Stereoselective synthesis of difunctionalized succinimides from aza-1,6-enynes by radical cascade reaction.
Meena, Shivam A.; Sharma, Poonam; Verma, Akhilesh K.; Chemical communications (Cambridge, England) 59 (2023) 7271–7274; doi:10.1039/d3cc01391j

data_7131629
_publ_section_title
;
 Stereoselective synthesis of difunctionalized succinimides from
 aza-1,6-enynes by radical cascade reaction.
;
_journal_issue                   47
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              7271
_journal_page_last               7274
_journal_paper_doi               10.1039/d3cc01391j
_journal_volume                  59
_journal_year                    2023
_chemical_formula_moiety         'C32 H26 Cl N O4 S Se'
_chemical_formula_sum            'C32 H26 Cl N O4 S Se'
_chemical_formula_weight         635.01
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_audit_creation_method           SHELXL-2019/1
_audit_update_record
;
2022-07-04 deposited with the CCDC.	2023-05-15 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_diffrn_radiation_type           MoK\a
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_exptl_absorpt_coefficient_mu    1.563
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.518
_exptl_crystal_description       block
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_exptl_crystal_size_min          0.16
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_refine_ls_extinction_method     none
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.998
_refine_ls_R_factor_all          0.0448
_refine_ls_R_factor_gt           0.0323
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0300P)^2^+1.7898P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0725
_refine_ls_wR_factor_ref         0.0785
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5735
_reflns_number_total             6906
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3cc01391j2.cif
_cod_data_source_block           mo_SMP27_0m_a
_cod_depositor_comments
'Adding full bibliography for 7131628--7131629.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
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