A Ferromagnetic Methoxido-Bridged Mn(III) Dimer and a Spin-Canted Metamagnetic μ1,3-Azido-Bridged Chain
Subrata Naiya; Saptarshi Biswas; Michael G. B. Drew; Carlos J. Gómez-García; Ashutosh Ghosh; Inorganic Chemistry 51 (2012) 5332–5341; doi:10.1021/ic300274n

data_4329118
_publ_section_title
;
 A Ferromagnetic Methoxido-Bridged Mn(III) Dimer and a Spin-Canted
 Metamagnetic \m1,3-Azido-Bridged Chain
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5332
_journal_page_last               5341
_journal_paper_doi               10.1021/ic300274n
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C22 H30 Mn2 N16 O2'
_chemical_formula_weight         660.50
_chemical_name_systematic
; 
 ? 
;
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_diffrn_ambient_temperature      150(2)
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_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device       'Oxford Diffaction X-Calibur System'
_diffrn_measurement_method       '321 frames, counting time 10 s.'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
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_exptl_crystal_size_mid          0.04
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.740
_refine_ls_R_factor_all          0.1525
_refine_ls_R_factor_gt           0.0536
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
_refine_ls_weighting_details 
  w=1/[\s^2^(Fo^2^)+(0.0389P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3 
;
_refine_ls_weighting_scheme      calc
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