Directed <i>cis</i>-hydrosilylation of borylalkynes to borylsilylalkenes.
Stefanowska, Kinga; Sokolnicki, Tomasz; Walkowiak, Jędrzej; Czapik, Agnieszka; Franczyk, Adrian; Chemical communications (Cambridge, England) 58 (2022) 12046–12049; doi:10.1039/d2cc04318a

data_7130865
_publ_section_title
;
 Directed <i>cis</i>-hydrosilylation of borylalkynes to borylsilylalkenes.
;
_journal_issue                   86
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              12046
_journal_page_last               12049
_journal_paper_doi               10.1039/d2cc04318a
_journal_volume                  58
_journal_year                    2022
_chemical_formula_moiety         'C23 H38 B2 O4 Si'
_chemical_formula_sum            'C23 H38 B2 O4 Si'
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Olex2 1.3-ac4
(compiled 2019.04.23 svn.r3594 for Rigaku Oxford Diffraction, GUI svn.r5739)
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_audit_update_record
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2022-07-29 deposited with the CCDC.	2022-09-23 downloaded from the CCDC.
;
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'CrysAlisPro convention (1999,Acta A55,543-557)'
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_diffrn_source                   'micro-focus sealed X-ray tube'
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;
CrysAlisPro 1.171.41.112a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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'w=1/[\s^2^(Fo^2^)+(0.0949P)^2^+2.4057P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7130861--7130865.cif.'
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;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.309
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