An efficient synthesis of polyynyl and polyynediyl complexes of ruthenium(II) †
Bruce, Michael I.; Hall, Ben C.; Kelly, Brian D.; Low, Paul J.; Skelton, Brian W.; White, Allan H.; Journal of the Chemical Society, Dalton Transactions  (1999) 3719–; doi:10.1039/a905174k

data_7027654
_publ_section_title
;
 An efficient synthesis of polyynyl and polyynediyl complexes of
 ruthenium(II)&#x200A;&#x2020;
;
_journal_issue                   21
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              3719
_journal_paper_doi               10.1039/a905174k
_journal_year                    1999
_chemical_formula_sum            'C94 H86 O2 P4 Ru2'
_chemical_formula_weight         1573.76
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_cell_angle_beta                 118.11(3)
_cell_angle_gamma                90.00000
_cell_formula_units_Z            4
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_cell_length_b                   14.710(9)
_cell_length_c                   25.874(9)
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_cell_measurement_temperature    293
_cell_measurement_theta_max      14.4
_cell_measurement_theta_min      8.3
_cell_volume                     7894(7)
_computing_cell_refinement       'Enraf Nonius software'
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_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  xtal
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_diffrn_ambient_temperature      293
_diffrn_measurement_device_type
;
CAD4 diffractometer               
;
_diffrn_measurement_method       '2\q-\w scans'
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_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
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_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       0
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_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -27
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_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  3600
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_exptl_absorpt_coefficient_mu    .513
_exptl_absorpt_correction_T_max  .94
_exptl_absorpt_correction_T_min  .92
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
 XTAL absorb                
;
_exptl_crystal_density_diffrn    1.324
_exptl_crystal_description       prism
_exptl_crystal_F_000             3256
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.15
_refine_diff_density_min         -1.93
_refine_ls_abs_structure_details none
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   2.135
_refine_ls_goodness_of_fit_ref   2.967
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           block
_refine_ls_number_constraints    0
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_refine_ls_number_reflns         6675
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .150
_refine_ls_R_factor_gt           .083
_refine_ls_shift/su_max          .176
_refine_ls_shift/su_mean         .0061
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         .090
_refine_ls_wR_factor_ref         .083
_reflns_limit_h_max              20
_reflns_limit_h_min              0
_reflns_limit_k_max              17
_reflns_limit_k_min              0
_reflns_limit_l_max              26
_reflns_limit_l_min              -27
_reflns_number_gt                6675
_reflns_number_observed          14092
_reflns_number_total             14092
_reflns_threshold_expression     'I    > 3.00 sig(I   )'
_cod_data_source_file            905174ksup1.cif
_cod_data_source_block           br530
_cod_original_sg_symbol_Hall     -p_2ybc
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_cod_database_code               7027654