Uniting Ruthenium(II) and Platinum(II) Polypyridine Centers in Heteropolymetallic Complexes Giving Strong Two-Photon Absorption.
Shi, Pengfei; Coe, Benjamin J.; Sánchez, Sergio; Wang, Daqi; Tian, Yupeng; Nyk, Marcin; Samoc, Marek; Inorganic chemistry 54 (2015) 11450–11456; doi:10.1021/acs.inorgchem.5b02089

data_4346768
_publ_section_title
;
 Uniting Ruthenium(II) and Platinum(II) Polypyridine Centers in
 Heteropolymetallic Complexes Giving Strong Two-Photon Absorption.
;
_journal_issue                   23
_journal_name_full               'Inorganic chemistry'
_journal_page_first              11450
_journal_page_last               11456
_journal_paper_doi               10.1021/acs.inorgchem.5b02089
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'C70 H52 F6 N19 O15 P Pt2 Ru'
_chemical_formula_weight         2035.53
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                73.804(4)
_cell_angle_beta                 83.470(3)
_cell_angle_gamma                82.994(3)
_cell_formula_units_Z            2
_cell_length_a                   8.5286(3)
_cell_length_b                   22.2375(10)
_cell_length_c                   23.1600(9)
_cell_measurement_temperature    150(2)
_cell_volume                     4171.9(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.1305
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            14633
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.77
_exptl_absorpt_coefficient_mu    3.627
_exptl_absorpt_correction_T_max  0.6701
_exptl_absorpt_correction_T_min  0.6122
_exptl_crystal_density_diffrn    1.620
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'red block'
_exptl_crystal_F_000             1988
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.12
_platon_squeeze_details
;
;
_refine_diff_density_max         3.697
_refine_diff_density_min         -2.264
_refine_diff_density_rms         0.277
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1028
_refine_ls_number_reflns         14633
_refine_ls_number_restraints     319
_refine_ls_restrained_S_all      1.044
_refine_ls_R_factor_all          0.1331
_refine_ls_R_factor_gt           0.1037
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1604P)^2^+45.6204P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2688
_refine_ls_wR_factor_ref         0.2993
_reflns_number_gt                10074
_reflns_number_total             14633
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic5b02089_si_004.cif
_cod_data_source_block           '[4][NO3]5[PF6].H2O'
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4346768