Phosphorous(v) Lewis acids: water/base tolerant P<sub>3</sub>-trimethylated trications.
Bayne, J. M.; Fasano, V.; Szkop, K. M.; Ingleson, M. J.; Stephan, D. W.; Chemical communications (Cambridge, England) 54 (2018) 12467–12470; doi:10.1039/c8cc06564k

data_7122449
_publ_section_title
;
 Phosphorous(v) Lewis acids: water/base tolerant
 P<sub>3</sub>-trimethylated trications.
;
_journal_issue                   88
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              12467
_journal_page_last               12470
_journal_paper_doi               10.1039/c8cc06564k
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C50 H55 F9 N O10 P3 S3'
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_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-08-11 deposited with the CCDC.
2018-10-12 downloaded from the CCDC.
;
_cell_angle_alpha                77.042(2)
_cell_angle_beta                 81.897(2)
_cell_angle_gamma                72.530(3)
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_computing_cell_refinement       'Bruker SAINT'
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_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      396(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.998
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_exptl_absorpt_correction_type   none
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_exptl_crystal_description       block
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_refine_ls_R_factor_all          0.0692
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0632P)^2^+3.1432P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1353
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9345
_reflns_number_total             12195
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8cc06564k2.cif
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_cod_depositor_comments
'Adding full bibliography for 7122448--7122449.cif.'
_cod_database_code               7122449
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