Photoinduced Dimerization Reaction Coupled with Oxygenation of a Platinum(II)-Hydrazone Complex.
Kobayashi, Atsushi; Yamamoto, Daisuke; Horiki, Hiroyuki; Sawaguchi, Kana; Matsumoto, Takeshi; Nakajima, Kiyohiko; Chang, Ho-Chol; Kato, Masako; Inorganic chemistry 53 (2014) 2573–2581; doi:10.1021/ic402879g

data_4337821
_publ_section_title
;
 Photoinduced Dimerization Reaction Coupled with Oxygenation of a
 Platinum(II)-Hydrazone Complex.
;
_journal_issue                   5
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2573
_journal_page_last               2581
_journal_paper_doi               10.1021/ic402879g
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety         'C48 H36 Cl2 N6 O P2 Pt2'
_chemical_formula_sum            'C48 H36 Cl2 N6 O P2 Pt2'
_chemical_formula_weight         1235.89
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.0000
_cell_angle_beta                 98.718(3)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   15.241(5)
_cell_length_b                   11.609(4)
_cell_length_c                   25.365(8)
_cell_measurement_temperature    130
_cell_measurement_theta_max      28.16
_cell_volume                     4436(3)
_computing_cell_refinement       'CrystalClear-SM Expert 2.0 r16'
_computing_data_collection
'CrystalClear-SM Expert 2.0 r16 (Rigaku, 2013)'
_computing_data_reduction        'CrystalClear-SM Expert 2.0 r16'
_computing_molecular_graphics    'CrystalStructure 4.0'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Altomare, et al., 1994)'
_diffrn_ambient_temperature      130
_diffrn_detector_area_resol_mean 14.629
_diffrn_measured_fraction_theta_full 0.941
_diffrn_measured_fraction_theta_max 0.941
_diffrn_measurement_device_type  'Rigaku Mercury70'
_diffrn_measurement_method       \w
_diffrn_radiation_type           Synchrotron
_diffrn_radiation_wavelength     0.68900
_diffrn_reflns_av_R_equivalents  0.1697
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            45115
_diffrn_reflns_theta_full        28.16
_diffrn_reflns_theta_max         28.16
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    65.10
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.322
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.850
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Platelet
_exptl_crystal_F_000             2376.00
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_refine_diff_density_max         5.460
_refine_diff_density_min         -5.580
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     550
_refine_ls_number_reflns         11231
_refine_ls_number_restraints     0
_refine_ls_R_factor_gt           0.0676
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^)+(0.1067P)^2^+12.6374P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.2046
_reflns_number_gt                9640
_reflns_number_total             11231
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            ic402879g_si_001.cif
_cod_data_source_block           '__Pt2'
_cod_database_code               4337821