N-Bromoacetamide-mediated domino cyclization and elimination of homoallylic trichloroacetimidates: a novel approach toward the synthesis of 1-bromo-2-amino-3-butene derivatives.
Zhu, Rui; Yu, Kai; Gu, Zhenhua; Organic & biomolecular chemistry 12 (2014) 6653–6660; doi:10.1039/c4ob01126k

data_7153946
_publ_section_title
;
 N-Bromoacetamide-mediated domino cyclization and elimination of
 homoallylic trichloroacetimidates: a novel approach toward the synthesis
 of 1-bromo-2-amino-3-butene derivatives.
;
_journal_issue                   34
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              6653
_journal_page_last               6660
_journal_paper_doi               10.1039/c4ob01126k
_journal_volume                  12
_journal_year                    2014
_chemical_formula_sum            'C13 H13 Br Cl3 N O2'
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_computing_cell_refinement       'CrysAlisPro (Agilent Technologies)'
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_computing_molecular_graphics    'Ortep-3 (L. J. Farrugia, 2001)'
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_diffrn_measurement_device_type  'Gemini S Ultra, Agilent Technologies'
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.21 (release 14-08-2012 CrysAlis171 .NET)
(compiled Sep 14 2012,17:21:16)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    1.596
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0901P)^2^+0.5444P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                1714
_reflns_number_total             2164
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4ob01126k2.cif
_cod_data_source_block           shelxl
_cod_depositor_comments          'Adding full bibliography for 7153946.cif.'
_cod_database_code               7153946