The path to an open-shell metallo-germylene: direct ligation, or reduction and metathesis?
Schulz, Annika; Heinz, Myron; Holthausen, Max C.; Hadlington, Terrance J.; Chemical science 16 (2025) 20265–20274; doi:10.1039/d5sc04265h

data_1575789
_publ_section_title
;
 The path to an open-shell metallo-germylene: direct ligation, or
 reduction and metathesis?
;
_journal_issue                   43
_journal_name_full               'Chemical science'
_journal_page_first              20265
_journal_page_last               20274
_journal_paper_doi               10.1039/d5sc04265h
_journal_volume                  16
_journal_year                    2025
_chemical_formula_moiety         'C62 H86 Ge2 N2 P2 Si2'
_chemical_formula_sum            'C62 H86 Ge2 N2 P2 Si2'
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_space_group_crystal_system      monoclinic
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2025-08-14 deposited with the CCDC.	2025-09-15 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
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_computing_cell_refinement       'STOE X-AREA 1.76'
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_diffrn_measurement_device_type  'STOE StadiVari'
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_diffrn_radiation_collimation    '0.6 mm diameter'
_diffrn_radiation_monochromator  'Graded multilayer mirror'
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_diffrn_source                   'Genix 3D HF Mo'
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_exptl_crystal_colour            orange-purple
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0818P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                3671
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 1575788--1575792.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1575789
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              89110