Tetrapalladium-Containing Polyoxotungstate [Pd(II)4(α-P2W15O56)2](16-): A Comparative Study.
Izarova, Natalya V.; Maksimovskaya, Raisa I.; Willbold, Sabine; Kögerler, Paul; Inorganic chemistry 53 (2014) 11778–11784; doi:10.1021/ic502080x

data_4341316
_publ_section_title
;
 Tetrapalladium-Containing Polyoxotungstate [Pd(II)4(\a-P2W15O56)2](16-):
 A Comparative Study.
;
_journal_issue                   21
_journal_name_full               'Inorganic chemistry'
_journal_page_first              11778
_journal_page_last               11784
_journal_paper_doi               10.1021/ic502080x
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'H142 Na16 O183 P4 Pd4 W30'
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 ? 
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
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_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    3.729
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0665P)^2^+401.3832P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1874
_reflns_number_gt                13246
_reflns_number_total             14717
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic502080x_si_002.cif
_cod_data_source_block           Pd4(P2W15)2
_cod_depositor_comments          'Adding full bibliography for 4341316.cif.'
_cod_original_cell_volume        4231.88(16)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4341316