LMucko/crystallography-open-database huggingface dataset:
Synthese eines Titana-Oxacyclohexanringes durch kontrollierte Ringöffnung von Tetrahydrofuran. Kristallstrukturen von [Ti(CH~2~)~4~O{Me~2~Si(NBut)~2~}]~2~, [TiCl{Me~2~Si(NBut)~2~}]~3~(μ~3~-O)(μ~3~-Cl) und [Li~2~(THF)~3~{Me~2~Si(NBut)~2~}]
Mommertz, Andreas; Leo, Roland; Massa, Werner; Harms, Klaus; Dehnicke, Kurt; Zeitschrift fuer Anorganische und Allgemeine Chemie 624 (1998) 1647–1652; doi:10.1002/(sici)1521-3749(199810)624:10<1647::aid-zaac1647>3.0.co;2-4

data_1100574
_publ_section_title
;
 Synthese eines Titana-Oxacyclohexanringes durch kontrollierte Ring\"offnung
 von Tetrahydrofuran. Kristallstrukturen von
 [Ti(CH~2~)~4~O{Me~2~Si(NBut)~2~}]~2~,
 [TiCl{Me~2~Si(NBut)~2~}]~3~(\m~3~-O)(\m~3~-Cl) und
 [Li~2~(THF)~3~{Me~2~Si(NBut)~2~}]
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   10
_journal_name_full
;
 Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_page_first              1647
_journal_page_last               1652
_journal_paper_doi
10.1002/(sici)1521-3749(199810)624:10<1647::aid-zaac1647>3.0.co;2-4
_journal_volume                  624
_journal_year                    1998
_chemical_formula_sum            'C28 H64 N4 O2 Si2 Ti2'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                73.365(19)
_cell_angle_beta                 73.53(2)
_cell_angle_gamma                76.594(17)
_cell_formula_units_Z            1
_cell_length_a                   8.6362(15)
_cell_length_b                   8.957(2)
_cell_length_c                   13.116(2)
_cod_database_code               1100574
Synthese eines Titana-Oxacyclohexanringes durch kontrollierte Ringöffnung von Tetrahydrofuran. Kristallstrukturen von [Ti(CH~2~)~4~O{Me~2~Si(NBut)~2~}]~2~, [TiCl{Me~2~Si(NBut)~2~}]~3~(μ~3~-O)(μ~3~-Cl) und [Li~2~(THF)~3~{Me~2~Si(NBut)~2~}]
Mommertz, Andreas; Leo, Roland; Massa, Werner; Harms, Klaus; Dehnicke, Kurt; Zeitschrift fuer Anorganische und Allgemeine Chemie 624 (1998) 1647–1652; doi:10.1002/(sici)1521-3749(199810)624:10<1647::aid-zaac1647>3.0.co;2-4

data_1100575
_publ_section_title
;
 Synthese eines Titana-Oxacyclohexanringes durch kontrollierte Ring\"offnung
 von Tetrahydrofuran. Kristallstrukturen von
 [Ti(CH~2~)~4~O{Me~2~Si(NBut)~2~}]~2~,
 [TiCl{Me~2~Si(NBut)~2~}]~3~(\m~3~-O)(\m~3~-Cl) und
 [Li~2~(THF)~3~{Me~2~Si(NBut)~2~}]
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   10
_journal_name_full
;
 Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_page_first              1647
_journal_page_last               1652
_journal_paper_doi
10.1002/(sici)1521-3749(199810)624:10<1647::aid-zaac1647>3.0.co;2-4
_journal_volume                  624
_journal_year                    1998
_chemical_formula_sum            'C30 H72 Cl4 N6 O Si3 Ti3'
_space_group_IT_number           8
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'I -2y'
_symmetry_space_group_name_H-M   'I 1 m 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.630(6)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.8627(15)
_cell_length_b                   18.8232(19)
_cell_length_c                   11.5770(9)
_cod_original_sg_symbol_H-M      'I m'
_cod_original_formula_sum        'C30 H72 Cl4 N6 O1 Si3 Ti3'
_cod_database_code               1100575
Synthese eines Titana-Oxacyclohexanringes durch kontrollierte Ringöffnung von Tetrahydrofuran. Kristallstrukturen von [Ti(CH~2~)~4~O{Me~2~Si(NBut)~2~}]~2~, [TiCl{Me~2~Si(NBut)~2~}]~3~(μ~3~-O)(μ~3~-Cl) und [Li~2~(THF)~3~{Me~2~Si(NBut)~2~}]
Mommertz, Andreas; Leo, Roland; Massa, Werner; Harms, Klaus; Dehnicke, Kurt; Zeitschrift fuer Anorganische und Allgemeine Chemie 624 (1998) 1647–1652; doi:10.1002/(sici)1521-3749(199810)624:10<1647::aid-zaac1647>3.0.co;2-4

