Shedding light on an ultra-bright photoluminescent lamellar gold thiolate coordination polymer [Au(p-SPhCO2Me)]n.
Lavenn, Christophe; Guillou, Nathalie; Monge, Miguel; Podbevšek, Darjan; Ledoux, Gilles; Fateeva, Alexandra; Demessence, Aude; Chemical communications (Cambridge, England) 52 (2016) 9063–9066; doi:10.1039/c5cc10448c

data_7118775
_publ_section_title
;
 Shedding light on an ultra-bright photoluminescent lamellar gold thiolate
 coordination polymer [Au(p-SPhCO2Me)]n.
;
_journal_issue                   58
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              9063
_journal_page_last               9066
_journal_paper_doi               10.1039/c5cc10448c
_journal_volume                  52
_journal_year                    2016
_chemical_formula_sum            'C8 H7 Au O2 S'
_chemical_formula_weight         364.18
_chemical_name_systematic        (AuSPhCO2Me)n
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_audit_update_record
;
2015-12-10 deposited with the CCDC.
2016-02-18 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   37.4027(12)
_cell_length_b                   7.01569(12)
_cell_length_c                   6.36593(10)
_cell_measurement_temperature    293
_cell_volume                     1670.46(7)
_computing_molecular_graphics    DIAMOND
_computing_structure_refinement  TOPAS
_computing_structure_solution    TOPAS
_diffrn_ambient_temperature      293
_diffrn_measurement_device_type  'Bruker D8 Advance diffractometer'
_diffrn_radiation_monochromator  'Ge(111) monochromator'
_diffrn_radiation_type           'CuKa1 radiation'
_diffrn_radiation_wavelength     1.5406
_diffrn_source                   'X-ray sealed tube'
_exptl_crystal_colour            Colourless
_exptl_crystal_description       powder
_exptl_crystal_preparation       Luminescent
_pd_meas_2theta_range_inc        0.010119
_pd_meas_2theta_range_max        100.00
_pd_meas_2theta_range_min        2.500
_pd_proc_2theta_range_inc        0.010
_pd_proc_2theta_range_max        100.000
_pd_proc_2theta_range_min        3.000
_pd_proc_ls_background_function  'Chebychev polynomial'
_pd_proc_ls_profile_function
'modified Thompson-Cox-Hastings pseudo-Voigt '
_pd_proc_ls_prof_R_factor        0.056
_pd_proc_ls_prof_wR_factor       0.076
_pd_spec_mounting                'glass capillary'
_pd_spec_mount_mode              transmission
_pd_spec_shape                   cylinder
_refine_ls_goodness_of_fit_all   6.41
_refine_ls_number_reflns         877
_refine_ls_number_restraints     3
_refine_ls_R_I_factor            0.038
_cod_data_source_file            c5cc10448c2.cif
_cod_data_source_block           Au-SPhCO2Me
_cod_depositor_comments
'Adding full bibliography for 7118775--7118776.cif.'
_cod_original_cell_volume        1670.454(67)
_cod_original_sg_symbol_H-M      Pbca
_cod_database_code               7118775
_refine_ls_number_structural_parameters 21
_refine_ls_number_profile_parameters 24