Synthesis and Structures of Tungsten (1-Pyridinio)imido Complexes and Their Facile N-N Bond Cleavage1
Hiroshige Ishino; Shin'ichi Tokunaga; Hidetake Seino; Youichi Ishii; Masanobu Hidai; Inorganic Chemistry 38 (1999) 2489–2496; doi:10.1021/ic981116n

data_4322008
_publ_contact_author
;
    Masanobu Hidai
 Department of Chemistry and Biotechnology, Graduate School of Engineering,
The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
;
_publ_contact_author_fax         ' +81-3-5800-6945 '
_publ_contact_author_phone       ' +81-3-5800-6945 ext 7261 '
_publ_section_title
;
 Synthesis and Structures of Tungsten (1-Pyridinio)imido Complexes and
 Their Facile N-N Bond Cleavage1
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2489
_journal_page_last               2496
_journal_paper_doi               10.1021/ic981116n
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C17 H23 Cl2 N O P2 W'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_audit_creation_date             'Mon Aug 17 14:38:10 1998'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 110.755(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4.00
_cell_length_a                   13.0529(8)
_cell_length_b                   9.985(2)
_cell_length_c                   18.070(1)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    20.0
_cell_measurement_theta_max      39.81
_cell_measurement_theta_min      38.66
_cell_volume                     2202.3(5)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
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_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
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_diffrn_measurement_device       AFC7R
_diffrn_measurement_method       'omega/2-theta scans'
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_refine_ls_shift/esd_max         0.0040
_refine_ls_structure_factor_coef F
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_cod_data_source_file            ic981116n_5.cif
_cod_data_source_block           '[WCl2(NH)(CO)(PMe2Ph)2]'
_cod_original_cell_volume        2202.2(4)
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_cod_database_code               4322008