Radical Philicity Inversion in Co- and Fe-Catalyzed Hydrogen-Atom-Transfer-Initiated Cyclizations of Unsaturated Acylsilanes
Wu, Bin; Zhu, Rong; ACS Catalysis 10 (2019) 510–; doi:10.1021/acscatal.9b04774

data_4517169
_publ_section_title
;
 Radical Philicity Inversion in Co- and Fe-Catalyzed
 Hydrogen-Atom-Transfer-Initiated Cyclizations of Unsaturated Acylsilanes
;
_journal_issue                   1
_journal_name_full               'ACS Catalysis'
_journal_page_first              510
_journal_paper_doi               10.1021/acscatal.9b04774
_journal_volume                  10
_journal_year                    2019
_chemical_formula_sum            'C11 H22 O2'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.29a (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0513P)^2^+4.7514P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            cs9b04774_si_002.cif
_cod_data_source_block           3
_cod_depositor_comments          'Adding full bibliography for 4517169.cif.'
_cod_database_code               4517169
_shelx_shelxl_version_number     2014/7
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