Preparation of chalcogenolato-bridged dinuclear Tp*Rh-Cp*Ru complexes (Tp*= hydrotris(3,5-dimethylpyrazol-1-yl)borate, Cp*=eta(5)-pentamethylcyclopentadienyl) and binding of dioxygen to their Ru sites.
Nagao, Shoken; Seino, Hidetake; Hidai, Masanobu; Mizobe, Yasushi; Dalton transactions (Cambridge, England : 2003)  (2005) 3166–3172; doi:10.1039/b503153m

data_7008468
_publ_section_title
;
 Preparation of chalcogenolato-bridged dinuclear Tp*Rh-Cp*Ru complexes
 (Tp*= hydrotris(3,5-dimethylpyrazol-1-yl)borate,
 Cp*=eta(5)-pentamethylcyclopentadienyl) and binding of dioxygen to
 their Ru sites.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3166
_journal_page_last               3172
_journal_paper_doi               10.1039/b503153m
_journal_year                    2005
_chemical_formula_moiety         'C41 H55 B Cl N6 O3 S2 Rh Ru '
_chemical_formula_sum            'C41 H55 B Cl N6 O3 Rh Ru S2'
_chemical_formula_weight         994.28
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 92.029(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.2271(7)
_cell_length_b                   19.3709(13)
_cell_length_c                   20.1713(13)
_cell_measurement_reflns_used    16298
_cell_measurement_temperature    293.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     4384.1(5)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 3.00'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_detector_area_resol_mean 14.62
_diffrn_measured_fraction_theta_full 0.9849
_diffrn_measured_fraction_theta_max 0.9849
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.030
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            35318
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.921
_exptl_absorpt_correction_T_max  0.832
_exptl_absorpt_correction_T_min  0.800
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.506
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2040.00
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.66
_refine_diff_density_min         -0.60
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.113
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     560
_refine_ls_number_reflns         7941
_refine_ls_R_factor_gt           0.0390
_refine_ls_shift/su_max          0.0240
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0010Fo^2^ + 1.0000\s^2^(Fo) + 0.2000]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1030
_reflns_number_gt                7941
_reflns_number_total             10208
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            b503153m.txt
_cod_data_source_block           Complex_5a
_cod_original_formula_sum        'C41 H55 B Cl N6 O3 S2 Rh Ru '
_cod_database_code               7008468