Asymmetric Visible-Light Photoredox Cross-Dehydrogenative Coupling of Aldehydes with Xanthenes
Larionov, Evgeny; Mastandrea, Marco M.; Pericàs, Miquel A.; ACS Catalysis 7 (2017) 7008–; doi:10.1021/acscatal.7b02659

data_4514205
_publ_section_title
;
 Asymmetric Visible-Light Photoredox Cross-Dehydrogenative Coupling of
 Aldehydes with Xanthenes
;
_journal_issue                   10
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_journal_paper_doi               10.1021/acscatal.7b02659
_journal_volume                  7
_journal_year                    2017
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'CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)'
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'CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)'
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'CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)'
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;
 Fullsphere data collection, phi and omega scans
;
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; 
 CrystalClear-SM Expert 2.1 b29 (Rigaku, 2013)
;
_exptl_crystal_colour            Yellow
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;
 Flack x determined using 1999 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.029(15)
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_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0706P)^2^+1.5241P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                6349
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_cod_data_source_file            cs7b02659_si_003.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 4514205--4514206.cif.
;
_cod_original_cell_volume        4967.8(3)
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