Synthesis and structural systematics of mixed triphenylphosphine/imidazole base adducts of silver(I) oxyanion salts †
Cingolani, Augusto; Effendy,; Marchetti, Fabio; Pettinari, Claudio; Skelton, Brian W.; White, Allan H.; Journal of the Chemical Society, Dalton Transactions  (1999) 4047–; doi:10.1039/a906624a

data_7702423
_publ_section_title
;
 Synthesis and structural systematics of mixed
 triphenylphosphine/imidazole base adducts of silver(I) oxyanion
 salts&#x200A;&#x2020;
;
_journal_issue                   22
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              4047
_journal_paper_doi               10.1039/a906624a
_journal_year                    1999
_chemical_formula_structural     '[(Ph3P)Ag(C4H6N2)3](CF3CO2)'
_chemical_formula_sum            'C32 H33 Ag F3 N6 O2 P'
_chemical_formula_weight         729.49
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                89.71(3)
_cell_angle_beta                 71.83(3)
_cell_angle_gamma                62.54(3)
_cell_formula_units_Z            2
_cell_length_a                   14.516(5)
_cell_length_b                   14.219(5)
_cell_length_c                   10.022(4)
_cell_measurement_reflns_used    8
_cell_measurement_temperature    293
_cell_measurement_theta_max      17.5
_cell_measurement_theta_min      13.3
_cell_volume                     1720.2(13)
_computing_cell_refinement       'Siemens SAINT (Siemens, 1995)'
_computing_data_collection       'Siemens SMART (Siemens, 1995)'
_computing_data_reduction        xtal
_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  xtal
_computing_structure_solution    xtal
_diffrn_ambient_temperature      293
_diffrn_measurement_device_type
;
CAD4 diffractometer
;
_diffrn_measurement_method       '2\q-\w scans'
_diffrn_radiation_detector       'single counter'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .018
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            6141
_diffrn_reflns_theta_max         25
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  3600
_diffrn_standards_number         8
_exptl_absorpt_coefficient_mu    .69
_exptl_absorpt_correction_T_max  .90
_exptl_absorpt_correction_T_min  .83
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
 SADABS; Sheldrick, 1996
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.408
_exptl_crystal_description       prism
_exptl_crystal_F_000             744
_exptl_crystal_size_max          .38
_exptl_crystal_size_mid          .24
_exptl_crystal_size_min          .20
_refine_diff_density_max         .53
_refine_diff_density_min         -.61
_refine_ls_extinction_coef       850(85)
_refine_ls_extinction_expression Zachariasen
_refine_ls_extinction_method     Zachariasen
_refine_ls_goodness_of_fit_all   1.416
_refine_ls_goodness_of_fit_ref   1.668
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     539
_refine_ls_number_reflns         3537
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .087
_refine_ls_R_factor_gt           0.047
_refine_ls_shift/su_max          0.325
_refine_ls_shift/su_mean         .013
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_all         .050
_refine_ls_wR_factor_ref         0.043
_reflns_limit_h_max              17
_reflns_limit_h_min              0
_reflns_limit_k_max              16
_reflns_limit_k_min              -14
_reflns_limit_l_max              11
_reflns_limit_l_min              -11
_reflns_number_gt                3537
_reflns_number_observed          3537
_reflns_number_total             6076
_reflns_threshold_expression     'I    > 3.00 sig(I   )'
_cod_data_source_file            906624a.txt
_cod_data_source_block           cp12
_cod_original_sg_symbol_Hall     -p_1
_cod_original_sg_symbol_H-M      P_-1
_cod_original_formula_sum        'C32 H33 Ag1 F3 N6 O2 P1'
_cod_database_code               7702423