An air-stable, Zn<sup>2+</sup>-based catalyst for hydrosilylation of alkenes and alkynes.
Groutchik, Kristina; Jaiswal, Kuldeep; Dobrovetsky, Roman; Organic & biomolecular chemistry 19 (2021) 5544–5550; doi:10.1039/d1ob00782c

data_7158096
_publ_section_title
;
 An air-stable, Zn<sup>2+</sup>-based catalyst for hydrosilylation of
 alkenes and alkynes.
;
_journal_issue                   25
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              5544
_journal_page_last               5550
_journal_paper_doi               10.1039/d1ob00782c
_journal_volume                  19
_journal_year                    2021
_chemical_formula_moiety         'B12 I12, C12 H18 N6 Zn'
_chemical_formula_sum            'C12 H18 B12 I12 N6 Zn'
_chemical_formula_weight         1964.21
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_space_group_name_Hall           '-R 3 2"'
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_audit_update_record
;
2021-04-18 deposited with the CCDC.	2021-05-25 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'ApexDuo, Bruker-AXS'
_diffrn_measurement_method       '0.5 deg. \f scans'
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_refine_ls_R_factor_gt           0.0212
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0149P)^2^+5.5429P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                621
_reflns_number_total             703
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           rom53
_cod_depositor_comments
'Adding full bibliography for 7158095--7158098.cif.'
_cod_original_cell_volume        3357.1(8)
_cod_database_code               7158096
_shelx_shelxl_version_number     2018/1
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_shelx_res_checksum              2131