MnSO<sub>4</sub>-promoted S-O bond cleavage for synthesizing functionalized sulfonium ylides from activated alkynes and sulfoxides.
Chen, Wei-Li; Liu, Zhang-Wei; Wang, Ying-Chun; Ma, Xiao-Pan; Mo, Dong-Liang; Organic & biomolecular chemistry 20 (2022) 1656–1661; doi:10.1039/d1ob02491d

data_7158522
_publ_section_title
;
 MnSO<sub>4</sub>-promoted S-O bond cleavage for synthesizing
 functionalized sulfonium ylides from activated alkynes and sulfoxides.
;
_journal_issue                   8
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              1656
_journal_page_last               1661
_journal_paper_doi               10.1039/d1ob02491d
_journal_volume                  20
_journal_year                    2022
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C10 H16 O5 S'
_chemical_formula_sum            'C10 H16 O5 S'
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2019-09-03 deposited with the CCDC.	2022-02-01 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
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_cell_length_b                   10.698(5)
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_cell_measurement_theta_min      2.69
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_computing_cell_refinement       'SAINT v8.27A (Bruker, 2012)'
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_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement
;
XL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution
;
XS, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0645P)^2^+0.0778P] where P=(Fo^2^+2Fc^2^)/3'
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_refine_ls_wR_factor_ref         0.1026
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_cod_depositor_comments          'Adding full bibliography for 7158522.cif.'
_cod_database_code               7158522
_olex2_submission_special_instructions 'No special instructions were received'