LMucko/crystallography-open-database huggingface dataset:
Chalcogen centered spirocyclic mixed metal carbonyl complexes: Synthesis and molecular structures of (CO)~8~(μ-PCy~2~)Re~2~(μ~4~-E)Fe~2~(μ-ER)(CO)~6~ and ((CO)~8~(μ-PCy~2~)Re~2~(μ~4~-E)Fe~2~(CO)~6~)~2~(μ~4~-E~2~) (E = S, Se, Te; R = org. residue)
Klose, Stefanie; Flörke, Ulrich; Mathur, Pradeep; Egold, Hans; Organometallics  (2003) –; doi:

data_4062108
_publ_section_title
;
Chalcogen centered spirocyclic mixed metal carbonyl complexes:
Synthesis and molecular structures of
(CO)~8~(\m-PCy~2~)Re~2~(\m~4~-E)Fe~2~(\m-ER)(CO)~6~ and
((CO)~8~(\m-PCy~2~)Re~2~(\m~4~-E)Fe~2~(CO)~6~)~2~(\m~4~-E~2~)
(E = S, Se, Te; R = org. residue)
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'C52 H44 Fe4 O28 P2 Re4 Te4'
_chemical_formula_sum            'C52 H44 Fe4 O28 P2 Re4 Te4'
_chemical_formula_weight         2657.41
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                108.910(4)
_cell_angle_beta                 90.285(4)
_cell_angle_gamma                102.955(4)
_cell_formula_units_Z            1
_cell_length_a                   9.351(2)
_cell_length_b                   12.026(3)
_cell_length_c                   17.270(4)
_cell_measurement_temperature    153(2)
_cell_volume                     1784.0(7)
_diffrn_ambient_temperature      153(2)
_exptl_crystal_density_diffrn    2.473
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062108
Ligand-Controlled Asymmetric Induction at a Transition Metal-Bonded α-Carbon in Ester and Amide Enolates. Diastereoselective Formation of Oxapalladacycles Applied to the Synthesis of a Chiral Nonracemic 2H-1-Benzopyran.
Portscheller, Janelle L.; Lilly, Sara E.; Malinakova, Helena C.; Organometallics  (2003) –; doi:

data_4062109
_publ_section_title
;
  Ligand-Controlled Asymmetric Induction at a Transition Metal-Bonded
  \a-Carbon in Ester and Amide Enolates.  Diastereoselective Formation of
  Oxapalladacycles Applied to the Synthesis of a Chiral Nonracemic
  2H-1-Benzopyran.
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'C39 H40 O3 P2 Pd'
_chemical_formula_sum            'C39 H40 O3 P2 Pd'
_chemical_formula_weight         725.05
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 95.101(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.4777(5)
_cell_length_b                   14.8627(6)
_cell_length_c                   18.4151(8)
_cell_measurement_temperature    100(2)
_cell_volume                     3401.6(2)
_diffrn_ambient_temperature      100(2)
_exptl_crystal_density_diffrn    1.416
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               4062109
Insertion of Isocyanides into Group 4 Metal-Carbon and Metal-Nitrogen Bonds. Syntheses and DFT Calculations
Martins, Ana M.; Ascenso, José R.; de Azevedo, Cristina G.; Dias, Alberto R.; Duarte, M. Teresa; da Silva, João F.; Veiros, Luís F.; Rodrigues, Sandra S.; Organometallics 22 (2003) 4218–4228; doi:10.1021/om030211n

data_4062110
_publ_section_title
;
 Insertion of Isocyanides into Group 4 Metal-Carbon and Metal-Nitrogen Bonds.
 Syntheses and DFT Calculations
;
_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              4218
_journal_page_last               4228
_journal_paper_doi               10.1021/om030211n
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C20 H22 Cl2 N2 Ti'
_chemical_formula_weight         409.20
_chemical_name_common            '[Ti(eta5-Ind){C(NMe2)N(2,6-Me2Ph)}Cl2]'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                98.41(2)
_cell_angle_beta                 102.31(2)
_cell_angle_gamma                106.73(2)
_cell_formula_units_Z            2
_cell_length_a                   7.211(2)
_cell_length_b                   10.872(2)
_cell_length_c                   14.069(2)
_cell_measurement_temperature    293(2)
_cell_volume                     1006.4(4)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.350
_cod_database_code               4062110
Insertion of Isocyanides into Group 4 Metal-Carbon and Metal-Nitrogen Bonds. Syntheses and DFT Calculations
Martins, Ana M.; Ascenso, José R.; de Azevedo, Cristina G.; Dias, Alberto R.; Duarte, M. Teresa; da Silva, João F.; Veiros, Luís F.; Rodrigues, Sandra S.; Organometallics 22 (2003) 4218–4228; doi:10.1021/om030211n

