A rare three-dimensional POM-based inorganic metal polymer bonded by CO<sub>2</sub> with high catalytic performance for CO<sub>2</sub> cycloaddition.
Cheng, Weiwei; Xue, Yun-Shan; Luo, Xi-Ming; Xu, Yan; Chemical communications (Cambridge, England) 54 (2018) 12808–12811; doi:10.1039/c8cc07041e

data_7122376
_publ_section_title
;
 A rare three-dimensional POM-based inorganic metal polymer bonded by
 CO<sub>2</sub> with high catalytic performance for CO<sub>2</sub>
 cycloaddition.
;
_journal_issue                   91
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              12808
_journal_page_last               12811
_journal_paper_doi               10.1039/c8cc07041e
_journal_volume                  54
_journal_year                    2018
_chemical_formula_sum            'C33 H74 Mo12 N2 O42 P Zn4'
_chemical_formula_weight         2614.67
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-09-21 deposited with the CCDC.
2018-09-24 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      296(2)
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_diffrn_measurement_device_type  'Bruker Apex2 CCD'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1177P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7122376.cif.'
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