Synthesis of a Vanadium(III) Tris(arylthiolato) Complex and Its Reactions with Azide and Azo Compounds: Formation of a Sulfenamide Complex via Cleavage of an Azo NN Bond
Komuro, Takashi; Matsuo, Tsukasa; Kawaguchi, Hiroyuki; Tatsumi, Kazuyuki; Inorganic Chemistry 44 (2005) 175–177; doi:10.1021/ic048721c

data_4308375
_publ_section_title
;
 Synthesis of a Vanadium(III) Tris(arylthiolato) Complex and Its Reactions
 with Azide and Azo Compounds: Formation of a Sulfenamide Complex via
 Cleavage of an Azo NN Bond
;
_journal_coden_ASTM              INOCAJ
_journal_issue                   2
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              175
_journal_page_last               177
_journal_paper_doi               10.1021/ic048721c
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C46 H78 N S3 Si6 V '
_chemical_formula_sum            'C46 H78 N S3 Si6 V'
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_symmetry_cell_setting           monoclinic
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_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_audit_creation_method           'by CrystalStructure v3.5.1'
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_cell_angle_beta                 99.814(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.295(3)
_cell_length_b                   16.438(4)
_cell_length_c                   27.386(7)
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_cell_measurement_temperature    173.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     5454(2)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
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_diffrn_measured_fraction_theta_full 0.9945
_diffrn_measured_fraction_theta_max 0.9961
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
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_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            dark-red
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_exptl_crystal_size_max          0.13
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'w = 1/[0.0028Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
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_cod_original_cell_volume        5454.0(25)
_cod_original_formula_sum        'C46 H78 N S3 Si6 V '
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