Crystal Structures and Luminescence Properties of Platinum(II) Complexes Containing 3,3'-Biisoquinoline
Masako Kato; Kumiko Sasano; Chizuko Kosuge; Mikio Yamazaki; Shigenobu Yano; Masaru Kimura; Inorganic Chemistry 35 (1996) 116–123; doi:10.1021/ic9507124

data_4323771
_publ_contact_author
;
    Dr Masako Kato
    Department of Chemistry
    Faculty of Science
    Nara Women's University
    Nara 630
    Japan
;
_publ_contact_author_email       kato@cc.nara-wu.ac.jp
_publ_contact_author_fax         81-742-20-3393
_publ_contact_author_phone       81-742-20-3393
_publ_section_title
;
 Crystal Structures and Luminescence Properties of Platinum(II) Complexes
 Containing 3,3'-Biisoquinoline
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              116
_journal_page_last               123
_journal_paper_doi               10.1021/ic9507124
_journal_volume                  35
_journal_year                    1996
_chemical_formula_sum            'C20 H13 N4 O0.5 Pt'
_space_group_IT_number           57
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      57
_symmetry_space_group_name_Hall  '-P 2c 2b'
_symmetry_space_group_name_H-M   'P b c m'
_audit_creation_date             'Thu May 18 14:30:00 1995'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4.00
_cell_length_a                   13.989(2)
_cell_length_b                   18.304(1)
_cell_length_c                   6.682(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    20.0
_cell_measurement_theta_max      29.68
_cell_measurement_theta_min      25.31
_cell_volume                     1711.0(8)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_computing_structure_solution    MITHRIL90
_diffrn_ambient_temperature      20.0
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
_diffrn_orient_matrix_UB_11      -0.01800
_diffrn_orient_matrix_UB_12      -0.05166
_diffrn_orient_matrix_UB_13      -0.03080
_diffrn_orient_matrix_UB_21      0.06175
_diffrn_orient_matrix_UB_22      -0.01725
_diffrn_orient_matrix_UB_23      0.05877
_diffrn_orient_matrix_UB_31      -0.03119
_diffrn_orient_matrix_UB_32      -0.00430
_diffrn_orient_matrix_UB_33      0.13415
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoKalpha
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_diffrn_reflns_limit_h_min       -18
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_diffrn_reflns_number            2289
_diffrn_reflns_theta_max         27.4845
_diffrn_standards_decay_%        0.68
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu_cm 81.810
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.411
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            orange
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_exptl_crystal_density_meas      1.99
_exptl_crystal_description       plate
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_refine_ls_extinction_coef       0.00000
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         970
_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0390
_refine_ls_shift/esd_max         0.2280
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0340
_cod_data_source_file            ic9507124_1.cif
_cod_data_source_block           '[Pt(CN)2(i-biq)].0.5H2O'
_cod_original_cell_volume        1710.9(6)
_cod_original_sg_symbol_H-M      'P b c m '
_cod_original_formula_sum        'Pt O0.5 N4 C20 H13'
_cod_database_code               4323771