<i>catena</i>-Poly[[di-μ-benzoato-κ^4^<i>O</i>:<i>O</i>'-disilver(I)]-μ-<i>N</i>,<i>N</i>'-bis(2-fluorobenzylidene)butane-1,4-diamine-κ^2^<i>N</i>:<i>N</i>']
You, Zhong-Lu; Zhu, Hai-Liang; Acta Crystallographica Section C 60 (2004) m567–m568; doi:10.1107/S0108270104023066

data_2014565
_publ_section_title
<i>catena</i>-Poly[[di-\m-benzoato-\k^4^<i>O</i>:<i>O</i>'-disilver(I)]-\m-<i>N</i>,<i>N</i>'-bis(2-fluorobenzylidene)butane-1,4-diamine-\k^2^<i>N</i>:<i>N</i>']
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m567
_journal_page_last               m568
_journal_paper_doi               10.1107/S0108270104023066
_journal_volume                  60
_journal_year                    2004
_chemical_formula_iupac          '[Ag2 (C7 H5 O2)2 (C18 H18 F2 N2)]'
_chemical_formula_moiety         'C32 H28 Ag2 F2 N2 O4'
_chemical_formula_sum            'C32 H28 Ag2 F2 N2 O4'
_chemical_formula_weight         758.30
_chemical_name_systematic
;
catena-Poly[[di-\m-benzoato-\k^4^O:O'-disilver(I)]-\m-N,N'-
bis(2-fluorobenzylidene)butane-1,4-diamine-\k^2^N:N']
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                86.978(6)
_cell_angle_beta                 84.452(7)
_cell_angle_gamma                77.115(7)
_cell_formula_units_Z            1
_cell_length_a                   5.703(3)
_cell_length_b                   10.313(5)
_cell_length_c                   12.805(6)
_cell_measurement_reflns_used    1624
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      23.447
_cell_measurement_theta_min      2.622
_cell_volume                     730.3(6)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 1997)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       \w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0472
_diffrn_reflns_av_sigmaI/netI    0.0592
_diffrn_reflns_limit_h_max       4
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            3880
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.03
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.393
_exptl_absorpt_correction_T_max  0.8182
_exptl_absorpt_correction_T_min  0.7047
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.724
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             378
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.856
_refine_diff_density_min         -1.840
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.981
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     190
_refine_ls_number_reflns         2524
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.981
_refine_ls_R_factor_all          0.0948
_refine_ls_R_factor_gt           0.0801
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[\s^2^(Fo^2^)+(0.1604P)^2^] where P = (Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2007
_refine_ls_wR_factor_ref         0.2149
_reflns_number_gt                1952
_reflns_number_total             2524
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            sq1176.cif
_cod_data_source_block           I
_cod_original_cell_volume        730.4(6)
_cod_original_sg_symbol_H-M      'p -1'
_cod_database_code               2014565
_cod_database_fobs_code          2014565