Structural diversity in the coordination of amidines and guanidines to monovalent metal halides.
Oakley, Sarah H.; Soria, Delia B.; Coles, Martyn P.; Hitchcock, Peter B.; Dalton transactions (Cambridge, England : 2003)  (2004) 537–546; doi:10.1039/b314707j

data_7013786
_publ_section_title
;
 Structural diversity in the coordination of amidines and guanidines to
 monovalent metal halides.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              537
_journal_page_last               546
_journal_paper_doi               10.1039/b314707j
_journal_year                    2004
_chemical_compound_source        'synthesis as described'
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_chemical_formula_sum            'C76 H64 Cl2 Cu2 N8'
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_chemical_name_common            '[{CuCl(PhNCPhNHPh)}2]'
_chemical_name_systematic
;
?
;
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_cell_angle_gamma                92.424(3)
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_cell_measurement_theta_min      3.705
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_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
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_diffrn_ambient_temperature      173(2)
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device       KappaCCD
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_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -18
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_diffrn_reflns_theta_full        27.84
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_exptl_absorpt_coefficient_mu    0.82
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_exptl_absorpt_process_details
;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.37
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
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_refine_ls_number_reflns         7363
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0836
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_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0461P)^2^+0.4421P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1099
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b314707j.txt
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_cod_original_cell_volume        1559.94(13)
_cod_original_sg_symbol_H-M      P-1
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