A Novel Self-Generating Liquid MOCVD Precursor for Cobalt Oxide Thin Films
; Chemistry of Materials  (2003) –; doi:10.1021/cm034305z

data_4000294
_publ_section_title
;
A Novel Self-Generating Liquid MOCVD Precursor for Cobalt Oxide Thin Films
;
_journal_name_full               'Chemistry of Materials'
_journal_paper_doi               10.1021/cm034305z
_journal_year                    2003
_chemical_formula_moiety         '(C5 H1 O2 F6 -1)2, (Co +2), (H2 O)2'
_chemical_formula_sum            'C20 H28 Co F12 O11'
_chemical_formula_weight         731.35
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 110.040(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.5346(6)
_cell_length_b                   7.9586(4)
_cell_length_c                   22.6169(8)
_cell_measurement_temperature    293(2)
_cell_volume                     2965.1(2)
_diffrn_ambient_temperature      150
_diffrn_measurement_device_type  'Siemens/SMART CCD'
_diffrn_measurement_method       \q/2\q
_diffrn_radiation_monochromator  'Gobel mirrors'
_diffrn_radiation_source         'Siemens Cu rotating anode'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.1147
_diffrn_reflns_av_sigmaI/netI    0.0710
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            5772
_diffrn_reflns_theta_max         57.59
_diffrn_reflns_theta_min         2.77
_exptl_absorpt_coefficient_mu    5.738
_exptl_absorpt_correction_type   'SADABS, SHELDRICK'
_exptl_crystal_density_diffrn    1.638
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1484
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.25
_refine_ls_extinction_coef       0.00020(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.895
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     417
_refine_ls_number_reflns         3534
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.895
_refine_ls_R_factor_all          0.0826
_refine_ls_R_factor_gt           0.0704
_refine_ls_shift/su_max          0.157
_refine_ls_shift/su_mean         0.032
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1552P)^2^+5.0455P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1829
_refine_ls_wR_factor_ref         0.1967
_reflns_number_gt                2878
_reflns_number_total             3534
_reflns_threshold_expression     >2sigma(I)
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               4000294