Elementorganisch substituierte Ammonium-Salze. Die Kristallstrukturen von [HN(SnMe~3~)~3~]I, [H~2~N(SnMe~3~)~2~][SnMe~3~Cl~2~] und [N(AsMe~3~)~2~]Br
Hillwig, R.; Harms, K.; Dehnicke, K.; Müller, U.; Zeitschrift fuer Anorganische und Allgemeine Chemie 623 (1997) 676–682; doi:10.1002/zaac.199762301107

data_1100453
_publ_section_title
;
 Elementorganisch substituierte Ammonium-Salze. Die Kristallstrukturen von
 [HN(SnMe~3~)~3~]I, [H~2~N(SnMe~3~)~2~][SnMe~3~Cl~2~] und [N(AsMe~3~)~2~]Br
;
_journal_coden_ASTM              ZAACAB
_journal_issue                   1-6
_journal_name_full
;
 Zeitschrift fuer Anorganische und Allgemeine Chemie
;
_journal_page_first              676
_journal_page_last               682
_journal_paper_doi               10.1002/zaac.199762301107
_journal_volume                  623
_journal_year                    1997
_chemical_formula_sum            'C9 H28 I N Sn3'
_space_group_IT_number           198
_symmetry_cell_setting           cubic
_symmetry_Int_Tables_number      198
_symmetry_space_group_name_Hall  'P 2ac 2ab 3'
_symmetry_space_group_name_H-M   'P 21 3'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   15.587(3)
_cell_length_b                   15.587(3)
_cell_length_c                   15.587(3)
_cod_depositor_comments
;

  Following symmetrically equivalent atoms were removed in order to
  leave only atoms from asymmetric unit:

  Sn1E* Sn 0.53269(4) 0.28237(4) -0.16572(4)
  C1E* C 0.5345(7) 0.2325(5) -0.2936(7)
  H3E* H 0.5472(7) 0.1722(5) -0.2920(7)
  H4E* H 0.5777(7) 0.2617(5) -0.3263(7)
  H5E* H 0.4795(7) 0.2412(5) -0.3198(7)
  C2E* C 0.4501(6) 0.3849(7) -0.1342(6)
  H6E* H 0.4832(6) 0.4323(7) -0.1129(6)
  H7E* H 0.4103(6) 0.3666(7) -0.0909(6)
  H8E* H 0.4191(6) 0.4025(7) -0.1844(6)
  C3E* C 0.5339(6) 0.1825(6) -0.0730(6)
  H9E* H 0.4760(6) 0.1669(6) -0.0587(6)
  H10E* H 0.5631(6) 0.2017(6) -0.0223(6)
  H11E* H 0.5631(6) 0.1335(6) -0.0962(6)
  Sn1J* Sn 0.66572(4) 0.46731(4) -0.21763(4)
  C1J* C 0.7936(7) 0.4655(5) -0.2675(7)
  H3J* H 0.7920(7) 0.4528(5) -0.3278(7)
  H4J* H 0.8263(7) 0.4223(5) -0.2383(7)
  H5J* H 0.8198(7) 0.5205(5) -0.2588(7)
  C2J* C 0.6342(6) 0.5499(7) -0.1151(6)
  H6J* H 0.6129(6) 0.5168(7) -0.0677(6)
  H7J* H 0.5909(6) 0.5897(7) -0.1334(6)
  H8J* H 0.6844(6) 0.5809(7) -0.0975(6)
  C3J* C 0.5730(6) 0.4661(6) -0.3175(6)
  H9J* H 0.5587(6) 0.5240(6) -0.3331(6)
  H10J* H 0.5223(6) 0.4369(6) -0.2983(6)
  H11J* H 0.5962(6) 0.4369(6) -0.3665(6)
  Sn2E* Sn 0.46673(5) 0.71415(4) 0.17890(5)
  C4E* C 0.4439(7) 0.8472(8) 0.1762(8)
  H12E* H 0.4441(7) 0.8690(8) 0.2338(8)
  H13E* H 0.3890(7) 0.8578(8) 0.1504(8)
  H14E* H 0.4878(7) 0.8753(8) 0.1435(8)
  C5E* C 0.5341(8) 0.6567(7) 0.0780(6)
  H15E* H 0.5372(8) 0.6955(7) 0.0302(6)
  H16E* H 0.5051(8) 0.6052(7) 0.0608(6)
  H17E* H 0.5911(8) 0.6428(7) 0.0968(6)
  C6E* C 0.5057(9) 0.6742(7) 0.3019(7)
  H18E* H 0.4713(9) 0.7028(7) 0.3443(7)
  H19E* H 0.5650(9) 0.6886(7) 0.3104(7)
  H20E* H 0.4984(9) 0.6133(7) 0.3073(7)
  Sn2J* Sn 0.32110(5) 0.53327(4) 0.21415(5)
  C4J* C 0.3238(7) 0.5561(8) 0.3472(8)
  H12J* H 0.2662(7) 0.5559(8) 0.3690(8)
  H13J* H 0.3496(7) 0.6110(8) 0.3578(8)
  H14J* H 0.3565(7) 0.5122(8) 0.3753(8)
  C5J* C 0.4220(8) 0.4659(7) 0.1567(6)
  H15J* H 0.4698(8) 0.4628(7) 0.1955(6)
  H16J* H 0.4392(8) 0.4949(7) 0.1052(6)
  H17J* H 0.4032(8) 0.4089(7) 0.1428(6)
  C6J* C 0.1981(9) 0.4943(7) 0.1742(7)
  H18J* H 0.1557(9) 0.5287(7) 0.2028(7)
  H19J* H 0.1896(9) 0.4350(7) 0.1886(7)
  H20J* H 0.1927(9) 0.5016(7) 0.1133(7)

  Andrius Merkys
  2013-11-12
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_cod_original_formula_sum        'C9 H28 I1 N1 Sn3'
_cod_database_code               1100453