First Redox Polymer Bearing One-Step Successive Two-Electron-Transfer Process Based on Redox Potential Inversion
Nishiumi, Toyohiko; Chimoto, Yuya; Hagiwara, Yuki; Higuchi, Masayoshi; Yamamoto, Kimihisa; Macromolecules 37 (2004) 2661–; doi:10.1021/ma035370x

data_1506853
_publ_section_title
;
 First Redox Polymer Bearing One-Step Successive Two-Electron-Transfer
 Process Based on Redox Potential Inversion
;
_journal_issue                   7
_journal_name_full               Macromolecules
_journal_page_first              2661
_journal_paper_doi               10.1021/ma035370x
_journal_volume                  37
_journal_year                    2004
_chemical_formula_moiety         'C34 H26 Cl3 F3 N2 O10 '
_chemical_formula_sum            'C34 H26 Cl3 F3 N2 O10'
_chemical_formula_weight         785.94
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Mon Apr 14 15:38:21 2003'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                96.53(3)
_cell_angle_beta                 88.67(3)
_cell_angle_gamma                99.57(3)
_cell_formula_units_Z            4
_cell_length_a                   10.360(4)
_cell_length_b                   18.181(6)
_cell_length_c                   18.481(6)
_cell_measurement_reflns_used    20966
_cell_measurement_temperature    93(1)
_cell_measurement_theta_max      60.1
_cell_measurement_theta_min      6.0
_cell_volume                     3410(2)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9736
_diffrn_measured_fraction_theta_max 0.9736
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.060
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            28881
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_exptl_absorpt_coefficient_mu    0.347
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.531
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.70
_refine_diff_density_min         -1.35
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.14
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     907
_refine_ls_number_reflns         15218
_refine_ls_R_factor_gt           0.0842
_refine_ls_shift/su_max          0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.06700(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2092
_reflns_number_gt                7005
_reflns_number_total             15218
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ma035370xsi20040207_020732.cif
_cod_data_source_block           AQA2PLUS
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C34 H26 Cl3 F3 N2 O10 '
_cod_database_code               1506853