Bis[4-amino-<i>N</i>-(4-methylpyrimidin-2-yl-κ<i>N</i>^3^)benzenesulfonamidato-κ<i>N</i>](2,2'-bipyridine-κ^2^<i>N</i>,<i>N</i>')mercury(II)
Hossain, G. M. Golzar; Amoroso, A. J.; Acta Crystallographica Section E 70 (2014) m127–m128; doi:10.1107/S1600536814004760

data_2239209
_publ_section_title
;
 Bis[4-amino-<i>N</i>-(4-methylpyrimidin-2-yl-\k<i>N</i>^3^)benzenesulfonamidato-\k<i>N</i>](2,2'-bipyridine-\k^2^<i>N</i>,<i>N</i>')mercury(II)
;
_journal_coeditor_code           HB7201
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m127
_journal_page_last               m128
_journal_paper_doi               10.1107/S1600536814004760
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac          '[Hg (C11 H11 N4 O2 S)2 (C10 H8 N2)]'
_chemical_formula_moiety         'C32 H30 Hg N10 O4 S2'
_chemical_formula_sum            'C32 H30 Hg N10 O4 S2'
_chemical_formula_weight         883.37
_chemical_name_systematic
Bis[4-amino-<i>N</i>-(4-methylpyrimidin-2-yl-\k<i>N</i>^3^)benzenesulfonamidato-\k<i>N</i>](2,2'-bipyridine-\k^2^<i>N</i>,<i>N</i>')mercury(II)
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                90
_cell_angle_beta                 100.202(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   18.7483(8)
_cell_length_b                   15.0824(7)
_cell_length_c                   12.1143(6)
_cell_measurement_reflns_used    3874
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.91
_cell_volume                     3371.4(3)
_computing_cell_refinement
'DENZO (Otwinowski & Minor, 1997) and COLLECT (Hooft, 1998)'
_computing_data_collection
'DENZO (Otwinowski & Minor, 1997) and COLLECT (Hooft, 1998)'
_computing_data_reduction
'DENZO (Otwinowski & Minor, 1997) and COLLECT (Hooft, 1998)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX (Farrugia, 2012)'
_computing_structure_refinement  'SHELXL2013 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0719
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            29910
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.510
_diffrn_reflns_theta_min         3.196
_exptl_absorpt_coefficient_mu    4.743
_exptl_absorpt_correction_T_max  0.648
_exptl_absorpt_correction_T_min  0.600
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SORTAV; Blessing, 1995)]'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.740
_exptl_crystal_description       Block
_exptl_crystal_F_000             1744
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.125
_refine_diff_density_min         -0.745
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.101
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     231
_refine_ls_number_reflns         3874
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.101
_refine_ls_R_factor_all          0.0498
_refine_ls_R_factor_gt           0.0392
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0108P)^2^+13.7149P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0712
_refine_ls_wR_factor_ref         0.0739
_reflns_number_gt                3408
_reflns_number_total             3874
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            hb7201sup1.cf
_cod_data_source_block           I
_cod_database_code               2239209
_cod_database_fobs_code          2239209
_shelx_estimated_absorpt_t_min   0.600
_shelx_estimated_absorpt_t_max   0.648
_shelx_hkl_checksum              64927
_shelx_res_checksum              34382