Ligand exchange of tris(2,4-di-<i>tert</i>-butylphenyl) phosphite: a practical and efficient route to organo gold(I) complexes.
Vesseur, David; Li, Shuo; Mallet-Ladeira, Sonia; Bourissou, Didier; Chemical communications (Cambridge, England) 61 (2025) 18717–18720; doi:10.1039/d5cc05744b

data_7135201
_publ_section_title
;
 Ligand exchange of tris(2,4-di-<i>tert</i>-butylphenyl) phosphite: a
 practical and efficient route to organo gold(I) complexes.
;
_journal_issue                   94
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              18717
_journal_page_last               18720
_journal_paper_doi               10.1039/d5cc05744b
_journal_volume                  61
_journal_year                    2025
_chemical_formula_moiety         'C18 H29 Au F3 P S'
_chemical_formula_sum            'C18 H29 Au F3 P S'
_chemical_formula_weight         562.41
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_method           SHELXL-2019/2
_audit_update_record
;
2025-08-26 deposited with the CCDC.	2025-10-23 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 105.659(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.2996(14)
_cell_length_b                   25.654(5)
_cell_length_c                   10.1969(18)
_cell_measurement_reflns_used    9964
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      28.33
_cell_measurement_theta_min      2.22
_cell_volume                     2090.5(7)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
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_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'SHELXT (Sheldrick 2015)'
_diffrn_ambient_temperature      193(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker kappa APEX-II CCD Quazar'
_diffrn_measurement_method       'Phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0329
_diffrn_reflns_av_unetI/netI     0.0138
_diffrn_reflns_Laue_measured_fraction_full 0.999
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_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
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_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_l_max       13
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_diffrn_reflns_number            65560
_diffrn_reflns_point_group_measured_fraction_full 0.999
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_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.787
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+3.6731P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0429
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_reflns_Friedel_coverage         0.000
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5cc05744b2.cif
_cod_data_source_block           DV906_a
_cod_original_cell_volume        2090.5(6)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7135201
_shelx_shelxl_version_number     2019/2
_shelx_estimated_absorpt_t_min   0.186
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_shelx_res_checksum              20671