A simple, general synthesis of mixed d‒f complexes containing both {Re(CO)3Cl(diimine)} and lanthanide-tris(β-diketonate) luminophores linked by bis-diimine bridging ligands
Nail M. Shavaleev; Zöe R. Bell; Michael D. Ward; J. Chem. Soc., Dalton Trans.  (2002) 3925–3927; doi:10.1039/b207832e

data_7012138
_publ_section_title
;
 A simple, general synthesis of mixed d--f complexes containing both
 {Re(CO)3Cl(diimine)} and lanthanide-tris(\b-diketonate) luminophores
 linked by bis-diimine bridging ligands
;
_journal_issue                   21
_journal_name_full               'J. Chem. Soc., Dalton Trans.'
_journal_page_first              3925
_journal_page_last               3927
_journal_paper_doi               10.1039/b207832e
_journal_year                    2002
_chemical_formula_sum            'C41 H36 Cl Er F21 N4 O9 Re'
_chemical_formula_weight         1516.65
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                81.475(17)
_cell_angle_beta                 88.39(2)
_cell_angle_gamma                83.33(2)
_cell_formula_units_Z            2
_cell_length_a                   11.756(4)
_cell_length_b                   12.029(3)
_cell_length_c                   18.647(5)
_cell_measurement_temperature    173(2)
_cell_volume                     2590.0(13)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Siemens SMART Area Detector'
_diffrn_measurement_method
'\w rotation with narrow frames (0.3 degrees)'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1108
_diffrn_reflns_av_sigmaI/netI    0.1411
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            23986
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.72
_exptl_absorpt_coefficient_mu    4.126
_exptl_absorpt_correction_T_max  0.80
_exptl_absorpt_correction_T_min  0.27
_exptl_absorpt_correction_type   'Empirical, pseudo-azimuthal scan (SADABS)'
_exptl_crystal_colour            clear
_exptl_crystal_density_diffrn    1.945
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1462
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.274
_refine_diff_density_min         -1.713
_refine_diff_density_rms         0.199
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.937
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     698
_refine_ls_number_reflns         9114
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.937
_refine_ls_R_factor_all          0.1125
_refine_ls_R_factor_gt           0.0565
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0465P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1040
_refine_ls_wR_factor_ref         0.1227
_reflns_number_gt                5556
_reflns_number_total             9114
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b207832e.txt
_cod_data_source_block           snoopys
_cod_original_cell_volume        2589.9(13)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7012138