Structural characterization and magnetic property studies of a mixed-valence {Co<sup>III</sup>Co} complex with a μ<sub>4</sub>-oxo tetrahedral {Co} motif.
Fiorini, Guillermo; Carrella, Luca; Rentschler, Eva; Alborés, Pablo; Dalton transactions (Cambridge, England : 2003) 49 (2020) 932–940; doi:10.1039/c9dt03561c

data_7703040
_publ_section_title
;
 Structural characterization and magnetic property studies of a
 mixed-valence {Co<sup>III</sup>Co} complex with a \m<sub>4</sub>-oxo
 tetrahedral {Co} motif.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              932
_journal_page_last               940
_journal_paper_doi               10.1039/c9dt03561c
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C48 H81 Co5 N2 O18'
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_audit_update_record
;
2019-08-30 deposited with the CCDC.	2019-12-09 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
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;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            purple
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_exptl_crystal_description       block
_exptl_crystal_F_000             2648
_exptl_crystal_preparation       'Magnetic properties'
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1201P)^2^+0.6240P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2268
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_reflns_number_gt                6160
_reflns_number_total             14306
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments          'Adding full bibliography for 7703040.cif.'
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_cod_database_code               7703040
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              86608