A heterometallic D‒A hybrid heterostructural framework with enhanced visible-light photocatalytic properties
Liu, Jian-Jun; You, Ming-Hua; Li, Meng-Hua; Huang, Chang-Cang; Lin, Mei-Jin; CrystEngComm 22 (2020) 420–424; doi:10.1039/C9CE01582E

data_7239679
_publ_section_title
;
 A heterometallic D--A hybrid heterostructural framework with enhanced
 visible-light photocatalytic properties
;
_journal_issue                   3
_journal_name_full               CrystEngComm
_journal_page_first              420
_journal_page_last               424
_journal_paper_doi               10.1039/C9CE01582E
_journal_volume                  22
_journal_year                    2020
_chemical_formula_sum            'C68 H56 Ce Cu6 I9 N8 O12'
_chemical_formula_weight         2840.66
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-12-03 deposited with the CCDC.	2019-12-04 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2007)'
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2014/6 (Sheldrick, 2014)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.994
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_diffrn_measurement_device_type  'CCD area detector'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrystalClear (Rigaku Inc., 2007)'
_exptl_crystal_colour            black
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_exptl_crystal_description       platelike
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_refine_ls_R_factor_all          0.1421
_refine_ls_R_factor_gt           0.0703
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0805P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1639
_refine_ls_wR_factor_ref         0.1951
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10646
_reflns_number_total             20060
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9ce01582e2.cif
_cod_data_source_block           complex1
_cod_depositor_comments
;Adding full bibliography for 7239679.cif.

 Adding full bibliography for 7239679.cif.
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7239679
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              11824
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