Fragmentation of Bicyclic γ-Silyloxy-β-hydroxy-α-diazolactones as an Approach to Ynolides.
Bayir, Ali; Brewer, Matthias; The Journal of organic chemistry 79 (2014) 6037–6046; doi:10.1021/jo500634d

data_4029617
_publ_section_title
;
 Fragmentation of Bicyclic \g-Silyloxy-\b-hydroxy-\a-diazolactones as an
 Approach to Ynolides.
;
_journal_issue                   13
_journal_name_full               'The Journal of organic chemistry'
_journal_page_first              6037
_journal_page_last               6046
_journal_paper_doi               10.1021/jo500634d
_journal_volume                  79
_journal_year                    2014
_chemical_formula_moiety         'C9 H10 O3'
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_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0656P)^2^+0.2181P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1071
_refine_ls_wR_factor_ref         0.1111
_reflns_number_gt                1787
_reflns_number_total             1975
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            jo500634d_si_002.cif
_cod_data_source_block           ab_3_98_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4029617.cif.
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4029617