C-h activation/functionalization catalyzed by simple, well-defined low-valent cobalt complexes.
Fallon, Brendan J.; Derat, Etienne; Amatore, Muriel; Aubert, Corinne; Chemla, Fabrice; Ferreira, Franck; Perez-Luna, Alejandro; Petit, Marc; Journal of the American Chemical Society 137 (2015) 2448–2451; doi:10.1021/ja512728f

data_4123428
_publ_section_title
;
 C-h activation/functionalization catalyzed by simple, well-defined
 low-valent cobalt complexes.
;
_journal_issue                   7
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              2448
_journal_page_last               2451
_journal_paper_doi               10.1021/ja512728f
_journal_volume                  137
_journal_year                    2015
_chemical_formula_moiety         'C29 H24 F N O'
_chemical_formula_sum            'C29 H24 F N O'
_chemical_formula_weight         421.49
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_cell_angle_alpha                80.098(2)
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_cell_length_b                   10.0505(2)
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_cell_measurement_temperature    200(1)
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_computing_cell_refinement       'Bruker SAINT'
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_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'
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_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  'curved graphite'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_av_unetI/netI     0.0128
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_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            43996
_diffrn_reflns_point_group_measured_fraction_full 0.994
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_diffrn_reflns_theta_full        25.242
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_exptl_absorpt_process_details
; 
R.H. Blessing, Acta Cryst. (1995), A51, 33-38
;
_exptl_crystal_colour            yellow
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_refine_ls_number_reflns         6940
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_refine_ls_R_factor_all          0.0595
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0853P)^2^+0.2700P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja512728f_si_006.cif
_cod_data_source_block           bdf240f2
_cod_depositor_comments
'Adding full bibliography for 4123423--4123429.cif.'
_cod_original_cell_volume        1141.24(5)
_cod_database_code               4123428