Electron-rich linear triplatinum complexes stabilized by a spinning tetraphosphine, tris(diphenylphosphinomethyl)phosphine.
Tanase, Tomoaki; Koike, Kanako; Uegaki, Miho; Hatada, Satoko; Nakamae, Kanako; Kure, Bunsho; Ura, Yasuyuki; Nakajima, Takayuki; Dalton transactions (Cambridge, England : 2003) 45 (2016) 7209–7214; doi:10.1039/c6dt00624h

data_7038972
_publ_section_title
;
 Electron-rich linear triplatinum complexes stabilized by a spinning
 tetraphosphine, tris(diphenylphosphinomethyl)phosphine.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7209
_journal_page_last               7214
_journal_paper_doi               10.1039/c6dt00624h
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C98 H94 Cl4 F12 N2 P10 Pt3 '
_chemical_formula_sum            'C98 H94 Cl4 F12 N2 P10 Pt3'
_chemical_formula_weight         2564.63
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_update_record
;
2016-01-27 deposited with the CCDC.
2016-03-29 downloaded from the CCDC.
;
_cell_angle_alpha                107.847(2)
_cell_angle_beta                 114.560(5)
_cell_angle_gamma                94.641(3)
_cell_formula_units_Z            1
_cell_length_a                   13.328(4)
_cell_length_b                   14.042(5)
_cell_length_c                   15.350(5)
_cell_measurement_reflns_used    6560
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      3.1
_cell_volume                     2414.1(14)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_molecular_graphics    'Mercury 3.0'
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SIR97
_diffrn_ambient_temperature      153(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.945
_diffrn_measured_fraction_theta_max 0.951
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.048
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            19548
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.42
_exptl_absorpt_coefficient_mu    4.666
_exptl_absorpt_correction_T_max  0.954
_exptl_absorpt_correction_T_min  0.698
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.764
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1256.00
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.01
_exptl_crystal_size_min          0.01
_refine_diff_density_max         2.10
_refine_diff_density_min         -1.83
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.095
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     584
_refine_ls_number_reflns         10465
_refine_ls_R_factor_gt           0.0597
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0548P)^2^+3.9881P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1447
_reflns_number_gt                7783
_reflns_number_total             10465
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            c6dt00624h2.cif
_cod_data_source_block           complex3_2DM
_cod_depositor_comments
'Adding full bibliography for 7038972--7038973.cif.'
_cod_original_cell_volume        2414.0(14)
_cod_original_formula_sum        'C98 H94 Cl4 F12 N2 P10 Pt3 '
_cod_database_code               7038972