Double addition of H2 to transition metalborane complexes: a hydride shuttle process between boron and transition metal centres
Nikolaos Tsoureas; Yu-Ying Kuo; Mairi Haddow; Gareth Owen; Chem.Commun. 47 (2011) 484–; doi:10.1039/c0cc02245d

data_7105787
_publ_section_title
;
Double addition of H2 to transition metal&#x0096;borane complexes: 
a &#x0091;hydride shuttle&#x0092; process between boron and 
transition metal centres
;
_journal_name_full               Chem.Commun.
_journal_page_first              484
_journal_paper_doi               10.1039/c0cc02245d
_journal_volume                  47
_journal_year                    2011
_chemical_formula_moiety         'C49 H36 B2 N14 Rh2, 2(C6 H6)'
_chemical_formula_sum            'C61 H48 B2 N14 Rh2'
_chemical_formula_weight         1204.57
_chemical_name_systematic
;
?
;
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_cell_angle_gamma                111.872(2)
_cell_formula_units_Z            2
_cell_length_a                   11.5334(5)
_cell_length_b                   15.3688(6)
_cell_length_c                   15.8442(6)
_cell_measurement_reflns_used    9977
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      31.38
_cell_measurement_theta_min      2.82
_cell_volume                     2539.18(18)
_computing_cell_refinement       'Bruker Apex II'
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_diffrn_measured_fraction_theta_max 0.996
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_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_limit_h_max       19
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_diffrn_reflns_limit_k_min       -25
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_diffrn_reflns_theta_max         36.32
_diffrn_reflns_theta_min         1.81
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_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.576
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0384P)^2^+0.6313P] where P=(Fo^2^+2Fc^2^)/3'
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