Multifunctional Two-Dimensional Metal-Organic Frameworks for Radionuclide Sequestration and Detection.
Surbella, 3rd, Robert G; Reilly, Dallas D.; Sinnwell, Michael A.; McNamara, Bruce K.; Sweet, Lucas E.; Schwantes, Jon M.; Thallapally, Praveen K.; ACS applied materials & interfaces 13 (2021) 45696–45707; doi:10.1021/acsami.1c11018

data_4519047
_publ_section_title
;
 Multifunctional Two-Dimensional Metal-Organic Frameworks for Radionuclide
 Sequestration and Detection.
;
_journal_issue                   38
_journal_name_full               'ACS applied materials &amp; interfaces'
_journal_page_first              45696
_journal_page_last               45707
_journal_paper_doi               10.1021/acsami.1c11018
_journal_volume                  13
_journal_year                    2021
_chemical_formula_moiety         '[Eu(C12H6N2O4)3(C12H8N2)]'
_chemical_formula_sum            'C30 H17 Eu N5 O6'
_chemical_formula_weight         695.45
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
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_cell_angle_beta                 70.509(17)
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_cell_formula_units_Z            2
_cell_length_a                   10.938(7)
_cell_length_b                   10.939(6)
_cell_length_c                   14.771(11)
_cell_measurement_reflns_used    9396
_cell_measurement_temperature    100(2)
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_cell_measurement_theta_min      5.865
_cell_volume                     1559.0(18)
_computing_cell_refinement       'SAINT, Bruker-AXS'
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_diffrn_measured_fraction_theta_max 0.974
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_diffrn_radiation_wavelength     0.71076
_diffrn_reflns_av_R_equivalents  0.0491
_diffrn_reflns_av_unetI/netI     0.0577
_diffrn_reflns_Laue_measured_fraction_full 0.993
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_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.974
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_diffrn_reflns_theta_max         30.851
_diffrn_reflns_theta_min         2.932
_diffrn_source                   'Sealed Tube, Triumph Monochromator'
_diffrn_source_type              Seimens
_exptl_absorpt_coefficient_mu    2.059
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6497
_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            'light green'
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_exptl_crystal_recrystallization_method 'Hydrothermal Synthesis'
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_refine_ls_matrix_type           full
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_refine_ls_R_factor_all          0.0655
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+9.6140P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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