Bulky arene-bridged bis(amide) and bis(amidinate) complexes of germanium(II) and tin(II).
Garg, Palak; Dange, Deepak; Jones, Cameron; Dalton transactions (Cambridge, England : 2003) 50 (2021) 9118–9122; doi:10.1039/d1dt01642c

data_7707613
_publ_section_title
;
 Bulky arene-bridged bis(amide) and bis(amidinate) complexes of
 germanium(II) and tin(II).
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9118
_journal_page_last               9122
_journal_paper_doi               10.1039/d1dt01642c
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C72.5 H98.5 Cl2 Ge2 N4 O'
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_audit_update_record
;
2021-06-08 deposited with the CCDC.	2021-06-08 downloaded from the CCDC.
;
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_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
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_refine_ls_R_factor_gt           0.0598
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1220P)^2^+18.3977P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                10959
_reflns_number_total             13955
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d1dt01642c2.cif
_cod_data_source_block           Cj1498
_cod_depositor_comments
'Adding full bibliography for 7707610--7707619.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C72.50 H98.50 Cl2 Ge2 N4 O'
_cod_database_code               7707613
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.772
_shelx_estimated_absorpt_t_max   0.797
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