Breaking C‒O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes
Monsigny, Louis; Thuéry, Pierre; Berthet, Jean-Claude; Cantat, Thibault; ACS Catalysis 9 (2019) 9025–; doi:10.1021/acscatal.9b01408

data_4514630
_publ_section_title
;
 Breaking C--O Bonds with Uranium: Uranyl Complexes as Selective Catalysts
 in the Hydrosilylation of Aldehydes
;
_journal_issue                   10
_journal_name_full               'ACS Catalysis'
_journal_page_first              9025
_journal_paper_doi               10.1021/acscatal.9b01408
_journal_volume                  9
_journal_year                    2019
_chemical_formula_sum            'C29 H33 F6 N3 O11 S2 U'
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'Nonius Kappa-CCD area-detector diffractometer'
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'two \f and six \w scans with 2\% steps (376 frames)'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0391P)^2^+4.5978P] where P=(Fo^2^+2Fc^2^)/3'
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