Chiral Synthesis of a Mononuclear Nickel(II) Complex Formed from an Achiral Tripodal Amine Ligand: Spontaneous Resolution
A. Srinivasa Rao; Abhijit Pal; Rajarshi Ghosh; Samar K. Das; Inorganic Chemistry 48 (2009) 1802–1804; doi:10.1021/ic802171b

data_4301615
_publ_contact_author_address
; 
School of Chemistry
University of Hyderabad
Hyderabad 500 046,
India
;
_publ_contact_author_email       skdsc@uohyd.ernet.in
_publ_contact_author_fax         '91 40 23012460'
_publ_contact_author_name
;
Dr. Samar K. Das
;
_publ_contact_author_phone       '91 40 23011007'
_publ_section_title
;
Chiral Synthesis of a Mononuclear Nickel(II) Complex Formed from an Achiral
Tripodal Amine Ligand: Spontaneous Resolution
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1802
_journal_page_last               1804
_journal_paper_doi               10.1021/ic802171b
_journal_volume                  48
_journal_year                    2009
_chemical_formula_sum            'C8 H18 N6 Ni S2'
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_exptl_absorpt_correction_T_min  0.6127
_exptl_absorpt_correction_type   empirical
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_exptl_crystal_colour            'light blue'
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0678P)^2^+1.7660P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Empirical' changed to
'empirical' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        1379.7(11)
_cod_database_code               4301615