Selective formation of silver(i) bis-phospholane macrocycles and further evidence that gold(i) is smaller than silver(i).
Streitberger, Markus; Schmied, Andy; Hoy, Reinhard; Hey-Hawkins, Evamarie; Dalton transactions (Cambridge, England : 2003) 45 (2016) 11644–11649; doi:10.1039/c6dt00945j

data_7039305
_publ_section_title
;
 Selective formation of silver(i) bis-phospholane macrocycles and further
 evidence that gold(i) is smaller than silver(i).
;
_journal_issue                   29
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11644
_journal_page_last               11649
_journal_paper_doi               10.1039/c6dt00945j
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C35 H64 Ag2 B2 Cl4 F8 P4'
_chemical_formula_weight         1139.9
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4
_audit_creation_date             2015-11-16T12:59:56-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2015-11-30 deposited with the CCDC.
2016-05-18 downloaded from the CCDC.
;
_cell_angle_alpha                72.496(5)
_cell_angle_beta                 71.499(5)
_cell_angle_gamma                87.663(5)
_cell_formula_units_Z            1
_cell_length_a                   10.229(5)
_cell_length_b                   10.332(5)
_cell_length_c                   12.516(5)
_cell_measurement_reflns_used    8814
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      37.2815
_cell_measurement_theta_min      3.1245
_cell_volume                     1194.1(10)
_computing_cell_refinement
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
        (compiled Oct 27 2011,15:02:11)
;
_computing_data_collection
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
        (compiled Oct 27 2011,15:02:11)
;
_computing_data_reduction
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
        (compiled Oct 27 2011,15:02:11)
;
_computing_molecular_graphics    'ORTEP3 for Windows (L. J. Farrugia, 1997)'
_computing_publication_material  'WINGX  (L.J. Farrugia,1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Giacovazzo 1993)'
_diffrn_ambient_temperature      130(2)
_diffrn_detector_area_resol_mean 16.356
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini'
_diffrn_measurement_method       '\w scans'
_diffrn_orient_matrix_UB_11      -0.0198699
_diffrn_orient_matrix_UB_12      0.0679811
_diffrn_orient_matrix_UB_13      -0.0084902
_diffrn_orient_matrix_UB_21      -0.0703123
_diffrn_orient_matrix_UB_22      -0.0232992
_diffrn_orient_matrix_UB_23      0.0188694
_diffrn_orient_matrix_UB_31      -0.0052854
_diffrn_orient_matrix_UB_32      -0.0060344
_diffrn_orient_matrix_UB_33      0.0592145
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0175
_diffrn_reflns_av_unetI/netI     0.0271
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            23349
_diffrn_reflns_theta_full        36.32
_diffrn_reflns_theta_max         36.32
_diffrn_reflns_theta_min         3.13
_exptl_absorpt_coefficient_mu    1.234
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.85737
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
        (compiled Oct 27 2011,15:02:11)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.585
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             578
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.2
_refine_diff_density_max         0.922
_refine_diff_density_min         -1.019
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     318
_refine_ls_number_reflns         11560
_refine_ls_number_restraints     102
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.04
_refine_ls_R_factor_gt           0.0308
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0289P)^2^+0.4946P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0685
_refine_ls_wR_factor_ref         0.0735
_reflns_number_gt                9722
_reflns_number_total             11560
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            c6dt00945j2.cif
_cod_data_source_block           4
_cod_depositor_comments
'Adding full bibliography for 7039305--7039308.cif.'
_cod_original_cell_volume        1194.1(9)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7039305