Building blocks for the chemistry of perfluorinated alkoxyaluminates [Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>]<sup>-</sup>: simplified preparation and characterization of Li<sup>+</sup>-Cs<sup>+</sup>, Ag<sup>+</sup>, NH<sub>4</sub><sup>+</sup>, N<sub>2</sub>H<sub>5</sub><sup>+</sup> and N<sub>2</sub>H<sub>7</sub><sup>+</sup> salts.
Malinowski, Przemysław J; Jaroń, Tomasz; Domańska, Małgorzata; Slattery, John M.; Schmitt, Manuel; Krossing, Ingo; Dalton transactions (Cambridge, England : 2003) 49 (2020) 7766–7773; doi:10.1039/d0dt00592d

data_7704012
_publ_section_title
;
 Building blocks for the chemistry of perfluorinated alkoxyaluminates
 [Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>]<sup>-</sup>: simplified
 preparation and characterization of Li<sup>+</sup>-Cs<sup>+</sup>,
 Ag<sup>+</sup>, NH<sub>4</sub><sup>+</sup>,
 N<sub>2</sub>H<sub>5</sub><sup>+</sup> and
 N<sub>2</sub>H<sub>7</sub><sup>+</sup> salts.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7766
_journal_page_last               7773
_journal_paper_doi               10.1039/d0dt00592d
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C16 Al F36 Na O4'
_chemical_formula_weight         990.13
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_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
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_audit_update_record
;
2020-03-31 deposited with the CCDC.	2020-04-06 downloaded from the CCDC.
;
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_cell_length_b                   10.1222(6)
_cell_length_c                   21.3566(13)
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_cell_measurement_theta_min      2.224
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_diffrn_ambient_temperature      190(2)
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_diffrn_measurement_device_type  'Bruker Smart Apex II Quazar'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_type           MoK\a
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_diffrn_source                   'INCOATEC Mo Microsource'
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_exptl_absorpt_correction_T_min  0.7066
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_refine_ls_extinction_method     none
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_refine_ls_restrained_S_all      1.485
_refine_ls_R_factor_all          0.0463
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0723P)^2^+1.5469P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                3627
_reflns_number_total             4222
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7704008--7704017.cif.'
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_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              43752