Modulating the σ-Accepting Properties of an Antimony Z-type Ligand via Anion Abstraction: Remote-Controlled Reactivity of the Coordinated Platinum Atom.
You, Di; Yang, Haifeng; Sen, Srobona; Gabbaï, François P; Journal of the American Chemical Society 140 (2018) 9644–9651; doi:10.1021/jacs.8b05520

data_4132685
_publ_section_title
;
 Modulating the \s-Accepting Properties of an Antimony Z-type Ligand via
 Anion Abstraction: Remote-Controlled Reactivity of the Coordinated
 Platinum Atom.
;
_journal_issue                   30
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              9644
_journal_page_last               9651
_journal_paper_doi               10.1021/jacs.8b05520
_journal_volume                  140
_journal_year                    2018
_chemical_formula_sum            'C44 H41 Cl2 F3 N P2 Pt Sb'
_chemical_formula_weight         1090.46
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                69.737(5)
_cell_angle_beta                 77.030(5)
_cell_angle_gamma                80.654(5)
_cell_formula_units_Z            2
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_cell_length_b                   13.608(7)
_cell_length_c                   17.248(9)
_cell_measurement_reflns_used    7758
_cell_measurement_temperature    110(2)
_cell_measurement_theta_max      56.218
_cell_measurement_theta_min      4.620
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_av_unetI/netI     0.0695
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.968
_diffrn_reflns_limit_h_max       12
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_diffrn_reflns_limit_k_min       -18
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_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.968
_diffrn_reflns_theta_full        25.242
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_diffrn_reflns_theta_min         2.310
_exptl_absorpt_coefficient_mu    4.286
_exptl_absorpt_correction_T_max  0.8142
_exptl_absorpt_correction_T_min  0.6738
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.752
_exptl_crystal_description       needle
_exptl_crystal_F_000             1064
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.070
_exptl_crystal_size_min          0.050
_refine_diff_density_max         1.147
_refine_diff_density_min         -1.570
_refine_diff_density_rms         0.170
_refine_ls_extinction_method     none
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_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
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_refine_ls_restrained_S_all      1.011
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0301P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                8452
_reflns_number_total             10270
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja8b05520_si_002.cif
_cod_data_source_block           3
_cod_original_cell_volume        2067.0(18)
_cod_database_code               4132685
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.674
_shelx_estimated_absorpt_t_max   0.814
_exptl_absorpt_special_details   SADABS
_shelx_res_checksum              63701
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