Synthesis, structures, and electronic properties of triple- and double-decker ruthenocenes incorporated by a group 14 metallole dianion ligand.
Kuwabara, Takuya; Guo, Jing-Dong; Nagase, Shigeru; Sasamori, Takahiro; Tokitoh, Norihiro; Saito, Masaichi; Journal of the American Chemical Society 136 (2014) 13059–13064; doi:10.1021/ja507330p

data_4122575
_publ_section_title
;
 Synthesis, structures, and electronic properties of triple- and
 double-decker ruthenocenes incorporated by a group 14 metallole dianion
 ligand.
;
_journal_issue                   37
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13059
_journal_page_last               13064
_journal_paper_doi               10.1021/ja507330p
_journal_volume                  136
_journal_year                    2014
_chemical_formula_moiety         'C38 H55 Ru Si2 Sn, C16 H32 Li O4'
_chemical_formula_sum            'C54 H87 Li O4 Ru Si2 Sn'
_chemical_formula_weight         1083.14
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_cell_volume                     2725.5(6)
_computing_cell_refinement       'Bruker SMART'
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_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_Laue_measured_fraction_full 0.991
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_diffrn_reflns_limit_k_min       -18
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_diffrn_reflns_limit_l_min       -17
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_diffrn_reflns_theta_full        25.242
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_exptl_absorpt_coefficient_mu    0.816
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         11187
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.015
_refine_ls_R_factor_all          0.0702
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0437P)^2^+1.2385P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 4122573--4122575.cif.'
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