Effect of the heteroatom on the magnetic and luminescence properties of hybrid lanthanide-substituted Keggin-type polyoxometalates.
Bustamante-Fernández, Janire; Ruiz-Bilbao, Estibaliz; Rodríguez-Esteban, Corina; Gonidec, Mathieu; García, José A; Lezama, Luis; Gutiérrez-Zorrilla, Juan M; Oyarzabal, Itziar; Artetxe, Beñat; Dalton transactions (Cambridge, England : 2003) 53 (2024) 13330–13334; doi:10.1039/d4dt01379d

data_7716725
_publ_section_title
;
 Effect of the heteroatom on the magnetic and luminescence properties of
 hybrid lanthanide-substituted Keggin-type polyoxometalates.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13330
_journal_page_last               13334
_journal_paper_doi               10.1039/d4dt01379d
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         'C20 H22 Br2 Ge K3.8 N2 O49.4 Tm W11, 6.6(O)'
_chemical_formula_sum            'C20 H50 Br2 Ge K5 N2 O57 Tm W11'
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_audit_update_record
;
2024-04-26 deposited with the CCDC.	2024-07-25 downloaded from the CCDC.
;
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'CrysAlisPro convention (1999,Acta A55,543-557)'
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_diffrn_source                   'micro-focus sealed X-ray tube'
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;
        CrysAlisPro 1.171.40.67a (Rigaku Oxford Diffraction, 2019)
        Numerical absorption correction based on gaussian integration over
                        a multifaceted crystal model
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0737P)^2^+222.4484P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 7716716--7716725.cif.'
_cod_original_cell_volume        13259.3(4)
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