Expanding the Series of Alkali Metal Plumbolyl Complexes to Na and K
Diaz-Rodriguez, Roberto; Kitos, Alexandros; Murugesu, Muralee; Dalton Transactions  (2022) –; doi:10.1039/D2DT02615E

data_7711281
_publ_section_title
;
 Expanding the Series of Alkali Metal Plumbolyl Complexes to Na and K
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT02615E
_journal_year                    2022
_chemical_formula_moiety         'C36 H56 Na2 O2 Pb Si2'
_chemical_formula_sum            'C36 H56 Na2 O2 Pb Si2'
_chemical_formula_weight         830.15
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Air-sensitive,Moisture-sensitive,Heat-sensitive,Oxygen-sensitive
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_space_group_name_Hall           '-I 2ya'
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_atom_sites_solution_secondary   difmap
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_audit_update_record
;
2022-06-14 deposited with the CCDC.	2022-09-16 downloaded from the CCDC.
;
_cell_angle_alpha                90
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_cell_measurement_theta_min      2.37
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_computing_cell_refinement       'Bruker SAINT'
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_diffrn_ambient_temperature      203(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
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_diffrn_reflns_limit_l_min       -35
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_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
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_exptl_absorpt_coefficient_mu    4.023
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.5232
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.282
_exptl_crystal_description       needle
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_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: Alkanes/tetrahydrofuran'
_exptl_crystal_size_max          0.16
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_refine_ls_extinction_method     none
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_refine_ls_matrix_type           full
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_refine_ls_restrained_S_all      1.008
_refine_ls_R_factor_all          0.1218
_refine_ls_R_factor_gt           0.0579
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0563P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1112
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_reflns_Friedel_coverage         0.000
_reflns_number_gt                4459
_reflns_number_total             7553
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d2dt02615e2.cif
_cod_data_source_block           4a
_cod_original_cell_volume        8603.6(13)
_cod_original_sg_symbol_H-M      'I 2/a'
_cod_database_code               7711281
_shelx_shelxl_version_number     2018/3
_shelx_res_checksum              75333
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