The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4',4''-(MeOCH<sub>2</sub>CH<sub>2</sub>O)<sub>3</sub>-3,3',3''-Co<sub>3</sub>(μ<sup>3</sup>-O)(μ<sup>3</sup>-S)(1,2-C<sub>2</sub>B<sub>9</sub>H<sub>10</sub>)<sub>3</sub>].
Stogniy, Marina Yu; Anufriev, Sergey A.; Shmal'ko, Akim V.; Antropov, Sergey M.; Anisimov, Aleksei A.; Suponitsky, Kyrill Yu; Filippov, Oleg A.; Sivaev, Igor B.; Dalton transactions (Cambridge, England : 2003) 50 (2021) 2671–2688; doi:10.1039/d0dt03857a

data_7706515
_publ_section_title
;
 The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic
 substitution reactions to the synthesis of tricobalt tris(dicarbollide)
 Na[4,4',4''-(MeOCH<sub>2</sub>CH<sub>2</sub>O)<sub>3</sub>-3,3',3''-Co<sub>3</sub>(\m<sup>3</sup>-O)(\m<sup>3</sup>-S)(1,2-C<sub>2</sub>B<sub>9</sub>H<sub>10</sub>)<sub>3</sub>].
;
_journal_issue                   7
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'Dalton transactions (Cambridge, England : 2003)'
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_journal_paper_doi               10.1039/d0dt03857a
_journal_volume                  50
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_chemical_formula_moiety         'C15 H51 B27 Co3 Na O7 S'
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_audit_update_record
;
2020-11-03 deposited with the CCDC.	2021-01-25 downloaded from the CCDC.
;
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'SHELXL-2014/6 (Sheldrick, 2014) and PLATON (Spek, 2015)'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0502P)^2^+5.4194P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
'Adding full bibliography for 7706515--7706517.cif.'
_cod_original_cell_volume        3926.9(5)
_cod_original_sg_symbol_H-M      'P 21/n'
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