The role of coordinated solvent on Co(ii) ions in tuning the single molecule magnet properties in a {CoDy} system.
Peng, Yan; Mereacre, Valeriu; Anson, Christopher E.; Powell, Annie K.; Dalton transactions (Cambridge, England : 2003) 46 (2017) 5337–5343; doi:10.1039/c7dt00548b

data_7042477
_publ_section_title
;
 The role of coordinated solvent on Co(ii) ions in tuning the single
 molecule magnet properties in a {CoDy} system.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5337
_journal_page_last               5343
_journal_paper_doi               10.1039/c7dt00548b
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C58 H52 Co2 Dy2 N6 O20, 2(C H2 Cl2)'
_chemical_formula_sum            'C60 H56 Cl4 Co2 Dy2 N6 O20'
_chemical_formula_weight         1765.76
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2016-11-25 deposited with the CCDC.
2017-03-14 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 105.717(2)
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_diffrn_measurement_device_type  'Bruker SMART Apex'
_diffrn_measurement_method       'CCD area detector, \w-scans'
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_diffrn_reflns_limit_h_max       15
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_diffrn_source                   'rotating anode'
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_exptl_absorpt_process_details   'SADABS 2.10 (Bruker AXS Inc., 2005)'
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_exptl_crystal_description       block
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0882P)^2^+11.2587P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1424
_reflns_Friedel_coverage         0.000
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_reflns_number_total             6971
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7dt00548b2.cif
_cod_data_source_block           co2dy2m
_cod_depositor_comments
'Adding full bibliography for 7042476--7042478.cif.'
_cod_database_code               7042477
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              5334