Synthesis and reactivities of a bis(cyanamido)-capped triruthenium complex.
Tanabe, Yoshiaki; Kajitani, Hidenobu; Iwasaki, Masakazu; Ishii, Youichi; Dalton transactions (Cambridge, England : 2003)  (2007) 4701–4707; doi:10.1039/b708328a

data_7006032
_publ_section_title
;
 Synthesis and reactivities of a bis(cyanamido)-capped triruthenium
 complex.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4701
_journal_page_last               4707
_journal_paper_doi               10.1039/b708328a
_journal_year                    2007
_chemical_formula_moiety         'C74 H90 B N5 P2 Ru3 '
_chemical_formula_sum            'C74 H90 B N5 P2 Ru3'
_chemical_formula_weight         1425.53
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                88.780(18)
_cell_angle_beta                 88.233(18)
_cell_angle_gamma                86.027(17)
_cell_formula_units_Z            2
_cell_length_a                   10.842(4)
_cell_length_b                   17.058(6)
_cell_length_c                   18.305(5)
_cell_measurement_reflns_used    379
_cell_measurement_temperature    123.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     3375(2)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.858
_diffrn_measured_fraction_theta_max 0.858
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.015
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            31515
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.756
_exptl_absorpt_correction_T_max  0.797
_exptl_absorpt_correction_T_min  0.618
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            dark_red
_exptl_crystal_density_diffrn    1.403
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1472.00
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.30
_refine_diff_density_max         0.84
_refine_diff_density_min         -0.63
_refine_ls_extinction_coef       169(8)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     857
_refine_ls_number_reflns         10781
_refine_ls_R_factor_gt           0.0306
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[2.2900\s(Fo^2^)]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0350
_reflns_number_gt                10781
_reflns_number_total             13267
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b708328a.txt
_cod_data_source_block           '__(PPN)[(Cp*Ru)3(NCN){(NCN)(BEt3)}]'
_cod_original_cell_volume        3375.0(19)
_cod_original_formula_sum        'C74 H90 B N5 P2 Ru3 '
_cod_database_code               7006032