Influence of Terminal Acryloyl Arms on the Coordination Chemistry of a Ditopic Pyrimidine-Hydrazone Ligand: Comparison of Pb(II), Zn(II), Cu(II), and Ag(I) Complexes
Daniel J. Hutchinson; Lyall R. Hanton; Stephen C. Moratti; Inorganic Chemistry 52 (2013) 2716–2728; doi:10.1021/ic3027978

data_4334068
_publ_contact_author             'Hanton, Lyall R.'
_publ_contact_author_email       lhanton@Chemistry.otago.ac.nz
_publ_section_title
;
 Influence of Terminal Acryloyl Arms on the Coordination Chemistry of a
 Ditopic Pyrimidine-Hydrazone Ligand: Comparison of Pb(II), Zn(II),
 Cu(II), and Ag(I) Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2716
_journal_page_last               2728
_journal_paper_doi               10.1021/ic3027978
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         'C30 H28 Ag3.50 F9 N8 O14 S3'
_chemical_formula_sum            'C30 H28 Ag3.5 F9 N8 O14 S3'
_chemical_formula_weight         1369.33
_chemical_name_systematic
;
 ?
;
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_symmetry_space_group_name_Hall  '-P 1'
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_cell_angle_beta                 94.273(4)
_cell_angle_gamma                96.468(4)
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_cell_length_b                   13.5150(11)
_cell_length_c                   16.5799(13)
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_cell_measurement_temperature    90(2)
_cell_measurement_theta_max      24.00
_cell_measurement_theta_min      2.26
_cell_volume                     2514.8(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      90(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
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_diffrn_reflns_theta_max         24.07
_diffrn_reflns_theta_min         2.26
_diffrn_standards_number         0
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_exptl_absorpt_correction_T_min  0.829
_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            yellow
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_exptl_crystal_description       rod
_exptl_crystal_F_000             1339
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_platon_squeeze_details
;
;
_refine_diff_density_max         2.210
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_refine_ls_R_factor_all          0.0661
_refine_ls_R_factor_gt           0.0550
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0901P)^2^+11.9869P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            ic3027978_si_001_1.cif
_cod_data_source_block           Complex_8(sdjh963)
_cod_original_cell_volume        2514.8(5)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C30 H28 Ag3.50 F9 N8 O14 S3'
_cod_database_code               4334068