Copper-Catalyzed Regio- and Stereoselective Aminoboration of Alkenylboronates.
Nishikawa, Daiki; Hirano, Koji; Miura, Masahiro; Organic letters 18 (2016) 4856–4859; doi:10.1021/acs.orglett.6b02338

data_1544165
_publ_section_title
;
 Copper-Catalyzed Regio- and Stereoselective Aminoboration of
 Alkenylboronates.
;
_journal_issue                   19
_journal_name_full               'Organic letters'
_journal_page_first              4856
_journal_page_last               4859
_journal_paper_doi               10.1021/acs.orglett.6b02338
_journal_volume                  18
_journal_year                    2016
_chemical_formula_moiety         'C32 H39 B2 N5 O'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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_cell_angle_beta                 100.941(12)
_cell_angle_gamma                90.0000
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_cell_measurement_theta_max      27.50
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_computing_publication_material  'CrystalStructure 4.2.1 (Rigaku, 2016)'
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_computing_structure_solution    'Il Milione (Burla, et al., 2007)'
_diffrn_ambient_temperature      173
_diffrn_detector_area_resol_mean 13.653
_diffrn_measured_fraction_theta_full 0.996
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_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -13
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_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            12766
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_diffrn_reflns_point_group_measured_fraction_max 0.990
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_diffrn_reflns_theta_min         3.268
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_exptl_absorpt_correction_T_min  0.978
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_exptl_crystal_colour            colorless
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
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_refine_ls_number_reflns         6599
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0540P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 1544164--1544165.cif.'
_cod_database_code               1544165
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