Enantioselective Synthesis of Chiral α-Thio-Quaternary Stereogenic Centers via Phase-Transfer-Catalyzed α-Alkylation of α-Acylthiomalonates.
Ha, Min Woo; Lee, Jun Young; Kim, Doyoung; Lee, Geumwoo; Lee, Jae Kyun; Hong, Suckchang; Park, Hyeung-Geun; The Journal of organic chemistry 83 (2018) 1011–1018; doi:10.1021/acs.joc.7b02605

data_4033344
_publ_section_title
;
 Enantioselective Synthesis of Chiral \a-Thio-Quaternary Stereogenic
 Centers via Phase-Transfer-Catalyzed \a-Alkylation of
 \a-Acylthiomalonates.
;
_journal_issue                   2
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              1011
_journal_page_last               1018
_journal_paper_doi               10.1021/acs.joc.7b02605
_journal_volume                  83
_journal_year                    2018
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_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
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_cell_measurement_theta_max      27.48
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_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
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_computing_structure_solution    'Il Milione (Burla, et al., 2007)'
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_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
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'Flack, H. D. (1983), Acta Cryst. A39, 876-881.  2944 Friedel Pairs'
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_refine_ls_structure_factor_coef Fsqd
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'w = 1/[\s^2^(Fo^2^)+(0.0474P)^2^+0.4996P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments          'Adding full bibliography for 4033344.cif.'
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