From molecular germanates to microporous Ge@C via twin polymerization.
Kitschke, Philipp; Walter, Marc; Rüffer, Tobias; Lang, Heinrich; Kovalenko, Maksym V.; Mehring, Michael; Dalton transactions (Cambridge, England : 2003) 45 (2016) 5741–5751; doi:10.1039/c6dt00049e

data_7038576
_publ_section_title
;
 From molecular germanates to microporous Ge@C via twin polymerization.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5741
_journal_page_last               5751
_journal_paper_doi               10.1039/c6dt00049e
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         '2(C21 H18 Ge O6), C H2 Cl2, 4(C2 H8 N)'
_chemical_formula_sum            'C25.5 H35 Cl Ge N2 O6'
_chemical_formula_weight         573.59
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-I 2ya'
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_symmetry_space_group_name_Hall  '-I 2ya'
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2016-02-04 deposited with the CCDC.
2016-02-24 downloaded from the CCDC.
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_cell_angle_alpha                90
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
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_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
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_diffrn_radiation_type           CuK\a
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.442
_exptl_crystal_description       plate
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0410P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                6286
_reflns_number_total             8596
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt00049e2.cif
_cod_data_source_block           shelx
_cod_depositor_comments
'Adding full bibliography for 7038574--7038576.cif.'
_cod_original_cell_volume        10568(4)
_cod_original_formula_sum        'C25.50 H35 Cl Ge N2 O6'
_cod_database_code               7038576
_shelxl_version_number           2013-4
_shelx_res_checksum              14442