From Stiba- and Bismaheteroboroxines to N,C,N-Chelated Diorganoantimony(III) and Bismuth(III) Cations-An Unexpected Case of Aryl Group Migration.
Dostál, Libor; Jambor, Roman; R°užička, Aleš; Jirásko, Robert; Lyčka, Antonín; Beckmann, Jens; Ketkov, Sergey; Inorganic chemistry 54 (2015) 6010–6019; doi:10.1021/acs.inorgchem.5b00893

data_4343080
_publ_section_title
;
 From Stiba- and Bismaheteroboroxines to N,C,N-Chelated
 Diorganoantimony(III) and Bismuth(III) Cations-An Unexpected Case of Aryl
 Group Migration.
;
_journal_issue                   12
_journal_name_full               'Inorganic chemistry'
_journal_page_first              6010
_journal_page_last               6019
_journal_paper_doi               10.1021/acs.inorgchem.5b00893
_journal_volume                  54
_journal_year                    2015
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'COLLECT (Hooft, 1998) and DENZO (Otwinowski & Minor, 1997)'
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;
Gaussian integration (Coppens, 1970)
;
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;
 Flack x determined using 3396 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   -0.045(4)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0115P)^2^+6.7807P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 4343079--4343083.cif.'
_cod_original_cell_volume        4122.8(6)
_cod_original_formula_sum        'C42 H45 B5 Bi N2 O6.50'
_cod_database_code               4343080