Strikingly diverse reactivity of structurally identical silylene and stannylene
Parvin, Nasrina; Dasgupta, Rajarshi; Pal, Shiv; Sen, Sakya Singha; Khan, Shabana; Dalton Transactions 46 (2017) 6528–6532; doi:10.1039/C7DT01055A

data_7042744
_publ_section_title
;
 Strikingly diverse reactivity of structurally identical silylene and stannylene
;
_journal_coden_ASTM              DTARAF
_journal_issue                   20
_journal_name_full               'Dalton Transactions'
_journal_page_first              6528
_journal_page_last               6532
_journal_paper_doi               10.1039/C7DT01055A
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C15 H23 Br N2 Sn'
_chemical_formula_sum            'C15 H23 Br N2 Sn'
_chemical_formula_weight         429.95
_chemical_properties_physical
', Air-sensitive,Moisture-sensitive,Oxygen-sensitive'
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
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_audit_update_record
;
2017-03-03 deposited with the CCDC.
2017-04-20 downloaded from the CCDC.
;
_cell_angle_alpha                86.414(9)
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_cell_angle_gamma                85.949(8)
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_cell_measurement_temperature    150(2)
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_cell_measurement_theta_min      2.41
_cell_volume                     882.8(5)
_computing_cell_refinement       'Bruker SAINT'
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_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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'Sheldrick, G. M. (2012) SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0681P)^2^+1.7767P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             3205
_reflns_threshold_expression     'I > 2\s(I)'
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