Catalytic hydrogenation of carbonyl and nitro compounds using an [N,O]-chelate half-sandwich ruthenium catalyst.
Yao, Zi-Jian; Zhu, Jing-Wei; Lin, Nan; Qiao, Xin-Chao; Deng, Wei; Dalton transactions (Cambridge, England : 2003) 48 (2019) 7158–7166; doi:10.1039/c8dt02677g

data_7047115
_publ_section_title
;
 Catalytic hydrogenation of carbonyl and nitro compounds using an
 [N,O]-chelate half-sandwich ruthenium catalyst.
;
_journal_issue                   21
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7158
_journal_page_last               7166
_journal_paper_doi               10.1039/c8dt02677g
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C22 H28 Cl N O Ru'
_chemical_formula_weight         458.97
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-06-30 deposited with the CCDC.
2018-07-24 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           GaK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.997
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_diffrn_reflns_point_group_measured_fraction_full 0.997
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0352P)^2^+1.4826P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0870
_refine_ls_wR_factor_ref         0.0922
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_reflns_number_gt                3926
_reflns_number_total             4501
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           ga_80629a_a
_cod_depositor_comments
'Adding full bibliography for 7047115--7047116.cif.'
_cod_database_code               7047115
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