Synthesis of homometallic divalent lanthanide organoimides from benzyl complexes.
Wolf, Benjamin M.; Stuhl, Christoph; Anwander, Reiner; Chemical communications (Cambridge, England) 54 (2018) 8826–8829; doi:10.1039/c8cc05234d

data_7121956
_publ_section_title
;
 Synthesis of homometallic divalent lanthanide organoimides from benzyl
 complexes.
;
_journal_issue                   64
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              8826
_journal_page_last               8829
_journal_paper_doi               10.1039/c8cc05234d
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C84 H112 O6 Sm4'
_chemical_formula_weight         1819.13
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2018-06-28 deposited with the CCDC.
2018-07-12 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'XT, VERSION 2014/5'
_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.999
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_exptl_absorpt_correction_T_max  0.6513
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_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   sadabs
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0178P)^2^+2.4421P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                7639
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8cc05234d2.cif
_cod_data_source_block           1-Sm_do_mo_BW307_0m
_cod_depositor_comments
'Adding full bibliography for 7121956--7121961.cif.'
_cod_original_cell_volume        1889.8(18)
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_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              81658