LMucko/crystallography-open-database huggingface dataset:
Highly Enantiomerically Enriched α-Haloalkyl Grignard Reagents
Hoffmann, Reinhard W.; Nell, Peter G.; Leo, Roland; Harms, Klaus; Chemistry - A European Journal 6 (2000) 3359–3365; doi:10.1002/1521-3765(20000915)6:18<3359::AID-CHEM3359>3.0.CO;2-U

data_1100201
_publ_section_title
;
 Highly Enantiomerically Enriched \a-Haloalkyl Grignard Reagents
;
_journal_coden_ASTM              CEUJED
_journal_issue                   18
_journal_name_full               'Chemistry - A European Journal'
_journal_page_first              3359
_journal_page_last               3365
_journal_paper_doi
10.1002/1521-3765(20000915)6:18<3359::AID-CHEM3359>3.0.CO;2-U
_journal_volume                  6
_journal_year                    2000
_chemical_formula_moiety         'C14 H12 Cl2 O1 S1'
_chemical_formula_sum            'C14 H12 Cl2 O S'
_chemical_melting_point          386.15
_chemical_name_systematic
;
(R,R)-p-Chlorophenyl-1-chloro-2-phenylethyl sulfoxide
;
_space_group_IT_number           1
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      1
_symmetry_space_group_name_Hall  'P 1'
_symmetry_space_group_name_H-M   'P 1'
_cell_angle_alpha                71.564(5)
_cell_angle_beta                 62.985(5)
_cell_angle_gamma                62.938(5)
_cell_formula_units_Z            2
_cell_length_a                   9.0180(6)
_cell_length_b                   9.6771(8)
_cell_length_c                   9.9740(7)
_cell_volume                     683.920
_diffrn_ambient_temperature      213
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.453
_exptl_crystal_description       plate
_exptl_crystal_preparation       acetone
_refine_ls_R_factor_gt           4.37
_refine_ls_wR_factor_gt          4.37
_cod_original_formula_sum        'C14 H12 Cl2 O1 S1'
_cod_database_code               1100201
Highly Enantiomerically Enriched α-Haloalkyl Grignard Reagents
Hoffmann, Reinhard W.; Nell, Peter G.; Leo, Roland; Harms, Klaus; Chemistry - A European Journal 6 (2000) 3359–3365; doi:10.1002/1521-3765(20000915)6:18<3359::AID-CHEM3359>3.0.CO;2-U

data_1100202
_publ_section_title
;
 Highly Enantiomerically Enriched \a-Haloalkyl Grignard Reagents
;
_journal_coden_ASTM              CEUJED
_journal_issue                   18
_journal_name_full               'Chemistry - A European Journal'
_journal_page_first              3359
_journal_page_last               3365
_journal_paper_doi
10.1002/1521-3765(20000915)6:18<3359::AID-CHEM3359>3.0.CO;2-U
_journal_volume                  6
_journal_year                    2000
_chemical_formula_moiety         'C14 H12 Br1 Cl1 O1 S1'
_chemical_formula_sum            'C14 H12 Br Cl O S'
_chemical_melting_point          345.15
_chemical_name_systematic
;
(-)-(R,R)-p-Chlorophenyl-1-bromo-2-phenylethyl sulfoxide
;
_space_group_IT_number           1
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      1
_symmetry_space_group_name_Hall  'P 1'
_symmetry_space_group_name_H-M   'P 1'
_cell_angle_alpha                84.681(8)
_cell_angle_beta                 62.893(6)
_cell_angle_gamma                63.397(6)
_cell_formula_units_Z            2
_cell_length_a                   9.1121(8)
_cell_length_b                   9.7596(7)
_cell_length_c                   9.9764(11)
_cell_volume                     699.198
_diffrn_ambient_temperature      213
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.632
_exptl_crystal_description       'Irregular plate'
_exptl_crystal_preparation       actetone
_refine_ls_R_factor_gt           5.23
_refine_ls_wR_factor_gt          5.23
_cod_original_formula_sum        'C14 H12 Br1 Cl1 O1 S1'
_cod_database_code               1100202
Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
Chitsaz, S.; Folkerts, H.; Grebe, J.; Gröb, T.; Harms, K.; Hiller, W.; Krieger, M.; Massa, W.; Merle, J.; Möhlen, M.; Neumüller, B.; Dehnicke, K.; Zeitschrift für Anorganische und Allgemeine Chemie 626 (2000) 775–783; doi:10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h

