Transition metal (Rh and Fe) complexes and main-group (Se and B) adducts with N,N'-diphosphanyl NHC ligands: a study of stereoelectronic properties.
Ai, Pengfei; Danopoulos, Andreas A.; Braunstein, Pierre; Dalton transactions (Cambridge, England : 2003) 45 (2016) 4771–4779; doi:10.1039/c6dt00318d

data_7038248
_publ_section_title
;
 Transition metal (Rh and Fe) complexes and main-group (Se and B) adducts
 with N,N'-diphosphanyl NHC ligands: a study of stereoelectronic
 properties.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4771
_journal_page_last               4779
_journal_paper_doi               10.1039/c6dt00318d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C46 H92 Cl6 Fe3 N4 O2 P4'
_chemical_formula_sum            'C46 H92 Cl6 Fe3 N4 O2 P4'
_chemical_formula_weight         1237.36
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      trigonal
_space_group_IT_number           148
_space_group_name_Hall           '-R 3'
_space_group_name_H-M_alt        'R -3 :H'
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2016-01-22 deposited with the CCDC.
2016-02-03 downloaded from the CCDC.
;
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_cell_angle_gamma                120
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_cell_volume                     15473(4)
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_diffrn_measurement_method       '\f and \w scans'
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_platon_squeeze_details
;
The residual electron density was assigned to half a molecule of 
the tetrahydrofuran solvent [270/18= 15 e per asymmetric unit; half a
molecule of C4H8O1 would give 20 e]. 
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0766P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7038248--7038253.cif.'
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