Oxidative addition of small molecules to a dinuclear Au(I) amidinate complex, Au2[(2,6-Me2Ph)2N2CH]2. Syntheses and characterization of Au(II) amidinate complexes including one which possesses Au(II)-oxygen bonds.
Abdou, Hanan E.; Mohamed, Ahmed A.; Fackler, Jr, John P; Inorganic chemistry 46 (2007) 9692–9699; doi:10.1021/ic700929e

data_4339687
_publ_section_title
;
 Oxidative addition of small molecules to a dinuclear Au(I) amidinate
 complex, Au2[(2,6-Me2Ph)2N2CH]2. Syntheses and characterization of Au(II)
 amidinate complexes including one which possesses Au(II)-oxygen bonds.
;
_journal_issue                   23
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9692
_journal_page_last               9699
_journal_paper_doi               10.1021/ic700929e
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C38 H46 Au2 I2 N4 O'
_chemical_formula_weight         1222.53
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                84.815(2)
_cell_angle_beta                 78.352(2)
_cell_angle_gamma                88.577(2)
_cell_formula_units_Z            1
_cell_length_a                   8.0611(12)
_cell_length_b                   10.9563(16)
_cell_length_c                   11.3520(17)
_cell_measurement_temperature    110(2)
_cell_volume                     977.9(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full 0.928
_diffrn_measured_fraction_theta_max 0.928
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0309
_diffrn_reflns_av_sigmaI/netI    0.0459
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            8515
_diffrn_reflns_theta_full        28.41
_diffrn_reflns_theta_max         28.41
_diffrn_reflns_theta_min         1.84
_exptl_absorpt_coefficient_mu    9.105
_exptl_crystal_density_diffrn    2.076
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             912
_refine_diff_density_max         2.722
_refine_diff_density_min         -4.260
_refine_diff_density_rms         0.282
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     215
_refine_ls_number_reflns         4557
_refine_ls_number_restraints     10
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0459
_refine_ls_R_factor_gt           0.0422
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0866P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1204
_refine_ls_wR_factor_ref         0.1249
_reflns_number_gt                4078
_reflns_number_total             4557
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic700929e-file005.cif
_cod_data_source_block           dinuclearI2
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               4339687