Dioxygen/Hydrogen Peroxide Interconversion Using Redox Couples of Saddle-Distorted Porphyrins and Isophlorins.
Suzuki, Wataru; Kotani, Hiroaki; Ishizuka, Tomoya; Kojima, Takahiko; Journal of the American Chemical Society 141 (2019) 5987–5994; doi:10.1021/jacs.9b01038

data_4128393
_publ_section_title
;
 Dioxygen/Hydrogen Peroxide Interconversion Using Redox Couples of
 Saddle-Distorted Porphyrins and Isophlorins.
;
_journal_issue                   14
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5987
_journal_page_last               5994
_journal_paper_doi               10.1021/jacs.9b01038
_journal_volume                  141
_journal_year                    2019
_chemical_formula_sum            'C98 H64 F12 N4 O'
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_cell_measurement_temperature    120(2)
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_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
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_exptl_absorpt_coefficient_mu    0.085
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_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0854P)^2^+2.5879P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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