<i>catena</i>-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ^4^<i>O</i>^1^,<i>O</i>^6^:<i>O</i>^1^,<i>O</i>^2^)copper(II)sodium]-μ-tetrafluoridoborate-1:1'κ^2^<i>F</i>:<i>F</i>']
Yang, Yu; Gao, Po; Yang, Jing-Lin; Hou, Hai-Ge; Gao, Ting; Acta Crystallographica Section E 68 (2012) m37–; doi:10.1107/S1600536811051713

data_2233194
_publ_section_title
;
 <i>catena</i>-Poly[[bis(\m-2-formyl-6-methoxyphenolato-1:2\k^4^<i>O</i>^1^,<i>O</i>^6^:<i>O</i>^1^,<i>O</i>^2^)copper(II)sodium]-\m-tetrafluoridoborate-1:1'\k^2^<i>F</i>:<i>F</i>']
;
_journal_coeditor_code           HY2490
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m37
_journal_paper_doi               10.1107/S1600536811051713
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Cu Na (B F4) (C8 H7 O3)2]'
_chemical_formula_moiety         'C16 H14 B Cu F4 Na O6'
_chemical_formula_sum            'C16 H14 B Cu F4 Na O6'
_chemical_formula_weight         475.62
_chemical_name_systematic
;
<i>catena</i>-Poly[[bis(\m-2-formyl-6-methoxyphenolato-
1:2\k^4^<i>O</i>^1^,<i>O</i>^6^:<i>O</i>^1^,<i>O</i>^2^)copper(II)sodium]-
\m-tetrafluoridoborate-1:1'\k^2^<i>F</i>:<i>F</i>']
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 105.16(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.932(2)
_cell_length_b                   19.349(4)
_cell_length_c                   9.940(2)
_cell_measurement_reflns_used    9827
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.46
_cell_measurement_theta_min      2.99
_cell_volume                     1843.7(7)
_computing_cell_refinement       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_collection       'RAPID-AUTO (Rigaku, 1998)'
_computing_data_reduction        'CrystalStructure (Rigaku/MSC, 2002)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 1999)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0995
_diffrn_reflns_av_sigmaI/netI    0.0854
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            17729
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         2.99
_exptl_absorpt_coefficient_mu    1.279
_exptl_absorpt_correction_T_max  0.8196
_exptl_absorpt_correction_T_min  0.7785
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.714
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             956
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.503
_refine_diff_density_min         -0.343
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     292
_refine_ls_number_reflns         4201
_refine_ls_number_restraints     30
_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.1308
_refine_ls_R_factor_gt           0.0611
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0582P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1196
_refine_ls_wR_factor_ref         0.1428
_reflns_number_gt                2278
_reflns_number_total             4201
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hy2490.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2233194
_cod_database_fobs_code          2233194