Cationic PCP iridaepoxide and carbene complexes for facile water elimination and activation processes.
Doyle, Lauren E.; Piers, Warren E.; Bi, David W.; Dalton transactions (Cambridge, England : 2003) 46 (2017) 4346–4354; doi:10.1039/c7dt00563f

data_7042378
_publ_section_title
;
 Cationic PCP iridaepoxide and carbene complexes for facile water
 elimination and activation processes.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4346
_journal_page_last               4354
_journal_paper_doi               10.1039/c7dt00563f
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C31 H38 F6 Ir N O5 P2 S4'
_chemical_formula_sum            'C31 H38 F6 Ir N O5 P2 S4'
_chemical_formula_weight         1001.00
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
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_atom_sites_solution_hydrogens   mixed
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;
2017-02-02 deposited with the CCDC.
2017-03-08 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Nonius Kappa CCD area detector'
_diffrn_measurement_method       '\w & \p scans'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0180P)^2^+21.0130P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             8514
_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7042378--7042379.cif.'
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