Anionic cyclometalated Pt(ii) and Pt(iv) complexes respectively bearing one or two 1,2-benzenedithiolate ligands.
Ionescu, Andreea; Godbert, Nicolas; Aiello, Iolinda; Ricciardi, Loredana; La Deda, Massimo; Crispini, Alessandra; Sicilia, Emilia; Ghedini, Mauro; Dalton transactions (Cambridge, England : 2003) 47 (2018) 11645–11657; doi:10.1039/c8dt02444h

data_7047214
_publ_section_title
;
 Anionic cyclometalated Pt(ii) and Pt(iv) complexes respectively bearing
 one or two 1,2-benzenedithiolate ligands.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11645
_journal_page_last               11657
_journal_paper_doi               10.1039/c8dt02444h
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C19 H12 N Pt S2, C16 H36 N'
_chemical_formula_sum            'C35 H48 N2 Pt S2'
_chemical_formula_weight         755.96
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-06-10 deposited with the CCDC.
2018-08-03 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_radiation_monochromator  graphite
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_exptl_absorpt_correction_T_min  0.4560
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_refine_ls_R_factor_all          0.0689
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0344P)^2^+4.0475P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0773
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_reflns_number_total             7450
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt02444h2.cif
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_cod_depositor_comments
'Adding full bibliography for 7047214--7047215.cif.'
_cod_original_cell_volume        3393(3)
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_shelx_shelxl_version_number     2014/7
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