Homogeneous cobalt-catalyzed deoxygenative hydrogenation of amides to amines
Papa, Veronica; Cabrero-Antonino, Jose R.; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias; Catalysis Science & Technology 10 (2020) 6116–6128; doi:10.1039/D0CY01078B

data_1558490
_publ_section_title
;
 Homogeneous cobalt-catalyzed deoxygenative hydrogenation of amides to
 amines
;
_journal_issue                   18
_journal_name_full               'Catalysis Science &amp; Technology'
_journal_page_first              6116
_journal_page_last               6128
_journal_paper_doi               10.1039/D0CY01078B
_journal_volume                  10
_journal_year                    2020
_chemical_formula_sum            'C95 H104 B2 Cl2 Co2 F10 O12 P6'
_chemical_formula_weight         2023.98
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_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-12-16 deposited with the CCDC.	2020-06-25 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 8.3333
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_exptl_absorpt_correction_T_max  0.43
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_exptl_crystal_colour            brown
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_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.0560
_refine_ls_R_factor_gt           0.0509
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0616P)^2^+35.3704P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                16775
_reflns_number_total             18493
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0cy01078b2.cif
_cod_data_source_block           ax1802w_sq
_cod_depositor_comments          'Adding full bibliography for 1558490.cif.'
_cod_database_code               1558490
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              16370
_shelx_fab_checksum              46839