Complexes of late transition metals containing the mixed donor ligands 2,6-(RSCH2)2C5H3N (R = Ph, Me): Crystal structures of [{Cu(2,6-(PhSCH2)2C5H3N)(µ-X)}2] (X = Cl, Br) and [Ni(2,6-(PhSCH2)2C5H3N)Br2]
Ball, Rachel J.; Genge, Anthony R. J.; Radford, Alison L.; Skelton, Brian W.; Tolhurst, Vicki-Anne; White, Allan H.; Journal of the Chemical Society, Dalton Transactions  (2001) 2807–; doi:10.1039/b104332n

data_7010830
_publ_section_title
;
 Complexes of late transition metals containing the mixed donor ligands
 2,6-(RSCH2)2C5H3N (R = Ph, Me): Crystal structures of
 [{Cu(2,6-(PhSCH2)2C5H3N)(&#x00B5;-X)}2] (X = Cl, Br) and
 [Ni(2,6-(PhSCH2)2C5H3N)Br2]
;
_journal_issue                   19
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2807
_journal_paper_doi               10.1039/b104332n
_journal_year                    2001
_chemical_formula_moiety         'C38 H34 Br2 Cu2 N2 S4 '
_chemical_formula_sum            'C38 H34 Br2 Cu2 N2 S4'
_chemical_formula_weight         933.84
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_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_secondary   difmap
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?
;
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_cell_length_b                   13.133(6)
_cell_length_c                   7.866(2)
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teXsan for Windows version 1.06 (MSC, 1997-1999)
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teXsan for Windows version 1.06 (MSC, 1997-1999)
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SIR92 (Altomare, et. al. 1994)
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_diffrn_orient_matrix_UB_31      -0.09946
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_diffrn_radiation_detector       'scintillation counter'
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;
psi-scans (North,Phillips & Matthews, 1968)
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_file            b104332n.txt
_cod_data_source_block           '_rb06_CuBrS2N'
_cod_original_cell_volume        937.8(7)
_cod_original_sg_symbol_H-M      'P -1       '
_cod_original_formula_sum        'C38 H34 Br2 Cu2 N2 S4 '
_cod_database_code               7010830