Silver(i), gold(i) and palladium(ii) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues.
Vaughan, Jamila; Carter, Damien J.; Rohl, Andrew L.; Ogden, Mark I.; Skelton, Brian W.; Simpson, Peter V.; Brown, David H.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 1484–1495; doi:10.1039/c5dt04213e

data_7037480
_publ_section_title
;
 Silver(i), gold(i) and palladium(ii) complexes of a NHC-pincer ligand
 with an aminotriazine core: a comparison with pyridyl analogues.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1484
_journal_page_last               1495
_journal_paper_doi               10.1039/c5dt04213e
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C87 H108 Au4 Br Cl N24, 2(F6 P), 2(C2 H3 N)'
_chemical_formula_sum            'C91 H114 Au4 Br Cl F12 N26 P2'
_chemical_formula_weight         2765.24
_space_group_IT_number           14
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_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
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;
2015-10-13 deposited with the CCDC.
2015-11-23 downloaded from the CCDC.
;
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_cell_formula_units_Z            4
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;
        CrysAlisPro, Oxford Diffraction Ltd.,
        Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
        (compiled Nov  6 2009,16:24:50)
;
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        CrysAlisPro, Oxford Diffraction Ltd.,
        Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
        (compiled Nov  6 2009,16:24:50)
;
_computing_data_reduction
;
        CrysAlisPro, Oxford Diffraction Ltd.,
        Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
        (compiled Nov  6 2009,16:24:50)
;
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_diffrn_measurement_device       'four-circle diffractometer'
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;
        CrysAlis RED, Oxford Diffraction Ltd.
;
_exptl_crystal_colour            colourless
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0668P)^2^+76.0916P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                18091
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt04213e2.cif
_cod_data_source_block           dbja52
_cod_depositor_comments
'Adding full bibliography for 7037477--7037482.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7037480
_shelx_res_checksum              2251
_shelx_hkl_checksum              84658