LMucko/crystallography-open-database huggingface dataset:
Carbon‒Oxygen Bond Formation at Metal(IV) Centers: Reactivity of Palladium(II) and Platinum(II) Complexes of the [2,6-(Dimethylaminomethyl)phenyl-N,C,N]-(Pincer) Ligand toward Iodomethane and Dibenzoyl Peroxide; Structural Studies of M(II) and M(IV) Complexes
Canty, Allan J.; Denney, Melanie C.; van Koten, Gerard; Skelton, Brian W.; White, Allan H.; Organometallics 23 (2004) 5432–5439; doi:10.1021/om040061w

data_4060976
_publ_section_title
;
 Carbon--Oxygen Bond Formation at Metal(IV) Centers: Reactivity of
 Palladium(II) and Platinum(II) Complexes of the
 [2,6-(Dimethylaminomethyl)phenyl-N,C,N]-(Pincer) Ligand toward
 Iodomethane and Dibenzoyl Peroxide; Structural Studies of M(II)
 and M(IV) Complexes
;
_journal_coden_ASTM              ORGND7
_journal_issue                   23
_journal_name_full               Organometallics
_journal_page_first              5432
_journal_page_last               5439
_journal_paper_doi               10.1021/om040061w
_journal_volume                  23
_journal_year                    2004
_chemical_formula_moiety         'C27 H32 N2 O4 Pt1, C3 H6 O, H2 O'
_chemical_formula_sum            'C30 H40 N2 O6 Pt'
_chemical_formula_weight         717.78
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.00000
_cell_angle_beta                 95.497(2)
_cell_angle_gamma                90.00000
_cell_formula_units_Z            4
_cell_length_a                   9.3107(7)
_cell_length_b                   11.6368(9)
_cell_length_c                   27.094(2)
_cell_measurement_temperature    150(2)
_cell_volume                     2922.0(4)
_exptl_crystal_density_diffrn    1.636
_cod_original_sg_symbol_Hall     -p_2yn
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C30 H40 N2 O6 Pt1'
_cod_database_code               4060976
Copper Complexes with N-Alkylated NS~2~-Macrocyclic Ligands: Synthesis, Characterization, and Capabilities as Aziridination Precatalysts
Conry ,Rebecca R.; Tipton, A. Alex; Striejewske, William S.; Erkizia, Edurne; Malwitz, Mark A.; Caffaratti, Angela; Natkin, Jonathan A.; Organometallics 23 (2004) 5210–5218; doi:10.1021/om040098g

data_4060977
_publ_section_title
;
Copper Complexes with N-Alkylated NS~2~-Macrocyclic Ligands:
Synthesis, Characterization, and Capabilities as Aziridination Precatalysts
;
_journal_issue                   22
_journal_name_full               Organometallics
_journal_page_first              5210
_journal_page_last               5218
_journal_paper_doi               10.1021/om040098g
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C10 H20 Cu F6 N2 P S2'
_chemical_formula_weight         440.91
_chemical_temperature_decomposition 435.0(10)
_space_group_IT_number           18
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2 2ab'
_symmetry_space_group_name_H-M   'P 21 21 2'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   15.917(2)
_cell_length_b                   30.197(4)
_cell_length_c                   7.3647(6)
_cell_measurement_temperature    297(2)
_cell_volume                     3539.7(7)
_diffrn_ambient_temperature      297(2)
_exptl_crystal_density_diffrn    1.655
_exptl_crystal_density_meas      ?
_refine_ls_R_factor_obs          0.0555
_refine_ls_wR_factor_obs         0.1352
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_chemical_melting_point' tag was changed to
'_chemical_temperature_decomposition' since the value had been given
as '434-436 K (dec)'. The value was changed to '435.0(10)' - the
average value was taken and precision was estimated.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_database_code               4060977
Copper Complexes with N-Alkylated NS~2~-Macrocyclic Ligands: Synthesis, Characterization, and Capabilities as Aziridination Precatalysts
Conry ,Rebecca R.; Tipton, A. Alex; Striejewske, William S.; Erkizia, Edurne; Malwitz, Mark A.; Caffaratti, Angela; Natkin, Jonathan A.; Organometallics 23 (2004) 5210–5218; doi:10.1021/om040098g

