1,2,4-Tri(<sup><i>t</i></sup>Bu)cyclopentadienyl gallium (Cp'''Ga) as a versatile reagent for the synthesis of Lewis adducts and ionic compounds.
Ding, Yi; Tang, Yongheng; Nazish, Mohd; Ruth, Paul Niklas; Wachendorf, Sophia Luisa; Herbst-Irmer, Regine; Stalke, Dietmar; Roesky, Herbert W.; Chemical communications (Cambridge, England) 61 (2025) 13441–13444; doi:10.1039/d5cc03933a

data_7134886
_publ_section_title
;
 1,2,4-Tri(<sup><i>t</i></sup>Bu)cyclopentadienyl gallium (Cp'''Ga) as a
 versatile reagent for the synthesis of Lewis adducts and ionic compounds.
;
_journal_issue                   71
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              13441
_journal_page_last               13444
_journal_paper_doi               10.1039/d5cc03933a
_journal_volume                  61
_journal_year                    2025
_chemical_formula_moiety         'C35 H29 B0.91 F15 Ga1.09, 0.5(C6 H6)'
_chemical_formula_sum            'C38 H32 B0.91 F15 Ga1.09'
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_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2019/1
_audit_update_record
;
2024-07-23 deposited with the CCDC.	2025-07-24 downloaded from the CCDC.
;
_cell_angle_alpha                77.99(2)
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_cell_measurement_temperature    100(2)
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker Smart APEX II Quazar'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_type           MoK\a
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_refine_ls_restrained_S_all      0.947
_refine_ls_R_factor_all          0.0358
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0283P)^2^+0.7948P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                6722
_reflns_number_total             7711
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7134886--7134888.cif.'
_cod_database_code               7134886
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