Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides.
Böserle, Jiří; Zhigulin, Grigory; Ketkov, Sergey; Jambor, Roman; RůŽička, Aleš; Dostál, Libor; Dalton transactions (Cambridge, England : 2003) 47 (2018) 14880–14883; doi:10.1039/c8dt03357a

data_7047664
_publ_section_title
;
 Diverse reactivity of a boraguanidinato germylene toward organic
 pseudohalides.
;
_journal_issue                   42
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14880
_journal_page_last               14883
_journal_paper_doi               10.1039/c8dt03357a
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C66 H96 B3 Ge3 N9 S, 0.5(C6 H14)'
_chemical_formula_sum            'C69 H103 B3 Ge3 N9 S'
_chemical_formula_weight         1340.86
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_audit_update_record
;
2018-08-06 deposited with the CCDC.
2018-09-27 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_computing_molecular_graphics    'Platon (Spek, 2009)'
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_diffrn_ambient_temperature      150(2)
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker D8 - Venture'
_diffrn_measurement_method       '\f and \w scans to fill the Ewald sphere'
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_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_exptl_absorpt_process_details
;
SADABS-2016/2 - Bruker AXS area detector
scaling and absorption correction
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0373P)^2^+4.2067P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7047661--7047664.cif.'
_cod_database_code               7047664
_exptl_absorpt_special_details
;
The ratio of minimum to maximum
apparent transmission was 0.793
;
_shelxl_version_number           2013-4
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