Unusual doping of donor-acceptor-type conjugated polymers using lewis acids.
Poverenov, Elena; Zamoshchik, Natalia; Patra, Asit; Ridelman, Yonatan; Bendikov, Michael; Journal of the American Chemical Society 136 (2014) 5138–5149; doi:10.1021/ja501024n

data_4121590
_publ_section_title
;
 Unusual doping of donor-acceptor-type conjugated polymers using lewis
 acids.
;
_journal_issue                   13
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5138
_journal_page_last               5149
_journal_paper_doi               10.1021/ja501024n
_journal_volume                  136
_journal_year                    2014
_chemical_formula_moiety         'C24 H25 N3 O4 S2'
_chemical_formula_sum            'C24 H25 N3 O4 S2'
_chemical_formula_weight         483.59
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_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.3891(9)
_cell_angle_beta                 93.4893(12)
_cell_angle_gamma                98.754(3)
_cell_formula_units_Z            2
_cell_length_a                   4.6255(2)
_cell_length_b                   9.9456(2)
_cell_length_c                   24.8078(7)
_cell_measurement_reflns_used    5241
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      28.70
_cell_measurement_theta_min      2.55
_cell_volume                     1111.85(6)
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_computing_data_collection       'Collect package (Bruker Nonius)'
_computing_data_reduction        HKL
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
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_diffrn_measured_fraction_theta_max 0.992
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_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            4840
_diffrn_reflns_theta_full        27.10
_diffrn_reflns_theta_max         27.10
_diffrn_reflns_theta_min         3.33
_exptl_absorpt_coefficient_mu    0.278
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.444
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0508P)^2^+0.8258P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1035
_refine_ls_wR_factor_ref         0.1103
_reflns_number_gt                3945
_reflns_number_total             4840
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja501024n_si_003.cif
_cod_data_source_block           bd54
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_Hall     -P1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4121590