A radical coupled pathway to a stable and terminally bound titanium methylidene.
Kurogi, Takashi; Carroll, Patrick J.; Mindiola, Daniel J.; Chemical communications (Cambridge, England) 53 (2017) 3412–3414; doi:10.1039/c7cc00371d

data_7119700
_publ_section_title
;
 A radical coupled pathway to a stable and terminally bound titanium
 methylidene.
;
_journal_issue                   24
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3412
_journal_page_last               3414
_journal_paper_doi               10.1039/c7cc00371d
_journal_volume                  53
_journal_year                    2017
_chemical_formula_moiety         'C37 H64 N2 O P2 Ti, 0.5(C5 H12)'
_chemical_formula_sum            'C39.5 H70 N2 O P2 Ti'
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_chemical_properties_physical    ', Air-sensitive,Moisture-sensitive'
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_space_group_name_Hall           '-P 1'
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Olex2 1.2
(compiled 2016.11.30 svn.r3368 for OlexSys, GUI svn.r5269)
;
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;
2017-01-16 deposited with the CCDC.
2017-02-20 downloaded from the CCDC.
;
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'w=1/[\s^2^(Fo^2^)+(0.0383P)^2^+2.8484P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 7119699--7119700.cif.'
_cod_original_formula_sum        'C39.50 H70 N2 O P2 Ti'
_cod_database_code               7119700
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_olex2_submission_special_instructions 'No special instructions were received'