Extending Stannyl Anion Chemistry to the Actinides: Synthesis and Characterization of a Uranium-Tin Bond.
Winston, Matthew S.; Batista, Enrique R.; Yang, Ping; Tondreau, Aaron M.; Boncella, James M.; Inorganic chemistry 55 (2016) 5534–5539; doi:10.1021/acs.inorgchem.6b00543

data_4347739
_publ_section_title
;
 Extending Stannyl Anion Chemistry to the Actinides: Synthesis and
 Characterization of a Uranium-Tin Bond.
;
_journal_issue                   11
_journal_name_full               'Inorganic chemistry'
_journal_page_first              5534
_journal_page_last               5539
_journal_paper_doi               10.1021/acs.inorgchem.6b00543
_journal_volume                  55
_journal_year                    2016
_chemical_formula_sum            'C35 H35 Cl4 Li N7 U'
_chemical_formula_weight         940.45
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
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_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
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_atom_sites_solution_secondary   difmap
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_cell_angle_beta                 113.735(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.762(4)
_cell_length_b                   11.798(3)
_cell_length_c                   19.524(4)
_cell_measurement_reflns_used    9949
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.23
_cell_measurement_theta_min      2.51
_cell_volume                     3745.3(15)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       15
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_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         2.51
_exptl_absorpt_coefficient_mu    4.654
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6454
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.668
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1828
_exptl_crystal_size_max          0.17
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_refine_ls_R_factor_all          0.0785
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0000P)^2^+120.9876P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1580
_refine_ls_wR_factor_ref         0.1629
_reflns_number_gt                7381
_reflns_number_total             9257
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic6b00543_si_003.cif
_cod_data_source_block           mwuiii_stuff
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        3745.3(14)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4347739