Benzoquinolateplatinum(ii) complexes as building blocks in the synthesis of Pt-Ag extended structures.
Forniés, Juan; Ibáñez, Susana; Lalinde, Elena; Martín, Antonio; Moreno, M. Teresa; Tsipis, Athanassios C.; Dalton transactions (Cambridge, England : 2003) 41 (2012) 3439–3451; doi:10.1039/c2dt11885h

data_7018378
_publ_section_title
;
 Benzoquinolateplatinum(ii) complexes as building blocks in the synthesis
 of Pt-Ag extended structures.
;
_journal_issue                   12
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3439
_journal_page_last               3451
_journal_paper_doi               10.1039/c2dt11885h
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C24 H13 F5 N2 Pt'
_chemical_formula_weight         619.45
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                106.468(2)
_cell_angle_beta                 96.835(2)
_cell_angle_gamma                92.411(2)
_cell_formula_units_Z            2
_cell_length_a                   9.4647(2)
_cell_length_b                   10.2895(3)
_cell_length_c                   10.5812(2)
_cell_measurement_reflns_used    13177
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.7873
_cell_measurement_theta_min      3.6808
_cell_volume                     978.06(4)
_computing_cell_refinement
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.24 (release 21-04-2008 CrysAlis171 .NET)
(compiled Apr 21 2008,18:23:10)
;
_computing_data_collection
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.32.24 (release 21-04-2008 CrysAlis171 .NET)
(compiled Apr 21 2008,18:23:10)
;
_computing_data_reduction
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.24 (release 21-04-2008 CrysAlis171 .NET)
(compiled Apr 21 2008,18:23:10)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 16.0655
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.874
_diffrn_measurement_details
;
1 omega -47.00 5.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- -19.8053 45.0000 300.0000 0.0000 0.0000 52

2 omega -41.00 13.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- -19.8053 -77.0000 180.0000 0.0000 0.0000 54

3 omega -44.00 7.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- -19.8053 -45.0000 330.0000 0.0000 0.0000 51

4 omega -41.00 13.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- -19.8053 -77.0000 300.0000 0.0000 0.0000 54

5 omega -53.00 2.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- -19.8053 77.0000 120.0000 0.0000 0.0000 55

6 omega -2.00 53.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- -19.8053 77.0000 150.0000 0.0000 0.0000 55

7 omega -5.00 47.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- 22.2271 45.0000 240.0000 0.0000 0.0000 52

8 omega -50.00 5.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- 22.2271 -77.0000 180.0000 0.0000 0.0000 55

9 omega -50.00 5.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- 22.2271 -77.0000 60.0000 0.0000 0.0000 55

10 omega -53.00 24.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- 22.2271 0.0000 240.0000 0.0000 0.0000 77

11 omega -95.00 55.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- -19.8053 0.0000 330.0000 0.0000 0.0000 150

12 omega -95.00 20.00 1.0000 7.0000
omega____ theta____ kappa____ phi______ omega'___ theta'___ frames
- -19.8053 0.0000 0.0000 0.0000 0.0000 115

;
_diffrn_measurement_device_type  'Oxfor Diffraction Xcalibur'
_diffrn_measurement_method       omega
_diffrn_orient_matrix_UB_11      -0.0631737864
_diffrn_orient_matrix_UB_12      -0.0440809426
_diffrn_orient_matrix_UB_13      -0.0193644893
_diffrn_orient_matrix_UB_21      -0.0412762820
_diffrn_orient_matrix_UB_22      0.0567812778
_diffrn_orient_matrix_UB_23      0.0066157576
_diffrn_orient_matrix_UB_31      0.0033274564
_diffrn_orient_matrix_UB_32      -0.0036247973
_diffrn_orient_matrix_UB_33      -0.0674030891
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0177
_diffrn_reflns_av_sigmaI/netI    0.0170
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            15035
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         28.94
_diffrn_reflns_theta_min         3.98
_exptl_absorpt_coefficient_mu    7.235
_exptl_absorpt_correction_T_max  0.272
_exptl_absorpt_correction_T_min  0.109
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.24 (release 21-04-2008 CrysAlis171 .NET)
(compiled Apr 21 2008,18:23:10)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.103
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             588
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.785
_refine_diff_density_min         -0.643
_refine_diff_density_rms         0.091
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         4516
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0159
_refine_ls_R_factor_gt           0.0145
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0200P)^2^+0.5872P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0344
_refine_ls_wR_factor_ref         0.0346
_reflns_number_gt                4288
_reflns_number_total             4516
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt11885h.txt
_cod_data_source_block           5
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7018378