Redox-Associated η1 to η2 Conversion of Disulfide Ligands in Dinuclear Ruthenium Complexes
Kumiko Yoshioka; Hayato Kikuchi; Jun Mizutani; Kazuko Matsumoto; Inorganic Chemistry 40 (2001) 2234–2239; doi:10.1021/ic000392a

data_4319580
_publ_section_title
;
 Redox-Associated \h1 to \h2 Conversion of Disulfide Ligands in Dinuclear
 Ruthenium Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2234
_journal_page_last               2239
_journal_paper_doi               10.1021/ic000392a
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C18 H45 Br4 N3 O12 P4 Ru2 S2 Zn'
_chemical_formula_weight         1270.72
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                102.96(2)
_cell_angle_beta                 102.02(2)
_cell_angle_gamma                109.10(2)
_cell_formula_units_Z            2
_cell_length_a                   15.943(4)
_cell_length_b                   17.703(4)
_cell_length_c                   8.883(1)
_cell_measurement_reflns_used    15
_cell_measurement_temperature    223.2
_cell_measurement_theta_max      12.1
_cell_measurement_theta_min      10.1
_cell_volume                     2198.1(9)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SHELXS86
_diffrn_measurement_device_type  'Rigaku AFC7R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.021
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            6914
_diffrn_standards_decay_%        13.88
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.154
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_correction_T_min  0.489
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.920
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_refine_diff_density_max         0.95
_refine_diff_density_min         -0.85
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.158
_refine_ls_number_parameters     433
_refine_ls_number_reflns         4280
_refine_ls_R_factor_gt           0.0506
_refine_ls_shift/su_max          0.0030
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo) + 0.00133|Fo|^2^]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0750
_reflns_number_gt                3985
_reflns_number_total             0
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic000392a_2.cif
_cod_data_source_block           C18H45Br4N3O12P4S2Ru2Zn
_cod_original_cell_volume        2198(1)
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C18 H45 Br4 N3 O12 P4 S2 Ru2 Zn '
_cod_database_code               4319580