Systematic reductive oligomerization of isocyanides with a vanadium(ii) complex.
Hasegawa, Sui; Ishida, Yutaka; Kawaguchi, Hiroyuki; Chemical communications (Cambridge, England) 57 (2021) 8296–8299; doi:10.1039/d1cc03463d

data_7128700
_publ_section_title
;
 Systematic reductive oligomerization of isocyanides with a vanadium(ii)
 complex.
;
_journal_issue                   67
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              8296
_journal_page_last               8299
_journal_paper_doi               10.1039/d1cc03463d
_journal_volume                  57
_journal_year                    2021
_chemical_formula_moiety         'C42 H50 N2 O2 V, C18 H36 K N2 O6, C4 H8 O'
_chemical_formula_sum            'C64 H94 K N4 O9 V'
_chemical_formula_weight         1153.47
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Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
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2021-04-06 deposited with the CCDC.	2021-07-21 downloaded from the CCDC.
;
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_diffrn_detector                 'Rigaku HyPix-6000 area detector'
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;
List of Runs (angles in degrees, time in seconds):

 # Type Start End Width t~exp~ \w \q \k \f Frames
 1 \w -17.00 43.00 0.50 0.19 -- -38.95 19.00 30.00 120
 2 \w -20.00 43.00 0.50 0.19 -- -38.95 19.00 -90.00 126
 3 \w 8.00 34.00 0.50 0.19 -- -38.95 19.00-180.00 52
 4 \w -15.00 34.00 0.50 0.19 -- -38.95 19.00-120.00 98
 5 \w -37.00 42.00 0.50 0.19 -- -38.95 37.00 -60.00 158
 6 \w -9.00 16.00 0.50 0.19 -- 38.95 -19.00 90.00 50
 7 \w -45.00 -20.00 0.50 0.19 -- 38.95 -19.00 90.00 50
 8 \w 13.00 76.00 0.50 0.19 -- 38.95-118.00 129.00 126
 9 \w 77.00 102.00 0.50 0.19 -- 38.95-159.00 -23.00 50
 10 \w 51.00 119.00 0.50 0.19 -- 38.95-178.00 -90.00 136
 11 \w 37.00 104.00 0.50 0.74 -- 113.00-159.00 -23.00 134
 12 \w 90.00 123.00 0.50 0.74 -- 113.00-139.00 -42.76 66
 13 \w 82.00 108.00 0.50 0.74 -- 113.00-111.00 30.00 52
 14 \w 77.00 108.00 0.50 0.74 -- 113.00-111.00 90.00 62
 15 \w 74.00 108.00 0.50 0.74 -- 113.00-111.00 120.00 68
 16 \w 47.00 72.00 0.50 0.74 -- 113.00-118.00 129.00 50
 17 \w 42.00 75.00 0.50 0.74 -- 113.00 -61.00 60.00 66
 18 \w 78.00 105.00 0.50 0.74 -- 113.00 -94.00 0.00 54
 19 \w 79.00 105.00 0.50 0.74 -- 113.00 -94.00 -60.00 52
 20 \w 64.00 105.00 0.50 0.74 -- 113.00 -94.00-120.00 82
 21 \w 81.00 106.00 0.50 0.74 -- 113.00 -94.00-180.00 50
 22 \w 73.00 108.00 0.50 0.74 -- 113.00-111.00-180.00 70
 23 \w 49.00 103.00 0.50 0.74 -- 113.00 -94.00 -90.00 108
 24 \w 47.00 98.00 0.50 0.74 -- 113.00 -94.00 -30.00 102
 25 \w 43.00 80.00 0.50 0.74 -- 113.00-111.00 0.00 74
 26 \w 38.00 74.00 0.50 0.74 -- 113.00 -61.00 0.00 72
 27 \w 43.00 75.00 0.50 0.74 -- 113.00 -94.00 0.00 64
 28 \w 35.00 73.00 0.50 0.74 -- 113.00 -94.00 -60.00 76
 29 \w 38.00 74.00 0.50 0.74 -- 113.00 -61.00 -90.00 72
 30 \w 33.00 108.00 0.50 0.74 -- 113.00-111.00-150.00 150
