A stimuli-responsive dimeric capsule built from an acridine-based metallacycle for ratiometric fluorescence sensing of TNP.
Jin, Qi-Qi; Duan, Xiao-Fang; Yan, Dan-Ni; Yin, Fan; Li, Chen-Chen; Zhou, Li-Peng; Cai, Li-Xuan; Sun, Qing-Fu; Dalton transactions (Cambridge, England : 2003) 54 (2025) 4998–5005; doi:10.1039/d4dt03334e

data_7718034
_publ_section_title
;
 A stimuli-responsive dimeric capsule built from an acridine-based
 metallacycle for ratiometric fluorescence sensing of TNP.
;
_journal_issue                   12
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4998
_journal_page_last               5005
_journal_paper_doi               10.1039/d4dt03334e
_journal_volume                  54
_journal_year                    2025
_chemical_formula_sum            'C70 H74 N18 O12 Pd2'
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_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2019/3
_audit_update_record
;
2024-11-21 deposited with the CCDC.	2025-01-30 downloaded from the CCDC.
;
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_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_refine_ls_R_factor_all          0.0742
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2113
_refine_ls_wR_factor_ref         0.2256
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_reflns_number_gt                15546
_reflns_number_total             19463
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           jqq-230318_auto_sq
_cod_depositor_comments          'Adding full bibliography for 7718034.cif.'
_cod_original_cell_volume        4850.30(15)
_cod_database_code               7718034
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