Pentamethyl- and 1,2,4-tri(tert-butyl)cyclopentadienyl containing p-block complexes - differences and similarities.
Ding, Yi; Ruth, Paul Niklas; Herbst-Irmer, Regine; Stalke, Dietmar; Yang, Zhi; Roesky, Herbert W.; Dalton transactions (Cambridge, England : 2003) 50 (2021) 2067–2074; doi:10.1039/d0dt04412a

data_7706443
_publ_section_title
;
 Pentamethyl- and 1,2,4-tri(tert-butyl)cyclopentadienyl containing p-block
 complexes - differences and similarities.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2067
_journal_page_last               2074
_journal_paper_doi               10.1039/d0dt04412a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C17 H29 Ge, Cl3 Ge'
_chemical_formula_sum            'C17 H29 Cl3 Ge2'
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_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-12-11 deposited with the CCDC.	2021-01-18 downloaded from the CCDC.
;
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'SHELXT(G.M.Sheldrick,Acta Cryst.(2015)A71,3-8)'
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker Smart APEX II Quazar'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_min         1.603
_diffrn_source                   'INCOATEC Microsource'
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_exptl_absorpt_correction_T_max  0.4330
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_exptl_crystal_colour            colourless
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0141P)^2^+4.9615P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0614
_refine_ls_wR_factor_ref         0.0622
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_reflns_number_gt                6064
_reflns_number_total             6504
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7706437--7706443.cif.'
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