Palladium-catalyzed oxidation of β-C(sp3)-H bond of primary alkylamines through a rare four-membered palladacycle intermediate.
Su, Bo; Bunescu, Ala; Qiu, Yehao; Zuend, Stephan J.; Ernst, Martin; Hartwig, John F.; Journal of the American Chemical Society  (2020) –; doi:10.1021/jacs.0c01629

data_4134720
_publ_section_title
;
 Palladium-catalyzed oxidation of \b-C(sp3)-H bond of primary alkylamines
 through a rare four-membered palladacycle intermediate.
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_paper_doi               10.1021/jacs.0c01629
_journal_year                    2020
_chemical_formula_moiety         'C36 H24 F18 N O P Pd, C H4 O'
_chemical_formula_sum            'C37 H28 F18 N O2 P Pd'
_chemical_formula_weight         997.97
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_space_group_name_Hall           '-P 1'
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_diffrn_measured_fraction_theta_max 0.999
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_diffrn_measurement_method       '\w scans'
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_exptl_absorpt_process_details
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0603P)^2^+1.0057P] where P=(Fo^2^+2Fc^2^)/3'
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