Modular synthesis of heptaarylindole.
Suzuki, Shin; Asako, Takashi; Itami, Kenichiro; Yamaguchi, Junichiro; Organic & biomolecular chemistry 16 (2018) 3771–3776; doi:10.1039/c8ob00993g

data_7156242
_publ_section_title
;
 Modular synthesis of heptaarylindole.
;
_journal_issue                   20
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              3771
_journal_page_last               3776
_journal_paper_doi               10.1039/c8ob00993g
_journal_volume                  16
_journal_year                    2018
_chemical_formula_sum            'C50 H41 Cl3 F3 N O3 S'
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_audit_update_record
;
2017-10-18 deposited with the CCDC.
2018-05-03 downloaded from the CCDC.
;
_cell_angle_alpha                103.099(7)
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_cell_angle_gamma                98.173(7)
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_computing_cell_refinement
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Rigaku CrystalClear-SM Expert 2.1 b29
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_computing_data_collection
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Rigaku CrystalClear-SM Expert 2.1 b29
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_computing_data_reduction
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Rigaku CrystalClear-SM Expert 2.1 b29
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_computing_molecular_graphics    'Yadokari-XG 2009 (Wakita Nemoto et al., 2009)'
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_diffrn_ambient_temperature      123(2)
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_diffrn_measured_fraction_theta_full 0.981
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Rigaku CrystalClear-SM Expert 2.1 b29
;
_diffrn_measurement_method       'profile data from \w-scans'
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_diffrn_source                   'Rotating Anode'
_exptl_absorpt_coefficient_mu    0.310
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '\'Jacobson, R. (1998) Private communication\''
_exptl_crystal_colour            Colorless
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0827P)^2^+3.2370P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1657
_refine_ls_wR_factor_ref         0.1725
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6440
_reflns_number_total             7672
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8ob00993g2.cif
_cod_data_source_block           8I
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7156239--7156243.cif.
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_cod_database_code               7156242
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.955
_shelx_estimated_absorpt_t_max   0.970
_shelx_res_checksum              87078