Sterically demanding methoxy and methyl groups in ruthenium complexes lead to enhanced quantum yields for blue light triggered photodissociation.
Qu, Fengrui; Martinez, Kristina; Arcidiacono, Ashley M.; Park, Seungjo; Zeller, Matthias; Schmehl, Russell H.; Paul, Jared J.; Kim, Yonghyun; Papish, Elizabeth T.; Dalton transactions (Cambridge, England : 2003) 47 (2018) 15685–15693; doi:10.1039/c8dt03295e

data_7047678
_publ_section_title
;
 Sterically demanding methoxy and methyl groups in ruthenium complexes
 lead to enhanced quantum yields for blue light triggered
 photodissociation.
;
_journal_issue                   44
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15685
_journal_page_last               15693
_journal_paper_doi               10.1039/c8dt03295e
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C38 H32 N6 O2 Ru, Cl2'
_chemical_formula_sum            'C38 H32 Cl2 N6 O2 Ru'
_chemical_formula_weight         776.66
_chemical_name_common            '[(neo)2Ru(4,4'-dhbp)]Cl2'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_H-M   'P -1'
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_audit_update_record
;
2018-08-11 deposited with the CCDC.
2018-10-01 downloaded from the CCDC.
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0479P)^2^+0.9162P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0934
_refine_ls_wR_factor_ref         0.0977
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7602
_reflns_number_total             9012
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt03295e2.cif
_cod_data_source_block           4OH
_cod_depositor_comments
'Adding full bibliography for 7047677--7047678.cif.'
_cod_database_code               7047678
_shelx_shelxl_version_number     2017/1
_shelx_res_checksum              85250
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_publcif_funding_html
;
;