A unique Bi-Bi bond forming reaction using organobismuth oxides and phosphorus compounds bearing a P(=O)H group.
Shimada, Shigeru; Maruyama, Junpei; Choe, Yoong-Kee; Yamashita, Takashi; Chemical communications (Cambridge, England)  (2009) 6168–6170; doi:10.1039/b914316e

data_7104948
_publ_section_title
;
 A unique Bi-Bi bond forming reaction using organobismuth oxides and
 phosphorus compounds bearing a P(=O)H group.
;
_journal_issue                   41
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              6168
_journal_page_last               6170
_journal_paper_doi               10.1039/b914316e
_journal_year                    2009
_chemical_formula_moiety         'C30 H29 Bi N O3 P '
_chemical_formula_sum            'C30 H29 Bi N O3 P'
_chemical_formula_weight         691.52
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_date             2008-03-04
_audit_creation_method           'by CrystalStructure 3.8'
_cell_angle_alpha                90.0000
_cell_angle_beta                 104.122(1)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   11.8574(5)
_cell_length_b                   12.9440(5)
_cell_length_c                   17.2181(7)
_cell_measurement_reflns_used    8399
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      28.3
_cell_measurement_theta_min      2.4
_cell_volume                     2562.81(18)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    'DIRDIF99 (PATTY)'
_diffrn_ambient_temperature      153(2)
_diffrn_detector_area_resol_mean '8.366 [pixels/mm]'
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.921
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.020
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            15216
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         28.27
_exptl_absorpt_coefficient_mu    6.963
_exptl_absorpt_correction_T_max  0.434
_exptl_absorpt_correction_T_min  0.312
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
SADABS; Sheldrick 1996
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.792
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1352.00
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_refine_diff_density_max         2.31
_refine_diff_density_min         -1.18
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     354
_refine_ls_number_reflns         5720
_refine_ls_R_factor_gt           0.0214
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w = 1/[0.2000\s(Fo^2^) + 0.0600]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0488
_reflns_number_gt                5045
_reflns_number_total             5721
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b914316e.txt
_cod_data_source_block           compound-6a
_cod_original_formula_sum        'C30 H29 Bi N O3 P '
_cod_database_code               7104948