Cationic carbohydroxylation of alkenes and alkynes using the cation pool method.
Suga, Seiji; Kageyama, Yasuhisa; Babu, Govindarajulu; Itami, Kenichiro; Yoshida, Jun-ichi; Organic letters 6 (2004) 2709–2711; doi:10.1021/ol049049q

data_1507064
_publ_section_title
;
 Cationic carbohydroxylation of alkenes and alkynes using the cation pool
 method.
;
_journal_issue                   16
_journal_name_full               'Organic letters'
_journal_page_first              2709
_journal_page_last               2711
_journal_paper_doi               10.1021/ol049049q
_journal_volume                  6
_journal_year                    2004
_chemical_formula_moiety         'C15 H23 N O3 Si '
_chemical_formula_sum            'C15 H23 N O3 Si'
_chemical_formula_weight         293.44
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      5
_symmetry_space_group_name_Hall  'C 2y'
_symmetry_space_group_name_H-M   'C 1 2 1'
_cell_angle_alpha                90
_cell_angle_beta                 94.813(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.733(1)
_cell_length_b                   6.3666(5)
_cell_length_c                   24.617(2)
_cell_measurement_reflns_used    9802
_cell_measurement_temperature    296.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.8
_cell_volume                     1676.2(2)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 2.00'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.9966
_diffrn_measured_fraction_theta_max 0.9966
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.044
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            7246
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    0.146
_exptl_absorpt_correction_T_max  0.957
_exptl_absorpt_correction_T_min  0.711
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
    Higashi, T. (1995). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.163
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.30
_refine_diff_density_max         0.31
_refine_diff_density_min         -0.23
_refine_ls_extinction_coef       16.2(3)
_refine_ls_extinction_method
'Larson (1970) Crystallographic Computing eq. 22'
_refine_ls_goodness_of_fit_ref   9.488
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     205
_refine_ls_number_reflns         1756
_refine_ls_R_factor_gt           0.0460
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/\s^2^(Fo)'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_ref         0.0160
_reflns_number_gt                1756
_reflns_number_total             2056
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ol049049qsi20040523_095854.cif
_cod_data_source_block           '_kageyama2________________'
_cod_original_formula_sum        'C15 H23 N O3 Si '
_cod_database_code               1507064