Carbon dioxide hydrosilylation promoted by cobalt pincer complexes.
Scheuermann, Margaret L.; Semproni, Scott P.; Pappas, Iraklis; Chirik, Paul J.; Inorganic chemistry 53 (2014) 9463–9465; doi:10.1021/ic501901n

data_4341038
_publ_section_title
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 Carbon dioxide hydrosilylation promoted by cobalt pincer complexes.
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_journal_issue                   18
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9463
_journal_page_last               9465
_journal_paper_doi               10.1021/ic501901n
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C24 H44 Co N O2 P2'
_chemical_formula_weight         499.47
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_cell_measurement_reflns_used    9934
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_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'ORTEP 3 (Farraguia, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR 92 (Giacavazzo, 1993)'
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_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX II CCD'
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_diffrn_reflns_limit_l_min       -29
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_exptl_absorpt_coefficient_mu    0.795
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_exptl_absorpt_correction_T_min  0.6905
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS v2008/1 (Bruker AXS)'
_exptl_crystal_colour            red
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_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Columnar
_exptl_crystal_F_000             1068
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_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0236P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0432
_refine_ls_wR_factor_ref         0.0434
_reflns_number_gt                6014
_reflns_number_total             6068
_reflns_threshold_expression     >2\s(I)
_cod_data_source_file            ic501901n_si_002.cif
_cod_data_source_block           mls1
_cod_depositor_comments
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The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Tetragonal' changed to 'tetragonal'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4341038--4341039.cif.
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_cod_original_sg_symbol_H-M      P4(1)
_cod_database_code               4341038