Solid-to-Solid Oxidation of a Vanadium(IV) to a Vanadium(V) Compound: Chemisty of a Sulfur-Containing Siderophore
Pabitra B. Chatterjee; Debbie C. Crans; Inorganic Chemistry 51 (2012) 9144–9146; doi:10.1021/ic301026b

data_4330174
_publ_section_title
;
 Solid-to-Solid Oxidation of a Vanadium(IV) to a Vanadium(V) Compound:
 Chemisty of a Sulfur-Containing Siderophore
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9144
_journal_page_last               9146
_journal_paper_doi               10.1021/ic301026b
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C17 H11 N3 O3 S2 V'
_chemical_formula_weight         420.35
_chemical_name_systematic
; 
 ? 
;
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_cell_length_b                   8.5662(8)
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_cell_measurement_temperature    120(2)
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_cell_measurement_theta_min      2.74
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_computing_cell_refinement       'Bruker APEX2 (Bruker, 2009)'
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_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
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_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_k_max       10
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_diffrn_reflns_theta_max         24.81
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_exptl_absorpt_correction_T_max  0.9801
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SCALE (Bruker, 2009)'
_exptl_crystal_colour            brown
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         2795
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_refine_ls_R_factor_all          0.1005
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0568P)^2^+3.4681P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1085
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic301026b_si_002.cif
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_cod_original_cell_volume        1654.4(3)
_cod_database_code               4330174