Rhodium-catalyzed asymmetric arylation of allyl sulfones under the conditions of isomerization into alkenyl sulfones.
Lim, Kelvin Meng-Hui; Hayashi, Tamio; Journal of the American Chemical Society 137 (2015) 3201–3204; doi:10.1021/jacs.5b00216

data_4129292
_publ_section_title
;
 Rhodium-catalyzed asymmetric arylation of allyl sulfones under the
 conditions of isomerization into alkenyl sulfones.
;
_journal_issue                   9
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3201
_journal_page_last               3204
_journal_paper_doi               10.1021/jacs.5b00216
_journal_volume                  137
_journal_year                    2015
_chemical_formula_sum            'C10 H11 Br O2 S'
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; 
 Flack x determined using 1075 quotients [(I+)-(I-)]/[(I+)+(I-)] 
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259). 
;
_refine_ls_abs_structure_Flack   0.016(4)
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'w=1/[\s^2^(Fo^2^)+(0.0577P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_data_source_file            ja5b00216_si_001.cif
_cod_data_source_block           E384
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_exptl_crystal_density_meas' value 'Not Measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               4129292
_shelx_estimated_absorpt_t_min   0.312
_shelx_estimated_absorpt_t_max   0.533
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