New heterobimetallic ferrocenyl derivatives are promising antitrypanosomal agents.
Rodríguez Arce, Esteban; Putzu, Eugenia; Lapier, Michel; Maya, Juan Diego; Olea Azar, Claudio; Echeverría, Gustavo A; Piro, Oscar E.; Medeiros, Andrea; Sardi, Florencia; Comini, Marcelo; Risi, Gastón; Salinas, Gustavo; Correia, Isabel; Pessoa, João Costa; Otero, Lucía; Gambino, Dinorah; Dalton transactions (Cambridge, England : 2003) 48 (2019) 7644–7658; doi:10.1039/c9dt01317b

data_7049707
_publ_section_title
;
 New heterobimetallic ferrocenyl derivatives are promising
 antitrypanosomal agents.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7644
_journal_page_last               7658
_journal_paper_doi               10.1039/c9dt01317b
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C41 H35 F6 Fe N4 O3 P3 Pd S'
_chemical_formula_weight         1032.95
_chemical_name_systematic
'1,1'-bis (dipheny1phosphino)ferrocene 5-nitrofuryl-N-methylthiosemicarbazonato palladium(II) hexafluorophosphate'
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
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;
2019-01-15 deposited with the CCDC.    2019-04-15 downloaded from the CCDC.
;
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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(compiled Jul 11 2012,15:38:31)
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_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.0304
_diffrn_reflns_av_unetI/netI     0.0452
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CrysAlisPro, Agilent Technologies,
Version 1.171.36.20 (release 27-06-2012 CrysAlis171 .NET)
(compiled Jul 11 2012,15:38:31)
Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            violet
_exptl_crystal_density_diffrn    1.609
_exptl_crystal_description       plate
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'Re-crystallisation from solvent: Dichloromethane-hexane'
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_refine_ls_extinction_method     none
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_refine_ls_number_reflns         9171
_refine_ls_number_restraints     0
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_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0394P)^2^+6.0347P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0961
_refine_ls_wR_factor_ref         0.1053
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7379
_reflns_number_total             9171
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt01317b2.cif
_cod_data_source_block           PddppfTM
_cod_depositor_comments
'Adding full bibliography for 7049704--7049707.cif.'
_cod_database_code               7049707
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.731
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_shelx_res_checksum              89354