data_1100576
_publ_section_title
;
 Synthese eines Titana-Oxacyclohexanringes durch kontrollierte Ring\"offnung
 von Tetrahydrofuran. Kristallstrukturen von
 [Ti(CH~2~)~4~O{Me~2~Si(NBut)~2~}]~2~,
 [TiCl{Me~2~Si(NBut)~2~}]~3~(\m~3~-O)(\m~3~-Cl) und
 [Li~2~(THF)~3~{Me~2~Si(NBut)~2~}]
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   10
_journal_name_full
;
 Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_page_first              1647
_journal_page_last               1652
_journal_paper_doi
10.1002/(sici)1521-3749(199810)624:10<1647::aid-zaac1647>3.0.co;2-4
_journal_volume                  624
_journal_year                    1998
_chemical_formula_sum            'C22 H48 Li2 N2 O3 Si'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 95.697(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.5090(8)
_cell_length_b                   15.5891(13)
_cell_length_c                   16.4206(4)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C22 H48 Li2 N2 O3 Si1'
_cod_database_code               1100576
Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb), [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C≡C-Ph)], [Na(THF)~6~][Lu~2~(μ-NH~2~)(μ-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als Polymerisationskatalysatoren
Karl, M.; Seybert, G.; Massa, W.; Harms, K.; Agarwal, S.; Maleika, R.; Stelter, W.; Greiner, A.; Neumüller, W.; Heitz, B.; Dehnicke, K.; Zeitschrift für anorganische und allgemeine Chemie 625 (1999) 1301–1309; doi:10.1002/(sici)1521-3749(199908)625:8<1301::aid-zaac1301>3.0.co;2-0

data_1100577
_publ_section_title
;
 Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen
 von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb),
 [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C\\tb C-Ph)],
 [Na(THF)~6~][Lu~2~(\m-NH~2~)(\m-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie
 von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als
 Polymerisationskatalysatoren
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   8
_journal_name_full
;
 Zeitschrift f\"ur anorganische und allgemeine Chemie
;
_journal_page_first              1301
_journal_page_last               1309
_journal_paper_doi
10.1002/(sici)1521-3749(199908)625:8<1301::aid-zaac1301>3.0.co;2-0
_journal_volume                  625
_journal_year                    1999
_chemical_formula_sum            'C37 H95 N3 Na O9 Si7 Sm'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-I 2ya'
_symmetry_space_group_name_H-M   'I 1 2/a 1'
_cell_angle_alpha                90
_cell_angle_beta                 94.925(15)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   22.753(2)
_cell_length_b                   22.2736(14)
_cell_length_c                   23.844(2)
_cod_original_sg_symbol_H-M      'I 2/a'
_cod_original_formula_sum        'C37 H95 N3 Na1 O9 Si7 Sm1'
_cod_database_code               1100577
Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb), [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C≡C-Ph)], [Na(THF)~6~][Lu~2~(μ-NH~2~)(μ-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als Polymerisationskatalysatoren
Karl, M.; Seybert, G.; Massa, W.; Harms, K.; Agarwal, S.; Maleika, R.; Stelter, W.; Greiner, A.; Neumüller, W.; Heitz, B.; Dehnicke, K.; Zeitschrift für anorganische und allgemeine Chemie 625 (1999) 1301–1309; doi:10.1002/(sici)1521-3749(199908)625:8<1301::aid-zaac1301>3.0.co;2-0

