Two Co(ii)-based coordination polymers as multi-responsive luminescent sensors for the detection of levofloxacin, benzaldehyde and Fe3+ ions in water media
Liu, Ya; Ren, Li; Cui, Guang-Hua; CrystEngComm 23 (2021) 7485–7495; doi:10.1039/D1CE01169C

data_7243584
_publ_section_title
;
 Two Co(ii)-based coordination polymers as multi-responsive luminescent
 sensors for the detection of levofloxacin, benzaldehyde and Fe3+ ions in
 water media
;
_journal_issue                   42
_journal_name_full               CrystEngComm
_journal_page_first              7485
_journal_page_last               7495
_journal_paper_doi               10.1039/D1CE01169C
_journal_volume                  23
_journal_year                    2021
_chemical_formula_sum            'C28.5 H21 Co N3 O5'
_chemical_formula_weight         544.41
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-07-03 deposited with the CCDC.	2021-09-24 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 107.237(6)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   12.6009(7)
_cell_length_b                   30.1566(12)
_cell_length_c                   13.5693(8)
_cell_measurement_temperature    293(2)
_cell_volume                     4924.8(5)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.948
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0397
_diffrn_reflns_av_unetI/netI     0.0376
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.948
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       42
_diffrn_reflns_limit_k_min       -42
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            34509
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.948
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.546
_diffrn_reflns_theta_min         2.072
_exptl_absorpt_coefficient_mu    0.743
_exptl_crystal_density_diffrn    1.469
_exptl_crystal_F_000             2240
_refine_diff_density_max         0.615
_refine_diff_density_min         -0.578
_refine_diff_density_rms         0.058
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     340
_refine_ls_number_reflns         7162
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0824
_refine_ls_R_factor_gt           0.0519
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0599P)^2^+3.3064P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1159
_refine_ls_wR_factor_ref         0.1274
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4979
_reflns_number_total             7162
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1ce01169c1.cif
_cod_data_source_block           sys-85-2
_cod_depositor_comments
'Adding full bibliography for 7243583--7243584.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C28.50 H21 Co N3 O5'
_cod_database_code               7243584
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              43123
_shelx_hkl_checksum              62760