The Gilded Edge in Acetylenic Scaffolding: Pd-Catalyzed Cross-Coupling Reactions of Phosphine-Gold(I) Oligoynyl Complexes.
Mazzanti, Virginia; Jiang, Huixin; Gotfredsen, Henrik; Morsing, Thorbjørn J; Parker, Christian R.; Nielsen, Mogens Brøndsted; Organic letters 16 (2014) 3736–; doi:10.1021/ol5015587

data_1517023
_publ_section_title
;
 The Gilded Edge in Acetylenic Scaffolding: Pd-Catalyzed Cross-Coupling
 Reactions of Phosphine-Gold(I) Oligoynyl Complexes.
;
_journal_issue                   14
_journal_name_full               'Organic letters'
_journal_page_first              3736
_journal_paper_doi               10.1021/ol5015587
_journal_volume                  16
_journal_year                    2014
_chemical_formula_moiety         'C58 H37.31 Au2 N2 O4 P2, 1.7(C H2 Cl2)'
_chemical_formula_sum            'C59.7 H40.71 Au2 Cl3.4 N2 O4 P2'
_chemical_formula_weight         1426.53
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             2014-05-28
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Olex2 1.2
(compiled 2014.03.20 svn.r2918 for OlexSys, GUI svn.r4816)
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;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.0849 before and 0.0569 after correction.
The Ratio of minimum to maximum transmission is 0.7103.
The \l/2 correction factor is 0.0000.
;
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'w=1/[\s^2^(Fo^2^)+(0.0339P)^2^+8.5662P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 1517022--1517023.cif.'
_cod_database_code               1517023