On the σ-complex character of bis(gallyl)/digallane transition metal species.
Kalkuhl, Till L.; Qin, Lei; Zhao, Lili; Frenking, Gernot; Hadlington, Terrance J.; Chemical science 14 (2023) 11088–11095; doi:10.1039/d3sc03772j

data_1569923
_publ_section_title
;
 On the &#x3c3;-complex character of bis(gallyl)/digallane transition
 metal species.
;
_journal_issue                   40
_journal_name_full               'Chemical science'
_journal_page_first              11088
_journal_page_last               11095
_journal_paper_doi               10.1039/d3sc03772j
_journal_volume                  14
_journal_year                    2023
_chemical_formula_moiety         'C31 H43 Cl2 Ga N P Si'
_chemical_formula_sum            'C31 H43 Cl2 Ga N P Si'
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_audit_update_record
;
2023-05-30 deposited with the CCDC.	2023-09-22 downloaded from the CCDC.
;
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_refine_ls_restrained_S_all      1.074
_refine_ls_R_factor_all          0.0444
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0578P)^2^+0.1503P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             6369
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 1569923--1569928.cif.'
_cod_database_code               1569923
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_shelx_res_checksum              92853
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