Structural and magnetic studies of mononuclear lanthanide complexes derived from N-rich chiral Schiff bases.
Pilichos, E.; Font-Bardia, M; Escuer, A.; Mayans, J.; Dalton transactions (Cambridge, England : 2003) 50 (2021) 1746–1753; doi:10.1039/d0dt04224b

data_7706235
_publ_section_title
;
 Structural and magnetic studies of mononuclear lanthanide complexes
 derived from N-rich chiral Schiff bases.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1746
_journal_page_last               1753
_journal_paper_doi               10.1039/d0dt04224b
_journal_volume                  50
_journal_year                    2021
_chemical_absolute_configuration rm
_chemical_formula_moiety         'C18 H20 Gd N7 O9, C H4 O'
_chemical_formula_sum            'C19 H24 Gd N7 O10'
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_audit_update_record
;
2020-11-08 deposited with the CCDC.	2020-12-29 downloaded from the CCDC.
;
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_measurement_device_type  'D8 Venture'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0266
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_diffrn_reflns_theta_min         3.612
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_exptl_crystal_preparation       'Magnetic properties'
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'Re-crystallisation from solvent: Methanol/Diethylether'
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_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.036(10)
_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0190
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+0.8069P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7706233--7706235.cif.'
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