A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te).
Suzuki, Ayumi; Arai, Takahiro; Ikenaga, Kota; Mutoh, Yuichiro; Tsuchida, Noriko; Saito, Shinichi; Ishii, Youichi; Dalton transactions (Cambridge, England : 2003) 46 (2016) 44–48; doi:10.1039/c6dt04440a

data_7041253
_publ_section_title
;
 A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand:
 systematic studies of a series of chalcogenocarbonyl complexes
 [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te).
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              44
_journal_page_last               48
_journal_paper_doi               10.1039/c6dt04440a
_journal_volume                  46
_journal_year                    2016
_chemical_formula_sum            'C27 H31 Cl N2 Ru Te'
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2016-08-24 deposited with the CCDC.
2016-11-24 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_cell_volume                     2586.3(5)
_computing_cell_refinement       'Bruker SAINT'
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'Yadokari-XG 2009 (Wakita Nemoto et al., 2009)'
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'Yadokari-XG 2009 (Wakita,Nemoto et al., 2009)'
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_diffrn_reflns_point_group_measured_fraction_full 1.000
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_exptl_absorpt_coefficient_mu    1.832
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'Re-crystallisation from solvent: dichloromethane/hexane'
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_refine_ls_restrained_S_all      1.044
_refine_ls_R_factor_all          0.0181
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0187P)^2^+2.1333P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                5567
_reflns_number_total             5910
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           CpCTe_AS-2-6_DCMHex
_cod_depositor_comments          'Adding full bibliography for 7041253.cif.'
_cod_database_code               7041253
_shelx_shelxl_version_number     2014/7
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