A blessing and a curse: impact of urea derivatives on the secondary building unit of Ca-MOFs prepared in deep eutectic solvents.
Teixeira, Michaël; Louis, Benoît; Baudron, Stéphane A; Dalton transactions (Cambridge, England : 2003) 54 (2025) 5006–5016; doi:10.1039/d4dt03254c

data_7718051
_publ_section_title
;
 A blessing and a curse: impact of urea derivatives on the secondary
 building unit of Ca-MOFs prepared in deep eutectic solvents.
;
_journal_issue                   12
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5006
_journal_page_last               5016
_journal_paper_doi               10.1039/d4dt03254c
_journal_volume                  54
_journal_year                    2025
_chemical_formula_sum            'C13 H12 Ca N2 O5'
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_audit_update_record
;
2024-11-19 deposited with the CCDC.	2025-02-12 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_exptl_crystal_description       rod
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_refine_ls_matrix_type           full
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_refine_ls_restrained_S_all      1.124
_refine_ls_R_factor_all          0.0577
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0301P)^2^+1.4857P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0898
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_reflns_number_total             1652
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4dt03254c2.cif
_cod_data_source_block           CaMOF4
_cod_depositor_comments
'Adding full bibliography for 7718045--7718055.cif.'
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_shelx_estimated_absorpt_t_min   0.986
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