Bis(pentalene)dititanium chemistry: C-H, C-X and H-H bond activation.
Tsoureas, Nikolaos; Green, Jennifer C.; Cloke, F Geoffrey N; Dalton transactions (Cambridge, England : 2003) 47 (2018) 14531–14539; doi:10.1039/c8dt02654h

data_7047566
_publ_section_title
;
 Bis(pentalene)dititanium chemistry: C-H, C-X and H-H bond activation.
;
_journal_issue                   41
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14531
_journal_page_last               14539
_journal_paper_doi               10.1039/c8dt02654h
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C65 H114 N2 Si4 Ti2'
_chemical_formula_sum            'C65 H114 N2 Si4 Ti2'
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_chemical_name_systematic        7
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Air-sensitive,Moisture-sensitive,Oxygen-sensitive
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
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;
2018-09-12 deposited with the CCDC.
2018-09-17 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini ultra'
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_diffrn_radiation_type           CuK\a
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.44a (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'intense green'
_exptl_crystal_density_diffrn    1.124
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'Re-crystallisation from solvent: n-pentane'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1439P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             11727
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           7
_cod_depositor_comments
'Adding full bibliography for 7047563--7047567.cif.'
_cod_database_code               7047566
_shelx_shelxl_version_number     2017/1
_shelx_estimated_absorpt_t_min   0.796
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_oxdiff_exptl_absorpt_empirical_full_min 0.436
_oxdiff_exptl_absorpt_empirical_full_max 5.550
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_shelx_res_checksum              71886