Diamond: A gem mineral with properties for industrial use

Diamond
The most popular gem. The hardest known substance. An amazing number of uses.
Diamond Crystal: A gem-quality diamond crystal in the rock in which it was formed. It is an octahedral crystal with triangular dissolution features on its surface and an estimated weight of about 1.5 carats. From the Udachnaya Mine, Yakutia, Siberia, Russia. Specimen and photo by Arkenstone /Â www.iRocks.com.
What is Diamond?
Diamond is a rare, naturally occurring mineral composed entirely of carbon. Each carbon atom in a diamond is surrounded by four other carbon atoms and connected to each of them by strong covalent bonds - the strongest type of chemical bond. This simple, uniform, tightly-bonded arrangement yields one of the most durable and versatile substances known.
Diamond is the hardest known natural substance. It is also chemically resistant and has the highest thermal conductivity of any natural material. These properties make it suitable for use as a cutting tool and for other uses where durability is required.
Diamond also has special optical properties such as a high index of refraction, high dispersion, and an adamantine luster. These properties help make diamond the world's
most popular gemstone and enable it to be used in specialty lenses where durability and performance are required.
Because diamond is composed of the element carbon, many people believe that it must have formed from coal. This is still taught in many classrooms - but it is not true!
Physical Properties of Diamond
Most diamonds are brown or yellow in color. The jewelry industry has favored colorless diamonds or those that have a color so subtle that it is difficult to notice. Diamonds in vivid hues of red, orange, green, blue, pink, purple, violet, and yellow are extremely rare and sell for high prices. A few white, gray and black diamonds are also cut and used as gems. Most industrial-grade diamonds are brown, yellow, gray, green and black crystals that lack the color and clarity to be a nice gem.
How Do Diamonds Form?
Diamonds are not native to Earth's surface. Instead they form at high temperatures and pressures that occur in Earth's mantle about 100 miles below Earth's surface.
How do diamonds form?
A detailed article that explains the four sources of diamonds found at Earth's surface.
Most of the diamonds that have been discovered were delivered to Earth's surface by deep-source volcanic eruptions. These eruptions begin in the mantle, and on their way up they tear out pieces of mantle rock and deliver them to Earth's surface without melting. These blocks from the mantle are known as xenoliths. They contain diamonds that were formed at the high temperature and pressure conditions of the mantle.
People produce diamonds by mining the rock that contains the xenoliths or by mining the soils and sediments that formed as the diamond-bearing rocks weathered away.
Some diamonds are thought to form in the high-temperature/pressure conditions of subduction zones or asteroid impact sites. Some are delivered to Earth in meteorites. No commercial diamond mines have been developed in deposits with these origins.
Diamond Consumption in the United States In 2018, imports of diamonds into the United States for consumption totaled about $26 billion. Imports for consumption of all nondiamond gemstones totaled about $2.0 billion. These statistics clearly show that diamond is the most popular gemstone with U.S. consumers by an enormous margin. The United States accounted for about 35% of the world's diamond consumption, making it the leading diamond consumer.
Leading diamond producers: This chart shows the estimated annual production of gem-quality diamonds, in millions of carats, for the world's leading diamond-producing nations. Production levels during 2020 and 2021 were severely reduced at many mines by COVID-19 and supply chain problems. Graph by Geology.com. Data from USGS Mineral Commodity Summaries, Natural Resources Canada, and Kimberley Process participants. Learn about the countries that produce diamonds.
Gem vs. Industrial Diamonds
Gem diamonds are diamonds with color and clarity that make them suitable for jewelry or investment use. These diamonds are rare and make up a minor portion of worldwide diamond production. Gemstone diamonds are sold for their beauty and quality.
Natural diamond crystals have a specific gravity that ranges between approximately 3.4 to 3.6. This range exists because most diamonds contain impurities and have irregularities in their crystal structure. Gem-quality diamonds are the most perfect diamonds, with minimal impurities and defects. They have a specific gravity that is very close to 3.52.
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Industrial diamonds are mostly used in cutting, grinding, drilling, and polishing procedures. Here, hardness and heat conductivity characteristics are the qualities being purchased. Size, clarity, color and other measures of quality relevant to gemstones are not as important. Industrial diamonds are often crushed to produce micron-sized abrasive powders. Large amounts of diamonds that are of gemstone quality but have a shape or size that cannot be profitably cut enter the industrial diamond trade.
