Magnetic anisotropy in square pyramidal cobalt(II) complexes supported by a tetraazo macrocyclic ligand.
Cui, Hui-Hui; Ding, Man-Man; Zhang, Xiu-Du; Lv, Wei; Zhang, Yi-Quan; Chen, Xue-Tai; Wang, Zhenxing; Ouyang, Zhong-Wen; Xue, Zi-Ling; Dalton transactions (Cambridge, England : 2003) 49 (2020) 14837–14846; doi:10.1039/d0dt01954b

data_7705667
_publ_section_title
;
 Magnetic anisotropy in square pyramidal cobalt(II) complexes supported by
 a tetraazo macrocyclic ligand.
;
_journal_issue                   42
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14837
_journal_page_last               14846
_journal_paper_doi               10.1039/d0dt01954b
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C36 H48 B Br Co N4'
_chemical_formula_weight         686.43
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/6
_audit_update_record
;
2018-03-03 deposited with the CCDC.	2020-09-17 downloaded from the CCDC.
;
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_cell_length_c                   31.079(2)
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_cell_measurement_temperature    155(2)
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_diffrn_ambient_temperature      155(2)
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
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_exptl_absorpt_correction_T_min  0.5487
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            blue
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0909P)^2^+12.0429P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7705666--7705667.cif.'
_cod_original_cell_volume        6821.6(9)
_cod_original_sg_symbol_H-M      'P 21/c'
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