Porphyrin-based mixed-valent Ag(I)/Ag(II) and Cu(I)/Cu(II) networks as efficient heterogeneous catalysts for the azide-alkyne "click" reaction and promising oxidation of ethylbenzene
Jiang, Wei; Yang, Jin; Liu, Ying-Ying; Ma, Jian-Fang; Chemical Communications (Cambridge, United Kingdom) 52 (2016) 1373–1376; doi:10.1039/c5cc08456c

data_7118454
_publ_section_title
;
 Porphyrin-based mixed-valent Ag(I)/Ag(II) and Cu(I)/Cu(II) networks as
 efficient heterogeneous catalysts for the azide-alkyne "click" reaction
 and promising oxidation of ethylbenzene
;
_journal_coden_ASTM              CHCOFS
_journal_issue                   7
_journal_name_full
;
 Chemical Communications (Cambridge, United Kingdom)
;
_journal_page_first              1373
_journal_page_last               1376
_journal_paper_doi               10.1039/c5cc08456c
_journal_volume                  52
_journal_year                    2016
_chemical_formula_moiety         'C158 H108 Ag4 N42 O6'
_chemical_formula_sum            'C158 H108 Ag4 N42 O6'
_chemical_formula_weight         3122.30
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_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
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;
2015-11-16 deposited with the CCDC.
2015-11-23 downloaded from the CCDC.
;
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_cell_volume                     14077.9(14)
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_computing_data_collection       'CrysAlis (Oxford Diffraction, 2006)'
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
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_diffrn_measurement_device_type  'Oxford Diffraction Gemini R Ultra'
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_exptl_absorpt_process_details
;
CrysAlis (Oxford Diffraction, 2006) 
;
_exptl_crystal_colour            purple
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1149P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_file            c5cc08456c2.cif
_cod_data_source_block           Compound-2
_cod_depositor_comments
'Adding full bibliography for 7118453--7118456.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7118454