LMucko/crystallography-open-database huggingface dataset:
Oxidative Coupling of Alkynes mediated by [RuCp(SbR3)(CH3CN)2]+ (R = Ph, n-Bu): Metallacyclopentatriene Intermediates and the Formation of Butadienyl Carbenes
Becker, Eva; Mereiter, Kurt; Puchberger, Michael; Schmid, Roland; Kirchner, Karl; Organometallics  (2003) –; doi:

data_4062008
_publ_section_title
;
Oxidative Coupling of Alkynes mediated by [RuCp(SbR3)(CH3CN)2]+
(R = Ph, n-Bu):  Metallacyclopentatriene Intermediates and the
Formation of Butadienyl Carbenes
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'C41 H36 Ru Sb 1+,  F6 P 1-'
_chemical_formula_sum            'C41 H36 F6 P Ru Sb'
_chemical_formula_weight         896.49
_chemical_name_common
;
trans-[CpRu(eta3-CH2C(CH2Ph)CH-eta1-C=CH-Ph)(SbPh3)]PF6
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 98.01(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.382(4)
_cell_length_b                   18.470(6)
_cell_length_c                   14.760(5)
_cell_measurement_temperature    223(2)
_cell_volume                     3613(2)
_diffrn_ambient_temperature      223(2)
_exptl_crystal_density_diffrn    1.648
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062008
; Organometallics  (2003) –; doi:

data_4062009
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C17 H15 N O'
_chemical_formula_weight         249.30
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 94.882(9)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.5260(8)
_cell_length_b                   10.4956(10)
_cell_length_c                   15.3645(16)
_cell_measurement_temperature    173(2)
_cell_volume                     1369.9(2)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.209
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062009
; Organometallics  (2003) –; doi:

data_4062010
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C20 H21 N O4'
_chemical_formula_weight         339.38
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   11.9844(11)
_cell_length_b                   14.5392(14)
_cell_length_c                   19.9966(18)
_cell_measurement_temperature    133(2)
_cell_volume                     3484.3(6)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.294
_cod_database_code               4062010
; Organometallics  (2003) –; doi:

data_4062011
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C13 H17.22 N O2.11'
_chemical_formula_weight         221.26
_space_group_IT_number           88
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-I 4ad'
_symmetry_space_group_name_H-M   'I 41/a :2'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   17.8744(14)
_cell_length_b                   17.8744(14)
_cell_length_c                   15.6983(18)
_cell_measurement_temperature    133(2)
_cell_volume                     5015.5(8)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.172
_cod_original_sg_symbol_H-M      'I 41/a'
_cod_database_code               4062011
; Organometallics  (2003) –; doi:

data_4062012
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C17 H17 N O'
_chemical_formula_weight         251.32
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 110.02
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.2829(12)
_cell_length_b                   11.5491(12)
_cell_length_c                   10.1581(11)
_cell_measurement_temperature    173(2)
_cell_volume                     1353.9(2)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.233
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062012
; Organometallics  (2003) –; doi:

data_4062013
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C36 H38 N3 O2.5'
_chemical_formula_weight         552.69
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 94.002(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   10.9302(11)
_cell_length_b                   25.491(2)
_cell_length_c                   21.9214(18)
_cell_measurement_temperature    133(2)
_cell_volume                     6092.8(10)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.205
_cod_depositor_comments
;
The following automatic conversions were performed:
'_geom_bond_publ_flag' value 'Y' changed to 'y' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (86 times).

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062013
; Organometallics  (2003) –; doi:

data_4062014
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C36 H37 N3 O2'
_chemical_formula_weight         543.69
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.116(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.1747(14)
_cell_length_b                   15.6855(18)
_cell_length_c                   15.9240(18)
_cell_measurement_temperature    133(2)
_cell_volume                     3040.9(6)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.188
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4062014
; Organometallics  (2003) –; doi:

data_4062015
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C9 H6 O2'
_chemical_formula_weight         146.14
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 96.419(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   7.7327(8)
_cell_length_b                   13.3949(14)
_cell_length_c                   13.5108(14)
_cell_measurement_temperature    133(2)
_cell_volume                     1390.7(3)
_diffrn_ambient_temperature      133(2)
_exptl_crystal_density_diffrn    1.396
_cod_original_sg_symbol_H-M      'C c'
_cod_database_code               4062015
; Organometallics  (2003) –; doi:

