Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity
M. Angeles Alvarez; M. Esther García; Daniel García-Vivó; Alberto Ramos; Miguel A. Ruiz; Jaime Suárez; Inorganic Chemistry 51 (2012) 34–36; doi:10.1021/ic2023456

data_4327917
_publ_section_title
;
 Symmetrization in a Phosphinidene-Bridged Complex To Give a
 Diphosphanediyl Derivative with Metal-Centered Reactivity
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              34
_journal_page_last               36
_journal_paper_doi               10.1021/ic2023456
_journal_volume                  51
_journal_year                    2012
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C46 H70 Mo2 P2, 2(C H2 Cl2), 2(B F4)'
_chemical_formula_sum            'C48 H74 B2 Cl4 F8 Mo2 P2'
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_chemical_name_systematic
;
 ?
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CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
;
_computing_data_collection
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CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
;
_computing_data_reduction
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CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
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_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0568
_diffrn_reflns_limit_h_max       12
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CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.36 (release 02-08-2010 CrysAlis171 .NET)
(compiled Aug  2 2010,13:00:58)
empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
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_refine_ls_R_factor_gt           0.0518
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0962P)^2^+0.1368P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1326
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_reflns_number_gt                4869
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_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            ic2023456_si_002_2.cif
_cod_data_source_block           compound3
_cod_original_cell_volume        1373.51(10)
_cod_database_code               4327917