A new metal‒metal bonded diruthenium(II,III) compound bridged by the dianionic tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate (5-Clsalpy2−)
Miyasaka, Hitoshi; Kachi-Terajima, Chihiro; Ishii, Tomohiko; Yamashita, Masahiro; Journal of the Chemical Society, Dalton Transactions  (2001) 1929–; doi:10.1039/b103186b

data_7010755
_publ_section_title
;
 A new metal--metal bonded diruthenium(II,III) compound bridged by the
 dianionic tridentate ligand N-(2-pyridyl)-2-oxy-5-chlorobenzylaminate
 (5-Clsalpy2&#x2212;)
;
_journal_issue                   13
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1929
_journal_paper_doi               10.1039/b103186b
_journal_year                    2001
_chemical_formula_sum            'C40 H48 Cl2 N4 Na O9 Ru2'
_chemical_formula_weight         1024.88
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                90.150(2)
_cell_angle_beta                 90.138(2)
_cell_angle_gamma                69.2587(7)
_cell_formula_units_Z            4
_cell_length_a                   15.9459(5)
_cell_length_b                   22.0822(9)
_cell_length_c                   12.7695(5)
_cell_measurement_reflns_used    32927
_cell_measurement_temperature    103.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1.4
_cell_volume                     4205.0(3)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9720
_diffrn_measured_fraction_theta_max 0.9720
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.036
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            37111
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.914
_exptl_absorpt_correction_T_max  0.913
_exptl_absorpt_correction_T_min  0.793
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.619
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.130
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.89
_refine_diff_density_min         -1.24
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.635
_refine_ls_number_parameters     1063
_refine_ls_number_reflns         13473
_refine_ls_R_factor_gt           0.0440
_refine_ls_shift/su_max          0.2892
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1120
_reflns_number_gt                13473
_reflns_number_total             9376
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            b103186b.txt
_cod_data_source_block           B103186B
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C40 H48 Cl2 N4 Na O9 Ru2 '
_cod_database_code               7010755