Solvatomorphism, CO2 adsorption and luminescence properties of non-aromatic bis-hydroxamate-based metal–organic frameworks
Ushakov, Daniil A.; Ryadun, Alexey A.; Kovalenko, Konstantin A.; Kirilyuk, Igor A.; Demakov, Pavel A.; Fedin, Vladimir P.; CrystEngComm 27 (2025) 4699–4706; doi:10.1039/D5CE00383K

data_7250460
_publ_section_title
;
 Solvatomorphism, CO2 adsorption and luminescence properties of
 non-aromatic bis-hydroxamate-based metal--organic frameworks
;
_journal_issue                   27
_journal_name_full               CrystEngComm
_journal_page_first              4699
_journal_page_last               4706
_journal_paper_doi               10.1039/D5CE00383K
_journal_volume                  27
_journal_year                    2025
_chemical_formula_sum            'C24 H46 N4 O16 Tb2'
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_audit_update_record
;
2025-02-26 deposited with the CCDC.	2025-05-26 downloaded from the CCDC.
;
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_diffrn_measurement_device       'four-circle diffractometer'
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_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_av_unetI/netI     0.0386
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.123a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.810
_exptl_crystal_description       prism
_exptl_crystal_F_000             476
_exptl_crystal_preparation       Luminescent
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_refine_ls_restrained_S_all      1.005
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0173P)^2^+1.2081P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0495
_refine_ls_wR_factor_ref         0.0521
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3537
_reflns_number_total             3886
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5ce00383k2.cif
_cod_data_source_block           ud22-3_auto
_cod_depositor_comments
'Adding full bibliography for 7250459--7250460.cif.'
_cod_database_code               7250460
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.530
_shelx_estimated_absorpt_t_max   0.688
_shelx_res_checksum              21571