Redox flexibility in a germanium hydride manifold: hydrogen shuttling <i>via</i> oxidative addition and reductive elimination.
Caise, Alexa; Hicks, Jamie; Heilmann, Andreas; Aldridge, Simon; Chemical communications (Cambridge, England) 59 (2023) 7251–7254; doi:10.1039/d3cc01411h

data_7131657
_publ_section_title
;
 Redox flexibility in a germanium hydride manifold: hydrogen shuttling
 <i>via</i> oxidative addition and reductive elimination.
;
_journal_issue                   47
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              7251
_journal_page_last               7254
_journal_paper_doi               10.1039/d3cc01411h
_journal_volume                  59
_journal_year                    2023
_chemical_formula_moiety         'C21 H36 Ge N2 O2'
_chemical_formula_sum            'C21 H36 Ge N2 O2'
_chemical_formula_weight         421.11
_space_group_crystal_system      monoclinic
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Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
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_audit_update_record
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2023-02-16 deposited with the CCDC.	2023-05-16 downloaded from the CCDC.
;
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;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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'w=1/[\s^2^(Fo^2^)+(0.0364P)^2^+0.7541P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 7131655--7131658.cif.'
_cod_database_code               7131657
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_shelx_estimated_absorpt_t_max   0.760
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C9(H9), C12(H12), C15(H15), C18(H18)
2.b Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C8(H8A,H8B)
2.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C21(H21)
2.d Idealised Me refined as rotating group:
 C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), C13(H13A,H13B,H13C), C14(H14A,H14B,
 H14C), C16(H16A,H16B,H16C), C17(H17A,H17B,H17C), C19(H19A,H19B,H19C), C20(H20A,
 H20B,H20C)
;
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_olex2_submission_special_instructions 'No special instructions were received'