Synthesis of Polysubstituted Polycyclic Aromatic Hydrocarbons by Gold-Catalyzed Cyclization–Oxidation of Alkylidenecyclopropane-Containing 1,5-Enynes
Yu, Liu-Zhu; Wei, Yin; Shi, Min; ACS Catalysis 7 (2017) 4242–; doi:10.1021/acscatal.7b00784

data_4514121
_publ_section_title
;
 Synthesis of Polysubstituted Polycyclic Aromatic Hydrocarbons by
 Gold-Catalyzed Cyclization--Oxidation of
 Alkylidenecyclopropane-Containing 1,5-Enynes
;
_journal_issue                   7
_journal_name_full               'ACS Catalysis'
_journal_page_first              4242
_journal_paper_doi               10.1021/acscatal.7b00784
_journal_volume                  7
_journal_year                    2017
_chemical_formula_sum            'C24 H17 Cl O'
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_atom_sites_solution_hydrogens   geom
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_cell_length_c                   11.064(2)
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_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
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_diffrn_reflns_theta_max         26.000
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_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6638
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
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_exptl_crystal_description       prismatic
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_refine_ls_matrix_type           full
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_refine_ls_R_factor_all          0.0764
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0763P)^2^+0.1569P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             3649
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           cd15335
_cod_depositor_comments
'Adding full bibliography for 4514120--4514122.cif.'
_cod_database_code               4514121
_shelx_estimated_absorpt_t_min   0.956
_shelx_estimated_absorpt_t_max   0.973
_shelxl_version_number           2013-4
_shelx_res_checksum              15112
_shelx_hkl_checksum              77199