Enantioselective Friedel-Crafts type addition of indoles to nitro-olefins using a chiral hydrogen-bonding catalyst–synthesis of optically active tetrahydro-beta-carbolines.
Zhuang, Wei; Hazell, Rita G.; Jørgensen, Karl Anker; Organic & biomolecular chemistry 3 (2005) 2566–2571; doi:10.1039/b505220c

data_7150181
_publ_section_title
;
 Enantioselective Friedel-Crafts type addition of indoles to
 nitro-olefins using a chiral hydrogen-bonding catalyst--synthesis of
 optically active tetrahydro-beta-carbolines.
;
_journal_issue                   14
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              2566
_journal_page_last               2571
_journal_paper_doi               10.1039/b505220c
_journal_volume                  3
_journal_year                    2005
_chemical_formula_moiety         'C16 H26 F6 N2 O4 S2'
_chemical_formula_sum            'C16 H26 F6 N2 O4 S2'
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_chemical_name_systematic
;
(R,R) N-(1,2-Dicyclohexyl-2-trifluoromethanesulfonylamino-ethyl9-
C,C,C-trifluoro-methanesulfonamide
;
_space_group_IT_number           15
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ORTEP-III (Burnett & Johnson, 1996), KRYSTAL
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SIR97 (Altomare et al., 1997 ), KRYSTAL
;
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details
;
w= 1/{[\s~cs~(F^2^)+B+(1+A)F^2^]^1/2^- |F|}^2^
where A = 0.10 and B = 5.0
;
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;
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Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

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data
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data
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Automatic conversion script
Id: cif_correct_tags 5005 2017-03-03 11:38:54Z antanas 
;
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