AlCl3-Catalyzed Hydrosilylation of Alkynes with Hydropolysilanes†
Kato, Nobu; Tamura, Yusuke; Kashiwabara, Taigo; Sanji, Takanobu; Tanaka, Masato; Organometallics 29 (2010) 5274–; doi:10.1021/om100376d

data_4066264
_publ_section_title
;
 AlCl3-Catalyzed Hydrosilylation of Alkynes with Hydropolysilanes&#x2020;
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_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              5274
_journal_paper_doi               10.1021/om100376d
_journal_volume                  29
_journal_year                    2010
_chemical_formula_moiety         'C22 H46 Si4 '
_chemical_formula_sum            'C22 H46 Si4'
_chemical_formula_weight         422.95
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                63.935(11)
_cell_angle_beta                 70.324(13)
_cell_angle_gamma                67.875(12)
_cell_formula_units_Z            2
_cell_length_a                   9.708(2)
_cell_length_b                   11.504(2)
_cell_length_c                   14.970(3)
_cell_measurement_reflns_used    4151
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     1361.5(5)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR97
_diffrn_ambient_temperature      113
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.920
_diffrn_measured_fraction_theta_max 0.920
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.017
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            9884
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.223
_exptl_absorpt_correction_T_max  0.956
_exptl_absorpt_correction_T_min  0.887
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.032
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             468.00
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.92
_refine_diff_density_min         -0.56
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.956
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     284
_refine_ls_number_reflns         4609
_refine_ls_R_factor_gt           0.0611
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[0.0131Fo^2^ + 1.0000\s(Fo^2^)]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1143
_reflns_number_gt                4609
_reflns_number_total             5746
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om100376d_si_001.cif
_cod_data_source_block           '__ktn0802703'
_cod_original_cell_volume        1361.4(5)
_cod_original_formula_sum        'C22 H46 Si4 '
_cod_database_code               4066264