Reactions of Ru(CCPh)(PPh3)2Cp* with tetracyanoethene: cycloaddition, formation of unusual η2-CNR complexes and oligomerisation via bridging cyanocarbon ligands
Bruce, Michael I.; Skelton, Brian W.; White, Allan H.; Zaitseva, Natasha N.; Journal of the Chemical Society, Dalton Transactions  (2001) 3627–; doi:10.1039/b105131h

data_7010905
_publ_section_title
;
 Reactions of Ru(C&#xE002;CPh)(PPh3)2Cp* with tetracyanoethene:
 cycloaddition, formation of unusual \h2-CNR complexes and
 oligomerisation via bridging cyanocarbon ligands
;
_journal_issue                   24
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              3627
_journal_paper_doi               10.1039/b105131h
_journal_year                    2001
_chemical_formula_sum            'C70 H61 N10 P Ru2'
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_cell_measurement_temperature    150
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_cell_measurement_theta_min      3.4
_cell_volume                     3035.4(3)
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_computing_molecular_graphics    xtal
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_diffrn_measurement_device_type
;
Bruker SMART CCD diffractometer
;
_diffrn_measurement_method       '\w scans'
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_diffrn_radiation_monochromator  graphite
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_diffrn_radiation_type           'Mo K\a'
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_diffrn_reflns_av_sigmaI/netI    .096
_diffrn_reflns_limit_h_max       17
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_exptl_absorpt_process_details
;
SADABS; Sheldrick, 1996
;
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_refine_ls_structure_factor_coef F
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_refine_ls_wR_factor_ref         .059
_reflns_d_resolution_high        .585
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_reflns_Friedel_coverage         0
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_reflns_limit_k_max              25
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_reflns_threshold_expression     'F    > 4.00 sig(F   )'
_cod_data_source_file            b105131h.txt
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_cod_original_sg_symbol_H-M      P_-1
_cod_original_formula_sum        'C70 H61 N10 P1 Ru2'
_cod_database_code               7010905