Short lead(ii) soaps: from weakly fluorescent crystals to strongly phosphorescent and structurally varied vitreous phases. A thermal, structural and spectroscopic study
Francisco J. Martinez-Casado; Miguel Ramos-Riesco; Jose A. Rodriguez-Cheda; Fabio Cucinotta; Alejandro Fernandez-Martinez; Leoncio Garrido; Emilio Matesanz; Leonardo Marchese; Journal of Materials Chemistry C 2 (2014) 9489–9496; doi:10.1039/C4TC01645A

data_7233907
_publ_section_title
;
 Short lead(ii) soaps: from weakly fluorescent crystals to strongly
 phosphorescent and structurally varied vitreous phases. A thermal,
 structural and spectroscopic study
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              9489
_journal_page_last               9496
_journal_paper_doi               10.1039/C4TC01645A
_journal_volume                  2
_journal_year                    2014
_chemical_formula_moiety         'C6 H10 O4 Pb'
_chemical_formula_sum            'C6 H10 O4 Pb'
_chemical_formula_weight         353.33
_chemical_name_common            'Lead(II) propionate'
_space_group_IT_number           11
_space_group_name_Hall           '-P 2yb'
_space_group_name_H-M_alt        'P 1 21/m 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_cell_angle_alpha                90.00000
_cell_angle_beta                 97.8573(9)
_cell_angle_gamma                90.00000
_cell_formula_units_Z            2
_cell_length_a                   4.77810(5)
_cell_length_b                   7.21366(7)
_cell_length_c                   13.05820(10)
_cell_measurement_temperature    298(2)
_cell_volume                     445.859(7)
_computing_structure_refinement  FULLPROF
_diffrn_ambient_temperature      298
_diffrn_detector_type            X'Celerator
_diffrn_measurement_device_type  'PANalytical X Pert Pro Alpha-1'
_diffrn_measurement_method       '2\q scan'
_diffrn_radiation_monochromator  Ge(111)
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54056
_diffrn_source                   'rotating-anode X-ray tube'
_diffrn_source_target            Cu
_exptl_absorpt_coefficient_mu    35.833
_exptl_absorpt_correction_type   cylinder
_exptl_crystal_density_diffrn    2.632
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.008000
_pd_meas_2theta_range_max        84.98601
_pd_meas_2theta_range_min        2.50600
_pd_meas_number_of_points        10311
_pd_meas_scan_method             step
_pd_proc_2theta_range_inc        0.008000
_pd_proc_2theta_range_max        85.0125
_pd_proc_2theta_range_min        2.5325
_pd_proc_ls_pref_orient_corr     ' ?'
_pd_proc_ls_prof_R_factor        13.5879
_pd_proc_ls_prof_wR_expected     13.5325
_pd_proc_ls_prof_wR_factor       17.9144
_pd_proc_wavelength              1.540560
_pd_spec_mounting                'borosilicate capillary'
_pd_spec_mount_mode              transmission
_pd_spec_shape                   cylinder
_refine_ls_goodness_of_fit_all   1.32
_refine_ls_number_parameters     86
_refine_ls_number_reflns         446
_refine_ls_number_restraints     0
_refine_ls_R_I_factor            6.3348
_cod_data_source_file            1000004.cif
_cod_data_source_block           PCOD1000004
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_database_code               7233907
_pd_proc_ls_prof_cr_factor       21.3830
_pd_proc_ls_prof_cwr_factor      24.0742
_pd_proc_ls_prof_cwr_expected    18.1857
_pd_proc_ls_prof_chi2            1.7524
_pd_proc_ls_prof_echi2           1.8232