Hexaphenyl carbodiphosphorane adducts of heavier group 15 element trichlorides: syntheses, properties and reactivities.
Münzer, Jörn E; Kneusels, Nis-Julian H; Weinert, Bastian; Neumüller, Bernhard; Kuzu, Istemi; Dalton transactions (Cambridge, England : 2003) 48 (2019) 11076–11085; doi:10.1039/c9dt01784d

data_7700307
_publ_section_title
;
 Hexaphenyl carbodiphosphorane adducts of heavier group 15 element
 trichlorides: syntheses, properties and reactivities.
;
_journal_issue                   29
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11076
_journal_page_last               11085
_journal_paper_doi               10.1039/c9dt01784d
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C39 H30 Bi Cl F6 O6 P2 S2'
_chemical_formula_sum            'C39 H30 Bi Cl F6 O6 P2 S2'
_chemical_formula_weight         1079.12
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
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Olex2 1.2
(compiled 2017.01.04 svn.r3372 for OlexSys, GUI svn.r5292)
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2019-06-04 deposited with the CCDC.    2019-06-17 downloaded from the CCDC.
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0833P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments
'Adding full bibliography for 7700302--7700307.cif.'
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_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C19(H19), C3(H3), C18(H18), C4(H4), C33(H33), C13(H13), C15(H15), C25(H25),
 C17(H17), C37(H37), C7(H7), C28(H28), C6(H6), C31(H31), C29(H29), C16(H16),
 C21(H21), C34(H34), C27(H27), C36(H36), C35(H35), C5(H5), C30(H30), C24(H24),
 C9(H9), C12(H12), C11(H11), C22(H22), C10(H10), C23(H23)
;
_olex2_submission_special_instructions 'No special instructions were received'