Mono-carboxylated diaminedichloridoplatinum(iv) complexes - selective synthesis, characterization, and cytotoxicity.
Pichler, Verena; Valiahdi, Seied M.; Jakupec, Michael A.; Arion, Vladimir B.; Galanski, Markus; Keppler, Bernhard K.; Dalton transactions (Cambridge, England : 2003) 40 (2011) 8187–8192; doi:10.1039/c1dt10301f

data_7016356
_publ_section_title
;
 Mono-carboxylated diaminedichloridoplatinum(iv) complexes - selective
 synthesis, characterization, and cytotoxicity.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8187
_journal_page_last               8192
_journal_paper_doi               10.1039/c1dt10301f
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C9 H20 Cl2 N2 O5 Pt'
_chemical_formula_sum            'C9 H20 Cl2 N2 O5 Pt'
_chemical_formula_weight         502.26
_chemical_name_common
;
(OC-6-43)-Dichlorido(N,N-dimethyl-ethane-1,2-
diamine)hydroxido(4-methoxy-4-oxobutanoato)platinum(IV)
;
_chemical_name_systematic
;
(OC-6-43)-Dichlorido(N,N-dimethyl-ethane-1,2-diamine)hydroxido(4-
methoxy-4-oxobutanoato)platinum(IV)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                89.567(3)
_cell_angle_beta                 79.707(2)
_cell_angle_gamma                84.467(2)
_cell_formula_units_Z            2
_cell_length_a                   8.1295(3)
_cell_length_b                   8.3664(3)
_cell_length_c                   11.0750(4)
_cell_measurement_reflns_used    9878
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.83
_cell_measurement_theta_min      2.45
_cell_volume                     737.65(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0623
_diffrn_reflns_av_sigmaI/netI    0.0323
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            47115
_diffrn_reflns_theta_full        29.99
_diffrn_reflns_theta_max         29.99
_diffrn_reflns_theta_min         2.56
_exptl_absorpt_coefficient_mu    9.889
_exptl_absorpt_correction_T_max  0.3185
_exptl_absorpt_correction_T_min  0.2424
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.261
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             480
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.016
_refine_diff_density_min         -0.923
_refine_diff_density_rms         0.162
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     172
_refine_ls_number_reflns         4280
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0240
_refine_ls_R_factor_gt           0.0206
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0205P)^2^+1.0794P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0455
_refine_ls_wR_factor_ref         0.0466
_reflns_number_gt                3954
_reflns_number_total             4280
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt10301f.txt
_cod_data_source_block           VEPI107
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7016356