Two novel bi-functional hybrid materials constructed from POMs and a Schiff base with excellent third-order NLO and catalytic properties.
Hu, Gonghao; Miao, Hao; Mei, Hua; Zhou, Shuai; Xu, Yan; Dalton transactions (Cambridge, England : 2003) 45 (2016) 7947–7951; doi:10.1039/c6dt00138f

data_7039038
_publ_section_title
;
 Two novel bi-functional hybrid materials constructed from POMs and a
 Schiff base with excellent third-order NLO and catalytic properties.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7947
_journal_page_last               7951
_journal_paper_doi               10.1039/c6dt00138f
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C55 H111 B2 Co5 N35 O108 W24'
_chemical_formula_weight         7719.45
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-03-04 deposited with the CCDC.
2016-04-15 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      296(2)
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_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Bruker Apex2 CCD'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0905
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2003)'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0693P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                18962
_reflns_number_total             27484
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt00138f2.cif
_cod_data_source_block           hgh-8
_cod_depositor_comments
'Adding full bibliography for 7039038--7039039.cif.'
_cod_original_cell_volume        7584.7(16)
_cod_database_code               7039038
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              56100