Linear Trinuclear Pt...Mo-Mo Complexes [Mo2PtX2(pyphos)2(O2CR)2]2 (X = Cl, Br, I; R = CH3, C(CH3)3; pyphos = 6-(Diphenylphosphino)-2-pyridonate) with an Axial Interaction between the Quadruply Bonded Mo2 Moiety and the Platinum Atom
Hiroshi Nakano; Akira Nakamura; Kazushi Mashima; Inorganic Chemistry 35 (1996) 4007–4012; doi:10.1021/ic950988b

data_4323835
_publ_section_title
;
 Linear Trinuclear Pt...Mo-Mo Complexes [Mo2PtX2(pyphos)2(O2CR)2]2 (X =
 Cl, Br, I; R = CH3, C(CH3)3; pyphos = 6-(Diphenylphosphino)-2-pyridonate)
 with an Axial Interaction between the Quadruply Bonded Mo2 Moiety and the
 Platinum Atom
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4007
_journal_page_last               4012
_journal_paper_doi               10.1021/ic950988b
_journal_volume                  35
_journal_year                    1996
_chemical_formula_sum            'C44 H44 Cl2 Mo2 N2 O6 P2 Pt'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Tue Nov 21 21:50:44 1995'
_audit_creation_method           'from TEXRAY.INF file'
_cell_angle_alpha                101.20(2)
_cell_angle_beta                 117.00(1)
_cell_angle_gamma                85.47(2)
_cell_formula_units_Z            2.00
_cell_length_a                   13.541(3)
_cell_length_b                   17.029(3)
_cell_length_c                   12.896(3)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    23.0
_cell_measurement_theta_max      0.00
_cell_measurement_theta_min      0.00
_cell_volume                     2599.0(10)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan: PROCESS (MSC)'
_computing_publication_material  'teXsan: FINISH (MSC)'
_computing_structure_refinement  'teXsan: LS (MSC)'
_computing_structure_solution    SHELXS86
_diffrn_ambient_temperature      23.0
_diffrn_measurement_device       AFC5R
_diffrn_measurement_method       'omega scans with profile analysis'
_diffrn_orient_matrix_UB_11      -0.06390
_diffrn_orient_matrix_UB_12      -0.01677
_diffrn_orient_matrix_UB_13      -0.07941
_diffrn_orient_matrix_UB_21      0.00184
_diffrn_orient_matrix_UB_22      -0.05477
_diffrn_orient_matrix_UB_23      0.01805
_diffrn_orient_matrix_UB_31      -0.05276
_diffrn_orient_matrix_UB_32      0.01741
_diffrn_orient_matrix_UB_33      0.03449
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode'
_diffrn_radiation_type           MoKalpha
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  8.90
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -4
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_number            4868
_diffrn_reflns_theta_max         29.7254
_diffrn_standards_decay_%        -2.73
_diffrn_standards_interval_count 0
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu_cm 33.542
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.757
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            unknown
_exptl_crystal_density_diffrn    1.554
_exptl_crystal_description       unknown
_exptl_crystal_F_000             1192.00
_exptl_crystal_size_max          0.000
_exptl_crystal_size_min          0.000
_refine_diff_density_max         -1.49840
_refine_diff_density_min         1.75880
_refine_ls_extinction_coef       0.00000
_refine_ls_extinction_method     Zachariasen_type_2_Gaussian_isotropic
_refine_ls_goodness_of_fit_obs   3.100
_refine_ls_matrix_type           full
_refine_ls_number_parameters     604
_refine_ls_number_reflns         8148
_refine_ls_number_restraints     0
_refine_ls_R_factor_obs          0.0500
_refine_ls_shift/esd_max         1.4800
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_obs         0.0640
_cod_data_source_file            ic950988b_1.cif
_cod_data_source_block           Mo2PtCl2(Pyphos)2(O2CMe3)2.(CH2Cl2)
_cod_original_cell_volume        2599(1)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C44 H44 O6 N2 Cl2 P2 Mo2 Pt'
_cod_database_code               4323835