Sterically Controlled Ru(II)-Catalyzed Divergent Synthesis of 2-Methylindoles and Indolines through a C-H Allylation/Cyclization Cascade.
Manna, Manash Kumar; Bairy, Gurupada; Jana, Ranjan; The Journal of organic chemistry 83 (2018) 8390–8400; doi:10.1021/acs.joc.8b01034

data_4035539
_publ_section_title
;
 Sterically Controlled Ru(II)-Catalyzed Divergent Synthesis of
 2-Methylindoles and Indolines through a C-H Allylation/Cyclization
 Cascade.
;
_journal_issue                   15
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              8390
_journal_page_last               8400
_journal_paper_doi               10.1021/acs.joc.8b01034
_journal_volume                  83
_journal_year                    2018
_chemical_formula_sum            'C20 H16 N2'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_exptl_crystal_size_max          0.720
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2016/6 (Sheldrick 2016)'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0532P)^2^+0.2260P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                2094
_reflns_number_total             2661
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_original_sg_symbol_H-M      'P 21/n'
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_shelx_res_checksum              22237
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