Expanding icosahedral frameworks: structure and bonding of bicapped icosahedral cluster [(Cp*Co)<sub>4</sub>Fe(CO)B<sub>9</sub>H<sub>11</sub>].
Giri, Soumen; Bairagi, Subhash; Shyamal, Sampad; Ghosh, Sundargopal; Chemical communications (Cambridge, England) 62 (2026) 1981–1985; doi:10.1039/d5cc06191a

data_7135511
_publ_section_title
;
 Expanding icosahedral frameworks: structure and bonding of bicapped
 icosahedral cluster
 [(Cp*Co)<sub>4</sub>Fe(CO)B<sub>9</sub>H<sub>11</sub>].
;
_journal_issue                   6
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              1981
_journal_page_last               1985
_journal_paper_doi               10.1039/d5cc06191a
_journal_volume                  62
_journal_year                    2026
_chemical_formula_sum            'C41 H71 B9 Co4 Fe O'
_chemical_formula_weight         968.83
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2019/3
_audit_update_record
;
2025-10-29 deposited with the CCDC.	2025-12-22 downloaded from the CCDC.
;
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'ORTEP3 (Farrugia, 1997) and Mercury (Bruno et al., 2002)'
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_diffrn_ambient_temperature      100(2)
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0943P)^2^+0.1327P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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