Λ~L~Λ~L~-Bis(μ-<small>L</small>-cysteinato)-1:2κ^3^<i>S</i>:<i>N</i>,<i>S</i>;1:3κ^3^<i>S</i>:<i>N</i>,<i>S</i>-tetrakis(ethylenediamine)-2κ^4^<i>N</i>,<i>N</i>';3κ^4^<i>N</i>,<i>N</i>'-dicobalt(III)silver(I) tris(perchlorate) pentahydrate
Tamura, Motoshi; Yoshinari, Nobuto; Igashira-Kamiyama, Asako; Konno, Takumi; Acta Crystallographica Section E 63 (2007) m1641–m1642; doi:10.1107/S1600536807020442

data_2213909
_publ_section_title
;\L~L~\L~L~-Bis(\m-<small>L</small>-cysteinato)-1:2\k^3^<i>S</i>:<i>N</i>,<i>S</i>;1:3\k^3^<i>S</i>:<i>N</i>,<i>S</i>-tetrakis(ethylenediamine)-2\k^4^<i>N</i>,<i>N</i>';3\k^4^<i>N</i>,<i>N</i>'-dicobalt(III)silver(I)
 tris(perchlorate) pentahydrate
;
_journal_coeditor_code           NG2256
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1641
_journal_page_last               m1642
_journal_paper_doi               10.1107/S1600536807020442
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac
'[Ag Co2 (C3 H5 N1 O2 S1)2 (C2 H8 N2)4] (Cl1 O4)3, 5H2 O'
_chemical_formula_moiety
'C14 H42 Ag Co2 N10 O4 S2 3+, 3(Cl O4 -), 5(H2 O)'
_chemical_formula_sum            'C14 H52 Ag Cl3 Co2 N10 O21 S2'
_chemical_formula_weight         1092.86
_chemical_name_systematic
;
\L~L~\L~L~-Bis(\m-L-cysteinato)-
1:2\k^3^S:<i>N</i>,<i>S</i>;1:3\k^3^S:<i>N</i>,<i>S</i>-
tetrakis(ethylenediamine)-2\k^4^<i>N</i>,<i>N</i>';3\k^4^<i>N</i>,<i>N</i>'-
dicobalt(III)silver(I) tris(perchlorate) pentahydrate
;
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C 2y'
_symmetry_space_group_name_H-M   'C 1 2 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.507(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.542(2)
_cell_length_b                   9.050(2)
_cell_length_c                   13.728(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.6
_cell_volume                     1912.1(6)
_computing_cell_refinement
;
MSC/AFC Diffractometer Control Software
;
_computing_data_collection
;
MSC/AFC Diffractometer Control Software
(Molecular Structure Corporation, 1992)
;
_computing_data_reduction        'CrystalStructure (Rigaku/MSC, 2004)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution
;
SIR92 (Altomare <i>et al.</i>,  1994)
;
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku AFC-7S'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0147
_diffrn_reflns_av_sigmaI/netI    0.0224
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            2426
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.54
_diffrn_standards_decay_%        14.41
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.773
_exptl_absorpt_correction_T_max  0.7408
_exptl_absorpt_correction_T_min  0.5374
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North <i>et al.</i>,  1968)'
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    1.898
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             1116
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.365
_refine_diff_density_min         -0.250
_refine_ls_abs_structure_details 'Flack (1983)'
_refine_ls_abs_structure_Flack   0.001(18)
_refine_ls_extinction_coef       0.0150(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL97
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     322
_refine_ls_number_reflns         2346
_refine_ls_number_restraints     13
_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.0264
_refine_ls_R_factor_gt           0.0230
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0348P)^2^+0.6577P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0587
_refine_ls_wR_factor_ref         0.0601
_reflns_number_gt                2219
_reflns_number_total             2346
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            ng2256.cif
_cod_data_source_block           I
_cod_original_cell_volume        1912.0(6)
_cod_original_sg_symbol_H-M      'C 2'
_cod_database_code               2213909
_cod_database_fobs_code          2213909