data_1100578
_publ_section_title
;
 Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen
 von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb),
 [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C\\tb C-Ph)],
 [Na(THF)~6~][Lu~2~(\m-NH~2~)(\m-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie
 von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als
 Polymerisationskatalysatoren
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   8
_journal_name_full
;
 Zeitschrift f\"ur anorganische und allgemeine Chemie
;
_journal_page_first              1301
_journal_page_last               1309
_journal_paper_doi
10.1002/(sici)1521-3749(199908)625:8<1301::aid-zaac1301>3.0.co;2-0
_journal_volume                  625
_journal_year                    1999
_chemical_formula_sum            'C37 H95 N3 Na O9 Si7 Yb'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-I 2ya'
_symmetry_space_group_name_H-M   'I 1 2/a 1'
_cell_angle_alpha                90
_cell_angle_beta                 95.441(8)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   22.4160(16)
_cell_length_b                   22.2972(15)
_cell_length_c                   23.7339(13)
_cod_original_sg_symbol_H-M      'I 2/a'
_cod_original_formula_sum        'C37 H95 N3 Na1 O9 Si7 Yb1'
_cod_database_code               1100578
Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb), [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C≡C-Ph)], [Na(THF)~6~][Lu~2~(μ-NH~2~)(μ-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als Polymerisationskatalysatoren
Karl, M.; Seybert, G.; Massa, W.; Harms, K.; Agarwal, S.; Maleika, R.; Stelter, W.; Greiner, A.; Neumüller, W.; Heitz, B.; Dehnicke, K.; Zeitschrift für anorganische und allgemeine Chemie 625 (1999) 1301–1309; doi:10.1002/(sici)1521-3749(199908)625:8<1301::aid-zaac1301>3.0.co;2-0

data_1100579
_publ_section_title
;
 Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen
 von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb),
 [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C\\tb C-Ph)],
 [Na(THF)~6~][Lu~2~(\m-NH~2~)(\m-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie
 von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als
 Polymerisationskatalysatoren
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   8
_journal_name_full
;
 Zeitschrift f\"ur anorganische und allgemeine Chemie
;
_journal_page_first              1301
_journal_page_last               1309
_journal_paper_doi
10.1002/(sici)1521-3749(199908)625:8<1301::aid-zaac1301>3.0.co;2-0
_journal_volume                  625
_journal_year                    1999
_chemical_formula_sum            'C38 H83 N3 Na O3 Si6 Sm'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.549(9)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.4447(10)
_cell_length_b                   23.2529(14)
_cell_length_c                   17.3216(14)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C38 H83 N3 Na1 O3 Si6 Sm1'
_cod_database_code               1100579
Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb), [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C≡C-Ph)], [Na(THF)~6~][Lu~2~(μ-NH~2~)(μ-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als Polymerisationskatalysatoren
Karl, M.; Seybert, G.; Massa, W.; Harms, K.; Agarwal, S.; Maleika, R.; Stelter, W.; Greiner, A.; Neumüller, W.; Heitz, B.; Dehnicke, K.; Zeitschrift für anorganische und allgemeine Chemie 625 (1999) 1301–1309; doi:10.1002/(sici)1521-3749(199908)625:8<1301::aid-zaac1301>3.0.co;2-0

data_1100580
_publ_section_title
;
 Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen
 von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb),
 [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C\\tb C-Ph)],
 [Na(THF)~6~][Lu~2~(\m-NH~2~)(\m-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie
 von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als
 Polymerisationskatalysatoren
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   8
_journal_name_full
;
 Zeitschrift f\"ur anorganische und allgemeine Chemie
;
_journal_page_first              1301
_journal_page_last               1309
_journal_paper_doi
10.1002/(sici)1521-3749(199908)625:8<1301::aid-zaac1301>3.0.co;2-0
_journal_volume                  625
_journal_year                    1999
_chemical_formula_sum            'C51 H131 Lu2 N6 Na O6 Si9'
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.423(2)
_cell_length_b                   19.946(4)
_cell_length_c                   26.039(6)
_cod_original_formula_sum        'C51 H131 Lu2 N6 Na1 O6 Si9'
_cod_database_code               1100580
Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb), [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C≡C-Ph)], [Na(THF)~6~][Lu~2~(μ-NH~2~)(μ-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als Polymerisationskatalysatoren
Karl, M.; Seybert, G.; Massa, W.; Harms, K.; Agarwal, S.; Maleika, R.; Stelter, W.; Greiner, A.; Neumüller, W.; Heitz, B.; Dehnicke, K.; Zeitschrift für anorganische und allgemeine Chemie 625 (1999) 1301–1309; doi:10.1002/(sici)1521-3749(199908)625:8<1301::aid-zaac1301>3.0.co;2-0

