Bis(diethylenetriamine-<i>N</i>'-acetato)-di-μ-hydroxo-dicobalt(III) Perchlorate
Chen, M.-Q.; Liu, J.; Mao, Z.-W.; Hang, Q.-W.; Tang, W.-X.; Acta Crystallographica Section C 51 (1995) 1080–1082; doi:10.1107/S0108270194013387

data_2003510
_publ_section_title
;
 Bis(diethylenetriamine-<i>N</i>'-acetato)-di-\m-hydroxo-dicobalt(III)
 Perchlorate
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1080
_journal_page_last               1082
_journal_paper_doi               10.1107/S0108270194013387
_journal_volume                  51
_journal_year                    1995
_chemical_formula_sum            'C12 H30 Cl2 Co2 N6 O14'
_chemical_formula_weight         671.18
_space_group_IT_number           130
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-P 4a 2ac'
_symmetry_space_group_name_H-M   'P 4/n c c :2'
_atom_type_scat_source           IntTabIV
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   14.203(6)
_cell_length_b                   14.203(6)
_cell_length_c                   22.447(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      16.0
_cell_measurement_theta_min      14.5
_cell_volume                     4528(3)
_diffrn_measurement_device       'Enraf-Nonius CAD-4'
_diffrn_measurement_method       \w/2\q
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.70930
_diffrn_reflns_av_R_equivalents  0.027
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            6790
_diffrn_reflns_theta_max         50.0
_diffrn_standards_decay_%        0.1
_diffrn_standards_interval_time  33.33
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.783
_exptl_absorpt_correction_T_max  0.9993
_exptl_absorpt_correction_T_min  0.8045
_exptl_absorpt_correction_type
;
empirical (North, Phillips & Mathews, 1968)
;
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.968
_exptl_crystal_description       rectangular
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.97(11)
_refine_diff_density_min         0.00(11)
_refine_ls_extinction_coef       1.8819E-8
_refine_ls_extinction_method
;
|F~c~|(1 + gI~c~)^-1^ (Zachariasen, 1963)
;
_refine_ls_goodness_of_fit_obs   4.149
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_number_parameters     160
_refine_ls_number_reflns         1550
_refine_ls_R_factor_obs          0.051
_refine_ls_shift/esd_max         0.02
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      unit
_refine_ls_wR_factor_obs         0.047
_reflns_number_observed          1550
_reflns_number_total             2363
_reflns_observed_criterion       I>3\s(I)
_cod_data_source_file            ab1161.cif
_cod_data_source_block           ab1161a
_cod_original_cell_volume        4528.18
_cod_original_sg_symbol_H-M      'P 4/n c c'
_cod_database_code               2003510