Highly Chemoselective Hydroboration of Alkynes and Nitriles Catalyzed by Group 4 Metal Amidophosphine–Borane Complexes
Bhattacharjee, Jayeeta; Harinath, Adimulam; Bano, Kulsum; Panda, Tarun K.; ACS Omega 5 (2020) 1595–1606; doi:10.1021/acsomega.9b03598

data_4517309
_publ_section_title
;
 Highly Chemoselective Hydroboration of Alkynes and Nitriles Catalyzed by
 Group 4 Metal Amidophosphine--Borane Complexes
;
_journal_issue                   3
_journal_name_full               'ACS Omega'
_journal_page_first              1595
_journal_page_last               1606
_journal_paper_doi               10.1021/acsomega.9b03598
_journal_volume                  5
_journal_year                    2020
_chemical_formula_moiety         'C60 H60 B4 N4 P4 Zr'
_chemical_formula_sum            'C60 H60 B4 N4 P4 Zr'
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'CrysAlisPro, Agilent Technologies,Version 1.171.35.19 (release 27-10-2011CrysAlis171 .NET)(compiled Oct 27'
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'CrysAlisPro, Agilent Technologies,Version 1.171.35.19 (release 27-10-2011CrysAlis171 .NET)(compiled Oct 27'
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'CrysAlisPro, Agilent Technologies,Version 1.171.35.19 (release 27-10-2011CrysAlis171 .NET)(compiled Oct 27'
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_diffrn_ambient_temperature      150(2)
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_diffrn_reflns_theta_max         71.301
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_diffrn_source                   'sealed X-ray tube'
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_exptl_absorpt_correction_T_min  0.69971
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         11938
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_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1719P)^2^+1.4925P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2751
_refine_ls_wR_factor_ref         0.3015
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8834
_reflns_number_total             11938
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           exp_5322
_cod_depositor_comments
;Adding full bibliography for 4517307--4517309.cif.

 Adding full bibliography for 4517307--4517309.cif.
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4517309
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