Facile synthesis of 1,5-disubstituted 1,2,3-triazoles by the regiospecific alkylation of a ruthenium triazolato complex.
Chang, Chao-Wan; Lee, Gene-Hsiang; Dalton transactions (Cambridge, England : 2003) 48 (2019) 2028–2037; doi:10.1039/c8dt04189j

data_7048674
_publ_section_title
;
 Facile synthesis of 1,5-disubstituted 1,2,3-triazoles by the
 regiospecific alkylation of a ruthenium triazolato complex.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2028
_journal_page_last               2037
_journal_paper_doi               10.1039/c8dt04189j
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C12 H8 F5 N3 O2'
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_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
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_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2018-10-15 deposited with the CCDC.
2019-01-02 downloaded from the CCDC.
;
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_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
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_diffrn_measurement_device_type  'Bruker D8 VENTURE'
_diffrn_measurement_method       '\f and \w scans'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0366P)^2^+0.2603P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7048674--7048676.cif.'
_cod_database_code               7048674
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