Synthesis and Structures of the First Bismuth-Ester Complexes Using Heterobifunctional Thiolate Anchored Ligands and Mass Spectrometric Identification of Ligand-Bridged Derivatives
Glen G. Briand; Neil Burford; Melanie D. Eelman; T. Stanley Cameron; Katherine N. Robertson; Inorganic Chemistry 42 (2003) 3136–3141; doi:10.1021/ic0261934

data_4313558
_publ_section_title
;
 Synthesis and Structures of the First Bismuth-Ester Complexes Using
 Heterobifunctional Thiolate Anchored Ligands and Mass Spectrometric
 Identification of Ligand-Bridged Derivatives
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3136
_journal_page_last               3141
_journal_paper_doi               10.1021/ic0261934
_journal_volume                  42
_journal_year                    2003
_chemical_formula_moiety         'C4 H7 Bi1 Cl2 O2 S1'
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_symmetry_space_group_name_Hall  '-P 2yab'
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_cell_angle_gamma                90
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_cell_length_b                   10.284(4)
_cell_length_c                   11.099(4)
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_cell_measurement_temperature    143
_cell_measurement_theta_max      20.0
_cell_measurement_theta_min      19.6
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teXsan for Windows version 1.06 (MSC, 1997-1999)
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teXsan for Windows version 1.06 (MSC, 1997-1999)
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SIR92 (Altomare, et. al. 1994)
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_diffrn_measured_fraction_theta_max 0.948
_diffrn_measurement_device       'Rigaku AFC5R'
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;
North,Phillips & Matthews, 1968
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_exptl_crystal_colour            yellow
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_refine_ls_structure_factor_coef Fsqd
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;
w=1/[\s^2^(Fo^2^)+(0.0316P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0668
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_reflns_number_gt                1642
_reflns_number_total             2659
_reflns_threshold_expression     I>2.00\s(I)
_cod_data_source_file            ic0261934si20030128_124611.cif
_cod_data_source_block           melanie1b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'P 21/a '
_cod_original_formula_sum        'C4 H7 Bi1 Cl2 O2 S1 '
_cod_database_code               4313558