Modulation of properties in analogues of Zeise's anion on changing the ligand trans to ethene. X-Ray crystal structures of trans-[PtCl(2)(OH)(η(2)-C(2)H(4))](-) and trans-[PtCl(2)(η(1)-CH(2)NO(2))(η(2)-C(2)H(4))](-).
Benedetti, Michele; Barone, Carmen R.; Antonucci, Daniela; Vecchio, Vita M.; Ienco, Andrea; Maresca, Luciana; Natile, Giovanni; Fanizzi, Francesco P.; Dalton transactions (Cambridge, England : 2003) 41 (2012) 3014–3021; doi:10.1039/c2dt11934j

data_7018202
_publ_section_title
;
 Modulation of properties in analogues of Zeise's anion on changing the
 ligand trans to ethene. X-Ray crystal structures of
 trans-[PtCl(2)(OH)(\h(2)-C(2)H(4))](-) and
 trans-[PtCl(2)(\h(1)-CH(2)NO(2))(\h(2)-C(2)H(4))](-).
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3014
_journal_page_last               3021
_journal_paper_doi               10.1039/c2dt11934j
_journal_volume                  41
_journal_year                    2012
_chemical_absolute_configuration unk
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C24 H20 P, C3 H6 Cl2 N O2 Pt'
_chemical_formula_sum            'C27 H26 Cl2 N O2 P Pt'
_chemical_formula_weight         693.45
_chemical_name_systematic
;
?
;
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      9
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2011-03-03T14:30:57-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 91.915(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   17.8100(4)
_cell_length_b                   7.41700(10)
_cell_length_c                   19.2250(6)
_cell_measurement_reflns_used    5617
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      29.158
_cell_measurement_theta_min      4.3208
_cell_measurement_wavelength     0.71073
_cell_volume                     2538.14(10)
_computing_cell_refinement
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.41 (release 13-09-2010 CrysAlis171 .NET)
(compiled Sep 13 2010,14:28:38)
;
_computing_data_collection
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.41 (release 13-09-2010 CrysAlis171 .NET)
(compiled Sep 13 2010,14:28:38)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.41 (release 13-09-2010 CrysAlis171 .NET)
(compiled Sep 13 2010,14:28:38)
;
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 16.4547
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.867
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_measurement_method       '\w scans'
_diffrn_orient_matrix_UB_11      -0.003497
_diffrn_orient_matrix_UB_12      0.0215259
_diffrn_orient_matrix_UB_13      -0.0359248
_diffrn_orient_matrix_UB_21      -0.0072502
_diffrn_orient_matrix_UB_22      0.0912577
_diffrn_orient_matrix_UB_23      0.0085405
_diffrn_orient_matrix_UB_31      0.0390134
_diffrn_orient_matrix_UB_32      0.0188587
_diffrn_orient_matrix_UB_33      -0.0003704
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0345
_diffrn_reflns_av_unetI/netI     0.053
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            9451
_diffrn_reflns_theta_full        25.25
_diffrn_reflns_theta_max         29.22
_diffrn_reflns_theta_min         4.33
_exptl_absorpt_coefficient_mu    5.827
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.49531
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.41 (release 13-09-2010 CrysAlis171 .NET)
(compiled Sep 13 2010,14:28:38)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.815
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       cubic
_exptl_crystal_F_000             1352
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.1
_refine_diff_density_max         1.401
_refine_diff_density_min         -1.209
_refine_diff_density_rms         0.123
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.569(9)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     308
_refine_ls_number_reflns         4760
_refine_ls_number_restraints     26
_refine_ls_restrained_S_all      1.021
_refine_ls_R_factor_all          0.0382
_refine_ls_R_factor_gt           0.0339
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0335P)^2^+0.6461P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0735
_refine_ls_wR_factor_ref         0.077
_reflns_number_gt                4405
_reflns_number_total             4760
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt11934j.txt
_cod_data_source_block           c3
_cod_original_sg_symbol_H-M      'C c'
_cod_database_code               7018202