Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 6004–6014; doi:10.1039/c5dt02535d

data_7036093
_publ_section_title
;
 Salt metathesis versus protonolysis routes for the synthesis of
 silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR)
 complexes.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6004
_journal_page_last               6014
_journal_paper_doi               10.1039/c5dt02535d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C20 H50 N Na O4 Si2'
_chemical_formula_sum            'C20 H50 N Na O4 Si2'
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_symmetry_space_group_name_Hall  '-P 2yn'
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Olex2 1.2
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2015-08-03 deposited with the CCDC.
2015-08-05 downloaded from the CCDC.
;
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
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CrysAlisPro, Agilent Technologies,
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(compiled Mar 27 2014,17:12:48)
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CrysAlisPro, Agilent Technologies,
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(compiled Mar 27 2014,17:12:48)
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  1 omega  -35.00   15.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
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  2 omega   -1.00   91.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
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  3 omega    8.00   49.00   1.0000   80.0000
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  4 omega   20.00   97.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
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  5 omega  -20.00   16.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
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  6 omega   35.00  110.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
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  7 omega   35.00  110.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
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  8 omega   -6.00   97.00   1.0000   80.0000
omega____ theta____ kappa____ phi______ frames
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
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Empirical absorption correction using spherical harmonics,
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'w=1/[\s^2^(Fo^2^)+(0.0400P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7036089--7036100.cif.'
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_chemical_oxdiff_formula         'C30 N3 Si3 Th'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C11(H11A,H11B), C17(H17A,H17B), C18(H18A,H18B), C19(H19A,H19B)
2.b Me refined with riding coordinates:
 C8(H8A,H8B,H8C), C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C12(H12A,H12B,H12C),
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;
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