Novel Photorearrangements of 2-Aza-1,4-dienes To Produce Vinylaziridines and Cyclopropylimines
Diego Armesto; Olga Caballero; Ulises Amador; Journal of the American Chemical Society 119 (1997) 12659–12660; doi:10.1021/ja972054n

data_4117091
_publ_contact_author_address
; Departamento de Quimica Organica I,
  Facultad de Ciencias Quimicas,
  Universidad Complutense de Madrid,
  Avenida Complutense s/n
  28040-Madrid
  Spain
;
_publ_contact_author_email       darmesto@eucmos.sim.ucm.es
_publ_contact_author_fax         34-1-394-4103
_publ_contact_author_name        'Prof. Diego Armesto'
_publ_contact_author_phone       34-1-394-4316
_publ_section_title
;
 Novel Photorearrangements of 2-Aza-1,4-dienes To Produce Vinylaziridines
 and Cyclopropylimines
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              12659
_journal_page_last               12660
_journal_paper_doi               10.1021/ja972054n
_journal_volume                  119
_journal_year                    1997
_chemical_formula_sum            'C34 H27 N'
_chemical_formula_weight         449.59
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_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   'Fourier synthesis'
_atom_sites_solution_primary     Multan
_atom_sites_solution_secondary   'XRAY 80'
_audit_creation_method           PARSTCIF
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_cell_angle_beta                 96.75(2)
_cell_angle_gamma                111.05(3)
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_cell_length_a                   10.843(2)
_cell_length_b                   11.223(5)
_cell_length_c                   11.654(3)
_cell_measurement_radiation      Mo(Kalpha)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    298
_cell_measurement_wavelength     0.71069
_cell_volume                     1280.3(8)
_diffrn_ambient_temperature      298
_diffrn_measurement_method       omega/2theta
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           Mo(Kalpha)
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.01
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_diffrn_reflns_limit_h_min       -15
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_diffrn_reflns_limit_l_min       0
_diffrn_reflns_reduction_process ' ......'
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_diffrn_standards_decay_%        1
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_diffrn_standards_number         3/75
_exptl_absorpt_coefficient_mu    0.0668
_exptl_absorpt_correction_type   none
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_exptl_crystal_F_000             476.0
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_refine_diff_density_max         0.2
_refine_ls_goodness_of_fit_ref   0.47
_refine_ls_hydrogen_treatment    isotropic
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_refine_ls_structure_factor_coef F
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_reflns_number_gt                3808
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_cod_data_source_file            ja972054n.cif
_cod_data_source_block           (I)
_cod_original_sg_symbol_H-M      ' P -1 '
_cod_original_formula_sum        'C34 N1 H27 '
_cod_database_code               4117091