Unprecedented pseudo-zeroth-order kinetics of the catecholase-like activity of mixed-valence MnIIMn2III complexes
Dasgupta, Sanchari; Karim, Suhana; Khatua, Somanjana; Adhikary, Amit; Acharya, Krishnendu; Zangrando, Ennio; Maity, Suvendu; Das, Debasis; New Journal of Chemistry 47 (2023) 9681–9691; doi:10.1039/D2NJ06357C

data_7062425
_publ_section_title
;
 Unprecedented pseudo-zeroth-order kinetics of the catecholase-like
 activity of mixed-valence MnIIMn2III complexes
;
_journal_issue                   20
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              9681
_journal_page_last               9691
_journal_paper_doi               10.1039/D2NJ06357C
_journal_volume                  47
_journal_year                    2023
_chemical_formula_moiety         'C32 H42 Br4 Mn3 N2 O14, 3(C H4 O)'
_chemical_formula_sum            'C35 H54 Br4 Mn3 N2 O17'
_chemical_formula_weight         1259.26
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_atom_sites_solution_hydrogens   mixed
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_audit_update_record
;
2019-05-17 deposited with the CCDC.	2023-04-05 downloaded from the CCDC.
;
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_diffrn_radiation_monochromator  Si111
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+0.5824P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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'Adding full bibliography for 7062424--7062425.cif.'
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