Bis(tetraphenylphosphonium) bis[<i>N</i>-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2{-})-κ^2^<i>S</i>,<i>S</i>']platinate(II)
Guilardi, S.; Flauzino Neto, Wilson P.; Vieira, Lucas C. C.; Amin, Raquel S.; Oliveira, Marcelo R. L.; Acta Crystallographica Section E 66 (2010) m251–; doi:10.1107/S1600536810003272

data_2225252
_publ_section_title
;Bis(tetraphenylphosphonium)
 bis[<i>N</i>-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2{-})-\k^2^<i>S</i>,<i>S</i>']platinate(II)
;
_journal_coeditor_code           HB5315
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m251
_journal_paper_doi               10.1107/S1600536810003272
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '(C24 H20 P)2 [Pt (C7 H3 Cl2 N O2 S3)2]'
_chemical_formula_moiety         '2(C24 H20 P +), C14 H6 Cl4 N2 O4 Pt S6 2-'
_chemical_formula_sum            'C62 H46 Cl4 N2 O4 P2 Pt S6'
_chemical_formula_weight         1474.3
_chemical_name_systematic
;
Bis(tetraphenylphosphonium)
bis[<i>N</i>-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2-)-
\k^2^<i>S</i>,<i>S</i>']platinate(II)
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                76.9510(10)
_cell_angle_beta                 88.3530(10)
_cell_angle_gamma                86.1930(10)
_cell_formula_units_Z            1
_cell_length_a                   9.62840(10)
_cell_length_b                   10.3409(2)
_cell_length_c                   15.1278(2)
_cell_measurement_reflns_used    20612
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.103
_cell_measurement_theta_min      2.91
_cell_volume                     1463.94(4)
_computing_cell_refinement
'DENZO and SCALEPACK (Otwinowski & Minor, 1997)'
_computing_data_collection       'COLLECT (Nonius, 2000)'
_computing_data_reduction
'DENZO and SCALEPACK (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'Mercury (Macrae <i>et al.</i>, 2006)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      120
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device       '95mm CCD camera on \k-goniostat'
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'CCD rotation images, thick slices'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.029
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            11423
_diffrn_reflns_theta_full        27.25
_diffrn_reflns_theta_max         27.25
_diffrn_reflns_theta_min         2.94
_exptl_absorpt_coefficient_mu    2.899
_exptl_absorpt_correction_T_max  0.477
_exptl_absorpt_correction_T_min  0.439
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   '(Coppens <i>et al.</i>,  1965)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.672
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             736
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.3
_refine_diff_density_max         0.693
_refine_diff_density_min         -2.579
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.11
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     367
_refine_ls_number_reflns         6536
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.11
_refine_ls_R_factor_gt           0.0249
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0373P)^2^+0.5896P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0676
_reflns_number_gt                6483
_reflns_number_total             6536
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb5315.cif
_cod_data_source_block           I
_cod_database_code               2225252
_cod_database_fobs_code          2225252