Formation of trans(N)-bis(amino acidato)(2,2′-bipyridine)cobalt(III) complexes following the UV irradiation of amino acidatobis(2,2′bipyridine)cobalt(III) complexes in dimethyl sulfoxide
Hartshorn, Richard M.; Telfer, Shane G.; Journal of the Chemical Society, Dalton Transactions  (1999) 3217–; doi:10.1039/a904486h

data_7027591
_publ_section_title
;
 Formation of trans(N)-bis(amino
 acidato)(2,2&#x2032;-bipyridine)cobalt(III) complexes following the UV
 irradiation of amino acidatobis(2,2&#x2032;bipyridine)cobalt(III)
 complexes in dimethyl sulfoxide
;
_journal_issue                   18
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              3217
_journal_paper_doi               10.1039/a904486h
_journal_year                    1999
_chemical_formula_sum            'C16 H22 Cl Co N4 O9'
_chemical_formula_weight         508.76
_chemical_name_systematic
;
trans(N)-bis(alaninato)(2,2'-bipyridine)cobalt(III) perchlorate monohydrate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.06(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.556(7)
_cell_length_b                   10.345(7)
_cell_length_c                   18.62(3)
_cell_measurement_reflns_used    27
_cell_measurement_temperature    144(2)
_cell_volume                     2008(4)
_computing_cell_refinement       XSCAnS
_computing_data_collection       XSCAnS
_computing_data_reduction        XSCAnS
_computing_molecular_graphics    xp
_computing_publication_material  xcif
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      144(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Siemens P4 four circle'
_diffrn_measurement_method       'Omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0902
_diffrn_reflns_av_sigmaI/netI    0.0910
_diffrn_reflns_limit_h_max       2
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            3872
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.22
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.047
_exptl_absorpt_correction_T_max  0.8179
_exptl_absorpt_correction_T_min  0.5277
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'psi scans'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.683
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1048
_exptl_crystal_size_max          0.70
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.749
_refine_diff_density_min         -0.637
_refine_diff_density_rms         0.096
_refine_ls_extinction_coef       9999
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     294
_refine_ls_number_reflns         3531
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.1134
_refine_ls_R_factor_gt           0.0595
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0496P)^2^+2.2925P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1116
_refine_ls_wR_factor_ref         0.1300
_reflns_number_gt                2250
_reflns_number_total             3531
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            904486Hsup1.cif
_cod_data_source_block           stala
_cod_original_cell_volume        2008(3)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7027591
_cell_measurement_2theta_min     5.745
_cell_measurement_2theta_max     27.937