Fast Photochromism Involving Thermally-Activated Valence Isomerization of Phenoxyl-Imidazolyl Radical Complex Derivatives.
Kobayashi, Yoichi; Shima, Kentaro; Mutoh, Katsuya; Abe, Jiro; The journal of physical chemistry letters 7 (2016) 3067–3072; doi:10.1021/acs.jpclett.6b01271

data_8000232
_publ_section_title
;
 Fast Photochromism Involving Thermally-Activated Valence Isomerization of
 Phenoxyl-Imidazolyl Radical Complex Derivatives.
;
_journal_issue                   16
_journal_name_full               'The journal of physical chemistry letters'
_journal_page_first              3067
_journal_page_last               3072
_journal_paper_doi               10.1021/acs.jpclett.6b01271
_journal_volume                  7
_journal_year                    2016
_chemical_formula_sum            'C51 H51.42 N2 O'
_chemical_formula_weight         708.36
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_symmetry_space_group_name_Hall  '-P 1'
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_diffrn_measured_fraction_theta_max 0.970
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_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -20
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_exptl_crystal_colour            colorless
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
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_refine_ls_number_reflns         14081
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_refine_ls_R_factor_all          0.0875
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0858P)^2^+2.4756P] where P=(Fo^2^+2Fc^2^)/3'
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_refine_ls_wR_factor_ref         0.1780
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 8000231--8000232.cif.'
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