Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of Dihydroisoquinolones.
Hyster, Todd K.; Dalton, Derek M.; Rovis, Tomislav; Chemical science (Royal Society of Chemistry : 2010) 6 (2015) 254–258; doi:10.1039/C4SC02590C

data_1517870
_publ_section_title
;
 Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical
 Cyclopentadienyl Enables a Regioselective Synthesis of
 Dihydroisoquinolones.
;
_journal_issue                   1
_journal_name_full
'Chemical science (Royal Society of Chemistry : 2010)'
_journal_page_first              254
_journal_page_last               258
_journal_paper_doi               10.1039/C4SC02590C
_journal_volume                  6
_journal_year                    2015
_chemical_formula_moiety         'C21 H29 Cl N Rh'
_chemical_formula_sum            'C21 H29 Cl N Rh'
_chemical_formula_weight         433.81
_chemical_name_systematic
;

 ?

;
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_diffrn_ambient_temperature      120(2)
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_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'CCD area detector'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Sheldrick, G. M. (2008) SADABS. University of Gottingen, Germany.'
_exptl_crystal_colour            yellow
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_exptl_crystal_density_meas      ?
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0573P)^2^+1.1136P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_file            c4sc02590c2.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2827 2014-09-09 07:05:25Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not determined' was changed to
'?' - the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 1517870.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1517870