Intramolecular C−H and N−H Transfer by Ruthenium(II) Amidophosphine Complexes
Fryzuk, Michael D.; Petrella, Michael J.; Patrick, Brian O.; Organometallics 24 (2005) 5440–; doi:10.1021/om050574i

data_4076083
_publ_section_title
;
 Intramolecular C&#x2212;H and N&#x2212;H Transfer by Ruthenium(II)
 Amidophosphine Complexes
;
_journal_issue                   22
_journal_name_full               Organometallics
_journal_page_first              5440
_journal_paper_doi               10.1021/om050574i
_journal_volume                  24
_journal_year                    2005
_chemical_formula_sum            'C43 H58 N2 Na O P Ru Si2'
_chemical_formula_weight         830.12
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             2005-06-13
_audit_creation_method           'by teXsan v1.8'
_audit_update_record
;
?
;
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_cell_angle_gamma                64.334(4)
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_cell_length_a                   10.2121(4)
_cell_length_b                   10.3162(3)
_cell_length_c                   22.133(1)
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_cell_measurement_temperature    173.2
_cell_measurement_theta_max      27.87
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_computing_cell_refinement       'd*TREK (MSC, 1996-1998)'
_computing_data_collection       'd*TREK (MSC, 1996-1998)'
_computing_data_reduction        'd*TREK (MSC, 1996-1998)'
_computing_publication_material  'teXsan (MSC, 1992-1997)'
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_computing_structure_solution
;
SIR97 (Altomare, et. al. 1998)
;
_diffrn_ambient_temperature      173.2
_diffrn_detector_area_resol_mean 11.76
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_diffrn_measurement_device_type  'Rigaku/ADSC CCD'
_diffrn_measurement_method       'area detector'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo^2^)]'
_refine_ls_weighting_scheme      sigma
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_refine_ls_wR_factor_ref         0.0821
_reflns_number_gt                7131
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_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            om050574isi20050708_045639.cif
_cod_data_source_block           mf482/Ph[NPN]Ru.NaTHF
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        2061.3(2)
_cod_original_sg_symbol_H-M      'P -1       '
_cod_original_formula_sum        'C43 H58 N2 Na O P Ru Si2 '
_cod_database_code               4076083