Intra-complex energy transfer of europium(III) complexes containing anthracene and phenanthrene moieties.
Osawa, Masahisa; Hoshino, Mikio; Wada, Tatsuo; Hayashi, Fumi; Osanai, Shuichi; The journal of physical chemistry. A 113 (2009) 10895–10902; doi:10.1021/jp905160w

data_1516357
_publ_section_title
;
 Intra-complex energy transfer of europium(III) complexes containing
 anthracene and phenanthrene moieties.
;
_journal_issue                   41
_journal_name_full               'The journal of physical chemistry. A'
_journal_page_first              10895
_journal_page_last               10902
_journal_paper_doi               10.1021/jp905160w
_journal_volume                  113
_journal_year                    2009
_chemical_formula_moiety         'C55 H49 Eu F18 O8 P2 '
_chemical_formula_sum            'C55 H49 Eu F18 O8 P2'
_chemical_formula_weight         1393.87
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 96.2858(18)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   15.8040(16)
_cell_length_b                   20.343(2)
_cell_length_c                   18.9226(19)
_cell_measurement_reflns_used    8871
_cell_measurement_temperature    90.1
_cell_measurement_theta_max      32.5
_cell_measurement_theta_min      2.0
_cell_volume                     6047.1(10)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  SHELXL
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.054
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            58078
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    1.193
_exptl_absorpt_correction_T_max  0.788
_exptl_absorpt_correction_T_min  0.735
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
    Higashi, T. (1999). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.531
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2792.00
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         3.35
_refine_diff_density_min         -1.34
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.113
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     758
_refine_ls_number_reflns         13752
_refine_ls_R_factor_gt           0.0589
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0882P)^2^+26.9445P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1779
_reflns_number_gt                12413
_reflns_number_total             13752
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            jp905160w_si_002.cif
_cod_data_source_block           '__EuA'
_cod_original_cell_volume        6047.2(10)
_cod_original_formula_sum        'C55 H49 Eu F18 O8 P2 '
_cod_database_code               1516357