Nitrosocarbonyl-Henry and Denitration Cascade: Synthesis of α-Ketoamides and α-Keto Oximes.
Reddy, Mallu Kesava; Mallik, Sumitava; Ramakrishna, Isai; Baidya, Mahiuddin; Organic letters 19 (2017) 1694–1697; doi:10.1021/acs.orglett.7b00482

data_1545561
_publ_section_title
;
 Nitrosocarbonyl-Henry and Denitration Cascade: Synthesis of \a-Ketoamides
 and \a-Keto Oximes.
;
_journal_issue                   7
_journal_name_full               'Organic letters'
_journal_page_first              1694
_journal_page_last               1697
_journal_paper_doi               10.1021/acs.orglett.7b00482
_journal_volume                  19
_journal_year                    2017
_chemical_formula_sum            'C9 H9 N O2'
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_symmetry_space_group_name_Hall  '-P 2ybc'
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_atom_sites_solution_hydrogens   mixed
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
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_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
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_refine_ls_R_factor_all          0.0532
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0489P)^2^+0.1347P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0946
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_reflns_number_total             1454
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           trae
_cod_depositor_comments
'Adding full bibliography for 1545561--1545562.cif.'
_cod_database_code               1545561
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_shelx_estimated_absorpt_t_min   0.980
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_shelx_hkl_checksum              26204