Coupling of CO2 and Epoxides Catalysed by Novel N-Fused Mesoionic Carbene Complexes of Nickel(II)
Watt, Fabian A.; Sieland, Benedikt; Dickmann, Nicole; Schoch, Roland; Herbst-Irmer, Regine; Ott, Holger; Paradies, Jan; Kuckling, Dirk; Hohloch, Stephan; Dalton Transactions  (2021) –; doi:10.1039/D1DT03311E

data_7708653
_publ_section_title
;
 Coupling of CO2 and Epoxides Catalysed by Novel N-Fused Mesoionic Carbene
 Complexes of Nickel(II)
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D1DT03311E
_journal_year                    2021
_chemical_formula_sum            'C35 H43 Cl2 N7 Ni O2'
_chemical_formula_weight         723.37
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-09-29 deposited with the CCDC.	2021-10-27 downloaded from the CCDC.
;
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_cell_length_b                   13.8963(7)
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_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.40
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_cell_volume                     1672.07(15)
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker D8 Quest'
_diffrn_measurement_method       'omega + phi scans'
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_diffrn_reflns_av_unetI/netI     0.0303
_diffrn_reflns_Laue_measured_fraction_full 0.997
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, 1995'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0374P)^2^+0.7614P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                6519
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_reflns_threshold_expression     'I > 2\s(I)'
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