Sodium mediated deprotonative borylation of arenes using sterically demanding B(CH<sub>2</sub>SiMe<sub>3</sub>)<sub>3</sub>: unlocking polybasic behaviour and competing lateral borane sodiation.
Tortajada, Andreu; Bole, Leonie J.; Mu, Manting; Stanford, Martin; Peñas-Defrutos, Marconi N; García-Melchor, Max; Hevia, Eva; Chemical science 14 (2023) 6538–6545; doi:10.1039/d3sc01705b

data_1569052
_publ_section_title
;
 Sodium mediated deprotonative borylation of arenes using sterically
 demanding B(CH<sub>2</sub>SiMe<sub>3</sub>)<sub>3</sub>: unlocking
 polybasic behaviour and competing lateral borane sodiation.
;
_journal_issue                   24
_journal_name_full               'Chemical science'
_journal_page_first              6538
_journal_page_last               6545
_journal_paper_doi               10.1039/d3sc01705b
_journal_volume                  14
_journal_year                    2023
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_symmetry_space_group_name_Hall  'C -2yc'
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;
2023-03-01 deposited with the CCDC.	2023-05-05 downloaded from the CCDC.
;
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'CrysAlisPro convention (1999,Acta A55,543-557)'
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;
        CrysAlisPro 1.171.40.61a (Rigaku Oxford Diffraction, 2019)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light colourless'
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;
 Flack x determined using 2919 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
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_refine_ls_structure_factor_coef Fsqd
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'w=1/[\s^2^(Fo^2^)+(0.0875P)^2^+1.0043P] where P=(Fo^2^+2Fc^2^)/3'
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'Adding full bibliography for 1569049--1569054.cif.'
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