LMucko/crystallography-open-database huggingface dataset:
Investigating the latent polymorphism of maleic acid
W. Jones; Graeme Day; W.D.Sam Motherwell; Andrew V. Trask; Chemical Communications  (2006) –; doi:10.1039/b513442k

data_7100672
_publ_section_title
;
Investigating the latent polymorphism of maleic acid
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513442k
_journal_year                    2006
_chemical_formula_moiety         'C4 H4 O4'
_chemical_formula_sum            'C4 H4 O4'
_chemical_formula_weight         116.07
_chemical_name_common            'Maleic Acid'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 124.423(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.4749(8)
_cell_length_b                   10.0849(12)
_cell_length_c                   7.5465(7)
_cell_measurement_temperature    180(2)
_cell_volume                     469.26(9)
_diffrn_ambient_temperature      180(2)
_exptl_crystal_density_diffrn    1.643
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7100672
Investigating the latent polymorphism of maleic acid
W. Jones; Graeme Day; W.D.Sam Motherwell; Andrew V. Trask; Chemical Communications  (2006) –; doi:10.1039/b513442k

data_7100673
_publ_section_title
;
Investigating the latent polymorphism of maleic acid
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513442k
_journal_year                    2006
_chemical_formula_moiety         'C4 H4 O4'
_chemical_formula_sum            'C4 H4 O4'
_chemical_formula_weight         116.07
_chemical_name_common            'Maleic Acid'
_space_group_IT_number           7
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P -2yc'
_symmetry_space_group_name_H-M   'P 1 c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 102.220(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   3.6933(3)
_cell_length_b                   7.4840(5)
_cell_length_c                   8.5933(7)
_cell_measurement_temperature    180(2)
_cell_volume                     232.14(3)
_diffrn_ambient_temperature      180(2)
_exptl_crystal_density_diffrn    1.661
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P c'
_cod_database_code               7100673
The ionothermal synthesis of SIZ-6 ‒ a layered aluminophosphate
Parnham, Emily R.; Wheatley, Paul S.; Morris, Russell E.; Chemical Communications  (2006) 380–382; doi:10.1039/b513458g

data_7100674
_publ_section_title
;
 The ionothermal synthesis of SIZ-6 -- a layered aluminophosphate
;
_journal_coden_ASTM              CHCOFS
_journal_issue                   4
_journal_name_full               'Chemical Communications'
_journal_page_first              380
_journal_page_last               382
_journal_paper_doi               10.1039/b513458g
_journal_year                    2006
_chemical_formula_moiety         Al4(PO4)3(HPO4)2.0.2H2O.C6H11N2
_chemical_formula_sum            'C6 H13.4 Al4 N2 O20.2 P5'
_chemical_formula_weight         699.38
_space_group_crystal_system      orthorhombic
_space_group_IT_number           64
_space_group_name_Hall           '-C 2ac 2'
_space_group_name_H-M_alt        'C m c e'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   17.5472(14)
_cell_length_b                   18.0516(15)
_cell_length_c                   35.560(3)
_cell_measurement_temperature    150(2)
_cell_volume                     11263.9(16)
_diffrn_ambient_temperature      150(2)
_exptl_crystal_density_diffrn    1.65
_cod_database_code               7100674
Synthesis and Structures of Poly(perfluoroethyl)[60]fullerenes: 1,7,16,36,46,49-C60(C2F5)6 and 1,6,11,18,24,27,32,35-C60(C2F5)8
Ivan E. Kareev; Igor V. Kuvychko; Sergey F. Lebedkin; Susie M. Miller; Oren P. Anderson; Steven H. Strauss; Olga V. Boltalina; Chemical Communications  (2006) –; doi:10.1039/b513477c

