Pt(II)- or Au(III)-catalyzed [3+2] cycloaddition of metal-containing azomethine ylides: highly efficient synthesis of the mitosene skeleton.
Kusama, Hiroyuki; Miyashita, Yuichi; Takaya, Jun; Iwasawa, Nobuharu; Organic letters 8 (2006) 289–292; doi:10.1021/ol052610f

data_1505827
_publ_section_title
;
 Pt(II)- or Au(III)-catalyzed [3+2] cycloaddition of metal-containing
 azomethine ylides: highly efficient synthesis of the mitosene skeleton.
;
_journal_issue                   2
_journal_name_full               'Organic letters'
_journal_page_first              289
_journal_page_last               292
_journal_paper_doi               10.1021/ol052610f
_journal_volume                  8
_journal_year                    2006
_chemical_formula_moiety         'C27 H33 N O '
_chemical_formula_sum            'C27 H33 N O'
_chemical_formula_weight         387.56
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.70(6)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.73(1)
_cell_length_b                   12.94(2)
_cell_length_c                   16.36(2)
_cell_measurement_temperature    223.2
_cell_volume                     2267(5)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
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_computing_structure_solution    SIR97
_diffrn_measured_fraction_theta_full 0.9948
_diffrn_measured_fraction_theta_max 0.9948
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.021
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_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
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_diffrn_reflns_theta_full        27.48
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_exptl_absorpt_correction_T_max  0.987
_exptl_absorpt_correction_T_min  0.987
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.136
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       unknown
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_refine_diff_density_min         -0.30
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_refine_ls_R_factor_gt           0.0564
_refine_ls_shift/su_max          0.1462
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.17400(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     F^2^>2.0\s(F^2^)
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_cod_original_formula_sum        'C27 H33 N O '
_cod_database_code               1505827