Synthesis, characterization, and crystal structures of organonickel(II) complexes coordinated to novel 1-bromo-2,6-bis{[(λ^5^-phosphanylidene)imino]methyl}benzene NCN-pincer ligands
Guillet, Gary L.; Pitts, Skyler L.; Sheriff, Kirkland W.; Rucker, Donna N.; Rogers, Aaryn L.; Acta Crystallographica Section C 75 (2019) 1381–1388; doi:10.1107/S2053229619012038

data_2021767
_publ_section_title
;
 Synthesis, characterization, and crystal structures of organonickel(II)
 complexes coordinated to novel
 1-bromo-2,6-bis{[(\l^5^-phosphanylidene)imino]methyl}benzene NCN-pincer
 ligands
;
_journal_coeditor_code           JX3045
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_journal_name_full               'Acta Crystallographica Section C'
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_journal_page_last               1388
_journal_paper_doi               10.1107/S2053229619012038
_journal_volume                  75
_journal_year                    2019
_chemical_formula_iupac          '[Ni Br (C44 H61 N2 P2)]'
_chemical_formula_moiety         'C44 H61 Br N2 Ni P2'
_chemical_formula_sum            'C44 H61 Br N2 Ni P2'
_chemical_formula_weight         818.50
_chemical_name_systematic
(2,6-Bis{[(dicyclohexylphenyl-\l^5^-phosphanylidene)imino]methyl}phenyl-\k^3^<i>N</i>,<i>C</i>^1^,<i>N</i>')bromidonickel(II)
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
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;
CrystalClear (Rigaku, 2009)
;
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CrystalClear (Rigaku, 2009)
;
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CrystalClear (Rigaku, 2009)
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OLEX2 (Dolomanov <i>et al.</i>,  2009)
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OLEX2 (Dolomanov <i>et al.</i>,  2009)
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SHELXL2014 (Sheldrick, 2015b)
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SHELXT (Sheldrick, 2015a)
;
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;
(<i>REQAB</i>; Rigaku, 1998)
;
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'w=1/[\s^2^(Fo^2^)+(0.0692P)^2^+6.6008P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 2021765--2021768.cif.'
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