Novel Disilaplatinacyclopentenes Bearing Dialkylsulfide Ligands: Preparation, Characterization, and Mechanistic Consideration of Hydrosilane Reduction of Carboxamides by Bifunctional Organohydrosilanes
Tsutsumi, Hironori; Sunada, Yusuke; Nagashima, Hideo; Organometallics 30 (2011) 68–; doi:10.1021/om100867f

data_4063717
_publ_section_title
;
 Novel Disilaplatinacyclopentenes Bearing Dialkylsulfide Ligands:
 Preparation, Characterization, and Mechanistic Consideration of
 Hydrosilane Reduction of Carboxamides by Bifunctional Organohydrosilanes
;
_journal_issue                   1
_journal_name_full               Organometallics
_journal_page_first              68
_journal_paper_doi               10.1021/om100867f
_journal_volume                  30
_journal_year                    2011
_chemical_formula_moiety         'C15 H28 Pt S2 Si2 '
_chemical_formula_sum            'C15 H28 Pt S2 Si2'
_chemical_formula_weight         523.77
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_cell_angle_alpha                90.0000
_cell_angle_beta                 93.668(5)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   8.787(2)
_cell_length_b                   17.074(4)
_cell_length_c                   12.779(3)
_cell_measurement_reflns_used    6719
_cell_measurement_temperature    113.1
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     1913.3(8)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SIR97
_diffrn_ambient_temperature      113
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       \w
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.110
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15003
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_exptl_absorpt_coefficient_mu    7.638
_exptl_absorpt_correction_T_max  0.683
_exptl_absorpt_correction_T_min  0.398
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.818
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1024.00
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_refine_diff_density_max         3.90
_refine_diff_density_min         -1.49
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     209
_refine_ls_number_reflns         4367
_refine_ls_R_factor_gt           0.0464
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[0.0025Fo^2^ + 1.0000\s(Fo^2^)]/(4Fo^2^)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.1569
_reflns_number_gt                4066
_reflns_number_total             4367
_reflns_threshold_expression     F^2^>2.0\s(F^2^)
_cod_data_source_file            om100867f_si_001.cif
_cod_data_source_block           '_(SI2)Pt(S-S)(3)'
_cod_original_cell_volume        1913.1(9)
_cod_original_formula_sum        'C15 H28 Pt S2 Si2 '
_cod_database_code               4063717