Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to β-Silyl (Z)-Enamides.
Kim, Youngchan; Dateer, Ramesh B.; Chang, Sukbok; Organic letters 19 (2017) 190–193; doi:10.1021/acs.orglett.6b03485

data_1545229
_publ_section_title
;
 Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading
 to \b-Silyl (Z)-Enamides.
;
_journal_issue                   1
_journal_name_full               'Organic letters'
_journal_page_first              190
_journal_page_last               193
_journal_paper_doi               10.1021/acs.orglett.6b03485
_journal_volume                  19
_journal_year                    2017
_chemical_formula_sum            'C25 H35 N O2 S Si'
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_diffrn_reflns_limit_l_min       -16
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0506P)^2^+0.8048P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0935
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_reflns_number_total             5577
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            ol6b03485_si_002.cif
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_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 
;
_cod_database_code               1545229
_shelx_estimated_absorpt_t_min   0.906
_shelx_estimated_absorpt_t_max   0.964
_shelxl_version_number           2013-4
_shelx_res_checksum              59423
_shelx_hkl_checksum              28570