Bis[(2-methylbenzyl)bis(pyridin-2-ylmethyl-κ<i>N</i>)amine-κ<i>N</i>]manganese(II) bis(perchlorate)
Butcher, Ray J.; Gultneh, Yilma; Yisgedu, T. B.; Acta Crystallographica Section E 70 (2014) m100–m101; doi:10.1107/S1600536814003055

data_2239438
_publ_section_title
;
 Bis[(2-methylbenzyl)bis(pyridin-2-ylmethyl-\k<i>N</i>)amine-\k<i>N</i>]manganese(II)
 bis(perchlorate)
;
_journal_coeditor_code           MW2117
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m100
_journal_page_last               m101
_journal_paper_doi               10.1107/S1600536814003055
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac          '[Mn (C20 H21 N3)2] (Cl O4)2'
_chemical_formula_moiety         'C40 H42 Mn N6 2+, 2(Cl O4 -)'
_chemical_formula_sum            'C40 H42 Cl2 Mn N6 O8'
_chemical_formula_weight         860.63
_chemical_name_systematic
'Bis[(2-methylbenzyl)bis(pyridin-2-ylmethyl-\k<i>N</i>)amine-\k<i>N</i>]manganese(II) bis(perchlorate)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
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_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   23.162(3)
_cell_length_b                   10.4755(11)
_cell_length_c                   19.391(2)
_cell_measurement_reflns_used    45
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      12.49
_cell_measurement_theta_min      4.98
_cell_volume                     4119.1(9)
_computing_cell_refinement       'XSCANS (Siemens, 1991)'
_computing_data_collection       'XSCANS (Siemens, 1991)'
_computing_data_reduction        'XDISK (Siemens, 1991)'
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_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       '\w scans'
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_diffrn_reflns_av_R_equivalents  0.0208
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_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -25
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_diffrn_reflns_theta_full        25.500
_diffrn_reflns_theta_max         27.498
_diffrn_reflns_theta_min         2.188
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.509
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_exptl_absorpt_correction_T_min  0.72
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   '(XEMP; Siemens, 1989)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.388
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0957P)^2^+3.6800P] where P=(Fo^2^+2Fc^2^)/3'
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