Low-dimensional compounds containing cyanide groups. XXV. Synthesis, spectroscopic properties and crystal structures of two ionic iron(II) complexes with tricyanomethanide: tris(1,10-phenanthroline-κ^2^<i>N</i>,<i>N</i>')iron(II) bis(tricyanomethanide) and tris(2,2'-bipyridine-κ^2^<i>N</i>,<i>N</i>')iron(II) bis(tricyanomethanide) sesquihydrate
Potočňák, Ivan; Váhovská, Lucia; Herich, Peter; Acta Crystallographica Section C 70 (2014) 432–436; doi:10.1107/S2053229614006512

data_2019573
_publ_section_title
;
 Low-dimensional compounds containing cyanide groups. XXV. Synthesis,
 spectroscopic properties and crystal structures of two ionic iron(II)
 complexes with tricyanomethanide:
 tris(1,10-phenanthroline-\k^2^<i>N</i>,<i>N</i>')iron(II)
 bis(tricyanomethanide) and
 tris(2,2'-bipyridine-\k^2^<i>N</i>,<i>N</i>')iron(II)
 bis(tricyanomethanide) sesquihydrate
;
_journal_coeditor_code           EM3067
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              432
_journal_page_last               436
_journal_paper_doi               10.1107/S2053229614006512
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac          '[Fe (C12 H8 N2)3] (C4 N3)2'
_chemical_formula_moiety         'C36 H24 Fe N6 2+, 2(C4 N3 -)'
_chemical_formula_sum            'C44 H24 Fe N12'
_chemical_formula_weight         776.60
_chemical_name_systematic
;
Tris(1,10-phenanthroline-\k^2^<i>N</i>,<i>N</i>')iron(II)
bis(tricyanomethanide)
;
_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-P 2yn'
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_cell_measurement_temperature    193(2)
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_computing_cell_refinement       'WinCell in X-AREA (Stoe & Cie, 2002)'
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_diffrn_measurement_device_type  'Stoe IPDSII'
_diffrn_measurement_method       \w
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_exptl_crystal_colour            'dark red'
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_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.0328P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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