Tethered CAAC-CAAC dimers: oxidation to persistent radical cations and bridging-unit dependent reactivity/stability of the dications.
Nayak, Mithilesh Kumar; Suhr, Simon; Chrysochos, Nicolas; Rawat, Hemant; Schulzke, Carola; Chandrasekhar, Vadapalli; Sarkar, Biprajit; Jana, Anukul; Chemical communications (Cambridge, England) 57 (2021) 1210–1213; doi:10.1039/d0cc07385g

data_7127670
_publ_section_title
;
 Tethered CAAC-CAAC dimers: oxidation to persistent radical cations and
 bridging-unit dependent reactivity/stability of the dications.
;
_journal_issue                   10
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'Chemical communications (Cambridge, England)'
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_journal_paper_doi               10.1039/d0cc07385g
_journal_volume                  57
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2020-05-21 deposited with the CCDC.	2020-12-18 downloaded from the CCDC.
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;
CrysAlisPro 1.171.39.29d (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            green
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 Refined as an inversion twin.
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0276P)^2^+1.9241P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_number_gt                6026
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'Adding full bibliography for 7127659--7127670.cif.'
_cod_database_code               7127670
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_shelx_estimated_absorpt_t_min   0.965
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