Cationic Stannylenes: In Situ Generation and NMR Spectroscopic Characterization.
Sindlinger, Christian P.; Aicher, Frederik S. W.; Wesemann, Lars; Inorganic chemistry 56 (2017) 548–560; doi:10.1021/acs.inorgchem.6b02377

data_4344932
_publ_section_title
;
 Cationic Stannylenes: In Situ Generation and NMR Spectroscopic
 Characterization.
;
_journal_issue                   1
_journal_name_full               'Inorganic chemistry'
_journal_page_first              548
_journal_page_last               560
_journal_paper_doi               10.1021/acs.inorgchem.6b02377
_journal_volume                  56
_journal_year                    2017
_chemical_formula_sum            'C83 H83 B F15 N4 Sn2'
_chemical_formula_weight         1669.72
_chemical_name_systematic
;
 ?
;
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_symmetry_space_group_name_Hall  '-P 1'
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_cell_volume                     3745.51(12)
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_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.752
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_exptl_absorpt_correction_T_min  0.9159
_exptl_absorpt_correction_type   numerical
_exptl_crystal_colour            green
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_exptl_crystal_description       prism
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_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.017
_refine_ls_R_factor_all          0.0571
_refine_ls_R_factor_gt           0.0362
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0341P)^2^+2.5758P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 4344932.cif.'
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