Aggregation of the Half-Sandwich Trisulfido Complex of Tungsten with Silver Ions: Synthesis of a Cyanide-Bridged Helical Polymer {[(η5-C5Me5)WS3]2Ag3(CN)}∞and a Cyclic Cluster [(η5-C5Me5)WS3Ag]4
Jian-Ping Lang; Kazuyuki Tatsumi; Inorganic Chemistry 38 (1999) 1364–1367; doi:10.1021/ic980883j

data_4321829
_publ_section_title
;
 Aggregation of the Half-Sandwich Trisulfido Complex of Tungsten with
 Silver Ions: Synthesis of a Cyanide-Bridged Helical Polymer
 {[(\h5-C5Me5)WS3]2Ag3(CN)}\\infty and a Cyclic Cluster
 [(\h5-C5Me5)WS3Ag]4
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1364
_journal_page_last               1367
_journal_paper_doi               10.1021/ic980883j
_journal_volume                  38
_journal_year                    1999
_chemical_formula_moiety         'C21 H30 Ag3 N S6 W2 '
_chemical_formula_sum            'C21 H30 Ag3 N S6 W2'
_chemical_formula_weight         1180.14
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_date             'Thu Oct 29 10:50:30 1998'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 109.91(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.415(5)
_cell_length_b                   9.616(6)
_cell_length_c                   21.659(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.9
_cell_volume                     3019(2)
_computing_cell_refinement       'Rigaku/AFC Diffractometer Control'
_computing_data_collection       'Rigaku/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_computing_structure_solution    SHELXS86
_diffrn_ambient_temperature      296.2
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      -0.05926
_diffrn_orient_matrix_UB_12      -0.03806
_diffrn_orient_matrix_UB_13      0.00218
_diffrn_orient_matrix_UB_21      0.03205
_diffrn_orient_matrix_UB_22      -0.08855
_diffrn_orient_matrix_UB_23      0.01901
_diffrn_orient_matrix_UB_31      0.01491
_diffrn_orient_matrix_UB_32      0.03905
_diffrn_orient_matrix_UB_33      0.04522
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.118
_diffrn_reflns_av_sigmaI/netI    0.062
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            5904
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.00
_diffrn_standards_decay_%        -0.44
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    9.935
_exptl_absorpt_correction_T_max  0.980
_exptl_absorpt_correction_T_min  0.361
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            dark-red
_exptl_crystal_density_diffrn    2.597
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2192.00
_exptl_crystal_size_max          0.350
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.150
_refine_diff_density_max         3.30
_refine_diff_density_min         -2.01
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.526
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     298
_refine_ls_number_reflns         3579
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0000
_refine_ls_R_factor_gt           0.0000
_refine_ls_shift/su_max          0.0010
_refine_ls_shift/su_mean         0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00053|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0000
_refine_ls_wR_factor_ref         0.0542
_reflns_number_gt                0
_reflns_number_total             5678
_reflns_threshold_expression     >2.0sigma(I)
_cod_data_source_file            ic980883j_1.cif
_cod_data_source_block           '[{h5-C5Me5)WS3}2Ag3(CN)]n'
_cod_original_cell_volume        3018(1)
_cod_original_sg_symbol_H-M      'P 21/c '
_cod_original_formula_sum        'C21 H30 Ag3 N S6 W2 '
_cod_database_code               4321829