Synthesis of cobalt(II) phenolate selenoether complexes to mimic hydrogenase-like activity for hydrogen gas production.
Upadhyay, Aditya; Kanika, ?; Mandhar, Yogesh; Batabyal, Monojit; Raju, Saravanan; Jaiswal, Svastik; Butcher, Ray J.; Kumar, Sangit; Dalton transactions (Cambridge, England : 2003) 52 (2022) 159–174; doi:10.1039/d2dt02820d

data_7711739
_publ_section_title
;
 Synthesis of cobalt(II) phenolate selenoether complexes to mimic
 hydrogenase-like activity for hydrogen gas production.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              159
_journal_page_last               174
_journal_paper_doi               10.1039/d2dt02820d
_journal_volume                  52
_journal_year                    2022
_chemical_formula_moiety         'C50 H38 Co N2 O2 Se4'
_chemical_formula_sum            'C50 H38 Co N2 O2 Se4'
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_audit_update_record
;
2022-11-03 deposited with the CCDC.	2022-11-09 downloaded from the CCDC.
;
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_diffrn_measurement_device_type  'Bruker APEX-II CCD'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0300P)^2^+8.0783P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
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_reflns_number_gt                2898
_reflns_number_total             3721
_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d2dt02820d2.cif
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'Adding full bibliography for 7711737--7711740.cif.'
_cod_original_cell_volume        4367.9(7)
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