Stereocontrol in nucleophilic substitution reactions at silicon: the role of permutation in generating silicon-centered chirality.
Bauer, Jonathan O.; Strohmann, Carsten; Journal of the American Chemical Society 137 (2015) 4304–4307; doi:10.1021/jacs.5b00861

data_4129346
_publ_section_title
;
 Stereocontrol in nucleophilic substitution reactions at silicon: the role
 of permutation in generating silicon-centered chirality.
;
_journal_issue                   13
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              4304
_journal_page_last               4307
_journal_paper_doi               10.1021/jacs.5b00861
_journal_volume                  137
_journal_year                    2015
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;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.37 (release 24-10-2008 CrysAlis171 .NET)
(compiled Oct 24 2008,09:44:38)'
;
_computing_data_collection
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.32.37 (release 24-10-2008 CrysAlis171 .NET)
(compiled Oct 24 2008,09:44:38)
;
_computing_data_reduction
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CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.37 (release 24-10-2008 CrysAlis171 .NET)
(compiled Oct 24 2008,09:44:38)
;
_computing_molecular_graphics
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Ortep-3 (Farrugia, 1997) and Schakal 92
 (Keller 1992)
;
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_diffrn_radiation_type           MoK\a
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;
CrysAlis RED, Oxford Diffraction Ltd. Empirical absorption correction using
spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.
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_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0618P)^2^+1.1218P] where P=(Fo^2^+2Fc^2^)/3'
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