Tandem deoxygenative hydrosilation of carbon dioxide with a cationic scandium hydridoborate and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>.
Beh, Daniel W.; Piers, Warren E.; Gelfand, Benjamin S.; Lin, Jian-Bin; Dalton transactions (Cambridge, England : 2003) 49 (2020) 95–101; doi:10.1039/c9dt04323c

data_7702003
_publ_section_title
;
 Tandem deoxygenative hydrosilation of carbon dioxide with a cationic
 scandium hydridoborate and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              95
_journal_page_last               101
_journal_paper_doi               10.1039/c9dt04323c
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C35 H37 B2 N9 O Sc, C19 H3 B F15'
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;
2019-11-06 deposited with the CCDC.	2019-11-22 downloaded from the CCDC.
;
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 Reference: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10.
;
_exptl_crystal_colour            Colorless
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1100P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7702000--7702003.cif.'
_cod_original_cell_volume        2676(2)
_cod_database_code               7702003
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_shelx_res_checksum              7828