Manganese complexes with chelating and bridging di-triazolylidene ligands: synthesis and reactivity.
Friães, Sofia; Realista, Sara; Gomes, Clara S. B.; Martinho, Paulo N.; Veiros, Luis F.; Albrecht, Martin; Royo, Beatriz; Dalton transactions (Cambridge, England : 2003) 50 (2021) 5911–5920; doi:10.1039/d1dt00444a

data_7707071
_publ_section_title
;
 Manganese complexes with chelating and bridging di-triazolylidene
 ligands: synthesis and reactivity.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5911
_journal_page_last               5920
_journal_paper_doi               10.1039/d1dt00444a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C48 H46 Mn N6 O2 P2, C2 H3 N, Br, H2 O'
_chemical_formula_sum            'C50 H51 Br Mn N7 O3 P2'
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   mixed
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;
2021-02-02 deposited with the CCDC.	2021-04-06 downloaded from the CCDC.
;
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;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            yellow
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_refine_ls_R_factor_all          0.1929
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3019
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'Adding full bibliography for 7707067--7707071.cif.'
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_shelx_res_checksum              66293
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