A phosphine-free iron complex-catalyzed synthesis of cycloalkanes <i>via</i> the borrowing hydrogen strategy.
Bettoni, Léo; Gaillard, Sylvain; Renaud, Jean-Luc; Chemical communications (Cambridge, England) 56 (2020) 12909–12912; doi:10.1039/d0cc05840h

data_7127329
_publ_section_title
;
 A phosphine-free iron complex-catalyzed synthesis of cycloalkanes
 <i>via</i> the borrowing hydrogen strategy.
;
_journal_issue                   85
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              12909
_journal_page_last               12912
_journal_paper_doi               10.1039/d0cc05840h
_journal_volume                  56
_journal_year                    2020
_chemical_absolute_configuration ad
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_chemical_name_systematic
;
(2,3,4,5,6-pentamethylphenyl)(1,8,8-trimethylbicyclo[3.2.1]octan-3-yl)methanone
;
_space_group_crystal_system      monoclinic
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;
2020-07-28 deposited with the CCDC.	2020-09-18 downloaded from the CCDC.
;
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;
 Flack x determined using 616 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0435P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments          'Adding full bibliography for 7127329.cif.'
_cod_original_cell_volume        952.0(11)
_cod_original_sg_symbol_H-M      'P 21'
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