data_7100675
_publ_section_title
;
Synthesis and Structures of
Poly(perfluoroethyl)[60]fullerenes: 1,7,16,36,46,49-C60(C2F5)6 and
1,6,11,18,24,27,32,35-C60(C2F5)8
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513477c
_journal_year                    2006
_chemical_formula_sum            'C76 F40'
_chemical_formula_weight         1672.76
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 98.424(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.9559(18)
_cell_length_b                   13.5701(13)
_cell_length_c                   21.425(2)
_cell_measurement_temperature    100(2)
_cell_volume                     5451.7(9)
_diffrn_ambient_temperature      100(2)
_exptl_crystal_density_diffrn    2.038
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7100675
Synthesis and Structures of Poly(perfluoroethyl)[60]fullerenes: 1,7,16,36,46,49-C60(C2F5)6 and 1,6,11,18,24,27,32,35-C60(C2F5)8
Ivan E. Kareev; Igor V. Kuvychko; Sergey F. Lebedkin; Susie M. Miller; Oren P. Anderson; Steven H. Strauss; Olga V. Boltalina; Chemical Communications  (2006) –; doi:10.1039/b513477c

data_7100676
_publ_section_title
;
Synthesis and Structures of
Poly(perfluoroethyl)[60]fullerenes: 1,7,16,36,46,49-C60(C2F5)6 and
1,6,11,18,24,27,32,35-C60(C2F5)8
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513477c
_journal_year                    2006
_chemical_formula_sum            'C72 F30'
_chemical_formula_weight         1434.72
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                89.944(2)
_cell_angle_beta                 84.994(2)
_cell_angle_gamma                75.915(2)
_cell_formula_units_Z            2
_cell_length_a                   9.8807(8)
_cell_length_b                   14.6719(13)
_cell_length_c                   16.5397(14)
_cell_measurement_temperature    100(2)
_cell_volume                     2316.3(3)
_diffrn_ambient_temperature      100(2)
_exptl_crystal_density_diffrn    2.057
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               7100676
; Chemical Communications  (2006) –; doi:10.1039/b513543e

data_7100677
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513543e
_journal_year                    2006
_chemical_formula_moiety         'C28 H39 Na O26 S4 Yb, C24 H20 P, 5(H2 O)'
_chemical_formula_sum            'C52 H69 Na O31 P S4 Yb'
_chemical_formula_weight         1545.31
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.0
_cell_angle_beta                 104.908(2)
_cell_angle_gamma                90.0
_cell_formula_units_Z            4
_cell_length_a                   21.271(3)
_cell_length_b                   11.375(2)
_cell_length_c                   26.372(4)
_cell_measurement_temperature    153(2)
_cell_volume                     6166.1(17)
_exptl_crystal_density_diffrn    1.665
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7100677
Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer
Spencer Williams; Emma Denehy; Jonathan M. White; Chemical Communications  (2006) –; doi:10.1039/b513712h

data_7100678
_publ_section_title
;
Ground state structures of sulfate monoesters and
sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl
transfer
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513712h
_journal_year                    2006
_chemical_formula_sum            'C7 H7 K O5 S'
_chemical_formula_weight         242.29
_chemical_name_common            'potassium 4-methoxyphenyl sulfate'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 93.3540(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   7.1098(4)
_cell_length_b                   38.923(2)
_cell_length_c                   7.1463(4)
_cell_measurement_temperature    130(2)
_cell_volume                     1974.2(2)
_diffrn_ambient_temperature      130(2)
_exptl_crystal_density_diffrn    1.630
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7100678
Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer
Spencer Williams; Emma Denehy; Jonathan M. White; Chemical Communications  (2006) –; doi:10.1039/b513712h

data_7100679
_publ_section_title
;
Ground state structures of sulfate monoesters and
sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl
transfer
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513712h
_journal_year                    2006
_chemical_formula_sum            'C7 H9 N O4 S'
_chemical_formula_weight         203.21
_chemical_name_common            '4-methoxyphenyl sulfamate'
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   4.9816(4)
_cell_length_b                   7.0344(5)
_cell_length_c                   25.1874(18)
_cell_measurement_temperature    130(2)
_cell_volume                     882.63(11)
_diffrn_ambient_temperature      130(2)
_exptl_crystal_density_diffrn    1.529
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               7100679
Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer
Spencer Williams; Emma Denehy; Jonathan M. White; Chemical Communications  (2006) –; doi:10.1039/b513712h

