Copper-Catalyzed Electrochemical Selective B-H Oxygenation of <i>o</i>-Carboranes at Room Temperature.
Au, Yik Ki; Lyu, Hairong; Quan, Yangjian; Xie, Zuowei; Journal of the American Chemical Society  (2020) –; doi:10.1021/jacs.0c02490

data_4134632
_publ_section_title
;
 Copper-Catalyzed Electrochemical Selective B-H Oxygenation of
 <i>o</i>-Carboranes at Room Temperature.
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_paper_doi               10.1021/jacs.0c02490
_journal_year                    2020
_chemical_formula_sum            'C35 H48 B10 N2 O3'
_chemical_formula_weight         652.85
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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_cell_angle_alpha                88.6570(10)
_cell_angle_beta                 71.5080(10)
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_cell_length_b                   16.1808(6)
_cell_length_c                   18.8504(6)
_cell_measurement_reflns_used    2179
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      15
_cell_measurement_theta_min      15
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_computing_cell_refinement       'BRUKER D8VENTURE DIFFRACTOMETER'
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_computing_molecular_graphics    'BRUKER SHELXTL'
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_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'BRUKER D8VENTURE DIFFRACTOMETER'
_diffrn_measurement_method       'PHI & OMEGA SCAN'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.997
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1354P)^2^+1.7891P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_hkl_checksum              78104