A dipyrromethane-based diphosphane-germylene as precursor to tetrahedral copper(i) and T-shaped silver(i) and gold(i) PGeP pincer complexes.
Cabeza, Javier A.; Fernández, Israel; García-Álvarez, Pablo; Laglera-Gándara, Carlos J; Dalton transactions (Cambridge, England : 2003) 48 (2019) 13273–13280; doi:10.1039/c9dt03045j

data_7700693
_publ_section_title
;
 A dipyrromethane-based diphosphane-germylene as precursor to tetrahedral
 copper(i) and T-shaped silver(i) and gold(i) PGeP pincer complexes.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13273
_journal_page_last               13280
_journal_paper_doi               10.1039/c9dt03045j
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C25 H42 Ge N2 P2'
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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;
2019-07-02 deposited with the CCDC.    2019-07-30 downloaded from the CCDC.
;
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'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
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'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
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'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
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'MERCURY (Cambridge Crystallographic Data Centre: Cambridge, UK, 2019)'
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_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device_type  'Xcalibur, Onyx, Nova'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0467P)^2^+0.8339P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7700693--7700696.cif.'
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