Syntheses, crystal structure, and photoelectric properties of two selenoantimonates A-Zn-Sb-Se (A = Rb and Cs).
Zhang, Lirong; Teri, Gele; Qi, Liming; Bai, Sagala; Liu, Xin; Baiyin, Menghe; Dalton transactions (Cambridge, England : 2003) 53 (2024) 14735–14741; doi:10.1039/d4dt01944j

data_7716851
_publ_section_title
;
 Syntheses, crystal structure, and photoelectric properties of two
 selenoantimonates A-Zn-Sb-Se (A = Rb and Cs).
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14735
_journal_page_last               14741
_journal_paper_doi               10.1039/d4dt01944j
_journal_volume                  53
_journal_year                    2024
_chemical_formula_moiety         '0.5(Rb16 Sb8 Se28 Zn8)'
_chemical_formula_sum            'Rb8 Sb4 Se14 Zn4'
_chemical_formula_weight         2537.79
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_Int_Tables_number      14
_atom_sites_solution_primary     iterative
_audit_creation_date             2023-12-27
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2024-01-08 deposited with the CCDC.	2024-08-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 107.306(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
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_cell_length_b                   9.2235(5)
_cell_length_c                   17.0951(12)
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_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_diffrn_ambient_temperature      280.0
_diffrn_measured_fraction_theta_full 0.9997
_diffrn_measured_fraction_theta_max 0.9997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0810P)^2^+38.5136P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_limit_h_min              -14
_reflns_limit_k_max              10
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_reflns_limit_l_max              20
_reflns_limit_l_min              0
_reflns_number_gt                2747
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_reflns_threshold_expression     I>=2u(I)
_cod_data_source_file            d4dt01944j2.cif
_cod_data_source_block           mo_80Z_300K_0m
_cod_depositor_comments
'Adding full bibliography for 7716851--7716852.cif.'
_cod_database_code               7716851
_olex2_refinement_description
;
;
_olex2_submission_special_instructions 'No special instructions were received'