Chan–Evans–Lam Couplings with Copper Iminoarylsulfonate Complexes: Scope and Mechanism
Hardouin Duparc, Valérie; Bano, Guillaume L.; Schaper, Frank; ACS Catalysis 8 (2018) 7308–; doi:10.1021/acscatal.8b01881

data_4515564
_publ_section_title
;
 Chan--Evans--Lam Couplings with Copper Iminoarylsulfonate Complexes:
 Scope and Mechanism
;
_journal_issue                   8
_journal_name_full               'ACS Catalysis'
_journal_page_first              7308
_journal_paper_doi               10.1021/acscatal.8b01881
_journal_volume                  8
_journal_year                    2018
_chemical_formula_moiety         'C13 H13 Cu N2 O4 S, C F3 O3 S'
_chemical_formula_sum            'C14 H13 Cu F3 N2 O7 S2'
_chemical_formula_weight         505.92
_space_group_crystal_system      triclinic
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Olex2 1.2
(compiled 2017.03.28 svn.r3405 for OlexSys, GUI svn.r5337)
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
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'w=1/[\s^2^(Fo^2^)+(0.0583P)^2^+0.4458P] where P=(Fo^2^+2Fc^2^)/3'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2.a Rotating group:
 O1(H1A,H1B)
2.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C6(H6), C8(H8), C9(H9), C11(H11)
2.c Idealised Me refined as rotating group:
 C13(H13A,H13B,H13C)
;
_shelx_res_checksum              30062
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_olex2_submission_special_instructions 'No special instructions were received'