Synthesis of aryl anti-vicinal diamines via aza-Brook rearrangement-initiated nucleophilic addition of α-silylamines to imines.
Lin, Chao-Yang; Sun, Zhao; Xu, Yan-Jun; Lu, Chong-Dao; The Journal of organic chemistry 80 (2015) 3714–3722; doi:10.1021/acs.joc.5b00255

data_4036147
_publ_section_title
;
 Synthesis of aryl anti-vicinal diamines via aza-Brook
 rearrangement-initiated nucleophilic addition of \a-silylamines to
 imines.
;
_journal_issue                   7
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              3714
_journal_page_last               3722
_journal_paper_doi               10.1021/acs.joc.5b00255
_journal_volume                  80
_journal_year                    2015
_chemical_formula_sum            'C33 H31 N2 O2 P'
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_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
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_atom_sites_solution_secondary   difmap
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_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.373(4)
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_computing_cell_refinement       'Bruker SMART'
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_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
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_exptl_absorpt_correction_type   numerical
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1421P)^2^+0.1687P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2041
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_reflns_number_gt                4150
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_cod_data_source_file            jo5b00255_si_002.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Numerical' was
changed to 'numerical' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        2773.7(15)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               4036147