Direct coordination of a germanium(ii) dicationic center to transition metals.
Raut, Ravindra K.; Majumdar, Moumita; Chemical communications (Cambridge, England) 53 (2017) 1467–1469; doi:10.1039/c6cc09525a

data_7119301
_publ_section_title
;
 Direct coordination of a germanium(ii) dicationic center to transition
 metals.
;
_journal_issue                   9
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              1467
_journal_page_last               1469
_journal_paper_doi               10.1039/c6cc09525a
_journal_volume                  53
_journal_year                    2017
_chemical_formula_moiety         'C39 H39 Ag F15 Ge2 N9 O15 S5'
_chemical_formula_sum            'C39 H39 Ag F15 Ge2 N9 O15 S5'
_chemical_formula_weight         1572.14
_chemical_name_systematic        Compound2
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-11-28 deposited with the CCDC.
2017-01-03 downloaded from the CCDC.
;
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_cell_angle_gamma                106.078(6)
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_cell_measurement_theta_min      3.36
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      100(2)
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_diffrn_measurement_device_type  'D8 Venture APEX-II'
_diffrn_measurement_method       'CMOS-Photon 100'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0506
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_diffrn_reflns_number            24387
_diffrn_reflns_point_group_measured_fraction_full 0.976
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_exptl_crystal_colour            'Pale Yellow'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0369P)^2^+28.8312P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7119297--7119301.cif.'
_cod_original_cell_volume        2819.6(8)
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