data_4062111
_publ_section_title
;
 Insertion of Isocyanides into Group 4 Metal-Carbon and Metal-Nitrogen Bonds.
 Syntheses and DFT Calculations
;
_journal_issue                   21
_journal_name_full               Organometallics
_journal_page_first              4218
_journal_page_last               4228
_journal_paper_doi               10.1021/om030211n
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C62 H74 Cl2 N8 Zr2'
_chemical_formula_weight         1184.63
_chemical_name_common            '[Zr(eta5-Ind){C(NMe2)N(2,6-Me2Ph)}2Cl]'
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.1130(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.505(2)
_cell_length_b                   15.839(3)
_cell_length_c                   17.342(3)
_cell_measurement_temperature    293(2)
_cell_volume                     3434.9(10)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.145
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               4062111
Synthesis and Characterization of Chiral Diphosphine Platinum(II) VANOL and VAPOL Complexes
Becker, Jennifer; White, Peter; Gagne, Michel; Organometallics  (2003) –; doi:

data_4062112
_publ_section_title
;
Synthesis and Characterization of Chiral Diphosphine Platinum(II)
VANOL and VAPOL Complexes
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'Pt P2 C59 H46 O2 Cl2 '
_chemical_formula_sum            'C59 H46 Cl2 O2 P2 Pt'
_chemical_formula_weight         1114.94
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.0
_cell_angle_beta                 104.802(1)
_cell_angle_gamma                90.0
_cell_formula_units_Z            4
_cell_length_a                   18.6328(6)
_cell_length_b                   12.1003(4)
_cell_length_c                   22.1229(7)
_cell_measurement_temperature    173
_cell_volume                     4822.4(3)
_diffrn_ambient_temperature      173
_exptl_crystal_density_diffrn    1.536
_refine_ls_R_factor_obs          0.031
_refine_ls_wR_factor_obs         0.034
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_atom_site_thermal_displace_type' tag value 'Uij' was replaced with
'Uani' value 66 times.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'Pt P2 C59 H46 O2 Cl2 '
_cod_database_code               4062112
; Organometallics  (2003) –; doi:

data_4062113
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         '4(C15 H26 Al N O)'
_chemical_formula_sum            'C60 H104 Al4 N4 O4'
_chemical_formula_weight         1053.39
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                78.056(5)
_cell_angle_beta                 80.587(5)
_cell_angle_gamma                87.421(5)
_cell_formula_units_Z            2
_cell_length_a                   10.310(5)
_cell_length_b                   12.692(5)
_cell_length_c                   25.691(5)
_cell_measurement_temperature    173(2)
_cell_volume                     3245(2)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.078
_cod_database_code               4062113
; Organometallics  (2003) –; doi:

data_4062114
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'C18 H30 Al N O'
_chemical_formula_sum            'C18 H30 Al N O'
_chemical_formula_weight         303.43
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 96.603(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.7860(3)
_cell_length_b                   10.2945(4)
_cell_length_c                   18.1648(7)
_cell_measurement_temperature    183
_cell_volume                     1817.8(1)
_diffrn_ambient_temperature      183
_exptl_crystal_density_diffrn    1.11
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062114
; Organometallics  (2003) –; doi:

data_4062115
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'C52 H44 Al2 B F15 N2 O2'
_chemical_formula_sum            'C52 H44 Al2 B F15 N2 O2'
_chemical_formula_weight         1078.69
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                114.004(5)
_cell_angle_beta                 91.562(5)
_cell_angle_gamma                93.640(5)
_cell_formula_units_Z            2
_cell_length_a                   10.1644(2)
_cell_length_b                   16.1355(2)
_cell_length_c                   16.6117(3)
_cell_measurement_temperature    173
_cell_volume                     2479.59(12)
_diffrn_ambient_temperature      173
_exptl_crystal_density_diffrn    1.44
_cod_database_code               4062115
; Organometallics  (2003) –; doi:

