The synthesis of three new Cu5, Cu8 and Cu12 clusters via the use of a semi-flexible aminotriazine-based bis-methylpyridine ligand.
Chiang, Chun-Hung; Tzeng, Yen-Wen; Yang, Chen-I; Nakano, Motohiro; Wan, Wun-Long; Lai, Long-Li; Lee, Gene-Hsiang; Dalton transactions (Cambridge, England : 2003) 46 (2017) 1237–1248; doi:10.1039/c6dt04236h

data_7041508
_publ_section_title
;
 The synthesis of three new Cu5, Cu8 and Cu12 clusters via the use of a
 semi-flexible aminotriazine-based bis-methylpyridine ligand.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1237
_journal_page_last               1248
_journal_paper_doi               10.1039/c6dt04236h
_journal_volume                  46
_journal_year                    2017
_chemical_formula_sum            'C77 H118 Cl6 Cu5 N16 O38'
_chemical_formula_weight         2406.27
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2016-12-08 deposited with the CCDC.
2016-12-08 downloaded from the CCDC.
;
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_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device_type  'NONIUS KappaCCD'
_diffrn_measurement_method       '\w scans'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0985P)^2^+4.0272P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             11482
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7041508--7041510.cif.'
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