Isolation of OH-bridged Ag(i)/Cu(iii) and ion-pair Cu(i)/Cu(iii) trifluoromethyl complexes with monophosphines.
Xiao, Chang; Zhang, Song-Lin; Dalton transactions (Cambridge, England : 2003) 48 (2019) 848–853; doi:10.1039/c8dt03876g

data_7048311
_publ_section_title
;
 Isolation of OH-bridged Ag(i)/Cu(iii) and ion-pair Cu(i)/Cu(iii)
 trifluoromethyl complexes with monophosphines.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              848
_journal_page_last               853
_journal_paper_doi               10.1039/c8dt03876g
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C36 H50 Ag Cu F9 O P'
_chemical_formula_sum            'C36 H50 Ag Cu F9 O P'
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_symmetry_space_group_name_Hall  '-P 1'
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_audit_update_record
;
2018-05-07 deposited with the CCDC.
2018-12-04 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
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_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0282
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_exptl_absorpt_coefficient_mu    1.202
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_exptl_crystal_colour            colourless
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_exptl_crystal_F_000             892
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_exptl_crystal_size_mid          0.600
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0600P)^2^+0.6139P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0825
_refine_ls_wR_factor_ref         0.0868
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7771
_reflns_number_total             8640
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt03876g2.cif
_cod_data_source_block           b180402ajiangs_0m_a
_cod_depositor_comments          'Adding full bibliography for 7048311.cif.'
_cod_database_code               7048311
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.532
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