Lewis Acid promoted titanium alkylidene formation: off-cycle intermediates relevant to olefin trimerization catalysis.
Sattler, Aaron; VanderVelde, David G.; Labinger, Jay A.; Bercaw, John E.; Journal of the American Chemical Society 136 (2014) 10790–10800; doi:10.1021/ja5055687

data_4122278
_publ_section_title
;
 Lewis Acid promoted titanium alkylidene formation: off-cycle
 intermediates relevant to olefin trimerization catalysis.
;
_journal_issue                   30
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              10790
_journal_page_last               10800
_journal_paper_doi               10.1021/ja5055687
_journal_volume                  136
_journal_year                    2014
_chemical_formula_sum            'C43 H64 Cl N O3 Si2 Ti'
_chemical_formula_weight         782.48
_chemical_name_systematic
; 
 ? 
;
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'w=1/[\s^2^(Fo^2^)+(0.0650P)^2^+3.3731P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 4122278--4122281.cif.'
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