Effect of Two Interacting Rings in Metalloporphyrin Dimers upon Stepwise Oxidations.
Dey, Soumyajit; Sil, Debangsu; Pandit, Younis Ahmad; Rath, Sankar Prasad; Inorganic chemistry 55 (2016) 3229–3238; doi:10.1021/acs.inorgchem.5b02065

data_4346750
_publ_section_title
;
 Effect of Two Interacting Rings in Metalloporphyrin Dimers upon Stepwise
 Oxidations.
;
_journal_issue                   7
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3229
_journal_page_last               3238
_journal_paper_doi               10.1021/acs.inorgchem.5b02065
_journal_volume                  55
_journal_year                    2016
_chemical_formula_sum            'C74 H92 F12 N8 O2 Sb2 Zn2'
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_space_group_name_Hall           '-C 2yc'
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_atom_sites_solution_hydrogens   mixed
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_cell_length_c                   21.678(5)
_cell_measurement_reflns_used    999
_cell_measurement_temperature    100(2)
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_diffrn_ambient_temperature      100(2)
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_diffrn_measured_fraction_theta_max 0.997
_diffrn_radiation_type           MoK\a
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_diffrn_reflns_av_unetI/netI     0.0468
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_diffrn_reflns_Laue_measured_fraction_max 0.997
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_diffrn_reflns_limit_l_min       -26
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_exptl_absorpt_correction_T_max  0.795
_exptl_absorpt_correction_T_min  0.724
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_exptl_absorpt_process_details   'SADABS 2.05 (Sheldrick, 2002)'
_exptl_crystal_colour            'dark red'
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_exptl_crystal_size_min          0.160
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_refine_ls_extinction_method     none
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_refine_ls_R_factor_all          0.0647
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0565P)^2^+29.2838P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_refine_ls_wR_factor_ref         0.1237
_reflns_Friedel_coverage         0.000
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_reflns_threshold_expression     'I > 2\s(I)'
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_shelx_estimated_absorpt_t_max   0.805
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