Synthesis of Heterometallic Bismuth/Molydenum Alkoxides and Their Behavior on Silica Surfaces
Christian Limberg; Marc Hunger; Wilhelm Habicht; Elisabeth Kaifer; Inorganic Chemistry 41 (2002) 3359–3365; doi:10.1021/ic011252j

data_4318137
_publ_contact_author
;
        PD Dr. Christian Limberg
        Anorganisch-Chemisches Institut
        Ruprecht-Karls Universitaet Heidelberg
        Im Neuenheimer Feld 270
        69120 Heidelberg
        Bundesrepublik Deutschland
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_publ_contact_author_email       limberg@urz.uni-heidelberg.de
_publ_contact_author_fax         '049 6221 54-5707'
_publ_contact_author_phone       '049 6221 54-6450'
_publ_section_title
;
 Synthesis of Heterometallic Bismuth/Molydenum Alkoxides and Their
 Behavior on Silica Surfaces
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3359
_journal_page_last               3365
_journal_paper_doi               10.1021/ic011252j
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C14.2 H20.4 Bi Cl2 Mo O6.8'
_chemical_formula_weight         675.73
_chemical_name_systematic
; 

  ? 

;
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_cell_length_a                   12.980(3)
_cell_length_b                   7.8700(16)
_cell_length_c                   21.787(4)
_cell_measurement_temperature    200
_cell_volume                     2195.2(8)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200
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_diffrn_reflns_av_R_equivalents  0.0433
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_diffrn_reflns_limit_l_min       -28
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_exptl_absorpt_coefficient_mu    8.847
_exptl_absorpt_correction_type   experimentell
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_exptl_crystal_density_method    'not measured'
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_refine_ls_number_restraints     0
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0734P)^2^+22.0100P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                2463
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_cod_data_source_file            ic011252j.cif
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_cod_depositor_comments
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The following automatic conversions were performed:

'_symmetry_cell_setting' tag value 'monoklin' was replaced with
'monoclinic' value as specified in the replacement file
'/home/robertas/cod-tools/perl-scripts/inputs/replacement_values.lst'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
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_cod_original_formula_sum        'C14.20 H20.40 Bi Cl2 Mo O6.80'
_cod_database_code               4318137