Formation of Mono(dithiolene)-Thiocarboxamido Complexes in Reactions of Thio(dithiocarbamato)-Mo/W Complexes and Dimethyl Acetylenedicarboxylate
Patrick J. Lim; Damian A. Slizys; Edward R. T. Tiekink; Charles G. Young; Inorganic Chemistry 44 (2005) 114–121; doi:10.1021/ic048882g

data_4308339
_publ_section_title
;
Formation of Mono(dithiolene)-Thiocarboxamido Complexes in Reactions of
Thio(dithiocarbamato)-Mo/W Complexes and Dimethyl Acetylenedicarboxylate
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              114
_journal_page_last               121
_journal_paper_doi               10.1021/ic048882g
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C22 H33 B N7 Mo O2 S2 '
_chemical_formula_sum            'C22 H33 B Mo N7 O2 S2'
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_cell_angle_beta                 82.038(1)
_cell_angle_gamma                62.051(1)
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_cell_length_a                   10.0501(2)
_cell_length_b                   10.1181(2)
_cell_length_c                   14.7404(3)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    123
_cell_measurement_theta_max      0.0
_cell_measurement_theta_min      0.0
_cell_volume                     1307.98(5)
_computing_cell_refinement       'Denzo-SMN (1997)'
_computing_data_collection       'collect (1998)'
_computing_data_reduction        'teXsan (MSC, 1992-1997)'
_computing_publication_material  'teXsan (MSC, 1992-1997)'
_computing_structure_refinement  'teXsan (MSC, 1992-1997)'
_diffrn_ambient_temperature      123
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       '/f scans'
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_diffrn_orient_matrix_UB_33      0.00000
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_reduction_process 'Lp corrections applied'
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_diffrn_reflns_theta_min         3.4
_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.694
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            olive
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_exptl_crystal_density_meas      ?
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_refine_ls_R_factor_gt           0.035
_refine_ls_shift/su_max          <0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo)]'
_refine_ls_weighting_scheme      sigma
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_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            ic048882gsi20040817_084428_3.cif
_cod_data_source_block           Tp*Mo(S2CNEt2)(CO)2
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C22 H33 B N7 Mo O2 S2 '
_cod_database_code               4308339