Iminoacylation. 3. Formation of Platinum(IV)-Based Metallaligands Due to Facile One-End Addition of vic-Dioximes to Coordinated Organonitriles1-3
Vadim Yu. Kukushkin; Tatyana B. Pakhomova; Nadezhda A. Bokach; Gabriele Wagner; Maxim L. Kuznetsov; Markus Galanski; Armando J. L. Pombeiro; Inorganic Chemistry 39 (2000) 216–225; doi:10.1021/ic990552m

data_4300047
_publ_section_title
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Iminoacylation. 3. Formation of Platinum(IV)-Based Metallaligands Due to
Facile One-End Addition of vic-Dioximes to Coordinated Organonitriles1-3
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_journal_name_full               'Inorganic Chemistry'
_journal_page_first              216
_journal_page_last               225
_journal_paper_doi               10.1021/ic990552m
_journal_volume                  39
_journal_year                    2000
_chemical_formula_sum            'C32 H44 Cl8 N12 O8 Pt2'
_chemical_formula_weight         1398.56
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.000
_cell_angle_beta                 94.460
_cell_angle_gamma                90.000
_cell_formula_units_Z            4
_cell_length_a                   10.290
_cell_length_b                   18.153
_cell_length_c                   13.059
_cell_measurement_radiation      MoK\a
_cell_measurement_temperature    293
_cell_measurement_wavelength     .71069
_cell_volume                     2431.961
_computing_molecular_graphics
'SIR97(Cascarano al.,Acta Cryst.,1996,A52,C-79)'
_computing_publication_material
'SIR97(Cascarano al.,Acta Cryst.,1996,A52,C-79)'
_computing_structure_refinement
'SIR97(Cascarano al.,Acta Cryst.,1996,A52,C-79)'
_computing_structure_solution
'SIR97(Cascarano al.,Acta Cryst.,1996,A52,C-79)'
_diffrn_ambient_temperature      293
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71069
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_exptl_absorpt_coefficient_mu    13.085
_exptl_crystal_density_diffrn    3.777
_exptl_crystal_F_000             2664
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   6.919
_refine_ls_goodness_of_fit_obs   6.919
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           Full
_refine_ls_number_parameters     280
_refine_ls_number_reflns         2699
_refine_ls_R_factor_all          .058
_refine_ls_R_factor_obs          .058
_refine_ls_shift/esd_max         .019
_refine_ls_shift/esd_mean        .001
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     W=1.0
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         .078
_refine_ls_wR_factor_obs         .078
_reflns_limit_h_max              13
_reflns_limit_h_min              0
_reflns_limit_k_max              25
_reflns_limit_k_min              0
_reflns_limit_l_max              18
_reflns_limit_l_min              -18
_reflns_number_observed          2699
_reflns_number_total             3345
_reflns_observed_criterion       ' F >4.0 sigma(F) '
_cod_depositor_comments
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The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'W=1.0' was changed to 'calc'.
New tag '_refine_ls_weighting_details' was created. The value of the
new tag was set to 'W=1.0'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
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_cod_original_formula_sum        H44C32N12O8Cl8Pt2
_cod_database_code               4300047