Accelerating Ethylene Polymerization Using Secondary Metal Ions in Tetrahydrofuran
Xiao, Dawei; Cai, Zhongzheng; Do, Loi; Dalton Transactions  (2019) –; doi:10.1039/C9DT04288A

data_7701996
_publ_section_title
;
 Accelerating Ethylene Polymerization Using Secondary Metal Ions in
 Tetrahydrofuran
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/C9DT04288A
_journal_year                    2019
_chemical_formula_sum            'C35 H45 F12 Na Ni O11 P2 Sb2'
_chemical_formula_weight         1256.85
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2019-09-09 deposited with the CCDC.	2019-11-22 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_cell_length_c                   29.875(2)
_cell_measurement_reflns_used    9889
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      27.51
_cell_measurement_theta_min      2.25
_cell_volume                     9636.7(12)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0226
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_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       33
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_exptl_absorpt_correction_T_max  0.7456
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_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
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_exptl_crystal_description       block
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_exptl_crystal_size_min          0.10
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_refine_diff_density_rms         0.177
_refine_ls_extinction_method     none
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_refine_ls_number_reflns         10926
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_refine_ls_R_factor_all          0.0741
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0987P)^2^+79.5237P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1547
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_reflns_Friedel_coverage         0.000
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_reflns_number_total             10926
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           4bNa
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_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              25053