Lewis acid-base adducts of group 13 elements: synthesis, structure and reactivity toward benzaldehyde.
Ganesamoorthy, C.; Matthias, M.; Bläser, D; Wölper, C; Schulz, S.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 11437–11444; doi:10.1039/c6dt01688j

data_7039527
_publ_section_title
;
 Lewis acid-base adducts of group 13 elements: synthesis, structure and
 reactivity toward benzaldehyde.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11437
_journal_page_last               11444
_journal_paper_doi               10.1039/c6dt01688j
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C47 H41 F15 Ga2 N2'
_chemical_formula_weight         1058.26
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_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_atom_sites_solution_secondary   difmap
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;
2016-04-28 deposited with the CCDC.
2016-06-10 downloaded from the CCDC.
;
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; 
 Bruker D8 KAPPA series II with APEX II area detector system
;
_diffrn_measurement_method
;
 Data collection strategy APEX 2/COSMO
;
_diffrn_radiation_monochromator  'Triumph Goebel mirror'
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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; 
 BRUKER AXS SMART APEX 2 Vers. 3.0-2009
 R.H. Blessing, Acta Cryst. (1995) A51 33-38 
;
_exptl_crystal_colour            colourless
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_exptl_crystal_size_max          0.323
_exptl_crystal_size_mid          0.244
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0266
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0328P)^2^+1.9736P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             16118
_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7039525--7039528.cif.'
_cod_database_code               7039527
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.677
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_shelx_res_checksum              80597