Synthesis, structure, solution behavior, reactivity and biological evaluation of oxidovanadium(iv/v) thiosemicarbazone complexes.
Saswati, ?; Adão, Pedro; Majumder, Sudarshana; Dash, Subhashree P.; Roy, Satabdi; Kuznetsov, Maxim L.; Costa Pessoa, João; Gomes, Clara S. B.; Hardikar, Manasi R.; Tiekink, Edward R. T.; Dinda, Rupam; Dalton transactions (Cambridge, England : 2003) 47 (2018) 11358–11374; doi:10.1039/c8dt01668b

data_7047094
_publ_section_title
;
 Synthesis, structure, solution behavior, reactivity and biological
 evaluation of oxidovanadium(iv/v) thiosemicarbazone complexes.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11358
_journal_page_last               11374
_journal_paper_doi               10.1039/c8dt01668b
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C14 H12 F N4 O2 S V'
_chemical_formula_sum            'C14 H12 F N4 O2 S V'
_chemical_formula_weight         370.28
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-02-21 deposited with the CCDC.
2018-07-23 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_computing_molecular_graphics
;
ORTEP-3 for Windows (Farrugia, 2012) and DIAMOND (Brandenburg, 2006)
;
_computing_publication_material  'SHELXL2014/7 (Sheldrick, 2015)'
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'Agilent Technologies SuperNova Dual diffractometer with Atlas detector'
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_exptl_crystal_colour            yellow
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_refine_ls_extinction_method     none
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_refine_ls_restrained_S_all      1.007
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0589P)^2^+3.1385P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             3723
_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7047093--7047094.cif.'
_cod_original_cell_volume        3049.1(11)
_cod_database_code               7047094
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              16174