data_1100203
_publ_section_title
;
 Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs
 [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              775
_journal_page_last               783
_journal_paper_doi
10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h
_journal_volume                  626
_journal_year                    2000
_chemical_formula_moiety         'C3 H11 N1 P1 1+,Cl1 1-'
_chemical_formula_sum            'C3 H11 Cl N P'
_chemical_name_systematic        'Aminotrimethylphosphonium chloride'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_H-M   'P 21/n'
_cell_angle_alpha                90
_cell_angle_beta                 103.31(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.866(1)
_cell_length_b                   9.388(1)
_cell_length_c                   11.243(1)
_cell_volume                     705.235
_diffrn_ambient_temperature      202.15
_exptl_crystal_density_diffrn    1.201
_refine_ls_R_factor_gt           2.39
_refine_ls_wR_factor_gt          2.39
_cod_original_formula_sum        'C3 H11 Cl1 N1 P1'
_cod_database_code               1100203
Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
Chitsaz, S.; Folkerts, H.; Grebe, J.; Gröb, T.; Harms, K.; Hiller, W.; Krieger, M.; Massa, W.; Merle, J.; Möhlen, M.; Neumüller, B.; Dehnicke, K.; Zeitschrift für Anorganische und Allgemeine Chemie 626 (2000) 775–783; doi:10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h

data_1100204
_publ_section_title
;
 Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs
 [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              775
_journal_page_last               783
_journal_paper_doi
10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h
_journal_volume                  626
_journal_year                    2000
_chemical_formula_moiety         'C6 H17 N1 P1 1+,Cl1 1-'
_chemical_formula_sum            'C6 H17 Cl N P'
_chemical_name_systematic
;
Aminotriethylphosphonium chloride
;
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   12.736(4)
_cell_length_b                   11.488(3)
_cell_length_c                   13.020(3)
_cell_volume                     1904.971
_diffrn_ambient_temperature      223
_exptl_crystal_colour            yellow-brown.
_exptl_crystal_density_diffrn    1.183
_exptl_crystal_description       platelet
_refine_ls_R_factor_gt           4.19
_refine_ls_wR_factor_gt          4.19
_cod_original_formula_sum        'C6 H17 Cl1 N1 P1'
_cod_database_code               1100204
Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
Chitsaz, S.; Folkerts, H.; Grebe, J.; Gröb, T.; Harms, K.; Hiller, W.; Krieger, M.; Massa, W.; Merle, J.; Möhlen, M.; Neumüller, B.; Dehnicke, K.; Zeitschrift für Anorganische und Allgemeine Chemie 626 (2000) 775–783; doi:10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h

data_1100205
_publ_section_title
;
 Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs
 [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              775
_journal_page_last               783
_journal_paper_doi
10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h
_journal_volume                  626
_journal_year                    2000
_chemical_formula_moiety         'C6 H19 N1 P1 Si1 1+,C1 F3 O3 S1 1-'
_chemical_formula_sum            'C7 H19 F3 N O3 P S Si'
_chemical_name_systematic
;
Trimethylsilylaminotrimethylphosphonium trifluoromethanesulfonate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 115.389(6)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   17.7708(11)
_cell_length_b                   11.7355(4)
_cell_length_c                   16.1137(10)
_cell_volume                     3035.935
_diffrn_ambient_temperature      190.15
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.371
_exptl_crystal_description       platelet
_refine_ls_R_factor_gt           3.32
_refine_ls_wR_factor_gt          3.32
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C7 H19 F3 N1 O3 P1 S1 Si1'
_cod_database_code               1100205
Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
Chitsaz, S.; Folkerts, H.; Grebe, J.; Gröb, T.; Harms, K.; Hiller, W.; Krieger, M.; Massa, W.; Merle, J.; Möhlen, M.; Neumüller, B.; Dehnicke, K.; Zeitschrift für Anorganische und Allgemeine Chemie 626 (2000) 775–783; doi:10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h

