Energy-Transfer Rate in Crystals of Double-Complex Salts Composed of [Ru(N-N)3]2+ (N-N = 2,2'-Bipyridine or 1,10-Phenanthroline) and [Cr(CN)6]3-: Effect of Relative Orientation between Donor and Acceptor
Takuhiro Otsuka; Akiko Sekine; Naoki Fujigasaki; Yuji Ohashi; Youkoh Kaizu; Inorganic Chemistry 40 (2001) 3406–3412; doi:10.1021/ic0013936

data_4319938
_publ_section_title
;
 Energy-Transfer Rate in Crystals of Double-Complex Salts Composed of
 [Ru(N-N)3]2+ (N-N = 2,2'-Bipyridine or 1,10-Phenanthroline) and
 [Cr(CN)6]3-: Effect of Relative Orientation between Donor and Acceptor
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3406
_journal_page_last               3412
_journal_paper_doi               10.1021/ic0013936
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C42 H44 Cl0.5 Cr0.5 N9 O8 Ru'
_chemical_formula_weight         947.66
_chemical_name_systematic
;

 ?

;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                89.87(4)
_cell_angle_beta                 107.47(3)
_cell_angle_gamma                96.68(3)
_cell_formula_units_Z            2
_cell_length_a                   13.930(5)
_cell_length_b                   14.783(5)
_cell_length_c                   11.137(6)
_cell_measurement_temperature    296(2)
_cell_volume                     2171.5(16)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.1149
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            10049
_diffrn_reflns_theta_full        27.72
_diffrn_reflns_theta_max         27.72
_diffrn_reflns_theta_min         1.54
_exptl_absorpt_coefficient_mu    0.573
_exptl_crystal_density_diffrn    1.449
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             975
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.1
_refine_diff_density_max         3.060
_refine_diff_density_min         -1.364
_refine_diff_density_rms         0.197
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.208
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     516
_refine_ls_number_reflns         10049
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.208
_refine_ls_R_factor_all          0.2008
_refine_ls_R_factor_gt           0.1189
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/\s^2^(Fo^2^)+(0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3165
_refine_ls_wR_factor_ref         0.3642
_reflns_number_gt                5767
_reflns_number_total             10049
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0013936_1.cif
_cod_data_source_block           shelxl
_cod_original_cell_volume        2171.4(16)
_cod_original_formula_sum        'C42 H44 Cl0.50 Cr0.50 N9 O8 Ru'
_cod_database_code               4319938