Linear Trinuclear Pt...Mo-Mo Complexes [Mo2PtX2(pyphos)2(O2CR)2]2 (X = Cl, Br, I; R = CH3, C(CH3)3; pyphos = 6-(Diphenylphosphino)-2-pyridonate) with an Axial Interaction between the Quadruply Bonded Mo2 Moiety and the Platinum Atom
Hiroshi Nakano; Akira Nakamura; Kazushi Mashima; Inorganic Chemistry 35 (1996) 4007–4012; doi:10.1021/ic950988b

data_4323838
_publ_section_title
;
 Linear Trinuclear Pt...Mo-Mo Complexes [Mo2PtX2(pyphos)2(O2CR)2]2 (X =
 Cl, Br, I; R = CH3, C(CH3)3; pyphos = 6-(Diphenylphosphino)-2-pyridonate)
 with an Axial Interaction between the Quadruply Bonded Mo2 Moiety and the
 Platinum Atom
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4007
_journal_page_last               4012
_journal_paper_doi               10.1021/ic950988b
_journal_volume                  35
_journal_year                    1996
_chemical_formula_sum            'C42 H40 Br2 Cl8 Mo2 N2 O6 P2 Pt'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_creation_date             'Tue Nov 21 22:17:51 1995'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 124.444(8)
_cell_angle_gamma                90
_cell_formula_units_Z            8.00
_cell_length_a                   34.733(4)
_cell_length_b                   17.818(10)
_cell_length_c                   22.530(5)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    23.0
_cell_measurement_theta_max      32.52
_cell_measurement_theta_min      27.27
_cell_volume                     11499(7)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_computing_structure_solution    'DIRDIF92 (PATTY)'
_diffrn_ambient_temperature      23.0
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
_diffrn_orient_matrix_UB_11      -0.01737
_diffrn_orient_matrix_UB_12      -0.04864
_diffrn_orient_matrix_UB_13      -0.01680
_diffrn_orient_matrix_UB_21      -0.03025
_diffrn_orient_matrix_UB_22      0.02798
_diffrn_orient_matrix_UB_23      -0.02734
_diffrn_orient_matrix_UB_31      0.00130
_diffrn_orient_matrix_UB_32      0.00121
_diffrn_orient_matrix_UB_33      -0.04321
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  4.08
_diffrn_reflns_limit_h_max       48
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_number            17559
_diffrn_reflns_theta_max         30.0194
_diffrn_standards_decay_%        4.14
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu_cm 47.092
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.607
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.803
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             6016.00
_exptl_crystal_size_max          0.600
_exptl_crystal_size_min          0.200
_refine_diff_density_max         -2.16150
_refine_diff_density_min         2.98940
_refine_ls_extinction_coef       0.00000
_refine_ls_extinction_method     Zachariasen_type_2_Gaussian_isotropic
_refine_ls_goodness_of_fit_obs   1.430
_refine_ls_matrix_type           full
_refine_ls_number_parameters     588
_refine_ls_number_reflns         8659
_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0600
_refine_ls_shift/esd_max         9.5440
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0840
_cod_data_source_file            ic950988b_4.cif
_cod_data_source_block           C42H40O6N2Cl8Br2P2Mo2Pt
_cod_original_cell_volume        11498(5)
_cod_original_sg_symbol_H-M      'C 2/c '
_cod_original_formula_sum        'C42 H40 O6 N2 Cl8 Br2 P2 Mo2 Pt'
_cod_database_code               4323838