Pivalate complexes of copper(ii) with aliphatic amines as potential precursors for depositing nanomaterials from the gas phase
Butrymowicz-Kubiak, A.; Luba, W.; Madajska, K.; Muzioł, T.; Szymańska, I. B.; New Journal of Chemistry 48 (2024) 6232–6245; doi:10.1039/D3NJ04959K

data_7063086
_publ_section_title
;
 Pivalate complexes of copper(ii) with aliphatic amines as potential
 precursors for depositing nanomaterials from the gas phase
;
_journal_issue                   14
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              6232
_journal_page_last               6245
_journal_paper_doi               10.1039/D3NJ04959K
_journal_volume                  48
_journal_year                    2024
_chemical_formula_moiety         '(Cu 2+)3, (C5 H9 O2 1-)6, (C4 H11 N)2'
_chemical_formula_sum            'C38 H76 Cu3 N2 O12'
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;
2023-05-09 deposited with the CCDC.	2024-02-22 downloaded from the CCDC.
;
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.55a (Rigaku Oxford Diffraction, 2022)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'light blue'
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_exptl_crystal_size_mid          0.060
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_refine_ls_R_factor_all          0.0934
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1154P)^2^+3.4439P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1940
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_reflns_number_total             6871
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3nj04959k2.cif
_cod_data_source_block           new-wl6-3D-tw3shape_twin1_hklf5
_cod_depositor_comments
'Adding full bibliography for 7063085--7063088.cif.'
_cod_original_cell_volume        2384.10(17)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7063086
_shelx_shelxl_version_number     2018/1
_shelx_estimated_absorpt_t_min   0.781
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