Diastereoselective Production of Homoallylic Alcohols Bearing Quaternary Centers from γ-Substituted Allylic Indiums and Ketones
Srinivasarao Arulananda Babu; Makoto Yasuda; Akio Baba; Journal of Organic Chemistry 72 (2007) 10264–10267; doi:10.1021/jo701899j

data_4023114
_publ_section_title
;
 Diastereoselective Production of Homoallylic Alcohols Bearing
 Quaternary Centers from \g-Substituted Allylic Indiums and Ketones
;
_journal_name_full               'Journal of Organic Chemistry'
_journal_page_first              10264
_journal_page_last               10267
_journal_paper_doi               10.1021/jo701899j
_journal_volume                  72
_journal_year                    2007
_chemical_formula_sum            'C15 H20 O4'
_chemical_formula_weight         264.32
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_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             'Mon Feb 20 06:19:28 2006'
_audit_creation_method           'by teXsan'
_cell_angle_alpha                90.30(2)
_cell_angle_beta                 102.78(2)
_cell_angle_gamma                71.53(2)
_cell_formula_units_Z            4
_cell_length_a                   10.967(2)
_cell_length_b                   14.081(3)
_cell_length_c                   10.481(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      15.0
_cell_measurement_theta_min      13.6
_cell_volume                     1493.6(7)
_computing_cell_refinement       'MSC/AFC Diffractometer Control'
_computing_data_collection       'MSC/AFC Diffractometer Control'
_computing_data_reduction        'teXsan Ver. 1.11'
_computing_publication_material  'teXsan Ver. 1.11'
_computing_structure_refinement  'teXsan Ver. 1.10'
_computing_structure_solution    SIR92
_diffrn_measured_fraction_theta_full 1.0008
_diffrn_measured_fraction_theta_max 1.0008
_diffrn_measurement_device_type  'Rigaku AFC5R'
_diffrn_measurement_method       \w-2\q
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.038
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            9156
_diffrn_reflns_theta_full        30.02
_diffrn_reflns_theta_max         30.02
_diffrn_standards_decay_%        9.01
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.084
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.175
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.500
_exptl_crystal_size_min          0.150
_refine_diff_density_max         0.26
_refine_diff_density_min         -0.30
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.246
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     503
_refine_ls_number_reflns         8732
_refine_ls_R_factor_gt           0.0559
_refine_ls_shift/su_max          1.3762
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[\s^2^(Fo^2^) + (0.05000(Max(Fo^2^,0) + 2Fc^2^)/3)^2^]'
_refine_ls_weighting_scheme      calc
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_cod_data_source_block           babu430
_cod_original_sg_symbol_H-M      'P -1         '
_cod_original_formula_sum        'C15 H20 O4 '
_cod_database_code               4023114