Synthesis of Functionalized Thieno[2,3-<i>b</i>]indoles via One-Pot Reaction of Indoline-2-thiones with Morita-Baylis-Hillman and Rauhut-Currier Adducts of Nitroalkenes.
Mane, Vaijinath; Baiju, Thekke V.; Namboothiri, Irishi N. N.; ACS omega 3 (2018) 17617–17628; doi:10.1021/acsomega.8b02147

data_4516154
_publ_section_title
;
 Synthesis of Functionalized Thieno[2,3-<i>b</i>]indoles via One-Pot
 Reaction of Indoline-2-thiones with Morita-Baylis-Hillman and
 Rauhut-Currier Adducts of Nitroalkenes.
;
_journal_issue                   12
_journal_name_full               'ACS omega'
_journal_page_first              17617
_journal_page_last               17628
_journal_paper_doi               10.1021/acsomega.8b02147
_journal_volume                  3
_journal_year                    2018
_chemical_formula_moiety         'C26 H31 N3 O4 S'
_chemical_formula_sum            'C26 H32 N3 O4 S'
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Olex2 1.2-alpha
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AFC12 (Right): Kappa 3 circle
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'w=1/[\s^2^(Fo^2^)+(0.0419P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C9(H9), C10(H10), C6(H6), C2(H2)
2.b Aromatic/amide H refined with riding coordinates:
 N1(H1), C20(H20), C12(H12), C17(H17), C16(H16), C13(H13), C23(H23), C22(H22),
 C21(H21)
2.c Idealised Me refined as rotating group:
 C25(H25A,H25B,H25C), C15(H15A,H15B,H15C), C8(H8A,H8B,H8C), C7(H7A,H7B,H7C),
 C1(H1A,H1B,H1C), C3(H3A,H3B,H3C)
;
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_olex2_submission_special_instructions 'No special instructions were received'