Synthesis and properties of antimony(III) and bismuth(III) halide complexes of diphosphines and diarsines. Crystal structures of [Bi2I6{o-C6H4(AsMe2)2}2], [Sb2Br6{o-C6H4(PPh2)2}2], [Sb2Cl6{o-C6H4(AsMe2)2}], and [BiCl3{o-C6H4(P(O)Ph2)2}(thf)]
Genge, Anthony R. J.; Hill, Nicholas J.; Levason, William; Reid, Gillian; Journal of the Chemical Society, Dalton Transactions  (2001) 1007–; doi:10.1039/b010179f

data_7010535
_publ_section_title
;
 Synthesis and properties of antimony(III) and bismuth(III) halide
 complexes of diphosphines and diarsines. Crystal structures of
 [Bi2I6{o-C6H4(AsMe2)2}2], [Sb2Br6{o-C6H4(PPh2)2}2],
 [Sb2Cl6{o-C6H4(AsMe2)2}], and [BiCl3{o-C6H4(P(O)Ph2)2}(thf)]
;
_journal_issue                   7
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1007
_journal_paper_doi               10.1039/b010179f
_journal_year                    2001
_chemical_formula_moiety         'C34 H28 Bi Cl3 O3 P2 '
_chemical_formula_structural     '[BiCl3(thf){o-C6H4(PPh2)2}]'
_chemical_formula_sum            'C34 H28 Bi Cl3 O3 P2'
_chemical_formula_weight         861.88
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             19101-01-03
_audit_creation_method           'by teXsan v1.8'
_cell_angle_alpha                90
_cell_angle_beta                 101.80(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.043(2)
_cell_length_b                   19.467(2)
_cell_length_c                   14.530(2)
_cell_measurement_reflns_used    20
_cell_measurement_temperature    150.2
_cell_measurement_theta_max      8.0
_cell_measurement_theta_min      7.0
_cell_volume                     3334.4(8)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan (MSC, 1992-1997)'
_computing_publication_material  'teXsan (MSC, 1992-1997)'
_computing_structure_refinement  'teXsan (MSC, 1992-1997)'
_computing_structure_solution
;
DIRDIF92 PATTY (Beurskens, 1992)
;
_diffrn_ambient_temperature      150.2
_diffrn_measurement_device_type  'Rigaku AFC7S'
_diffrn_measurement_method       \w-2\q
_diffrn_orient_matrix_UB_11      0.06510
_diffrn_orient_matrix_UB_12      -0.03183
_diffrn_orient_matrix_UB_13      -0.00027
_diffrn_orient_matrix_UB_21      -0.01578
_diffrn_orient_matrix_UB_22      -0.02365
_diffrn_orient_matrix_UB_23      0.05706
_diffrn_orient_matrix_UB_31      -0.05204
_diffrn_orient_matrix_UB_32      -0.03265
_diffrn_orient_matrix_UB_33      -0.04107
_diffrn_radiation_detector       'scintillation counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.04400
_diffrn_reflns_av_sigmaI/netI    0.110
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            6374
_diffrn_reflns_reduction_process 'Lp corrections applied'
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.01
_diffrn_standards_decay_%        -0.09
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.647
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.865
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details
;
(North,Phillips & Matthews, 1968)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.717
_exptl_crystal_density_meas      ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1680.00
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.17
_refine_diff_density_max         1.02
_refine_diff_density_min         -0.82
_refine_ls_abs_structure_details -
_refine_ls_abs_structure_Flack   -
_refine_ls_extinction_coef       -
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.267
_refine_ls_goodness_of_fit_ref   1.267
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     388
_refine_ls_number_reflns         3648
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0332
_refine_ls_R_factor_gt           0.0332
_refine_ls_shift/su_max          0.0200
_refine_ls_shift/su_mean         0.0100
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00001|Fo|^2^]'
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         0.0334
_refine_ls_wR_factor_ref         0.0334
_reflns_number_gt                3648
_reflns_number_total             6074
_reflns_threshold_expression     I>2.00\s(I)
_cod_data_source_file            b010179f.txt
_cod_data_source_block           nhbicl3_Bi(oPh(OPPh2)2)Cl3(thf)
_cod_original_cell_volume        3334.7(9)
_cod_original_sg_symbol_H-M      'P 21/n     '
_cod_original_formula_sum        'C34 H28 Bi Cl3 O3 P2 '
_cod_database_code               7010535