Supramolecular interactions induced hinge-like motion of a metal-organic framework accompanied by anisotropic thermal expansion.
Zhang, Lei; Kuang, Xiaofei; Wu, Xiaoyuan; Yang, Wenbin; Lu, Canzhong; Dalton transactions (Cambridge, England : 2003) 43 (2014) 7146–7152; doi:10.1039/c3dt53580k

data_7029788
_publ_section_title
;
 Supramolecular interactions induced hinge-like motion of a metal-organic
 framework accompanied by anisotropic thermal expansion.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7146
_journal_page_last               7152
_journal_paper_doi               10.1039/c3dt53580k
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C72 H51 Ag4 Mo8 N24 O27.5'
_chemical_formula_weight         2891.37
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
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_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.416(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.0765(5)
_cell_length_b                   16.3158(5)
_cell_length_c                   25.6800(8)
_cell_measurement_reflns_used    19879
_cell_measurement_temperature    100.01(15)
_cell_measurement_theta_max      29.4130
_cell_measurement_theta_min      3.3040
_cell_volume                     8354.6(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100.01(15)
_diffrn_detector_area_resol_mean 10.3503
_diffrn_measured_fraction_theta_full 0.970
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0377
_diffrn_reflns_av_sigmaI/netI    0.0350
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            19300
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.07
_exptl_absorpt_coefficient_mu    2.167
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.80965
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            pale-yellow
_exptl_crystal_density_diffrn    2.299
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block-like
_exptl_crystal_F_000             5580
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.709
_refine_diff_density_min         -1.843
_refine_diff_density_rms         0.128
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.043
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     616
_refine_ls_number_reflns         7157
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.043
_refine_ls_R_factor_all          0.0340
_refine_ls_R_factor_gt           0.0300
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0369P)^2^+34.6944P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0732
_refine_ls_wR_factor_ref         0.0758
_reflns_number_gt                6525
_reflns_number_total             7157
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3dt53580k2.cif
_cod_data_source_block           A_100K
_cod_depositor_comments
;Adding full bibliography for
 ./tmp-cod-update-bibliographies-12899/cifs/7029788.cif.
;
_cod_original_cell_volume        8354.6(4)
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C72 H51 Ag4 Mo8 N24 O27.50'
_cod_database_code               7029788