Crystal structure of chloridopentakis(dimethyl sulfoxide-κ<i>O</i>)chromium(III) dichloride
Son, Kyung-sun; Woo, Jeong Oh; Kim, Namhun; Kang, Sung Kwon; Acta Crystallographica Section E 70 (2014) m309–; doi:10.1107/S1600536814015852

data_2239826
_publ_section_title
;
 Crystal structure of chloridopentakis(dimethyl
 sulfoxide-\k<i>O</i>)chromium(III) dichloride
;
_journal_coeditor_code           WM5034
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m309
_journal_paper_doi               10.1107/S1600536814015852
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac          '[Cr Cl (C2 H6 O S)5] Cl2'
_chemical_formula_moiety         'C10 H30 Cl Cr O5 S5 2+, 2(Cl -)'
_chemical_formula_sum            'C10 H30 Cl3 Cr O5 S5'
_chemical_formula_weight         548.99
_chemical_name_systematic
;
Chloridopentakis(dimethyl sulfoxide-\k<i>O</i>)chromium(III) dichloride
;
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_symmetry_cell_setting           triclinic
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_cell_length_c                   13.0088(5)
_cell_measurement_reflns_used    2991
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.21
_cell_measurement_theta_min      2.18
_cell_volume                     1228.26(9)
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_diffrn_ambient_temperature      296(2)
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_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
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_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1149
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_diffrn_reflns_theta_max         25.5
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_exptl_absorpt_correction_T_max  0.935
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(<i>SADABS</i>; Bruker, 2002)
;
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.484
_exptl_crystal_description       block
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_exptl_crystal_size_min          0.05
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_refine_ls_R_factor_all          0.1433
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_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0582P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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