Synthesis and reactivity of acyclic heterotrinuclear metal complexes.
Sahoo, Rajata Kumar; Wölper, Christoph; Möbius, Joost; Schulz, Stephan; Chemical communications (Cambridge, England) 61 (2025) 16774–16777; doi:10.1039/d5cc03627e

data_7135011
_publ_section_title
;
 Synthesis and reactivity of acyclic heterotrinuclear metal complexes.
;
_journal_issue                   86
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              16774
_journal_page_last               16777
_journal_paper_doi               10.1039/d5cc03627e
_journal_volume                  61
_journal_year                    2025
_chemical_formula_sum            'C33 H51 Al N2 Zn'
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_space_group_name_Hall           '-P 2ac 2n'
_space_group_name_H-M_alt        'P n m a'
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_atom_sites_solution_primary     direct
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_audit_update_record
;
2025-06-25 deposited with the CCDC.	2025-09-25 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_c                   9.8381(11)
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_cell_measurement_temperature    100(2)
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_cell_volume                     3178.7(6)
_computing_cell_refinement       'BRUKER APEX3(v2019.1-0)'
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_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker D8 KAPPA II (APEX II detector)'
_diffrn_measurement_method       'Data collection strategy APEX 3/Queen'
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_diffrn_source                   'fine-focus sealed tube'
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_exptl_absorpt_process_details   'SADABS, Blessing, Acta Cryst 1995 A51 33-38'
_exptl_crystal_colour            'pale orange'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0103P)^2^+6.2659P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7135011--7135020.cif.'
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