<i>catena</i>-Poly[[tetrakis(hexamethylphosphoramide-κ<i>O</i>)bis(nitrato-κ^2^<i>O</i>,<i>O</i>')lanthanum(III)] [silver(I)-di-μ~2~-sulfido-tungstate(VI)-di-μ~2~-sulfido]]
Tang, Guodong; Zhang, Jinfang; Zhang, Chi; Lu, Lude; Acta Crystallographica Section E 64 (2008) m399–m400; doi:10.1107/S1600536807066597

data_2217530
_publ_section_title
;<i>catena</i>-Poly[[tetrakis(hexamethylphosphoramide-\k<i>O</i>)bis(nitrato-\k^2^<i>O</i>,<i>O</i>')lanthanum(III)]
 [silver(I)-di-\m~2~-sulfido-tungstate(VI)-di-\m~2~-sulfido]]
;
_journal_coeditor_code           HG2364
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m399
_journal_page_last               m400
_journal_paper_doi               10.1107/S1600536807066597
_journal_volume                  64
_journal_year                    2008
_chemical_formula_iupac          '[La (N O3)2 (C6 H18 N3 O P)4] [Ag W S4]'
_chemical_formula_moiety         'C24 H72 La N14 O10 P4 +, Ag S4 W -'
_chemical_formula_sum            'C24 H72 Ag La N14 O10 P4 S4 W'
_chemical_formula_weight         1399.71
_chemical_name_systematic
;
catena-Poly[[tetrakis(hexamethylphosphoramide-\kO)bis(nitrato-
\k^2^O,O')lanthanum(III)]
[silver(I)-di-\m~2~-sulfido-tungsten(VI)-di-\m~2~-sulfido]]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.502(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.883(2)
_cell_length_b                   30.070(4)
_cell_length_c                   11.5283(15)
_cell_measurement_reflns_used    19164
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      25.3
_cell_measurement_theta_min      3.1
_cell_volume                     5505.7(12)
_computing_cell_refinement       'CrystalClear (Rigaku, 2000)'
_computing_data_collection       'CrystalClear (Rigaku, 2000)'
_computing_data_reduction        'CrystalStructure (Rigaku/MSC, 2002)'
_computing_molecular_graphics    'SHELXL97 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      295(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0491
_diffrn_reflns_av_sigmaI/netI    0.0395
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       35
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            50056
_diffrn_reflns_theta_full        25.35
_diffrn_reflns_theta_max         25.35
_diffrn_reflns_theta_min         3.18
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.520
_exptl_absorpt_correction_T_max  0.26
_exptl_absorpt_correction_T_min  0.18
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            orange--red
_exptl_crystal_density_diffrn    1.689
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2784
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.42
_exptl_crystal_size_min          0.38
_refine_diff_density_max         1.073
_refine_diff_density_min         -1.897
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.146
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     462
_refine_ls_number_reflns         10031
_refine_ls_number_restraints     32
_refine_ls_restrained_S_all      1.147
_refine_ls_R_factor_all          0.0676
_refine_ls_R_factor_gt           0.0589
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0507P)^2^+23.8085P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1327
_refine_ls_wR_factor_ref         0.1373
_reflns_number_gt                8984
_reflns_number_total             10031
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hg2364.cif
_cod_data_source_block           I
_cod_original_cell_volume        5505.8(12)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2217530
_cod_database_fobs_code          2217530