Construction of the Multidecker Anthracene-Silver(I) System by Intramolecular π-π Interactions
Megumu Munakata; Liang Ping Wu; Takayoshi Kuroda-Sowa; Masahiko Maekawa; Yusaku Suenaga; Tetsuhiro Ohta; Hisashi Konaka; Inorganic Chemistry 42 (2003) 2553–2558; doi:10.1021/ic020379l

data_4313453
_publ_section_title
;
 Construction of the Multidecker Anthracene-Silver(I) System by
 Intramolecular \p-\p Interactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2553
_journal_page_last               2558
_journal_paper_doi               10.1021/ic020379l
_journal_volume                  42
_journal_year                    2003
_chemical_formula_moiety         'C48 H42 Ag2 Cl2 O8 '
_chemical_formula_sum            'C48 H42 Ag2 Cl2 O8'
_chemical_formula_weight         1033.50
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 89.238(1)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.504(2)
_cell_length_b                   23.858(8)
_cell_length_c                   23.062(1)
_cell_measurement_temperature    295.2
_cell_volume                     4128.4(18)
_computing_cell_refinement       D*TREK
_computing_data_collection       D*TREK
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  SHELXL97
_computing_structure_solution    SAPI91
_diffrn_measured_fraction_theta_full 1.00
_diffrn_measured_fraction_theta_max 1.00
_diffrn_measurement_device_type  'Quantum CCD/Rigaku AFC7'
_diffrn_measurement_method       \w
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.000
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            4854
_diffrn_reflns_theta_full        28.17
_diffrn_reflns_theta_max         28.17
_exptl_absorpt_coefficient_mu    1.132
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.663
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             2088.0
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_refine_diff_density_max         1.25
_refine_diff_density_min         -3.42
_refine_ls_extinction_coef       0.0000
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.725
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     272
_refine_ls_number_reflns         3194
_refine_ls_R_factor_gt           0.1086
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.4132
_reflns_number_gt                3194
_reflns_number_total             4747
_reflns_threshold_expression     >2.0sigma(I)
_cod_data_source_file            ic020379l_3.cif
_cod_data_source_block           '[Ag2(dmban)2(ClO4)2(p-xyle'
_cod_original_cell_volume        4128(1)
_cod_original_formula_sum        'C48 H42 Ag2 Cl2 O8 '
_cod_database_code               4313453