Linking of Alcohols with Vinyl Azides.
Wang, Yi-Feng; Hu, Ming; Hayashi, Hirohito; Xing, Bengang; Chiba, Shunsuke; Organic letters 18 (2016) 992–; doi:10.1021/acs.orglett.6b00116

data_1542699
_publ_contact_author
;
Dr Shunsuke Chiba
Division of Chemistry and Biological Chemistry
School of Physical and Mathematical Sciences
Nanyang Technological University
21 Nanyang Link
Singapore 637371
Singapore
;
_publ_section_title
;
 Linking of Alcohols with Vinyl Azides.
;
_journal_issue                   5
_journal_name_full               'Organic letters'
_journal_page_first              992
_journal_paper_doi               10.1021/acs.orglett.6b00116
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C17 H16 F N O'
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_symmetry_space_group_name_H-M   'P -1'
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_cell_length_c                   11.6094(12)
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_cell_measurement_theta_min      3.6126
_cell_volume                     679.03(12)
_computing_cell_refinement       'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_data_reduction        'SAINT V8.34A (Bruker AXS Inc., 2013)'
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_diffrn_ambient_temperature      103.(2)
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_diffrn_reflns_limit_k_max       15
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_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.317
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             284
_exptl_crystal_size_max          0.420
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.380
_refine_diff_density_max         0.382
_refine_diff_density_min         -0.379
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     181
_refine_ls_number_reflns         4293
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0756
_refine_ls_R_factor_gt           0.0518
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0631P)^2^+0.1341P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1380
_reflns_number_gt                3136
_reflns_number_total             4293
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ol6b00116_si_002.cif
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_shelx_res_checksum              10533
_shelx_hkl_checksum              9185