Intermediates and Reactivity in Iron-Catalyzed Cross-Couplings of Alkynyl Grignards with Alkyl Halides.
Kneebone, Jared L.; Brennessel, William W.; Neidig, Michael L.; Journal of the American Chemical Society 139 (2017) 6988–7003; doi:10.1021/jacs.7b02363

data_4126130
_publ_section_title
;
 Intermediates and Reactivity in Iron-Catalyzed Cross-Couplings of Alkynyl
 Grignards with Alkyl Halides.
;
_journal_issue                   20
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              6988
_journal_page_last               7003
_journal_paper_doi               10.1021/jacs.7b02363
_journal_volume                  139
_journal_year                    2017
_chemical_formula_moiety         'C95 H151 Br Fe Mg N2 P2 Si3'
_chemical_formula_sum            'C95 H151 Br Fe Mg N2 P2 Si3'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_diffrn_ambient_temperature      100.0(5)
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'w=1/[\s^2^(Fo^2^)+(0.0291P)^2^+24.7457P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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