Initiator Control of Conjugated Polymer Topology in Ring-Opening Alkyne Metathesis Polymerization.
von Kugelgen, Stephen; Bellone, Donatela E.; Cloke, Ryan R.; Perkins, Wade S.; Fischer, Felix R.; Journal of the American Chemical Society 138 (2016) 6234–6239; doi:10.1021/jacs.6b02422

data_4130343
_publ_section_title
;
 Initiator Control of Conjugated Polymer Topology in Ring-Opening Alkyne
 Metathesis Polymerization.
;
_journal_issue                   19
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              6234
_journal_page_last               6239
_journal_paper_doi               10.1021/jacs.6b02422
_journal_volume                  138
_journal_year                    2016
_chemical_formula_sum            'C19 H24 F18 Mo O5'
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_space_group_name_H-M_alt        'P 1 21/n 1'
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_cell_measurement_temperature    100(2)
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_diffrn_source                   'fine-focus sealed tube'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            orange
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0316
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0140P)^2^+4.2505P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_database_code               4130343
_shelx_estimated_absorpt_t_min   0.904
_shelx_estimated_absorpt_t_max   0.950
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