Coordination Chemistry of Silanedithiolato Ligands Derived from Cyclotrisilathiane: Synthesis and Structures of Complexes of Iron(II), Cobalt(II), Palladium(II), Copper(I), and Silver(I)
Takashi Komuro; Tsukasa Matsuo; Hiroyuki Kawaguchi; Kazuyuki Tatsumi; Inorganic Chemistry 42 (2003) 5340–5347; doi:10.1021/ic0343253

data_4314089
_publ_section_title
;
 Coordination Chemistry of Silanedithiolato Ligands Derived from
 Cyclotrisilathiane: Synthesis and Structures of Complexes of Iron(II),
 Cobalt(II), Palladium(II), Copper(I), and Silver(I)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5340
_journal_page_last               5347
_journal_paper_doi               10.1021/ic0343253
_journal_volume                  42
_journal_year                    2003
_chemical_formula_moiety         'C22 H57 Ag2 P3 S3 Si2 '
_chemical_formula_sum            'C22 H57 Ag2 P3 S3 Si2'
_chemical_formula_weight         782.70
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      4
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90
_cell_angle_beta                 106.969(6)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.188(3)
_cell_length_b                   11.726(4)
_cell_length_c                   16.051(5)
_cell_measurement_reflns_used    5922
_cell_measurement_temperature    173.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.2
_cell_volume                     1834.0(10)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 3.10'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 28.57
_diffrn_measured_fraction_theta_full 0.9749
_diffrn_measured_fraction_theta_max 0.9762
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.041
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            14295
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    1.442
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.417
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             748.00
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.07
_refine_diff_density_max         2.16
_refine_diff_density_min         -2.40
_refine_ls_abs_structure_details
'Flack, H. D. (1983), Acta Cryst. A39, 876-881.  0 Friedel Pairs'
_refine_ls_abs_structure_Flack   0.00(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     295
_refine_ls_number_reflns         14281
_refine_ls_R_factor_gt           0.0420
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0000Fo^2^ + 1.2000\s^2^(Fo) + 0.0000]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0970
_reflns_number_gt                10906
_reflns_number_total             4310
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic0343253si20030617_084419_4.cif
_cod_data_source_block           Ag2S3(SiMe2)2(PEt3)3
_cod_original_cell_volume        1834.2(10)
_cod_original_formula_sum        'C22 H57 Ag2 P3 S3 Si2 '
_cod_database_code               4314089