Crystal-glass phase transition enabling reversible fluorescence switching in zero-dimensional antimony halides
Yin, Meijuan; Li, Baihan; Yi, Zishuo; Zhang, Yuchi; Xia, Zhiguo; Xu, Yan; Chemical Communications  (2023) –; doi:10.1039/D3CC03752E

data_7132072
_publ_section_title
;
 Crystal-glass phase transition enabling reversible fluorescence switching
 in zero-dimensional antimony halides
;
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/D3CC03752E
_journal_year                    2023
_chemical_formula_sum            'C44 H48 Cl5 P2 Sb'
_chemical_formula_weight         937.76
_space_group_crystal_system      monoclinic
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_atom_sites_solution_hydrogens   geom
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_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2023-08-01 deposited with the CCDC.	2023-08-30 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      293(2)
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_diffrn_measured_fraction_theta_max 0.857
_diffrn_measurement_device_type  'Bruker PHOTON2 CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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;
SADABS-2004/1. Bruker AXS Inc., Madison, Wisconsin, USA, 2004
;
_exptl_crystal_colour            colorless
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_refine_ls_number_reflns         5152
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.998
_refine_ls_R_factor_all          0.0747
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0310P)^2^+2.5918P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             5152
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_original_cell_volume        2203.2(6)
_cod_original_sg_symbol_H-M      'P 21/c'
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