Reversible Aromaticity Transfer in a Bora-Cycle: Boron-Ligand Cooperation.
Gellrich, Urs; Diskin-Posner, Yael; Shimon, Linda J. W.; Milstein, David; Journal of the American Chemical Society 138 (2016) 13307–13313; doi:10.1021/jacs.6b07454

data_4130850
_publ_section_title
;
 Reversible Aromaticity Transfer in a Bora-Cycle: Boron-Ligand
 Cooperation.
;
_journal_issue                   40
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13307
_journal_page_last               13313
_journal_paper_doi               10.1021/jacs.6b07454
_journal_volume                  138
_journal_year                    2016
_chemical_formula_moiety         'C20 H19 B N2 O2'
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_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
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_diffrn_measurement_device_type  'Rigaku XtaLAB Pro: Kappa dual home/near'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.4c (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0434P)^2^+0.6631P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ja6b07454_si_002.cif
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_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4130850
_shelx_estimated_absorpt_t_min   0.949
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