Synthesis and characterisation of homoleptic 2,9-diaryl-1,10-phenanthroline copper(i) complexes: influencing selectivity in photoredox-catalysed atom-transfer radical addition reactions.
Nicholls, Thomas P.; Caporale, Chiara; Massi, Massimiliano; Gardiner, Michael G.; Bissember, Alex C.; Dalton transactions (Cambridge, England : 2003) 48 (2019) 7290–7301; doi:10.1039/c8dt04116d

data_7049136
_publ_section_title
;
 Synthesis and characterisation of homoleptic
 2,9-diaryl-1,10-phenanthroline copper(i) complexes: influencing
 selectivity in photoredox-catalysed atom-transfer radical addition
 reactions.
;
_journal_issue                   21
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7290
_journal_page_last               7301
_journal_paper_doi               10.1039/c8dt04116d
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C184 H244 Cu2 F12 N10 O11 P2'
_chemical_formula_weight         3188.90
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_space_group_name_Hall           '-P 2yc'
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_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2018-11-25 deposited with the CCDC.    2019-02-13 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.751
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_diffrn_reflns_theta_max         32.246
_diffrn_reflns_theta_min         0.966
_diffrn_source                   'MX2 Beamline Australian Synchrotron'
_exptl_absorpt_coefficient_mu    0.334
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            red
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.1243P)^2^+4.8397P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                27444
_reflns_number_total             46557
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8dt04116d2.cif
_cod_data_source_block           as92tn06
_cod_depositor_comments
'Adding full bibliography for 7049133--7049136.cif.'
_cod_database_code               7049136
_shelx_shelxl_version_number     2018/3
_shelx_estimated_absorpt_t_min   0.993
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