Target Specific Tactics in Olefin Metathesis: Synthetic Approach to cis-syn-cis-Triquinanes and -Propellanes.
Kotha, Sambasivarao; Aswar, Vikas R.; Organic letters 18 (2016) 1808–1811; doi:10.1021/acs.orglett.6b00537

data_1555516
_publ_section_title
;
 Target Specific Tactics in Olefin Metathesis: Synthetic Approach to
 cis-syn-cis-Triquinanes and -Propellanes.
;
_journal_issue                   8
_journal_name_full               'Organic letters'
_journal_page_first              1808
_journal_page_last               1811
_journal_paper_doi               10.1021/acs.orglett.6b00537
_journal_volume                  18
_journal_year                    2016
_chemical_formula_moiety         'C19 H17 N O2'
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
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_cell_angle_beta                 100.066(12)
_cell_angle_gamma                104.431(12)
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_cell_length_b                   8.581(7)
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_cell_measurement_temperature    150
_cell_measurement_theta_max      29.20
_cell_measurement_theta_min      3.00
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_computing_cell_refinement       'CrystalClear-SM Expert 2.1 b28'
_computing_data_collection       'CrystalClear-SM Expert 2.1 b28 (Rigaku, 2013)'
_computing_data_reduction        'CrystalClear-SM Expert 2.1 b28'
_computing_molecular_graphics    'CrystalStructure 4.0'
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_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      150
_diffrn_detector_area_resol_mean 7.111
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_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       \w
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_exptl_absorpt_process_details   'NUMABS (Rigaku, 1999)'
_exptl_crystal_colour            colorless
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0682P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1904
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