A novel fluorene-based gold(I) complex with aggregate fluorescence change: a single-component white light-emitting
Zhao Chen; Di Wu; Xie Han; Jinhua Liang; Jun Yin; Guang-Ao Yu; Sheng Hua Liu; Chem.Commun. 50 (2014) 11033–; doi:10.1039/C4cc04469J

data_7115623
_publ_section_title
;
 A novel fluorene-based gold(I) complex with aggregate fluorescence
 change: a single-component white light-emitting
;
_journal_name_full               Chem.Commun.
_journal_page_first              11033
_journal_paper_doi               10.1039/C4cc04469J
_journal_volume                  50
_journal_year                    2014
_chemical_formula_sum            'C77 H56 Au2 F10 N2 O2'
_chemical_formula_weight         1625.17
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.367(9)
_cell_angle_beta                 90.803(9)
_cell_angle_gamma                102.203(8)
_cell_formula_units_Z            2
_cell_length_a                   11.9116(16)
_cell_length_b                   12.7221(17)
_cell_length_c                   21.939(3)
_cell_measurement_reflns_used    9967
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      43.26
_cell_measurement_theta_min      3.56
_cell_volume                     3245.9(8)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.949
_diffrn_measured_fraction_theta_max 0.949
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.2465
_diffrn_reflns_av_sigmaI/netI    0.3666
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            21688
_diffrn_reflns_theta_full        43.40
_diffrn_reflns_theta_max         43.40
_diffrn_reflns_theta_min         2.02
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    9.039
_exptl_absorpt_correction_T_max  0.4651
_exptl_absorpt_correction_T_min  0.4101
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    1.663
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1592
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.444
_refine_diff_density_min         -1.083
_refine_diff_density_rms         0.263
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.161
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     742
_refine_ls_number_reflns         4569
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.161
_refine_ls_R_factor_all          0.2354
_refine_ls_R_factor_gt           0.1066
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2691
_refine_ls_wR_factor_ref         0.3093
_reflns_number_gt                2733
_reflns_number_total             4569
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4cc04469j2.cif
_cod_data_source_block           e:\131030d\work\cu_131030d_0m
_cod_original_cell_volume        3245.8(8)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7115623