Elucidating the secondary effect in the Lewis acid mediated anodic shift of electrochemical oxidation of a Cu(ii) complex with a N<sub>2</sub>O<sub>2</sub> donor unsymmetrical ligand.
Maity, Souvik; Ghosh, Soumavo; Ghosh, Ashutosh; Dalton transactions (Cambridge, England : 2003) 48 (2019) 14898–14913; doi:10.1039/c9dt03323h

data_7701082
_publ_section_title
;
 Elucidating the secondary effect in the Lewis acid mediated anodic shift
 of electrochemical oxidation of a Cu(ii) complex with a
 N<sub>2</sub>O<sub>2</sub> donor unsymmetrical ligand.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14898
_journal_page_last               14913
_journal_paper_doi               10.1039/c9dt03323h
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C42 H52 Cu2 F6 K N4 O8 P'
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
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_audit_update_record
;
2019-08-14 deposited with the CCDC.    2019-09-09 downloaded from the CCDC.
;
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_measured_fraction_theta_full 0.999
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
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_exptl_crystal_description       BLOCK
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2890
_refine_ls_wR_factor_ref         0.3300
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5621
_reflns_number_total             8281
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt03323h2.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'EMPIRICAL' changed to
'empirical' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7701082--7701083.cif.
;
_cod_database_code               7701082
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              91363