Platinum-Catalyzed Dehydroalkoxylation-Cyclization Cascade via N-O Bond Cleavage
Itaru Nakamura; Yusuke Sato; Masahiro Terada; Journal of the American Chemical Society 131 (2009) 4198–4199; doi:10.1021/ja900174t

data_4104101
_publ_contact_author_address
;

Department of Chemistry
Graduate School of Science
Tohoku University
Sendai 980-8578
Japan
;
_publ_contact_author_email
;
itaru-n@mail.tains.tohoku.ac.jp
;
_publ_contact_author_name
;
Itaru Nakamura
;
_publ_contact_author_phone
;
+81(0)22 7956754
;
_publ_section_title
;
 Platinum-Catalyzed Dehydroalkoxylation-Cyclization Cascade via N-O Bond
 Cleavage
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              4198
_journal_page_last               4199
_journal_paper_doi               10.1021/ja900174t
_journal_volume                  131
_journal_year                    2009
_chemical_formula_moiety         'C23 H18 N2 O2 '
_chemical_formula_sum            'C23 H18 N2 O2'
_chemical_formula_weight         354.41
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                69.1766
_cell_angle_beta                 80.9397
_cell_angle_gamma                86.5353
_cell_formula_units_Z            2
_cell_length_a                   6.2669
_cell_length_b                   9.2991
_cell_length_c                   15.9031
_cell_measurement_reflns_used    2425
_cell_measurement_temperature    173.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.4
_cell_volume                     855.423
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR2004
_diffrn_detector_area_resol_mean 29.26
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.044
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            12305
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_exptl_absorpt_coefficient_mu    0.089
_exptl_absorpt_correction_T_max  0.982
_exptl_absorpt_correction_T_min  0.976
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
    Higashi, T. (1999). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.376
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             372.00
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.43
_refine_diff_density_min         -0.39
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     262
_refine_ls_number_reflns         3858
_refine_ls_R_factor_gt           0.0645
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0067Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2228
_reflns_number_gt                2977
_reflns_number_total             3856
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ja900174t_si_002.cif
_cod_data_source_block           '___a'
_cod_original_cell_volume        855.4230
_cod_original_formula_sum        'C23 H18 N2 O2 '
_cod_database_code               4104101