Synthesis and structural characterization of amido scorpionate rare earth metals complexes.
Márquez-Segovia, Isabel; Lara-Sánchez, Agustín; Otero, Antonio; Fernández-Baeza, Juan; Castro-Osma, José Antonio; Sánchez-Barba, Luis F; Rodríguez, Ana M; Dalton transactions (Cambridge, England : 2003) 43 (2014) 9586–9595; doi:10.1039/c4dt00770k

data_7030826
_publ_section_title
;
 Synthesis and structural characterization of amido scorpionate rare earth
 metals complexes.
;
_journal_issue                   25
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9586
_journal_page_last               9595
_journal_paper_doi               10.1039/c4dt00770k
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C35 H49 N6 Si3 Y'
_chemical_formula_weight         726.98
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_atom_sites_solution_hydrogens   mixed
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_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_c                   16.652(3)
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_cell_measurement_temperature    180(2)
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_cell_measurement_theta_min      2.282
_cell_volume                     3831(2)
_computing_cell_refinement       'Bruker SAINT'
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_computing_data_reduction        'Bruker SAINT, SADABS, XPREP'
_computing_molecular_graphics    'WINGX v2013.3 (Farrugia, 2013)'
_computing_publication_material  'WINGX v2013.3 (Farrugia, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      180(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
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_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0475P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7030826--7030828.cif.'
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