A structural and spectrophotometric study on the complexation of Am(iii) with TMOGA in comparison with the extracted complex of DMDOOGA.
Tian, Guoxin; Shuh, David K.; Beavers, Christine M.; Teat, Simon J.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 18469–18474; doi:10.1039/c4dt02882a

data_7036639
_publ_section_title
;
 A structural and spectrophotometric study on the complexation of Am(iii)
 with TMOGA in comparison with the extracted complex of DMDOOGA.
;
_journal_issue                   42
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18469
_journal_page_last               18474
_journal_paper_doi               10.1039/c4dt02882a
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C24 H48 Am Cl3 N6 O21'
_chemical_formula_weight         1106.03
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2014-09-06 deposited with the CCDC.
2015-09-24 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_measurement_theta_min      2.60
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_diffrn_ambient_temperature      200(2)
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_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX II CCD diffractometer'
_diffrn_measurement_method       '\w/\q scans'
_diffrn_radiation_type           synchrotron
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_diffrn_reflns_number            17029
_diffrn_reflns_point_group_measured_fraction_full 0.997
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_exptl_crystal_colour            'v. pale pink\yellow'
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_exptl_crystal_description       Block
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0665P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                3700
_reflns_number_total             4462
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c4dt02882a1.cif
_cod_data_source_block           amtmoga_a
_cod_depositor_comments          'Adding full bibliography for 7036639.cif.'
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_shelx_estimated_absorpt_t_min   0.902
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_shelx_res_checksum              45446