Structural isomers of M(dca)2 molecule-based magnets. Crystal structure of tetrahedrally coordinated sheet-like β-Zn(dca)2 and β-Co/Zn(dca)2, and the octahedrally coordinated rutile-like α-Co(dca)2, where dca‒ = dicyanamide, N(CN)2−, and magnetism of β-Co(dca)2
Jensen, Paul; Batten, Stuart R.; Fallon, Gary D.; Moubaraki, Boujemaa; Murray, Keith S.; Price, David J.; Chemical Communications  (1999) 177–; doi:10.1039/a808777f

data_7115193
_publ_contact_author
;
    Prof. K.S. Murray
    Department of Chemistry
    Monash University
    Clayton, Vic. 3168
    AUSTRALIA
;
_publ_section_title
;
 Structural isomers of M(dca)2 molecule-based magnets. Crystal structure
 of tetrahedrally coordinated sheet-like \b-Zn(dca)2 and \b-Co/Zn(dca)2,
 and the octahedrally coordinated rutile-like \a-Co(dca)2, where dca-- =
 dicyanamide, N(CN)2&#x2212;, and magnetism of \b-Co(dca)2
;
_journal_issue                   2
_journal_name_full               'Chemical Communications'
_journal_page_first              177
_journal_paper_doi               10.1039/a808777f
_journal_year                    1999
_chemical_formula_moiety         'C4 Co N6 '
_chemical_formula_sum            'C4 Co N6'
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_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      58
_symmetry_space_group_name_Hall  '-P 2 2n'
_symmetry_space_group_name_H-M   'P n n m'
_audit_creation_date             'Tue Oct 13 14:58:16 1998'
_audit_creation_method           'from TEXRAY.INF file'
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_cell_angle_beta                 90
_cell_angle_gamma                90
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_cell_length_b                   5.9748(3)
_cell_length_c                   7.4039(4)
_cell_measurement_reflns_used    0
_cell_measurement_temperature    123.2
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_cell_measurement_theta_min      0.0
_cell_volume                     311.57(2)
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_computing_data_reduction        teXsan
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_diffrn_measurement_device       'Nonius KappaCCD diffractometer'
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_diffrn_radiation_detector       CCD
_diffrn_radiation_monochromator  graphite
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_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      sigma
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_cod_data_source_file            808777f.txt
_cod_data_source_block           alphaCo(dca)2
_cod_original_sg_symbol_H-M      'P n n m    '
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_cod_database_code               7115193