A bent two-coordinate silver(I) complex with 2,2',3,3'-tetrahydro-4,4'-dithia-1,1'-binaphylidene
Wen, Ming; Munakata, Megumu; Suenaga, Yusaku; Kuroda-Sowa, Takayoshi; Maekawa, Masahiko; Yan, Sheng Gang; Acta Crystallographica Section E 57 (2001) m246–m247; doi:10.1107/S1600536801007759

data_2200345
_publ_section_title
;
 A bent two-coordinate silver(I) complex with
 2,2',3,3'-tetrahydro-4,4'-dithia-1,1'-binaphylidene
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m246
_journal_page_last               m247
_journal_paper_doi               10.1107/S1600536801007759
_journal_volume                  57
_journal_year                    2001
_chemical_formula_iupac          '[Ag (C18 H16 S2)] P F6'
_chemical_formula_moiety         'C18 H16 Ag S2 1+, P F6 1-'
_chemical_formula_sum            'C18 H16 Ag F6 P S2'
_chemical_formula_weight         549.28
_space_group_IT_number           56
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ab 2ac'
_symmetry_space_group_name_H-M   'P c c n'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.109(3)
_cell_length_b                   15.014(2)
_cell_length_c                   17.139(2)
_cell_measurement_reflns_used    28404
_cell_measurement_temperature    200
_cell_measurement_theta_max      27.6
_cell_measurement_theta_min      6.3
_cell_volume                     1829.3(8)
_computing_cell_refinement       D*TREK
_computing_data_collection       'D*TREK (Rigaku Corporation, 1991)'
_computing_data_reduction
'teXsan Ver. 1.10 (Molecular Structure Corporation, 1985 & 1999)'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'MULTAN88 (Debaerdemaeker et al., 1988)'
_diffrn_measurement_device_type  'Quantum CCD/Rigaku AFC8'
_diffrn_measurement_method       \w
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .7107
_diffrn_reflns_av_R_equivalents  .039
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            28404
_diffrn_reflns_theta_max         27.6
_diffrn_reflns_theta_min         6.3
_exptl_absorpt_coefficient_mu    1.475
_exptl_absorpt_correction_T_max  .863
_exptl_absorpt_correction_T_min  .694
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(REQAB; Jacobson, 1998)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.994
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_size_max          .20
_exptl_crystal_size_mid          .20
_exptl_crystal_size_min          .10
_refine_diff_density_max         .88
_refine_diff_density_min         -.48
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.13
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     128
_refine_ls_number_reflns         1777
_refine_ls_R_factor_gt           .034
_refine_ls_shift/su_max          <0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.0266P)^2^+4.3325P] where P = (Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         .079
_reflns_number_gt                1777
_reflns_number_total             2082
_reflns_threshold_expression     I>2.0\s(I)
_cod_data_source_file            tk6013.cif
_cod_data_source_block           AgPF6-ttp
_cod_original_cell_volume        1829.4(8)
_cod_database_code               2200345