High-nuclearity silver ethynide clusters containing polynucleating oxygen donor ligands.
Jin, Jun-Ling; Xie, Yun-Peng; Lu, Xing; Dalton transactions (Cambridge, England : 2003) 47 (2018) 12972–12978; doi:10.1039/c8dt02700e

data_7047346
_publ_section_title
;
 High-nuclearity silver ethynide clusters containing polynucleating oxygen
 donor ligands.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12972
_journal_page_last               12978
_journal_paper_doi               10.1039/c8dt02700e
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C159 H227 Ag30 Bi6 Cl2 F48 O51.5 P6'
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
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_audit_update_record
;
2018-08-16 deposited with the CCDC.
2018-08-22 downloaded from the CCDC.
;
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
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_diffrn_measurement_device_type  'Bruker D8 Quest'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+3055.1331P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2105
_refine_ls_wR_factor_ref         0.2231
_reflns_Friedel_coverage         0.000
_reflns_number_gt                13286
_reflns_number_total             16825
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt02700e2.cif
_cod_data_source_block           Complex4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7047343--7047346.cif.
;
_cod_original_cell_volume        24342(3)
_cod_original_formula_sum        'C159 H227 Ag30 Bi6 Cl2 F48 O51.50 P6'
_cod_database_code               7047346
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.591
_shelx_estimated_absorpt_t_max   0.758
_shelx_res_checksum              88236
_shelx_fab_checksum              15411