Oxidative Addition, Reduction and Reductive Coupling: The Versatile Reactivity of Subvalent Gallium Cations.
Schorpp, Marcel; Tamim, Razan; Krossing, Ingo; Dalton Transactions  (2021) –; doi:10.1039/D1DT02682H

data_7708281
_publ_section_title
;
 Oxidative Addition, Reduction and Reductive Coupling: The Versatile
 Reactivity of Subvalent Gallium Cations.
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D1DT02682H
_journal_year                    2021
_chemical_formula_moiety         'C16 Al F36 O4, C33 H43 N3 Sb, C7 H8'
_chemical_formula_sum            'C56 H51 Al F36 N3 O4 Sb'
_chemical_formula_weight         1662.72
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
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_audit_creation_method
;
FinalCif V85 by Daniel Kratzert, Freiburg 2021,
https://github.com/dkratzert/FinalCif
;
_audit_update_record
;
2021-09-03 deposited with the CCDC.	2021-09-08 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_length_b                   20.990(9)
_cell_length_c                   22.636(10)
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_cell_measurement_theta_min      2.647
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_diffrn_detector_type            'Bruker PHOTON III'
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_diffrn_measurement_device       'three-circle diffractometer'
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_diffrn_reflns_theta_min         1.707
_diffrn_source                   'microfocus sealed X-ray tube'
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_exptl_absorpt_process_details
;
TWINABS - Bruker AXS scaling for twinned crystals - Version 2012/1: Krause, L.,
Herbst-Irmer, R., Sheldrick G.M. & Stalke D., J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            black
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_refine_diff_density_max         1.087
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'w=1/[\s^2^(Fo^2^)] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0879
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_reflns_number_gt                8810
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7708281
_shelx_shelxl_version_number     2018/3
_olex2_diffrn_ambient_temperature_device 'Oxford Cryostream 800'
_shelx_res_checksum              42129