A novel route to the fluorinated diimines: carbon monoxide-promoted reductive homocoupling of fluorinated imidoyl iodides in the presence of a palladium catalyst
Amii, Hideki; Kohda, Mitsuhiro; Seo, Motoharu; Uneyama, Kenji; Chemical Communications (Cambridge, United Kingdom)  (2003) 1752–1753; doi:10.1039/b303040g

data_7103739
_publ_section_title
;
 A novel route to the fluorinated diimines: carbon monoxide-promoted reductive
 homocoupling of fluorinated imidoyl iodides in the presence of a palladium
 catalyst
;
_journal_coden_ASTM              CHCOFS
_journal_issue                   14
_journal_name_full
'Chemical Communications (Cambridge, United Kingdom)'
_journal_page_first              1752
_journal_page_last               1753
_journal_paper_doi               10.1039/b303040g
_journal_year                    2003
_chemical_formula_moiety         'C16 H8 Cl2 F6 N2 '
_chemical_formula_sum            'C16 H8 Cl2 F6 N2'
_chemical_formula_weight         413.15
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      13
_symmetry_space_group_name_Hall  '-P 2yac'
_symmetry_space_group_name_H-M   'P 1 2/n 1'
_audit_creation_date             'Fri May  2 22:02:46 2003'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90
_cell_angle_beta                 100.907(9)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   7.2370(8)
_cell_length_b                   9.150(2)
_cell_length_c                   13.068(2)
_cell_measurement_temperature    288.2
_cell_volume                     849.7(2)
_computing_cell_refinement       PROCESS
_computing_data_collection       PROCESS
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR97
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.8943
_diffrn_measured_fraction_theta_max 0.8943
_diffrn_measurement_device_type  'Rigaku RAXIS-IV Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            1430
_diffrn_reflns_theta_full        25.18
_diffrn_reflns_theta_max         25.18
_exptl_absorpt_coefficient_mu    0.445
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.615
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       unknown
_exptl_crystal_size_max          0.000
_exptl_crystal_size_mid          0.000
_exptl_crystal_size_min          0.000
_refine_diff_density_max         0.26
_refine_diff_density_min         -0.25
_refine_ls_extinction_coef       0.23(5)
_refine_ls_extinction_method     'Zachariasen(1967) type 2 Gaussian isotropic'
_refine_ls_goodness_of_fit_ref   1.387
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     119
_refine_ls_number_reflns         1115
_refine_ls_R_factor_gt           0.0702
_refine_ls_shift/su_max          0.0046
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.01000|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1371
_reflns_number_gt                1115
_reflns_number_total             1371
_reflns_threshold_expression     F^2^>5.0\s(F^2^)
_cod_data_source_file            b303040g.txt
_cod_data_source_block           p-Cl
_cod_original_formula_sum        'C16 H8 Cl2 F6 N2 '
_cod_database_code               7103739