Luminescence properties of some monomeric and dimeric cycloplatinated(ii) complexes containing biphosphine ligands.
Aghakhanpour, Reza Babadi; Nabavizadeh, S. Masoud; Rashidi, Mehdi; Kubicki, Maciej; Dalton transactions (Cambridge, England : 2003) 44 (2015) 15829–15842; doi:10.1039/c5dt02450a

data_7035981
_publ_section_title
;
 Luminescence properties of some monomeric and dimeric cycloplatinated(ii)
 complexes containing biphosphine ligands.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15829
_journal_page_last               15842
_journal_paper_doi               10.1039/c5dt02450a
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C37 H32 N P2 Pt, Cl'
_chemical_formula_sum            'C37 H32 Cl N P2 Pt'
_chemical_formula_weight         783.11
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           60
_space_group_name_Hall           '-P 2n 2ab'
_space_group_name_H-M_alt        'P b c n'
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
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_audit_creation_method           SHELXL-2013
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;
2015-07-24 deposited with the CCDC.
2015-07-29 downloaded from the CCDC.
;
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_computing_cell_refinement       'CrysAlis Pro (Oxford Diffraction (2009))'
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; 
SHELXTL (Sheldrick, 2008), Mercury (Macrae et al., 2008)
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_computing_publication_material  'SHELXL-2013 (Sheldrick, 2008)'
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_diffrn_ambient_temperature      295(2)
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_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       '/w scan'
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_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.0652
_diffrn_reflns_av_unetI/netI     0.0462
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_diffrn_reflns_laue_measured_fraction_max 0.998
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_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -24
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_diffrn_reflns_limit_l_min       -20
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_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.000
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_diffrn_reflns_theta_min         3.123
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_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.34376
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.21 (release 20-01-2012 CrysAlis171 .NET)
(compiled Jan 23 2012,18:06:46)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.622
_exptl_crystal_description       plate
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_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.965
_refine_diff_density_min         -2.020
_refine_diff_density_rms         0.129
_refine_ls_extinction_method     none
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_refine_ls_number_reflns         5644
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0611
_refine_ls_R_factor_gt           0.0416
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0722P)^2^+2.3256P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1100
_refine_ls_wR_factor_ref         0.1248
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4289
_reflns_number_total             5644
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt02450a2.cif
_cod_data_source_block           3a
_cod_depositor_comments
'Adding full bibliography for 7035981--7035984.cif.'
_cod_database_code               7035981
_shelxl_version_number           2013-4
_shelx_res_checksum              32293