data_4060978
_publ_section_title
;
Copper Complexes with N-Alkylated NS~2~-Macrocyclic Ligands:
Synthesis, Characterization, and Capabilities as Aziridination Precatalysts
;
_journal_issue                   22
_journal_name_full               Organometallics
_journal_page_first              5210
_journal_page_last               5218
_journal_paper_doi               10.1021/om040098g
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C8 H17 Br2 Cu N S2'
_chemical_formula_weight         414.71
_chemical_name_common            'Complex 4'
_chemical_temperature_decomposition 449.5(5)
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.7942(6)
_cell_length_b                   12.6656(14)
_cell_length_c                   13.8021(14)
_cell_measurement_temperature    299(2)
_cell_volume                     1362.5(2)
_diffrn_ambient_temperature      299(2)
_exptl_crystal_density_diffrn    2.022
_refine_ls_R_factor_obs          0.0367
_refine_ls_wR_factor_obs         0.0775
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_chemical_melting_point' tag was changed to
'_chemical_temperature_decomposition' since the value had been given
as '449-450 K (dec)'. The value was changed to '449.5(5)' - the
average value was taken and precision was estimated.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_database_code               4060978
Origin of Enantioselectivity in Asymmetric Hydrovinylations Catalyzed by Phosphoramidite Nickel Catalysts: An Experimentally Supported Density Functional Study
Hölscher, Markus; Franciò, Giancarlo; Leitner, Walter; Organometallics 23 (2004) 5606–5617; doi:10.1021/om040107l

data_4060979
_publ_section_title
;
 Origin of Enantioselectivity in Asymmetric Hydrovinylations Catalyzed by
 Phosphoramidite Nickel Catalysts: An Experimentally Supported Density
 Functional Study
;
_journal_coden_ASTM              ORGND7
_journal_issue                   23
_journal_name_full               Organometallics
_journal_page_first              5606
_journal_page_last               5617
_journal_paper_doi               10.1021/om040107l
_journal_volume                  23
_journal_year                    2004
_chemical_formula_weight         624.51
_chemical_name_common            ((C10H6)O)2PNCH((Me)(Ph))2
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 106.49(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   9.594(4)
_cell_length_b                   15.841(10)
_cell_length_c                   10.786(5)
_cell_measurement_temperature    243(2)
_cell_volume                     1572.0(14)
_diffrn_ambient_temperature      243(2)
_exptl_crystal_density_diffrn    1.319
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               4060979
Facile Alkene Insertion into a Rhodium(III)‒Acetyl Bond: Potential Catalysts for CO/Alkene Copolymerization
Haynes, Anthony; Haslam, Claire E.; Bonnington, Kevin J.; Parish, Louise; Adams, Harry; Spey, Sharon E.; Marder, Todd B.; Coventry, David N.; Organometallics 23 (2004) 5907–5909; doi:10.1021/om049258e

data_4060980
_publ_section_title
;
 Facile Alkene Insertion into a Rhodium(III)--Acetyl Bond:
 Potential Catalysts for CO/Alkene Copolymerization
;
_journal_coden_ASTM              ORGND7
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              5907
_journal_page_last               5909
_journal_paper_doi               10.1021/om049258e
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C20 H26 B F4 O2 Rh'
_chemical_formula_weight         488.13
_space_group_IT_number           33
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2c -2n'
_symmetry_space_group_name_H-M   'P n a 21'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   32.942(17)
_cell_length_b                   15.150(8)
_cell_length_c                   8.584(5)
_cell_measurement_temperature    298(2)
_cell_volume                     4284(4)
_diffrn_ambient_temperature      298(2)
_exptl_crystal_density_diffrn    1.514
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4060980
Facile Alkene Insertion into a Rhodium(III)‒Acetyl Bond: Potential Catalysts for CO/Alkene Copolymerization
Haynes, Anthony; Haslam, Claire E.; Bonnington, Kevin J.; Parish, Louise; Adams, Harry; Spey, Sharon E.; Marder, Todd B.; Coventry, David N.; Organometallics 23 (2004) 5907–5909; doi:10.1021/om049258e

data_4060981
_publ_section_title
;
 Facile Alkene Insertion into a Rhodium(III)--Acetyl Bond:
 Potential Catalysts for CO/Alkene Copolymerization
;
_journal_coden_ASTM              ORGND7
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              5907
_journal_page_last               5909
_journal_paper_doi               10.1021/om049258e
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C23 H30 B F4 O2 Rh'
_chemical_formula_weight         528.19
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 94.19(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.872(4)
_cell_length_b                   15.409(4)
_cell_length_c                   12.658(4)
_cell_measurement_temperature    293(2)
_cell_volume                     2309.4(12)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.519
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4060981
A Trisilyl Zincate Containing Bidentate [(Me3Si)2Si(CH2)2Si(SiMe3)2]2- Ligands
Woods, Jaime B.; Yu, Xianghua; Chen, Tianniu; Xue, Zi-Ling; Organometallics 23 (2004) 5910–5912; doi:10.1021/om049277o