data_1100206
_publ_section_title
;
 Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs
 [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              775
_journal_page_last               783
_journal_paper_doi
10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h
_journal_volume                  626
_journal_year                    2000
_chemical_formula_moiety         '2(C6 H17 N1 P1 1+),H10 B10 2-'
_chemical_formula_sum            'C12 H44 B10 N2 P2'
_chemical_name_systematic
;
bis(Aminotriethylphosphonium) decahydro-closo-decaborate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 96.34(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.093(1)
_cell_length_b                   17.036(1)
_cell_length_c                   18.001(2)
_cell_volume                     2466.661
_diffrn_ambient_temperature      223
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.041
_exptl_crystal_description       needles
_refine_ls_R_factor_gt           5.33
_refine_ls_wR_factor_gt          5.33
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1100206
Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
Chitsaz, S.; Folkerts, H.; Grebe, J.; Gröb, T.; Harms, K.; Hiller, W.; Krieger, M.; Massa, W.; Merle, J.; Möhlen, M.; Neumüller, B.; Dehnicke, K.; Zeitschrift für Anorganische und Allgemeine Chemie 626 (2000) 775–783; doi:10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h

data_1100207
_publ_section_title
;
 Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs
 [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              775
_journal_page_last               783
_journal_paper_doi
10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h
_journal_volume                  626
_journal_year                    2000
_chemical_formula_moiety         'C18 H17 N1 P1 1+,Cl2 I1 1-'
_chemical_formula_sum            'C18 H17 Cl2 I N P'
_chemical_name_systematic
;
Aminotriphenylphosphonium dichloroiodide
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                114.12(2)
_cell_angle_beta                 104.50(2)
_cell_angle_gamma                93.21(2)
_cell_formula_units_Z            2
_cell_length_a                   8.253(3)
_cell_length_b                   10.864(3)
_cell_length_c                   12.412(4)
_cell_volume                     967.441
_diffrn_ambient_temperature      213
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.634
_exptl_crystal_description       regular
_refine_ls_R_factor_gt           6.44
_refine_ls_wR_factor_gt          6.44
_cod_original_formula_sum        'C18 H17 Cl2 I1 N1 P1'
_cod_database_code               1100207
Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
Chitsaz, S.; Folkerts, H.; Grebe, J.; Gröb, T.; Harms, K.; Hiller, W.; Krieger, M.; Massa, W.; Merle, J.; Möhlen, M.; Neumüller, B.; Dehnicke, K.; Zeitschrift für Anorganische und Allgemeine Chemie 626 (2000) 775–783; doi:10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h

data_1100208
_publ_section_title
;
 Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs
 [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              775
_journal_page_last               783
_journal_paper_doi
10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h
_journal_volume                  626
_journal_year                    2000
_chemical_formula_moiety         'C6 H17 N1 P1 1+,I1 1-'
_chemical_formula_sum            'C6 H17 I N P'
_chemical_name_systematic
;
Aminotriethylphosphonium iodide
;
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      19
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.121(1)
_cell_length_b                   12.333(2)
_cell_length_c                   12.571(2)
_cell_volume                     1104.027
_diffrn_ambient_temperature      223
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.571
_exptl_crystal_description       plates
_refine_ls_R_factor_gt           5.76
_refine_ls_wR_factor_gt          5.76
_cod_original_formula_sum        'C6 H17 I1 N1 P1'
_cod_database_code               1100208
Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
Chitsaz, S.; Folkerts, H.; Grebe, J.; Gröb, T.; Harms, K.; Hiller, W.; Krieger, M.; Massa, W.; Merle, J.; Möhlen, M.; Neumüller, B.; Dehnicke, K.; Zeitschrift für Anorganische und Allgemeine Chemie 626 (2000) 775–783; doi:10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h

data_1100209
_publ_section_title
;
 Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs
 [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              775
_journal_page_last               783
_journal_paper_doi
10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h
_journal_volume                  626
_journal_year                    2000
_chemical_formula_moiety         'C9 H25 N1 P1 Si1 1+,I1 1-'
_chemical_formula_sum            'C9 H25 I N P Si'
_chemical_name_systematic
;
Trimethylsilylaminotriethylphosphonium iodide
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 115.19(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.602(1)
_cell_length_b                   8.742(1)
_cell_length_c                   14.621(1)
_cell_volume                     1573.229
_diffrn_ambient_temperature      203
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.407
_exptl_crystal_description       plates
_refine_ls_R_factor_gt           6.6
_refine_ls_wR_factor_gt          6.6
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C9 H25 I1 N1 P1 Si1'
_cod_database_code               1100209
Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
Chitsaz, S.; Folkerts, H.; Grebe, J.; Gröb, T.; Harms, K.; Hiller, W.; Krieger, M.; Massa, W.; Merle, J.; Möhlen, M.; Neumüller, B.; Dehnicke, K.; Zeitschrift für Anorganische und Allgemeine Chemie 626 (2000) 775–783; doi:10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h

