Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions.
Ageshina, Alexandra A.; Sterligov, Grigorii K.; Rzhevskiy, Sergey A.; Topchiy, Maxim A.; Chesnokov, Gleb A.; Gribanov, Pavel S.; Melnikova, Elizaveta K.; Nechaev, Mikhail S.; Asachenko, Andrey F.; Bermeshev, Maxim V.; Dalton transactions (Cambridge, England : 2003) 48 (2019) 3447–3452; doi:10.1039/c9dt00216b

data_7049011
_publ_section_title
;
 Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in
 the Buchwald-Hartwig reaction under solvent-free conditions.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3447
_journal_page_last               3452
_journal_paper_doi               10.1039/c9dt00216b
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C58 H83 Cl2 N2 O2 P Pd'
_chemical_formula_sum            'C58 H83 Cl2 N2 O2 P Pd'
_chemical_formula_weight         1048.53
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/6
_audit_update_record
;
2019-01-24 deposited with the CCDC.    2019-02-13 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0379P)^2^+6.4999P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt00216b2.cif
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'Adding full bibliography for 7049010--7049011.cif.'
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