Synthesis, crystal structure and thermal properties of bis(1,3-dicyclohexylthiourea-κ<i>S</i>)bis(isothiocyanato-κ<i>N</i>)cobalt(II)
Krebs, Christoph; Jess, Inke; Näther, Christian; Acta Crystallographica Section E 78 (2022) –; doi:10.1107/S205698902101327X

data_2243961
_publ_section_title
;
 Synthesis, crystal structure and thermal properties of
 bis(1,3-dicyclohexylthiourea-\k<i>S</i>)bis(isothiocyanato-\k<i>N</i>)cobalt(II)
;
_journal_coeditor_code           ZQ2269
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S205698902101327X
_journal_volume                  78
_journal_year                    2022
_chemical_formula_iupac          '[Co (N C S)2 (C13 H24 N2 S)2]'
_chemical_formula_moiety         'C28 H48 Co N6 S4'
_chemical_formula_sum            'C28 H48 Co N6 S4'
_chemical_formula_weight         655.89
_chemical_name_systematic
;
Bis(1,3-dicyclohexylthiourea-\k<i>S</i>)bis(isothiocyanato-\k<i>N</i>)cobalt(II)
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
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;
Olex2 1.3-ac4
(compiled 2020.11.27 svn.r5f609507 for Rigaku Oxford Diffraction, GUI svn.r6214)
;
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_cell_length_c                   18.8910(3)
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;
CrysAlisPro (Rigaku OD, 2021)
;
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CrysAlisPro (Rigaku OD, 2021)
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CrysAlisPro (Rigaku OD, 2021)
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DIAMOND (Brandenburg & Putz, 1999)
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Publcif (Westrip, 2010)
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<i>SHELXL2016/6</i> (Sheldrick, 2015b)
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<i>SHELXT2014/5</i> (Sheldrick, 2015a)
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_diffrn_reflns_limit_k_min       -11
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_diffrn_reflns_limit_l_min       -20
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;
(CrysAlisPro; Rigaku OD, 2021)
;
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_refine_diff_density_min         -0.362
_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0348
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0540P)^2^+5.0479P] where P=(Fo^2^+2Fc^2^)/3'
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_refine_ls_wR_factor_ref         0.0958
_reflns_number_gt                3462
_reflns_number_total             3503
_reflns_threshold_expression     'I > 2\s(I)'
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