Synthesis of new photosensitive H2BBQ(2+)[ZnCl4](2-)/[(ZnCl)2(μ-BBH)] complexes, through selective oxidation of H2O to H2O2.
Stylianou, M.; Hadjiadamou, I.; Drouza, C.; Hayes, S. C.; Lariou, E.; Tantis, I.; Lianos, P.; Tsipis, A. C.; Keramidas, A. D.; Dalton transactions (Cambridge, England : 2003) 46 (2017) 3688–3699; doi:10.1039/c6dt04643f

data_7042190
_publ_section_title
;
 Synthesis of new photosensitive H2BBQ(2+)[ZnCl4](2-)/[(ZnCl)2(\m-BBH)]
 complexes, through selective oxidation of H2O to H2O2.
;
_journal_issue                   11
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3688
_journal_page_last               3699
_journal_paper_doi               10.1039/c6dt04643f
_journal_volume                  46
_journal_year                    2017
_chemical_formula_sum            'C60 H80 Cl4 N12 O18 Zn4'
_chemical_formula_weight         1660.64
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
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_space_group_name_Hall           '-P 1'
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;
2016-12-08 deposited with the CCDC.
2017-02-21 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_full 0.999
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_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
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_diffrn_reflns_av_unetI/netI     0.0755
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_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.855
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_diffrn_reflns_theta_max         29.627
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_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    1.607
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.88686
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
'Sun Oct 11 10:18:51 2015'
;
_exptl_crystal_colour            colourless
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_exptl_crystal_description
;
'Sun Oct 11 10:18:51 2015'
;
_exptl_crystal_F_000             1712
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0415P)^2^+25.0857P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7042187--7042190.cif.'
_cod_original_cell_volume        3448.8(2)
_cod_database_code               7042190
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