In situ production of silver nanoparticles on an aldehyde-equipped conjugated porous polymer and subsequent heterogeneous reduction of aromatic nitro groups at room temperature
Jie Liu; Jieshun Cui; Filipe Vilela; Jun He; Matthias Zeller; Allen D. Hunter; Zhengtao Xu; Chem.Commun. 51 (2015) 12197–; doi:10.1039/C5cc04476F

data_7117549
_publ_section_title
;
 In situ production of silver nanoparticles on an aldehyde-equipped
 conjugated porous polymer and subsequent heterogeneous reduction of
 aromatic nitro groups at room temperature
;
_journal_name_full               Chem.Commun.
_journal_page_first              12197
_journal_paper_doi               10.1039/C5cc04476F
_journal_volume                  51
_journal_year                    2015
_chemical_formula_sum            'C40 H20 O4 S8'
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_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2015-05-15 deposited with the CCDC.
2015-06-24 downloaded from the CCDC.
;
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_computing_structure_refinement
;  
SHELXL-2014/7 (Sheldrick, 2014), 
SHELXLE Rev656 (H\"ubschle et al., 2011)
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
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_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_device_type  'Bruker AXS D8 Quest CMOS diffractometer'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_monochromator  'laterally graded multilayer (Goebel) mirror'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_k_min       -34
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_diffrn_reflns_point_group_measured_fraction_full 0.994
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_diffrn_source                   'I-mu-S microsource X-ray tube'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0361P)^2^+0.5085P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0827
_refine_ls_wR_factor_ref         0.0856
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3360
_reflns_number_total             3740
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5cc04476f2.cif
_cod_data_source_block           Quest15mz002_0m
_cod_original_cell_volume        807.37(8)
_cod_database_code               7117549
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.773
_shelx_estimated_absorpt_t_max   0.905
_shelx_res_checksum              30373
_shelx_hkl_checksum              73675