Boron complexes of aromatic 5-substituted iminopyrrolyl ligands: synthesis, structure, and luminescence properties.
Rodrigues, Ana I.; Figueira, Cláudia A; Gomes, Clara S. B.; Suresh, D.; Ferreira, Bruno; Di Paolo, Roberto E.; Pereira, Daniel de Sa; Dias, Fernando B.; Calhorda, Maria José; Morgado, Jorge; Maçanita, António L; Gomes, Pedro T.; Dalton transactions (Cambridge, England : 2003) 48 (2019) 13337–13352; doi:10.1039/c9dt02718a

data_7700823
_publ_section_title
;
 Boron complexes of aromatic 5-substituted iminopyrrolyl ligands:
 synthesis, structure, and luminescence properties.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13337
_journal_page_last               13352
_journal_paper_doi               10.1039/c9dt02718a
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C35 H35 B N2'
_chemical_formula_sum            'C35 H35 B N2'
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_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2019-06-30 deposited with the CCDC.    2019-08-12 downloaded from the CCDC.
;
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_cell_measurement_temperature    150(2)
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_cell_volume                     2765.6(5)
_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      150(2)
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_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
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_exptl_crystal_description       prism
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0430P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1222
_refine_ls_wR_factor_ref         0.1504
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4684
_reflns_number_total             10449
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt02718a3.cif
_cod_data_source_block           8
_cod_depositor_comments
'Adding full bibliography for 7700823--7700825.cif.'
_cod_original_cell_volume        2765.6(6)
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_shelx_shelxl_version_number     2016/6
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_shelx_res_checksum              51717