Novel Aggregation of Bis(thiolato)-type Cobalt(III) Octahedra Assisted by Silver(I) Ions: Structural Interconversion by Counter Anions
Konno, Takumi; Aridomi, Takashi; Hattori, Masashi; Hirotsu, Masakazu; Chemistry Letters 35 (2006) 316–; doi:10.1246/cl.2006.316

data_8000105
_publ_section_title
;
 Novel Aggregation of Bis(thiolato)-type Cobalt(III) Octahedra Assisted by
 Silver(I) Ions: Structural Interconversion by Counter Anions
;
_journal_issue                   3
_journal_name_full               'Chemistry Letters'
_journal_page_first              316
_journal_paper_doi               10.1246/cl.2006.316
_journal_volume                  35
_journal_year                    2006
_chemical_formula_moiety         'C12 H42 Ag3 Co2 N13 O16 S4 '
_chemical_formula_sum            'C12 H42 Ag3 Co2 N13 O16 S4'
_chemical_formula_weight         1194.25
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_audit_creation_date             2005-11-25
_audit_creation_method           'by CrystalStructure 3.6.0'
_cell_angle_alpha                90
_cell_angle_beta                 123.08(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   23.532(4)
_cell_length_b                   11.907(3)
_cell_length_c                   14.797(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.1
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.6
_cell_volume                     3474.0(13)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.6.0'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 0.9986
_diffrn_measured_fraction_theta_max 0.9986
_diffrn_measurement_device_type  'Rigaku AFC7S'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.033
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            4299
_diffrn_reflns_theta_full        27.53
_diffrn_reflns_theta_max         27.53
_diffrn_standards_decay_%        2.03
_diffrn_standards_interval_count 0
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.916
_exptl_absorpt_correction_T_max  0.558
_exptl_absorpt_correction_T_min  0.499
_exptl_absorpt_correction_type   psi-scans
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            dark-brownplate
_exptl_crystal_density_diffrn    2.283
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2368.00
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.69
_refine_diff_density_min         -1.42
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     241
_refine_ls_number_reflns         4006
_refine_ls_R_factor_gt           0.0410
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0017Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1320
_reflns_number_gt                2909
_reflns_number_total             4006
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            35-316sup1.cif
_cod_data_source_block           '[3](NO3)5'
_cod_original_cell_volume        3473(1)
_cod_original_sg_symbol_Hall     -c_2yc
_cod_original_sg_symbol_H-M      c_1_2/c_1
_cod_original_formula_sum        'C12 H42 Ag3 Co2 N13 O16 S4 '
_cod_database_code               8000105