Highly selective synthesis of substituted (E)-alkenylsilatranes via catalytic trans-silylation and mechanistic implications.
Sztorch, Bogna; Frąckowiak, Dawid; Pyziak, Jadwiga; Czapik, Agnieszka; Hoffmann, Marcin; Marciniec, Bogdan; Dalton transactions (Cambridge, England : 2003) 46 (2017) 4975–4981; doi:10.1039/c7dt00201g

data_7042513
_publ_section_title
;
 Highly selective synthesis of substituted (E)-alkenylsilatranes via
 catalytic trans-silylation and mechanistic implications.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4975
_journal_page_last               4981
_journal_paper_doi               10.1039/c7dt00201g
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C15 H21 N O3 Si'
_chemical_formula_sum            'C15 H21 N O3 Si'
_chemical_formula_weight         291.42
_space_group_crystal_system      orthorhombic
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_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2016-12-22 deposited with the CCDC.
2017-03-16 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'New Xcalibur, EosS2'
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_diffrn_reflns_point_group_measured_fraction_full 0.995
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_exptl_crystal_description       plate
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0618
_refine_ls_R_factor_gt           0.0416
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0473P)^2^+0.9776P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0977
_refine_ls_wR_factor_ref         0.1087
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_reflns_number_gt                2015
_reflns_number_total             2641
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7042512--7042514.cif.'
_cod_database_code               7042513
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              89586