[μ-<i>N</i>,<i>N</i>'-Bis(diphenylphosphinomethyl)benzene-1,4-diamine-κ^2^<i>P</i>:<i>P</i>']bis[(2,2'-bipyridine-κ^2^<i>N</i>,<i>N</i>')silver(I)] bis(perchlorate) acetone disolvate
Gui, Liu-Cheng; Ni, Qing-Ling; Jiang, Xuan-Feng; Zeng, Jian-Qiang; Wang, Xiu-Jian; Acta Crystallographica Section E 65 (2009) m589–m590; doi:10.1107/S1600536809014871

data_2221582
_publ_section_title
;[\m-<i>N</i>,<i>N</i>'-Bis(diphenylphosphinomethyl)benzene-1,4-diamine-\k^2^<i>P</i>:<i>P</i>']bis[(2,2'-bipyridine-\k^2^<i>N</i>,<i>N</i>')silver(I)]
 bis(perchlorate) acetone disolvate
;
_journal_coeditor_code           AT2766
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m589
_journal_page_last               m590
_journal_paper_doi               10.1107/S1600536809014871
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac
'[Ag2 (C10 H8 N2)2 (C32 H30 N2 P2)] (Cl O4)2, 2C3 H6 O'
_chemical_formula_moiety         'C52 H46 Ag2 N6 P2 2+, 2(Cl O4 -), 2(C3 H6 O)'
_chemical_formula_sum            'C58 H58 Ag2 Cl2 N6 O10 P2'
_chemical_formula_weight         1347.68
_chemical_name_systematic
;[\m-<i>N</i>,<i>N</i>'-Bis(diphenylphosphinomethyl)benzene-1,4-diamine-
\k^2^<i>P</i>:<i>P</i>']bis[(2,2'-bipyridine-\k^2^<i>N</i>,<i>N</i>')silver(I)]
bis(perchlorate)
 acetone disolvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.432(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   10.6372(13)
_cell_length_b                   15.8958(19)
_cell_length_c                   16.6684(19)
_cell_measurement_reflns_used    3856
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.87
_cell_measurement_theta_min      2.30
_cell_volume                     2817.5(6)
_computing_cell_refinement       'SAINT (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0442
_diffrn_reflns_av_sigmaI/netI    0.0697
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            14114
_diffrn_reflns_theta_full        27.07
_diffrn_reflns_theta_max         27.07
_diffrn_reflns_theta_min         1.77
_exptl_absorpt_coefficient_mu    0.912
_exptl_absorpt_correction_T_max  0.833
_exptl_absorpt_correction_T_min  0.657
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1998)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.589
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1372
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.018
_refine_diff_density_min         -0.680
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         6120
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0888
_refine_ls_R_factor_gt           0.0464
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0655P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1057
_refine_ls_wR_factor_ref         0.1322
_reflns_number_gt                3944
_reflns_number_total             6120
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            at2766.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2221582
_cod_database_fobs_code          2221582