Ruthenium η4-Trimethylenemethane Complexes Containing Tripodal Phosphanomethylamine Ligands
Scherl, Peter; Kruckenberg, Achim; Mader, Steffen; Wadepohl, Hubert; Gade, Lutz H.; Organometallics 31 (2012) 7024–; doi:10.1021/om300794h

data_4079528
_publ_section_title
;
 Ruthenium \h4-Trimethylenemethane Complexes Containing Tripodal
 Phosphanomethylamine Ligands
;
_journal_issue                   19
_journal_name_full               Organometallics
_journal_page_first              7024
_journal_paper_doi               10.1021/om300794h
_journal_volume                  31
_journal_year                    2012
_chemical_formula_sum            'C25 H54 N P3 Ru'
_chemical_formula_weight         562.67
_chemical_properties_physical    air-sensitive
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_block_code                ga_ps15
_audit_creation_date
;
'Wed Jan 25 14:35:26 2012'
;
_audit_creation_method
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_audit_update_record             'Wed Jan 25 14:42:46 CET 2012'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   16.58020(4)
_cell_length_b                   18.09136(4)
_cell_length_c                   19.48429(4)
_cell_measurement_reflns_used    170398
_cell_measurement_temperature    115
_cell_measurement_theta_max      71.8742
_cell_measurement_theta_min      3.4973
_cell_volume                     5844.48(2)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      115
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 15.9241
_diffrn_detector_type            'Agilent EOS'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_details
;
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  5 omega  -15.00   23.00   1.0000    1.5000
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  8 omega    6.00   33.00   1.0000    3.0000
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  9 omega   10.00   35.00   1.0000    3.0000
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 16 omega   18.00   43.00   1.0000    3.0000
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 17 omega   18.00   43.00   1.0000    3.0000
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 18 omega   19.00   44.00   1.0000    3.0000
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 19 omega   19.00   44.00   1.0000    3.0000
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 20 omega   19.00   44.00   1.0000    3.0000
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 25 omega   23.00   48.00   1.0000    3.0000
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omega____ theta____ kappa____ phi______ frames
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 30 omega  100.00  126.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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 31 omega   28.00  114.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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 32 omega   59.00  118.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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 33 omega   28.00   55.00   1.0000    3.0000
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    -       58.0000   77.0000 -116.0000 27

 34 omega   29.00   55.00   1.0000    3.0000
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 35 omega   58.00   85.00   1.0000    3.0000
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 36 omega   29.00  128.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       58.0000   77.0000 -169.0000 99

 37 omega   29.00   91.00   1.0000    3.0000
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 38 omega   -5.00   87.00   1.0000    3.0000
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 39 omega    3.00   86.00   1.0000    3.0000
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 40 omega   16.00   45.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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 41 omega   63.00   90.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       74.0000  -80.0000  -43.0000 27

 42 omega    7.00   95.00   1.0000    3.0000
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 43 omega  139.00  178.00   1.0000    6.0000
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 44 omega   80.00  106.00   1.0000    6.0000
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    -      110.2342   77.0000 -180.0000 26

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 46 omega   80.00  106.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   77.0000  -90.0000 26

 47 omega   80.00  177.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   77.0000   60.0000 97

 48 omega  111.00  177.00   1.0000    6.0000
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    -      110.2342   77.0000 -150.0000 66

 49 omega   80.00  106.00   1.0000    6.0000
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 50 omega  117.00  177.00   1.0000    6.0000
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 51 omega   80.00  106.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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 52 omega  123.00  164.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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 53 omega   80.00  106.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   77.0000  -60.0000 26

 54 omega  114.00  175.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   77.0000  120.0000 61

 55 omega   80.00  106.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   77.0000  120.0000 26

 56 omega  140.00  177.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   77.0000 -120.0000 37

 57 omega   80.00  106.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   77.0000 -120.0000 26

 58 omega  117.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   77.0000   90.0000 61

 59 omega   80.00  105.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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 60 omega   80.00  106.00   1.0000    6.0000
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 61 omega   85.00  131.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   38.0000 -180.0000 46

 62 omega   85.00  116.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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 63 omega   88.00  114.00   1.0000    6.0000
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 65 omega   80.00  106.00   1.0000    6.0000
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 68 omega   64.00   99.00   1.0000    6.0000
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    -      110.2342   77.0000  150.0000 50

 73 omega   88.00  151.00   1.0000    6.0000
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 74 omega   89.00  115.00   1.0000    6.0000
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    -      110.2342   50.0000   30.0000 26

 75 omega   80.00  106.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   77.0000  150.0000 26

