Structural Diversity in Copper−Sulfur Chemistry: Synthesis of Novel Cu/S Clusters through Metathesis Reactions
York, John T.; Bar-Nahum, Itsik; Tolman, William B.; Inorganic Chemistry 46 (2007) 8105–8107; doi:10.1021/ic700760p

data_4333343
_publ_section_title
;
 Structural Diversity in Copper&#x2212;Sulfur Chemistry:&#x00A0; Synthesis
 of Novel Cu/S Clusters through Metathesis Reactions
;
_journal_issue                   20
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8105
_journal_page_last               8107
_journal_paper_doi               10.1021/ic700760p
_journal_volume                  46
_journal_year                    2007
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C10 H22 Cl Cu N2'
_chemical_formula_sum            'C10 H22 Cl Cu N2'
_chemical_formula_weight         269.29
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_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           19
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_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      24.98
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_diffrn_measurement_device_type  'Bruker SMART Platform CCD'
_diffrn_measurement_method       'area detector, omega scans'
_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_l_min       -16
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_diffrn_reflns_theta_full        25.06
_diffrn_reflns_theta_max         25.06
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_exptl_absorpt_correction_T_max  0.8309
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, R. Blessing, 1995'
_exptl_crystal_colour            Colorless
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_exptl_crystal_density_meas      ?
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_exptl_crystal_description       Plate
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_refine_ls_abs_structure_details
'Flack H D (1983), 927 Friedel pairs, Acta Cryst. A39, 876-881'
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_refine_ls_R_factor_gt           0.0323
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0075P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                1603
_reflns_number_total             2231
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic700760psup1.cif
_cod_data_source_block           05336m
_cod_depositor_comments
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The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P212121
_cod_database_code               4333343