Unique reactivity of an α-ketiminopyridine ligand with metal–alkyls: Synthesis and ROP of ε-caprolactone
Novák, Miroslav; Jambor, Roman; R°užičková, Zdeňka; Podzimek, Štěpán; New Journal of Chemistry 45 (2021) 3800–3808; doi:10.1039/D0NJ05498D

data_7060316
_publ_section_title
;
 Unique reactivity of an \a-ketiminopyridine ligand with metal--alkyls:
 Synthesis and ROP of \e-caprolactone
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              3800
_journal_page_last               3808
_journal_paper_doi               10.1039/D0NJ05498D
_journal_volume                  45
_journal_year                    2021
_chemical_formula_moiety         'C28 H41 Li N2 O3'
_chemical_formula_sum            'C28 H41 Li N2 O3'
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_audit_update_record
;
2021-01-06 deposited with the CCDC.	2021-01-20 downloaded from the CCDC.
;
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'COLLECT (Hooft, 1998) and DENZO (Otwinowski & Minor, 1997)'
_computing_data_reduction        'COLLECT and DENZO'
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_diffrn_ambient_temperature      150(1)
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_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker Nonius KappaCCD area detector'
_diffrn_measurement_method       '\f and \w scans to fill the Ewald sphere'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_point_group_measured_fraction_full 0.989
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_exptl_absorpt_process_details
;
SADABS-2016/2 - Bruker AXS area detector
scaling and absorption correction
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0439P)^2^+1.7078P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 7060316--7060319.cif.'
_cod_database_code               7060316
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_exptl_absorpt_special_details
;
The ratio of minimum to maximum
apparent transmission was 0.793
;
_shelx_res_checksum              10988