Sequential Synthesis of 3d-3d'-4f Heterometallic Heptanuclear Clusters in between Lacunary Polyoxometalates.
Sato, Rinta; Suzuki, Kosuke; Minato, Takuo; Yamaguchi, Kazuya; Mizuno, Noritaka; Inorganic chemistry 55 (2016) 2023–2029; doi:10.1021/acs.inorgchem.5b02358

data_4346916
_publ_section_title
;
 Sequential Synthesis of 3d-3d'-4f Heterometallic Heptanuclear Clusters in
 between Lacunary Polyoxometalates.
;
_journal_issue                   5
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2023
_journal_page_last               2029
_journal_paper_doi               10.1021/acs.inorgchem.5b02358
_journal_volume                  55
_journal_year                    2016
_chemical_formula_sum            'C140 Fe Gd2 Mn4 N11 O82 Si2 W18'
_chemical_formula_weight         7103.10
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   none
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 112.5396(9)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   30.3095(5)
_cell_length_b                   23.7850(4)
_cell_length_c                   33.7132(6)
_cell_measurement_reflns_used    29563
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      29.53
_cell_measurement_theta_min      1.12
_cell_volume                     22447.7(7)
_computing_cell_refinement       HKL2000
_computing_data_collection       'Rigaku CrystalClear'
_computing_data_reduction        HKL2000
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      113(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_device_type  CCD
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_unetI/netI     0.0495
_diffrn_reflns_Laue_measured_fraction_full 0.986
_diffrn_reflns_Laue_measured_fraction_max 0.972
_diffrn_reflns_number            30528
_diffrn_reflns_point_group_measured_fraction_full 0.986
_diffrn_reflns_point_group_measured_fraction_max 0.972
_diffrn_reflns_theta_full        25.240
_diffrn_reflns_theta_max         29.535
_diffrn_reflns_theta_min         1.123
_exptl_absorpt_coefficient_mu    10.123
_exptl_absorpt_correction_T_max  0.489
_exptl_absorpt_correction_T_min  0.200
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'HKL2000 DENZO SCALEPACK'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.102
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             12748
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.080
_platon_squeeze_details
;
;
_refine_diff_density_max         3.493
_refine_diff_density_min         -3.644
_refine_diff_density_rms         0.678
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     784
_refine_ls_number_reflns         30522
_refine_ls_number_restraints     68
_refine_ls_restrained_S_all      1.090
_refine_ls_R_factor_all          0.1337
_refine_ls_R_factor_gt           0.1005
_refine_ls_shift/su_max          0.012
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1751P)^2^+487.5007P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2872
_refine_ls_wR_factor_ref         0.3123
_reflns_Friedel_coverage         0.000
_reflns_number_gt                20046
_reflns_number_total             30522
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ic5b02358_si_002.cif
_cod_data_source_block           FeMn4Gd2
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4346916
_shelx_estimated_absorpt_t_min   0.431
_shelx_estimated_absorpt_t_max   0.498
_shelxl_version_number           2013-3
_shelx_res_checksum              70286
_shelx_hkl_checksum              34580