Two highly crystalline coordination polymers with two-dimensional PbS networks for photocatalytic synthesis of imines
Li, Yang; Cheng, Xiuyan; Li, Ze; Jin, Yigang; Sun, Yimeng; Zou, Ye; Liu, Liyao; Duan, Ran; Zhang, Jianling; Xu, Wei; Catalysis Science & Technology 12 (2022) 4851–4856; doi:10.1039/D2CY00797E

data_1567180
_publ_section_title
;
 Two highly crystalline coordination polymers with two-dimensional PbS
 networks for photocatalytic synthesis of imines
;
_journal_issue                   15
_journal_name_full               'Catalysis Science &amp; Technology'
_journal_page_first              4851
_journal_page_last               4856
_journal_paper_doi               10.1039/D2CY00797E
_journal_volume                  12
_journal_year                    2022
_chemical_formula_sum            'C6 H4 Pb S2'
_chemical_formula_weight         347.41
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_update_record
;
2022-01-19 deposited with the CCDC.	2022-06-07 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 93.3828(19)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.4789(7)
_cell_length_b                   5.2068(5)
_cell_length_c                   17.4623(16)
_cell_measurement_temperature    293
_cell_volume                     678.82(11)
_diffrn_ambient_temperature      293
_diffrn_measurement_device       CuK\a
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54059
_exptl_absorpt_coefficient_mu    53.2
_exptl_crystal_density_diffrn    3.399
_exptl_crystal_F_000             616
_pd_char_colour                  yellow
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.01
_pd_meas_2theta_range_max        120.000
_pd_meas_2theta_range_min        5.000
_pd_meas_number_of_points        11501
_pd_proc_2theta_range_inc        0.01
_pd_proc_2theta_range_max        120
_pd_proc_2theta_range_min        5
_pd_proc_ls_background_function  '25 Legendre polynoms'
_pd_proc_ls_pref_orient_corr     none
_pd_proc_ls_profile_function     Pseudo-Voigt
_pd_proc_ls_prof_R_factor        0.0269
_pd_proc_ls_prof_wR_expected     0.0405
_pd_proc_ls_prof_wR_factor       0.0358
_refine_ls_goodness_of_fit_all   0.88
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_constraints    2
_refine_ls_number_parameters     68
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0180
_refine_ls_R_factor_gt           0.0179
_refine_ls_shift/su_max          0.0220
_refine_ls_shift/su_mean         0.0027
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0218
_refine_ls_wR_factor_gt          0.0217
_cod_data_source_file            d2cy00797e2.cif
_cod_data_source_block           I_CCDC1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_diffrn_radiation_probe' value 'X-ray' was changed to
'x-ray' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 1567179--1567180.cif.
;
_cod_original_cell_volume        678.83(11)
_cod_original_sg_symbol_Hall     '-P 2ycb'
_cod_original_formula_sum        'C6 H4 Pb1 S2'
_cod_database_code               1567180