Access to Isoquinolines and Isoquinolin-3-ols via Rh(III)-Catalyzed Coupling/Cyclization Cascade Reaction of Arylimidates and Diazo Compounds.
Li, Xing Guang; Sun, Min; Jin, Qiao; Liu, Kai; Liu, Pei Nian; The Journal of organic chemistry 81 (2016) 3901–3910; doi:10.1021/acs.joc.6b00264

data_4036672
_publ_section_title
;
 Access to Isoquinolines and Isoquinolin-3-ols via Rh(III)-Catalyzed
 Coupling/Cyclization Cascade Reaction of Arylimidates and Diazo
 Compounds.
;
_journal_issue                   9
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              3901
_journal_page_last               3910
_journal_paper_doi               10.1021/acs.joc.6b00264
_journal_volume                  81
_journal_year                    2016
_chemical_formula_sum            'C24 H21 N O3'
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_space_group_name_Hall           '-P 2ybc'
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_cell_length_c                   7.5849(12)
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_cell_measurement_theta_min      5.178
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_diffrn_measured_fraction_theta_max 1.000
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_diffrn_reflns_point_group_measured_fraction_max 1.000
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_exptl_absorpt_correction_T_min  0.5835
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
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_refine_ls_extinction_coef       0.0058(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.059
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_refine_ls_matrix_type           full
_refine_ls_number_parameters     256
_refine_ls_number_reflns         3502
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0684
_refine_ls_R_factor_gt           0.0510
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0352P)^2^+1.6184P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1069
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_reflns_number_total             3502
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           dm15289
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4036672
_shelxl_version_number           2013-4
_shelx_res_checksum              13388
_shelx_hkl_checksum              3696