(Thio)(silyl)carbene and (seleno)(silyl)carbene gold(i) complexes from the reaction of bis(methylene)-λ<sup>4</sup>-sulfane and bis(methylene)-λ<sup>4</sup>-selane with chloro(dimethylsulfide)gold(i).
Sugamata, Koh; Urao, Yukiko; Minoura, Mao; Dalton transactions (Cambridge, England : 2003) 49 (2020) 7688–7691; doi:10.1039/d0dt00967a

data_7704521
_publ_section_title
;
 (Thio)(silyl)carbene and (seleno)(silyl)carbene gold(i) complexes from
 the reaction of bis(methylene)-\l<sup>4</sup>-sulfane and
 bis(methylene)-\l<sup>4</sup>-selane with chloro(dimethylsulfide)gold(i).
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7688
_journal_page_last               7691
_journal_paper_doi               10.1039/d0dt00967a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C43 H45 Au2 Cl S Se Si3'
_chemical_formula_sum            'C43 H45 Au2 Cl S Se Si3'
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;
2020-02-21 deposited with the CCDC.	2020-05-27 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type
'esperanto-CrysAlisPro-abstract goniometer imported esperanto images'
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_diffrn_reflns_limit_h_min       -13
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_diffrn_reflns_point_group_measured_fraction_full 0.996
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_exptl_absorpt_correction_T_max  1.00000
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.67a (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.875
_exptl_crystal_description       prism
_exptl_crystal_F_000             1140
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0196
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0387P)^2^+0.7463P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0547
_refine_ls_wR_factor_ref         0.0550
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9224
_reflns_number_total             9612
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt00967a3.cif
_cod_data_source_block           CSeCAu
_cod_depositor_comments
'Adding full bibliography for 7704520--7704521.cif.'
_cod_original_cell_volume        2101.99(8)
_cod_database_code               7704521
_shelx_shelxl_version_number     2018/1
_shelx_estimated_absorpt_t_min   0.981
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_shelx_res_checksum              90473