Pd/Cu-catalyzed cascade Heck-type reactions of alkenyl halides with terminal alkynes toward substituted pyrrolidine analogues.
Xu, Shiji; Wang, Qiang; Sun, Jing; Han, Ying; Hu, Weiming; Wang, Lei; Yan, Chao-Guo; Organic & biomolecular chemistry 21 (2023) 5742–5746; doi:10.1039/d3ob00740e

data_7159398
_publ_section_title
;
 Pd/Cu-catalyzed cascade Heck-type reactions of alkenyl halides with
 terminal alkynes toward substituted pyrrolidine analogues.
;
_journal_issue                   28
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              5742
_journal_page_last               5746
_journal_paper_doi               10.1039/d3ob00740e
_journal_volume                  21
_journal_year                    2023
_chemical_formula_moiety         'C22 H23 N O2 S'
_chemical_formula_sum            'C22 H23 N O2 S'
_chemical_formula_weight         365.47
_space_group_crystal_system      monoclinic
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_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2023-05-11 deposited with the CCDC.	2023-06-27 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0508P)^2^+0.6429P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1058
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_reflns_number_total             3844
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3ob00740e2.cif
_cod_data_source_block           XSJ20220725
_cod_depositor_comments          'Adding full bibliography for 7159398.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7159398
_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              6032