The Effects of Anion Variation and Ligand Derivatization on Silver Coordination Networks Based upon Weaker Interactions
Natalia J. Melcer; Gary D. Enright; John A. Ripmeester; George K. H. Shimizu; Inorganic Chemistry 40 (2001) 4641–4648; doi:10.1021/ic0103749

data_4320209
_publ_section_title
;
 The Effects of Anion Variation and Ligand Derivatization on Silver
 Coordination Networks Based upon Weaker Interactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4641
_journal_page_last               4648
_journal_paper_doi               10.1021/ic0103749
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C7 H8 Ag0.5 F3 N P0.5 S'
_chemical_formula_weight         264.62
_chemical_name_systematic
;
  ?
;
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yac'
_symmetry_space_group_name_H-M   'P 1 2/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.87
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.9658(11)
_cell_length_b                   3.9056(4)
_cell_length_c                   19.6400(18)
_cell_measurement_temperature    293(2)
_cell_volume                     916.70(15)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_wavelength     0.70930
_diffrn_reflns_av_R_equivalents  0.0689
_diffrn_reflns_av_sigmaI/netI    0.0579
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            9857
_diffrn_reflns_theta_full        28.73
_diffrn_reflns_theta_max         28.73
_diffrn_reflns_theta_min         1.95
_exptl_absorpt_coefficient_mu    1.473
_exptl_crystal_density_diffrn    1.917
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             524
_refine_diff_density_max         1.934
_refine_diff_density_min         -0.713
_refine_diff_density_rms         0.129
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     190
_refine_ls_number_reflns         2347
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0734
_refine_ls_R_factor_gt           0.0530
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0602P)^2^+1.1769P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1111
_refine_ls_wR_factor_ref         0.1208
_reflns_number_gt                1892
_reflns_number_total             2347
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0103749_2.cif
_cod_data_source_block           t
_cod_original_formula_sum        'C7 H8 Ag0.50 F3 N P0.50 S'
_cod_database_code               4320209