Insight into Technetium Amidoxime Complex: Oxo Technetium(V) Complex of N-Substituted Benzamidoxime as New Basic Structure for Molecular Imaging
Khajadpai Thipyapong; Tomoya Uehara; Yuji Tooyama; Henrik Braband; Roger Alberto; Yasushi Arano; Inorganic Chemistry 50 (2011) 992–998; doi:10.1021/ic101714q

data_4324346
_publ_section_title
;
 Insight into Technetium Amidoxime Complex: Oxo Technetium(V) Complex of
 N-Substituted Benzamidoxime as New Basic Structure for Molecular Imaging
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              992
_journal_page_last               998
_journal_paper_doi               10.1021/ic101714q
_journal_volume                  50
_journal_year                    2011
_chemical_formula_sum            'C16 H15 F N4 O3 Tc'
_chemical_formula_weight         428.32
_chemical_name_systematic
; 
 ? 
;
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_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
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_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
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_cell_length_a                   13.4823(5)
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
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_diffrn_ambient_temperature      183(2)
_diffrn_measured_fraction_theta_full 0.999
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_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0467
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_diffrn_reflns_limit_h_min       -15
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_diffrn_reflns_limit_k_min       -18
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_diffrn_reflns_theta_max         26.37
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         3173
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1101P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
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d:\aci\tooyama\yt030210\pna21\gral_yt030210\yt030210
_cod_original_cell_volume        1632.39(11)
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