Synthesis of Heterodinuclear (Carbene)platinum (or palladium) Complex That Gives μ-Alkenyl-Type Complex by Deprotonation
Tanaka, Shin-ichi; Komine, Nobuyuki; Hirano, Masafumi; Komiya, Sanshiro; Organometallics 28 (2009) 5368–; doi:10.1021/om900421k

data_4069803
_publ_section_title
;
 Synthesis of Heterodinuclear (Carbene)platinum (or palladium) Complex
 That Gives \m-Alkenyl-Type Complex by Deprotonation
;
_journal_issue                   18
_journal_name_full               Organometallics
_journal_page_first              5368
_journal_paper_doi               10.1021/om900421k
_journal_volume                  28
_journal_year                    2009
_chemical_formula_moiety         'C22 H23 Cl Co O5 P Pt '
_chemical_formula_sum            'C22 H23 Cl Co O5 P Pt'
_chemical_formula_weight         687.87
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 108.42(4)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   9.935(4)
_cell_length_b                   26.390(10)
_cell_length_c                   9.775(5)
_cell_measurement_reflns_used    14
_cell_measurement_temperature    200.0
_cell_measurement_theta_max      14.6
_cell_measurement_theta_min      12.7
_cell_volume                     2431.5(19)
_computing_cell_refinement       WinAFC
_computing_data_collection       WinAFC
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.084
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            6716
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 0
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    6.611
_exptl_absorpt_correction_T_max  0.589
_exptl_absorpt_correction_T_min  0.439
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            'light orange'
_exptl_crystal_density_diffrn    1.879
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1328.00
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.67
_refine_diff_density_min         -3.34
_refine_ls_extinction_coef       0.00029(14)
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.924
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     282
_refine_ls_number_reflns         5560
_refine_ls_R_factor_gt           0.0473
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0550P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1462
_reflns_number_gt                2671
_reflns_number_total             5560
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om900421k_si_002.cif
_cod_data_source_block           complex_6
_cod_original_cell_volume        2431.6(19)
_cod_original_formula_sum        'C22 H23 Cl Co O5 P Pt '
_cod_database_code               4069803