data_4060982
_publ_section_title
;
 A Trisilyl Zincate Containing Bidentate
 [(Me3Si)2Si(CH2)2Si(SiMe3)2]2- Ligands
;
_journal_coden_ASTM              ORGND7
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              5910
_journal_page_last               5912
_journal_paper_doi               10.1021/om049277o
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C4.44 H10.22 K0.11 O0.67 Si Zn0.11'
_chemical_formula_weight         114.05
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                60.196(3)
_cell_angle_beta                 75.945(3)
_cell_angle_gamma                78.761(3)
_cell_formula_units_Z            18
_cell_length_a                   12.603(2)
_cell_length_b                   16.901(3)
_cell_length_c                   16.917(3)
_cell_measurement_temperature    173(2)
_cell_volume                     3021.3(9)
_diffrn_ambient_temperature      173(2)
_exptl_crystal_density_diffrn    1.128
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4060982
Heterocyclized Carbometalation of Alkynes: Unexpected Formation of Eight-Membered Oxazirconacycles with an Intramolecularly Coordinated Isoquinoline Moiety
Zhou, Shaolin; Liu, Dongyun; Liu, Yuanhong; Organometallics 23 (2004) 5900–5902; doi:10.1021/om049302q

data_4060983
_publ_section_title
;
 Heterocyclized Carbometalation of Alkynes: Unexpected Formation of
 Eight-Membered Oxazirconacycles with an Intramolecularly Coordinated
 Isoquinoline Moiety
;
_journal_coden_ASTM              ORGND7
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              5900
_journal_page_last               5902
_journal_paper_doi               10.1021/om049302q
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C76 H62 N2 O10 Zr2'
_chemical_formula_weight         1345.72
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 102.655(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.658(2)
_cell_length_b                   22.853(4)
_cell_length_c                   24.228(5)
_cell_measurement_temperature    293(2)
_cell_volume                     6298(2)
_diffrn_ambient_temperature      293(2)
_exptl_crystal_density_diffrn    1.419
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4060983
Thermal Equilibrium between a Lattice-Framework Disilene and the Corresponding Silylene
Tsutsui, Shinobu; Tanaka, Hiromasa; Kwon, Eunsang; Matsumoto, Shigeki; Sakamoto, Kenkichi; Organometallics 23 (2004) 5659–5661; doi:10.1021/om049306v

data_4060984
_publ_section_title
;
 Thermal Equilibrium between a Lattice-Framework Disilene and the
 Corresponding Silylene
;
_journal_coden_ASTM              ORGND7
_journal_issue                   24
_journal_name_full               Organometallics
_journal_page_first              5659
_journal_page_last               5661
_journal_paper_doi               10.1021/om049306v
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C38 H72 Si4'
_chemical_formula_weight         641.32
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 121.528(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.118(5)
_cell_length_b                   13.125(3)
_cell_length_c                   17.174(4)
_cell_measurement_temperature    123(2)
_cell_volume                     4057.5(17)
_diffrn_ambient_temperature      123(2)
_exptl_crystal_density_diffrn    1.050
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4060984
Heterobimetallic Metallaborane Chemistry: Synthesis and Characterization of a "Lightly Stabilized" Molybdairidahexaborane, [{Cp*Ir}{(CO)3(THF)Mo}B4H8], and Its Direct Conversion to [{Cp*Ir}{(CO)3(L)Mo}B4H8] (L = CO, PPh3, NCPh, CNBu, NH3, PPh3CHC(O)OMe)
Macías, Ramón; Fehlner, Thomas P.; Beatty, Alicia M.; Noll, Bruce; Organometallics 23 (2004) 5994–6001; doi:10.1021/om049308f

