Thermodynamics of N-H bond formation in bis(phosphine) molybdenum(ii) diazenides and the influence of the trans ligand.
Bezdek, Máté J; Chirik, Paul J.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 15922–15930; doi:10.1039/c6dt01932c

data_7039749
_publ_section_title
;
 Thermodynamics of N-H bond formation in bis(phosphine) molybdenum(ii)
 diazenides and the influence of the trans ligand.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15922
_journal_page_last               15930
_journal_paper_doi               10.1039/c6dt01932c
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C98 H80 B F24 Mo N3 P4'
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_chemical_name_systematic        '[(dppe)2(CH3CN)Mo(NNCy)][BArF24]'
_chemical_properties_physical    ', Air-sensitive,Moisture-sensitive'
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2016-06-13 deposited with the CCDC.
2016-06-29 downloaded from the CCDC.
;
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_diffrn_radiation_type           CuK\a
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_diffrn_reflns_number            111003
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0762P)^2^+13.2669P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7039747--7039749.cif.'
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