A dicoordinate gold(I)-ethylene complex.
Navarro, Miquel; Miranda-Pizarro, Juan; Moreno, Juan J.; Navarro-Gilabert, Carlos; Fernández, Israel; Campos, Jesús; Chemical communications (Cambridge, England) 57 (2021) 9280–9283; doi:10.1039/d1cc02769g

data_7128783
_publ_section_title
;
 A dicoordinate gold(I)-ethylene complex.
;
_journal_issue                   73
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              9280
_journal_page_last               9283
_journal_paper_doi               10.1039/d1cc02769g
_journal_volume                  57
_journal_year                    2021
_chemical_formula_sum            'C94 H90 Au B F24 N P'
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_space_group_name_Hall           '-P 1'
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_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-04-19 deposited with the CCDC.	2021-08-11 downloaded from the CCDC.
;
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_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      28.10
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_cell_volume                     5273.8(8)
_computing_cell_refinement       'Bruker APEX3'
_computing_data_collection       'Bruker APEX3'
_computing_data_reduction        'Bruker APEX3'
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_diffrn_ambient_temperature      193(2)
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker D8Quest'
_diffrn_measurement_method       '\f and \w scans'
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_diffrn_source                   'IuS 3.0 Microfocus Source'
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_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.5092
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ' Apex3 v2016.9-0 (Bruker, 2016)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.214
_exptl_crystal_description       plate
_exptl_crystal_F_000             1952
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_exptl_crystal_size_min          0.05
_platon_squeeze_details
;
The unit cell contains 6 pentane molecules which have
 been treated as a diffuse contribution to the overall scattering
 without specific atom positions by SQUEEZE/PLATON.'
;
_refine_diff_density_max         1.769
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         26156
_refine_ls_number_restraints     18
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_refine_ls_R_factor_all          0.0783
_refine_ls_R_factor_gt           0.0512
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.2439P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1414
_refine_ls_wR_factor_ref         0.1596
_reflns_Friedel_coverage         0.000
_reflns_number_gt                19604
_reflns_number_total             26156
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cc02769g2.cif
_cod_data_source_block           jcm01421a_a_sq
_cod_depositor_comments
'Adding full bibliography for 7128779--7128784.cif.'
_cod_database_code               7128783
_shelx_shelxl_version_number     2014/7
_platon_squeeze_void_probe_radius 1.20
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