Chemo-, Regio-, and Stereoselective Trifluoromethylation of Styrenes via Visible Light-Driven Single-Electron Transfer (SET) and Triplet-Triplet Energy Transfer (TTET) Processes.
Lin, Qing-Yu; Xu, Xiu-Hua; Qing, Feng-Ling; The Journal of organic chemistry 79 (2014) 10434–; doi:10.1021/jo502040t

data_4030069
_publ_section_title
;
 Chemo-, Regio-, and Stereoselective Trifluoromethylation of Styrenes via
 Visible Light-Driven Single-Electron Transfer (SET) and Triplet-Triplet
 Energy Transfer (TTET) Processes.
;
_journal_issue                   21
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              10434
_journal_paper_doi               10.1021/jo502040t
_journal_volume                  79
_journal_year                    2014
_chemical_formula_moiety         'C13 H14 F3 N O'
_chemical_formula_sum            'C13 H14 F3 N O'
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_cell_measurement_theta_max      66.87
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_theta_full        67.05
_diffrn_reflns_theta_max         67.05
_diffrn_reflns_theta_min         5.38
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_exptl_absorpt_correction_T_min  0.4127
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_exptl_crystal_colour            colorless
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
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_refine_ls_R_factor_all          0.0570
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1063P)^2^+0.1714P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments          'Adding full bibliography for 4030069.cif.'
_cod_original_cell_volume        1236.4(4)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4030069