Divergent synthesis of indole-fused polycycles via Rh(ii)-catalyzed intramolecular [3 + 2] cycloaddition and C–H functionalization of indolyltriazoles
Zhang, Yong-Sheng; Tang, Xiang-Ying; Shi, Min; Organic Chemistry Frontiers 2 (2015) 1516–; doi:10.1039/C5QO00216H

data_1553171
_publ_section_title
;
 Divergent synthesis of indole-fused polycycles via Rh(ii)-catalyzed
 intramolecular [3 + 2] cycloaddition and C--H functionalization of
 indolyltriazoles
;
_journal_issue                   11
_journal_name_full               'Organic Chemistry Frontiers'
_journal_page_first              1516
_journal_paper_doi               10.1039/C5QO00216H
_journal_volume                  2
_journal_year                    2015
_chemical_formula_sum            'C28 H29 N3 O4 S2'
_chemical_formula_weight         535.66
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2014-08-07 deposited with the CCDC.
2015-09-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 105.831(2)
_cell_angle_gamma                90
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_cell_length_c                   14.6463(12)
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_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      45.227
_cell_measurement_theta_min      4.497
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_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
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_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_R_equivalents  0.0333
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_diffrn_reflns_limit_l_min       -18
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0883P)^2^+0.2866P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               1553171
_shelxl_version_number           2013-4
_shelx_res_checksum              60624
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