Collisional Electron Transfer Route between Homogeneous Porphyrin Dye and Catalytic TiO2/Re(I) Particles for CO2 Reduction
Choi, Sunghan; Kim, Chul Hoon; Baeg, Jin-Ook; Son, Ho-Jin; Pac, Chyongjin; Kang, Sang Ook; ACS Applied Energy Materials 3 (2020) 11581–11596; doi:10.1021/acsaem.0c01300

data_4518396
_publ_section_title
;
 Collisional Electron Transfer Route between Homogeneous Porphyrin Dye and
 Catalytic TiO2/Re(I) Particles for CO2 Reduction
;
_journal_issue                   12
_journal_name_full               'ACS Applied Energy Materials'
_journal_page_first              11581
_journal_page_last               11596
_journal_paper_doi               10.1021/acsaem.0c01300
_journal_volume                  3
_journal_year                    2020
_chemical_formula_moiety         'C102 H156 N4 O4 Si2 Zn', 'C8 H16 O2'
_chemical_formula_sum            'C110 H172 N4 O6 Si2 Zn'
_chemical_formula_weight         1768.15
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_space_group_name_Hall           '-C 2yc'
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_cell_angle_beta                 100.831(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   38.361(3)
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_cell_length_c                   17.6645(12)
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_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.302
_cell_measurement_theta_min      2.162
_cell_volume                     10550.9(14)
_computing_cell_refinement       'APEX3 (Bruker, 2016)'
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_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX3 CCD diffractometer'
_diffrn_measurement_method       \w-scans
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_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
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_diffrn_reflns_limit_l_min       -21
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_diffrn_reflns_theta_min         1.755
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldric, 1996)'
_exptl_crystal_colour            purple
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         9678
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_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.1247
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0783P)^2^+53.3170P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_original_sg_symbol_H-M      'C 2/c'
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