Chromium mediated reductive coupling of isonitrile forms unusual heterocycles.
Shen, Jingmei; Yap, Glenn P. A.; Theopold, Klaus H.; Journal of the American Chemical Society 136 (2014) 3382–3384; doi:10.1021/ja501291p

data_4121490
_publ_section_title
;
 Chromium mediated reductive coupling of isonitrile forms unusual
 heterocycles.
;
_journal_issue                   9
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3382
_journal_page_last               3384
_journal_paper_doi               10.1021/ja501291p
_journal_volume                  136
_journal_year                    2014
_chemical_formula_sum            'C96 H143 Cr2 N10 O0.5'
_chemical_formula_weight         1549.20
_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           '-P 2n 2ab'
_space_group_name_H-M_alt        'P b c n'
_symmetry_space_group_name_Hall  '-P 2n 2ab'
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_computing_structure_solution    'Bruker SHELXTL'
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_diffrn_measurement_device_type  'Bruker AXS APEX diffractometer'
_diffrn_measurement_method       '\f and \w scans'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'APEX2 (Bruker, 2007)'
_exptl_crystal_colour            brown
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'w=1/[\s^2^(Fo^2^)+(0.0647P)^2^+8.9162P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_original_formula_sum        'C96 H143 Cr2 N10 O0.50'
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