Evaluation of Simple Amides in the Selective Recovery of Gold from Secondary Sources by Solvent Extraction
Doidge, Euan D.; Kinsman, Luke M. M.; Ji, Yiran; Carson, Innis; Duffy, Andrew J.; Kordas, Izabela A.; Shao, Eddie; Tasker, Peter A.; Ngwenya, Bryne T.; Morrison, Carole A.; Love, Jason B.; ACS Sustainable Chemistry & Engineering 7 (2019) 15019–; doi:10.1021/acssuschemeng.9b03436

data_4515219
_publ_section_title
;
 Evaluation of Simple Amides in the Selective Recovery of Gold from
 Secondary Sources by Solvent Extraction
;
_journal_issue                   17
_journal_name_full               'ACS Sustainable Chemistry &amp; Engineering'
_journal_page_first              15019
_journal_paper_doi               10.1021/acssuschemeng.9b03436
_journal_volume                  7
_journal_year                    2019
_chemical_formula_sum            'C44 H94 Cl6 N4 O4 Sn'
_chemical_formula_weight         1074.62
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_cell_angle_alpha                90
_cell_angle_beta                 111.389(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   18.1977(5)
_cell_length_b                   8.4952(2)
_cell_length_c                   19.6349(5)
_cell_measurement_temperature    293(2)
_cell_volume                     2826.36(14)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.882
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0354
_diffrn_reflns_av_unetI/netI     0.0321
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.882
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            33010
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.882
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.568
_diffrn_reflns_theta_min         3.068
_exptl_absorpt_coefficient_mu    0.775
_exptl_crystal_density_diffrn    1.263
_exptl_crystal_F_000             1140
_refine_diff_density_max         0.534
_refine_diff_density_min         -0.448
_refine_diff_density_rms         0.069
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.892
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     284
_refine_ls_number_reflns         6984
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.892
_refine_ls_R_factor_all          0.0400
_refine_ls_R_factor_gt           0.0309
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1072
_refine_ls_wR_factor_ref         0.1192
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5975
_reflns_number_total             6984
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            sc9b03436_si_002.cif
_cod_data_source_block           jl18002_refinalized
_cod_database_code               4515219
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              4146
_shelx_hkl_checksum              46374