A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO2under mild and co-catalyst free conditions
Han, Yun-Hu; Zhou, Zhong-Yuan; Tian, Chong-Bin; Du, Shao-Wu; Green Chem. 18 (2016) 4086–; doi:10.1039/C6GC00413J

data_7225170
_publ_section_title
;
 A dual-walled cage MOF as an efficient heterogeneous catalyst for the
 conversion of CO2under mild and co-catalyst free conditions
;
_journal_issue                   14
_journal_name_full               'Green Chem.'
_journal_page_first              4086
_journal_paper_doi               10.1039/C6GC00413J
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C50 H68 N14 O16 Zn2'
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_chemical_name_systematic
;
 ?
;
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_symmetry_space_group_name_Hall  '-I 2 2 3'
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_audit_update_record
;
2016-03-29 deposited with the CCDC.
2016-05-10 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  Saturn724+
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_exptl_absorpt_coefficient_mu    0.670
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_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            White
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_exptl_crystal_description       Prism
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1261P)^2^+11.1189P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2318
_refine_ls_wR_factor_ref         0.2349
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4670
_reflns_number_total             4768
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6gc00413j2.cif
_cod_data_source_block           x_sq
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7225170.cif.
;
_cod_original_cell_volume        23534.5(7)
_cod_database_code               7225170
_shelxl_version_number           2014-3
_platon_squeeze_void_probe_radius 1.20