Tetravalent Titanium, Zirconium, and Cerium Oxo and Peroxo Complexes Containing an Imidodiphosphinate Ligand
Guo-Cang Wang; Herman H. Y. Sung; Ian D. Williams; Wa-Hung Leung; Inorganic Chemistry 51 (2012) 3640–3647; doi:10.1021/ic202564h

data_4328651
_publ_contact_author_name
;
;
_publ_section_title
;
 Tetravalent Titanium, Zirconium, and Cerium Oxo and Peroxo Complexes
 Containing an Imidodiphosphinate Ligand
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3640
_journal_page_last               3647
_journal_paper_doi               10.1021/ic202564h
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C24 H64 K2 N2 O8 P4, 4(H2 O)'
_chemical_formula_sum            'C24 H72 K2 N2 O12 P4'
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 ? 
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
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XL, G.M. Sheldrick, Acta Cryst.
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  1 omega -102.00  -15.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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  2 omega -112.00  -15.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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  3 omega  -64.00   11.00   1.0000    2.0000
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  4 omega  -65.00   31.00   1.0000    2.0000
omega____ theta____ kappa____ phi______ frames
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  5 omega -112.00  -41.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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  6 omega  107.00  138.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -90.0000  147.0000 31

  7 omega   45.00  102.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -90.0000  147.0000 57

  8 omega   81.00  108.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -86.0000  -60.0000 27

  9 omega   37.00   70.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000 -180.0000 33

 10 omega   37.00   71.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000   30.0000 34

 11 omega   38.00   72.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000 -150.0000 34

 12 omega   38.00  141.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -92.0000 -137.0000 103

 13 omega   37.00   68.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000    0.0000 31

 14 omega   38.00   71.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000  -60.0000 33

 15 omega   37.00   70.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000  -30.0000 33

 16 omega   41.00   72.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000  120.0000 31

 17 omega  120.00  145.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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 18 omega   37.00   72.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
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 19 omega   39.00   68.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000  150.0000 29

 20 omega   40.00   69.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -50.0000   60.0000 29

 21 omega   41.00   72.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000 -120.0000 31

 22 omega   38.00   69.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000   60.0000 31

 23 omega   39.00   69.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -25.0000  -90.0000 30

 24 omega   39.00   68.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -86.0000  -60.0000 29

 25 omega   42.00  129.00   1.0000    6.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -90.0000   19.0000 87
;
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CrysAlisPro, Oxford Diffraction Ltd.,
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empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            colorless
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_refine_ls_number_reflns         3726
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'calc w=1/[\s^2^(Fo^2^)+(0.1182P)^2^+0.1148P] where P=(Fo^2^+2Fc^2^)/3'
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