Exceptionally effective benzene/cyclohexane separation using a nitro-decorated metal-organic framework.
Sapianik, Aleksandr A.; Kovalenko, Konstantin A.; Samsonenko, Denis G.; Barsukova, Marina O.; Dybtsev, Danil N.; Fedin, Vladimir P.; Chemical communications (Cambridge, England) 56 (2020) 8241–8244; doi:10.1039/d0cc03227a

data_7126693
_publ_section_title
;
 Exceptionally effective benzene/cyclohexane separation using a
 nitro-decorated metal-organic framework.
;
_journal_issue                   59
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              8241
_journal_page_last               8244
_journal_paper_doi               10.1039/d0cc03227a
_journal_volume                  56
_journal_year                    2020
_chemical_formula_sum            'C40 H23 Li2 N5 O18 Zn2'
_chemical_formula_weight         1006.25
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
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_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-03-26 deposited with the CCDC.	2020-06-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_measurement_temperature    100(2)
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_diffrn_measurement_device_type  'Rayonix SX-165 CCD'
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_exptl_crystal_colour            yellow
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1964P)^2^+9.4800P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2617
_refine_ls_wR_factor_ref         0.2702
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_reflns_number_gt                4915
_reflns_number_total             5888
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0cc03227a2.cif
_cod_data_source_block           ntf-01
_cod_depositor_comments          'Adding full bibliography for 7126693.cif.'
_cod_original_cell_volume        5178.8(17)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7126693
_shelx_shelxl_version_number     2018/3
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_shelx_estimated_absorpt_t_max   0.936
_shelx_res_checksum              20769
_shelx_hkl_checksum              21743