Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes.
Geeson, Michael B.; Transue, Wesley J.; Cummins, Christopher C.; Journal of the American Chemical Society 141 (2019) 13336–13340; doi:10.1021/jacs.9b07069

data_4128903
_publ_section_title
;
 Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic
 Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes.
;
_journal_issue                   34
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13336
_journal_page_last               13340
_journal_paper_doi               10.1021/jacs.9b07069
_journal_volume                  141
_journal_year                    2019
_chemical_formula_sum            'C33 H40 B F4 Fe O4 P'
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_cell_length_b                   12.7003(13)
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_cell_measurement_temperature    100(2)
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_diffrn_reflns_Laue_measured_fraction_full 0.999
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_exptl_crystal_density_diffrn    1.432
_exptl_crystal_description       needle
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.1608P)^2^+25.5434P] where P=(Fo^2^+2Fc^2^)/3'
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