A novel two-step Fe-Au type spin-crossover behavior in a Hofmann-type coordination complex {Fe(4-methylpyrimidine)<sub>2</sub>[Au(CN)<sub>2</sub>]<sub>2</sub>}.
Kitase, Kosuke; Kitazawa, Takafumi; Dalton transactions (Cambridge, England : 2003) 49 (2020) 12210–12214; doi:10.1039/d0dt01681k

data_7704681
_publ_section_title
;
 A novel two-step Fe-Au type spin-crossover behavior in a Hofmann-type
 coordination complex
 {Fe(4-methylpyrimidine)<sub>2</sub>[Au(CN)<sub>2</sub>]<sub>2</sub>}.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
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_journal_paper_doi               10.1039/d0dt01681k
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C14 H12 Au2 Fe N8'
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;
2019-12-23 deposited with the CCDC.	2020-06-18 downloaded from the CCDC.
;
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SADABS-2016/2 - Bruker AXS area detector scaling and absorption correction
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0346P)^2^] where P=(Fo^2^+2Fc^2^)/3'
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_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Numerical' was
changed to 'numerical' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7704681--7704683.cif.
;
_cod_database_code               7704681
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