Challenges in the synthetic routes to Mn(BH4)2: insight into intermediate compounds.
Tumanov, Nikolay A.; Safin, Damir A.; Richter, Bo; Łodziana, Zbigniew; Jensen, Torben R.; Garcia, Yann; Filinchuk, Yaroslav; Dalton transactions (Cambridge, England : 2003) 44 (2015) 6571–6580; doi:10.1039/c4dt03807j

data_7033961
_publ_section_title
;
 Challenges in the synthetic routes to Mn(BH4)2: insight into intermediate
 compounds.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6571
_journal_page_last               6580
_journal_paper_doi               10.1039/c4dt03807j
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'B5 H20 Mn2, 2(C4 H10 O), Li'
_chemical_formula_sum            'C8 H40 B5 Li Mn2 O2'
_chemical_formula_weight         339.27
_chemical_name_common
;
lithium dimanganese pentaborohydride bis(diethyl ether)
;
_chemical_name_systematic        ' ?'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_update_record
;
2014-02-06 deposited with the CCDC.
2015-02-10 downloaded from the CCDC.
;
_cell_angle_alpha                90.00000
_cell_angle_beta                 110.8649(14)
_cell_angle_gamma                90.00000
_cell_formula_units_Z            4
_cell_length_a                   21.7106(3)
_cell_length_b                   7.72944(12)
_cell_length_c                   14.02422(19)
_cell_volume                     2199.09(6)
_computing_structure_refinement  FULLPROF
_computing_structure_solution    FOX
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.827420
_exptl_absorpt_coefficient_mu    1.138
_exptl_crystal_density_diffrn    1.025
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             728.0
_pd_char_colour                  yellow
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.007216
_pd_meas_2theta_range_max        36.06976
_pd_meas_2theta_range_min        0.04690
_pd_meas_number_of_points        4994
_pd_meas_scan_method             fixed
_pd_proc_2theta_range_inc        0.007216
_pd_proc_2theta_range_max        36.0778
_pd_proc_2theta_range_min        0.0549
_pd_proc_ls_pref_orient_corr     ' ?'
_pd_proc_ls_prof_R_factor        3.8975
_pd_proc_ls_prof_wR_expected     0.5179
_pd_proc_ls_prof_wR_factor       5.3471
_pd_proc_wavelength              0.827420
_pd_spec_mounting
; 
Sample in 0.5 mm glass capillary was mounted in argon-filled glovebox
;
_pd_spec_mount_mode              transmission
_pd_spec_shape                   cylinder
_refine_ls_goodness_of_fit_all   10.3242
_refine_ls_number_parameters     24
_refine_ls_number_reflns         569
_refine_ls_number_restraints     77
_refine_ls_R_I_factor            5.0528
_refine_ls_shift/su_max          0.01
_cod_data_source_file            c4dt03807j1.cif
_cod_data_source_block           Mn2Li(BH4)5*C4H10O5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 7033961--7033963.cif.
;
_cod_database_code               7033961
_pd_proc_ls_prof_cr_factor       10.5242
_pd_proc_ls_prof_cwr_factor      11.2901
_pd_proc_ls_prof_cwr_expected    1.0936
_pd_proc_ls_prof_chi2            106.5897
_pd_proc_ls_prof_echi2           108.6613