 31 \w 39.00 73.00 0.50 0.74 -- 113.00 -61.00-150.00 68
 32 \w 35.00 67.00 0.50 0.74 -- 113.00-111.00-180.00 64
 33 \w 36.00 65.00 0.50 0.74 -- 113.00 -94.00-180.00 58
 34 \w 41.00 75.00 0.50 0.74 -- 113.00 -61.00-180.00 68
 35 \w 33.00 158.00 0.50 0.74 -- 113.00 15.00 -60.00 250
 36 \w 138.00 175.00 0.50 0.74 -- 113.00 61.00 -90.00 74
 37 \w 142.00 167.00 0.50 0.74 -- 113.00 111.00 -90.00 50
 38 \w 137.00 177.00 0.50 0.74 -- 113.00 111.00-180.00 80
 39 \w 109.00 134.00 0.50 0.74 -- 113.00 111.00 -90.00 50
 40 \w 104.00 129.00 0.50 0.74 -- 113.00 118.00-144.00 50
 41 \w 90.00 117.00 0.50 0.74 -- 113.00 61.00 -90.00 54
 42 \w 144.00 177.00 0.50 0.74 -- 113.00 15.00 30.00 66
 43 \w 130.00 178.00 0.50 0.74 -- 113.00 61.00 120.00 96
 44 \w 146.00 178.00 0.50 0.74 -- 113.00 61.00 150.00 64
 45 \w 95.00 121.00 0.50 0.74 -- 113.00 111.00 120.00 52
 46 \w 87.00 178.00 0.50 0.74 -- 113.00 111.00 150.00 182
 47 \w 88.00 114.00 0.50 0.74 -- 113.00 159.00 8.00 52
 48 \w 108.00 134.00 0.50 0.74 -- 113.00 178.00 -60.00 52
 49 \w 57.00 84.00 0.50 0.19 -- 38.95 159.00 8.00 54
 50 \w 47.00 116.00 0.50 0.74 -- 113.00 178.00 -30.00 138
 51 \w 55.00 95.00 0.50 0.74 -- 113.00 178.00 -60.00 80
 52 \w 85.00 121.00 0.50 0.74 -- 113.00 61.00 120.00 72
 53 \w 36.00 138.00 0.50 0.74 -- 113.00 15.00 30.00 204
 54 \w 36.00 106.00 0.50 0.74 -- 113.00-111.00 150.00 140
 55 \w 33.00 64.00 0.50 0.74 -- 113.00-111.00 120.00 62
 56 \w 33.00 71.00 0.50 0.74 -- 113.00-111.00 90.00 76
 57 \w -79.00 -44.00 0.50 0.19 -- -38.95 118.00-144.00 70
 58 \w -72.00 -47.00 0.50 0.74 -- -102.00 141.00-101.84 50
 59 \w -91.00 -65.00 0.50 0.74 -- -102.00 159.00 8.00 52
 60 \w -110.00 -84.00 0.50 0.19 -- -38.95 159.00 8.00 52
 61 \w -107.00 -82.00 0.50 0.74 -- -102.00 102.00-115.20 50
 62 \w -108.00 -80.00 0.50 0.74 -- -102.00 118.00-144.00 56
 63 \w -124.00 -86.00 0.50 0.74 -- -102.00 141.00-101.84 76
 64 \w -108.00 -82.00 0.50 0.74 -- -102.00 111.00 150.00 52
 65 \w -172.00 -65.00 0.50 0.74 -- -102.00 -30.00 0.00 214
 66 \w -113.00 -14.00 0.50 0.19 -- -38.95 -57.00 -30.00 198
;
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'CrysAlisPro convention (1999,Acta A55,543-557)'
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_exptl_absorpt_correction_T_max  1.00000
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'dark green'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
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_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0419
_refine_ls_R_factor_gt           0.0396
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0555P)^2^+1.2315P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                12092
_reflns_number_total             12949
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cc03463d2.cif
_cod_data_source_block           v_ono_cn_k_crypt
_cod_depositor_comments
'Adding full bibliography for 7128700--7128707.cif.'
_cod_original_cell_volume        3121.80(8)
_cod_database_code               7128700