Effects of diminished steric protection at phosphorus on stability and reactivity of oxaphosphirane complexes.
Fassbender, J.; Schnakenburg, G.; Espinosa Ferao, A.; Streubel, R.; Dalton transactions (Cambridge, England : 2003) 47 (2018) 9347–9354; doi:10.1039/c8dt01979g

data_7046903
_publ_section_title
;
 Effects of diminished steric protection at phosphorus on stability and
 reactivity of oxaphosphirane complexes.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9347
_journal_page_last               9354
_journal_paper_doi               10.1039/c8dt01979g
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C23 H11 F10 O7 P W'
_chemical_formula_sum            'C23 H11 F10 O7 P W'
_chemical_formula_weight         804.14
_chemical_name_systematic        JF-85
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
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Olex2 1.2
(compiled 2015.01.26 svn.r3150 for OlexSys, GUI svn.r4998)
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;
2016-03-24 deposited with the CCDC.
2018-06-15 downloaded from the CCDC.
;
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'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[\s^2^(Fo^2^)+(0.0378P)^2^]
 where P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 7046902--7046905.cif.'
_cod_database_code               7046903
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C1(H1), C2(H2)
2.b Idealised Me refined as rotating group:
 C16(H16A,H16B,H16C), C17(H17A,H17B,H17C), C18(H18A,H18B,H18C)
;
_shelx_res_checksum              23552
_olex2_submission_special_instructions 'No special instructions were received'