<i>catena</i>-Poly[[nitratosilver(I)]-μ-2,2'-dithiobis(5-nitropyridine)]
López-Rodríguez, Matías; Brito, Iván; Vargas, Danitza; Cárdenas, Alejandro; Acta Crystallographica Section E 62 (2006) m2690–m2692; doi:10.1107/S1600536806037822

data_2210760
_publ_section_title
;
 <i>catena</i>-Poly[[nitratosilver(I)]-\m-2,2'-dithiobis(5-nitropyridine)]
;
_journal_coeditor_code           OM2053
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2690
_journal_page_last               m2692
_journal_paper_doi               10.1107/S1600536806037822
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          '[Ag (N O3) (C10 H6 N4 O4 S2)]'
_chemical_formula_moiety         'C10 H6 Ag N5 O7 S2'
_chemical_formula_sum            'C10 H6 Ag N5 O7 S2'
_chemical_formula_weight         480.21
_chemical_name_systematic
;
catena-Poly[[nitratosilver(I)]-\m-2,2'-dithiobis(5-nitropyridine)]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 92.709(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.9734(8)
_cell_length_b                   24.911(3)
_cell_length_c                   9.8107(13)
_cell_measurement_reflns_used    97
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      23.12
_cell_measurement_theta_min      2.5
_cell_volume                     1458.2(3)
_computing_cell_refinement       SMART-NT
_computing_data_collection       'SMART-NT (Bruker, 2001)'
_computing_data_reduction        'SAINT-NT (Bruker, 2000)'
_computing_molecular_graphics
'ORTEP-3 for Windows (Farrugia, 1997) and PLATON (Spek, 2003)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       '\f and \w'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0696
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            10449
_diffrn_reflns_theta_full        27
_diffrn_reflns_theta_max         27
_diffrn_reflns_theta_min         1.63
_exptl_absorpt_coefficient_mu    1.719
_exptl_absorpt_correction_T_max  0.721
_exptl_absorpt_correction_T_min  0.590
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS in SAINT-NT; Bruker, 2000)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.187
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             944
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.19
_refine_diff_density_max         0.657
_refine_diff_density_min         -0.616
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.995
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     236
_refine_ls_number_reflns         3154
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.995
_refine_ls_R_factor_gt           0.0517
_refine_ls_shift/su_max          0.007
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0483P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1158
_reflns_number_gt                1982
_reflns_number_total             3154
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            om2053.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2210760
_cod_database_fobs_code          2210760