Reactions of Triosmium Carbonyl Clusters with Thionylaniline. Crystal Structures of Os~3~(CO)~9~(μ~3~-NPh)(μ~3~-S), Os~3~(CO)~9~(μ~3~,η^2^-(PhN)~2~SO)(μ~3~-S), and Os~3~(CO)~8~(NCMe)(μ~3~-NPh)(μ~3~-S).
Wen-Yann Yeh; Charlotte L. Stern; Duward F. Shriver; Inorganic Chemistry 36 (1997) 4408–4414; doi:10.1021/ic961153j

data_4323583
_publ_contact_author
;
D.F. Shriver
Department of Chemistry
Northwestern University
Evanston, IL 60208-3113, USA
;
_publ_contact_author_email       ' Shriver@chem.nwu.edu '
_publ_contact_author_fax         ' 847-491-7713 '
_publ_contact_author_phone       ' 847-491-5655'
_publ_section_title
;
 Reactions of Triosmium Carbonyl Clusters with Thionylaniline. Crystal
 Structures of Os~3~(CO)~9~(\m~3~-NPh)(\m~3~-S),
 Os~3~(CO)~9~(\m~3~,\h^2^-(PhN)~2~SO)(\m~3~-S), and
 Os~3~(CO)~8~(NCMe)(\m~3~-NPh)(\m~3~-S).
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4408
_journal_page_last               4414
_journal_paper_doi               10.1021/ic961153j
_journal_volume                  36
_journal_year                    1997
_chemical_formula_sum            'C16 H8 N2 O8 Os3 S'
_chemical_formula_weight         958.91
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_symmetry_space_group_name_Hall  '-P 2yn'
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_audit_creation_date             'Wed Jul 16 10:33:36 1997'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                90
_cell_angle_beta                 93.72(2)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   18.792(3)
_cell_length_b                   8.856(3)
_cell_length_c                   26.210(9)
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_cell_measurement_temperature    153.2
_cell_measurement_theta_max      24.0
_cell_measurement_theta_min      21.0
_cell_volume                     4353(2)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
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_refine_ls_shift/esd_max         0.0100
_refine_ls_structure_factor_coef F
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_cod_original_cell_volume        4352(1)
_cod_original_sg_symbol_H-M      'P 21/n '
_cod_original_formula_sum        'C16 H8 N2 O8 Os3 S '
_cod_database_code               4323583