Rigid, yet flexible: formation of unprecedented silver MB-DIPY dimers with orthogonal chromophore geometry.
Zatsikha, Yuriy V.; Shamova, Liliya I.; Blesener, Tanner S.; Herbert, David E.; Nemykin, Victor N.; Dalton transactions (Cambridge, England : 2003) 49 (2020) 5034–5038; doi:10.1039/d0dt00927j

data_7703731
_publ_section_title
;
 Rigid, yet flexible: formation of unprecedented silver MB-DIPY dimers
 with orthogonal chromophore geometry.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5034
_journal_page_last               5038
_journal_paper_doi               10.1039/d0dt00927j
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C56 H32 Ag2 N6 O4 S4, C H4 O'
_chemical_formula_sum            'C57 H36 Ag2 N6 O5 S4'
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2020-02-10 deposited with the CCDC.	2020-03-13 downloaded from the CCDC.
;
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_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  'TRIUMPH curved--crystal'
_diffrn_radiation_source         'fine-focus tube'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns.reduction_process narrow--frame
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0719P)^2^+5.7112P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1286
_refine_ls_wR_factor_ref         0.1482
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7340
_reflns_number_total             11041
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt00927j2.cif
_cod_data_source_block           nem022
_cod_depositor_comments          'Adding full bibliography for 7703731.cif.'
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_shelx_shelxl_version_number     2017/1
_shelx_estimated_absorpt_t_min   0.919
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_shelx_res_checksum              67925