Union is strength: π–π stacking interactions are capable of preventing solid-state racemization of tris-chelate complexes
Gavrikov, Andrey V.; Ilyukhin, Andrey B.; CrystEngComm 26 (2024) 1677–1682; doi:10.1039/D4CE00104D

data_7248147
_publ_section_title
;
 Union is strength: \p--\p stacking interactions are capable of preventing
 solid-state racemization of tris-chelate complexes
;
_journal_issue                   12
_journal_name_full               CrystEngComm
_journal_page_first              1677
_journal_page_last               1682
_journal_paper_doi               10.1039/D4CE00104D
_journal_volume                  26
_journal_year                    2024
_chemical_formula_moiety         'C36 H24 Co N6, Dy N5 O15'
_chemical_formula_sum            'C36 H24 Co Dy N11 O15'
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_audit_update_record
;
2023-09-15 deposited with the CCDC.	2024-02-14 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_exptl_absorpt_process_details   'SADABS 2014/5'
_exptl_crystal_colour            yellow
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_exptl_crystal_description       block
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0400P)^2^+1.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0699
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_reflns_number_gt                10670
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7248144--7248174.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7248147
_shelx_res_checksum              52811