A demonstration of dispersion: How white light is separated into its component colors while passing through a prism. Diamonds have a high dispersion. NASA Image.
Diamond as a Gemstone
Diamonds are the world's most popular gemstones. Many times more money is spent on diamonds than on all other gemstones combined. Part of the reason for diamond's popularity is a result of its optical properties - or how it reacts with light. Other factors include its durability, fashion, custom, and aggressive marketing by diamond producers. Diamond serves as the birthstone for the month of April.
Diamonds have a very bright luster - the highest non-metallic luster - known as "adamantine." Their high luster gives them the ability to reflect a high percentage of the light that strikes their surface. This is one property that gives diamond gemstones their "sparkle." And, when a diamond is being fashioned into a gem, the facet angles are planned to reflect a maximum amount of light from its internal surfaces.
Diamond also has a high dispersion. As white light passes through a diamond, this high dispersion causes that light to separate into its component colors. Dispersion is what enables a prism to separate white light into the colors of the spectrum. This property of dispersion is what gives diamonds their colorful "fire."
Argyle diamonds: Octahedral diamond crystals from the Argyle Mine of Western Australia. The Argyle Mine produces diamonds in a wide range of colors. Most Argyle diamonds are brown, some are near colorless, and a very rare number are red, pink, blue or violet. The Argyle Mine is the world's only consistent producer of pink diamonds. Rare red, blue, and violet diamonds are also found at Argyle. Image copyright 2016Â Rio Tinto.
Diamond Gemstone Quality
The quality of a diamond that has been faceted into a gem is primarily determined by four factors: color, cut, clarity, and carat weight. A standardized method of assessing diamond quality was developed in the 1950s by the Gemological Institute of America and is known as "The 4Cs of Diamond Quality" [5].
Color: Most gem-quality diamonds range from colorless to slightly yellow, brown, or gray. The most highly regarded and valuable diamonds are those that are completely colorless. These are the ones sold for the highest prices. However, another category of diamond gemstone is increasing in popularity. These are colored diamonds, which occur in a variety of hues including red, pink, yellow, orange, purple, blue, green and brown.
Fancy Color Diamonds
An article about the popularity of colored diamonds and how they obtain their wonderful colors.
The value of colored diamonds is based upon the intensity, purity and quality of their color. Those with a saturated, vivid color are called "fancy-color diamonds" or "fancies". On average, only one diamond in 10,000 has a color that earns the "fancy" designation. This rarity makes fancy-color diamonds extremely valuable. Some of them have sold at auction for over one million dollars per carat. They are some of the world's most valuable and spectacular diamonds.
Clarity: The ideal diamond is free from fractures and inclusions (particles of foreign material within the gem). These detract from the appearance of the gem and interfere with the passage of light. When present in large numbers, dark colors, obvious positions or sizes then will significantly degrade the appearance of a cut gem and lower its value. They can also reduce the strength of the stone.
Cut: The quality of design and craftsmanship used in cutting a diamond is what determines its appearance. The angles to which the facets are cut, the proportions of the design, and the quality of the polishing are what determine its face-up appearance, brilliance, scintillation, pattern, and fire. Ideal stones are perfectly polished to be highly reflective and emit a maximum amount of fire. Corresponding faceted faces are equal in size and identical in shape. And, the edges of each faceted face meet perfectly with each of its neighbors.
Carat: Diamonds are sold by the carat (a unit of weight equal to 1/5th of a gram or 1/142nd of an ounce). Small diamonds usually cost less per carat than larger stones of equal quality. This is because very small stones are very common and large stones are exceptionally rare.
Industrial Diamonds: Small diamonds, less then 1 millimeter in size, that are suitable for making abrasive granules for industrial use. Industrial diamonds might be polycrystalline, have numerous inclusions, have poor clarity, contain fractures, have a small size, or have other characteristics that disqualify them from gem or technology uses.
Cubic Diamond Crystal: A green diamond crystal. The color and cubic crystal shape are natural. Many natural diamond crystals are cubic or octahedral in shape. This diamond is about 4 millimeters across and is suitable for industrial use.
Diamond Drill Bit: A drill bit used in the drilling of oil wells. Each of the cutting tips has small grains of diamond embedded in the metal. These cut their way through the rock as the bit turns. Image copyright iStockphoto / mikeuk.
