Deprotonation-Induced Enantioselective Aggregation and Deprotonation-Induced Ligand Rearrangement of Copper(II) Complexes Yield 1D Homochiral and Heterochiral Chains and a Cyclic Tetramer, Respectively
Yoshiki Shii; Yuri Motoda; Toshihiro Matsuo; Fumiaki Kai; Toshio Nakashima; Jean-Pierre Tuchagues; Naohide Matsumoto; Inorganic Chemistry 38 (1999) 3513–3522; doi:10.1021/ic9813260

data_4322153
_publ_contact_author
;
Naohide Matsumoto
 Department of Chemistry, Faculty of Science, Kumamoto University,
Kurokami 2-39-1, Kumamoto 860-8555, Japan
;
_publ_contact_author_email       'naohide@aster.sci.kumamoto-u.ac.jp '
_publ_contact_author_fax         +81-96-342-3390
_publ_contact_author_phone       ' +81-96-342-3390'
_publ_section_title
;
 Deprotonation-Induced Enantioselective Aggregation and
 Deprotonation-Induced Ligand Rearrangement of Copper(II) Complexes Yield
 1D Homochiral and Heterochiral Chains and a Cyclic Tetramer, Respectively
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3513
_journal_page_last               3522
_journal_paper_doi               10.1021/ic9813260
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C15 H23 Cl2 Cu N7 O8'
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      9
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_audit_creation_date             'Thu Dec 25 16:28:58 1997'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 130.282(4)
_cell_angle_gamma                90
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_cell_length_a                   21.800(2)
_cell_length_b                   8.574(1)
_cell_length_c                   16.148(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    20.0
_cell_measurement_theta_max      40.35
_cell_measurement_theta_min      37.35
_cell_volume                     2302.6(5)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_computing_structure_solution    SAPI91
_diffrn_ambient_temperature      20.0
_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
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_diffrn_orient_matrix_UB_13      0.01400
_diffrn_orient_matrix_UB_21      0.04905
_diffrn_orient_matrix_UB_22      0.06386
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_diffrn_orient_matrix_UB_32      -0.00863
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_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoKalpha
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_exptl_absorpt_coefficient_mu_cm 12.365
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_exptl_crystal_colour            blue
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_refine_ls_extinction_method     Zachariasen_type_2_Gaussian_isotropic
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_refine_ls_matrix_type           full
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_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0450
_refine_ls_shift/esd_max         1.9510
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0330
_cod_data_source_file            ic9813260_4.cif
_cod_data_source_block           Cu_(2_3)Me
_cod_depositor_comments
;
 Changing the _geom_bond_publ_flag tag to the _geom_angle_publ_flag tag
 and the _geom_angle_publ_flag tag to the _geom_bond_publ_flag tag.

 Antanas Vaitkus,
 2017-01-29
;
_cod_original_cell_volume        2302.7(5)
_cod_original_formula_sum        'C15 H23 N7 O8 Cl2 Cu'
_cod_database_code               4322153