Synthesis and catalytic activity of heterobimetallic Au/M (M = Rh<sup>III</sup>, Ir<sup>III</sup>) complexes with ditopic mono- and triphosphane ligands.
Predarska, Ivana; Körber, Wieland; Lönnecke, Peter; Gelman, Dmitri; Hey-Hawkins, Evamarie; Dalton transactions (Cambridge, England : 2003) 53 (2024) 16159–16169; doi:10.1039/d4dt01247j

data_7716467
_publ_section_title
;
 Synthesis and catalytic activity of heterobimetallic Au/M (M =
 Rh<sup>III</sup>, Ir<sup>III</sup>) complexes with ditopic mono- and
 triphosphane ligands.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              16159
_journal_page_last               16169
_journal_paper_doi               10.1039/d4dt01247j
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         'C27 H36 Cl N P Rh'
_chemical_formula_sum            'C27 H36 Cl N P Rh'
_chemical_formula_weight         543.90
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_space_group_name_Hall           '-P 2yn'
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_audit_update_record
;
2023-12-31 deposited with the CCDC.	2024-06-24 downloaded from the CCDC.
;
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_computing_data_collection       'CrysAlisPro 1.171.42.92a (Rigaku OD, 2023)'
_computing_data_reduction        'CrysAlisPro 1.171.42.92a (Rigaku OD, 2023)'
_computing_molecular_graphics
;
 ORTEP3 for Windows
 L. J. Farrugia, J. Appl. Crystallogr. 1997, 30, 565.
 or
 DIAMOND Version 4.6.8
 K. Brandenburg, Crystal Impact GbR, Bonn, Germany
;
_computing_publication_material
;
 WINGX
 L.J. Farrugia,
 J. Appl. Cryst., 2012, 45, 849-854.
;
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_diffrn_reflns_av_unetI/netI     0.0231
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.92a (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear orange'
_exptl_crystal_density_diffrn    1.410
_exptl_crystal_description       prism
_exptl_crystal_F_000             1128
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_refine_ls_matrix_type           full
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_refine_ls_restrained_S_all      1.111
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_gt           0.0298
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0196P)^2^+1.9676P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0610
_refine_ls_wR_factor_ref         0.0630
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7679
_reflns_number_total             8446
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4dt01247j2.cif
_cod_data_source_block           comp3_x2945fin
_cod_depositor_comments
'Adding full bibliography for 7716464--7716472.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7716467
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              48666
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