Rhodium(II)-catalyzed synthesis of 2-aminoquinoline derivatives from 2-quinolones and <i>N</i>-sulfonyl-1,2,3-triazoles.
Kahar, Nilesh M.; Jadhav, Pankaj P.; Dawande, Sudam G.; Organic & biomolecular chemistry 21 (2023) 8267–8272; doi:10.1039/d3ob00971h

data_7159587
_publ_section_title
;
 Rhodium(II)-catalyzed synthesis of 2-aminoquinoline derivatives from
 2-quinolones and <i>N</i>-sulfonyl-1,2,3-triazoles.
;
_journal_issue                   41
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              8267
_journal_page_last               8272
_journal_paper_doi               10.1039/d3ob00971h
_journal_volume                  21
_journal_year                    2023
_chemical_formula_moiety         'C23  H18  N2  O3  S1'
_chemical_formula_sum            'C23 H18 N2 O3 S'
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_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
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_audit_update_record
;
2023-04-07 deposited with the CCDC.	2023-09-27 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_computing_cell_refinement       'Bruker SAINT'
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_computing_molecular_graphics    'Ortep for Windows (Farrugia, 2012)'
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_diffrn_ambient_temperature      296(2)
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_diffrn_reflns_limit_k_min       -28
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_exptl_crystal_density_method    'not measured'
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_refine_ls_shift/su_max          0
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0489P)^2^+0.1269P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1103
_refine_ls_wR_factor_ref         0.1216
_reflns_Friedel_coverage         0
_reflns_number_gt                3397
_reflns_number_total             4892
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d3ob00971h2.cif
_cod_data_source_block           AV-SGD866
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'NONE' was changed
to 'none' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 

 Adding full bibliography for 7159587.cif.
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7159587
_shelx_res_checksum              32981