Palladium(II)-catalyzed directed trifluoromethylthiolation of unactivated C(sp³)-H bonds.
Xiong, Heng-Ying; Besset, Tatiana; Cahard, Dominique; Pannecoucke, Xavier; The Journal of organic chemistry 80 (2015) 4204–4212; doi:10.1021/acs.joc.5b00505

data_4036200
_publ_section_title
;
 Palladium(II)-catalyzed directed trifluoromethylthiolation of unactivated
 C(sp&#x00B3;)-H bonds.
;
_journal_issue                   8
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              4204
_journal_page_last               4212
_journal_paper_doi               10.1021/acs.joc.5b00505
_journal_volume                  80
_journal_year                    2015
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C15 H15 F3 N2 O1 S1'
_chemical_formula_sum            'C15 H15 F3 N2 O S'
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_space_group_IT_number           14
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_diffrn_measurement_device_type  'SMART APEX'
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_min         1.78
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_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.419
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0838P)^2^+0.1900P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     >2\s(I)
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