Pd(II)-Catalyzed Bidentate Directing Group-Aided Chemoselective Acetoxylation of Remote ε-C(sp<sup>2</sup>)-H Bonds in Heteroaryl-Aryl-Based Biaryl Systems.
Naveen, ?; Rajkumar, Vadla; Babu, Srinivasarao Arulananda; Gopalakrishnan, Bojan; The Journal of organic chemistry 81 (2016) 12197–12211; doi:10.1021/acs.joc.6b01933

data_4037296
_publ_section_title
;
 Pd(II)-Catalyzed Bidentate Directing Group-Aided Chemoselective
 Acetoxylation of Remote \e-C(sp<sup>2</sup>)-H Bonds in
 Heteroaryl-Aryl-Based Biaryl Systems.
;
_journal_issue                   24
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              12197
_journal_page_last               12211
_journal_paper_doi               10.1021/acs.joc.6b01933
_journal_volume                  81
_journal_year                    2016
_chemical_formula_moiety         'C18 H14 N2 O2 S'
_chemical_formula_sum            'C18 H14 N2 O2 S'
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
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_atom_sites_solution_primary     direct
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  Olex2 1.1
  (compiled 2011.11.01 svn.r2039, GUI svn.r3906)
;
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;
        CrystalClear-SM Expert 2.0 r15 (Rigaku, 2011)
;
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;
        CrystalClear-SM Expert 2.0 r15 (Rigaku, 2011)
;
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;
        CrystalClear-SM Expert 2.0 r15 (Rigaku, 2011)
;
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;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
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;
        XtaLABmini: Fixed Chi 2 circle
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;
        Rigaku Mercury375R (2x2 bin mode)
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1470P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1556
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_shelx_estimated_absorpt_t_max   0.956
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