Striking transformations of the hydroborylene ligand in a HB:\ρightarrow Ni<sup>II</sup> complex with isocyanides and CO.
Hadlington, T. J.; Szilvási, T; Driess, M.; Chemical science 9 (2018) 2595–2600; doi:10.1039/c7sc04792d

data_1548868
_publ_section_title
;
 Striking transformations of the hydroborylene ligand in a HB:\\rightarrow
 Ni<sup>II</sup> complex with isocyanides and CO.
;
_journal_issue                   9
_journal_name_full               'Chemical science'
_journal_page_first              2595
_journal_page_last               2600
_journal_paper_doi               10.1039/c7sc04792d
_journal_volume                  9
_journal_year                    2018
_chemical_formula_moiety         'C66 H105 B Cl N6 Ni O6 Si2'
_chemical_formula_sum            'C66 H105 B Cl N6 Ni O6 Si2'
_chemical_formula_weight         1239.70
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2017-10-10 deposited with the CCDC.
2018-02-05 downloaded from the CCDC.
;
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_diffrn_reflns_limit_l_min       -27
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;
CrysAlisPro 1.171.38.43c (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0883P)^2^+2.1411P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
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_reflns_number_total             12907
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           compound_2-Xyl
_cod_depositor_comments
'Adding full bibliography for 1548865--1548871.cif.'
_cod_database_code               1548868
_shelx_shelxl_version_number     2016/6
_shelx_res_checksum              64441