Selective palladium(ii)-mediated oxidation of homoallylic N-tert-butanesulfinyl amine derivatives.
Sirvent, Ana; Soler, Tatiana; Foubelo, Francisco; Yus, Miguel; Chemical communications (Cambridge, England) 53 (2017) 2701–2704; doi:10.1039/c7cc00826k

data_7119633
_publ_section_title
;
 Selective palladium(ii)-mediated oxidation of homoallylic
 N-tert-butanesulfinyl amine derivatives.
;
_journal_issue                   18
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              2701
_journal_page_last               2704
_journal_paper_doi               10.1039/c7cc00826k
_journal_volume                  53
_journal_year                    2017
_chemical_absolute_configuration syn
_chemical_formula_moiety         'C19 H26 Br N O3 S'
_chemical_formula_sum            'C19 H26 Br N O3 S'
_chemical_formula_weight         428.38
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2017-01-26 deposited with the CCDC.
2017-02-07 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.997
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_diffrn_measurement_method       'phi and omega scans'
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0000P)^2^+0.4033P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1104
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_reflns_number_gt                2641
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_reflns_threshold_expression     I>2\s(I)
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_cod_depositor_comments          'Adding full bibliography for 7119633.cif.'
_cod_original_cell_volume        2079.8(10)
_cod_original_sg_symbol_H-M      'P 212121'
_cod_database_code               7119633