The unanti-cipated oxidation of a tertiary amine in a tetra-cyclic glyoxal-cyclam condensate yielding zinc(II) coordinated to a sterically hindered amine oxide.
Hubin, Daniel J.; Cunningham, Blue M.; Hubin, Timothy J.; Ebel, Jonathan P.; Krause, Jeanette A.; Oliver, Allen G.; Acta crystallographica. Section E, Crystallographic communications 80 (2024) 343–346; doi:10.1107/S2056989024001889

data_2023046
_publ_section_title
;
 The unanti-cipated oxidation of a tertiary amine in a tetra-cyclic
 glyoxal-cyclam condensate yielding zinc(II) coordinated to a sterically
 hindered amine oxide.
;
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_journal_issue                   'Pt 4'
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'Acta crystallographica. Section E, Crystallographic communications'
_journal_page_first              343
_journal_page_last               346
_journal_paper_doi               10.1107/S2056989024001889
_journal_volume                  80
_journal_year                    2024
_chemical_formula_iupac          '[Zn Cl3 (C12 H23 N4 O)], H2 O'
_chemical_formula_moiety         'C12 H23 Cl3 N4 O Zn, H2 O'
_chemical_formula_sum            'C12 H25 Cl3 N4 O2 Zn'
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_chemical_name_systematic
;
Trichlorido(1,4,11-triaza-8-azoniatetracyclo[6.6.2.0^4,16^.0^11,15^]hexadecane
1-oxide-\k<i>O</i>)zinc(II) monohydrate
;
_space_group_crystal_system      monoclinic
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SAINT V8.40B (Bruker, 2021)
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APEX-4 (Bruker, 2021)
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SAINT V8.40B (Bruker, 2021)
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<i>Olex2 1.5</i> (Dolomanov <i>et al.</i>,  2009), Mercury (Macrae <i>et
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2020)
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<i>Olex2 1.5</i> (Dolomanov <i>et al.</i>,  2009) and PublCIF (Westrip,
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<i>SHELXL2019/2</i> (Sheldrick, 2015b)
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<i>SHELXT2014/5</i> (Sheldrick, 2015a)
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(SADABS; Krause <i>et al.</i>,  2015)
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'w=1/[\s^2^(Fo^2^)+(0.0244P)^2^+0.8924P] where P=(Fo^2^+2Fc^2^)/3'
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