Photosensitization via Dye Coordination: A New Strategy to Synthesize Metal Nitrosyls That Release NO under Visible Light
Michael J. Rose; Marilyn M. Olmstead; Pradip K. Mascharak; Journal of the American Chemical Society 129 (2007) 5342–5343; doi:10.1021/ja070247x

data_4109353
_publ_section_title
;
 Photosensitization via Dye Coordination: A New Strategy to Synthesize
 Metal Nitrosyls That Release NO under Visible Light
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5342
_journal_page_last               5343
_journal_paper_doi               10.1021/ja070247x
_journal_volume                  129
_journal_year                    2007
_chemical_formula_moiety         'C20 H17 N5 O4 Ru, C2 H6 O S'
_chemical_formula_sum            'C22 H23 N5 O5 Ru S'
_chemical_formula_weight         570.58
_chemical_name_common            '[Ru(Me~2~bpb)(NO)(OH)]^.^DMSO'
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                75.430(3)
_cell_angle_beta                 75.300(3)
_cell_angle_gamma                89.954(3)
_cell_formula_units_Z            2
_cell_length_a                   9.6421(4)
_cell_length_b                   10.2603(4)
_cell_length_c                   12.2844(5)
_cell_measurement_reflns_used    6693
_cell_measurement_temperature    90(2)
_cell_measurement_theta_max      31.5
_cell_measurement_theta_min      3.0
_cell_volume                     1135.14(8)
_computing_cell_refinement       'SAINT v. 7.23a (Bruker, 2006)'
_computing_data_collection       'Apex2 v. 2.02 (Bruker, 2006)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL, XP (Sheldrick, 1994)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      90(2)
_diffrn_detector_area_resol_mean 8.3
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker Apex2'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0184
_diffrn_reflns_av_sigmaI/netI    0.0190
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            14663
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.90
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.828
_exptl_absorpt_correction_T_max  0.9292
_exptl_absorpt_correction_T_min  0.8388
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2.10 (Sheldrick, 2003)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.669
_exptl_crystal_description       parallelepiped
_exptl_crystal_F_000             580
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.09
_refine_diff_density_max         0.490
_refine_diff_density_min         -0.496
_refine_diff_density_rms         0.063
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     315
_refine_ls_number_reflns         5198
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.054
_refine_ls_R_factor_all          0.0213
_refine_ls_R_factor_gt           0.0199
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0253P)^2^+0.8666P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0522
_refine_ls_wR_factor_ref         0.0532
_reflns_number_gt                4949
_reflns_number_total             5198
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            ja070247xsi20070122_055450.cif
_cod_data_source_block           mn1809
_cod_database_code               4109353