Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal structure of [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine).
Cinellu, Maria A.; Minghetti, Giovanni; Stoccoro, Sergio; Zucca, Antonio; Manassero, Mario; Chemical communications (Cambridge, England)  (2004) 1618–1619; doi:10.1039/b404890c

data_7113400
_publ_section_title
;
 Reaction of gold(III) oxo complexes with alkenes. Synthesis of
 unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal
 structure of [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) =
 6-isopropyl-2,2'-bipyridine).
;
_journal_issue                   14
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              1618
_journal_page_last               1619
_journal_paper_doi               10.1039/b404890c
_journal_year                    2004
_chemical_formula_sum            'C22 H23.5 Au F6 N2.5 P'
_chemical_formula_weight         664.88
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_audit_creation_date             04-02-17
_audit_creation_method           'from The Personal SDP version 2.1.1'
_cell_angle_alpha                90
_cell_angle_beta                 114.15(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.717(1)
_cell_length_b                   12.833(1)
_cell_length_c                   15.272(2)
_cell_measurement_reflns_used    197
_cell_measurement_temperature    223
_cell_measurement_theta_max      23
_cell_measurement_theta_min      3
_cell_volume                     2453.0(5)
_computing_cell_refinement       'SMART (Bruker)'
_computing_data_collection       'SMART (Bruker)'
_computing_data_reduction        'SAINT (Bruker)'
_computing_molecular_graphics    'The Personal SDP (1991)'
_computing_publication_material  'The Personal SDP (1991)'
_computing_structure_refinement
;
Full-matrix least-squares  (The Personal SDP, 1991)
;
_computing_structure_solution
;
SHELXS-86  (Sheldrick, 1986) as implemented in The Personal SDP
;
_diffrn_ambient_temperature      223
_diffrn_measurement_device       'SMART (Bruker)'
_diffrn_measurement_method       omega
_diffrn_radiation_detector       'SMART CCD area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           Mo-K\a
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_reduction_process SAINT
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         3.00
_diffrn_standards_decay_%        0.00
_diffrn_standards_number         248
_exptl_absorpt_coefficient_mu    6.107
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.659
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
SADABS
;
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.800
_exptl_crystal_description       prism
_exptl_crystal_F_000             1284
_exptl_crystal_size_max          0.350
_exptl_crystal_size_mid          0.270
_exptl_crystal_size_min          0.250
_refine_diff_density_max         1.176
_refine_diff_density_min         -.596
_refine_ls_goodness_of_fit_all   1.391
_refine_ls_goodness_of_fit_obs   1.391
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     291
_refine_ls_number_reflns         5027
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.054
_refine_ls_R_factor_obs          0.054
_refine_ls_shift/esd_max         0.013
_refine_ls_shift/esd_mean        0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_obs         0.090
_cod_data_source_file            b404890c.txt
_cod_data_source_block           compound_2c.0.5CH3CN
_cod_original_cell_volume        2453.1(4)
_cod_original_formula_sum        'C22 H23.5 Au1 F6 N2.5 P1'
_cod_database_code               7113400
_diffrn_reflns_number_total      33327
_diffrn_reflns_number_independent 5027
_r_int                           0.0273
_total_number_of_frames          2450
_time_per_frame_seconds          25
_frame_width_degrees             0.30
_detector_sample_distance_cm     4.00
_conventional_r1_(i>2\s(i))      0.032
_reflections_with_i>2\s(i)       4055
_refine_diff_density_esd         0.140