Synthesis of mono-, di-, and triaminobismuthanes and observation of C-C coupling of aromatic systems with bismuth(iii) chloride.
Hering-Junghans, Christian; Schulz, Axel; Thomas, Max; Villinger, Alexander; Dalton transactions (Cambridge, England : 2003) 45 (2016) 6053–6059; doi:10.1039/c6dt00229c

data_7038496
_publ_section_title
;
 Synthesis of mono-, di-, and triaminobismuthanes and observation of C-C
 coupling of aromatic systems with bismuth(iii) chloride.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6053
_journal_page_last               6059
_journal_paper_doi               10.1039/c6dt00229c
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         'C38 H54 Bi2 N4 Si2'
_chemical_formula_sum            'C38 H54 Bi2 N4 Si2'
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_chemical_name_systematic
;
 ?
;
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_symmetry_space_group_name_H-M   'P n a 21'
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2016-01-15 deposited with the CCDC.
2016-02-18 downloaded from the CCDC.
;
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_diffrn_radiation_monochromator  graphite
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;
 Flack x determined using 2702 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   0.000(7)
_refine_ls_extinction_method     none
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0177P)^2^+0.2495P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 7038481--7038499.cif.'
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