Synthesis and First X-ray Structural Analysis of Monomeric Imino-λ5-stibanes
Yoshihiro Matano; Hazumi Nomura; Hitomi Suzuki; Inorganic Chemistry 39 (2000) 1340–1341; doi:10.1021/ic991120e

data_4320833
_publ_contact_author_address
;
    Sakyo-ku, Kyoto 606-8502, JAPAN
;
_publ_contact_author_email       ' matano@kuchem.kyoto-u.ac.jp '
_publ_contact_author_fax         ' +81-75-753-4000 '
_publ_contact_author_name        ' Yoshihiro Matano'
_publ_contact_author_phone       ' +81-75-753-4042 '
_publ_section_title
;
 Synthesis and First X-ray Structural Analysis of Monomeric
 Imino-\l5-stibanes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1340
_journal_page_last               1341
_journal_paper_doi               10.1021/ic991120e
_journal_volume                  39
_journal_year                    2000
_chemical_formula_moiety         'C22 H21 F3 N O5 S Sb '
_chemical_formula_sum            'C22 H21 F3 N O5 S Sb'
_chemical_formula_weight         590.22
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Fri Aug 20 16:23:13 1999'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                100.29(2)
_cell_angle_beta                 110.43(2)
_cell_angle_gamma                107.50(1)
_cell_formula_units_Z            2
_cell_length_a                   10.955(2)
_cell_length_b                   14.268(2)
_cell_length_c                   9.055(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    299.2
_cell_measurement_theta_max      12.2
_cell_measurement_theta_min      11.0
_cell_volume                     1199.6(6)
_computing_cell_refinement       'Rigaku/AFC Diffractometer Control'
_computing_data_collection       'Rigaku/AFC Diffractometer Control'
_computing_data_reduction        teXsan
_computing_publication_material  teXsan
_computing_structure_refinement  teXsan
_diffrn_ambient_temperature      299.2
_diffrn_measurement_device_type  'Rigaku AFC7S'
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      0.09450
_diffrn_orient_matrix_UB_12      0.05004
_diffrn_orient_matrix_UB_13      0.08929
_diffrn_orient_matrix_UB_21      0.02708
_diffrn_orient_matrix_UB_22      -0.05911
_diffrn_orient_matrix_UB_23      0.02009
_diffrn_orient_matrix_UB_31      0.03959
_diffrn_orient_matrix_UB_32      0.00267
_diffrn_orient_matrix_UB_33      -0.08407
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.012
_diffrn_reflns_av_sigmaI/netI    0.018
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            5869
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.52
_diffrn_standards_decay_%        5.53
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.291
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.634
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             588.00
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.74
_refine_diff_density_min         -1.10
_refine_ls_extinction_coef       0.024(2)
_refine_ls_extinction_method     'Zachariasen(1967) type 2 Gaussian isotropic'
_refine_ls_goodness_of_fit_ref   1.131
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     299
_refine_ls_number_reflns         5133
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0265
_refine_ls_R_factor_gt           0.0265
_refine_ls_shift/su_max          0.0090
_refine_ls_shift/su_mean         0.0020
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00096|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0403
_refine_ls_wR_factor_ref         0.0403
_reflns_number_gt                5133
_reflns_number_total             5521
_reflns_threshold_expression     >2.0sigma(I)
_cod_data_source_file            ic991120e_2.cif
_cod_data_source_block           o-Ans3Sb_NSO2CF3
_cod_original_cell_volume        1199.5(6)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C22 H21 F3 N O5 S Sb '
_cod_database_code               4320833