Tuning the fluorescence emission in mononuclear heteroleptic trigonal silver(i) complexes
Durini, Sara; Ardizzoia, G. Attilio; Therrien, Bruno; Brenna, Stefano; New J. Chem. 41 (2017) 3006–; doi:10.1039/C6NJ04058F

data_7056048
_publ_section_title
;
 Tuning the fluorescence emission in mononuclear heteroleptic trigonal
 silver(i) complexes
;
_journal_issue                   8
_journal_name_full               'New J. Chem.'
_journal_page_first              3006
_journal_paper_doi               10.1039/C6NJ04058F
_journal_volume                  41
_journal_year                    2017
_chemical_formula_moiety         'C26 H24 Ag N3 O P, N O3'
_chemical_formula_sum            'C26 H24 Ag N4 O4 P'
_chemical_formula_weight         595.33
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-12-05 deposited with the CCDC.
2017-03-08 downloaded from the CCDC.
;
_cell_angle_alpha                95.769(7)
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_cell_angle_gamma                94.544(7)
_cell_formula_units_Z            2
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_cell_length_b                   10.4096(9)
_cell_length_c                   14.7569(11)
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_cell_measurement_temperature    203(2)
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_cell_measurement_theta_min      2.20
_cell_volume                     1262.68(18)
_computing_cell_refinement       'CELL (Stoe IPDS Software, 2000)'
_computing_data_collection       'EXPOSE (Stoe IPDS Software, 2000)'
_computing_data_reduction        'INTEGRATE (Stoe IPDS Software, 2000)'
_computing_molecular_graphics    'ORTEP (Farrugia, 1997)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      203(2)
_diffrn_detector_area_resol_mean 0.81\%A
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'STOE IPDS'
_diffrn_measurement_method       'phi oscillation'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0687
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_diffrn_reflns_limit_h_min       -11
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_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.902
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0198P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0549
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_reflns_number_gt                5046
_reflns_number_total             6829
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6nj04058f2.cif
_cod_data_source_block           D:complex2
_cod_depositor_comments
'Adding full bibliography for 7056048--7056051.cif.'
_cod_database_code               7056048
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              13880