The Mechanism of N-N Double Bond Cleavage by an Iron(II) Hydride Complex.
Bellows, Sarina M.; Arnet, Nicholas A.; Gurubasavaraj, Prabhuodeyara M.; Brennessel, William W.; Bill, Eckhard; Cundari, Thomas R.; Holland, Patrick L.; Journal of the American Chemical Society 138 (2016) 12112–12123; doi:10.1021/jacs.6b04654

data_4130568
_publ_section_title
;
 The Mechanism of N-N Double Bond Cleavage by an Iron(II) Hydride Complex.
;
_journal_issue                   37
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              12112
_journal_page_last               12123
_journal_paper_doi               10.1021/jacs.6b04654
_journal_volume                  138
_journal_year                    2016
_chemical_formula_moiety         'C74 H82 Fe2 N8, C5 H12'
_chemical_formula_sum            'C79 H94 Fe2 N8'
_chemical_formula_weight         1267.32
_chemical_name_common            holsc30
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
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_cell_angle_beta                 96.110(3)
_cell_angle_gamma                90
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_cell_length_b                   19.714(3)
_cell_length_c                   20.122(3)
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_cell_measurement_theta_max      37.40
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART APEX II CCD Platform'
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_diffrn_reflns_av_unetI/netI     0.0629
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_diffrn_reflns_limit_h_max       29
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; 
 w=1/[\s^2^(Fo^2^)+(0.0665P)^2^+0.6143P] 
 where P=(Fo^2^+2Fc^2^)/3 
;
_refine_ls_weighting_scheme      calc
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_cod_original_cell_volume        6760.3(15)
_cod_original_sg_symbol_H-M      'P 21/c'
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