Preparation and reactivity of diazoalkane complexes of ruthenium stabilised by an indenyl ligand.
Albertin, Gabriele; Antoniutti, Stefano; Castro, Jesús; Dottorello, Gianluca; Dalton transactions (Cambridge, England : 2003) 44 (2015) 9289–9303; doi:10.1039/c5dt00755k

data_7035033
_publ_section_title
;
 Preparation and reactivity of diazoalkane complexes of ruthenium
 stabilised by an indenyl ligand.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9289
_journal_page_last               9303
_journal_paper_doi               10.1039/c5dt00755k
_journal_volume                  44
_journal_year                    2015
_chemical_formula_moiety         'C46 H46 N2 O3 P2 Ru, C24 H20 B'
_chemical_formula_sum            'C70 H65 B N2 O3 P2 Ru'
_chemical_formula_weight         1156.06
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/6
_audit_update_record
;
2015-02-18 deposited with the CCDC.
2015-04-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 104.0830(9)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.3586(5)
_cell_length_b                   17.5065(5)
_cell_length_c                   22.5506(7)
_cell_measurement_reflns_used    9945
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      68.31
_cell_measurement_theta_min      2.97
_cell_volume                     5881.1(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker CCD Smart 6000'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  'Incoatec Quazar MX multilayer optics'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0611
_diffrn_reflns_av_unetI/netI     0.0357
_diffrn_reflns_laue_measured_fraction_full 0.997
_diffrn_reflns_laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            88517
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         68.371
_diffrn_reflns_theta_min         2.966
_diffrn_source                   'Incoatec I\muS microsource'
_exptl_absorpt_coefficient_mu    3.054
_exptl_absorpt_correction_T_max  0.4672
_exptl_absorpt_correction_T_min  0.2938
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2014/2 (Bruker AXS Inc.)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.306
_exptl_crystal_description       prism
_exptl_crystal_F_000             2408
_exptl_crystal_size_max          0.217
_exptl_crystal_size_mid          0.208
_exptl_crystal_size_min          0.089
_refine_diff_density_max         0.792
_refine_diff_density_min         -1.355
_refine_diff_density_rms         0.079
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.079
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     715
_refine_ls_number_reflns         10708
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.079
_refine_ls_R_factor_all          0.0484
_refine_ls_R_factor_gt           0.0452
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0978P)^2^+0.4207P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1273
_refine_ls_wR_factor_ref         0.1314
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9656
_reflns_number_total             10708
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c5dt00755k1.cif
_cod_data_source_block           3c_IndP2RuNNFluo
_cod_depositor_comments
'Adding full bibliography for 7035033--7035035.cif.'
_cod_database_code               7035033
_shelx_estimated_absorpt_t_min   0.557
_shelx_estimated_absorpt_t_max   0.773
_shelxl_version_number           2014/6
_shelx_res_checksum              7609