Synthesis and thermal properties of the heterometallic nickel–ruthenium complex: a potential precursor for catalytically active nanosized Ni–Ru alloy
Filatov, E. Yu; Borodin, A. O.; Kuratieva, N. V.; Plusnin, P. E.; Urlukov, A. S.; Potemkin, D. I.; Korenev, S. V.; Kostin, G. A.; New Journal of Chemistry 46 (2022) 19009–19017; doi:10.1039/D2NJ03402F

data_7061941
_publ_section_title
;
 Synthesis and thermal properties of the heterometallic nickel--ruthenium
 complex: a potential precursor for catalytically active nanosized Ni--Ru
 alloy
;
_journal_issue                   39
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              19009
_journal_page_last               19017
_journal_paper_doi               10.1039/D2NJ03402F
_journal_volume                  46
_journal_year                    2022
_chemical_formula_moiety         'C4 H17 N9 Ni O10 Ru'
_chemical_formula_sum            'C4 H17 N9 Ni O10 Ru'
_chemical_formula_weight         511.04
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2022-09-12 deposited with the CCDC.	2022-09-14 downloaded from the CCDC.
;
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_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.42
_cell_volume                     1669.87(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 25
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_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Bruker Nonius X8Apex CCD area-detector'
_diffrn_measurement_method       '\f scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       8
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_diffrn_reflns_limit_l_min       -22
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_diffrn_standards_decay_%        0
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_exptl_crystal_colour            orange
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_exptl_crystal_description       prism
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_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0476
_refine_ls_R_factor_gt           0.0341
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0263P)^2^+0.3832P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0693
_refine_ls_wR_factor_ref         0.0735
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6232
_reflns_number_total             7684
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            d2nj03402f2.cif
_cod_data_source_block           bor538
_cod_depositor_comments          'Adding full bibliography for 7061941.cif.'
_cod_database_code               7061941
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.730
_shelx_estimated_absorpt_t_max   0.867
_shelx_res_checksum              20005