Pre-organisation of ligand donor sets modulates the supramolecular structure of bis(pyridyl‒imine) silver(i) chelates
Venter, Chané; Akerman, Matthew P.; CrystEngComm 23 (2021) 1294–1304; doi:10.1039/D0CE01610A

data_7242039
_publ_section_title
;
 Pre-organisation of ligand donor sets modulates the supramolecular
 structure of bis(pyridyl--imine) silver(i) chelates
;
_journal_issue                   5
_journal_name_full               CrystEngComm
_journal_page_first              1294
_journal_page_last               1304
_journal_paper_doi               10.1039/D0CE01610A
_journal_volume                  23
_journal_year                    2021
_chemical_formula_moiety         'C18 H14 Ag N4, F6 Sb [+ solvent]'
_chemical_formula_sum            'C18 H14 Ag F6 N4 Sb'
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
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_atom_sites_solution_primary     direct
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-09-23 deposited with the CCDC.	2021-01-08 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       '\w and \f-scans'
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_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5493
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_exptl_crystal_colour            colourless
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_exptl_crystal_description       needle
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         11340
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.135
_refine_ls_R_factor_all          0.1064
_refine_ls_R_factor_gt           0.0909
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0132P)^2^+145.7698P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1788
_refine_ls_wR_factor_ref         0.1851
_reflns_Friedel_coverage         0.000
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_reflns_number_total             11340
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0ce01610a2.cif
_cod_data_source_block           shelx_CCDC1
_cod_depositor_comments
'Adding full bibliography for 7242038--7242041.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7242039
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.680
_shelx_estimated_absorpt_t_max   0.980
_shelx_res_checksum              26084
_shelx_fab_checksum              77061