Design, synthesis, characterization and evaluation of the anticancer activity of water-soluble half-sandwich ruthenium(ii) arene halido complexes
Khan, Tanveer A.; Bhar, Kishalay; Thirumoorthi, Ramalingam; Roy, Tapta Kanchan; Sharma, Anuj K.; New Journal of Chemistry 44 (2020) 239–257; doi:10.1039/C9NJ03663F

data_7059058
_publ_section_title
;
 Design, synthesis, characterization and evaluation of the anticancer
 activity of water-soluble half-sandwich ruthenium(ii) arene halido
 complexes
;
_journal_issue                   1
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              239
_journal_page_last               257
_journal_paper_doi               10.1039/C9NJ03663F
_journal_volume                  44
_journal_year                    2020
_chemical_formula_sum            'C115 H138 Cl18 N12 Ru4'
_chemical_formula_weight         2730.75
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/4
_audit_update_record
;
2019-06-03 deposited with the CCDC.	2019-11-18 downloaded from the CCDC.
;
_cell_angle_alpha                78.665(5)
_cell_angle_beta                 75.648(5)
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_cell_volume                     2824.6(18)
_computing_cell_refinement       'Bruker SAINT'
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_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      293(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
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_exptl_absorpt_coefficient_mu    1.006
_exptl_crystal_colour            red
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1418P)^2^+10.4444P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1814
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                8664
_reflns_number_total             9825
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9nj03663f2.cif
_cod_data_source_block           shelx
_cod_depositor_comments
;Adding full bibliography for 7059058.cif.

 Adding full bibliography for 7059058.cif.
;
_cod_database_code               7059058
_shelx_shelxl_version_number     2016/4
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