Substrate and product binding inside a stimuli-responsive coordination cage acting as a singlet oxygen photosensitizer.
Pullen, Sonja; Löffler, Susanne; Platzek, André; Holstein, Julian J.; Clever, Guido H.; Dalton transactions (Cambridge, England : 2003) 49 (2020) 9404–9410; doi:10.1039/d0dt01674h

data_7704667
_publ_section_title
;
 Substrate and product binding inside a stimuli-responsive coordination
 cage acting as a singlet oxygen photosensitizer.
;
_journal_issue                   27
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9404
_journal_page_last               9410
_journal_paper_doi               10.1039/d0dt01674h
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C270 H224 B3 Cl2.5 F12 N24 O10 Pd4'
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_chemical_properties_physical    Air-sensitive,Moisture-sensitive
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_space_group_name_Hall           '-P 4a 2ac'
_space_group_name_H-M_alt        'P 4/n c c :2'
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;
2019-09-09 deposited with the CCDC.	2020-06-15 downloaded from the CCDC.
;
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_diffrn_source                   'microfocus sealed X-ray tube'
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;
SADABS-2014/5 - Bruker AXS area detector scaling and absorption correction:
Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D., J. Appl. Cryst. 48
(2015) 3-10
;
_exptl_crystal_colour            colourless
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'slow vapor diffusion of diethyl ether into an acetonitrile solution of the host-guest complex'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.5366
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt01674h2.cif
_cod_data_source_block           sl433_sq
_cod_depositor_comments
'Adding full bibliography for 7704666--7704667.cif.'
_cod_original_cell_volume        30009(6)
_cod_original_sg_symbol_H-M      'P 4/n c c'
_cod_original_formula_sum        'C270 H224 B3 Cl2.50 F12 N24 O10 Pd4'
_cod_database_code               7704667
_diffrn_ambient_temperature_device 'Oxford Cryostream 800'
_olex2_diffrn_ambient_temperature_device 'Oxford Cryostream 800'
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.782
_shelx_estimated_absorpt_t_max   0.882
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