Efficient catalytic insertion of acetylenes into a carbon-carbon single bond of nonstrained cyclic compounds under mild conditions.
Kuninobu, Yoichiro; Kawata, Atsushi; Takai, Kazuhiko; Journal of the American Chemical Society 128 (2006) 11368–11369; doi:10.1021/ja064022i

data_4101584
_publ_section_title
;
 Efficient catalytic insertion of acetylenes into a carbon-carbon
 single bond of nonstrained cyclic compounds under mild conditions.
;
_journal_issue                   35
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              11368
_journal_page_last               11369
_journal_paper_doi               10.1021/ja064022i
_journal_volume                  128
_journal_year                    2006
_chemical_formula_moiety         'C19 H24 O2 S2 '
_chemical_formula_sum            'C19 H24 O2 S2'
_chemical_formula_weight         348.52
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 103.659(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
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_cell_length_c                   10.1712(6)
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_cell_measurement_temperature    296.2
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_diffrn_measurement_device_type  'Rigaku RAXIS-IV Imaging Plate'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.09000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
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