data_1100581
_publ_section_title
;
 Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen
 von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb),
 [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C\\tb C-Ph)],
 [Na(THF)~6~][Lu~2~(\m-NH~2~)(\m-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie
 von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als
 Polymerisationskatalysatoren
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   8
_journal_name_full
;
 Zeitschrift f\"ur anorganische und allgemeine Chemie
;
_journal_page_first              1301
_journal_page_last               1309
_journal_paper_doi
10.1002/(sici)1521-3749(199908)625:8<1301::aid-zaac1301>3.0.co;2-0
_journal_volume                  625
_journal_year                    1999
_chemical_formula_sum            'C20 H52 N2 Na2 O2 Si4'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                110.03(1)
_cell_angle_beta                 112.91(1)
_cell_angle_gamma                96.80(1)
_cell_formula_units_Z            1
_cell_length_a                   9.030(1)
_cell_length_b                   10.465(1)
_cell_length_c                   10.558(1)
_cod_database_code               1100581
Cycloadducts from highly functionalized nitrones and oximes as ligands in the enantioselective addition of diethylzinc to benzaldehyde
Baskaran, Subramanian; Aurich, Hans Günter; Biesemeier, Frank; Harms, Klaus; Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999)  (1998) 3717–3724; doi:10.1039/a806744i

data_1100582
_publ_section_title
;
 Cycloadducts from highly functionalized nitrones and oximes as ligands in
 the enantioselective addition of diethylzinc to benzaldehyde
;
_journal_coden_ASTM              JCPRB4
_journal_issue                   22
_journal_name_full
;
 Journal of the Chemical Society, Perkin Transactions 1:
 Organic and Bio-Organic Chemistry (1972-1999)
;
_journal_page_first              3717
_journal_page_last               3724
_journal_paper_doi               10.1039/a806744i
_journal_year                    1998
_chemical_formula_sum            'C26 H34 N2 O7'
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'I 2y'
_symmetry_space_group_name_H-M   'I 1 2 1'
_cell_angle_alpha                90
_cell_angle_beta                 91.674(10)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   11.444(1)
_cell_length_b                   6.006(1)
_cell_length_c                   18.591(1)
_cod_original_sg_symbol_H-M      'I 2'
_cod_database_code               1100582
Cycloadducts from highly functionalized nitrones and oximes as ligands in the enantioselective addition of diethylzinc to benzaldehyde
Baskaran, Subramanian; Aurich, Hans Günter; Biesemeier, Frank; Harms, Klaus; Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999)  (1998) 3717–3724; doi:10.1039/a806744i

data_1100583
_publ_section_title
;
 Cycloadducts from highly functionalized nitrones and oximes as ligands in
 the enantioselective addition of diethylzinc to benzaldehyde
;
_journal_coden_ASTM              JCPRB4
_journal_issue                   22
_journal_name_full
;
 Journal of the Chemical Society, Perkin Transactions 1:
 Organic and Bio-Organic Chemistry (1972-1999)
;
_journal_page_first              3717
_journal_page_last               3724
_journal_paper_doi               10.1039/a806744i
_journal_year                    1998
_chemical_formula_sum            'C10 H16 N2 O4'
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.968(1)
_cell_length_b                   8.448(1)
_cell_length_c                   21.719(1)
_cod_database_code               1100583
Diastereoselective photocycloaddition of an axial chiral enamide
Bach, Thorsten; Schröder, Jürgen; Harms, Klaus; Tetrahedron Letters 40 (1999) 9003–9004; doi:10.1016/s0040-4039(99)01933-4

