Sticking and patching: tuning and anchoring cyclometallated ruthenium(II) complexes.
Ertl, Cathrin D.; Ris, Daniel P.; Meier, Stefan C.; Constable, Edwin C.; Housecroft, Catherine E.; Neuburger, Markus; Zampese, Jennifer A.; Dalton transactions (Cambridge, England : 2003) 44 (2015) 1557–1570; doi:10.1039/c4dt02797c

data_7033136
_publ_section_title
;
 Sticking and patching: tuning and anchoring cyclometallated ruthenium(II)
 complexes.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1557
_journal_page_last               1570
_journal_paper_doi               10.1039/c4dt02797c
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C33 H26 N5 O2 Ru, F6 P'
_chemical_formula_sum            'C33 H26 F6 N5 O2 P Ru'
_chemical_formula_weight         770.63
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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_cell_angle_beta                 108.261(2)
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_cell_length_c                   15.0031(9)
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_cell_measurement_theta_min      4.45
_cell_volume                     3116.8(3)
_computing_cell_refinement       'Bruker SAINT'
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_computing_data_reduction        'Bruker SAINT'
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_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
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_diffrn_measured_fraction_theta_max 1.008
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           CuK\a
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_diffrn_reflns_Laue_measured_fraction_full 1.012
_diffrn_reflns_Laue_measured_fraction_max 1.008
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_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
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_diffrn_reflns_limit_l_min       -17
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_diffrn_reflns_point_group_measured_fraction_full 1.012
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_diffrn_reflns_theta_max         68.203
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         5856
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_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.0276
_refine_ls_R_factor_gt           0.0248
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; 
 w=1/[\s^2^(Fo^2^)+(0.0360P)^2^+2.0125P] 
 where P=(Fo^2^+2Fc^2^)/3 
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0642
_refine_ls_wR_factor_ref         0.0664
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_reflns_number_total             5856
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           dpr39
_cod_depositor_comments
'Adding full bibliography for 7033136--7033138.cif.'
_cod_database_code               7033136
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_shelx_estimated_absorpt_t_max   0.949
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