Chelation-assisted Pd-catalysed ortho-selective oxidative C-H/C-H cross-coupling of aromatic carboxylic acids with arenes and intramolecular Friedel-Crafts acylation: one-pot formation of fluorenones.
Sun, Denan; Li, Bijin; Lan, Jingbo; Huang, Quan; You, Jingsong; Chemical communications (Cambridge, England) 52 (2016) 3635–3638; doi:10.1039/c6cc00103c

data_7118663
_publ_section_title
;
 Chelation-assisted Pd-catalysed ortho-selective oxidative C-H/C-H
 cross-coupling of aromatic carboxylic acids with arenes and
 intramolecular Friedel-Crafts acylation: one-pot formation of
 fluorenones.
;
_journal_issue                   18
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              3635
_journal_page_last               3638
_journal_paper_doi               10.1039/c6cc00103c
_journal_volume                  52
_journal_year                    2016
_chemical_formula_moiety         'C14 H8 F2 O2'
_chemical_formula_sum            'C14 H8 F2 O2'
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_symmetry_space_group_name_Hall  '-P 2yn'
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2015-12-23 deposited with the CCDC.
2016-01-28 downloaded from the CCDC.
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omega____ theta____ kappa____ phi______ frames
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  2 omega   -2.00   82.00   1.0000   11.3550
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Empirical absorption correction using spherical harmonics,
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'Adding full bibliography for 7118662--7118663.cif.'
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;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C00B(H00B), C00C(H00C), C00D(H00D), C00E(H00E), C00F(H00F)
2.b Idealised Me refined as rotating group:
 C00I(H00A,H00G,H00H)
;
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