<i>catena</i>-Poly[silver(I)-bis[μ-bis(diphenylphosphino)methane-κ^2^<i>P</i>:<i>P</i>']-μ-thiocyanato-κ^2^<i>S</i>:<i>S</i>-silver(I)-μ-thiocyanato-κ^2^<i>S</i>:<i>N</i>]
Song, Li-Li; Cui, Li-Na; Jin, Qiong-Hua; Zhang, Cun-Lin; Acta Crystallographica Section E 66 (2010) m1237–m1238; doi:10.1107/S1600536810035622

data_2227515
_publ_section_title
;
 <i>catena</i>-Poly[silver(I)-bis[\m-bis(diphenylphosphino)methane-\k^2^<i>P</i>:<i>P</i>']-\m-thiocyanato-\k^2^<i>S</i>:<i>S</i>-silver(I)-\m-thiocyanato-\k^2^<i>S</i>:<i>N</i>]
;
_journal_coeditor_code           HB5620
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1237
_journal_page_last               m1238
_journal_paper_doi               10.1107/S1600536810035622
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Ag (N C S) (C25 H22 P2)]'
_chemical_formula_moiety         'C26 H22 Ag N P2 S'
_chemical_formula_sum            'C26 H22 Ag N P2 S'
_chemical_formula_weight         550.32
_chemical_name_systematic
;
<i>catena</i>-Poly[silver(I)-bis[\m-bis(diphenylphosphino)methane-
\k^2^<i>P</i>:<i>P</i>']-\m-thiocyanato-\k^2^<i>S</i>:<i>S</i>-silver(I)-
\m-thiocyanato-\k^2^<i>S</i>:<i>N</i>]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.4700(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   13.0712(14)
_cell_length_b                   23.080(2)
_cell_length_c                   15.6340(16)
_cell_measurement_reflns_used    4221
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      23.067
_cell_measurement_theta_min      2.273
_cell_volume                     4707.9(8)
_computing_cell_refinement       'SAINT (Bruker, 2007)'
_computing_data_collection       'SMART (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0561
_diffrn_reflns_av_sigmaI/netI    0.0760
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            23675
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    1.095
_exptl_absorpt_correction_T_max  0.721
_exptl_absorpt_correction_T_min  0.650
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2007)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.553
_exptl_crystal_density_meas      1.553
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2224
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.32
_refine_diff_density_max         1.339
_refine_diff_density_min         -1.312
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     559
_refine_ls_number_reflns         8306
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.1266
_refine_ls_R_factor_gt           0.0588
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0414P)^2^+37.5530P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1215
_refine_ls_wR_factor_ref         0.1684
_reflns_number_gt                4539
_reflns_number_total             8306
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            hb5620.cif
_cod_data_source_block           I
_cod_original_cell_volume        4708.0(8)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2227515
_cod_database_fobs_code          2227515