Covalently linked triarylborane-iridium(III) complex as a photocatalyst for CO<sub>2</sub> reduction.
Fukumoto, Ryo; Yokoo, Takuya; Sakuda, Eri; Omoto, Kenichiro; Horiuchi, Shinnosuke; Arikawa, Yasuhiro; Umakoshi, Keisuke; Chemical communications (Cambridge, England) 61 (2025) 14943–14946; doi:10.1039/d5cc03094c

data_7134903
_publ_section_title
;
 Covalently linked triarylborane-iridium(III) complex as a photocatalyst
 for CO<sub>2</sub> reduction.
;
_journal_issue                   77
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              14943
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_journal_paper_doi               10.1039/d5cc03094c
_journal_volume                  61
_journal_year                    2025
_chemical_formula_sum            'C69 H73 B2 Cl2 F4 Ir N4'
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_audit_update_record
;
2024-06-25 deposited with the CCDC.	2025-08-18 downloaded from the CCDC.
;
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_computing_data_collection       'CrystalClear-SM Expert 2.1 b46 (Rigaku. 2016)'
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_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
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_diffrn_measurement_device_type  'Rigaku Saturn70'
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_exptl_crystal_colour            Yellow
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0120P)^2^+28.4704P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1845
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_reflns_number_gt                8793
_reflns_number_total             14108
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d5cc03094c2.cif
_cod_data_source_block           shelx_trans
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 

 Adding full bibliography for 7134903.cif.
;
_cod_original_sg_symbol_H-M      'P 21/c'
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_shelx_shelxl_version_number     2019/3
_shelx_estimated_absorpt_t_min   0.785
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_shelx_res_checksum              52693