Bis[μ~2~-bis(diphenylphosphanyl)methane-κ^2^<i>P</i>:<i>P</i>']bis(μ~4~-diphenylphosphinato-κ^4^<i>O</i>:<i>O</i>:<i>O</i>':<i>O</i>')bis[μ~2~-trifluoromethanesulfonato(0.546/0.454)]-κ^2^<i>O</i>:<i>O</i>';κ^2^<i>O</i>:<i>O</i>-tetrasilver(I) acetonitrile disolvate
Tang, Li-ping; Jia, Chen; Huang, Li-li; Xie, Jia-Li; Acta Crystallographica Section E 67 (2011) m1141–m1142; doi:10.1107/S160053681102931X

data_2231153
_publ_section_title
;
 Bis[\m~2~-bis(diphenylphosphanyl)methane-\k^2^<i>P</i>:<i>P</i>']bis(\m~4~-diphenylphosphinato-\k^4^<i>O</i>:<i>O</i>:<i>O</i>':<i>O</i>')bis[\m~2~-trifluoromethanesulfonato(0.546/0.454)]-\k^2^<i>O</i>:<i>O</i>';\k^2^<i>O</i>:<i>O</i>-tetrasilver(I)
 acetonitrile disolvate
;
_journal_coeditor_code           HY2447
_journal_issue                   8
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1141
_journal_page_last               m1142
_journal_paper_doi               10.1107/S160053681102931X
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac
'[Ag4 (C12 H10 O2 P)2 (C F3 O3 S)2 (C25 H22 P2)2], 2C2 H3 N'
_chemical_formula_moiety         'C76 H64 Ag4 F6 O10 P6 S2, 2(C2 H3 N)'
_chemical_formula_sum            'C80 H70 Ag4 F6 N2 O10 P6 S2'
_chemical_formula_weight         2014.80
_chemical_name_systematic
;
Bis[\m~2~-bis(diphenylphosphanyl)methane-\k^2^<i>P</i>:<i>P</i>']bis(\m~4~-
diphenylphosphinato-\k^4^<i>O</i>:<i>O</i>:<i>O</i>':<i>O</i>')bis[\m~2~-
trifluoromethanesulfonato(0.546/0.454)]-
\k^2^<i>O</i>:<i>O</i>';\k^2^<i>O</i>:<i>O</i>-tetrasilver(I) acetonitrile
disolvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.967(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.730(7)
_cell_length_b                   15.169(9)
_cell_length_c                   23.688(12)
_cell_measurement_reflns_used    9952
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.6
_cell_volume                     4184(4)
_computing_cell_refinement       'CrystalClear (Rigaku, 2005)'
_computing_data_collection       'CrystalClear (Rigaku, 2005)'
_computing_data_reduction        'CrystalClear (Rigaku, 2005)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 13.6612
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku Mercury CCD'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0549
_diffrn_reflns_av_sigmaI/netI    0.0405
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            41763
_diffrn_reflns_theta_full        27.58
_diffrn_reflns_theta_max         27.58
_diffrn_reflns_theta_min         2.45
_exptl_absorpt_coefficient_mu    1.157
_exptl_absorpt_correction_T_max  0.8365
_exptl_absorpt_correction_T_min  0.7768
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrystalClear; Rigaku, 2005)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.599
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             2016
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.635
_refine_diff_density_min         -0.608
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     610
_refine_ls_number_reflns         9645
_refine_ls_number_restraints     1173
_refine_ls_restrained_S_all      1.008
_refine_ls_R_factor_all          0.0706
_refine_ls_R_factor_gt           0.0550
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0595P)^2^+6.7650P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1335
_refine_ls_wR_factor_ref         0.1443
_reflns_number_gt                7705
_reflns_number_total             9645
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hy2447.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2231153
_cod_database_fobs_code          2231153