Synthesis of benzosultams <i>via</i> Ag(I)-catalyzed alkylative cyclization of vinyl sulfonamides.
Dupud, Raju; Merugu, Karthik Kumar; R, Remyachand; Ramesh, Remya; Organic & biomolecular chemistry 23 (2024) 103–107; doi:10.1039/d4ob01583e

data_7160225
_publ_section_title
;
 Synthesis of benzosultams <i>via</i> Ag(I)-catalyzed alkylative
 cyclization of vinyl sulfonamides.
;
_journal_issue                   1
_journal_name_full               'Organic &amp; biomolecular chemistry'
_journal_page_first              103
_journal_page_last               107
_journal_paper_doi               10.1039/d4ob01583e
_journal_volume                  23
_journal_year                    2024
_chemical_formula_moiety         'C19 H23 N O2 S'
_chemical_formula_sum            'C19 H23 N O2 S'
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_space_group_crystal_system      monoclinic
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_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2019/3
_audit_update_record
;
2024-09-27 deposited with the CCDC.	2024-11-07 downloaded from the CCDC.
;
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_diffrn_reflns_Laue_measured_fraction_full 0.998
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_diffrn_reflns_point_group_measured_fraction_full 0.998
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_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            colourless
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0595P)^2^+3.4397P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_total             3606
_reflns_threshold_expression     'I > 2\s(I)'
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_cod_depositor_comments
'Adding full bibliography for 7160225--7160226.cif.'
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_shelx_res_checksum              81504