Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum-nitrogen heterocycles.
Drescher, Regina; Lin, Shujuan; Hofmann, Alexander; Lenczyk, Carsten; Kachel, Stephanie; Krummenacher, Ivo; Lin, Zhenyang; Braunschweig, Holger; Chemical science 11 (2020) 5559–5564; doi:10.1039/d0sc02032j

data_1558062
_publ_section_title
;
 Ring expansion of alumoles with organic azides: selective formation of
 six-membered aluminum-nitrogen heterocycles.
;
_journal_issue                   21
_journal_name_full               'Chemical science'
_journal_page_first              5559
_journal_page_last               5564
_journal_paper_doi               10.1039/d0sc02032j
_journal_volume                  11
_journal_year                    2020
_chemical_formula_moiety         'C32 H58 Al N Si'
_chemical_formula_sum            'C32 H58 Al N Si'
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_audit_update_record
;
2020-02-28 deposited with the CCDC.	2020-05-14 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker X8-APEX II'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0408P)^2^+0.8081P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                5869
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0sc02032j2.cif
_cod_data_source_block           AlHo137_a
_cod_depositor_comments
;Adding full bibliography for 1558058--1558063.cif.

 Adding full bibliography for 1558058--1558063.cif.
;
_cod_database_code               1558062
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_shelx_res_checksum              52691