An insight into the communication between β-olefin/phenyl olefin-mediated acceptors and porphyrin π-system: a way to establish porphyrin based chemodosimeters and chemosensors.
Chahal, Mandeep K.; Sankar, Muniappan; Butcher, Ray J.; Physical chemistry chemical physics : PCCP 19 (2017) 4530–4540; doi:10.1039/c6cp08396j

data_7227354
_publ_section_title
;
 An insight into the communication between \b-olefin/phenyl
 olefin-mediated acceptors and porphyrin \p-system: a way to establish
 porphyrin based chemodosimeters and chemosensors.
;
_journal_issue                   6
_journal_name_full               'Physical chemistry chemical physics : PCCP'
_journal_page_first              4530
_journal_page_last               4540
_journal_paper_doi               10.1039/c6cp08396j
_journal_volume                  19
_journal_year                    2017
_chemical_formula_moiety         'C232 H140 N20 Ni4 O16, C1 H1 Cl3'
_chemical_formula_sum            'C233 H141 Cl3 N20 Ni4 O16'
_chemical_formula_weight         3817.84
_chemical_name_common
;
 2-Nitro-12,13-bis(4-formylphenyl)-5,10,15,20-tetraphenylporphyrin nickel(II) complex
;
_chemical_name_systematic
;
 2-Nitro-12,13-bis(4-formylphenyl)-5,10,15,20-tetraphenylporphyrinatonickel(II)
;
_space_group_crystal_system      triclinic
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;
2016-12-02 deposited with the CCDC.
2017-01-04 downloaded from the CCDC.
;
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'Re-crystallisation from solvent: Chloroform and hexane'
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'w=1/[\s^2^(Fo^2^)+(0.1401P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7227352--7227354.cif.'
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