A hydrogen-bridged bis(silylene) complex as a platform for small molecule activation <i>via</i> adjacent metal-ligand cooperation.
Hashimoto, Hisako; Matsuo, Satomi; Odagiri, Yuto; Tobita, Hiromi; Dalton transactions (Cambridge, England : 2003) 54 (2025) 915–919; doi:10.1039/d4dt03226h

data_7717664
_publ_section_title
;
 A hydrogen-bridged bis(silylene) complex as a platform for small molecule
 activation <i>via</i> adjacent metal-ligand cooperation.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               919
_journal_paper_doi               10.1039/d4dt03226h
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C24 H42 O3 Si2 W'
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_audit_update_record
;
2024-11-18 deposited with the CCDC.	2024-12-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 125.3613(12)
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;
'SHELXL-97 (Sheldrick, 1997)', 'SHELXL-2018/3 (Sheldrick, 2018)'
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
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_exptl_crystal_colour            'pale yellow'
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0320P)^2^+8.4675P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 7717662--7717666.cif.'
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_shelx_shelxl_version_number     2018/3
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