Influence of counterions on the formation of supramolecular platinum group metal complexes containing pyridyl thioamide derivatives: antioxidant and antimicrobial studies
Dkhar, Lincoln; Gupta, Hrishikesh; Poluri, Krishna Mohan; Gannon, Paige M.; Kaminsky, Werner; Kollipara, Mohan Rao; New Journal of Chemistry 46 (2022) 19241–19253; doi:10.1039/D2NJ03108F

data_7061862
_publ_section_title
;
 Influence of counterions on the formation of supramolecular platinum
 group metal complexes containing pyridyl thioamide derivatives:
 antioxidant and antimicrobial studies
;
_journal_issue                   40
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              19241
_journal_page_last               19253
_journal_paper_doi               10.1039/D2NJ03108F
_journal_volume                  46
_journal_year                    2022
_chemical_formula_moiety         'C20 H27 Ir N8 S2'
_chemical_formula_sum            'C20 H27 Ir N8 S2'
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_audit_update_record
;
2022-02-26 deposited with the CCDC.	2022-09-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
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'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
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_diffrn_measurement_device       '95mm CCD camera on \k-goniostat'
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_diffrn_orient_matrix_UB_33      -0.021008
_diffrn_radiation_monochromator  'horizonally mounted graphite crystal'
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_diffrn_radiation_type           Mok\a
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_diffrn_reflns_av_unetI/netI     0.0804
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_diffrn_source                   'Enraf Nonius FR590'
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_exptl_absorpt_coefficient_mu    5.131
_exptl_absorpt_correction_T_max  0.637
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SCALEPACK 2008'
_exptl_crystal_colour            brown
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_exptl_crystal_description       prism
_exptl_crystal_F_000             1248
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_exptl_crystal_size_min          0.100
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_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0500P)^2^+10.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1361
_refine_ls_wR_factor_ref         0.1446
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4695
_reflns_number_total             6283
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d2nj03108f2.cif
_cod_data_source_block           shelx_CCDC9
_cod_depositor_comments
'Adding full bibliography for 7061852--7061867.cif.'
_cod_original_sg_symbol_H-M      P21/a
_cod_database_code               7061862
_shelx_shelxl_version_number     2014/7
_shelx_estimated_absorpt_t_min   0.398
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_shelx_res_checksum              36422
_shelx_fab_checksum              1005