Preparation and reactivity of diazoalkane complexes of ruthenium stabilised by an indenyl ligand.
Albertin, Gabriele; Antoniutti, Stefano; Castro, Jesús; Dottorello, Gianluca; Dalton transactions (Cambridge, England : 2003) 44 (2015) 9289–9303; doi:10.1039/c5dt00755k

data_7035035
_publ_section_title
;
 Preparation and reactivity of diazoalkane complexes of ruthenium
 stabilised by an indenyl ligand.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9289
_journal_page_last               9303
_journal_paper_doi               10.1039/c5dt00755k
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C59 H58 O3 P3 Ru, C24 H20 B'
_chemical_formula_sum            'C83 H78 B O3 P3 Ru'
_chemical_formula_weight         1328.24
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/6
_audit_update_record
;
2015-02-18 deposited with the CCDC.
2015-04-13 downloaded from the CCDC.
;
_cell_angle_alpha                72.786(9)
_cell_angle_beta                 76.549(9)
_cell_angle_gamma                71.730(9)
_cell_formula_units_Z            2
_cell_length_a                   11.0701(19)
_cell_length_b                   17.550(3)
_cell_length_c                   20.754(3)
_cell_measurement_reflns_used    8618
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      66.46
_cell_measurement_theta_min      2.26
_cell_volume                     3613.6(10)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.943
_diffrn_measured_fraction_theta_max 0.916
_diffrn_measurement_device_type  'Bruker CCD Smart 6000'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  'Incoatec Quazar MX multilayer optics'
_diffrn_radiation_source         'Incoatec I\muS microsource'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0702
_diffrn_reflns_av_unetI/netI     0.0435
_diffrn_reflns_laue_measured_fraction_full 0.943
_diffrn_reflns_laue_measured_fraction_max 0.916
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            69131
_diffrn_reflns_point_group_measured_fraction_full 0.943
_diffrn_reflns_point_group_measured_fraction_max 0.916
_diffrn_reflns_theta_full        64.000
_diffrn_reflns_theta_max         67.453
_diffrn_reflns_theta_min         2.256
_exptl_absorpt_coefficient_mu    2.746
_exptl_absorpt_correction_T_max  0.7530
_exptl_absorpt_correction_T_min  0.4713
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2012/1 (Bruker AXS Inc.)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.221
_exptl_crystal_description       plate
_exptl_crystal_F_000             1388
_exptl_crystal_size_max          0.308
_exptl_crystal_size_mid          0.249
_exptl_crystal_size_min          0.056
_refine_diff_density_max         1.770
_refine_diff_density_min         -0.816
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.183
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     823
_refine_ls_number_reflns         11910
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.183
_refine_ls_R_factor_all          0.1461
_refine_ls_R_factor_gt           0.1075
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+24.1348P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1926
_refine_ls_wR_factor_ref         0.2173
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8844
_reflns_number_total             11910
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt00755k1.cif
_cod_data_source_block           14d_phosphonium
_cod_depositor_comments
'Adding full bibliography for 7035033--7035035.cif.'
_cod_original_cell_volume        3613.5(11)
_cod_database_code               7035035
_shelx_estimated_absorpt_t_min   0.485
_shelx_estimated_absorpt_t_max   0.861
_shelxl_version_number           2014/6
_shelx_res_checksum              40573