A germanimidoyl chloride: synthesis, characterization and reactivity.
Li, Tong; Zhang, Li; He, Yuhao; Chen, Yizhen; Wang, Dongmin; Liu, Jingjing; Tan, Gengwen; Chemical communications (Cambridge, England) 59 (2023) 1533–1536; doi:10.1039/d2cc05970c

data_7131188
_publ_section_title
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 A germanimidoyl chloride: synthesis, characterization and reactivity.
;
_journal_issue                   11
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              1533
_journal_page_last               1536
_journal_paper_doi               10.1039/d2cc05970c
_journal_volume                  59
_journal_year                    2023
_chemical_formula_sum            'C71 H90 Ge Li N O'
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_space_group_name_Hall           '-P 1'
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_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2022-11-04 deposited with the CCDC.	2023-01-17 downloaded from the CCDC.
;
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_cell_measurement_theta_max      53.98
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      138(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           GaK\a
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_diffrn_reflns_av_unetI/netI     0.0495
_diffrn_reflns_Laue_measured_fraction_full 0.997
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_diffrn_reflns_point_group_measured_fraction_full 0.997
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_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         54.075
_diffrn_reflns_theta_min         2.237
_exptl_absorpt_coefficient_mu    0.609
_exptl_absorpt_correction_T_max  0.7506
_exptl_absorpt_correction_T_min  0.6344
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.080
_exptl_crystal_description       block
_exptl_crystal_F_000             1132
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.130
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_refine_diff_density_rms         0.060
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
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_refine_ls_restrained_S_all      1.048
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_refine_ls_R_factor_gt           0.0446
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0660P)^2^+1.2213P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1155
_refine_ls_wR_factor_ref         0.1235
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9537
_reflns_number_total             11882
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d2cc05970c2.cif
_cod_data_source_block           6
_cod_depositor_comments
'Adding full bibliography for 7131185--7131189.cif.'
_cod_database_code               7131188
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.888
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_shelx_hkl_checksum              62682
_shelx_fab_checksum              48959