Probing the non-innocent nature of an amino-functionalised β-diketiminate ligand in silylene/iminosilane systems.
Do, Dinh Cao Huan; Vasko, Petra; Fuentes, M Ángeles; Hicks, Jamie; Aldridge, Simon; Dalton transactions (Cambridge, England : 2003) 49 (2020) 8701–8709; doi:10.1039/d0dt01447h

data_7704659
_publ_section_title
;
 Probing the non-innocent nature of an amino-functionalised
 \b-diketiminate ligand in silylene/iminosilane systems.
;
_journal_issue                   25
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8701
_journal_page_last               8709
_journal_paper_doi               10.1039/d0dt01447h
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C37 H65 N4 P Si3, C6 H6'
_chemical_formula_sum            'C43 H71 N4 P Si3'
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;
2020-04-09 deposited with the CCDC.	2020-06-10 downloaded from the CCDC.
;
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_diffrn_measurement_method       '\w scans'
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
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_exptl_crystal_description       plare
_exptl_crystal_F_000             1656
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.1166
_refine_ls_R_factor_gt           0.0601
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0402P)^2^+0.8739P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                6481
_reflns_number_total             10425
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt01447h2.cif
_cod_data_source_block           (2-Dipp)Si(NDipp)(P(SiMe3)2)
_cod_depositor_comments
'Adding full bibliography for 7704658--7704661.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7704659
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.975
_shelx_estimated_absorpt_t_max   0.993
_shelx_res_checksum              23307