Photoredox-Catalyzed Reductive Dimerization of Isatins and Isatin-Derived Ketimines: Diastereoselective Construction of 3,3'-Disubstituted Bisoxindoles.
Wang, Chao-Ming; Xia, Peng-Ju; Xiao, Jun-An; Li, Jun; Xiang, Hao-Yue; Chen, Xiao-Qing; Yang, Hua; The Journal of organic chemistry 82 (2017) 3895–3900; doi:10.1021/acs.joc.6b03056

data_4032410
_publ_section_title
;
 Photoredox-Catalyzed Reductive Dimerization of Isatins and Isatin-Derived
 Ketimines: Diastereoselective Construction of 3,3'-Disubstituted
 Bisoxindoles.
;
_journal_issue                   7
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              3895
_journal_page_last               3900
_journal_paper_doi               10.1021/acs.joc.6b03056
_journal_volume                  82
_journal_year                    2017
_chemical_formula_sum            'C60 H48 N4 O8'
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_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
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_cell_angle_beta                 85.903(5)
_cell_angle_gamma                66.308(4)
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_cell_length_b                   9.3471(7)
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_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.03
_cell_measurement_theta_min      2.46
_cell_volume                     1162.38(16)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
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_diffrn_reflns_av_sigmaI/netI    0.0287
_diffrn_reflns_limit_h_max       10
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_diffrn_reflns_limit_k_max       11
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_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            11990
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         2.46
_exptl_absorpt_coefficient_mu    0.091
_exptl_crystal_colour            COLORLESS
_exptl_crystal_density_diffrn    1.361
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BAR
_exptl_crystal_F_000             500
_exptl_crystal_size_max          0.3
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_exptl_crystal_size_min          0.2
_refine_diff_density_max         0.789
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
_refine_ls_number_parameters     147
_refine_ls_number_reflns         4081
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_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.1125
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_refine_ls_shift/su_mean         0.021
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1206P)^2^+2.8879P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2435
_refine_ls_wR_factor_ref         0.2582
_reflns_number_gt                3325
_reflns_number_total             4081
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            jo6b03056_si_001.cif
_cod_data_source_block           ja
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 4032408--4032410.cif.
;
_cod_original_cell_volume        1162.38(15)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4032410