Palladium-Catalyzed Stereoretentive Olefination of Unactivated C(sp(3))-H Bonds with Vinyl Iodides at Room Temperature: Synthesis of β-Vinyl α-Amino Acids.
Wang, Bo; Lu, Chengxi; Zhang, Shu-Yu; He, Gang; Nack, William A.; Chen, Gong; Organic letters 16 (2014) 6260–; doi:10.1021/ol503248f

data_1518290
_publ_section_title
;
 Palladium-Catalyzed Stereoretentive Olefination of Unactivated C(sp(3))-H
 Bonds with Vinyl Iodides at Room Temperature: Synthesis of \b-Vinyl
 \a-Amino Acids.
;
_journal_issue                   23
_journal_name_full               'Organic letters'
_journal_page_first              6260
_journal_paper_doi               10.1021/ol503248f
_journal_volume                  16
_journal_year                    2014
_chemical_formula_moiety         'C26 H21 N3 O4, C3 H6 O'
_chemical_formula_sum            'C29 H27 N3 O5'
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_cell_measurement_temperature    298(2)
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_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
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_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
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_diffrn_reflns_limit_l_min       -18
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_diffrn_reflns_theta_max         28.54
_diffrn_reflns_theta_min         1.92
_exptl_absorpt_coefficient_mu    0.089
_exptl_absorpt_correction_T_max  0.9894
_exptl_absorpt_correction_T_min  0.9815
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_exptl_crystal_colour            colorless
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_exptl_crystal_density_method    'not measured'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0987P)^2^+0.0444P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1823
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_cod_data_source_file            ol503248f_si_003.cif
_cod_data_source_block           bzw2t
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 

 Adding full bibliography for 1518290--1518291.cif.
;
_cod_original_cell_volume        1279.5(6)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1518290