Novel Methylpalladium(II) Complexes Bearing Tridentate Imidazole-Based Chelate Ligands: Synthesis, Structural Characterization, and Reactivity
Rüther, Thomas; Done, Melanie C.; Cavell, Kingsley J.; Peacock, Evan J.; Skelton, Brian W.; White, Allan H.; Organometallics 20 (2001) 5522–; doi:10.1021/om0104363

data_4077379
_publ_section_title
;
 Novel Methylpalladium(II) Complexes Bearing Tridentate Imidazole-Based
 Chelate Ligands:&#x00A0; Synthesis, Structural Characterization, and
 Reactivity
;
_journal_issue                   26
_journal_name_full               Organometallics
_journal_page_first              5522
_journal_paper_doi               10.1021/om0104363
_journal_volume                  20
_journal_year                    2001
_chemical_formula_sum
'C32.4163 H52.167 B2.1667 F8.6667 N12 O4.75 Pd2'
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_symmetry_space_group_name_Hall  '-R 3 2"c'
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_cell_angle_beta                 90.00000
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_cell_length_c                   69.505(4)
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_cell_measurement_temperature    123
_cell_measurement_theta_max      26.4
_cell_measurement_theta_min      2.4
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_computing_cell_refinement       'Siemens SAINT (Siemens, 1995)'
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_computing_molecular_graphics    xtal
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_diffrn_measurement_device_type
;
Bruker SMART CCD diffractometer
;
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_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_theta_min         2.17
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    .894
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS; Sheldrick, 1996
;
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_refine_ls_structure_factor_coef F
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_refine_ls_wR_factor_ref         .072
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_reflns_d_resolution_low         9.387
_reflns_Friedel_coverage         0
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_reflns_limit_l_min              0
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_reflns_threshold_expression     'F    > 4.00 sig(F   )'
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_cod_original_sg_symbol_Hall     -r_3_2"c
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