Synthesis and Characterization of Terpyridine-Supported Boron Cations: Evidence for Pentacoordination at Boron
Gregory P. McGovern; Di Zhu; Adelia J. A. Aquino; Dragoslav Vidović; Michael Findlater; Inorganic Chemistry 52 (2013) 13865–13868; doi:10.1021/ic401486y

data_4336958
_publ_section_title
;
 Synthesis and Characterization of Terpyridine-Supported Boron Cations:
 Evidence for Pentacoordination at Boron
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              13865
_journal_page_last               13868
_journal_paper_doi               10.1021/ic401486y
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         'C32 H18 B F10 N5, 2(C F3 O3 S), C H2 Cl2'
_chemical_formula_sum            'C35 H20 B Cl2 F16 N5 O6 S2'
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_cell_angle_gamma                91.36(3)
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_cell_length_b                   17.648(4)
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_computing_data_reduction
'DENZO and Scalepack (Otwinoski and Minor, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      153(2)
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_diffrn_measurement_method       '\w scans'
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_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_T_min  0.8929
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'DENZO and Scalepack (Otwinoski and Minor, 1997)'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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