Tetranuclear [Co-Gd]2 Complexes: Aiming at a Better Understanding of the 3d-Gd Magnetic Interaction
Verónica Gómez; Laure Vendier; Montserrat Corbella; Jean- Pierre Costes; Inorganic Chemistry 51 (2012) 6396–6404; doi:10.1021/ic300711h

data_4329391
_publ_section_title
;
 Tetranuclear [Co-Gd]2 Complexes: Aiming at a Better Understanding of the
 3d-Gd Magnetic Interaction
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6396
_journal_page_last               6404
_journal_paper_doi               10.1021/ic300711h
_journal_volume                  51
_journal_year                    2012
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C66 H88 Co2 Gd2 N4 O18, 2(C H4 O)'
_chemical_formula_sum            'C68 H96 Co2 Gd2 N4 O20'
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        CrysAlisPro, Oxford Diffraction Ltd.,
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        CrysAlisPro, Oxford Diffraction Ltd.,
        Version 1.171.33.66 (release 28-04-2010 CrysAlis171 .NET)
        (compiled Apr 28 2010,14:27:37)
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        CrysAlisPro, Oxford Diffraction Ltd.,
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        (compiled Apr 28 2010,14:27:37)
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_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
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_diffrn_orient_matrix_UB_33      0.0286183
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_exptl_absorpt_correction_T_max  0.978
_exptl_absorpt_correction_T_min  0.883
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;
        CrysAlisPro, Oxford Diffraction Ltd.,
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        empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
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_refine_ls_extinction_method     none
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.928
_refine_ls_R_factor_all          0.0297
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_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0278P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0469
_refine_ls_wR_factor_ref         0.048
_reflns_number_gt                5995
_reflns_number_total             7563
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            ic300711h_si_002_3.cif
_cod_data_source_block           complex_6
_cod_original_cell_volume        3709.1(6)
_cod_database_code               4329391