A symmetric, triply interlaced 3-D anionic MOF that exhibits both magnetic order and SMM behaviour.
Campo, J.; Falvello, L. R.; Forcén-Vázquez, E; Sáenz de Pipaón, C; Palacio, F.; Tomás, M; Dalton transactions (Cambridge, England : 2003) 45 (2016) 16764–16768; doi:10.1039/c6dt02652d

data_7040437
_publ_section_title
;
 A symmetric, triply interlaced 3-D anionic MOF that exhibits both
 magnetic order and SMM behaviour.
;
_journal_issue                   42
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              16764
_journal_page_last               16768
_journal_paper_doi               10.1039/c6dt02652d
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C24 H48 Co6 K4 O44'
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;
With reference to International Tables for Crystallography,
Volume A, Fifth Edition, Ed. Th. Hahn, this is Space Group
88, Origin Choice 1. The origin is at (-4), and (-1) is at
(0, 1/4, 1/8).
;
_symmetry_space_group_name_Hall  'I 4bw -1bw'
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2016-06-22 deposited with the CCDC.
2016-08-22 downloaded from the CCDC.
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CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
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CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
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CrysAlisPro, Agilent Technologies,
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Multi-scan absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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_exptl_crystal_colour            'dark pink'
_exptl_crystal_density_diffrn    2.104
_exptl_crystal_description       block
_exptl_crystal_F_000             3128
_exptl_crystal_preparation       ', Magnetic properties'
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No quotients, so Flack parameter determined by classical intensity fit
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0286P)^2^+15.7043P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0730
_refine_ls_wR_factor_ref         0.0734
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    0.000
_reflns_Friedel_fraction_max     0.000
_reflns_number_gt                3442
_reflns_number_total             3514
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt02652d2.cif
_cod_data_source_block           p890l
_cod_depositor_comments          'Adding full bibliography for 7040437.cif.'
_cod_database_code               7040437
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_shelxl_version_number           2013-4
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