Homocoupling of CO and isocyanide mediated by a C,C'-bis(silylenyl)-substituted ortho-carborane.
Xiong, Yun; Yao, Shenglai; Szilvási, Tibor; Ruzicka, Ales; Driess, Matthias; Chemical communications (Cambridge, England) 56 (2020) 747–750; doi:10.1039/c9cc08680c

data_7125811
_publ_section_title
;
 Homocoupling of CO and isocyanide mediated by a
 C,C'-bis(silylenyl)-substituted ortho-carborane.
;
_journal_issue                   5
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              747
_journal_page_last               750
_journal_paper_doi               10.1039/c9cc08680c
_journal_volume                  56
_journal_year                    2020
_chemical_formula_sum            'C50 H74 B10 N6 Si2'
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_audit_update_record
;
2019-11-04 deposited with the CCDC.	2019-12-06 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      150(2)
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_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Single source at offset, Atlas'
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.151
_exptl_crystal_description       prism
_exptl_crystal_F_000             1976
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_refine_ls_restrained_S_all      1.015
_refine_ls_R_factor_all          0.0538
_refine_ls_R_factor_gt           0.0426
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0609P)^2^+1.7081P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1080
_refine_ls_wR_factor_ref         0.1186
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7942
_reflns_number_total             9584
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9cc08680c2.cif
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_cod_depositor_comments
'Adding full bibliography for 7125810--7125811.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7125811
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.794
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_shelx_res_checksum              4598