Diamond concrete saw: A concrete saw with a diamond blade of about three feet in diameter. Saws of this type are usually cut under a water spray that cools the blade, removes cuttings, and prevents the production of airborne dust. Saws of this type are a common sight where highway or other concrete work is being done. US Air Force Image.
Diamonds Used as an Abrasive
Because diamonds are very hard (ten on the Mohs scale), they are often used as an abrasive. Most industrial diamonds are used for that purpose. Small particles of diamond are embedded in saw blades, drill bits, and grinding wheels. These tools are then used for cutting, drilling, or grinding hard materials. They might also be ground into a fine powder and made into a "diamond paste" that is used for very fine grinding or polishing.
As early as the 16th century, gem cutters began using small particles of diamond to cut and polish other diamonds. Diamond is the only abrasive that can do that job. Now, in the 21st century, lasers are used to cut many diamonds, but small particles of diamond are still used for all diamond polishing.
Carbonado Diamonds
are a rare variety of diamonds. They have the same hardness as diamond but are much tougher because they are polycrystalline.
The worldwide demand for industrial diamonds greatly exceeds the supply that can be obtained through mining. A shortage of diamond abrasives began occurring during World War II. In the 1950s, methods of producing synthetic diamonds were discovered. Soon, the methods of making synthetic diamonds were so efficient that synthetic diamond abrasives were more reliably available and less expensive than diamond abrasives made from natural diamonds. Today, synthetic diamond abrasives are made in hundreds of factories and their cost is under $1 per carat - and they perform just as well as abrasives made from natural diamonds in industrial use.
The best way to learn about minerals is to study with a collection of small specimens that you can handle, examine, and observe their properties. Inexpensive mineral collections are available in the Geology.com Store. Image copyright iStockphoto / Anna Usova.
Other Uses of Diamonds
Most industrial diamonds are used as abrasives. However, diamonds are used in many other applications.
Diamond windows
are made from thin diamond membranes. They are used to cover openings in lasers, x-ray machines, and vacuum chambers. They are transparent, very durable, and resistant to heat and abrasion.
Diamond speaker domes
enhance the performance of high-quality speakers. Diamond is a very stiff material, and when made into a thin dome it can vibrate rapidly without the deformation that would degrade sound quality.
Heat sinks
are materials that absorb or transmit excess heat. Diamond has the highest thermal conductivity of any material. It is used to conduct heat away from the heat-sensitive parts of high-performance microelectronics.
Low-friction microbearings
are needed in tiny mechanical devices. Just as some watches have jewel bearings in their movements, diamonds are used where extreme abrasion resistance, durability, and reliability are needed.
Wear-resistant parts
can be produced by coating surfaces with a thin coating of diamond. In this process, carbon is converted into a vapor that deposits diamond on the surface of parts prone to wear.
Mohs - Vickers hardness comparison: This chart compares the hardness of index minerals of the Mohs hardness scale (an integer scale) with their Vickers hardness (a continuous scale). Mohs hardness is a resistance to being scratched, while Vickers hardness is a resistance to indentation under pressure. The graph shows the great difference between the Vickers hardness of corundum and diamond - which are only one unit apart on the Mohs hardness scale.
How Hard Is Diamond?
Although diamond is known as the world's hardest natural material and has been assigned a hardness of 10 on the Mohs hardness scale, that information is an oversimplification. Diamond crystals vary in hardness by direction.
Mineral Hardness Scales
Mineral
Mohs
Vickers (kg/mm2)
Talc
1
27
Gypsum
2
61
Calcite
3
157
Fluorite
4
315
Apatite
5
535
Orthoclase
6
817
Quartz
7
1161
Topaz
8
1567
Corundum
9
2035
Diamond
10
10000
The direction of greatest hardness is parallel to the octahedral crystal planes. When diamond crystals are being cut and polished into gems, it is very difficult to cut them in that direction with a diamond saw. So instead of using a diamond saw or the traditional practice of breaking them by cleaving, much of this work is now done by laser sawing.
Facets cut parallel to the octahedral crystal direction are also difficult to polish, so cutters either change direction or risk leaving a "lizard skin" texture on the facet.
The softest direction in a diamond crystal is parallel to the cubic planes. The best polishing is done on facets that are parallel to that direction. Although that is the softest direction in a diamond, the hardness is several times harder than corundum, the second-hardest mineral of the Mohs hardness scale.
