Synthesis of Ketonylplatinum(III) Dinuclear Complexes: Observation of the Competitive Radical vs Electrophilic Displacement in Pt(III)-Promoted C-H Bond Activation of Ketones
Yong-Shou Lin; Hanae Misawa; Jun Yamada; Kazuko Matsumoto; Journal of the American Chemical Society 123 (2001) 569–575; doi:10.1021/ja9943041

data_4115432
_publ_section_title
;
 Synthesis of Ketonylplatinum(III) Dinuclear Complexes: Observation of the
 Competitive Radical vs Electrophilic Displacement in Pt(III)-Promoted C-H
 Bond Activation of Ketones
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              569
_journal_page_last               575
_journal_paper_doi               10.1021/ja9943041
_journal_volume                  123
_journal_year                    2001
_chemical_formula_sum            'C15 H39 N9 O13 Pt2'
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_cell_length_b                   17.225(3)
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_cell_measurement_temperature    298.2
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_exptl_crystal_description       prismatic
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_refine_diff_density_min         -0.96
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00010|Fo|^2^]'
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_cod_data_source_block           C15H39N9O13Pt2
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_cod_original_formula_sum        'C15 H39 N9 O13 Pt2 '
_cod_database_code               4115432