Unusual κ1 coordination of a β-diketiminate ligand in niobium complexes.
Ziegler, Jessica A.; Bergman, Robert G.; Arnold, John; Dalton transactions (Cambridge, England : 2003) 45 (2016) 12661–12668; doi:10.1039/c6dt02373h

data_7040066
_publ_section_title
;
 Unusual \k1 coordination of a \b-diketiminate ligand in niobium
 complexes.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12661
_journal_page_last               12668
_journal_paper_doi               10.1039/c6dt02373h
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C38 H55 Cl N3 Nb'
_chemical_formula_weight         682.21
_chemical_name_common            (BDI)CpClNb(NtBu)
_chemical_properties_physical    ', Air-sensitive,Moisture-sensitive'
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_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
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_audit_update_record
;
2016-07-14 deposited with the CCDC.
2016-07-18 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_full 0.998
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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'Re-crystallisation from solvent: Pentane'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0289P)^2^+18.9646P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7040063--7040066.cif.'
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