Aromaticity as stabilizing element in the bidentate activation for the catalytic reduction of carbon dioxide.
Lu, Zhenpin; Hausmann, Heike; Becker, Sabine; Wegner, Hermann A.; Journal of the American Chemical Society 137 (2015) 5332–5335; doi:10.1021/jacs.5b02905

data_4129430
_publ_section_title
;
 Aromaticity as stabilizing element in the bidentate activation for the
 catalytic reduction of carbon dioxide.
;
_journal_issue                   16
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5332
_journal_page_last               5335
_journal_paper_doi               10.1021/jacs.5b02905
_journal_volume                  137
_journal_year                    2015
_chemical_formula_sum            'C27 H21 B2 Br2 O4'
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.33(3)
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0449P)^2^+2.5843P] where P=(Fo^2^+2Fc^2^)/3'
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