A concise and versatile route to tetrahydro-1-benzazepines carrying [<i>a</i>]-fused heterocyclic units: synthetic sequence and spectroscopic characterization, and the molecular and supramolecular structures of one intermediate and two products
Guerrero, Sergio A.; Ramírez, Juan E.; Palma, Alirio; Cobo, Justo; Glidewell, Christopher; Acta Crystallographica Section C 75 (2019) –; doi:10.1107/S2053229619000871

data_2021455
_publ_section_title
;
 A concise and versatile route to tetrahydro-1-benzazepines carrying
 [<i>a</i>]-fused heterocyclic units: synthetic sequence and spectroscopic
 characterization, and the molecular and supramolecular structures of one
 intermediate and two products
;
_journal_coeditor_code           FN3291
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_journal_name_full               'Acta Crystallographica Section C'
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;
;
_journal_paper_doi               10.1107/S2053229619000871
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_journal_year                    2019
_chemical_formula_iupac          'C15 H17 Cl N2 O4'
_chemical_formula_moiety         'C15 H17 Cl N2 O4'
_chemical_formula_sum            'C15 H17 Cl N2 O4'
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(4a<i>RS</i>,6<i>SR</i>)-9-chloro-6-hydroxy-3-(2-hydroxyethyl)-2,3,4a,5,6,7-hexahydrobenzo[<i>f</i>]pyrazino[1,2-<i>a</i>]azepine-1,4-dione
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;
SAINT (Bruker, 2016)
;
_computing_data_collection
;
APEX3 (Bruker, 2016)
;
_computing_data_reduction
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SAINT (Bruker, 2016)
;
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PLATON (Spek, 2009)
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SHELXL2014 (Sheldrick, 2015) and PLATON (Spek, 2009)
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SHELXL2014 (Sheldrick, 2015)
;
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;
SIR92 (Altomare <i>et al.</i>,  1994)
;
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'INCOATEC high brilliance microfocus sealed tube'
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;
(SADABS; Bruker, 2015)
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0338P)^2^+1.0495P] where P=(Fo^2^+2Fc^2^)/3'
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