E-Selective Allyl Transfer Reaction in a μ-η1:η2-Crotylplatinum−Cobalt Complex
Komine, Nobuyuki; Hirota, Takuma; Hirano, Masafumi; Komiya, Sanshiro; Organometallics 27 (2008) 2145–; doi:10.1021/om701062g

data_4070835
_publ_section_title
;
 E-Selective Allyl Transfer Reaction in a
 \m-\h1:\h2-Crotylplatinum&#x2212;Cobalt Complex
;
_journal_issue                   9
_journal_name_full               Organometallics
_journal_page_first              2145
_journal_paper_doi               10.1021/om701062g
_journal_volume                  27
_journal_year                    2008
_chemical_formula_moiety         'C39 H37 Co O3 P2 Pt '
_chemical_formula_sum            'C39 H37 Co O3 P2 Pt'
_chemical_formula_weight         869.69
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 91.18(3)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   9.316(4)
_cell_length_b                   18.188(4)
_cell_length_c                   20.671(5)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    200.1
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.7
_cell_volume                     3501.7(19)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.075
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            8245
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_standards_decay_%        -0.46
_diffrn_standards_interval_count 0
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.576
_exptl_absorpt_correction_T_max  0.633
_exptl_absorpt_correction_T_min  0.375
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.650
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1720.00
_exptl_crystal_size_max          0.46
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         7.27
_refine_diff_density_min         -4.38
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     412
_refine_ls_number_reflns         8245
_refine_ls_R_factor_gt           0.0536
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0035Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2064
_reflns_number_gt                5220
_reflns_number_total             8033
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om701062g-file004.cif
_cod_data_source_block           3b
_cod_original_cell_volume        3501.7(18)
_cod_original_formula_sum        'C39 H37 Co O3 P2 Pt '
_cod_database_code               4070835