Synthesis and Characterization of Phenanthrylphosphine Gold Complex: Observation of Au-Induced Blue-Green Phosphorescence at Room Temperature
Masahisa Osawa; Mikio Hoshino; Munetaka Akita; Tatsuo Wada; Inorganic Chemistry 44 (2005) 1157–1159; doi:10.1021/ic048538j

data_4308680
_publ_contact_author_name        'Masahisa Osawa '
_publ_section_title
;
Synthesis and Characterization of Phenanthrylphosphine Gold Complex:
Observation of Au-Induced Blue-Green Phosphorescence at Room Temperature
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1157
_journal_page_last               1159
_journal_paper_doi               10.1021/ic048538j
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C26 H19 O P '
_chemical_formula_sum            'C26 H19 O P'
_chemical_formula_weight         378.41
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Thu Jun 24 12:02:16 2004'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                80.126(2)
_cell_angle_beta                 73.148(2)
_cell_angle_gamma                75.032(2)
_cell_formula_units_Z            2
_cell_length_a                   9.0031(6)
_cell_length_b                   10.5751(8)
_cell_length_c                   11.1424(7)
_cell_measurement_reflns_used    21600
_cell_measurement_temperature    100.2
_cell_measurement_theta_max      30.0
_cell_measurement_theta_min      1.90
_cell_volume                     975.48(12)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9618
_diffrn_measured_fraction_theta_max 0.9618
_diffrn_measurement_device_type  'Rigaku RAXIS-CS Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.049
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            13446
_diffrn_reflns_theta_full        30.03
_diffrn_reflns_theta_max         30.03
_exptl_absorpt_coefficient_mu    0.154
_exptl_absorpt_correction_T_max  0.955
_exptl_absorpt_correction_T_min  0.791
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.288
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_size_max          0.700
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.300
_refine_diff_density_max         0.33
_refine_diff_density_min         -0.38
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.661
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     253
_refine_ls_number_reflns         5180
_refine_ls_R_factor_gt           0.0557
_refine_ls_shift/su_max          0.0002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     F^2^>2.0\s(F^2^)
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_cod_data_source_block           9DPPO
_cod_original_cell_volume        975.5(1)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C26 H19 O P '
_cod_database_code               4308680