Hydrazinium(1+) Hexafluorogallate(III) and Hydrazinium(2+) Aquapentafluorogallate(III)
Meden, A.; Siftar, J.; Golic, L.; Acta Crystallographica Section C 52 (1996) 493–496; doi:10.1107/S0108270195011310

data_2004628
_publ_section_title
;
 Hydrazinium(1+) Hexafluorogallate(III) and Hydrazinium(2+)
 Aquapentafluorogallate(III)
;
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              493
_journal_page_last               496
_journal_paper_doi               10.1107/S0108270195011310
_journal_volume                  52
_journal_year                    1996
_chemical_formula_moiety         '(N2 H6 2+) (Ga F5 H2 O 2-)'
_chemical_formula_structural     '(N2 H6) (Ga F5 H2 O)'
_chemical_formula_sum            'F5 Ga H8 N2 O'
_chemical_formula_weight         216.79
_chemical_name_systematic
;
hydrazinium pentafluoroaquagallate
;
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_audit_creation_method           from_xtal_archive_file_using_CIFIO
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   9.2480(10)
_cell_length_b                   10.9420(10)
_cell_length_c                   11.1990(10)
_cell_measurement_reflns_used    69
_cell_measurement_temperature    293
_cell_measurement_theta_max      14.907
_cell_measurement_theta_min      6.044
_cell_volume                     1133.24(19)
_computing_cell_refinement       'Xray PARAM, local program'
_computing_data_collection       'CAD-4 Software (Enraf-Nonius, 1989)'
_computing_data_reduction
'DIFDAT SORTRF ADDREF Xtal3.2 (Hall, Flack & Stewart, 1992)'
_computing_molecular_graphics    'ORTEP (Johnson, 1965)'
_computing_publication_material  'BONDLA CIFIO Xtal3.2'
_computing_structure_refinement  'CRYLSQ Xtal3.2'
_computing_structure_solution    Xtal3.2
_diffrn_ambient_temperature      293
_diffrn_measurement_device       'Enraf-Nonius CAD-4'
_diffrn_measurement_method       \w/2\q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         xray_tube
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  .022
_diffrn_reflns_av_sigmaI/netI    .02
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            8569
_diffrn_reflns_theta_max         24.9
_diffrn_reflns_theta_min         3.41
_diffrn_standards_decay_%        -12.68
_diffrn_standards_interval_time  333
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.88
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.541
_exptl_crystal_description       irregular
_exptl_crystal_F_000             848
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.08
_refine_diff_density_max         .72
_refine_diff_density_min         -.65
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.162
_refine_ls_goodness_of_fit_obs   1.026
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     114
_refine_ls_number_reflns         907
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .037
_refine_ls_R_factor_obs          .026
_refine_ls_shift/esd_max         .271
_refine_ls_shift/esd_mean        .066
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      'Regina weighting scheme'
_refine_ls_wR_factor_all         .024
_refine_ls_wR_factor_obs         .019
_reflns_number_observed          805
_reflns_number_total             990
_reflns_observed_criterion       refl_observed_if_Inet_>_2_sigma(Inet)
_cod_data_source_file            ka1142.cif
_cod_data_source_block           II
_cod_original_cell_volume        1133.2(2)
_cod_original_formula_sum        'H8 F5 Ga N2 O'
_cod_database_code               2004628