Fluorescent ligand design for mononuclear copper(I) complex fluorescence in aqueous solution
Saga, Makoto; Sakane, Genta; Yamazaki, Shigeo; Saito, Keiitsu; Inorganica Chimica Acta 502 (2020) 119368–; doi:10.1016/j.ica.2019.119368

data_1565441
_publ_section_title
;
 Fluorescent ligand design for mononuclear copper(I) complex fluorescence
 in aqueous solution
;
_journal_name_full               'Inorganica Chimica Acta'
_journal_page_first              119368
_journal_paper_doi               10.1016/j.ica.2019.119368
_journal_volume                  502
_journal_year                    2020
_chemical_formula_moiety         'C24 H32 Cu N4 O9 S2'
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_space_group_name_Hall           '-P 2yn'
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_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
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_cell_length_b                   14.275(2)
_cell_length_c                   16.108(3)
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_cell_measurement_theta_max      27.49
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_computing_data_collection
'CrystalClear-SM Expert 2.0 r16 (Rigaku, 2014)'
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_diffrn_ambient_temperature      93
_diffrn_detector_area_resol_mean 29.257
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0253
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_diffrn_reflns_point_group_measured_fraction_full 0.979
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_diffrn_reflns_theta_min         3.080
_diffrn_standards_interval_count .
_diffrn_standards_number         0
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_refine_ls_number_reflns         6133
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_refine_ls_R_factor_gt           0.0281
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0544P)^2^+0.6544P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0793
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_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ICA-2020-502-119368.cif
_cod_data_source_block           Q1_20190309
_cod_original_cell_volume        2721.7(7)
_cod_database_code               1565441
_shelx_res_checksum              36993
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