Synthesis, characterization and reactivity of linear-type S-bridged trinuclear complexes containing vanadium(III) ion. Crystal structures of [VIII{M(aet)3}2](ClO4)3 (M = RhIII, IrIII; aet = 2-aminoethanethiolate)†
Miyashita, Yoshitaro; Hamajima, Masato; Yamada, Yasunori; Fujisawa, Kiyoshi; Okamoto, Ken-ichi; Journal of the Chemical Society, Dalton Transactions  (2001) 2089–; doi:10.1039/b101965l

data_7010663
_publ_section_title
;
 Synthesis, characterization and reactivity of linear-type S-bridged
 trinuclear complexes containing vanadium(III) ion. Crystal structures
 of [VIII{M(aet)3}2](ClO4)3 (M&#x2005;=&#x2005;RhIII, IrIII;
 aet&#x2005;=&#x2005;2-aminoethanethiolate)&#x2020;
;
_journal_issue                   14
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2089
_journal_paper_doi               10.1039/b101965l
_journal_year                    2001
_chemical_formula_sum            'C12 H36 Cl3 Ir2 N6 O12 S6 V'
_chemical_formula_weight         1190.55
_space_group_IT_number           148
_symmetry_cell_setting           trigonal
_symmetry_Int_Tables_number      148
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_audit_creation_date             'Thu Jun 15 18:35:25 2000'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            6
_cell_length_a                   14.578(9)
_cell_length_b                   14.578(9)
_cell_length_c                   26.47(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      14.9
_cell_measurement_theta_min      12.0
_cell_volume                     4872(6)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.10'
_computing_publication_material  'teXsan Ver. 1.10'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SHELXS86
_diffrn_measured_fraction_theta_full 1.5470
_diffrn_measured_fraction_theta_max 1.5470
_diffrn_measurement_device_type  'Rigaku AFC7S'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.073
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            8088
_diffrn_reflns_theta_full        27.51
_diffrn_reflns_theta_max         27.51
_diffrn_standards_decay_%        6.13
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    9.173
_exptl_absorpt_correction_T_max  0.480
_exptl_absorpt_correction_T_min  0.328
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North, Phillips & Mathews, 1968)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.435
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       cubic
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.080
_refine_diff_density_max         2.45
_refine_diff_density_min         -2.23
_refine_ls_extinction_coef       0.00011(2)
_refine_ls_extinction_method     'Zachariasen(1967) type 2 Gaussian isotropic'
_refine_ls_goodness_of_fit_ref   1.360
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     129
_refine_ls_number_reflns         1438
_refine_ls_R_factor_gt           0.0417
_refine_ls_shift/su_max          0.1064
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      unit
_refine_ls_wR_factor_ref         0.0474
_reflns_number_gt                1373
_reflns_number_total             3853
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            b101965l.txt
_cod_data_source_block           sak70425-IrVIr
_cod_original_cell_volume        4871(4)
_cod_original_sg_symbol_H-M      'R -3         '
_cod_original_formula_sum        'C12 H36 Cl3 Ir2 N6 O12 S6 V '
_cod_database_code               7010663