Application of a mild hydrothermal method to the synthesis of mixed transition-metal(ii)/uranium(iv) fluorides
Felder, Justin; Yeon, Jeongho; Smith, Mark; zur Loye, Hans-Conrad; Inorganic Chemistry Frontiers 4 (2017) 368–; doi:10.1039/C6QI00491A

data_4349610
_publ_section_title
;
 Application of a mild hydrothermal method to the synthesis of mixed
 transition-metal(ii)/uranium(iv) fluorides
;
_journal_issue                   2
_journal_name_full               'Inorganic Chemistry Frontiers'
_journal_page_first              368
_journal_paper_doi               10.1039/C6QI00491A
_journal_volume                  4
_journal_year                    2017
_chemical_formula_moiety         '2(F5 U), H12 O6 Zn, 2(H2 O)'
_chemical_formula_sum            'F10 H16 O8 U2 Zn'
_chemical_formula_weight         875.56
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
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_atom_sites_solution_hydrogens   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-11-07 deposited with the CCDC.
2016-12-26 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 94.2424(13)
_cell_angle_gamma                90
_cell_formula_units_Z            2
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_diffrn_measurement_device_type  'Bruker D8 QUEST'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0123P)^2^+0.8800P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                1941
_reflns_number_total             2015
_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_estimated_absorpt_t_min   0.235
_shelx_estimated_absorpt_t_max   0.429
_shelx_res_checksum              46911
_shelx_hkl_checksum              27299