Synthesis, crystal structure and thermal behavior of tetrakis(3-cyanopyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II), which shows strong pseudosymmetry
Näther, Christian; Jess, Inke; Acta Crystallographica Section E Crystallographic Communications 79 (2023) –; doi:10.1107/S2056989023006862

data_2022855
_publ_section_title
;
 Synthesis, crystal structure and thermal behavior of
 tetrakis(3-cyanopyridine N-oxide-\kO)bis(thiocyanato-\kN)cobalt(II),
 which shows strong pseudosymmetry
;
_journal_coeditor_code           HB8070
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_journal_name_full
'Acta Crystallographica Section E Crystallographic Communications'
_journal_paper_doi               10.1107/S2056989023006862
_journal_volume                  79
_journal_year                    2023
_chemical_formula_iupac          '[Co (N C S)2 (C6 H4 N2 O)4]'
_chemical_formula_moiety         'C26 H16 Co N10 O4 S2'
_chemical_formula_sum            'C26 H16 Co N10 O4 S2'
_chemical_formula_weight         655.54
_chemical_name_systematic
;
Tetrakis(3-cyanopyridine <i>N</i>-oxide-\k<i>O</i>)bis(thiocyanato-\k<i>N</i>)\
cobalt(II)
;
_space_group_crystal_system      monoclinic
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Olex2 1.3-ac4
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;
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CrysAlisPro 1.171.42.40a (Rigaku OD, 2022)
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CrysAlisPro 1.171.42.40a (Rigaku OD, 2022)
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CrysAlisPro 1.171.42.40a (Rigaku OD, 2022)
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DIAMOND (Brandenburg & Putz, 1999)
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Publcif (Westrip, 2010)
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<i>SHELXL2016/6</i> (Sheldrick, 2015a)
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<i>SHELXT2014/5</i> (Sheldrick, 2015b)
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(CrysAlisPro; Rigaku OD, 2022)
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;
<i>SHELXL2016/6</i> (Sheldrick, 2015a)
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_refine_ls_shift/su_mean         0.000
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'w=1/[\s^2^(Fo^2^)+(0.0511P)^2^+0.3714P] where P=(Fo^2^+2Fc^2^)/3'
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