Dichotomous mechanistic behavior in Narasaka–Heck cyclizations: electron rich Pd-catalysts generate iminyl radicals
Race, Nicholas J.; Faulkner, Adele; Shaw, Megan H.; Bower, John F.; Chem. Sci. 7 (2016) 1508–; doi:10.1039/C5SC04037J

data_1540581
_publ_section_title
;
 Dichotomous mechanistic behavior in Narasaka--Heck cyclizations: electron
 rich Pd-catalysts generate iminyl radicals
;
_journal_issue                   2
_journal_name_full               'Chem. Sci.'
_journal_page_first              1508
_journal_paper_doi               10.1039/C5SC04037J
_journal_volume                  7
_journal_year                    2016
_chemical_formula_moiety         'C23 H34 N2 O'
_chemical_formula_sum            'C23 H34 N2 O'
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_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-10-01 deposited with the CCDC.
2015-11-18 downloaded from the CCDC.
;
_cell_angle_alpha                75.866(2)
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_cell_angle_gamma                87.755(1)
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker Apex II kappa CCD area detector'
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0479P)^2^+0.2992P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments          'Adding full bibliography for 1540581.cif.'
_cod_original_sg_symbol_H-M      P-1
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