Zirconium and Hafnium Complexes Containing N-Alkyl-Substituted Amine Biphenolate Ligands: Unexpected Ligand Degradation and Divergent Complex Constitutions Governed by N-Alkyls
Lan-Chang Liang; Chia-Cheng Chien; Ming-Tsz Chen; Sheng-Ta Lin; Inorganic Chemistry 52 (2013) 7709–7716; doi:10.1021/ic400891b

data_4335388
_publ_section_title
;
 Zirconium and Hafnium Complexes Containing N-Alkyl-Substituted Amine
 Biphenolate Ligands: Unexpected Ligand Degradation and Divergent Complex
 Constitutions Governed by N-Alkyls
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7709
_journal_page_last               7716
_journal_paper_doi               10.1021/ic400891b
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         'C66 H102 N2 O4 Zr'
_chemical_formula_sum            'C66 H102 N2 O4 Zr'
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_chemical_name_systematic
;
 ?
;
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_cell_angle_gamma                86.994(4)
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_cell_volume                     3494.0(5)
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
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_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.973
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_diffrn_radiation_type           MoK\a
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.1273P)^2^+0.1444P] where P=(Fo^2^+2Fc^2^)/3'
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