2007
_chemical_formula_sum            'C42 H49 O4 Os P Pt Sn'
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_chemical_name_systematic
; 
 ? 
;
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_cell_length_c                   21.044(2)
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_computing_cell_refinement       'SAINT+  V6.2 (Bruker, 2001)'
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_computing_molecular_graphics    'SHELXTL V6.1 (Sheldrick, 1997)'
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega scans'
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_diffrn_reflns_limit_l_min       -28
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_diffrn_standards_decay_%        <1
_exptl_absorpt_coefficient_mu    6.480
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.686
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2208
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_refine_ls_number_reflns         22398
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0815P)^2^+5.6601P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja070617hsup2.cif
_cod_data_source_block           p-1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

 Adding full bibliography for 4119115.cif.
;
_cod_original_cell_volume        4540.8(8)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4119115
_cod_duplicate_entry 4109529