Generation of a zinc and rhodium containing metallomacrocycle by rearrangement of a six-coordinate precursor complex.
Groß, C; Sun, Y.; Jost, T.; Grimm, T.; Klein, M. P.; Niedner-Schatteburg, G; Becker, S.; Thiel, W. R.; Chemical communications (Cambridge, England) 56 (2020) 368–371; doi:10.1039/c9cc07723e

data_7125454
_publ_section_title
;
 Generation of a zinc and rhodium containing metallomacrocycle by
 rearrangement of a six-coordinate precursor complex.
;
_journal_issue                   3
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              368
_journal_page_last               371
_journal_paper_doi               10.1039/c9cc07723e
_journal_volume                  56
_journal_year                    2020
_chemical_formula_sum            'C57 H55 N5 P2'
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_audit_update_record
;
2019-09-17 deposited with the CCDC.	2019-11-26 downloaded from the CCDC.
;
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_diffrn_radiation_type           'Cu K\a'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
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_exptl_crystal_description       'transparent prism'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0468P)^2^+1.5110P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0933
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                6877
_reflns_number_total             7649
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9cc07723e2.cif
_cod_data_source_block           shelx
_cod_depositor_comments
'Adding full bibliography for 7125454--7125455.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7125454
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.722
_shelx_estimated_absorpt_t_max   0.804
_shelx_res_checksum              45914