Higher-order cyclization reactions of alkenyl Fischer carbene complexes: a new selective all-carbon [8 + 2] cyclization with 8-methoxyheptafulvene and computational mechanistic analysis.
García-Rodríguez, Jaime; González, Jairo; Santamaría, Javier; Suárez-Sobrino, Ángel L; Rodríguez, Miguel A; Dalton transactions (Cambridge, England : 2003) 45 (2016) 11353–11361; doi:10.1039/c6dt01465h

data_7039483
_publ_section_title
;
 Higher-order cyclization reactions of alkenyl Fischer carbene complexes:
 a new selective all-carbon [8 + 2] cyclization with 8-methoxyheptafulvene
 and computational mechanistic analysis.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11353
_journal_page_last               11361
_journal_paper_doi               10.1039/c6dt01465h
_journal_volume                  45
_journal_year                    2016
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2014-09-25 deposited with the CCDC.
2016-06-10 downloaded from the CCDC.
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CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
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_computing_data_collection
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CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
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CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
(compiled May  8 2007,13:10:02)
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_computing_molecular_graphics    'PLATON (Spek, 2006)'
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;
 Oxford Diffraction Xcalibur Nova
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_diffrn_measurement_method       '\f and \w scans'
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CrysAlis RED, Oxford Diffraction Ltd.,
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Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
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_exptl_crystal_colour            colorless
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_exptl_crystal_density_method    'not measured'
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_refine_ls_number_reflns         3068
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0522P)^2^+0.2986P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                2939
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_reflns_threshold_expression     >2sigma(I)
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'Adding full bibliography for 7039483--7039484.cif.'
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