1,4-Dihydropyridines as Alkyl Radical Precursors: Introducing the Aldehyde Feedstock to Nickel/Photoredox Dual Catalysis.
Gutiérrez-Bonet, Álvaro; Tellis, John C.; Matsui, Jennifer K.; Vara, Brandon A.; Molander, Gary A.; ACS catalysis 6 (2016) 8004–8008; doi:10.1021/acscatal.6b02786

data_4516719
_publ_section_title
;
 1,4-Dihydropyridines as Alkyl Radical Precursors: Introducing the
 Aldehyde Feedstock to Nickel/Photoredox Dual Catalysis.
;
_journal_issue                   12
_journal_name_full               'ACS catalysis'
_journal_page_first              8004
_journal_page_last               8008
_journal_paper_doi               10.1021/acscatal.6b02786
_journal_volume                  6
_journal_year                    2016
_chemical_formula_moiety         'C18 H32 N2 Ni O4, 2(Cl), C4 H8 O'
_chemical_formula_sum            'C22 H40 Cl2 N2 Ni O5'
_chemical_formula_weight         542.17
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_date             2016-06-21
_audit_creation_method
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Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
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_cell_length_b                   30.400(2)
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_cell_measurement_temperature    100
_cell_measurement_theta_max      25.41
_cell_measurement_theta_min      3.12
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_diffrn_measurement_device       'CMOS area detector'
_diffrn_measurement_device_type  'Bruker D8QUEST'
_diffrn_measurement_method       '\w and \f scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_av_unetI/netI     0.0245
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_diffrn_reflns_theta_min         3.117
_diffrn_source                   'sealed tube'
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            'light blue'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1083P)^2^+11.2889P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                2217
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
;
The following automatic conversions were performed:

data name '_exptl_crystal_color' was replaced with
'_exptl_crystal_colour' as specified in the replacement file
'data/replacement-values/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 9268 2022-04-12 08:56:07Z antanas 
;
_cod_database_code               4516719