3D to 2D reorganization of silver-thiol nanostructures, triggered by solvent vapor annealing.
Dell'Elce, Simone; Liscio, Fabiola; Kovtun, Alessandro; Allegri, Stefano; Roscioni, Otello M.; Albonetti, Cristiano; De Luca, Giovanna; Amenitsch, Heinz W.; Demitri, Nicola; Giorgini, Loris; Morandi, Vittorio; Stellacci, Francesco; Liscio, Andrea; Palermo, Vincenzo; Nanoscale 10 (2018) 23018–23026; doi:10.1039/c8nr07109h

data_1550315
_publ_section_title
;
 3D to 2D reorganization of silver-thiol nanostructures, triggered by
 solvent vapor annealing.
;
_journal_issue                   48
_journal_name_full               Nanoscale
_journal_page_first              23018
_journal_page_last               23026
_journal_paper_doi               10.1039/c8nr07109h
_journal_volume                  10
_journal_year                    2018
_chemical_formula_moiety         'Ag44, 30 (C6 H4 F S), 4 (C24 H20 P)'
_chemical_formula_sum            'C276 H200 Ag44 F30 P4 S30'
_chemical_formula_weight         9918.31
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2018-03-15 deposited with the CCDC.
2018-10-10 downloaded from the CCDC.
;
_cell_angle_alpha                95.04(3)
_cell_angle_beta                 114.57(3)
_cell_angle_gamma                117.69(3)
_cell_formula_units_Z            1
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_cell_length_b                   21.475(4)
_cell_length_c                   22.535(5)
_cell_measurement_reflns_used    2470
_cell_measurement_temperature    400(2)
_cell_measurement_theta_max      24.305
_cell_measurement_theta_min      1.044
_cell_volume                     7633(5)
_computing_cell_refinement       'XDS (Kabsch, 2010)'
_computing_data_collection       'Elettra XRD1 Data Collection SW'
_computing_data_reduction        'XDS (Kabsch, 2010)'
_computing_molecular_graphics    'Ortep3 for Windows - Coot'
_computing_publication_material  'enCIFer - publCIF'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      400(2)
_diffrn_measured_fraction_theta_full 0.968
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type
;
'Huber 4-circles Kappa Goniometer, Pilatus 2M detector'
;
_diffrn_measurement_method       'Rotating crystal'
_diffrn_radiation_type           Synchrotron
_diffrn_radiation_wavelength     0.700
_diffrn_reflns_av_R_equivalents  0.0538
_diffrn_reflns_av_unetI/netI     0.0664
_diffrn_reflns_Laue_measured_fraction_full 0.968
_diffrn_reflns_Laue_measured_fraction_max 0.968
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            64828
_diffrn_reflns_point_group_measured_fraction_full 0.968
_diffrn_reflns_point_group_measured_fraction_max 0.968
_diffrn_reflns_theta_full        24.305
_diffrn_reflns_theta_max         24.305
_diffrn_reflns_theta_min         1.044
_diffrn_source                   'Elettra Synchrotron - XRD1 BL'
_diffrn_standards_decay_%        0
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_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.875
_exptl_absorpt_correction_T_max  0.7453
_exptl_absorpt_correction_T_min  0.6332
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS v2012/1 (Bruker, 2012)'
_exptl_crystal_colour            Black
_exptl_crystal_density_diffrn    2.158
_exptl_crystal_description       'Thick prisms'
_exptl_crystal_F_000             4734
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.030
_refine_diff_density_max         1.269
_refine_diff_density_min         -0.958
_refine_diff_density_rms         0.180
_refine_ls_extinction_coef       0.00020(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2017/1 (Sheldrick 2017)'
_refine_ls_goodness_of_fit_ref   1.060
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1454
_refine_ls_number_reflns         25167
_refine_ls_number_restraints     1098
_refine_ls_restrained_S_all      1.115
_refine_ls_R_factor_all          0.1250
_refine_ls_R_factor_gt           0.0773
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0973P)^2^+78.7448P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2195
_refine_ls_wR_factor_ref         0.2602
_reflns_Friedel_coverage         0.000
_reflns_number_gt                15105
_reflns_number_total             25167
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c8nr07109h2.cif
_cod_data_source_block           AgNP400K
_cod_depositor_comments
'Adding full bibliography for 1550315--1550316.cif.'
_cod_original_cell_volume        7632(4)
_cod_database_code               1550315
_shelx_shelxl_version_number     2017/1
_shelx_estimated_absorpt_t_min   0.762
_shelx_estimated_absorpt_t_max   0.919
_shelx_res_checksum              3162
_shelx_hkl_checksum              33714