Magnetic Spongelike Behavior of 3D Ferrimagnetic {[MnII(imH)]2[NbIV(CN)8]}n with Tc= 62 K
Dawid Pinkowicz; Robert Podgajny; Maria Bałanda; Magdalena Makarewicz; Bartłomiej Gaweł; Wiesław Łasocha; Barbara Sieklucka; Inorganic Chemistry 47 (2008) 9745–9747; doi:10.1021/ic801248f

data_4306429
_publ_contact_author_address
;Jagielonian University
Faculty of Chemistry
Ingardena 3
30-060 Krakow
Poland
;
_publ_contact_author_email
'podgajny@chemia.uj.edu.pl, pinkowic@chemia.uj.edu.pl'
_publ_contact_author_name        'Robert Podgajny, Dawid Pinkowicz'
_publ_section_title
;
Magnetic Spongelike Behavior of 3D Ferrimagnetic
{[MnII(imH)]2[NbIV(CN)8]}n with Tc= 62 K
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9745
_journal_page_last               9747
_journal_paper_doi               10.1021/ic801248f
_journal_volume                  47
_journal_year                    2008
_chemical_formula_moiety         '{Mn(imidazole)}2, {[Nb(IV)(CN)8]'
_chemical_formula_sum            'C14 Mn2 N12 Nb'
_chemical_formula_weight         539
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                104.077(2)
_cell_angle_beta                 103.004(3)
_cell_angle_gamma                95.874(2)
_cell_formula_units_Z            2
_cell_length_a                   10.1272(2)
_cell_length_b                   10.9746(2)
_cell_length_c                   9.9608(2)
_cell_volume                     1031.73(4)
_computing_publication_material  '(Jana2000; Petricek and Dusek, 2000)'
_computing_structure_refinement  '(Jana2000; Petricek and Dusek, 2000)'
_diffrn_ambient_temperature      273
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54178
_exptl_absorpt_coefficient_mu    14.507
_exptl_absorpt_process_details   '(Jana2000; Petricek and Dusek, 2000)'
_exptl_crystal_density_diffrn    1.7345
_exptl_crystal_F_000             518
_pd_char_colour                  red
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.02
_pd_meas_2theta_range_max        70.000
_pd_meas_2theta_range_min        7.000
_pd_meas_number_of_points        3151
_pd_proc_2theta_range_inc        0.02
_pd_proc_2theta_range_max        70
_pd_proc_2theta_range_min        7
_pd_proc_ls_pref_orient_corr     'March & Dollase'
_pd_proc_ls_profile_function     Pseudo-Voigt
_pd_proc_ls_prof_R_factor        0.0451
_pd_proc_ls_prof_wR_expected     0.0186
_pd_proc_ls_prof_wR_factor       0.0593
_refine_ls_extinction_method     none
_refine_ls_number_parameters     9
_refine_ls_R_factor_all          0.0463
_refine_ls_R_factor_gt           0.0462
_refine_ls_shift/su_max          0.0410
_refine_ls_shift/su_mean         0.0185
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_gt          0.0502
_refine_ls_wR_factor_ref         0.0502
_cod_data_source_file            ic801248f_si_001.cif
_cod_data_source_block           powder
_cod_original_cell_volume        1031.73(2)
_cod_original_formula_sum        'C14 Mn2 N12 Nb1'
_cod_database_code               4306429