Unexpected Reactivity and Coordination in Gallium(III) and Indium(III) Chloride Complexes With Geometrically Constrained Thio- and Selenoether Ligands
Kathryn George; Marek Jura; William Levason; Mark E. Light; Luke P. Ollivere; Gillian Reid; Inorganic Chemistry 51 (2012) 2231–2240; doi:10.1021/ic202670v

data_4328459
_publ_contact_author_address
;   School of Chemistry
    University of Southampton
    Southampton SO17 1BJ, UK
;
_publ_contact_author_email       gr@soton.ac.uk
_publ_contact_author_fax         '023 8059 3781'
_publ_contact_author_name        'Professor Gillian Reid'
_publ_contact_author_phone       '023 8059 3609'
_publ_section_title
;
 Unexpected Reactivity and Coordination in Gallium(III) and Indium(III)
 Chloride Complexes With Geometrically Constrained Thio- and Selenoether
 Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2231
_journal_page_last               2240
_journal_paper_doi               10.1021/ic202670v
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C12 H24 Cl2 Ga Se4 1+, Cl4 Ga 1-'
_chemical_formula_sum            'C12 H24 Cl6 Ga2 Se4'
_chemical_formula_weight         836.29
_chemical_name_systematic
; 
 dichloro(1,5,9,13-tetraselenacyclohexadecane)gallium tetrachlorogallate(III)
;
_space_group_crystal_system      orthorhombic
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_symmetry_space_group_name_H-M   'P b c a'
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_atom_sites_solution_primary     direct
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_audit_author_name               'Webster, M.'
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'Bruker-Nonius APEX II CCD camera on \k-goniostat'
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'G.M. Sheldrick, (2007). SADABS. Version 2007/2. Bruker AXS Inc.'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0152P)^2^+14.7511P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_database_code               4328459