Nanoscale layer-separated zincophosphate framework enabled by dual-mode aromatic pillar engineering for selective luminescent dye detection.
Jian, Jia-Yi; Wei, Pi-Chen; Chang, Kai-Chi; Hsu, Chun-Ru; Lu, Ching-Ping; Wang, Chih-Min; Dalton transactions (Cambridge, England : 2003)  (2026) –; doi:10.1039/d6dt00476h

data_7720861
_publ_section_title
;
 Nanoscale layer-separated zincophosphate framework enabled by dual-mode
 aromatic pillar engineering for selective luminescent dye detection.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6503
_journal_page_last               6509
_journal_paper_doi               10.1039/d6dt00476h
_journal_volume                  55
_journal_year                    2026
_chemical_formula_sum            'C110 H81 N10 O24 P6 Zn8'
_chemical_formula_weight         2635.63
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2025-12-16 deposited with the CCDC.	2026-04-01 downloaded from the CCDC.
;
_cell_angle_alpha                100.8440(10)
_cell_angle_beta                 102.8970(10)
_cell_angle_gamma                98.8790(10)
_cell_formula_units_Z            2
_cell_length_a                   13.3935(5)
_cell_length_b                   18.8575(6)
_cell_length_c                   22.5482(8)
_cell_measurement_reflns_used    15238
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.39
_cell_measurement_theta_min      2.39
_cell_volume                     5336.3(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0933
_diffrn_reflns_av_sigmaI/netI    0.0839
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            113656
_diffrn_reflns_theta_full        25.39
_diffrn_reflns_theta_max         25.39
_diffrn_reflns_theta_min         1.12
_exptl_absorpt_coefficient_mu    1.935
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.640
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2666
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.679
_refine_diff_density_min         -0.948
_refine_diff_density_rms         0.173
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1423
_refine_ls_number_reflns         19534
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.0824
_refine_ls_R_factor_gt           0.0681
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1408P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1852
_refine_ls_wR_factor_ref         0.2002
_reflns_number_gt                15238
_reflns_number_total             19534
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            d6dt00476h2.cif
_cod_data_source_block           NTOU-11
_cod_depositor_comments          'Adding full bibliography for 7720861.cif.'
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7720861