data_7100680
_publ_section_title
;
Ground state structures of sulfate monoesters and
sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl
transfer
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513712h
_journal_year                    2006
_chemical_formula_sum            'C8 H10 K N O6 S'
_chemical_formula_weight         287.33
_chemical_name_common            'potassium 4-acetamidophenyl sulfate'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                89.0620(10)
_cell_angle_beta                 81.3830(10)
_cell_angle_gamma                79.6480(10)
_cell_formula_units_Z            2
_cell_length_a                   6.7995(5)
_cell_length_b                   6.9857(5)
_cell_length_c                   12.1695(9)
_cell_measurement_temperature    130(2)
_cell_volume                     562.18(7)
_diffrn_ambient_temperature      130(2)
_exptl_crystal_density_diffrn    1.697
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               7100680
Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer
Spencer Williams; Emma Denehy; Jonathan M. White; Chemical Communications  (2006) –; doi:10.1039/b513712h

data_7100681
_publ_section_title
;
Ground state structures of sulfate monoesters and
sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl
transfer
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513712h
_journal_year                    2006
_chemical_formula_sum            'C6 H4 K N O6 S'
_chemical_formula_weight         257.26
_chemical_name_common            'potassium 4-nitrophenyl sulfate'
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   6.9153(4)
_cell_length_b                   13.1212(7)
_cell_length_c                   18.9869(10)
_cell_measurement_temperature    130(2)
_cell_volume                     1722.82(16)
_diffrn_ambient_temperature      130(2)
_exptl_crystal_density_diffrn    1.984
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               7100681
Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer
Spencer Williams; Emma Denehy; Jonathan M. White; Chemical Communications  (2006) –; doi:10.1039/b513712h

data_7100682
_publ_section_title
;
Ground state structures of sulfate monoesters and
sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl
transfer
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513712h
_journal_year                    2006
_chemical_formula_sum            'C2 H2 F3 K O4 S'
_chemical_formula_weight         218.20
_chemical_name_common            'potassium 2,2,2-trifluoroethyl sulfate'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 107.962(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.862(3)
_cell_length_b                   7.0333(16)
_cell_length_c                   9.150(2)
_cell_measurement_temperature    130(2)
_cell_volume                     726.1(3)
_diffrn_ambient_temperature      130(2)
_exptl_crystal_density_diffrn    1.996
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7100682
Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer
Spencer Williams; Emma Denehy; Jonathan M. White; Chemical Communications  (2006) –; doi:10.1039/b513712h

data_7100683
_publ_section_title
;
Ground state structures of sulfate monoesters and
sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl
transfer
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513712h
_journal_year                    2006
_chemical_formula_sum            'C H3 K O4 S'
_chemical_formula_weight         150.19
_chemical_name_common            'potassium methyl sulfate'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 93.147(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.1599(13)
_cell_length_b                   6.9471(10)
_cell_length_c                   7.3311(10)
_cell_measurement_temperature    130(2)
_cell_volume                     465.81(11)
_diffrn_ambient_temperature      130(2)
_exptl_crystal_density_diffrn    2.142
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7100683
Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer
Spencer Williams; Emma Denehy; Jonathan M. White; Chemical Communications  (2006) –; doi:10.1039/b513712h

data_7100684
_publ_section_title
;
Ground state structures of sulfate monoesters and
sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl
transfer
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513712h
_journal_year                    2006
_chemical_formula_sum            'C6 H6 N2 O5 S'
_chemical_formula_weight         218.19
_chemical_name_common            '4-nitrophenyl sulfamate'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 98.383(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.9687(10)
_cell_length_b                   6.9592(7)
_cell_length_c                   12.2538(12)
_cell_measurement_temperature    130(2)
_cell_volume                     841.01(15)
_diffrn_ambient_temperature      130(2)
_exptl_crystal_density_diffrn    1.723
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7100684
Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer
Spencer Williams; Emma Denehy; Jonathan M. White; Chemical Communications  (2006) –; doi:10.1039/b513712h

data_7100685
_publ_section_title
;
Ground state structures of sulfate monoesters and
sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl
transfer
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b513712h
_journal_year                    2006
_chemical_formula_sum            'C6 H6 N2 O5 S'
_chemical_formula_weight         218.19
_chemical_name_common            '3-nitrophenyl sulfamate'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 116.410(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.8417(13)
_cell_length_b                   8.2431(10)
_cell_length_c                   10.2599(13)
_cell_measurement_temperature    130(2)
_cell_volume                     821.22(17)
_diffrn_ambient_temperature      130(2)
_exptl_crystal_density_diffrn    1.765
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7100685