Tetrakis(triphenylphosphane-κ<i>P</i>)silver(I) trifluoroacetate ethanol monosolvate
Ng, Seik Weng; Acta Crystallographica Section E 68 (2012) m1536–; doi:10.1107/S1600536812045060

data_2237071
_publ_section_title
;
 Tetrakis(triphenylphosphane-\k<i>P</i>)silver(I) trifluoroacetate ethanol
 monosolvate
;
_journal_coeditor_code           XU5640
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1536
_journal_paper_doi               10.1107/S1600536812045060
_journal_volume                  68
_journal_year                    2012
_chemical_formula_iupac          '[Ag (C18 H15 P)4] (C2 F3 O), C2 H6 O'
_chemical_formula_moiety         'Ag C72 H60 P4 +, C2 F3 O -, C2 H6 O'
_chemical_formula_sum            'C76 H66 Ag F3 O3 P4'
_chemical_formula_weight         1316.04
_chemical_name_systematic
;
Tetrakis(triphenylphosphane-\k<i>P</i>)silver(I) trifluoroacetate ethanol
monosolvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                89.4032(8)
_cell_angle_beta                 85.4648(9)
_cell_angle_gamma                87.7804(9)
_cell_formula_units_Z            2
_cell_length_a                   11.8005(2)
_cell_length_b                   14.5169(2)
_cell_length_c                   18.4830(3)
_cell_measurement_reflns_used    7238
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.0895
_cell_measurement_theta_min      2.2107
_cell_volume                     3153.89(9)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'APEX2 (Bruker, 2009)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics    'X-SEED (Barbour, 2001)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker SMART APEX'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0295
_diffrn_reflns_av_sigmaI/netI    0.0515
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            27139
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.11
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.480
_exptl_absorpt_correction_T_max  0.9272
_exptl_absorpt_correction_T_min  0.9101
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2009)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.386
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1360
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.724
_refine_diff_density_min         -0.870
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     868
_refine_ls_number_reflns         14387
_refine_ls_number_restraints     218
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0639
_refine_ls_R_factor_gt           0.0469
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0520P)^2^+3.9561P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1111
_refine_ls_wR_factor_ref         0.1218
_reflns_number_gt                11357
_reflns_number_total             14387
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            xu5640.cif
_cod_data_source_block           I
_cod_database_code               2237071
_cod_database_fobs_code          2237071