Formation of a caged rhodium complex via an intramolecular, metal-mediated [2 + 2 + 1] cycloaddition of alkynes and CO
Baker, Murray V.; Brown, David H.; Skelton, Brian W.; White, Allan H.; Journal of the Chemical Society, Dalton Transactions  (2002) 2595–; doi:10.1039/b202713e

data_7011673
_publ_section_title
;
 Formation of a caged rhodium complex via an intramolecular,
 metal-mediated [2 + 2 + 1] cycloaddition of alkynes and CO
;
_journal_issue                   13
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2595
_journal_paper_doi               10.1039/b202713e
_journal_year                    2002
_chemical_formula_sum            'C26 H42 F6 N4 O3 P Rh'
_chemical_formula_weight         706.52
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_cell_measurement_theta_max      24.8
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_cell_volume                     1458.9(3)
_computing_cell_refinement       'Siemens SAINT (Siemens, 1995)'
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_diffrn_measurement_device_type
;
Bruker SMART CCD diffractometer
;
_diffrn_measurement_method       '\w scans'
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_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_theta_min         2.26
_diffrn_standards_decay_%        0
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_exptl_absorpt_process_details
;
SADABS; Sheldrick, 1996
;
_exptl_crystal_colour            yellow
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_exptl_crystal_description       prism
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_refine_ls_structure_factor_coef F
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_reflns_d_resolution_high        .583
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_reflns_threshold_expression     'F    > 4.00 sig(F   )'
_cod_data_source_file            b202713e.txt
_cod_data_source_block           dhb107
_cod_original_sg_symbol_Hall     -p_1
_cod_original_sg_symbol_H-M      P_-1
_cod_original_formula_sum        'C26 H42 F6 N4 O3 P1 Rh1'
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