Alkyl and Hydrido Complexes of Platinum(IV) Supported by the Bis(8-quinolyl)methylsilyl Ligand
Sangtrirutnugul, Preeyanuch; Tilley, T. Don; Organometallics 27 (2008) 2223–; doi:10.1021/om701162h

data_4070972
_publ_section_title
;
 Alkyl and Hydrido Complexes of Platinum(IV) Supported by the
 Bis(8-quinolyl)methylsilyl Ligand
;
_journal_issue                   10
_journal_name_full               Organometallics
_journal_page_first              2223
_journal_paper_doi               10.1021/om701162h
_journal_volume                  27
_journal_year                    2008
_chemical_formula_moiety         'C21 H21 N2 Pt Si, C24 B F20'
_chemical_formula_sum            'C45 H21 B F20 N2 Pt Si'
_chemical_formula_weight         1203.63
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Wed May  9 16:00:25 2007'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                108.625(1)
_cell_angle_beta                 103.534(1)
_cell_angle_gamma                104.601(1)
_cell_formula_units_Z            2
_cell_length_a                   12.5123(6)
_cell_length_b                   12.6603(6)
_cell_length_c                   15.4852(7)
_cell_measurement_reflns_used    7447
_cell_measurement_temperature    148.2
_cell_measurement_theta_max      24.7
_cell_measurement_theta_min      2.5
_cell_volume                     2113.01(17)
_computing_cell_refinement       'Bruker-AXS SAINT v6.40'
_computing_data_collection       'Bruker-AXS SMART v5.631'
_computing_data_reduction        'Bruker-AXS SAINT v6.40'
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    SIR97
_diffrn_measured_fraction_theta_full 0.9843
_diffrn_measured_fraction_theta_max 0.9843
_diffrn_measurement_device_type  'Bruker APEX'
_diffrn_measurement_method       \w-scans
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.015
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            11962
_diffrn_reflns_theta_full        24.74
_diffrn_reflns_theta_max         24.74
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.462
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.77
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            'Pale yellow'
_exptl_crystal_density_diffrn    1.892
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1164.00
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.060
_refine_diff_density_max         1.01
_refine_diff_density_min         -0.46
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.803
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     631
_refine_ls_number_reflns         6312
_refine_ls_R_factor_all          0.0293
_refine_ls_R_factor_gt           0.0294
_refine_ls_shift/su_max          0.0022
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00022|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0394
_refine_ls_wR_factor_ref         0.0394
_reflns_number_gt                6312
_reflns_number_total             7092
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            om701162h-file002.cif
_cod_data_source_block           nuch37
_cod_original_cell_volume        2113.00(17)
_cod_original_sg_symbol_Hall     '-P 1       '
_cod_original_sg_symbol_H-M      'P -1       '
_cod_original_formula_sum        'C45 H21 B F20 N2 Pt Si '
_cod_database_code               4070972