In situ generated polysiloxanes stabilizing μ3-oxo bridged Sb3 triangles.
Santhana Raj Prabhu, M.; Ugandhar, Uppara; Baskar, Viswanathan; Dalton transactions (Cambridge, England : 2003) 45 (2016) 6963–6967; doi:10.1039/c5dt01590a

data_7038724
_publ_section_title
;
 In situ generated polysiloxanes stabilizing \m3-oxo bridged Sb3
 triangles.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6963
_journal_page_last               6967
_journal_paper_doi               10.1039/c5dt01590a
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C51 H75 Cl6 N3 O16 Sb3 Si6'
_chemical_formula_sum            'C51 H75 Cl6 N3 O16 Sb3 Si6'
_chemical_formula_weight         1732.63
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2016-03-05 deposited with the CCDC.
2016-03-08 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'Bruker SHELXTL'
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_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0326
_diffrn_reflns_av_unetI/netI     0.0530
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0465P)^2^+4.1013P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                12327
_reflns_number_total             14323
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt01590a2.cif
_cod_data_source_block           3
_cod_depositor_comments
'Adding full bibliography for 7038722--7038725.cif.'
_cod_database_code               7038724
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