Construction of the Multidecker Anthracene-Silver(I) System by Intramolecular π-π Interactions
Megumu Munakata; Liang Ping Wu; Takayoshi Kuroda-Sowa; Masahiko Maekawa; Yusaku Suenaga; Tetsuhiro Ohta; Hisashi Konaka; Inorganic Chemistry 42 (2003) 2553–2558; doi:10.1021/ic020379l

data_4313452
_publ_section_title
;
 Construction of the Multidecker Anthracene-Silver(I) System by
 Intramolecular \p-\p Interactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2553
_journal_page_last               2558
_journal_paper_doi               10.1021/ic020379l
_journal_volume                  42
_journal_year                    2003
_chemical_formula_moiety         'C36 H24 Ag4 F12 O12 S4 '
_chemical_formula_sum            'C36 H24 Ag4 F12 O12 S4'
_chemical_formula_weight         1436.27
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                94.67(3)
_cell_angle_beta                 112.93(3)
_cell_angle_gamma                107.97(3)
_cell_formula_units_Z            1
_cell_length_a                   10.622(5)
_cell_length_b                   11.474(4)
_cell_length_c                   10.426(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      18.9
_cell_measurement_theta_min      15.5
_cell_volume                     1083.3(9)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  SHELXL97
_computing_structure_solution    SIR88
_diffrn_measured_fraction_theta_full 1.00
_diffrn_measured_fraction_theta_max 1.00
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.012
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            5237
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_standards_decay_%        1.20
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.082
_exptl_absorpt_correction_T_max  0.659
_exptl_absorpt_correction_T_min  0.604
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.202
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             696.0
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.200
_refine_diff_density_max         2.07
_refine_diff_density_min         -1.85
_refine_ls_extinction_coef       0.0000
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     316
_refine_ls_number_reflns         3993
_refine_ls_R_factor_gt           0.0535
_refine_ls_shift/su_max          0.0020
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.0809P)^2^+4.0909P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1567
_reflns_number_gt                3993
_reflns_number_total             4967
_reflns_threshold_expression     >2.0sigma(I)
_cod_data_source_file            ic020379l_2.cif
_cod_data_source_block           '[Ag2(dpan)0.5_(CF3SO3)2(be'
_cod_original_cell_volume        1083.2(9)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C36 H24 Ag4 F12 O12 S4 '
_cod_database_code               4313452