data_4062116
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'C48 H52 Al2 B F15 N2 O2'
_chemical_formula_sum            'C48 H52 Al2 B F15 N2 O2'
_chemical_formula_weight         1038.71
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 90.479(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   16.8813(2)
_cell_length_b                   11.1788(1)
_cell_length_c                   25.4984(4)
_cell_measurement_temperature    173
_cell_volume                     4811.7(1)
_diffrn_ambient_temperature      173
_exptl_crystal_density_diffrn    1.43
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062116
Synthesis of Bimetallic Cubane-Type Mo2M2S4 Clusters (M = Ir, Rh, Ru) and Reductive Cleavage of N-N Bond of 1,1-Methylphenylhydrazine Affording N-Methylaniline Using Mo2Ir2S4 and Mo2Rh2S4 Clusters as Catalyst Precursors
Yasushi Mizobe; Organometallics  (2003) –; doi:

data_4062117
_publ_section_title
;
Synthesis of Bimetallic Cubane-Type Mo2M2S4 Clusters (M = Ir, Rh, Ru)
 and Reductive Cleavage of N-N Bond of 1,1-Methylphenylhydrazine
 Affording N-Methylaniline Using Mo2Ir2S4 and Mo2Rh2S4 Clusters as
 Catalyst Precursors
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C26 H44 Cl4 Ir2 Mo2 N2 O3 S4'
_chemical_formula_weight         1279.02
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 107.77(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.782(3)
_cell_length_b                   22.056(3)
_cell_length_c                   17.219(3)
_cell_measurement_temperature    296.2
_cell_volume                     3899(1)
_diffrn_ambient_temperature      296.2
_exptl_crystal_density_diffrn    2.178
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C26 H44 Cl4 Ir2 N2 Mo2 O3 S4 '
_cod_database_code               4062117
; Organometallics  (2003) –; doi:

data_4062118
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C65 H91.5 B2 F8 N6 Pd2'
_chemical_formula_weight         1343.36
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 113.146(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   34.094(3)
_cell_length_b                   16.5750(15)
_cell_length_c                   24.868(2)
_cell_measurement_temperature    203(2)
_cell_volume                     12921.7(19)
_diffrn_ambient_temperature      203(2)
_exptl_crystal_density_diffrn    1.381
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C65 H91.50 B2 F8 N6 Pd2'
_cod_database_code               4062118
Matsuo, Yutaka; Nakamura, Eiichi; Organometallics  (2003) –; doi:

data_4062119
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'C77 H23 Cl1 O2 Ru1'
_chemical_formula_structural     'C77 H23 CL1 O2 RU1'
_chemical_formula_sum            'C74 H23 Cl O2 Ru'
_chemical_formula_weight         1080.44
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 97.444(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.7640(6)
_cell_length_b                   16.9730(9)
_cell_length_c                   21.9850(12)
_cell_measurement_temperature    193(2)
_cell_volume                     4352.8(4)
_diffrn_ambient_temperature      193(2)
_exptl_crystal_density_diffrn    1.649
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062119
Unexpected Formation of a Weak Metal-Metal Bond: Synthesis, Electronic Properties, and Second-Order NLO Responses of Push-Pull Late-Early Heteronuclear Bimetallic Complexes with W(CO)~3~(1,10-phenanthroline) Acting as a Donor Ligand
Pizzotti, Maddalena; Ugo, Renato; Dragonetti, Claudia; Annoni, Elisabetta; Demartin, Francesco; Mussini, Patrizia; Organometallics 22 (2003) 4001–4011; doi:10.1021/om030247f

