A coordination polymer-derived Co<sub>3</sub>O<sub>4</sub>/Co-N@NMC composite material as a Zn-air battery cathode electrocatalyst and microwave absorber.
Wang, Yaqin; Xu, Xinxin; Liu, Luyao; Chen, Jin; Shi, Guimei; Dalton transactions (Cambridge, England : 2003) 48 (2019) 7150–7157; doi:10.1039/c8dt03792b

data_7047729
_publ_section_title
;
 A coordination polymer-derived Co<sub>3</sub>O<sub>4</sub>/Co-N@NMC
 composite material as a Zn-air battery cathode electrocatalyst and
 microwave absorber.
;
_journal_issue                   21
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7150
_journal_page_last               7157
_journal_paper_doi               10.1039/c8dt03792b
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C21 H25 Co1.5 N2 O11'
_chemical_formula_weight         569.83
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2018-08-29 deposited with the CCDC.
2018-10-03 downloaded from the CCDC.
;
_cell_angle_alpha                69.693(3)
_cell_angle_beta                 75.801(2)
_cell_angle_gamma                82.165(2)
_cell_formula_units_Z            2
_cell_length_a                   10.1175(2)
_cell_length_b                   10.6294(3)
_cell_length_c                   12.5269(4)
_cell_measurement_reflns_used    15978
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.07
_cell_measurement_theta_min      3.37
_cell_volume                     1222.91(6)
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.871
_diffrn_measured_fraction_theta_max 0.871
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0273
_diffrn_reflns_av_sigmaI/netI    0.0374
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15978
_diffrn_reflns_theta_full        29.07
_diffrn_reflns_theta_max         29.07
_diffrn_reflns_theta_min         3.37
_exptl_absorpt_coefficient_mu    1.091
_exptl_absorpt_correction_T_max  0.822
_exptl_absorpt_correction_T_min  0.778
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.547
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             587
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.664
_refine_diff_density_min         -0.567
_refine_diff_density_rms         0.074
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     352
_refine_ls_number_reflns         5713
_refine_ls_number_restraints     15
_refine_ls_restrained_S_all      1.087
_refine_ls_R_factor_all          0.0529
_refine_ls_R_factor_gt           0.0428
_refine_ls_shift/su_max          1.337
_refine_ls_shift/su_mean         0.100
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1403
_refine_ls_wR_factor_ref         0.1512
_reflns_number_gt                4837
_reflns_number_total             5713
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c8dt03792b2.cif
_cod_data_source_block           416a
_cod_depositor_comments          'Adding full bibliography for 7047729.cif.'
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C21 H25 Co1.50 N2 O11'
_cod_database_code               7047729