Palladium(II)-catalyzed oxidative transformation of allylic alcohols and vinyl ethers into 2-alkoxytetrahydrofurans: catechol as an activator of catalyst.
Minami, Kimi; Kawamura, Yasufumi; Koga, Koichi; Hosokawa, Takahiro; Organic letters 7 (2005) 5689–5692; doi:10.1021/ol052377l

data_1506771
_publ_section_title
;
 Palladium(II)-catalyzed oxidative transformation of allylic alcohols and
 vinyl ethers into 2-alkoxytetrahydrofurans: catechol as an activator of
 catalyst.
;
_journal_issue                   25
_journal_name_full               'Organic letters'
_journal_page_first              5689
_journal_page_last               5692
_journal_paper_doi               10.1021/ol052377l
_journal_volume                  7
_journal_year                    2005
_chemical_formula_moiety         'C13 H15 N O4 '
_chemical_formula_sum            'C13 H15 N O4'
_chemical_formula_weight         249.27
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                95.35(1)
_cell_angle_beta                 97.18(1)
_cell_angle_gamma                113.337(8)
_cell_formula_units_Z            2
_cell_length_a                   11.014(1)
_cell_length_b                   13.147(2)
_cell_length_c                   4.8355(6)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      14.3
_cell_measurement_theta_min      12.9
_cell_volume                     629.98(15)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
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_computing_structure_solution    SIR88
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_diffrn_measured_fraction_theta_max 1.0021
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.007
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -6
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_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_standards_decay_%        0.95
_diffrn_standards_interval_count 150
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_exptl_absorpt_correction_T_min  0.906
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.07000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
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_cod_data_source_block
2-Ethoxy-(Z)-4-(4-nitrobenzylidene)tetrahydrofuran
_cod_original_cell_volume        630.0(1)
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C13 H15 N O4 '
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