μ-(Furan-2-carbaldehyde azine)-1κ^2^<i>O</i>,<i>N</i>:2κ^2^<i>N</i>',<i>O</i>'-bis[(furan-2-carbaldehyde azine-κ^2^<i>N</i>,<i>O</i>)silver(I)] bis(hexafluorophosphate): an unusual complex containing two metal atoms and three ligands
Wang, Le; Dong, Yu-Bin; Ma, Jian-Ping; Huang, Ru-Qi; Acta Crystallographica Section E 61 (2005) m2369–m2370; doi:10.1107/S1600536805033611

data_2207245
_publ_section_title
;\m-(Furan-2-carbaldehyde
 azine)-1\k^2^<i>O</i>,<i>N</i>:2\k^2^<i>N</i>',<i>O</i>'-bis[(furan-2-carbaldehyde
 azine-\k^2^<i>N</i>,<i>O</i>)silver(I)] bis(hexafluorophosphate): an unusual
 complex containing two metal atoms and three ligands
;
_journal_coeditor_code           HB6291
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2369
_journal_page_last               m2370
_journal_paper_doi               10.1107/S1600536805033611
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Ag2 (C10 H8 N2 O2)3] (P1 F6)2'
_chemical_formula_moiety         'C30 H24 Ag2 N6 O6 2+, 2F6 P -'
_chemical_formula_sum            'C30 H24 Ag2 F12 N6 O6 P2'
_chemical_formula_weight         1070.23
_chemical_name_systematic
;\m-(furan-2-carbaldehyde
 azine)-1\k^2^O,N:2\k^2^N',O'-bis[(furan-2-carbaldehyde
azine-\k^2^N,O)silver(I)]
 bis(hexafluorophosphate)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.829(3)
_cell_angle_beta                 98.144(3)
_cell_angle_gamma                117.247(2)
_cell_formula_units_Z            1
_cell_length_a                   9.414(2)
_cell_length_b                   9.943(2)
_cell_length_c                   11.332(3)
_cell_measurement_reflns_used    2033
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.70
_cell_measurement_theta_min      2.34
_cell_volume                     920.0(4)
_computing_cell_refinement       'SAINT (Bruker, 1997)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL  (Bruker, 2001)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Bruker SMART CCD'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0233
_diffrn_reflns_av_sigmaI/netI    0.0481
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            4924
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.84
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    1.264
_exptl_absorpt_correction_T_max  0.940
_exptl_absorpt_correction_T_min  0.659
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 1997)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.932
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       slab
_exptl_crystal_F_000             526
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.685
_refine_diff_density_min         -0.493
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     262
_refine_ls_number_reflns         3346
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0514
_refine_ls_R_factor_gt           0.0441
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.0581P)^2^+0.2485P] where P = (Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1066
_refine_ls_wR_factor_ref         0.1112
_reflns_number_gt                2888
_reflns_number_total             3346
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb6291.cif
_cod_data_source_block           I
_cod_original_formula_sum        'C30 H24 Ag2 F12 N6 O6 P2 '
_cod_database_code               2207245
_cod_database_fobs_code          2207245