<i>catena</i>-Poly[[silver(I)-μ-4-aminopyridine] perchlorate]: a 1-D staircase coordination polymer
Golder, Ryan K.; Fitchett, Christopher M.; Wikaira, Jan L.; Steel, Peter J.; Acta Crystallographica Section E 66 (2010) m1324–; doi:10.1107/S1600536810037682

data_2227287
_publ_section_title
;
 <i>catena</i>-Poly[[silver(I)-\m-4-aminopyridine] perchlorate]: a 1-D
 staircase coordination polymer
;
_journal_coeditor_code           BV2161
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1324
_journal_paper_doi               10.1107/S1600536810037682
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Ag (C5 H6 N2)] Cl O4'
_chemical_formula_moiety         'C5 H6 Ag N2 +, Cl O4 -'
_chemical_formula_sum            'C5 H6 Ag Cl N2 O4'
_chemical_formula_weight         301.44
_chemical_name_common            2
_chemical_name_systematic
'<i>catena</i>-Poly[[silver(I)-\m-4-aminopyridine] perchlorate]'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.198(2)
_cell_angle_beta                 96.992(2)
_cell_angle_gamma                100.452(2)
_cell_formula_units_Z            2
_cell_length_a                   5.0720(2)
_cell_length_b                   9.0025(3)
_cell_length_c                   9.5520(3)
_cell_measurement_reflns_used    6232
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      26.43
_cell_measurement_theta_min      3.03
_cell_volume                     424.37(3)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'APEX2 (Bruker, 2009)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      113(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0458
_diffrn_reflns_av_sigmaI/netI    0.0189
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            9107
_diffrn_reflns_theta_full        26.43
_diffrn_reflns_theta_max         26.43
_diffrn_reflns_theta_min         2.31
_exptl_absorpt_coefficient_mu    2.671
_exptl_absorpt_correction_T_max  0.8780
_exptl_absorpt_correction_T_min  0.4549
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2009)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.359
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             292
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.567
_refine_diff_density_min         -0.778
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     127
_refine_ls_number_reflns         1740
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0232
_refine_ls_R_factor_gt           0.0214
_refine_ls_shift/su_max          0.017
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0333P)^2^+0.1489P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0506
_refine_ls_wR_factor_ref         0.0514
_reflns_number_gt                1591
_reflns_number_total             1740
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            bv2161.cif
_cod_data_source_block           I
_cod_database_code               2227287
_cod_database_fobs_code          2227287