Redox state switching of transition metals by deprotonation of the tridentate ligand 2,6-bis(imidazol-2-yl)pyridine.
Stupka, Gilles; Gremaud, Ludovic; Bernardinelli, Gérald; Williams, Alan F.; Dalton transactions (Cambridge, England : 2003)  (2004) 407–412; doi:10.1039/b313440g

data_7013723
_publ_section_title
;
 Redox state switching of transition metals by deprotonation of the
 tridentate ligand 2,6-bis(imidazol-2-yl)pyridine.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              407
_journal_page_last               412
_journal_paper_doi               10.1039/b313440g
_journal_year                    2004
_chemical_formula_moiety         '(C11 H9 N5)2 (P F6)2 (C2 H3 N)2 (H2 O) Ru'
_chemical_formula_sum            'C26 H26 F12 N12 O P2 Ru'
_chemical_formula_weight         913.7
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
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_audit_creation_method           from_xtal_archive_file_using_CIFIO
_audit_update_record             2003-10-10
_cell_angle_alpha                95.093(7)
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_cell_angle_gamma                97.794(6)
_cell_formula_units_Z            2
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_cell_length_c                   25.5753(14)
_cell_measurement_reflns_used    7998
_cell_measurement_temperature    200
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_cell_volume                     1819.19(17)
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_diffrn_measurement_device_type  'Stoe Ipds'
_diffrn_measurement_method       \f
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .034
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_diffrn_reflns_limit_h_min       -10
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_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            19580
_diffrn_reflns_theta_full        28.06
_diffrn_reflns_theta_max         28.06
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    .622
_exptl_absorpt_correction_T_max  .9689
_exptl_absorpt_correction_T_min  .8714
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'XRED; Stoe & Cie, 1999'
_exptl_crystal_colour            violet
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_exptl_crystal_density_meas      ?
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_refine_ls_shift/su_max          .10
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     \w=1/[\s^2^(Fo)+0.00015(Fo^2^)]
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                5735
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_reflns_threshold_expression     'refl observed if Fo > 3.99 \s(Fo)'
_cod_data_source_file            b313440g.txt
_cod_data_source_block           UPKA
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not_measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        1819.19(18)
_cod_database_code               7013723