A new ladder-type silver(I) coordination polymer with 4,4'-bipyridine and 4-[(4-carboxybenzyloxy)methyl]benzoate ligands: synthesis, crystal structure, fluorescence properties and Hirshfeld surface analysis
Chen, Zhao; Zhang, Zilong; Zhang, Chong; Xiao, Yu; Acta Crystallographica Section C 76 (2020) 952–957; doi:10.1107/S2053229620011882

data_2022249
_publ_section_title
;
 A new ladder-type silver(I) coordination polymer with 4,4'-bipyridine and
 4-[(4-carboxybenzyloxy)methyl]benzoate ligands: synthesis, crystal
 structure, fluorescence properties and Hirshfeld surface analysis
;
_journal_coeditor_code           DG3009
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              952
_journal_page_last               957
_journal_paper_doi               10.1107/S2053229620011882
_journal_volume                  76
_journal_year                    2020
_chemical_formula_iupac          '[Ag (C16 H13 O5) (C10 H8 N2)]'
_chemical_formula_moiety         'C26 H21 Ag N2 O5'
_chemical_formula_sum            'C26 H21 Ag N2 O5'
_chemical_formula_weight         549.32
_chemical_name_systematic
Poly[(\m-4,4'-bipyridine-\k^2^<i>N</i>:<i>N</i>'){\m-4-[(4-carboxybenzyloxy)methyl]benzoato-\k<i>O</i>}silver(I)](<i>Ag</i>---<i>Ag</i>)
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_cell_angle_alpha                78.610(5)
_cell_angle_beta                 81.339(6)
_cell_angle_gamma                70.031(6)
_cell_formula_units_Z            2
_cell_length_a                   7.9269(6)
_cell_length_b                   11.3939(8)
_cell_length_c                   13.6589(8)
_cell_measurement_reflns_used    2207
_cell_measurement_temperature    289(2)
_cell_measurement_theta_max      21.0270
_cell_measurement_theta_min      3.6930
_cell_volume                     1132.01(14)
_computing_cell_refinement
;
CrysAlis PRO (Agilent, 2014)
;
_computing_data_collection
;
CrysAlis PRO (Agilent, 2014)
;
_computing_data_reduction
;
CrysAlis PRO (Agilent, 2014)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov <i>et al.</i>, 2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov <i>et al.</i>, 2009)
;
_computing_structure_refinement
;
SHELXL2018 (Sheldrick, 2015b)
;
_computing_structure_solution
;
SHELXT2015 (Sheldrick, 2015a)
;
_diffrn_ambient_temperature      289(2)
_diffrn_detector_area_resol_mean 16.0233
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type
'Agilent SuperNova Single Source diffractometer with an E detector'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0730
_diffrn_reflns_av_unetI/netI     0.0896
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            14148
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.098
_diffrn_reflns_theta_min         3.346
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.932
_exptl_absorpt_correction_T_max  0.871
_exptl_absorpt_correction_T_min  0.429
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Agilent, 2014)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.612
_exptl_crystal_description       plate
_exptl_crystal_F_000             556
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.552
_refine_diff_density_min         -0.570
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.999
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     303
_refine_ls_number_reflns         4035
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.999
_refine_ls_R_factor_all          0.0979
_refine_ls_R_factor_gt           0.0512
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0304P)^2^+0.7458P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0898
_refine_ls_wR_factor_ref         0.1151
_reflns_number_gt                2501
_reflns_number_total             4035
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            dg3009sup1.cif
_cod_data_source_block           I
_cod_depositor_comments          'Adding full bibliography for 2022249.cif.'
_cod_database_code               2022249
_cod_database_fobs_code          2022249
_shelx_hkl_checksum              16410
_shelx_res_checksum              36499
_shelxl_version_number           2.014