Merging of the photocatalyst decatungstate and naphthalene diimide in a hybrid structure for the oxidative coupling of amines
Liu, Zhengfen; Li, Xiaobo; Chen, Jian; Li, Chao; Luo, Fumang; Cheng, Fei-Xiang; Liu, Jian-Jun; Dalton Transactions  (2022) –; doi:10.1039/D2DT01003H

data_7710304
_publ_section_title
;
 Merging of the photocatalyst decatungstate and naphthalene diimide in a
 hybrid structure for the oxidative coupling of amines
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT01003H
_journal_year                    2022
_chemical_formula_moiety         'C24 H33 N5 O21 W5 Zn'
_chemical_formula_sum            'C24 H33 N5 O21 W5 Zn'
_chemical_formula_weight         1712.17
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2022-02-03 deposited with the CCDC.	2022-05-12 downloaded from the CCDC.
;
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
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_diffrn_measured_fraction_theta_max 0.964
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
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_diffrn_reflns_theta_max         24.712
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_exptl_absorpt_coefficient_mu    13.454
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.56075
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2004)'
_exptl_crystal_colour            yellow
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_exptl_crystal_description       block
_exptl_crystal_F_000             1560
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_exptl_crystal_size_mid          0.15
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0450
_refine_ls_R_factor_gt           0.0346
_refine_ls_shift/su_max          0.043
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0535P)^2^+5.7415P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0932
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_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              39969
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