Synthesis and Reactivities of (Arylsulfonyl)amido Complexes of Ruthenium(II)
Wa-Hung Leung; Man-Ching Wu; Joyce L. C. Chim; Wing-Tak Wong; Inorganic Chemistry 35 (1996) 4801–4803; doi:10.1021/ic9513806

data_4323862
_publ_section_title
;
 Synthesis and Reactivities of (Arylsulfonyl)amido Complexes of
 Ruthenium(II)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4801
_journal_page_last               4803
_journal_paper_doi               10.1021/ic9513806
_journal_volume                  35
_journal_year                    1996
_chemical_formula_sum            'C48.5 H51 Cl I2 N2 O2 P2 Ru2 S4'
_chemical_formula_weight         1375.54
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             'Sun Feb  2 05:33:53 2026'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 103.93(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.960(1)
_cell_length_b                   26.355(2)
_cell_length_c                   19.862(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    568.2
_cell_measurement_theta_max      11.0
_cell_measurement_theta_min      6.5
_cell_volume                     5568.4(10)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_diffrn_ambient_temperature      568.2
_diffrn_measurement_device       unknown
_diffrn_measurement_method       'omega/2-theta scans'
_diffrn_orient_matrix_UB_11      -0.03397
_diffrn_orient_matrix_UB_12      0.03432
_diffrn_orient_matrix_UB_13      0.00687
_diffrn_orient_matrix_UB_21      0.04093
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_diffrn_orient_matrix_UB_23      0.05069
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_diffrn_orient_matrix_UB_32      0.01608
_diffrn_orient_matrix_UB_33      -0.00861
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoKalpha
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_diffrn_standards_decay_%        0.00
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_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.944
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.641
_exptl_crystal_description       block
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
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_reflns_number_observed          4772
_reflns_number_total             7591
_reflns_observed_criterion       3.00
_cod_data_source_file            ic9513806_2.cif
_cod_data_source_block           WTW150_RU(PPH3)2CO(DTC)(NH
_cod_original_sg_symbol_H-M      'P 21/n '
_cod_original_formula_sum        'C48.50 H51 Cl I2 N2 O2 P2 S4 Ru2 '
_cod_database_code               4323862