<i>cis</i>-Dichloridobis(diethylphenylphosphine-κ<i>P</i>)platinum(II)
Domańska-Babul, Wioleta; Pikies, Jerzy; Chojnacki, Jaroslaw; Acta Crystallographica Section E 63 (2007) m2583–m2583; doi:10.1107/S1600536807045540

data_2215647
_publ_section_title
;
 <i>cis</i>-Dichloridobis(diethylphenylphosphine-\k<i>P</i>)platinum(II)
;
_journal_coeditor_code           RZ2163
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2583
_journal_page_last               m2583
_journal_paper_doi               10.1107/S1600536807045540
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Pt Cl2 (C10 H15 P)2]'
_chemical_formula_moiety         'C20 H30 Cl2 P2 Pt'
_chemical_formula_sum            'C20 H30 Cl2 P2 Pt'
_chemical_formula_weight         598.37
_chemical_name_systematic
;
<i>cis</i>-Dichloridobis(diethylphenylphosphine-\kP)platinum(II)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 94.865(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.8957(5)
_cell_length_b                   9.0402(5)
_cell_length_c                   16.3565(5)
_cell_measurement_reflns_used    12825
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      32.4335
_cell_measurement_theta_min      2.2482
_cell_volume                     2194.63(16)
_computing_cell_refinement
;
CrysAlis RED (Oxford Diffraction, 2006)
;
_computing_data_collection
;
CrysAlis CCD (Oxford Diffraction, 2006)
;
_computing_data_reduction
;
CrysAlis RED (Oxford Diffraction, 2006)
;
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material
'WinGX (Farrugia, 1999) and PLATON (Spek, 2003)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Oxford Diffraction KM-4 CCD'
_diffrn_measurement_method       '0.75\% \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0131
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            9492
_diffrn_reflns_theta_full        26
_diffrn_reflns_theta_max         26
_diffrn_reflns_theta_min         2.5
_exptl_absorpt_coefficient_mu    6.785
_exptl_absorpt_correction_T_max  0.398
_exptl_absorpt_correction_T_min  0.278
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
[CrysAlis RED; Oxford Diffraction (2006), Clark & Reid (1995)]
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.811
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1168
_exptl_crystal_size_max          0.1634
_exptl_crystal_size_mid          0.1116
_exptl_crystal_size_min          0.0597
_refine_diff_density_max         1.326
_refine_diff_density_min         -1.252
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.358
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     230
_refine_ls_number_reflns         4301
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.358
_refine_ls_R_factor_gt           0.0248
_refine_ls_shift/su_max          0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0454P)^2^+6.1376P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0889
_reflns_number_gt                4145
_reflns_number_total             4301
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            rz2163.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2215647
_cod_database_fobs_code          2215647