σ-Silane, Disilanyl, and [W(μ-H)Si(μ-H)W] Bridging Silylene Complexes via the Reactions of W(PMe3)4(η(2)-CH2PMe2)H with Phenylsilanes.
Zuzek, Ashley A.; Neary, Michelle C.; Parkin, Gerard; Journal of the American Chemical Society  (2014) 141217070549000–; doi:10.1021/ja510703s

data_4123152
_publ_section_title
;
 \s-Silane, Disilanyl, and [W(\m-H)Si(\m-H)W] Bridging Silylene Complexes
 via the Reactions of W(PMe3)4(\h(2)-CH2PMe2)H with Phenylsilanes.
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              141217070549000
_journal_paper_doi               10.1021/ja510703s
_journal_year                    2014
_chemical_formula_sum            'C38.5 H82 P6 Si3 W2'
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_chemical_name_systematic
; 
 ? 
;
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_space_group_name_Hall           '-P 1'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w=1/[\s^2^(Fo^2^)] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0648
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_reflns_number_total             15992
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja510703s_si_002.cif
_cod_data_source_block           wsiw6s10
_cod_original_cell_volume        2589.8(8)
_cod_original_formula_sum        'C38.50 H82 P6 Si3 W2'
_cod_database_code               4123152
_shelx_estimated_absorpt_t_min   0.289
_shelx_estimated_absorpt_t_max   0.798
_shelxl_version_number           2013-4
_shelx_res_checksum              1346
_shelx_hkl_checksum              33555