Synthesis and study of Fe →Pd interactions in unsymmetric Pd(ii) complexes with phosphinoferrocene guanidine ligands.
Bárta, Ondřej; Gyepes, Róbert; Císařová, Ivana; Alemayehu, Adam; Štěpnička, Petr; Dalton transactions (Cambridge, England : 2003) 49 (2020) 4225–4229; doi:10.1039/d0dt00812e

data_7703756
_publ_section_title
;
 Synthesis and study of Fe \\rightarrow Pd interactions in unsymmetric
 Pd(ii) complexes with phosphinoferrocene guanidine ligands.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4225
_journal_page_last               4229
_journal_paper_doi               10.1039/d0dt00812e
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C29 H34 Cl Fe N3 P Pd, F6 Sb'
_chemical_formula_sum            'C29 H34 Cl F6 Fe N3 P Pd Sb'
_chemical_formula_weight         889.01
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
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_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2020-02-22 deposited with the CCDC.	2020-03-16 downloaded from the CCDC.
;
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_cell_measurement_temperature    150(2)
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_cell_volume                     3439.81(11)
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_computing_data_collection       'Bruker Instrument Service v2016.11.0.2'
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_diffrn_ambient_temperature      150(2)
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker D8 VENTURE Kappa Duo PHOTON 100 CMOS'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  'Quazar Mo multilayer optic'
_diffrn_radiation_source         'I\mS micro-focus sealed tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_h_min       -21
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_diffrn_reflns_theta_min         2.083
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_exptl_absorpt_correction_T_min  0.35
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS-2016/2 - Bruker AXS'
_exptl_crystal_colour            'dark red'
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_exptl_crystal_description       prism
_exptl_crystal_F_000             1752
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0202P)^2^+5.0333P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0539
_refine_ls_wR_factor_ref         0.0549
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_reflns_number_gt                7428
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt00812e3.cif
_cod_data_source_block           ob175b
_cod_depositor_comments
'Adding full bibliography for 7703751--7703757.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7703756
_shelx_shelxl_version_number     2017/1
_shelx_estimated_absorpt_t_min   0.343
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_shelx_res_checksum              93072