White luminescence achieved by a multiple thermochromic emission in a hybrid organic-inorganic compound based on 3-picolylamine and copper(i) iodide.
Farinella, F.; Maini, L.; Mazzeo, P. P.; Fattori, V.; Monti, F.; Braga, D.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 17939–17947; doi:10.1039/c6dt03049a

data_7040837
_publ_section_title
;
 White luminescence achieved by a multiple thermochromic emission in a
 hybrid organic-inorganic compound based on 3-picolylamine and copper(i)
 iodide.
;
_journal_issue                   44
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              17939
_journal_page_last               17947
_journal_paper_doi               10.1039/c6dt03049a
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C6 H8 Cu2 I2 N2'
_chemical_formula_sum            'C6 H8 Cu2 I2 N2'
_chemical_formula_weight         489.04
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_update_record
;
2016-08-01 deposited with the CCDC.
2016-10-10 downloaded from the CCDC.
;
_cell_angle_alpha                98.9803(19)
_cell_angle_beta                 96.2793(18)
_cell_angle_gamma                108.8729(14)
_cell_formula_units_Z            2
_cell_length_a                   9.9408(2)
_cell_length_b                   7.60946(14)
_cell_length_c                   7.63997(16)
_cell_measurement_temperature    298
_cell_volume                     532.19(2)
_diffrn_ambient_temperature      298
_diffrn_measurement_device_type  'Bragg Brentano'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.541874
_exptl_crystal_colour            white
_exptl_crystal_density_diffrn    3.052
_exptl_crystal_description       powder
_exptl_crystal_preparation       ', Luminescent'
_pd_char_colour                  white
_pd_meas_number_of_points        7421
_pd_proc_2theta_range_inc        0.00836
_pd_proc_2theta_range_max        69.99848
_pd_proc_2theta_range_min        7.99967
_pd_proc_ls_prof_R_factor        0.0406
_pd_proc_ls_prof_wR_expected     0.0221
_pd_proc_ls_prof_wR_factor       0.0574
_pd_spec_mounting                'flat sample stage'
_pd_spec_mount_mode              reflection
_refine_ls_goodness_of_fit_all   2.59160
_refine_ls_number_parameters     83
_refine_ls_R_I_factor            0.0104
_refine_ls_shift/su_max          0.00556113823
_reflns_d_resolution_high        1.33489
_reflns_d_resolution_low         9.26777
_reflns_limit_h_max              7
_reflns_limit_h_min              0
_reflns_limit_k_max              5
_reflns_limit_k_min              -5
_reflns_limit_l_max              5
_reflns_limit_l_min              -5
_reflns_number_total             474
_cod_data_source_file            c6dt03049a2.cif
_cod_data_source_block           Bianco_2016
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7040837--7040839.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7040837