Synthesis and structures of new oligomethylene-bridged double ladders. How far can the layers be separated?
Jens Beckmann; Dainis Dakternieks; Andrew Duthie; Fong Sheen Kuan; Klaus Jurkschat; Markus Schürman; Edward R. T. Tiekink; New J.Chem.(Nouv.J.Chim.) 28 (2004) 1268–1276; doi:10.1039/b316009b

data_7050284
_publ_section_title
;
Synthesis and structures of new oligomethylene-bridged double 
ladders. How far can the layers be separated?
;
_journal_name_full               'New J.Chem.(Nouv.J.Chim.)'
_journal_page_first              1268
_journal_page_last               1276
_journal_paper_doi               10.1039/b316009b
_journal_volume                  28
_journal_year                    2004
_chemical_formula_sum            'C60 H144 Cl8 O4 Si8 Sn8'
_chemical_formula_weight         2387.59
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90
_cell_angle_beta                 101.3916(7)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   38.6254(7)
_cell_length_b                   12.3153(2)
_cell_length_c                   21.5662(5)
_cell_measurement_reflns_used    41657
_cell_measurement_temperature    173
_cell_measurement_theta_max      25.4
_cell_measurement_theta_min      3.3
_cell_volume                     10056.6(3)
_diffrn_ambient_temperature      173
_diffrn_detector_area_resol_mean ?
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.073
_diffrn_reflns_av_sigmaI/netI    0.1425
_diffrn_reflns_limit_h_max       46
_diffrn_reflns_limit_h_min       -46
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            41657
_diffrn_reflns_theta_max         25.4
_diffrn_reflns_theta_min         3.3
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.295
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.577
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             4736
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.01
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.88
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     397
_refine_ls_number_reflns         9194
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.88
_refine_ls_R_factor_all          0.128
_refine_ls_R_factor_gt           0.046
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.051
_refine_ls_wR_factor_ref         0.063
_reflns_number_gt                4994
_reflns_number_total             9194
_reflns_threshold_expression     I>2sigma(I)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not determined' was changed to
'?' - the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7050284