Novel ternary Ag<sup>II</sup>Co<sup>III</sup>F<sub>5</sub> fluoride: synthesis, structure and magnetic characteristics.
Jezierski, Daniel; Mazej, Zoran; Grochala, Wojciech; Dalton transactions (Cambridge, England : 2003) 53 (2024) 13731–13742; doi:10.1039/d4dt00419a

data_7715832
_publ_section_title
;
 Novel ternary Ag<sup>II</sup>Co<sup>III</sup>F<sub>5</sub> fluoride:
 synthesis, structure and magnetic characteristics.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13731
_journal_page_last               13742
_journal_paper_doi               10.1039/d4dt00419a
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         'Ag Co F5'
_chemical_formula_sum            'Ag Co F5'
_chemical_formula_weight         261.8
_chemical_name_common            'Silver(II) Cobalt(III) Pentafluoride'
_chemical_name_systematic        'Silver(II) Cobalt(III) Pentafluoride'
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
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_audit_update_record
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2024-02-14 deposited with the CCDC.	2024-04-22 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 115.976(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.274(2)
_cell_length_b                   7.628(2)
_cell_length_c                   7.529(2)
_cell_measurement_temperature    293
_cell_volume                     375.55(17)
_diffrn_ambient_temperature      293
_diffrn_measurement_device_type  'PANalytical XPert Pro diffractometer'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Co K\a'
_diffrn_radiation_wavelength     1.7902
_exptl_absorpt_coefficient_mu    17.752
_exptl_crystal_density_diffrn    4.630
_exptl_crystal_F_000             260
_exptl_crystal_preparation       'Magnetic properties'
_pd_instr_location               ' ?'
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_pd_proc_ls_background_function  '35 Legendre polynoms'
_pd_proc_ls_pref_orient_corr     'March & Dollase'
_pd_proc_ls_profile_function     Pseudo-Voigt
_pd_proc_ls_prof_R_factor        0.0112
_pd_proc_ls_prof_wR_expected     0.0102
_pd_proc_ls_prof_wR_factor       0.0168
_refine_ls_goodness_of_fit_all   1.66
_refine_ls_number_constraints    0
_refine_ls_number_parameters     66
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0299
_refine_ls_R_factor_gt           0.0248
_refine_ls_shift/su_max          0.0233
_refine_ls_shift/su_mean         0.0058
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0324
_refine_ls_wR_factor_gt          0.0310
_cod_data_source_file            d4dt00419a2.cif
_cod_data_source_block           global
_cod_depositor_comments
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The following automatic conversions were performed:

data item '_diffrn_radiation_probe' value 'X-ray' was changed to
'x-ray' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 

 Adding full bibliography for 7715832.cif.
;
_cod_original_cell_volume        375.58(19)
_cod_database_code               7715832