Mechanism of Preferential Enrichment, an Unusual Enantiomeric Resolution Phenomenon Caused by Polymorphic Transition during Crystallization of Mixed Crystals Composed of Two Enantiomers
Rui Tamura; Daisuke Fujimoto; Zsolt Lepp; Kentaro Misaki; Hideyuki Miura; Hiroki Takahashi; Takanori Ushio; Tadashi Nakai; Ken Hirotsu; Journal of the American Chemical Society 124 (2002) 13139–13153; doi:10.1021/ja020454r

data_4115237
_publ_section_title
;
 Mechanism of Preferential Enrichment, an Unusual Enantiomeric Resolution
 Phenomenon Caused by Polymorphic Transition during Crystallization of
 Mixed Crystals Composed of Two Enantiomers
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13139
_journal_page_last               13153
_journal_paper_doi               10.1021/ja020454r
_journal_volume                  124
_journal_year                    2002
_chemical_formula_moiety         'C24 H35 N3 O9 S '
_chemical_formula_sum            'C24 H35 N3 O9 S'
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_symmetry_cell_setting           triclinic
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                100.57(2)
_cell_angle_beta                 103.63(1)
_cell_angle_gamma                80.88(1)
_cell_formula_units_Z            2
_cell_length_a                   9.337(2)
_cell_length_b                   16.2932(7)
_cell_length_c                   9.338(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.1
_cell_measurement_theta_max      42.3
_cell_measurement_theta_min      15.1
_cell_volume                     1347.2(5)
_computing_cell_refinement       UNKNOWN
_computing_data_collection       UNKNOWN
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 2.00'
_computing_structure_refinement  CRYSTALS
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_diffrn_measured_fraction_theta_max 0.8237
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_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Cu K\a'
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_diffrn_reflns_limit_k_min       -19
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_exptl_absorpt_correction_type
;
\y scans (North,Phillips & Matthews, 1968)
;
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
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_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.07
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_refine_diff_density_min         -0.34
_refine_ls_extinction_method     none
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[0.005Fo^2^ + 1.000\s^2^(Fo)]'
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_cod_data_source_block           '_NNMe3OPr'
_cod_original_cell_volume        1347.2(4)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C24 H35 N3 O9 S '
_cod_database_code               4115237