Temperature controlled formation of polar copper phosphonates showing large dielectric anisotropy and a dehydration-induced switch from ferromagnetic to antiferromagnetic interactions.
Wang, Peng-Fei; Bao, Song-Song; Huang, Xin-Da; Akutagawa, T.; Zheng, Li-Min; Chemical communications (Cambridge, England) 54 (2018) 6276–6279; doi:10.1039/c8cc02819b

data_7121714
_publ_section_title
;
 Temperature controlled formation of polar copper phosphonates showing
 large dielectric anisotropy and a dehydration-induced switch from
 ferromagnetic to antiferromagnetic interactions.
;
_journal_issue                   49
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              6276
_journal_page_last               6279
_journal_paper_doi               10.1039/c8cc02819b
_journal_volume                  54
_journal_year                    2018
_chemical_formula_moiety         'C14 H12 Cu3 O12 P2'
_chemical_formula_sum            'C14 H12 Cu3 O12 P2'
_chemical_formula_weight         624.80
_space_group_crystal_system      orthorhombic
_space_group_IT_number           60
_space_group_name_Hall           '-P 2n 2ab'
_space_group_name_H-M_alt        'P b c n'
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2018-04-05 deposited with the CCDC.
2018-05-23 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0365P)^2^+4.9220P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7121713--7121714.cif.'
_cod_database_code               7121714
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