Azido- and amido-substituted gallium hydrides supported by N-heterocyclic carbenes.
Swarnakar, Anindya K.; Ferguson, Michael J.; McDonald, Robert; Rivard, Eric; Dalton transactions (Cambridge, England : 2003) 46 (2017) 1406–1412; doi:10.1039/c6dt04595b

data_1544974
_publ_section_title
;
 Azido- and amido-substituted gallium hydrides supported by N-heterocyclic
 carbenes.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1406
_journal_page_last               1412
_journal_paper_doi               10.1039/c6dt04595b
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C27 H43.85 Cl0.15 Ga N3 Si2'
_chemical_formula_sum            'C27 H43.85 Cl0.15 Ga N3 Si2'
_chemical_formula_weight         541.72
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-11-28 deposited with the CCDC.
2017-01-02 downloaded from the CCDC.
;
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_computing_structure_solution    'SHELXT-2014 (Sheldrick 2015)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.967
_diffrn_measured_fraction_theta_max 0.959
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           CuK\a
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_exptl_absorpt_correction_T_max  0.5707
_exptl_absorpt_correction_T_min  0.3806
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_exptl_absorpt_process_details   'SADABS 2014/5'
_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0417P)^2^+0.7628P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.0828
_reflns_Friedel_coverage         0.000
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_reflns_number_total             5997
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           riv16g0_IMesGaH2NTMS2_cmpd_3
_cod_depositor_comments
'Adding full bibliography for 1544973--1544977.cif.'
_cod_database_code               1544974
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