Halogen substitution regulates the phase transition temperature and band gap of semiconductor compounds.
Li, Hui-Hui; Wang, Chang-Feng; Wu, Ya-Xing; Jiang, Fan; Shi, Chao; Ye, Heng-Yun; Zhang, Yi; Chemical communications (Cambridge, England) 56 (2020) 1697–1700; doi:10.1039/c9cc09477f

data_7126113
_publ_section_title
;
 Halogen substitution regulates the phase transition temperature and band
 gap of semiconductor compounds.
;
_journal_issue                   11
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              1697
_journal_page_last               1700
_journal_paper_doi               10.1039/c9cc09477f
_journal_volume                  56
_journal_year                    2020
_chemical_formula_sum            'C6 H24 Bi Cl6 N3'
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_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-09-16 deposited with the CCDC.	2020-01-06 downloaded from the CCDC.
;
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_cell_measurement_temperature    293(2)
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_diffrn_measurement_device_type  'Rigaku, SCXmini'
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_exptl_absorpt_coefficient_mu    9.945
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_refine_ls_shift/su_mean         0.004
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0820P)^2^+6.2619P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9cc09477f2.cif
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_cod_original_sg_symbol_H-M      'C 2/m'
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_shelx_res_checksum              82018