Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene.
Ledet, Anthony D.; Hudnall, Todd W.; Dalton transactions (Cambridge, England : 2003) 45 (2016) 9820–9826; doi:10.1039/c6dt00300a

data_7038215
_publ_section_title
;
 Reduction of a diamidocarbene-supported borenium cation: isolation of a
 neutral boryl-substituted radical and a carbene-stabilized aminoborylene.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9820
_journal_page_last               9826
_journal_paper_doi               10.1039/c6dt00300a
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         {(C24H28N2O2)-B-Cl-N(C3H7)2-C6H6
_chemical_formula_sum            'C33 H45 B Cl N3 O2'
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_audit_update_record
;
2016-01-20 deposited with the CCDC.
2016-02-01 downloaded from the CCDC.
;
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_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
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_diffrn_reflns_av_R_equivalents  0.0632
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0737P)^2^+2.1522P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6dt00300a2.cif
_cod_data_source_block           3-radical
_cod_depositor_comments
'Adding full bibliography for 7038214--7038215.cif.'
_cod_original_cell_volume        1573.9(6)
_cod_database_code               7038215
_shelx_shelxl_version_number     2014/7
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