Isolation and Detailed Characterization of the trans-[(H2O)2FeCl4]- Anion: Stabilization of Novel Iron(III) Species by Large Organic Cations
Bruce D. James; Margarita Bakalova; John Liesegang; William Michael Reiff; Brian W. Skelton; Allan H. White; Inorganic Chemistry 40 (2001) 4617–4622; doi:10.1021/ic001264p

data_4320148
_publ_contact_author_address
;
   Department of Chemistry
   University of Western Australia
   35 Stirling Hwy,
   Crawley,
   Western Australia 6009,
   Australia
;
_publ_contact_author_email       bws@crystal.uwa.edu.au
_publ_contact_author_fax         (+61)_08_9380_1118
_publ_contact_author_name        'Skelton, B. W.'
_publ_contact_author_phone       (+61)_08-9380_3481
_publ_section_title
;
 Isolation and Detailed Characterization of the trans-[(H2O)2FeCl4]-
 Anion: Stabilization of Novel Iron(III) Species by Large Organic Cations
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4617
_journal_page_last               4622
_journal_paper_doi               10.1021/ic001264p
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C6 H16 Cl3.5 Fe0.5 N2 O'
_chemical_formula_weight         284.22
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
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_cell_angle_gamma                90.00000
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_cell_measurement_theta_max      25.0
_cell_measurement_theta_min      25.0
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_computing_cell_refinement       'Enraf Nonius software'
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_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
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_diffrn_measurement_device_type
;
 CAD4 diffractometer
;
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_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
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_exptl_absorpt_correction_T_max  .88
_exptl_absorpt_correction_T_min  .77
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
 XTAL absorb                 
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.618
_exptl_crystal_description       needle
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_exptl_crystal_size_mid          .20
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_refine_ls_number_restraints     0
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_refine_ls_structure_factor_coef F
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_reflns_limit_h_max              19
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_reflns_limit_k_min              0
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_reflns_limit_l_min              0
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_reflns_threshold_expression     'I    > 3.00 sig(I   )'
_cod_data_source_file            ic001264p_1.cif
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_cod_original_sg_symbol_Hall     -p_2ac_2n
_cod_original_formula_sum        'C6 H16 Cl3.5 Fe.5 N2 O1'
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