<i>meso</i>-Tetrakis(ethylenediamine)-1κ^4^<i>N</i>,<i>N</i>';3κ^4^<i>N</i>,<i>N</i>'-di-μ-sulfidoacetato-1:2κ^3^<i>O</i>,<i>S</i>:<i>S</i>;2:3κ^3^<i>S</i>:<i>S</i>,<i>O</i>-dicobalt(III)silver(I) triperchlorate
Nobuto Yoshinari; Asako Igashira-Kamiyama; Takumi Konno; Acta Crystallographica Section E 62 (2006) m1229–m1231; doi:10.1107/S1600536806015868

data_2209221
_publ_section_title
;<i>meso</i>-Tetrakis(ethylenediamine)-1\k^4^<i>N</i>,<i>N</i>';3\k^4^<i>N</i>,<i>N</i>'-di-\m-sulfidoacetato-1:2\k^3^<i>O</i>,<i>S</i>:<i>S</i>;2:3\k^3^<i>S</i>:<i>S</i>,<i>O</i>-dicobalt(III)silver(I)
 triperchlorate
;
_journal_coeditor_code           IS2029
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1229
_journal_page_last               m1231
_journal_paper_doi               10.1107/S1600536806015868
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          '[Ag Co2 (C2 H4 O2 S)2 (C2 H8 N2)4] (Cl O4)3'
_chemical_formula_moiety         'C12 H40 Ag Co2 N8 O4 S2 3+, 3Cl O4 -'
_chemical_formula_sum            'C12 H40 Ag Cl3 Co2 N8 O16 S2'
_chemical_formula_weight         944.69
_chemical_name_systematic
;
<i>meso</i>-Tetrakis(ethylenediamine)-1\k^4^N,N';3\k^4^N,N'-
di-\m-sulfidoacetato-1:2\k^3^O,S:S;2:3\k^3^S:S,O-
dicobalt(III)silver(I) triperchlorate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 106.857(14)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.486(3)
_cell_length_b                   8.974(2)
_cell_length_c                   14.410(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      14.7
_cell_volume                     1545.3(6)
_computing_cell_refinement
;
MSC/AFC Diffractometer Control Software
;
_computing_data_collection
;
MSC/AFC Diffractometer Control Software
(Molecular Structure Corporation, 1992)
;
_computing_data_reduction
;
Crystal structure (Rigaku/MSC, 2004)
;
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR92 (Altomare <i>et al.</i>,  1994)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Rigaku AFC-7S'
_diffrn_measurement_method       \w--2\q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0210
_diffrn_reflns_av_sigmaI/netI    0.0347
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            3700
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         2.56
_diffrn_standards_decay_%        -0.13
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.164
_exptl_absorpt_correction_T_max  0.5831
_exptl_absorpt_correction_T_min  0.4922
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North <i>et al.</i>,  1968)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.030
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             952
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.591
_refine_diff_density_min         -0.418
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     253
_refine_ls_number_reflns         3542
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.026
_refine_ls_R_factor_all          0.0525
_refine_ls_R_factor_gt           0.0325
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0367P)^2^+1.5353P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0778
_refine_ls_wR_factor_ref         0.0850
_reflns_number_gt                2788
_reflns_number_total             3542
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            is2029.cif
_cod_data_source_block           I
_cod_original_cell_volume        1545.2(6)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2209221
_cod_database_fobs_code          2209221