Tandem hydrogenation and condensation of fluorinated α,β-unsaturated ketones with primary amines, catalyzed by nickel.
Castellanos-Blanco, Nahury; Flores-Alamo, Marcos; García, Juventino J; Dalton transactions (Cambridge, England : 2003) 44 (2015) 15653–15663; doi:10.1039/c5dt02366a

data_7035948
_publ_section_title
;
 Tandem hydrogenation and condensation of fluorinated \a,\b-unsaturated
 ketones with primary amines, catalyzed by nickel.
;
_journal_issue                   35
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'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               15663
_journal_paper_doi               10.1039/c5dt02366a
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C47 H76 F6 Ni2 O P4'
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 ?
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2015-06-19 deposited with the CCDC.
2015-07-23 downloaded from the CCDC.
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Analytical numeric absorption correction using a multifaceted crystal
                        model based on expressions derived by R.C. Clark & J.S.
        (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            brown
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'w=1/[\s^2^(Fo^2^)+(0.0271P)^2^+1.8386P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7035948--7035950.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
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