Thermal dehydrochlorination in the 4-fluoroaniline-trichloroborane system: identification of reactive intermediates involved in the formation of B,B',B''-trichloro-N,N',N''-tri((4-fluoro)phenyl)borazine.
Hahn, Jennifer; Krieg, Matthias; Keck, Constanze; Maichle-Mössmer, Cäcilia; Fink, Reinhold F.; Bettinger, Holger F.; Dalton transactions (Cambridge, England : 2003) 47 (2018) 17304–17316; doi:10.1039/c8dt03954b

data_7048249
_publ_section_title
;
 Thermal dehydrochlorination in the 4-fluoroaniline-trichloroborane
 system: identification of reactive intermediates involved in the
 formation of B,B',B''-trichloro-N,N',N''-tri((4-fluoro)phenyl)borazine.
;
_journal_issue                   48
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_page_last               17316
_journal_paper_doi               10.1039/c8dt03954b
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C18 H12 B3 Cl3 F3 N3'
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_chemical_properties_physical    ', Air-sensitive,Moisture-sensitive'
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_audit_update_record
;
2017-03-02 deposited with the CCDC.
2018-11-05 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      100(2)
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0484P)^2^+3.7900P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7048248--7048250.cif.'
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