<i>catena</i>-Poly[[lead(II)-μ-<i>N</i>'-[1-(pyridin-2-yl-κ<i>N</i>)ethylidene]isonicotinohydrazidato-κ^3^<i>N</i>',<i>O</i>:<i>N</i>^1^] perchlorate]
Shahverdizadeh, Gholam Hossein; Tiekink, Edward R. T.; Mirtamizdoust, Babak; Acta Crystallographica Section E 67 (2011) m1727–m1728; doi:10.1107/S1600536811046691

data_2232698
_publ_section_title
;
 <i>catena</i>-Poly[[lead(II)-\m-<i>N</i>'-[1-(pyridin-2-yl-\k<i>N</i>)ethylidene]isonicotinohydrazidato-\k^3^<i>N</i>',<i>O</i>:<i>N</i>^1^]
 perchlorate]
;
_journal_coeditor_code           HB6465
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1727
_journal_page_last               m1728
_journal_paper_doi               10.1107/S1600536811046691
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Pb (C13 H11 N4 O)] Cl O4'
_chemical_formula_moiety         'C13 H11 N4 O Pb +, Cl O4 -'
_chemical_formula_sum            'C13 H11 Cl N4 O5 Pb'
_chemical_formula_weight         545.90
_chemical_name_systematic
;
<i>catena</i>-Poly[[lead(II)-\m-<i>N</i>'-[1-(pyridin-2-
yl-\k<i>N</i>)ethylidene]isonicotinohydrazidato-
\k^3^<i>N</i>',<i>O</i>:<i>N</i>^1^] perchlorate]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.1740(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.0620(6)
_cell_length_b                   14.4431(8)
_cell_length_c                   11.1456(7)
_cell_measurement_reflns_used    4195
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.97
_cell_measurement_theta_min      2.33
_cell_volume                     1599.03(16)
_computing_cell_refinement       'SAINT (Bruker, 2007)'
_computing_data_collection       'SMART (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics
;
ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)
;
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0263
_diffrn_reflns_av_sigmaI/netI    0.0285
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            8396
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.33
_exptl_absorpt_coefficient_mu    10.750
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6906
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.268
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1024
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.554
_refine_diff_density_min         -0.446
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     218
_refine_ls_number_reflns         2811
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.066
_refine_ls_R_factor_all          0.0315
_refine_ls_R_factor_gt           0.0222
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0241P)^2^+1.6546P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0509
_refine_ls_wR_factor_ref         0.0555
_reflns_number_gt                2392
_reflns_number_total             2811
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb6465.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2232698
_cod_database_fobs_code          2232698