Bis(μ-pyridine-1-carbaldehyde azine-κ^2^<i>N</i>,<i>N</i>':κ<i>N</i>'')disilver(I) bis(<i>p</i>-toluenesulfonate)
Broker, Grant A.; Tiekink, Edward R. T.; Acta Crystallographica Section E 63 (2007) m2420–m2421; doi:10.1107/S1600536807040809

data_2215135
_publ_section_title
;
 Bis(\m-pyridine-1-carbaldehyde
 azine-\k^2^<i>N</i>,<i>N</i>':\k<i>N</i>'')disilver(I)
 bis(<i>p</i>-toluenesulfonate)
;
_journal_coeditor_code           HB2512
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2420
_journal_page_last               m2421
_journal_paper_doi               10.1107/S1600536807040809
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ag2 (C12 H10 N4)2] (C7 H7 S O3)2'
_chemical_formula_moiety         'C24 H20 Ag2 N8 2+, 2(C7 H7 S1 O3 -)'
_chemical_formula_sum            'C38 H34 Ag2 N8 O6 S2'
_chemical_formula_weight         978.61
_chemical_name_systematic
;
Bis(\m-pyridine-1-carbaldehyde azine-\k^2^N,N':\kN'')disilver(I)
bis(p-toluenesulfonate)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                78.12(3)
_cell_angle_beta                 76.75(3)
_cell_angle_gamma                70.13(3)
_cell_formula_units_Z            1
_cell_length_a                   7.9619(17)
_cell_length_b                   9.4382(11)
_cell_length_c                   13.468(3)
_cell_measurement_reflns_used    2621
_cell_measurement_temperature    98(2)
_cell_measurement_theta_max      30.2
_cell_measurement_theta_min      2.6
_cell_volume                     917.4(4)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC, 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC, 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC, 2005)'
_computing_molecular_graphics
'ORTEPII (Johnson, 1976) and DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR92 (Altomare <i>et al.</i>,  1994)'
_diffrn_ambient_temperature      98(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Rigaku/MSC AFC12\k/SATURN724'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.018
_diffrn_reflns_av_sigmaI/netI    0.017
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            10013
_diffrn_reflns_theta_full        26.50
_diffrn_reflns_theta_max         26.5
_diffrn_reflns_theta_min         2.6
_diffrn_standards_decay_%        <1
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.242
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.715
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.771
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             492
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.46
_refine_diff_density_min         -0.42
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.07
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     254
_refine_ls_number_reflns         3776
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.07
_refine_ls_R_factor_all          0.020
_refine_ls_R_factor_gt           0.020
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0249P)^2^+0.8243P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.051
_refine_ls_wR_factor_ref         0.052
_reflns_number_gt                3713
_reflns_number_total             3776
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb2512.cif
_cod_data_source_block           I
_cod_original_cell_volume        917.4(3)
_cod_original_sg_symbol_Hall     '-P 1 '
_cod_original_sg_symbol_H-M      ' P -1'
_cod_database_code               2215135
_cod_database_fobs_code          2215135