Regulation of magnetic relaxation behavior by replacing 3d transition metal ions in [M<sub>2</sub>Dy<sub>2</sub>] complexes containing two different organic chelating ligands.
Wang, Hui-Sheng; Yin, Cheng-Ling; Hu, Zhao-Bo; Chen, Yong; Pan, Zhi-Quan; Song, You; Zhang, Yi-Quan; Zhang, Zai-Chao; Dalton transactions (Cambridge, England : 2003) 48 (2019) 10011–10022; doi:10.1039/c9dt00774a

data_7700064
_publ_section_title
;
 Regulation of magnetic relaxation behavior by replacing 3d transition
 metal ions in [M<sub>2</sub>Dy<sub>2</sub>] complexes containing two
 different organic chelating ligands.
;
_journal_issue                   27
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10011
_journal_page_last               10022
_journal_paper_doi               10.1039/c9dt00774a
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety
'C60 H74 Co2 Gd2 N8 O18, 2(N O3), 6CH3OH, 1.5H2O'
_chemical_formula_sum            'C66 H101 Co2 Gd2 N10 O31.5'
_chemical_formula_weight         1970.92
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-05-06 deposited with the CCDC.    2019-05-23 downloaded from the CCDC.
;
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_computing_cell_refinement       'Bruker SMART'
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_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'PHOTON 100 CMOS detector'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_theta_min         3.079
_diffrn_source                   'fine-focus sealed tube'
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_exptl_absorpt_correction_T_max  0.7452
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_refine_ls_number_reflns         6783
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_refine_ls_R_factor_all          0.0658
_refine_ls_R_factor_gt           0.0420
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0026P)^2^+3.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0650
_refine_ls_wR_factor_ref         0.0688
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5337
_reflns_number_total             6783
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            c9dt00774a2.cif
_cod_data_source_block           complex_2'
_cod_depositor_comments
'Adding full bibliography for 7700062--7700065.cif.'
_cod_original_formula_sum        'C66 H101 Co2 Gd2 N10 O31.50'
_cod_database_code               7700064
_shelx_shelxl_version_number     2014/7
_shelx_res_checksum              6554
_shelx_fab_checksum              71797