The preparation and characterization of trans-platinum(IV) complexes with unusually high cytotoxicity.
Cubo, Leticia; Hambley, Trevor W.; Sanz Miguel, Pablo J.; Carnero, Amancio; Navarro-Ranninger, Carmen; Quiroga, Adoración G; Dalton transactions (Cambridge, England : 2003) 40 (2011) 344–347; doi:10.1039/c0dt00565g

data_7014361
_publ_section_title
;
 The preparation and characterization of trans-platinum(IV) complexes
 with unusually high cytotoxicity.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              344
_journal_page_last               347
_journal_paper_doi               10.1039/c0dt00565g
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C3 H14 Cl2 N2 O2 Pt, 3(H2 O)'
_chemical_formula_sum            'C3 H20 Cl2 N2 O5 Pt'
_chemical_formula_weight         430.2
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2010-05-20T20:29:59-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                77.605(3)
_cell_angle_beta                 82.586(2)
_cell_angle_gamma                74.228(2)
_cell_formula_units_Z            2
_cell_length_a                   6.1970(3)
_cell_length_b                   8.1633(5)
_cell_length_c                   12.9784(7)
_cell_measurement_reflns_used    12779
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.28
_cell_measurement_theta_min      3.22
_cell_volume                     615.36(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.988
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.029
_diffrn_reflns_av_unetI/netI     0.0263
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            12779
_diffrn_reflns_theta_full        25
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         3.22
_exptl_absorpt_coefficient_mu    11.832
_exptl_absorpt_correction_T_max  0.388
_exptl_absorpt_correction_T_min  0.134
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.322
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prisms
_exptl_crystal_F_000             408
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.118
_refine_diff_density_min         -1.157
_refine_diff_density_rms         0.13
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     123
_refine_ls_number_reflns         3024
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.0195
_refine_ls_R_factor_gt           0.0166
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0151P)^2^+0.5724P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0365
_refine_ls_wR_factor_ref         0.0376
_reflns_number_gt                2832
_reflns_number_total             3024
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            C0DT00565G.TXT
_cod_data_source_block           1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7014361