Isomerization of trans-[Ru(PTA)4Cl2] to cis-[Ru(PTA)4Cl2] in water and organic solvent: revisiting the chemistry of [Ru(PTA)4Cl2].
Mebi, Charles A.; Frost, Brian J.; Inorganic chemistry 46 (2007) 7115–7120; doi:10.1021/ic700971n

data_4339925
_publ_section_title
;
 Isomerization of trans-[Ru(PTA)4Cl2] to cis-[Ru(PTA)4Cl2] in water and
 organic solvent: revisiting the chemistry of [Ru(PTA)4Cl2].
;
_journal_issue                   17
_journal_name_full               'Inorganic chemistry'
_journal_page_first              7115
_journal_page_last               7120
_journal_paper_doi               10.1021/ic700971n
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C24 H62 N12 O6.25 P4 Ru'
_chemical_formula_weight         843.81
_chemical_name_systematic
;

 ?

;
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_computing_cell_refinement       'Bruker SMART'
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_computing_molecular_graphics    'Bruker SHELXTL'
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_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
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_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_T_max  0.9400
_exptl_absorpt_correction_T_min  0.8756
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.531
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1776
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0281P)^2^+1.6299P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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