Dinuclear ruthenium complexes containing the hpbl ligand: synthesis, characterization, linkage isomerism, and epoxidation catalysis.
Francàs, Laia; González-Gil, Rosa María; Moyano, Daniel; Benet-Buchholz, Jordi; García-Antón, Jordi; Escriche, Lluís; Llobet, Antoni; Sala, Xavier; Inorganic chemistry 53 (2014) 10394–10402; doi:10.1021/ic501483s

data_4341153
_publ_section_title
;
 Dinuclear ruthenium complexes containing the hpbl ligand: synthesis,
 characterization, linkage isomerism, and epoxidation catalysis.
;
_journal_issue                   19
_journal_name_full               'Inorganic chemistry'
_journal_page_first              10394
_journal_page_last               10402
_journal_paper_doi               10.1021/ic501483s
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C48 H44 Cl2 F12 N10 O4.5 P2 Ru2'
_chemical_formula_weight         1395.91
_chemical_name_systematic
;
 ?
;
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_atom_sites_solution_hydrogens   mixed
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_diffrn_detector_area_resol_mean 512
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_diffrn_measurement_method
;
 Fullsphere data collection, phi and omega scans
;
_diffrn_measurement_specimen_support 'magnetic support with MicroMount'
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; 
 SADABS Version 2008/1 Bruker-Nonius
 Blessing, Acta Cryst. (1995) A51 33-38
;
_exptl_crystal_colour            red
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0913P)^2^+5.1446P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                8053
_reflns_number_total             11330
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic501483s_si_002.cif
_cod_data_source_block           LFF3408b_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4341153--4341154.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C48 H44 Cl2 F12 N10 O4.50 P2 Ru2'
_cod_database_code               4341153
_shelx_estimated_absorpt_t_min   0.858
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_shelxl_version_number           2014-3
_shelx_res_checksum              28751
_shelx_hkl_checksum              81716