Cobalt- or rhodium-catalyzed synthesis of 1,2-dihydrophosphete oxides <i>via</i> C-H activation and formal phosphoryl migration.
Xu, Shengbo; Mi, Ruijie; Zheng, Guangfan; Li, Xingwei; Chemical science 15 (2024) 6012–6021; doi:10.1039/d4sc00649f

data_1571245
_publ_section_title
;
 Cobalt- or rhodium-catalyzed synthesis of 1,2-dihydrophosphete oxides
 <i>via</i> C-H activation and formal phosphoryl migration.
;
_journal_issue                   16
_journal_name_full               'Chemical science'
_journal_page_first              6012
_journal_page_last               6021
_journal_paper_doi               10.1039/d4sc00649f
_journal_volume                  15
_journal_year                    2024
_chemical_formula_sum            'C32 H23 Br Cl3 N2 O2 P'
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2022-08-26 deposited with the CCDC.	2024-03-12 downloaded from the CCDC.
;
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0409P)^2^+0.6965P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 1571245--1571246.cif.'
_cod_original_cell_volume        1509.54(7)
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