Half-sandwich iron(II) complexes with protic acyclic diaminocarbene ligands: synthesis, deprotonation and metalation reactions
Ruiz, Javier; García, Lucía; Vivanco, Marilín; Sol, Daniel; Garcia-Granda, Santiago; Dalton Trans.  (2017) –; doi:10.1039/C7DT02049J

data_7043605
_publ_section_title
;
 Half-sandwich iron(II) complexes with protic acyclic diaminocarbene
 ligands: synthesis, deprotonation and metalation reactions
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT02049J
_journal_year                    2017
_chemical_formula_sum            'C43 H41 Au Fe N3 O P'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
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_atom_sites_solution_hydrogens   geom
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;
2017-07-05 deposited with the CCDC.
2017-07-13 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_cell_measurement_reflns_used    6999
_cell_measurement_temperature    100.2(2)
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_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
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_computing_data_collection
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CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
;
_computing_data_reduction
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CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
;
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;
Parkin S,Moezzi B & Hope H, (1995) J. Appl. Cryst. 28, 53-56
Cubic fit to sin(theta)/lambda - 24 parameters
;
_exptl_crystal_colour            yellow
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0969P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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