Cluster Harvesting by Successive Reduction of a Metal Halide with a Nonconventional Reduction Agent: A Benefit for the Exploration of Metal-Rich Halide Systems
Markus Ströbele; Agnieszka Mos; Hans-Jürgen Meyer; Inorganic Chemistry 52 (2013) 6951–6956; doi:10.1021/ic4009366

data_4335288
_publ_contact_author
;
        H.-J\"urgen Meyer
        Institut f\"ur Anorganische Chemie
        Universit\"at T\"ubingen
        Auf der Morgenstelle 18
        72076 T\"ubingen
        Bundesrepublik Deutschland
;
_publ_contact_author_email       juergen.meyer@uni-tuebingen.de
_publ_contact_author_fax         '07071 29-5702'
_publ_contact_author_phone       '07071 29-76226'
_publ_section_title
;
 Cluster Harvesting by Successive Reduction of a Metal Halide with a
 Nonconventional Reduction Agent: A Benefit for the Exploration of
 Metal-Rich Halide Systems
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6951
_journal_page_last               6956
_journal_paper_doi               10.1021/ic4009366
_journal_volume                  52
_journal_year                    2013
_chemical_formula_moiety         Fe2W2Cl10
_chemical_formula_sum            'Cl10 Fe2 W2'
_chemical_formula_weight         833.924
_chemical_name_systematic        ' ?'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_creation_method           'FullProf Suite'
_cell_angle_alpha                90.00000
_cell_angle_beta                 109.713(4)
_cell_angle_gamma                90.00000
_cell_formula_units_Z            4
_cell_length_a                   6.2486(4)
_cell_length_b                   16.734(1)
_cell_length_c                   12.6373(9)
_cell_measurement_temperature    298
_cell_volume                     1243.97(14)
_computing_structure_refinement  FULLPROF
_computing_structure_solution    'EXPO 2009'
_diffrn_ambient_temperature      298
_diffrn_measurement_device_type  StadIP
_diffrn_radiation_monochromator  Germanium
_diffrn_radiation_type           'Cu K\a1'
_diffrn_radiation_wavelength     1.54060
_diffrn_source                   'x-ray tube'
_diffrn_source_target            Cu
_exptl_absorpt_coefficient_mu    71.063
_pd_char_colour                  'dark green'
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.020000
_pd_meas_2theta_range_max        90.00000
_pd_meas_2theta_range_min        11.00000
_pd_meas_number_of_points        3951
_pd_proc_2theta_range_inc        0.020000
_pd_proc_2theta_range_max        90.0000
_pd_proc_2theta_range_min        11.0000
_pd_proc_ls_pref_orient_corr     ' ?'
_pd_proc_ls_prof_R_factor        2.3245
_pd_proc_ls_prof_wR_expected     1.5392
_pd_proc_ls_prof_wR_factor       3.0738
_pd_proc_wavelength              1.540598
_pd_spec_mount_mode              transmission
_pd_spec_shape                   flat_sheet
_refine_ls_number_parameters     40
_refine_ls_number_reflns         549
_refine_ls_number_restraints     0
_refine_ls_R_I_factor            9.4417
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_cod_data_source_file            ic4009366_si_001.cif
_cod_data_source_block           Cl10Fe2W2
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4335288
_pd_proc_ls_prof_cr_factor       21.7009
_pd_proc_ls_prof_cwr_factor      18.9531
_pd_proc_ls_prof_cwr_expected    9.4909
_pd_proc_ls_prof_chi2            3.9879
_pd_proc_ls_prof_echi2           3.9632