Cooperative Metathesis of H-H/Sn-CAr bonds in stannylene-Ni0 systems
Gilch, Jonas M.; Iddrisu, Mustapha; Keil, Philip M.; Szilvasi, Tibor; Hadlington, Terrance John; Chemical Science  (2026) –; doi:10.1039/D5SC09496H

data_1576698
_publ_section_title
;
 Cooperative metathesis of H-H/Sn-C<sup>Ar</sup> bonds in
 stannylene-Ni<sup>0</sup> systems.
;
_journal_issue                   16
_journal_name_full               'Chemical science'
_journal_page_first              7938
_journal_page_last               7946
_journal_paper_doi               10.1039/d5sc09496h
_journal_volume                  17
_journal_year                    2026
_chemical_formula_moiety         'C51 H64 N Ni P Si Sn'
_chemical_formula_sum            'C51 H64 N Ni P Si Sn'
_chemical_formula_weight         927.49
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_space_group_IT_number           85
_space_group_name_Hall           '-P 4a'
_space_group_name_H-M_alt        'P 4/n :2'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2025-10-01 deposited with the CCDC.	2026-02-25 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'STOE StadiVari'
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_diffrn_source                   'Genix 3D HF Mo'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'STOE X-AREA 1.76'
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_refine_ls_R_factor_gt           0.0342
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0483P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                7134
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           4
_cod_depositor_comments
'Adding full bibliography for 1576689--1576698.cif.'
_cod_original_sg_symbol_H-M      'P 4/n'
_cod_database_code               1576698
_shelx_shelxl_version_number     2018/3
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