Reactivity of Bulky Formamidinatosamarium(II or III) Complexes with C═O and C═S Bonds.
Deacon, Glen B.; Junk, Peter C.; Wang, Jun; Werner, Daniel; Inorganic chemistry  (2014) 141110081832000–; doi:10.1021/ic502181g

data_4341601
_publ_section_title
;
 Reactivity of Bulky Formamidinatosamarium(II or III) Complexes with
 C&#x2550;O and C&#x2550;S Bonds.
;
_journal_name_full               'Inorganic chemistry'
_journal_page_first              141110081832000
_journal_paper_doi               10.1021/ic502181g
_journal_year                    2014
_chemical_formula_moiety         'C74.50 H87 N4 O Sm'
_chemical_formula_sum            'C74.5 H87 N4 O Sm'
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_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
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_cell_measurement_temperature    123(1)
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_computing_cell_refinement       'DENZO-SMN (Otwinowski & Minor, 1997)'
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
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_exptl_crystal_colour            'light yellow'
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_exptl_crystal_description       rods
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0995
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_cod_data_source_file            ic502181g_si_001.cif
_cod_data_source_block           Compound7
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Empirical' changed to
'empirical' according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 
;
_cod_original_cell_volume        3233.7(11)
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C74.50 H87 N4 O Sm'
_cod_database_code               4341601