<i>catena</i>-Poly[[[diaqua(nitrato-κ^2^<i>O</i>,<i>O</i>')(2,2':6',2''-terpyridine-κ^3^<i>N</i>,<i>N</i>',<i>N</i>'')ytterbium(III)]-μ-cyanido-κ^2^<i>N</i>:<i>C</i>-[dicyanidoplatinum(II)]-μ-cyanido-κ^2^<i>C</i>:<i>N</i>] acetonitrile monosolvate]
Smith, Philip A.; Stojanovic, Milorad; Sykora, Richard E.; Acta Crystallographica Section E 66 (2010) m1619–m1620; doi:10.1107/S1600536810047380

data_2228471
_publ_section_title
;
 <i>catena</i>-Poly[[[diaqua(nitrato-\k^2^<i>O</i>,<i>O</i>')(2,2':6',2''-terpyridine-\k^3^<i>N</i>,<i>N</i>',<i>N</i>'')ytterbium(III)]-\m-cyanido-\k^2^<i>N</i>:<i>C</i>-[dicyanidoplatinum(II)]-\m-cyanido-\k^2^<i>C</i>:<i>N</i>]
 acetonitrile monosolvate]
;
_journal_coeditor_code           NC2203
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1619
_journal_page_last               m1620
_journal_paper_doi               10.1107/S1600536810047380
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac
'[Pt Yb (C N)4 (N O3) (C15 H11 N3) (H2 O)2], C2 H3 N'
_chemical_formula_moiety         'C19 H15 N8 O5 Pt Yb, C2 H3 N'
_chemical_formula_sum            'C21 H18 N9 O5 Pt Yb'
_chemical_formula_weight         844.57
_chemical_name_systematic
;
<i>catena</i>-Poly[[[diaqua(nitrato-\k^2^<i>O</i>,<i>O</i>')(2,2':6',2''-
terpyridine-\k^3^<i>N</i>,<i>N</i>',<i>N</i>'')ytterbium(III)]-\m-cyanido-
\k^2^<i>N</i>:<i>C</i>-[dicyanidoplatinum(II)]-\m-cyanido-
\k^2^<i>C</i>:<i>N</i>] acetonitrile monosolvate]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                79.083(3)
_cell_angle_beta                 72.689(3)
_cell_angle_gamma                78.660(3)
_cell_formula_units_Z            2
_cell_length_a                   9.0810(3)
_cell_length_b                   10.1939(3)
_cell_length_c                   14.4718(6)
_cell_measurement_reflns_used    8297
_cell_measurement_temperature    290(2)
_cell_measurement_theta_max      25.6241
_cell_measurement_theta_min      3.1208
_cell_volume                     1241.70(8)
_computing_cell_refinement
;
<i>CrysAlis PRO</i> (Oxford Diffraction, 2010)
;
_computing_data_collection
;
<i>CrysAlis PRO</i> (Oxford Diffraction, 2010)
;
_computing_data_reduction
;
<i>CrysAlis PRO</i> (Oxford Diffraction, 2010)
;
_computing_molecular_graphics
'<i>OLEX2</i> (Dolomanov <i>et al.</i>, 2009)'
_computing_publication_material  '<i>publCIF</i> (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      290(2)
_diffrn_detector_area_resol_mean 16.0514
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Oxford Diffraction Xcalibur E'
_diffrn_measurement_method       '\w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0229
_diffrn_reflns_av_sigmaI/netI    0.0295
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            9396
_diffrn_reflns_theta_full        25.68
_diffrn_reflns_theta_max         25.68
_diffrn_reflns_theta_min         3.13
_exptl_absorpt_coefficient_mu    9.421
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.24881
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(<i>CrysAlis PRO</i>; Oxford Diffraction, 2010)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.259
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             790
_exptl_crystal_size_max          0.49
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.27
_refine_diff_density_max         1.730
_refine_diff_density_min         -1.367
_refine_ls_extinction_coef       0.00308(18)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     'SHELXL97 (Sheldrick, 2008)'
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     336
_refine_ls_number_reflns         4701
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0286
_refine_ls_R_factor_gt           0.0235
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0345P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0575
_refine_ls_wR_factor_ref         0.0587
_reflns_number_gt                4049
_reflns_number_total             4701
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            nc2203.cif
_cod_data_source_block           I
_cod_database_code               2228471
_cod_database_fobs_code          2228471