Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart's Cationic Iridium(III) Pincer Complex.
Metsänen, Toni T; Hrobárik, Peter; Klare, Hendrik F. T.; Kaupp, Martin; Oestreich, Martin; Journal of the American Chemical Society 136 (2014) 6912–6915; doi:10.1021/ja503254f

data_4121776
_publ_contact_author
;
        Martin Oestreich
        Institut f\"ur Chemie
        Technische Universit\"at Berlin 
        Strasse des 17. Juni 135
        10623 Berlin
        Germany
;
_publ_section_title
;
 Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by
 Brookhart's Cationic Iridium(III) Pincer Complex.
;
_journal_issue                   19
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              6912
_journal_page_last               6915
_journal_paper_doi               10.1021/ja503254f
_journal_volume                  136
_journal_year                    2014
_chemical_formula_sum            'C30 H51 Ir O2 P2 Si'
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 ?
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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CrysAlisPro, Agilent Technologies,
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Empirical absorption correction using spherical harmonics,
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_exptl_crystal_colour            yellow
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'calc w=1/[\s^2^(Fo^2^)+(0.0745P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 4121776--4121777.cif.'
_cod_original_cell_volume        1635.61(18)
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