Bis(dimethylglyoximato)(phenylacetylido)(triphenylphosphine)rhodium(III) Dichloromethane, [Rh(C~4~H~7~N~2~O~2~)~2~(C~8~H~5~)(C~18~H~15~P)].CH~2~Cl~2~
Dunaj-Jurco, M.; Kettmann, V.; Steinborn, D.; Ludwig, M.; Acta Crystallographica Section C 51 (1995) 210–213; doi:10.1107/S010827019400586X

data_2010482
_publ_section_title
;
 Bis(dimethylglyoximato)(phenylacetylido)(triphenylphosphine)rhodium(III)
 Dichloromethane,
 [Rh(C~4~H~7~N~2~O~2~)~2~(C~8~H~5~)(C~18~H~15~P)].CH~2~Cl~2~
;
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              210
_journal_page_last               213
_journal_paper_doi               10.1107/S010827019400586X
_journal_volume                  51
_journal_year                    1995
_chemical_formula_moiety
;
[Rh(C~4~H~7~N~2~O~2~)~2~(C~18~H~15~P)(C~8~H~5~)].CH~2~Cl~2~
;
_chemical_formula_sum            'C35 H36 Cl2 N4 O4 P Rh'
_chemical_formula_weight         781.48
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_type_scat_source           IntTabIV
_cell_angle_alpha                90.
_cell_angle_beta                 103.00(6)
_cell_angle_gamma                90.
_cell_formula_units_Z            4
_cell_length_a                   20.378(9)
_cell_length_b                   9.914(5)
_cell_length_c                   17.272(8)
_cell_measurement_reflns_used    15
_cell_measurement_temperature    293
_cell_measurement_theta_max      17
_cell_measurement_theta_min      6
_cell_volume                     3400(3)
_diffrn_measurement_device       'Syntex P2~1~'
_diffrn_measurement_method       \w/2\q
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.024
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            6388
_diffrn_reflns_theta_max         25
_diffrn_standards_decay_%        .0
_diffrn_standards_interval_time  90
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    0.74
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            'brownish yellow'
_exptl_crystal_density_diffrn    1.527
_exptl_crystal_density_meas      1.530(10)
_exptl_crystal_description       prisms
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.28
_refine_diff_density_min         -0.32
_refine_ls_extinction_method     'none ?'
_refine_ls_goodness_of_fit_obs   1.34
_refine_ls_hydrogen_treatment    noref
_refine_ls_number_parameters     442
_refine_ls_number_reflns         4478
_refine_ls_R_factor_obs          0.045
_refine_ls_shift/esd_max         0.13
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      'unit if |F| < 60 and 60/|F| if |F| >= 60'
_refine_ls_wR_factor_obs         0.056
_reflns_number_observed          4478
_reflns_number_total             6022
_reflns_observed_criterion       I>=2\s(I)
_cod_data_source_file            mu1107.cif
_cod_data_source_block           mu1107_structure_1_of_1
_cod_original_cell_volume        3400(2)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C35 H36 Cl2 N4 O4 P1 Rh'
_cod_database_code               2010482