LMucko/crystallography-open-database huggingface dataset:
The utility of aryloxide ligands as bridging ligands for europium and calcium- containing compounds
Evans, W. J.; McClelland, W. G.; Greci, M. A.; Ziller, J. W.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 145–156; doi:

data_4030775
_publ_section_title
;
 The utility of aryloxide ligands as bridging ligands for europium and
 calcium- containing compounds
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              145
_journal_page_last               156
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'C44 H66 Eu2 O10'
_chemical_formula_weight         1058.91
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.271(2)
_cell_length_b                   19.526(3)
_cell_length_c                   20.822(4)
_cell_volume                     4582.5(14)
_diffrn_ambient_temperature      163
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    2.765
_exptl_crystal_density_diffrn    1.535
_refine_ls_number_parameters     506
_refine_ls_number_reflns         4182
_refine_ls_R_factor_gt           0.028
_refine_ls_wR_factor_gt          0.033
_cod_data_source_file            EJSSIC-1996-33-145-156-1.cif
_cod_data_source_block           C44H66O10Eu2
_cod_depositor_comments
;
No atomic coordinates in the paper
;
_cod_original_cell_volume        4582.3(13)
_cod_database_code               4030775
The utility of aryloxide ligands as bridging ligands for europium and calcium- containing compounds
Evans, W. J.; McClelland, W. G.; Greci, M. A.; Ziller, J. W.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 145–156; doi:

data_4030776
_publ_section_title
;
 The utility of aryloxide ligands as bridging ligands for europium and
 calcium- containing compounds
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              145
_journal_page_last               156
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'C24 H38 Ca2 O6'
_chemical_formula_weight         502.709
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 114.895(9)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.380(2)
_cell_length_b                   13.278(2)
_cell_length_c                   15.254(2)
_cell_volume                     2641.9(7)
_diffrn_ambient_temperature      163
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    0.270
_exptl_crystal_density_diffrn    1.163
_refine_ls_number_parameters     281
_refine_ls_number_reflns         2583
_refine_ls_R_factor_gt           0.055
_refine_ls_wR_factor_gt          0.057
_cod_data_source_file            EJSSIC-1996-33-145-156-2.cif
_cod_data_source_block           C44H66O10Eu2
_cod_depositor_comments
;
 Changing atom parameters to '?' to indicate that atomic coordinates
 for this entry are unknown.

