Deposition of LaAlO3 films by liquid injection MOCVD using a new [La‒Al] single source alkoxide precursor
Manning, Troy D.; Loo, Yim Fun; Jones, Anthony C.; Aspinall, Helen C.; Chalker, Paul R.; Bickley, Jamie F.; Smith, Lesley M.; Critchlow, Gary W.; Journal of Materials Chemistry 15 (2005) 3384–; doi:10.1039/b507004j

data_7203824
_publ_section_title
;
 Deposition of LaAlO3 films by liquid injection MOCVD using a new
 [La--Al] single source alkoxide precursor
;
_journal_issue                   33
_journal_name_full               'Journal of Materials Chemistry'
_journal_page_first              3384
_journal_paper_doi               10.1039/b507004j
_journal_volume                  15
_journal_year                    2005
_chemical_formula_sum            'C42 H98 Al2 La2 O14'
_chemical_formula_weight         1158.98
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                78.436(2)
_cell_angle_beta                 70.332(2)
_cell_angle_gamma                68.465(2)
_cell_formula_units_Z            1
_cell_length_a                   9.8000(10)
_cell_length_b                   12.5617(13)
_cell_length_c                   13.7551(14)
_cell_measurement_temperature    100(2)
_cell_volume                     1477.5(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.866
_diffrn_measured_fraction_theta_max 0.866
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0294
_diffrn_reflns_av_sigmaI/netI    0.0701
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            8774
_diffrn_reflns_theta_full        28.12
_diffrn_reflns_theta_max         28.12
_diffrn_reflns_theta_min         1.75
_exptl_absorpt_coefficient_mu    1.506
_exptl_crystal_density_diffrn    1.303
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             602
_refine_diff_density_max         3.211
_refine_diff_density_min         -3.326
_refine_diff_density_rms         0.187
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.295
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     285
_refine_ls_number_reflns         6233
_refine_ls_number_restraints     55
_refine_ls_restrained_S_all      1.294
_refine_ls_R_factor_all          0.0848
_refine_ls_R_factor_gt           0.0780
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0501P)^2^+11.6967P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1734
_refine_ls_wR_factor_ref         0.1757
_reflns_number_gt                5679
_reflns_number_total             6233
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b507004j.txt
_cod_data_source_block           tdm75m
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               7203824