Diamond simulants: The photos above compare strontium titanate, moissanite, and cubic zirconia with diamond. Moissanite and cubic zirconia have dispersions that are competitive with diamond, and the dispersion of strontium titanate is over-the-top. In the photo above, the strontium titanate is a 6-millimeter round. The other stones are 4-millimeter rounds. This difference in size does give strontium titanate an advantage.
Diamond Simulants
Diamond simulants are materials that look like diamond, but they have different chemical compositions. Diamond simulants can be natural materials such as colorless zircon or sapphire. More often they are man-made materials such as cubic zirconia (ZrO2), moissanite (SiC), YAG (yttrium aluminum garnet Y3Al5O12), or strontium titanate (SrTiO3).
Synthetic diamonds of various colors grown by the high-pressure high-temperature technique. Image by Wikipedia contributor Materialscientist.
Synthetic Diamonds
Diamond is a very valuable material, and people have been working for centuries to create them in laboratories and factories. Synthetic diamonds are man-made materials that have the same chemical composition, crystal structure, optical properties and physical behavior as natural diamonds. Other names used for synthetic diamonds include: "lab-grown," "lab-created," and "man-made". These names properly indicate that the diamonds were not naturally formed in the Earth, but were instead created by people.
The first commercially successful synthesis of diamond was accomplished in 1954 by workers at General Electric. Since then, many companies have been successful at producing synthetic diamond suitable for industrial use. Today, most of the industrial diamond consumed is synthetic, with China being the world leader with a production of over 4 billion carats per year. Most important industrialized nations are now able to produce synthetic diamonds for industrial use in factories.
In the last decade, several companies have developed technology that enables them to produce gem-quality laboratory-created diamonds up to a few carats in size in several different colors - including colorless. Some companies use high-pressure, high-temperature methods - these are known as HTHP diamonds. Others create diamonds using a chemical vapor deposition process - these are known as CVD diamonds. These man-made gems are being sold in jewelry stores and on the internet at a significant discount to natural stones of similar quality and size. They have a beautiful appearance and an attractive price tag. Synthetic diamonds are required to be sold with a disclosure that enables the buyer to clearly understand that they were made by people.
[5] Diamond Quality Factors: An explanation of how diamonds are evaluated using the 4Cs. Gemological Institute of America. Last accessed August 2022.
Consumers and Synthetic Diamonds
Synthetic diamonds have been the dominant type of diamond in industrial applications since the end of the 20th century. Most of the diamonds used to make abrasives and cutting tools are now synthetic. Virtually all diamonds used to make windows, speaker domes, heat sinks, low-friction microbearings, wear-resistant parts, and other technology products are now synthetic.
Synthetic diamonds for these purposes are much less costly than mined diamonds, have more consistent properties, and are becoming available in made-to-order specifications. There are no emotional barriers for synthetic diamonds to replace mined diamonds in these uses.
In the jewelry industry, there is considerable debate about the willingness of consumers to accept synthetic diamonds. Some believe that jewelry consumers want "real diamonds" - meaning "mined diamonds." Others believe that synthetic diamonds will be favored by people who dislike the human rights and environmental problems associated with some of the diamonds that are mined. However, the real motivator will likely be price. Currently, many synthetic diamonds made for jewelry use have a 30 to 40% price advantage on mined diamonds. This will likely be the greatest motivator for consumers to accept synthetic diamonds.
Observation and speculation.... If you walk into almost any mall jewelry store and look into the cases where ruby, sapphire, and emeralds are sold, you will often see that most of the stones offered are synthetic. A person with very little training can often recognize them by their bright color and superb clarity. The synthetic materials have a superior appearance, and their prices are small compared to natural gems of similar size and apparent quality. Consumers get better appearance for a lower price, and the majority of them accept that transaction on the low-price end of the price range.
The battle for emotion and sales dominance in the popular-price ruby, sapphire, and emerald market was won by synthetics decades ago. In the next decade the diamond market might also move in favor of synthetics. It's already starting as synthetic diamonds take a very visible position in the market. The price of synthetic diamonds will likely decline as more and more machines to produce them are placed into service, become more efficient, and competition among manufacturers intensifies. Eventually, the price differential between natural and synthetic diamonds will be greater than many customers will be able to ignore, and they will buy synthetic. If the next world-class advertising campaign promotes synthetic diamonds, a huge shift in consumer demand might occur. That world-class advertising campaign might be Lightbox, which offers "white" and colored diamonds at the unheard-of price of $800 per carat.