Palladium(ii) complexes featuring a mixed phosphine-pyridine-iminophosphorane pincer ligand: synthesis and reactivity.
Cheisson, Thibault; Auffrant, Audrey; Dalton transactions (Cambridge, England : 2003) 45 (2016) 2069–2078; doi:10.1039/c5dt02789f

data_7036289
_publ_section_title
;
 Palladium(ii) complexes featuring a mixed
 phosphine-pyridine-iminophosphorane pincer ligand: synthesis and
 reactivity.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2069
_journal_page_last               2078
_journal_paper_doi               10.1039/c5dt02789f
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C42 H37 N3 P2 Pd, 2(B F4)'
_chemical_formula_sum            'C42 H37 B2 F8 N3 P2 Pd'
_chemical_formula_weight         925.70
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2015-07-22 deposited with the CCDC.
2015-08-25 downloaded from the CCDC.
;
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_cell_angle_gamma                90
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SIR97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      150.0(1)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Kappa APEX II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
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_exptl_absorpt_correction_T_min  0.927743
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_refine_ls_R_factor_all          0.0728
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0001P)^2^+67.6524P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7036288--7036291.cif.'
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