Reversibility in Reactions of Linker-Bridged Distannenes with Terminal Alkynes at Ambient Temperature.
Schneider, Julia; Henning, Jens; Edrich, Jessica; Schubert, Hartmut; Wesemann, Lars; Inorganic chemistry 54 (2015) 6020–6027; doi:10.1021/acs.inorgchem.5b00896

data_4343090
_publ_section_title
;
 Reversibility in Reactions of Linker-Bridged Distannenes with Terminal
 Alkynes at Ambient Temperature.
;
_journal_issue                   12
_journal_name_full               'Inorganic chemistry'
_journal_page_first              6020
_journal_page_last               6027
_journal_paper_doi               10.1021/acs.inorgchem.5b00896
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'C95 H116 O Sn2, C4 H10 O'
_chemical_formula_sum            'C99 H126 O2 Sn2'
_chemical_formula_weight         1585.38
_chemical_name_systematic
; 
 ? 
;
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_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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_cell_angle_beta                 107.206(2)
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_cell_length_b                   31.2528(9)
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_cell_measurement_reflns_used    425
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      24.2312
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
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_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX--II CCD'
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_diffrn_radiation_monochromator  graphite
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.225
_exptl_crystal_density_method    'not measured'
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_refine_ls_number_reflns         15748
_refine_ls_number_restraints     113
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_refine_ls_R_factor_all          0.0542
_refine_ls_R_factor_gt           0.0437
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0293P)^2^+19.7715P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            9_JE1p21c.cif
_cod_data_source_block           TripXantHCCPh
_cod_depositor_comments
'Adding full bibliography for 4343090--4343095.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4343090
_computing_bruker_data_scaling   'SADABS V2008/1 (Bruker AXS)'