Reaction of a germylene, stannylene, or plumbylene with trimethylaluminum and trimethylgallium: insertion into Al-C or ga-C bonds, a reversible metal-carbon insertion equilibrium, and a new route to diplumbenes.
Erickson, Jeremy D.; Fettinger, James C.; Power, Philip P.; Inorganic chemistry 54 (2015) 1940–1948; doi:10.1021/ic502824w

data_4342304
_publ_section_title
;
 Reaction of a germylene, stannylene, or plumbylene with trimethylaluminum
 and trimethylgallium: insertion into Al-C or ga-C bonds, a reversible
 metal-carbon insertion equilibrium, and a new route to diplumbenes.
;
_journal_issue                   4
_journal_name_full               'Inorganic chemistry'
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_journal_paper_doi               10.1021/ic502824w
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'C51 H59 Al Ge'
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Olex2 1.2
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'w=1/[\s^2^(Fo^2^)+(0.0286P)^2^+2.5993P] where P=(Fo^2^+2Fc^2^)/3'
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;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 4342304--4342310.cif.
;
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1. Others
 Fixed Sof: H16A(0.56) H16B(0.56) H16C(0.56) H16D(0.44) H16E(0.44) H16F(0.44)
 H51A(0.56) H51B(0.56) H51C(0.56) H51D(0.44) H51E(0.44) H51F(0.44)
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