Reactivity of Quinoline-8-carbaldehyde toward Platina-β-diketone and Acetyl(amine)platinum(II) Complexes. Formation of Acyl(hydroxyalkyl)platinum(IV)
Zumeta, Itziar; Kluge, Tim; Mendicute-Fierro, Claudio; Wagner, Cristoph; Ibarlucea, Lourdes; Rüffer, Tobias; San Nacianceno, Virginia; Steinborn, Dirk; Garralda, María A.; Organometallics 33 (2014) 788–; doi:10.1021/om4011774

data_4082465
_publ_section_title
;
 Reactivity of Quinoline-8-carbaldehyde toward Platina-\b-diketone and
 Acetyl(amine)platinum(II) Complexes. Formation of
 Acyl(hydroxyalkyl)platinum(IV)
;
_journal_issue                   3
_journal_name_full               Organometallics
_journal_page_first              788
_journal_paper_doi               10.1021/om4011774
_journal_volume                  33
_journal_year                    2014
_chemical_formula_moiety         'C22 H17 Cl N2 O3 Pt, 2(C H Cl3)'
_chemical_formula_sum            'C24 H19 Cl7 N2 O3 Pt'
_chemical_formula_weight         826.65
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.378(6)
_cell_angle_beta                 96.434(6)
_cell_angle_gamma                114.039(5)
_cell_formula_units_Z            2
_cell_length_a                   9.3775(7)
_cell_length_b                   10.5872(7)
_cell_length_c                   15.4558(11)
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      29.75
_cell_measurement_theta_min      2.58
_cell_volume                     1386.13(18)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.963
_diffrn_measured_fraction_theta_max 0.963
_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0348
_diffrn_reflns_av_sigmaI/netI    0.0334
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            8603
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.58
_exptl_absorpt_coefficient_mu    5.767
_exptl_absorpt_correction_T_max  0.21905
_exptl_absorpt_correction_T_min  0.10759
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Spek, A.L. (2009). Acta Cryst. D65, 148-155.'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.981
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             796
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.19
_refine_diff_density_max         1.312
_refine_diff_density_min         -1.574
_refine_diff_density_rms         0.157
_refine_ls_extinction_coef       0.0029(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     338
_refine_ls_number_reflns         4693
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.097
_refine_ls_R_factor_all          0.0303
_refine_ls_R_factor_gt           0.0276
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0556P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0779
_refine_ls_wR_factor_ref         0.0808
_reflns_number_gt                4229
_reflns_number_total             4693
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om4011774_si_001.cif
_cod_data_source_block           complex_3
_cod_original_cell_volume        1386.13(17)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4082465