Identification of a Nitrenoid Reductive Elimination Pathway in Nickel-Catalyzed C–N Cross-Coupling
Simon, Connor M.; Dudra, Samantha L.; McGuire, Ryan T.; Ferguson, Michael J.; Johnson, Erin R.; Stradiotto, Mark; ACS Catalysis 12 (2022) 1475–1480; doi:10.1021/acscatal.1c05386

data_4519297
_publ_section_title
;
 Identification of a Nitrenoid Reductive Elimination Pathway in
 Nickel-Catalyzed C--N Cross-Coupling
;
_journal_issue                   2
_journal_name_full               'ACS Catalysis'
_journal_page_first              1475
_journal_page_last               1480
_journal_paper_doi               10.1021/acscatal.1c05386
_journal_volume                  12
_journal_year                    2022
_chemical_formula_moiety         'C42 H45 N Ni O5 P2 S, C6 H6'
_chemical_formula_sum            'C48 H51 N Ni O5 P2 S'
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_point_group_measured_fraction_full 0.967
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_exptl_absorpt_process_details
; 
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D., 
 J. Appl. Cryst. 48 (2015) 3-10 
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0420P)^2^+2.0232P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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