Triptycene-Based Porous Metal-Assisted Salphen Organic Frameworks: Influence of the Metal Ions on Formation and Gas Sorption
Reinhard, Dennis; Zhang, Wen-Shan; Vaynzof, Yana; Rominger, Frank; Schröder, Rasmus R.; Mastalerz, Michael; Chemistry of Materials 30 (2018) 2781–; doi:10.1021/acs.chemmater.8b00614

data_4003115
_publ_section_title
;
 Triptycene-Based Porous Metal-Assisted Salphen Organic Frameworks:
 Influence of the Metal Ions on Formation and Gas Sorption
;
_journal_issue                   8
_journal_name_full               'Chemistry of Materials'
_journal_page_first              2781
_journal_paper_doi               10.1021/acs.chemmater.8b00614
_journal_volume                  30
_journal_year                    2018
_chemical_formula_sum            'C71 H53 Cl9 O12'
_chemical_formula_weight         1417.18
_chemical_name_common            '3 in manuscript'
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   geom
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_cell_angle_gamma                66.9730(10)
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_cell_length_b                   13.8776(3)
_cell_length_c                   23.4581(4)
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_cell_measurement_theta_min      3.56
_cell_volume                     3253.08(11)
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_computing_structure_solution    'SHELXT-2014 (Sheldrick 2014)'
_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'STOE Stadivari'
_diffrn_measurement_method       'rotation method, \w scans'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.990
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_diffrn_source                   'Genix3D Cu HF'
_exptl_absorpt_coefficient_mu    4.072
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_exptl_absorpt_correction_T_min  0.415
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0593P)^2^+4.8938P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_exptl_absorpt_special_details   'X-Area LANA 1.70.0.0 (STOE, 2017)'
_shelx_res_checksum              53463
_shelx_hkl_checksum              27446