Isolation of a Metastable Intermediate in a Heterometallic Cu(II)-Hg(II) 1D Polymeric Chain: Synthesis, Crystal Structure, and Photophysical Properties.
Mobin, Shaikh M.; Mishra, Veenu; Chaudhary, Archana; Inorganic chemistry 54 (2015) 1293–1299; doi:10.1021/ic502514e

data_4342222
_publ_section_title
;
 Isolation of a Metastable Intermediate in a Heterometallic Cu(II)-Hg(II)
 1D Polymeric Chain: Synthesis, Crystal Structure, and Photophysical
 Properties.
;
_journal_issue                   4
_journal_name_full               'Inorganic chemistry'
_journal_page_first              1293
_journal_page_last               1299
_journal_paper_doi               10.1021/ic502514e
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'C40 H47 Cu Hg N3 O8'
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;
 ?
;
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_computing_cell_refinement       'CrysAlis RED, Oxford Diffraction Ltd.,'
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_computing_data_reduction        'CrysAlis RED, Oxford Diffraction Ltd.,'
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_diffrn_measurement_device_type  'OXFORD DIFFRACTION SUPER NOVA'
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;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            green
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1842P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                4890
_reflns_number_total             6899
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic502514e_si_006.cif
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 4342221--4342223.cif.
;
_cod_original_cell_volume        1962.2(3)
_cod_database_code               4342222