Palladium-catalyzed intramolecular rearrangement of vinylidenecyclopropanes through C‒C bond activation
Pan, Dong; Chen, Gen-Qiang; Tang, Xiang-Ying; Shi, Min; Organic Chemistry Frontiers 2 (2015) 792–; doi:10.1039/C5QO00127G

data_1553139
_publ_section_title
;
 Palladium-catalyzed intramolecular rearrangement of
 vinylidenecyclopropanes through C--C bond activation
;
_journal_issue                   7
_journal_name_full               'Organic Chemistry Frontiers'
_journal_page_first              792
_journal_paper_doi               10.1039/C5QO00127G
_journal_volume                  2
_journal_year                    2015
_chemical_formula_sum            'C20 H26 N O2 S'
_chemical_formula_weight         344.48
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2013-09-03 deposited with the CCDC.
2015-04-29 downloaded from the CCDC.
;
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_cell_angle_gamma                96.596(2)
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_cell_length_c                   11.6537(14)
_cell_measurement_reflns_used    4003
_cell_measurement_temperature    140(2)
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_cell_measurement_theta_min      2.44
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_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      140(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_Laue_measured_fraction_full 0.992
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0796P)^2^+0.2291P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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