Catalyst-free geminal aminofluorination of ortho-sulfonamide-tethered alkylidenecyclopropanes via a Wagner-Meerwein rearrangement.
Fan, Xing; Wang, Qiang; Wei, Yin; Shi, Min; Chemical communications (Cambridge, England) 54 (2018) 10503–10506; doi:10.1039/c8cc05634j

data_7122207
_publ_section_title
;
 Catalyst-free geminal aminofluorination of ortho-sulfonamide-tethered
 alkylidenecyclopropanes via a Wagner-Meerwein rearrangement.
;
_journal_issue                   74
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              10503
_journal_page_last               10506
_journal_paper_doi               10.1039/c8cc05634j
_journal_volume                  54
_journal_year                    2018
_chemical_absolute_configuration unk
_chemical_formula_sum            'C22 H17 Br F N O2 S'
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_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2016-04-18 deposited with the CCDC.
2018-08-20 downloaded from the CCDC.
;
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; 
 Refined as an inversion twin. 
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0492P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7122207--7122209.cif.'
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