A New One-Dimensional Platinum System Consisting of Carboxylate-Bridged cis-Diammineplatinum Dimers1
Ken Sakai; Masao Takeshita; Yuko Tanaka; Takuma Ue; Masayuki Yanagisawa; Masaya Kosaka; Taro Tsubomura; Masamichi Ato; Takeo Nakano; Journal of the American Chemical Society 120 (1998) 11353–11363; doi:10.1021/ja980055p

data_4116869
_publ_contact_author
;
    Dr Ken Sakai
    Department of Industrial Chemistry
    Seikei University
    Kichijoji-Kitamachi
    Musashino, Tokyo 180
    Japan
;
_publ_contact_author_email       ksakai@.ch.seikei.ac.jp
_publ_contact_author_fax         '+81 422 37 3871'
_publ_contact_author_phone       '+81 422 37 3759'
_publ_section_title
;
 A New One-Dimensional Platinum System Consisting of Carboxylate-Bridged
 cis-Diammineplatinum Dimers1
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11353
_journal_page_last               11363
_journal_paper_doi               10.1021/ja980055p
_journal_volume                  120
_journal_year                    1998
_chemical_formula_moiety
;
2(C14 H22 N4 O4 Pt2), C14 H16 N2 O4 Pt1, Si F6, 2(B F4), 3(H2 O)
;
_chemical_formula_sum            'C42 H66 B2 F14 N10 O15 Pt5 Si'
_chemical_formula_weight         2242.18
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_date             97-05-16
_audit_creation_method           'teXsan (modified by Ken Sakai)'
_audit_update_record
;
97-05-16    text and data added by Ken Sakai
;
_cell_angle_alpha                90
_cell_angle_beta                 109.84(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4.00
_cell_length_a                   19.078(4)
_cell_length_b                   17.014(3)
_cell_length_c                   21.212(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.0
_cell_measurement_theta_max      69.91
_cell_measurement_theta_min      67.26
_cell_volume                     6476.6(19)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_computing_structure_solution    SAPI91
_diffrn_ambient_temperature      296.0
_diffrn_measurement_device       'Rigaku AFC5S'
_diffrn_measurement_method       \q/2\q
_diffrn_orient_matrix_UB_11      0.02911
_diffrn_orient_matrix_UB_12      0.00330
_diffrn_orient_matrix_UB_13      -0.03123
_diffrn_orient_matrix_UB_21      -0.04733
_diffrn_orient_matrix_UB_22      -0.00314
_diffrn_orient_matrix_UB_23      -0.03920
_diffrn_orient_matrix_UB_31      -0.00418
_diffrn_orient_matrix_UB_32      0.05860
_diffrn_orient_matrix_UB_33      -0.00034
_diffrn_radiation_detector       'scintillation,NaI,Rigaku SC-30'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0411
_diffrn_reflns_av_sigmaI/netI    0.0658
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            10362
_diffrn_reflns_theta_max         60.00
_diffrn_reflns_theta_min         2.21
_diffrn_standards_decay_%        -0.31
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    20.822
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.2810
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   'psi-scans (North's method)'
_exptl_crystal_colour            'pale blue'
_exptl_crystal_density_diffrn    2.2995
_exptl_crystal_description       plate-needle
_exptl_crystal_F_000             4192.00
_exptl_crystal_size_max          0.83
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.05
_refine_diff_density_max         3.31
_refine_diff_density_min         -2.22
_refine_ls_abs_structure_details
;
none
;
_refine_ls_extinction_coef       0.67(4)
_refine_ls_extinction_method     Zachariasen_type_2_gaussian_isotropic
_refine_ls_goodness_of_fit_obs   2.430
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     785
_refine_ls_number_reflns         7949
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0713
_refine_ls_R_factor_obs          0.0561
_refine_ls_shift/esd_max         0.0090
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma_w=1/\s^2^(F)+0.000100F^2^
_refine_ls_wR_factor_all         0.0512
_refine_ls_wR_factor_obs         0.0501
_reflns_number_observed          7949
_reflns_number_total             10023
_reflns_observed_criterion       I_>_2.0_sigma(I)
_cod_data_source_file            ja980055p_5.cif
_cod_data_source_block           complex10
_cod_original_cell_volume        6477(1)
_cod_original_formula_sum        'B2 C42 F14 H66 N10 O15 Pt5 Si1'
_cod_database_code               4116869