Distinctly different reactivity of bis(silylenyl)-<i>versus</i> phosphanyl-silylenyl-substituted <i>o</i>-dicarborane towards O<sub>2</sub>, N<sub>2</sub>O and CO<sub>2</sub>.
Xiong, Yun; Yao, Shenglai; Ruzicka, Ales; Driess, Matthias; Chemical communications (Cambridge, England) 57 (2021) 5965–5968; doi:10.1039/d1cc01939b

data_7128325
_publ_section_title
;
 Distinctly different reactivity of bis(silylenyl)-<i>versus</i>
 phosphanyl-silylenyl-substituted <i>o</i>-dicarborane towards
 O<sub>2</sub>, N<sub>2</sub>O and CO<sub>2</sub>.
;
_journal_issue                   48
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'Chemical communications (Cambridge, England)'
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_journal_paper_doi               10.1039/d1cc01939b
_journal_volume                  57
_journal_year                    2021
_chemical_formula_sum            'C39 H64 B10 N4 O2 Si2'
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_audit_update_record
;
2021-04-06 deposited with the CCDC.	2021-05-13 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Single source at offset, Atlas'
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_diffrn_radiation_type           CuK\a
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
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_exptl_crystal_description       block
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0728P)^2^+4.0001P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1257
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_reflns_number_gt                3874
_reflns_number_total             4072
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1cc01939b2.cif
_cod_data_source_block           2
_cod_depositor_comments
'Adding full bibliography for 7128322--7128326.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7128325
_shelx_shelxl_version_number     2014/7
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