Ruthenaphosphaalkenyls: Synthesis, Structures, and Their Conversion to η2-Phosphaalkene Complexes
Greenacre, Victoria K.; Trathen, Nicola; Crossley, Ian R.; Organometallics 34 (2015) 2533–; doi:10.1021/om5012177

data_4085713
_publ_section_title
;
 Ruthenaphosphaalkenyls: Synthesis, Structures, and Their Conversion to
 \h2-Phosphaalkene Complexes
;
_journal_issue                   11
_journal_name_full               Organometallics
_journal_page_first              2533
_journal_paper_doi               10.1021/om5012177
_journal_volume                  34
_journal_year                    2015
_chemical_formula_moiety         'C46 H42 Cl O P3 Ru Si'
_chemical_formula_sum            'C46 H42 Cl O P3 Ru Si'
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_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
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Olex2 1.2
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
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  1 omega  -17.00   92.00   1.0000    1.2500
omega____ theta____ kappa____ phi______ frames
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  2 omega  -16.00   89.00   1.0000    1.2500
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  4 omega   34.00  124.00   1.0000    1.2500
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  5 omega  -17.00   92.00   1.0000    1.2500
omega____ theta____ kappa____ phi______ frames
    -       55.0000  -90.0000 -177.5090 109

  6 omega   29.00  127.00   1.0000    1.2500
omega____ theta____ kappa____ phi______ frames
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  7 omega   40.00   83.00   1.0000    5.5000
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  8 omega   38.00   71.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
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  9 omega   38.00  147.00   1.0000    5.5000
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 10 omega   37.00   72.00   1.0000    5.5000
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 11 omega   37.00   72.00   1.0000    5.5000
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 12 omega   38.00  147.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
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 13 omega   38.00   71.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
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 14 omega   37.00   72.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
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 15 omega   38.00   71.00   1.0000    5.5000
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 16 omega   38.00   71.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -38.0000  -60.0000 33

 17 omega   37.00  178.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
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 18 omega   38.00   71.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
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 19 omega   88.00  172.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
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 20 omega   47.00   80.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
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 21 omega   46.00   79.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
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 22 omega   53.00  134.00   1.0000    5.5000
omega____ theta____ kappa____ phi______ frames
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;
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CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            'clear orange'
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'w=1/[\s^2^(Fo^2^)+(0.0425P)^2^+0.5802P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 4085712--4085714.cif.'
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_cod_database_code               4085713
_chemical_oxdiff_formula         C30H100Cl1Si2U1
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_reflns_odcompleteness_iscentric 1
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_olex2_refinement_description
;
;
_olex2_submission_special_instructions 'No special instructions were received'