Phenoxo-bridged dinuclear mixed valence cobalt(III/II) complexes with reduced Schiff base ligands: synthesis, characterization, band gap measurements and fabrication of Schottky barrier diodes.
Banerjee, Abhisek; Das, Dhananjoy; Ray, Partha Pratim; Banerjee, Snehasis; Chattopadhyay, Shouvik; Dalton transactions (Cambridge, England : 2003) 50 (2021) 1721–1732; doi:10.1039/d0dt03707a

data_7706434
_publ_section_title
;
 Phenoxo-bridged dinuclear mixed valence cobalt(III/II) complexes with
 reduced Schiff base ligands: synthesis, characterization, band gap
 measurements and fabrication of Schottky barrier diodes.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1721
_journal_page_last               1732
_journal_paper_doi               10.1039/d0dt03707a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C28 H32 Co2 N9 O8'
_chemical_formula_sum            'C28 H32 Co2 N9 O8'
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_audit_update_record
;
2020-12-02 deposited with the CCDC.	2020-12-16 downloaded from the CCDC.
;
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_diffrn_measurement_method       '321 frames, counting time 10 s.'
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.177
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1073P)^2^+2.9891P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1672
_refine_ls_wR_factor_ref         0.1798
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5231
_reflns_number_total             5539
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_cod_data_source_file            d0dt03707a2.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7706434--7706435.cif.
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7706434
_shelx_shelxl_version_number     2018/3
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_shelx_res_checksum              12307