Intracellular distribution of fluorescent copper and zinc bis(thiosemicarbazonato) complexes measured with fluorescence lifetime spectroscopy.
Hickey, James L.; James, Janine L.; Henderson, Clare A.; Price, Katherine A.; Mot, Alexandra I.; Buncic, Gojko; Crouch, Peter J.; White, Jonathan M.; White, Anthony R.; Smith, Trevor A.; Donnelly, Paul S.; Inorganic chemistry 54 (2015) 9556–9567; doi:10.1021/acs.inorgchem.5b01599

data_4346511
_publ_section_title
;
 Intracellular distribution of fluorescent copper and zinc
 bis(thiosemicarbazonato) complexes measured with fluorescence lifetime
 spectroscopy.
;
_journal_issue                   19
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9556
_journal_page_last               9567
_journal_paper_doi               10.1021/acs.inorgchem.5b01599
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'C30 H43 B F2 N8 O2 S4'
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_atom_sites_solution_hydrogens   mixed
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_cell_angle_alpha                93.022(10)
_cell_angle_beta                 105.926(10)
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_cell_formula_units_Z            2
_cell_length_a                   9.6568(10)
_cell_length_b                   10.9113(13)
_cell_length_c                   17.452(2)
_cell_measurement_reflns_used    3114
_cell_measurement_temperature    130.0(2)
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_cell_volume                     1764.9(4)
_computing_cell_refinement
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CrysAlisPro, Oxford Diffraction Ltd.,
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_computing_data_collection
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CrysAlisPro, Oxford Diffraction Ltd.,
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      130.0(2)
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_diffrn_radiation_source         'Enhance (Cu) X-ray Source'
_diffrn_radiation_type           'Cu K\a'
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_diffrn_reflns_point_group_measured_fraction_full 0.985
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_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         73.323
_diffrn_reflns_theta_min         4.059
_exptl_absorpt_coefficient_mu    2.905
_exptl_absorpt_correction_T_max  1.00000
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CrysAlisPro, Oxford Diffraction Ltd.,
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0426P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0966
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_reflns_number_gt                3904
_reflns_number_total             6774
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ic5b01599_si_001.cif
_cod_data_source_block           shelx
_cod_database_code               4346511
_shelx_shelxl_version_number     2014/7
_chemical_oxdiff_usercomment     'B2 p151 J Hickey'
_shelx_res_checksum              2145
_shelx_hkl_checksum              35941