Field-induced slow relaxation of magnetization in the S = 3/2 octahedral complexes trans-[Co{(OPPh2)(EPPh2)N}2(dmf)2], E = S, Se: effects of Co‒Se vs. Co‒S coordination
Ferentinos, Eleftherios; Xu, Meixing; Grigoropoulos, Alexios; Bratsos, Ioannis; Raptopoulou, Catherine P.; Psycharis, Vassilis; Jiang, Shang-Da; Kyritsis, Panayotis; Inorganic Chemistry Frontiers 6 (2019) 1405–; doi:10.1039/C9QI00135B

data_4350004
_publ_section_title
;
 Field-induced slow relaxation of magnetization in the S = 3/2 octahedral
 complexes trans-[Co{(OPPh2)(EPPh2)N}2(dmf)2], E = S, Se: effects of
 Co--Se vs. Co--S coordination
;
_journal_issue                   6
_journal_name_full               'Inorganic Chemistry Frontiers'
_journal_page_first              1405
_journal_paper_doi               10.1039/C9QI00135B
_journal_volume                  6
_journal_year                    2019
_chemical_formula_sum            'C54 H54 Co N4 O4 P4 S2'
_chemical_formula_weight         1069.94
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/6
_audit_update_record
;
2019-01-20 deposited with the CCDC.	2019-04-12 downloaded from the CCDC.
;
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_cell_measurement_theta_min      6.67
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_diffrn_measured_fraction_theta_max 0.932
_diffrn_measurement_device_type  'Rigaku R-AXIS SPIDER IPDS'
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_exptl_crystal_colour            'light purple'
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_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0496
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_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0571P)^2^+1.2764P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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