One-Pot Synthesis of Highly Substituted 4-Acetonylindoles via Sequential Dearomatization and Silver-Catalyzed Domino Reaction.
Feng, Xin; Wang, Huiqing; Yang, Bo; Fan, Renhua; Organic letters 16 (2014) 3600–3603; doi:10.1021/ol501678v

data_1516712
_publ_section_title
;
 One-Pot Synthesis of Highly Substituted 4-Acetonylindoles via Sequential
 Dearomatization and Silver-Catalyzed Domino Reaction.
;
_journal_issue                   13
_journal_name_full               'Organic letters'
_journal_page_first              3600
_journal_page_last               3603
_journal_paper_doi               10.1021/ol501678v
_journal_volume                  16
_journal_year                    2014
_chemical_formula_sum            'C28 H27 N O3 S'
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
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_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.972
_diffrn_measured_fraction_theta_max 0.998
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_diffrn_reflns_point_group_measured_fraction_full 0.972
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_refine_ls_R_factor_all          0.1101
_refine_ls_R_factor_gt           0.0772
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; 
 w=1/[\s^2^(Fo^2^)+(0.1549P)^2^] 
 where P=(Fo^2^+2Fc^2^)/3 
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2028
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 1516712.cif.'
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