Conversion of [Pt(SRf)2(PPh2 ? n(C6F5)n + 1)2] ( n = 0 or 1, Rf?C6HF4-4) through carbon?fluorine bond activation to [Pt(SRf)2(1,2-C6F4(SRf)-(PPh2))] and chiral [Pt(SRf)2(1,2-C6F4(SRf)(PPh(C6F5)))]Electronic Supplementary Information (ESI) available: experimental procedures and spectral data for all new compounds and crystallographic data for 5, 8 and 10. http://www.rsc.org/suppdata/cc/b4/b407328b/
Villanueva, Luis; Arroyo, Maribel; Bern�s, Sylvain; Torrens, Hugo; Chemical Communications  (2004) 1942–1943; doi:10.1039/b407328b

data_7111364
_publ_section_title
;
 Conversion of [Pt(SRf)2(PPh2 ? n(C6F5)n + 1)2] ( n = 0 or 1, Rf?C6HF4-4)
 through carbon?fluorine bond activation to
 [Pt(SRf)2(1,2-C6F4(SRf)-(PPh2))] and chiral
 [Pt(SRf)2(1,2-C6F4(SRf)(PPh(C6F5)))]Electronic Supplementary Information
 (ESI) available: experimental procedures and spectral data for all new
 compounds and crystallographic data for 5, 8 and 10.
 http://www.rsc.org/suppdata/cc/b4/b407328b/
;
_journal_issue                   17
_journal_name_full               'Chemical Communications'
_journal_page_first              1942
_journal_page_last               1943
_journal_paper_doi               10.1039/b407328b
_journal_year                    2004
_chemical_formula_moiety         'C36 H8 F21 P Pt S3'
_chemical_formula_sum            'C36 H8 F21 P Pt S3'
_chemical_formula_weight         1161.66
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2003-06-02
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.898(8)
_cell_angle_beta                 107.898(7)
_cell_angle_gamma                105.595(7)
_cell_formula_units_Z            2
_cell_length_a                   11.8338(10)
_cell_length_b                   12.4575(14)
_cell_length_c                   14.5848(13)
_cell_measurement_reflns_used    88
_cell_measurement_temperature    296(1)
_cell_measurement_theta_max      13.01
_cell_measurement_theta_min      4.70
_cell_volume                     1921.9(4)
_computing_cell_refinement       'XSCAnS 2.21 (Fait, 1996)'
_computing_data_collection       'XSCAnS 2.21 (Fait, 1996)'
_computing_data_reduction        'XSCAnS 2.21 (Fait, 1996)'
_computing_molecular_graphics    'SHELXTL 5.10 (Sheldrick, 1998)'
_computing_publication_material  'SHELX97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELX97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXTL 5.10 (Sheldrick, 1998)'
_diffrn_ambient_temperature      296(1)
_diffrn_detector                 'Scintillation counter'
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0295
_diffrn_reflns_av_sigmaI/netI    0.0403
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            13307
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.74
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_current           30
_diffrn_source_power             1.5
_diffrn_source_voltage           50
_diffrn_standards_decay_%        1.5
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.986
_exptl_absorpt_correction_T_max  0.888
_exptl_absorpt_correction_T_min  0.480
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '50 psi scans with XSCAnS 2.21 (Fait, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.007
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1108
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.595
_refine_diff_density_min         -1.253
_refine_diff_density_rms         0.088
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     559
_refine_ls_number_reflns         6727
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0460
_refine_ls_R_factor_gt           0.0348
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0452P)^2^+1.0207P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0798
_refine_ls_wR_factor_ref         0.0849
_reflns_number_gt                5688
_reflns_number_total             6727
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            b407328bsup1.cif
_cod_data_source_block           lv104-3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        1921.9(3)
_cod_database_code               7111364