Rhodium-catalyzed cyclization of acceptor-substituted biphenyl α-diazoketones: a study of the substitution effect on chemoselectivity.
Chen, Kuo-Hsin; Chiang, Yi-Jung; Zhu, Jia-Liang; Organic & biomolecular chemistry 16 (2018) 8353–8364; doi:10.1039/c8ob01489b

data_7156398
_publ_section_title
;
 Rhodium-catalyzed cyclization of acceptor-substituted biphenyl
 \a-diazoketones: a study of the substitution effect on chemoselectivity.
;
_journal_issue                   37
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              8353
_journal_page_last               8364
_journal_paper_doi               10.1039/c8ob01489b
_journal_volume                  16
_journal_year                    2018
_chemical_formula_moiety         'C15 H12 O3 S'
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;
2018-04-13 deposited with the CCDC.
2018-08-31 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0427P)^2^+0.9636P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0916
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_reflns_number_gt                2147
_reflns_number_total             2530
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_cod_data_source_file            c8ob01489b2.cif
_cod_data_source_block           chen2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7156397--7156398.cif.
;
_cod_original_sg_symbol_H-M      P2(1)/n
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_shelx_shelxl_version_number     2014/7
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_shelx_res_checksum              27438