Crystal structure of a twisted-ribbon type double-stranded Ag<sup>I</sup> coordination polymer: <i>catena</i>-poly[[silver(I)-μ<sub>3</sub>-bis-(pyridin-3-ylmeth-yl)sulfane-κ<sup>3</sup><i>N</i>:<i>N</i>':<i>S</i>] nitrate].
Moon, Suk-Hee; Kang, Youngjin; Park, Ki-Min; Acta crystallographica. Section E, Crystallographic communications 73 (2017) 1587–1589; doi:10.1107/S2056989017013925

data_2311452
_publ_section_title
;
 Crystal structure of a twisted-ribbon type double-stranded Ag<sup>I</sup>
 coordination polymer:
 <i>catena</i>-poly[[silver(I)-\m<sub>3</sub>-bis-(pyridin-3-ylmeth-yl)sulfane-\k<sup>3</sup><i>N</i>:<i>N</i>':<i>S</i>]
 nitrate].
;
_journal_issue                   'Pt 10'
_journal_name_full
'Acta crystallographica. Section E, Crystallographic communications'
_journal_page_first              1587
_journal_page_last               1589
_journal_paper_doi               10.1107/S2056989017013925
_journal_volume                  73
_journal_year                    2017
_chemical_formula_iupac          '[Ag (C12 H12 N2 S)] N O3'
_chemical_formula_moiety         'C12 H12 Ag N2 S +, N O3 -'
_chemical_formula_sum            'C12 H12 Ag N3 O3 S'
_chemical_formula_weight         386.18
_chemical_name_systematic
'<i>catena</i>-Poly[[silver(I)-\m~3~-bis(pyridin-3-ylmethyl)sulfane-\k^3^<i>N</i>:<i>N</i>':<i>S</i>] nitrate]'
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 98.636(3)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   22.432(3)
_cell_length_b                   8.1656(12)
_cell_length_c                   15.036(2)
_cell_measurement_reflns_used    3272
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      1.84
_cell_volume                     2722.9(7)
_computing_cell_refinement
;
SAINT (Bruker, 2014)
;
_computing_data_collection
;
APEX2 (Bruker, 2014)
;
_computing_data_reduction
;
SAINT (Bruker, 2014)
;
_computing_molecular_graphics
;
DIAMOND (Brandenburg, 2010)
;
_computing_publication_material
;
SHELXTL (Sheldrick, 2008) and publCIF (Westrip, 2010)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0790
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            7550
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.999
_diffrn_reflns_theta_min         2.658
_exptl_absorpt_coefficient_mu    1.644
_exptl_absorpt_correction_T_max  0.8956
_exptl_absorpt_correction_T_min  0.6581
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2014)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.884
_exptl_crystal_description       plate
_exptl_crystal_F_000             1536
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.050
_refine_diff_density_max         0.655
_refine_diff_density_min         -0.659
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.972
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     209
_refine_ls_number_reflns         2676
_refine_ls_number_restraints     24
_refine_ls_restrained_S_all      0.986
_refine_ls_R_factor_all          0.0811
_refine_ls_R_factor_gt           0.0436
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0526P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0935
_refine_ls_wR_factor_ref         0.1087
_reflns_number_gt                1763
_reflns_number_total             2676
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            sj5535sup1.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2311452
_shelx_estimated_absorpt_t_min   0.684
_shelx_estimated_absorpt_t_max   0.922
_shelx_hkl_checksum              91248
_shelx_res_checksum              30376