Copper(i), silver(i) and gold(i) complexes of N-heterocyclic carbene-phosphinidene.
Adiraju, Venkata A. K.; Yousufuddin, Muhammed; Rasika Dias, H. V.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 4449–4454; doi:10.1039/c4dt03285c

data_7033141
_publ_section_title
;
 Copper(i), silver(i) and gold(i) complexes of N-heterocyclic
 carbene-phosphinidene.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4449
_journal_page_last               4454
_journal_paper_doi               10.1039/c4dt03285c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C27 H29 Au2 Cl2 N2 P'
_chemical_formula_sum            'C27 H29 Au2 Cl2 N2 P'
_chemical_formula_weight         877.32
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_cell_angle_beta                 98.0400(19)
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_cell_measurement_theta_min      3.03
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_diffrn_measurement_device_type  'Bruker D8 Quest'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0554
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_diffrn_reflns_Laue_measured_fraction_full 0.998
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_refine_ls_R_factor_all          0.0506
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0500P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0905
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_reflns_number_gt                8500
_reflns_number_total             10423
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           rad162_0m_a
_cod_depositor_comments
'Adding full bibliography for 7033139--7033142.cif.'
_cod_database_code               7033141
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_shelx_estimated_absorpt_t_max   0.610
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