First Ln-MOF as a trifunctional luminescent probe for the efficient sensing of aspartic acid, Fe<sup>3+</sup> and DMSO.
Yang, Dongdong; Lu, Liping; Feng, Sisi; Zhu, Miaoli; Dalton transactions (Cambridge, England : 2003) 49 (2020) 7514–7524; doi:10.1039/d0dt00938e

data_7704391
_publ_section_title
;
 First Ln-MOF as a trifunctional luminescent probe for the efficient
 sensing of aspartic acid, Fe<sup>3+</sup> and DMSO.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7514
_journal_page_last               7524
_journal_paper_doi               10.1039/d0dt00938e
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C23 H17 O15 Sm'
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-09-29 deposited with the CCDC.	2020-05-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_length_c                   13.1223(9)
_cell_measurement_reflns_used    9599
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_cell_volume                     2251.1(3)
_computing_cell_refinement       'Bruker SAINT'
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      296(2)
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0609
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_diffrn_reflns_limit_h_max       14
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_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       16
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_diffrn_reflns_point_group_measured_fraction_full 0.999
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_diffrn_reflns_theta_max         28.256
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_exptl_absorpt_coefficient_mu    2.694
_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.017
_exptl_crystal_description       block
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_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.25
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         5572
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_refine_ls_R_factor_all          0.0776
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_refine_ls_shift/su_max          0.026
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0116P)^2^+12.6596P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0673
_refine_ls_wR_factor_ref         0.0770
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4001
_reflns_number_total             5572
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0dt00938e2.cif
_cod_data_source_block           L79+Sm-1
_cod_depositor_comments
'Adding full bibliography for 7704388--7704392.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7704391
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