Robust high-connected rare-earth MOFs as efficient heterogeneous catalysts for CO2 conversion.
Wei, Na; Zuo, Rong-Xia; Zhang, Yu-Yang; Han, Zheng-Bo; Gu, Xue-Jun; Chemical communications (Cambridge, England) 53 (2017) 3224–3227; doi:10.1039/c7cc00363c

data_7119731
_publ_section_title
;
 Robust high-connected rare-earth MOFs as efficient heterogeneous
 catalysts for CO2 conversion.
;
_journal_issue                   22
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3224
_journal_page_last               3227
_journal_paper_doi               10.1039/c7cc00363c
_journal_volume                  53
_journal_year                    2017
_chemical_formula_sum            'C39 H22 Er3 O19'
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_space_group_name_Hall           '-P 6c'
_space_group_name_H-M_alt        'P 63/m'
_symmetry_space_group_name_Hall  '-P 6c'
_symmetry_space_group_name_H-M   'P 63/m'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-01-01 deposited with the CCDC.
2017-02-23 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_measurement_temperature    100(2)
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_cell_volume                     2288.16(11)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
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_diffrn_reflns_av_unetI/netI     0.0430
_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_theta_max         73.231
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_exptl_absorpt_coefficient_mu    10.436
_exptl_absorpt_correction_T_max  0.788
_exptl_absorpt_correction_T_min  0.729
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.880
_exptl_crystal_description       block
_exptl_crystal_F_000             1222
_exptl_crystal_size_max          0.380
_exptl_crystal_size_mid          0.360
_exptl_crystal_size_min          0.290
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0599P)^2^+140.6023P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2642
_refine_ls_wR_factor_ref         0.2653
_reflns_Friedel_coverage         0.000
_reflns_number_gt                1488
_reflns_number_total             1546
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7cc00363c2.cif
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_cod_depositor_comments
'Adding full bibliography for 7119730--7119731.cif.'
_cod_original_cell_volume        2288.16(15)
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_shelx_res_checksum              11607
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