Facile C-H Bond Metathesis Mediated by a Stannylene.
Lai, Ting Yi; Fettinger, James C.; Power, Philip P.; Journal of the American Chemical Society 140 (2018) 5674–5677; doi:10.1021/jacs.8b01878

data_4132151
_publ_section_title
;
 Facile C-H Bond Metathesis Mediated by a Stannylene.
;
_journal_issue                   17
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5674
_journal_page_last               5677
_journal_paper_doi               10.1021/jacs.8b01878
_journal_volume                  140
_journal_year                    2018
_chemical_formula_moiety         'C74 H88 Sn2, 2(C7 H8)'
_chemical_formula_sum            'C88 H104 Sn2'
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_computing_cell_refinement       'SAINT (8.37a) (Bruker, 2016)'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_exptl_absorpt_correction_T_min  0.7427
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_exptl_absorpt_process_details   'SADABS 2016/2 (Sheldrick, 2016)'
_exptl_crystal_colour            Red
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_exptl_crystal_F_000             732
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0309P)^2^+0.5971P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0597
_refine_ls_wR_factor_ref         0.0608
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10639
_reflns_number_total             11466
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja8b01878_si_002.cif
_cod_data_source_block           CL033FMI
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_database_code               4132151
_shelx_shelxl_version_number     2017/1
_shelx_estimated_absorpt_t_min   0.740
_shelx_estimated_absorpt_t_max   0.844
_shelx_res_checksum              3454
_shelx_hkl_checksum              45050