<i>catena</i>-Poly[[(1,10-phenanthroline-κ^2^<i>N</i>,<i>N</i>')lead(II)]-μ-azido-κ^2^<i>N</i>^1^:<i>N</i>^3^-μ-nitrito-κ^3^<i>O</i>,<i>O</i>':<i>O</i>'-[(1,10-phenanthroline-κ^2^<i>N</i>,<i>N</i>')lead(II)]-di-μ-azido-κ^4^<i>N</i>^1^:<i>N</i>^1^]
Mohammadnezhad, Gholamhossein; Ghanbarpour, Ali Reza; Amini, Mostafa M.; Ng, Seik Weng; Acta Crystallographica Section E 66 (2010) m821–; doi:10.1107/S1600536810022907

data_2226735
_publ_section_title
;
 <i>catena</i>-Poly[[(1,10-phenanthroline-\k^2^<i>N</i>,<i>N</i>')lead(II)]-\m-azido-\k^2^<i>N</i>^1^:<i>N</i>^3^-\m-nitrito-\k^3^<i>O</i>,<i>O</i>':<i>O</i>'-[(1,10-phenanthroline-\k^2^<i>N</i>,<i>N</i>')lead(II)]-di-\m-azido-\k^4^<i>N</i>^1^:<i>N</i>^1^]
;
_journal_coeditor_code           XU2775
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m821
_journal_paper_doi               10.1107/S1600536810022907
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Pb2 (N3)3 (N O2) (C12 H8 N2)2]'
_chemical_formula_moiety         'C24 H16 N14 O2 Pb2'
_chemical_formula_sum            'C24 H16 N14 O2 Pb2'
_chemical_formula_weight         946.89
_chemical_name_systematic
;
<i>catena</i>-Poly[[(1,10-phenanthroline-\k<i>N</i>,<i>N</i>')lead(II)]-\m-
azido-\k^2^<i>N</i>^1^:<i>N</i>^3^-\m-nitrito-
\k^3^<i>O</i>,<i>O</i>':<i>O</i>'-[(1,10-phenanthroline-
\k<i>N</i>,<i>N</i>')lead(II)]-di-\m-azido-\k^4^<i>N</i>^1^:<i>N</i>^1^]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.5410(10)
_cell_angle_beta                 109.6650(10)
_cell_angle_gamma                104.6260(10)
_cell_formula_units_Z            1
_cell_length_a                   7.6860(5)
_cell_length_b                   9.2056(6)
_cell_length_c                   9.9080(7)
_cell_measurement_reflns_used    4831
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.3
_cell_measurement_theta_min      2.3
_cell_volume                     635.32(7)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'APEX2 (Bruker, 2009)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics    'X-SEED (Barbour, 2001)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker SMART APEX diffractometer'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0331
_diffrn_reflns_av_sigmaI/netI    0.0490
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            6004
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.19
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    13.289
_exptl_absorpt_correction_T_max  0.109
_exptl_absorpt_correction_T_min  0.040
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    2.475
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Irregular
_exptl_crystal_F_000             438
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.30
_refine_diff_density_max         2.167
_refine_diff_density_min         -1.968
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     193
_refine_ls_number_reflns         2888
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0303
_refine_ls_R_factor_gt           0.0276
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0348P)^2^+1.3333P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0694
_refine_ls_wR_factor_ref         0.0706
_reflns_number_gt                2716
_reflns_number_total             2888
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            xu2775.cif
_cod_data_source_block           I
_cod_database_code               2226735
_cod_database_fobs_code          2226735