Synthesis and coordination chemistry of enantiopure t-BuMeP(O)H.
Gallen, Albert; Orgué, Sílvia; Muller, Guillermo; Escudero-Adán, Eduardo C; Riera, Antoni; Verdaguer, Xavier; Grabulosa, Arnald; Dalton transactions (Cambridge, England : 2003) 47 (2018) 5366–5379; doi:10.1039/c8dt00897c

data_7045901
_publ_section_title
;
 Synthesis and coordination chemistry of enantiopure t-BuMeP(O)H.
;
_journal_issue                   15
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'Dalton transactions (Cambridge, England : 2003)'
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_journal_paper_doi               10.1039/c8dt00897c
_journal_volume                  47
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_chemical_absolute_configuration ad
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;
2018-03-07 deposited with the CCDC.
2018-03-21 downloaded from the CCDC.
;
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_computing_structure_solution    Sir2014
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;
 Fullsphere data collection, phi and omega scans
;
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; 
 CrysAlisPro 1.171.38.37f (Rigaku OD, 2015)
;
_exptl_crystal_colour            colourless
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;
 Classical Flack method preferred over Parsons because s.u. lower.
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0868P)^2^+27.9054P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                9614
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt00897c2.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Trigonal' changed to 'trigonal'
according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7045898--7045902.cif.
;
_cod_original_cell_volume        2083.94(6)
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