Luminescence of mononuclear Pt(ii) complexes with glycolate: external stimuli-induced excimer emission changes to oligomer emissions.
Ohno, Keiji; Komuro, Masaya; Sugaya, Tomoaki; Nagasawa, Akira; Fujihara, Takashi; Dalton transactions (Cambridge, England : 2003) 49 (2020) 1873–1882; doi:10.1039/c9dt03996a

data_7703344
_publ_section_title
;
 Luminescence of mononuclear Pt(ii) complexes with glycolate: external
 stimuli-induced excimer emission changes to oligomer emissions.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1873
_journal_page_last               1882
_journal_paper_doi               10.1039/c9dt03996a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C12 H16 N2 O6 Pt'
_chemical_formula_weight         479.36
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2019-04-23 deposited with the CCDC.	2020-01-07 downloaded from the CCDC.
;
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_cell_formula_units_Z            4
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_cell_length_c                   7.0413(8)
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_cell_volume                     1410.5(3)
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  'Bruker Helios multilayer confocal mirror'
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0335
_diffrn_reflns_av_unetI/netI     0.0253
_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_limit_h_min       -13
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_exptl_absorpt_coefficient_mu    9.977
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS-2014/2 - Bruker 2014'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.257
_exptl_crystal_description       needle
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_exptl_crystal_size_max          0.11
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_refine_ls_restrained_S_all      0.849
_refine_ls_R_factor_all          0.0322
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0271P)^2^+3.9322P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0451
_refine_ls_wR_factor_ref         0.0493
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2464
_reflns_number_total             2981
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           fuji_kmr_Ptbpyla_01a
_cod_depositor_comments
'Adding full bibliography for 7703344--7703345.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7703344
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