Pt-Catalyzed Hydrosilylation of 1,3-Diynes with Triorganosilanes: Regio- and Stereoselective Synthesis of Mono- or Bis-silylated Adducts.
Walkowiak, Jędrzej; Salamon, Katarzyna; Franczyk, Adrian; Stefanowska, Kinga; Szyling, Jakub; Kownacki, Ireneusz; The Journal of organic chemistry 84 (2019) 2358–2365; doi:10.1021/acs.joc.8b03143

data_4033749
_publ_contact_author
;
Maciej Kubicki   
Faculty of Chemistry 
Adam Mickiewicz University
Grunwaldzka 6              
60-780 Pozna\'n   
Poland             
;
_publ_section_title
;
 Pt-Catalyzed Hydrosilylation of 1,3-Diynes with Triorganosilanes: Regio-
 and Stereoselective Synthesis of Mono- or Bis-silylated Adducts.
;
_journal_issue                   4
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              2358
_journal_page_last               2365
_journal_paper_doi               10.1021/acs.joc.8b03143
_journal_volume                  84
_journal_year                    2019
_chemical_formula_moiety         'C24 H22 Si'
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;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0376P)^2^+0.5649P] where P=(Fo^2^+2Fc^2^)/3'
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