Palladium complexes of N-heterocyclic carbenes displaying an unsymmetrical N-alkylfluorenyl/N'-aryl substitution pattern and their behaviour in Suzuki-Miyaura cross coupling.
Almallah, Hamzé; Brenner, Eric; Matt, Dominique; Harrowfield, Jack; Jahjah, Mohamad; Hijazi, Akram; Dalton transactions (Cambridge, England : 2003) 48 (2019) 14516–14529; doi:10.1039/c9dt02948f

data_7701187
_publ_section_title
;
 Palladium complexes of N-heterocyclic carbenes displaying an
 unsymmetrical N-alkylfluorenyl/N'-aryl substitution pattern and their
 behaviour in Suzuki-Miyaura cross coupling.
;
_journal_issue                   38
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14516
_journal_page_last               14529
_journal_paper_doi               10.1039/c9dt02948f
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C36 H39 Cl2 N3 O Pd, C H2 Cl2'
_chemical_formula_sum            'C37 H41 Cl4 N3 O Pd'
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
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_audit_block_doi                 10.5517/ccdc.csd.cc21pw6v
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_audit_update_record
;
2019-02-18 deposited with the CCDC.    2019-09-16 downloaded from the CCDC.
;
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_cell_volume                     3637.48(11)
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_computing_structure_solution    'SHELXS-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      173(2)
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_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_h_max       15
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_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            59394
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_exptl_absorpt_process_details   'MULscanABS in PLATON (Spek, 2003)'
_exptl_crystal_colour            yellow
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_exptl_crystal_description       plate
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0589P)^2^+2.0747P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1002
_refine_ls_wR_factor_ref         0.1218
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6730
_reflns_number_total             8352
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt02948f2.cif
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_cod_depositor_comments
'Adding full bibliography for 7701184--7701187.cif.'
_cod_database_code               7701187
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