Chemical Properties of Mononuclear and Dinuclear Phenylplatinum(II) Hydroxo Complexes with Cod Ligands. Transmetalation of Arylboronic Acids, Coupling of the Phenyl Ligands, and Carbonylation
Suzaki, Yuji; Osakada, Kohtaro; Organometallics 25 (2006) 3251–; doi:10.1021/om060206u

data_4075319
_publ_section_title
;
 Chemical Properties of Mononuclear and Dinuclear Phenylplatinum(II)
 Hydroxo Complexes with Cod Ligands. Transmetalation of Arylboronic Acids,
 Coupling of the Phenyl Ligands, and Carbonylation
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3251
_journal_paper_doi               10.1021/om060206u
_journal_volume                  25
_journal_year                    2006
_chemical_formula_moiety         'C24 H25 F6 N2 P Pt '
_chemical_formula_sum            'C24 H25 F6 N2 P Pt'
_chemical_formula_weight         681.53
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_formula_units_Z            8
_cell_length_a                   17.465(7)
_cell_length_b                   15.145(7)
_cell_length_c                   17.870(8)
_cell_measurement_reflns_used    10748
_cell_measurement_temperature    293.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     4727(4)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.072
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            32823
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    6.044
_exptl_absorpt_correction_T_max  0.000
_exptl_absorpt_correction_T_min  0.000
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.915
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             2640.00
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.05
_refine_diff_density_min         -1.34
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     332
_refine_ls_number_reflns         4983
_refine_ls_R_factor_gt           0.0418
_refine_ls_shift/su_max          0.0085
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[1.0000\s(Fo^2^)]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0762
_reflns_number_gt                3018
_reflns_number_total             5384
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om060206usi20060303_034538.cif
_cod_data_source_block           form1
_cod_original_formula_sum        'C24 H25 F6 N2 P Pt '
_cod_database_code               4075319