A facile and benign synthesis of binuclear ruthenium(I) “sawhorse” complexes
Kepert, Christopher M.; Deacon, Glen B.; Spiccia, Leone; Fallon, Gary D.; Skelton, Brian W.; White, Allan H.; Journal of the Chemical Society, Dalton Transactions  (2000) 2867–; doi:10.1039/b002304n

data_7009612
_publ_section_title
;
 A facile and benign synthesis of binuclear ruthenium(I)
 &#x201C;sawhorse&#x201D; complexes
;
_journal_issue                   16
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2867
_journal_paper_doi               10.1039/b002304n
_journal_year                    2000
_chemical_formula_sum            'C18 H16 N2 O8 Ru2'
_chemical_formula_weight         590.47
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.00000
_cell_angle_beta                 106.42(4)
_cell_angle_gamma                90.00000
_cell_formula_units_Z            4
_cell_length_a                   15.746(8)
_cell_length_b                   8.634(4)
_cell_length_c                   15.837(7)
_cell_measurement_reflns_used    50
_cell_measurement_temperature    173.2
_cell_measurement_theta_max      33.8
_cell_measurement_theta_min      11.5
_cell_volume                     2065.2(17)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_molecular_graphics    teXsan
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  teXsan
_diffrn_ambient_temperature      173.2
_diffrn_measurement_device_type
;
   NICOLET                          
;
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_detector       'CCD area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .7107
_diffrn_reflns_av_R_equivalents  .0354
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            2034
_diffrn_reflns_theta_max         25
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 297
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.51
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  .689
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details
;
 DIFABS, Walker and Stuart       
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.899
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1160
_exptl_crystal_size_max          0
_exptl_crystal_size_mid          0
_exptl_crystal_size_min          0
_refine_diff_density_max         .58
_refine_diff_density_min         -.85
_refine_ls_goodness_of_fit_ref   3.437
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     136
_refine_ls_number_reflns         1567
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           .0269
_refine_ls_shift/su_max          .0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         .0345
_reflns_limit_h_max              18
_reflns_limit_h_min              -17
_reflns_limit_k_max              10
_reflns_limit_k_min              0
_reflns_limit_l_max              0
_reflns_limit_l_min              -18
_reflns_number_gt                1567
_reflns_number_observed          1567
_reflns_number_total             1959
_reflns_threshold_expression     'I    > 3.00 sig(I   )'
_cod_data_source_file            b002304n.txt
_cod_data_source_block           rupyoa
_cod_original_sg_symbol_Hall     -c_2yc
_cod_original_sg_symbol_H-M      C_1_2/c_1
_cod_database_code               7009612