Complexe entre un Carboxylate de Rhodium(II) et un Dérivé de la [1,4]Thiazépine: Synthèse et Structure Cristalline de Tétrakis(μ-acétato)bis{[11-aminodibenzo[b,f][1,4]thiazépine]rhodium(II)}(Rh—Rh)
Lemoine, P.; Tomas, A.; Viossat, B.; Mettey, Y.; Vierfond, J. M.; Acta Crystallographica Section C Crystal Structure Communications 51 (1995) 377–; doi:10.1107/S0108270194006773

data_2019347
_publ_section_title
;
 Complexe entre un Carboxylate de Rhodium(II) et un D\'eriv\'e de la
 [1,4]Thiaz\'epine: Synth\`ese et Structure Cristalline de
 T\'etrakis(\m-ac\'etato)bis{[11-aminodibenzo[b,f][1,4]thiaz\'epine]rhodium(II)}(Rh---Rh)
;
_journal_issue                   3
_journal_name_full
'Acta Crystallographica Section C Crystal Structure Communications'
_journal_page_first              377
_journal_paper_doi               10.1107/S0108270194006773
_journal_volume                  51
_journal_year                    1995
_chemical_formula_sum            'C34 H32 N4 O8 Rh2 S2'
_chemical_formula_weight         894.58
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_type_scat_source           IntTabIV
_cell_angle_alpha                90
_cell_angle_beta                 126.29(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   17.670(5)
_cell_length_b                   16.554(6)
_cell_length_c                   14.753(3)
_cell_measurement_reflns_used    29
_cell_measurement_temperature    293.0(10)
_cell_measurement_theta_max      8.9
_cell_measurement_theta_min      1.9
_cell_volume                     3478(2)
_diffrn_measurement_device       'Syntex P2~1~'
_diffrn_measurement_method       \q-2\q
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            5442
_diffrn_reflns_theta_max         30
_diffrn_standards_decay_%        <1
_diffrn_standards_interval_count 50
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.02
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            Rouge
_exptl_crystal_density_diffrn    1.71
_exptl_crystal_density_meas      1.68(2)
_exptl_crystal_description       Parall\'el\'epip\'edique
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.54
_refine_diff_density_min         -0.60
_refine_ls_extinction_coef       none
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_obs   5.70
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     228
_refine_ls_number_reflns         2041
_refine_ls_R_factor_obs          0.0476
_refine_ls_shift/esd_max         0.008
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      unit
_refine_ls_wR_factor_obs         0.0476
_reflns_number_observed          2041
_reflns_number_total             5288
_reflns_observed_criterion       I>5\s(I)
_cod_data_source_file            pa1130sup1.cif
_cod_data_source_block           pa1130_structure_1_of_1
_cod_database_code               2019347