Synthesis and decarbonylation chemistry of gallium phosphaketenes.
Wilson, Daniel W. N.; Myers, William K.; Goicoechea, Jose M.; Dalton transactions (Cambridge, England : 2003) 49 (2020) 15249–15255; doi:10.1039/d0dt03174g

data_7705676
_publ_section_title
;
 Synthesis and decarbonylation chemistry of gallium phosphaketenes.
;
_journal_issue                   43
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15249
_journal_page_last               15255
_journal_paper_doi               10.1039/d0dt03174g
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C42 H45 Ga N3 O P, C7 H8'
_chemical_formula_sum            'C49 H53 Ga N3 O P'
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_chemical_name_systematic
;
 Ga(PCO)[(NDipp)2C12H5]*tol
;
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;
2020-08-25 deposited with the CCDC.	2020-10-13 downloaded from the CCDC.
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;
CrysAlisPro 1.171.38.43b (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            black
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0466P)^2^+0.9783P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0926
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7705675--7705683.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
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_shelx_shelxl_version_number     2018/1
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