Stimuli-responsive Zn(ii) complexes showing the structural conversion and on/off switching of catalytic properties
Kwon, So Hyeon; Lee, Sunwoo; Tessarolo, Jacopo; Lee, Haeri; RSC Advances 14 (2024) 32655–32660; doi:10.1039/D4RA06058J

data_7249464
_publ_section_title
;
 Stimuli-responsive Zn(ii) complexes showing the structural conversion and
 on/off switching of catalytic properties
;
_journal_issue                   44
_journal_name_full               'RSC Advances'
_journal_page_first              32655
_journal_page_last               32660
_journal_paper_doi               10.1039/D4RA06058J
_journal_volume                  14
_journal_year                    2024
_chemical_formula_moiety         'C24 H22 Br4 N6 Zn2'
_chemical_formula_sum            'C24 H22 Br4 N6 Zn2'
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_audit_update_record
;
2024-02-06 deposited with the CCDC.	2024-10-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_diffrn_source                   'fine-focus sealed tube'
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_exptl_crystal_description       rod
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+2.4549P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0682
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                2570
_reflns_number_total             3073
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4ra06058j2.cif
_cod_data_source_block           03-Zn2Br4L
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7249464
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.487
_shelx_estimated_absorpt_t_max   0.797
_shelx_res_checksum              40087