Synthesis and SMM behaviour of trinuclear versus dinuclear 3d-5f uranyl(v)-cobalt(ii) cation-cation complexes.
Chatelain, Lucile; Tuna, Floriana; Pécaut, Jacques; Mazzanti, Marinella; Dalton transactions (Cambridge, England : 2003) 46 (2017) 5498–5502; doi:10.1039/c6dt04558h

data_7041724
_publ_section_title
;
 Synthesis and SMM behaviour of trinuclear versus dinuclear 3d-5f
 uranyl(v)-cobalt(ii) cation-cation complexes.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               5502
_journal_paper_doi               10.1039/c6dt04558h
_journal_volume                  46
_journal_year                    2017
_chemical_formula_sum            'C74.5 H74.5 Co2 I N12.5 O6 U'
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 ? 
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2016-12-02 deposited with the CCDC.
2016-12-23 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
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Mercury 3.1 New software for searching the Cambridge Structural Database 
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OLEX2: a complete structure solution, refinement and analysis program 
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SUPERFLIP program (Palatinus, L. & Chapuis, G. J. Appl. Cryst., 2007,
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  1 omega   34.00   77.00   1.0000   10.0000
omega____ theta____ kappa____ phi______ frames
    -       25.4051 -127.0000 -120.0000 43

  2 omega  -77.00    3.00   1.0000   10.0000
omega____ theta____ kappa____ phi______ frames
    -      -27.1239  -77.0000   30.0000 80

  3 omega  -88.00    6.00   1.0000   10.0000
omega____ theta____ kappa____ phi______ frames
    -      -27.1239  -19.0000  150.0000 94

  4 omega  -49.00    1.00   1.0000   10.0000
omega____ theta____ kappa____ phi______ frames
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_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            'lustrous dark red'
_exptl_crystal_density_diffrn    1.482
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_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.1838
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0959P)^2^+0.0633P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7041724--7041725.cif.'
_cod_original_formula_sum        'C74.50 H74.50 Co2 I N12.50 O6 U'
_cod_database_code               7041724
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