Diastereoselective Production of Homoallylic Alcohols Bearing Quaternary Centers from γ-Substituted Allylic Indiums and Ketones
Srinivasarao Arulananda Babu; Makoto Yasuda; Akio Baba; Journal of Organic Chemistry 72 (2007) 10264–10267; doi:10.1021/jo701899j

data_4023113
_publ_section_title
;
 Diastereoselective Production of Homoallylic Alcohols Bearing
 Quaternary Centers from \g-Substituted Allylic Indiums and Ketones
;
_journal_name_full               'Journal of Organic Chemistry'
_journal_page_first              10264
_journal_page_last               10267
_journal_paper_doi               10.1021/jo701899j
_journal_volume                  72
_journal_year                    2007
_chemical_formula_moiety         'C21 H24 O2 '
_chemical_formula_sum            'C21 H24 O2'
_chemical_formula_weight         308.42
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_date             'Thu Jun  8 07:34:20 2006'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90
_cell_angle_beta                 95.1256(7)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.0909(3)
_cell_length_b                   10.0236(4)
_cell_length_c                   19.1774(8)
_cell_measurement_reflns_used    12980
_cell_measurement_temperature    273.2
_cell_measurement_theta_max      30.5
_cell_measurement_theta_min      2.0
_cell_volume                     1740.5(1)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9968
_diffrn_measured_fraction_theta_max 0.9968
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.049
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            20892
_diffrn_reflns_theta_full        30.48
_diffrn_reflns_theta_max         30.48
_exptl_absorpt_coefficient_mu    0.074
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.821
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.177
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_size_max          0.350
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.000
_refine_diff_density_max         0.67
_refine_diff_density_min         -0.37
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.791
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     304
_refine_ls_number_reflns         3034
_refine_ls_R_factor_gt           0.1250
_refine_ls_shift/su_max          0.1633
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.07000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2265
_reflns_number_gt                2248
_reflns_number_total             5283
_reflns_threshold_expression     F^2^&gt;2.0\s(F^2^)
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_cod_data_source_block           1664_2
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C21 H24 O2 '
_cod_database_code               4023113