Synthesis and reactivity of rare-earth metal phosphaethynolates.
Bestgen, Sebastian; Chen, Qien; Rees, Nicholas H.; Goicoechea, Jose M.; Dalton transactions (Cambridge, England : 2003) 47 (2018) 13016–13024; doi:10.1039/c8dt03427c

data_7047356
_publ_section_title
;
 Synthesis and reactivity of rare-earth metal phosphaethynolates.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13016
_journal_page_last               13024
_journal_paper_doi               10.1039/c8dt03427c
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C55 H78 N4 Nd O2 P'
_chemical_formula_sum            'C55 H78 N4 Nd O2 P'
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_chemical_name_systematic
;
 Nd{CH[N(Dipp)]2}2(THF)(OCP)
;
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_space_group_name_Hall           '-P 1'
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;
2018-07-24 deposited with the CCDC.
2018-08-23 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
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;
CrysAlisPro 1.171.38.43b (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0619P)^2^+10.7697P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7047353--7047362.cif.'
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