Mechanism of formation of iron(II) complexes with pentadentate ligands via C-C bond formation between trans-[Fe(2,4-bis(2-pyridylmethylimino)pentane)(MeCN)2]ClO4]2.MeCN and various nitriles.
Kurosaki, Hiromasa; Ishikawa, Yoshinobu; Ishihara, Takao; Yamamoto, Teruo; Yamaguchi, Yoshihiro; Goto, Masafumi; Dalton transactions (Cambridge, England : 2003)  (2005) 1086–1092; doi:10.1039/b414207a

data_7007950
_publ_section_title
;
 Mechanism of formation of iron(II) complexes with pentadentate ligands
 via C-C bond formation between
 trans-[Fe(2,4-bis(2-pyridylmethylimino)pentane)(MeCN)2]ClO4]2.MeCN and
 various nitriles.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1086
_journal_page_last               1092
_journal_paper_doi               10.1039/b414207a
_journal_year                    2005
_chemical_formula_sum            'C29 H32 Cl2 Fe N6 O8'
_chemical_formula_weight         719.36
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Tue Sep 14 11:41:38 2004'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                99.28(2)
_cell_angle_beta                 110.98(1)
_cell_angle_gamma                84.53(2)
_cell_formula_units_Z            2
_cell_length_a                   11.597(2)
_cell_length_b                   14.866(4)
_cell_length_c                   9.855(2)
_cell_measurement_reflns_used    17
_cell_measurement_temperature    293.2
_cell_measurement_theta_max      11.3
_cell_measurement_theta_min      10.0
_cell_volume                     1564.3(6)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SAPI91
_diffrn_measured_fraction_theta_full 1.0011
_diffrn_measured_fraction_theta_max 1.0011
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.016
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            7546
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_standards_decay_%        0.22
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.712
_exptl_absorpt_correction_T_max  0.867
_exptl_absorpt_correction_T_min  0.830
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.527
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.40
_refine_diff_density_min         -0.32
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.865
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     401
_refine_ls_number_reflns         3570
_refine_ls_R_factor_gt           0.0529
_refine_ls_shift/su_max          0.0810
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00000|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0392
_reflns_number_gt                3570
_reflns_number_total             7192
_reflns_threshold_expression     F^2^>3.0\s(F^2^)
_cod_data_source_file            b414207a.txt
_cod_data_source_block           mebpy1
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C29 H32 Cl2 Fe N6 O8 '
_cod_database_code               7007950