Stereoselectivity in a Chiral Ruthenium Ethylene Hydride Complex: Evidence of an Agostic Intermediate
Faller, J. W.; Fontaine, Philip P.; Organometallics 26 (2007) 1738–; doi:10.1021/om060868j

data_4072601
_publ_section_title
;
 Stereoselectivity in a Chiral Ruthenium Ethylene Hydride Complex:&#x00A0;
 Evidence of an Agostic Intermediate
;
_journal_issue                   7
_journal_name_full               Organometallics
_journal_page_first              1738
_journal_paper_doi               10.1021/om060868j
_journal_volume                  26
_journal_year                    2007
_chemical_formula_moiety         'C28 H41 N P Ru, F6 P'
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_computing_cell_refinement       Denzo-SMN
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_computing_publication_material  'teXsan for Windows v. 1.06 (MSC 1999)'
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SIR92 (Altomare, et. al. 1994)
;
_diffrn_ambient_temperature      173.2
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_diffrn_reflns_limit_l_min       -26
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_diffrn_reflns_reduction_process 'Lp corrections applied'
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_diffrn_reflns_theta_min         0.91
_diffrn_standards_decay_%        0.00
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.703
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
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_refine_ls_R_factor_gt           0.0380
_refine_ls_shift/su_max          0.0000
_refine_ls_shift/su_mean         0.0001
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo)]'
_refine_ls_weighting_scheme      sigma
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_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            om060868jsi20060922_115754.cif
_cod_data_source_block           '_2605[TetherRu(ethylene)H]'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        5843.94(13)
_cod_original_sg_symbol_H-M      'P 21/c     '
_cod_original_formula_sum        'C28 H41 F6 N P2 Ru '
_cod_database_code               4072601