Synthesis of β-Imino Carbonyl Enolato Complexes by Reaction of Nickel(II), Palladium(II), and Copper(II) Acetates with the Enaminodiones (MeOCO)(RCO)CC(R')NH2 (R = Me, OMe; R' = Et, EtOCO)
Marino Basato; Umberto Vettori; Augusto C. Veronese; Alfonso Grassi; Giovanni Valle; Inorganic Chemistry 37 (1998) 6737–6745; doi:10.1021/ic9716114

data_4323237
_publ_section_title
;
 Synthesis of \b-Imino Carbonyl Enolato Complexes by Reaction of
 Nickel(II), Palladium(II), and Copper(II) Acetates with the Enaminodiones
 (MeOCO)(RCO)CC(R')NH2 (R = Me, OMe; R' = Et, EtOCO)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6737
_journal_page_last               6745
_journal_paper_doi               10.1021/ic9716114
_journal_volume                  37
_journal_year                    1998
_chemical_formula_moiety         'C18 H24 N2 O12 Pd'
_chemical_formula_sum            'C18 H24 N2 O12 Pd'
_chemical_formula_weight         566.79
_chemical_name_systematic
;
bis(1-ethoxy-2-imino-4-methoxy-3-methoxycarbonyl-1,4-butanedionato-N2,O4)pal
ladium
;
_space_group_IT_number           14
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_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_cell_angle_gamma                90.00
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_cell_length_c                   13.918(2)
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_cell_measurement_temperature    293(2)
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_cell_measurement_theta_min      7
_cell_volume                     2209.7(7)
_computing_structure_refinement  'SHELXL76 (Sheldrick, 1976)'
_computing_structure_solution    'SHELX86 (Sheldrick., 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       'Philips PW 1100 diffractometer'
_diffrn_measurement_method       \q/2\q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
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_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       0
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_diffrn_standards_decay_%        10
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_exptl_absorpt_coefficient_mu    0.0907
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_exptl_crystal_description       prism
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_exptl_crystal_size_min          0.12
_refine_ls_extinction_method     none
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_refine_ls_number_restraints     0
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_refine_ls_shift/esd_mean        0.0022
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     w=1/[\s^2^(F)+0.000682F^2^]
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                3122
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(F)+0.000682F^2^]' was changed to 'calc'. New tag
'_refine_ls_weighting_details' was created. The value of the new tag
was set to 'w=1/[\s^2^(F)+0.000682F^2^]'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2219.7(7)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4323237