Synthesis and photophysical properties of Ir(iii)/Re(i) dyads: control of Ir→Re photoinduced energy transfer.
Saad, Suad T.; Metherell, Alexander J.; Baggaley, Elizabeth; Ward, Michael D.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 11568–11579; doi:10.1039/c6dt01614f

data_7039711
_publ_section_title
;
 Synthesis and photophysical properties of Ir(iii)/Re(i) dyads: control of
 Ir\\rightarrow Re photoinduced energy transfer.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11568
_journal_page_last               11579
_journal_paper_doi               10.1039/c6dt01614f
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C51 H35 Cl F10 Ir N9 O3 P Re'
_chemical_formula_weight         1456.70
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2016-04-25 deposited with the CCDC.
2016-06-27 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      100(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0206
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_exptl_crystal_preparation       Luminescent
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
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_refine_ls_extinction_method     none
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_refine_ls_number_restraints     102
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0469P)^2^+6.4785P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                11757
_reflns_number_total             13119
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt01614f1.cif
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_cod_depositor_comments
'Adding full bibliography for 7039709--7039714.cif.'
_cod_original_cell_volume        2877.0(10)
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_shelx_res_checksum              44253
_solvent_exptl_crystal_recrystallization_method 'MeCN / ether'