Heterodinuclear titanium/zinc catalysis: synthesis, characterization and activity for CO2/epoxide copolymerization and cyclic ester polymerization.
Garden, Jennifer A.; White, Andrew J. P.; Williams, Charlotte K.; Dalton transactions (Cambridge, England : 2003) 46 (2017) 2532–2541; doi:10.1039/c6dt04193k

data_7041937
_publ_section_title
;
 Heterodinuclear titanium/zinc catalysis: synthesis, characterization and
 activity for CO2/epoxide copolymerization and cyclic ester
 polymerization.
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2532
_journal_page_last               2541
_journal_paper_doi               10.1039/c6dt04193k
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         'C46 H72 N4 O4 Ti Zn, C6 H14'
_chemical_formula_sum            'C52 H86 N4 O4 Ti Zn'
_chemical_formula_weight         944.51
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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;
2016-09-28 deposited with the CCDC.
2017-01-13 downloaded from the CCDC.
;
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; 
CrysAlisPro 1.171.38.43 (Rigaku Oxford Diffraction, 2015) 
Analytical numeric absorption correction using a multifaceted crystal 
model based on expressions derived by R.C. Clark & J.S. Reid. 
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897) 
Empirical absorption correction using spherical harmonics, 
implemented in SCALE3 ABSPACK scaling algorithm. 
;
_exptl_crystal_colour            Yellow
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0493P)^2^+0.4484P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7041936--7041937.cif.'
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