Ligand-assisted O-dealkylation of bis(bipyridyl) ruthenium(II) phosphine-ether complexes †
Rogers, Cerrie W.; Patrick, Brian O.; Rettig, Steven J.; Wolf, Michael O.; Journal of the Chemical Society, Dalton Transactions  (2001) 1278–; doi:10.1039/b008931l

data_7010429
_publ_section_title
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 Ligand-assisted O-dealkylation of bis(bipyridyl) ruthenium(II)
 phosphine-ether complexes&#x200A;&#x2020;
;
_journal_issue                   8
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1278
_journal_paper_doi               10.1039/b008931l
_journal_year                    2001
_chemical_formula_moiety         'C39 H33 F12 N4 O P3 Ru '
_chemical_formula_sum            'C39 H33 F12 N4 O P3 Ru'
_chemical_formula_weight         995.69
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_date             2000-03-07
_audit_creation_method           'by teXsan v1.8'
_audit_update_record
;
?
;
_cell_angle_alpha                90
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_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.0656(4)
_cell_length_b                   20.2301(5)
_cell_length_c                   16.9836(6)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    173.2
_cell_measurement_theta_max      0.0
_cell_measurement_theta_min      0.0
_cell_volume                     4044.9(2)
_computing_cell_refinement       'd*TREK (MSC, 1996-1998)'
_computing_data_collection       'd*TREK (MSC, 1996-1998)'
_computing_data_reduction        'd*TREK (MSC, 1996-1998)'
_computing_publication_material  'teXsan (MSC, 1992-1997)'
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_computing_structure_solution
;
SIR97 (Altomare, et. al. 1998)
;
_diffrn_ambient_temperature      173.2
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_diffrn_measurement_device_type  'Rigaku/ADSC CCD'
_diffrn_measurement_method       'area detector'
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_diffrn_radiation_detector       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_av_R_equivalents  0.03762
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_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -22
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_diffrn_reflns_reduction_process 'Lp corrections applied'
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_diffrn_reflns_theta_min         3.18
_diffrn_standards_decay_%        0.00
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_refine_ls_extinction_method     none
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_refine_ls_goodness_of_fit_ref   1.470
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_refine_ls_R_factor_all          0.0450
_refine_ls_R_factor_gt           0.0310
_refine_ls_shift/su_max          0.0500
_refine_ls_shift/su_mean         0.0021
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[\s^2^(Fo)]'
_refine_ls_weighting_scheme      sigma
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_refine_ls_wR_factor_ref         0.0420
_reflns_number_gt                7434
_reflns_number_total             8759
_reflns_threshold_expression     I>3.00\s(I)
_cod_data_source_file            b008931l.txt
_cod_data_source_block           mw004
_cod_original_sg_symbol_H-M      'P 21/n     '
_cod_original_formula_sum        'C39 H33 F12 N4 O P3 Ru '
_cod_database_code               7010429