Crystal structure of <i>catena</i>-poly[[[aqua-bis-(di-methyl-formamide-κ<i>O</i>)magnesium(II)]-μ<sub>3</sub>-(2,2'-bi-pyridine-5,5'-di-carboxyl-ato-κ<sup>5</sup><i>O</i><sup>2</sup>:<i>O</i><sup>2'</sup>:<i>N</i>,<i>N</i>':<i>O</i><sup>5</sup>)-[di-chlorido-platinum(II)]] di-methyl-formamide monosolvate].
Lundvall, Fredrik; Tilset, Mats; Acta crystallographica. Section E, Crystallographic communications 73 (2017) 971–974; doi:10.1107/S2056989017008118

data_2311388
_publ_section_title
;
 Crystal structure of
 <i>catena</i>-poly[[[aqua-bis-(di-methyl-formamide-\k<i>O</i>)magnesium(II)]-\m<sub>3</sub>-(2,2'-bi-pyridine-5,5'-di-carboxyl-ato-\k<sup>5</sup><i>O</i><sup>2</sup>:<i>O</i><sup>2'</sup>:<i>N</i>,<i>N</i>':<i>O</i><sup>5</sup>)-[di-chlorido-platinum(II)]]
 di-methyl-formamide monosolvate].
;
_journal_coeditor_code           VN2129
_journal_issue                   'Pt 7'
_journal_name_full
'Acta crystallographica. Section E, Crystallographic communications'
_journal_page_first              971
_journal_page_last               974
_journal_paper_doi               10.1107/S2056989017008118
_journal_volume                  73
_journal_year                    2017
_chemical_formula_iupac
'[Mg Pt Cl2 (C12 H6 N2 O4) (C3 H7 N O)2 (H 2 O)], C3 H7 N O'
_chemical_formula_moiety         'C18 H22 Cl2 Mg N4 O7 Pt, C3 H7 N O'
_chemical_formula_sum            'C21 H29 Cl2 Mg N5 O8 Pt'
_chemical_formula_weight         769.79
_chemical_name_systematic
;<i>catena</i>-Poly[[[aquabis(dimethylformamide-\k<i>O</i>)magnesium(II)]-\m~3~-(2,2'-bipyridine-5,5'-dicarboxylato-\k^5^<i>O</i>^2^:<i>O</i>^2'^:<i>N</i>,<i>N</i>':<i>O</i>^5^)-[dichloridoplatinum(II)]] dimethylformamide
monosolvate]
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_method
;
Olex2 1.2
(compiled 2017.03.28 svn.r3405 for OlexSys, GUI svn.r5337)
;
_cell_angle_alpha                69.206(14)
_cell_angle_beta                 80.361(17)
_cell_angle_gamma                69.054(14)
_cell_formula_units_Z            2
_cell_length_a                   9.224(4)
_cell_length_b                   12.083(6)
_cell_length_c                   13.673(7)
_cell_measurement_reflns_used    9986
_cell_measurement_temperature    100
_cell_measurement_theta_max      24.753
_cell_measurement_theta_min      2.373
_cell_volume                     1329.1(11)
_computing_cell_refinement
;
SAINT (Bruker, 2015)
;
_computing_data_collection
;
APEX3 (Bruker, 2016)
;
_computing_data_reduction
;
SAINT (Bruker, 2015)
;
_computing_molecular_graphics
;
DIAMOND (Brandenburg, 2014) and
<i>ChemBioDraw Ultra</i> (Cambridge Soft, 2012)
;
_computing_publication_material
;
publCIF (Westrip, 2010)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015b) and <i>OLEX2</i> (Dolomanov <i>et al.</i>,
 2009)
;
_computing_structure_solution
;
SHELXT (Sheldrick, 2015a)
;
_diffrn_ambient_temperature      100
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker PHOTON CCD'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0573
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            31765
_diffrn_reflns_theta_full        24.983
_diffrn_reflns_theta_max         24.983
_diffrn_reflns_theta_min         2.367
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.558
_exptl_absorpt_correction_T_max  0.7451
_exptl_absorpt_correction_T_min  0.5176
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Krause <i>et al.</i>, 2015)
;
_exptl_crystal_colour            'clear yellow'
_exptl_crystal_density_diffrn    1.923
_exptl_crystal_description       needle
_exptl_crystal_F_000             756
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.924
_refine_diff_density_min         -2.420
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.086
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     352
_refine_ls_number_reflns         4615
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.086
_refine_ls_R_factor_all          0.0295
_refine_ls_R_factor_gt           0.0276
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0491P)^2^+1.4382P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0720
_refine_ls_wR_factor_ref         0.0738
_reflns_number_gt                4405
_reflns_number_total             4615
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            vn2129sup1.cif
_cod_data_source_block           I
_cod_database_code               2311388
_shelx_estimated_absorpt_t_min   0.403
_shelx_estimated_absorpt_t_max   0.635
_shelx_hkl_checksum              3163
_shelx_res_checksum              22240