Distinctly different reactivity of bis(silylenyl)-<i>versus</i> phosphanyl-silylenyl-substituted <i>o</i>-dicarborane towards O<sub>2</sub>, N<sub>2</sub>O and CO<sub>2</sub>.
Xiong, Yun; Yao, Shenglai; Ruzicka, Ales; Driess, Matthias; Chemical communications (Cambridge, England) 57 (2021) 5965–5968; doi:10.1039/d1cc01939b

data_7128323
_publ_section_title
;
 Distinctly different reactivity of bis(silylenyl)-<i>versus</i>
 phosphanyl-silylenyl-substituted <i>o</i>-dicarborane towards
 O<sub>2</sub>, N<sub>2</sub>O and CO<sub>2</sub>.
;
_journal_issue                   48
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'Chemical communications (Cambridge, England)'
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_journal_paper_doi               10.1039/d1cc01939b
_journal_volume                  57
_journal_year                    2021
_chemical_formula_sum            'C27 H55 B10 N4 O P Si'
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;
2021-04-06 deposited with the CCDC.	2021-05-13 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.998
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'SuperNova, Single source at offset/far, Atlas'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0645P)^2^+4.5019P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                5064
_reflns_number_total             6495
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7128322--7128326.cif.'
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_cod_database_code               7128323
_shelx_shelxl_version_number     2018/3
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