Easily accessible, hydrocarbon-soluble, crystalline, anhydrous lanthanide (Nd, La, and Y) phosphates.
Nifant'ev, Ilya E.; Tavtorkin, Alexander N.; Shlyahtin, Andrei V.; Korchagina, Sof'ya A.; Gavrilenko, Inna F.; Glebova, Natalya N.; Churakov, Andrei V.; Dalton transactions (Cambridge, England : 2003) 42 (2013) 1223–1230; doi:10.1039/c2dt31505j

data_7022053
_publ_section_title
;
 Easily accessible, hydrocarbon-soluble, crystalline, anhydrous lanthanide
 (Nd, La, and Y) phosphates.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1223
_journal_page_last               1230
_journal_paper_doi               10.1039/c2dt31505j
_journal_volume                  42
_journal_year                    2013
_chemical_formula_moiety         'C102 H168 Nd2 O24 P6'
_chemical_formula_sum            'C102 H168 Nd2 O24 P6'
_chemical_formula_weight         2252.66
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                65.781(2)
_cell_angle_beta                 75.178(3)
_cell_angle_gamma                82.048(3)
_cell_formula_units_Z            1
_cell_length_a                   14.273(3)
_cell_length_b                   14.921(3)
_cell_length_c                   15.089(3)
_cell_measurement_reflns_used    9905
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      29.566
_cell_measurement_theta_min      2.339
_cell_volume                     2831.1(10)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART APEX II'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0259
_diffrn_reflns_av_sigmaI/netI    0.0387
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            29369
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         28.00
_diffrn_reflns_theta_min         1.48
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.057
_exptl_absorpt_correction_T_max  0.9017
_exptl_absorpt_correction_T_min  0.8165
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2004)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.321
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1182
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.972
_refine_diff_density_min         -0.456
_refine_diff_density_rms         0.082
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     628
_refine_ls_number_reflns         13617
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.075
_refine_ls_R_factor_all          0.0389
_refine_ls_R_factor_gt           0.0310
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0469P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0794
_refine_ls_wR_factor_ref         0.0827
_reflns_number_gt                11903
_reflns_number_total             13617
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            c2dt31505j.txt
_cod_data_source_block           c
_cod_original_cell_volume        2831.1(9)
_cod_database_code               7022053