Four-coordinated see-saw N-(aryl)-2-(propan-2-ylidene)hydrazinecarbothioamide complexes of nickel(ii), copper(ii) and zinc(ii) and their propensity for catalytic cyclisation.
Tarai, Arup; Baruah, Jubaraj B.; Dalton transactions (Cambridge, England : 2003) 47 (2018) 4921–4930; doi:10.1039/C8DT00453F

data_7045787
_publ_section_title
;
 Four-coordinated see-saw
 N-(aryl)-2-(propan-2-ylidene)hydrazinecarbothioamide complexes of
 nickel(ii), copper(ii) and zinc(ii) and their propensity for catalytic
 cyclisation.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4921
_journal_page_last               4930
_journal_paper_doi               10.1039/C8DT00453F
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C22 H28 N6 Ni O2 S2, 2(C3 H7 N O)'
_chemical_formula_sum            'C28 H42 N8 Ni O4 S2'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2018-01-27 deposited with the CCDC.
2018-03-07 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'CCD area detector'
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_exptl_absorpt_correction_type   multi-scan
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0500P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt00453f2.cif
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_cod_depositor_comments
'Adding full bibliography for 7045785--7045793.cif.'
_cod_original_cell_volume        3428.7(9)
_cod_database_code               7045787
_shelx_shelxl_version_number     2014/7
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