data_4062120
_publ_section_title
;
 Unexpected Formation of a Weak Metal-Metal Bond: Synthesis,
 Electronic Properties, and Second-Order NLO Responses of Push-Pull Late-Early
 Heteronuclear Bimetallic Complexes with W(CO)~3~(1,10-phenanthroline) Acting
 as a Donor Ligand
;
_journal_issue                   20
_journal_name_full               Organometallics
_journal_page_first              4001
_journal_page_last               4011
_journal_paper_doi               10.1021/om030247f
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C17 H8 Cl Ir N2 O5 W'
_chemical_formula_weight         731.75
_space_group_IT_number           18
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2 2ab'
_symmetry_space_group_name_H-M   'P 21 21 2'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.337(4)
_cell_length_b                   17.050(9)
_cell_length_c                   6.905(8)
_cell_measurement_temperature    293(2)
_cell_volume                     2041.1(26)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    2.381
_refine_ls_R_factor_obs          0.0488
_refine_ls_wR_factor_obs         0.1203
_cod_database_code               4062120
Unexpected Formation of a Weak Metal-Metal Bond: Synthesis, Electronic Properties, and Second-Order NLO Responses of Push-Pull Late-Early Heteronuclear Bimetallic Complexes with W(CO)~3~(1,10-phenanthroline) Acting as a Donor Ligand
Pizzotti, Maddalena; Ugo, Renato; Dragonetti, Claudia; Annoni, Elisabetta; Demartin, Francesco; Mussini, Patrizia; Organometallics 22 (2003) 4001–4011; doi:10.1021/om030247f

data_4062121
_publ_section_title
;
 Unexpected Formation of a Weak Metal-Metal Bond: Synthesis,
 Electronic Properties, and Second-Order NLO Responses of Push-Pull Late-Early
 Heteronuclear Bimetallic Complexes with W(CO)~3~(1,10-phenanthroline) Acting
 as a Donor Ligand
;
_journal_issue                   20
_journal_name_full               Organometallics
_journal_page_first              4001
_journal_page_last               4011
_journal_paper_doi               10.1021/om030247f
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C18 H8 Cl2 N2 O6 Os W'
_chemical_formula_weight         793.21
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                83.580(10)
_cell_angle_beta                 88.500(10)
_cell_angle_gamma                82.000(10)
_cell_formula_units_Z            2
_cell_length_a                   7.3963(7)
_cell_length_b                   11.3377(11)
_cell_length_c                   12.3266(12)
_cell_measurement_temperature    293(2)
_cell_volume                     1017.1(2)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    2.590
_refine_ls_R_factor_obs          0.0305
_refine_ls_wR_factor_obs         0.0747
_cod_database_code               4062121
; Organometallics  (2003) –; doi:

data_4062122
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C38 H16 Cu4 F20'
_chemical_formula_weight         1106.67
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 91.7160(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.2253(9)
_cell_length_b                   15.3381(9)
_cell_length_c                   15.8026(9)
_cell_measurement_temperature    173(2)
_cell_volume                     3688.7(4)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.993
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062122
; Organometallics  (2003) –; doi:

data_4062123
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C25 H2 Cl Cu4 F20'
_chemical_formula_weight         971.88
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                86.9080(10)
_cell_angle_beta                 88.6850(10)
_cell_angle_gamma                79.9220(10)
_cell_formula_units_Z            2
_cell_length_a                   10.3875(6)
_cell_length_b                   10.8497(6)
_cell_length_c                   12.1005(6)
_cell_measurement_temperature    100(2)
_cell_volume                     1340.62(13)
_diffrn_ambient_temperature      100(2)
_exptl_crystal_density_diffrn    2.408
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062123
Germylene Reactions with Quinones Shed Light on Germylene Phenone Equilibria
Sweeder, Ryan D.; Gdula, Robyn L.; Ludwig, Bonnie J.; Banaszak Holl, Mark M.; Kampf, Jeff W.; Organometallics 22 (2003) 3222–3229; doi:10.1021/om0302589

data_4062124
_publ_section_title
;
 Germylene Reactions with Quinones Shed Light on Germylene Phenone Equilibria
;
_journal_coden_ASTM              ORGND7
_journal_issue                   16
_journal_name_full               Organometallics
_journal_page_first              3222
_journal_page_last               3229
_journal_paper_doi               10.1021/om0302589
_journal_volume                  22
_journal_year                    2003
_chemical_formula_sum            'C42 H84 Ge2 O2 Si8'
_chemical_formula_weight         990.99
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 105.339(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.5817(11)
_cell_length_b                   19.9366(16)
_cell_length_c                   22.2808(18)
_cell_measurement_temperature    133(2)
_cell_volume                     5818.1(8)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.131
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

 Updated bibliographical information.

 Antanas Vaitkus,
 2019-09-11
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062124