Iridium-catalyzed C3-selective asymmetric allylation of 7-azaindoles with secondary allylic alcohols.
Sawano, Takahiro; Matsui, Takeshi; Koga, Marina; Ishikawa, Eri; Takeuchi, Ryo; Chemical communications (Cambridge, England) 57 (2021) 9684–9687; doi:10.1039/d1cc03968g

data_7128920
_publ_section_title
;
 Iridium-catalyzed C3-selective asymmetric allylation of 7-azaindoles with
 secondary allylic alcohols.
;
_journal_issue                   76
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              9684
_journal_page_last               9687
_journal_paper_doi               10.1039/d1cc03968g
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C12 H10 F6 N2 O4'
_chemical_formula_sum            'C12 H10 F6 N2 O4'
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_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2021-04-26 deposited with the CCDC.	2021-09-01 downloaded from the CCDC.
;
_cell_angle_alpha                115.47(2)
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_computing_structure_solution    'SHELXT Version 2018/2 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296
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_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
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_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
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'w = 1/[\s^2^(Fo^2^)+(0.1140P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 7128920--7128921.cif.'
_cod_original_cell_volume        745.9(8)
_cod_database_code               7128920
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