Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes.
Kennedy, Alan R.; Kerr, William J.; Moir, Rory; Reid, Marc; Organic & biomolecular chemistry 12 (2014) 7927–7931; doi:10.1039/c4ob01570c

data_7154026
_publ_section_title
;
 Anion effects to deliver enhanced iridium catalysts for hydrogen isotope
 exchange processes.
;
_journal_issue                   40
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              7927
_journal_page_last               7931
_journal_paper_doi               10.1039/c4ob01570c
_journal_volume                  12
_journal_year                    2014
_chemical_formula_sum            'C53 H37 B F24 N2'
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_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device_type  'Oxford Diffraction Gemini S'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
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_exptl_absorpt_correction_type   multi-scan
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;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.46 (release 25-11-2010 CrysAlis171 .NET)
(compiled Nov 25 2010,17:55:46)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
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_exptl_crystal_density_method    'not measured'
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_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0803P)^2^+3.8076P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1595
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_reflns_number_gt                8411
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_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            c4ob01570c2.cif
_cod_data_source_block           exp_2706
_cod_depositor_comments
'Adding full bibliography for 7154023--7154026.cif.'
_cod_original_cell_volume        5236.07(19)
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7154026