Facile Styrene Formation from Ethylene and a Phenylplatinum(II) Complex Leading to an Observable Platinum(II) Hydride
Pal, Shrinwantu; Kusumoto, Shuhei; Nozaki, Kyoko; Organometallics 36 (2017) 502–; doi:10.1021/acs.organomet.6b00892

data_4086952
_publ_section_title
;
 Facile Styrene Formation from Ethylene and a Phenylplatinum(II) Complex
 Leading to an Observable Platinum(II) Hydride
;
_journal_issue                   3
_journal_name_full               Organometallics
_journal_page_first              502
_journal_paper_doi               10.1021/acs.organomet.6b00892
_journal_volume                  36
_journal_year                    2017
_chemical_formula_sum            'C34 H48 K O5 P Pt S'
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_space_group_crystal_system      monoclinic
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_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
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Rigaku CrystalClear-SM Expert 2.0 r3
;
_computing_data_collection
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Rigaku CrystalClear-SM Expert 2.0 r3
;
_computing_data_reduction
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Rigaku CrystalClear-SM Expert 2.0 r3
;
_computing_molecular_graphics
'Yadokari-XG 2009 (Wakita Nemoto et al., 2009)'
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'Yadokari-XG 2009 (Wakita,Nemoto et al., 2009)'
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_diffrn_ambient_temperature      93
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Rigaku CrystalClear-SM Expert 2.0 r3
;
_diffrn_measurement_method       'profile data from \w-scans'
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_diffrn_reflns_limit_k_min       -19
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_diffrn_source                   'Rotating Anode'
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_exptl_crystal_colour            Colorless
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_exptl_crystal_description       Prism
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_refine_ls_R_factor_all          0.0731
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0327P)^2^+38.6331P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1220
_refine_ls_wR_factor_ref         0.1301
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9418
_reflns_number_total             10563
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            complex6.cif
_cod_data_source_block           complex6
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Numerical' changed to
'numerical' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 4086950--4086953.cif.
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4086952
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.477
_shelx_estimated_absorpt_t_max   0.918
_shelx_res_checksum              97788
_shelx_hkl_checksum              51314