Homolytic cleavage of Lawesson's reagent: N-heterocyclic carbene complexes of ArPS<sub>2</sub> (Ar = 4-CH<sub>3</sub>O-C<sub>6</sub>H<sub>4</sub>).
Soleimani, Ebrahim; Robertson, Katherine N.; Pye, Cory C.; Clyburne, Jason A. C.; Dalton transactions (Cambridge, England : 2003) 47 (2018) 6299–6303; doi:10.1039/c8dt00457a

data_7046006
_publ_section_title
;
 Homolytic cleavage of Lawesson's reagent: N-heterocyclic carbene
 complexes of ArPS<sub>2</sub> (Ar =
 4-CH<sub>3</sub>O-C<sub>6</sub>H<sub>4</sub>).
;
_journal_issue                   18
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6299
_journal_page_last               6303
_journal_paper_doi               10.1039/c8dt00457a
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         '2(C34 H45 N2 O P S2), C7 H8'
_chemical_formula_sum            'C75 H98 N4 O2 P2 S4'
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_space_group_crystal_system      monoclinic
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_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
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_audit_update_record
;
2017-12-05 deposited with the CCDC.
2018-04-05 downloaded from the CCDC.
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0430P)^2^+2.5958P] where P=(Fo^2^+2Fc^2^)/3'
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_reflns_threshold_expression     'I > 2\s(I)'
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'Adding full bibliography for 7046005--7046006.cif.'
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