Ring-opening of cyclic ethers by aluminum hydridotriphenylborate.
Mukherjee, Debabrata; Osseili, Hassan; Truong, Khai-Nghi; Spaniol, Thomas P.; Okuda, Jun; Chemical communications (Cambridge, England) 53 (2017) 3493–3496; doi:10.1039/c7cc01159h

data_7119739
_publ_section_title
;
 Ring-opening of cyclic ethers by aluminum hydridotriphenylborate.
;
_journal_issue                   24
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3493
_journal_page_last               3496
_journal_paper_doi               10.1039/c7cc01159h
_journal_volume                  53
_journal_year                    2017
_chemical_formula_moiety         'C15 H34 Al N4 O, C18 H16 B, C4 H8 O'
_chemical_formula_sum            'C37 H58 Al B N4 O2'
_chemical_formula_weight         628.66
_chemical_name_common            Al-HBPh3
_chemical_name_systematic
;
 ?
;
_chemical_properties_physical
', Air-sensitive,Moisture-sensitive,Hygroscopic,Oxygen-sensitive'
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2017-02-02 deposited with the CCDC.
2017-03-03 downloaded from the CCDC.
;
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_diffrn_radiation_monochromator  'multilayer optics'
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_diffrn_reflns_limit_k_min       -14
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_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            11357
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'Re-crystallisation from solvent: thf, pentane'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0421P)^2^+1.9212P]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1795
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'Adding full bibliography for 7119739--7119740.cif.'
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