 Antanas Vaitkus,
 2017-01-27

No atomic coordinates in the paper
;
_cod_original_cell_volume        2641.9(6)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4030776
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030785
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'La Rb S2'
_chemical_formula_weight         288.503
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   4.296(1)
_cell_length_b                   4.296(1)
_cell_length_c                   22.930(6)
_cell_volume                     366.49(15)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    19.288
_exptl_crystal_density_diffrn    3.922
_exptl_crystal_F_000             378
_refine_ls_number_parameters     8
_refine_ls_number_reflns         166
_refine_ls_R_factor_gt           0.018
_cod_data_source_file            EJSSIC-1996-33-213-216-1.cif
_cod_data_source_block           RbLaS2
_cod_original_cell_volume        20
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030785
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030786
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'Ho Rb S2'
_chemical_formula_weight         314.54
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   4.037(3)
_cell_length_b                   4.037(3)
_cell_length_c                   22.844(18)
_cell_volume                     322.4(4)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    30.395
_exptl_crystal_density_diffrn    4.860
_exptl_crystal_F_000             408
_refine_ls_number_parameters     8
_refine_ls_number_reflns         285
_refine_ls_R_factor_gt           0.053
_cod_data_source_file            EJSSIC-1996-33-213-216-10.cif
_cod_data_source_block           RbHoS2
_cod_original_cell_volume        322.4(6)
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030786
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030787
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'Er Rb S2'
_chemical_formula_weight         316.87
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   4.026(3)
_cell_length_b                   4.026(3)
_cell_length_c                   22.802(20)
_cell_volume                     320.1(4)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    31.738
_exptl_crystal_density_diffrn    4.931
_exptl_crystal_F_000             411
_refine_ls_number_parameters     8
_refine_ls_number_reflns         147
_refine_ls_R_factor_gt           0.054
_cod_data_source_file            EJSSIC-1996-33-213-216-11.cif
_cod_data_source_block           RbErS2
_cod_original_cell_volume        320.1(6)
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030787
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030788
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'Rb S2 Tm'
_chemical_formula_weight         318.54
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   4.020(1)
_cell_length_b                   4.020(1)
_cell_length_c                   22.838(6)
_cell_volume                     319.63(14)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    32.914
_exptl_crystal_density_diffrn    4.965
_exptl_crystal_F_000             414
_refine_ls_number_parameters     8
_refine_ls_number_reflns         236
_refine_ls_R_factor_gt           0.044
_cod_data_source_file            EJSSIC-1996-33-213-216-12.cif
_cod_data_source_block           RbTmS2
_cod_original_cell_volume        319.6(2)
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030788
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030789
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'Rb S2 Yb'
_chemical_formula_weight         322.65
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   3.991(1)
_cell_length_b                   3.991(1)
_cell_length_c                   22.717(7)
_cell_volume                     313.36(15)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    34.713
_exptl_crystal_density_diffrn    5.129
_exptl_crystal_F_000             417
_refine_ls_number_parameters     8
_refine_ls_number_reflns         266
_refine_ls_R_factor_gt           0.018
_cod_data_source_file            EJSSIC-1996-33-213-216-13.cif
_cod_data_source_block           RbYbS2
_cod_original_cell_volume        313.4(2)
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030789
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030790
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'Lu Rb S2'
_chemical_formula_weight         324.58
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   3.991(1)
_cell_length_b                   3.991(1)
_cell_length_c                   22.838(7)
_cell_volume                     315.03(15)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    35.775
_exptl_crystal_density_diffrn    5.133
_exptl_crystal_F_000             420
_refine_ls_number_parameters     8
_refine_ls_number_reflns         280
_refine_ls_R_factor_gt           0.034
_cod_data_source_file            EJSSIC-1996-33-213-216-14.cif
_cod_data_source_block           RbLuS2
_cod_original_cell_volume        315.0(2)
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030790
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030791
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'Ce Rb S2'
_chemical_formula_weight         289.73
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   4.249(3)
_cell_length_b                   4.249(3)
_cell_length_c                   22.851(22)
_cell_volume                     357.3(5)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    20.373
_exptl_crystal_density_diffrn    4.040
_exptl_crystal_F_000             381
_refine_ls_number_parameters     8
_refine_ls_number_reflns         92
_refine_ls_R_factor_gt           0.036
_cod_data_source_file            EJSSIC-1996-33-213-216-2.cif
_cod_data_source_block           RbCeS2
_cod_original_cell_volume        357.3(7)
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030791
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030792
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'Pr Rb S2'
_chemical_formula_weight         290.52
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   4.221(2)
_cell_length_b                   4.221(2)
_cell_length_c                   22.897(9)
_cell_volume                     353.3(3)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    21.283
_exptl_crystal_density_diffrn    4.096
_exptl_crystal_F_000             384
_refine_ls_number_parameters     8
_refine_ls_number_reflns         376
_refine_ls_R_factor_gt           0.052
_cod_data_source_file            EJSSIC-1996-33-213-216-3.cif
_cod_data_source_block           RbPrS2
_cod_original_cell_volume        353.3(4)
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030792
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030793
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'Nd Rb S2'
_chemical_formula_weight         293.85
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   4.194(2)
_cell_length_b                   4.194(2)
_cell_length_c                   22.894(12)
_cell_volume                     348.7(3)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    22.245
_exptl_crystal_density_diffrn    4.197
_exptl_crystal_F_000             387
_refine_ls_number_parameters     8
_refine_ls_number_reflns         237
_refine_ls_R_factor_gt           0.026
_cod_data_source_file            EJSSIC-1996-33-213-216-4.cif
_cod_data_source_block           RbNdS2
_cod_original_cell_volume        348.8(4)
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030793
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030794
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'Rb S2 Sm'
_chemical_formula_weight         299.97
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   4.143(2)
_cell_length_b                   4.143(2)
_cell_length_c                   22.880(9)
_cell_volume                     340.1(3)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    24.314
_exptl_crystal_density_diffrn    4.394
_exptl_crystal_F_000             393
_refine_ls_number_parameters     8
_refine_ls_number_reflns         244
_refine_ls_R_factor_gt           0.022
_cod_data_source_file            EJSSIC-1996-33-213-216-5.cif
_cod_data_source_block           RbSmS2
_cod_original_cell_volume        340.1(4)
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030794
Ternary rubidium rare-earth sulphides; synthesis and structure
Bronger, W.; Eyck, J.; Kruse, K.; Schmitz, D.; European Journal of Solid State and Inorganic Chemistry 33 (1996) 213–216; doi:

data_4030795
_publ_section_title
;
 Ternary rubidium rare-earth sulphides; synthesis and structure
;
_journal_name_full
'European Journal of Solid State and Inorganic Chemistry'
_journal_page_first              213
_journal_page_last               216
_journal_volume                  33
_journal_year                    1996
_chemical_formula_sum            'Eu Rb S2'
_chemical_formula_weight         301.57
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      166
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            3
_cell_length_a                   4.126(2)
_cell_length_b                   4.126(2)
_cell_length_c                   22.890(12)
_cell_volume                     337.5(3)
_diffrn_ambient_temperature      293
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_exptl_absorpt_coefficient_mu    25.390
_exptl_crystal_density_diffrn    4.451
_exptl_crystal_F_000             396
_refine_ls_number_parameters     8
_refine_ls_number_reflns         255
_refine_ls_R_factor_gt           0.022
_cod_data_source_file            EJSSIC-1996-33-213-216-6.cif
_cod_data_source_block           RbEuS2
_cod_original_cell_volume        337.5(4)
_cod_original_sg_symbol_H-M      'R -3 m'
_cod_database_code               4030795