Unmasking the Catalytic Activity of a Platinum Complex with a Lewis Acidic, Non-innocent Antimony Ligand.
You, Di; Gabbaï, François P; Journal of the American Chemical Society 139 (2017) 6843–6846; doi:10.1021/jacs.7b03287

data_4126040
_publ_section_title
;
 Unmasking the Catalytic Activity of a Platinum Complex with a Lewis
 Acidic, Non-innocent Antimony Ligand.
;
_journal_issue                   20
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              6843
_journal_page_last               6846
_journal_paper_doi               10.1021/jacs.7b03287
_journal_volume                  139
_journal_year                    2017
_chemical_formula_moiety         'C38 H28 Cl F6 O6 P2 Pt S2 Sb'
_chemical_formula_sum            'C38 H28 Cl F6 O6 P2 Pt S2 Sb'
_chemical_formula_weight         1172.95
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2017-03-06
_audit_creation_method
;
Olex2 1.2
(compiled 2017.03.02 svn.r3394 for OlexSys, GUI svn.r5324)
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_cell_length_c                   17.657(3)
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_cell_measurement_temperature    110(2)
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_cell_measurement_theta_min      2.17
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_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      110(2)
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_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0266
_diffrn_reflns_av_unetI/netI     0.0349
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.994
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_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            22234
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.022
_diffrn_reflns_theta_min         2.157
_exptl_absorpt_coefficient_mu    4.174
_exptl_absorpt_correction_T_max  0.7454
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0853 before and 0.0521 after correction.
The Ratio of minimum to maximum transmission is 0.8326.
The \l/2 correction factor is 0.00150.
;
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
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_exptl_crystal_description       block
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0345P)^2^+1.9358P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0652
_refine_ls_wR_factor_ref         0.0683
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7510
_reflns_number_total             8444
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           dyc105_0m_sq
_cod_depositor_comments          'Adding full bibliography for 4126040.cif.'
_cod_original_cell_volume        2153.3(6)
_cod_database_code               4126040
_shelx_shelxl_version_number     2014/7
_olex2_refinement_description
;
1. Others
 Fixed Uiso: H2(0.045) H3(0.054) H4(0.046) H5(0.036) H18(0.032) H8(0.04)
 H9(0.048) H10(0.045) H11(0.035) H14(0.032) H15(0.036) H30(0.028) H16(0.04)
 H17(0.04) H24(0.035) H23(0.044) H22(0.044) H20(0.029) H32(0.036) H26(0.03)
 H27(0.039) H36(0.044) H28(0.041) H35(0.057) H29(0.038) H21(0.038) H34(0.053)
 H33(0.05)
 Fixed X: H2(1.3956) H3(1.6126) H4(1.7552) H5(1.6873) H18(1.6622) H8(1.0142)
 H9(0.7839) H10(0.6469) H11(0.7389) H14(1.4768) H15(1.6092) H30(0.9559)
 H16(1.7668) H17(1.7915) H24(1.3962) H23(1.4102) H22(1.5106) H20(1.5924)
 H32(0.7788) H26(0.927) H27(0.8793) H36(1.0466) H28(0.8673) H35(0.9424)
 H29(0.9011) H21(1.605) H34(0.7511) H33(0.6772)
 Fixed Y: H2(-0.0782) H3(-0.1294) H4(-0.0462) H5(0.0803) H18(-0.0568)
 H8(0.0334) H9(0.0943) H10(0.237) H11(0.323) H14(0.23) H15(0.1311) H30(0.4057)
 H16(-0.0584) H17(-0.1526) H24(0.3264) H23(0.5092) H22(0.5967) H20(0.3172)
 H32(0.5092) H26(0.1124) H27(0.0538) H36(0.4442) H28(0.1704) H35(0.6391)
 H29(0.3487) H21(0.4992) H34(0.7664) H33(0.7047)
 Fixed Z: H2(0.9125) H3(0.9334) H4(0.847) H5(0.7349) H18(0.6485) H8(0.9313)
 H9(0.9651) H10(0.881) H11(0.7635) H14(0.5001) H15(0.3926) H30(0.5246)
 H16(0.4137) H17(0.5404) H24(0.7788) H23(0.7773) H22(0.663) H20(0.553)
 H32(0.6248) H26(0.6699) H27(0.5672) H36(0.7634) H28(0.4455) H35(0.7917)
 H29(0.4244) H21(0.5532) H34(0.7396) H33(0.6513)
;
_shelx_res_checksum              25816
_shelx_hkl_checksum              93120
_shelx_fab_checksum              22605
_olex2_submission_special_instructions 'No special instructions were received'