Palladium alkyl complexes with a formazanate ligand: synthesis, structure and reactivity.
Milocco, Francesca; de Vries, Folkert; Dall'Anese, Anna; Rosar, Vera; Zangrando, Ennio; Otten, Edwin; Milani, Barbara; Dalton transactions (Cambridge, England : 2003) 47 (2018) 14445–14451; doi:10.1039/c8dt03130d

data_7047384
_publ_section_title
;
 Palladium alkyl complexes with a formazanate ligand: synthesis, structure
 and reactivity.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14445
_journal_page_last               14451
_journal_paper_doi               10.1039/c8dt03130d
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C40 H36 N8 O2 Pd2, C H2 Cl2'
_chemical_formula_sum            'C41 H38 Cl2 N8 O2 Pd2'
_chemical_formula_weight         958.49
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/1
_audit_update_record
;
2018-04-09 deposited with the CCDC.
2018-08-30 downloaded from the CCDC.
;
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_cell_measurement_theta_min      2.11
_cell_volume                     1928.4(9)
_computing_cell_refinement       'XDS (Kabsch, 2010)'
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_computing_data_reduction        'XDS - CCP4'
_computing_molecular_graphics    'Ortep3 for Windows'
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_diffrn_measurement_device_type  'Dectris Pilatus 2M'
_diffrn_measurement_method       'CCD rotation images, thick slices'
_diffrn_radiation_monochromator  Si111
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/1 (Sheldrick 2018)'
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_refine_ls_number_restraints     0
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0522P)^2^+5.2537P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1026
_refine_ls_wR_factor_ref         0.1031
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10833
_reflns_number_total             11162
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7047382--7047384.cif.'
_cod_original_cell_volume        1928.5(8)
_cod_database_code               7047384
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