Homotrinuclear ruthenium(ii) and rhodium(i) complexes of redox-active tris(ferrocenyl)arene-based tris-phosphanes.
Straube, Axel; Coburger, Peter; Hey-Hawkins, Evamarie; RSC advances 14 (2024) 24652–24660; doi:10.1039/d4ra03822c

data_7249183
_publ_section_title
;
 Homotrinuclear ruthenium(ii) and rhodium(i) complexes of redox-active
 tris(ferrocenyl)arene-based tris-phosphanes.
;
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_journal_paper_doi               10.1039/d4ra03822c
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_chemical_formula_sum            'C108 H120.13 Cl3 Fe3 O3 P3 Rh3'
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2024-05-23 deposited with the CCDC.	2024-07-29 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
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_diffrn_reflns_theta_max         28.282
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_diffrn_source                   'Enhance (Mo) X-ray Source'
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.35 (release 13-08-2014 CrysAlis171 .NET)
(compiled Aug 13 2014,18:06:01)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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_exptl_crystal_colour            'clear light orange'
_exptl_crystal_density_diffrn    1.520
_exptl_crystal_description       needle
_exptl_crystal_F_000             2202
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_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0938
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0352P)^2^+7.6961P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                16560
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_reflns_threshold_expression     'I > 2\s(I)'
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