Spin-state tuning at pseudotetrahedral d(7) ions: examining the structural and magnetic phenomena of four-coordinate [BP3]CoII-X systems.
Jenkins, David M.; Peters, Jonas C.; Journal of the American Chemical Society 127 (2005) 7148–7165; doi:10.1021/ja045310m

data_4129231
_publ_section_title
;
 Spin-state tuning at pseudotetrahedral d(7) ions: examining the
 structural and magnetic phenomena of four-coordinate [BP3]CoII-X systems.
;
_journal_issue                   19
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              7148
_journal_page_last               7165
_journal_paper_doi               10.1021/ja045310m
_journal_volume                  127
_journal_year                    2005
_chemical_formula_sum            'C53 H50 B Co P3 S'
_chemical_formula_weight         881.64
_chemical_name_common            '[PhBP3]CoS(2,6-Me2-Ph)'
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_space_group_name_Hall           '-P 1'
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_cell_angle_beta                 77.5460(10)
_cell_angle_gamma                77.9190(10)
_cell_formula_units_Z            2
_cell_length_a                   12.0158(9)
_cell_length_b                   12.5469(9)
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_diffrn_ambient_temperature      100(2)
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_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_exptl_crystal_colour            dichroic
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blade
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_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
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_refine_ls_weighting_scheme      sigma
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_cod_data_source_block           dmj39
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