Palladium-catalyzed alkyne polyannulation of diphenols and unactivated internal diynes: a new synthetic route to functional heterocyclic polymers
Zhang, Yun; Lam, Jacky W. Y.; Tang, Ben Zhong; Polym. Chem. 7 (2016) 330–; doi:10.1039/C5PY01466B

data_1540420
_publ_section_title
;
 Palladium-catalyzed alkyne polyannulation of diphenols and unactivated
 internal diynes: a new synthetic route to functional heterocyclic
 polymers
;
_journal_issue                   2
_journal_name_full               'Polym. Chem.'
_journal_page_first              330
_journal_paper_doi               10.1039/C5PY01466B
_journal_volume                  7
_journal_year                    2016
_chemical_formula_moiety         'C21 H16 O3 S'
_chemical_formula_sum            'C21 H16 O3 S'
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_chemical_name_systematic        5-(methylsulfonyl)-2,3-diphenylbenzofuran
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2015-09-11 deposited with the CCDC.
2015-10-23 downloaded from the CCDC.
;
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CrysAlisPro, Agilent Technologies,
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
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O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
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XL, G.M. Sheldrick, Acta Cryst.
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omega____ theta____ kappa____ phi______ frames
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  3 omega  -14.00   69.00   1.0000    8.0000
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  4 omega  -15.00   85.00   1.0000    8.0000
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  5 omega   29.00  127.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
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  6 omega   70.00  124.00   1.0000    8.0000
omega____ theta____ kappa____ phi______ frames
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  7 omega   42.00   71.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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  8 omega   39.00   64.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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  9 omega   42.00   71.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      110.0000  -38.0000    0.0000 29

 10 omega   37.00   72.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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 11 omega   90.00  125.00   1.0000   15.0000
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 12 omega   37.00   72.00   1.0000   15.0000
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 13 omega   38.00   65.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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 14 omega   41.00   71.00   1.0000   15.0000
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 15 omega   40.00   67.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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 16 omega   44.00   82.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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 17 omega   40.00   71.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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 18 omega   38.00   66.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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 19 omega   44.00  131.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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 20 omega   88.00  115.00   1.0000   15.0000
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 21 omega  131.00  166.00   1.0000   15.0000
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 22 omega   46.00  146.00   1.0000   15.0000
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 23 omega   39.00   87.00   1.0000   15.0000
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 24 omega   93.00  142.00   1.0000   15.0000
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 25 omega   38.00   65.00   1.0000   15.0000
omega____ theta____ kappa____ phi______ frames
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;
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            'light yellow'
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0464P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_data_source_block           benzofuran
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;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 1540420.cif.
;
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_reflns_odcompleteness_completeness 95.83
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