DNA Cleavage by the Photocontrolled Cooperation of ZnII Centers in an Azobenzene-Linked Dizinc Complex
Anangamohan Panja; Takashi Matsuo; Satoshi Nagao; Shun Hirota; Inorganic Chemistry 50 (2011) 11437–11445; doi:10.1021/ic201244y

data_4326846
_publ_section_title
;
 DNA Cleavage by the Photocontrolled Cooperation of ZnII Centers in an
 Azobenzene-Linked Dizinc Complex
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              11437
_journal_page_last               11445
_journal_paper_doi               10.1021/ic201244y
_journal_volume                  50
_journal_year                    2011
_chemical_formula_moiety         'C40 H40 N12 O12 Zn2'
_chemical_formula_sum            'C40 H40 N12 O12 Zn2'
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_atom_sites_solution_secondary   difmap
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_cell_angle_beta                 96.537(3)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            2
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_cell_length_b                   14.3362(8)
_cell_length_c                   18.7059(10)
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_cell_measurement_theta_max      25.38
_cell_measurement_theta_min      3.04
_cell_volume                     2234.6(2)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_data_reduction        'RAPID AUTO'
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_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'Il Milione (Burla, et al., 2007)'
_diffrn_ambient_temperature      123
_diffrn_detector_area_resol_mean 10.000
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_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
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_exptl_absorpt_correction_T_max  0.989
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_description       needle
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_refine_ls_shift/su_max          0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0773P)^2^+6.4302P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2291
_reflns_number_gt                2110
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_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic201244y_si_002.cif
_cod_data_source_block           2n-a2obpea-No3_4
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