Synthesis and reactivity at the Ir-<sup>Me</sup>Tpm platform: from κ<sup>1</sup>-N coordination to κ<sup>3</sup>-N-based organometallic chemistry.
Fernández-Alvarez, Francisco J; Polo, Víctor; García-Orduña, Pilar; Lahoz, Fernando J.; Pérez-Torrente, Jesús J; Oro, Luis A.; Lalrempuia, Ralte; Dalton transactions (Cambridge, England : 2003) 48 (2019) 6455–6463; doi:10.1039/c9dt00703b

data_7049422
_publ_section_title
;
 Synthesis and reactivity at the Ir-<sup>Me</sup>Tpm platform: from
 \k<sup>1</sup>-N coordination to \k<sup>3</sup>-N-based organometallic
 chemistry.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               6463
_journal_paper_doi               10.1039/c9dt00703b
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C24 H34 Cl Ir N6'
_chemical_formula_sum            'C24 H34 Cl Ir N6'
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_space_group_name_Hall           '-P 1'
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;
2017-12-21 deposited with the CCDC.    2019-03-25 downloaded from the CCDC.
;
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_cell_measurement_reflns_used    9951
_cell_measurement_temperature    100(2)
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_cell_volume                     2404.21(16)
_computing_cell_refinement
'SAINT+ in APEX2 v. 2008.4 (Bruker AXS, 2008)'
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'SAINT+ in APEX2 v. 2008.4 (Bruker AXS, 2008)'
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;
 SADABS: Area-Detector Absorption Correction. (1996) Bruker-AXS 
 within APEX2 package.
;
_exptl_crystal_colour            yellow
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'Re-crystallisation from solvent: Toluene / deuterated benzene'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0197P)^2^+3.8880P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_total             12204
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_cod_depositor_comments
'Adding full bibliography for 7049422--7049425.cif.'
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_shelxl_version_number           2014-3
_shelx_res_checksum              65282