Radical Coupling of Iodocarbonyl Compounds with Butenylindium Generated by Transmetalation between Cyclopropylmethylstannane and Indium Halides
Yasuda, Makoto; Kiyokawa, Kensuke; Osaki, Kenji; Baba, Akio; Organometallics 28 (2009) 132–; doi:10.1021/om8009156

data_4068524
_publ_section_title
;
 Radical Coupling of Iodocarbonyl Compounds with Butenylindium Generated
 by Transmetalation between Cyclopropylmethylstannane and Indium Halides
;
_journal_issue                   1
_journal_name_full               Organometallics
_journal_page_first              132
_journal_paper_doi               10.1021/om8009156
_journal_volume                  28
_journal_year                    2009
_chemical_formula_moiety         'C42 H52 Cl2 In2 P2 '
_chemical_formula_sum            'C42 H52 Cl2 In2 P2'
_chemical_formula_weight         919.37
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 104.0760(14)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            2
_cell_length_a                   9.3691(5)
_cell_length_b                   23.7556(13)
_cell_length_c                   10.1652(5)
_cell_measurement_reflns_used    13964
_cell_measurement_temperature    273.1
_cell_measurement_theta_max      30.5
_cell_measurement_theta_min      3.2
_cell_volume                     2194.5(2)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR92
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.056
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            27640
_diffrn_reflns_theta_full        30.48
_diffrn_reflns_theta_max         30.48
_exptl_absorpt_coefficient_mu    1.270
_exptl_absorpt_correction_T_max  0.530
_exptl_absorpt_correction_T_min  0.328
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
    Higashi, T. (1995). Program for Absorption Correction.
    Rigaku Corporation, Tokyo, Japan.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.391
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             932.00
_exptl_crystal_size_max          0.70
_exptl_crystal_size_mid          0.60
_exptl_crystal_size_min          0.50
_refine_diff_density_max         0.77
_refine_diff_density_min         -0.45
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     249
_refine_ls_number_reflns         2851
_refine_ls_R_factor_gt           0.0449
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[0.0015Fo^2^ + 1.0000\s(Fo^2^)]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0576
_reflns_number_gt                2822
_reflns_number_total             6665
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om8009156_si_002.cif
_cod_data_source_block           '_664-4-0oC'
_cod_original_formula_sum        'C42 H52 Cl2 In2 P2 '
_cod_database_code               4068524