Ruthenium(II) and Osmium(II) Mixed Chelates Based on Pyrenyl-Pyridylimidazole and 2,2'-Bipyridine Ligands as Efficient DNA Intercalators and Anion Sensors.
Mardanya, Sourav; Karmakar, Srikanta; Maity, Dinesh; Baitalik, Sujoy; Inorganic chemistry 54 (2015) 513–526; doi:10.1021/ic502271k

data_4342001
_publ_section_title
;
 Ruthenium(II) and Osmium(II) Mixed Chelates Based on
 Pyrenyl-Pyridylimidazole and 2,2'-Bipyridine Ligands as Efficient DNA
 Intercalators and Anion Sensors.
;
_journal_issue                   2
_journal_name_full               'Inorganic chemistry'
_journal_page_first              513
_journal_page_last               526
_journal_paper_doi               10.1021/ic502271k
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'C42 H29 Cl2 N7 O9 Ru'
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_chemical_name_systematic
; 
 ? 
;
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_computing_cell_refinement       'Bruker SAINT'
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_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_exptl_absorpt_coefficient_mu    0.608
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            red
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_exptl_crystal_description       rectanguler
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1500P)^2^+2.9812P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                7451
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic502271k_si_002.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 

 Adding full bibliography for 4342001--4342002.cif.
;
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               4342001