Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: isolation of a Pt(II), Shimoi-type, Eta1-BH complex
Marta Rosello-Merino; Raquel J. Rama; Josefina Diez; Salvador Conejero; Chem.Commun. 52 (2016) 8389–; doi:

data_7119675
_publ_section_title
;
 Catalytic dehydrocoupling of amine-boranes and amines into
 diaminoboranes: isolation of a Pt(II), Shimoi-type, Eta1-BH complex
;
_journal_name_full               Chem.Commun.
_journal_page_first              8389
_journal_volume                  52
_journal_year                    2016
_chemical_compound_source        synthesis
_chemical_formula_moiety         'C27 H47 B N5 Pt, C32 H12 B F24'
_chemical_formula_sum            'C59 H59 B2 F24 N5 Pt'
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_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2016-03-16 deposited with the CCDC.
2016-06-03 downloaded from the CCDC.
;
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_computing_cell_refinement       'Bruker SAINT'
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_computing_molecular_graphics    'PLATON (Spek, 2008)'
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_diffrn_measured_fraction_theta_max 0.961
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_point_group_measured_fraction_full 0.779
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_exptl_crystal_density_diffrn    1.556
_exptl_crystal_description       prism
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;
;
_refine_diff_density_max         1.653
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0411P)^2^+135.6565P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0981
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
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_shelx_res_checksum              22524