Synthesis and Characterization of Dimethylbis(2-pyridyl)borate Nickel(II) Complexes: Unimolecular Square-Planar to Square-Planar Rotation around Nickel(II).
Celaje, Jeff A.; Pennington-Boggio, Megan K; Flaig, Robinson W.; Richmond, Michael G.; Williams, Travis J.; Organometallics 33 (2014) 2019–2026; doi:10.1021/om500173j

data_4082951
_publ_section_title
;
 Synthesis and Characterization of Dimethylbis(2-pyridyl)borate Nickel(II)
 Complexes: Unimolecular Square-Planar to Square-Planar Rotation around
 Nickel(II).
;
_journal_issue                   8
_journal_name_full               Organometallics
_journal_page_first              2019
_journal_page_last               2026
_journal_paper_doi               10.1021/om500173j
_journal_volume                  33
_journal_year                    2014
_chemical_formula_moiety         'C30 H29 B Cl N2 Ni P'
_chemical_formula_sum            'C30 H29 B Cl N2 Ni P'
_chemical_formula_weight         553.49
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_cell_length_c                   13.046(2)
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_computing_cell_refinement       'APEX2 v2013.10-0 (Bruker AXS)'
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_diffrn_reflns_av_unetI/netI     0.0427
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_exptl_crystal_colour            'clear red'
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_refine_ls_R_factor_all          0.0664
_refine_ls_R_factor_gt           0.0522
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0750P)^2^+1.7017P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            om500173j_si_002.cif
_cod_data_source_block           final_sqd
_cod_depositor_comments
;Adding full bibliography for 4082950--4082951.cif.

 Adding full bibliography for 4082950--4082951.cif.
;
_cod_original_cell_volume        1539.5(5)
_cod_database_code               4082951
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_shelx_estimated_absorpt_t_max   0.857
_shelxl_version_number           2013-3
_shelx_res_checksum              1547
_shelx_hkl_checksum              24629