Catalytic Anti-Markovnikov Hydroallylation of Terminal and Functionalized Internal Alkynes: Synthesis of Skipped Dienes and Trisubstituted Alkenes.
Mailig, Melrose; Hazra, Avijit; Armstrong, Megan K.; Lalic, Gojko; Journal of the American Chemical Society 139 (2017) 6969–6977; doi:10.1021/jacs.7b02104

data_4126135
_publ_section_title
;
 Catalytic Anti-Markovnikov Hydroallylation of Terminal and Functionalized
 Internal Alkynes: Synthesis of Skipped Dienes and Trisubstituted Alkenes.
;
_journal_issue                   20
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              6969
_journal_page_last               6977
_journal_paper_doi               10.1021/jacs.7b02104
_journal_volume                  139
_journal_year                    2017
_chemical_formula_moiety         'C45 H65 Cu N2 O Si'
_chemical_formula_sum            'C45 H65 Cu N2 O Si'
_chemical_formula_weight         741.62
_chemical_name_common            MA_03_102
_chemical_name_systematic        MA_03_102
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
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_cell_measurement_temperature    100(2)
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_cell_volume                     4197.3(5)
_computing_cell_refinement       'SAINT (Bruker, 2007)'
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_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.999
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_diffrn_source                   'fine-focus sealed tube'
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0422P)^2^+1.0065P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0876
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                5161
_reflns_number_total             7737
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja7b02104_si_002.cif
_cod_data_source_block           MA_03_102
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_shelx_estimated_absorpt_t_min   0.5678
_shelx_estimated_absorpt_t_max   0.7452
_exptl_absorpt_special_details
;
 180 seconds, 0.5 degrees, 40.00 mm
;
_shelx_res_checksum              99622
_shelx_hkl_checksum              20131