Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors.
Johnson, Miles W.; DiPasquale, Antonio G.; Bergman, Robert G.; Toste, F. Dean; Organometallics 33 (2014) 4169–4172; doi:10.1021/om500663m

data_4084222
_publ_section_title
;
 Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom
 Donors.
;
_journal_issue                   16
_journal_name_full               Organometallics
_journal_page_first              4169
_journal_page_last               4172
_journal_paper_doi               10.1021/om500663m
_journal_volume                  33
_journal_year                    2014
_chemical_formula_sum            'C19 H23 Au Cl4 N2 O'
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_chemical_name_systematic
; 
 toste116 
;
_space_group.centring_type       P
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_diffrn_source                   'fine focus sealed tube'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
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_exptl_crystal_density_diffrn    1.859
_exptl_crystal_description       plate
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_refine_ls_extinction_method     none
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_refine_ls_number_parameters     240
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.048
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_refine_ls_R_factor_gt           0.0274
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0297P)^2^+16.4429P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0652
_refine_ls_wR_factor_ref         0.0676
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3867
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            om500663m_si_002.cif
_cod_data_source_block           cpd15
_cod_depositor_comments
;Adding full bibliography for 4084216--4084222.cif.

The following automatic conversions were performed:

'_space_group.centring_type' value 'primitive' was replaced with the
value 'P' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_values.lst'.

Automatic conversion script
Id: cif_fix_values 5642 2017-10-24 12:04:52Z antanas 
;
_cod_database_code               4084222
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