data_4060985
_publ_section_title
;
 Heterobimetallic Metallaborane Chemistry: Synthesis and Characterization
 of a "Lightly Stabilized" Molybdairidahexaborane, [{Cp*Ir}{(CO)3(THF)Mo}B4H8],
 and Its Direct Conversion to [{Cp*Ir}{(CO)3(L)Mo}B4H8]
 (L = CO, PPh3, NCPh, CNBu, NH3, PPh3CHC(O)OMe)
;
_journal_coden_ASTM              ORGND7
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              5994
_journal_page_last               6001
_journal_paper_doi               10.1021/om049308f
_journal_volume                  23
_journal_year                    2004
_chemical_formula_sum            'C14 H23 B4 Ir Mo O4'
_chemical_formula_weight         586.70
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 103.9170(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   16.8242(8)
_cell_length_b                   11.9429(5)
_cell_length_c                   19.9351(9)
_cell_measurement_temperature    100(2)
_cell_volume                     3888.0(3)
_diffrn_ambient_temperature      100(2)
_exptl_crystal_density_diffrn    2.005
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4060985
Heterobimetallic Metallaborane Chemistry: Synthesis and Characterization of a "Lightly Stabilized" Molybdairidahexaborane, [{Cp*Ir}{(CO)3(THF)Mo}B4H8], and Its Direct Conversion to [{Cp*Ir}{(CO)3(L)Mo}B4H8] (L = CO, PPh3, NCPh, CNBu, NH3, PPh3CHC(O)OMe)
Macías, Ramón; Fehlner, Thomas P.; Beatty, Alicia M.; Noll, Bruce; Organometallics 23 (2004) 5994–6001; doi:10.1021/om049308f

data_4060986
_publ_section_title
;
 Heterobimetallic Metallaborane Chemistry: Synthesis and Characterization
 of a "Lightly Stabilized" Molybdairidahexaborane, [{Cp*Ir}{(CO)3(THF)Mo}B4H8],
 and Its Direct Conversion to [{Cp*Ir}{(CO)3(L)Mo}B4H8]
 (L = CO, PPh3, NCPh, CNBu, NH3, PPh3CHC(O)OMe)
;
_journal_coden_ASTM              ORGND7
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              5994
_journal_page_last               6001
_journal_paper_doi               10.1021/om049308f
_journal_volume                  23
_journal_year                    2004
_chemical_formula_moiety         'C20 H28 B4 Ir Mo N O3'
_chemical_formula_sum            'C20 H28 B4 Ir Mo N O3'
_chemical_formula_weight         661.81
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90.00
_cell_angle_beta                 119.8180(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   29.2740(6)
_cell_length_b                   10.5875(2)
_cell_length_c                   17.3862(4)
_cell_measurement_temperature    100(2)
_cell_volume                     4675.24(17)
_diffrn_ambient_temperature      100(2)
_exptl_crystal_density_diffrn    1.880
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4060986
Heterobimetallic Metallaborane Chemistry: Synthesis and Characterization of a "Lightly Stabilized" Molybdairidahexaborane, [{Cp*Ir}{(CO)3(THF)Mo}B4H8], and Its Direct Conversion to [{Cp*Ir}{(CO)3(L)Mo}B4H8] (L = CO, PPh3, NCPh, CNBu, NH3, PPh3CHC(O)OMe)
Macías, Ramón; Fehlner, Thomas P.; Beatty, Alicia M.; Noll, Bruce; Organometallics 23 (2004) 5994–6001; doi:10.1021/om049308f

data_4060987
_publ_section_title
;
 Heterobimetallic Metallaborane Chemistry: Synthesis and Characterization
 of a "Lightly Stabilized" Molybdairidahexaborane, [{Cp*Ir}{(CO)3(THF)Mo}B4H8],
 and Its Direct Conversion to [{Cp*Ir}{(CO)3(L)Mo}B4H8]
 (L = CO, PPh3, NCPh, CNBu, NH3, PPh3CHC(O)OMe)
;
_journal_coden_ASTM              ORGND7
_journal_issue                   25
_journal_name_full               Organometallics
_journal_page_first              5994
_journal_page_last               6001
_journal_paper_doi               10.1021/om049308f
_journal_volume                  23
_journal_year                    2004
_chemical_formula_moiety         'C18 H32 B4 Ir Mo N O3'
_chemical_formula_sum            'C18 H32 B4 Ir Mo N O3'
_chemical_formula_weight         641.83
_space_group_IT_number           61
_space_group_name_Hall           '-P 2ac 2ab'
_space_group_name_H-M_alt        'P b c a'
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      61
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   13.7651(3)
_cell_length_b                   13.8575(3)
_cell_length_c                   24.5446(5)
_cell_measurement_temperature    100(2)
_cell_volume                     4681.88(17)
_diffrn_ambient_temperature      100(2)
_exptl_crystal_density_diffrn    1.821
_cod_database_code               4060987