Cyaphide group transfer from covalent metal complexes: contrasting pathways to transmetallation.
Yang, Eric S.; Goicoechea, Jose M.; Chemical communications (Cambridge, England) 61 (2025) 725–727; doi:10.1039/d4cc06131d

data_7134035
_publ_section_title
;
 Cyaphide group transfer from covalent metal complexes: contrasting
 pathways to transmetallation.
;
_journal_issue                   4
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              725
_journal_page_last               727
_journal_paper_doi               10.1039/d4cc06131d
_journal_volume                  61
_journal_year                    2025
_chemical_formula_moiety         'C57 H77 Au Ga N4 P, C7 H8'
_chemical_formula_sum            'C64 H85 Au Ga N4 P'
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_chemical_name_systematic
;
 (IDipp)AuGa(CP)(NacNac)*tol
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
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_audit_update_record
;
2024-11-14 deposited with the CCDC.	2024-12-06 downloaded from the CCDC.
;
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_diffrn_measurement_device       'four-circle diffractometer'
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_diffrn_source                   'micro-focus sealed X-ray tube'
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.57a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.323
_exptl_crystal_description       block
_exptl_crystal_F_000             2488
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_exptl_crystal_size_mid          0.200
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0248P)^2^+2.5763P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0505
_refine_ls_wR_factor_ref         0.0523
_reflns_Friedel_coverage         0.000
_reflns_number_gt                11600
_reflns_number_total             12642
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d4cc06131d2.cif
_cod_data_source_block           ESY392
_cod_depositor_comments
'Adding full bibliography for 7134035--7134036.cif.'
_cod_original_cell_volume        6064.19(9)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7134035
_shelx_shelxl_version_number     2018/1
_shelx_estimated_absorpt_t_min   0.374
_shelx_estimated_absorpt_t_max   0.664
_shelx_res_checksum              9814
_shelx_hkl_checksum              17958