Cooperative enhancement of redox catalysis in divanadium complexes binucleated by 1,8-naphthyridine-2,7-dicarboxylate.
Simran, Simran; Tansky, Maxym; Trabulsi, Seth; Deng, Liangzi; Chu, Ching-Wu; Ozarowski, Andrew; Comito, Robert J.; Dalton transactions (Cambridge, England : 2003) 54 (2025) 15400–15405; doi:10.1039/d5dt01296a

data_7719549
_publ_section_title
;
 Cooperative enhancement of redox catalysis in divanadium complexes
 binucleated by 1,8-naphthyridine-2,7-dicarboxylate.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15400
_journal_page_last               15405
_journal_paper_doi               10.1039/d5dt01296a
_journal_volume                  54
_journal_year                    2025
_chemical_formula_sum            'C22 H36 N2 O11 S3 V2'
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_chemical_properties_physical    Air-sensitive
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_audit_update_record
;
2025-04-23 deposited with the CCDC.	2025-10-02 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_exptl_absorpt_correction_T_max  0.4920
_exptl_absorpt_correction_T_min  0.4577
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.480
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_refine_ls_restrained_S_all      1.047
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0416P)^2^+2.8438P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0932
_refine_ls_wR_factor_ref         0.1018
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_reflns_number_gt                5967
_reflns_number_total             7671
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5dt01296a2.cif
_cod_data_source_block           MT7-055_XW364
_cod_depositor_comments
'Adding full bibliography for 7719545--7719549.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7719549
_shelx_shelxl_version_number     2018/3
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_shelx_res_checksum              1774
_shelx_hkl_checksum              28382