Highly Stereo- and Regioselective Ni-Catalyzed Homoallylation of Aldimines with Conjugated Dienes Promoted by Diethylzinc
Masanari Kimura; Atsuko Miyachi; Keisuke Kojima; Shuji Tanaka; Yoshinao Tamaru; Journal of the American Chemical Society 126 (2004) 14360–14361; doi:10.1021/ja0450354

data_4113137
_publ_section_title
;
 Highly Stereo- and Regioselective Ni-Catalyzed Homoallylation of
 Aldimines with Conjugated Dienes Promoted by Diethylzinc
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              14360
_journal_page_last               14361
_journal_paper_doi               10.1021/ja0450354
_journal_volume                  126
_journal_year                    2004
_chemical_formula_moiety         'C25 H25 N3 O7 '
_chemical_formula_sum            'C25 H25 N3 O7'
_chemical_formula_weight         479.49
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
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_cell_angle_beta                 100.568(3)
_cell_angle_gamma                109.558(2)
_cell_formula_units_Z            2
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_cell_length_b                   10.749(1)
_cell_length_c                   13.384(2)
_cell_measurement_temperature    297.2
_cell_volume                     1212.9(2)
_computing_cell_refinement       D*TREK
_computing_data_collection       D*TREK
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
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_diffrn_measured_fraction_theta_max 0.9077
_diffrn_measurement_device_type  'Quantum CCD/Rigaku AFC7'
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_diffrn_reflns_limit_l_max       15
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Jacobson, 1998)'
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_refine_diff_density_min         -0.47
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_refine_ls_R_factor_gt           0.0612
_refine_ls_shift/su_max          0.0001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     F^2^>2.0\s(F^2^)
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_cod_original_formula_sum        'C25 H25 N3 O7 '
_cod_database_code               4113137