data_1100210
_publ_section_title
;
 Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs
 [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              775
_journal_page_last               783
_journal_paper_doi
10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h
_journal_volume                  626
_journal_year                    2000
_chemical_formula_moiety         'C9 H27 N1 P1 Si2 1+,I1 1-'
_chemical_formula_sum            'C9 H27 I N P Si2'
_chemical_name_systematic
;
bis(Trimethylsilyl)aminotrimethylphosphonium iodide
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 111.79(3)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   19.254(9)
_cell_length_b                   12.6907(9)
_cell_length_c                   15.073(4)
_cell_volume                     3419.888
_diffrn_ambient_temperature      213
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.412
_exptl_crystal_description       needle
_refine_ls_R_factor_gt           5.81
_refine_ls_wR_factor_gt          5.81
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C9 H27 I1 N1 P1 Si2'
_cod_database_code               1100210
Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
Chitsaz, S.; Folkerts, H.; Grebe, J.; Gröb, T.; Harms, K.; Hiller, W.; Krieger, M.; Massa, W.; Merle, J.; Möhlen, M.; Neumüller, B.; Dehnicke, K.; Zeitschrift für Anorganische und Allgemeine Chemie 626 (2000) 775–783; doi:10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h

data_1100211
_publ_section_title
;
 Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs
 [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              775
_journal_page_last               783
_journal_paper_doi
10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h
_journal_volume                  626
_journal_year                    2000
_chemical_formula_moiety         'C12 H33 N1 P1 Si2 1+,I1 1-'
_chemical_formula_sum            'C12 H33 I N P Si2'
_chemical_name_systematic
;
bis(Trimethylsilyl)aminotriethylphosphonium iodide
;
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      60
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   25.540(2)
_cell_length_b                   13.223(1)
_cell_length_c                   11.653(2)
_cell_volume                     3935.398
_diffrn_ambient_temperature      223
_exptl_crystal_colour            colorless.
_exptl_crystal_density_diffrn    1.369
_exptl_crystal_description       prisms
_refine_ls_R_factor_gt           3.7
_refine_ls_wR_factor_gt          3.7
_cod_original_formula_sum        'C12 H33 I1 N1 P1 Si2'
_cod_database_code               1100211
Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
Chitsaz, S.; Folkerts, H.; Grebe, J.; Gröb, T.; Harms, K.; Hiller, W.; Krieger, M.; Massa, W.; Merle, J.; Möhlen, M.; Neumüller, B.; Dehnicke, K.; Zeitschrift für Anorganische und Allgemeine Chemie 626 (2000) 775–783; doi:10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h

data_1100212
_publ_section_title
;
 Die Kristallstrukturen einer Serie von Verbindungen mit Kationen des Typs
 [R~3~PNH~2~]^+^, [R3PN(H)SiMe~3~]^+^ und [R3PN(SiMe~3~)~2~]^+^
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   3
_journal_name_full
;
 Zeitschrift f\"ur Anorganische und Allgemeine Chemie
;
_journal_page_first              775
_journal_page_last               783
_journal_paper_doi
10.1002/(sici)1521-3749(200003)626:3<775::aid-zaac775>3.0.co;2-h
_journal_volume                  626
_journal_year                    2000
_chemical_formula_moiety         'C24 H33 N1 P1 Si2 1+,I3 1-'
_chemical_formula_sum            'C24 H33 I3 N P Si2'
_chemical_name_systematic
;
bis(Trimethylsilyl)aminotriphenylphosphonium triiodide
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90
_cell_angle_beta                 105.96(1)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.477(1)
_cell_length_b                   10.476(1)
_cell_length_c                   16.016(4)
_cell_volume                     1528.794
_diffrn_ambient_temperature      223
_exptl_crystal_colour            brown.
_exptl_crystal_density_diffrn    1.745
_exptl_crystal_description       columns
_refine_ls_R_factor_gt           3.34
_refine_ls_wR_factor_gt          3.34
_cod_original_sg_symbol_H-M      'P 21'
_cod_original_formula_sum        'C24 H33 I3 N1 P1 Si2'
_cod_database_code               1100212