Reactions of the Eight-Coordinate Rhenium Complex ReH4(hq)(PPh3)2 (hq = 2-Hydroxyquinoline Monoanion) with Monodentate Tertiary Phosphines: Formation of Pentagonal Bipyramidal Dihydridorhenium(III) Complexes of the Type ReH2(hq)(PPh3)2(PR3)
Talia M. McKinney; Phillip E. Fanwick; Richard A. Walton; Inorganic Chemistry 38 (1999) 1548–1554; doi:10.1021/ic981155z

data_4321882
_publ_contact_author
;
     Richard A. Walton
     Department of Chemistry
     Purdue University
     1393 Brown Building
     W. Lafayette
     IN 47907
     USA
;
_publ_contact_author_email       walton@chem.purdue.edu
_publ_contact_author_fax         '(765) 494 0239'
_publ_contact_author_phone       '(765) 494 5464'
_publ_section_title
;
 Reactions of the Eight-Coordinate Rhenium Complex ReH4(hq)(PPh3)2 (hq =
 2-Hydroxyquinoline Monoanion) with Monodentate Tertiary Phosphines:
 Formation of Pentagonal Bipyramidal Dihydridorhenium(III) Complexes of
 the Type ReH2(hq)(PPh3)2(PR3)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1548
_journal_page_last               1554
_journal_paper_doi               10.1021/ic981155z
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C57 H49 N O P3 Re'
_chemical_formula_weight         1043.15
_chemical_name_systematic        ' ?'
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_symmetry_space_group_name_Hall  '-C 2yc'
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'International Tables for Crystallography (Vol C) '
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_cell_angle_gamma                90.00
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_cell_length_a                   45.685(4)
_cell_length_b                   12.2110(12)
_cell_length_c                   36.400(6)
_cell_measurement_reflns_used    579
_cell_measurement_temperature    156
_cell_measurement_theta_max      43
_cell_measurement_theta_min      12
_cell_volume                     18416(4)
_computing_cell_refinement       CAD4_(Enraf-Nonius,_1977)
_computing_data_collection       CAD4_(Enraf-Nonius,_1977)
_computing_data_reduction        PROCESS_MolEN_(Fair,_1990)
_computing_molecular_graphics
;
    ORTEP (Johnson, 1976)
    Xtal_GX (Hall, 1995)
    PLUTON (Spek, 1991)
;
_computing_publication_material  CIF_VAX_MolEN_(Fair,_1990)
_computing_structure_refinement  SHELX97_(Sheldrick,_1997)
_computing_structure_solution    PATTY_(DIRDIF92,_Beurskins,_1992)
_diffrn_ambient_temperature      156
_diffrn_measurement_device_type  Enraf_Nonius_CAD4
_diffrn_measurement_method       \w
_diffrn_radiation_type           MO-K\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_standards_decay_%        0.00
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_exptl_absorpt_coefficient_mu    2.818
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            red
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_exptl_crystal_description       needle
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_exptl_crystal_size_mid          0.14
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1236P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     >2.0\s(I)
_cod_data_source_file            ic981155z_1.cif
_cod_data_source_block           Compound5
_cod_original_cell_volume        18416(8)
_cod_original_formula_sum        'C57 H49 N1 O1 P3 Re1'
_cod_database_code               4321882