Grignard-mediated rearrangement of trifluoroacetyl from dihydroisoquinoline enamides to afford tertiary trifluoromethylcarbinols.
Achary, Raghavendra; Mathi, Gangadhar Rao; Kim, Seulgi; Hwang, Jong Yeon; Kim, Pilho; Organic & biomolecular chemistry 16 (2018) 1452–1456; doi:10.1039/c7ob03079g

data_7156090
_publ_section_title
;
 Grignard-mediated rearrangement of trifluoroacetyl from
 dihydroisoquinoline enamides to afford tertiary trifluoromethylcarbinols.
;
_journal_issue                   9
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              1452
_journal_page_last               1456
_journal_paper_doi               10.1039/c7ob03079g
_journal_volume                  16
_journal_year                    2018
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;
2017-02-14 deposited with the CCDC.
2018-02-05 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0516P)^2^+0.2559P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7156090--7156091.cif.
;
_cod_original_sg_symbol_H-M      P2(1)/c
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