AgSbF6-Catalyzed anti-Markovnikov Hydroboration of Terminal Alkynes
Mamidala, Ramesh; Pandey, Vipin Kumar; RIT, ARNAB; Chemical Communications  (2018) –; doi:10.1039/C8CC07499B

data_7122766
_publ_section_title
;
 AgSbF6-Catalyzed anti-Markovnikov Hydroboration of Terminal Alkynes
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/C8CC07499B
_journal_year                    2018
_chemical_formula_moiety         'C18 H27 B O2'
_chemical_formula_sum            'C18 H27 B O2'
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-08-22 deposited with the CCDC.
2018-12-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_cell_measurement_temperature    296(2)
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_radiation_type           MoK\a
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_exptl_absorpt_process_details   'SADABS V2014/5(Bruker AXS.Inc)'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1207P)^2^+18.3356P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             9239
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           1
_cod_original_cell_volume        5258.2(9)
_cod_database_code               7122766
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.983
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