Zn(ii) and Cu(ii) formamidine complexes: structural, kinetics and polymer tacticity studies in the ring-opening polymerization of ε-caprolactone and lactides
Akpan, Ekemini D.; Ojwach, Stephen O.; Omondi, Bernard; Nyamori, Vincent O.; New J. Chem. 40 (2016) 3499–; doi:10.1039/C5NJ03159A

data_7055372
_publ_section_title
;
 Zn(ii) and Cu(ii) formamidine complexes: structural, kinetics and polymer
 tacticity studies in the ring-opening polymerization of \e-caprolactone
 and lactides
;
_journal_issue                   4
_journal_name_full               'New J. Chem.'
_journal_page_first              3499
_journal_paper_doi               10.1039/C5NJ03159A
_journal_volume                  40
_journal_year                    2016
_chemical_formula_moiety         'C58 H84 N4 O8 Zn2'
_chemical_formula_sum            'C58 H84 N4 O8 Zn2'
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_audit_update_record
;
2016-01-23 deposited with the CCDC.
2016-02-10 downloaded from the CCDC.
;
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_cell_volume                     5913.7(2)
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_diffrn_ambient_temperature      173(2)
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_diffrn_measurement_device_type  'Bruker Smart ApexII CCD'
_diffrn_measurement_method       '\f and \w scans'
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'Re-crystallisation from solvent: Dichloromethane and hexane'
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0387P)^2^+4.6119P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7055371--7055374.cif.'
_cod_original_cell_volume        5913.6(2)
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_shelx_res_checksum              42029