<i>catena</i>-Poly[[bis(μ-anilinoacetato-κ^2^<i>O</i>:<i>O</i>')bis(μ-anilinoacetato-κ^3^<i>O</i>,<i>O</i>':<i>O</i>)bis[(1,10-phenanthroline-κ^2^<i>N</i>,<i>N</i>')samarium(III)]-μ-anilinoacetato-κ^2^<i>O</i>:<i>O</i>']
Zhong, H.; Yang, X.-M.; Xie, H.-L.; Luo, C.-J.; Acta Crystallographica Section E 63 (2007) m2508–m2509; doi:10.1107/S1600536807043528

data_2215330
_publ_section_title
<i>catena</i>-Poly[[bis(\m-anilinoacetato-\k^2^<i>O</i>:<i>O</i>')bis(\m-anilinoacetato-\k^3^<i>O</i>,<i>O</i>':<i>O</i>)bis[(1,10-phenanthroline-\k^2^<i>N</i>,<i>N</i>')samarium(III)]-\m-anilinoacetato-\k^2^<i>O</i>:<i>O</i>']
_journal_coeditor_code           AT2392
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2508
_journal_page_last               m2509
_journal_paper_doi               10.1107/S1600536807043528
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Sm2 (C8 H8 N O2)6 (C12 H8 N2)2]'
_chemical_formula_moiety         'C72 H64 N10 O12 Sm2'
_chemical_formula_sum            'C72 H64 N10 O12 Sm2'
_chemical_formula_weight         1562.04
_chemical_name_common
;
catena-Poly[Bis[(1,10-phenanthroline-N,N')tri(anilinoacetato-O,O')
samarium(III)]]
;
_chemical_name_systematic
;
<i>catena</i>-Poly[[bis(\m-anilinoacetato-\k^2^<i>O</i>:<i>O</i>')bis(\m-\
anilinoacetato-\k^3^<i>O</i>,<i>O</i>':<i>O</i>)bis[(1,10-phenanthroline-\
\k^2^<i>N</i>,<i>N</i>')samarium(III)]-
bis-(\m-anilinoacetato-\k^2^<i>O</i>:<i>O</i>')]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.998(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   19.998(3)
_cell_length_b                   8.498(2)
_cell_length_c                   20.783(2)
_cell_measurement_reflns_used    8997
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      26.721
_cell_measurement_theta_min      2.706
_cell_volume                     3377.6(10)
_computing_cell_refinement       'SAINT (Siemens, 1996)'
_computing_data_collection       'APEX2 (Bruker, 2005)'
_computing_data_reduction        'SAINT (Siemens, 1996)'
_computing_molecular_graphics    'SHELXTL (Siemens, 1996)'
_computing_publication_material  'SHELXTL (Siemens, 1996)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker APEX II area-detector diffractometer'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0427
_diffrn_reflns_av_sigmaI/netI    0.0477
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            27195
_diffrn_reflns_theta_full        27.40
_diffrn_reflns_theta_max         27.40
_diffrn_reflns_theta_min         2.05
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.791
_exptl_absorpt_correction_T_max  0.8714
_exptl_absorpt_correction_T_min  0.5902
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.536
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plane
_exptl_crystal_F_000             1572
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.542
_refine_diff_density_min         -0.814
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.977
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     403
_refine_ls_number_reflns         7519
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      0.976
_refine_ls_R_factor_all          0.0723
_refine_ls_R_factor_gt           0.0496
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1002P)^2^+0.2850P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1402
_refine_ls_wR_factor_ref         0.1523
_reflns_number_gt                4974
_reflns_number_total             7519
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            at2392.cif
_cod_data_source_block           I
_cod_original_cell_volume        3377.7(10)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2215330
_cod_database_fobs_code          2215330