Alkoxo-bridged copperII complexes as nodes in designing solid-state architectures. The interplay of coordinative and d10-d10 metal-metal interactions in sustaining supramolecular solid-state architectures.
Paraschiv, Carmen; Andruh, Marius; Ferlay, Sylvie; Hosseini, Mir Wais; Kyritsakas, Nathalie; Planeix, Jean-Marc; Stanica, Nicolae; Dalton transactions (Cambridge, England : 2003)  (2005) 1195–1202; doi:10.1039/b500231a

data_7008251
_publ_section_title
;
 Alkoxo-bridged copperII complexes as nodes in designing solid-state
 architectures. The interplay of coordinative and d10-d10 metal-metal
 interactions in sustaining supramolecular solid-state architectures.
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1195
_journal_page_last               1202
_journal_paper_doi               10.1039/b500231a
_journal_year                    2005
_chemical_formula_moiety         'C5 H6 Ag Cu N3 O'
_chemical_formula_sum            'C5 H6 Ag Cu N3 O'
_chemical_formula_weight         295.55
_chemical_name_systematic        ' ?'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 98.425(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.3107(2)
_cell_length_b                   17.3911(8)
_cell_length_c                   6.0139(5)
_cell_measurement_temperature    173
_cell_volume                     859.82(9)
_computing_publication_material  CIFGEN_IN_OpenMoleN_(_1997)
_computing_structure_refinement  LSFM_OpenMoleN_(_1997)
_computing_structure_solution    Direct_methods_(SIR,_Burla_et_al.,_1989)
_diffrn_ambient_temperature      173
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_details
;
2822 reflections were collected using program Collect
("Collect" Data collection software, Nonius B.V., 1998)
The conditions were as follow : crystal to detector distance =  36. mm.
Scan angle =  1.6 deg 1 scans of   60 sec per frame.
Data collection was divided into  2 set(s)
with the following starting angles and number of frames :

Set 1 Theta =    8.80 Omega =    0.00 Kappa =    0.00   64 frames
Set 2 Theta =   -8.50 Kappa = -164.00 Phi   =    0.00   24 frames
Friedel pairs were averaged. Internal R = 0.03
;
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       '\p scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           Mo-K\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.030
_diffrn_reflns_av_sigmaI/netI    0.333
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            2822
_diffrn_reflns_theta_full        30.09
_diffrn_reflns_theta_max         30.09
_diffrn_reflns_theta_min         2.5
_diffrn_source                   xray_tube
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    4.695
_exptl_absorpt_correction_T_max  0.791
_exptl_absorpt_correction_T_min  0.754
_exptl_absorpt_correction_type   refdelf_(Walker_&_Stuart,_1983)
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.283
_exptl_crystal_density_method    none
_exptl_crystal_description       prism
_exptl_crystal_F_000             564
_exptl_crystal_size_max          0.06
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.593
_refine_diff_density_min         -1.283
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.335
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     100
_refine_ls_number_reflns         1375
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.153
_refine_ls_R_factor_gt           0.101
_refine_ls_shift/esd_mean        0.000
_refine_ls_shift/su_max          0.003
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.246
_refine_ls_wR_factor_ref         0.126
_reflns_number_gt                1375
_reflns_number_total             2581
_reflns_threshold_expression     >3.0\s(I)
_cod_data_source_file            b500231a.txt
_cod_data_source_block           st1504
_cod_original_cell_volume        859.82(8)
_cod_database_code               7008251