Mixed-valence di-ruthenium(II,III) complexes of redox non-innocent <i>N</i>-aryl-<i>o</i>-phenylenediamine derivatives.
Dutta, Debarpan; Maity, Suvendu; Kundu, Suman; Ghosh, Prasanta; Dalton transactions (Cambridge, England : 2003) 50 (2021) 7791–7803; doi:10.1039/d1dt00779c

data_7707323
_publ_section_title
;
 Mixed-valence di-ruthenium(II,III) complexes of redox non-innocent
 <i>N</i>-aryl-<i>o</i>-phenylenediamine derivatives.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7791
_journal_page_last               7803
_journal_paper_doi               10.1039/d1dt00779c
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C60 H46 Cl4 N8 O8 P2 Ru2'
_chemical_formula_sum            'C60 H46 Cl4 N8 O8 P2 Ru2'
_chemical_formula_weight         1412.93
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2021-04-09 deposited with the CCDC.	2021-05-05 downloaded from the CCDC.
;
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_cell_measurement_theta_min      2.82
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_measured_fraction_theta_full 0.986
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.986
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_diffrn_reflns_point_group_measured_fraction_full 0.986
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_diffrn_reflns_theta_max         25.500
_diffrn_reflns_theta_min         2.885
_diffrn_source                   Mo
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            black
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_exptl_crystal_size_min          0.19
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         5475
_refine_ls_number_restraints     0
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_refine_ls_R_factor_all          0.0387
_refine_ls_R_factor_gt           0.0331
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0040P)^2^+2.3255P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0735
_refine_ls_wR_factor_ref         0.0808
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_reflns_number_gt                4992
_reflns_number_total             5475
_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7707320--7707323.cif.'
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