 76 omega   39.00  114.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342  -80.0000  171.0000 75

 77 omega   88.00  114.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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 78 omega   90.00  156.00   1.0000    6.0000
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    -      110.2342   50.0000   60.0000 66

 79 omega   88.00  113.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   63.0000  -60.0000 25

 80 omega  117.00  142.00   1.0000    6.0000
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 81 omega   88.00  129.00   1.0000    6.0000
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 82 omega   88.00  115.00   1.0000    6.0000
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 83 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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    -      110.2342  -80.0000  102.0000 45

 85 omega   85.00  111.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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 86 omega   85.00  169.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   38.0000  -90.0000 84

 87 omega   39.00  127.00   1.0000    6.0000
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 88 omega  -26.00   72.00   1.0000    1.5000
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 89 omega  -73.00   44.00   1.0000    1.5000
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 91 omega  -69.00   21.00   1.0000    1.5000
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 92 omega  -21.00   69.00   1.0000    1.5000
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 93 omega  -16.00   84.00   1.0000    1.5000
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 96 omega  -63.00   26.00   1.0000    3.0000
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 98 omega   19.00   49.00   1.0000    3.0000
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 99 omega   18.00   46.00   1.0000    3.0000
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100 omega   19.00   47.00   1.0000    3.0000
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101 omega   24.00  124.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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102 omega   23.00   49.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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103 omega   24.00  124.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       54.0000   77.0000   38.0000 100

104 omega   25.00  124.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       54.0000   76.0000  -42.0000 99

105 omega   23.00   49.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       54.0000   78.0000  178.0000 26

106 omega   24.00  124.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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107 omega   28.00  128.00   1.0000    3.0000
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108 omega   28.00  128.00   1.0000    3.0000
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109 omega   28.00  128.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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110 omega   28.00  128.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       58.0000   77.0000 -169.0000 100

111 omega   28.00  128.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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112 omega   30.00  128.00   1.0000    3.0000
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113 omega   -9.00   94.00   1.0000    3.0000
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114 omega   -5.00   97.00   1.0000    3.0000
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115 omega   -5.00   98.00   1.0000    3.0000
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116 omega   -1.00  102.00   1.0000    3.0000
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117 omega    3.00  106.00   1.0000    3.0000
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118 omega    3.00  106.00   1.0000    3.0000
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119 omega    7.00  110.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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120 omega    7.00  110.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       78.0000  -80.0000  -33.0000 103

121 omega   11.00  114.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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122 omega   11.00  113.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
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123 omega   11.00  113.00   1.0000    3.0000
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124 omega   88.00  178.00   1.0000    6.0000
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126 omega   88.00  178.00   1.0000    6.0000
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127 omega   85.00  178.00   1.0000    6.0000
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128 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   50.0000 -180.0000 90

129 omega   85.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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130 omega   80.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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131 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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132 omega   88.00  178.00   1.0000    6.0000
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133 omega   80.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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134 omega   40.00  140.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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135 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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136 omega   39.00  142.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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137 omega   85.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   38.0000 -150.0000 93

138 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   63.0000 -120.0000 90

139 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   50.0000  120.0000 90

140 omega   76.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   25.0000   30.0000 102

141 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   50.0000 -120.0000 90

142 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   50.0000  -60.0000 90

143 omega   40.00  140.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342  -77.0000   90.0000 100

144 omega   37.00   94.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342  -25.0000 -180.0000 57

145 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   63.0000    0.0000 90

146 omega   37.00   94.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342  -25.0000 -120.0000 57

147 omega   39.00  142.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342  -80.0000  -74.0000 103

148 omega   37.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342  -12.0000  -90.0000 141

149 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   63.0000  120.0000 90

150 omega   37.00   94.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342  -25.0000  120.0000 57

151 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   50.0000   30.0000 90

152 omega   85.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   38.0000  -90.0000 93

153 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   63.0000   60.0000 90

154 omega   39.00  142.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342  -80.0000  -28.0000 103

155 omega   85.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   38.0000   60.0000 93

156 omega   39.00  142.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342  -80.0000 -111.0000 103

157 omega   85.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   38.0000    0.0000 93

158 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   50.0000  150.0000 90

159 omega   88.00  178.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.2342   63.0000  -30.0000 90

160 phi      0.00  120.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
 -40.0000    0.0000    0.0000     -     120

161 omega  -73.00   73.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
    -        0.0000    0.0000  240.0000 146

162 phi    120.00  240.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
   0.0000    0.0000  -20.0000     -     120

