Synthesis and coordination chemistry of the PPN ligand 2-[bis(diisopropylphosphanyl)methyl]-6-methylpyridine
Han, Delong; Andres, Benjamin; Spannenberg, Anke; Beweries, Torsten; Acta Crystallographica Section C 73 (2017) 917–922; doi:10.1107/S205322961701261X

data_2020933
_publ_section_title
;
 Synthesis and coordination chemistry of the PPN ligand
 2-[bis(diisopropylphosphanyl)methyl]-6-methylpyridine
;
_journal_coeditor_code           OV3095
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              917
_journal_page_last               922
_journal_paper_doi               10.1107/S205322961701261X
_journal_volume                  73
_journal_year                    2017
_chemical_formula_iupac          '[Fe Cl2 (C19 H35 N P2)]'
_chemical_formula_moiety         'C19 H35 Cl2 Fe N P2'
_chemical_formula_sum            'C19 H35 Cl2 Fe N P2'
_chemical_formula_weight         466.17
_chemical_name_systematic
{2-[Bis(diisopropylphosphanyl)methyl]-6-methylpyridine-\k^2^<i>P</i>,<i>N</i>}dichloridoiron(II)
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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_cell_measurement_temperature    150(2)
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_cell_volume                     1160.35(3)
_computing_cell_refinement
;
SAINT (Bruker, 2013)
;
_computing_data_collection
;
APEX2 (Bruker, 2014)
;
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;
SAINT (Bruker, 2013)
;
_computing_molecular_graphics
;
XP in SHELXTL (Sheldrick, 2015)
;
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;
publCIF (Westrip, 2010)
;
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;
SHELXL-2014/7 (Sheldrick, 2015)
;
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;
SHELXS97 (Sheldrick, 2015)
;
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_exptl_absorpt_process_details
;
(SADABS; Bruker, 2014)
;
_exptl_crystal_colour            colourless
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_exptl_crystal_description       prism
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_exptl_crystal_size_min          0.349
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_refine_ls_R_factor_all          0.0282
_refine_ls_R_factor_gt           0.0254
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0371P)^2^+0.4053P] where P=(Fo^2^+2Fc^2^)/3'
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