Controlling magnetism via transition metal exchange in the series of intermetallics Eu(T1,T2)5In (T = Cu, Ag, Au)
Smetana, Volodymyr; Mudryk, Yaroslav; Pecharsky, Vitalij K.; Mudring, Anja-Verena; Journal of Materials Chemistry C 6 (2018) 1353–; doi:10.1039/C7TC04964A

data_7237005
_publ_section_title
;
 Controlling magnetism via transition metal exchange in the series of
 intermetallics Eu(T1,T2)5In (T = Cu, Ag, Au)
;
_journal_issue                   6
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              1353
_journal_paper_doi               10.1039/C7TC04964A
_journal_volume                  6
_journal_year                    2018
_chemical_formula_sum            'Ag3.09 Cu1.91 Eu In'
_chemical_formula_weight         721.40
_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_Hall           '-P 2ac 2n'
_space_group_name_H-M_alt        'P n m a'
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-08-01 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.8834(18)
_cell_length_b                   5.3927(11)
_cell_length_c                   11.243(2)
_cell_measurement_reflns_used    1373
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.252
_cell_measurement_theta_min      2.922
_cell_volume                     538.60(18)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker Venture'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0712
_diffrn_reflns_av_unetI/netI     0.1001
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            1373
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.252
_diffrn_reflns_theta_min         2.922
_exptl_absorpt_coefficient_mu    33.886
_exptl_absorpt_correction_T_max  0.01
_exptl_absorpt_correction_T_min  0.008
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_density_diffrn    8.903
_exptl_crystal_description       'irregular fragment'
_exptl_crystal_F_000             1250
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_refine_diff_density_max         2.548
_refine_diff_density_min         -3.901
_refine_diff_density_rms         0.736
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.983
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     43
_refine_ls_number_reflns         800
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.983
_refine_ls_R_factor_all          0.1047
_refine_ls_R_factor_gt           0.0551
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0451P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1026
_refine_ls_wR_factor_ref         0.1137
_reflns_Friedel_coverage         0.000
_reflns_number_gt                516
_reflns_number_total             800
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7tc04964a2.cif
_cod_data_source_block           23
_cod_original_cell_volume        538.60(19)
_cod_database_code               7237005
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              27584