Lead and tin β-diketiminato amido/anilido complexes: competitive nucleophilic reactivity at the β-diketiminato γ-carbon.
Harris, Lisa A.-M.; Tam, Eric C. Y.; Coles, Martyn P.; Fulton, J. Robin; Dalton transactions (Cambridge, England : 2003) 43 (2014) 13803–13814; doi:10.1039/c4dt01714e

data_7031968
_publ_section_title
;
 Lead and tin \b-diketiminato amido/anilido complexes: competitive
 nucleophilic reactivity at the \b-diketiminato \g-carbon.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13803
_journal_page_last               13814
_journal_paper_doi               10.1039/c4dt01714e
_journal_volume                  43
_journal_year                    2014
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C35 H55 N3 Pb'
_chemical_formula_sum            'C35 H55 N3 Pb'
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;
 ?
;
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_cell_angle_gamma                90
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_cell_length_b                   20.3151(2)
_cell_length_c                   17.9079(3)
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_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.103
_cell_measurement_theta_min      3.395
_cell_measurement_wavelength     0.71073
_cell_volume                     3464.11(8)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Nonius BV, 1997-2000)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
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_diffrn_ambient_temperature      173(2)
_diffrn_detector                 'CCD plate'
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_diffrn_measurement_device       '95mm CCD camera on \k-goniostat'
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_diffrn_orient_matrix_type       'by Nonius Collect from scalepack cell'
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_diffrn_orient_matrix_UB_12      0.86211E-2
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_diffrn_orient_matrix_UB_22      0.312583E-1
_diffrn_orient_matrix_UB_23      -0.42132E-1
_diffrn_orient_matrix_UB_31      -0.543424E-1
_diffrn_orient_matrix_UB_32      -0.370357E-1
_diffrn_orient_matrix_UB_33      -0.273886E-1
_diffrn_radiation_monochromator  graphite
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        [c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            Orange
_exptl_crystal_density_diffrn    1.39
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             1472
_exptl_crystal_size_max          0.32
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_refine_diff_density_max         0.807
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_refine_diff_density_rms         0.089
_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         7664
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_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_gt           0.0251
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0217P)^2^+3.8769P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.053
_refine_ls_wR_factor_ref         0.0564
_reflns_number_gt                6565
_reflns_number_total             7664
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt01714e2.cif
_cod_data_source_block           (2)-nov509
_cod_depositor_comments
'Adding full bibliography for 7031968--7031975.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7031968