Synthesis of Azepines by a Gold-Catalyzed Intermolecular [4 + 3]-Annulation
Nathan D. Shapiro; F. Dean Toste; Journal of the American Chemical Society 130 (2008) 9244–9245; doi:10.1021/ja803890t

data_4108093
_publ_section_title
;
 Synthesis of Azepines by a Gold-Catalyzed Intermolecular [4 +
 3]-Annulation
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              9244
_journal_page_last               9245
_journal_paper_doi               10.1021/ja803890t
_journal_volume                  130
_journal_year                    2008
_chemical_formula_moiety         'C33 H36 N2 O6 '
_chemical_formula_sum            'C33 H36 N2 O6'
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_symmetry_cell_setting           triclinic
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Wed May 21 16:22:20 2008'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                91.177(2)
_cell_angle_beta                 108.735(2)
_cell_angle_gamma                99.232(2)
_cell_formula_units_Z            2
_cell_length_a                   10.009(1)
_cell_length_b                   11.164(1)
_cell_length_c                   14.152(2)
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_cell_measurement_temperature    152.2
_cell_measurement_theta_max      23.0
_cell_measurement_theta_min      2.0
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_diffrn_measured_fraction_theta_max 0.9946
_diffrn_measurement_device_type  'Bruker APEX'
_diffrn_measurement_method       \w-scans
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_limit_h_max       11
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_diffrn_reflns_theta_full        24.71
_diffrn_reflns_theta_max         24.71
_diffrn_standards_decay_%        0
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_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
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_exptl_crystal_description       blocklike
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_refine_ls_structure_factor_coef F
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_refine_ls_weighting_scheme      calc
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