Imino exchange reaction in a dearomatization strategy: synthesis of N-acyl diarylamines and phenothiazines from two anilines
Zhang, Li; Wang, Huiqing; Yang, Bo; Fan, Renhua; Org. Chem. Front. 1 (2014) 1055–; doi:10.1039/C4QO00201F

data_1553027
_publ_section_title
;
 Imino exchange reaction in a dearomatization strategy: synthesis of
 N-acyl diarylamines and phenothiazines from two anilines
;
_journal_issue                   9
_journal_name_full               'Org. Chem. Front.'
_journal_page_first              1055
_journal_paper_doi               10.1039/C4QO00201F
_journal_volume                  1
_journal_year                    2014
_chemical_formula_sum            'C22 H18 F3 N O'
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_space_group_name_Hall           '-P 2ybc'
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_audit_creation_method           SHELXL-2013
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_cell_angle_gamma                90
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_cell_length_b                   10.644(4)
_cell_length_c                   18.906(8)
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_cell_measurement_temperature    293(2)
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_cell_measurement_theta_min      2.207
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_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
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_computing_structure_solution    'Bruker SHELXTL'
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_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -14
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_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.987
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_exptl_crystal_size_mid          0.200
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         3993
_refine_ls_number_restraints     42
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_refine_ls_R_factor_gt           0.0616
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; 
 w=1/[\s^2^(Fo^2^)+(0.0921P)^2^] 
 where P=(Fo^2^+2Fc^2^)/3 
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1495
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_cod_original_cell_volume        1857.1(13)
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_shelx_hkl_checksum              10767