Electronic effects of substituents on the stability of the iridanaphthalene compound [Ir[upper bond 1 start]Cp*{[double bond, length as m-dash]C(OMe)CH[double bond, length as m-dash]C(o-C[upper bond 1 end]6H4)(Ph)}(PMe3)]PF6.
Talavera, M.; Bravo, J.; Castro, J.; García-Fontán, S; Hermida-Ramón, J M; Bolaño, S; Dalton transactions (Cambridge, England : 2003) 43 (2014) 17366–17374; doi:10.1039/c4dt02744b

data_7032766
_publ_section_title
;
 Electronic effects of substituents on the stability of the
 iridanaphthalene compound [Ir[upper bond 1 start]Cp*{[double bond, length
 as m-dash]C(OMe)CH[double bond, length as m-dash]C(o-C[upper bond 1
 end]6H4)(Ph)}(PMe3)]PF6.
;
_journal_issue                   46
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              17366
_journal_page_last               17374
_journal_paper_doi               10.1039/c4dt02744b
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C29 H36 Ir N O3 P, C24 H20 B, C H2 Cl2'
_chemical_formula_sum            'C54 H58 B Cl2 Ir N O3 P'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
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_cell_angle_gamma                90
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
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_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+26.1479P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments          'Adding full bibliography for 7032766.cif.'
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