data_4062016
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C32 H30 Cl2 N4 Ti'
_chemical_formula_weight         589.40
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   15.5864(7)
_cell_length_b                   16.2149(7)
_cell_length_c                   23.5128(11)
_cell_measurement_temperature    180(2)
_cell_volume                     5942.4(5)
_diffrn_ambient_temperature      180(2)
_exptl_crystal_density_diffrn    1.318
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062016
; Organometallics  (2003) –; doi:

data_4062017
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C9 H5 O S4 Sb'
_chemical_formula_weight         379.12
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 99.06(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   10.087(2)
_cell_length_b                   16.123(3)
_cell_length_c                   14.689(3)
_cell_measurement_temperature    293(2)
_cell_volume                     2359.1(8)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    2.135
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062017
; Organometallics  (2003) –; doi:

data_4062018
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C20 H29 N2 O2 S8 Sb'
_chemical_formula_weight         707.68
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.606(3)
_cell_length_b                   14.742(3)
_cell_length_c                   16.379(3)
_cell_measurement_temperature    250(2)
_cell_volume                     3044.0(10)
_diffrn_ambient_temperature      250(2)
_exptl_crystal_density_diffrn    1.544
_cod_database_code               4062018
; Organometallics  (2003) –; doi:

data_4062019
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C26 H30 N O2 S8 Sb'
_chemical_formula_weight         766.74
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 112.161(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.1301(10)
_cell_length_b                   12.5159(10)
_cell_length_c                   17.0510(10)
_cell_measurement_temperature    293(2)
_cell_volume                     3188.0(4)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.597
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062019
; Organometallics  (2003) –; doi:

data_4062020
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C26 H30 N O2 S8 Sb'
_chemical_formula_weight         766.74
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   18.886(4)
_cell_length_b                   12.885(3)
_cell_length_c                   26.254(5)
_cell_measurement_temperature    293(2)
_cell_volume                     6389(2)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.594
_cod_database_code               4062020
; Organometallics  (2003) –; doi:

data_4062021
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C26 H30 N S10 Sb'
_chemical_formula_weight         798.86
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 112.94(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.800(3)
_cell_length_b                   12.457(3)
_cell_length_c                   17.418(4)
_cell_measurement_temperature    293(2)
_cell_volume                     3356.6(12)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.581
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062021
; Organometallics  (2003) –; doi:

data_4062022
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C26 H30 N O S9 Sb'
_chemical_formula_weight         782.80
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 112.92(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.503(3)
_cell_length_b                   12.462(3)
_cell_length_c                   17.325(4)
_cell_measurement_temperature    293(2)
_cell_volume                     3281.8(11)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.584
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062022
Ligand Displacement Reaction of Ru(η^4^-1,5-COD)(η^6^-1,3,5-COT) with Lewis Bases
Masafumi Hirano; Rie Asakawa; Chifumi Nagata; Takashi Miyasaka; Nobuyuki Komine; Sanshiro Komiya; Organometallics 22 (2003) 2378–; doi:10.1021/om030064t

data_4062023
_publ_section_title
;
Ligand Displacement Reaction of Ru(\h^4^-1,5-COD)(\h^6^-1,3,5-COT)
with Lewis Bases
;
_journal_name_full               Organometallics
_journal_page_first              2378
_journal_paper_doi               10.1021/om030064t
_journal_volume                  22
_journal_year                    2003
_chemical_formula_moiety         'C23 H39 N3 Ru '
_chemical_formula_sum            'C23 H39 N3 Ru'
_chemical_formula_weight         458.65
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 116.96(2)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   29.030(6)
_cell_length_b                   9.726(6)
_cell_length_c                   19.438(6)
_cell_measurement_temperature    200.2
_cell_volume                     4891(3)
_exptl_crystal_density_diffrn    1.245
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C23 H39 N3 Ru '
_cod_database_code               4062023
Reactivity of [Ru3(CO)12] with dibenzothiophene and methyl- benzo and dibenzothiophenes
Chehata, Alexander; Oviedo, Alberto; Arévalo, Alma; Bernès, Sylvain; García, Juventino J.; Organometallics  (2003) –; doi:

data_4062024
_publ_section_title
;
Reactivity of [Ru3(CO)12] with dibenzothiophene and methyl- benzo
 and dibenzothiophenes
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'Ru2 (CO)6 (C12 H8)'
_chemical_formula_sum            'C18 H8 O6 Ru2'
_chemical_formula_weight         522.38
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 110.262(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.4126(7)
_cell_length_b                   29.775(3)
_cell_length_c                   8.4638(9)
_cell_measurement_temperature    293(2)
_cell_volume                     1752.4(3)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.980
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062024
Reactivity of [Ru3(CO)12] with dibenzothiophene and methyl- benzo and dibenzothiophenes
Chehata, Alexander; Oviedo, Alberto; Arévalo, Alma; Bernès, Sylvain; García, Juventino J.; Organometallics  (2003) –; doi:

