Five-Coordinate [Pt(II)(bipyridine)2(phosphine)](n+) Complexes: Long-Lived Intermediates in Ligand Substitution Reactions of [Pt(bipyridine)2](2+) with Phosphine Ligands.
Lo, Warrick K. C.; Cavigliasso, Germán; Stranger, Robert; Crowley, James D.; Blackman, Allan G.; Inorganic chemistry 53 (2014) 3595–; doi:10.1021/ic403089j

data_4337989
_publ_section_title
;
 Five-Coordinate [Pt(II)(bipyridine)2(phosphine)](n+) Complexes:
 Long-Lived Intermediates in Ligand Substitution Reactions of
 [Pt(bipyridine)2](2+) with Phosphine Ligands.
;
_journal_issue                   7
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3595
_journal_paper_doi               10.1021/ic403089j
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C76 H80 N8 O23 P2 Pt2 S4'
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_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 103.382(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.8665(4)
_cell_length_b                   24.5917(7)
_cell_length_c                   15.8557(7)
_cell_measurement_reflns_used    19426
_cell_measurement_temperature    100.0(2)
_cell_measurement_theta_max      29.6930
_cell_measurement_theta_min      3.2610
_cell_volume                     4501.3(3)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_collection
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
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_computing_molecular_graphics    'Bruker SHELXTL'
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_diffrn_ambient_temperature      100.0(2)
_diffrn_detector_area_resol_mean 5.1725
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  mirror
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_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0585
_diffrn_reflns_av_sigmaI/netI    0.0413
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
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_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            46506
_diffrn_reflns_theta_full        26.37
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_exptl_absorpt_coefficient_mu    3.305
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_exptl_absorpt_correction_T_min  0.561
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Numerical absorption correction based on gaussian integration over
            a multifaceted crystal model
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.515
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       triangular
_exptl_crystal_F_000             2052
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.17
_refine_diff_density_max         5.418
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_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.080
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_refine_ls_number_reflns         9184
_refine_ls_number_restraints     79
_refine_ls_restrained_S_all      1.080
_refine_ls_R_factor_all          0.1033
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1139P)^2^+66.5705P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2181
_refine_ls_wR_factor_ref         0.2358
_reflns_number_gt                7425
_reflns_number_total             9184
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            ic403089j_si_003.cif
_cod_data_source_block           wkl_ptn4p_2
_cod_depositor_comments
'Adding full bibliography for 4337989--4337990.cif.'
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4337989