Synthesis of tri-, tetra-, and pentacarbonyl derivatives via ozonolysis of 1,4-dienes and cyclization to polyaromatic systems.
Kersten, Laura; Harms, Klaus; Hilt, Gerhard; The Journal of organic chemistry 79 (2014) 11661–11673; doi:10.1021/jo502308d

data_4030241
_publ_section_title
;
 Synthesis of tri-, tetra-, and pentacarbonyl derivatives via ozonolysis
 of 1,4-dienes and cyclization to polyaromatic systems.
;
_journal_issue                   23
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              11661
_journal_page_last               11673
_journal_paper_doi               10.1021/jo502308d
_journal_volume                  79
_journal_year                    2014
_chemical_formula_moiety         'C19 H22 O5'
_chemical_formula_sum            'C19 H22 O5'
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_chemical_name_common            lk96624
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_cell_measurement_theta_max      26.9993
_cell_measurement_theta_min      2.5035
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_diffrn_ambient_temperature      230(2)
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker D8 QUEST area detector'
_diffrn_measurement_method       '\w and \f scans'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_T_min  0.98
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_exptl_absorpt_process_details   ' '
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.341
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_exptl_crystal_description       fragment
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_refine_ls_number_reflns         3769
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_refine_ls_R_factor_all          0.0720
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0562P)^2^+0.6040P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             3769
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            jo502308d_si_001.cif
_cod_data_source_block           45
_cod_depositor_comments
'Adding full bibliography for 4030241--4030242.cif.'
_cod_database_code               4030241
_shelx_estimated_absorpt_t_min   0.978
_shelx_estimated_absorpt_t_max   0.994
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_shelx_res_checksum              76411
_shelx_hkl_checksum              44853