Annulative π-extension of BODIPYs made easy via gold(i)-catalyzed cycloisomerization
Labella, Jorge; Durán-Sampedro, Gonzalo; Martínez-Díaz, M. Victoria; Torres, Tomás; Chemical Science 11 (2020) 10778–10785; doi:10.1039/D0SC01054E

data_1558314
_publ_section_title
;
 Annulative \p-extension of BODIPYs made easy via gold(i)-catalyzed
 cycloisomerization
;
_journal_issue                   39
_journal_name_full               'Chemical Science'
_journal_page_first              10778
_journal_page_last               10785
_journal_paper_doi               10.1039/D0SC01054E
_journal_volume                  11
_journal_year                    2020
_chemical_formula_sum            'C48 H37 B F2 N2 O2'
_chemical_formula_weight         722.60
_chemical_name_common            JL363-68_200K
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_update_record
;
2020-02-20 deposited with the CCDC.	2020-06-09 downloaded from the CCDC.
;
_cell_angle_alpha                111.599(3)
_cell_angle_beta                 95.542(3)
_cell_angle_gamma                94.737(3)
_cell_formula_units_Z            2
_cell_length_a                   7.4833(5)
_cell_length_b                   14.4445(10)
_cell_length_c                   19.1563(10)
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_cell_measurement_temperature    200.(2)
_cell_measurement_theta_max      20.7423
_cell_measurement_theta_min      2.8300
_cell_volume                     1900.6(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      200.(2)
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker Kappa Apex II'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0644
_diffrn_reflns_av_unetI/netI     0.0611
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_diffrn_reflns_limit_k_max       17
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_diffrn_reflns_limit_l_min       -23
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_diffrn_reflns_theta_max         25.35
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_exptl_absorpt_coefficient_mu    0.083
_exptl_absorpt_correction_T_max  1.00
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            'intense purple'
_exptl_crystal_density_diffrn    1.263
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             756
_exptl_crystal_size_max          0.229
_exptl_crystal_size_mid          0.097
_exptl_crystal_size_min          0.033
_refine_diff_density_max         0.322
_refine_diff_density_min         -0.351
_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_number_reflns         6928
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.075
_refine_ls_R_factor_all          0.1122
_refine_ls_R_factor_gt           0.0528
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1022P)^2^+0.0087P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1404
_refine_ls_wR_factor_ref         0.1859
_reflns_number_gt                4056
_reflns_number_total             6928
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0sc01054e2.cif
_cod_data_source_block           02878JorgeLabella
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'Adding full bibliography for 1558304--1558314.cif.'
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