Luminescent diphosphine fluorophenylthiolate silver(i) compounds that exhibit argentophilic interactions
Moreno-Alcántar, Guillermo; Nácar-Anaya, Antonio; Flores-Álamo, Marcos; Torrens, Hugo; New J. Chem. 40 (2016) 6577–; doi:10.1039/C6NJ00984K

data_7055669
_publ_section_title
;
 Luminescent diphosphine fluorophenylthiolate silver(i) compounds that
 exhibit argentophilic interactions
;
_journal_issue                   8
_journal_name_full               'New J. Chem.'
_journal_page_first              6577
_journal_paper_doi               10.1039/C6NJ00984K
_journal_volume                  40
_journal_year                    2016
_chemical_formula_moiety         'C64 H50 Ag2 F4 P4 S2'
_chemical_formula_sum            'C64 H50 Ag2 F4 P4 S2'
_chemical_formula_weight         1298.78
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
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;
2016-02-19 deposited with the CCDC.
2016-06-21 downloaded from the CCDC.
;
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        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
;
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        CrysAlisPro, Agilent Technologies,
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        (compiled Aug  2 2013,16:46:58)
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        CrysAlisPro, Agilent Technologies,
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        (compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics
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          'Ortep-3 for Windows (Farrugia, 1997)'
      L. J. Farrugia, J. Appl. Crystallogr., 1997, 30, 565.
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        'WinGX publication routines (Farrugia, 1999)'                 
    L. J. Farrugia, J. Appl. Crystallogr., 1999, 32, 837-838.
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_computing_structure_solution
;
      'SHELXS-2014 (Sheldrick, 2008)'
      G. M. Sheldrick, Acta Crystallogr., Sect. A: 
      Found. Crystallogr., 2008, 64, 112-122.
;
_diffrn_ambient_temperature      298(2)
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_diffrn_measurement_method       '\w scans'
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;
        CrysAlisPro, Agilent Technologies,
        Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
        (compiled Aug  2 2013,16:46:58)
Analytical numeric absorption correction using a multifaceted crystal
                        model based on expressions derived by R.C. Clark & J.S.
        (Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.481
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_refine_ls_matrix_type           full
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_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0643
_refine_ls_R_factor_gt           0.0371
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0266P)^2^+1.3556P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0696
_refine_ls_wR_factor_ref         0.0814
_reflns_Friedel_coverage         0
_reflns_number_gt                10136
_reflns_number_total             14065
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c6nj00984k2.cif
_cod_data_source_block           2A
_cod_depositor_comments
'Adding full bibliography for 7055667--7055670.cif.'
_cod_original_cell_volume        2913.02(16)
_cod_database_code               7055669
_shelx_estimated_absorpt_t_min   0.691
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_shelx_res_checksum              1426