Rhodium-Catalyzed Chemoselective Hydrosilylation of Nitriles to an Imine Oxidation Level Enabled by a Pincer-type Group 13 Metallylene Ligand
Takaya, Jun; Ogawa, Koki; Nakaya, Ryota; Iwasawa, Nobuharu; ACS Catalysis 10 (2020) 12223–12228; doi:10.1021/acscatal.0c02779

data_4518121
_publ_section_title
;
 Rhodium-Catalyzed Chemoselective Hydrosilylation of Nitriles to an Imine
 Oxidation Level Enabled by a Pincer-type Group 13 Metallylene Ligand
;
_journal_issue                   20
_journal_name_full               'ACS Catalysis'
_journal_page_first              12223
_journal_page_last               12228
_journal_paper_doi               10.1021/acscatal.0c02779
_journal_volume                  10
_journal_year                    2020
_chemical_formula_moiety         'C43 H37 Cl3 In N3 O P2 Rh', 'C4 H8 O In Cl4'
_chemical_formula_sum            'C47 H45 Cl7 In2 N3 O2 P2 Rh'
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_space_group_name_Hall           '-P 1'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.46e (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
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'w=1/[\s^2^(Fo^2^)+(0.0217P)^2^+2.7467P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 4518119--4518122.cif.'
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