data_1100585
_publ_section_title
;
 Diastereoselective photocycloaddition of an axial chiral enamide
;
_journal_coden_ASTM              TELEAY
_journal_issue                   51
_journal_name_full               'Tetrahedron Letters'
_journal_page_first              9003
_journal_page_last               9004
_journal_paper_doi               10.1016/s0040-4039(99)01933-4
_journal_volume                  40
_journal_year                    1999
_chemical_formula_sum            'C21 H25 N O2'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 101.617(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.5303(4)
_cell_length_b                   11.7446(8)
_cell_length_c                   14.8819(6)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C21 H25 N1 O2'
_cod_database_code               1100585
Die Kristallstrukturen der Triarylzinkate [Mg~2~Br~3~(THF)~6~][ZnPh~3~] und [MgBr(THF)~5~][ZnMes~3~]
Krieger, Matthias; Geiseler, Gertraud; Harms, Klaus; Merle, Jan; Massa, Werner; Dehnicke, Kurt; Zeitschrift fuer Anorganische und Allgemeine Chemie 624 (1998) 1387–1388; doi:10.1002/(sici)1521-3749(199809)624:9<1387::aid-zaac1387>3.0.co;2-m

data_1100586
_publ_section_title
;
 Die Kristallstrukturen der Triarylzinkate
 [Mg~2~Br~3~(THF)~6~][ZnPh~3~] und [MgBr(THF)~5~][ZnMes~3~]
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   9
_journal_name_full
;
 Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_page_first              1387
_journal_page_last               1388
_journal_paper_doi
10.1002/(sici)1521-3749(199809)624:9<1387::aid-zaac1387>3.0.co;2-m
_journal_volume                  624
_journal_year                    1998
_chemical_formula_sum            'C49 H71 Br3 Mg2 O6 Zn'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 100.33(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   18.388(7)
_cell_length_b                   15.367(3)
_cell_length_c                   18.609(5)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C49 H71 Br3 Mg2 O6 Zn1'
_cod_database_code               1100586
Die Kristallstrukturen der Triarylzinkate [Mg~2~Br~3~(THF)~6~][ZnPh~3~] und [MgBr(THF)~5~][ZnMes~3~]
Krieger, Matthias; Geiseler, Gertraud; Harms, Klaus; Merle, Jan; Massa, Werner; Dehnicke, Kurt; Zeitschrift fuer Anorganische und Allgemeine Chemie 624 (1998) 1387–1388; doi:10.1002/(sici)1521-3749(199809)624:9<1387::aid-zaac1387>3.0.co;2-m

data_1100587
_publ_section_title
;
 Die Kristallstrukturen der Triarylzinkate
 [Mg~2~Br~3~(THF)~6~][ZnPh~3~] und [MgBr(THF)~5~][ZnMes~3~]
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   9
_journal_name_full
;
 Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_page_first              1387
_journal_page_last               1388
_journal_paper_doi
10.1002/(sici)1521-3749(199809)624:9<1387::aid-zaac1387>3.0.co;2-m
_journal_volume                  624
_journal_year                    1998
_chemical_formula_sum            'C47 H73 Br Mg O5 Zn'
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   19.8876(10)
_cell_length_b                   20.0341(10)
_cell_length_c                   23.7074(10)
_cod_original_formula_sum        'C47 H73 Br1 Mg1 O5 Zn1'
_cod_database_code               1100587
Chiral organometallic reagents. Part XXIII. On the stereochemistry of the carbolithiation reaction of vinyl sulfides
Hoffmann, Reinhard W.; Koberstein, Ralf; Harms, Klaus; Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999)  (1999) 183–192; doi:10.1039/a808116f

data_1100588
_publ_section_title
;
 Chiral organometallic reagents. Part XXIII. On the stereochemistry of the
 carbolithiation reaction of vinyl sulfides
;
_journal_coden_ASTM              JCPKBH
_journal_issue                   2
_journal_name_full
;
 Journal of the Chemical Society, Perkin Transactions 2:
 Physical Organic Chemistry (1972-1999)
;
_journal_page_first              183
_journal_page_last               192
_journal_paper_doi               10.1039/a808116f
_journal_year                    1999
_chemical_formula_sum            'C26 H38 S Sn'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 90.768(11)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   10.667(2)
_cell_length_b                   29.670(4)
_cell_length_c                   15.9184(19)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C26 H38 S1 Sn1'
_cod_database_code               1100588