data_4062025
_publ_section_title
;
Reactivity of [Ru3(CO)12] with dibenzothiophene and methyl- benzo
 and dibenzothiophenes
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C17 H8 O8 Ru3'
_chemical_formula_weight         643.44
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                102.708(9)
_cell_angle_beta                 90.403(11)
_cell_angle_gamma                117.640(9)
_cell_formula_units_Z            2
_cell_length_a                   8.2086(12)
_cell_length_b                   8.5820(10)
_cell_length_c                   15.9425(18)
_cell_measurement_temperature    293(2)
_cell_volume                     962.8(2)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    2.220
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4062025
The Presence of [Ar~2~Cu]^-^ and [(RCC)~2~Cu]^-^ Homocuprate Moieties in the Neutral Mixed Cuprate [Cu~2~Li~2~(CCR)~2~Ar~2~]
Kronenburg, Claudia M.P.; Jastrzebski, Johann T.B.H.; Lutz, Martin; Spek, Anthony L.; van Koten, Gerard; Organometallics  (2003) –; doi:

data_4062026
_publ_section_title
;
The Presence of [Ar~2~Cu]^-^ and [(RCC)~2~Cu]^-^ Homocuprate Moieties
in the Neutral Mixed Cuprate [Cu~2~Li~2~(CCR)~2~Ar~2~]
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'C42 H52 Cu2 Li2 N4'
_chemical_formula_sum            'C42 H52 Cu2 Li2 N4'
_chemical_formula_weight         753.84
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                97.7242(7)
_cell_angle_beta                 103.7379(6)
_cell_angle_gamma                114.7861(7)
_cell_formula_units_Z            2
_cell_length_a                   12.7340(2)
_cell_length_b                   12.8276(1)
_cell_length_c                   14.2614(2)
_cell_measurement_temperature    150(2)
_cell_volume                     1980.83(4)
_diffrn_ambient_temperature      150(2)
_exptl_crystal_density_diffrn    1.264
_cod_database_code               4062026
The Presence of [Ar~2~Cu]^-^ and [(RCC)~2~Cu]^-^ Homocuprate Moieties in the Neutral Mixed Cuprate [Cu~2~Li~2~(CCR)~2~Ar~2~]
Kronenburg, Claudia M.P.; Jastrzebski, Johann T.B.H.; Lutz, Martin; Spek, Anthony L.; van Koten, Gerard; Organometallics  (2003) –; doi:

data_4062027
_publ_section_title
;
The Presence of [Ar~2~Cu]^-^ and [(RCC)~2~Cu]^-^ Homocuprate Moieties
in the Neutral Mixed Cuprate [Cu~2~Li~2~(CCR)~2~Ar~2~]
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_moiety         'C46 H64 Cu2 Li2 N4 Si2, 0.56(C6 H6)'
_chemical_formula_sum            'C49.36 H67.36 Cu2 Li2 N4 Si2'
_chemical_formula_weight         913.89
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                81.5370(7)
_cell_angle_beta                 78.6000(7)
_cell_angle_gamma                69.5940(6)
_cell_formula_units_Z            2
_cell_length_a                   11.8848(2)
_cell_length_b                   13.3156(2)
_cell_length_c                   18.6519(3)
_cell_measurement_temperature    150(2)
_cell_volume                     2702.06(7)
_diffrn_ambient_temperature      150(2)
_exptl_crystal_density_diffrn    1.123
_cod_database_code               4062027
DI-tert-BUTYLMAGNESIUM: SYNTHESIS AND STRUCTURE
Starowieyski Kazimierz B; Organometallics  (2003) –; doi:

data_4062028
_publ_section_title
;
DI-tert-BUTYLMAGNESIUM: SYNTHESIS AND STRUCTURE
;
_journal_name_full               Organometallics
_journal_year                    2003
_chemical_formula_sum            'C16 H36 Mg2'
_chemical_formula_weight         277.07
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 91.4200(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.90200(10)
_cell_length_b                   11.17700(10)
_cell_length_c                   18.9200(2)
_cell_measurement_temperature    150(2)
_cell_volume                     1881.92(3)
_diffrn_ambient_temperature      150(2)
_exptl_crystal_density_diffrn    0.978
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4062028