Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum-nitrogen heterocycles.
Drescher, Regina; Lin, Shujuan; Hofmann, Alexander; Lenczyk, Carsten; Kachel, Stephanie; Krummenacher, Ivo; Lin, Zhenyang; Braunschweig, Holger; Chemical science 11 (2020) 5559–5564; doi:10.1039/d0sc02032j

data_1558063
_publ_section_title
;
 Ring expansion of alumoles with organic azides: selective formation of
 six-membered aluminum-nitrogen heterocycles.
;
_journal_issue                   21
_journal_name_full               'Chemical science'
_journal_page_first              5559
_journal_page_last               5564
_journal_paper_doi               10.1039/d0sc02032j
_journal_volume                  11
_journal_year                    2020
_chemical_formula_moiety         'C47 H62 Al N3'
_chemical_formula_sum            'C47 H62 Al N3'
_chemical_formula_weight         695.97
_chemical_name_systematic        Terhphenylazid
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
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_space_group_name_Hall           '-P 2ybc'
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_audit_update_record
;
2020-02-28 deposited with the CCDC.	2020-05-14 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+19.2125P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2254
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_reflns_number_gt                7641
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_reflns_threshold_expression     'I > 2\s(I)'
_cod_data_source_file            d0sc02032j2.cif
_cod_data_source_block           ReDr024_a
_cod_depositor_comments
;Adding full bibliography for 1558058--1558063.cif.

 Adding full bibliography for 1558058--1558063.cif.
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1558063
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_shelx_estimated_absorpt_t_max   0.990
_shelx_res_checksum              25696