163 omega  -26.00   72.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
    -        0.0000   38.0000  -90.0000 98

164 omega  -73.00   73.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
    -        0.0000    0.0000  120.0000 146

165 omega  -73.00   73.00   1.0000    1.5000
omega____ theta____ kappa____ phi______ frames
    -        0.0000    0.0000    0.0000 146

166 omega  -50.00   30.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -      -42.5000   38.0000 -150.0000 80

167 omega -113.00  -12.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -      -42.5000  -77.0000  120.0000 101

168 omega -113.00  -12.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -      -42.5000  -77.0000  -90.0000 101

169 omega -113.00  -12.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -      -42.5000  -77.0000 -180.0000 101

170 omega   14.00   46.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   80.0000  102.0000 32

171 omega   15.00   47.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       46.0000   79.0000  151.0000 32

172 omega   19.00   47.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       50.0000   79.0000 -168.0000 28

173 omega   19.00   47.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       50.0000   79.0000  142.0000 28

174 omega   25.00  124.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       54.0000   76.0000  -54.0000 99

175 omega   25.00  124.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       54.0000   76.0000  102.0000 99

176 omega   24.00  124.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       54.0000   77.0000   14.0000 100

177 omega   25.00  125.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       55.1171   77.0000 -150.0000 100

178 omega  -18.00   61.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       55.1171    0.0000  120.0000 79

179 omega  -18.00  128.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       55.1171    0.0000    0.0000 146

180 omega  -18.00  128.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       55.1171    0.0000  240.0000 146

181 omega  -18.00  128.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       55.1171    0.0000  120.0000 146

182 omega  -18.00  128.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       55.1171    0.0000    0.0000 146

183 omega   29.00  128.00   1.0000    3.0000
omega____ theta____ kappa____ phi______ frames
    -       58.0000   76.0000   99.0000 99

;
_diffrn_measurement_device       '\k-geometry diffractometer'
_diffrn_measurement_device_type  'Agilent SuperNova, Dual, Cu at zero, Eos'
_diffrn_measurement_method       '\w and \p scans'
_diffrn_measurement_specimen_support 'polyimid foil'
_diffrn_orient_matrix_UB_11      0.0071200000
_diffrn_orient_matrix_UB_12      0.0707069000
_diffrn_orient_matrix_UB_13      -0.0437347000
_diffrn_orient_matrix_UB_21      0.0604468000
_diffrn_orient_matrix_UB_22      0.0322174000
_diffrn_orient_matrix_UB_23      0.0520283000
_diffrn_orient_matrix_UB_31      0.0701505000
_diffrn_orient_matrix_UB_32      -0.0349158000
_diffrn_orient_matrix_UB_33      -0.0404104000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.5418
_diffrn_reflns_av_R_equivalents  0.0554
_diffrn_reflns_av_sigmaI/netI    0.0922
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            319895
_diffrn_reflns_theta_full        66.97
_diffrn_reflns_theta_max         71.8742
_diffrn_reflns_theta_min         3.4973
_diffrn_source                   'Agilent SuperNova (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    5.967
_exptl_absorpt_correction_T_max  0.921
_exptl_absorpt_correction_T_min  0.891
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
Analytical numeric absorption correction using a multifaceted crystal
            model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.279
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             2400
_exptl_crystal_size_max          0.2049
_exptl_crystal_size_mid          0.1384
_exptl_crystal_size_min          0.1313
_refine_diff_density_max         0.387
_refine_diff_density_min         -0.514
_refine_diff_density_rms         0.042
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     301
_refine_ls_number_reflns         5744
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0174
_refine_ls_R_factor_gt           0.0172
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0211P)^2^+3.1225P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0434
_refine_ls_wR_factor_ref         0.0436
_reflns_number_gt                5646
_reflns_number_total             5744
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om300794h_si_002.cif
_cod_data_source_block           compound_3
_cod_database_code               4079528
_audit_block_refno               1426
_audit_block_usercomment         'PS_SM18, orange, irregular'
_cell_oxdiff_length_a            16.58764(14)
_cell_oxdiff_length_b            18.08484(16)
_cell_oxdiff_length_c            19.48258(17)
_cell_oxdiff_angle_alpha         89.9560(7)
_cell_oxdiff_angle_beta          89.9903(7)
_cell_oxdiff_angle_gamma         90.0109(7)
_cell_oxdiff_volume              5844.48(9)
_cell_oxdiff_measurement_reflns_used 170398
_reflns_odcompleteness_completeness 99.93
_reflns_odcompleteness_theta     66.97
_reflns_odcompleteness_iscentric 1