Construction of the Multidecker Anthracene-Silver(I) System by Intramolecular π-π Interactions
Megumu Munakata; Liang Ping Wu; Takayoshi Kuroda-Sowa; Masahiko Maekawa; Yusaku Suenaga; Tetsuhiro Ohta; Hisashi Konaka; Inorganic Chemistry 42 (2003) 2553–2558; doi:10.1021/ic020379l

data_4313451
_publ_section_title
;
 Construction of the Multidecker Anthracene-Silver(I) System by
 Intramolecular \p-\p Interactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2553
_journal_page_last               2558
_journal_paper_doi               10.1021/ic020379l
_journal_volume                  42
_journal_year                    2003
_chemical_formula_moiety         'C32 H34 Ag2 Cl2 O8 '
_chemical_formula_sum            'C32 H34 Ag2 Cl2 O8'
_chemical_formula_weight         833.26
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 97.32(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   7.885(2)
_cell_length_b                   12.345(2)
_cell_length_c                   17.059(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      12.5
_cell_measurement_theta_min      11.2
_cell_volume                     1647.0(6)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  SHELXL97
_computing_structure_solution    MITHRIL90
_diffrn_measured_fraction_theta_full 1.00
_diffrn_measured_fraction_theta_max 1.00
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.018
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            3130
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_standards_decay_%        14.85
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.396
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.680
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       brick
_exptl_crystal_F_000             836.0
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.78
_refine_diff_density_min         -0.87
_refine_ls_extinction_coef       0.0000
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     199
_refine_ls_number_reflns         1974
_refine_ls_R_factor_gt           0.0567
_refine_ls_shift/su_max          0.0010
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.1016P)^2^+5.6717P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2047
_reflns_number_gt                1974
_reflns_number_total             2906
_reflns_threshold_expression     >2.0sigma(I)
_cod_data_source_file            ic020379l_1.cif
_cod_data_source_block           '[Ag(dman)0.5(ClO4)(p-xylen'
_cod_original_cell_volume        1646.9(6)
_cod_original_formula_sum        'C32 H34 Ag2 Cl2 O8 '
_cod_database_code               4313451