Cu(ii) complexes of N-rich aroylhydrazone: magnetism and catalytic activity towards microwave-assisted oxidation of xylenes.
Sutradhar, Manas; Roy Barman, Tannistha; Alegria, Elisabete C. B. A.; Guedes da Silva, M Fátima C; Liu, Cai-Ming; Kou, Hui-Zhong; Pombeiro, Armando J. L.; Dalton transactions (Cambridge, England : 2003) 48 (2019) 12839–12849; doi:10.1039/c9dt02196e

data_7700566
_publ_section_title
;
 Cu(ii) complexes of N-rich aroylhydrazone: magnetism and catalytic
 activity towards microwave-assisted oxidation of xylenes.
;
_journal_issue                   34
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12839
_journal_page_last               12849
_journal_paper_doi               10.1039/c9dt02196e
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C68 H48 Cl12 Cu8 N20 O4'
_chemical_formula_sum            'C68 H48 Cl12 Cu8 N20 O4'
_chemical_formula_weight         2142.98
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_symmetry_space_group_name_Hall  '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-05-23 deposited with the CCDC.    2019-07-15 downloaded from the CCDC.
;
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_computing_structure_solution    'SHELXS-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
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_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Bruker APEX-II PHOTON 100'
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_exptl_absorpt_correction_T_max  0.767
_exptl_absorpt_correction_T_min  0.605
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            brown
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.1194
_refine_ls_R_factor_gt           0.0943
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0771P)^2^+55.7316P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2278
_refine_ls_wR_factor_ref         0.2433
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4777
_reflns_number_total             6324
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt02196e2.cif
_cod_data_source_block           shelx_CCDC2
_cod_depositor_comments
'Adding full bibliography for 7700564--7700566.cif.'
_cod_original_cell_volume        4176.9(11)
_cod_database_code               7700566
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              789
_shelx_fab_checksum              59515