Phosphine-catalyzed fixation of CO2 with γ-hydroxyl alkynone under ambient temperature and pressure: kinetic resolution and further conversion
Sun, Yao-Liang; Wei, Yin; Shi, Min; Organic Chemistry Frontiers 6 (2019) 2420–; doi:10.1039/C9QO00642G

data_1554993
_publ_section_title
;
 Phosphine-catalyzed fixation of CO2 with \g-hydroxyl alkynone under
 ambient temperature and pressure: kinetic resolution and further
 conversion
;
_journal_issue                   14
_journal_name_full               'Organic Chemistry Frontiers'
_journal_page_first              2420
_journal_paper_doi               10.1039/C9QO00642G
_journal_volume                  6
_journal_year                    2019
_chemical_formula_sum            'C14 H11 N O5'
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_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2016-12-29 deposited with the CCDC.	2019-05-20 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
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_diffrn_reflns_Laue_measured_fraction_full 1.000
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
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_refine_ls_R_factor_all          0.0519
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0628P)^2^+0.1544P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_data_source_block           cd16781
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1554993
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_shelx_estimated_absorpt_t_max   0.987
_shelxl_version_number           2013-4
_shelx_res_checksum              31292
_shelx_hkl_checksum              11808