Unprecedented Boron-Functionalized Carborane Derivatives by Facile and Selective Cobalt-Induced B-H Activation
Zhaojin Wang; Hongde Ye; Yuguang Li; Yizhi Li; Hong Yan; Journal of the American Chemical Society 135 (2013) 11289–11298; doi:10.1021/ja4047075

data_4120205
_publ_section_title
;
 Unprecedented Boron-Functionalized Carborane Derivatives by Facile and
 Selective Cobalt-Induced B-H Activation
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11289
_journal_page_last               11298
_journal_paper_doi               10.1021/ja4047075
_journal_volume                  135
_journal_year                    2013
_chemical_formula_moiety         'C16 H23 B10 Co O S2'
_chemical_formula_sum            'C16 H23 B10 Co O S2'
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_chemical_name_systematic
; 
 ? 
;
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_computing_data_collection       'SMART (Bruker, 2000)'
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_diffrn_ambient_temperature      293(2)
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_diffrn_measurement_method       'phi and omega scans'
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_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Dark-brown
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0828P)^2^+1.8918P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja4047075_si_001_05.cif
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