Cleavage of C-O and C-H bonds in ethers by a genuine Si[double bond, length as m-dash]O bond.
Kobayashi, Ryo; Ishida, Shintaro; Iwamoto, Takeaki; Dalton transactions (Cambridge, England : 2003) 50 (2021) 1413–1421; doi:10.1039/d0dt04240d

data_7706178
_publ_section_title
;
 Cleavage of C-O and C-H bonds in ethers by a genuine Si[double bond,
 length as m-dash]O bond.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1413
_journal_page_last               1421
_journal_paper_doi               10.1039/d0dt04240d
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C70 H108 O6 Si, C6H6, 0.5(C6H6), 0.5(C6H6)'
_chemical_formula_sum            'C82 H120 O6 Si'
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_chemical_properties_physical
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
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_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-10-12 deposited with the CCDC.	2020-12-21 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device_type  'Bruker D8 goniometer with CCD area detector'
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_diffrn_radiation_type           CuK\a
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_diffrn_source                   'Bruker TXS fine-focus rotating anode'
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'Re-crystallisation from solvent: benzene'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1568P)^2^+1.8741P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt04240d4.cif
_cod_data_source_block           200227B3_a
_cod_depositor_comments
'Adding full bibliography for 7706178--7706180.cif.'
_cod_database_code               7706178
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.938
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_shelx_res_checksum              29840