Hydrophosphination-type reactivity promoted by bismuth phosphanides: scope and limitations.
Schwamm, R. J.; Fulton, J. R.; Coles, M. P.; Fitchett, C. M.; Dalton transactions (Cambridge, England : 2003) 46 (2017) 2068–2071; doi:10.1039/c7dt00226b

data_7041871
_publ_section_title
;
 Hydrophosphination-type reactivity promoted by bismuth phosphanides:
 scope and limitations.
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2068
_journal_page_last               2071
_journal_paper_doi               10.1039/c7dt00226b
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C19 H28 N O P'
_chemical_formula_sum            'C19 H28 N O P'
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2016-01-12 deposited with the CCDC.
2017-01-27 downloaded from the CCDC.
;
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_cell_measurement_temperature    120.01(10)
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_computing_cell_refinement
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        CrysAlisPro, Agilent Technologies,
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        (compiled Feb  9 2015,16:26:32)
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_computing_molecular_graphics    'Ortep for Windows (Farrugia, 2012)'
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_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, EosS2'
_diffrn_measurement_method       '\w scans'
_diffrn_orient_matrix_UB_11      -0.0473936
_diffrn_orient_matrix_UB_12      -0.0320461
_diffrn_orient_matrix_UB_13      0.0316348
_diffrn_orient_matrix_UB_21      0.0223386
_diffrn_orient_matrix_UB_22      -0.0759056
_diffrn_orient_matrix_UB_23      -0.0128454
_diffrn_orient_matrix_UB_31      0.109378
_diffrn_orient_matrix_UB_32      0.0016199
_diffrn_orient_matrix_UB_33      0.0240202
_diffrn_radiation_monochromator  mirror
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_diffrn_reflns_av_unetI/netI     0.0373
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_diffrn_reflns_point_group_measured_fraction_full 1
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.37.35h (release 09-02-2015 CrysAlis171 .NET)
        (compiled Feb  9 2015,16:26:32)
Numerical absorption correction based on gaussian integration over
                        a multifaceted crystal model
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_density_diffrn    1.186
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3440
_exptl_crystal_size_max          0.3716
_exptl_crystal_size_mid          0.097
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_refine_ls_number_constraints    0
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_refine_ls_number_reflns         17290
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_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.0542
_refine_ls_R_factor_gt           0.0504
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1010P)^2^+3.2862P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1399
_refine_ls_wR_factor_ref         0.1454
_reflns_number_gt                15724
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c7dt00226b2.cif
_cod_data_source_block           Compound-7-RJS04-191
_cod_depositor_comments
'Adding full bibliography for 7041870--7041871.cif.'
_cod_original_cell_volume        8886.72(8)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7041871