Temporal separation of catalytic activities allows anti-Markovnikov reductive functionalization of terminal alkynes.
Li, Le; Herzon, Seth B.; Nature chemistry 6 (2014) 22–27; doi:10.1038/nchem.1799

data_1513790
_publ_section_title
;
 Temporal separation of catalytic activities allows anti-Markovnikov
 reductive functionalization of terminal alkynes.
;
_journal_issue                   1
_journal_name_full               'Nature chemistry'
_journal_page_first              22
_journal_page_last               27
_journal_paper_doi               10.1038/nchem.1799
_journal_volume                  6
_journal_year                    2014
_chemical_formula_sum            'C17 H16 F6 N3 P Ru'
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_chemical_name_systematic
; 
 ? 
;
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'CrystalClear-SM Expert 2.0 r12 (Rigaku, 2011)'
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'CrystalClear-SM Expert 2.0 r12 (Rigaku, 2011)'
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'CrystalClear-SM Expert 2.0 r12 (Rigaku, 2011)'
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_diffrn_ambient_temperature      150(2)
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_diffrn_measured_fraction_theta_max 0.999
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_diffrn_radiation_monochromator  graphite
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_diffrn_reflns_theta_full        30.50
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_exptl_absorpt_correction_type   multi-scan
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_exptl_crystal_colour            Colorless
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1008
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_number_reflns         5819
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_refine_ls_structure_factor_coef Fsqd
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'calc w=1/[\s^2^(Fo^2^)+(0.0220P)^2^+0.5172P] where P=(Fo^2^+2Fc^2^)/3'
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_cod_database_code               1513790