<i>catena</i>-Poly[[[aquasilver(I)]-μ-4,4'-bipyridine-κ^2^<i>N</i>:<i>N</i>'] 4-aminobenzoate nitrate hydrate]
Zhang, Yong-Mei; Hou, Dong-Yan; Xin, Guang; Li, Tie-Chun; Acta Crystallographica Section E 66 (2010) m287–; doi:10.1107/S1600536810005052

data_2225401
_publ_section_title
;<i>catena</i>-Poly[[[aquasilver(I)]-\m-4,4'-bipyridine-\k^2^<i>N</i>:<i>N</i>']
 4-aminobenzoate nitrate hydrate]
;
_journal_coeditor_code           WM2305
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m287
_journal_paper_doi               10.1107/S1600536810005052
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac
'2[Ag (C10 H8 N2) (H2 O)] (C7 H6 N O2) (N O3) , H2 O'
_chemical_formula_moiety
'2C10 H10 Ag N2 O + , C7 H6 N O2 - , N O3 - , H2 O'
_chemical_formula_sum            'C27 H28 Ag2 N6 O8'
_chemical_formula_weight         780.29
_chemical_name_systematic
;<i>catena</i>-Poly[[[aquasilver(I)]-\m-4,4'-bipyridine-\k^2^<i>N</i>:<i>N</i>')]
4-aminobenzoate
 nitrate hydrate]
;
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 103.2310(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.2595(4)
_cell_length_b                   17.3531(8)
_cell_length_c                   9.9267(4)
_cell_measurement_reflns_used    2847
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.09
_cell_measurement_theta_min      2.11
_cell_volume                     1385.01(11)
_computing_cell_refinement       'SAINT (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0236
_diffrn_reflns_av_sigmaI/netI    0.0272
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            7782
_diffrn_reflns_theta_full        26.09
_diffrn_reflns_theta_max         26.09
_diffrn_reflns_theta_min         2.11
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.477
_exptl_absorpt_correction_T_max  0.83
_exptl_absorpt_correction_T_min  0.54
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.871
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             780
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.17
_refine_diff_density_max         0.341
_refine_diff_density_min         -0.376
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     230
_refine_ls_number_reflns         2847
_refine_ls_number_restraints     8
_refine_ls_restrained_S_all      1.065
_refine_ls_R_factor_all          0.0299
_refine_ls_R_factor_gt           0.0230
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0284P)^2^+0.2523P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0549
_refine_ls_wR_factor_ref         0.0586
_reflns_number_gt                2390
_reflns_number_total             2847
_reflns_threshold_expression     I>2\s(I)
_cod_data_source_file            wm2305.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/m'
_cod_database_code               2225401
_cod_database_fobs_code          2225401