Silicon-aryl cooperative activation of ammonia.
Doleschal, Martin Ernst; Kostenko, Arseni; Liu, Jin Yu; Inoue, Shigeyoshi; Chemical communications (Cambridge, England) 60 (2024) 13020–13023; doi:10.1039/d4cc04617j

data_7133789
_publ_section_title
;
 Silicon-aryl cooperative activation of ammonia.
;
_journal_issue                   89
_journal_name_full               'Chemical communications (Cambridge, England)'
_journal_page_first              13020
_journal_page_last               13023
_journal_paper_doi               10.1039/d4cc04617j
_journal_volume                  60
_journal_year                    2024
_chemical_compound_source        'see text'
_chemical_formula_moiety         'C54 H78 N3 P Si5, C5 H12'
_chemical_formula_sum            'C59 H90 N3 P Si5'
_chemical_formula_weight         1012.76
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
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_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
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_atom_sites_solution_secondary   difmap
_audit_update_record
;
2024-08-14 deposited with the CCDC.	2024-10-01 downloaded from the CCDC.
;
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_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device       ' \k-geometry diffractometer '
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_diffrn_measurement_method       ' phi- and omega-rotation '
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_diffrn_reflns_limit_l_min       -20
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_diffrn_reflns_reduction_process
;
;
_diffrn_reflns_theta_full        25.24
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_exptl_absorpt_coefficient_mu    0.183
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_exptl_crystal_colour            colorless
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_exptl_crystal_description       fragment
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_exptl_crystal_size_max          0.228
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_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'W=1/[\S^2^(FO^2^)+(0.0561P)^2^+7.2754P] WHERE P=(FO^2^+2FC^2^)/3'
_refine_ls_weighting_scheme      calc
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_cod_depositor_comments          'Adding full bibliography for 7133789.cif.'
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