A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres.
Streuff, Jan; White, David E.; Virgil, Scott C.; Stoltz, Brian M.; Nature chemistry 2 (2010) 192–196; doi:10.1038/nchem.518

data_1508011
_publ_section_title
;
 A palladium-catalysed enolate alkylation cascade for the formation of
 adjacent quaternary and tertiary stereocentres.
;
_journal_issue                   3
_journal_name_full               'Nature chemistry'
_journal_page_first              192
_journal_page_last               196
_journal_paper_doi               10.1038/nchem.518
_journal_volume                  2
_journal_year                    2010
_chemical_absolute_configuration ad
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_refine_ls_weighting_scheme' value 'Sigma' changed to
'sigma' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_atom_sites_solution_primary' value 'Direct methods' was changed to
'direct'.

'_atom_sites_solution_secondary' value 'Difference Fourier map' was
changed to 'difmap'.

'_atom_sites_solution_hydrogens' value 'Difference Fourier map' was
changed to 'difmap'.

Automatic conversion script
Id: cif_fix_values 6452 2018-10-05 10:23:21Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)2(1)2(1)
_cod_database_code               1508011