A 3D oxalate-based network as a precursor for the CoMn₂O₄ spinel: synthesis and structural and magnetic studies.
Habjanič, Jelena; Jurić, Marijana; Popović, Jasminka; Molčanov, Krešimir; Pajić, Damir; Inorganic chemistry 53 (2014) 9633–9643; doi:10.1021/ic501134y

data_4340936
_publ_section_title
;
 A 3D oxalate-based network as a precursor for the CoMn&#x2082;O&#x2084;
 spinel: synthesis and structural and magnetic studies.
;
_journal_issue                   18
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9633
_journal_page_last               9643
_journal_paper_doi               10.1021/ic501134y
_journal_volume                  53
_journal_year                    2014
_chemical_absolute_configuration ad
_chemical_formula_moiety         '2(C3 Mn O6), C30 H24 Co N6, 0.67(O3)'
_chemical_formula_sum            'C36 H24 Co Mn2 N6 O14'
_chemical_formula_weight         933.44
_space_group_IT_number           213
_symmetry_cell_setting           cubic
_symmetry_space_group_name_Hall  'P 4bd 2ab 3'
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_cell_length_c                   15.6685(1)
_cell_measurement_reflns_used    3872
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      75.2654
_cell_measurement_theta_min      3.9867
_cell_volume                     3846.65(4)
_computing_cell_refinement
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.35.21 (release 20-01-2012 CrysAlis171 .NET)
        (compiled Jan 23 2012,18:06:46)
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_computing_data_collection
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.35.21 (release 20-01-2012 CrysAlis171 .NET)
        (compiled Jan 23 2012,18:06:46)
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_computing_data_reduction
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.35.21 (release 20-01-2012 CrysAlis171 .NET)
        (compiled Jan 23 2012,18:06:46)
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_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.97
_diffrn_measured_fraction_theta_max 0.97
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_diffrn_radiation_wavelength     1.54179
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_exptl_absorpt_correction_T_max  1
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_exptl_crystal_colour            yellow
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_exptl_crystal_description       prism
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_refine_ls_abs_structure_Flack   -0.020(5)
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
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'calc w=1/[\s^2^(Fo^2^)+(0.0447P)^2^+0.6840P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                1253
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_cod_data_source_file            ic501134y_si_002.cif
_cod_data_source_block           marijana-zuti-aps
_cod_depositor_comments
'Adding full bibliography for 4340936--4340937.cif.'
_cod_original_formula_sum        ' C36 H24 Co Mn2 N6 O14'
_cod_database_code               4340936