Gold(I)-catalyzed polycyclization of linear dienediynes to seven-membered ring-containing polycycles via tandem cyclopropanation/Cope rearrangement/C-H activation.
Cai, Pei-Jun; Wang, Yi; Liu, Cheng-Hang; Yu, Zhi-Xiang; Organic letters 16 (2014) 5898–5901; doi:10.1021/ol5028706

data_1518272
_publ_section_title
;
 Gold(I)-catalyzed polycyclization of linear dienediynes to seven-membered
 ring-containing polycycles via tandem cyclopropanation/Cope
 rearrangement/C-H activation.
;
_journal_issue                   22
_journal_name_full               'Organic letters'
_journal_page_first              5898
_journal_page_last               5901
_journal_paper_doi               10.1021/ol5028706
_journal_volume                  16
_journal_year                    2014
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'calc w=1/[\s^2^(Fo^2^)+(0.0300P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
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;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_refine_ls_hydrogen_treatment' value 'CONSTR' changed
to 'constr' according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 

 Adding full bibliography for 1518272.cif.
;
_cod_original_cell_volume        1963.6(10)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1518272