Controlled release of the guest molecule via borate formation of a fluorinated boronic ester cage.
Takata, Hisatsugu; Ono, Kosuke; Iwasawa, Nobuharu; Chemical communications (Cambridge, England) 56 (2020) 5613–5616; doi:10.1039/d0cc01441a

data_7126347
_publ_section_title
;
 Controlled release of the guest molecule via borate formation of a
 fluorinated boronic ester cage.
;
_journal_issue                   42
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              5613
_journal_page_last               5616
_journal_paper_doi               10.1039/d0cc01441a
_journal_volume                  56
_journal_year                    2020
_chemical_formula_moiety         'C60 H54 B6 F6 O12, 4(C8 H10)'
_chemical_formula_sum            'C88 H94 B6 F6 O12'
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_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
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_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2020-01-27 deposited with the CCDC.	2020-04-07 downloaded from the CCDC.
;
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_diffrn_ambient_temperature      173(2)
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_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID IP area detector system'
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_diffrn_reflns_theta_min         3.045
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_exptl_absorpt_coefficient_mu    0.087
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_exptl_absorpt_process_details   'absorption was corrected by ABSCOR'
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.4332
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_reflns_number_gt                7364
_reflns_number_total             9398
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0cc01441a2.cif
_cod_data_source_block           shelx
_cod_depositor_comments          'Adding full bibliography for 7126347.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7126347
_shelx_shelxl_version_number     2016/6
_shelx_estimated_absorpt_t_min   0.983
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_shelx_res_checksum              50206