Highly Efficient Peterson Olefination Leading to Unsaturated Selenoamides and Their Characterization
Toshiaki Murai; Akinori Fujishima; Chigusa Iwamoto; Shinzi Kato; Journal of Organic Chemistry 68 (2003) 7979–7982; doi:10.1021/jo034653k

data_4022495
_publ_section_title
;
 Highly Efficient Peterson Olefination Leading to Unsaturated
 Selenoamides and Their Characterization
;
_journal_name_full               'Journal of Organic Chemistry'
_journal_page_first              7979
_journal_page_last               7982
_journal_paper_doi               10.1021/jo034653k
_journal_volume                  68
_journal_year                    2003
_chemical_formula_sum            'C15 H16 Br N Se'
_chemical_formula_weight         369.16
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 99.044(9)
_cell_angle_gamma                90
_cell_formula_units_Z            8
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_cell_length_b                   29.510(5)
_cell_length_c                   15.509(3)
_cell_measurement_reflns_used    4421
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     2960.6(9)
_computing_cell_refinement       CRYSTALCLEAR
_computing_data_collection       CRYSTALCLEAR
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SHELXS86
_diffrn_detector_area_resol_mean 14.62
_diffrn_measured_fraction_theta_full 0.9906
_diffrn_measured_fraction_theta_max 0.9906
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_av_R_equivalents  0.068
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_diffrn_reflns_limit_h_min       -8
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_diffrn_reflns_theta_max         27.53
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_exptl_absorpt_correction_type   none
_exptl_crystal_colour            Brown
_exptl_crystal_density_diffrn    1.656
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
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_refine_ls_R_factor_gt           0.0543
_refine_ls_shift/su_max          0.0017
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
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_cod_original_formula_sum        'C15 H16 Br N Se '
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