Gold-catalyzed alkenylation and arylation of phosphorothioates.
Urvashi, ?; Mishra, Sampoorna; Patil, Nitin T.; Chemical science 14 (2023) 13134–13139; doi:10.1039/d3sc04888h

data_1570216
_publ_section_title
;
 Gold-catalyzed alkenylation and arylation of phosphorothioates.
;
_journal_issue                   45
_journal_name_full               'Chemical science'
_journal_page_first              13134
_journal_page_last               13139
_journal_paper_doi               10.1039/d3sc04888h
_journal_volume                  14
_journal_year                    2023
_chemical_formula_moiety         'C20 H16 Br O3 P S'
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Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_audit_update_record
;
2023-08-25 deposited with the CCDC.	2023-10-30 downloaded from the CCDC.
;
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_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1546P)^2^+11.0305P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 1570215--1570216.cif.'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C007(H007), C008(H008), C00C(H00C), C00E(H00E), C00F(H00F), C00G(H00G),
 C00H(H00H), C00I(H00I), C00J(H00J), C00K(H00K), C00L(H00L), C00M(H00M),
 C00N(H00N), C00O(H00O), C00P(H00P), C00Q(H00Q)
;
_shelx_res_checksum              46283
_olex2_submission_special_instructions 'No special instructions were received'